Food Additives and Flavoring

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    Presented By:MUHAMAD NASRULLAH BIN ROSLANNOURUL EMMILIA BINTI MOHD FAZLIANIS SYAHIRAH BINTI AHMAD FUADKHALIL AFIF BIN JAMIRANNURHANIN AQILA BINTI MOHAMMED NOOR

    FooD aDDITIVEs AnD fLAVORINg

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    Food Additives

    Food Colouring

    Glazing Agent

    Sweeteners Antioxidant

    Thickeners

    Antifoaming Agents

    Food Flavouring

    Used for taste

    Used for smell

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    FOOD COLOURING

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    Food colour Food color is any substance that is added

    to food or drinkto change its color.

    There are majorthreecategories offood colors; 1) Natural colors

    2) Synthetic colors

    3) Lakes and dyes

    http://en.wikipedia.org/wiki/Foodhttp://en.wikipedia.org/wiki/Drinkhttp://en.wikipedia.org/wiki/Colorhttp://en.wikipedia.org/wiki/Colorhttp://en.wikipedia.org/wiki/Drinkhttp://en.wikipedia.org/wiki/Food
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    Natural foodcolour

    Natural Food Color is any dye,pigment or any other substanceobtained from vegetable, animal,mineral, or source capable of coloring

    food, drug, cosmetic or any part ofhuman body, colors come from varietyof sources such as seeds, fruits,vegetables, algae & insect.

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    example

    BETANIN: IUPAC name:4-(2-(2-carboxy-5-(beta-D-glucopyranosyloxy)-

    2,3-dihydro-6-hydroxy-1H-indol-

    1-yl)ethenyl)-2,3-dihydro-(S-

    (R*,R*))-2,6-pyridinedicarboxylic

    acidMolecular formula :C24H27N2O13

    Used forcoloring meat and sausages.

    For coloring ice cream and powdered softdrinkbeverages

    Betanin is also used in soups as wellas tomato and bacon products..

    Used forcoloring meat and sausages.

    For coloring ice cream and powdered softdrinkbeverages

    Betanin is also used in soups as wellas tomato and bacon products..

    http://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry_nomenclaturehttp://en.wikipedia.org/wiki/Chemical_formulahttp://en.wikipedia.org/wiki/Chemical_formulahttp://en.wikipedia.org/wiki/Chemical_formulahttp://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry_nomenclaturehttp://en.wikipedia.org/wiki/International_Union_of_Pure_and_Applied_Chemistry_nomenclature
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    exampleCARAMEL It is a soluble food coloring, made by a

    carefully controlled heat treatment ofcarbohydrates in a processcalled caramelization.

    Its color ranges frompale yellow to amber todark brown.

    Beverages such as cola use caramelcoloring, and it is also used as food coloring.

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    Synthetic foodcolouringalso known as Artificial

    Food Coloursmanufactured

    chemically and are themost commonly useddyes in the food,

    pharmaceutical andcosmetic industries.

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    example

    It is also known, FD&C Yellow 5, Acid Yellow 23, Food

    Yellow 4. Tartrazine is derived from petroleum. It is water soluble.

    Used in Desserts and sweets, Beverages, Snacks,Condiments and spreads &Other processed foods

    TARTRAZINEIUPAC name

    Trisodium (4E)-5-oxo-1-(4-

    sulfonatophenyl)-4-[(4-

    sulfonatophenyl) hydrazono]-3-

    pyrazolecarboxylate

    Molecular formulaC16H9N4Na3O9S2

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    example

    often found in:ice cream, canned processed peas, packetsoups, bottled food colorings, icings, icepops, blue raspberry flavored products,dairy products, sweets and drinks, especially theliqueur blue curacao.

    BRILLIANT BLUE FCF IUPAC name: ethyl - [4 - [ [4 -[ethyl -[(3 - sulfophenyl)methyl] amino] phenyl] - (2 -

    sulfophenyl) methylidene] - 1 -

    cyclohexa - 2, 5 - dienylidene]

    - [(3 - sulfophenyl) methyl]

    azaniumMolecular formula:

    C37H34N2Na2O9S3

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    DyesandlakesColor additives are available for use in food aseither "dyes" or lake pigments (commonly known as"lakes").

    Dyes dissolve in water, but are not soluble in oil.Manufactured as powders, granules, liquids orother special purpose forms.

    Lakes are made by combining dyes with salts to

    make insoluble compounds. Lakes tintby dispersion. Lakes are not oil soluble, but are oildispersible

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    example

    ANILINE YELLOW:

    IUPAC name:

    4-PhenyldiazenylanilineMolecular formula:

    C6H5N=NC6H4NH2

    Aniline Yellow is a yellow azo dye and an aromaticamine. It is a derivate of azobenzene. It has theappearance of an orange powder. It is a carcinogen.

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    example

    SUDAN I:

    It is alysochrome, a diazo-conjugate dye with a chemical formula

    of 1-phenylazo-2-naphthol. Sudan I is a powdered substancewith an orange-red appearance. Sudan I has also been adopted for coloring various foodstuffs,

    including particular brands of curry powder and chili powder

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    Glazing agent

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    Glazing agents also known as polishing agents

    are food additives that provide a shinyappearance or protective layer to the product.

    Most glazing agents are based on natural waxessuch as beeswax, carnauba wax but can also be

    made from artificial waxes such as Crystallinewax which are produced from de-oiling

    petrolatum.

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    Source(s) DerivedFrom

    Other NaturalAnimal Plant Chemical (Synthetic)

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    Naturalor Artificial? Both (Can be derived from Natural & Artificial

    Sources)

    Common glazing agents are:

    -Stearic acid or fatty acid

    -Beeswax-white and yellow

    -Carnauba wax

    -Shellac

    -Petrolatum or Petroleum jelly

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    SWEETENERS

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    What are sweeteners?

    Food additive that

    duplicates the effect ofsugar in taste.

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    XYLITOL SORBITOL

    Are natural sugar substitutes for food use.Found in berries, fruit, vegetables &

    mushrooms.

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    XYLITOL

    Categorized as polyalcohol (alditol).

    IUPAC name: pentane-1,2,3,4,5-pentol.

    Chemical formula: (CHOH)3(CH2OH)2

    Produced by hydrogenation of xylosewhich converts the sugar (an aldehyde)

    into a primary alcohol.

    xylose xylitol

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    SORBITOL

    Also known as gluticol (a sugar alcohol).

    Obtained by reduction of glucose

    (changing the aldehyde group to a

    hydroxyl group). IUPAC name: hexane-1,2,3,4,5,6-hexol.

    glucose sorbitol

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    ANTIOXIDANTS

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    Used as food additivesto help guard against

    food deterioration. It inhibits the oxidation

    of the foodconstituents.

    What are antioxidants used for?

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    Natural Antioxidants

    Ascorbic Acid(vitamin c)

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    Ascorbic Acid

    Water soluble

    Cannot protect fats from oxidation The fat-soluble esters of ascorbic acid with long-chain fatty acids

    can be used as food antioxidants

    Sodium Ascorbate Calcium Ascorbate Potassium Ascorbate

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    Tocopherols

    Are s class of chemical compounds of which may have vitaminE activity.

    It is a series of organic compounds consisting of variousmethylated phenols.

    It prevents oils from going rancid.

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    Synthetic Antioxidants

    Propyl gallate, or propyl 3,4,5-trihydroxybenzoate isan ester formed by the condensation of gallic acid and propanol.

    tert-Butylhydroquinone is an aromatic organic compound whichis a type of phenol. It is a derivative of hydroquinone, substituted

    with tert-butyl group.

    Butylated hydroxyanisole (BHA) is an antioxidant consisting of amixture of two isomeric organic compounds, 2-tert-butyl-4-

    hydroxyanisole and 3-tert-butyl-4-hydroxyanisole. It is a waxy solidused as a food additive.

    Butylated hydroxytoluene (BHT), also knownas butylhydroxytoluene, is a lipophilic (fat-soluble) organic

    compound, chemically a derivative of phenol.

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    Thickeners

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    Also known as thickeningagents

    The term applied tosubstances which increasethe viscosity of a solution orliquid/solid mixture without

    substantially modifying itsother properties.

    Improve the suspension ofother ingredients or

    emulsions which increasesthe stability of the product.

    http://en.wikipedia.org/wiki/Viscosityhttp://en.wikipedia.org/wiki/Suspension_(chemistry)http://en.wikipedia.org/wiki/Emulsionhttp://en.wikipedia.org/wiki/Emulsionhttp://en.wikipedia.org/wiki/Suspension_(chemistry)http://en.wikipedia.org/wiki/Viscosity
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    Where we use thickeners??

    Food

    Mechanical and thixotropic agents

    Cosmetics

    Paint and printing thickenersPetrochemistry

    Explosives and incendiaries

    APPLICATION OF THICKENERS

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    APPLICATION OF THICKENERS

    in food

    Food thickeners frequently are based on proteins.

    A flavourless powdered starch used for this purposeis a fecula (comes from substance that has beentreated).

    Example of substance to get starch:ArrowrootCorn starchKatakuri starch(one of Lilys family)Potato starchSagoTapioca

    http://en.wikipedia.org/wiki/Starchhttp://en.wikipedia.org/wiki/Cornstarchhttp://en.wikipedia.org/wiki/Arrowroothttp://en.wikipedia.org/wiki/Cornstarchhttp://en.wikipedia.org/wiki/Erythronium_japonicumhttp://en.wikipedia.org/wiki/Potato_starchhttp://en.wikipedia.org/wiki/Tapiocahttp://en.wikipedia.org/wiki/Sagohttp://en.wikipedia.org/wiki/Tapiocahttp://en.wikipedia.org/wiki/Tapiocahttp://en.wikipedia.org/wiki/Sagohttp://en.wikipedia.org/wiki/Sagohttp://en.wikipedia.org/wiki/Tapiocahttp://en.wikipedia.org/wiki/Potato_starchhttp://en.wikipedia.org/wiki/Potato_starchhttp://en.wikipedia.org/wiki/Erythronium_japonicumhttp://en.wikipedia.org/wiki/Erythronium_japonicumhttp://en.wikipedia.org/wiki/Erythronium_japonicumhttp://en.wikipedia.org/wiki/Cornstarchhttp://en.wikipedia.org/wiki/Cornstarchhttp://en.wikipedia.org/wiki/Arrowroothttp://en.wikipedia.org/wiki/Arrowroothttp://en.wikipedia.org/wiki/Cornstarchhttp://en.wikipedia.org/wiki/Starch
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    Different thickeners may be more or less suitable in a given

    application, due to differences in taste, clarity, and their responses to

    chemical and physical conditions.

    Gelling agents are food additives used to thicken and stabilize various

    foods, like jellies, desserts and candies.

    The agents provide the foods with texture through formation of a gel.

    Some stabilizers and thickening agents are gelling agents.

    Typical gelling agents include:

    natural gums

    starches

    pectin

    agar-agar

    gelatin

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    Anti-Foaming

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    A defoamer or an anti-foaming agent is a

    chemical additive thatreduces and hinders theformationof foam in industrial

    process liquids. An additive which

    reduces the surfacetension of a solution or

    emulsion, thus inhibitingor modifying theformation of a foam.

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    The anti-foaming can be classified into several

    examples, such as:i. Oil based defoamers

    ii. Powder defoamers

    iii. Water based defoamersiv. Silicone based defoamers

    The foam must be prevented from forming

    because it may lead to some industrial

    problems.

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    Example of industrial problems:

    1. Mechanical problem factors Mechanical factors that may generate from foam and

    entrapped air:

    o Leaky seals on pumps

    o High pressure pumps

    2. Foam in process and coolant liquids Foam, entrained and dissolved air that are present in

    coolants and processing liquids, may cause variouskinds of problems:

    o Bacterial growth

    o Reduced capacity of pumps and storagetanks

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    APPLICATION OF anti-

    foaming in food

    To curb effusion oreffervescence in preparationor serving.

    The agents are included in a variety of foodssuch as chicken nuggets in the formof polydimethylsiloxane (a type of silicone).

    Silicone oil is also added to cooking oil to preventfoaming in deep-frying.

    http://en.wikipedia.org/wiki/Effusionhttp://en.wikipedia.org/wiki/Effervescence_(chemistry)http://en.wikipedia.org/wiki/Chicken_nuggetshttp://en.wikipedia.org/wiki/Polydimethylsiloxanehttp://en.wikipedia.org/wiki/Siliconehttp://en.wikipedia.org/wiki/Siliconehttp://en.wikipedia.org/wiki/Polydimethylsiloxanehttp://en.wikipedia.org/wiki/Chicken_nuggetshttp://en.wikipedia.org/wiki/Chicken_nuggetshttp://en.wikipedia.org/wiki/Effervescence_(chemistry)http://en.wikipedia.org/wiki/Effusion
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    TASTE

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    Glutamic acid salts

    most commonly usedflavor enhancers

    Present in wide varietyof food such ascheese & soy sauce.

    Used as flavor

    enhancer in its saltform, monosodiumglutamate (MSG)

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    Guanylic acid salts

    Nucleotide saltstypically combined withglutamic acid as flavorenhancers.

    often found in instantnoodles, potato chips

    and snacks, savouryrice, tinned vegetables,cured meats, andpacket soup.

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    Acetic acid

    Gives vinegar its sour tasteand distinctive smell.

    As an acidity regulator andas a condiment.

    Ascorbic acid

    Found in oranges and green

    peppers and gives a crisp,slightly sour taste. Betterknown as vitamin C.

    Used as antioxidant.

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    Fumaric acid

    Has a fruit-like taste.

    Used in beverages, jellies,

    jams, breads and bakingpowders.

    Citric acid

    Found in citrus fruits and gives themtheir sour taste.Add an acidic, or sour, taste to foodsand soft drinks.

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    Lactic acid

    Found in various milkor fermented products andgive them a rich tartness.

    Used in beer brewing.

    Malic acid

    Found in apples and gives

    them their sour/tart taste.

    The source of extremetartness in most candies.

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    Phosphoric acid

    Used in all Cola drinksto give an acid taste.

    used to acidify foodsand beverages such

    as various colas. provides a tangy or

    sour taste.

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    Tartaric acid

    Found in grapes and

    wines and gives them atart taste.

    Combined with bakingsoda to function as aleavening agent.

    One of the main acidsfound in wine.

    Give sour taste

    Act as antioxidant

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    SMELL

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    Diacetyl

    butanedione or butane- 2,3-dione

    added to some foods to

    impart a buttery flavour

    manufacturers of artificial

    butter

    flavouring, margarines or

    similar oil-based products

    typically add diacetyl

    Isoamyl acetate

    3-methylbut-1-yl ethanoate used to confer banana

    flavour in foods solution of isoamyl acetate

    in ethanol thatis used as an artificial flavour.

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    Benzaldehyde Cinnamic aldehyde

    Simplest aromatic aldehydeAlmondlike-odour

    gives cinnamon its flavour and odour. flavouring in chewing gum, icecream, candy, and beveranges can be use as food adulterants powdered beechnut husk aromatizedwith cinnamaldehyde can be marketedas powdered cinnamon

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    Ethyl propionate Methyl anthranilate

    methyl 2- aminobenzoate orcarbomethoxyaniline, Isan ester of anthranilic acid flavouring of candy, soft drinks gumsand drugs

    Ethyl ester ofproprionic acidPineapple-like-odour

    (fruity odour)

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    Limonene Ethyl decadienoate

    Pear ester andorganic chemicalcompound used inflavours

    Pear-like-taste andodors

    used in natural flavorsand fragrances for its

    intense fruity flavor

    1-methyl-4-(1-methylethenyl)-cyclohexene

    strong smell of oranges

    D-limonene is used in foodmanufacturing and some

    medicines

    to relieve gastroesophageal

    reflux disease and heartburn

    Eth l lt l

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    Allyl hexanoate

    Ethyl maltol

    prop-2-enyl hexanoate

    pineapple flavors adds a sweet juicy note tocitrus flavors

    2-Ethyl-3-hydroxy-4-pyranonemore commonflavorant maltol byreplacement of the methylgroup by an ethyl groupCaramalized sugar andcooked fruit.

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    Ethylvanilin

    Methyl salicylate3-ethoxy-4-hydroxybenzaldehyde,bourbonal

    Used in production in chocolate

    (oil of wintergreen orwintergreen oil)is an organic ester that is naturallyproduced by many species of plants

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    The END

    Thank you for your consideration