DVLS Standards Catalog - gallpe.com

DVLS Standards Catalog

Boosting laboratory efficiency www.davinci-ls.com

Call +31-10-258 1878 for prices on the DVLS Standards Page 2


Rotterdam, January 2016 Dear Distribution Partner, We are proud to present you the 2016 edition of the Da Vinci Laboratory Solutions (DVLS) Standards Catalog for the Petrochemical Industry. The standards are manufactured by Spectrum Quality Standards (SQS), a leading supplier of certified, verified and analytically traceable standards since 1994. This catalog provides an overview of the most commonly used standards in the petrochemical industry. In case a standard is missing or you would like to inquire about the costs, do not hesitate to contact us with your specific requirements. The standards are also included in the special DVLS kits for DHA and SimDist applications. For more information on the DVLS Standards and Kits please contact our supplies department. Da Vinci Laboratory Solutions B.V. Telephone number : +31 10 258 1870 Tel Supplies dept : +31 10 258 1878 Fax number : +31 10 258 1879 E-mail : [email protected] Our supplies specialist will be happy to assist you on selecting the required standard and any custom made standard. With kind regards, Da Vinci Laboratory Solutions B.V. Willem van Raalte Managing Director P.S. Looking for a standard that meets a specific method? Check page 63!

mailto:[email protected]


Oxygenate Standards for Gas Chromatography

Oxygenate Calibration Standards [ASTM D4815, D5599] 7 Alcohol Calibration Standards [Oxyalcohol, Oxytex] 8 Oxygenate Daily Check Standards [DCK 1 thru 10] 8 Low Level Oxygenate Standard [Low Ox] 9 MTBE Impurity Standards [ASTM D5441] 9 Gasoline Reference Standards [CALRR1, 2, 3, FIA] 10 Reference Blank Standards [BLK-] 10 Oxygenated Gasoline Standards [NIST] 11 Oxygenates in Water [OXY-W] 11 Fuel Ethanol Standards [ASTM D5501] 11 Calibration Standards for Infrared Analyzers [IRQC1 thru 10] 12 Octane Check Standards [OCT 1 thru 3] 12 Benzene Check Standards [IRQC 12 thru 15] 12

PONA and PIANO Standards / DHA Standards

Biodiesel in Diesel Standards [ASTM D7371 Low Set A, B and C] 35 Biodiesel in Diesel Standards [ASTM D7371 High Set A, B and C] 36 Biodiesel in Diesel Standards [ASTM D7371 Ultra High Set A, B and C] 37 IP585 FAME Standards [IP585] Calibration and Check Standards 37

Quantitative PIANO Mixture [PIANO-1, -10, ASTM D6729, D6730, D6733] 13 PIANO Paraffins Standard [PIANO-P] 14 PIANO Isoparaffins Standard [PIANO-I] 15 PIANO Aromatics Standard [PIANO-A] 16 PIANO Naphthalene Standard [PIANO-N] 17 PIANO Olefins Standard [PIANO-O] 18 Combined PIANO Standards [PIANO-5, PIANO-5-SET] 19 Quantitative PONA Mixture [PONA-1, -10, ASTM D5134] 19 PONA-7 [PONA-7-1, -10 ASTM D6730, D6733 19 SIMDIS Calibration Standards [ASTM D3710] 20 Boiling Range Distribution [ASTM D6352] 20 Polywax Calibration [ASTM D7169, D6352] 20 Engine Oil Volatized at 371 C [ASTM D6417] 21 Quantitative Alkylate Reference [ALK-1] 21 SIMDIS Calibration Standards [ASTM D2887, D7213] 22 GRS Reference Gas Oil #2 [ASTM D2887] 23

Benzene, Aromatic and Biodiesel Standards

Benzene Purity Standards [ASTM D5713] 23 Benzene Purity Standards [D4492] 24 Benzene Calibration Standards [ASTM D3606M, B, D, N, EM, EB, EN] 24 Benzene Check Standards [ASTM D3606DBE thru –DN] 25 Quality Control Reference Material [D5769 AR1000, 3000, 4000] 25 Aromatics in Finished Gasoline [ASTM D5769 - 3-Component Internal] 26 Aromatics in Finished Gasoline [ASTM D5769 – 4-Component Internal] 27 Deuterated Internal Standards [ASTM D5769 INT-1, -5, T-1, T-5] 28 D6550 Olefins in Finished Gasoline [6550CAL, CAL-S, -H, -X, CK, REF] 29 Total Aromatics in Finished Gasoline [ASTM D5580] 30 D1319 Aromatics and Olefins by FIA [FIA1000, CALFIA, FIA1000-CY] 30 Aromatics in Diesel & Aviation Fuels [ASTM D5186] 31 Aromatics for UOP Methods [UOP720, 744, 931, 831, 551] 32 Aromatics for UOP Methods [UOP798, 690, 868, 880] 33 Non-Aromatics for UOP Methods [UOP543, 621, 870] 34

CONTENTS


Total Sulfur by UV Fluorescence [ASTM D5453] 38 Sulfur by Oxidative Microcoulometry [ASTM D3120, D3246, and D3961] 38 Sulfur by Rateometric Colorimetry [ASTM D4045, D6313] 38 Sulfur by High Temp Combustion [ASTM D1552] 39 Sulfur by Combustion & Electrochemical Detection [ASTM D6428] 39 Trace Nitrogen by Combustion & Electrochemical Detection [ASTM D6069] 39 Trace Nitrogen by Chemiluminescence [ASTM D4629, D5762] 40 Sulfur and Nitrogen Standards [SNCAL, SNCK] 40 Sulfur by X-ray Spectrometry [ASTM D2622, D4294] 41 Calibration Set for Low Level Sulfur [CARB XRF1, 2] 41 Sulfur Standards in Bulk Quantities 42 EPA ULSD Qualification Set [EPA PB, -PB-S] 42 Standards for Ultra Low Sulfur Diesel [ASTM D5453] 42 Standards for Ultra Low Sulfur Diesel [ASTM D7039] 42 D5623 Mercaptan Sulfur Standards [MSX-14, MSX-1] 43 D5623 Mercaptan Sulfur Standards [MSX-22] 44 D3227 Mercaptan Sulfide Standards [UOP163] 44 D5623 Multi-Component Sulfur Standards [MSX-41] 45 D5623 Mercaptan Sulfur & Thiophene [MSX-1, -M, -THIO] 46 Organic Chlorides in Crude Oil [ASTM D4929 (b)] 47 Organic Chloride in Hydrocarbons [ASTM D5808] 47 Organo Fluorine Standards [FC-1, FP-1, FB-2, FH-1, FT-1] 47 Chlorine in Mineral Oil Standards [OCR1, 2, CK, XOS-CL-M, CL-H2O, -DCK] 48 Chlorine & Sulfur in Mineral Oil [OCS-R1, R2, CK] 48

Nitrogen and Sulfur Standards

D2386 Freezing Point Standards [FPZ 50, 45] 49 D97 Pour Point Standards [PP5, 10, 15, 20, 40, 50] 49 D2500 Cloud Point Standards [CP5, 2, 10, 15, 20] 49 D6371/IP309 Cold Filter Plug Point [CFPP1, 2, 3] 49 D5949 Pour Point for Phase [PP67-PH, PP17-PH] 50 D5773 Cloud Point for Phase [CP55-PH, CP15-PH] 50 D5972 Freeze Point for Phase [FPZ51-PH, FPZ4-PH] 50 D92, D93, D56 Flash Point Standards [FP60, 75, 93] 50 D92, D93, D56 Flash Point Standards [FP200, 230, TCC40, 55, 60, 68] 50 IP33/IP170 Abel Flash Point [AB40] 51

Physical Properties Standards

CONTENTS

Biodiesel in Diesel Standards [ASTM D7371 Low Set A, B and C] 35 Biodiesel in Diesel Standards [ASTM D7371 High Set A, B and C] 36 Biodiesel in Diesel Standards [ASTM D7371 Ultra High Set A, B and C] 37 IP585 FAME Standards [IP585] Calibration and Check Standards 37

Benzene, Aromatic and Biodiesel Standards


Certified Flash Points [FP53ND, 65UD, 110TD, 134HEX, 115TD, 138HEX, 51ND, 67UD] 52 D445 Viscosity Standards [VIS4, 7, 20, 60, 180, 520] 52 D5188 Vapor–Liquid Ratio Temp [VL1, VL2] 52 D5482, D5191 Vapor Pressure Standards [VP1-7, 5191-20,-54G,-54G-S,-5G,-L 53 Determination of Silicon as Siloxane [SIL-CAL, -CK] 53 D6045, D848, D6258 Color Standards [SAY, ASTM, 848-03, 6258CAL –CK] 54 D86 Group 1, 2 & 4 Synthetic Distillation Standards [D86-1, -2, -3, 4-1, 4-2] 55 D850 Distillation Standards [D850-4-1, -2] 56 D3230 Salt in Crude Standards [3230CAL-QT, 3230DCK-16] 56

Physical Properties Standards

D611 Aniline Point Standards [AP611, AP611E] 57 D611 Pure Aniline [ANP] 57 D6304 Water for Coulometric Karl Fischer [KF40, 60, 100, 500, 1000, 5000] 58 D6304 Water for Volumetric Karl Fischer [KF100, 1000, 5000] 58 Wear Metal Standards in Oils [D5708, D4927, D5863 WM12, WM21] 59 D5059 Lead in Gasoline Standards [5059-A, 5059-ISTD] 60 D3237 Lead in Gasoline Standards [3237-02, -05, -10, X3] 60 Phosphorous in Gasoline by XRF [P-CAL, P-DCK] 60 Matrix Oils and Stabilizer Solutions [S20, S75, LS-D] 60 Standards for Underground Fuel Spills [BTEX / MTBE Mix - BTEX-M-200, -2000] 61 Standards for Underground Fuel Spills [BTEX / MTBE Cal Sets – BTEX-CAL-L, -H] 61 Standards for Underground Fuel Spills [GRO-MIX, GRO-CAL] 61 Ion Chromatography Standards [IC-11, IC-4] 62

CONTENTS

Miscellaneous Standards

Additional information

ASTM/EN/IP/ISO conversion table 63 Request form custom made standards 64


The Clean Air Act of 1995 mandated the use of Reformulated Gasoline in designated areas of the country. The EPA designated two ASTM Methods for the analysis of Oxygenates in Gasoline and the use of a Five Point Calibration Set with DME as the Internal Standard. The following Oxygenate Calibration Sets are packaged in 2 ml ampoules and are certified to +/- 1% relative and are NIST traceable by weight.

D4815 Calibration Set D5599 Calibration Set

Nominal % Wt. 1-Butanol 0.25 – 5.0 Methanol 0.5 – 15.0 Ethanol 0.25 – 15.0 MTBE 1.0 – 16.0 ETBE 1.25 – 15.0 1-Propanol 0.25 – 5.0 2-Propanol 0.25 – 5.0 Iso-Butanol 0.25 – 5.0 DIPE 0.25 – 5.0 TAME 0.5 – 15.0 Sec-Butyl Alcohol 0.25- - 5.0 t-Amyl Alcohol 0.25 – 2.5 t-Butyl Alcohol 0.5 – 15.0 DME 5.0 RFA Balance 11 Mixtures

Nominal % Wt. Methanol 0.25 – 12.5 Ethanol 0.25 – 13.0 t-Butanol 0.25 – 12.5 MTBE 0.25 – 15.0 ETBE 1.0 – 18.0 TAME 0.10 – 2.0 DIPE 0.25 – 5.0 RFA Balance +DME +5.0 1-Butanol 0.25 – 5.0

8 Mixtures

Low Calibration Set D4815 Calibration Set

Nominal, ppm Wt. MTBE 100, 250, 500, 750 1000 ppm wt. in RFA MTBE 1, 5, 10, 50, 100, 500, 1000 ppm wt. in Isooctane Standards are available in 2 ml or 10 ml ampoules. An internal standard, DME, can be added at 5 % wt.

LOWCAL Calibration Set (2 ml) in RFA Calibration Set (10 ml) in RFA Calibration Set (2 ml) in ISO Calibration Set (10 ml) in ISO

Nominal % Wt. Methanol 0.25 – 12.5 Ethanol 0.25 – 13.0 t-Butanol 0.25 – 12.5 MTBE 0.25 – 15.0 ETBE 1.0 – 18.0 TAME 0.10 – 2.0 DIPE 0.25 – 5.0 DME 5.0 RFA Balance 8 Mixtures

Standards can also be custom made to any specifications. Please contact us for more information.

OXYGENATE STANDARDS


OXYGENATE STANDARDS

Alcohol Calibration Standards

Alcohol/Ether Nominal % Wt. Alcohol/Ether Nominal % Wt. Isopropanol 0.25 – 12.0 Isopropanol 0.25 – 12.0 N-Propanol 0.25 – 12.0 N-Propanol 0.25 – 12.0 Iso-Butanol 0.25 – 12.0 Iso-Butanol 0.25 – 12.0 Sec-Butanol 0.25 – 12.0 Sec-Butanol 0.25 – 12.0 N-Butanol 0.25 – 12.0 N-Butanol 0.25 – 12.0 DIPE 0.25 – 12.0 DIPE 0.25 – 20.0 t-Amyl Alcohol 0.25 – 12.0 t-Amyl Alcohol 0.25 – 12.0 RFA Balance RFA Balance +DME 5.0 +DME 5.0

Check Standards

The EPA requires calibrations be checked using a Calibration Check Standard at least once per analysis batch or once per 10 samples; and an Independent Reference Standard at least once per analysis batch or at least once per 100 samples. Additionally, the Calibration Check Standard and the Reference Standard must be made from different lots of raw materials and by different persons. Spectrum manufactures Check Standards in compliance with EPA regulations. They consist of a Calibration Check Standard, a Reference Standard and a Reference Blank. Catalog # Product (Set of 10) / (Set of 60) DCK-1-(# of days) 14.9% wt. MTBE/RFA DCK-2-(# of days) 11.0% wt. MTBE/RFA DCK-3-(# of days) 5.77% wt. ETOH/RFA DCK-4-(# of days) 7.77% wt. ETOH/RFA DCK-5-(# of days) 12.80% wt. TAME/RFA DCK-6-(# of days) 17.30% wt. TAME/RFA DCK-7-(# of days) 12.80% wt. ETBE/RFA DCK-8-(# of days) 17.30% wt. ETBE/RFA DCK-10-(# of days) 10% wt. ETOH/RFA


Spectrum offers standards for analyzers used for determination of trace level oxygenates and impurities in hydrocarbon matrices. We supply a comprehensive range of standards in an n-Hexane matrix at concentrations ranging from 1 – 500 ppm wt. Standards can be supplied either in 2 ml glass ampoules, 0.8 Liter cylinders or mini-inert vials. Component Nominal Component Nominal Concentration Concentration ppm wt. ppm wt. Dimethyl Ether 1.0 n-Butanol 1.0 Acetaldehyde 1.0 iso-Butanol 1.0 Methanol 1.0 iso-Butanal 1.0 Ethanol 1.0 Butyraldehyde 1.0 Propyl Ether 1.0 tert-Ethyl butyl Ether 1.0 Propionaldehyde 1.0 Di-Iso Propyl Ether 1.0 Isopropanol 1.0 tert-Butyl Methyl Ether 1.0 tert-Butanol 1.0 tert-Amyl Ether 1.0 Propanol 1.0 Acetone 1.0 Methyl Ethyl Ketone 1.0 Valderaldehyde 1.0 Diethyl Ether 1.0 n-Hexane Balance Catalog # Product LOW-OX 10 2 ml glass ampoules LOW-OX CYL 0.8 Liter Cylinder

The standards can be custom made to any specified concentration. Components can be added to suit your needs.

ASTM D5441 MTBE Impurity Standard

Standards are supplied in 2 ml flame sealed ampoules under a nitrogen atmosphere at the listed concentrations. tert-Amyl Methyl Ether 0.5 % wt. n-Pentane 0.25% wt. tert-Butanol 0.5 % wt. cis-2-Pentene 0.25% wt. sec-Butyl Methyl Ether 0.25 % wt. trans-2-Pentene 0.25% wt. Methanol 0.5 % wt. Di-Isobutylene 0.5 % wt. n-Heptane 0.5% wt. C12+ as Triisobutylene 0.5 % wt. Iso-Pentane 0.25 % wt. MTBE Balance Catalog # Product MTBE MTBE Impurity Standard (Set of 10)

LOW LEVEL OXYGENATE STANDARDS


In early 1996 we conducted an Inter-Laboratory study on a California Phase II Gasoline. The object of the study was to provide a well analyzed standard for checking calibrations and for use in SQC Programs. A total of 25 refinery laboratories participated and the results were statistically analyzed and the mean reported. The Gasoline is packaged in 25 ml glass ampoules under an argon atmosphere. Average results are tabulated below: ASTM Number Test Results D4052 Density @ 60 F 0.7389 D2622 Sulfur by XRF 31 ppm D5453 Sulfur by Chemiluminescence 28 ppm D1319 Aromatics by FIA 22.2 % LV D1319 Olefins by FIA 5.7 % LV D5769 Total Aromatics by GC/MS 21.60 % LV D5580 Total Aromatics 22.43 % LV D5580 Benzene 0.79 % LV D3606 Benzene 0.80 % LV D5769 Benzene by GC/MS 0.81 % LV D5769 Aromatics by GC/MS 21.81 % LV D5599 MTBE by OFID 11.22 % wt. D4815 MTBE 11.15 % wt. D5191 RVP 6.87 psi Evap. Rec. D86 Distillation IBP - 98.1 98.1 10% - 142.9 145.3 50% - 207.2 209.1 90% - 295.0 300.1 EP - 381.3 380.2

Catalog # Product CALRR1 1 x 25 ml ampoule CALRR2 5 x 25 ml ampoule CALRR3 Set of 10 x 2 ml ampoules CALFIA Set of 10 for FIA D1319

Gasoline Reference Blank

The Gasoline contains less than 10 ppm wt. oxygenates as MTBE. It is packaged in 10x2ml flame sealed ampoules per set. Larger quantities are available in ampoules or bottles. Catalog # Product BLK-GAS Gasoline Reference Blank *We also offer the following sets of Blanks: Catalog # Product ISO-BLANK Nitrogen in Isooctane Blank BLK-DIESEL Diesel Blank BLK-OIL DRACOL 10 Oil Blank BLK-PX P-Xylene Blank BLK-TOL Toluene Blank BLK Reference Blank for ASTM D3606

GASOLINE REFERENCE STANDARDS


Oxygenated Gasoline Standards are packaged in 20 ml ampoules. Use of this Standard determines validation of the Oxygen content of fuels. These Standards can be used with ASTM Methods D4815 and D5599. Each set contains one each of the following Oxygenates or can be supplied in custom configurations. Catalog # Product Set of 5 NIST 577 5.77% wt. Ethanol in RFA Gasoline NIST 128 12.8% wt. TAME in RFA Gasoline NIST 173 17.3% wt. TAME in RFA Gasoline NIST 129 12.8% wt. ETBE in RFA Gasoline NIST 174 17.3% wt. ETBE in RFA Gasoline

Oxygenates in Water

Calibration Sets are available containing Methanol, MTBE, Acetone and tert-Butyl Alcohol in Water at 1, 10, 20, 50, 100, 250 and 500 ppm wt. Calibration Sets can also be custom made to any specification. Catalog # Product OXY-W Seven Point Calibration Set

ASTM D5501 Fuel Ethanol Standards

The increasing use of fuel Ethanol as an Oxygenate Additive in Gasoline has made its composition important to ensure blended fuel complies with Federal and State laws. Our Standards meet the requirements of ASTM D5501. Concentrations below are in mass %:

Components [mass %]

Mix 1 Mix 2 Mix 3 Mix 4 Mix 5

Methanol 0.6 0.5 0.3 0.2 0.1

Ethanol 20.0 50.0 75.0 90.0 99.4

Heptane 10.0 10.0 10.0 4.0 0.5

Hydrocarbon Diluent

69.4 39.5 14.8 5.8 0.0

Catalog # Product ETOH5501CK Fuel Ethanol Check Std. [Specify Mix 1-5] (10x2ml) 5501CAL-5 Fuel Ethanol Calibration Set (5x2ml)

GASOLINE REFERENCE STANDARDS


Infrared Analyzers provide rapid and accurate analysis that can replace the expense and time delay of laboratory analysis. They are used to determine the Gasoline Oxygenate content to ensure product quality and compliance with regulatory authorities. Spectrum offers Calibration Standards for Portable and On-line Infrared Analyzers for the determination of Oxygenates, Benzene and Octane numbers in Gasoline. The standards are either single or multi-component blends of Oxygenates in a Gasoline Matrix and are supplied in 20 ml ampoules.

Infrared Calibration Standards

Catalog # Product (Set of 5) IRQC 1 14.9% wt. MTBE / RFA Gasoline IRQC 2 11.0% wt. MTBE / RFA Gasoline IRQC 3 5.77% wt. ETOH / RFA Gasoline IRQC 4 7.77% wt. ETOH / RFA Gasoline IRQC 5 12.80% wt. TAME / RFA Gasoline IRQC 6 17.30% wt. TAME / RFA Gasoline IRQC 7 12.80% wt. ETBE / RFA Gasoline IRQC 8 17.30% wt. ETBE / RFA Gasoline IRQC10-M 10.0% wt. MTBE / RFA Gasoline IRQC10-E 10.0% wt. ETOH / RFA Gasoline IRQC B Instrument Blank / RFA Gasoline *Concentrations can be reported in either liquid volume or weight %. Benzene and Oxygen contents are also reported.

Octane Check Standards

Standards are packaged in 20 ml ampoules and the RON, MON and (R+M)/2 are reported. Catalog # Product (Set of 5) OCT1 11.0% wt. MTBE / RFA Gasoline OCT2 7.77% wt. ETOH / RFA Gasoline OCT3 RFA Gasoline

Benzene Check Standards

Standards are packaged in 20 ml ampoules and can be custom made to any specification. Catalog # Product (Set of 5) IRQC 12 1.0% LV Benzene, 5% LV Toluene / Isooctane IRQC 13 1.3% LV Benzene / Isooctane IRQC 14 0.8% LV Benzene, 8% LV Ethanol / Isooctane IRQC 15 1.3% LV Benzene, 10% LV Ethanol / Isooctane

CALIBRATION STANDARDS FOR INFRARED ANALYZERS


This mixture for ASTM Methods D6729, D6730, D6733 and D5134, can be used to determine retention times, indices and response factors for components of complex mixtures. Nominal values of each component are listed. Mixtures are supplied in 2 ml flame sealed ampoules under a nitrogen blanket. Weights are reported as percentages and in grams.

PIANO Standard

N-Pentane 2.3% Benzene 2.3% N-Hexane 2.4% Toluene 2.4% N-Heptane 2.4% Ethylbenzene 2.4% N-Octane 2.4% p-Xylene 3.3% N-Nonane 2.4% Propylbenzene 3.3% N-Decane 2.4% Cumene 1.8% N-Undecane 2.4% 3-Ethyltoluene 1.9% N-Dodecane 2.4% 1,2,4 Trimethylbenzene 1.7% 1,3,5 Trimethylbenzene 1.4% Isopentane 1.9% n-Butyl Benzene 2.4% 2-Methyl Pentane 1.7% Iso-Butylbenzene 2.2% 3-Methylpentane 1.7% 1,2,4,5 Tetramethylbenzene 1.2% 2,2 Dimethylpentane 1.6% n-Pentylbenzene 2.4% 2,3 Dimethylpentane 1.8% 2,4 Dimethylpentane 1.8% 1-Pentene 2.2% 2,2,4 Trimethylpentane 2.2% 1-Hexene 2.4% 2,3 Dimethyl-2-Butene 2.4% Cyclohexane 2.4% 1-Heptene 2.0% Methylcyclohexane 2.4% 2,3,3 Trimethyl-1-Butene 1.1% Ethylcyclohexane 2.4% 1-Octene 2.4% Propylcyclohexane 2.4% 2-Methyl-1-Heptene 1.3% N-Butylcyclohexane 2.4% 1-Nonene 2.4% N-Pentylcyclohexane 2.4% 1-Decene 2.4% Decalin 1.9% 1-Undecene 2.4% 1-Dodecene 2.4% Catalog # Product PIANO-1 1 x 1ml PIANO-10 10 x 1ml *This material will be sealed with 1ml of material inside a 2ml ampoule.

PIANO STANDARD


PIANO Paraffins Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Paraffins Standard: Component CAS Number Concentration Wt. % N-Pentane 109-66-0 9.3805 N-Hexane 110-54-3 9.5081 N-Heptane 142-82-5 9.7762 N-Octane 111-65-9 9.5445 N-Nonane 111-84-2 9.0422 N-Decane 124-18-5 9.2452 N-Undecane 1120-21-4 9.3129 N-Dodecane 112-40-3 9.4040 N-Tridecane 629-50-5 8.9068 N-Tetradecane 629-59-4 8.7923 N-Pentadecane 629-62-9 7.0875 Catalog # Product PIANO-P PIANO Paraffins Standard – 0.1ml

*This material will be sealed with 1ml of material inside a 2ml ampoule.

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the

following Methods: D6729, D6730, D6733, and D5134. The following Components and

Concentrations make up the PIANO Paraffins Standard:

Component CAS Number Concentration Wt. %

N-Pentane 109-66-0 9.3805

N-Hexane 110-54-3 9.5081

N-Heptane 142-82-5 9.7762

N-Octane 111-65-9 9.5445

N-Nonane 111-84-2 9.0422

N-Decane 124-18-5 9.2452

N-Undecane 1120-21-4 9.3129

N-Dodecane 112-40-3 9.4040

N-Tridecane 629-50-5 8.9068

N-Tetradecane 629-59-4 8.7923

N-Pentadecane 629-62-9 7.0875

Catalog # Product Price

PIANO-P PIANO Paraffins Standard - 1ml $200

PIANO STANDARDS


PIANO Isoparaffins Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Isoparaffins Standard: Component CAS Number Concentration Wt. % Isopentane 78-78-4 2.1598 2,3-Dimethylbutane 79-29-8 0.4426 2-Methylpentane 107-83-5 3.2231 3-Methylpentane 96-14-0 5.2986 2,2-Dimethylpentane 590-35-2 1.7590 2,4-Dimethylpentane 108-08-7 3.6384 2,2,3-Trimethylbutane 464-06-2 3.8709 3,3-Dimethylpentane 562-49-2 1.8405 2-Methylhexane 591-76-4 2.3337 2,3-Dimethylpentane 565-59-3 1.7623 3-Methylhexane 589-34-4 1.5852 3-Ethylpentane 617-78-7 0.5205 2,2-Dimethylhexane ND 1.2986 2,5-Dimethylhexane 592-13-2 3.6687 2,2,3-Trimethylpentane 564-02-3 1.7026 2,4-Dimethylhexane 589-43-5 1.6285 2,3-Dimethylhexane 584-94-1 1.5967 2-Methylheptane 592-27-8 4.3203 4-Methylheptane 589-53-7 3.1640 3-Methylheptane 589-81-1 5.3850 3-Ethylhexane 589-34-4 0.7031 3,3-Dimethylheptane ND 1.6595 2,5-Dimethylheptane ND 5.5593 3,5-Dimethylheptane ND 0.7489 2,3-Dimethylheptane 3074-71-3 1.4660 3,4-Dimethylheptane ND 3.6314 2-Methyloctane ND 3.7096 3-Methyloctane ND 5.5379 3,3-Diethylpentane ND 1.5530 2,2-Dimethyloctane ND 3.2185 3,3-Dimethyloctane ND 3.1402 2,3-Dimethyloctane ND 3.7968 3-Ethyloctane ND 3.6480 2-Methylnonane 871-83-0 3.6687 3-Methylnonane ND 5.6948 Catalog # Product PIANO-I PIANO Isoparaffins Standard - 0.1ml *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

PIANO STANDARDS


PIANO Aromatics Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Aromatics Standard: Component CAS Number Concentration Wt. % Benzene 71-43-2 7.03127 Toluene 108-88-3 4.5064 EthylBenzene 100-41-4 6.6590 m-Xylene 108-38-3 2.2344 p-Xylene 106-42-3 4.7388 o-Xylene 95-47-6 2.2236 Isopropylbenzene 98-82-8 2.1898 n-Propylbenzene 103-65-1 4.4891 1-Methyl-3-ethylbenzene 620-14-4 2.1676 1-Methyl-4-ethylbenzene 622-96-8 2.1352 1,3,5-Trimethylbenzene 108-67-8 1.1092 1-Methyl-2-ethylbenzene 611-14-3 2.2158 1,2,4-Trimethylbenzene 95-63-6 2.4987 tert-Butylbenzene 98-06-6 4.5264 Isobutylbenzene 538-93-2 4.3482 sec-Butylbenzene 135-98-8 2.2168 1-Methyl-3-isopropylbenzene 535-77-3 1.0917 1-Methyl-4-isopropylbenzene 99-87-6 1.0547 1-Methyl-2-isopropylbenzene 527-84-4 1.1096 1-Methyl-3-n-propylbenzene 1074-43-7 2.0801 1-Methyl-4-n-propylbenzene 1074-55-1 2.1910 n-Butylbenzene 104-51-8 2.1747 1,2-Diethylbenzene 135-01-3 1.0781 1-Methyl-2-n-propylbenzene 1074-17-5 2.2098 1,4-Dimethyl-2-ethylbenzene 1758-88-9 2.2502 1,3-Dimethyl-5-ethylbenzene 934-74-7 2.1652 1,2-Dimethyl-4-ethylbenzene 934-80-5 2.2212 1,3-Dimethyl-2-ethylbenzene 2870-04-4 1.1274 1,2-Dimethyl-3-ethylbenzene 933-98-2 2.1549 1,2,4,5-Tetramethylbenzene 95-93-2 0.2359 2-Methylbutylbenzene ND 1.1258 trans-1-Butyl-1-2-methylbenzene ND 0.7571 n-Pentylbenzene 538-68-1 4.4008 t-1-Butyl-1,3,5-dimethylbenzene ND 2.1295 t-1-butyl-ethylbenzene ND 2.2036 1,3,5-Triethylbenzene 102-25-0 4.4823 1,2,4-Triethylbenzene 877-44-1 1.0960 n-Hexylbenzene 1077-16-3 4.4206

Catalog # Product PIANO-A PIANO Aromatics Standard - 0.1ml *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

PIANO STANDARDS


PIANO STANDARDS

PIANO Naphthalene Standard

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Napthalene Standard:

Component CAS Number Concentration Wt. % Cyclopentane 287-92-3 4.8876 Methylcyclopentane 96-37-7 3.2154 Cyclohexane 110-82-7 5.3106 1,1-Dimethylcyclopentane 1638-26-2 3.4257 cis-1,3-Dimethylcyclopentane 2532-58-3 0.5945 trans-1,2-Dimethylcyclopentane 2452-99-5 1.4437 trans-1,3-Dimethylcyclopentane 2453-00-1 2.7038 Methylcyclohexane 108-87-2 5.6166 Ethylcyclopentane 1640-89-7 3.5158 ctc-1,2,3-Trimethylcyclopentane 19374-46-0 1.5596 cct-1,2,4-Trimethylcyclopentane ND 3.6982 ctc-1,2,4-Trimethylcyclopentane 16883-48-0 1.6450 trans-1,4-Dimethylcyclohexane 27195-67-1 3.4980 1-Ethyl-1-methylcyclopentane ND 1.0582 trans-1,2-Dimethylcyclohexane 27195-67-1 1.6415 ccc-1,2,3-Trimethylcyclopentane 2613-69-6 0.7945 Isopropylcyclopentane 3875-51-2 3.4532 cis-1,2-Dimethylcyclohexane 27195-67-1 3.6636 n-Propylcyclopentane 2040-96-2 3.6166 ccc-1,3,5-Trimethylcyclohexane 1795-27-3 3.4996 1,1,4-Trimethylcyclohexane ND 3.6194 ctt-1,2,4-Trimethylcyclohexane 7667-60-9 3.5740 ctc-1,2,4-Trimethylcyclohexane 7667-59-6 3.4826 1,1,2-Trimethylcyclohexane ND 3.3152 Isobutylcyclopentane 3788-32-7 3.6658 Isopropylcyclohexane 696-29-7 5.6751 n-Butylcyclopentane 2040-95-1 3.6624 Isobutylcyclohexane 1678-98-4 5.5462 t-1-Methyl-2-propylcyclohexane ND 3.8141 t-1-Methyl-2-(4MP)cyclopentane ND 3.7326 Catalog # Product PIANO-N PIANO Napthalene Standard - 0.1ml *This material will be sealed with 0.1ml of material inside a 2ml ampoule.


PIANO STANDARDS

The following PIANO Standards can be used for Detailed Hydrocarbon Analysis and for the following Methods: D6729, D6730, D6733, and D5134. The following Components and Concentrations make up the PIANO Olefins Standard: Component CAS Number Concentration Wt.% 3-Methyl-1-butene 563-45-1 1.9608% 1-Pentene 109-67-1 4.0999% 2-Methyl-1-butene 563-46-2 1.4268% 2-Methyl-1, 3-butadiene 78-79-5 2.4036% trans-2-Pentene 646-04-8 1.7990% cis-2-Pentene 627-20-3 1.9683% 4-Methylpentene-1 691-37-2 3.3837% 1-Hexene 592-41-6 6.9484% trans-2-Hexene 4050-45-7 1.7285% 2-Methylpentene-2 625-27-4 3.3104% cis-2-Hexene 7688-21-3 3.8552% 1-Heptene 592-76-7 7.4930% trans-3-Heptene ND 3.6247% cis-3-Heptene ND 5.7577% trans-2-Heptene ND 3.6684% cis-2-Heptene ND 5.6638% 1-Octene 111-66-0 7.5936% trans-2-Octene ND 1.9463% cis-2-Octene 7642-04-8 3.8744% 1-Nonene 124-11-8 7.5680% trans-3-Nonene ND 1.8292% cis-3-Nonene ND 3.9639% trans-2-Nonene ND 1.8292% cis-2-Nonene ND 2.7013% 1-Decene 872-05-9 8.0821% Catalog # Product PIANO-O PIANO Olefins Standard - 0.1ml *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

PIANO Olefins Standard


1-Butene 2.6% Methanol 2.7% 1-Pentene 2.5% Ethanol 2.7% 1-Hexene 2.7% tert-Butyl Methyl Ether 2.7% 1-Heptene 2.7% tert-Amyl Methyl Ether 2.7% 1-Octene 2.7% tert-Butanol 2.7% 1-Nonene 2.7% tert-Butyl Ethyl Ether 2.7% 1-Decene 2.7% 1-Undecene 2.7% Cyclopentane 2.8% 1-Dodecene 2.7% Cyclohexane 2.7% Methylcyclohexane 2.7% N-Propane 0.5% Ethylcyclohexane 2.7% N-Butane 2.5% Propylcyclohexane 2.7% N-Pentane 2.7% n-Butylcyclohexane 2.7% N-Hexane 2.7% N-Heptane 2.7% Benzene 2.7% N-Octane 2.7% Toluene 2.8% N-Nonane 2.7% Ethylbenzene 2.7% N-Decane 2.7% Propylbenzene 2.7% N-Undecane 2.7% N-Butylbenzene 2.7% N-Dodecane 2.7% N-Pentylbenzene 2.7% Catalog # Product PONA-1 1 x 1 ml ampoule PONA-10 10 x 1 ml ampoules PONA-7 *Call for more information – Pricing upon request*

All 5 of the PIANO Standards, the PIANO-P, PIANO-I, PIANO-A, PIANO-N and PIANO-O can be combined as well in the following ways. *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

Combined PIANO Standards

Catalog # Product PIANO-5 All 5 PIANO Standards combined into 0.1 ml In addition, all 5 individual PIANO Standards can be combined with the PIANO-5 Standard: Catalog # Product PIANO-5-SET The PIANO-5 Combined Standard with 5 Individual PIANO Stds

PONA STANDARD

This mixture can be used to determine retention times, indices and response factors for components of complex mixtures. Nominal values of each component are listed. Mixtures are supplied in 1 ml flame sealed ampoules under a Nitrogen blanket. Weights are reported as percentages and in grams.

PIANO STANDARDS


ASTM D3710 Calibration Mix – Volume / Volume

Spectrum offers Standards covering the Boiling Range Distribution of Gasoline and Gasoline components. Calibration mixes are either in weight / weight or volume / volume. 2-Methylbutane 10.5% p-Xylene 14.0% N-Pentane 8.1% n-Propylbenzene 4.7% 2-Methylpentane 5.8% n-Decane 3.5% N-Hexane 5.8% n-Butylbenzene 3.5% 2,4-Dimethylpentane 5.8% n-Dodecane 3.5% N-Heptane 10.5% n-Tridecane 2.3% Toluene 11.6% n-Tetradecane 2.3% N-Octane 5.8% n-Pentadecane 2.3% Catalog # Product Set of 10 x 1 ml 3710-1 ASTM D3710 Calibration Set

ASTM D6352 Calibration Mixture

Spectrum offers Standards covering the Boiling Range Distribution of Petroleum Distillate Fractions. They are applicable to fractions having an initial boiling point greater than 174 C to a final boiling point of less than 700 C. Calibration Mixes are Polywax 655 or 1000 dissolved in Carbon Disulfide at a concentration of 1 part to 200 parts. Lower Boiling Point n-Paraffins (nominally C10 to C40) are added. The Calibration Mixture covers the range of n-Paraffins from C10 to C100. Catalog # Product 6352REF Reference Oil per 4 oz bottle #can also be used as reference for D7169

ASTM 7169 Calibration Mixture

Catalog # Product POLY655/1000 Polywax 655/1000 per 1.1 ml

SIMDIS ANALYSIS


High Temperature SIMDIS

This Standard can be used to estimate the amount of engine oil volatilized at 371 C in accordance with ASTM D6417. Standards are packaged in 2 ml ampoules, concentrations are weight / weight. N-Octane 0.042% Eicosane 0.043% N-Nonane 0.042% N-Tricosane 0.043% N-Decane 0.043% N-Octacosane 0.042% N-Undecane 0.043% N-Dotriacontane 0.043% N-Dodecane 0.042% N-Tetratriacontane 0.042% N-Tridecane 0.043% N-Hexatriacontane 0.043% N-Tetradecane 0.042% N-Tetracontane 0.041% N-Pentadecane 0.042% N-Tetratetracontane 0.022% N-Hexadecane 0.043% N-Pentacontane 0.022% N-Heptadecane 0.043% N-Dopentacontane 0.020% N-Octadecane 0.042% N-Hexacontane 0.021% N-Nonadecane 0.043% In Carbon Disulfide / Cyclohexane Catalog # Product Set of 10 x 1 ml 6417-1 ASTM D6417 Calibration Set

Quantitative Alkylate Reference Sample

The Standard is a well characterized sample of an actual refinery Alkylation Stream. It can be used to determine retention times, indices and monitor response factors of complex hydrocarbon mixtures. The Standard includes a data sheet listing individual components by weight %, mole % and liquid volume %; retention times and indices for each component; composition by carbon; a calculated boiling point and octane report. A summary of the group types is listed below: GROUP TYPE % Weight % Volume %Mole Aromatics 1.85 1.47 1.51 I-Paraffins 90.23 90.04 87.07 Napthalenes 0.68 0.60 0.59 Olefins 0.013 0.013 0.014 Paraffin 5.02 6.02 9.16 Oxygenates 0.0 0.0 0.0 Unidentified 2.22 1.86 1.65 Catalog # Product 10 x 1 ml ALK-1 Alkylate Reference Standard

SIMDIS ANALYSIS


ASTM D2887 Calibration Mix – Weight/Weight

n-Hexane 6.0% n-Octadecane 5.0% n-Heptane 6.0% n-Eicosane 2.0% n-Octane 8.0% n-Tetracosane 2.0% n-Nonane 8.0% n-Octacosane 1.0% n-Decane 12.0% n-Dotriacontane 1.0% n-Undecane 12.0% n-Hexatriacontane 1.0% n-Dodecane 12.0% n-Tetracontane 1.0% n-Tetradecane 12.0% n-Tetrateteracontane 1.0% n-Hexadecane 10.0% Catalog # Product Set of 10 x 1 ml 2887-1 ASTM D2887 Calibration Set C6-C44

n-Pentane 4.03% n-Hexadecane 8.92% n-Hexane 4.94% Eicosane 1.99% n-Heptane 4.93% n-Tetracosane 1.96% n-Octane 7.87% n-Octacosane 0.998% n-Nonane 8.14% n-Dotriacontane 1.01% n-Decane 11.90% n-Hexatricontane 0.969% n-Undecane 11.88% n-Tetracontane 0.979% n-Dodecane 11.88% n-Tetratetracontane 0.983% n-Tetradecane 11.91% n-Octadecane 3.93% Other Impurities 0.80% Catalog # Product Set of 10 x 1 ml 2887-1P ASTM D2887 Calibration Set C5-C44 n-Pentane 5.22% n-Octadecane 3.99% n-Hexane 4.97% n-Tetracosane 0.981% n-Heptane 5.96% n-Octacosane 0.990% n-Octane 7.89% n-Dotriacontane 0.989% n-Nonane 8.05% n-Hexatricontane 0.970% n-Decane 11.88% n-Tetracontane 0.982% n-Undecane 11.75% n-Tetratetracontane 0.979% n-Dodecane 11.89% n-Pentacontane 0.492% n-Tetradecane 11.82% n-Hexacontane 0.491% n-Hexadecane 7.88% Eicosane 1.05% Other Impurities 0.78% Catalog # Product Set of 10 x 1 ml 2887-EXT-1 ASTM D2887 Calibration Set - Extended

SIMDIS ANALYSIS


REFERENCE GAS OIL

Reference Gas Oil for ASTM D2887

Spectrum now offers Reference Gas Oil for D2887 from Global Reference Standards. Reference Gas Oil #2 Lot #1 has been approved by ASTM and is now available for purchase. Catalog # Product per bottle GRS-RGO-QT REFERENCE GAS OIL #2 LOT #1 MADE BY GRS - QT GRS-RGO2-2 REFERENCE GAS OIL #2 LOT #1 MADE BY GRS - 2 OZ

BENZENE PURITY STANDARD

Spectrum offers two Standards meeting ASTM D5713 and D4492 requirements. Calibration mixtures have the appropriate internal standard added and are also available without internal standard.

ASTM D5713 Calibration Mix – Weight / Weight

Iso-Pentane 100 ppm cis 1,3 Dimethylcyclopentane 100 ppm N-Pentane 100 ppm trans 1,3 Dimethylcyclopentane 100 ppm 2,2 Dimethylbutane 100 ppm Heptane 200 ppm Cyclopentane 100 ppm Methylcyclohexane 100 ppm 2,3 Dimethylbutane 100 ppm Ethylcyclopentane 50 ppm 2 Methylpentane 200 ppm 2,4 Dimethylhexane 100 ppm 3 Methylpentane 200 ppm 1,2,3 Trimethylcyclopentane 50 ppm n-Hexane 300 ppm 2,3,4 Trimethylpentane 50 ppm 2,2 Dimethylpentane 100 ppm Methylcyclopentane 200 ppm Toluene 50 ppm 2,4 Dimethylpentane 100 ppm Ethylbenzene 100 ppm 2,2,3 Trimethylbutane 100 ppm p-Xylene 100 ppm 3,3 Dimethylpentane 50 ppm m-Xylene 100 ppm Cyclohexane 100 ppm Cumene 100 ppm 2-Methylhexane 100 ppm o-Xylene 100 ppm 2,3 Dimethylpentane 100 ppm Benzene Balance 1,1 Dimethylcyclopentane 100 ppm 3 Methylhexane 100 ppm Internal Standard - n-Octane 10,000 ppm wt. Catalog # Product per 1 ml 5713-WISTD D5713 Calibration with Internal Standard 5713-noISTD D5713 Calibration without Internal Standard


ASTM D4492 Calibration Mix – Weight / Weight

The Calibration Mixture has the same composition as the D5713 Mixture; however, n-Nonane has been added as the Internal Standard at 1000 ppm wt. Catalog # Product per 1 ml 4492-WISTD D4492 Calibration with Internal Standard 4492-noISTD D4492 Calibration without Internal Standard *This material will be sealed with 0.1ml of material inside a 2ml ampoule.

BENZENE STANDARDS – ASTM D3606

The EPA has identified Benzene as a major pollutant in Reformulated Gasoline and has designated ASTM Method D3606 for its determination. We offer a set of Calibration Standards meeting all ASTM requirements and are composed of seven individual standards in an Isooctane Matrix. The Standards are packaged in 2ml ampoules and are available with either MEK, 2-Butanol or DME as the Internal Standard. The Standards are NIST Traceable by weight.

ASTM D3606 Calibration Set

Std # Benzene % LV Toluene % LV Internal Standard 1 5.0 20 +4%LV 2 2.5 15 +4%LV 3 1.25 10 +4%LV 4 0.65 5 +4%LV 5 0.33 2.5 +4%LV 6 0.12 1.0 +4%LV 7 0.06 0.5 +4%LV Calibration Standards with the following Internal Standards are available: Catalog # Product Internal Standard 3606M Calibration Set +4% LV MEK 3606B Calibration Set +4% LV 2-Butanol 3606D Calibration Set +4% LV DME 3606N Calibration Set No Internal Standard Additionally, as Ethanol elutes with Benzene, we offer a Calibration Set containing Ethanol. Catalog # Product Internal Standard 3606EM10 Calibration Set - 10% Ethanol +4% LV MEK 3606EB10 Calibration Set – 10% Ethanol +4% LV 2-Butanol 3606EB6 Calibration Set – 6% Ethanol +4% LV 2-Butanol 3606EN5 Calibration Set – 5.77% Ethanol No Internal Standard 3606EN7 Calibration Set – 7.77% Ethanol No Internal Standard 3606EN10 Calibration Set – 10.0% Ethanol No Internal Standard

BENZENE PURITY STANDARD


D3606 Check Standards

Accuracy of the Calibration can be monitored daily by the use of Check Standards. We offer the following mixtures: Catalog # Benzene Toluene Ethanol Internal Std. Set of 10 3606DBE-(#of days) 1.0 5.0 10.0 +4% 2-Butanol 3606D2B-(#of days) 0.50 3.0 ------- +4% 2-Butanol 3606D3B-(#of days) 1.0 5.0 ------- +4% 2-Butanol 3606DME-(#of days) 1.0 5.0 10.0 +4% MEK 3606D5M-(#of days) 1.0 5.0 ------- +4% MEK 3606D6M-(#of days) 0.50 3.0 ------- +4% MEK 3606DM-(#of days) 1.0 5.0 ------- +4% DME 3606DN-(#of days) 1.0 5.0 ------- No Internal Std. *We also offer Check Standards in 30, 60, 90 and 180 day supplies at the following prices: Product D3606 Daily Check Standard – 60 day set D3606 Daily Check Standard – 180 day set *Custom Calibration Standard sets and Check Standards are available. Call for details.

AROMATIC STANDARDS

ASTM D5769 Quality Control Reference Material

Check Standards are available with or without Deuterated Internal Standard mixtures. All concentrations are in weight %. Hexane -12% Toluene -9% Heptane -17% 1,3 Dimethylbenzene -3% Octane -17% 1,2 Dimethylbenzene -3% Decane -12% Ethylbenzene -3% Dodecane -5% 1,2,4 – Trimethylbenzene -3% Isooctane -12% 1,2,4,5 – Trimethylbenzene -2% Benzene -1% Naphthalene -1% Catalog # Product AR1000 Quality Control Reference Material - 3 component – with ISTD [10x2ml] AR3000 Quality Control Reference Material - no Internal Std. [5x10ml] AR4000 Quality Control Reference Material – 4 component – with ISTD [10x2ml]

BENZENE STANDARDS – ASTM D3606


ASTM D5769 Aromatics in Finished Gasolines

Multi-component Calibration Standards are available for the current version of this Method with or without the 3-Component Deuterated Internal Standard mixture. The Internal Standard mixture is in the ratio Benzene-d6 – 2ml, Ethylbenzene-d10 – 2ml and Naphthalene-d8 – 1 gram. The Standards have the following nominal compositions:

Component Std 1 Std 2 Std 3 Std 4 Std 5 Std 6 Wt% Wt% Wt% Wt% Wt% Wt%

Benzene 5.2 4.2 2.9 1.6 0.8 0.40 Toluene 19.6 16.0 11.0 6.0 3.0 1.60 Ethylbenzene 5.2 4.0 2.9 1.6 0.8 0.40 m-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 p-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 o-Xylene 6.3 5.0 3.5 1.9 0.9 0.40 Isopropylbenzene 3.0 2.5 1.7 0.9 0.5 0.40 n-Propylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 3-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 4-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,3,5-Trimethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 2-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,2,4-Trimethylbenzene 5.2 4.0 2.9 1.6 0.8 0.25 1,2,3-Trimethylbenzene 3.2 2.5 1.8 1.0 0.5 0.40 Indan 3.5 2.7 1.9 1.0 0.5 0.25 1,4-Diethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 n-Butylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 1,2-Diethylbenzene 3.0 2.5 1.8 0.9 0.5 0.25 1,2,4,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.25 1,2,3,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.15 Naphthalene 2.5 2.0 1.3 0.7 0.4 0.15 1-Methylnaphthalene 2.5 2.0 1.3 0.7 0.4 0.2 2-Methylnaphthalene 2.4 2.0 1.4 0.7 0.4 0.2 Isooctane Balance

The 3-Component Internal Standard mixture – [Benzene-d6, Ethylbenzene-d10 and Naphthalene-d8] is added to the Calibration Standards in the ratio of 5 parts Internal Standard mixture to 100 parts weight Calibration Standard. Catalog # Product 5769CAL-3ISTD Calibration Set with 3 Internal Standards (6x1ml) 5769CAL-5noISTD Calibration Set without Internal Standard (6x5ml) 5769CAL-10noISTD Calibration Set without Internal Standard (6x10ml)

AROMATIC STANDARDS


ASTM D5769 Aromatics in Finished Gasolines

Multi-Component Calibration Standards are available for the current version of this Method with the 4-Component Deuterated Internal Standard Mixture. The Internal Standard mixture is in the ratio Benzene-d6 - 2ml, Ethylbenzene-d10 - 2ml, Naphthalene-d8 – 1 gram and Toluene-d8 – 7ml. The Standards have the following nominal compositions:

Component Std 1 Std 2 Std 3 Std 4 Std 5 Std 6 Wt% Wt% Wt% Wt% Wt% Wt%

Benzene 5.2 4.2 2.9 1.6 0.8 0.40 Toluene 19.6 16.0 11.0 6.0 3.0 1.60 Ethylbenzene 5.2 4.0 2.9 1.6 0.8 0.40 m-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 p-Xylene 6.2 5.0 3.5 1.9 0.9 0.40 o-Xylene 6.3 5.0 3.5 1.9 0.9 0.40 Isopropylbenzene 3.0 2.5 1.7 0.9 0.5 0.40 n-Propylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 3-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 4-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,3,5-Trimethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 2-Ethyltoluene 3.0 2.5 1.7 0.9 0.5 0.25 1,2,4-Trimethylbenzene 5.2 4.0 2.9 1.6 0.8 0.25 1,2,3-Trimethylbenzene 3.2 2.5 1.8 1.0 0.5 0.40 Indan 3.5 2.7 1.9 1.0 0.5 0.25 1,4-Diethylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 n-Butylbenzene 3.0 2.5 1.7 0.9 0.5 0.25 1,2-Diethylbenzene 3.0 2.5 1.8 0.9 0.5 0.25 1,2,4,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.25 1,2,3,5-Tetramethylbenzene 2.0 1.7 1.2 0.6 0.3 0.15 Naphthalene 2.5 2.0 1.3 0.7 0.4 0.15 1-Methylnaphthalene 2.5 2.0 1.3 0.7 0.4 0.2 2-Methylnaphthalene 2.4 2.0 1.4 0.7 0.4 0.2 Isooctane Balance

The 4-Component Internal Standard mixture, [Benzene-d6, Ethylbenzene-d10, Toluene-d8 and Naphthalene-d8] is added to the Calibration Standards in the ratio of 12 parts Internal Standard mixture to 100 parts weight Calibration Standard. Catalog # Product 5769CAL-4ISTD Calibration Set with 4 Internal Standards (6x1ml) 5769CAL-5noISTD Calibration Set without Internal Standard (6x5ml) 5769CAL-10noISTD Calibration Set without Internal Standard (6x10ml)

AROMATIC STANDARDS


ASTM D5769 Internal Standards for GC/MS

Internal Standards are available containing Deuterated Ethylbenzene-d10, Naphthalene-d8 and Benzene-d6 as specified in the ASTM Method for the determination of Benzene, Toluene and Total Aromatics in Finished Gasoline by GC/MS. The Internal Standard, used for the sample preparation, is packaged in 5ml flame sealed ampoules and has the following composition:

Benzene-d6 2ml Ethylbenzene-d10 2ml

Naphthalene-d8 1 gram

Catalog # Product 5769INT-1 Internal Standard 1x5ml ampoules 5769INT-5 Internal Standard 5x5ml ampoules The Internal Standard can also be custom packaged to your specifications.

ASTM D5769 Internal Standards for GC/MS with Toluene d8

Internal Standard containing Deuterated Ethylbenzene-d10, Naphthalene-d8, Benzene-d6 and Toluene-d8 as specified in the ASTM Method. The Internal Standard used for the sample preparation is packaged in 10ml flame sealed ampoules and has the following composition:

Benzene-d6 2ml Ethylbenzene-d10 2ml

Naphthalene-d8 1 gram Toluene-d8 7ml

Catalog # Product 5769INT-T-1 Internal Standard including Toluene-d8 1x10ml ampoule 5769INT-T-5 Internal Standard including Toluene-d8 5x10ml ampoules The Internal Standard can also be custom packaged to your specifications.

AROMATIC STANDARDS


ASTM D6550 Olefins in Gasoline by SFC

The Method Covers the determination of the total Olefin content of Gasolines by Super-Critical Chromatography (SFC). The application range is 1 to 25% weight total Olefins. We offer two sets of Standards; one is a set of Synthetic Olefins mixtures and the other a set of Gasoline Standards analyzed by consensus analysis. The following Standards are available packaged in 2 ml flame sealed ampoules. Catalog # Product 6550CAL-S Calibration Set 1.0, 3.5, 6.0, 8.5, 12.0 % wt. 6550CAL-H Calibration Set 12.0, 17.0, 25.0 % wt. 6550CAL-X Calibration Set 1.0, 3.5, 6.0, 8.5, 12.0, 17.0, 25.0 % wt. 6550CK Check Standard 4.0% wt. Total Olefins [set of 10] The Olefin Standards are made in a Matrix of 75% wt. Isooctane and 25% wt. Toluene [75/25 ISO/TOL]. Catalog # Product 6550REF Reference Check Standard 10.0% wt. Total Olefins The Reference Standards are made in a Gasoline Matrix and analyzed by consensus analysis. Standards can also be made to your specifications.

OLEFINS STANDARDS


The Air Resources Board of California requires Finished Gasoline to be tested for Total Aromatics using ASTM Method D5580. This Method covers the determination of Benzene, Toluene, Ethylbenzene, Xylenes, C9 and heavier Aromatics, and Total Aromatics. The Internal Standard is 2-Hexanone. The Standards conform to ASTM D5580 and are NIST traceable by weight. We offer a Multi-Component Calibration Standard, Selectivity, Valve Timing and a Daily Check Standard with the following composition.

ASTM D5580 Aromatic Calibration Set

Nominal Liquid Volume % Std # Benzene Toluene Ethylbenzene O-Xylene 1,2,4-TMB 2-Hexanone Isooctane

1 0.10 15.0 0.50 5.0 0.50 10.0 Balance 2 0.50 5.0 1.0 1.0 10.0 10.0 Balance 3 1.0 10.0 2.5 2.5 2.5 10.0 Balance 4 2.0 2.5 5.0 10.0 1.0 10.0 Balance 5 5.0 1.0 10.0 0.50 5.0 10.0 Balance Daily Ck 1.0 10.0 4.0 4.0 4.0 10.0 Balance Valve Ck 5.0 5.0 5.0 5.0 5.0 10.0 Balance Catalog # Product 5580CAL Calibration set includes Selectivity and Valve Timing 5580CAL-E Calibration set includes Ethanol 5580CAL-Px Calibration set includes 0.5 – 10% LV p-Xylene 5580CAL-N Calibration set without Internal Standard – 20ml ampoules 5580DCK Daily Check Standard Set of 10 5580DCK-60 Daily Check Standard 60 day set 5580DCK-D Daily Check Standard includes Dodecane 5580SEL Selectivity Standard Set of 10 5580VT Valve Timing Standard Set of 10

ASTM D1319 Aromatics and Olefins by FIA

Difficulties with the precision and accuracy of this important test have led to the introduction of a Standard providing a baseline for comparison when used on a regular basis. The Standards are supplied in 2ml ampoules and have the following composition:

Toluene 30% LV 1-Hexene 10% LV Isooctane Balance

Catalog # Product FIA 1000 FIA Daily Check Standard 10x2ml ampoules CALFIA California Phase II Gasoline 10x2ml ampoules FIA1000-CY FIA 1000 Standard in 800 CC Cylinder

AROMATIC STANDARDS


ASTM D5186 Aromatics in Diesel and Aviation Fuels

The analysis of Motor Diesel and Aviation Fuels by Supercritical Fluid Chromatography (ASTM D5186) requires the use of a performance mixture. We supply two such mixtures meeting high and low specifications. The mixtures are supplied in 2ml flame sealed ampoules under a Nitrogen atmosphere.

ASTM D5186 Performance Mixture

Component % Weight (HIGH) % Weight (LOW) Tetralin 3.0 1.0 Naphthalene 2.0 1.0 Toluene 20.0 8.0 Hexadecane 75.0 90.0

Catalog # Product Set of 10 5186-10 Low Concentration 5186-25 High Concentration

ASTM D5186 Calibration Set

An Inter-Laboratory study was conducted using Diesel Fuel. A total of 11 Refinery and Independent Laboratories analyzed the Standards for both Total Aromatics and Poly-Nuclear Aromatics and the results were statistically analyzed. The standards are packaged in 2ml glass ampoules under a Nitrogen atmosphere. The means are tabulated below:

LOW RANGE

Standard # Total Aromatics Poly-Nuclear Aromatics 1 2.06 % wt 0.23 % wt 2 5.64 % wt 0.89 % wt 3 11.0 % wt 2.06 % wt 4 14.6 % wt 2.50 % wt 5 21.6 % wt 4.31 % wt

HIGH RANGE

Standard # Total Aromatics Poly-Nuclear Aromatics 1 14.6 % wt 2.50 % wt 2 21.6 % wt 4.44 % wt 3 26.6 % wt 6.00 % wt 4 32.6 % wt 7.50 % wt 5 38.6 % wt 11.8 % wt

Catalog # Product / per set 5186CAL HI 5186 Calibration Set – Hi Range 5186CAL LO 5186 Calibration Set – Lo Range

AROMATIC STANDARDS


Aromatic Standards for UOP Methods

The following standards for UOP Methods for Trace Impurities in Aromatic Hydrocarbons and are packaged in 2 ml flame sealed ampoules:

UOP 720 Impurities in High Purity P-Xylene

UOP 744 Aromatics in Hydrocarbons

The Standard contains n-Heptane, Benzene, Toluene, Mixed Xylene, 1-Methyl-2-Ethylbenzene and 1,2,3,4,-Tetramethylbenzene at concentrations 10 – 25 % wt. Catalog # Product Set of 10 UOP744 Aromatics in Hydrocarbons

UOP 931 Impurities in Mixed Xylenes

UOP 831 Hydrocarbons in Sulfolane

The Standard contains Benzene, Toluene, Ethylbenzene, Cumene and n-Nonane in a Sulfolane Matrix at concentrations of 10 ppm wt. Catalog # Product Set of 10 UOP831 Hydrocarbons in Sulfolane

UOP 551 Hexanes in Olefin-Free Gasoline

The Standard contains Benzene, Toluene, 1-Methyl-2-Ethylbenzene, n-Undecane in an n-Heptane Matrix at concentrations of 2 % wt. Catalog # Product Set of 10 UOP931 Mixed Xylenes Impurity Standard

The Standard contains n-Hexane, Benzene, Toluene, Ethylbenzene, o-Xylene, m-Xylene, p-Xylene at concentrations of approximately 14% wt. Catalog # Product Set of 10 UOP551 Hexanes in Gasoline

AROMATIC STANDARDS

The Standards contain o-Xylene, m-Xylene, Ethylbenzene, n-Undecane (ISTD) at concentrations of 0.1 % wt in a p-Xylene Matrix. Catalog # Product Set of 10 UOP720 Xylene Impurity Standard


Aromatic Standards for UOP Methods

UOP 798 Trace p-Diethylbenzene in C8 Aromatics

The Standard contains p-Diethylbenzene and Indane in a p-Xylene Matrix at a concentration of 5 ppm wt. Catalog # Product Set 10 UOP798 Trace p-Diethylbenzene

UOP 690 Octanes in Olefin-Free Gasoline

The Standard contains n-Octane, Benzene, Toluene, Ethylbenzene, o-Xylene, m-Xylene and p-Xylene at concentrations of approximately 14% wt. Catalog # Product Set of 10 UOP690 Octanes in Gasoline

UOP 868 Trace Saturates in High Purity Aromatics

The Standard contains Cyclohexane, n-Hexane, Methylcyclohexane, N-Heptane, Ethylcyclohexane, n-Octane, Propylcyclohexane, n-Nonane, Butylcyclohexane, n-Decane in a Toluene Matrix at a concentration of 500 ppm wt. Catalog # Product Set of 10 UOP868 Saturates in Gasoline

UOP 880 Distillate Reformer and Reformate Standards

Catalog # Product ______ UOP880-RFRMR Reformer Standard - 10 x 2 ml ampoules UOP880-RFRMR-4 Reformer Standard – 4 oz. bottle UOP880-RFRMT Reformate Standard – 10 x 2 ml UOP880-RFRMT-4 Reformate Standard – 4 oz. bottle

AROMATIC STANDARDS


UOP 621 Non-Aromatic Hydrocarbons in High-Purity Aromatics by Gas Chromatography


The Standard contains Pentane; N-Hexane; Heptane; Methylcyclohexane; N-Octane; Ethylcyclohexane; Nonane; Indan; N-Decane; Benzene; Toluene; P-xylene and Cumene in a concentration ranging from 0.3 %WT to 18.848 %WT.

Catalog # Product Set of 10 UOP 870 Carbon Distribution of Paraffins/Naphthenes Aromatics Std

Catalog # Product Set of 10 UOP 621 Boiling Point of Hydrocarbons Standard

The Standard contains: Pentane; N-Hexane; Heptane; N-Octane; Nonane; N-Decane; Undecane; Dodecane; Tridecane; Tetradecane; Pentadecane; Hexadecane; Heptadecane; Octadecane; Nonadecane and Eicosane in a concentration of approximately 6 % WT.

The Standard contains N-Dodecane in a Toluene Matrix.

Catalog # Product Set of 10 UOP543-RF Non-Aromatic Hydrocarbons Response Factor Standard

UOP 543 Non-Aromatic Hydrocarbons Response Factor Standard


The Standard contains Undecane, Benzene and Toluene in a P-xylene matrix, in a concentration of approximately 100 PPM and packaged in 2ml flame sealed ampoules. Catalog # Product Set of 10 UOP543-IMP Non-Aromatic Hydrocarbon Standard

NON-AROMATIC HYDROCARBON STANDARDS


ASTM D7371 Biodiesel Standards

ASTM D7371 is used to determine the biodiesel content in Diesel fuel by Furrier Transfer Infrared (FTIR). We offer the following Calibration Standards and Daily Check Standards, packaged in 5ml ampoules.

D7371 Low Calibration Set A D7371 Low Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-Low 10.00 DCCF-Low 0.25 DCCF-Low 12.50 DCCF-Low 0.50 DCCF-Low 15.00 DCCF-Low 1.00 DCCF-Low 17.50 DCCF-Low 2.50 DCCF-Low 20.00 DCCF-Low 5.00 DCCF-Low 25.00 DCCF-Low 7.50 DCCF-Low 30.00 DCCF-Low 10.00 DCCF-Low

Set A, Mixtures 1-8 Set B, Mixtures 8-14

Catalog # Product 7371CAL-L-A D7371 Low Calibration Standard – Set A [0.00-10.00] – 5ml ampoules 7371CAL-L-B D7371 Low Calibration Standard – Set B [10.00-30.00] – 5ml ampoules

D7371 Low Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-Low 50.00 DCCF-Low 70.00 DCCF-Low 80.00 DCCF-Low 90.00 DCCF-Low 95.00 DCCF-Low 97.00 DCCF-Low 99.00 DCCF-Low 99.80 DCCF-Low

Set C, Mixtures 14-22

Catalog # Product 7371CAL-L-C D7371 Low Calibration Standard – Set C [30.00-99.80] – 5ml ampoules 7371DCK-L D7371 Daily Check Standard – Low [*Biodiesel / Solvent] – 10x5ml set 7371DCK-H D7371 Daily Check Standard – High [*Biodiesel / Solvent] – 10x5ml set 7371DCK-UH D7371 Daily Check Standard – Ultra High [*Biodiesel/Solvent] -10x5ml set *Upon ordering our Daily Check Standards, customer must specify the Biodiesel % and Solvent required.

BIODIESEL STANDARDS



BIODIESEL STANDARDS


D7371 High Calibration Set A D7371 High Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-High 10.00 DCCF-High 0.25 DCCF-High 12.50 DCCF-High 0.50 DCCF-High 15.00 DCCF-High 1.00 DCCF-High 17.50 DCCF-High 2.50 DCCF-High 20.00 DCCF-High 5.00 DCCF-High 25.00 DCCF-High 7.50 DCCF-High 30.00 DCCF-High 10.00 DCCF-High


Catalog # Product 7371CAL-H-A D7371 High Calibration Standard – Set A [0.00-10.00] – 5ml ampoules 7371CAL-H-B D7371 High Calibration Standard – Set B [10.00-30.00] – 5ml ampoules

D7371 High Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-High 50.00 DCCF-High 70.00 DCCF-High 80.00 DCCF-High 90.00 DCCF-High 95.00 DCCF-High 97.00 DCCF-High 99.00 DCCF-High 99.80 DCCF-High

Set C, Mixtures 36-44 Catalog # Product 7371CAL-H-C D7371 High Calibration Standard – Set C [30.00-99.80] – 5ml ampoules



IP585 Calibration Standards

Catalog # Product IP585 IP585 Calibration Standard [2, 4, 6, 8, 10, 20, 40, 60, 80, 100 mg/kg + d33] IP585CAL IP585 Calibration Standard [Up to 5 concentrations][*Background] *Please specify the concentrations and background upon ordering this product.

BIODIESEL STANDARDS


D7371 Ultra High Calibration Set A D7371 Ultra High Calibration Set B

Biodiesel [vol%] Solvent Biodiesel [vol%] Solvent 0.00 DCCF-Ultra High 10.00 DCCF-Ultra High 0.25 DCCF-Ultra High 12.50 DCCF-Ultra High 0.50 DCCF-Ultra High 15.00 DCCF-Ultra High 1.00 DCCF-Ultra High 17.50 DCCF-Ultra High 2.50 DCCF-Ultra High 20.00 DCCF-Ultra High 5.00 DCCF-Ultra High 25.00 DCCF-Ultra High 7.50 DCCF-Ultra High 30.00 DCCF-Ultra High 10.00 DCCF-Ultra High


Catalog # Product 7371CAL-UH-A D7371 Ultra High Calibration Standard – Set A [0.00-10.00] – 5ml ampoules 7371CAL-UH-B D7371 Ultra High Calibration Standard – Set B [10.00-30.00]– 5ml ampoules

D7371 Ultra High Calibration Set C

Biodiesel [vol%] Solvent 30.00 DCCF-Ultra High 50.00 DCCF-Ultra High 70.00 DCCF-Ultra High 80.00 DCCF-Ultra High 90.00 DCCF-Ultra High 95.00 DCCF-Ultra High 97.00 DCCF-Ultra High 99.00 DCCF-Ultra High 99.80 DCCF-Ultra High

Set C, Mixtures 36-44

Catalog # Product 7371CAL-H-C D7371 Ultra High Calibration Standard – Set C [30.00-99.80] – 5ml ampoules


Calibration Standards conforming to ASTM D5453 and ASTM D4629 are available in several ranges in an Isooctane or Toluene Matrix. A Check Standard is also available to verify the calibration on a routine basis. All Standards are NIST traceable by weight.

ASTM D5453 Total Sulfur by UV Fluorescence

ASTM Method D5453 is the determination of Sulfur in Liquid Petroleum Hydrocarbons by Ultraviolet Fluorescence. In accordance with the Method, 3 ranges of Calibration Standards are offered in either a Toluene or an Isooctane Matrix and are packaged in 2 ml ampoules. Catalog # Product 5453R1 Calibration Set [1, 2.5, 5, 7.5, 10 ng/ul] 5453R2 Calibration Set [5, 25, 50, 100, 200 ng/ul] 5453R3 Calibration Set [100, 250, 500, 750, 1000 ng/ul] 5453X3 Calibration Set including all 3 Ranges 5453DCK D5453 Daily Check Standard (Specify Concentration) (set of 10)

ASTM D3120, D3246 and D3961 Sulfur by Oxidative Microcoulometry

ASTM D4045 & D6313 Sulfur by Rateometric Colorimetry

NITROGEN AND SULFUR STANDARDS

These Methods use Oxidative Microcoulometry to determine Sulfur. Calibration and Check Standards are available using n-Dibutyl Sulfide in Isooctane. Catalog # Product 3120CAL Calibration Set 1, 10, 25, 50, 100 ppm wt. 3246CAL Calibration Set 1, 10, 25, 50, 100 ppm wt. 3961CAL Calibration Set 1, 10, 25, 50, 100 ppm wt.

The Method is used to determine Sulfur in the range 0.1 to 10 ppm wt in Hydrocarbons by Hydrogenolysis and Rateometric Colorimetry. Standards are prepared using n-Dibutyl Sulfide in an Isooctane Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product 4045CAL Calibration Set 0.1, 0.5, 1, 2.5, 5.0, 10 ppm wt per set 4045DCK Daily Check Standard (Specify Concentration) set of 10 6313CAL Calibration Set 0.1, 0.5, 1, 2.5, 5.0, 10 ppm wt per set 6313DCK Daily Check Standard (Specify Concentration) set of 10


ASTM D1552 Sulfur by High Temperature Combustion

This Method is used to determine Total Sulfur in Petroleum products including Lubricating Oils. Standards are made with Di-butyl Sulfide in a Mineral Oil Matrix in concentrations from 0.06 to 10% wt Sulfur and packaged in 100 ml bottles. Catalog # Product 1552DCK [Specify Concentration]

ASTM D6428 Sulfur by Combustion and Electrochemical Detection

ASTM D6069 Trace Nitrogen by Combustion and Electrochemical Detection

This Method covers the determination of Total Nitrogen in Liquid Hydrocarbons and related chemicals. Standards are made with either Pyridine in an Isooctane Matrix or Carbazole in a Toluene Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product 6069R1 Calibration Set 0.1, 0.5, 1, 2.5, 5, 10 ppm wt 6069R2 Calibration Set 10, 25, 50, 75, 100 ppm wt 6069DCK Daily Check Standard (Specify Concentration) /set of 10


This Method covers the determination of Total Sulfur in Liquid Hydrocarbons and related chemicals. Standards are made with either n-Dibutyl Sulfide or Benzothiophene in an Isooctane Matrix and packaged in 2ml flame sealed ampoules. Catalog # Product 6428R1 Calibration Set 0.1, 0.5, 1, 2.5, 5, 10 ppm wt 6428R2 Calibration Set 10, 25, 50, 75, 100 ppm wt 6428DCK Daily Check Standard (Specify Concentration) /set of 10


ASTM D4629 Trace Nitrogen by Chemiluminescence

ASTM D5762 Trace Nitrogen by Chemiluminescence

This Method is used to determine Nitrogen in products with higher boiling points. Standards are made with Acridine as the Nitrogen species in a Toluene Matrix and are packaged in 2ml ampoules with a shelf life of approximately 3 months. Catalog # Product 5762CAL Calibration Set 1, 5, 10, 50, 100 ng/uL 5762DCK Daily Check Standard (Specify Concentration) /set of 10

Sulfur and Nitrogen Standards


ASTM Method D4629 is the determination of Trace Nitrogen in Liquid Petroleum Hydrocarbons by Chemiluminescence detection. Calibration sets and Check Standards are made with Pyridine as the Nitrogen species and are available in a Toluene or Isooctane Matrix. All Standards are sealed in 2ml ampoules under a Helium Headspace. Catalog # Product 4629CAL Calibration Set 1, 2, 10, 20, 50, 100, 200, 500, 1000 4629DCK Calibration Check Standard (Specify Concentration) /set of 10 Standards can also be custom made in Matrices similar to the compound to be analyzed.

Calibration and Check Standards are also available for the calibration of instruments configured for the simultaneous determination of Nitrogen and Sulfur. Catalog # Product SNCAL Calibration Set [5 Concentrations + Blank][Background] SNCK Daily Check Standard [Concentration][Background] set of 10 *Please specify which concentrations for Sulfur and Nitrogen are needed, as well as the background matrix upon ordering.


ASTM D2622 Sulfur by X-Ray Fluorescence

ASTM D4294 Sulfur by Energy Dispersive Spectrometry

SULFUR BY X-RAY SPECTROMETRY

Calibration Standards are available for ASTM D2622-08 [2008 Method] covering a Total Sulfur content of 0.0010 to 5% wt in a White Oil Matrix or Isooctane/Toluene 75/25 mixture plus 10% ETOH. They are offered in three ranges and are packaged in 30ml amber bottles. D2622 Standards using Poly Sulfides are available upon request. Range 1 (0-1000 mg/kg) Range 2 (0.10 – 1.00 mass%) Range 3 (1.0 – 5.0 mass%) 0.0 0.100 1.0 5 0.250 2.0 10 0.500 3.0 100 1.000 4.0 250 5.0 500 750 1000

Catalog # Product 2622R1 D2622 Range 1 Calibration Set – 30ml Bottles 2622R2 D2622 Range 2 Calibration Set – 30ml Bottles 2622R3 D2622 Range 3 Calibration Set – 30ml Bottles 2622X3 D2622 Calibration in all 3 Ranges – 30ml Bottles 2622DCK-L D2622 Daily Check Standard [*Concentration] – Liter *Please specify the concentration needed upon ordering our daily check standards.

Calibration Standards for ASTM D4294-08 [2008 Method] are available in three ranges from 0 to 5% wt Sulfur in a Mineral Oil, Isooctane or Diesel Fuel Matrix and packaged in 30ml amber bottles. D4294 Standards using Poly Sulfides are available upon request. Range 1 (0-1000 mg/kg) Range 2 (0.10 – 1.00 mass%) Range 3 (1.0 – 5.0 mass%) 0.0 0.100 1.0 5 0.250 2.0 10 0.500 3.0 100 1.000 4.0 250 5.0 500 750 1000 Catalog # Product 4294R1 D4294 Range 1 Calibration Set – 30ml Bottles 4294R2 D4294 Range 2 Calibration Set – 30ml Bottles 4294X3 D4294 Calibration in all 3 Ranges – 30 ml bottles 4294DCK-L D4294 Daily Check Standard [*Concentration] - Liter *Please specify the concentration needed upon ordering our daily check standards.


EPA ULSD Qualification Set

Calibration Standards for D5453 in Diesel Fuel packaged in 2ml ampoules: Catalog # Sulfur Concentration ppm wt Set: 5453RD D5453 Custom Range Calibration Set [4.0, 8.0, 12.0, 16.0, 20.0 PPM 5453R3D D5453 Range 3 Calibration Set [0, 100, 200, 300, 400, 500, 600 PPM] 5453DCK-D D5453 Daily Check [Concentration][Background] - 10X2ml

Calibration Standards for ASTM D7039 in Diesel Fuel packaged in 10ml ampoules:

Catalog # Product (ppm wt) Set: 7039CAL-LO D7039 Low Range Calibration Set [0, 2, 5, 10, 15, 20, 25 PPM Wt] 7039CAL-H D7039 High Range Calibration Set [5 High Concentrations + Blank] 7039CAL-BIO D7039 Calibration Set in Biodiesel [0, 2, 5, 10, 15, 20, 25 PPM] 7039CAL-XOS D7039 XOS Calibration Set [0-500 PPM] in Diesel – 6 x 10ml 7039DCK D7039 Daily Check [Concentration] in Diesel Fuel - 10 x 10ml The Standards above may be packaged in varying quantities upon request. Please specify the concentrations or background matrices upon ordering, when applicable.

Sulfur Standards in Diesel Fuel

We have Standards meeting the requirements set forth in EPA Method 80.580 to 80.585. The EPA requires a series of standards to be run consecutively over a period of 20 days, using the same instrument, in order to qualify each instrument. The results are then submitted to the EPA for approval.

1. All sample sets are supplied in 10 ml glass ampoules; 2. 20 samples of Diesel Fuel with a Sulfur content between 5-15 ppm wt Sulfur; 3. 20 samples of Diesel Fuel with a Sulfur content between 200-500 ppm wt Sulfur; 4. 10 samples of a Gravimetric Standard in the range 1-10 ppm wt Sulfur; 5. 10 samples of a Gravimetric Standard in the range 10-20 ppm wt Sulfur; 6. 10 samples of a Gravimetric Standard in the range 100-200 ppm wt Sulfur; 7. 10 samples of a Gravimetric Standard in the range of 400-500 ppm wt Sulfur; 8. All samples are in Diesel Fuel;

Catalog # Product EPA PB EPA ULSD Qualification Set [Contains: High, Low, Accuracy and Precision] - 80x10ml EPAPB-S EPA Short (Low) Set [Contains: 5-15ppm Precision, 1-10, 1-20ppm Accuracy] -40x10ml

SULFUR STANDARDS


ASTM D5623 Sulfur Compounds by Selective Detection

Standards for this Method are available either as Multi-Component Mixtures or as Individual Components in a Base Fuel. According to ASTM D5623, an Internal Standard – Bromothiophene, is added. Component Sulfur ppm wt As Compound ppm wt Methanethiol 100 151 Ethanethiol 100 194 Dimethylsulfide 100 194 2-Propanethiol 100 238 T-Butanethiol 100 282 1-Propanethiol 100 237 Thiophene 100 263 Diethylsulfide 100 289 1-Butanethiol 100 282 Diethyl Disulfide 100 193 Thiophenol 100 345 Benzothiophene 100 423 Bromothiophene (Internal) 100 512 Diphenyl Sulfide 100 588 *Base Fuel Balance Balance

*The Base Fuel is a mixture of 40% LV Isooctane, 40% LV Hexanes and 20% LV Toluene.

All Standards are packaged in 2 ml ampoules under a Nitrogen atmosphere and are NIST traceable by weight. The concentrations above are also available packaged individually in 2 ml ampoules in the same base fuel at 1000 ppm wt or any specified concentration needed. Catalog # Product MSX-14 Multi-Component Standard at 100 ppm wt Sulfur – 10x2ml MSX-14-1 Multi-Component Standard at 100 ppm wt Sulfur – 1x2ml MSX-1 Single Component Standard at 1000 ppm wt Sulfur – 10x2ml MSX-1-1 Single Component Standard at 1000 ppm wt Sulfur – 1x2ml Additionally, Standards can be made to any specified concentration using varying combinations of Sulfur species or solvents.

SULFUR STANDARDS



UOP 163 ASTM D3227 Determination of Mercaptan Sulfur in Hydrocarbons

This Standard contains 22 Sulfur species in a Base Fuel matrix and packaged in 2ml ampoules.

Component as Compound ppm wt

2-Methyl 1 Propanethiol T-Butylsulfide 2-Methylthiophene 1-Heptanethiol 3-Methylthiophene 1,4 Butanedithiol 1,2 Ethane Dithiol Methyl Ethyl Sulfide 1-Pentanethiol Propyl Disulfide 2-Ethylthiophene 1-Octanethiol Propylsulfide Benzothiophene T-Butyldisulfide 1-Hexanethiol 1,5 Pentanedithiol Carbon Disulfide 1-Nonanethiol Methyl Sulfide 1-Decanethiol Propanethiol

*Base Fuel is 40% LV Isooctane, 40% LV Hexane and 20% LV Toluene

Catalog # Product MSX-22 Multi-Component Standard at 50 ppm wt as component – 10x2ml MSX-22-1 Multi-Component Standard at 50 ppm wt as component – 1x2ml Additionally, Standards can be made to any specified concentration using varying combinations of Sulfur species or solvents.

Standards are prepared in a mixture of Isooctane and Toluene to determine inflection points during the Potentiometric Titration of Mercaptan Sulfur in Hydrocarbon liquids. The Standards are prepared with Tert-Nonyl Mercaptan. They are packaged in 20ml flame sealed ampoules and offered in various concentrations, please specify at the time of order which concentration you require. Please call for pricing and availability. Catalog # Product UOP-163-(concentration) Tert-Nonyl Mercaptan as Sulfur [6 x 20ml]* *Pricing per concentration specified at time of order.

SULFUR STANDARDS


SULFUR STANDARDS

This Standard is a 41 Component 100 ppm Sulfur Standard in a Base Fuel Matrix. They are packaged in 2ml ampoules and are NIST Traceable by weight.

GRAVIMETRIC UNCERTAINTY +/- 2% COMPONENT PPM WT COMPOUND 2-Methyl-1-Propanethiol 101 2-Methyl Thiophene 99.5 3-Methyl Thiophene 101 1,2 Ethane Dithiol 99.5 1-Pentanethiol 100 2-Ethyl Thiophene 100 Propyl Sulfide 100 1,5 Pentanethiol 100 1-Nonanethiol 100 1-Decanethiol 100 Propanethiol 99.6 T-Butyl Sulfide 100 1-Heptanethiol 99.8 1,4 Butanethiol 102 Methyl Ethyl Sulfide 100 Propyl Disulfide 100 1-Octanethiol 100 T-Butyl Disulfide 99.6 Benzothiophene 101 1-Hexanethiol 99.9 Carbon Disulfide 105 Methyl Sulfide 101 Ethyl Sulfide 100 Thiophene 99.2 N-Butanethiol 99.8 Tetrahydrothiophene 99.8 Ethyl Disulfide 101 Thiophenol 100 Methanethiol 95.9 2-Methyl-1-Butanethiol 100 3-Methyl-1-Butanethiol 100 Ethyl Mercaptan 102 2-Propanethiol 100 2-Propyl Thiophene 101 2-Butyl Thiophene 100 3-Butyl Thiophene 101 Bromothiophene 104 Methylbenzothiophene 100 Phenyl Sulfide 100 T-Butyl Methyl Sulfide 100 T-Butanethiol 100 *Base Fuel *40% LV Isooctane, 40% LV Hexane, 20% LV Toluene Catalog # Product MSX-41 Multi-Component Standard at 100 ppm wt Sulfur – 10x2ml MSX-41-1 Multi-Component Standard at 100 ppm – 1 x 2ml



Mercaptan Sulfur Standards

Additional Sulfur compounds are available as Single Components packaged in 2ml ampoules at any specified concentration, up to 1% weight as the compound. They can also be packaged as Multi-Component mixtures. 2-Methyl-1-Propane Thiol Tert-Butyl Sulfide 2-Methyl Thiophene 1-Heptane Thiol 3-Methyl Thiophene 1,4 Butane Thiol 1,2 Ethane Dithiol Methyl Ethyl Sulfide 1-Pentane Thiol Propyl Disulfide 2-Ethyl Thiophene 1-Octane Thiol Propyl Sulfide Tert-Butyl Disulfide 1,5 Pentane Thiol Benzothiophene 1-Nonane Thiol Hexane Thiol 1-Decane Thiol Carbon Disulfide Propane Thiol Methyl Sulfide

All Standards are made in a mixture of 40% LV Isooctane, 40% LV Hexanes and 20% LV Toluene. Please specify concentration upon ordering.

Catalog # Product MSX-1-C Single Component [As Component] – 10x2ml MSX1-1-C Single Component [As Component] – 1x2ml MSX-M Multi-Component Custom Standard

Thiophene Sulfur Standards Standards are prepared in an Isooctane / Hexane mixture, are packaged in 2 ml flame sealed ampoules and have the following composition: Component ppm wt Sulfur ppm wt Compound 2-Methylthiophene 100 309 3-Methylthiophene 100 303 Dibenzothiophene 100 574 Tetrahydrothiophene 100 272 Thiophene 100 263 Benzothiophene 100 418 *Base Fuel Balance *Base Fuel consists of 70% wt Isooctane / 30% wt n-Hexane.

Catalog # Product MSX-THIO Thiophene Sulfur Standard [Specify Concentration/Background] [10 x 2ml]

SULFUR STANDARDS


ASTM D4929 (B) Organic Chloride in Crude Oil

Standards are made for ASTM Method D4929 (B) for the determination of chloride in Crude Oil. The Standards are made with Chlorobenzene in an Isooctane Matrix and packaged in 2ml ampoules. Catalog # Product 4929CAL Calibration Set 1, 5, 10, 25, 50, 100 ppm wt 4929DCK Daily Check Standard [specify concentration] [10 x 2ml]

ASTM D5808 Organic Chloride in Hydrocarbons

Standards are available for the determination of Organic Chloride in Hydrocarbons and related chemicals. They are made with 2,4,6 Trichlorophenol in a Methanol matrix and packaged 2ml ampoules. Catalog # Product 5808CAL Calibration Set 1, 5, 10, 15, 25 ppm wt 5808DCK Daily Check Standard [specify concentration] [10 x 2ml]

Organo Fluorine Standards

Standards are made in an Isooctane Matrix using the listed compounds. Three Point Calibration Sets covering the ranges 0, 1, 3, 5 mg F/L and 10, 50, 100 mg F/L are available. Catalog # Compound Set FC-1 Trichloro-trifluoroethane FP-1 1-Fluoropentane FB-2 1-Fluorobenzene FH-1 1-Fluorohexane FT-1 1-Fluorotoluene Calibration Check Standards are available and can be made to your specifications.

ORGANIC CHLORIDE STANDARDS


Chlorine in Mineral Oil

Chlorine and Sulfur in Mineral Oil

The Standards contain Chlorine as Chlorobenzene and Sulfur as Di-butyl Sulfide in a Mineral Oil Matrix. Two ranges of Calibration sets are available in addition to a Check Standard. The Standards are packaged in 30ml amber bottles. Range 1 Range 2 Sulfur Chlorine Sulfur Chlorine 0.10% 1.00% 0.100% 5.0% wt 0.20% 0.30% 0.500% 2.5% wt 0.30% 0.60% 1.00% 1.00% wt 0.50% 0.40% 2.50% 0.500% wt 0.70% 0.20% 5.00% 0.100% wt 1.00% 0.0 BLANK BLANK Catalog # Product Set OCS-R1 Range 1 Sulfur Chlorine Calibration Set OCS-R2 Range 2 Sulfur Chlorine Calibration Set OCS-CK Sulfur Chlorine Check Standard [specify concentration] [Liter]

Calibration Standards for the determination of Organic Chloride in Mineral Oil and related Hydrocarbons are available in two ranges from 0 to 0.10% wt and 0 to 5.0 % wt Chloride in a Mineral Oil Matrix. Chlorobenzene is used as the Chloride species and the standards are packaged in 30ml bottles. Range 1 Range 2 0.0020 % 0.100% 0.0050 % 0.500% 0.010 % 1.00 % 0.030 % 2.50 % 0.060 % 5.00 % 0.100 % BLANK BLANK

Catalog # Product Set OCR1 Range 1 Chloride Calibration Set OCR2 Range 2 Chloride Calibration Set OCR-CK Chlorine Check Standard [specify concentration] [Liter] *We also have the following Chloride Check and Calibration Standards available:

Catalog # Product Set XOS-CL-M Chloride Calibration for XOS [0-500 PPM] in Mineral Oil [7x10ml] XOS-CL-H2O Chloride Calibration for XOS [0-500 PPM] in Water [7x10ml] CLDCK Chloride Daily Check Standard [Specify Concentration/Background] [10x10ml]

ORGANIC CHLORIDE STANDARDS


ASTM D2386 Freezing Point Standards

ASTM D97 Pour Point Standards

Pour Points are determined by consensus analysis. Standards are packaged in 250 ml bottles. Catalog # Pour Point Approximate Value PP5 -5 C PP10 -10 C PP15 -15 C PP20 -20 C PP40 -40 C PP50 -50 C

ASTM D2500 Cloud Point Standards

Cloud Points are determined by consensus analysis. Standards are packaged in 250 ml bottles. Catalog # Cloud Point Approximate Value CP5 +5 C CP2 -2 C CP10 -10 C CP15 -15 C CP20 -20 C

ASTM D6371 / IP309 Cold Filter Plug Point Standards

Standards are available for the Cold Filter Plug Point Test; verified by consensus analysis and packaged in 250 ml bottles. Catalog # Cold Filter Plug Point Temperature CFPP1 -18 C CFPP2 -33 C CFPP3 -46 C

PHYSICAL TESTING STANDARDS

Standards are packaged in 250 ml amber bottles and verified by consensus analysis. Catalog # Nominal Freezing Point FPZ 50 -50 C FPZ 45 -45 C


ASTM D5949 Pour Point Standards for Phase

Standards are packaged in 250ml bottles and verified by consensus analysis. Catalog # Pour Point Approximate Value PP67-PH 67.6 C PP17-PH 17.6 C

ASTM D5773 Cloud Point Standards for Phase

ASTM D5972 Freeze Point Standards for Phase

Standards are packaged in 250ml bottles and verified by consensus analysis. Catalog # Freeze Point Approximate Value FPZ51-PH 51.4 C FPZ4-PH 4.9 C

ASTM D93 Pensky-Martens Flash Point

Standards are packaged in 250 ml amber glass bottles and verified by consensus analysis. Catalog # Nominal Flash Point FP60 60 C FP60-20 60 C [5x20ml] FP75 75 C FP75-20 75 C [5x20ml] FP93 93 C FP93-20 93 C [5x20ml]

Standards are packaged in 250ml bottles and verified by consensus analysis. Catalog # Cloud Point Approximate Value CP55-PH 55.1 C CP15-PH 15.2 C



ASTM D92 Cleveland Open Cup Flash Point

ASTM D56 Tag Closed Cup Flash Point

Standards are packaged in 250 ml amber glass bottles and verified by consensus analysis. Catalog # Nominal Flash Point TCC40 42 C TCC40-20 42 C [5x20ml] TCC55 55 C TCC55-20 55 C [5x20ml] TCC60 60 C TCC60-20 60 C [5x20ml] TCC68 67 C TCC68-20 67 C [5x20ml]

IP33 / IP170 Abel Flash Point

Standards are packaged in 250 ml amber glass bottles and verified by consensus analysis. Catalog # Nominal Flash Point AB40 41 C

Standards are packaged in 250 ml amber glass bottles and verified by consensus analysis. Catalog # Nominal Flash Point FP200 200 C FP200-20 200 C [5x20ml] FP230 230 C FP230-20 230 C [5x20ml]



Certified Flash Point Standards

ASTM D445 Viscosity Standards

Oils are tested in accordance with ASTM D445 and are packaged in 500 ml amber bottles. Nominal Viscosity Catalog # Viscosity @ 40 C VIS4 4 Cst VIS7 7 Cst VIS20 19 Cst VIS60 61 Cst VIS180 180 Cst VIS520 520 Cst

These Reference Materials are stable, pure Hydrocarbon, with a Method Specific Flash Point determined by an Inter-Laboratory study. Standards are packaged in 250 ml bottles. Catalog # Nominal Flash Point ASTM # FP53ND 54 C PMCC D93 FP65UD 70 C PMCC D93 FP110TD 110 C PMCC D93 FP134HEX 134 C PMCC D93 FP115TD 116 C COC D92 FP138HEX 140 C COC D92 FP51ND 50 C TCC D56 FP67UD 67 C TCC D56


ASTM D5188 Vapor-Liquid Ratio-Temperature

Performance Check samples for ASTM D5188 are supplied in 20 ml flame sealed ampoules for the daily monitoring of instrument performance. Catalog # V/L Temp Set of 5 VL1 36.1 C (96.9 F) VL2 68.7 C (155.7 F)


ASTM D5482 / D5191 Vapor Pressure Standards

Determination of Silicon as Siloxanes in Hydrocarbons

Silicon compounds are a source of catalyst contamination and their identification and quantification is important for processing control. We offer the following standards in an Isooctane Matrix, packaged in 2 ml ampoules. Standard Hexamethyl- Octamethyl- Decamethyl- Total cyclotris iloxane cyclotetrasiloxane cyclopentasiloxane S ilicon / ppm wt 1 0.100 0.100 0.100 0.300 2 0.300 0.100 0.100 0.600 3 1.00 0.300 0.300 1.6 4 5.00 2.0 2.00 9.0 5 10.0 4.0 2.00 16.0 Catalog # Product SIL-CAL Silicon Calibration Set 0.3 – 16 ppm wt SIL-CK Silicon Check Standard [Specify Concentration]

Spectrum offers a range of Vapor Pressure Quality Control samples for ASTM D5482 and D5191 (mini-methods), consisting of pure solvents of known vapor pressure. The samples are packaged in 10ml flame sealed ampoules. Catalog # Standard # Vapor Pressure Set of 10 VP1 1 (9.77 p.s.i.) [CYCLOPENTANE] VP2 2 (10.75 p.s.i.) [2,2-DIMETHYLBUTANE] VP3 3 (4.28 p.s.i.) [2,3-DIMETHYLBUTANE] VP4 4 (6.77 p.s.i.) [2-METHYLPENTANE] VP5 5 (3.26 p.s.i.) [CYCLOHEXANE] VP6 6 (1.03 p.s.i.) [TOLUENE] VP7 7 (16.36 psi) [N-PENTANE] Spectrum now manufactures a D5191 44/56 Mixture to replace the dwindling supply of Neo-Hexane: Catalog # Description 5191-20 D5191 STANDARD [44/56] - 5X20ML AMPOULES 5191-L D5191 STANDARD [44/56] – LITER BOTTLE 5191-5G D5191 STANDARD [44/56] – 5 GALLONS 5191-54G D5191 STANDARD [44/56] – 54 GALLON DRUM



The Standards are used for the determination of dye Solvent Red 164 in commercially available Diesel Fuels using Visible Spectroscopy. The Standards are made with Solvent Red 26, which is available in a Certified Pure form; against which, the Solvent Red 164 is measured. They are packaged in 100ml amber bottles in a Kerosene Matrix with the following concentrations: Catalog # Red Dye 26 Concentration, mg/L 6258CAL 0, 3, 6, 9, 12, 15 6258CK Check Standard [Specify Concentration]

ASTM D6045 Color by the Automatic Tristimulus Method

The Method covers the Automatic Determination of the color of a wide range of petroleum products and correlates to test Methods ASTM D156 and D1500. Two sets of Color Standards are available for the respective Methods and can be used either to calibrate an instrument, or check an existing calibration. The following standards are packaged in 100 ml amber bottles. Saybolt Color ASTM Color +30 1 +25 3 +19 5 +15 7 +12 0 -15 Catalog # Product Set SAYBOLT [Specify Color]-4 Saybolt Color Standard in 4 oz bottle SAYBOLT [Specify Color]-8 Saybolt Color Standard in 8 oz bottle 6045 SAY-125 Saybolt Color Set of 4 x 125ml bottles 6045 SAY-100 Saybolt Color Set of 7 x 100ml bottles 6045ASTM-100 ASTM Color Set of 4 x 100ml bottles 6045ASTM-16 ASTM Color Set of 4 x 500ml bottles ASTM-[Specify Color]-4 ASTM Color Standard in 4 oz bottle ASTM-[Specify Color]-8 ASTM Color Standard in 8 oz bottle

Platinum Cobalt Standard

ASTM D6258 Solvent Red 164 Dye Concentration in Diesel Fuel

Catalog # Product Set 848-03SET Platinum Cobalt Color Standard – 15 x 100 ml bottles

COLOR STANDARDS


ASTM D86 Synthetic Distillation Standard

The automatic distillation apparatus duplicates the distillation conditions of the manual method. The increased reliance on electronic control requires an independent standard to verify the apparatus is performing correctly. Spectrum has introduced a synthetic blend of Hydrocarbons that boil in the temperature range specified in ASTM D86 Distillation Groups 1 & 2 and ASTM D850. D86 Groups 1 & 2 cover the boiling range 129 F to 368 F (54-187C) and are verified by consensus analysis with twelve refinery laboratories.

DISTILLATION RANGE IBP 129F 10% 180 F 50% 228 F 90% 319 F EP 368 F

Catalog # Product D86-1 Synthetic Distillation Standard 0.5 L D86-2 Synthetic Distillation Standard 1.0 L D86-3 Synthetic Distillation Standard 4 x 1 L bottles

ASTM D86 Group 4 Distillation Standard

The Group 4 Standard is a Diesel Fuel with a Distillation Range from 379 F to 700 F (193-371 C) and verified by consensus analysis.

DISTILLATION RANGE IBP 379 F 10% 439 F 50% 525 F 90% 639 F EP 700 F

Catalog # Product D86-4-1 Group 4 Distillation Standard 0.25 L D86-4-2 Group 4 Distillation Standard 0.50 L

The automatic distillation apparatus duplicates the distillation conditions of the manual method. The increased

reliance on electronic control requires an independent standard to verify the apparatus is performing correctly.

Spectrum has introduced a synthetic blend of Hydrocarbons that boil in the temperature range specified in ASTM

D86 Distillation Groups 1 and 2 and ASTM D850. Groups 1 and 2 cover the boiling range 129 F to 368 F (54 to 187 C)

and verified by consensus analysis with twelve refinery laboratories.

DISTILLATION RANGE

IBP 129 F

10% 180 F

50% 228 F

90% 319 F

EP 368 F

Catalog # Product Price

D86-1 Synthetic Distillation Standard 0.5 L $145

D86-2 Synthetic Distillation Standard 1.0 L $250

D86-3 Synthetic Distillation Standard 4 x 1 L $950

DISTILLATION STANDARDS


D3230 Salt in Crude Mixed Salts Solution (Diluted)

D3230 Salt in Crude Calibration Standard (Diluted) – Mix 1-15 in Liter bottles Catalog # Product 3230CAL-QT D3230 Calibration Std. [DILUTED] - MIX -1-15 –Liter bottles

D3230 Salt in Crude Standard (Concentrated)

D3230 Salt in Crude Daily Check Standard (Concentrated, not diluted) - 10:20:70 Chlorides, 63:37 tr. H2O - 1-Butanol and MEOH packaged in 16 oz bottle. Catalog # Product 3230DCK-16 D3230 Salt in Crude Daily Check Standard – 16 oz bottle

D3230 SALT IN CRUDE STANDARDS

ASTM D850 Distillation Standard

DISTILLATION STANDARDS

This Method covers the Distillation of Aromatic Hydrocarbons with relatively narrow boiling ranges. The Standard is Toluene ‘spiked’ with a small amount of Xylenes to create a boiling range of 1.0 C. Samples were analyzed by consensus analysis.

DISTILLATION RANGE IBP -110.3 50% Pt. -110.6 Dry Pt. -111.4

Catalog # Product D850-4-1 ASTM D850 Distillation Standard 0.25 L D850-4-2 ASTM D850 Distillation Standard 0.50 L


ASTM D611 Aniline Point Standards

The accuracy of Automated Aniline Point Apparatus can be verified using a range of Standards whose Aniline Points are determined using ASTM D611 (Method A). Standards are packaged in 20ml ampoules in an inert atmosphere. Standard Nominal Aniline Point 1 0 C 2 30 C 3 55 C 4 68 C 5 94 C Calibration Standards for the Automatic Aniline Point Apparatus, Method D611 (E), are available in the following ranges and packaged in 20ml ampoules. Standard Nominal Aniline Point 1 43 C 2 62 C 3 77 C Catalog # Product AP611 Aniline Point Verification Set (5 Standards) AP611E Calibration Set, 3 Points for Method 611 (E)

ASTM D611 Pure Aniline

For routine purposes, pure Aniline can be packaged in ampoules under Dry Nitrogen. This minimizes the risk on contamination by moisture. Under these conditions, the Aniline will remain unchanged for period exceeding six months. Catalog # Product Set of 5 ANP 15ml of pure Aniline in ampoules *There is 15ml of material in a 20ml ampoule for the item listed above.

ANILINE POINT STANDARDS

D3230 SALT IN CRUDE MIXED SALTS SOLUTION (DILUTE)


ASTM D6304 Water by Karl Fischer

Standards are available for Coulometric Karl Fischer Titrations and are packaged in 5 ml ampoules in sets of 10. The following concentrations are available: Catalog # Product Set of 10 KF40-4 5ml ampoules, water content 40 ug/gram KF60-4 5ml ampoules, water content 60/ug/gram KF100-4 5ml ampoules, water content 100 ug/gram KF500-4 5ml ampoules, water content 500 ug/gram KF1000-4 5ml ampoules, water content 1000 ug/gram KF5000-4 5ml ampoules, water content 5000 ug/gram Standards are also available for Volumetric Karl Fischer Determinations, packaged in 20ml ampoules in sets of 5. The following concentrations are available: Catalog # Product Set of 5 KF100-20 20ml ampoules, water content 100 ug/gram KF1000-20 20ml ampoules, water content 1000 ug/gram KF5000-20 20ml ampoules, water content 5000 ug/gram Water Standards can be custom made to any specified concentration and packaged in 2, 5, 10 or 20 ml ampoules. Please call us for details.

WATER STANDARDS


Wear Metal Standards

Spectrum offers a range of Organo-Metallic Calibration Standards for the analysis of Metals in Oils. The Standards are Sulfur-free and are stabilized with a Proprietary Chelating Agent. Standards include both single and multi-element mixtures designed for use with specific ASTM Methods, such as ASTM D5708, D4927 and D5863 using Plasma Emission (ICP or DCP), Atomic Absorption (AAS), or Wavelength Dispersive X-ray Fluorescence Spectrometry. Stock Standards are listed below, custom single and multi-element Standards in Mineral Oil, Deodorized Kerosene, or Xylene are also available. Please let us know your specifications. The WM-12 Series contain the following elements: Ag, Al, Cr, Cu, Fe, Mg, Na, Ni, Pb, si, Sn, and Ti. Catalog # Concentration per 100mls per 200mls WM12-10 10 ppm WM12-30 30 ppm WM12-50 50 ppm WM12-100 100 ppm WM12-300 300 ppm WM12-500 500 ppm The WM-21 Series contain the following elements: Ag, Al, B, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, P, Pb, Si, Sn, Ti, V and Zn. Catalog # Concentration per 100mls per 200 mls WM21-10 10 ppm WM21-30 3 ppm WM21-50 50 ppm WM21-100 100 ppm WM21-300 300 ppm WM21-500 500 ppm Concentrated Standards of the elements above are available and are stabilized with Chelating Agents.

ORGANO METALLIC STANDARDS


ASTM D5059 Lead in Gasoline

ASTM D3237 Lead in Gasoline

Standards are available to cover the range 0.010 to 0.10 grams of Lead / U.S. Gallon. Working Standards can be prepared from these solutions and are available in 100 ml bottles. Catalog # Concentration, Pb grams / U.S . Gallon 100mls 3237-02 0.02 3237-05 0.05 3237-10 0.10 3237X3 Set of 3 above concentrations

Phosphorus in Gasoline by X-Ray Spectrometry

Matrix Oils and Stabilizer Solutions

Standards are available for Method A. The Standards are prepared in a Toluene, Isooctane or Gasoline matrix and are packaged in 100ml amber bottles. The Bismuth Internal Standard is available separately and is prepared in Mixed Xylenes. Catalog # Concentration, Pb grams / U.S . Gallon 5059-A D5059 Standard [0.10, 1.0, 2.0, 3.0, 4.0, 5.0] [Specify Background] – 100ml bottles set 5059-ISTD D5059 Standard with Internal [0.793 g Bi / L] – 100ml bottle each

Calibration and Daily Check Standards are available for the proposed ASTM Method for Phosphorus in Gasoline in an 80% LV Isooctane / 20% LV Toluene matrix and packaged in 20ml ampoules. Catalog # Product P-CAL Phosphorus in Gasoline 5 point Calibration set [1, 3, 5, 10, 25 PPM] – 20ml ampoules P-DCK Phosphorus in Gasoline Daily Check Standard [Specify Concentration] 5x20ml

Catalog # Product / per Liter S20 Mineral Oil – 20 Cst S75 Mineral Oil – 75 Cst LS-D Diesel Fuel < 1 ppm Sulfur

ORGANO METALLIC STANDARDS


Underground Fuel Spills (UST)

Standards are prepared in 2 ml flame sealed ampoules and can be made to any specified composition and concentration.

BTEX / MTBE Mixture

200 ug/ml and 2000 ug/ml of each component in Methanol: Benzene Toluene Ethylbenzene o-Xylene Methyl Tertiary Butyl Ether m-Xylene p-Xylene Catalog # Product Set of 10 BTEX-M-200 200 ug/ml of BTEX/MTBE Mixture in Methanol BTEX-M-2000 2000 ug/ml of BTEX/MTBE Mixture in Methanol

BTEX / MTBE Calibration Set

Five Point BTEX Calibration Sets are available in the range 1 to 50 ug/ml and also range 100 to 2000 ug/ml in Methanol and can be made to any specified concentration. Catalog # Product per Set BTEX-CAL-L BTEX Calibration Set Low Range [1, 5, 10, 25, 50 ug/ml] BTEX-CAL-H BTEX Calibration Set High Range [10, 250, 500, 1000, 2000 ug/ml

Gasoline Range Organics (GRO / MIX)

2000 ug/ml of each component in Methanol: Benzene 1,2,4 Trimethylbenzene Ethylbenzene 1,2,3 Trimethylbenzene 3-MethylPentane o-Xylene Toluene Catalog # Product Set of 10 GRO-MIX 2000 ug/ml of GRO / MIX components in Methanol Five Point Calibration Sets are available in range 1 to 50 ug/ml in Methanol or can be made to any specified concentrations upon request. Catalog # Product per Set GRO-CAL GRO/MIX Calibration Set [1, 5, 10, 25, 50 ug/ml in Methanol

ENVIRONMENTAL STANDARDS


Ion Chromatography Standards

We offer Standards in an Aqueous Matrix for the determination of Ion concentrations in waste streams and effluents. Standards can be prepared in glass ampoules or bottles and are NIST Traceable by Weight. Standards can also be custom made to your specifications in either single or multi-component mixtures.

Anion Multi-Component Standards

Fluoride 50 ppm wt. Acetate 500 ppm wt. Propionate 300 ppm wt. Formate 700 ppm wt. Chloride 1100 ppm wt. Bromide 135 ppm wt. Malonate 250 ppm wt. Sulfate 900 ppm wt. Oxalate 450 ppm wt. Phosphate 150 ppm wt. Thiosulfate 1150 ppm wt. Catalog # Product per 125mls IC-11 Anion Multi-Component Standards – 11 Components Chloride 400 ppm wt. Bromide 400 ppm wt. Sulfate 400 ppm wt. Thiosulfate 600 ppm wt. Catalog # Product per 125mls IC-4 Anion Multi-Component Standards – 4 Components

WATER STANDARDS


ASTM D-

EN IP ISO UOP Page ASTM

D- EN IP ISO UOP Page

56 53 5713 23

86 3405 57 5762 40

92 22592 36 2592 52 5769 25

92 22592 403 2592 52 5772 71 3105 54

93 22719 34 2719 52 5773 52

93 22719 404 2719 52 5792 435 52

97 15 51 5792 16 52

445 71 3105 54 5808 49

611 59 5863 61

848 56 5868 49

850 58 5949 52

1319 156 3837 30 6045 56

1552 39 6069 39

2386 16 51 6258 56

2386 435 51 6304 60

2500 23015 219 51 6313 38

2622 448 14596 41 6334 42

2887 406 3924 22 6352 480 20

3120 16591 38 6366 39

3227 163 46 6371 309 51

3230 77 58 6417 21

3237 62 6428 39

3246 38 6550 29

3606 425 12177 24 6729 13

3710 20 6730 13

3961 38 6733 13

4045 38 6839 13

4294 336 8754 41 7039 44

4492 23 7169 507 20

4629 379 40 7371 14078 35

4815 7 33 53

4927 61 170 13736 53

4929 49 585 37

5059 62 543 34

5134 13 551 32

5186 391 31 621 34

5188 55 690 33

5191 55 720 32

5441 9 744 32

5453 38 798 33

5453 44 831 32

5482 55 868 33

5501 11 870 34

5580 30 880 33

5599 1601 1408 7 931 32

5623 45

5708 61

ASTM/EN/IP/ISO Conversion table


In case a standard is missing, just fill in the requirements and we will provide you with a custom made standard.

Da Vinci Laboratory Solutions

Attn. Supplies Department

T: + 31 (0)10 258 1878

F: + 31 (0)10 258 1879

E-mail: [email protected]

Company :___________________________________________________________________

Contact person :____________________________________________________________________

Address :____________________________________________________________________

:____________________________________________________________________

ZIP, City, State :____________________________________________________________________

Country :____________________________________________________________________

Telephone :____________________________________________________________________

E-mail :____________________________________________________________________

Method : ASTM / IP / UOP / EN / ISO____________________________________________

Matrix :____________________________________________________________________

Volume :___________________________________________________________________ml

Quantity :___________________________________________________________________

Components Concentration Unit concentration

Request Form Custom Made Standards

Documents

DVLS Standards Catalog - gallpe.com