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ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-103-JUL-19 Date Collected:
General
Drinking Water Full Package
Colour, True
Conductivity
Turbidity
pH
Total Dissolved Solids
Sulfate (SO4)
Nitrite (as N)
Nitrate (as N)
Fluoride (F)
Chloride (Cl)
Alkalinity, Total (as CaCO3)
Total Dissolved Solids by Gravimetric
Sulfate in Water by IC
Nitrite in Water by IC (Low Level)
Nitrate in Water by IC (Low Level)
Fluoride in Water by IC
Chloride in Water by IC
Alkalinity Species by Titration
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
CU
uS/cm
NTU
pH
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
1
10
1.5
15
7-10.5
500
500
250
<5.0
493
1.23
8.46
345
56.9
<0.0010
0.147
0.098
15.0
193
GB #1Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
*
*
*
06-JUL-19
08-JUL-19
05-JUL-19
08-JUL-19
09-JUL-19
16-JUL-19
16-JUL-19
16-JUL-19
16-JUL-19
16-JUL-19
08-JUL-19
1PAGE of
HTD
HTD
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-203-JUL-19 Date Collected:
General
Drinking Water Full Package
Colour, True
Conductivity
Turbidity
pH
Total Dissolved Solids
Sulfate (SO4)
Nitrite (as N)
Nitrate (as N)
Fluoride (F)
Chloride (Cl)
Alkalinity, Total (as CaCO3)
Total Dissolved Solids by Gravimetric
Sulfate in Water by IC
Nitrite in Water by IC (Low Level)
Nitrate in Water by IC (Low Level)
Fluoride in Water by IC
Chloride in Water by IC
Alkalinity Species by Titration
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
CU
uS/cm
NTU
pH
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
1
10
1.5
15
7-10.5
500
500
250
<5.0
468
0.70
8.18
309
56.2
<0.0010
0.146
0.099
14.8
192
GB #2Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
*
*
*
12-JUL-19
14-JUL-19
12-JUL-19
14-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
14-JUL-19
2PAGE of
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-303-JUL-19 Date Collected:
Metals
Hardness (as CaCO3)
Aluminum (Al)-TotalAntimony (Sb)-TotalArsenic (As)-TotalBarium (Ba)-TotalBeryllium (Be)-TotalBismuth (Bi)-TotalBoron (B)-TotalCadmium (Cd)-TotalCalcium (Ca)-TotalCesium (Cs)-TotalChromium (Cr)-TotalCobalt (Co)-TotalCopper (Cu)-TotalIron (Fe)-TotalLead (Pb)-TotalLithium (Li)-TotalMagnesium (Mg)-TotalManganese (Mn)-TotalMolybdenum (Mo)-TotalNickel (Ni)-TotalPhosphorus (P)-TotalPotassium (K)-TotalRubidium (Rb)-TotalSelenium (Se)-TotalSilicon (Si)-TotalSilver (Ag)-TotalSodium (Na)-TotalStrontium (Sr)-TotalSulfur (S)-TotalTellurium (Te)-TotalThallium (Tl)-TotalThorium (Th)-TotalTin (Sn)-TotalTitanium (Ti)-TotalTungsten (W)-TotalUranium (U)-TotalVanadium (V)-TotalZinc (Zn)-TotalZirconium (Zr)-Total
Total Metals in Water by CRC ICPMS
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
mg/L
mg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L
0.0060.01
1
50.005
0.05
2.0
0.005
0.12
0.05
0.02
500
0.1
1.00.3
0.02
200
5.0
246
<0.00300.000110.003250.0188
<0.00010<0.000050
0.259<0.0000050
47.9<0.0000100.00495
<0.000100.001130.161
0.0001330.007330.7
0.001180.004440.00216<0.0504.20
0.000510.00185
9.90<0.000010
6.450.20020.5
<0.00020<0.000010<0.00010<0.00010<0.000300.000110.0000920.000570.0070
<0.00020
GB #3Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
15-JUL-19
13-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-19
3PAGE of
HTC
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-303-JUL-19 Date Collected:
MetalsMatrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
GB #3Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
4PAGE of
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-403-JUL-19 Date Collected:
Metals
Hardness (as CaCO3)
Aluminum (Al)-TotalAntimony (Sb)-TotalArsenic (As)-TotalBarium (Ba)-TotalBeryllium (Be)-TotalBismuth (Bi)-TotalBoron (B)-TotalCadmium (Cd)-TotalCalcium (Ca)-TotalCesium (Cs)-TotalChromium (Cr)-TotalCobalt (Co)-TotalCopper (Cu)-TotalIron (Fe)-TotalLead (Pb)-TotalLithium (Li)-TotalMagnesium (Mg)-TotalManganese (Mn)-TotalMolybdenum (Mo)-TotalNickel (Ni)-TotalPhosphorus (P)-TotalPotassium (K)-TotalRubidium (Rb)-TotalSelenium (Se)-TotalSilicon (Si)-TotalSilver (Ag)-TotalSodium (Na)-TotalStrontium (Sr)-TotalSulfur (S)-TotalTellurium (Te)-TotalThallium (Tl)-TotalThorium (Th)-TotalTin (Sn)-TotalTitanium (Ti)-TotalTungsten (W)-TotalUranium (U)-TotalVanadium (V)-TotalZinc (Zn)-TotalZirconium (Zr)-Total
Total Metals in Water by CRC ICPMS
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
mg/L
mg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L
0.0060.01
1
50.005
0.05
2.0
0.005
0.12
0.05
0.02
500
0.1
1.00.3
0.02
200
5.0
251
<0.00300.000110.003340.0192
<0.00010<0.000050
0.259<0.0000050
47.5<0.0000100.00481
<0.000100.001150.167
0.0001390.007032.1
0.001330.004640.00214<0.0504.39
0.000570.00184
9.43<0.000010
7.010.20520.3
<0.00020<0.000010<0.00010<0.00010<0.000300.000100.0001040.000650.0064
<0.00020
GB #4Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
15-JUL-19
13-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-19
5PAGE of
HTC
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-403-JUL-19 Date Collected:
MetalsMatrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
GB #4Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
6PAGE of
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-503-JUL-19 Date Collected:
Merc
Mercury (Hg)-Total
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
mg/L 0.001<0.000050
GB #5Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
16-JUL-19
7PAGE of
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
ResultCDWQG
MACUnits of MeasureTest Description Aesthetic
ObjectiveDate
AnalyzedQualifier
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
L2304543-603-JUL-19 Date Collected:
Merc
Mercury (Hg)-Total
Matrix:Lab Sample ID:
Sampled By:
Box 219 - 1350 Aster StreetPemberton BC V0N 2L0
Edward WitwickiATTN:
SQUAMISH-LILLOOET REG. DISTRICT
mg/L 0.001<0.000050
GB #6Sample ID:
L2304543
Date:PO No.:
WO No.:
17-JUL-19
16-JUL-19
8PAGE of
ADDITIONAL 12-JUL-19 12:28
* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.
CDWQG = Health Canada Guideline Limits updated JUNE 2019
Approved byCarla FuginskiAccount Manager
Project Ref:
9
Guidelines & Objectives
L2304543 CONTD....
Health Canada MAC Health Related Criteria LimitsNitrate/Nitrite-N* Criteria limit is 10 mg/L (1.0 mg/L if present as all Nitrite-N). High concentrations may contribute to blue baby syndrome in infants.Lead* A cumulative body poison, uncommon in naturally occurring hard waters.Fluoride* Present in fluoridated water supplies at 0.8 mg/L to reduce dental caries. Elevated levels causes fluorosis (mottling of teeth).Total Coliforms* Criteria is 0 CFU/100mL. Adverse health effects.E. Coli* Criteria is 0 CFU/100 mL. Certain E. Coli bacteria can be life threatening.
*Health Canada Canadian Drinking Water Quality Guidelines (MAC limit)
Aesthetic Objective Concentration LevelsAlkalinity Acid neutralizing capacity. Usually a measure of carbonate and bicarbonates and calculated and reported as calcium carbonate.Balance Quality control parameter ratioing cations to anionsBicarbonate See Alkalinity. Report as the anion HCO3-1Carbonate See Alkalinity. Reported at the anion CO3-2Calcium See Hardness. Common major cation of water chemistry.Chloride Common major anion of water chemistry.Conductance Physical test measuring water salinity (dissolved ions or solids)Hardness Classical measure or capacity of water to precipitate soap (chiefly calcium and magnesium ions). Causes scaling tendency in water if carbonates/bicarbonates are present (if >200 mg/L). For drinking water purposes waters with results <200 mg/L are considered acceptable, results >200 mg/L are considered poor but can be tolerated. Results >500 mg/L are unacceptable.Hydroxide See alkalinityMagnesium See hardness. Common major cation of water chemistry. Elevated levels (>125 mg/L) may exert a cathartic or diuretic action.pH Measure of water acidity/alkalinity. Normal range is 7.0-8.5.Potassium Common major cation of water chemistry.Sodium Common major cation of water chemistry. Measure of salinity (saltiness).The aesthetic objective (not related to health) for sodium in drinking water is 200 mg/L. However, where sodium concentration of the drinking water exceeds 20 mg/L, it is recommended that any person on a sodium restricted diet consult with his/her physician or Medical Officer of Health concerning the use of that water.Sulphate Common major anion of water chemistry. Elevated levels may exert a cathartic or diuretic action.Total Dissolved Solids A measure of water salinity.Iron Causes staining to laundry and porcelain and astringent taste. Oxidizes to red-brown precipitate on exposure to air.Manganese Elevated levels may cause staining of laundry and porcelain.HeterotrophicPlate Count Criteria is 500 cfu/mL Measure of heterotrophic bacteria present.
9PAGE of
HTD
HTC
Hold time exceeded for re-analysis or dilution, but initial testing was conducted within hold time.
Hardness was calculated from Total Ca and/or Mg concentrations and may be biased high (dissolved Ca/Mg results unavailable).
Sample Parameter Qualifier key listed:
Description Qualifier
GLOSSARY OF REPORT TERMSSurrogates are compounds that are similar in behaviour to target analyte(s), but that do not normally occur in environmental samples. For applicable tests, surrogates are added to samples prior to analysis as a check on recovery. In reports that display the D.L. column, laboratory objectives for surrogates are listed there.mg/kg - milligrams per kilogram based on dry weight of samplemg/kg wwt - milligrams per kilogram based on wet weight of samplemg/kg lwt - milligrams per kilogram based on lipid-adjusted weight mg/L - unit of concentration based on volume, parts per million.< - Less than.D.L. - The reporting limit.N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.
9
Quality Control ReportPage 1 of
Client:
Contact:
SQUAMISH-LILLOOET REG. DISTRICTBox 219 - 1350 Aster Street Pemberton BC V0N 2L0Edward Witwicki
Report Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
ALK-TITR-VA
CL-IC-N-VA
COLOUR-TRUE-VA
EC-PCT-VA
Water
Water
Water
Water
R4696300
R4710468
R4707905
R4712725
R4712860
R4695596
R4709367
Batch
Batch
Batch
Batch
Batch
Batch
Batch
CRM
MB
CRM
MB
LCS
MB
LCS
MB
LCS
MB
CRM
MB
CRM
MB
WG3097567-3
WG3097567-1
WG3103651-3
WG3103651-1
WG3096945-2
WG3096945-1
WG3103657-2
WG3103657-1
WG3106300-2
WG3106300-1
WG3096692-2
WG3096692-1
WG3103587-2
WG3103587-1
VA-ALK-TITR-CONTROL
VA-ALK-TITR-CONTROL
VA-COLOUR-T
VA-COLOUR-T
Alkalinity, Total (as CaCO3)
Alkalinity, Total (as CaCO3)
Alkalinity, Total (as CaCO3)
Alkalinity, Total (as CaCO3)
Chloride (Cl)
Chloride (Cl)
Chloride (Cl)
Chloride (Cl)
Chloride (Cl)
Chloride (Cl)
Colour, True
Colour, True
Colour, True
Colour, True
101.3
<1.0
102.1
<1.0
100.8
<0.50
101.5
<0.50
103.4
<0.50
96.1
<5.0
97.6
<5.0
08-JUL-19
08-JUL-19
14-JUL-19
14-JUL-19
06-JUL-19
06-JUL-19
13-JUL-19
13-JUL-19
16-JUL-19
16-JUL-19
06-JUL-19
06-JUL-19
12-JUL-19
12-JUL-19
85-115
85-115
90-110
90-110
90-110
85-115
85-115
%
mg/L
%
mg/L
%
mg/L
%
mg/L
%
mg/L
%
CU
%
CU
1
1
0.5
0.5
0.5
5
5
11
Quality Control ReportPage 2 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
EC-PCT-VA
F-IC-N-VA
HG-TOT-CVAFS-VA
MET-T-CCMS-VA
Water
Water
Water
Water
R4696300
R4710468
R4707905
R4712725
R4712860
R4712364
R4709654
Batch
Batch
Batch
Batch
Batch
Batch
Batch
CRM
MB
CRM
MB
LCS
MB
LCS
MB
LCS
MB
LCS
MB
LCS
WG3097567-4
WG3097567-1
WG3103651-4
WG3103651-1
WG3096945-2
WG3096945-1
WG3103657-2
WG3103657-1
WG3106300-2
WG3106300-1
WG3106081-2
WG3106081-1
WG3104190-2
VA-EC-PCT-CONTROL
VA-EC-PCT-CONTROL
Conductivity
Conductivity
Conductivity
Conductivity
Fluoride (F)
Fluoride (F)
Fluoride (F)
Fluoride (F)
Fluoride (F)
Fluoride (F)
Mercury (Hg)-Total
Mercury (Hg)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
100.1
<2.0
96.7
<2.0
100.7
<0.020
104.0
<0.020
104.5
<0.020
99.0
<0.000050
110.3
106.0
103.8
08-JUL-19
08-JUL-19
14-JUL-19
14-JUL-19
06-JUL-19
06-JUL-19
13-JUL-19
13-JUL-19
16-JUL-19
16-JUL-19
16-JUL-19
16-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
90-110
90-110
90-110
90-110
90-110
80-120
80-120
80-120
80-120
%
uS/cm
%
uS/cm
%
mg/L
%
mg/L
%
mg/L
%
mg/L
%
%
%
2
2
0.02
0.02
0.02
0.00005
11
Quality Control ReportPage 3 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-T-CCMS-VA Water
R4709654BatchLCSWG3104190-2
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Calcium (Ca)-Total
Cesium (Cs)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Magnesium (Mg)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Phosphorus (P)-Total
Potassium (K)-Total
Rubidium (Rb)-Total
Selenium (Se)-Total
Silicon (Si)-Total
Silver (Ag)-Total
Sodium (Na)-Total
Strontium (Sr)-Total
Sulfur (S)-Total
Tellurium (Te)-Total
Thallium (Tl)-Total
Thorium (Th)-Total
Tin (Sn)-Total
Titanium (Ti)-Total
Tungsten (W)-Total
Uranium (U)-Total
Vanadium (V)-Total
103.0
98.5
103.0
91.0
99.96
99.2
104.5
101.6
102.3
100.0
101.5
103.4
96.0
104.5
105.3
100.2
100.4
113.1
110.9
107.0
100.9
100.9
101.1
110.1
105.5
103.6
101.3
102.6
105.5
102.3
103.6
105.9
105.0
105.1
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
11
Quality Control ReportPage 4 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-T-CCMS-VA Water
R4709654BatchLCS
MB
WG3104190-2
WG3104190-1
Zinc (Zn)-Total
Zirconium (Zr)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Calcium (Ca)-Total
Cesium (Cs)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Magnesium (Mg)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Phosphorus (P)-Total
Potassium (K)-Total
Rubidium (Rb)-Total
Selenium (Se)-Total
Silicon (Si)-Total
Silver (Ag)-Total
Sodium (Na)-Total
Strontium (Sr)-Total
Sulfur (S)-Total
Tellurium (Te)-Total
Thallium (Tl)-Total
103.6
100.1
<0.0030
<0.00010
<0.00010
<0.00010
<0.00010
<0.000050
<0.010
<0.0000050
<0.050
<0.000010
0.00013
<0.00010
<0.00050
<0.010
<0.000050
<0.0010
<0.0050
<0.00010
<0.000050
<0.00050
<0.050
<0.050
<0.00020
<0.000050
<0.10
<0.000010
<0.050
<0.00020
<0.50
<0.00020
<0.000010
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
80-120
80-120
%
%
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
MB-LOR
0.003
0.0001
0.0001
0.0001
0.0001
0.00005
0.01
0.000005
0.05
0.00001
0.0001
0.0001
0.0005
0.01
0.00005
0.001
0.005
0.0001
0.00005
0.0005
0.05
0.05
0.0002
0.00005
0.1
0.00001
0.05
0.0002
0.5
0.0002
0.00001
11
Quality Control ReportPage 5 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-T-CCMS-VA Water
R4709654
R4712092
Batch
Batch
MB
LCS
WG3104190-1
WG3104133-2
Thorium (Th)-Total
Tin (Sn)-Total
Titanium (Ti)-Total
Tungsten (W)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Zirconium (Zr)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Calcium (Ca)-Total
Cesium (Cs)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Magnesium (Mg)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Phosphorus (P)-Total
Potassium (K)-Total
Rubidium (Rb)-Total
Selenium (Se)-Total
<0.00010
<0.00010
<0.00030
<0.00010
<0.000010
<0.00050
<0.0030
<0.00020
106.1
106.1
103.0
112.1
105.1
105.3
104.4
108.2
105.4
100.6
110.1
104.3
104.1
104.3
107.3
104.2
103.1
106.8
107.6
106.1
102.2
110.8
109.8
110.7
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
0.0001
0.0001
0.0003
0.0001
0.00001
0.0005
0.003
0.0002
11
Quality Control ReportPage 6 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-T-CCMS-VA Water
R4712092BatchLCS
MB
WG3104133-2
WG3104133-1 NP
Silicon (Si)-Total
Silver (Ag)-Total
Sodium (Na)-Total
Strontium (Sr)-Total
Sulfur (S)-Total
Tellurium (Te)-Total
Thallium (Tl)-Total
Thorium (Th)-Total
Tin (Sn)-Total
Titanium (Ti)-Total
Tungsten (W)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Zirconium (Zr)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Calcium (Ca)-Total
Cesium (Cs)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Magnesium (Mg)-Total
Manganese (Mn)-Total
102.4
106.1
101.8
106.6
101.6
103.7
109.0
107.9
105.4
105.5
111.2
105.8
107.8
110.5
110.4
<0.0030
<0.00010
<0.00010
<0.00010
<0.00010
<0.000050
<0.010
<0.0000050
<0.050
<0.000010
<0.00010
<0.00010
<0.00050
<0.010
<0.000050
<0.0010
<0.0050
<0.00010
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
80-120
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
0.003
0.0001
0.0001
0.0001
0.0001
0.00005
0.01
0.000005
0.05
0.00001
0.0001
0.0001
0.0005
0.01
0.00005
0.001
0.005
0.0001
11
Quality Control ReportPage 7 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-T-CCMS-VA
NO2-L-IC-N-VA
Water
Water
R4712092
R4707905
R4712725
Batch
Batch
Batch
MB
LCS
MB
LCS
MB
WG3104133-1
WG3096945-2
WG3096945-1
WG3103657-2
WG3103657-1
NPMolybdenum (Mo)-Total
Nickel (Ni)-Total
Phosphorus (P)-Total
Potassium (K)-Total
Rubidium (Rb)-Total
Selenium (Se)-Total
Silicon (Si)-Total
Silver (Ag)-Total
Sodium (Na)-Total
Strontium (Sr)-Total
Sulfur (S)-Total
Tellurium (Te)-Total
Thallium (Tl)-Total
Thorium (Th)-Total
Tin (Sn)-Total
Titanium (Ti)-Total
Tungsten (W)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Zirconium (Zr)-Total
Nitrite (as N)
Nitrite (as N)
Nitrite (as N)
Nitrite (as N)
<0.000050
<0.00050
<0.050
<0.050
<0.00020
<0.000050
<0.10
<0.000010
<0.050
<0.00020
<0.50
<0.00020
<0.000010
<0.00010
<0.00010
<0.00030
<0.00010
<0.000010
<0.00050
<0.0030
<0.00020
98.4
<0.0010
102.5
<0.0010
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
06-JUL-19
06-JUL-19
13-JUL-19
13-JUL-19
90-110
90-110
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
mg/L
%
mg/L
0.00005
0.0005
0.05
0.05
0.0002
0.00005
0.1
0.00001
0.05
0.0002
0.5
0.0002
0.00001
0.0001
0.0001
0.0003
0.0001
0.00001
0.0005
0.003
0.0002
0.001
0.001
11
Quality Control ReportPage 8 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
NO2-L-IC-N-VA
NO3-L-IC-N-VA
PH-PCT-VA
SO4-IC-N-VA
Water
Water
Water
Water
R4712860
R4707905
R4712725
R4712860
R4696300
R4710468
R4707905
Batch
Batch
Batch
Batch
Batch
Batch
Batch
LCS
MB
LCS
MB
LCS
MB
LCS
MB
CRM
CRM
LCS
MB
WG3106300-2
WG3106300-1
WG3096945-2
WG3096945-1
WG3103657-2
WG3103657-1
WG3106300-2
WG3106300-1
WG3097567-2
WG3103651-2
WG3096945-2
WG3096945-1
VA-PH7-BUF
VA-PH7-BUF
Nitrite (as N)
Nitrite (as N)
Nitrate (as N)
Nitrate (as N)
Nitrate (as N)
Nitrate (as N)
Nitrate (as N)
Nitrate (as N)
pH
pH
Sulfate (SO4)
Sulfate (SO4)
102.8
<0.0010
101.2
<0.0050
102.2
<0.0050
103.9
<0.0050
7.01
7.00
102.7
<0.30
16-JUL-19
16-JUL-19
06-JUL-19
06-JUL-19
13-JUL-19
13-JUL-19
16-JUL-19
16-JUL-19
08-JUL-19
14-JUL-19
06-JUL-19
06-JUL-19
90-110
90-110
90-110
90-110
6.9-7.1
6.9-7.1
90-110
%
mg/L
%
mg/L
%
mg/L
%
mg/L
pH
pH
%
mg/L
0.001
0.005
0.005
0.005
0.3
11
Quality Control ReportPage 9 ofReport Date: 17-JUL-19Workorder: L2304543
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
SO4-IC-N-VA
TDS-VA
TURBIDITY-VA
Water
Water
Water
R4712725
R4712860
R4704050
R4709650
R4694924
R4709191
Batch
Batch
Batch
Batch
Batch
Batch
LCS
MB
LCS
MB
LCS
MB
DUP
LCS
MB
CRM
DUP
MB
CRM
MB
WG3103657-2
WG3103657-1
WG3106300-2
WG3106300-1
WG3099519-2
WG3099519-1
WG3104183-3
WG3104183-2
WG3104183-1
WG3097106-2
WG3097106-3
WG3097106-1
WG3103695-2
WG3103695-1
L2304543-2
VA-FORM-40
L2304543-1
VA-FORM-40
Sulfate (SO4)
Sulfate (SO4)
Sulfate (SO4)
Sulfate (SO4)
Total Dissolved Solids
Total Dissolved Solids
Total Dissolved Solids
Total Dissolved Solids
Total Dissolved Solids
Turbidity
Turbidity
Turbidity
Turbidity
Turbidity
103.6
<0.30
105.4
<0.30
102.2
<10
312
99.3
<10
108.1
1.20
<0.10
103.8
<0.10
13-JUL-19
13-JUL-19
16-JUL-19
16-JUL-19
09-JUL-19
09-JUL-19
13-JUL-19
13-JUL-19
13-JUL-19
05-JUL-19
05-JUL-19
05-JUL-19
12-JUL-19
12-JUL-19
1.0
2.5
20
15
90-110
90-110
85-115
85-115
85-115
85-115
%
mg/L
%
mg/L
%
mg/L
mg/L
%
mg/L
%
NTU
NTU
%
NTU
0.3
0.3
10
10
0.1
0.1
309
1.23
11
Quality Control ReportPage 10 ofReport Date: 17-JUL-19Workorder: L2304543
Sample Parameter Qualifier Definitions:
Description Qualifier
MB-LOR Method Blank exceeds ALS DQO. Limits of Reporting have been adjusted for samples with positive hits below 5x blank level.
Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate
Legend:
11
Quality Control ReportPage 11 ofReport Date: 17-JUL-19Workorder: L2304543
ALS Product Description Sample
ID Sampling Date Date Processed Rec. HT Actual HT
Physical Tests
Anions and Nutrients
2
2
2
12
12
12
03-JUL-19 15:40
03-JUL-19 15:40
03-JUL-19 15:40
03-JUL-19 15:4003-JUL-19 15:40
03-JUL-19 15:4003-JUL-19 15:40
03-JUL-19 15:4003-JUL-19 15:40
12-JUL-19 23:19
13-JUL-19 01:20
12-JUL-19 12:29
08-JUL-19 09:1414-JUL-19 08:09
16-JUL-19 07:4213-JUL-19 08:28
16-JUL-19 07:4213-JUL-19 08:28
3
7
3
0.250.25
33
33
9
9
9
114257
1310
1310
Colour (True) by Spectrometer
Total Dissolved Solids by Gravimetric
Turbidity by Meter
pH by Meter (Automated)
Nitrate in Water by IC (Low Level)
Nitrite in Water by IC (Low Level)
EHT
EHT
EHT
EHTR-FMEHTR-FM
EHTEHT
EHTEHT
Qualifier
Legend & Qualifier Definitions:
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
Hold Time Exceedances:
Notes*:Where actual sampling date is not provided to ALS, the date (& time) of receipt is used for calculation purposes.Where actual sampling time is not provided to ALS, the earlier of 12 noon on the sampling date or the time (& date) of receipt isused for calculation purposes. Samples for L2304543 were received on 05-JUL-19 08:40.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal governmentrequirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by theUS EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
Units
days
days
days
hourshours
daysdays
daysdays
EHTR-FM: EHTR: EHTL: EHT: Rec. HT:
Exceeded ALS recommended hold time prior to sample receipt. Field Measurement recommended.Exceeded ALS recommended hold time prior to sample receipt.Exceeded ALS recommended hold time prior to analysis. Sample was received less than 24 hours prior to expiry.Exceeded ALS recommended hold time prior to analysis.ALS recommended hold time (see units).
11