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Electro-chemical Machining
presented by
Dr. P. SahaDepartment of Mechanical Engineering IIT Kharagpur
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 2
Surface
Treatments
Coating Machining
Passivation
AnodisingElectro-
Chemical
Machining
Thin
Coating
Thick
Coating
Electroplating Electroforming
Electro Chemical Processing
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A Basic Electro-chemical Cell
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Basic electrochemistry of a plating bath
Anode reaction:
M Mn+ + ne-
Mn+ + Zm- MmZn
Mn+ + n(OH)- M(OH)n
Electrolyte (ionization)
MmZn Mn+ + Zm-
H2O H+ + (OH)-
Cathode reaction:
Mn+ + ne- M 2 H+ + 2e- H2
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Concept of Electro-chemical Machining
• Reverse of
electroplating
• Job becomes anode,
which gets eroded.
• Tool remains unaltered
(neither deposition nor
erosion)
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 6
Outcome:
No damage to the tool
( neither deposition nor erosion)
Basic Electrochemistry in Electrochemical Machining
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 7
ECM setup
with fixture
Electrolytic
tank
DC power
supply
(Continuous
or Pulsed)
Sludge
Electrolyte
Pump
Centrifuge
Basic scheme of an ECM machine
Electrolyte
+ Sludge
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Schematic Diagram of an ECM Machine
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 9
Various Voltage Drops at the Electrodes and Electrolyte
CURRENT DENSITY :
10 to 100 A/cm2
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Faraday’s Laws of Electrolysis
When an electric current passing through an electrolyte results in
chemical reaction.
1. The amount of any substance deposited or dissolved (W), produced by current is proportional to the quantity of electricity passed (Q) through the electrolyte.
W Q∞ .Q I t=where, ‘I’ is the current and ‘t’ is the time for which current flows
where, A and v are Atomic weight and Valency of the substancerespectively.
W ECE∞ /ECE A v=
1. The quantities of substances liberated or deposited on the electrode by the passage of a given quantity of electricity (current) are proportional to the electrochemical equivalent weights of those substances.
and
and
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Combining the two laws:
or
(1/ ) ( / )W F A v Q=
(1/ ) ( / ) .W F A v I t=where, F is the Faraday’s Constant, F = 96,500 Coulombs
So the removal rate,
ˆ ( / ) ( / . )W W t A F v I= = gm-equivalent/s
cm3/s( / . ) ( / )MRR A F va d In ρ=
where, ρ is density of the material, g/cm3)
( / . ) ( / )CFeed rate A F v J ρ= cm/s
where Jc
is the current density = I / Surface area
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 12
So material removal rate at any point is proportional to current density.
gm (equivalent)/s
For an ALLOY, with ‘n’ number of elements present in it;
1
ˆ (100. / )[1/ / ]n
i i ii
W I F X v A=
= ∑
So the removal rate,
Valency, atomic weight and their percentage presence are
represented by v1to v
n, A
1to A
nand X
1to X
n
respectively;
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Transfer of tool profile to workpiece is possible in ECM
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?
Whether the dissolution reactions In ECM proceed if
only an appropriate constant voltage is provided to the electrodes and
there is zero feed of the cathode tool with respect to the anode workpiece ?
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The rate of anodic dissolution:
dW = a. dh.ρ = (1/F) (ECE) I dt
Or, the rate of change of gap:
(dh/dt) = (1/F) (ECE) (I / a ρ)
Since,
Current, I = V / (γh/a),
where, V is the applied voltage and γ= specific resistance
(dh/dt) = (1/F) (ECE) (V/ γh ρ)
When, (1/F) (ECE) (V/ γρ), is constant = C
(dh/dt) = C / h (7)
The initial gap, h0 increases to h1 within time, t:
∫h0h1 h dh = ∫0
t C dt
h12 – h0
2 = 2 Ct (8)
The gap increases parabolically, machining rate decreases accordingly, and finally ceases to zero mech14.weebly.com
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WITH FEED = S
Eqn. 7 is written as:
(dh/dt) = C / h – s (9)
Under equilibrium condition, (dh/dt) = 0
So, feed rate, s = C/h, or h = C/ s
Again for constant feed rate,
h = constant =he, equilibrium gap = C/s
Hence the dimension-less parameters may be formed as:
h’ = (h/he) = (sh/C) and t’ = st/he = s2t/C
So a non-dimensional form of eqn. 9 is written as:
(dh’/dt’) = (1- h’) / h’ (10)
On integration between time, 0 to t’ and gap between h0’ to h1
’
t’ = [ (h0’- h1
’) + ln {( h0’- 1)/ (h1
’- 1) (11)
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 18
Equilibrium Gap
ELECTRODE GAP takes an EQUILIBRIUM GAP finally,
whatever the initial gap may be.
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SOME IMPORTANT FEATURES OF ECM PROCESS
1. The process attempts to maintain a constant gap (whatever may be the initial gap and feed rate). So the process is self regulated.
2. Value of equilibrium gap depends on feed rate
3. Higher feed-rate provides smaller gap hence higher current density higher MRR and higher job accuracy
4. Surface finish is independent of feed-rate
5. ECM process is independent of hardness of the material:
For materials above 450 BHN, ECM is better than conventional machining.
Typically harder material helps to improve the rate (for higher ECE of constituting elements).
6. There is no tool wear.
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Higher material removal is achieved by higher current.
Electrolyte flow is necessary to avoid
· ion concentration
· the deposition in the tool
· reaction precipitants (sludge)
· overheating of the electrolyte
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Typical values of parameters and conditions of ECM
Power supply
Type: Direct Current
Voltage: 5 to 30 V (continue or pulse)
Current: 50 to 40,000 A
Current Density: 10 to 500 A/cm2
Electrolyte
Type and Concentration
Most used: NaCl at 60 to 240 g/l
Frequently used: NaNO3 at 120 to 480 g/l
Less Frequently used: Proprietary Mixture
Temperature : 20 to 50o C
Flow rate: 16 l/min/100A
Velocity : 1500 to 3000 m/min
Inlet Pressure: 0.15 to 3 MPa
Outlet Pressure: 0.1 to 0.3 MPa
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Working Parameters
Frontal Working Gap : 0.05 to 0.3mm
Feed rate : 0.1 to 20mm/min
Electrode material : Brass, Copper, Bronze
Tolerance
2-dimensional shapes : 0.05-0.2 mm
3-dimensioanl shapes : 0.1mm
Surface Roughness (Ra) : 0.1 to 2.5 µm
Example of cathode tool
(above) and anode work
piece (below).
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An ECM Die Sinking Machine with Power supply
Courtesy AEG-Elotherm-Germany
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2/13/2018 P Saha, Mech Engg, IIT Kharagpur 25
PARTS MACHINED BY ECM PROCESS
(Courtesy AEG-Elotherm-Germany)
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Summary: Main characteristics of ECM
MRR in ECM does not depend on the mechanical properties of the metal but depends on work piece composition
Accuracy of ECM depends on shape and dimensions of machining workpiece and approximately is from 0.05 mm to 0.3 mm at using continuous current, and from 0.02 mm to 0.05 mm at using pulsed ECM.
Sharp corners are difficult to create because of stray current
Surface roughness of machined surface is decreasing with increasing machining rate (for typical materials) and approximately is equal from Ra=0.1 µm to Ra= 2.5 µm.
ECM generates no residual stress
The specific energy consumption of ECM is relative high and equal from 200 J/mm3 to 600 J/mm3.
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Thank You
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