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1
DOW™Water and Process Solutions
Basic Ultrafiltration
2
Scale of Filtration ProcessesRemoval capabilities of common filtration processes
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Rejected• Suspended solids
• High molecular weight solutes
• Colloids
• Macromolecules
• Bacteria & coliforms (6-log)
• Virus (2.5-log)
Typical treated water results:
• Turbidity < 0.3 NTU
• SDI < 3
Not Rejected (Passed)• Water
• Low MW dissolved solids
• Salts
• Sugars
• Dissolved organics*
• True colour
• Taste & odor compounds
* Can be removed with coagulationpre-treatment
Removal Capabilities of UF Membranes
4
Feed Water Parameters for Design
Minimum feed water quality data:
• Operating temperatures (min/max/avg)
• Turbidity & TSS
• TOC or COD
• Dissolved/total Fe and Mn
• FOG
• pH
Other information:
• Plant capacity (seasonal requirements)
• Feed water source
• End-use (RO pre-treatment, potable water...)
• Seasonal variations (algae blooms, extent/duration of excursions)
• Treated water quality requirements
• Redundancy requirements
Ideally a complete water analysis!!
5
DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
6
Membrane Material Selection
Important properties for a separation membrane are:
1. Selectivity (pore size);
2. Permeability;
3. Strength & flexibility; and
4. Chemical & thermal stability.
Reversal of fouling is the main concern in
low pressure membrane applications!
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DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
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• PVDF & PS/PES havesimilar strength
• PVDF is more flexible
– Required for aggressive airscour for more effectivecleaning
– Air scour enhances masstransfer & particulateremoval
5000ppm NaOCl
• PVDF has ~10x greater resistanceto NaOCl
– Better cleanability to restore TMP
– Extended membrane life
• PS/PES membranes usuallylimited to 200 ppm NaOCl
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DOW H-PVDF Material
Hydrophilicmembrane
Lower contactangle for higher
wettability
Higher resistance tofouling
Lower operating pressurerequirements
Source: inno-x.ch
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DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
11
Anatomy of a Hollow Fibre
Advantages:
• Maximizes fibre area andminimizes footprint
• Can plug a broken fibre tomaintain module integrity
HollowHollow fibrefibrecross sectioncross section
SupportSupportstructurestructure SkinSkin
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DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
13
Outside-In Advantage
• PVDF material (usually)
• Higher solids tolerance
• More surface area (~2x)
• Higher recovery with air scourassisted backwash
Outside-in
• PS/PES material (usually)
• Risk of plugging fibre lumen
• Fouls more rapidly
• Irreversible fouling ondifficult water
Inside-out
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DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
15
Pressurized UF• Higher packing density
Smaller footprint
Fewer modules
Less chemicals
• No excavation required
Reduced civil works
Submerged UF• Operates at lower fluxes
More modules required
• TMP limited to < 0.9 bar
Reduced throughput at lowertemperatures
Pressure Driven Advantage
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Module Structure
Filtrate
Feed
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DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
18
Flow Configuration
Dead-end
• Feed flow is perpendicular to thesurface of the membrane
• Solids and a small percentage of thefeed are retained
• High recovery/low energy
• Batch process
Cross-flow
• Flow travels tangentially across thesurface of the membrane
• A percentage of concentrate isrecirculated
• High energy/low per-pass recovery
• Continuous process
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ConcentrateTo Drain or
Recycle
Concentrate Bleed Format
Filtrate
RawWater
Filter100-300 m
BackwashTank
Air
Chemicals
Backwash Pump
Feed Pump
Waste
(Partially Open)
20
DOW™ UF Module
• 0.03µm nominal pore size
• H-PVDF material
• Hollow fibre configuration
• Outside-in flow path
• Pressurized module
• Dead-end filtration (typical)
• Range of active areas available
21
DOW™ UF – Product Specs
Product NameSFP, SFD-
2880SFP, SFD-
2860IW102-1100DW102-1100
IW74-1100DW74-1100
Active Area (m2) 77 51 102.5 74
Max Feed Pressure @ 20℃ (Bar) 6.25 5.0
Length (mm) 2360 1860 2359 1780
Empty / Shipping / Flooded Weight(kg) 61 / 71 / 100 48 / 55 / 83 60/70/93 49/56/76
Fibers Materials H-PVDF
Fiber Nominal Pore Size 30 nm
Flow Configuration Out/In
Feed Port 2” Side, Coupling
Filtrate Port 2” Side, Coupling 2” Top, Coupling
Concentrate Port 2” Top, Coupling 2” Side, Coupling
Air Scour ConnectionG 3/8” (Standard) or DN32
Glued Fitting (Option)Bottom
G 3/8” (Standard) or 1 ½”NPT (Option) Side