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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini Michele Maggini Born: Padova (IT) 1959 Full Professor of Organic Chemistry, University of Padova Department of Chemical Sciences Via Marzolo 1 - 35131 Padova, Italy Phone: +39 049-8275662; mobile: +39 3347151928 E-mail: [email protected] webpage: www.chimica.unipd.it/michele.maggini skype: m.maggini linkedin Education 1984 Master Degree (Laurea) in Chemistry, Department of Organic Chemistry, University of Padova, Italy. Fellowships 1984-1985 - Guest Researcher, Department of Organic Chemistry, University of Padova 1986-1988 - Research Associate, Searle Chemistry Labs., The University of Chicago, USA Professional appointments 1988-1989 - Senior Research Chemist - Lepetit Research Center, Dow Chemical, Gerenzano, Italy 1989-1998 - Research Chemist, National Council of Research, U. of Padova, Italy 1998-2000 - Associate Professor of Organic Chemistry, Organic Chemistry Dept., U. of Padova, Italy 2000- Full Professor of Organic Chemistry, Chemical Sciences Dept., U. of Padova, Italy Research interests Michele Maggini’s main research interests are the design, synthesis, characterization and applications of π-conjugated molecular architectures for solar energy conversion and the development of flow chemistry platforms for the synthesis of pharmaceutical products, the controlled functionalization of carbon nanostructures and the production of micro/nanosystems to encapsulate, carry and deliver active chemical ingredients. Scientific achievements Michele Maggini obtained his Laurea degree in Chemistry in 1984 in the group of Gianfranco Scorrano, working on the reactivity of aromatic nitroderivatives in alkaline- alcoholic media. In 1986, as a research associate with Philip Eaton at the U. of Chicago, he isolated the cycloaddition product of 1,2- dehydrocubane (cubene), one of the most pyramidalized olefin yet known (Encyclopædia Britannica, Yearbook of Science and the Future , 1990, page 308, JACS 1988, 110, 7230; JACS 1988, 110, 7232). With M. Prato, in 1989 Maggini tackled the total synthesis of bioactive indolizidine alkaloids and in 1992 began to investigate the chemical reactivity of the fullerenes, specifically through the cycloaddition of azomethine ylides (JACS 1993, 115, 9798 - 1089 citations, Acc. Chem. Res. 1998, 31, 519 - 763 citations). Within an international network of excellent collaborators, a wide variety of fullerene derivatives were produced and studied. For instance, those containing a covalently linked TEMPO moiety were investigated to elucidate and understand the peculiar characteristics of fullerene anions or triplet excited states (JACS 1997, 119, 789; JACS 2006, 128, 4734). These species are connected with relevant fullerene features, such as non -linear optical properties, electron or energy transfer in donor- acceptor systems (Angew. Chem., Int. Ed. 2000, 39, 3905) and singlet oxygen sensitization. In 1998, Maggini joined the Department of Chemical Sciences as associate professor and, since then, his research interests have focused mainly on the synthesis of molecular organic materials for solar energy conversion (Adv. Mater. 2001, 13 , 1871, Adv. Mater. 2002, 14, 1735, Energy & Environ. Sci. 2011, 4, 725) and on the development of flow chemistry platforms and methods for the synthesis of active pharmaceutical ingredients of industrial interest (J. Flow. Chem. 2015, 5, 17) or the batch-to-flow transpositions of distressing or unsafe

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Page 1: DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini · benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi,

DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Michele Maggini Born: Padova (IT) 1959 Full Professor of Organic Chemistry, University of Padova Department of Chemical Sciences Via Marzolo 1 - 35131 Padova, Italy Phone: +39 049-8275662; mobile: +39 3347151928 E-mail: [email protected] webpage: www.chimica.unipd.it/michele.maggini skype: m.maggini – linkedin

Education 1984 – Master Degree (Laurea) in Chemistry, Department of Organic Chemistry, University of Padova, Italy.

Fellowships 1984-1985 - Guest Researcher, Department of Organic Chemistry, University of Padova 1986-1988 - Research Associate, Searle Chemistry Labs., The University of Chicago, USA

Professional appointments 1988-1989 - Senior Research Chemist - Lepetit Research Center, Dow Chemical, Gerenzano, Italy 1989-1998 - Research Chemist, National Council of Research, U. of Padova, Italy 1998-2000 - Associate Professor of Organic Chemistry, Organic Chemistry Dept., U. of Padova, Italy 2000- Full Professor of Organic Chemistry, Chemical Sciences Dept., U. of Padova, Italy

Research interests Michele Maggini’s main research interests are the design, synthesis, characterization and applications of π-conjugated molecular architectures for solar energy conversion and the development of flow chemistry platforms for the synthesis of pharmaceutical products, the controlled functionalization of carbon nanostructures and the production of micro/nanosystems to encapsulate, carry and deliver active chemical ingredients.

Scientific achievements Michele Maggini obtained his Laurea degree in Chemistry in 1984 in the group of Gianfranco Scorrano,

working on the reactivity of aromatic nitroderivatives in alkaline- alcoholic media. In 1986, as a research

associate with Philip Eaton at the U. of Chicago, he isolated the cycloaddition product of 1,2-

dehydrocubane (cubene), one of the most pyramidalized olefin yet known (Encyclopædia Britannica,

Yearbook of Science and the Future , 1990, page 308, JACS 1988, 110, 7230; JACS 1988, 110, 7232).

With M. Prato, in 1989 Maggini tackled the total synthesis of bioactive indolizidine alkaloids and in 1992

began to investigate the chemical reactivity of the fullerenes, specifically through the cycloaddition of

azomethine ylides (JACS 1993, 115, 9798 - 1089 citations, Acc. Chem. Res. 1998, 31, 519 - 763

citations). Within an international network of excellent collaborators, a wide variety of fullerene

derivatives were produced and studied. For instance, those containing a covalently linked TEMPO

moiety were investigated to elucidate and understand the peculiar characteristics of fullerene anions or

triplet excited states (JACS 1997, 119, 789; JACS 2006, 128, 4734). These species are connected with

relevant fullerene features, such as non -linear optical properties, electron or energy transfer in donor-

acceptor systems (Angew. Chem., Int. Ed. 2000, 39, 3905) and singlet oxygen sensitization. In 1998,

Maggini joined the Department of Chemical Sciences as associate professor and, since then, his

research interests have focused mainly on the synthesis of molecular organic materials for solar energy

conversion (Adv. Mater. 2001, 13 , 1871, Adv. Mater. 2002, 14, 1735, Energy & Environ. Sci. 2011, 4,

725) and on the development of flow chemistry platforms and methods for the synthesis of active

pharmaceutical ingredients of industrial interest (J. Flow. Chem. 2015, 5, 17) or the batch-to-flow

transpositions of distressing or unsafe

Page 2: DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini · benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi,

DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

chemical syntheses (OPRD 2012, 16, 1146). Fast prototyping techniques are used for the quick

fabrication of polymer microfluidic devices based on soft photolithography (Adv, Synthesis & Catalysis

2008, 17, 2815) and the study of surface modification of microchannels by wet chemistry methods (Lab

Chip, 2012,12, 4041). By using original prototypes, or commercial flow reactors, Maggini studies the

synthesis and functionalisation of nanosystems, such as metal nanoparticles (Chem. Commun. 2013,

49 , 84) or carbon nanostructures (Chem. Commun. 2011, 47, 9092, J. Flow Chem. 2014, 4, 79). Often

the microfluidics toolbox is used to study reaction (Eur. J. Org. Chem. 2011, 28, 5571) or surface-

absorption kinetics (Chem. Commun. 2011, 47, 11656). The scientific production of Michele Maggini

counts 163 publications on peer-reviewed journals and 3 patents.

Bibliometric indicators Number of papers on peer-reviewed journals and book chapters: 185; Source: Google Scholar (https://scholar.google.it/citations?user=LybifkUAAAAJ&hl=it); Number of citations 10836; h-index=54; h- index=47 (WoS, 8370 citations); i10-index=146; h-index (since 2014)=23; i10-index (since 2014)=54.

Supervision of graduate students and postdoctoral fellows 1999-2017 – 5 postdocs, 11 PhD

students, 25 Master students, Department of Chemical Sciences – University of Padova

Teaching activities 1998-2017 – Istitutional teaching activity as associate professor and then, since 2000, as full professor at the University of Padova - Italy: Organic Chemistry 1 (for Chemistry, Industrial Chemistry, Materials Science, Natural Sciences, Biotechnology courses at BS level); Advanced Organic Synthesis (for Chemistry, Industrial Chemistry courses at MS level); Functional Organic Materials (for Materials Science at MS level); Carbon Nanostructures Chemistry (for the PhD program in Molecular Sciences)

Organisation of scientific meetings San Diego (1998), Seattle (1999), Toronto (2000), Washington (2001) - Fullerenes: Chemistry, Physics and New Directions, international symposium on the Organic Functionalization of the Fullerenes, The Electrochemical Society, chairman 2004 - nano.org: organic chemistry meets nanotechnology, co-chairman, Venezia 2006, 2007, 2008 - Summer School "A. Corbella" Seminars in Organic Synthesis, co-chairman, Gargnano, Italy 2011 - 3rd symposium on Continuous Flow Reactor Technology for Industrial Applications, chairman, Como, Italy 2015, 2016, 2017 – European Winter School on Physical Organic Chemistry, chairman, Bressanone, IT 2016 – EuCheMS Chemistry Congress, topic E4, Carbon-based Nanochemistry Section, convenor,

Seville, Spain.

Institutional responsibilities 2004-2012 Member of the Commission for Scientific Research of the U. of Padova 2014-2016 Coordinator of the Undergraduate Programme in Materials Science, U. of Padova 2014-2016 Coordinator of the Natural Sciences Class of the Galilean School of higher education, U. of Padova 2016-2017 member of the national Chemistry Panel for university research evaluation (GEV3-ANVUR) VQR 2011-2014. Since 2010 steering committee member of the PhD program in Science and Engineering of Materials and Nanostructures, Chemical Science Dept., U. of Padova Since 2016 Deputy director of the Galilean School of Higher Education, U. of Padova Since 2016 Director of the Department of Chemical Sciences, U. of Padova

Page 3: DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini · benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi,

DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Collaborative projects (a) NATO-CRG960099 on fullerene chemistry, coordinator (1996-1999); (b) Steering Committee member of EC project Brite EuRam III MOLALC, on Molecular Optical Limiting and Light Control (1997-2000); steering Committee member of EC projects Joule III on Molecular Plastic Solar Cells (1999-2001); (c) CNR-C00C4BD, Functional Fullerene Derivatives, local PI (2000); (d) U. of Padova, starting grant on Multiphoton Absorbing Organic Chromophores (2001); (e) Ministry of University and Research, PRIN 2004-035502, Functional Fullerenes for Materials Science Applications, local PI; PRIN 2006-034372, Oxidation of Carbon Nanotubes, local coordinator; PRIN 2008- 5M27SS, Carbon Nanostructures in Microfluidic Reactors, local coordinator; PRIN 2010-N3T9M4 Photosynthetic Artificial Nanostructures, local PI; (f) MISCHA (Fabrication, Characterization and Modelling of Microfluidic Devices) collaborative project sponsored by Fondazione CaRiPaRO, coordinator (2008-2011); (g) HELIOS (Highly Efficient Light Interactions with Organized Molecular Systems) collaborative project sponsored by the U. of Padova, coordinator (2009-2013); (h) Ministry of University and Research, FIRB-RBAP11C58Y, NANOSOLAR, local PI (2012-2016); (i) InnoGel (Innovative hydrogels for conservation agriculture) collaborative project sponsored by Fondazione CaRiPaRO, coordinator (2018-2020).

Commissions of trust Since 2002 editorial board member of the journal: Fullerenes, Nanotubes, and Carbon Nanostructures 2008-2012 scientific advisory board member for microreactor technology, Corning Inc., USA 2009 projects evaluator for F.R.S.-FNRS, Belgium 2011 projects evaluator for Fondazione CARITN, Trento, Italy 2012 projects evaluator for Fondazione Bruno Kessler, Trento, Italy 2012 project evaluator for Fondation FRC, Strasbourg, FR 2012-2013 evaluation panel member for Veneto Region 2004-2014 scientific advisor for Fabbrica Italiana Sintetici SpA (pharma group), Italy 2015-2016 scientific advisor for A.M.S.A. SpA (pharma group), Italy 2014-2016 project evaluator (ERC ST-grants) for EU 2016-2017 member of the National Chemistry Panel for University research evaluation (GEV3-ANVUR)

Regular reviewer activity for scientific chemistry journals published by Wiley, Royal Society of

Chemistry, American Chemical Society.

Memberships of scientific societies Italian Chemical Society; American Chemical Society

Major collaborations M. Prato (carbon nanostructures chemistry, U. of Trieste), A. Hirsch (carbon nanostructures π-conjugated molecular structures chemistry, U. of Erlangen, DE), F. Paolucci (electrochemistry of functional materials, U. of Bologna), S. Campagna (photophysical studies, U. of Messina), M. Muccini (organic solar cells development, ISMN-CNR, Bologna), P. Ceroni (photophysical characterization of π-conjugated molecules, U. of Bologna), D. Guldi (photophysics of carbon nanostructures, U. of Erlangen, DE), C. Bignozzi (hybrid organic-inorganic solar cells, U. of Ferrara), E. Galoppini (synthesis of organic photosensitizers, Rutgers U., Newark - USA), M. Benaglia (microreactor technology, U. of Milano).

Granted patents A. Castellin, M. Maggini, P. Donnola - Process for the synthesis of 4H-imidazo [1,5-a] [1,4] benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi, A. Pace, P. Salice - Method for synthesis of functionalised carbon nanotubes by cycloaddition under continuous flow conditions and apparatus for the method, 2013 - WO2012156297 A3

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Invited presentations to peer -reviewed internationally established conferences and/or

international advanced schools

1988 Symposium on pyramidalized olefins, ACS meeting, Los Angeles 1994 185 meeting of the Electrochemical Society (ECS), San Francisco 1995 187 meeting of ECS, Reno 1995 COST Action D2 Workshop on Selective Synthesis, Budapest 1996 189 meeting of ECS, Los Angeles 1996 13 IUPAC meeting ICPOC-13, Inchon (Korea) 1997 191 meeting of ECS, Montreal 1998 II Italian-Israeli meeting on Physical Organic Chemistry, Jerusalem 1999 ESOC 11, Göteborg 1999 195 meeting of ECS, Seattle 2000 III Spanish-Italian Symposium on Organic Chemistry, Malaga 2001 199 meeting of ECS, Washington 2002 201 meeting of ECS, Philadelphia 2004 Laboratory for plastic solar cells, Linz 2006 VI Spanish-Italian Symposium on Organic Chemistry, Taormina 2009 216 meeting of ECS, Vienna 2012 Scientific Update, Baveno (IT) 2013 223rd meeting of ECS, Toronto 2014 1st China-Italy Bilateral Symposium on Graphene, Dalian (China) 2014 PCC - Anders Ringbom Workshop, Åbo Akademi University, Turku (Fin) 2015 227 meeting of ECS, Chicago 2017 Liebig Kolleg, University of Giessen, DE 2018 Electron Donor-Acceptor Interactions Gordon Research Conference, Newport

Lectures at universities or research centers

(1) Merrel Dow Pharmaceuticals Inc., Cincinnati, 1988 (2) ISM-CNR, Bologna, 1994 (host: C. Taliani) (3) CNR Research Area, Padova, 1995 (host: P. Traldi) (4) Toyama University, 1996 (host: Y. Higuchi) (5) Kyoto University, 1996 (host: K. Komatsu) (6) Osaka University, 1996 (host: Y. Tobe) (7) Leopold-Franzens-Universität Innsbruck, 1996 (host: B. Kraeutler) (8) University of Notre Dame (USA) 1997 (host: D. Guldi) (9) ISOF-CNR, Bologna, 2001 (host: N. Camaioni) (10) University of Pavia, 2004 (host: P. Righetti) (11) BASF Ludwigshafen, 2005 (host: T. Gessner) (12) University L. Pasteur Strasbourg, 2006 (host: A. Bianco) (13) University of Muenster, 2007 (host: L. De Cola) (14) ENI-Donegani, 2009 (host: R. Po) (15) University of Erlangen, 2010 (host: D. Guldi) (16) University Milano Bicocca, 2010 (host: A. Abbotto) (17) University FUNDP, Namur (B), 2011 (host: D. Bonifazi) (18) Univeristy of Erlangen, 2012 (host: D. Guldi) (19) University of Graz, 2012 (host: O. Kappe) (20) University of Bari, 2014 (host: G. Farinola) (21) ISIS- Strasbourg, 2014 (host: L. De Cola) (22) University of Duisburg, 2018 (host: S. Barcikowski)

Prizes, Awards, Academy memberships 2015 - Angelo Mangini Medal - Organic Chemistry Division of the Italian Chemical Society 2016 – Member of Istituto Veneto di Scienze, Lettere ed Arti, Venezia.

Page 5: DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini · benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi,

DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Publications of Michele Maggini

1. M. Maggini, C. Paradisi, G. Scorrano, S. Daniele, F. Magno

Ion-Pairing Effect on the Reduction of Nitroarenes in Propan-2-ol Solutions: an Electrochemical Investigation. J. Chem. Soc., Perkin Trans. II, 1986, 267-69.

2. M. Maggini, P . E. Eaton Cubene (1,2-Dehydrocubane) J. Am. Chem. Soc.1988, 110, 7230-32.

3. R. Gilardi, M. Maggini, P. E. Eaton X-Ray Structures of Cubylcubane and 2-tert-Butylcubylcubane: Short Cage-Cage Bonds J. Am. Chem. Soc. 1988, 110, 7232-34.

4. S. Reddy, M. Maggini, J. Tsanaktsidis, P. E. Eaton Direct Radical Substitution on the Cubane Skeleton Tetrahedron Lett. 1988, 31, 805-06.

5. M. Maggini, M. Prato, G. Scorrano Imino Diels-Alder Cycloadditions: an Application to the Synthesis of (±)- Aristeromycin Tetrahedron Lett. 1990, 31, 6243-46.

6. M. Maggini, M. Passudetti, G. Gonzales-Trueba, U Quintily, G. Scorrano, M. Prato A General Procedure for the Fluorodenitration of Aromatic Substrates J. Org. Chem. 1991, 56, 6406-11.

7. Ihmels, M. Maggini, M. Prato, G. Scorrano Oxidation of Diazo Compounds by Dimethyl Dioxirane: an Extremely Mild and Efficient Method for the Preparation of Labile a -oxo-Aldehydes Tetrahedron Lett.1991, 32, 6215-18.

8. M. Maggini, M. Prato, G. Scorrano 2-Azanorbornadiene Tetrahedron Lett.1991, 32, 6957-60.

9. M. Maggini, M. Prato, M. Ranelli, G. Scorrano Synthesis of (-)-8-Deoxy-7-Hydroxy-Swainsonine and (±)-6,8-Dideoxy- Castanospermine Tetrahedron Lett.1992, 33, 6537-40.

10. M. Prato, M. Maggini, G. Scorrano, V. Lucchini Addition of Quadricyclane to C60: Easy Access to Fullerene Derivatives Bearing a Reactive Double Bond in the Side Chain J. Org. Chem. 1993, 58, 3613-15.

11. M. Prato, T. Suzuki, F. Wudl, V. Lucchini, M. Maggini, Experimental Evidence for Segregated

Ring Currents in C60. J. Am. Chem. Soc.1993, 115, 7876-77 12. Prato, V. Lucchini, M. Maggini, E. Stimpfl, G. Scorrano, M. Eiermann, T. Suzuki, F. Wudl

Energetic Preference in 5,6- and 6,6-Ring Junction Adducts of C60: Fulleroids and Methanofullerenes

J. Am. Chem. Soc.1993, 115, 8479-80. 13. Prato, A. Bianco, M. Maggini, G. Scorrano, C. Toniolo, F. Wudl Synthesis and

Characterization of the First Fullerene-Peptide J. Org. Chem.1993, 58, 5578-80. 14. Maggini, G. Scorrano, M. Prato

Addition of Azomethine Ylides to C60: Synthesis, Characterization and Functionalization of Fullerene-Pyrrolidines J. Am. Chem. Soc.1993, 115, 9798-99.

15. M. Maggini, G. Scorrano, A. Bianco, C. Toniolo, R. P. Sijbesma, F. Wudl, M. Prato Addition Reactions of C60 Leading to Fulleroprolines Journal of the Chemical Society, Chemical Communications1994, 305-06.

16. M. Maggini, A. Karlsson, G. Scorrano, G. Sandonà, G. Farnia, M. Prato Ferrocenyl Fulleropyrrolidines: a Cyclic Voltammetry Study J. Chem. Soc., Chem. Commun. 1994, 589-90.

17. M. Maggini, A. Karlsson, L. Pasimeni, G. Scorrano, M. Prato, L. Valli Synthesis of N-Acylated Fulleropyrrolidines: New Materials for the Preparation of Langmuir

Page 6: DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini · benzodiazepines, in particular midazolam and salts thereof, 2013 - US8557981 B2 M. Maggini, E. Menna, T. Carofiglio, E. Rossi,

DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Blodgett Films Containing Fullerenes Tetrahedron Lett. 1994, 35, 2985-88.

18. M. Maggini, L. Pasimeni, M. Prato, G. Scorrano, L. Valli Incorporation of an Acyl Group in Fulleropyrrolidines: Effects on Langmuir Monolayers Langmuir, 1994, 10, 4164-66.

19. C. Toniolo, A. Bianco, M. Maggini, G. Scorrano, M. Prato, M. Marastoni, R. Tomatis, S. Spisani, G. Palù, E. D. Blair A Bioactive Fullerene Peptide J. Med. Chem. 1994, 37, 4558-62.

20. M. Eiermann, F. Wudl, M. Prato, M. Maggini Electrochemically Induced Isomerization of a Fulleroid to a Methanofullerene J. Am. Chem. Soc. 1994, 116, 8364-65.

21. N. Zhang, S. R. Schricker, F. Wudl, M. Prato, M. Maggini, G. Scorrano A New C60 Polymer via Ring-Opening Methatesis Polymerization Chemistry of Materials 1995, 7, 441-42.

22. M. Maggini, G. Scorrano, M. Prato, G. Brusatin, P. Innocenzi, M. Guglielmi, A. Renier, R. Signorini, M. Meneghetti, R. Bozio C60 Derivatives Embedded in Sol-Gel Silica Films Advanced Materials 1995, 7, 404-06.

23. M. Maggini, A. Donò, G. Scorrano, M. Prato Synthesis of a [C60]Fullerene Derivative Covalently Linked to a Ruthenium (II) Tris(bipyridine) Complex J. Chem. Soc., Chem. Commun. 1995, 845-46.

24. M. Maggini, G. Scorrano, A. Bianco, C. Toniolo, M. Prato Synthesis and Characterization of Both Enantiomers of a Chiral C60 Derivative with C2 Simmetry Tetrahedron Lett.1995, 36, 2845-46.

25. F. Paolucci, M. Marcaccio, S. Roffia, G. Orlandi, F. Zerbetto, M. Prato, M. Maggini, G. Scorrano Electrochemical Monitoring of Valence Bond Isomers Interconversion in Bipyridyl- C61 Anions J. Am. Chem. Soc.1995, 117, 6572-80.

26. M. Eiermann, R. C. Haddon, B. Knight, Q. C. Li, M. Maggini, N. Martin, T. Ohno, M. Prato, T. Suzuki, F. Wudl Electrochemical Evidence for Trough-Space Orbital Interactions in Spiro Methanofullerenes Angewandte Chemie-International Edition In English 1995, 34, 1591-94.

27. N. S. Sariciftci, F. Wudl, A. J. Heeger, M. Maggini, G. Scorrano, M. Prato, P. C. Ford Photoinduced Electron Transfer and Long Lived Charge Separation in a Donor- Bridge-Acceptor Supramolecular "Dyad" Consisting of Ruthenium(II) Tris(bipyridine) Functionalized C60 Chemical Physics Letters 1995, 247, 510-14

28. C. Corvaja, M. Maggini, M. Prato, G. Scorrano, M. Venzin C60 Derivative Covalently Linked to a Nitroxide Radical: Time Resolved EPR Evidence of Electron Spin Polarization by Intramolecular Radical-Triplet Pair Interaction J. Am. Chem. Soc.1995, 117, 8857-58.

29. M. Prato, M. Maggini, C. Giacometti, G. Scorrano, G. Sandonà, G. Farnia Synthesis and Electrochemical Properties of Substituted Fulleropyrrolidines Tetrahedron 1996, 52, 5221-34.

30. S. Cossu, G. Cuomo, O. De Lucchi, M. Maggini, G. Valle Unexpected Formation of Dienes in the Diels-Alder Reaction of Exocyclic 1- Bromobutadienes of Polycyclic Hydrocarbons J. Org. Chem.1996, 61, 153-58.

31. Malabarba, R. Ciabatti, M. Maggini, P. Ferrari, L. Colombo, M. Denaro Structural Modifications of the Active Site in Teicoplanin and Related Glycopeptides. 2. Deglucoteicoplanin-Derived Tetrapeptide J. Org. Chem.1996, 61, 2151-57.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

32. F. Novello, M. Prato, T. Da Ros, M. De Amici, A. Bianco, C. Toniolo, M. Maggini

Stereoselective Additions to [60]Fullerene

Chemical Communications 1996, 903-04 33. M. Prato, M. Maggini, G. Scorrano

Synthesis and Applications of Fulleropyrrolidines Synthetic Metals, 1996, 77, 89-91. 34. Bianco, M. Maggini, G. Scorrano, C. Toniolo, G. Marconi, C. Villani, M. Prato Synthesis,

Chiroptical Properties and Configurational Assignment of Fulleroproline Derivatives and Peptides J. Am. Chem. Soc.1996, 118, 4072-80.

35. G. Agostini, C. Corvaja, M. Maggini, L. Pasimeni, M. Prato Fullerene Derivatives in Poly (Methylmethacrylate): an EPR and Zero-Field ODMR Study of their Photoexcited Triplet States Journal of Physical Chemistry 1996, 100, 13416-20.

36. R. Signorini, M. Zerbetto, M. Meneghetti, R. Bozio, M. Maggini, C. De Faveri, M. Prato, G. Scorrano Optical Limiting Properties of Soluble Fullerene Derivatives for Incorporation in Sol-Gel Materials Chemical Communications 1996, 1891-92.

37. T. Da Ros, M. Prato, F. Novello, M. Maggini, E. Banfi Easy Access to Water Soluble Fullerene Derivatives via 1,3-Dipolar Cycloadditions of Azomethine Ylides to C60 J. Org. Chem.1996, 61, 9070-72.

38. T. Da Ros, M. Prato, F. Novello, M. Maggini, M. De Amici, C. De Micheli Cycloaddition of Nitrile Oxides to [60]Fullerene Chemical Communications 1997, 59-60.

39. G. Brusatin, M. Guglielmi, R. Bozio, M. Meneghetti, R. Signorini, M. Maggini, G. Scorrano, M. Prato Preparation and Characterization of Fullerene Containing Sol-Gel Glass Journal of Sol-Gel Science and Technology1997, 8, 609-13.

40. F. Arena, F. Bullo, F. Conti, C. Corvaja, M. Maggini, M. Prato, G. Scorrano Synthesis and EPR studies of Radical and Biradical Anions of C60 Nitroxide Derivatives J. Am. Chem. Soc., 1997, 119, 789-95.

41. D. M. Guldi, M. Maggini, G. Scorrano, M. Prato, Intramolecular Electron Transfer in Fullerene/Ferrocene Based Donor-Bridge- Acceptor Dyads J. Am. Chem. Soc.1997, 119, 974-80.

42. L. Pandolfo, M. Maggini Reaction of trans-[Pt(H2)(PCy3)2] with C60. Reductive Elimination of H2 and Formation of [Pt(PCy3)2](h2-C60)] Journal of Organometallic Chemistry 1997, 540, 61-65.

43. Bianco, T. Bertolini, M. Crisma, G. Valle, C. Toniolo, M. Maggini, G. Scorrano, M.

Prato beta -Turn Induction by C60-Based Fulleroproline. Synthesis and Conformational Characterization of Fpr/Pro Small Peptides Journal of Peptide Research 1997, 50, 159-70.

44. Bianco, F. Gasparrini, M. Maggini, D. Misiti, A. Polese, M. Prato, G. Scorrano, C. Toniolo, C. Villani Molecular Recognition by a Silica-Bound Fullerene Derivative J. Am. Chem. Soc.1997, 119, 7550-54.

45. Corvaja, M. Maggini, M. Ruzzi, G. Scorrano, A. Toffoletti Spin Polarization in Fullerene Derivatives Containing a Nitroxide Group. Observation of the Intermediate Photoexcited Quartet State in Radical Triplet Pair Interaction Applied Magnetic Resonance 1997, 12, 477-93.

46. F. Conti, C. Corvaja, M. Maggini, F. Piu, G. Scorrano, A. Toffoletti Spin Polarization and Photoinduced Electron Transfer between Ferrocene and Fullerene

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Derivatives Containing a Nitroxide Group Applied Magnetic Resonance 1997, 13, 337-46.

47. M. Meneghetti, R. Signorini, M. Zerbetto, R. Bozio, M. Maggini, G. Scorrano, M. Prato, G. Brusatin, E. Menegazzo, M. Guglielmi Sol-Gel Materials Embedding Fullerene Derivatives for Optical Limiting Synthetic Metals 1997, 86, 2353-54.

48. L. Pasimeni, A. Hirsch, I. Lamparth, A. Herzog, M. Maggini, M. Prato, C. Corvaja, G. Scorrano Use of Transient EPR Spectroscopy of Excited Triplet State for the Structural Assignement of Bisadducts of Fullerene C60 J. Am. Chem. Soc.1997, 119, 12896-901.

49. L. Pasimeni, A. Hirsch, I. Lamparth, M. Maggini, M. Prato Transient EPR Studies of Excited Triplet States in Polyadducts of C60 and Bis(Ethoxycarbonyl)Methylene J. Am. Chem. Soc.1997, 119, 12902-905.

50. D.M. Guldi, M. Maggini, G. Scorrano, M. Prato Through Bond Mechanism versus Exciplex Formation in the Photochemistry of Fullerene/Ferrocene Donor-Bridge-Acceptor Dyads Research on Chemical Intermediates1997, 23, 561-73.

51. M. Guldi, M. Maggini Synthesis and Photophysical Properties of Electro- and Photoactive Fulleropyrrolidines Gazzetta Chimica Italiana 1997, 127, 779-85.

52. Bianco, V. Lucchini, M. Maggini, M. Prato, G. Scorrano, C. Toniolo Trans-Cis Amide Bond Isomerization in Fulleroprolines Journal of Peptide Science 1998, 4, 364-68.

53. M. Brustolon, A. Zoleo, G. Agostini, M. Maggini Radical Anions of Mono- and Bis-Fulleropyrrolidines: An EPR Study Journal of Physical Chemistry A1998, 102, 6331-39.

54. M. Prato, M. Maggini Fulleropyrrolidines: A Family of Full-Fledged Fullerene Derivatives Accounts of Chemical Research 1998, 31, 519-26.

55. M. Maggini, D. M. Guldi, S. Mondini, G. Scorrano, F. Paolucci, P. Ceroni, S. Roffia Photoinduced Electron Transfer in a Tris(2,2'-bipyridine)-C60-Ruthenium(II) Dyad: Evidence of Charge Recombination to a Fullerene Excited State Chemistry – a European Journal 1998, 4, 1992-2000.

56. M. Guldi, M. Maggini, G. Scorrano, M. Prato, A. Bianco, C. Toniolo Photoinduced electron transfer in supramolecular fullerene/ferrocene systems Journal of Information Recording 1998, 24, 33-39.

57. Polese, S. Mondini, A. Bianco, C. Toniolo, G. Scorrano, D. Guldi, M. Maggini Solvent-Dependent Intramolecular Electron Transfer in a Peptide-Linked [Ru(bpy)3]2+-C60 Dyad J. Am. Chem. Soc. 1999, 121, 3446-52.

58. M. Maggini, C. De Faveri, G. Scorrano, M. Prato, G. Brusatin, M. Guglielmi, M. Meneghetti, R. Signorini, R. Bozio Synthesis and Optical Limiting Behavior of Hybrid Inorganic-Organic Materials from Sol-Gel Processing of Organofullerenes Chemistry, a European Journal 1999, 5, 2501-2510.

59. M. Meneghetti,R. Signorini, S. Sartori, R. Bozio, M. Maggini, G. Scorrano, M. Prato, G. Brusatin, M. Guglielmi Optical Limiting of Multilayer Sol-Gel Structures Containing Fullerenes Synthetic Metals 1999, 103. 2474-2475.

60. Sandro Cattarin, Paola Ceroni, Dirk M. Guldi, Michele Maggini, Enzo Menna, Francesco Paolucci, Sergio Roffia, Gianfranco Scorrano Synthesis and Photoelectrochemical Properties of a Fullerene-Azothiophene Dyad Journal of

Materials Chemistry 1999, 9, 2743.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

61. Signorini, R.; Sartori, S.; Meneghetti, M.; Bozio, R.; Maggini, M.; Scorrano, G.; Prato, M.;

Brusatin, G.; Guglielmi, M.

Hybrid sol-gel glasses containing fullerene derivatives for bottleneck optical limiting with multilayer structures Nonlinear Opt. 1999, 21, 143-162

62. L. Pasimeni, U. Segre, M. Ruzzi, M. Maggini, M. Prato, K. Kordatos Preferential Orientation of Fulleropyrrolidine Bisadducts in E7 Liquid Crystal: A Time-Resolved Electron Paramagnetic Resonance Study J. Phys. Chem. B 1999, 103, 11275-11281.

63. G. Agostini, L. Pasimeni, M. Ruzzi, S. Monti, M. Maggini, M. Prato, I. Lamparth, A. Hirsch, "Fullerene Derivatives embedded in poly(methylmethacrylate): a laser flash photolysis and time resolved EPR study" Chem. Phys. 2000, 253, 105-113

64. M. Guldi, M. Maggini, S. Mondini, F. Guerin, J. H. Fendler "Formation, Characterization and Properties of Nanostructured [Ru(bpy)3]2+-C60 Langmuir-Blodgett Films in situ at the Air-Water Interface and ex situ on Substrates" Langmuir, 2000, 16, 1311-1318.

65. P. Ceroni, F. Conti, C. Corvaja, M. Maggini, F. Paolucci, S. Roffia, G. Scorrano and A. Toffoletti "TEMPO-C61. An Unusual Example of Fulleroid to Methanofullerene Conversion" J. Phys. Chem. A 2000, 104, 156-163.

66. Conti, C. Corvaja, A.Toffoletti, N. Mizuochi, Y. Ohba, S. Yamauchi, M. Maggini "EPR studies on a bi-nitroxide fullerene derivative in the ground triplet and first photoexcited quintet state". J. Phys. Chem. A 2000, 104, 4962-4967

67. D. Guldi, M. Maggini, N. Martin, M. Prato Charge separation in fullerene containing donor–bridge–acceptor molecules Carbon 2000, 38, 1615-1623

68. C. Luo, D. Guldi, M. Maggini, E. Menna, S. Mondini, N. Kotov, M. Prato Stepwise Assembled Photoactive Films Containing Donor-Linked Fullerenes Angew. Chem., Int. Ed. 2000, 39, 3905-3909.

69. C. Corvaja, L. Franco, M. Mazzoni, M. Maggini, G. Zordan, E. Menna, G. Scorrano Electron Spin Polarization in [60]Fullerene Bis-Nitroxides by Intramolecular Triplet- Triplet Interaction Chem. Phys. Lett. 2000, 330, 287-292.

70. P. Innocenzi, G. Brusatin, M. Guglielmi, R. Signorini, M. Meneghetti, R. Bozio, M. Maggini, G. Scorrano, M. Prato Optical limiting devices based on C60 derivatives in sol-gel hybrid organic- inorganic materials J. Sol-Gel Science and Technology 2000, 19, 263

71. R. Signorini, M. Meneghetti, R. Bozio, M. Maggini, G. Scorrano, M. Prato, G. Brusatin, P. Innocenzi, M. Guglielmi Optical limiting and Non Linear Optical Properties of Fullerene Derivatives Embedded in Hybrid Sol-Gel Glasses Carbon 2000, 38, 1653.

72. P. Ceroni, F. Conti, C. Corvaja, M. Maggini, F. Paolucci, S. Roffia, G. Scorrano, A. Toffoletti TEMPO-C61. An Unusual Example of Fulleroid to Methanofullerene Conversion J. Phys. Chem. A 2000, 104, 156.

73. P. Innocenzi, G. Brusatin, R. Bozio, R. Signorini, R. Bozio, M. Maggini glycidoxypropyltrimethoxysilane-TiO2 Hybrid Organic-Inorganic Materials for Optical Limiting J. non Cryst. Sol. 2000, 265/1-2, 68.

74. Cravino, G.Zerza, M. Maggini, S. Bucella, M. Svensson, M. R. Andersson, H. Neugebauer, N. S. Sariciftci A novel polythiophene with pendant fullerenes: toward donor/acceptor double- cable polymers Chem. Commun. 2000, 2487-2488.

75. Sartori, L. Garlaschelli, A. Toffoletti , C. Corvaja, M. Maggini, G. Scorrano Time-resolved EPR characterisation of radical–triplet pairs formed by host–guest interaction of a photoexcited C60–crown ether with an ammonium aminoxyl in liquid solution Chem. Commun. 2001, 311-312.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

76. D. M. Guldi, M. Maggini, E. Menna, G. Scorrano, P. Ceroni, M. Marcaccio, F. Paolucci,

S. Roffia

A Photosensitizer Dinuclear Ruthenium Complex: Intramolecular Energy Transfer to a Covalently Linked Fullerene Acceptor Chem. Eur. J. 2001, 7, 1597.

77. Angelini, P. De Maria, A. Fontana; M. Pierini, M. Maggini, F. Gasparrini, G. Zappia Study of the aggregation properties of a novel amphiphilic C-60 fullerene derivative Langmuir 2001, 17, 6404-6407

78. Gasparrini, D. Misiti, F. Della Negra, M. Maggini, G. Scorrano, C. Villani Molecular recognition of p-tert-butylcalixarenes by surface-linked fullerenes C-60 and C-70 Tetrahedron 2001, 57, 6997-7002

79. M. Carano, P. Ceroni, M. Maggini, M. Marcaccio, E. Menna, F. Paolucci, S. Roffia, G. Scorrano Identification and characterization of redox sites in supramolecular systems and their relevance for the design of photoactive devices. Ru(II)/C-60-based donor- acceptor dyads Collect. Czech. Chem. Commun. 2001, 66, 276-290.

80. Conti, C. Corvaja, M. Maggini, G. Scorrano, P. Ceroni, F. Paolucci, S. Roffia A fulleropyrrolidine binitroxide: synthesis, EPR and electrochemical features Phys. Chem. Chem. Phys. 2001, 3, 3518-3525

81. F. Conti, C. Corvaja, C. Gattazzo, A. Toffoletti, P. Bergo, M. Maggini, G. Scorrano, M. Prato Time-resolved EPR investigation of intramolecular photoinduced electron transfer in spin-labeled fullerene/ferrocene dyads Phys. Chem. Chem. Phys. 2001, 3, 3526-3531

82. M. S. F. Zhang, M. R. Andersson, M. Maggini, S. Bucella, E. Menna, O. Inganäs Soluble Polythiophenes with Pendant Fullerene Groups as Double Cable Materials for Photodiodes Adv. Mater. 2001, 13, 1871-1874.

83. K. Kordatos, M. Prato, E. Menna, G. Scorrano, M. Maggini Synthesis of fullerene derivatives for incorporation in sol-gel glasses J. Sol-Gel Science and Technology 2001, 22, 237-244.

84. Cravino, G. Zerza, H. Neugebauer, S. Bucella, M. Maggini, E. Menna, G. Scorrano, M. Svensson, M.R. Andersson, N.S. Sariciftci Electropolymerization and spectroscopic properties of a novel double-cable polythiophenewith pendant fullerenes for photovoltaic applications Synth. Metals 2001, 121, 1555-1556.

85. N. Camaioni, L. Garlaschelli, A. Geri, M. Maggini, G. Possamai, G. Ridolfi Solar Cells Based on Poly(3-Alkyl)Thiophenes and [60]Fullerene: A Comparative Study J. Mater. Chem. 2002, 12, 2065-2070.

86. N. Camaioni, G. Ridolfi, G. Casalbore-Miceli, G. Possamai, M. Maggini The Effect of a Mild Thermal Treatment on the Performance of Poly(3- Alkylthiophene)/Fullerene Solar Cells. Adv. Mater. 2002, 14, 1735-1738.

87. M. Maggini, G. Possamai, E. Menna, G. Scorrano, N. Camaioni, G. Ridolfi, G. Casalbore-Miceli, L. Franco, M. Ruzzi, C. Corvaja Solar Cells Based on a Fullerene–Azothiophene Dyad Chem. Commun. 2002, 2028-2029.

88. Cravino, G. Zerza, H. Neugebauer, M. Maggini, S. Bucella, E. Menna, M. Svensson, M. R. Andersson, C. J. Brabec, N. S. Sariciftci Electrochemical and Photophysical Properties of a Novel Polythiophene with Pendant

Fulleropyrrolidine Moieties: Toward “Double Cable” Polymers for Optoelectronic Devices

J. Phys. Chem. B 2002, 106, 70-76. 89. M. Mazzoni, L. Franco, C. Corvaja, G. Zordan, E. Menna, G. Scorrano, M. Maggini Synthesis,

Epr and Endor of [60]Fulleropyrrolidine Bisadducts with Nitroxide Addends: Magnitude and Sign of the Exchange Interaction ChemPhysChem 2002, 3, 527-531.

90. M. Mazzoni, L. Franco, A. Ferrarini, C. Corvaja, G. Zordan, G. Scorrano, M. Maggini

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

Unexpected High Ordering of a [60]Fullerene Nitroxide in the Nematic Phase of 4-4 '-

Azoxyanisole

Liq. Cryst. 2002, 29, 203-208. 91. Bagno, S. Claeson, M. Maggini, M. L. Martini, M. Prato, G. Scorrano [60]Fullerene as a

Substituent Chem. Eur. J. 2002, 8, 1016-1023.

92. Bianco, C. Corvaja, M. Crisma, D. M. Guldi, M. Maggini, E. Sartori, C. Toniolo A Helical Peptide Receptor for [60]Fullerene Chem. Eur. J. 2002, 8, 1544-1553.

93. N. Camaioni, G. Ridolfi, G. Casalbore-Miceli, G. Possamai, L. Garlaschelli, M. Maggini A stabilization effect of [60]fullerene in donor-acceptor organic solar cells Solar Energy Mater. & Solar Cells 2003, 76, 107-113.

94. C. Nasr, D. M. Guldi, M. Maggini, F. Paolucci, S. Hotchandani Photosensitization of Nanocrystalline SnO2 Films with a Tris(2,2'-Bipyridine) Ruthenium(II)-Fullerene Dyad Fullerenes, Nanotubes and Carbon Nanostructures 2003, 11, 121-133.

95. M. Carano, C. Corvaja, L. Garlaschelli, M. Maggini, M. Marcaccio, F. Paolucci, D. Pasini, P.P. Righetti, E. Sartori, A. Toffoletti Methanofullerenes from Macrocyclic Malonates Eur. J. Org. Chem. 2003, 374-384.

96. Cravino, G. Zerza, M. Maggini, S. Bucella, M. Svensson, M.R .Andersson, H. Neugebauer, C.J. Brabec, Sariciftci, N.S. A soluble donor-acceptor double-cable polymer: Polythiophene with pendant fullerenes Monatshefte für Chemie 2003, 134, 518-5127.

97. Possamai, N. Camaioni, G. Ridolfi, L. Franco, M. Ruzzi, E. Menna, G. Casalbore- Miceli, A. M. Fichera, G. Scorrano, C. Corvaja, M. Maggini A Fullerene-Azothiophene Dyad for Photovoltaics Synthetic Metals 2003, 139, 585-588.

98. G. Possamai, M. Maggini, E. Menna, G. Scorrano, L. Franco, M. Ruzzi, C. Corvaja, G. Ridolfi, P. Samorì, A. Geri, N. Camaioni A Fullerene-Based Dyad For Organic Photovoltaic Cells Applied Physics A 2004, 79, 51.

99. G. Ridolfi, N. Camaioni, G. Casalbore-Miceli, A. M. Fichera, M. Maggini, G. Possamai Structural Characteristics of Soluble Fullerene Films J. Solid State Electr. 2004, 8, 277.

100. P. Sofou, Y. Elemes, E. Panou-Pomonis, A. Stavrakoudis, V. Tsikaris, C. Sakarellos, M. Sakarellos-Daitsiotis, M. Maggini, F. Formaggio, C. Toniolo Synthesis of a proline-rich [60]fullerene peptide with potential biological activity Tetrahedron 2004, 60, 2823.

101. G.Fabbrini,E.Menna,M.Maggini,A.Canazza,G.Marcolongo,M.Meneghetti Zinc-induced switching of the non linear optical properties of a functionalized bis(styryl)benzene J. Am. Chem. Soc. 2004, 126, 6238.

102. P. Innocenzi, P. Falcaro, S. Schergna, M. Maggini, E. Menna, H.Amenitschd, D. Grosso, G. S. Illia, C. Sanchez One-Pot Self-Assembling of Mesostructured Silica Films and Membranes Functionalisedwith Fullerene Derivatives J. Mater. Chem. 2004, 14, 1-6.

103. G. Possamai, S. Marcuz, M. Maggini, E. Menna, L. Franco, M. Ruzzi, S. Ceola, C. Corvaja, G. Ridolfi, A. Geri, N. Camaioni, D. M. Guldi, R. Sens, T. Gessner Synthesis, Photophysics, and Photoresponse of Fullerene-Based Azoaromatic Dyads Chem. Eur. J. 2005, 11, 5765.

104. F. Cardinali, J.-L. Gallani, S. Schergna, M. Maggini, J.-F. Nierengarten An amphiphilic C60 derivative with a tris(2,2’-bipyridine)ruthenium(II) polar head group: synthesis and incorporation in Langmuir films Tetrahedron Lett. 2005, 46, 2969.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

105. G. Angelini, C. Cusan, P. De Maria, A. Fontana, M. Maggini, M. Pierini, M. Prato, S.

Schergna, C. Villani

The Associative Properties of Some Amphiphilic Fullerene Derivatives Eur. J. Org. Chem. 2005, 1884.

106. N. Camaioni, G. Fabbrini, E. Menna, M. Maggini, G. Ridolfi, A. Zanelli Synthesis and Photoresponse of a Fullerene–Bis(Styryl)Benzene Dyad New J. Chem. 2006, 30, 335–342.

107. C. Corvaja, F. Conti, L. Franco M. Maggini Spin-labeled fulleropyrrolidines Comptes Rendus Chimie 2006, 9, 909–915.

108. L. Franco, S. Ceola, C. Corvaja, S. Bolzonella, W. Harneit, M. Maggini Synthesis and magnetic properties of N@C60 derivatives Chem. Phys. Lett. 2006, 422, 100-105.

109. L. Malfatti, P. Falcaro, H. Amenitsch, S. Caramori, R. Argazzi, C. A. Bignozzi, S. Enzo, M. Maggini, P. Innocenzi Mesostructured self-assembled titania films for photovoltaic applications Microporous and Mesoporous Materials 2006, 88, 304–311.

110. Polimeno, M. Zerbetto, L. Franco, M. Maggini, C. Corvaja Stochastic Modeling of CW-ESR Spectroscopy of [60]Fulleropyrrolidine Bisadducts with Nitroxide Probes J. Am. Chem. Soc. 2006, 128, 4734-4741.

111. D. M. Guldi, E. Menna, M. Maggini, M. Marcaccio, D. Paolucci, F. Paolucci, S. Campidelli, M. Prato, G. M. Aminur Rahman, S. Schergna Supramolecular Hybrids of [60]Fullerene and Single-Wall Carbon Nanotubes Chem. Eur. J. 2006, 12, 3975-3983.

112. Bianco, M. Maggini, M. Nogarole, G. Scorrano Hydrolysis Rate of Functionalized Fullerenes Bearing Alkoxysilanes: a Comparative Study Eur. J. Org. Chem. 2006, 2934–2941.

113. R. Bozio, E. Cecchetto, G. Fabbrini, C. Ferrante, M. Maggini, E. Menna, D. Pedron, R. Riccò, R. Signorini, M. Zerbetto One- and Two-Photon Absorption and Emission Properties of a Zn(II) Chemosensor J. Phys. Chem. A 2006, 110, 6459-6464.

114. G. Fabbrini, R. Riccò, E. Menna, M. Maggini, V. Amendola, M. Garbin, M. Villano, M. Meneghetti Sequential multiphoton absorption enhancement induced by zinc complexation in functionalized distyrylbenzene analogs Phys. Chem. Chem. Phys. 2007, 9, 616-621

115. F. Nastasi, F. Puntoriero, S. Campagna, S. Schergna, M. Maggini, F. Cardinali, W. Delavaux-Nicot, J. F. Nierengarten A luminescent multicomponent species made of fullerene and Ir(III) cyclometallated subunits Chem. Commun. 2007, 3556-3558.

116. D. Dattilo, L. Armelao, G. Fois, G. Mistura, M. Maggini Wetting properties of flat and porous silicon surfaces coated with a spiropyran Langmuir 2007, 23, 12945-12950.

117. G. Casalbore-Miceli, N. Camaioni, A. Geri, G. Ridolfi, A. Zanelli, M. C. Gallazzi, M. Maggini, T. Benincori Solid state charge trapping: Examples of polymer systems showing memory effect Journal of Electroanalytical Chemistry 2007, 603, 227-234.

118. S. Campestrini, C. Corvaja, M. D. Nardi, C. Ducati, L. Franco, M. Maggini, M. Meneghetti, E. Menna, G. Ruaro Investigation of the Inner Environment of Carbon Nanotubes with a Fullerene- Nitroxide Probe Small 2008, 3, 350-356

119. T. Carofiglio, P. Donnola, M. Maggini, M. Rossetto, E. Rossi Fullerene-Promoted Singlet-

Oxygen Photochemical Oxygenations in Glass- Polymer Microstructured Reactors Adv. Synth. Catal. 2008, 350, 2815-2822.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

120. S. Carlotto, R. Ricco, C. Ferrante, M. Maggini, A. Polimeno, C. Benzi, V. Barone An

integrated approach for the interpretation of emission fluorescence of DMABN- Crown

derivatives in polar environments Chem. Phys. Lett. 2008, 467, 204-209.

121. L. Malfatti, S. Costacurta, T. Kidchob, P. Innocenzi, M. Casula, H. Amenitsch, D. Dattilo, M. Maggini Mesostructured self-assembled silica films with reversible thermo-photochromic properties Microporous Mesoporous Mat. 2009, 120, 375-380.

122. Guryanov, F. M. Toma, A. M. Lopez, M. Carraro, T. Da Ros, G. Angelini, E. D'Aurizio, A. Fontana, M. Maggini, M. Prato, M. Bonchio Microwave-Assisted Functionalization of Carbon Nanostructures in Ionic Liquids Chem.-Eur. J. 2009, 15, 12837-12845.

123. Guryanov, A. M. Lopez, M. Carraro, T. Da Ros, G. Scorrano, M. Maggini, M. Prato, M. Bonchio Metal-free, retro-cycloaddition of fulleropyrrolidines in ionic liquids under microwave irradiation Chem. Commun. 2009, 3940-3942.

124. F. Conti, C. Corvaja, F. Busolo, G. Zordan, M. Maggini, S. Weber Time-resolved EPR investigation of [70]fulleropyrrolidine nitroxide isomers Phys. Chem. Chem. Phys. 2009, 11, 495-502.

125. R. Po, M. Maggini, N. Camaioni Polymer Solar Cells: Recent Approaches and Achievements J. Phys. Chem. C 2010, 114, 695-706.

126. F. Busolo, L. Franco, L. Armelao, M. Maggini Dynamics of a Nitroxide Layer Grafted onto Porous Silicon Langmuir 2010, 26, 1889-1893.

127. E. Collini, I. Fortunati, S. Scolaro, R. Signorini, C. Ferrante, R. Bozio, G. Fabbrini, M. Maggini, E. Rossi and S. Silvestrini A fullerene-distyrylbenzene photosensitizer for two-photon promoted singlet oxygen production

Phys. Chem. Chem. Phys. 2010, 12, 4656-4666. 128. E. Rossi, T. Carofiglio, A. Venturi, A. Ndobe, M. Muccini, M. Maggini Continuous-flow

synthesis of an efficient methanofullerene acceptor for bulk- heterojunction solar cells Energy & Environmental Science 2011, 4, 725.

129. S. Silvestrini, D. Dalle Nogare, T. Carofiglio, E. Menna, P. Canu, M. Maggini Continuous flow synthesis of methanofullerenes in microstructured reactors: a kinetic study Eur. J. Org. Chem. 2011, 5571.

130. P. Salice, P. Maity, E. Rossi, T. Carofiglio, E. Menna, M. Maggini The continuous-flow cycloadditions of azomethyne ylides to carbon nanotubes Chem. Commun. 2011, 47, 9092.

131. M. Mba, A. Moretto, L. Armelao, M. Crisma, C. Toniolo, M. Maggini Synthesis and Self-Assembly of Oligo(p-phenylenevinylene) Peptide Conjugates in Water Chem. Eur. J. 2011, 17, 2044.

132. M. Seri, E. Rossi, T. Carofiglio, S. Antonello, G. Ruani, M. Maggini, M. Muccini Efficient as-cast bulk-heterojunction solar cells based on a tert-butyl substituted methanofullerene acceptor J. Mater. Chem. 2011, 21, 18308.

133. I. Concina, E. Frison, A. Braga, S. Silvestrini, M. Maggini, G. Sberveglieri, A. Vomiero, T. Carofiglio On-line monitoring and active control of dye uptake in dye-sensitised solar cells Chem. Commun. 2011, 47, 11656.

134. S. Silvestrini, D. Ferraro, T. Toth, M. Pierno, T. Carofiglio, G.Mistura, M. Maggini, "Tailoring the wetting properties of thiolene microfluidic materials" Lab-on-a-chip 2012, 12, 4041-4043.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

135. E.M. Benetti, V. Causin, M. Maggini, "Conjugated Polymers in Cages: Templating Poly(3-

hexylthiophene) Nanocrystals by Inert Gel Matrices"

Adv. Mater. 2012, 114, 5636-5641. 136. E. Rossi, P. Woehl, M. Maggini, " Scalable in Situ Diazomethane Generation in Continuous-

Flow Reactors" Organic Process Research & Development 2012, 16, 1146-1149.

137. A. Ciogli, A. Fontana, F. Gasparrini, M. Maggini, M. Giovannoli, M. Pierini, F. Busolo, G. Siani, C. Villani Inductive and Mesomeric Effects of the [60]Fulleropyrrolidine Fragment and [60]Fullerene

Sphere: A Quantitative Evaluation Based on Theory and Experiments

138. L. Franco, A. Toffoletti, M. Maggini, " Time resolved EPR of [70]fullerene monoadducts in the

photoexcited triplet state", Phys. Chem. Chem. Phys. 2012, 41, 14358-14364.

139. S. Silvestrini, T. Carofiglio, M. Maggini Shape-selective growth of silver nanoparticles under continuous flow photochemical conditions Chem. Commun. 2013, 49, 84-86.

140. P. Chauhan, C. Hadad, A. Sartorelli, M. Zarattini, A. Herreros-López, M. Mba, M. Maggini, M. Prato, T. Carofiglio, Nanocrystalline cellulose– porphyrin hybrids: synthesis, supramolecular properties, and singlet-oxygen production Chem. Commun. 2013, 49, 1359-7345.

141. M. Mba, M. D’Acunzo, P. Salice, T. Carofiglio, M. Maggini, S. Caramori, A. Campana, A. Aliprandi, R. Argazzi, S. Carli, C. A. Bignozzi Sensitization of Nanocrystalline TiO2 with Multibranched Organic Dyes and Co(III)/(II)

Mediators: Strategies to Improve Charge Collection Efficiency

J. Phys. Chem. C 2013, 117, 19885-19896. 142. P. Chauhan, C. Hadad, A. H. Lopez, S. Silvestrini, V. La Parola, E. Frison, M. Maggini, M.

Prato, T. Carofiglio. A nanocellulose-dye conjugate for multi-format optical pH-sensing Chem. Commun. 2014, 50, 9493-9496.

143. Mazzier, D.; Favaro, M.; Agnoli, S.; Silvestrini, S.; Granozzi, G.; Maggini, M.; Moretto, A. Synthesis of luminescent 3D microstructures formed by carbon quantum dots and their self-assembly properties Chem. Commun. 2014, 50, 6592-6595.

144. Tampieri, F.; Silvestrini, S.; Ricco, R.; Maggini, M.; Barbon, A. A comparative electron paramagnetic resonance study of expanded graphites and graphene J. Mater. Chem. 2014, 2, 8105-8112.

145. De Filippo, C. C.; Tang, H.; Ravotto, L.; Bergamini, G.; Salice, P.; Mba, M.; Ceroni, P.; Galoppini, E.; Maggini, M. Synthesis and Electronic Properties of 1,2-Hemisquarimines and Their Encapsulation in a Cucurbit-7-uril Host Chemistry-a European Journal 2014, 20 (21), 6412-6420.

146. Marcia, M.; Singh, P.; Hauke, F.; Maggini, M.; Hirsch, A. Novel EDTA- ligands containing an integral perylene bisimide (PBI) core as an optical reporter unit Organic & Biomolecular Chemistry 2014, 12, 7045-7058.

147. Salice, P.; Ronchi, E.; Iacchetti, A.; Binda, M.; Natali, D.; Gomulya, W.; Manca, M.; Loi, M. A.; Iurlo, M.; Paolucci, F.; Maggini, M.; Pagani, G. A.; Beverina, L.; Menna, E. A fulleropyrrolidine-squaraine blue dyad: synthesis and application as an organic light detector J. Mater. Chem. C 2014, 2, 1396-1399.

148. Salice,P.;Rossi,E.;Pace,A.;Maity,P.;Carofiglio,T.;Menna,E.;Maggini, M.

Chemistry of Carbon Nanotubes in Flow.

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DIPARTIMENTO DI SCIENZE CHIMICHE Michele Maggini

J. Flow. Chem. 2014, 4, 79-85. 149. Zuccon S.;Zuppella,P.;Cristofani,M.;Silvestrini,S.;Corso,A.J.;Maggini, M.; Pelizzo, M. G.

Functional palladium metal films for plasmonic devices: an experimental proof. Journal of Optics 2014, 16 (5).

150. S. Bartocci, I. Morbioli, M. Maggini, M. Mba Solvent-tunable morphology and emission of pyrene-dipeptide organogels J. Peptide Sci. 2015, 21, 871-878.

151. G. Morgese, V. Causin, M. Maggini, S. Corra, S. Gross, E.M. Benetti Ultrastable Suspensions of Polyoxazoline-Functionalized ZnO Single Nanocrystals Chem. Mater. 2015, 27, 2957-2964.

152. S. Rossi, M. Benaglia, A. Puglisi, C.C. De Filippo, M. Maggini Continuous-Flow Stereoselective Synthesis in Microreactors: Nucleophilic Additions to Nitrostyrenes Organocatalyzed by a Chiral Bifunctional Catalyst J. Flow Chem. 2015, 5, 17-21.

153. K. Suzuki, L. Malfatti, D. Carboni, D. Loche, M. Casula, A. Moretto, M. Maggini, M. Takahashi, P. Innocenzi Energy Transfer Induced by Carbon Quantum Dots in Porous Zinc Oxide Nanocomposite Films

J. Phys. Chem. C 2015, 119, 2837-2843. 154. F. Nastasi, F. Puntoriero, M. Natali, M. Mba, M. Maggini, P. Mussini, M. Panigati, S.

Campagna Photoinduced intercomponent excited-state decays in a molecular dyad made of a dinuclear rhenium(I) chromophore and a fullerene electron acceptor unit Photochem. Photobiol. Sci. 2015, 14, 909-918.

155. M. Cristofani, E. Menna, M. Seri, M. Muccini, M. Prosa, S. Antonello, M. Mba, L. Franco, M. Maggini Tuning the Electron-Acceptor Properties of [60]Fullerene by Tailored Functionalization for Application in Bulk Heterojunction Solar Cells Asian J. Org. Chem 2016, 5, 676-684.

156. S.V. Suru, C.C. De Filippo, S. Silvestrini, M. Maggini, E. Iwuoha Novel 5-(Benzo[b]thiophen-3-yl)pyridine-3-carbaldehyde(BTPA) Functionalization Framework For Modulating Fullerene Electronics Chemistryopen 2017, 6, 354-359.

157. T. Gatti, E. Menna, M. Meneghetti, M. Maggini, A. Petrozza, F. Lamberti The Renaissance of fullerenes with perovskite solar cells Nano Energy 2017, 41, 84-100

158. N. Licciardello, S. Hunoldt, R. Bergmann, G. Singh, C. Mamat, A. Faramus, J. L. Z. Ddungu, S. Silvestrini, M. Maggini, L. De Cola, H. Stephan Biodistribution studies of ultrasmall silicon nanoparticles and carbon dots in experimental rats and tumor mice

Nanoscale, 2018, 21, 9880-9891 159. S. Silvestrini, C. C. De Filippo, N. Vicentini, E. Menna, R. Mazzaro, V. Morandi, L. Ravotto, P.

Ceroni, M. Maggini Controlled functionalization of reduced graphene oxide enabled by microfluidic reactors

Chem. Mater. 2018, 30, 2905-2914

160. M. Da Pian, M. Maggini, G. J. Vancso, V. Causin, E. M. Benetti Assembly of poly-3-(hexylthiophene) nanocrystals in marginal solvent: the role of PCBM Eur. Polymer J. 2018, 109, 222-228

161. S. Menichetti, C. Faggi, M. Onori, S. Piantini, M. Ferreira, S. Rocchi, M. Lupi, I. Marin, M. Maggini, C. Viglianisi Thia-bridged triarylamine hetero[4]helicenes: regioselective synthesis and

functionalization

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Eur. J. Org. Chem 2019, 1, 168-175

162. M. Da Pian, M. Maggini, G. J. Vancso, V. Causin, E. M. Benetti Poly(3-hexylthiophene) nanowhiskers filler in poly(ε-caprolactone) based nanoblends as potential bioactive material Eur. Polymer J. 2019, 114, 144-150

163. M. C. Frare, R. Pilot, C. C. De Filippo, V. Weber, R. Signorini, M. Maggini, R. Bozio Fullerene functionalized gold nanoparticles for optical limiting of continuous wave

lasers

Appl. Phys. B 2019, 125:47