Final Division Report

IASDATACHEMOURS15418002018DIVISION REPORT 11 2019-AMD 1212020

FLUOROMONOMERS MANUFACTURING PROCESS

DIVISION STACK EMISSIONS TEST REPORT TEST DATES 22 NOVEMBER AND

4 DECEMBER 2019

THE CHEMOURS COMPANY FAYETTEVILLE NORTH CAROLINA

Prepared for

THE CHEMOURS COMPANY 22828 NC Hwy 87 W

Fayetteville North Carolina 28306

Prepared by

WESTON SOLUTIONS INC 1400 Weston Way

PO Box 2653 West Chester Pennsylvania 19380

January 2020

WO No 15418002018

THE CHEMOURS COMPANY

FLOROMONOMERS MANUFACTURING PROCESS DIVISION STACK EMISSIONS TEST REPORT

TEST DATES 22 November and 4 December 2019

Weston Solutions Inc (WESTONreg) is a commercial laboratory operating within full accreditation of the Louisiana Environmental Laboratory Accreditation Program under Certificate Number 03024 The qualifications to provide defensible quality data as a certified commercial environmental testing firm as Agency Interest No 30815 was granted by the Louisiana Department of Environmental Quality under the Louisiana Administrative Code of LAC 331 Chapter 45 et al

I certify that I have personally examined and am familiar with the information contained herein Based on my information and belief formed after reasonable inquiry the statements and information in the document are true accurate and complete

Paul M Meeter Weston Solutions Inc

IASDATACHEMOURS15418002018DIVISION REPORT 11 2019-AMD 1212020 i

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

11 FACILITY AND BACKGROUND INFORMATION 1

12 TEST OBJECTIVES 1

13 TEST PROGRAM OVERVIEW 1

2 SUMMARY OF TEST RESULTS 4

3 PROCESS DESCRIPTIONS 6

31 FLUOROMONOMERS 6

32 PROCESS OPERATIONS AND PARAMETERS 6

4 DESCRIPTION OF TEST LOCATIONS 7

41 DIVISION STACK 7

5 SAMPLING AND ANALYTICAL METHODS 9

51 STACK GAS SAMPLING PROCEDURES 9

511 Pre-Test Determinations 9

52 STACK PARAMETERS 9

521 EPA Method 00109 522 EPA Method 0010 Sample Recovery 11 523 EPA Method 0010 Sample Analysis13

53 MM18 15

54 GAS COMPOSITION 17

6 DETAILED TEST RESULTS AND DISCUSSION 19 APPENDIX A PROCESS OPERATIONS DATA

APPENDIX B RAW AND REDUCED TEST DATA

APPENDIX C LABORATORY ANALYTICAL REPORT

APPENDIX D SAMPLE CALCULATIONS

APPENDIX E EQUIPMENT CALIBRATION RECORDS

APPENDIX F LIST OF PROJECT PARTICIPANTS

IASDATACHEMOURS15418002018DIVISION REPORT 11 2019-AMD 1212020 ii

LIST OF FIGURES

Title Page

Figure 4-1 Division Stack Test Port and Traverse Point Location 8

Figure 5-1 EPA Method 0010 Sampling Train 10

Figure 5-2 HFPO Dimer Acid Sample Recovery Procedures for Method 0010 14

Figure 5-3 Modified EPA Method 18 Sampling Train 16

Figure 5-4 WESTON Sampling System 18

IASDATACHEMOURS15418002018DIVISION REPORT 11 2019-AMD 1212020 iii

LIST OF TABLES

Title Page

Table 1-1 Sampling Plan for Division Stack 3

Table 2-1 Summary of HFPO Dimer Acid Division Stack Test Results 4

Table 2-2 Summary of Target Compound Division Stack Test Results 4

Table 6-1 Summary of HFPO Dimer Acid Test Data and Test Results Division Stack ndash M0010

Runs 1 and 2 20

Table 6-2 Summary of Target Compound Test Data and Test Results Division Stack ndash MM18

Runs 1 2 and 3 22

IASDATACHEMOURS15418002018DIVISION REPORT 11 2019-AMD 1212020 1

1 INTRODUCTION

11 FACILITY AND BACKGROUND INFORMATION

The Chemours Fayetteville Works (Chemours) is located in Bladen County North Carolina

approximately 10 miles south of the city of Fayetteville Chemours operating areas on the site

include the Fluoromonomers IXM and Polymers Processing Aid (PPA) manufacturing areas

Wastewater Treatment and Powerhouse

Chemours contracted Weston Solutions Inc (Weston) to perform HFPO Dimer Acid Fluoride

captured as HFPO Dimer Acid and other target compound emission testing on the Division

stack at the facility Testing was performed on 22 November and 4 December 2019 and generally

followed the ldquoEmission Test Protocolrdquo reviewed and approved by the North Carolina

Department of Environmental Quality (NCDEQ) This report provides the results from the

emission test program

12 TEST OBJECTIVES

The specific objectives for this test program were as follows

Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride and other target compounds from the Division stack which is located in the Fluoromonomers process area

Monitor and record process and emissions control data in conjunction with the test program

Provide representative emissions data

13 TEST PROGRAM OVERVIEW

During the emissions test program the concentrations and mass emissions rates of HFPO Dimer

Acid and other target compounds were measured at the Division stack

Table 1-1 provides a summary of the test location and the parameters that were measured along

with the samplinganalytical procedures that were followed

Section 2 provides a summary of test results A description of the processes is provided in

Section 3 Section 4 provides a description of the test locations The sampling and analytical

procedures are provided in Section 5 Detailed test results and discussion are provided in

Section 6

Appendix C includes the summary reports for the laboratory analytical results The full

laboratory data packages are provided in electronic format

2 SUMMARY OF TEST RESULTS

A total of three MM18 and two M0010 test runs were performed on the Division stack Table 2-1

provides a summary of the HFPO Dimer Acid emissions test results associated with M0010

Table 2-2 provides a summary of the target compound emissions test results associated with

MM18 Detailed test results summaries are provided in Section 6

It is important to note that emphasis is being placed on the characterization of the emissions

based on the M0010 stack test results Research conducted in developing the protocol for stack

testing HFPO Dimer Acid Fluoride HFPO Dimer Acid Ammonium Salt and HFPO Dimer Acid

realized that the resulting testing including collection of the air samples and extraction of the

various fraction of the sampling train would result in all three compounds being expressed as

simply the HFPO Dimer Acid However it should be understood that the total M0010 HFPO

Dimer Acid results provided in Table 2-1 and in this report include a percentage of each of the

three compounds

Table 2-1 Summary of M0010 HFPO Dimer Acid Division Stack Test Results

Division Stack ndash M0010 gsec lbhr

R1 194E-04 154E-03 R2 339E-04 269E-03 Average 266E-04 212E-03

Samples taken using MM18 were analyzed for the following volatile organic compounds (ldquotarget

compoundsrdquo) HFPO Dimer Methyl Ester as HFPO (HFPO Dimer Methyl Ester) 2-MTP as

HFPO (HFPO Monomer) Heptafluoropropyl 1222-tetrafluoroethyl ether (Fluoroether E-1)

Carbonyl Difluoride Total Fluorine and Hydrogen Fluoride Results of MM18 target compound

analysis are provided in Table 2-2

Table 2-2 Summary of MM18 Target Compound Division Stack Test Results

Target Compound

Division Stack MM18 Run 1

gsec lbhr gsec lbhr gsec lbhr HFPO Dimer Methyl Ester

lt438E-03 lt348E-02 lt260E-03 lt207E-02 lt263E-03 lt209E-02

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

lt182E-01 lt145E+00 lt109-01 lt863E-01 lt110E-01 lt870E-01

Note All lt values were below the laboratory analysis detection limits Emission rates were calculated using the method detection limit (MDL) for the first analytical fraction of the target compound

3 PROCESS DESCRIPTIONS

The Fluoromonomers area is included in the scope of this test program

31 FLUOROMONOMERS

These facilities produce a family of fluorocarbon compounds used to produce Chemours

products such as Nafionreg Krytoxreg and Vitonreg as well as sales to outside customers

At the time of testing process emissions were vented to the Division waste gas scrubber system

(which included the secondary scrubber) and vented to the Carbon Bed and then into the

Division stack The VE North building air systems were vented to the Carbon Bed and then into

the Division stack

32 PROCESS OPERATIONS AND PARAMETERS

The following table is a summary of the operation and products from the specific areas tested

Source OperationProduct Batch or Continuous VE North

PPVE Condensation is continuous Agitated Bed Reactor and Refining are batch

During the test program the following parameters were monitored by Chemours and are

included in Appendix A

Fluoromonomers Process o VEN Precurser Rate o VEN Condensation Rate o VEN ABR Rate

4 DESCRIPTION OF TEST LOCATIONS

41 DIVISION STACK

Two 6-inch ID test ports were installed on the 36-inch ID fiberglass stack as shown below The

four vents that enter the top of the stack and the one vent ~11 feet below are catch pots which

under normal process operations do not discharge to the stack They are used to vent process gas

to the stack in the event of a process upset and are not considered a flow contributor or a

disturbance

Per EPA Method 1 a total of 12 traverse points (six per axis) were used for M-0010 isokinetic

sampling Figure 4-1 provides a schematic of the test ports and traverse point locations

Location Distance from Flow Disturbance Downstream (B) Upstream (A)

Division Stack 30 feet gt 10 duct diameters

9 feet gt 3 diameters

The EPA Method 18 sample was collected at a constant rate at a single point at the approximate

center of the stack

5 SAMPLING AND ANALYTICAL METHODS

51 STACK GAS SAMPLING PROCEDURES

The purpose of this section is to describe the stack gas emissions sampling trains and to provide

details of the stack sampling and analytical procedures utilized during the emissions test

program

511 Pre-Test Determinations

Preliminary test data were obtained at the test location Stack geometry measurements were

measured and recorded and traverse point distances verified A preliminary velocity traverse

was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine

velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel

meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was

estimated by wet bulbdry bulb temperature measurements

A check for the presence or absence of cyclonic flow was previously conducted at the test

location The cyclonic flow check was negative (lt 20deg) verifying that the test location was

acceptable for testing

Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic

sampling procedures

Calibration of probe nozzles pitot tubes metering systems and temperature measurement

devices was performed as specified in Section 5 of EPA Method 5 test procedures

52 STACK PARAMETERS

521 EPA Method 0010

The sampling train utilized to perform the HFPO Dimer Acid sampling at the location was an

EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle

that attached directly to a heated borosilicate probe In order to minimize possible thermal

degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack

temperature to minimize water vapor condensation before the filter The probe was connected

directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter

A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a

Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing

approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet

temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and

a series of two impingers that contained 100 mL of high-purity distilled water The train also

included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling

train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap

The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the

condensate traps were maintained in an ice bath Ice water was continuously circulated in the

condenser and the XAD-2 module to maintain method-required temperature A control console

with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected

to the final impinger via an umbilical cord to complete the sample train

HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to

be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO

Dimer Acid Fluoride underwent hydrolysis instantaneously in water in the sampling train and

during the sample recovery step and was converted to HFPO Dimer Acid such that the amount

of HFPO Dimer Acid emissions represented a combination of both HFPO Dimer Acid Fluoride

and HFPO Dimer Acid

During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube

into the gas stream adjacent to the sampling nozzle The velocity pressure differential was

observed immediately after positioning the nozzle at each traverse point and the sampling rate

adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each

point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each

traverse point during all test periods as appropriate Leak checks were performed on the

sampling apparatus according to reference method instructions prior to and following each run

component change (if required) or during midpoint port changes

522 EPA Method 0010 Sample Recovery

At the conclusion of each test the sampling train was dismantled the openings sealed and the

components transported to the field laboratory trailer for recovery

A consistent procedure was employed for sample recovery

1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) weresealed and labeled

2 The glass fiber filter(s) were removed from the holder with tweezers and placed in apolyethylene container along with any loose particulate and filter fragments

3 The particulate adhering to the internal surfaces of the nozzle probe and front half of thefilter holder were rinsed with a solution of methanol and ammonium hydroxide into apolyethylene container while brushing a minimum of three times until no visibleparticulate remained Particulate adhering to the brush was rinsed with methanolammonium hydroxide into the same container The container was sealed

4 The volume of liquid collected in the first condensate trap was measured the valuerecorded and the contents poured into a polyethylene container

5 All train components between the filter exit and the first condensate trap were rinsed withmethanolammonium hydroxide The solvent rinse was placed in a separate polyethylenecontainer and sealed

6 The volume of liquid in impingers one and two and the second condensate trap weremeasured the values recorded and the sample was placed in the same container as Step 4above then sealed

7 The two impingers condensate trap and connectors were rinsed with methanolammonium hydroxide The solvent sample was placed in a separate polyethylenecontainer and sealed

8 The silica gel in the final impinger was weighed and the weight gain value recorded

9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filterand distilled water were retained for analysis

Each container was labeled to clearly identify its contents All samples were maintained cool

Following sample recovery all samples were transported to Eurofins TestAmerica

(TestAmerica) for sample extraction and analysis

See Figure 5-2 for a schematic of the Method 0010 sample recovery process

523 EPA Method 0010 Sample Analysis

Method 0010 sampling trains resulted in four separate analytical fractions for HFPO Dimer Acid

analysis according to SW-846 Method 3542

Front-half Compositemdashcomprised of the particulate filter and the probe nozzle and

front-half of the filter holder solvent rinses

Back-half Compositemdashcomprised of the first XAD-2 resin material and the back-half of

the filter holder with connecting glassware solvent rinses

Condensate Compositemdashcomprised of the aqueous condensates and the contents of

impingers one and two with solvent rinses

Breakthrough XAD-2 Resin Tubemdashcomprised of the resin tube behind the series of

impingers

The second XAD-2 resin material was analyzed separately to evaluate any possible sampling

train HFPO-DA breakthrough

The front-half and back-half composites and the second XAD-2 resin material were placed in

polypropylene wide-mouth bottles and tumbled with methanol containing 5 NH4OH for 18

hours Portions of the extracts were processed analytically for the HFPO dimer acid by liquid

chromatography and duel mass spectroscopy (HPLCMSMS) The condensate composite was

concentrated onto a solid phase extraction (SPE) cartridge followed by desorption from the

cartridge using methanol Portions of those extracts were also processed analytically by

HPLCMSMS

VACUUM LINEMAINVALVE

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

DRY ICE AND METHANOL

METHANOL IN EACH IMPINGER

FIGURE 5-3MODIFIED EPA METHOD 18 SAMPLING TRAIN FOR PFAS COMPOUNDS

GLASS IMPINGERS

STACK WALL

PLASTIC OR GLASS PROBE

PRESSUREDIFFERENTIAL

8 3 18

54 GAS COMPOSITION

The Weston mobile laboratory equipped with instrumental analyzers was used to measure carbon

dioxide (CO2) and oxygen (O2) concentrations A diagram of the Weston sampling system is

presented in Figure 5-4

For the Division stack test campaign the sample was collected at the exhaust of the Method

0010 sampling system At the end of the line a tee permitted the introduction of calibration gas

The sample was drawn through a heated Teflonreg sample line to the sample conditioner The

output from the sampling system was recorded electronically and one minute averages were

recorded and displayed on a data logger

Each analyzer was set up and calibrated internally by introduction of calibration gas standards

directly to the analyzer from a calibration manifold The calibration manifold is designed with an

atmospheric vent to release excess calibration gas and maintained the calibration at ambient

pressure The direct calibration sequence consisted of alternate injections of zero and mid-range

gases with appropriate adjustments until the desired responses were obtained The high-range

standards were then introduced in sequence without further adjustment

The sample line integrity was verified by performing a bias test before and after each test period

The sampling system bias test consisted of introducing the zero gas and one up-range calibration

standard in excess to the valve at the probe end when the system was sampling normally The

excess calibration gas flowed out through the probe to maintain ambient sampling system

pressure Calibration gas supply was regulated to maintain constant sampling rate and pressure

Instrument bias check response was compared to internal calibration responses to insure sample

line integrity and to calculate a bias correction factor after each run using the ratio of the

measured concentration of the bias gas certified by the calibration gas supplier

The oxygen and carbon dioxide content of each stack gas was measured according to EPA

Method 3A procedures which incorporate the latest updates of EPA Method 7E A Servomex

Model 4900 analyzer (or equivalent) was used to measure oxygen content A Servomex Model

4900 analyzer (or equivalent) was used to measure carbon dioxide content of the stack gas Both

analyzers were calibrated with EPA Protocol gases prior to the start of the test program and

performance was verified by sample bias checks before and after each test run

6 DETAILED TEST RESULTS AND DISCUSSION

M0010 test run number two was stopped prior to the full run time due to a process upset in the

area The run was considered complete and the sample was recovered and submitted for analysis

A total of two M0010 test runs were performed at the location A total of three MM18 test runs

were performed at the location

Table 6-1 provides detailed M0010 test data and test results for Division stack Table 6-2

provides detailed MM18 test data and test results for the Division stack

The Method 3A sampling indicated that the O2 and CO2 concentrations were at ambient air

levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all

calculations

It should be noted that methylene chloride was identified in the MM18 analytical results This

detection was due to a special procedure done in the process area in which methylene chloride

was used to unplug equipment that experienced plugging during testing Methylene chloride

would not typically be detected in this process area

APPENDIX A PROCESS OPERATIONS DATA

Division

Date 11222019TimeStack TestingHFPOVEN ProductVEN PrecursorVEN Condensation (HFPO)VEN ABRVEN RefiningStripper Column VentDivision WGS Recirculation FlowDivision WGS Inlet Flow

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

15000 kgh142 kgh 145 kgh 148 kgh 150 kgh 135 kgh 128 kgh 74 kgh103 kgh

RUN 3 0955-1125

800 900 1000 1100

15000 kgh65 kgh 73 kgh 110 kgh

Sample and Velocity Traverse Point Data Sheet - Method 1

Client CJtl 11 eAAI Operator Loact1onPlant Vltf t fcu I le v Date 2J- l

Source ( v ) _5 -rj(L W O Number JT(t O

Duct Type Circular D Rectangular Duct Indicate eppropMate type

Traverse Type II( Particulate Traverse D Velocity Traverse D CEM Traverse

Distance from far wall to outside of oort lln l = C ltdeglt ) Flow Disturbances -

Port Deoth (in) = D 121 ur Upstream - A (ft) (1 (t I

Deoth or Duct diameter (inI= C-D I (I Area of Duct (ff) -11 7 01 - - --

Total Traverse Points 1 I tJ fa

Total Traverse Points oer Port

Port Diameter flnl-Flanae-Threaded-Holel l I

Monorail Lenoth t) Rectangular Ducts Onty

Width of Duct rectanaular duct only (In I Total Ports (rectanoular duct only) Eauivalent Diameter= 12middotL Wl(L+W)

Traverse Point Locations

Distance from Traverse Inside Duct Distance1from Outside of

Point of Duct Wallinl Portin)

1 1 i I 1- I b2 jtmicro 1poundgt

2 ( gt-0 h A il1

l y gtf-uir 7 vr

3 21 I09S- timiddot 1T 1e 1 tJ lDI 1

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

CEM 3 Polnl(Long Measurmbullnt Unbull) StraUflcaton POnt Locations

0833 Note If stack dla lt 12 inch use EPA Method 1A

(Sample port upstream of pilot port) Note stack dia gt24 then adjust traverse point to 1 inch from wall

If stack dia lt24 then adjust traverse point to 05 inch from wall

l 2 T I 146

r 2 854 ) L

4 bull 0

r C 5 bull a 6 o I 7

8 p 0 o n 9

n II 12

Traverso Point Location Ptrcant of Stack Circular

NwnberofT IPoints 5 6 8

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

Downstream - B (ft) -

Upstream - A (duct diameters t

Downstream - B duct diameters) 61Diagram of Stack

11 _ ---

ltl Igt-

ry middoti 5D -

Duct 0middot1ameters Upstream from Flow Disturbance (Distance A

05 1 0 1 5 20 25 50

I I I I I I I

Stack Diametergt 24 Inches deg t

40 - A

plusmn --- -middot

Minimum Number cf bull

JO -Particulate Traverse Points

24 (chular) 25 (mctangulw dlJdltl)

Traverse Polllls for Velocity 16

I 10 _ Disturbance =Band Expansion Contraction etc

B(tmJiir)lilj

S1adDlaarDti1224Rnefl

Duct Dlemehn Downstraam from Acv Dl1furbance (Olslenca B)

Travers Point Location Panent of Stack ootanaular

NIJlber ofTnrne Polnls I 2 l 4 5 6 7 8 9 10 II ll

T I 250 167 125 100 8J 71 6J 56 50 45 41

2 7SO 51l0 31J 300 25J ZIA 18J 167 ISII llli 11l J 8) 3 625 500 417 )57 JU 278 250 227 208 l

4 75 70I ID 5110 431 IU 310 318 29Z o 5 900 750 60 563 500 4SO 409 Jll a 6 911 JU 611 U ru tea 458 I 7 C29 813 722 650 91 l4l

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS

DIVISION STACK

Test DataRun number 1 2Location Divison Stack Divison StackDate 112219 112219Time period 0826-1022 1139-1324Operator BB BB

Inputs For CalcsSq rt delta P 145039 122804Delta H 14025 10010Stack temp (degF) 716 794Meter temp (degF) 570 652Sample volume (act) 63136 47088Barometric press (inHg) 3002 3002Volume H2O imp (ml) 100 70Weight change sil gel (g) 244 145 CO2 00 00 O2 209 209 N2 791 791Area of stack (sqft) 7070 7070Sample time (min) 960 840Static pressure (inH2O) -035 -035Nozzle dia (in) 0160 0160Meter box cal 09972 09972Cp of pitot tube 084 084Traverse points 12 12

122020 1102 AM 112219 Div Stack M001028

ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Dimer Acid Page J~ orb client chemours Stack Conditions Meter Box ID K Factor Q wo 15418002018 Assumed Actual MeterBox Y rjq7 a Project ID Chemours Moisture ^~ 3 Meter Box Del H ~ $j ~~ Illltlal Mid-Point Final ModeSource ID Division Impinger Vol (ml) Probe ID Length L~~ ~ Sample Train (ft3) o o D 5 GAO U (~(~ Samp Loc ID STK Silica gel (g) Probe Material ~Boro Leak Check (in Hg) `~ ~ S ~~ ~

Run NoID 1 CO2 deg by Vol Q Pitot Thermocouple ID Pitot leak check good yes no no no Test Method ID M0010 02 by Vol ~ ~ Pitot Coe~cient 84~r Pitot Inspection good no ye no no Date ID NOV2019 Temperature (degF) ~ Noale ID ~~ Method 3 System good yes no yes no yes no SourceLocation Div(sion Stack Meter Temp (F) l~ Noale Measurements ~ 6 p ~ LO Temp Check re-Test Set POSt-Test Set Sample Date ~ Static Press (in H2O) mdash ~ 3 ~j ~J Avg Noale Dia (in) ~ ~ 6 bull ~ Meter Box Temp

Baro Press (in Hg) Area of Stack (ftz) Q~ Reference Temp Operator Ambient Temp (degF) ~ ~ Sample Time `~ (~ PasslFail (+- 2deg~ Pass Fail Pass Fail

Total Traverse Pts ~ a Temp Change Response ~ yes no yes no

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

avg uena r ( vvg uerca ry

a ~ ~Ib J Ava Sart Delta P Avo Sart Dei t

i oral vowme~ ( b vvg i s

~~~ nments

J ~lr ~ ~~~~13~

vvg i m J rvun~nnax rvunlnnax nnax rwax vac nnin~rv~ax

~~ d ltltu~~~~ te6~~~~( sq g H~ly~ EPA Method 0010 from EPA SW- 46

(~ Q~ ~~~ 29

ISOHINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Dimer Acid Page ~ or 1 Client Chemours Stack Conditions Meter Box ID qq~ ~ K Factor ~ 6 WO 15418002018 Assumed Actual Meter Box Y Project ID Chemours Moisture ~ Meter Box Del H ( gj ~ Init181 Mid-Point FIn81 ModeSource ID Division Impinger Vol (ml) Probe ID Length H q 4 ~ 6~ Sample Train (ft3) ~ Oo ~ jj ~ Samp Loc ID STK Silica gel (g)

mdash~ Probe Material Boro Leak Check (in Hg) ~

Run NoID 2 CO2 by Vol Pitot Thermocouple ID Pitot leak check good ~ no e no yes np Test Method ID M0010 02 deg by Vol ~ q Pitot Coefficient 084 Pitot Inspection good no e no yes no Date ID S L

NOV2019 Temperature (degF) MeterT m F

~~ Noale ID Method 3 S stem ood Y 9 Yes no yes no yes no ource ovation Diviswn Stack e P ( ) Noale Measurements I b~ ~ 60 ~ (~ Temp Check Pre-Test et Post-Test Set

Sample Date ~ ~ a mdash ( Static Press (in Hz0) mdash~ 3 Avg Noale Dia (in) ( ~ Meter Box Temp Baro Press (in Hg) Q Area of Stack (ft2) Reference Temp Operator Ambient Temp (degF) SQ Sample Time _q~-- `~j PassFail (+- 2deg) Pass Fail Pass Fail

Total Traverse Pts ~ ~ Temp Change Response yes no ves no

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

Avg Sgrt Delta P Avg Sgrt Del

t-~`~~5 ~~~~~~~

bully bull~ r ~~~~~~~~a~ miuimnn man max vac mnuPnax

~~ flg~ ~1q~1 lo ~-- QOIl2(o g3(tl5 (a~ (v ~I`b~(o0 Comments EPA Method 0010 from EPA SW-846

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

TEST DATA Test run number 1 2 3 Location Division Stack Division Stack Division Stack Test date 112219 112219 12419 Test time period 0826-1022 1139-1318 0955-1125Operator WF WF KS

SAMPLING DATA Duration minutes 84 78 90 Average dry gas meter press in H2O 341 356 500 Average dry gas meter temp deg F 549 6600 5450 Average absolute meter temp deg R 5149 5260 5145 Sample vol at meter cond dcl 143580 147394 159313 Meter box calibration Y 09996 09996 10140 Barometric pressure in Hg 3002 3002 3012 Sample volume dscl (1) 148843 149624 168860 Sample volume dscf (1) 5256 5283 5963

VOLUMETRIC FLOW RATE Avg gas stream volumetric flow dscfmin 33787 28485 31136

(1) Standard conditions = 68 deg F (20 deg C) and 2992 inches Hg (760mm Hg)

CHEMOURS-FAYETTEVILLE NCINPUTS FOR EPA MM18 TARGET COMPOUND CALCULATIONS

DIVISION STACK

FIELD DATA SHEET Client Chemours Run No

WO 15418002018 Test Method

Project ID CHEM-F Date

ModeSource ID Division Baro Press (in Hg)

Samp Loc Stack Ambient Temp (degF)

Source Division Stk Operator

Sample Time Comments Initial Probe Leak check

Final Probe Leak check

MM 1 S - HFPO Diener Acid Page ~ of ~ 1 Meter Box ID

Modified M18 Meter Box Y Q G

Nov 2019 Probe IDLength Leak Check (in Hg) (~~~ ~bdquo~~~ I I (~Q (1~~ ~

3Q (~Z Probe Material Pitot leak check good yecLpry yes no y~uc_Law

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Avg Delta H Total Volume Avg Tm Max Temp Max Vac Max Temp

FIELD DATA SHEET Client

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

15418002018 Test Method

CHEM-F Date

Division Baro Press (in Hg)

Stack Ambient Temp (degF)

Division Stk Operator

Sample Time

Initial Probe Leak check Final Probe Leak check

MM 18 - HFPO Dimer Acid 2 Meter Box ID ~0

Modified M18 Meter Box Y G~ ~+ Nov 2019 Probe IDLength Leak Check (in Hg)

~(~ p ~ Probe Material Pitot Teak check good

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~bulls~s7xix~~rax a

Hvg ueita n ~ i otai volume

35~ ~ I~1~~ Hvg i m Hoax I emp Max Vac Max Temp

~~v S~~-~Ll~

SAMPLE RECOVERY FIELD DATA

Client r~i4 ~`~ WO LocationPlant ~ ~~ bdquomdash r Source ampLocation J I~

Run No Sample Date ~~~~ ~ Recovery Date gt ~

Sample ID ~ ~~(~ Analyst ~ ~ Filter Number

Im in er 1 2 3 4 5 6 7 Im Total 8 Total

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

ca~~ I3 ~- -_~ i ImpingerColor ~A~ j~=~~ Labeled

mdash~ Silica Gel Condition Sealed

Run No ~ Sample Date ~ ~~ Recovery Date ~~~

Sample ID Analyst Filter Number ~~

Im in er 1 2 3 4 5 6 7 ImpTotai 8 Total

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Impinger Color ~j ( ~ Labeled

Silica Gel Condition Sealed

Run No lf~ Sample Dated ~ ~ Recovery Date ~~ tmdash

Sample ID ~ Analyst Filter Number

Im in er 1 2 3 4 5 6 7 ImpTotal 8 Total

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Gain ~ 4 ~G(~j~ ~ Impinger Color -~ ~ La~ed

Check COC for Sample IDs of Media Blanks ~ ~~

FIELD DATA SHEET MM 18 Client Chemours Run No 1 Meter Box ID

WO 15418002018 Test Method Modified M18 Meter Box Y D I~

Project ID CHEM-F Date ~I Dec 2019 Probe IDLength Leak Check (in Hg)

ModeSource ID VE NoRh Baro Press (in Hg) 3~~ Probe Mate~ai Pitot leak check good Samp Loc Stack Ambient Temp (degF) O

Source Division Operator f

Sample Time ~~ M~

Comments Initial Probe Leak check ~~ a ~~pi~

Final Probe Leak check ~~i y ~r~~~p

Page ~ of

yes no yes no yes no

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

--~ -- ~~-~ Avg Delta HJ Total Volume Avg Tm MaxTemp Max Vac Max Temp

Client ~ ~ lam C~1` s WO l~ 4 l~ gt~ti~- =~~ ~vi LocatioNPlant r-c~ t~ Source ampLocation ~ C JV~3c- mdash ~ y~~ ~~ 5

Run No 3 Sample Date Iz-~ ~-1 mdash j ~ Recovery Date ~~9

Sample ID Analyst Filter Number i l~ Im in er

1 2 3 4 5 6 7 Im Total 8 Total Contents Silica Gel

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Initial ~ ~ ~ C1~ bull ~- L ~c3~-~j ~ 13~

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Impinger Color ______~~ Labeled r

Silica Gel Condition +~U Sealed

Run No Sample Date Recovery Date

Sample ID Analyst Filter Number

Contents ~ Silica Gel

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Impinger Color Labeled

Contents Silica Gel

Initial

Check COC for Sample IDs of Media Blanks ~`

k3aT~AF c

ANALYTICAL REPORTJob Number 140-17458-1

Job Description VEN Stack - M0010

Contract Number LBIO-67048

ForChemours Company FC LLC The

co AECOMSabre Building Suite 300

4051 Ogletown RoadNewark DE 19713

Attention Michael Aucoin

_____________________________________________

Approved for releaseCourtney M AdkinsProject Manager II12102019 307 PM

Courtney M Adkins Project Manager II5815 Middlebrook Pike Knoxville TN 37921

(865)291-3000courtneyadkinstestamericainccom

12102019

This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page

The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager

This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature

Eurofins TestAmerica Knoxville

5815 Middlebrook Pike Knoxville TN 37921

Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom

12102019Page 1 of 21339

Table of ContentsCover Title Page 1

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Client Sample Results 11

Default Detection Limits 13

Surrogate Summary 14

QC Sample Results 15

Chronicle 18

Certification Summary 22

Manual Integration Summary 24

Organic Sample Data 25

LCMS 25

8321A_HFPO_Du 258321A_HFPO_Du QC Summary 268321A_HFPO_Du Sample Data 32Standards Data 40

8321A_HFPO_Du ICAL Data 408321A_HFPO_Du CCAL Data 63

Raw QC Data 758321A_HFPO_Du Tune Data 758321A_HFPO_Du Blank Data 808321A_HFPO_Du LCSLCSD Data 92

12102019Page 2 of 21340

Table of Contents8321A_HFPO_Du Run Logs 1058321A_HFPO_Du Prep Data 107

Method DV-LC-0012 114Method DV-LC-0012 QC Summary 115Method DV-LC-0012 Sample Data 123Standards Data 147

Method DV-LC-0012 CCAL Data 147Raw QC Data 165

Method DV-LC-0012 Tune Data 165Method DV-LC-0012 Blank Data 170Method DV-LC-0012 LCSLCSD Data 182

Method DV-LC-0012 Run Logs 198Method DV-LC-0012 Prep Data 200

Shipping and Receiving Documents 206

Client Chain of Custody 207

12102019Page 3 of 21341

DefinitionsGlossaryJob ID 140-17458-1Client Chemours Company FC LLC The

ProjectSite VEN Stack - M0010

Qualifiers

LCMSQualifier Description

LCS or LCSD is outside acceptance limits

Qualifier

B Compound was found in the blank and sample

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value

GlossaryThese commonly used abbreviations may or may not be present in this report

curren Listed under the D column to designate that the result is reported on a dry weight basis

Abbreviation

R Percent Recovery

CFL Contains Free Liquid

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoDDOE)

DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoDDOE)

LOQ Limit of Quantitation (DoDDOE)

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

12102019Page 4 of 21342

Method SummaryJob ID 140-17458-1Client Chemours Company FC LLC The

Method Method Description LaboratoryProtocol

SW8468321A HFPO-DA TAL DEN

SW8468321A PFOA and PFOS TAL DEN

TAL SOPNone Leaching Procedure TAL DEN

TAL SOPNone Leaching Procedure for Condensate TAL DEN

TAL SOPNone Leaching Procedure for XAD TAL DEN

Protocol References

SW846 = Test Methods For Evaluating Solid Waste PhysicalChemical Methods Third Edition November 1986 And Its Updates

TAL SOP = TestAmerica Laboratories Standard Operating Procedure

Laboratory References

TAL DEN = Eurofins TestAmerica Denver 4955 Yarrow Street Arvada CO 80002 TEL (303)736-0100

12102019Page 5 of 21343

Sample SummaryJob ID 140-17458-1Client Chemours Company FC LLC The

Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID

140-17458-1 G-25772578 DIV VEN STACK R1 M0010 FH Air 112219 0000 112519 0800

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

BREAKTHROUGH XAD-2 RESIN TUBE

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Job Narrative140-17458-1

Sample Receipt

The samples were received on November 25 2019 at 800 AM in good condition and properly preserved The temperature of the cooler at receipt was 16ordm C

Quality Control and Data Interpretation

Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements

Method 0010Method 3542 Sampling Train Preparation

Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample

Method 8321A The following samples were inadvertently spiked with a native solution of HFPO-DA rather than the isotope dilution

internal standard prior to extraction in the Knoxville Laboratory

middot DIV VEN Stack R1 FHmiddot DIV VEN Stack R1 BHmiddot DIV VEN R1 Breakthrough middot DIV VEN Stack R2 FHmiddot DIV VEN Stack R2 BHmiddot DIV VEN R2 Breakthrough

As a result these samples received a relatively small fortification of the native HFPO-DA and no labeled IDA as typically applied Upon

discovery of the processing issue the IDAs were post spiked onto the extracted samples which were then re-analyzed to acquire the

Total HFPO-DA content in the samples The spiked amount of native HFPO-DA was subsequently subtracted from the Total HFPO-DA

and the corrected concentration is reported in with the data set below

Please note that under these conditions the affected samples are not corrected for extraction losses through isotope dilution internal

standard data reduction However the HFPO-DA concentrations are accurate and useful for their intended purpose

Method 8321A The laboratory control sample (LCS) and or laboratory control sample duplicate (LCSD) for preparation batch 280-478940 and analytical batch 280-479928 recovered outside control limits for the following analytes HFPO These analytes were biased high in the LCS and were not detected in the associated samples therefore the data have been reported

No additional analytical or quality issues were noted other than those described above or in the DefinitionsGlossary page

Organic Prep

No analytical or quality issues were noted other than those described in the DefinitionsGlossary page

12102019Page 7 of 21345

Chemours VES Carbon Bed Outlet Test Analytical Report TestAmerica Job No 140-17458-1

December 10 2019

OUsers FoldersAdkinsCProject DocumentsSpecial ReportingChemours Corrected ValuesFayettevilleChemours Corrected Results HFPO-DA_DIV VEN Stack_12102019docx Created on 01302018 Last edited on 12102019 302 PM

The following samples were inadvertently spiked with a native solution of HFPO-DA prior to extraction

in the Knoxville laboratory

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN R1 Breakthrough

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

The HFPO-DA results presented below have been corrected to remove the laboratory contribution from the final result

TALS ID Client ID HFPO-DA Result (ugsample)

HFPO-DA Added in the lab

(ugsample)

HFPO-DA Corrected Result

(ugsample)

140-17458-1 DIV VEN Stack R1 FH

986 2 786

140-17458-2 DIV VEN Stack R1 BH

213 7 143

140-17458-4 DIV VEN R1 Breakthrough

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

QC Association SummaryJob ID 140-17458-1Client Chemours Company FC LLC The

Analysis Batch 464589

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA

Prep Batch 478940

Air None140-17458-1 G-25772578 DIV VEN STACK R1 M0010 FH TotalNA

Air NoneMB 280-47894014-A Method Blank TotalNA

Air NoneLCS 280-4789402-A Lab Control Sample TotalNA

Air NoneLCSD 280-4789403-A Lab Control Sample Dup TotalNA

Prep Batch 478993

Air None140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS 12amp3 CONDTotalNA

Prep Batch 479245

Air None140-17458-2 G-257925802582 DIV VEN STACK R1 M0010 BHTotalNA

Air None140-17458-4 G-2583 DIV VEN STACK R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA

Air 8321A 478993140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS 12amp3 CONDTotalNA

Air 8321A 478993MB 280-47899314-A Method Blank TotalNA

Air 8321A 478993LCS 280-4789932-A Lab Control Sample TotalNA

Air 8321A 478993LCSD 280-4789933-A Lab Control Sample Dup TotalNA

Air 8321A 478940140-17458-1 G-25772578 DIV VEN STACK R1 M0010 FH TotalNA

Air 8321A 479245140-17458-2 G-257925802582 DIV VEN STACK R1 M0010 BHTotalNA

12102019Page 9 of 21347

LCMS (Continued)

Analysis Batch 479929 (Continued)

Air 8321A 479245140-17458-4 G-2583 DIV VEN STACK R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotalNA

12102019Page 10 of 21348

Client Sample ResultsJob ID 140-17458-1Client Chemours Company FC LLC The

Lab Sample ID 140-17458-1Client Sample ID G-25772578 DIV VEN STACK R1 M0010 FHMatrix AirDate Collected 112219 0000

Date Received 112519 0800Sample Container Air Train

Method 8321A - PFOA and PFOSRL MDL

HFPO-DA 986 B 0100 00108 ugSample 112719 0804 120819 0915 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

Surrogate Dil FacAnalyzedPreparedQualifier LimitsRecovery

Lab Sample ID 140-17458-2Client Sample ID G-257925802582 DIV VEN STACK R1 M0010 BH

Matrix AirDate Collected 112219 0000Date Received 112519 0800Sample Container Air Train

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

Lab Sample ID 140-17458-3Client Sample ID G-2581 DIV VEN STACK R1 M0010 IMPINGERS 12amp3 COND

Method 8321A - HFPO-DARL MDL

HFPO-DA 0145 J 0212 00108 ugSample 112719 1236 120619 1241 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

Lab Sample ID 140-17458-4Client Sample ID G-2583 DIV VEN STACK R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBE

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

HFPO-DA ND 0196 000999 ugSample 112719 1236 120619 1244 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Default Detection LimitsClient Chemours Company FC LLC The Job ID 140-17458-1ProjectSite VEN Stack - M0010

Method 8321A - HFPO-DAPrep None

000250HFPO-DA ugSample

Analyte UnitsMDLRL

000128

Method 8321A - PFOA and PFOSPrep None

Analyte UnitsMDLRL

000270

0100HFPO-DA ugSample00200

12102019Page 13 of 21351

Job Description VEN Stack - MM-18

_____________________________________________

(865)291-3000 courtneyadkinstestamericainccom

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

Method 8260B 77Method 8260B QC Summary 78Method 8260B Sample Data 93Standards Data 287

Method 8260B ICAL Data 287Method 8260B CCAL Data 389

Raw QC Data 437Method 8260B Tune Data 437Method 8260B Blank Data 453Method 8260B LCSLCSD Data 461

12232019Page 2 of 89453

Table of ContentsMethod 8260B MSMSD Data 474

Method 8260B Run Logs 482Method 8260B Prep Data 495

HPLCIC 498

Method 9056 498Method 9056 QC Summary 499Method 9056 Sample Data 502Standards Data 538

Method 9056 ICAL Data 538Method 9056 CCAL Data 565

Raw QC Data 612Method 9056 Blank Data 612Method 9056 LCSLCSD Data 638Method 9056 MSMSD Data 644

Method 9056 Run Logs 650Method 9056 Prep Data 664

Method 9056A Total Halogens 667Method 9056A Total Halogens QC Summary 668Method 9056A Total Halogens Sample Data 676Standards Data 715

Method 9056A Total Halogens ICAL Data 715Method 9056A Total Halogens CCAL Data 740

Raw QC Data 781Method 9056A Total Halogens Blank Data 781Method 9056A Total Halogens LCSLCSD Data 817Method 9056A Total Halogens MSMSD Data 831

12232019Page 3 of 89454

Table of ContentsMethod 9056A Total Halogens Run Logs 839Method 9056A Total Halogens Prep Data 855

Inorganic Sample Data 864

General Chemistry Data 864

Gen Chem Cover Page 865

Gen Chem Sample Data 866

Gen Chem QC Data 878Gen Chem ICVCCV 878Gen Chem Duplicates 879

Gen Chem MDL 880

Gen Chem Analysis Run Log 881

Gen Chem Prep Data 882

Gen Chem Raw Data 884

12232019Page 4 of 89455

ProjectSite VEN Stack - MM-18

Qualifiers

GCMS VOAQualifier Description

Qualifier

H Sample was prepped or analyzed beyond the specified holding time

GCMS VOA TICsQualifier Description

Qualifier

J Indicates an Estimated Value for TICs

N Presumptive evidence of material

T Result is a tentatively identified compound (TIC) and an estimated value

HPLCICQualifier Description

Qualifier

General ChemistryQualifier Description

HF Field parameter with a holding time of 15 minutes Test performed by laboratory at clients request

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

SW8468260B Volatile Organic Compounds (GCMS) TAL KNX

SW8469056 Anions Ion Chromatography TAL KNX

SW8469041A pH TAL KNX

SW8465050 Bomb Preparation Method for Solid Waste TAL KNX

NoneMeOH Prep Methanol Impinger Preparation TAL KNX

Protocol References

None = None

TAL KNX = Eurofins TestAmerica Knoxville 5815 Middlebrook Pike Knoxville TN 37921 TEL (865)291-3000

12232019Page 6 of 89457

140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 Air 112219 0000 112519 0800

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

Impinger Sample Preparation and Analysis Impinger samples were analyzed for the volatile organic target analytes by purge and trap GCMS using Eurofins TestAmerica Knoxville standard operating procedure KNOX-MS-0015 based on the following method

middot SW-846 8260B ldquoVolatile Organic Compounds by Gas Chromatography Mass Spectrometry (GCMS)rdquo

Each sample is prepared by adding a known amount of sample to the purge water in a purge and trap vessel and spiking with internal standards surrogates and matrix spike analytes (as needed) Volatile compounds are introduced into the gas chromatograph by the purge and trap method The components are separated using the chromatograph and detected using a mass spectrometer which provides both qualitative and quantitative information

Impinger sample results were calculated using the following equation

Concentration μgsample = (C times DF times W times Vt) (Va)WhereC = On-column concentration μgLDF = Dilution factorW = Volume of water purged LVt = Methanol extract final volume μL Va = Volume of extract analyzed microL

Method 8260B The LCS (LCS 140-357061-A) for analytical batch 140-35903 recovered below marginal exceedance limits for Trichlorofluoromethane This is an ongoing instrument issue with LCS recoveries for this analyte The project manager approved moving forward with analysis for the current job

Method 8260B The following samples were analyzed outside of analytical holding time due to ongoing instrumentation problems Y-2972 R2 VEN DIV STACK MM18 IMPINGER 3 (140-17461-9) Y-2973 R2 VEN DIV STACK MM18 IMPINGER 4 (140-17461-10) Y-2974 R2 VEN DIV STACK MM18 IMPINGER 5 (140-17461-11) and Y-2975 R2 VEN DIV STACK MM18 IMPINGER 6 (140-17461-12)

Total Halogens The samples were prepared for total fluorine chlorine bromine andor iodine using SOP number KNOX-WC-0016 (based on ASTM Method E442 and SW-846 Method 5050) The sample is oxidized by combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen under pressure The liberated halogen compounds are absorbed primarily as halides in a sodium carbonatesodium bicarbonate buffer solution The combustion products are collected by repeated rinsing of the combustion apparatus and analyzed by ion chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 9056) The results are calculated using the following equation

C = [(Ccom times Vcom) W] times 1000 gKg

WhereC = Concentration of analyte in the sample mgKgCcom = Concentration of analyte in the combustate mgLVcom = Total volume of combustate LW = Weight of sample combusted g

Anions in Impinger Solutions Anions are is determined in accordance to SOP KNOX-WC-0005 (based on methods 3000A and 9056) The samples were diluted a minimum of 120 in ion chromatography solvent buffer solution to reduce the methanol concentration before injection Buffer concentrate was added until the pH was 10 Samples are diluted with ion chromatography eluate solution to bring the concentrations within the calibration range when necessary Higher dilutions are applied as necessary

An aliquot of prepared sample is introduced into the ion chromatograph Anions are identified based on their retention times as compared to those of known standards Quantification is accomplished by measuring the peak response and comparing it to a calibration curve generated from known standards

12232019Page 8 of 89459

The pH of all samples were tested with pH paper QC consisted of initial CCV and LCS which also serve as initial calibration duplicate analysis for every 10 samples and closing CCV A certified thermometer was used to check the ambient temperature

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

Air MeOH Prep140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 TotalNA

Air MeOH PrepMB 140-357062-A Method Blank TotalNA

Air MeOH PrepLCS 140-357061-A Lab Control Sample TotalNA

Air MeOH Prep140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

Air MeOH Prep140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

Air 8260B 35706140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 TotalNA

Air 8260B 35706MB 140-357062-A Method Blank TotalNA

Air 8260B 35706LCS 140-357061-A Lab Control Sample TotalNA

Air 8260B 35706140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

Air 8260B 35706140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

HPLCIC

Prep Batch 35705

Air MeOH PrepMB 140-3570514-B Method Blank TotalNA

Air MeOH PrepLCS 140-3570515-B Lab Control Sample TotalNA

Air MeOH PrepLCSD 140-3570516-B Lab Control Sample Dup TotalNA

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35706 (Continued)

Air MeOH PrepLCSD 140-3570619-A Lab Control Sample Dup TotalNA

Prep Batch 35707

Prep Batch 35761

Air 5050 35706140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 TotalNA

Air 5050 35707MB 140-3570717-B Method Blank TotalNA

Air 5050 35707LCS 140-3570718-B Lab Control Sample TotalNA

Air 5050 35707LCSD 140-3570719-B Lab Control Sample Dup TotalNA

Prep Batch 35762

Air 5050 35706140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

Air 5050 35706140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER 2 TotalNA

12232019Page 11 of 89462

HPLCIC (Continued)

Air 9056 35706MB 140-3570617-A Method Blank TotalNA

Air 9056 35706LCS 140-3570618-A Lab Control Sample TotalNA

Air 9056 35706LCSD 140-3570619-A Lab Control Sample Dup TotalNA

General Chemistry

Air 9041A140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 TotalNA

12232019Page 12 of 89463

General Chemistry (Continued)

Air 9041ALCS 140-360862 Lab Control Sample TotalNA

Air 9041A140-17461-1 DU Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1 TotalNA

12232019Page 13 of 89464

Lab Sample ID 140-17461-1Client Sample ID Y-2964 R1 VEN DIV STACK MM18 IMPINGER 1

Matrix AirDate Collected 112219 0000Date Received 112519 0800Sample Container Plastic 250ml - unpreserved

Method 8260B - Volatile Organic Compounds (GCMS)RL MDL

1112-Tetrachloroethane ND 426 562 ugSample 112919 1048 120619 2054 1

852 852 ugSample 112919 1048 120619 2054 111133-Pentafluorobutane ND

426 613 ugSample 112919 1048 120619 2054 1111-Trichloroethane ND

852 169 ugSample 112919 1048 120619 2054 1111-Trifluoro-22-dichloroethane ND

852 852 ugSample 112919 1048 120619 2054 1111-Trifluoroethane ND

426 818 ugSample 112919 1048 120619 2054 11122-Tetrachloroethane ND

852 477 ugSample 112919 1048 120619 2054 1112-Trichloro-122-trifluoroethane ND

852 852 ugSample 112919 1048 120619 2054 1112-trichloro-1-fluoroethane ND

852 426 ugSample 112919 1048 120619 2054 111-Dichloro-1-fluoroethane ND

852 852 ugSample 112919 1048 120619 2054 111-dichloro-22-difluoroethane ND

852 852 ugSample 112919 1048 120619 2054 111-dichloro-22-difluoroethene ND

426 511 ugSample 112919 1048 120619 2054 111-Dichloroethane ND

426 630 ugSample 112919 1048 120619 2054 111-Dichloroethene ND

426 460 ugSample 112919 1048 120619 2054 111-Dichloropropene ND

852 852 ugSample 112919 1048 120619 2054 111-Difluoroethene ND

852 852 ugSample 112919 1048 120619 2054 1122-trichloro-11-difluoroethane ND

426 136 ugSample 112919 1048 120619 2054 1123-Trichlorobenzene ND

426 106 ugSample 112919 1048 120619 2054 1123-Trichloropropane ND

426 886 ugSample 112919 1048 120619 2054 1124-Trimethylbenzene ND

852 150 ugSample 112919 1048 120619 2054 112-Dibromo-3-Chloropropane ND

426 562 ugSample 112919 1048 120619 2054 112-Dibromoethane (EDB) ND

426 749 ugSample 112919 1048 120619 2054 112-Dichlorobenzene ND

426 426 ugSample 112919 1048 120619 2054 112-Dichloropropane ND

852 869 ugSample 112919 1048 120619 2054 11-Chloro-11-difluoroethane ND

852 852 ugSample 112919 1048 120619 2054 122-dichloro-11-difluoroethylmethyl

170 273 ugSample 112919 1048 120619 2054 12-Butanone (MEK) ND

852 126 ugSample 112919 1048 120619 2054 12-chloro-111444-hexafluoro-2-but

852 852 ugSample 112919 1048 120619 2054 12-Chloro-111-Trifluoroethane ND

426 801 ugSample 112919 1048 120619 2054 12-Chlorotoluene ND

170 392 ugSample 112919 1048 120619 2054 12-Hexanone ND

372 372 ugSample 112919 1048 120619 2054 12-MTP as HFPO 820

426 114 ugSample 112919 1048 120619 2054 14-Isopropyltoluene ND

170 273 ugSample 112919 1048 120619 2054 14-Methyl-2-pentanone (MIBK) ND

170 101 ugSample 112919 1048 120619 2054 1Acetone ND

426 818 ugSample 112919 1048 120619 2054 1Benzene ND

426 596 ugSample 112919 1048 120619 2054 1Bromobenzene ND

12232019Page 14 of 89465

Method 8260B - Volatile Organic Compounds (GCMS) (Continued)RL MDL

Bromochloromethane ND 426 954 ugSample 112919 1048 120619 2054 1

426 732 ugSample 112919 1048 120619 2054 1Bromodichloromethane ND

426 129 ugSample 112919 1048 120619 2054 1Bromoform ND

852 494 ugSample 112919 1048 120619 2054 1Bromomethane ND

426 106 ugSample 112919 1048 120619 2054 1Carbon disulfide ND

426 562 ugSample 112919 1048 120619 2054 1Carbon tetrachloride ND

125 125 ugSample 112919 1048 120619 2054 1Carbonyl Difluoride ND

426 613 ugSample 112919 1048 120619 2054 1Chlorobenzene ND

426 920 ugSample 112919 1048 120619 2054 1Chlorodibromomethane ND

852 187 ugSample 112919 1048 120619 2054 1Chloroethane ND

426 494 ugSample 112919 1048 120619 2054 1Chloroform ND

852 354 ugSample 112919 1048 120619 2054 1Chloromethane ND

426 341 ugSample 112919 1048 120619 2054 1cis-12-Dichloroethene ND

426 732 ugSample 112919 1048 120619 2054 1cis-13-Dichloropropene ND

426 409 ugSample 112919 1048 120619 2054 1Dibromomethane ND

852 150 ugSample 112919 1048 120619 2054 1Dichlorodifluoromethane ND

426 698 ugSample 112919 1048 120619 2054 1Ethylbenzene ND

426 426 ugSample 112919 1048 120619 2054 1Heptafluoropropyl 1222-tetrafluoroethyl ether

426 112 ugSample 112919 1048 120619 2054 1Hexachlorobutadiene ND

409 409 ugSample 112919 1048 120619 2054 1HFPO dimer methyl ester as

HFPO-DA

426 596 ugSample 112919 1048 120619 2054 1Isopropylbenzene ND

852 698 ugSample 112919 1048 120619 2054 1mp-Xylene ND

426 273 ugSample 112919 1048 120619 2054 1Methylene Chloride 687

426 204 ugSample 112919 1048 120619 2054 1Naphthalene ND

426 109 ugSample 112919 1048 120619 2054 1n-Butylbenzene ND

426 920 ugSample 112919 1048 120619 2054 1n-Propylbenzene ND

426 443 ugSample 112919 1048 120619 2054 1o-Xylene ND

426 835 ugSample 112919 1048 120619 2054 1sec-Butylbenzene ND

426 920 ugSample 112919 1048 120619 2054 1Styrene ND

426 749 ugSample 112919 1048 120619 2054 1tert-Butylbenzene ND

426 562 ugSample 112919 1048 120619 2054 1Tetrachloroethene ND

426 784 ugSample 112919 1048 120619 2054 1Toluene ND

426 443 ugSample 112919 1048 120619 2054 1trans-12-Dichloroethene ND

426 150 ugSample 112919 1048 120619 2054 1trans-13-Dichloropropene ND

426 307 ugSample 112919 1048 120619 2054 1Trichloroethene ND

852 818 ugSample 112919 1048 120619 2054 1Trichlorofluoromethane ND

852 204 ugSample 112919 1048 120619 2054 1Vinyl chloride ND

Butanoic acid heptafluoro- sodium

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst Result CAS NoRT

1120619 2054112919 1048T JUnknown 489 ugSample 118

12-Dichloroethane-d4 (Surr) 117 70 - 160 112919 1048 120619 2054 1

4-Bromofluorobenzene (Surr) 110 112919 1048 120619 2054 157 - 152

12232019Page 15 of 89466

Method 8260B - Volatile Organic Compounds (GCMS) (Continued)

Dibromofluoromethane (Surr) 104 62 - 134 112919 1048 120619 2054 1

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

Method 9056 - Anions Ion ChromatographyRL MDL

Total Fluorine ND 9080 4540 ugSample 112919 1048 121119 2121 1

3750 1700 ugSample 112919 1048 121719 1902 20Hydrogen Fluoride ND

General ChemistryRL MDL

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

135-Trimethylbenzene ND 461 959 ugSample 112919 1048 120619 2119 1

461 103 ugSample 112919 1048 120619 2119 1Bromochloromethane ND

HFPO-DA

12232019Page 17 of 89468

n-Propylbenzene ND 461 995 ugSample 112919 1048 120619 2119 1

Unknown 561 T J ugSample 113 112919 1048 120619 2119 1

Dibromofluoromethane (Surr) 104 112919 1048 120619 2119 162 - 134

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

Total Fluorine 27900 9830 4920 ugSample 112919 1048 121119 2142 1

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

112-Trichloroethane ND 858 0892 ugSample 112919 1048 120619 2143 1

12232019Page 19 of 89470

Chlorodibromomethane ND 858 185 ugSample 112919 1048 120619 2143 1

858 858 ugSample 112919 1048 120619 2143 1Heptafluoropropyl

1222-tetrafluoroethyl ether

HFPO-DA

858 549 ugSample 112919 1048 120619 2143 1Methylene Chloride ND

1120619 2143112919 1048T J NCyclohexane 110-82-7248 ugSample 442

1120619 2143112919 1048T J N1-Dodecene 112-41-4105 ugSample 1207

1120619 2143112919 1048T J NCyclohexane hexyl- 4292-75-5129 ugSample 1269

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

Method 9056 - Anions Ion Chromatography (Continued)RL MDL

Hydrogen Fluoride ND 755 343 ugSample 112919 1048 121719 2029 20

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

22-Dichloropropane ND 264 772 ugSample 112919 1048 120619 2208 1

HFPO-DA

12232019Page 22 of 89473

trans-12-Dichloroethene ND 264 275 ugSample 112919 1048 120619 2208 1

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

11-Dichloropropene ND 241 260 ugSample 112919 1048 120619 2232 1

12232019Page 24 of 89475

Dibromomethane ND 241 231 ugSample 112919 1048 120619 2232 1

HFPO-DA

1120619 2232112919 1048T J NPropane 1112233-heptafluoro-3-

[(trifluoroethenyl)oxy]

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

Total Fluorine 4360 J 5140 2570 ugSample 112919 1048 121119 2330 1

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

111-Trifluoroethane ND 591 591 ugSample 112919 1048 120619 2346 1

12232019Page 31 of 89482

Carbon disulfide ND 296 733 ugSample 112919 1048 120619 2346 1

HFPO-DA

1623-05-8497 ugSample 122

1120619 2346112919 1048T J NCyclotetrasiloxane octamethyl- 556-67-2316 ugSample 878

1120619 2346112919 1048T J NSalicylic acid 2TMS derivative 3789-85-3307 ugSample 1136

12232019Page 32 of 89483

4-Bromofluorobenzene (Surr) 110 57 - 152 112919 1048 120619 2346 1

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

1112-Tetrachloroethane ND H 308 406 ugSample 112919 1048 120719 0010 1

615 615 ugSample 112919 1048 120719 0010 111133-Pentafluorobutane ND H

308 443 ugSample 112919 1048 120719 0010 1111-Trichloroethane ND H

615 122 ugSample 112919 1048 120719 0010 1111-Trifluoro-22-dichloroethane ND H

615 615 ugSample 112919 1048 120719 0010 1111-Trifluoroethane ND H

308 591 ugSample 112919 1048 120719 0010 11122-Tetrachloroethane ND H

615 345 ugSample 112919 1048 120719 0010 1112-Trichloro-122-trifluoroethane ND H

615 615 ugSample 112919 1048 120719 0010 1112-trichloro-1-fluoroethane ND H

615 308 ugSample 112919 1048 120719 0010 111-Dichloro-1-fluoroethane ND H

615 615 ugSample 112919 1048 120719 0010 111-dichloro-22-difluoroethane ND H

615 615 ugSample 112919 1048 120719 0010 111-dichloro-22-difluoroethene ND H

308 369 ugSample 112919 1048 120719 0010 111-Dichloroethane ND H

308 455 ugSample 112919 1048 120719 0010 111-Dichloroethene ND H

308 332 ugSample 112919 1048 120719 0010 111-Dichloropropene ND H

615 615 ugSample 112919 1048 120719 0010 111-Difluoroethene ND H

615 615 ugSample 112919 1048 120719 0010 1122-trichloro-11-difluoroethane ND H

308 985 ugSample 112919 1048 120719 0010 1123-Trichlorobenzene ND H

308 763 ugSample 112919 1048 120719 0010 1123-Trichloropropane ND H

308 640 ugSample 112919 1048 120719 0010 1124-Trimethylbenzene ND H

615 108 ugSample 112919 1048 120719 0010 112-Dibromo-3-Chloropropane ND H

308 406 ugSample 112919 1048 120719 0010 112-Dibromoethane (EDB) ND H

308 542 ugSample 112919 1048 120719 0010 112-Dichlorobenzene ND H

12232019Page 33 of 89484

12-Dichloropropane ND H 308 308 ugSample 112919 1048 120719 0010 1

308 345 ugSample 112919 1048 120719 0010 113-Dichloropropane ND H

615 628 ugSample 112919 1048 120719 0010 11-Chloro-11-difluoroethane ND H

123 197 ugSample 112919 1048 120719 0010 12-Butanone (MEK) ND H

615 615 ugSample 112919 1048 120719 0010 12-Chloro-111-Trifluoroethane ND H

308 578 ugSample 112919 1048 120719 0010 12-Chlorotoluene ND H

123 283 ugSample 112919 1048 120719 0010 12-Hexanone ND H

269 269 ugSample 112919 1048 120719 0010 12-MTP as HFPO 609 H

308 825 ugSample 112919 1048 120719 0010 14-Isopropyltoluene ND H

123 197 ugSample 112919 1048 120719 0010 14-Methyl-2-pentanone (MIBK) ND H

123 726 ugSample 112919 1048 120719 0010 1Acetone ND H

308 591 ugSample 112919 1048 120719 0010 1Benzene ND H

308 431 ugSample 112919 1048 120719 0010 1Bromobenzene ND H

308 689 ugSample 112919 1048 120719 0010 1Bromochloromethane ND H

308 529 ugSample 112919 1048 120719 0010 1Bromodichloromethane ND H

308 935 ugSample 112919 1048 120719 0010 1Bromoform ND H

615 357 ugSample 112919 1048 120719 0010 1Bromomethane ND H

308 763 ugSample 112919 1048 120719 0010 1Carbon disulfide ND H

308 406 ugSample 112919 1048 120719 0010 1Carbon tetrachloride ND H

901 901 ugSample 112919 1048 120719 0010 1Carbonyl Difluoride ND H

308 443 ugSample 112919 1048 120719 0010 1Chlorobenzene ND H

308 665 ugSample 112919 1048 120719 0010 1Chlorodibromomethane ND H

615 135 ugSample 112919 1048 120719 0010 1Chloroethane ND H

308 357 ugSample 112919 1048 120719 0010 1Chloroform ND H

615 256 ugSample 112919 1048 120719 0010 1Chloromethane ND H

308 246 ugSample 112919 1048 120719 0010 1cis-12-Dichloroethene ND H

308 529 ugSample 112919 1048 120719 0010 1cis-13-Dichloropropene ND H

308 295 ugSample 112919 1048 120719 0010 1Dibromomethane ND H

615 108 ugSample 112919 1048 120719 0010 1Dichlorodifluoromethane ND H

308 505 ugSample 112919 1048 120719 0010 1Ethylbenzene ND H

308 812 ugSample 112919 1048 120719 0010 1Hexachlorobutadiene ND H

HFPO-DA

308 431 ugSample 112919 1048 120719 0010 1Isopropylbenzene ND H

615 505 ugSample 112919 1048 120719 0010 1mp-Xylene ND H

308 197 ugSample 112919 1048 120719 0010 1Methylene Chloride ND H

308 148 ugSample 112919 1048 120719 0010 1Naphthalene ND H

12232019Page 34 of 89485

n-Butylbenzene ND H 308 788 ugSample 112919 1048 120719 0010 1

308 665 ugSample 112919 1048 120719 0010 1n-Propylbenzene ND H

308 320 ugSample 112919 1048 120719 0010 1o-Xylene ND H

308 603 ugSample 112919 1048 120719 0010 1sec-Butylbenzene ND H

308 665 ugSample 112919 1048 120719 0010 1Styrene ND H

308 542 ugSample 112919 1048 120719 0010 1tert-Butylbenzene ND H

308 406 ugSample 112919 1048 120719 0010 1Tetrachloroethene ND H

308 566 ugSample 112919 1048 120719 0010 1Toluene ND H

308 320 ugSample 112919 1048 120719 0010 1trans-12-Dichloroethene ND H

308 108 ugSample 112919 1048 120719 0010 1trans-13-Dichloropropene ND H

308 222 ugSample 112919 1048 120719 0010 1Trichloroethene ND H

615 591 ugSample 112919 1048 120719 0010 1Trichlorofluoromethane ND H

615 148 ugSample 112919 1048 120719 0010 1Vinyl chloride ND H

Unknown 490 T H J ugSample 113 112919 1048 120719 0010 1

1120719 0010112919 1048T H J NPropane 1112233-heptafluoro-3-

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

1120719 0010112919 1048T H J NCyclohexane 110-82-7426 ugSample 442

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

111-Trifluoroethane ND H 608 608 ugSample 112919 1048 120719 0035 1

12232019Page 36 of 89487

Carbon disulfide ND H 304 754 ugSample 112919 1048 120719 0035 1

HFPO-DA

304 778 ugSample 112919 1048 120719 0035 1n-Butylbenzene ND H

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1120719 0035112919 1048T H JUnknown 1700 ugSample 118

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

22-dichloro-11-difluoroethylmethyl

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Tetrachloroethene ND H 314 414 ugSample 112919 1048 120719 0059 1

Propene hexafluoro- 421 T H J N ugSample 113 116-15-4 112919 1048 120719 0059 1

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

11-Dichloroethene ND H 307 455 ugSample 112919 1048 120719 0124 1

12232019Page 41 of 89492

cis-13-Dichloropropene ND H 307 529 ugSample 112919 1048 120719 0124 1

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Default Detection LimitsClient Chemours Company FC LLC The Job ID 140-17461-1ProjectSite VEN Stack - MM-18

Method 8260B - Volatile Organic Compounds (GCMS)Prep MeOH Prep

2501112-Tetrachloroethane ugSample

Analyte UnitsMDLRL

50011133-Pentafluorobutane ugSample0500

250111-Trichloroethane ugSample0360

500111-Trifluoro-22-dichloroethane ugSample0990

500111-Trifluoroethane ugSample0500

2501122-Tetrachloroethane ugSample0480

500112-Trichloro-122-trifluoroethane ugSample0280

500112-trichloro-1-fluoroethane ugSample0500

50011-Dichloro-1-fluoroethane ugSample250

50011-dichloro-22-difluoroethane ugSample0500

50011-dichloro-22-difluoroethene ugSample0500

25011-Dichloroethane ugSample0300

25011-Dichloroethene ugSample0370

25011-Dichloropropene ugSample0270

50011-Difluoroethene ugSample500

500122-trichloro-11-difluoroethane ugSample0500

250123-Trichlorobenzene ugSample0800

250123-Trichloropropane ugSample0620

250124-Trimethylbenzene ugSample0520

50012-Dibromo-3-Chloropropane ugSample0880

25012-Dibromoethane (EDB) ugSample0330

25012-Dichlorobenzene ugSample0440

25012-Dichloropropane ugSample0250

5001-Chloro-11-difluoroethane ugSample0510

50022-dichloro-11-difluoroethylmethyl ether ugSample0500

1002-Butanone (MEK) ugSample160

5002-chloro-111444-hexafluoro-2-butene ugSample0740

5002-Chloro-111-Trifluoroethane ugSample0500

2502-Chlorotoluene ugSample0470

1002-Hexanone ugSample230

2502-MTP as HFPO ugSample250

2504-Isopropyltoluene ugSample0670

1004-Methyl-2-pentanone (MIBK) ugSample160

100Acetone ugSample590

250Benzene ugSample0480

250Bromobenzene ugSample0350

250Bromochloromethane ugSample0560

250Bromodichloromethane ugSample0430

250Bromoform ugSample0760

500Bromomethane ugSample290

250Carbon disulfide ugSample0620

250Carbon tetrachloride ugSample0330

12232019Page 43 of 89494

Method 8260B - Volatile Organic Compounds (GCMS) (Continued)Prep MeOH Prep

100Carbonyl Difluoride ugSample

Analyte UnitsMDLRL

250Chlorobenzene ugSample0360

250Chlorodibromomethane ugSample0540

500Chloroethane ugSample110

250Chloroform ugSample0290

500Chloromethane ugSample208

250cis-12-Dichloroethene ugSample0200

250cis-13-Dichloropropene ugSample0430

250Dibromomethane ugSample0240

500Dichlorodifluoromethane ugSample0880

250Ethylbenzene ugSample0410

250Heptafluoropropyl 1222-tetrafluoroethyl ether ugSample250

250Hexachlorobutadiene ugSample0660

250HFPO dimer methyl ester as HFPO-DA ugSample250

250Isopropylbenzene ugSample0350

500mp-Xylene ugSample0410

250Methylene Chloride ugSample160

250Naphthalene ugSample120

250n-Butylbenzene ugSample0640

250n-Propylbenzene ugSample0540

250o-Xylene ugSample0260

250sec-Butylbenzene ugSample0490

250Styrene ugSample0540

250tert-Butylbenzene ugSample0440

250Tetrachloroethene ugSample0330

250Toluene ugSample0460

250trans-12-Dichloroethene ugSample0260

250trans-13-Dichloropropene ugSample0880

250Trichloroethene ugSample0180

500Trichlorofluoromethane ugSample0480

500Vinyl chloride ugSample120

Method 9056 - Anions Ion ChromatographyPrep MeOH Prep

110Hydrogen Fluoride ugSample

Analyte UnitsMDLRL

1000Total Fluorine ugSample500

12232019Page 44 of 89495

_____________________________________________

Approved for releaseCourtney M AdkinsProject Manager II12302019 639 AM

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

4 MS MSD The analyte present in the original sample is greater than 4 times the matrix spike concentration therefore control limits are not

applicableE Result exceeded calibration range

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

Receipt The samples were received on December 7 2019 at 800 AM the samples arrived in good condition properly preserved and where required on ice The temperatures of the 2 coolers at receipt time were 09ordm C and 14ordm C

GCMS VOA Impinger Sample Preparation and Analysis Impinger samples were analyzed for the volatile organic target analytes by purge and trap GCMS using Eurofins TestAmerica Knoxville standard operating procedure KNOX-MS-0015 based on the following method

Method 8260B (LCS 140-359561-A) for analytical batch 140-35964 recovered below marginal exceedance limits for Trichlorofluoromethane This is an ongoing instrument issue with LCS recoveries for this analyte The project manager approved moving forward with analysis for the current job

Method 8260B The following samples were diluted to bring the concentration of target analytes within the calibration range Y-2976 R3 VEN DIV STACK MM18 IMPINGER 1 (140-17557-1) Y-2977 R3 VEN DIV STACK MM18 IMPINGER 2 (140-17557-2) Y-2978 R3 VEN DIV STACK MM18 IMPINGER 3 (140-17557-3) Y-2979 R3 VEN DIV STACK MM18 IMPINGER 4 (140-17557-4) Y-2980 R3 VEN DIV STACK MM18 IMPINGER 5 (140-17557-5) and Y-2981 R3 VEN DIV STACK MM18 IMPINGER 6 (140-17557-6) Elevated reporting limits (RLs) are provided

Method 8260B The continuing calibration verification (CCV) associated with batch 140-35990 recovered above the upper control limit for Chloroethane The samples associated with this CCV were non-detects for the affected analytes therefore the data have been reported

General Chemistry Total Halogens The samples were prepared for total fluorine chlorine bromine andor iodine using SOP number KNOX-WC-0016 (based on ASTM Method E442 and SW-846 Method 5050) The sample is oxidized by combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen under pressure The liberated halogen compounds are absorbed primarily as halides in a sodium carbonatesodium bicarbonate buffer solution The combustion products are collected by repeated rinsing of the combustion apparatus and analyzed by ion chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 9056) The results are calculated using the following equation

Anions in Impinger Solutions Anions are is determined in accordance to SOP KNOX-WC-0005 (based on methods 3000A and 9056) The samples were diluted a minimum of 120 in ion chromatography solvent buffer solution to reduce the methanol concentration before injection Buffer concentrate was added until the pH was 10 Samples are diluted with ion chromatography eluate solution to bring the

12302019Page 8 of 706103

concentrations within the calibration range when necessary Higher dilutions are applied as necessary

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

Air MeOH Prep140-17557-2 - DL Y-2977 R3 VEN DIV STACK MM18 IMPINGER 2 TotalNA

Air 8260B 35956140-17557-2 - DL Y-2977 R3 VEN DIV STACK MM18 IMPINGER 2 TotalNA

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

13-Dichlorobenzene ND 305 524 ugSample 121019 0947 121019 2234 1

266 266 ugSample 121019 0947 121019 2234 12-MTP as HFPO 2430 E

HFPO-DA

305 195 ugSample 121019 0947 121019 2234 1Methylene Chloride 211 J

12302019Page 16 of 706111

o-Xylene ND 305 317 ugSample 121019 0947 121019 2234 1

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Method 8260B - Volatile Organic Compounds (GCMS) - DLRL MDL

2-MTP as HFPO 2230 533 533 ugSample 121019 0947 121119 1629 1

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

124-Trichlorobenzene ND 297 100 ugSample 121019 0947 121019 2145 1

12302019Page 21 of 706116

Hexachlorobutadiene ND 297 785 ugSample 121019 0947 121019 2145 1

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

2-Chloro-111-Trifluoroethane ND 619 619 ugSample 121019 0947 121019 2120 1

HFPO-DA

12302019Page 24 of 706119

Vinyl chloride ND 619 149 ugSample 121019 0947 121019 2120 1

Propene hexafluoro- 445 T J N ugSample 113 116-15-4 121019 0947 121019 2120 1

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

Job Description VEN MM-18 Field QC

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

Raw QC Data 493Method 9056 Blank Data 493Method 9056 LCSLCSD Data 519

Raw QC Data 624Method 9056A Total Halogens Blank Data 624Method 9056A Total Halogens LCSLCSD Data 641

Method 9056A Total Halogens Run Logs 649Method 9056A Total Halogens Prep Data 658

12232019Page 3 of 820127

Table of ContentsLCMS 662

Method DV-LC-0012 ICAL Data 704Method DV-LC-0012 CCAL Data 751

Raw QC Data 763Method DV-LC-0012 Tune Data 763Method DV-LC-0012 Blank Data 768Method DV-LC-0012 LCSLCSD Data 772

Gen Chem QC Data 807Gen Chem ICVCCV 807

Gen Chem MDL 808

12232019Page 4 of 820128

ProjectSite VEN MM-18 Field QC

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

Method 8260B The following analyte(s) recovered outside control limits but within marginal exceedance limits for the LCS associated with batch 140-35880 Trichlorofluoromethane This is not indicative of a systematic control problem because these were random marginal exceedances Qualified results have been reported

LCMS No analytical or quality issues were noted other than those described in the DefinitionsGlossary page

General Chemistry Total Chlorine The samples were prepared for total chlorine using SOP number KNOX-WC-0016 (based on ASTM Method E442 and SW-846 Method 5050) The sample is oxidized by combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen under pressure The liberated halogen compounds are absorbed primarily as halides in a sodium carbonatesodium bicarbonate buffer solution The combustion products are collected by repeated rinsing of the combustion apparatus and analyzed by ion chromatography in accordance with SOP KNOX- WC-0005 (based on SW-846 Method 9056) The results are calculated using the following equation

12232019Page 8 of 820132

Organic Prep No analytical or quality issues were noted other than those described in the DefinitionsGlossary page

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

Air MeOH Prep140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air MeOH Prep140-17462-7 A-5786 QC MEOH RB TotalNA

Air MeOH Prep140-17462-8 A-5787 QC MEOH TB TotalNA

Air MeOH Prep140-17462-9 A-5788 QC MEOH PB TotalNA

Air MeOH Prep140-17462-2 MS A-5781 QC VEN DIV STACK MM18 IMPINGER 2 BTTotalNA

Air MeOH Prep140-17462-2 MSD A-5781 QC VEN DIV STACK MM18 IMPINGER 2 BTTotalNA

Air 8260B 35705140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air 8260B 35705140-17462-7 A-5786 QC MEOH RB TotalNA

Air 8260B 35705140-17462-8 A-5787 QC MEOH TB TotalNA

Air 8260B 35705140-17462-9 A-5788 QC MEOH PB TotalNA

Air 8260B 35705140-17462-2 MS A-5781 QC VEN DIV STACK MM18 IMPINGER 2 BTTotalNA

Air 8260B 35705140-17462-2 MSD A-5781 QC VEN DIV STACK MM18 IMPINGER 2 BTTotalNA

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

Air 5050 35705140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air 5050 35705140-17462-7 A-5786 QC MEOH RB TotalNA

Air 5050 35705140-17462-8 A-5787 QC MEOH TB TotalNA

Air 5050 35705140-17462-9 A-5788 QC MEOH PB TotalNA

12232019Page 11 of 820135

Prep Batch 479505

Air None140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air None140-17462-7 A-5786 QC MEOH RB TotalNA

Air None140-17462-8 A-5787 QC MEOH TB TotalNA

Air None140-17462-9 A-5788 QC MEOH PB TotalNA

Air 8321A 479505140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air 8321A 479505140-17462-7 A-5786 QC MEOH RB TotalNA

Air 8321A 479505140-17462-8 A-5787 QC MEOH TB TotalNA

Air 8321A 479505140-17462-9 A-5788 QC MEOH PB TotalNA

General Chemistry

Air 9041A140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BTTotalNA

Air 9041A140-17462-7 A-5786 QC MEOH RB TotalNA

Air 9041A140-17462-8 A-5787 QC MEOH TB TotalNA

Air 9041A140-17462-9 A-5788 QC MEOH PB TotalNA

12232019Page 12 of 820136

Lab Sample ID 140-17462-1Client Sample ID A-5780 QC VEN DIV STACK MM18 IMPINGER 1 BT

251 251 ugSample 112919 1045 120619 1517 12-MTP as HFPO ND

12232019Page 13 of 820137

HFPO-DA

Tentatively Identified Compound None ugSample 112919 1045 120619 1517 1

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

n-Butylbenzene ND 299 765 ugSample 112919 1045 120619 1542 1

Cyclohexane 433 T J N ugSample 442 110-82-7 112919 1045 120619 1542 1

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

Bromoform ND 291 885 ugSample 112919 1045 120619 1606 1

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

Lab Sample ID 140-17462-7Client Sample ID A-5786 QC MEOH RBMatrix AirDate Collected 112219 0000

Date Received 112519 0800Sample Container Plastic 250ml - unpreserved

12232019Page 27 of 820151

111-Trifluoro-22-dichloroethane ND 406 804 ugSample 112919 1045 120619 1404 1

12232019Page 28 of 820152

HFPO-DA

203 130 ugSample 112919 1045 120619 1404 1Methylene Chloride 131 J B

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

Lab Sample ID 140-17462-8Client Sample ID A-5787 QC MEOH TBMatrix AirDate Collected 112219 0000

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

trans-13-Dichloropropene ND 154 542 ugSample 112919 1045 120619 1428 1

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

Lab Sample ID 140-17462-9Client Sample ID A-5788 QC MEOH PBMatrix AirDate Collected 112219 0000

12232019Page 32 of 820156

11-Dichloroethene ND 181 267 ugSample 112919 1045 120619 1453 1

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Default Detection LimitsClient Chemours Company FC LLC The Job ID 140-17462-1ProjectSite VEN MM-18 Field QC

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

EXAMPLE CALCULATIONS FORVOLUMETRIC FLOW AND MOISTURE AND ISOKINETICS

Client Chemours Facility Fayetteville NCTest Number Run 1 Test Date 112219Test Location Division Stack Test Period 0826-1022

1 Volume of dry gas sampled at standard conditions (68 deg F 2992 in Hg) dscf

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf

Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf

Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O

Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor

1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg

136 = Specific gravity of mercury

2 Volume of water vapor in the gas sample corrected to standard conditions scf

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf

Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g

004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) ft3ml

004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant2185 (in Hg) (ft3)lb-mole)(deg R) absolutetemperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and4536 glb ft3g

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

bws = Proportion of water vapor by volume in the gasstream dimensionless

4 Mole fraction of dry gas

Md = 1 - bws

Md = 1 - 0024 = 0976

Md = Mole fraction of dry gas dimensionless

5 Dry molecular weight of gas stream lblb-mole

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis

O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis

CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide

divided by 100

6 Actual molecular weight of gas stream (wet basis) lblb-mole

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole

123120191101 AM 112219 Div Stack M0010

7 Average velocity of gas stream at actual conditions ftsec

Ts (avg)Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Vs = Average gas stream velocity ftsec (lblb-mole)(in Hg)12

8549 = Pitot tube constant ftsec x ------------------------------------ (deg R)(in H2O)

Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460

P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------

136delt p = Velocity head of stack in H2O

8 Average gas stream volumetric flow rate at actual conditions wacfmin

Qs(act) = 60 x Vs x As

Qs(act) = 60 x 820 x 707 = 34799

Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin

As = Cross-sectional area of stack ft260 = Conversion factor from seconds to minutes

9 Average gas stream dry volumetric flow rate at standard conditions dscfmin

PsQs(std) = 1764 x Md x ----- x Qs(act)

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin

123120191101 AM 112219 Div Stack M0010

10 Isokinetic variation calculated from intermediate values percent

17327 x Ts x Vm(std)I = -----------------------------------

Vs x O x Ps x Md x (Dn)2

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

I = Percent of isokinetic samplingO = Total sampling time minutes

Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)

standard pressure (2992 in Hg) the formula forcalculating area of circle D24 conversion of squarefeet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)(in Hg)(in2)(min) (deg R)(ft2)(sec)

1320201218 PM 112219 Div Stack M0010

SAMPLE CALCULATIONS FORHFPO DIMER ACID (METHOD 0010)

Client Chemours Plant Fayetteville NCTest Number Run 1 Test Date 112219Test Location Divison Stack Test Period 0826-1022

1 HFPO Dimer Acid concentration lbsdscf

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

W = Weight of HFPO Dimer Acid collected in sample in ug

Conc1 = Division Stack HFPO Dimer Acid concentration lbsdscf

22046x10-9 = Conversion factor from ug to lbs

2 HFPO Dimer Acid concentration ugdscm

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

Conc2 = Division Stack HFPO Dimer Acid concentration ugdscm

002832 = Conversion factor from cubic feet to cubic meters

1320201218 PM 112219 Div Stack M0010

3 HFPO Dimer Acid mass emission rate lbshr

MR1(Outlet) = Conc1 x Qs(std) x 60 minhr

MR1(Outlet) = 760E-10 x 33787 x 60

MR1(Outlet) = 154E-03

MR1(Outlet) = Division Stack HFPO Dimer Acid mass emission rate lbshr

4 HFPO Dimer Acid mass emission rate gsec

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

MR2(Outlet) = Division Stack HFPO Dimer Acid mass emission rate gsec

4536 = Conversion factor from pounds to grams

3600 = Conversion factor from hours to seconds

P-694 all in oneMOD

Pitot Tube Identification Number

Inspection Date 21919 Individual Conducting Inspection

Distance to A Plane (PA) - inches 046 PASSDistance to B Plane (PB) - inches 046 PASS

Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB

Q1 and Q2 must be lt 10o

B1 or B2 must be lt 5o

Z must be lt 0125 inches

W must be lt 003125 inches

X must be gt 075 inches

Thermocouple meets the Distance Criteria in the adjacent figure

Impact Pressure Opening Plane is above the Nozzle Entry Plane

Distance between Sample Nozzle and Pitot (X) - inches

NO YES

Angle of B1 from vertical A Tube- degrees (absolute) 0

Horizontal offset between A and B Tubes (Z) - inches

Vertical offset between A and B Tubes (W) - inches

PASSFAIL

Angle of B1 from vertical B Tube- degrees (absolute)

Angle of Q1 from vertical A Tube- degrees (absolute)

Angle of Q2 from vertical B Tube- degrees (absolute)

Type S Pitot Tube Inspection Data Form

Are Open Faces Aligned Perpendicular to the Tube Axis

YES NOPASS

If all Criteria PASS Cp is equal to 084

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Impact Pressure Opening Plane

Nozzle Entry Plane

Long Cal Box_30 2-21-19

Calibrator MDW Meter Box Number 30 Ambient Temp 72

Date 21-Feb-19 Wet Test Meter Number P-2952 Temp Reference Source

Dry Gas Meter Number 17485131

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

1832 1832 1832 1832 1832 18320 001 - Channel Temps must agree with +- 5oF or 3oC

2 - Acceptable Temperature Difference less than 15

20 100

18501128 10002

Dry Gas Meter

05 700

Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

Y - Ratio of accuracy of wet test meter to dry gas meter

∆H - Pressure differential across orifice

30 100 700

TemperaturesWet Test

15 100

107 09910

18851130 09946

150 09995

9321832

Reference Temperature

Select Temperature

Average Temperature

Reading

Thermocouple Simulator

(Accuracy +- 1oF)

Difference 2

Temperature Reading from Individual Thermocouple Input 1

Channel Number

Calibration Results

Baro Press in Hg ( Pb)

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

460FTempTest460FTempferenceReDiffTemp

Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN

DIVISION STACKMETER BOX NO 30

11222019Run 1 Run 2

MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100

CO2 = Percent carbon dioxide by volume dry basis 00 00 O2 = Percent oxygen by volume dry basis 209 209

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 570 652

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury

delta H = Avg pressure drop across the orifice meter during sampling in H2O 140 100Pb = Barometric Pressure in Hg 3002 3002

Pm = Pb + (delta H 136)

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2

2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 63136 47088

Y = Dry gas meter calibration factor (based on full calibration) 09972 09972Delta H = Dry Gas meter orifice calibration coefficient in H2O 18715 18715

avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 11783 09984O = Total sampling time minutes 96 84

Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = Absolute difference between Yqa and Y 254 231

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Long Cal Vost Box 5 11-29-18

Calibrator PM VOST Box Number VOST 5 Ambient Temp 72

Date 29-Nov-18 Wet Test Meter Number 10BB-1 Temp Reference Source

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meter

Tdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

1 - Channel Temps must agree with +- 5oF or 3oC

Wet Test Meter

Dry gas MeterWet Test

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

Long Cal and Temperature Cal Datasheet for VOST Dry Gas Meter Console

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Long Cal Vost Box 8 9_21_2019

Calibrator MDW VOST Box Number VOST 8 Ambient Temp 73

Date 21-Sep-19 Wet Test Meter Number 10BB-1 Temp Reference Source

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Temperature Reading from Individual Thermocouple Input 1 Temp

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

The following WESTON employees participated in this project

Paul Meeter Senior Project Manager

Jeff OrsquoNeill Senior Project Manager

Wes Fritz Senior Project Manager

Matt Winkeler Team Member

Kyle Schweitzer Team Member

Brandon Berger Team Member

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results

THE CHEMOURS COMPANY

FLOROMONOMERS MANUFACTURING PROCESS DIVISION STACK EMISSIONS TEST REPORT

TEST DATES 22 November and 4 December 2019

Weston Solutions Inc (WESTONreg) is a commercial laboratory operating within full accreditation of the Louisiana Environmental Laboratory Accreditation Program under Certificate Number 03024 The qualifications to provide defensible quality data as a certified commercial environmental testing firm as Agency Interest No 30815 was granted by the Louisiana Department of Environmental Quality under the Louisiana Administrative Code of LAC 331 Chapter 45 et al

I certify that I have personally examined and am familiar with the information contained herein Based on my information and belief formed after reasonable inquiry the statements and information in the document are true accurate and complete

Paul M Meeter Weston Solutions Inc

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

31 FLUOROMONOMERS 6

41 DIVISION STACK 7

53 MM18 15

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

Runs 1 and 2 20

Runs 1 2 and 3 22

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

three compounds

Target Compound

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

31 FLUOROMONOMERS

the Division stack

41 DIVISION STACK

disturbance

center of the stack

program

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

and HFPO Dimer Acid

impingers

HPLCMSMS

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

GLASS IMPINGERS

STACK WALL

8 3 18

54 GAS COMPOSITION

calculations

Division

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

RUN 3 0955-1125

800 900 1000 1100

2 ( gt-0 h A il1

l y gtf-uir 7 vr

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

l 2 T I 146

r 2 854 ) L

4 bull 0

8 p 0 o n 9

n II 12

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

11 _ ---

ltl Igt-

ry middoti 5D -

05 1 0 1 5 20 25 50

I I I I I I I

40 - A

plusmn --- -middot

B(tmJiir)lilj

T I 250 167 125 100 8J 71 6J 56 50 45 41

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

DIVISION STACK

122020 1102 AM 112219 Div Stack M001028

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

~~~ nments

J ~lr ~ ~~~~13~

(~ Q~ ~~~ 29

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

t-~`~~5 ~~~~~~~

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

DIVISION STACK

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

CHEM-F Date

Sample Time

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~v S~~-~Ll~

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Sample Time ~~ M~

Page ~ of

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Contents Silica Gel

Initial

k3aT~AF c

_____________________________________________

12102019

12102019Page 1 of 21339

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Chronicle 18

LCMS 25

12102019Page 2 of 21340

12102019Page 3 of 21341

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12102019Page 4 of 21342

Protocol References

12102019Page 5 of 21343

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Sample Receipt

Organic Prep

12102019Page 7 of 21345

December 10 2019

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

(ugsample)

986 2 786

213 7 143

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

Prep Batch 478940

Prep Batch 478993

Prep Batch 479245

12102019Page 9 of 21347

LCMS (Continued)

12102019Page 10 of 21348

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12102019Page 13 of 21351

_____________________________________________

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

12232019Page 2 of 89453

HPLCIC 498

12232019Page 3 of 89454

Gen Chem MDL 880

12232019Page 4 of 89455

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

Protocol References

None = None

12232019Page 6 of 89457

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

12232019Page 8 of 89459

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

HPLCIC

Prep Batch 35705

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35707

Prep Batch 35761

Prep Batch 35762

12232019Page 11 of 89462

HPLCIC (Continued)

General Chemistry

12232019Page 12 of 89463

12232019Page 13 of 89464

12232019Page 14 of 89465

HFPO-DA

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

12232019Page 15 of 89466

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

HFPO-DA

12232019Page 17 of 89468

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

12232019Page 19 of 89470

HFPO-DA

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

HFPO-DA

12232019Page 22 of 89473

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

12232019Page 24 of 89475

HFPO-DA

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

12232019Page 31 of 89482

HFPO-DA

1623-05-8497 ugSample 122

12232019Page 32 of 89483

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 33 of 89484

HFPO-DA

12232019Page 34 of 89485

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

12232019Page 36 of 89487

HFPO-DA

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

12232019Page 41 of 89492

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Analyte UnitsMDLRL

12232019Page 43 of 89494

Analyte UnitsMDLRL

12232019Page 44 of 89495

_____________________________________________

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

12302019Page 8 of 706103

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

HFPO-DA

12302019Page 16 of 706111

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

12302019Page 21 of 706116

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

HFPO-DA

12302019Page 24 of 706119

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

12232019Page 3 of 820127

Gen Chem MDL 808

12232019Page 4 of 820128

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

12232019Page 8 of 820132

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

12232019Page 11 of 820135

Prep Batch 479505

General Chemistry

12232019Page 12 of 820136

12232019Page 13 of 820137

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

12232019Page 27 of 820151

12232019Page 28 of 820152

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

12232019Page 32 of 820156

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

Md = 1 - bws

Md = 1 - 0024 = 0976

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

123120191101 AM 112219 Div Stack M0010

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Qs(act) = 60 x 820 x 707 = 34799

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

123120191101 AM 112219 Div Stack M0010

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

1320201218 PM 112219 Div Stack M0010

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

1320201218 PM 112219 Div Stack M0010

MR1(Outlet) = 760E-10 x 33787 x 60

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

P-694 all in oneMOD

NO YES

PASSFAIL

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Nozzle Entry Plane

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

05 700

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

15 100

107 09910

18851130 09946

150 09995

9321832

Select Temperature

Average Temperature

Reading

(Accuracy +- 1oF)

Difference 2

Channel Number

Calibration Results

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

11222019Run 1 Run 2

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

Wet Test Meter

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

31 FLUOROMONOMERS 6

41 DIVISION STACK 7

53 MM18 15

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

Runs 1 and 2 20

Runs 1 2 and 3 22

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

three compounds

Target Compound

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

31 FLUOROMONOMERS

the Division stack

41 DIVISION STACK

disturbance

center of the stack

program

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

and HFPO Dimer Acid

impingers

HPLCMSMS

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

GLASS IMPINGERS

STACK WALL

8 3 18

54 GAS COMPOSITION

calculations

Division

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

RUN 3 0955-1125

800 900 1000 1100

2 ( gt-0 h A il1

l y gtf-uir 7 vr

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

l 2 T I 146

r 2 854 ) L

4 bull 0

8 p 0 o n 9

n II 12

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

11 _ ---

ltl Igt-

ry middoti 5D -

05 1 0 1 5 20 25 50

I I I I I I I

40 - A

plusmn --- -middot

B(tmJiir)lilj

T I 250 167 125 100 8J 71 6J 56 50 45 41

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

DIVISION STACK

122020 1102 AM 112219 Div Stack M001028

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

~~~ nments

J ~lr ~ ~~~~13~

(~ Q~ ~~~ 29

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

t-~`~~5 ~~~~~~~

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

DIVISION STACK

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

CHEM-F Date

Sample Time

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~v S~~-~Ll~

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Sample Time ~~ M~

Page ~ of

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Contents Silica Gel

Initial

k3aT~AF c

_____________________________________________

12102019

12102019Page 1 of 21339

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Chronicle 18

LCMS 25

12102019Page 2 of 21340

12102019Page 3 of 21341

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12102019Page 4 of 21342

Protocol References

12102019Page 5 of 21343

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Sample Receipt

Organic Prep

12102019Page 7 of 21345

December 10 2019

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

(ugsample)

986 2 786

213 7 143

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

Prep Batch 478940

Prep Batch 478993

Prep Batch 479245

12102019Page 9 of 21347

LCMS (Continued)

12102019Page 10 of 21348

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12102019Page 13 of 21351

_____________________________________________

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

12232019Page 2 of 89453

HPLCIC 498

12232019Page 3 of 89454

Gen Chem MDL 880

12232019Page 4 of 89455

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

Protocol References

None = None

12232019Page 6 of 89457

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

12232019Page 8 of 89459

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

HPLCIC

Prep Batch 35705

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35707

Prep Batch 35761

Prep Batch 35762

12232019Page 11 of 89462

HPLCIC (Continued)

General Chemistry

12232019Page 12 of 89463

12232019Page 13 of 89464

12232019Page 14 of 89465

HFPO-DA

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

12232019Page 15 of 89466

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

HFPO-DA

12232019Page 17 of 89468

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

12232019Page 19 of 89470

HFPO-DA

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

HFPO-DA

12232019Page 22 of 89473

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

12232019Page 24 of 89475

HFPO-DA

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

12232019Page 31 of 89482

HFPO-DA

1623-05-8497 ugSample 122

12232019Page 32 of 89483

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 33 of 89484

HFPO-DA

12232019Page 34 of 89485

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

12232019Page 36 of 89487

HFPO-DA

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

12232019Page 41 of 89492

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Analyte UnitsMDLRL

12232019Page 43 of 89494

Analyte UnitsMDLRL

12232019Page 44 of 89495

_____________________________________________

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

12302019Page 8 of 706103

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

HFPO-DA

12302019Page 16 of 706111

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

12302019Page 21 of 706116

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

HFPO-DA

12302019Page 24 of 706119

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

12232019Page 3 of 820127

Gen Chem MDL 808

12232019Page 4 of 820128

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

12232019Page 8 of 820132

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

12232019Page 11 of 820135

Prep Batch 479505

General Chemistry

12232019Page 12 of 820136

12232019Page 13 of 820137

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

12232019Page 27 of 820151

12232019Page 28 of 820152

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

12232019Page 32 of 820156

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

Md = 1 - bws

Md = 1 - 0024 = 0976

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

123120191101 AM 112219 Div Stack M0010

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Qs(act) = 60 x 820 x 707 = 34799

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

123120191101 AM 112219 Div Stack M0010

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

1320201218 PM 112219 Div Stack M0010

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

1320201218 PM 112219 Div Stack M0010

MR1(Outlet) = 760E-10 x 33787 x 60

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

P-694 all in oneMOD

NO YES

PASSFAIL

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Nozzle Entry Plane

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

05 700

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

15 100

107 09910

18851130 09946

150 09995

9321832

Select Temperature

Average Temperature

Reading

(Accuracy +- 1oF)

Difference 2

Channel Number

Calibration Results

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

11222019Run 1 Run 2

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

Wet Test Meter

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

Runs 1 and 2 20

Runs 1 2 and 3 22

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

three compounds

Target Compound

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

31 FLUOROMONOMERS

the Division stack

41 DIVISION STACK

disturbance

center of the stack

program

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

and HFPO Dimer Acid

impingers

HPLCMSMS

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

GLASS IMPINGERS

STACK WALL

8 3 18

54 GAS COMPOSITION

calculations

Division

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

RUN 3 0955-1125

800 900 1000 1100

2 ( gt-0 h A il1

l y gtf-uir 7 vr

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

l 2 T I 146

r 2 854 ) L

4 bull 0

8 p 0 o n 9

n II 12

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

11 _ ---

ltl Igt-

ry middoti 5D -

05 1 0 1 5 20 25 50

I I I I I I I

40 - A

plusmn --- -middot

B(tmJiir)lilj

T I 250 167 125 100 8J 71 6J 56 50 45 41

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

DIVISION STACK

122020 1102 AM 112219 Div Stack M001028

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

~~~ nments

J ~lr ~ ~~~~13~

(~ Q~ ~~~ 29

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

t-~`~~5 ~~~~~~~

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

DIVISION STACK

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

CHEM-F Date

Sample Time

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~v S~~-~Ll~

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Sample Time ~~ M~

Page ~ of

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Contents Silica Gel

Initial

k3aT~AF c

_____________________________________________

12102019

12102019Page 1 of 21339

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Chronicle 18

LCMS 25

12102019Page 2 of 21340

12102019Page 3 of 21341

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12102019Page 4 of 21342

Protocol References

12102019Page 5 of 21343

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Sample Receipt

Organic Prep

12102019Page 7 of 21345

December 10 2019

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

(ugsample)

986 2 786

213 7 143

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

Prep Batch 478940

Prep Batch 478993

Prep Batch 479245

12102019Page 9 of 21347

LCMS (Continued)

12102019Page 10 of 21348

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12102019Page 13 of 21351

_____________________________________________

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

12232019Page 2 of 89453

HPLCIC 498

12232019Page 3 of 89454

Gen Chem MDL 880

12232019Page 4 of 89455

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

Protocol References

None = None

12232019Page 6 of 89457

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

12232019Page 8 of 89459

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

HPLCIC

Prep Batch 35705

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35707

Prep Batch 35761

Prep Batch 35762

12232019Page 11 of 89462

HPLCIC (Continued)

General Chemistry

12232019Page 12 of 89463

12232019Page 13 of 89464

12232019Page 14 of 89465

HFPO-DA

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

12232019Page 15 of 89466

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

HFPO-DA

12232019Page 17 of 89468

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

12232019Page 19 of 89470

HFPO-DA

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

HFPO-DA

12232019Page 22 of 89473

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

12232019Page 24 of 89475

HFPO-DA

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

12232019Page 31 of 89482

HFPO-DA

1623-05-8497 ugSample 122

12232019Page 32 of 89483

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 33 of 89484

HFPO-DA

12232019Page 34 of 89485

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

12232019Page 36 of 89487

HFPO-DA

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

12232019Page 41 of 89492

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Analyte UnitsMDLRL

12232019Page 43 of 89494

Analyte UnitsMDLRL

12232019Page 44 of 89495

_____________________________________________

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

12302019Page 8 of 706103

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

HFPO-DA

12302019Page 16 of 706111

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

12302019Page 21 of 706116

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

HFPO-DA

12302019Page 24 of 706119

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

12232019Page 3 of 820127

Gen Chem MDL 808

12232019Page 4 of 820128

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

12232019Page 8 of 820132

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

12232019Page 11 of 820135

Prep Batch 479505

General Chemistry

12232019Page 12 of 820136

12232019Page 13 of 820137

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

12232019Page 27 of 820151

12232019Page 28 of 820152

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

12232019Page 32 of 820156

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

Md = 1 - bws

Md = 1 - 0024 = 0976

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

123120191101 AM 112219 Div Stack M0010

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Qs(act) = 60 x 820 x 707 = 34799

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

123120191101 AM 112219 Div Stack M0010

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

1320201218 PM 112219 Div Stack M0010

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

1320201218 PM 112219 Div Stack M0010

MR1(Outlet) = 760E-10 x 33787 x 60

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

P-694 all in oneMOD

NO YES

PASSFAIL

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Nozzle Entry Plane

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

05 700

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

15 100

107 09910

18851130 09946

150 09995

9321832

Select Temperature

Average Temperature

Reading

(Accuracy +- 1oF)

Difference 2

Channel Number

Calibration Results

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

11222019Run 1 Run 2

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

Wet Test Meter

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results

LIST OF TABLES

Title Page

Runs 1 and 2 20

Runs 1 2 and 3 22

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

three compounds

Target Compound

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

31 FLUOROMONOMERS

the Division stack

41 DIVISION STACK

disturbance

center of the stack

program

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

and HFPO Dimer Acid

impingers

HPLCMSMS

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

GLASS IMPINGERS

STACK WALL

8 3 18

54 GAS COMPOSITION

calculations

Division

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

RUN 3 0955-1125

800 900 1000 1100

2 ( gt-0 h A il1

l y gtf-uir 7 vr

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

l 2 T I 146

r 2 854 ) L

4 bull 0

8 p 0 o n 9

n II 12

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

11 _ ---

ltl Igt-

ry middoti 5D -

05 1 0 1 5 20 25 50

I I I I I I I

40 - A

plusmn --- -middot

B(tmJiir)lilj

T I 250 167 125 100 8J 71 6J 56 50 45 41

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

DIVISION STACK

122020 1102 AM 112219 Div Stack M001028

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

~~~ nments

J ~lr ~ ~~~~13~

(~ Q~ ~~~ 29

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

t-~`~~5 ~~~~~~~

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

DIVISION STACK

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

CHEM-F Date

Sample Time

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~v S~~-~Ll~

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Sample Time ~~ M~

Page ~ of

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Contents Silica Gel

Initial

k3aT~AF c

_____________________________________________

12102019

12102019Page 1 of 21339

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Chronicle 18

LCMS 25

12102019Page 2 of 21340

12102019Page 3 of 21341

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12102019Page 4 of 21342

Protocol References

12102019Page 5 of 21343

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Sample Receipt

Organic Prep

12102019Page 7 of 21345

December 10 2019

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

(ugsample)

986 2 786

213 7 143

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

Prep Batch 478940

Prep Batch 478993

Prep Batch 479245

12102019Page 9 of 21347

LCMS (Continued)

12102019Page 10 of 21348

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12102019Page 13 of 21351

_____________________________________________

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

12232019Page 2 of 89453

HPLCIC 498

12232019Page 3 of 89454

Gen Chem MDL 880

12232019Page 4 of 89455

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

Protocol References

None = None

12232019Page 6 of 89457

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

12232019Page 8 of 89459

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

HPLCIC

Prep Batch 35705

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35707

Prep Batch 35761

Prep Batch 35762

12232019Page 11 of 89462

HPLCIC (Continued)

General Chemistry

12232019Page 12 of 89463

12232019Page 13 of 89464

12232019Page 14 of 89465

HFPO-DA

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

12232019Page 15 of 89466

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

HFPO-DA

12232019Page 17 of 89468

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

12232019Page 19 of 89470

HFPO-DA

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

HFPO-DA

12232019Page 22 of 89473

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

12232019Page 24 of 89475

HFPO-DA

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

12232019Page 31 of 89482

HFPO-DA

1623-05-8497 ugSample 122

12232019Page 32 of 89483

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 33 of 89484

HFPO-DA

12232019Page 34 of 89485

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

12232019Page 36 of 89487

HFPO-DA

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

12232019Page 41 of 89492

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Analyte UnitsMDLRL

12232019Page 43 of 89494

Analyte UnitsMDLRL

12232019Page 44 of 89495

_____________________________________________

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

12302019Page 8 of 706103

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

HFPO-DA

12302019Page 16 of 706111

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

12302019Page 21 of 706116

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

HFPO-DA

12302019Page 24 of 706119

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

12232019Page 3 of 820127

Gen Chem MDL 808

12232019Page 4 of 820128

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

12232019Page 8 of 820132

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

12232019Page 11 of 820135

Prep Batch 479505

General Chemistry

12232019Page 12 of 820136

12232019Page 13 of 820137

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

12232019Page 27 of 820151

12232019Page 28 of 820152

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

12232019Page 32 of 820156

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

Md = 1 - bws

Md = 1 - 0024 = 0976

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

123120191101 AM 112219 Div Stack M0010

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Qs(act) = 60 x 820 x 707 = 34799

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

123120191101 AM 112219 Div Stack M0010

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

1320201218 PM 112219 Div Stack M0010

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

1320201218 PM 112219 Div Stack M0010

MR1(Outlet) = 760E-10 x 33787 x 60

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

P-694 all in oneMOD

NO YES

PASSFAIL

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Nozzle Entry Plane

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

05 700

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

15 100

107 09910

18851130 09946

150 09995

9321832

Select Temperature

Average Temperature

Reading

(Accuracy +- 1oF)

Difference 2

Channel Number

Calibration Results

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

11222019Run 1 Run 2

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

Wet Test Meter

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

three compounds

Target Compound

HFPO Monomer

374E-01 297E+00 315E-01 250E+00 192E+00 153E+01

Fluoroether E-1

291E-02 231E-01 667E-02 530E-01 241E-02 192E-01

Carbonyl Difluoride

Total Fluorine

727E+00 578E+01 594E+00 472E+01 140E+01 111E+02

Hydrogen Fluoride

31 FLUOROMONOMERS

the Division stack

41 DIVISION STACK

disturbance

center of the stack

program

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

and HFPO Dimer Acid

impingers

HPLCMSMS

TEMPERATURESENSORS

BY-PASS VALVE

DRY GASMETER

CUBIC LITERS

ORIFICE

VACUUMGAUGE

AIR-TIGHT

GLASS IMPINGERS

STACK WALL

8 3 18

54 GAS COMPOSITION

calculations

Division

800 900 1000 1100 1300 1400 1500 1600RUN 1 0826-1022 RUN 2 - 1139-1320

Burnout

RUN 3 0955-1125

800 900 1000 1100

2 ( gt-0 h A il1

l y gtf-uir 7 vr

Igt 4 7 V

9S i 31 9 l- t

Cf5lv 35)7 $ f

4Mre (

l 2 T I 146

r 2 854 ) L

4 bull 0

8 p 0 o n 9

n II 12

146 tQ5

296 194

704 123

854 677

956 8D6

82 146

1154 918

middotltt

67 118 111

11 _ ---

ltl Igt-

ry middoti 5D -

05 1 0 1 5 20 25 50

I I I I I I I

40 - A

plusmn --- -middot

B(tmJiir)lilj

T I 250 167 125 100 8J 71 6J 56 50 45 41

i tu w 750 42 ill p 0

o n i 944 850 m 708 I 10 i5JI 1164 191

II 955 875 12 JJI

DIVISION STACK

122020 1102 AM 112219 Div Stack M001028

~~r~~~-

~~mdash~~ ~ ~ ~ ~ ~ i ~~~~mdash

~~-~~~Itibull1~~~ bull ~~~~~~~_~~

~~-~ I ~~~~~~~~~- ~~~

~~~ nments

J ~lr ~ ~~~~13~

(~ Q~ ~~~ 29

mdash~~~~ ~ bull

~~~~--- ~~~

~~mdash~~ ~ r ~ ~~~~~-

1~__2~ 000~5~

t-~`~~5 ~~~~~~~

_ t~~ ~~_~- 30

12120201028 AM 112219 Div Stack MM18

DIVISION STACK

bull ~

~~- ~~ ~~

~ ~~ ~ --~

------ --

Project ID

ModeSource ID

Samp Loc

Source

Comments

Chemours Run No

CHEM-F Date

Sample Time

~~ ~laquo

Page ~ of

pJCH ~~~

yes no yes no

~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~c~1 ~~~P~~~~i~ ~ ~m~ ~~~c~~~~~l~~~~ ~

m ~ ~_-1

~~v S~~-~Ll~

Contents Silica Gel

Final ~~ ~~j~zj ~ ~~7i ~ ~

~ `~ 1

Initial ~ G~ ~~ ~ ~ ~~ ~ ~ ~ utJ~ ~d

Contents Silica Gel

Final ~~r ~ 1o~i(~ ~0~ ~ ~Os

Initial ~ rs b~~~~ ~~~ ~~ Q ~~ f

Gain ~s d d

Contents Silica Gel

Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~~ b~

initial ~ ~ = ~ v b ~~gt ~ ~ ~~ - ~j

Sample Time ~~ M~

Page ~ of

a~ ~a~~~ o~r~~~~

~~~ ~~~~a~ ~~~ ~

~~~~ I ~~ ~~ ~ ~ ~~~~~~~~~ ~~~~em~~

--- -- ~~-

Final 4 ~ ~ G~ U ~O ~ ~ C1 ~~ 3 ~ _

Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v r C7 r

Initial ~~~ ~~0 607` ~C~ ~~ ~~ ~ f3 ~3

Contents Silica Gel

Initial

k3aT~AF c

_____________________________________________

12102019

12102019Page 1 of 21339

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 9

Chronicle 18

LCMS 25

12102019Page 2 of 21340

12102019Page 3 of 21341

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12102019Page 4 of 21342

Protocol References

12102019Page 5 of 21343

140-17458-2 G-257925802582 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-4 G-2583 DIV VEN STACK R1 M0010

Air 112219 0000 112519 0800

140-17458-6 G-258625872589 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12amp3 COND

Air 112219 0000 112519 0800

140-17458-8 G-2590 DIV VEN STACK R2 M0010

Air 112219 0000 112519 0800

12102019Page 6 of 21344

Sample Receipt

Organic Prep

12102019Page 7 of 21345

December 10 2019

DIV VEN Stack R1 FH

DIV VEN Stack R1 BH

DIV VEN Stack R2 FH

DIV VEN Stack R2 BH

(ugsample)

986 2 786

213 7 143

230 4 ND

658 25 408

363 65 298

219 4 ND

12102019Page 8 of 21346

Prep Batch 478940

Prep Batch 478993

Prep Batch 479245

12102019Page 9 of 21347

LCMS (Continued)

12102019Page 10 of 21348

13C3 HFPO-DA 133 50 - 200 112719 0804 120819 0915 1

13C3 HFPO-DA 116 50 - 200 120219 1125 120819 0955 1

13C3 HFPO-DA 116 50 - 200 112719 1236 120619 1241 1

13C3 HFPO-DA 126 50 - 200 120219 1125 120819 0958 1

12102019Page 11 of 21349

13C3 HFPO-DA 136 50 - 200 112719 0804 120819 0919 1

13C3 HFPO-DA 100 50 - 200 120219 1125 120819 1001 1

13C3 HFPO-DA 121 50 - 200 112719 1236 120619 1244 1

13C3 HFPO-DA 109 50 - 200 120219 1125 120819 1004 1

12102019Page 12 of 21350

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12102019Page 13 of 21351

_____________________________________________

12232019

12232019Page 1 of 89452

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 54

GCMS VOA 77

12232019Page 2 of 89453

HPLCIC 498

12232019Page 3 of 89454

Gen Chem MDL 880

12232019Page 4 of 89455

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 89456

Protocol References

None = None

12232019Page 6 of 89457

12232019Page 7 of 89458

Sample Receipt

GCMS VOA

12232019Page 8 of 89459

12232019Page 9 of 89460

GCMS VOA

Prep Batch 35706

HPLCIC

Prep Batch 35705

Prep Batch 35706

12232019Page 10 of 89461

HPLCIC (Continued)

Prep Batch 35707

Prep Batch 35761

Prep Batch 35762

12232019Page 11 of 89462

HPLCIC (Continued)

General Chemistry

12232019Page 12 of 89463

12232019Page 13 of 89464

12232019Page 14 of 89465

HFPO-DA

437 T J N ugSample 113 2218-54-4 112919 1048 120619 2054 1

12232019Page 15 of 89466

Toluene-d8 (Surr) 97 112919 1048 120619 2054 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 16 of 89467

HFPO-DA

12232019Page 17 of 89468

Toluene-d8 (Surr) 96 112919 1048 120619 2119 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 18 of 89469

12232019Page 19 of 89470

HFPO-DA

Toluene-d8 (Surr) 97 112919 1048 120619 2143 171 - 139

12232019Page 20 of 89471

pH 400 HF SU 121319 1501 1

12232019Page 21 of 89472

HFPO-DA

12232019Page 22 of 89473

Toluene-d8 (Surr) 96 112919 1048 120619 2208 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 23 of 89474

12232019Page 24 of 89475

HFPO-DA

1623-05-8104 ugSample 118

Toluene-d8 (Surr) 95 112919 1048 120619 2232 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 25 of 89476

12232019Page 26 of 89477

HFPO-DA

1623-05-8160 ugSample 118

12232019Page 27 of 89478

Toluene-d8 (Surr) 97 112919 1048 120619 2257 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 28 of 89479

HFPO-DA

12232019Page 29 of 89480

Toluene-d8 (Surr) 96 112919 1048 120619 2321 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 30 of 89481

12232019Page 31 of 89482

HFPO-DA

1623-05-8497 ugSample 122

12232019Page 32 of 89483

Toluene-d8 (Surr) 97 112919 1048 120619 2346 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 33 of 89484

HFPO-DA

12232019Page 34 of 89485

1623-05-82290 ugSample 118

1623-05-8410 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0010 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 35 of 89486

12232019Page 36 of 89487

HFPO-DA

484 T H J N ugSample 113 2218-54-4 112919 1048 120719 0035 1

1623-05-8316 ugSample 122

Toluene-d8 (Surr) 97 112919 1048 120719 0035 171 - 139

12232019Page 37 of 89488

pH 400 HF SU 121319 1501 1

12232019Page 38 of 89489

ND H 627 627 ugSample 112919 1048 120719 0059 1

HFPO-DA

12232019Page 39 of 89490

Toluene-d8 (Surr) 96 112919 1048 120719 0059 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 40 of 89491

12232019Page 41 of 89492

HFPO-DA

Toluene-d8 (Surr) 96 112919 1048 120719 0124 171 - 139

pH 400 HF SU 121319 1501 1

12232019Page 42 of 89493

Analyte UnitsMDLRL

12232019Page 43 of 89494

Analyte UnitsMDLRL

12232019Page 44 of 89495

_____________________________________________

12302019

12302019Page 1 of 70696

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 38

GCMS VOA 55

12302019Page 2 of 70697

HPLCIC 431

12302019Page 3 of 70698

Gen Chem MDL 695

12302019Page 4 of 70699

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12302019Page 5 of 706100

Protocol References

None = None

12302019Page 6 of 706101

12302019Page 7 of 706102

12302019Page 8 of 706103

12302019Page 9 of 706104

GCMS VOA

Prep Batch 35956

HPLCIC

Prep Batch 35956

12302019Page 10 of 706105

HPLCIC (Continued)

Prep Batch 35976

General Chemistry

12302019Page 11 of 706106

12302019Page 12 of 706107

12302019Page 13 of 706108

HFPO-DA

12302019Page 14 of 706109

Toluene-d8 (Surr) 89 71 - 139 121019 0947 121019 2258 1

pH 40 HF SU 121719 1337 1

12302019Page 15 of 706110

HFPO-DA

12302019Page 16 of 706111

Toluene-d8 (Surr) 89 121019 0947 121019 2234 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1629 171 - 139

pH 40 HF SU 121719 1337 1

12302019Page 17 of 706112

12302019Page 18 of 706113

HFPO-DA

12302019Page 19 of 706114

Toluene-d8 (Surr) 92 71 - 139 121019 0947 121019 2209 1

Toluene-d8 (Surr) 95 121019 0947 121119 1653 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 20 of 706115

12302019Page 21 of 706116

HFPO-DA

545 T J N ugSample 113 2218-54-4 121019 0947 121019 2145 1

1623-05-8761 ugSample 118

Toluene-d8 (Surr) 91 121019 0947 121019 2145 171 - 139

Toluene-d8 (Surr) 95 121019 0947 121119 1718 171 - 139

12302019Page 22 of 706117

pH 50 HF SU 121719 1337 1

12302019Page 23 of 706118

HFPO-DA

12302019Page 24 of 706119

Toluene-d8 (Surr) 91 121019 0947 121019 2120 171 - 139

pH 50 HF SU 121719 1337 1

12302019Page 25 of 706120

12302019Page 26 of 706121

HFPO-DA

Toluene-d8 (Surr) 92 121019 0947 121019 2056 171 - 139

Toluene-d8 (Surr) 96 121019 0947 121119 1742 171 - 139

pH 50 HF SU 121719 1339 1

12302019Page 27 of 706122

Analyte UnitsMDLRL

12302019Page 28 of 706123

Analyte UnitsMDLRL

12302019Page 29 of 706124

_____________________________________________

12232019

12232019Page 1 of 820125

Data Summaries 5

Definitions 5

Method Summary 6

Sample Summary 7

Case Narrative 8

QC Association 10

Chronicle 46

GCMS VOA 69

12232019Page 2 of 820126

HPLCIC 392

12232019Page 3 of 820127

Gen Chem MDL 808

12232019Page 4 of 820128

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12232019Page 5 of 820129

Protocol References

None = None

12232019Page 6 of 820130

Air 112219 0000 112519 0800

140-17462-7 A-5786 QC MEOH RB Air 112219 0000 112519 0800

140-17462-8 A-5787 QC MEOH TB Air 112219 0000 112519 0800

140-17462-9 A-5788 QC MEOH PB Air 112219 0000 112519 0800

12232019Page 7 of 820131

Sample Receipt

GCMS VOA

12232019Page 8 of 820132

12232019Page 9 of 820133

GCMS VOA

Prep Batch 35705

HPLCIC

Prep Batch 35705

12232019Page 10 of 820134

HPLCIC

Prep Batch 35762

12232019Page 11 of 820135

Prep Batch 479505

General Chemistry

12232019Page 12 of 820136

12232019Page 13 of 820137

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1517 171 - 139

12232019Page 14 of 820138

13C3 HFPO-DA 130 50 - 200 120419 1005 120819 1037 1

pH 400 HF SU 121319 1501 1

12232019Page 15 of 820139

HFPO-DA

12232019Page 16 of 820140

Toluene-d8 (Surr) 96 112919 1045 120619 1542 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1040 1

pH 400 HF SU 121319 1501 1

12232019Page 17 of 820141

12232019Page 18 of 820142

HFPO-DA

Toluene-d8 (Surr) 98 112919 1045 120619 1606 171 - 139

12232019Page 19 of 820143

13C3 HFPO-DA 129 50 - 200 120419 1005 120819 1044 1

pH 400 HF SU 121319 1501 1

12232019Page 20 of 820144

HFPO-DA

12232019Page 21 of 820145

Toluene-d8 (Surr) 96 112919 1045 120619 1631 171 - 139

13C3 HFPO-DA 126 50 - 200 120419 1005 120819 1047 1

pH 400 HF SU 121319 1503 1

12232019Page 22 of 820146

12232019Page 23 of 820147

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1655 171 - 139

12232019Page 24 of 820148

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1053 1

pH 400 HF SU 121319 1503 1

12232019Page 25 of 820149

HFPO-DA

12232019Page 26 of 820150

Toluene-d8 (Surr) 96 112919 1045 120619 1720 171 - 139

13C3 HFPO-DA 127 50 - 200 120419 1005 120819 1057 1

pH 400 HF SU 121319 1503 1

12232019Page 27 of 820151

12232019Page 28 of 820152

HFPO-DA

Toluene-d8 (Surr) 97 112919 1045 120619 1404 171 - 139

12232019Page 29 of 820153

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1100 1

pH 400 HF SU 121319 1503 1

12232019Page 30 of 820154

HFPO-DA

12232019Page 31 of 820155

Toluene-d8 (Surr) 96 112919 1045 120619 1428 171 - 139

13C3 HFPO-DA 125 50 - 200 120419 1005 120819 1103 1

pH 400 HF SU 121319 1503 1

12232019Page 32 of 820156

12232019Page 33 of 820157

HFPO-DA

Toluene-d8 (Surr) 96 112919 1045 120619 1453 171 - 139

13C3 HFPO-DA 131 50 - 200 120419 1005 120819 1106 1

pH 400 HF SU 121319 1503 1

12232019Page 34 of 820158

Analyte UnitsMDLRL

12232019Page 35 of 820159

Analyte UnitsMDLRL

12232019Page 36 of 820160

123120191101 AM 112219 Div Stack M0010

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

14031764 x 09972 x 63136 x ( 3002 + --------------------- )

136Vm(std) = ------------------------------------------------------------ = 64704

5704 + 460

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 100 ) + ( 004715 x 244 ) = 162

123120191101 AM 112219 Div Stack M0010

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

162bws = ------------------------- = 0024

162 + 64704

Md = 1 - bws

Md = 1 - 0024 = 0976

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 00 ) + ( 0320 x 209 ) + (0280 x ( 791 + 000 ))

MWd = 2884

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2884 x 0976 ) +( 18 ( 1 - 0976 )) = 2857

123120191101 AM 112219 Div Stack M0010

Ps x MWs

532Vs = 8549 x 084 x 145039 x ( -------------------- )^12 = 820

2999 x 2857Where

Qs(act) = 60 x 820 x 707 = 34799

2999Qs(std) = 1764 x 0976 x -------------------- x 34799

Qs(std) = 33787

123120191101 AM 112219 Div Stack M0010

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 532 x 64704I = -------------------------------------------------- = 1010

820 x 96 x 2999 x 0976 x (0160)^2Where

1320201218 PM 112219 Div Stack M0010

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

223 x 22046 x 10-9Conc1 = ------------------------------

Conc1 = 760E-10

Conc2 = W ( Vm(std) x 002832)

Conc2 = 223 ( 64704 x 002832 )

Conc2 = 122E+01

1320201218 PM 112219 Div Stack M0010

MR1(Outlet) = 760E-10 x 33787 x 60

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 154E-03 x 45359 3600

P-694 all in oneMOD

NO YES

PASSFAIL

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

Face Opening Planes

Q1 Q1 Q2

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

A-Side PlaneDt

Sampling D

Nozzle Entry Plane

Setting

in H20

(∆H) ft3

(Vw)ft3

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

05 700

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

15 100

107 09910

18851130 09946

150 09995

9321832

Select Temperature

Average Temperature

Reading

(Accuracy +- 1oF)

Difference 2

Channel Number

Calibration Results

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

11222019Run 1 Run 2

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 0 ) + ( 028 ( 100 - ( 0 + 209 )))

MWd = ( 669 ) + ( 000 ) + ( 2215 )

MWd = 2884 2884

Tma = Ts + 460

Tma = 5704 + 460

Tma = 51704 52519

Pm = 3002 + ( 14025 136)

Pm = 3012 3009

Yqa = ( 9600 6314 ) SQRT ( 00319 51704 29 ) ( 187 3012 2884 ) 118

Yqa = 1521 SQRT 478315 1625473 118

Yqa = 09719 09742

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0972 ) 09972 ) 100

Average Diff = 243

Allowable = 50

1220201119 AM 112219 Div Stack M0010171

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2000 20004890 2050 20504890 2025 21600000 2050 20509772 2100 21009772 2075 22800000 2220 222014768 2220 222014768 2220 22200000 2280 228020034 2280 228020034 2280 2280

Average 10088

oC oF1 2 3 4 5 60 0 0 0 00 00

100 100 100 100 1000 00500 500 500 500 5000 001000 1000 1000 1000 10000 00

Wet Test Meter

Gas Volume

50045 725

685 102 10137

695085 100

730 200 09943

110 10118

Dry Gas Meter

Temperatures

20 200

150 72515 17

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

050 070

Difference 2 ()

Average Temperature

Reading

500100

Channel Number

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

Resultsin H20

(∆H)liters (Vw)

liters (Vd)

oF (Tw)

Outlet oC (Tdo)

Inlet oC (Tdi)

Average oF (Td)

Time min (O)

0000 2400 24002999 2400 24002999 2400 24000000 2400 24008960 2400 24008960 2400 24000000 2400 24009934 2400 24009934 2400 24000000 2400 240018700 2400 240018700 2400 2400

Average 10088

oC oF1 2 3 4 5 632 32 32 32 320 00212 212 212 212 2120 00932 932 932 932 9320 001829 1829 1829 1829 18290 01

Wet Test Meter

Gas Volume

30000 720

750 118 10060

750035 90

710 99 10099

100 10099

Dry Gas Meter

Temperatures

170 190

100 720

Setting

Roto-meter

Liters per minute

Orifice Manometer

(Accuracy +- 1oF)

025 025

Channel Number

Difference 2 ()

Average Temperature

Reading

932212

Select Temperature

( ) ( )

( )( ) 2

O460tw

460tdPb

H03170H

460tw613

)460td(PbVwY

lowast+

lowast

+lowast∆lowast

+lowast

+lowastlowast=

( )( ) ( )( )( )

+minus+=

460FTempferenceRe

ADPB5DBtmp

FIELD DATA CALCS

SemiVol Results

ADPD0DEtmp

Data input

results

ADP152tmp

SEMIVOLCALC

ADPD8Ftmp

Data input

results

ADP2D63tmp

results

ADP5868tmp

Data input

ADPE9F3tmp

results

ADP2499tmp

Data input

results

ADP6F7Etmp

Data input

results