FLUOR DANIEL GTI S00076040 • / > h^-

FLUOR DANIEL GTI

• / > h^-f. ^

S00076040SUPERFUND RECORDS

May 28, 1 996 —— " ~ '' " '' ~"

Mr. Bruce MorrisonEnvironmental EngineerUnited States Environmental Protection Agency - Region VIISuperfund Branch726 Minnesota AvenueKansas City, KS 66101

RE: Response to Memorandum Regarding In-Depth Data Review of Appendix E and H,Site Characterization Report, Former Chemical Commodities Site, Olathe, Kansas.

Dear Mr. Morrison:

Summarized below are responses to items 1 , 3 and 4 listed under Other Issues in the memorandumfrom Mr. Douglas Brune to yourself regarding the in-depth data review of Appendices E and H, SiteCharacterization Report for the former Chemical Commodities, Inc. (CCI) site, Olathe, Kansas.Supporting data from the laboratory for issues 1 and 3 are also attached.

Issue 1. 1 ,2,3-trichloropropane and 1 ,2-dibromo-3-chloropropane were in the continuing calibrationstandard mixture; however, the areas for these two compounds were inadvertently not integrated whenthe standards were run. Therefore, on the continuing calibration summary report no response factor isshown for these two compounds. The associated continuing calibration standard quantitation reportshows that the two compounds were analyzed. Samples run on this day were reruns only. Thequantitation reports for the continuing calibration standard are attached. Also, 1 ,2,3-trichloropropaneand 1 ,2-dibromo-3-chloropropane were not identified in any of the remaining samples collected andanalyzed from the CCI site.

Issue 3. The continuing calibration data for 11/16/95 is attached.

Issue 4. The instruments are calibrated with microgram per liter 0/g/l) standards. When samples areanalyzed the dilution factor and sample weight/volume are entered into the instrument software. Theinstrument software does not routinely print out these input values; however, the information is recordedon the preparation logs. Therefore, the corrected value presented on the raw data represents the resultfor the sample with dilution factors (and sample weight for soils) already factored into the result.However, due to a limitation in the software, the units on the printout cannot be changed to milligramsper kilogram (mg/kg) for soils because the instrument was calibrated in /yg/l. The raw data presentedto the client has a corrected concentration reported with //g/l units but, in fact, the results are in theunits of mg/kg because of the limitations of the software.

L4726 4820 McGrath Street, Suite 100 / Ventura, CA 93003 USA (805) 644-9811 FAX (805) 644-3260

FLUOR DANIEL GTI

If you have any other questions please do not hesitate to contact us.

Sincerely,Fluor Daniel GTI, Inc.

Debra HagemeierSenior Chemist

c: Michael Sullivan (w/ enc.); Rocketdyne

Loveriza Sarmiento. PhDManager, Risk Assessment Services

United States Environmental Protection Agency - Region VIIMr. Bruce Morrison

May 28, 19962

Mil

Case to>'«

Contractor' GTEL

Contract No'

Instrument ID' 5970 flSD HP UOft

Calibration Date' 11/19/5-5

Time' IB'48

Laboratory ID' >V5265

Initial Calibration Date' 11/01/95

Minimum RF for SPCC is .1

Compound RF

Maximum it Diff for CCC is 25*

RF IDiff CCC SPCC

ChloronethaneDichlorodif luoromethaneVinyl chlorideBroBomethaneChloroethaneTrichlorof luoromethaneHllul chlorideftcroleinflcetone1.1-DichloroethenelodonethaneHethylene chlorideCarbon disulfideHcrylonitrilellethyl-tertbutyl ethertrans-1.2-Qichloroethene1,1-DichloroethaneV i n v l acetate2-ButanonePropionitrile2,2-Dichloropropanecis-l,2-DichloroetheneMethacrylonitrileChloroformBroHochloromethaneDiBROMOFLUOROMETHftNETetrahydrofuran1.1,1-Trichloroethane1,1-DichloropropeneCarbon tetrachloridel,2-OICHLOROETHftNE-D41.2-Dichloroethane

,58206.65568.29525.57085.22529

1.18996.56955.0224?.11558.40855.62851.44559

1.06967,10811

1.51065.44574.91111.75458.05659,05607.85525.51675.150211.15069.51167.95215.155421.06528.80060.62515.46511.52665

.57455

.57568

.27852

.56552

.257841.12566.67460.02002.15595.40667.85620.45451

1.12064.10705

1.54187.47576.99505.84445.05915.05225.98592.55855.15521

1.17797.51591.89092.12945

1.06105.67007.63289.45411.56845

1.52 »«40.905.66 «2.056.525.40

14.4311.0155.16

.41 «5.542.422.84,98

2.586.759.21 ««14.966.9910.5918.044.182.514.18 «1.564.422.98.40

8.681.571.947.94

iConc=200.00)

(Conc=50.00'l

(Conc=50.00)

RF - Response Factor from daily standard file at 100.00 ug/L

RF - fluerage Response Factor froia Initial Calibration Form UI

KDiff - I Difference from original average or curve

CCC - Calibration Check Compounds (») SPCC - Systen Performance Check Compounds (*«)

Form UII Page 1 of 3

"" "—continuing ijiiDraiion tnecr.——————————————HSL Compounds

Case No: Calibration Date: 11/19/95

Contractor: 6TEL lime: 18:41)

Contract No' Laboratory 10: >V5283

Instrument IBs 5970 flSD HP_Vl)fl Initial Calibration Date: 11/01/95

mnimum KF for SPCC is .1 rtaxinun Z Diff for CCC is 25*

Compound KF RF Miff CCC SPCC

BenzeneTrichloroethene1,2-DichloropropaneMethyl methacrylateBromodichloromethaneDibromomethane2-Chloroethylvinyl ether4-nethyl-2-pentanonecis-l,3-DichloropropeneTULUENE-DSToluenetrans-l,3-Dichloropropene1,1,2-Trichloroethane2-Hexanone1,3-DichloropropaneTetrachloroetheneDibromochloromethane1,2-DibroaoethaneChlorobenzene1,1,1,2-TetrachloroethaneEthylbenzenep&m-Xyleneso-XyleneStyreneIsopropylbenzeneBromoform1,1,2,2-Tetrachloroethane4-&R[inOFLUOR06ENZENE1,2,3-TrichloropropanePropylbenzeneBromobenzene1,3,5-Trimethylbenzene

.81551

.37640

.32574

.24113

.71631

.35777

.10188

.12367

.572491.14405.68050.52584.39123.29768.61755.40754.69510.56670.91245.49852.41966.51366.51467.89620.38637.50096.666471.52767.32848.68351.810951.03267

.91568

.39870

.36970

.25427

.74316

.37210

.13049

.13057

.669001.18086.76297.61164.40534.33861.67395.42968.70021.59798.99720.51148.45398.57859.57258.99005.42862.45888.698481.59053

-.78348.836041.16424

12.285.92

13.50 «5.453.754.0028.095.5816.863.22

12.12 «16.323.6113.759.135.43.73

5.529.29 •«2.608.18 '12.6411.2510.4710.948.40 «*4.80 «•4.11-14.633.0912.74

(Conc=50.00)

(Conc=200.00)

(Conc=50.00)


RF - fluerage Response Factor from Initial Calibration Fora UI

XDiff - * Difference from original average or curue

CCC - Calibration Check Compounds («) SPCC - Systen Performance Check Coapounds (•«]

Fora VII Page 2 of 3

C o n t i n u i n g C a l i b r a t i o n CheckKSL Compounds

Case No: Calibration Date: 11/19/95

Contractor: GTEL Tine: 18:48

Contract No: Laboratory 10: >V5283

Instrument 10: 5970 HSO HP UOfl Initial Calibration Date: 11/01/95

Minimum RF for SPCC is .1 Maximum I Diff for CCC is 25*

Compound R? RF Miff CCC SPCC

trans-l,4-Dichloro-2-butene2-Chlorotoluene4-Chlorotoluenetert-Butylbenzene1 ,2,4-Tr imethy Ibenzenesec-Butylbenzenep-Isopropyltoluene1,3-Dichlorobenzene1,4-DichlorobenzeneButylbenzene1.2-DichlorobenzeneHexachloroethanel,2-Dibrorao-3-chloropropane1,2,4-TrichlorobenzeneHexachlorobutadieneNaphthalene1,2,3-Trichlorobenzene

.25118 .30583

.67205 .75705

.67795 .78063

.57926 .660881.17734 1.32801.62122 .69118.67563 .756831.44529 1.602011.49890 1.61528.64395 .74689

1.41610 1.514371.01247 1.09973.343471.12755 1.18535.70804 .68879

2.50248 2.558401.08701 1.09839

21.769.6715.1414.0912.6011.2612.0210.847.7615.996.948.62-5.132.722.231.05


RF - ftuerage Response Factor fron Initial Calibration Fora VI

fcDiff - * Difference froa original average or curue

CCC - Calibration Check Compounds (>) SPCC - Systea Performance Check Compounds (*<)


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Data File: >V5283::D5 Quant Output File: ~V5283::D1Name: CV111895HP3 [1] Instrument ID: MSD_VOAMisc: 8260 STD @100UG/L PREP 9/17/95

Id File: ID_VOC::DBTitle: ID FILE FOR METHOD 8260Last Calibration: 951101 12:01

Operator ID: MARYJOQuant Time : 951119 19:29Injected at: 951119 13:48

Last Qcal Time: 951118 14:15

QUANT REPORT Page

Operator ID: MARYJOOutput File: "V5283::D1Data File: >V5283::D5Name: CV111895HP3 [1]Misc: 3260 STD @100UG/L PREP 9/17/95

ID File: ID_VOC: :DBTitle: ID FILE FOR METHOD 8260Last Calibration: 951101 12:01

Quant Rev: 7 Quant Time:Injected at:

Dilution Factor:Instrument ID:

951119 19:29951119 18:48

1.00000MSD VOA


Compound R.T. Scan# Area Cone Units

1)2)3)4)5).6)7)3)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)33)39)40)

*FluorobenzeneCh lor ome thane*Pentaf luorobenzeneDich 1 or od if luoromethaneVinyl chlorideBromomethaneChloroethaneTrichlorof luoromethaneAllyl chlorideAcroleinAcetone1, 1-DichloroethenelodomethaneMethylene chlorideCarbon disulfideAcrylonitrileMethyl-tertbutyl ethertrans-1, 2-Dichloroethene1 , 1-DichloroethaneVinyl acetate2-ButanonePropionitrile2 , 2-Dichloropropanecis-1 , 2-DichloroetheneMethacrylonitrileChloroformBromoch lor ome thaneDI BROMOFLUOROMETHANETetrahydrof uran1, 1, 1-Trichloroethane1 , 1-Dichloropropene

*1, 4 -Dif luorobenzeneCarbon tetrachloride1 , 2-DICHLOROETHANE-D41 , 2-DichloroethaneBenzeneTrichloroethene1 , 2-DichloropropaneMethyl methacrylateBromodich lor ome thane

14411345557666788888991010111111111212121213141313131315151516

.25

.07

.86

.62

.21

.01

.15

.68

.78

.51

.68

.96

.64

.00

.09

.29

.41

.74

.74

.74

.78

.94

.14

.23

.41

.63

.02

.15

.15

.64

.04

.41

.29

.41

.64

.70

.27

.72

.88

.31

54142

42420498895121224162170184217235239249255271320320371379389393402413432438438462482549494500511514591613621642

60622696371415891063857887010346867353318902191031112524520611515924264112865131734131053379989134725281846239131110869132

27919115244437722

3335768946012614536656300459246386228905289742103947260242419206182528169252116406340225

50.70.50.40.80.144.136.89.92.

219.117.91.98.98.89.94.98.98.99.106.108.109.97.99.97.

102.102.49.94.

102.100.50.104.50.

102.103 .102.102.98.

103.

00250069399834119960750239110919565785069380582229244590362805006141631613520853

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

9698

d 92I 9496889498888991

\ 94':f 93v 96d 981 72; 92959693969696

• 96•:* 89J 93!•! 953| 97t 9295

99979395

;-' 99£ 95ii 97<« 99'? 95^ 97

QUANT REPORT Page

Operator ID: MARYJOOutput File: " V 5 2 8 3 : : D 1Data File: >V5283::D5Name: CV111395HP3 [1]Misc: 3260 STD @100UG/L PREP 9/17/95

ID File: ID_VOC::DBTitle: ID FILE FOR METHOD 8260Last Calibration: 951101 12:01



951119 19:29951119 18:48

1.00000MSD VOA



41)42)43)44)45)46)47)43)49)50)51)52)53)54)55)56)57)53)59)60)61)62)63)64)65)67)63)69)70)71)72)73)74)75)76)77)73)79)30)31)33)

Dibromome thane2-Chloroethylvinyl ether4-Methyl-2-pentanonecis-1, 3-Dichloropropene*Chlorobenzene-d5TOLUENE-03Toluenetrans-1 , 3-Dichloropropene1,1, 2-Trichloroethane2-Hexanone1, 3-DichloropropaneTetrachloroetheneDibromochlorome thane1 , 2-DibromoethaneChlorobenzene1,1,1, 2-TetrachloroethaneEthylbenzenep&m-Xyleneso-XyleneStyreneI sop ropyl benzeneBromoform1,1,2, 2-Tetrachloroethane

*1 , 4-Dichlorobenzene-d44 -BROMOFLUOROBENZENEPropyl benzeneBromobenzene1,3, 5-Trimethylbenzenetrans-1 , 4-Dichloro-2-butene2 - Ch 1 or o toluene4-Chlorotoluene \tert-Butylbenzene1,2, 4-Trimethylbenzenesec-Butylbenzenep- I sopropyl toluene1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneButylbenzene1, 2-DichlorobenzeneHexachloroethane1,2, 4-Trichlorobenzene

16.17.17.17.22.18.18.19.19.19.20.20.20.21.22.22.22.23.24.24.25.25.25.29.25.26.26.26.26.26.27.27.28.28.28.29.29.30.30.31.35.

4312237451416108495719393843637480022533272374419643499037920692025596194917586449

648682687712946745755778798802832342366893952957960971

10311035108110791104123411151138114111611135116211691211121612421262127312881321134113931582

170352597415977430627319121822580129178823391515501612949525774316432426778522869038136519561017361844255021897437863216392017549126712410656216949016697917818024812865180157082166370140850283031147306161298341426344254159180322748234378252626

105.86.98.

106.50.49.

104.102.102.98.99.

164324105.102.104.103.102.208.104.102.107.104 .101.50.49.

106.104.105.102.100.108.106.103.106.104.107.103.108.106.

234378106.

2633372500813500310998.0818394095427097462581000748154379398843096580209456116.063

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LNO CALlSug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/LNO CALIBug/L

9894939691969896959899929794969697949798949593879697989491989892949996949796868-787

QUANT REPORT Page

Operator ID: MARYJOOutput File: 'V5283::D1Data File: >V5283::D5Name: CV111895HP3 [1]Misc: 8260 STD @100UG/L PREP 9/17/95




951119 19:29951119 18:48

1.00000MSD VOA



84)85)86)

HexachlorobutadieneNaphthalene1,2, 3-Trichlorobenzene

353636

.92

.14

.78

160316141645

146797545257234094

107102107

.95

.96

.29

ug/Lug/Lug/L

969890

* Compound is ISTD

[ CCC AND SPCC DAILY CALIBRATION CHECK OPERATOR REPORT VOA'S ]

DATA FILE NAME = >V5283::D5DATE AND TIME OF ANALYSIS = 11/19/95 18:48

SAMPLE = CV111895HP3 [1]MISCELLANEOUS = 8260 STD @100UG/L PREP 9/17/95

METHOD = M8260AINSTRUMENT = MSD_VOAOPERATOR = MARYJO SUPER GRP

Retention Times Response factors

DAILY.CCC COMPOUND CAL RF

Vinyl Chloride .2785

1, 1-Dichloroethene .4067

Chloroform 1.1780

1 , 2-Dichloropropane .3697

Toluene .7630

Ethylbenzene .4540

SPCC COMPOUND

Ch 1 or ome thane

1, 1-Dichloroethane

Bromof orm

1,1,2, 2-Tetrachloroethane

Chlorobenzene

5-POINTAVE RF

.2952

.4083

1.1307

.3257

.6805

.4197

DAILY RF

.5743

.9953

.4589

.6985

.9972

%D

5.65

.40

4.18

13.51

12. 12

8.17

DAILY CALIBRATION FOR VOA'S PASSED ALL CCC AND SPCC CRITERIA

THE RF AND RT VALUES WILL AUTOMATICALLY BE UPDATED IN YOUR IDFILE

[ RRT AND RF DAILY CALIBRATION GC/MS OPERATOR REPORT VOA'S ]

DATA FILE NAMEDATE AND TIME OF ANALYSIS

SAMPLEMISCELLANEOUS

METHODINSTRUMENTOPERATOR

>V5283::D511/19/95 18:48CV111895HP3 [1]8260 STD eiOOUG/L PREP 9/17/95M8260AMSD_VOAMARYJO SUPER GRP

Retention Times Response factors

Compound Name

Chlorome thaneDichlorodif luoromethaneVinyl chlorideBromomethaneChloroethaneTrich lor of luoromethaneAllyl chlorideAcroleinAcetone1, 1-DichloroethenelodomethaneHethylene chlorideCarbon disulfideAcrylonitrileMethyl-tertbutyl ethertrans-1, 2-Dichloroethene1, 1-DichloroethaneVinyl acetate2-ButanonePropionitrile2 , 2-Dichloropropanecis-l , 2-DichloroetheneMethacrylonitrileChloroformBromochlorome thaneTetrahydrofuran1,1, 1-Trichloroethane1, 1-DichloropropeneCarbon tetrachloride1 , 2-DichloroethaneBenzeneTrichloroethene1 , 2-DichloropropaneMethyl methacrylateBromodi chlorome thaneDibromomethane2-Chloroethylvinyl ether4 -Methyl-2-pentanonecis-l, 3-DichloropropeneToluenetrans-l , 3-Dichloropropene

RRTFOUND

.28552

.30520

.35506

.42210

.43414

.47884

. 65597

.54934

.56310

.58718

. 64392

.67490

.68178

.69898

.70930

.73683

.82108

.82108

.90876

.92252

.93973

.94662

.96211

.981051.01381.02411.06541.0999.92210.94619.950441.05941.09061.10191.13171.14021.18831.19541.2308.82690.84775

RRTIN THEIDFILE

.28552

.30401

.35394

.41766

.42973

.47452

.65538

.55030

.56408

.5,8648

.64159

.67606

.68123

.70019

.71053

.73638

.82250

.82250

.91378

.93101

.93791

.94825

.96550

.982741.01381.02761.06731. 1018.92212.94619.950441.06091.09061.10331.13311.14021.18971.20951.2322.82705.84788

RTDIFF-ERENCE

-.0002.02023.02022.06087.06082. 06068.02000-.0004-.0004.02000.04040-.0004.01993-.0005-.0005.01987-.0006-.0006-.0414-.0822.04025-.0006-.0210-.0006.01980-.0211-.0006-.0006-.0007-.0006-.0006-.0209-.0004-.0208-.0209-.0004-.0209-.2045-.0210-.0212-.0212

RFFOUND

.57435

.37568

.27852

.36538

.237851. 1262.67460.01987.15964.40667.85685.454311.1206.109661.3419.47576.99530.84445.03915.03225.98592.53833.133211.1780.31591. 129451.0610.87007.63289.56845.91568. 39870.36970.25427.74316.37210.13049.13057.66900.76297.61164

AVE. RFFROM5-POINT

.5821

.6357

.2952

.3709

.22331. 1900.5895.0225. 1154.4083.8285.4436

1.0897.1081

1.3107.4457.9111.7346.0366.0361.8352.5168.1302

1.1307.3117. 1334

1. 0653.8006.6231.5266.8155.3764.3257.2411.7163.3578.1019.1237.5725.6805.5258

RATIORF FOUNDTO RF INIDFILE

.70251

.40691

.803891.44981.3634.89112.929861.09801.1775.91018.98388.98115.89094.94190.98559.98566.998461.06061.08931.0980.97581.99219.972911.02241.0245.943641.02281.00051.04611.02631.03161.02131.0252.980831.03531.0526.86332.983671.06251.04351.0200

1,1, 2-^Trichloroethane2-Hexanone1 , 3-DichloropropaneTetrachloroetheneDibromochloromethane1, 2-DibromoethaneChlorobenzene1,1,1, 2-TetrachloroethaneEthylbenzenep&rn-Xyleneso-XyleneStyreneIsopropylbenzeneBromofornv1,1,2, 2-Tetrachloroethane1,2, 3-TrichloropropanePropyl benzeneBromobenzene1,3, 5-Trimethylbenzenetrans-1 , 4-Dichloro-2-butene2-Chlorotoluene4-Chlorotoluenetert-Butylbenzene1,2, 4-Trimethylbenzenesec- Butyl benzenep- I sopropyl toluene1 , 3-Dichlorobenzene1 , 4-DichlorobenzeneButylbenzene1 , 2-DichlorobenzeneHexachloroe thane1 , 2-Dibromo-3-chloropropane1,2, 4 -Tri chlorobenzeneHexachlorobutadieneNaphthalene1,2, 3-Trichlorobenzene

DI BROMOFLUOROMETHANE1 , 2-DICHLOROETHANE-D4TOLUENE-084 -BROMOFLUOROBENZENE

.86589

.86952

.89671

.90578

.92754

.952001.00541.01001.01271.02271.07711.08071.12241.12061.1432.00000.89861.90070.91459.89653.91528.92015.94929.95277.97083.98471.992361.00281.02571.03961.0756. 000001.20671.22121.22891.2504

1. 0241.93060.31733.83264

.86692

.87417

.89680

.90577

.92760

.952951.00451.01091.01271.02271.07701.08151.12231.12231.1440.88967.89939.90147.91466.89661.91535.92022.95002.95350.97085.98472.992361.00351.02571.03951.07571. 11801.20721.22111.22941.2502

1.0259.93062.81799.88342

-.0417-.1233-.0214-.0194-.0214-.0419-.0011-.0420-.0215-.0216-.0216-.0420-.0215-.0624-.0419-26.19-.0420-.0420-.0215-.0215-.0215-.0215-.0419-.0419-.0214-.0213-.0213-.0417-.0212-.0212-.0244-32.91-.0415-.0210-.0413-.0209

-.0006-.0007-.0212-.0420

.40534

.33861

.67395

.42968

.70021

.59798

.99720

.51148

.45398

.57859

.57258

.99005

.42862

.45888

.69848

.00000

.78348

.836041.1642.30583.73705.78063.660881.3280.69118.756831.60201.6153.746891.51441.0997.000001.1853.688792.55841.0984

.89092

.454111.18091.5905

.3912

.2977

.6176

.4075

.6951

.5667

.9125

.4985

.4197

.5137

.5147

.8962

.3864

.5010

.6665

.3285

.6835

.81091.0327.2512.6721.6780.5793

1.1773.6212.6756

1.44531.4989.6439

1.41611.0125.3435

1.1275.7080

2.50251.0870

. 0.0000

.9321

.46311.14411.5277

1.0231.98091.99984******1.05811.02831.04941.03091.02541.04131.04091.02741.07621.04581.0110.000001.06811.04541.05371.02931.00981.08841.06301.03961.06581.04021.07091.03451.08611.0616************1.06631.07951.02961.0729

.998071.0082.99626.99487

QUANT REPORT

Operator ID: MARYJOOutput File: "V5283::D1Data File: >V5283::D5Name: CV111395HP3 [1]Misc: 8260 STD @100UG/L PREP 9/17/95




951119 19:43951119 18:48

1.00000MSD VOA

Last Qcal Date: 951119 18:48

Compound R.T. Scan! Area Cone Units

1)2)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)13)19)20)21)22)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)33)39)40)41)42)43)44)45)46)47)48)49)50)51)52)53)54)55)56)57)

* Fluor obenzeneChloromethane*Pentaf lu or obenzeneDichlorodif luorome thaneVinyl chlorideBromomethaneChloroethaneTrichlorof luorome thaneAllyl chlorideAcroleinAcetone1 , 1-DichloroethenelodomethaneMethylene chlorideCarbon disulfideAcrylonitrileMethyl-tertbutyl ethertrans-1 , 2-Dichloroethene1, 1-DichloroethaneVinyl acetate2-ButanonePropionitrile2 , 2-Dichloropropanecis-1, 2-DichloroetheneMethacrylonitrileChloroformBromoch lor ome thaneDI BROMOFLUOROMETHANETetrahydrofuran1,1, 1-Trichloroe thane1, 1-Dichloropropene

*1 , 4-Dif lu or obenzeneCarbon tetrachloride1 , 2-DICHLOROETHANE-D41 , 2-DichloroethaneBenzeneTrichloroethene1, 2-DichloropropaneMethyl methacrylateBromodi ChloromethaneDibromome thane2-Chloroethylvinyl ether4 -Methyl-2-pentanonecis-1 , 3-Dichloropropene*Chlorobenzene-d5TOLUENE-08Toluenetrans-l, 3-Dichloropropene1,1, 2-Trichloroethane2-Hexanone1 , 3-DichloropropaneTetrachloroetheneDibromoch lor ome thane1 , 2-DibromoethaneCh lor obenzene1,1,1, 2-TetrachloroethaneEthylbenzene

14.254.07

11.863.624.215.015.155.687.786.516.686.967.648.008.098.298.418.749.749.74

10.7810.9411.1411.2311.4111.6312.0212.1512.1512.6413.0414.4113.2913.4113.6413.7015.2715.7215.8816.3116.4317.1217.2317.7422.5118.4118.6119.0819.4919.5720.1920.3920.8821.4322.6322.7422.80

5414242420498895121224162170184217235239249255271320320371379389393402413432438433462482549494500511514591613621642648682687712946745755778798802832842866893952957960

60622696371415891063857887010288467351318763191031113374416211515924245712865131734130313379989134725281777239131110869132

2791911524443772233357689460126145366563004592463862289052897421039472602424192061825281692521164063402251703525974159774306273191218225801291788233915155016129495257743164324267785228690381365195610173618

50.00 ug/L100.00 ug/L50.00 ug/L100.00 ug/L100.00 ug/L99.44 ug/L100.00 ug/L99.96 ug/L100.00 ug/L201.51 ug/L97.69 ug/L100.00 ug/L99.92 ug/L100.00 ug/L100.00 ug/L97.62 ug/L100.00 ug/L100.00 ug/L99.98 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L50.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L50.00 ug/L100.00 ug/L50.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L50.00 ug/L50.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L100.00 ug/L

969892949688949888899194939698729295969396969696899395979295999793959995979995979894939691969896959899929794969697

58) " p&m-Xylenes59) o-Xylene60) Styrene61) Isopropylbenzene62) Bromoform63) 1,1,2,2-Tetrachloroethane64) *1,4-Dichlorobenzene-d465) 4-BROMOFLUOROBENZENE66) 1,2,3-Trichloropropane67) Propylbenzene68) Bromobenzene69) 1, 3, 5-Triinethylbenzene70) trans-1,4-Dichloro-2-butene71) 2-Chlorotoluene72) 4-Chlorotoluene73) tert-Butylbenzene74) 1,2,4-Trimethylbenzene75) sec-Butylbenzene76) p-Isopropyltoluene77) 1,3-Dichlorobenzene73) 1,4-Dichlorobenzene79) Butylbenzene80) 1,2-Dichlorobenzene81) Hexachloroethane82) 1,2-Dibromo-3-chloropropane33) 1,2,4-Trichlorobenzene84) Hexachlorobutadiene35) Naphthalene36) 1,2,3-Trichlorobenzene

23.022 4 . 2 524.3325.2725 .2325.7429.4125.96

0.0026.4326.4926.9026.3726 .9227.0627.9228 .0228.5528 .9629.1929.4930.1730.5831.64

0.0035.4935.9236. 1436.78

9711031103510811079110412841115

xTT2jDTiss114111611135116211691211121612421262127312881321134113£3

(1454,)T582160316141645

442550218974378632163920175491267124106562169490

0166979178180248128

65180157082166370140850283031147306161298341426344254159180322748234378

0252626146797545257234094

200.100.100.100.100.100.50.50.0.

100.100.100.100.100.100.100.100.100.100.100.100.100.100.100.

0.100.100.100.100.

0000000000000000000000000000000000000000000000000000000000

ug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/Lug/L

9497989495938796

979894919898929499969497968687

87969890

* Compound is ISTD

C o n t i n u i n g C a l i b r a t i o n Check

Case ho:

Contractor: GTtL

Contract No:

instrument ID: jy/O riSD HP.Ul

(liriimun RF for SPCC is

Compound

ChioromethaneLichiorodif luoronethaneVinyl chlorideBrooomethaneChloroethaneTrichiorof luoromethaneHl l y i chlorideHcroieinHcetone1.1-uichioroethenelodomethanehethyiene chlorideCarbon disulfideHcrvlonitri ieMethyl -tertbutyl ethertrans-1.2-Dichloroethene1.1-DichloroethaneVinul acetate2-ButanonePropionitrile2.2-Dichloropropanecis-1.2-0ichloroetheneMethacrylonitrileChiorofornBroBochloronethaneOIBROnuFLUOROilETHHrttTetrahydrofuran1.1.1-Trichioroethane1.1-DichloropropeneCarbon tetrachloride1.2-DICHLOROETHHNE-D41.2-Dichloroethane

Hit

JH

.1

RF

.58206

.65566

.29525

.57085

.225291.16996.58955.02249.11558.40855.82851.44559

1.08967.10611

1.51065.44574.91111.75458.05659.05607.85525.51675.150211.15069.51167.95215.155421.06528.80060.62515.46511.52665

Compound:'

Calibration Date: il/io/95

nine' 10:i9

Laboratoru ID: H'5i54

i n i t i a l Caiit>ration Date: li/01/yf.

haximum I Diff for CCC is 25?

RF iuiff CCC SPCC

.61048 4.88 •«

.58688 56.82 - ,

.29105 1.42 « ( ) A£)

.55847 5.54 Mj " . f^

.25o75 6.05 cy ^1.11294 o.47 D.64272 9.02.02512 2.79 iConc=200.00i.12902 11.82 ' ,,.40111 1.77 * V H \.77099 6.94 tVx M' \ .46625 5.11 \V>\ \CO

1.08126 .77 I . \\\<\\ '.11450 5.75 \\ V \

1.55915 5.70 Vv \.44991 .95.96090 5.46 »*.85608 14.09.04016 9.76.U5162 11.78.97894 17.21.55522 5.57.14212 9.151.14599 l.iS ».51409 .78.86267 5.51 iConc=50.00l — ..15980 4.78

1.02000 4.25.84520 5.57.o0204 5.58.45496 1.76 iConc=50.00).55644 5.66

RF - Response Factor fron dailv standard file at 100.00 ug/L

RF - Huerage Response Factor from In i t i a l Calibration Forn VI

iOiff - < Difference fron original aueraqe or curge

CCC - Calibration Check Compounds ('«) SPCC - Sustea Perfornance Check Compounds l « « i

Fora vll Page 1 of 5

Continuing lalibration LheckHbL

tase Mo'

Lontractor' tltL

Lontract No:

instrument U'« 5V/U HbU HP VUH

Lalibration Uate' Il/l6/y5

line: U"iy

Laboratory 11" >V5/34

Initial Lalibration Date' 11/l'im

nininum Itt tor bfLC is .1

Lonpourid K'f

* Uitt for LtC is 2M!

ZUitt LLl

BenzeneIrichloroetnene1,2-UichloropropaneMethyl »ethacrylateBrouodichloronethaneUibrononethane2-Chloroethyluinyl ether4-nethyl-Z-pentanoriecis-l,3-0ichloropropenelULUthE-UBToluenetrans-l,3-L'ichloropropene1,1,2-Irichloroethane2-Hexanone1,3-DichloropropaneletrachloroetheneUibronochloronethane1,2-UibromoethaneLhlorobenzene1.1,1,'Z-letrachloroethanetthy Ibenrenepin-Xyleneso-XvleneStyreneIsopropylbenzenebroiooforB1,1,2,2-letrachloroethane4-BKflnUFLUURDUEN/EHt1,2,3-lrichloropropanePropylbenzeneBronobenzenel,i, 5-1 rimethyl benzene

.«1!>M

.3/641"

. 325/4

.2411?

./16>1

..-ib/7/

.lOlbU

.12367

.5724V1.14405.6U050.5Z5»4.3V123.2Y/6B.61/55.4U/54.6y>iu.566/0,yi245.Wi.41V66,51366.5146/.UV620.38637.500V6.666471.52767.3284«.64)351.810V5

1.U3267

.U772B

.3By46

.3622V

.25644

./336>

.376/y

.12235

.I33b4

.6475U1.170V5.73120.5V2B/.40152.346BU.6B66>.40140.6/BV'3.60725.V/y67.5U2M.45211.56V^5.55322,y/4B6.41/34.46130.72371)

1.5B645.35743.76450.82226

1.15451

7.:>73.47

11.22 «6.352.4^

>.!/20. (tyB.22

13.102.:-5/.4J- «U.752.6316.5011. iy1.512.337.167.37 «*.by

/.73 •10.827.4V«./«B.027.V2 ««8.iV «•3.858. 8111. B5l.3y11. BO

lL'onc=50.uO)

lConc=200.tH'|

(Conc:50.00)

RF - Kesponse factor from daily standard file at 100.00 ug7L

Kl- - Huerage Response factor fron Initial Calibration rora 01

ZUiff - Z Difference fron original auerage or curue

CtC - Calibration Check Compounds («| S'PtL - Systew Performance Check Compounds («•)

Fora Vll Page 2 of 3

Continuing Calibration CheckriSL Compounds

Case Ho:

Contractor' G1EL

Contract Ho:

Instrument ID: 5y70 nSD HP VUH

Calibration Date: H/16/y5

Laboratoru ID: >v52J4

initiai Calibration Date: li/ul/n

Hininua kF for SFCC is .1

Compound Kf

haxinua 2 Diff for CCC is 25*

RF iuiff CCC SPCC

trans-l,4-Dichloro-2-butene2-Cftiorotoluene4-Chiorotoluenetert-6utyibenzene1. 2, 4-Trinethyl benzenesec-Butwlbenzenep-itopropvltoluenet.5-Dichlorobenzene" "1,4-DichlorobenzeneButyibenzene1,2-DichlorobenzeneHexachloroethanei,2-Dibrono-5-ch!oropropane1.2,4-TrichlorobenzeneHexachlorobutadieneNaphthalene1,2,3-Trichlorobenzene

.25118 .50056

.6/205 ,71525

.67795 .75704

.57*26 .642251.17754 I. 51761.62122 .67275.67565 .755581.4452? 1. 565011.4?8yO 1.62456.645*5 .72008

1.41610 1.482521.01247 1.0165X.54547 .525*51.12755 1.16205.70804 .651582.50248 2.700061.08701 1.09096

iy.666.15

11.6710.6711. yj6.508.64fi-1 5 -a. 1?

8.5711.824.68.60

5.105.068.007.yo.56

ftp - Response Factor from daily standard file at 100.00 ug/1

ftF - Kuerage Response Factor fron Initial Calibration For» VI

iuiff - i Difference froii original auerage or curve

CCC - Calibration Check Compounds l«j SPCC - Systen ferfornance Check Coapounds ("1


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FLUOR DANIEL GTI S00076040 • / > h^-