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ICL INDUSTRIAL PRODUCTS
Dear customer!ICL Industrial Products (ICL-IP), the industrial chemicals division of Israel Chemicals Limited, is the world’s largest producer of elemental bromine, supplying over 33% of global demand. The company is a leader in the production and marketing of bromine and bromine compounds, and phosphorus-based compounds which are a fundamental component of many products that enhance well-being and, ultimately, save lives.With a heritage dating back to the early 20th Century, ICL has maintained an unwavering focus on innovation, striving to achieve the highest standards across all aspects of our business. We believe that what sets us apart from others are:
The quality of our people and our productsThe world’s highest concentration of bromine is found in the Dead Sea, which provides a virtually unlimited supply. ICL-IP’s highly skilled workforce uses the latest technologies to harness this rich natural resource, enabling us to produce bromine and bromine-based chemicals as well as minerals of the highest quality, in the most efficient manner. Furthermore, we have applied these skills and technologies to integrate the complementary chemistry of phosphorus, thus developing sustainable products with a broad variety of applications including flame retardants, plasticizers, hydraulic fluids, organic intermediates, water treatment, pharmaceutical chemicals, stabilizers, curing activators, viscosity enhancers, refractory materials, and so on. ICL-IP utilizes Total Quality Management, Lean and Six Sigma methodologies across all its plants worldwide to ensure consistent quality and to achieve improvements in its processes.
Our unique approach to customer serviceICL-IP is dedicated to meeting, and exceeding, our customers’ expectations. We offer the advantages of geographic proximity to major markets with internationally based subsidiaries coordinating the supply of finished products to the customers’ doorstep. We provide experienced technical support, and a workforce fully committed to quality and the protection of the environment.
The scale of our production facilities and our integrated supply chainWe are where our customers need us to be. ICL-IP’s bromine compounds plants in Israel and the Netherlands, along with Sinobrom, a JV in China, offer customer-oriented manufacturing facilities based on long-standing technological expertise. Our market-leading phosphorus-based flame retardants, plasticizers, lubricants and hydraulic fluids, are produced in plants in the US, Germany and China. The company’s worldwide marketing subsidiaries are: ICL-IP Europe B.V., The Netherlands; ICL-IP Israel Sales Office; ICL-IP America Inc., USA; ICL-IP Japan Ltd., Japan; ICL Asia Ltd., Hong-Kong; ICL China, PR China and ICL Brazil, Brazil.We serve hundreds of customers in five continents via an integrated supply chain which includes these production facilities and logistical centres, and a large fleet of unique transportation vessels, especially designed for the safest delivery of ICL-IP’s products.
Our commitment to upholding the highest environmental and safety standardsStrict adherence to international regulations on safety and environmental issues are fundamental business practices at ICL-IP, whose major plants have been granted ISO 14001 and OHSAS 18001 accreditation for Environmental and Safety Management Systems. Beyond this, ICL-IP has actively initiated and developed a program to reduce environmental emissions through a code of good practice known as the Voluntary Emission Control Action Program – VECAP.ICL-IP fully complies with the requirements of all regulatory systems worldwide for all its existing and new flame retardants, including the EU REACH regulation (EC 1907/2006) covering the Registration Evaluation, Authorization and Restriction of Chemicals.ICL has recently developed SAFR®, Systematic Assessment of Flame Retardants, a framework that provides a rigorous evaluation of specific flame retardants in their applications, thus enabling users to choose the most sustainable product for the intended use. As such, SAFR® is committed to the sustainable management of chemicals from the very first stage of the product design. For further details please consult: icl-group.com/sustainability/focusareas/Systematic_Assessment and safrworks.com
3
Responding to the needs of markets and industries by constant innovationThe Flame Retardant Business Unit takes an in-depth and long-term view of the plastic industry’s supply chain, so that its products and solutions are directly responsive to each market segment’s special needs and challenges. We continuously study and monitor the requirements and trends of these market segments, including those of supporting industries, which enables us to offer a valuable contribution to our customers by meeting their current needs and future requirements. ICL-IP R&D division translate these needs into new products and adapted solutions.
Flame retardants for diverse applicationsUsing the vast natural resource of bromine and minerals in the Dead Sea, ICL-IP produces a series of high-quality flame retardant products, applicable to a wide range of plastics, polymers and polymer alloys. ICL-IP also offers the world’s most comprehensive range of phosphorus-based flame retardants, fire resistant plasticizers and hydraulic fluids for high demanding applications. Bromine- and Phosphorus-based flame retardants are considered to be the two most efficient flame retardant families, constituting approximately 55% (in value) of total flame retardant usage. ICL-IP’s portfolio also includes a few additional non-halogen and non-phosphorus based flame retardants such as high purity grades of Magnesium Hydroxide.
SaFRon® & TexFRon® SeriesAs part of the FR BU’s focus on market needs, we have initiated a unique approach by developing tailor-made solutions:• SaFRon® series for high demanding polyurethane foam applications.• TexFRon® series for high quality textile coating applications.
Polymeric and reactive flame retardants – the next generation Polymeric flame retardants are sustainable products complying with national and international human health and environmental regulations. They have long been recognised as the safest and most ‘elegant’ flame retardants of high molecular weight man-made materials. Specifically, their beneficial qualities include:Non-leachingDue to their low solubility in water, once polymeric flame retardants are incorporated into the end-product plastic matrix, they become integrated with the plastic and leaching is not expected to occur.Non-bio-accumulativeTheir high molecular weight makes them unlikely to penetrate through the cell membranes of living tissues.Non-bloomingThey are not expected to migrate to the surface of the plastic during aging, thus eliminating any potential blooming in the finished product.ICL-IP is promoting a wide range of brominated polymeric flame retardants for various applications:• FR-1025: brominated polyacrylate• F-2000 series: brominated epoxy polymers with a wide range of molecular weight• F-3000 series: end-capped brominated epoxy polymers with various molecular weights• FR-803P: brominated polystyrene• FR-122P: Brominated butadiene / styrene block copolymer• TexFRon® P, TexFRon 4000Reactive flame retardants chemically react with the polymeric matrix in which they are incorporated and as such become an intrinsic, non- blooming, non-leaching part of the final article. Reactive flame retardants offered by ICL –IP include:• FR-1524(TBBA) for Printed Wired Boards• FR-513(TBNPA) and SaFRon® 6605 for rigid PU foams• FR-522 (DBNPG) for UPE applications• Fyrol 6, non-halogen FR for rigid PU foams and urethane elastomers.• VeriQuel™ R100, non-halogen FR for rigid PU foams• PolyQuel ® P100, polymeric phosphorus-based FR for epoxy resins in printed wiring boards
6
Selection Table
Brominated Flame Retardants
FR-11 (Ammonium Bromide)
FR-122P
FR-245
FR-370
FR-513
FR-522
FR-613
FR-720
FR-803P
FR-1025
FR-1410
FR-1524
APPLICATIONS
Brominated Epoxy Flame Retardants
F-2001
F-2200HM
F-2016
F-2100, F-2400
F-3014, F-3020
F-3100
HIPS
EPS /
XPS
ABS
Polye
thyle
ne
Polyp
ropyle
ne
TPE /
TPU
PBT /
PET
Nylon
= Po
lyami
de
PC /
PC AB
S
Alloy
s
PVC /
Flex
ible
Rubb
ers /
Elasto
mers
Epox
y Res
ins
Phen
olic R
esins
Unsa
turate
d Poly
ester
s
Flexib
le PU
Rigid
PU
Chip
/ Par
ticle
Board
s
Texti
les /
Fibers
Latex
/ Ad
hesiv
es
Inorganic Flame Retardants
FR-20
FR-1120 (synergist)
7
Phosflex®
Fyrolflex®
Tailor Made FR Solutions
6605
series
VeriQuel™ R100
PolyQuel® P100
Fyrol A710
Fyrol HF-5 / HF-5-HP (Low Emission)
Fyrol 6
Fyrol PCF / Fyrol PCF-LO (Low Odour)
Fyrol PNX / Fyrol PNX-LE (Low Emission)
Fyrol HF-9 / Fyrol HF-10
Fyrol® Series
Fyrolflex RDP/ RDP-HP
Fyrolflex Sol-DP
Lindol®
Lindol
Lindol XP Plus
Phosflex 4
Phosflex T-BEPPhosflex 31L/41LPhosflex 375
Phosflex 71B
Phosflex 362
Phosflex 390
Phosflex 418
Phosphorus Flame Retardants
HIPS /
PPO
EPS /
XPS
ABS
Polye
thylen
e
Polyp
ropyle
ne
TPE /
TPU
PBT /
PET
Nylon
= Po
lyami
de
PC /
PC AB
S
Alloy
s
PVC /
Flex
ible
Rubb
ers /
Elasto
mers
Epox
y Res
ins
Phen
olic R
esins
Unsa
turate
d Poly
ester
s
Flexib
le PU
Rigid
PU
Chip
/ Part
icle B
oards
Texti
les /
Fibers
Latex
/ Ad
hesiv
es
Cellu
losic
Plasti
c Com
posit
e
8
Products & Properties M.W. SpecificGravity
BromineContent
MeltingRange/Point-
Softening Range
TGA%WT. Loss @
Temp.
Brominated Flame RetardantsFR-11Ammonium bromideAPPLICATIONS: Chipboard, Wood Paper, Textile
NH4Br
CAS No. 12124-97-9
98 2.43 81% M.P.452°C
FR-122P ( polymer)Brominated Butadiene/Styrene Block CopolymerAPPLICATIONS: EPS and XPSADVANTAGES: non blooming, non leachable, low loading and good FR efficiency
CAS No. 1195978-93-8
100000 1.6 65% S. R.120-140
2% @ 243°C5% @ 257°C
10% @ 264°C
FR-245Tris(tribromophenoxy) triazineAPPLICATIONS: HIPS, ABSADVANTAGES: combination of good flow and impact, UV and thermal stability, non-blooming
CAS No. 25713-60-4
1067 2.44 67% M.P.230°C
2% @ 360°C5% @ 385°C
10% @ 400°C
FR-370Tris(tribromoneopentyl) phosphateAPPLICATIONS: PP, HIPS, ABS, Alloys, Adhesives, Fibers ADVANTAGES: UV and light stability. CAS No. 19186-97-1
1018.5 2.30 70%(3% P)
M.P.181°C
1% @ 282°C5% @ 309°C
10% @ 319°C
FR-513Tribromoneopentyl alcoholAPPLICATIONS: PU rigid andflexible foams, FR intermediateADVANTAGES: meets high FRstandards, high thermal stability, non-leaching, reactive CAS No. 36483-57-5
324.9 2.30 73% M.P.65°C
2% @ 139°C5% @ 155°C
10% @ 169°C
FR-522Dibromoneopentyl glycolAPPLICATIONS: UPE, PU rigid foamsADVANTAGES: high level of flame retardancy, light stability,transparency, reactive, non-leaching
CAS No. 3296-90-0
261.9 2.23 60% M.P.109.5°C
2% @ 200°C5% @ 225°C
10% @ 245°C
FR-613TribromophenolAPPLICATION: FR Intermediate, end capping of brominated epoxies
CAS No. 118-79-6
330.8 2.55 72% M.P.93°C
5% @ 120°C10% @ 132°C
FR-720Tetrabromobisphenol A -bis(2,3 dibromopropyl ether)APPLICATIONS: PP, HIPS, ABSADVANTAGES: good FR efficiency and thermal stability
CAS No. 21850-44-2
943.2 2.30 68% M.R.113-117°C
1% @ 291°C5% @ 306°C
10% @ 313°C
9For more information visit our website: www.iclfr.com
M.W. SpecificGravity
BromineContent
MeltingRange/Point-
Softening Range
TGA%WT. Loss @
Temp.
Brominated And Brominated Epoxy Flame RetardantsFR-803P (polymer)Brominated polystyreneAPPLICATIONS: Nylon, PBT, PETADVANTAGES: good CTI, thermal stability, non-blooming
CAS No. 88497-56-7
600000 2.1 66%min.
S.R.265-324°C
2% @ 340°C5% @ 358°C
10% @ 374°C
FR-1025 (polymer)Brominated polyacrylateAPPLICATIONS: PBT, Nylon, AlloysADVANTAGES: excellent thermal aging, CTI, good impact, compatibility with fiber reinforcement,recycling, non blooming
CAS No. 59447-57-3
600000 2.50 71% M.R.190-220°C
2% @ 320°C5% @ 330°C
10% @ 335°C
FR-1410Decabromodiphenyl ethaneAPPLICATIONS: HIPS, PE, PP, PBT, nylon, UPE, EpoxyADVANTAGES: FR efficiency, exceptional thermal stability and multi-purpose CAS No 84852-53-9
971.2 3.25 82% M.P.>350
2% @ 322°C5% @ 345°C
10% @ 360°C
FR-1524Tetrabromobisphenol-AAPPLICATIONS: Epoxy, Polycarbonate Resins, ABSADVANTAGES: high reactivity with epoxy, low color, high clarity, good FR efficiency good solubility CAS No. 79-94-7
543.7 2.17 58.5% M.P.181°C
2% @ 262°C5% @ 284°C
10% @ 301°C
F-2000 series - Brominated Epoxy F-2200 HM (Proprietary)APPLICATIONS: XPS, HIPS,PolyolefinsADVANTAGES: Thermal stabilizer, corrosion resistant, processing aid
CAS No. 3072-84-2
700 1.80 48% M.R.108-118°C
1% @ 289°C5% @ 326°C
10% @ 343°C
F-2000 series - Brominated Epoxy polymerF-2001 (polymer)APPLICATIONS: Unsaturated polyester and vinyl ester resinsADVANTAGES: High UV stability, solubilty in styrene
CAS No. 68928-70-1
2300 1.80 49-51% M.R.67-86°C
1% @ 280°C5% @ 320°C
10% @ 340°C
10
Products & Properties M.W. SpecificGravity
BromineContent
MeltingRange/Point-
Softening Range
TGA%WT. Loss @
Temp.
Brominated Epoxy Flame RetardantsF-2000 series - Brominated Epoxy polymer*
CAS No. 68928-70-1F-2016 (polymer)APPLICATION: ABSADVANTAGES: good processability, high thermal and UV stability, non-blooming
3200 1.80 52% S.R.105-121°C
2% @ 328°C5% @ 348°C
10% @ 363°C
F-2100L (polymer)APPLICATIONS: PBT, PC/ABSADVANTAGES: high thermal and UV stability, non-blooming, non corrosive, excellent processability
10000 1.80 52% 170-190°C 2% @ 355°C5% @ 364°C
10% @ 367°C
F-2100 (polymer)APPLICATIONS: PBT, PC/ABSADVANTAGES: high thermal and UV stability, non-blooming, non-corrosive, excellent processability
20000 1.80 52% S.R.180-205°C
2% @ 350°C5% @ 357°C
10% @ 361°C
F-2100H (polymer)APPLICATIONS: PBT, PET, Alloys (PC/ABS)ADVANTAGES: good mechanical, physical and flow properties, high thermal, UV stability, non blooming
25000 1.80 52% Tg130-150°C
2% @ 348°C5% @ 355°C
10% @ 359°C
F-2400E (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability
32000 1.80 53% Tg145-155°C
2% @ 345°C5% @ 352°C
10% @ 357°C
F-2400 (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability
50000 1.80 53% Tg145-155°C
2% @ 345°C5% @ 352°C
10% @ 357°C
F-2400H (polymer)APPLICATIONS: PBT, PET, Nylon, TPU, Alloys, ABSADVANTAGES: high thermal and UV stability, non-blooming, excellent processability
58000 - 68000
1.80 53% Tg145-155°C
2% @ 345°C5% @ 352°C
10% @ 357°C
F-3000 series - End capped Brominated Epoxy*
F-3014APPLICATIONS: HIPS, ABSADVANTAGES: good processability, non-blooming, high thermal and UV stability, good HDT impact strength, low metal adhesion
CAS No. 158725-44-1For U.S:
CAS No. 534584-61-7
1400 1.90 60% S.R.80-110°C
2% @ 293°C5% @ 330°C
10% @ 350°C
F-3020 (polymer)APPLICATIONS: HIPS, ABSADVANTAGES: good processability, nonblooming, hight thermal and UV stability, good HDT impact strength, low metal adhesion
CAS No. 15725-44-1For U.S:
CAS No. 534584-61-7
2300 1.90 57% S.R.105-120°C
2% @ 318°C5% @ 349°C
10% @ 357°C
F-3060 (polymer)APPLICATIONS: PBTADVANTAGES: good processability, nonblooming,hight thermal and UV stability, good HDT impactstrength, low metal adhesion
CAS No. 15725-44-1For U.S:
CAS No. 534584-61-7
8,800 1.90 55% S.R.120-125°C
2% @ 344°C5% @ 354°C
10% @ 359°C
F-3100 (polymer)APPLICATIONS: PBT, Nylon, Alloys, ABSADVANTAGES: processing - aid, excellent flow properties, non-blooming low metal adhesion and good thermal and UV stability
CAS No. 15725-44-1For U.S:
CAS No. 534584-61-7
15000 1.90 53% S.R.180-220°C
2% @ 343°C5% @ 352°C
10% @ 358°C
* Molecular weight can be tailored to specific requirements
11For more information visit our website: www.iclfr.com
SpecificGravity
PhosphorusContent
ChlorineContent
ViscositymPa.s -
25°C
TGA%WT. Loss @
Temp.
Phosphorus Flame RetardantsFyrol® series
Fyrol HF-5 / HF-5-HP (High Purity)Proprietary halogen-free FR additiveAPPLICATIONS: Flexible PU foamADVANTAGES: FR efficiency, low viscosity, low fogging and low VOC emissions.
Proprietary
1.3 14% 900 2% @ 169°C5% @ 213°C
10% @ 259°C
Fyrol HF-9Proprietary halogen-free phosphate ester flame retardantAPPLICATIONS: Flexible PU foamADVANTAGES: Highly effective in producing flame retardant flexible polyurethane foam meeting MVSS-302 criteria
1.2 10.8% 350
Fyrol HF-10Proprietary halogen-free phosphate ester flame retardantAPPLICATIONS: Flexible PU foamADVANTAGES: Highly effective in producing flame retardant flexible polyurethane foam meeting MVSS-302 and BS5852
1.3 12.7% 1,950
Fyrol A710Proprietary halogen-free flame retardantAPPLICATIONS: Flexible PU foamADVANTAGES: Excellent processing, low viscosity, low scorch.
1.18 8.5% 70
Fyrol PNXOligomeric ethyl ethylene phosphateAPPLICATIONS: Flexible PU foam, paper treatmentADVANTAGES: very high efficiency. CAS No. 184538-58-7
1.31 19% 1000 2% @ 185°C5% @ 215°C
10% @ 235°C
Fyrol PNX-LE (Low Emission)Modified oligomeric ethyl ethylene phosphateAPPLICATIONS: Flexible PU foamADVANTAGE: Low emission version of Fyrol PNX, low fogging/VOC for automotive
CAS No. 184538-58-7
1.31 19% 2250 2% @ 185°C5% @ 215°C
10% @ 235°C
Fyrol 6Diethyl N,N bis (2-hydroxyethyl) aminomethylphosphonateAPPLICATIONS: Reactive non halogen FR for rigid PU foam and urethane elastomersADVANTAGES: Excellent for spray, pour-in-place systems and slab foams. Permanency in PU foams
CAS No. 2781-11-5
1.16 12.0% 200 5% @ 170°C10% @ 195°C
Fyrol PCFTris (2-chloroisopropyl) phosphate.APPLICATIONS: Isocyanurate and rigid PU foams, flexible PU foam (BS5852), unsaturated polyesters and phenolicsADVANTAGES: Hydrolytic stability, low viscosity CAS No. 13674-84-5
1.29 9.5% 32.5% 65 2% @ 145°C5% @ 165°C
10% @ 180°C
Fyrol PCF-LO (Low Odour)Tris 2-chloroisopropyl phosphate.APPLICATIONS: Flexible PU foam for BS5852 applicationsADVANTAGES: Hydrolytic stability, low viscosity CAS No. 13674-84-5
1.29 9.5% 32.5% 72 2% @ 116°C5% @ 166°C
10% @ 180°C
12
Products & Properties SpecificGravity
PhosphorusContent
ChlorineContent
ViscosityMpa.s - 25°C
Melting Range
TGA%WT. Loss @
Temp.
Phosphorus Flame RetardantsFyrolflex® SeriesFyrolflex RDPResorcinol bis(diphenyl phosphate)APPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, styrenics, phenolic laminates, TPUADVANTAGES: High efficiency, high thermal stability CAS No. 57583-54-7
1.31 10.7% 480 2% @ 285°C5% @ 320°C
10% @ 335°C
Fyrolflex RDP/RDP-HP (High Purity)High purity oligomeric phosphate ester flame retardant with low triphenyl phosphate content.
1.30 10.7% 575 2% @ 335°C5% @ 356°C
10% @ 374°C
Fyrolflex Sol-DPProprietary aromatic phosphateAPPLICATIONS: Polycarbonate and its alloys, polyphenylene ether blends, UL94/V-2 ABS, processing aid for engineering resins, TPUADVANTAGES: Easy to handle solid free-flowing, high efficiency and good hydrolytic stability
Proprietary, solid dust free pastilles
1.30 10.7% M.R.105-108°C
2% @ 300°C5% @ 335°C
10% @ 350°C
Phosflex® SeriesPhosflex 4Tributyl phosphate APPLICATIONS: De-airing additive, extraction agent in metal and phosphoric acid production, high-boiling solvent for inks and paints.ADVANTAGE: Low viscosity
CAS No. 126-73-8
0.98 11.7% 5 2% @ 115°C5% @ 135°C
10% @ 150°C
Phosflex T-BEPTris(butoxyethyl) phosphateAPPLICATIONS: Emulsions of floor finishes, leveling agent in latex paints, processing aid for acrylonitrile rubber, antiblock agent for cast polyurethanesADVANTAGE: Low viscosity
CAS No. 78-51-3
1.02 7.8% 12 2% @ 170°C5% @ 200°C
10% @ 225°C
Phosflex 31L/41LIsopropylated triphenyl phosphate mixture APPLICATIONS: PVC film and sheeting compounds, PVC plastisols.ADVANTAGES: High thermal stability, good solvating properties
CAS No. 68937-41-7
1.18 8.3% 60/100 2% @ 210°C5% @ 230°C
10% @ 245°C
13For more information visit our website: www.iclfr.com
SpecificGravity
PhosphorusContent
ViscosityMpa.s - 25°C
Melting Range
TGA%WT. Loss @
Temp.
Phosphorus Flame RetardantsPhosflex® SeriesPhosflex 375Proprietary plasticizer blend of alkyl diphenyl phosphate and triaryl phosphate ester.APPLICATIONS: PVC films and sheeting compounds, PVC plastisols. ADVANTAGES: Blended alternative FR plasticizer for isopropylated TPPs, excellent FR
1.15 8.3% 48 2% @ 219°C5% @ 240°C
10% @ 257°C
Phosflex 71B / 71B - HP (High Purity)t-Butylated triphenyl phosphate mixtureAPPLICATIONS: Plasticizer for PVC and PVC foams, polyvinyl acetate emulsion, FR for modified HIPSADVANTAGE: High thermal stability
CAS No. 56803-37-3 and 65652-41-7 and 78-33-1
1.18 8.5% 70 2% @ 215°C5% @ 235°C
10% @ 250°C
Phosflex 3622-ethylhexyl diphenyl phosphateAPPLICATIONS: Plasticizer for PVC (plastisols, textile coatings), and vinyl/nitrile rubber foamed alloys, cellulosic polymers, PMMA, PSADVANTAGES: Good performance at low temperature, low smoke, FDA approved in coatings for food packaging. CAS No. 1241-94-7
1.09 8.5% 18 2% @ 180°C5% @ 200°C
10% @ 210°C
Phosflex 390Isodecyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting, foamed vinyl/nitrile rubber alloys, wire insulation, coatings for apparel and upholstery, polyvinyl acetate adhesives ADVANTAGES: Good performance at low temperature, low smoke
CAS No. 29761-21-5
1.07 7.9% 26 2% @ 205°C5% @ 220°C
10% @ 235°C
Phosflex 418Linear alkyl diphenyl phosphate APPLICATIONS: Plasticizer for PVC sheeting and wire insulation ADVANTAGES: Excellent plasticizing efficiency at low temperature, low smoke and low volatility CAS No 27460-02-2,
142474-86-0and 56827-92-0
1.04 7.2% 24 5% @ 215°C10% @ 235°C
Lindol® SeriesLindol & Lindol XP PlusTri(m,p-cresyl) phosphate mixtureAPPLICATIONS: Plasticizer for PVC, synthetic rubber, cellulosic films, FR for phenolic laminatesADVANTAGE: High efficiency
CAS No. 1330-78-5
1.17 8.4% 65 2% @ 220°C5% @ 235°C
10% @ 250°C
14
Products & Properties M.W. SpecificGravity
Avg.Particle
Size
BulkDensityKg/m3
TGA%WT. loss @
temp.
Mineral And Nitrogen Flame RetardantsInorganic Flame RetardantsFR-20Magnesium HydroxideGRADES:S5 (BET 5 m2/g) uncoated or coatedS7 (BET 7 m2/g) uncoated or coatedS10 (BET 10 m2/g) uncoated or coatedAPPLICATIONS: Wire and Cables, Electrical connectors, TPO for roofing, Foils and sheets, LD and HDPE, PP, Soft PVC, PAADVANTAGES: excellent smoke suppressant, acid scavenger, thermal stability. All above grades are available with Stearic acid surface treatment.
Mg(OH)2
CAS No. 1309-42-8
58.3 2.36
1.8-2.2 µm1.5-1.8 µm1.1-1.4 µm
0.5-0.7 2% @ 370°C5% @ 385°C
10% @ 402°C
FR-1120Calcium Borate on a silicate carrier.APPLICATIONS: Antimony Trioxide replacement in polyolefins, polyamides, styrenics and polyesters. Zinc Borate replacement in polyolefins and PVC.ADVANTAGES: Highly cost-efficient.
CAS No. 13701-64-9
2.6 6 µm 0.6-0.7 2% @ 253°C5% @ 319°C
10% @ 392°C
HIPS
/ PP
O
EPS /
XPS
ABS
Polye
thyle
ne
Polyp
ropyle
ne
PBT /
PET
Nylon
= Po
lyami
de
PC /
PC AB
S
Alloy
s
PVC /
Flex
ible
Rubb
ers /
Elasto
mers
Epox
y Res
ins
Phen
olic R
esins
Unsa
turate
d Poly
ester
s
Flexib
le PU
F
Rigid
PUF
Chip
/ Par
ticle
Board
s
Texti
les /
Fibers
Latex
/ Ad
hesiv
es
Cellu
losic
Plasti
c Com
posit
eSaFRon® and TexFRon® Series
E 6605E
9000 and 3000 SeriesT
PE
P and 4000 Series* TP
DE 5000 Series
AG
* TexFRon® 4002 is OEKO-TEX® Standard 100 certified
M.W.SpecificGravity
Phosphorus Content
ViscosityMpa.s - 250C Tg, 0C
TGA 0C, 5%
PolyQuel® P100APPLICATIONS: reactive, polymeric phosphorus-based flame retardant curing agent for epoxy resins in printed wiring boards. ADVANTAGES: high glass transition temperature and thermal stability; high flame retardant efficiency; low Dk and Df; especially recommended for lead-free, halogen-free, high Tg applications.
1400 7.1% 185 415
VeriQuel™ R100APPLICATIONS: phosphorous-rich reactive intermediate for PIR roof and wall insulation, closed cell spray foam insulation and rigid polyurethane foam. ADVANTAGES: Efficient TCPP replacement; non-emissive in PIR and closed cell spray foam formulation; low viscosity liquid, very good viscosity cutting characteristics, efficient processing aid in high viscosity PUR and PIR systems.
1.16 17 200
Strengths:A - Antimony oxide freeE - FR efficiencyT - Thermal stabilityD - Dust-freeP - Polymer & Non-blooming
Specialty Flame Retardants, Tailor-Made Solutions
15For more information visit our website: www.iclfr.com
Applications
✓ good ✓✓ very good ✓✓✓ excellent
Thermoplastics and Styrenic AlloysHIPS V-1/V-0
FR-1410 FR-245 F-3000*
PROPERTIES
Thermal stability ✓✓✓ ✓✓✓ ✓✓
Melt flow ✓✓ ✓✓✓
FR efficiency ✓✓ ✓✓✓ ✓
Impact ✓✓ ✓✓✓
UV / Light stability ✓✓ ✓✓
Heat distortion temp. ✓✓ ✓✓✓ ✓
Non-blooming ✓✓ ✓✓✓
Cost efficiency ✓✓✓ ✓✓✓ ✓
Recycling ✓✓✓ ✓✓✓ ✓✓✓
* Polymer
HIPS V-2Fyrolflex®
Sol-DP FR-720 FR-1410 FR-245 FR-370
PROPERTIES
Thermal stability ✓✓✓ ✓✓ ✓✓✓ ✓✓✓ ✓✓
Melt flow ✓✓✓ ✓✓✓ ✓ ✓✓
FR efficiency ✓✓✓ ✓✓ ✓✓
Impact ✓ ✓✓✓ ✓ ✓ ✓✓✓
UV / Light Stability ✓✓ ✓ ✓✓ ✓✓✓
Heat distortion temp. ✓ ✓ ✓✓
Non-blooming ✓✓ ✓✓ ✓✓ ✓✓
Cost efficiency ✓✓ ✓✓ ✓✓ ✓✓
Dust-free ✓✓✓
16
Applications
Thermoplastics and Styrenic AlloysABS V-1/V-0
FR-1524 FR-245 F-2000* FR-1410 F-3000*
PROPERTIES
Thermal stability ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓
Melt flow ✓✓✓ ✓ ✓✓ ✓ ✓✓
FR efficiency ✓✓✓ ✓✓ ✓✓✓ ✓✓✓ ✓
Impact ✓✓✓ ✓✓ ✓
UV / Light stability ✓✓ ✓✓✓ ✓✓
Heat distortion temp. ✓✓✓ ✓✓ ✓✓ ✓
Non-blooming ✓✓ ✓✓✓ ✓✓✓
Cost efficiency ✓✓✓ ✓✓✓ ✓ ✓✓ ✓
Recycling ✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓
ATO free option ✓✓✓
* Polymer
PC/ABS and HIPS/PPO alloys V-1/V-0Fyrolflex®
RDP /RDP-HPFyrolflex®
Sol-DP F-3000*
PROPERTIES
Phosphorus (P)/Bromine (Br) Based P P Br
Thermal stability ✓✓ ✓✓ ✓✓✓
Melt flow ✓✓ ✓✓ ✓
FR efficiency ✓✓✓ ✓✓✓ ✓✓✓
Impact ✓✓ ✓✓ ✓✓✓
UV / Light stability ✓✓✓ ✓✓✓ ✓✓
Hydrolytic stability ✓✓ ✓✓✓
Heat distortion temp. ✓ ✓✓✓
Non-plate-out ✓✓ ✓✓✓ ✓✓✓
Cost efficiency ✓✓ ✓ ✓✓✓
Liquid/solid handling Liquid Solid Solid
* Polymer
18
Applications
Engineering PlasticsPolyamideNon reinforced PA 6 and 6,6 V-O FR-803P* FR-1025* FR-1410 F-2400* FR-20
PROPERTIES
Thermal stability ✓✓✓ ✓ ✓✓ ✓✓
Melt flow ✓✓✓ ✓✓
FR efficiency ✓ ✓✓✓
Impact ✓✓✓ ✓✓ ✓
Comparative tracking index ✓✓ ✓ ✓✓✓
Thermal aging ✓✓ ✓✓✓ ✓
Recycling ✓ ✓✓✓ ✓
UV / Light stability ✓✓ ✓✓✓ ✓✓✓
Heat distortion temp. ✓ ✓✓ ✓✓ ✓✓ ✓✓✓
Non-blooming ✓✓ ✓✓✓ ✓✓✓
Cost efficiency ✓✓ ✓✓✓ ✓
* Polymer
PolyamideGlass reinforced PA 6 and 6,6 V-O FR-803P* FR-1025* FR-1410 F-2400* F-3100*
PROPERTIES
Thermal stability ✓✓✓ ✓ ✓✓ ✓✓
Melt flow ✓ ✓✓✓ ✓✓✓ ✓✓
FR efficiency ✓✓ ✓✓ ✓✓✓ ✓✓
Impact ✓ ✓✓✓ ✓✓ ✓✓
Comparative tracking index ✓✓ ✓ ✓
Thermal aging ✓✓ ✓✓✓ ✓ ✓
Recycling ✓✓ ✓✓
UV / Light stability ✓✓ ✓✓✓ ✓✓
Heat distortion temp. ✓✓ ✓✓✓ ✓✓ ✓✓ ✓✓
Non-blooming ✓✓✓ ✓✓✓ ✓✓✓
Cost efficiency ✓ ✓✓✓ ✓ ✓✓
ATO free option ✓✓✓ ✓✓✓
* Polymer
✓ good✓✓ very good✓✓✓ excellent
19For more information visit our website: www.iclfr.com
✓ good✓✓ very good✓✓✓ excellent
Engineering PlasticsPBT V-0
FR-1025* F-3100* F-2000* series FR-803P* FR-1410FR-1025
& F-2000* series
PROPERTIES
Thermal stability ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓ ✓✓
Melt flow ✓✓✓ ✓✓✓ ✓ to ✓✓ ✓✓
FR efficiency ✓✓ ✓ ✓ ✓ ✓✓
Impact ✓✓✓ ✓✓ ✓✓ ✓✓✓
Comparative tracking index ✓✓ ✓✓✓ ✓✓
Thermal aging ✓✓✓ ✓ ✓ ✓✓
Recycling ✓✓✓ ✓✓ ✓✓
UV / Light stability ✓✓ ✓✓ ✓✓✓ ✓✓
Heat distortion temp. ✓✓ ✓✓✓ ✓✓✓
Non-blooming ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓ ✓✓✓
Cost efficiency ✓ ✓✓ ✓✓ ✓✓ ✓✓✓ ✓✓
ATO free option ✓✓✓ ✓✓✓ ✓✓✓
* Polymer
20
PVC & Textile Adhesives Coating (TAC)Flexible PVC
Phosflex®
31L/41LPhosflex®
375Phosflex®
71BPhosflex®
362Phosflex®
390 Lindol®
PROPERTIES
FR efficiency ✓✓✓ ✓✓ ✓✓✓ ✓ ✓ ✓✓✓
Plasticizing performance ✓✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓✓
Low temperature flexibility ✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓✓
Low smoke ✓ ✓✓ ✓ ✓✓✓ ✓✓✓ ✓
Low volatility/Surface migration ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓
Low smell ✓ ✓✓ ✓✓✓ ✓ ✓ ✓
Chemical resistance (oil fats) ✓✓✓ ✓✓ ✓✓✓ ✓ ✓ ✓✓✓
Food approval ✓*
Cost efficiency ✓✓ ✓✓ ✓✓✓ ✓ ✓
* FDA Contact in coatings for confectionary applications
Applications
21For more information visit our website: www.iclfr.com
Textile Adhesives & Coating (TAC) TAC
TexFRon® 9001 TexFRon® 4002 TexFRon® P TexFRon® 5001 FR-1410
PROPERTIES: Phophorus (P) / Bromine (Br) based Br Br Br P Br
Solid/Liquid S S L L S
FR efficiency ✓✓✓ ✓✓✓ ✓✓ ✓ ✓✓✓
Transparency ✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓
Wash durability ✓✓✓ ✓✓✓ ✓✓✓ ✓✓ ✓✓
UV stability ✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓
Low melt tmp. ✓✓✓ ✓✓✓
Low fogging ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓
Self binding ✓ ✓ ✓✓✓ ✓
Polymeric ✓✓✓ ✓✓✓
Cost efficiency ✓✓ ✓✓✓ ✓ ✓✓ ✓✓✓
FABRIC TYPE
Polyester ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓ ✓✓✓
Polyester/Cotton blends ✓✓✓ ✓✓✓ ✓✓✓ ✓✓ ✓✓
Nylon & Nylon blends ✓✓ ✓✓ ✓✓
Cotton * ✓✓✓ ✓✓✓ ✓✓✓ ✓ ✓✓✓
* with additive - TexFRon AG
Back coating + + - + +Coating/padding + + + + +
AG: provides anti smoldering for BFRs combinations in cotton rich applications
Textile Exhaustion application
3000 provides flame retardancy to synthetic fibers yarns and fabrics
✓ good✓✓ very good✓✓✓ excellent
22
Rigid PUVeriQuel™
R100 Fyrol® 6 Fyrol® PCF SaFRon® 6605 Fyrol® PNX
PROPERTIES
Low viscosity ✓✓✓ ✓✓ ✓✓✓ ✓
FR efficiency ✓✓ ✓ ✓✓ ✓✓✓ ✓✓
System stability ✓✓✓ ✓✓✓ ✓✓✓
Reactive ✓✓✓ ✓✓✓ ✓✓
Cost efficiency ✓✓✓ ✓✓
EPS / XPS
Expanded and extruded polystyrene foams for building, construction and packaging industries are available in many forms:Sheets (thermal insulation), Profiles (decorative), Molded shapes (packaging).ICL-IP offers several flame retardants to match market needs in the various applications:
FR-122P• Polymeric FR• FR efficiency similar to FR-1206• Non-leaching and non-blooming
F-2200HM and F-2016• Proprietary co-FR for XPS applications• Heat /UV stabilized applications• Processing-aid effect
Polymeric FoamsFlexible PU
Fyrol® A710 Fyrol® PCF Fyrol® PNX Fyrol® PNX LE Fyrol® HF-9 Fyrol® HF-10
PROPERTIES
Low viscosity ✓✓✓ ✓✓✓ ✓ ✓✓
FR efficiency ✓✓ ✓✓✓ ✓✓✓ ✓✓ ✓✓
Low scorch ✓✓✓ ✓✓ ✓✓
Low fogging ✓✓ ✓✓✓ ✓✓
Compression set ✓✓✓ ✓✓✓ ✓ ✓ ✓✓ ✓✓
Reactive
Cost efficiency ✓✓✓ ✓ ✓ ✓
Applications
23For more information visit our website: www.iclfr.com
PolyolefinsPP
FR-370 FR-720 FR-1410 FR-1025* FR-20
PROPERTIES
Thermal stability ✓ ✓ ✓✓✓ ✓✓✓ ✓✓✓
Processability ✓✓ ✓ ✓✓✓
FR efficiency ✓✓ ✓✓ ✓✓✓
Impact ✓✓✓ ✓✓✓ ✓✓
UV / Light stability ✓✓✓ ✓ ✓ ✓✓ ✓✓
Non-blooming ✓✓ ✓✓✓
Cost efficiency ✓✓ ✓✓
Rating V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0 / V - 2 V - 0
* Polymer
PEFR-720 FR-1410 FR-1025* FR-20
PROPERTIES
Thermal stability ✓ ✓✓✓ ✓✓✓ ✓✓✓
Melt flow ✓✓✓ ✓✓
FR efficiency ✓✓ ✓✓✓
Impact ✓✓✓ ✓✓
UV / Light stability ✓ ✓ ✓✓ ✓✓
Non-blooming ✓✓✓
Cost efficiency ✓✓ ✓✓
* Polymer
✓ good ✓✓ very good ✓✓✓ excellent
Visit our website: www.iclfr.com | www.icl-group.com
Although the information and recommendations set forth herein (hereinafter “Information”) are presented in good faith and believed to be correct as of the date hereof, ICL INDUSTRIAL PRODUCTS. makes no representations as to the completeness, accuracy, quality or suitability of any information for any purpose. The use of the Information supplied herein shall be subject to and conditioned on that the persons receiving it and making use of it will make their own determination as to its safety and suitability for their purposes and applicable laws and other statutory demands prior to acquisitions, importations, exportations, transportations, implementations or uses of any kind. In no event will ICL INDUSTRIAL PRODUCTS. be responsible for damages of any nature whatsoever resulting, directly or indirectly, from the use or reliance upon Information.NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED OF MERCHANTABILIT Y, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
ICL - Industrial Products
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South AmericaICL Brasil Ltda.Rua George Ohm, 230 – 21º andar – Torre BBrooklin – Zip Code: 04576-020Tel: + 55 11 2155 4539 Fax : + 55 11 2155 4507 E-mail: [email protected]
Asia PacificChinaICL CHINAFloor 14th of No. 2 Tower of Jin Chuang Building,No. 4560 Jin Ke Road Pudong New District,Shanghai 201210, ChinaTel: +86 21 50296062E-mail: [email protected]
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Head OfficeICL-IPMakleff House, 12 Kroitzer St., P.O.B. 180Beer Sheva 84101, IsraelTel: +972 8 629 7608 Fax: +972 8 629 7846E-mail: [email protected]
EuropeICL Europe Konigin Wilheminaplein 30, 1062 KR, Amsterdam, The NetherlandsP.O. Box 465, 1000 AL Amsterdam, The NetherlandsTel: +31 (0)20 8005800 Fax: +31 (0) 8005805E-mail: [email protected]
North America and MexicoICL-IP America Inc.622 Emerson Road, Suite 500St. Louis, Missouri 63141, USATel: +1 877 661 4272 Fax: +1 314 983 7610E-mail: [email protected]
Other Asia PacificICL Asia ltd.25th Floor, One Capital Place18 Luard Road, Wanchai, Hong KongTel: (852) 2827 7761 Fax: (852) 2824 1502E-mail: [email protected]
Other parts of the WorldICL-IP Israel Sales OfficeMakleff House, 12 Kroitzer St., P.O.B. 180Beer Sheva 84101, IsraelTel: +972 8 629 7633 Fax: +972 8 629 7819E-mail: [email protected]