Engr 2110 Introduction to Material Science --Ch1

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    Engr 2110 Introduction toMaterial Science (for Engineers)

    Dr. Richard R. Lindeke, Ph.D.B Met. Eng. University of Minnesota, 1970Master’s Studies, Met Eng. Colorado School of

    Mines, 1978-79 (Electro-Slag Welding ofHeavy Section 2¼ Cr 1 Mo Steels)

    Ph.D., Ind. Eng. Penn State University, 1987(Foundry Engineering – CG AlloyDevelopment)

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    Syllabus and Website:Review the Syllabus

    Attendance is your job – come to class!Final is Common Time Monday or Tuesday

    Or our regularly scheduled time (Tuesday May 12 8-10 AM)Pop Quizzes and homework/Chapter Reviews (Ch 17/18) –(20% of your grade!)Don’t copy from others; don’t plagiarize – its just the rightthing to do!!

    Course Website:http://www.d.umn.edu/~rlindek1/ENGR2110/Cover_ Page.htm

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    Materials Science and

    EngineeringIt all about the raw materials and howthey are processed

    That is why we call it materialsENGINEERING

    M i n o r d if fe r e n c e s in Raw materials or

    processing parameters can meanm a j o r c h a n g e s i n th e p e r fo r m a n c eof the final material or product

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    Looking At CG Iron Alloy

    Development (Processing):

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    Looking At CG Iron Alloy

    Development (Processing):

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    Looking At CG Iron Alloy

    Development (Structures)

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    Looking At CG Iron Alloy

    Development (Results)

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    Our Text:Material Science and Engineering An Introduction

    by William D. Callister, Jr

    Seventh Edition, John Wiley & Sons, Inc.

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    And Remember: Materials

    “Drive” our Society! Ages of “Man” we survive based on the materials we control

    Stone Age – naturally occurring materialsSpecial rocks, skins, wood

    Bronze AgeCasting and forging

    Iron AgeHigh Temperature furnaces

    Steel AgeHigh Strength Alloys

    Non-Ferrous and Polymer Age Aluminum, Titanium and Nickel (superalloys) – aerospaceSilicon – InformationPlastics and Composites – food preservation, housing, aerospace and higherspeeds

    Exotic Materials Age?Nano-Material and bio-Materials – they are coming and then …

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    And Formula One – the future

    of automotive is …http://www.autofieldguide.com/articles/050701.html

    http://www.autofieldguide.com/articles/050701.htmlhttp://www.autofieldguide.com/articles/050701.html

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    Doing Materials!Engineered Materials are a function of:

    Raw Materials Elemental ControlProcessing History

    Our Role in Engineering Materials then is tounderstand the application and specify theappropriate material to do the job as a function of:

    Strength: yield and ultimateDuctility, flexibilityWeight/densityWorking EnvironmentCost: Lifecycle expenses, Environmental impact*

    * Economic and Environmental Factors often are the

    most important when making the final decision!

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    Example of Materials Engineering

    Work – Hip Implant

    With age or certain illnesses joints deteriorate.Particularly those with large loads (such aship).

    Adapted from Fig. 22.25, Callister 7e.

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    Example – Hip Implant

    Requirementsmechanical

    strength (manycycles)good lubricitybiocompatibility

    Adapted from Fig. 22.24, Callister 7e.

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    Example – Hip Implant

    Adapted from Fig. 22.24,Callister 7e.

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    Solution – Hip ImplantKey Problems toovercome:

    fixation agent to holdacetabular cupcup lubrication materialfemoral stem – fixingagent ( “ glue ” )must avoid any debris incupMust hold up in bodychemistryMust be strong yetflexible

    Acetabular Cup and

    Liner

    Ball

    FemoralStem

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    Introduction

    List the Major Types of MATERIALSThat You Know:

    METALSCERAMICSPOLYMERS

    COMPOSITES ADVANCED MATERIALS

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    Introduction, cont.Metals

    Steel, Cast Iron, Aluminum, Copper,Titanium, manyothers

    CeramicsGlass, Concrete,Brick, Alumina,Zirconia, SiN, SiC

    PolymersPlastics, Wood,Cotton (rayon,nylon), “glue”

    CompositesGlass Fiber-reinforced polymers,Carbon Fiber-reinforced polymers,Metal MatrixComposites, etc.

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    Thoughts about these

    “fundamental ” MaterialsMetals :

    Strong, ductilehigh thermal & electrical conductivityopaque, reflective.

    Polymers/plastics : Covalent bonding sharing of e ’sSoft, ductile, low strength, low densitythermal & electrical insulatorsOptically translucent or transparent.

    Ceramics : ionic bonding (refractory) – compounds ofmetallic & non-metallic elements (oxides, carbides,nitrides, sulfides)

    Brittle, glassy, elastic

    non-conducting (insulators)

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    The Materials Selection Process

    1. Pick Application Determine required Properties

    2. Properties Identify candidate Material(s)

    3. Material Identify required ProcessingProcessing: changes structure and overall shapeex: casting, sintering, vapor deposition, doping

    forming, joining, annealing.

    Properties: mechanical, electrical, thermal,

    magnetic, optical, deteriorative.

    Material: structure, composition.

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    But: Properties depend on Structure(strength or hardness)

    H a r

    d n e s s

    ( B H N )

    Cooling Rate (ºC/s)

    100

    200

    300

    400

    500

    600

    0.01 0.1 1 10 100 1000

    (d)

    30 µ m

    (c)

    4 µ m

    (b)

    30 µ m

    (a)

    30 µ m

    And: Processing can change structure! (seeabove structure vs Cooling Rate)

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    Another Example: Rolling of Steel

    At h 1 , L 1low UTSlow YShigh ductilityround grains

    A t h 2 L 2high UTShigh YSlow ductilityelongated grains

    Structure determines Properties but Processing determinesStructure !

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    Optical Properties of Ceramic arecontrolled by “Grain Structure”

    Grain Structure is a function of

    “Solidification” processing!

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    Electrical Properties (of Copper):

    Adapted from Fig. 18.8, Callister 7e.(Fig. 18.8 adapted from: J.O. Linde,

    Ann Physik 5 , 219 (1932); andC.A. Wert and R.M. Thomson,Physics of Solids , 2nd edition,

    McGraw-Hill Company, New York,1970.)

    T(°C)

    -200 -100 0

    1

    2

    34

    5

    6

    R e s

    i s t i v i t y ,

    ρ

    ( 1 0 - 8 O h m - m

    )

    0

    Electrical Resistivity of

    Copper is affected by:• Contaminate level

    • Degree of deformation

    • Operating temperature

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    THERMAL Properties• Space Shuttle Tiles:

    --Silica fiber insulation

    offers low heat conduction .

    • Thermal Conductivityof Copper: --It decreases when

    you add zinc!

    Adapted fromFig. 19.4W, Callister6e. (Courtesy ofLockheed AerospaceCeramics Systems,Sunnyvale, CA)(Note: "W" denotes fig.is on CD-ROM.)

    Adapted from Fig. 19.4, Callister 7e.(Fig. 19.4 is adapted from Metals Handbook:Properties and Selection: Nonferrous alloys andPure Metals , Vol. 2, 9th ed., H. Baker,(Managing Editor), American Society for Metals,1979, p. 315.)

    Composition (wt% Zinc)

    T h e r m a l

    C o n d u c

    t i v i t y

    ( W / m - K

    )

    400

    300

    200

    100

    00 10 20 30 40

    100 µ m

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    MAGNETIC Properties

    • Magnetic Permeabilityvs. Composition:--Adding 3 atomic % Si makes Fe a

    better recording medium!

    Adapted from C.R. Barrett, W.D. Nix, and A.S. Tetelman, The Principles of Engineering Materials , Fig. 1-7(a), p. 9,1973. Electronically reproducedby permission of Pearson Education, Inc.,Upper Saddle River, New Jersey.

    Fig. 20.23, Callister 7e.(Fig. 20.23 is from J.U. Lemke, MRS Bulletin ,Vol. XV, No. 3, p. 31, 1990.)

    • Magnetic Storage :--Recording medium

    is magnetized by

    recording head.

    Magnetic Field M a g n e t

    i z a t

    i o n Fe+3%Si

    Fe

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    DETERIORATIVE Properties

    • Stress & Saltwater...--causes cracks!

    Adapted from chapter-opening photograph,Chapter 17, Callister 7e.(from Marine Corrosion, Causes, andPrevention , John Wiley and Sons, Inc., 1975.)

    4 µ m--material:7150-T651 Al

    "alloy"(Zn,Cu,Mg,Zr)

    Adapted from Fig. 11.26,Callister 7e. (Fig. 11.26 provided courtesy of G.H.

    Narayanan and A.G. Miller, Boeing Commercial Airplane Company.)

    • Heat treatment: slowscrack speed in salt water!

    Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics ofEngineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source:Markus O. Speidel, Brown Boveri Co.)

    “held at

    160ºC for 1 hrbefore testing”

    increasing load c r a c

    k s p e e

    d ( m / s ) “as-is”

    10-10

    10-8

    Alloy 7178 tested insaturated aqueous NaClsolution at 23ºC

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    • Using the right material for the job.one that is most economical and

    “Greenest” when life usage is considered

    • Understanding the relation between

    properties , structure , and processing .• Recognizing new design opportunities offered

    by materials selection.

    Course Goal is to make you aware of theimportance of Material Selection by: