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Fabrication of Nanowire MOSFETS Virginia Polytechnic Institute Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski

Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

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Page 1: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Fabrication of Nanowire MOSFETS

Virginia Polytechnic Institute

Mehtab Singh Dhillon

Advisor : Dr. Marius Orlowski

Page 2: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Ideal MOSFET:

Gate electrode wraps all

around a nanowire semiconductor

(a single crystal cylinder of Si or Ge)

Page 3: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Nanowire Mosfets

A very simple construction of a nanowire MOSFET is proposed by using

Silicon-On-Insulator (SOI) substrates without advanced photolithography.

BO

XSi

Si 100 nm

} SOI-type

wafer

BO

X

Amount of BOX underetch

During last oxide removal

Si

Si

Si

Source/Drain

Page 4: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Deposition of Si3N4

• We deposit Silicon nitride on the silicon wafer

• Plasma enhanced chemical vapor deposition machine is used

to form a uniform layer

Inflow of gases

Chamber: plasma deposition

takes place

Wafer is loaded here

Computer control BO

XSi

Si

Si3N4

Page 5: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Cleaning of Wafer

• RCA cleaning of wafers with hydrogen peroxide to remove the

organic/inorganic impurities

• For every use wafer is treated with acetone, propane to remove

other impurities

Nitrogen gas

DI Water

Solvent and Developer

waste collected

Page 6: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

HDMS (trimethylsilyl)spin :

• Dehydration of wafer at 150 c for 13 minutes

• Wafer smoothly coated (30s with 2000 rpm)

• Used for adhesion for photoresist

• Also silicon dioxide reacts with HDMS to form water repellent

surface thus preventing aqueous developer to penetrate wafer

• soft bake the wafer at 100 C

Photoresist spinner

Wafer holder : creates vacuum

Control unit: Set run time; Desired rpm

Page 7: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Photoresist Spin

• Positive photoresist (AZ5214E) poured on wafer

• Spin for 50s at 2000rpm

• Bake for 2 minutes to remove all the solvents

• Thickness of resist determined by its viscosity and spin speed

• For 2000 rpm we have layer thickness of 1.98 micro meters

Photoresist spinner

BO

XSi

Si

Si3N4

PR

Page 8: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Mask Aligner: Exposure

• Wafer patterned with one micron line mask

• Wafer and the mask are aligned and brought close together

• Then exposed with UV light. UV light does not penetrate through the

patterned lines but passes through the other open area and thus attacks the

photoresist on wafer

• The exposure makes the photoresist soluble in the developer

• After exposure wafer baked for 30s at 100 C

• Post bake important for one micron lines as they are very thin; baking

makes the photoresist more durable

• Longer post bake makes the resist too hard for developer to dissolve

• Right balance between exposure time and post bake time is very important

Page 9: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Mask Aligner

BO

XSi

Si

Si3N4

PR

Moniter screen

Exposure source

Change mask

Function keys:

•Edit distance between wafer and

mask gap

•Change exposure time

•Align the masks with the wafer

Load wafer

Page 10: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Result of Patterning

• we successfully pattern the wafer with one micron lines

Page 11: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Trimming of Resist Lines

• Trimming is always done in a 2 step process

• Vertical trimming using plasma etching

• Lateral etching using chemicals like phosphoric acid, BOE(HF with water)

• Silicon nitride is etched using phosphoric acid

• Silicon dioxide is etched using BOE which is diluted hydrofluoric acid

BO

XSi

Si

Si3N4

PR

Page 12: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Deep Reactive Ion Etching

Page 13: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Silicon Nitride Trimming

• Silicon nitride is trimmed down using the plasma etching

• Lateral etching is done using phosphoric acid

vertical etching Lateral etching

• We now strip of the Photoresist

BO

XSi

Si

Si3N4

PR

BO

XSi

Si

PRSilicon Nitride

Page 14: Fabrication of Nanowire MOSFETSvmec.server310.com/wp-content/uploads/2017/07/nanowire...Mehtab Singh Dhillon Advisor : Dr. Marius Orlowski Ideal MOSFET: Gate electrode wraps all around

Silicon Trimming

Si

BOX

Si

Si3N4

Si

BOX

SiSi

Silicon vertical etch using plasma Silicon nitride stripped off

100-200 nm

• We can etch silicon using the DRIE plasma machine