CRC Report No. E-77-2c STUDY TO - Coordinating Research Council

COORDINATING RESEARCH COUNCIL INC

3650 MANSELL ROADSUITE 140ALPHARETTA GA 30022

CRC Report No E-77-2c

STUDY TO DETERMINE EVAPORATIVE EMISSION BREAKDOWN INCLUDING

PERMEATION EFFECTS AND DIURNAL EMISSIONS USING E20 FUELS ON AGING

ENHANCED EVAPORATIVE EMISSIONS CERTIFIED VEHICLES

December 2010

Final CRC E-77-2c Report - Dec 2010

i

The Coordinating Research Council Inc (CRC) is a non-profit corporation

supported by the petroleum and automotive equipment industries CRC

operates through the committees made up of technical experts from

industry and government who voluntarily participate The four main areas

of research within CRC are air pollution (atmospheric and engineering

studies) aviation fuels lubricants and equipment performance heavy-duty

vehicle fuels lubricants and equipment performance (eg diesel trucks)

and light-duty vehicle fuels lubricants and equipment performance (eg

passenger cars) CRCrsquos function is to provide the mechanism for joint

research conducted by the two industries that will help in determining the

optimum combination of petroleum products and automotive equipment

CRCrsquos work is limited to research that is mutually beneficial to the two

industries involved and all information is available to the public

CRC makes no warranty expressed or implied on the application of

information contained in this report In formulating and approving reports

the appropriate committee of the Coordinating Research Council Inc has

not investigated or considered patents which may apply to the subject

matter Prospective users of the report are responsible for protecting

themselves against liability for infringement of patents


i

Final Report

STUDY TO DETERMINE EVAPORATIVE EMISSION

BREAKDOWN INCLUDING PERMEATION EFFECTS AND

DIURNAL EMISSIONS USING E20 FUELS ON AGING

ENHANCED EVAPORATIVE EMISSIONS CERTIFIED

VEHICLES

CRC E-77-2c

Submitted by

Harold M Haskew PE

Tom Liberty

Harold Haskew amp Associates Inc

425 W Huron Street Suite 230

Milford MI


ii

Table of Contents

Page

Introduction

Background 1

Contract History and Period of Performance 1

Program Overview

Test Fuels 3

Test Procedures 5

E-77-2c Vehicle Selection 8

Composite Vehicle Fleet 9

Discussion of Test Results

Task 45 ndash Permeation Performance on E0 E10 and E20 Fuels 12

Static Emissions Performance12

Static Permeation Relationship 86ordm vs 105ordm F 15

Running Loss and Hot Soak Emissions Performance16

Diurnal Emissions Performance 19

Summary of Task 45 23

Task 47 ndash Effect of Leak Location on Permeation Emissions 24

Leaks with Pre-Enhanced and Pre-ORVR Systems 24

Leaks at Fuel Cap with ORVR Systems 25

Alternative Implanted Leak Locations27

Leak Location at Tank Top 28

Leak Location at Canister Inlet 29

Diurnal Leak Comparison 30


Speciation of Permeation Results 32

Basic Speciation File Example 32

Ozone Forming Potential Methodology34

Reactivity Comparison35

Summary and Recommendations for Additional Investigations 36

Acknowledgements 37

Steering Committee 37

Appendix I - Task 45 Individual Vehicle Data and Plots 38

Appendix II - Task 47 Individual Vehicle Data and Plots 60

Appendix III - E-77 Test Concept Measuring Leaks

Permeation and Diurnal Vapor Losses 69

Appendix IV ndash Speciation and Reactivity Results80

Appendix V ndash CRC E-77 and E-77-2 Fuel Specifications251


iii

List of Figures

Figure Description Page

1 Trap Canister 5

2 Static Test ndash Tank Pressurization 6

3 Static Test ndash Fuel Pump Energized 6

4 Test Procedure Flow Chart 7

5 86ordm F Static Performance12


7 Temperature Effect on Static Performance 15

8 Running Loss Performance 16

9 Hot Soak Performance 16

10 Day One Diurnal Performance19

11 Three Day Diurnal Performance 20

12 Simple Tank Venting System 24

13 Dodge Caravan Fuel System 26

14 Toyota Camry Fuel System 26

15 Caravan Top Tank Leak28

16 Camry Top Tank Leak 28

17 Caravan Canister Inlet Leak29

18 Camry Canister Inlet Leak 29

19 Caravan Diurnal Leak Comparison 10psi E10 Fuel 30


21 Camry Diurnal Leak Comparison 10psi E10 Fuel 31



iv

List of Tables

Table Description Page

1 7psi E20 Fuel Properties 3


3 E-77-2c Vehicle Fleet 8

4 E-77 Composite Fleet 9

5 Tier 1 Vehicle Static Data 13

6 Tier 2Zero Evap Vehicle Static Data 14

7 Tier 1 Vehicle Running Loss and Hot Soak Data 17

8 Tier 2Zero Evap Vehicle Running Loss and Hot Soak Data 18

9 Tier 1 Vehicle Diurnal Data 21

10 Tier 2Zero Evap Vehicle Diurnal Data 22

11 Fuel Cap Leak ndash Pre-Enhanced Pre-ORVR 25

12 Fuel Cap Leak ndash Enhanced and ORVR 27

13 Speciation File Example 33

14 Ozone Forming Potential Methodology34

15 Reactivity Comparison36


v

Acronyms

API American Petroleum Institute

ARB California Air Resources Board

ASTM ASTM International ndash a standards organization

ATL Automotive Testing Laboratory Inc

AQIRPAir Quality Improvement Research Program (AutoOil)

CAS Chemical Abstract Service

CFR Code of Federal Regulations

CRCCoordinating Research Council Inc

CVS Constant Volume Sampler

DHB Diurnal Heat Build

DVPE Dry Vapor Pressure Equivalent

EPA (US) Environmental Protection Agency

FID Flame Ionization Detector

FTTP Fuel Tank Temperature Profile

GC Gas Chromatograph

HC Hydrocarbon

HHampA Harold Haskew amp Associates

LA-92 Unified Driving Cycle

MIR Maximum Incremental Reactivity

MOVESMotor Vehicle Emissions Simulator

MTBE Methyl Tertiary Butyl Ether

NBR Nitrile Rubber or Acrylonitrile Butadiene Rubber

NREL National Renewable Energy Laboratories

OBD2 On-Board Diagnostics Level 2

ORVR Onboard Refueling Vapor Recovery

PFI Port Fuel Injection

psi Pounds Per Square Inch

PZEVPartial Zero Emission Vehicle (California)

RL SHED Running Loss Sealed Housing for Evaporative Determination

RVP Reid Vapor Pressure

SAE Society of Automotive Engineers

SHED Sealed Housing for Evaporative Determination

SwRI Southwest Research Institute

TEFVO Transient Emission Following Vehicle Operation (True Hot Soak)

THCTotal Hydrocarbon

VOC Volatile Organic Compound

VT SHED Variable Temperature Sealed Housing for Evaporative Determination


vi

Executive Summary

The National Renewable Energy Laboratories (NREL) in cooperation with the US

Environmental Protection Agency (USEPA or EPA) determined the need for an evaporative

emissions test program to characterize real-world evaporative emission events for planning and

inventory modeling purposes This program (E-77-2c) adds testing on E20 (20 volume percent

ethanol in gasoline) on additional vehicles to the E0 and E10 fuels previously evaluated in the

CRC E-77 series studies as well as additional implanted leak mechanisms

ldquoPermeationrdquo refers to the loss of fuel vapor through the various components of a vehiclersquos fuel

system Permeation occurs continuously but the rate depends on a number of factors including

the properties of storage container (gas tank etc) type of fuel hoses (material design shape)

the amount of fuel in the container environmental factors (including temperature) and fuel

properties (including oxygenates) Diurnal emissions are those that occur daily or over a 24-

hour period of testing and are measured while the vehiclersquos propulsion system is at rest

An additional part of this program was to expand on the leak study performed in E-77-2 with

additional ldquoimplanted leakrdquo evaluations on vehicles 207 and 211 Previous evaluations were

made with leaks implanted at the fuel cap For this program leaks were implanted at the top of

the fuel tank and separately at the canisterrsquos fuel vapor entry with 7 and 10 psi E10 fuel This

assignment was known as Task 47

The fuels used to evaluate the permeation performance of the vehicles in Task 45 and 47 were

20 volume percentage ethanol mixtures at two vapor pressures seven (7) and nine (9) psi RVP

Task 45 measured the permeation performance of the two vapor pressure fuels on the selected

fleet Task 47 continued a previous CRC investigation into the emission effect of implanted

leaks in the vapor system

The following table summarizes the fleet as tested in the E-77-2c program One vehicle No

220 a 2000 model year (MY) Chevrolet Malibu started the test program but was cancelled by

the steering committee when it exhibited a deteriorating leak condition during the program

Veh Evap Standards

No Year Make Model (all are ORVR)

221 2000 Mitsubishi Galant Tier 1

206 2002 Nissan Altima Tier 1

208 2002 Chevrolet Trailblazer Tier 1

209 2004 Chrysler Stratus Tier 1

210 2004 Chevrolet Impala Tier 2

213 2004 Dodge Ram 1500 Tier 2

222 2004 Ford Focus ZX3 Zero Evap

207 2001 Dodge Caravan Tier 1

211 2004 Toyota Camry XLE Tier 2

E-77-2c Vehicle Test Fleet Summary

Task 45 - E20 Fuel Effect on Emissions

Task 47 - Implanted Leak Effect with E20 Fuel


vii

This assignment (E-77-2c) only involved the performance of permeation measurements on

vehicles operated on two E20 fuels The main value of the data collected is realized when the

results are viewed in the context of the prior CRC work There are three sections in the

ldquoDiscussionrdquo portion of this report

The permeation performance of the ldquoCombined E-77 Fleetrdquo on the various fuels (Task

45 plus prior work)

The additional leak testing that was done in this project combined with the prior work to

overview the effect of leak location It also points out that the later vehicles with ORVR

systems had different leak effects (Task 47 plus prior work)

Description and details of the evaporative emission speciation measurements and the

methodology of the ldquoAverage Reactivityrdquo calculations that were made

Task 45 demonstrated that while the sample sizes are still too small to make comparisons with

statistical significance several trends are suggested Referring to the data presented and

comparing the average permeation performance for various groups the following trends and

observations are offered

The newer Tier 2 vehicles have lower permeation than Tier 1 on all fuels

Permeation is higher with E10 or E20 compared to an ethanol-free (E0) fuel

The tests performed for Task 47 demonstrated two findings that may have significance for air

quality modelers

Vehicles fitted with ORVR systems may have changed the emission impact of a small

leak at the fuel cap Leaks added at the fuel cap for the two ORVR vehicles tested

produced one day diurnal emissions almost an order of magnitude lower than was seen

with a previously tested non-ORVR Cavalier This change in the emissions measured is

thought to be due to the addition of ldquocheck valvesrdquo or ldquoanti-spitback valvesrdquo added to the

systems to improve the fuel fill control

Diurnal emissions measured with leaks implanted at the top of the fuel tank or at the

entry to the carbon canister were significantly higher than the emissions with a leak

implanted at the fuel cap on the two ORVR-equipped vehicles tested It was expected

that the permeation emissions from a leak at the top of the tank might be higher than

those from a leak at the fuel cap

The E-77-2c scope of work request included gas chromatographic speciation of all the

vehicle tests including the static tests the dynamic and the diurnals on both fuel vapor

pressures This generated a sizable file of test results Analysis or comment on the content

on the speciation other than the calculation of reactivity was not attempted and is beyond the

scope of this investigation The detailed speciation summaries are presented at the end of this

report in Appendix IV


1

STUDY TO DETERINE EVAPORATIVE EMISSION BREAKDOWN INCLUDING



CRC E-77-2c

Introduction

Background - The National Renewable Energy Laboratories (NREL) in cooperation with the

US Environmental Protection Agency (USEPA or EPA) determined the need for an evaporative


inventory modeling purposes Coordinating Research Councilrsquos (CRC) ldquoE-77 Pilot Study1rdquo

demonstrated that segregation of evaporative emission components was possible where fuel

system permeation emissions were measured separately from fuel tank and carbon canister

venting emissions Later CRC studies E-77-22 and E-77-2b

3 continued these measurement

techniques and added to a data base that was created to support new concepts in air inventory

modeling This program (E-77-2c) adds testing on E20 (20 volume percent ethanol in gasoline)

on additional vehicles to the E0 and E10 fuels previously evaluated in the CRC E-77 series

studies











assignment was known as ldquoTask 47rdquo

Contract History and Period of Performance - Harold Haskew amp Associates Inc (HHampA)4

was awarded the contract for this program and shared the testing responsibility with Automotive

Testing Laboratories Inc (ATL)5 in Mesa AZ The contract was dated June 1 2009 and the

first test was conducted on August 12 2009 (Task 47 leak test on Vehicle 211c with the E10

fuel) Weekly progress reports were made each Sunday with Number 1 dated August 9 2009

and the final number 31 dated March 4 2010

1 Available for download at CRCrsquos website wwwcrcaoorg in the Emissions Publications section

2 Ibid CRC E-77-2 ldquoEnhanced Evaporative Emission Vehiclesrdquo March 2010

3 Ibid CRC E-77-2b ldquoEvaporative Emissions from In-Use Vehicles Test Fleet Expansionrdquo SwRI

reg Project No

031493605 June 2010 4 Harold Haskew amp Associates Inc 425 W Huron Suite 230 Milford MI (248) 684-3410

5 Automotive Testing Laboratories Inc 263 S Mulberry Street Mesa AZ (480) 649-7906 Greg Barton President


2

This report is the fourth in a series of CRC E-77 reports but is organized to be a stand-alone

report without excessive reference to the previous publications Much of the documentation

concerning the theory and practice of the test procedure has been placed in Appendix III but

captured within this publication


3

Program Overview

Test Fuels

The fuels used to evaluate the permeation performance of the vehicles in the permeation

performance task and the implanted leak investigation were 20 volume percentage ethanol

mixtures at two vapor pressures seven (7) and nine (9) psi RVP The properties of the two test

fuels are listed in Tables 1 and 2 Fuel properties from previous CRC E-77 studies are contained

in Appendix V

Table 1 7 RVP E20 Fuel Properties

Haltermann products

Product E-77-2c 7 RVP E-20 batch no XH0721GP05 TMO No 800357

Product Code HF0712 tank no 662 Analysis date 8172009

TEST METHOD UNITS SPECIFICATIONS

MIN MAX

RESULTS

Distillation-IBP ASTM D86 ˚F 117

5 ˚F 136

10 ˚F 144

15 ˚F 148

20 ˚F 151

25 ˚F 154

30 ˚F 157

35 ˚F 159

40 ˚F 160

45 ˚F 162

50 ˚F 185 Target only 195 164

55 ˚F 168

60 ˚F 215

65 ˚F 245

70 ˚F 258

75 ˚F 272

80 ˚F 289

85 ˚F 305

90 ˚F 315 325 316

95 ˚F 323

Distillation-EP ˚F 437 342

Recovery vol Report 988

Residue vol Report 07

Loss vol Report 05

Gravity ASTM D4052 ˚API Report 554

Specific gravity ASTM D4052 Report 07571

Reid Vapor Pressure psi 64 67 70 69

Oxygen ASTM D4815 wt Report 726

Ethanol ASTM D4815 vol 190 210 200

Sulfur ASTM D5453 ppm wt 25 30 29

HC ratio ASTM D3343 Report 01559

CH ratio ASTM D3343 Report 64151

Composition aromatics corrected ASTM D1319 vol 210 250 229

Composition olefins corrected ASTM D1319 vol 70 110 72

Composition saturates corrected ASTM D1319 vol Report 499

Benzene content ASTM D3606 vol 09 11 10

Research Octane Number ASTM D2699 910 950 942

Motor Octane Number ASTM D2700 830 870 833

R+M2 D26992700 870 910 888

Net Heat of combustion ASTM D3338 btulb Report 18474


4


Haltermann products

Product CRC Project No E-74b Fuel 4 batch no XH0721GP03 TMO No 800357



MIN MAX

RESULTS


5 ˚F 123

10 ˚F 131

20 ˚F 140

30 ˚F 150

40 ˚F 156

50 ˚F 185 Target only 195 161

60 ˚F 165

70 ˚F 248

80 ˚F 285

90 ˚F 315 325 315

95 ˚F 322




Loss vol Report 14



Reid Vapor Pressure ASTM D5191 psi 84 87 90 84












R+M2 D26992700 870 910 891



5

Test Procedures

A Test Method for Separating Permeation from Tank Venting and Leaks ndash In a previous

CRC Project (E-65) the laboratory separated the canister loss from the permeation measurement

by venting the losses from the carbon canister

outside the SHED For Project E-77 the canister

vent losses were collected and measured in a

separate ldquotrap canisterrdquo on a scale outside the

SHED as shown in Figure 1 This vent line was

capped off ie sealed during the Static Test but

connected as shown in the figure for the Dynamic

and the Diurnal Test The ambient temperature in

the SHED was constant during the static test and

there was no vapor created at constant

temperature This vent was closed to pressurize

the system for the leak evaluations The resulting

SHED increase in HC mass was permeation6 The

last mechanism that needed to be evaluated was leaks Leaks can be both vapor and liquid A

liquid leak can have significant mass currently undetected by the vehiclersquos on-board diagnostic

system Considerable thought and effort have gone into the creation of a simple and effective

liquid leak detection methodology without success The techniques used in this project required

the use of a SHED for measurements The techniques were not simple but they proved

effective

Based on experience a vehiclersquos permeation rate is expected to lie between 4 and 90 mghour

The presence of a static liquid leak is expected to overwhelm this value such a leak would (or

could) be apparent by inspection Leaks from the vehicles were quantified in a three-step test

process The first step was to measure the static permeation rate of the vehicle at 86ordmF The

vehicle was allowed to stabilize at 86ordmF in the SHED and the permeation rate was calculated

from the mass increase in the SHED The second part of the test looking for pressure driven

leaks in the vapor system was performed by pressurizing the vehiclersquos tank to 5rdquo H2O through a

special fuel cap and tubing from outside the SHED (Figure 2) The special fuel cap the hose and

the pressurization apparatus was installed before the start of the sequence The HC concentration

in the SHED was monitored and the increase in the mass of HC in the SHED was compared to

the static permeation rate If there was no (or insignificant) rate of increase it was deduced that

no vapor leak is present

6 This is a simplification There are other HC sources present that are not fuel permeation These include tire paint

adhesives and vinyl emissions and the possibility of fuel leaks from the fuel injectors The investigators believe

these to be a minor component of the emissions measured in this study

Figure 1 Trap Canister


6

The third and final part of the test was to energize the vehiclersquos fuel pump and pressurize the

system up to and including the injectors (Figure 3) If there were a pressure leak in the liquid

system an increase in the SHED mass over time would be seen ie the leak would be additive

to the permeation rate

Figure 3 Static Test ndash Fuel Pump Energized

Other Tests (Dynamic Hot Soak and Diurnal) - A similar configuration is used to isolate the

tank venting losses from the permeation measurements determined by other test procedures The

vehiclersquos canister vent is connected with a low permeation hose (Teflontrade) to a bulk-head fitting

in the SHED wall and then to a separate ldquotrap canisterrdquo on a top-loading scale Any HC

emissions that escape from the vehiclersquos canister are captured in the trap canister and measured

at a 001 g (10 milligram) precision The trap canister (a 1 Liter Ford model) is purged before

each test and maintained at a ldquodryrdquo condition so that it captures all of the vehiclersquos escaping

emissions This assumption is probably violated during high vapor pressure tests where there are

30 or more grams of daily emissions

Figure 2 - Static Test ndash Tank Pressurization


7

Drain and 40 Fill

with Test Fuel

Road Preconditioning

Four LA-4rsquos or Equivalent

Drain and 40 Fill

with Test Fuel

Overnight Park at 86degF

Move to SHED

Connect Test Instrumentation

Stabilize at 86degF

Perform Constant Temperature

Permeation Series (86degF)

1 hour Permeation Rate Test

frac12 hour Tank Pressurized Test

frac12 hour Pump Energized Test

Transfer to RL SHED


Stabilize at 86degF

Perform Dynamic Permeation Test

Two LA92 Driving Cycles amp

One Hour Hot Soak

Drain and 40 Fill

With Test Fuel



Move to VT-SHED


Stabilize at 65degF for 6 hrs Minimum

Perform 3-Day Diurnal Evaluation

72 hr 65deg to 105degF VT Test

Drain and 40 Fill

with Next Test Fuel

Precondition Fuel System

With X1 Weeks Driving

On Test Fuel

Return to Precondition

Fuel System

Order of Fuels Tested

9 psi E20

7 psi E20

1 Preconditioning Duration

4 weeks for an Ethanol content change

1 week for RVP change only

Figure 4 ndash Test Procedure Flow Chart


8

E-77-2c Vehicle Selection

The vehicle mix was specified in the CRC Request for Proposal as eight vehicles for Task 45

and a repeat of two vehicles previously tested in CRC programs with implanted leaks for Task

47 Task 45 vehicles included five Tier 1 vehicles two Tier 2 vehicles and one ldquoZero Evaprdquo

vehicle

Table 3 summarizes the fleet as tested in the E-77-2c program One vehicle No 220 a 2000

model year (MY) Chevrolet Malibu (not shown in Table 3) started the test program after

exhibiting a deteriorating leak condition during the program it was cancelled by the steering

committee

A ldquoTier 1rdquo vehicle is one that certified to the EPArsquos ldquoEnhanced Evaporative Emissionrdquo

standards7 These evaporative standards were phased in starting in Model Year 1996 (see also 40

CFR 86096-8 (b)) with all light duty vehicles compliant by MY 1998 Vehicles certified to the

evaporative emissions standards prior to the enhanced standards are referred to as ldquoTier 0rdquo The

enhanced standards required control of diurnal emissions for up to three days (previously a one

day tank temperature rise compressed into a one hour time requirement) as well as control the

evaporative (ie non-tailpipe) emissions during vehicle operation (known as running losses) at

high (95degF) ambient conditions and a one-hour ldquohigh-temperature hot soakrdquo period immediately

following the drive Tier 2 standards8 used similar test procedures and conditions but lowered

the allowable limits to less than half the previous standards California required that a fraction of

the vehicles produced for California meet new ldquoZero Evaporative Emissionrdquo standards9 A

vehicle certified to the zero evap standards had diurnal plus hot soak fuel emissions at levels less

7 httpwwwepagovotaqstandardslight-dutytier1evaphtm See this EPA web page for a comprehensive chart

showing the various standards and the implementation schedules 8 Tier 2 Evaporative Emission Standards httpwwwepagovotaqstandardslight-dutytier2evaphtm and 40

CFR 86 Subpart S 9 Note several other states have adopted vehicle emissions standards identical to those of California

Table 3

Veh Evap Standards No Year Make Model (all are ORVR)


206 2002 Nissan Altima Tier 1 208 2002 Chevrolet Trailblazer Tier 1


210 2004 Chevrolet Impala Tier 2 213 2004 Dodge Ram 1500 Tier 2








9

than 00 grams per test10

The 00 gram requirement was later defined and accepted to be 0054

grams or 54 milligrams to include round off of the measurement A whole vehicle performance

limit of 350 mgtest was included to allow for non-fuel test contributors (eg tires adhesives

etc) on a whole vehicle test

Composite Vehicle Fleet

As stated previously the Task 45 of the E-77-2c program added seven vehicles tested on E20

fuel to the E-77 program database Table 4 below lists the ldquocomposite E-77 vehicle fleetrdquo sorted

by evap standard with the 2c vehicles indicated by the ldquocrdquo notation in the vehicle number

column of the light blue rows Not all data from the composite fleet are usable for later analysis

as the use of the INNOVA analyzer for identification of methanol (probably from windshield

washer fluid) and refrigerant (R-134a) leaks did not become available until the latter part of the

Pilot Program Pre INNOVA data tests that were not used in the analysis are indicated with the

yellow shading

Table 4

10 ldquoCALIFORNIA EVAPORATIVE EMISSION STANDARDS AND TEST PROCEDURES FOR 2001 AND

SUBSEQUENT MODEL MOTOR VEHICLESrdquo California Air Resources Board 1999 hellip Vehicles

demonstrating compliance with these evaporative emission standards shall also have zero (00) grams of fuel

evaporative emissions per test for the three-day and two-day diurnal-plus-hot-soak testshellip

Fuel Tank

Veh Tank Plastic

No Yr Make Model Odo Evap Family Evap Standard Size Metal

003 1992 Honda Accord 71129 92FG Tier 0 170 Metal

010 1992 Toyota Camry 162838 EV-E Tier 0 185 Metal

009 1995 Plymouth Neon 106220 SCR1050AYM02 Tier 0 112 Metal

004 1999 Dodge Grand Caravan SE 98765 XCRXE0101G2A Tier 0 200 Plastic

001 1996 Chevrolet S-10 68420 TGM1082AYMEA Tier 1 190 Metal

006 1996 Chevrolet Cavalier 112768 TGM1089AYMEA Tier 1 153 Metal


008 1996 Ford Explorer 114822 TFM1120AYMED Tier 1 210 Metal

202 1996 Ford Taurus 86538 TFM1115AYMEB Tier 1 160 Metal


204 1999 Honda Accord 100418 XHNXR0130AAA Tier 1 171 Metal

002 2000 Toyota Tacoma 80557 YTYXE0095AE0 Tier 1 151 Metal

220b 2000 Chevrolet Malibu 69367 YGMXR0124919 Tier 1 142 Plastic

221bc 2000 Mitsubishi Galant ES 97875 YDSXR0165A1F Tier 1 163 Plastic

205 2001 Toyota Corolla 92047 1TYXR0115AK1 Tier 1 132 Metal

207 2001 Dodge Caravan 92740 1CRXR0165XAA Tier 1 200 Plastic

206bc 2002 Nissan Altima 110399 2NSXR0120RCB Tier 1 200 Plastic

208bc 2002 Chevrolet Trailblazer 60233 2GMXR0175922 Tier 1 186 Plastic

209bc 2004 Chrysler Stratus 63778 4CRXR0130GBA Tier 1 160 Plastic

210bc 2004 Chevrolet Impala 63157 4GMXR0124919 Tier 2 170 Plastic

211 2004 Toyota Camry LE 43588 4TYXR0130A11 Tier 2 185 Plastic

213bc 2004 Dodge Ram 1500 99372 4CRXR0218GDH Tier 2 350 Plastic

214 2004 Ford Escape 40188 4FMXR0110BBE Tier 2 160 Plastic

215 2004 Toyota High Lander 88693 4TYXR0165PZ1 Tier 2 191 Plastic

212 2006 Ford Taurus 28354 6FMXR0185GAK Tier 2 180 Metal

005 2007 Ford Taurus 6916 7FMXR0185GAR Tier 2 180 Metal

222bc 2004 Ford Focus ZX3 71633 4FMXR0120GCX Zero Evap 140 Metal

E77 Program - No INNOVA data not used

E77 Program with INNOVA during diurnal testing

E77-2 Program

Prolem Vehicle - Unstable Leak data not used

E77-2b and 2c Programs

E-77 Composite Fleet - All Programs


10

It seemed desirable to combine as much as possible of the previous E-77 data (E-77 Pilot Study

E-77-2 and E-77-2b) with the newly gathered data into the discussion of results Not all of the

data were comparable The following summary is offered to explain the various choices

While not part of the contracted E-77 Pilot Study the laboratory found that the vehicle

tests needed to be corrected for the presence of the methanol and the refrigerant R134a

The INNOVA analyzer that the laboratory purchased and used to make these corrections

was not available for testing until vehicle 006 Of the remaining vehicles tested only 006

and 008 were Tier 1 models (Vehicle 007 was an implanted leak test and vehicles 009

and 010 were pre-enhanced Tier 0 models) The Pilot Study only ran a one-day diurnal

rather than the three-day test that became the norm

The 105ordmF static tests were first introduced in the E-77-2b test sequence to enhance the

evidence that permeation is directly affected by temperature The earlier test programs

did not have that information

Emission results are presented in later sections of the report for each of the four evaporative

emission elements (static running loss hot soak and diurnal) with data averaged for selected

and representative vehicles tested in the E-77 E-77-2 and E-77-2b programs that were operated

on the four fuels used in this (2c) study


11


While this assignment (E-77-2c) involved only permeation performance on two E20 fuels

additional value of this E-77-2c data is realized when the results are viewed in the context of the

prior CRC work There may be misleading conclusions when comparing data across fuels where

a different number of vehicles contribute to the bars within a technology group Drawing

inferences in fuel effects based on these averages is inappropriate because individual vehicle

effects come into play

There are three sections in the ldquoDiscussionrdquo portion of this report


45 plus prior work)






The actual test summaries and the plots of the results of each of the test vehicles on the two

volatilities of the E20 fuel are contained in the Appendices starting at page 38


12

Task 45 - Permeation Performance on the E0 E10 and E20 Fuels

Static Emissions Performance ndash Figures 5 and 6 below present the static permeation results for

the composite fleet and include the E20 results on the right side of each figure The static

performance averages gave similar fuel rankings to that which was seen with the more

significant diurnal test result averages

Figure 5 86ordm F Static Performance


0

10

20

30

40

50

60

70

7psi E0 9psi E0 7psi E10 10psi E10 7psi E20 9psi E20

Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel

86ordm F Static PerformanceAll E77 Programs

Tier 1

Tier 2

Zer Evap

7

4

77

7

7

6

266

6

6

Number above the bar is thenumber of tests in the averageCaution is advised Chart contains varying number of vehicles anddifferent ages of vehicles amongthe groupings

1

1

0

20

40

60

80

100

120

140


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

4

4

4

4

4

4

22

2

2

22

11



13

Tables 5 and 6 contain the data used in Figures 7 and 8 respectively as well as data from the

pressurizing of the tank and activating the fuel pump these features of the test were to check for

leaks and are discussed in detail in Appendix III

Table 5 Tier 1 Vehicle Static Data

Veh Eng Static Tank Pump Static Tank Pump

Veh No Desc Fuel Sys Fuel Test Pressurized On Test Pressurized On

202216 1996 Ford Taurus 30LPFI 10E10 324 00 00 --- --- ---

202216 See Note 1 7E10 325 00 00 --- --- ---

202216 9E0 178 136 00 --- --- ---

202216 7E0 204 380 00 --- --- ---

202216 9E20 204 00 00 --- --- ---

204 1999 Honda Accord 23LPFI 10E10 843 00 00 --- --- ---

204 7E10 664 00 00 --- --- ---

204 9E0 338 00 00 --- --- ---

204 7E0 129 00 00 --- --- ---

204 9E20 553 00 00 --- --- ---

205 2001 Toyota Corolla 18LPFI 10E10 416 00 00 --- --- --- E-77-2

205 7E10 596 00 00 --- --- ---

205 9E0 195 00 00 --- --- ---

205 7E0 99 00 00 --- --- ---

205 9E20 462 00 00 --- --- ---

207 2001 Dodge Caravan 33LPFI 10E10 787 00 00 --- --- ---

207 7E10 644 00 00 --- --- ---

207 9E0 325 00 00 --- --- ---

207 7E0 401 00 00 --- --- ---

207 9E20 882 00 00 --- --- ---

207L 2001 Dodge Caravan 33LPFI 10E10 976 --- 1209 --- --- ---

207L See Note 2 7E10 1468 --- 00 --- --- ---

206b 2002 Nissan Altima 25LPFI 10E10 1249 00 00 3141 00 00

206b 7E10 1493 00 00 3079 00 00

206b 9E0 611 00 00 1788 00 00

206b 7E0 520 00 00 1181 00 00

206c 9E20 702 00 00 1729 00 00

206c 7E20 938 00 00 2307 00 00

207c 2001 Dodge Caravan 33LPFI 10E10 6102 --- 4353 --- --- ---

207c See Note 2 7E10 5235 --- 2718 --- --- ---

207c 10E10 2325 --- 10837 --- --- ---

207c 7E10 1448 --- 3727 --- --- ---

208b 2002 Chev Trailblazer 42LPFI 10E10 375 00 00 612 00 00

208b 7E10 272 00 00 518 00 00

208b 9E0 372 00 00 550 00 91

208b 7E0 248 00 00 645 00 00

208c 9E20 219 00 00 396 00 00

208c 7E20 184 00 00 525 00 00

209b 2004 Chry Stratus 24LPFI 10E10 288 00 00 733 00 00

209b 7E10 286 00 00 541 00 00 E-77-2bc

209b 9E0 234 00 58 295 00 00

209b 7E0 168 19 79 288 00 00

209c 9E20 420 00 00 721 00 00

209c 7E20 235 00 00 411 00 00

220b 2000 Chevrolet Malibu 34LPFI 10E10 681 20128 23281 2143 33979 40776

220b See Note 3 7E10 504 9122 15724 1820 23090 28945

220b 9E0 1023 23181 28272 18581 35298 51362

220b 7E0 627 13515 16557 2792 22736 30082

221b 2000 Mitsubishi Galant 24LPFI 10E10 389 15687 16939 802 19326 21471

221b See Note 4 7E10 227 9307 9710 614 12823 14085

221b 9E0 556 13488 14060 948 16467 17882

221b 7E0 359 9888 9618 668 12159 13438

221c 9E20 265 6165 6734 723 10328 10971

221c 7E20 394 5312 5061 630 7462 7806

Averages

86 Stat Sample 105 Stat Sample

7psi E0 275 7 696 4

9psi E0 376 7 895 4

7psi E10 598 7 1188 4

10psi E10 621 7 1322 4

7psi E20 438 4 968 4

9psi E20 500 7 892 4

Note 1 - Vehicle 202 was found to have fuel injector leaks O ring leaks and a fuel neck leak Repairs were attempted and the

vehicle was renamed 216 and the test sequence was repeated The data generated was deemed questionable and was not

used in this analysis

Note 2 - Vehicle 207 was retested as 207L with an implanted 0020 diameter leak in the fuel cap and was tested on the 7 and

10 psi E10 fuels For the E77-2c program it was tested as 207c with implanted 0020 leaks seperatly at the tank top and at

the canister inlet During the static tests the tank was not pressurized because of the implanted leak This data was

inappropriate for inclusion in this analysis

Note 3 - Vehicle 220b exhibited a leak that was later determined to be a deteriorating crack in the fuel vapor vent elbow on the

fuel tank sending unit The vehicle was dropped from further testing

Note 4 - Vehicle 221 appeared to have a leak as indicated by the high permeation when the fuel tank was pressurized and

when the fuel pump was energized

86ordm F (mghr) 105ordm F (mghr)

Tank Top

Can Inlet


14


Zero Evap Vehicle Static Data



211 2004 Toyota Camry LE 30LPFI 10E10 199 00 00 --- --- ---

211 7E10 94 266 00 --- --- ---

211 9E0 101 00 00 --- --- ---

211 7E0 91 00 00 --- --- ---

211 9E20 558 00 00 --- --- ---

211L 2004 Toyota Camry LE 30LPFI 10E10 551 --- 821 --- --- ---

211L See Note 7E10 481 --- 1664 --- --- ---

212 2006 Ford Taurus 30LPFI 10E10 106 00 00 --- --- --- E-77-2

212 7E10 218 00 00 --- --- ---

212 9E0 32 00 00 --- --- ---

212 7E0 09 00 00 --- --- ---

212 9E20 47 00 00 --- --- ---

214 2004 Ford Escape 30LPFI 10E10 244 --- 00 --- --- ---

214 7E10 239 --- 00 --- --- ---

214 9E0 107 --- 00 --- --- ---

214 7E0 252 --- 00 --- --- ---

214 9E20 168 --- 00 --- --- ---

215 2004 Toyota Highlander 33LPFI 10E10 104 90 00 --- --- ---

215 7E10 122 00 00 --- --- ---

215 9E0 85 00 00 --- --- ---

215 7E0 87 00 00 --- --- ---

215 9E20 193 00 00 --- --- ---

210b 2004 Chev Impala 34LPFI 10E10 199 00 00 701 00 341

210b 7E10 299 00 00 519 00 232

210b 9E0 212 00 40 335 00 48

210b 7E0 187 00 00 355 00 00

210c 9E20 180 00 00 327 00 46

210c 7E20 152 00 00 340 00 00

211c 2004 Toyota Camry LE 30LPFI 10E10 1925 --- 8601 --- --- ---

211c See Note 7E10 4491 --- 2869 --- --- ---

211c 10E10 2247 --- 14727 --- --- ---

211c 7E10 2170 --- 7890 --- --- ---

213b 2004 Dodge Ram 1500 47LPFI 10E10 392 00 00 1068 00 00 E-77-2bc

213b 7E10 296 00 00 822 00 00

213b 9E0 147 00 00 345 00 00

213b 7E0 211 00 00 353 00 00

213c 9E20 298 00 00 751 00 00

213c 7E20 229 00 00 651 00 00

Averages


7psi E0 140 6 354 2

9psi E0 114 6 340 2

7psi E10 211 6 670 2

10psi E10 209 6 884 2

7psi E20 191 2 495 2

9psi E20 241 6 539 2


Note Vehicle 211 was renamed 211L when a 0020 diameter leak was implanted in the fuel cap For the E77-2c

program it was tested as 211c with implanted 0020 leaks seperatly at the tank top and at the canister inlet

Data generated was not appropriate to be included in this analysis

Tank Top

Can Inlet



222c 2004 Ford Focus 23LPFI 9E20 92 00 00 69 00 00

222c 7E20 69 00 00 71 00 00 E-77-2bc

Averages


7psi E20 69 1 71 1

9psi E20 92 1 69 1



15

Permeation Rate Relationships at 86ordm and 105ordmF - The relationship between the static

permeation rates measured at 86ordmF and 105ordmF have been previously shown to generally follow a

relationship of 105ordmF = 2 x 86ordmF11

This is usually stated as the relationship that follows a

doubling of the permeation rate for each 10ordmC (18ordmF) temperature increase The data measured

during this program is plotted in Figure 7 below with a 21 reference line added

Figure 7 ndash Temperature Effect on Static Permeation

The measurements made in this E-77-2c program appear to be consistent with previous trends

11 See SAE 2001-01-0730 ldquoEstimating Real Time Diurnal Permeation from Constant Temperature Measurementsrdquo

by Marek Lockhart et al March 2001 and CRC ldquoE-65 Final Report - Fuel Permeation from Automotive

Systemsrdquo Harold Haskew et al September 2004 Figures 19 amp 20

0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

10

5 d

eg

F S

tati

c P

erm

ea

tio

n -

mg

hr

86 deg F Static Permeation - mghr

Temperature Effect on Static PermeationNREL E77-2c Program Vehicles

Tier 1

Tier 2

Zero Evap


16

Running Loss and Hot Soak Performance - Permeation rate comparisons are shown below in

Figures 8 and 9 for the running loss and hot soak measurements for the composite fleet with

permeation trends similar to the diurnal and static results The units for the running loss

measurements are expressed in time units mghour which the authors feel are more appropriate

than the regulatory units of grams per mile The conversion back to grams per mile could be

made by multiplying by 4860 to get the mass per test and dividing by 20 to get the miles

traveled (2 x 10 miles per LA92)

Figure 8 ndash Running Loss Performance

Figure 9 ndash Hot Soak Permeation

Tables 7 and 8 contain the data used in Figures 8 and 9 respectively

0

50

100

150

200

250

300

350

400

450


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel

Running Loss PerformanceAll E77 Programs

Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1


0

10

20

30

40

50

60

70

80

90

100


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel

True Hot Soak PerformanceAll E77 Programs

Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1



17

Table 7

Tier 1 Vehicle Running Loss and Hot Soak Data

Veh Eng RL Tru-HS

Veh No Desc Fuel Sys Fuel mghr mghr

202216 1996 Ford Taurus 30LPFI 10E10 1742 118

202216 See Note 1 7E10 1683 192

202216 9E0 1091 254

202216 7E0 787 0

202216 9E20 543 74

204 1999 Honda Accord 23LPFI 10E10 3164 04

204 7E10 2879 297

204 9E0 2492 443

204 7E0 2226 187

204 9E20 2720 134

205 2001 Toyota Corolla 18LPFI 10E10 1916 295

205 7E10 2328 719

205 9E0 1031 10

205 7E0 671 00

205 9E20 1697 603

207 2001 Dodge Caravan 33LPFI 10E10 8581 2377

207 7E10 8122 1222

207 9E0 8339 58 E-77-2

207 7E0 8425 00

207 9E20 10282 00

207L 2001 Dodge Caravan 33LPFI 10E10 10012 3929

207L See Note 2 7E10 11393 5850

206b 2002 Nissan Altima 25LPFI 10E10 5465 1651

206b 7E10 4367 1749

206b 9E0 3656 1025

206b 7E0 2451 688

206c 9E20 3308 858

206c 7E20 5187 1063

207c 2001 Dodge Caravan 33LPFI 10E10 9997 14915

207c See Note 2 7E10 27694 5141

207c 10E10 9375 11140

207c 7E10 1146 6102

208b 2002 Chev Trailblazer 42LPFI 10E10 3295 360

208b 7E10 2547 773

208b 9E0 2280 379

208b 7E0 1249 750

208c 9E20 2415 269

208c 7E20 2785 205

209b 2004 Chry Stratus 24LPFI 10E10 3236 1137

209b 7E10 2057 245 E-77-2bc

209b 9E0 1444 50

209b 7E0 1662 168

209c 9E20 3671 719

209c 7E20 2560 282

220b 2000 Chevrolet Malibu 34LPFI 10E10 1340 51

220b See Note 3 7E10 6979 768

220b 9E0 24170 3525

220b 7E0 34473 7071

221b 2000 Mitsubishi Galant 24LPFI 10E10 1162 269

221b 7E10 1020 405

221b 9E0 1352 290

221b 7E0 1898 425

221c 9E20 1266 95

221c 7E20 619 25

Averages

RL HS Sample

7psi E0 2655 317 7

9psi E0 2942 322 7

7psi E10 3331 773 7

10psi E10 3831 870 7

7psi E20 2788 394 4

9psi E20 3623 382 7

Note 3 - Vehicle 220b exhibited a leak that was later determined to be a deteriorating crack in the fuel vapor vent elbow on

the fuel tank sending unit The vehicle was dropped from further testing

Note 1 - Vehicle 202 was found to have fuel injector leaks O ring leaks and a fuel neck leak Repairs were attempted and

the vehicle was renamed 216 and the test sequence was repeated The data generated was deemed questionable

and was not used in this analysis

Tank Top

Can Inlet

Note 2 - Vehicle 207 was retested as 207L with an implanted 0020 diameter leak in the fuel cap and was tested

on the 7 and 10 psi E10 fuels For the E77-2c program it was tested as 207c with implanted 0020 leaks seperatly at the

tank top and at the canister inlet This data was inappropriate for inclusion in this analysis


18

Table 8


Zero Evap Vehicle Running Loss and Hot Soak Data

Veh Eng RL Tru-HS


211 2004 Toyota Camry 30LPFI 10E10 1383 00

211 7E10 563 138

211 9E0 837 153

211 7E0 1046 07

211 9E20 4106 00

211L 2004 Toyota Camry LE 30LPFI 10E10 3024 2450

211L See Note 7E10 2511 62

212 2006 Ford Taurus 30LPFI 10E10 1489 00 E-77-2

212 7E10 2012 00

212 9E0 1158 04

212 7E0 1845 18

212 9E20 1168 49

214 2004 Ford Escape 30LPFI 10E10 1331 574

214 7E10 1057 329

214 9E0 967 521

214 7E0 363 33

214 9E20 1394 56

215 2004 Toyota Highlander 33LPFI 10E10 719 16

215 7E10 979 00

215 9E0 811 251

215 7E0 797 225

215 9E20 1025 0

210b 2004 Chev Impala 34LPFI 10E10 1475 606

210b 7E10 2183 618

210b 9E0 1711 198

210b 7E0 2160 490

210c 9E20 1943 540

210c 7E20 1246 759

211c 2004 Toyota Camry LE 30LPFI 10E10 8204 16719

211c See Note 7E10 3418 5894

211c 10E10 153795 19900

211c 7E10 47103 3993

213b 2004 Dodge Ram 1500 47LPFI 10E10 1309 09 E-77-2bc

213b 7E10 2431 605

213b 9E0 2031 145

213b 7E0 1351 122

213c 9E20 2572 40

213c 7E20 1869 334

Averages

RL HS Sample

7psi E0 1260 149 6

9psi E0 1253 212 6

7psi E10 1538 282 6

10psi E10 1284 201 6

7psi E20 1558 547 2

9psi E20 2035 198 6

Note Vehicle 211 was renamed 211L when a 0020 diameter leak was implanted in the fuel cap For the E77-

2c program it was tested as 211c with implanted 0020 leaks seperatly at the tank top and at the canister

inlet Data generated was not appropriate to be included in this analysis

Tank Top

Can Inlet

Veh Eng RL Tru-HS


222c 2004 Ford Focus 23LPFI 9E20 447 76

222c 7E20 683 00 E-77-2bc


19

Diurnal Emissions Performance - Figure 10 shows the Day One diurnal emission results for

the E-77 composite fleet segregated by ethanol level fuel vapor pressure and vehicle

technology group The ldquoDay Onerdquo performance is presented here because it includes the

maximum number of tests to include in the averages ndash the earlier Pilot Study program did not

include three-day diurnal evaluations The cumulative diurnal performance for the three-day

diurnal test is presented in Figure 11 with slightly fewer tests but a similar permeation

performance pattern

Starting at the left edge of Figure 10 there are two bars representing the average permeation

measured for the 24-hour (or the first 24 hours of a longer test) diurnal test (1-day) with the 7 psi

E0 fuel The left blue bar represents the average for the nine Tier 1 vehicles that have been

tested in the E-77 programs The six newer Tier 2 vehiclesrsquo permeation average is shown with

the green bar While the number of observations is small it indicates that on average the newer

vehicles have lower permeation on the 7 psi E0 fuel

A similar trend is indicated in the second pair of bars showing the permeation performance of

the E-77 vehicles tested with the higher vapor pressure (9 psi) E0 fuel The nine Tier 1 vehiclesrsquo

average indicated an increase in permeation with the higher vapor pressure fuel The third and

fourth pairs of bars in the figure show the results when the vehicles were tested with an E10 fuel

The permeation of the Tier 1 vehicles increased on average with the E10 fuels compared to the

ethanol free (E0) test fuels For the newer Tier 2 vehicles the average permeation was not

markedly different when comparing the E10 to the E0 results

The performance of the vehicles with the E20 fuels is represented by the right two pairs of bars

Addressing first the Tier 1 vehicles it appears that the permeation is higher with the E20 fuel

than the E0 but lower with E20 compared to E10 The Tier 2 vehicles do not indicate a marked

increase or difference with the E10 or E20 fuels although the numeric values are higher

Figure 10 ndash Day One Diurnal Performance

0

200

400

600

800

1000

1200

1400

1600


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel

Day One Diurnal PerformanceAll E77 Programs

Tier 1

Tier 2

Zero Evap

9

6

7

2

4

6

7

6

7

6

9

6

11



20

Similar observations are made when the data for the cumulative three-day diurnal permeation

emissions are charted in a similar fashion as shown in Figure 11 below In Figure 11 it should

be noted that the 10 psi E10 averages for the Tier 1 vehicles are highly driven by the results for

206(b) and the results for the Tier 2 vehicles are highly driven by the results for vehicle 214

Figure 11 ndash Three Day Diurnal Performance


0

500

1000

1500

2000

2500

3000

3500


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel

Three Day Total Diurnal PerformanceAll E77 Programs

Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

13801

11



21

Table 9

Tier 1 Vehicle Diurnal Data

Veh Eng

Veh No Desc Fuel Sys Fuel Day 1 Day 2 Day 3 Total

06 1996 Chevrolet Cavalier 22LPFI 7E0 3756 --- --- ---

9E0 4685 --- --- --- E-77

08 1996 Ford Explorer 40LPFI 7E0 1331 --- --- ---

9E0 1504 --- --- ---

202216 1996 Ford Taurus 30LPFI 10E10 25907 34779 36014 96700

202216 See Note 1 7E10 3975 3550 3621 11146

202216 9E0 3270 2667 2746 8683

202216 7E0 2117 2208 2081 6406

202216 9E20 4685 4526 4198 13409

204 1999 Honda Accord 23LPFI 10E10 15479 17799 17711 50989

204 7E10 12602 11652 11652 35906

204 9E0 6283 5810 5770 17863

204 7E0 3672 2877 2936 9485

204 9E20 11034 9606 9812 30452

205 2001 Toyota Corolla 18LPFI 10E10 17941 17309 17417 52667

205 7E10 17834 17150 15239 50223

205 9E0 4995 4810 5072 14877 E-77-2

205 7E0 3830 3654 3670 11154

205 9E20 17752 16900 16802 51454

207 2001 Dodge Caravan 33LPFI 10E10 14064 12644 12237 38945

207 7E10 10865 8120 8236 27221

207 9E0 4064 3373 3080 10517

207 7E0 3975 3026 2689 9690

207 9E20 15480 13702 13605 42787

207L 2001 Dodge Caravan 33LPFI 10E10 16449 --- --- 16449

207L See Note 2 7E10 21342 --- --- 21342

206b 2002 Nissan Altima 25LPFI 10E10 27766 310046 430282 768093

206b 7E10 25826 22585 21440 69850

206b 9E0 15000 12856 12508 40364

206b 7E0 11719 9312 8903 29933

206c 9E20 19585 17878 17010 54473

206c 7E20 19439 17081 15677 52197

207c 2001 Dodge Caravan 33LPFI 10E10 65125 --- --- ---

207c See Note 2 7E10 70847 --- --- ---

207c 10E10 105198 --- --- ---

207c 7E10 70668 --- --- ---

208b 2002 Chev Trailblazer 42LPFI 10E10 7950 5614 4958 18522

208b 7E10 7806 5104 4494 17405

208b 9E0 7780 5672 5194 18646

208b 7E0 4221 4194 4760 13175

208c 9E20 5065 3632 3319 12015

208c 7E20 5804 4338 3754 13895

209b 2004 Chry Stratus 24LPFI 10E10 5355 4235 4755 14345 E-77-2b2c

209b 7E10 3831 3491 3235 10557

209b 9E0 3278 2505 2243 8026

209b 7E0 3541 2497 2181 8219

209c 9E20 4564 3383 3160 11107

209c 7E20 5877 3465 2704 12046

220b 2000 Chevrolet Malibu 34LPFI 10E10 13061 18897 20558 52516

220b See Note 3 7E10 11776 16121 14831 42728

220b 9E0 67333 58848 70499 196680

220b 7E0 62187 62147 70419 194753

221b 2000 Mitsubishi Galant 24LPFI 10E10 8279 7241 7024 22545

221b 7E10 8947 6767 6180 21894

221b 9E0 7064 5437 5383 17884

221b 7E0 6030 5031 4870 15932

221c 9E20 7508 5847 5649 19004

221c 7E20 8172 5442 4988 18602

Averages

Mgs Sample Mgs Sample

7psi E0 4675 9 13941 7

9psi E0 6072 9 18311 7

7psi E10 12530 7 33294 7

10psi E10 13833 7 138015 7

7psi E20 9823 4 24185 4

9psi E20 11570 7 31613 7

Note 1 - Vehicle 202 was found to have fuel injector leaks O ring leaks and a fuel neck leak Repairs were

attempted and the vehicle was renamed 216 and the test sequence was repeated The data generated was

deemed questionable and was not used in this analysis

Note 2 - Vehicle 207 was retested as 207L with an implanted 0020 diameter leak in the fuel cap and was

tested on the 7 and 10 psi E10 fuels For the E77-2c program it was tested as 207c with implanted 0020

leaks seperatly at the tank top and at the canister inlet This data was inappropriate for inclusion in this analysis

Note 3 - Vehicle 220b exhibited a leak that was later determined to be a deteriorating crack in the fuel vapor vent

elbow on the fuel tank sending unit The vehicle was dropped from further testing

Diurnal Results - mg

Day 1 Total

Tank Top

Can Inlet


22

Table 10


Zero Evap Vehicle Diurnal Data

Veh Eng


211 2004 Toyota Camry 30LPFI 10E10 3370 2268 2179 7817

211 7E10 2438 1838 1843 6119

211 9E0 1303 1158 1006 3467

211 7E0 2071 1002 874 3947

211 9E20 2850 2218 2034 7101

211L 2004 Toyota Camry LE 30LPFI 10E10 25454 --- --- 25454

211L See Note 7E10 6783 --- --- 6783

212 2006 Ford Taurus 30LPFI 10E10 1243 879 1028 3150 E-77-2

212 7E10 1848 1002 758 3608

212 9E0 1005 708 574 2287

212 7E0 1016 712 570 2298

212 9E20 1310 833 750 2893

214 2004 Ford Escape 30LPFI 10E10 4920 8394 112475 125789

214 7E10 5242 3974 3944 13160

214 9E0 4559 3585 11017 19161

214 7E0 4943 3190 2815 10948

214 9E20 4709 4400 7518 16627

215 2004 Toyota Highlander 33LPFI 10E10 3192 2602 2370 8164

215 7E10 2247 2317 2675 7239

215 9E0 2021 1659 1763 5443

215 7E0 2483 2941 2888 8312

215 9E20 4168 4148 4506 12822

210b 2004 Chev Impala 34LPFI 10E10 4865 4583 4413 13861

210b 7E10 4451 3883 3591 11925

210b 9E0 4078 3774 3583 11434

210b 7E0 2706 2666 2211 7583

210c 9E20 3523 2749 2977 9250

210c 7E20 3686 2836 2711 9233

213b 2004 Dodge Ram 1500 47LPFI 10E10 6506 6154 7007 19667 E-77-2bc

213b 7E10 6028 5777 5889 17694

213b 9E0 3463 3284 2928 9675

213b 7E0 3578 2833 2765 9175

213c 9E20 6442 5293 4606 16342

213c 7E20 5019 5384 5461 15864

Averages


7psi E0 2799 6 7044 6

9psi E0 2738 6 8578 6

7psi E10 3709 6 9957 6

10psi E10 4016 6 29741 6

7psi E20 4352 2 12549 2

9psi E20 3833 6 10839 6


Day 1 Total

Note Vehicle 211 was renamed 211L when a 0020 diameter leak was implanted in the fuel cap data generated

was not appropriate to be included in this analysis

Veh Eng


222c 2004 Ford Focus 23LPFI 7E20 655 427 395 1477

222c 9E20 736 514 401 1651 E-77-2bc



23

Summary of Task 45

While the sample sizes are still too small to make comparison with statistical significance

several trends are suggested Referring to the figures shown above comparing the average

permeation performance for various groups the following trends and observations are offered

1 The newer Tier 2 vehicles have lower permeation than Tier 1 on all fuels

2 Permeation is higher with E10 or E20 compared to an ethanol-free (E0) fuel

3 Permeation is lower with E20 compared to E10 on the Tier 1 vehicles but the presence of

a reduction is less clear for the newer Tier 2 vehicles based on the few tests available for

analysis Further research may be needed to determine the sensitivity of newer vehicle

technologies to fuel effects

4 Higher average permeation emissions may be associated with increased fuel vapor

pressure for the Tier 1 vehicles tested in this program but the average permeation

emissions for the newer Tier 2 test vehicles show no clear trend with vapor pressure


24

Task 47 - Effect of Leak Location on Permeation Emissions

For the last four decades12

vehicles sold in the United States have been equipped with

evaporative emission control (evap) systems that are remarkably effective in reducing fuel

evaporative emissions from automotive fuel systems Light Duty Vehicles (LDV) starting in

model year 1998 even control refueling emission to a very high degree The performance of

these evap systems are however affected by leaks that may exist in the fuel system of a vehicle

These leaks can be the result of among other things poor connections scratched or misaligned

seals loose fuel caps and improper maintenance such as improper repairs done to other fuel

system components that could result in leaks Undetected (and un-repaired) leaks in automotive

fuel systems can be a potentially significant source of vehicle emissions

This source of emissions (leaks) was addressed by regulation starting in MY 1998 with the

implementation of onboard detection of fuel system leaks (OBD and a later OBDII) Current

OBDII systems are capable of detecting vapor leaks of 0020rdquo diameter-equivalent or larger

equivalent diameter and alerting the operator to bring the vehicle in for service As a result

leaks of this scale (if corrected) can become a much smaller contributor to vehicle fuel

emissions

Leaks with Pre-Enhanced Pre-ORVR Systems - There is a need to understand the frequency

and nature of leaks that may still exist in the inventory The Coordinating Research Council

(CRC) sponsored test programs (E-77 E-77-2) in recent periods that were designed to measure

emissions from implanted 0020rdquo diameter leaks located in the gas cap in several test vehicles

The test vehicles were subjected to a series of emission tests including a summertime (65deg to

105deg F) diurnal event

In the initial test program (CRC E-77) a 1996 Cavalier with Enhanced Evap control hardware

was selected as the test vehicle The Cavalier was equipped with a simple tank venting system

(Figure 12) with an inline 0055rdquo orifice in the vent line from the tank and leading forward to the

canister Because of the flow restrictions caused by the 0055rdquo orifice the length of the vent

12

The first federal requirement for fuel evaporative emission control was model year 1971 California required

systems a year earlier (1970)

Figure 12 ndash Simple Tank Venting System


25

line the multiple bends and the carbon bed in the canister the 0020rdquo leak implanted in the cap

provided a convenient parallel path to the atmosphere With an implanted leak in the fuel cap

about 21 grams of HC were emitted into the SHED (Table 11) during the diurnal test with E0

fuel while the baseline test with no leak resulted in only 04 grams of diurnal emissions It was

estimated using contemporary vapor generation models that the uncontrolled vapor emissions

from this test13

would have been 232 grams if the cap had been left off completely The 207

gram emissions level corresponds to a 89 loss to the environment

Table 11

Impact of 0020rdquo Leak on Diurnal Emissions

65deg ndash 105deg F Diurnal

1996 Cavalier

Test fuel Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

1996 Chevrolet Cavalier E0 038 2070 2032

Discussions about this test result created the realization that the location of the leak and the

configuration of the vehiclersquos fuel system would probably have a significant effect on the

resulting emissions Even though the leak in the fuel cap was smaller than the 0055rdquo orifice in

the tank vapor line most of the HC vapors passed through the leak to the atmosphere because it

was a path of relatively low resistance

Leaks at the Fuel Cap with ORVR Systems - In a subsequent test program (E-77-2) a similar

diurnal test was conducted on a 2001 Dodge Caravan (Fig 13) and a 2004 Toyota Camry (Fig

14) using E10 fuel Both vehicles were equipped with Onboard Refueling Vapor Recovery

(ORVR) systems as well as OBDII and Tier 1 Evap A 0020rdquo leak was implanted in the fuel

cap of each vehicle and the resulting SHED emissions are shown in Table 6 The resulting net

increases in emissions were 1 gram for the Caravan and 04 grams for the Camry much lower

than the results measured during the evaluation of the Cavalier

The following discussion attempts to explain the hardware and component differences that

contributed to the different results

13

70 psi RVP fuel 153 gallon tank 40 full 176 gallons total tank volume with a 67deg to 103degF temperature

increase


26

Figure 13 Dodge Caravan Fuel System with Enhanced Evap and ORVR

Figure 14 Toyota Camry Fuel System with Enhanced Evap and ORVR


27

Table 12



2002 Caravan and 2004 Camry

Test fuel

Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

2001 Dodge Caravan E10 109 213 104

2004 Toyota Camry E10 024 068 044

(The use of E10 test fuel should not have a significant effect on diurnal emissions)

There is an important difference in the configurations of these two vehicles compared to the

Cavalier that contributed to the low effect of leak implantation on diurnal permeation emissions

An Inlet Check Valve (ICV) is located in the fill pipe of the Dodge Caravan (item 11 on Figure

13) at the entrance to the tank The ICV is a common component in ORVR systems and is

designed to prevent spitback from the fuel tank during a refueling event During the diurnal tests

on the Caravan the ICV seal prevented HC vapors from taking a direct communication path up

the fill pipe and thus into the SHED There is a path from the top of the tankrsquos vapor space that

communicates with the area near the fuel cap (shown as item 2 a ldquorecirculation tuberdquo in Figure

13) but this appears to be a less attractive path compared to the refueling vapor path to the

canister

The Camry system shown in Figure 14 is more complex than the Caravan as the Toyota system

uses a ldquovent switchingrdquo configuration during refueling events

In each of the test vehicles the only flow path from the tank vapor space to the cap is through the

vapor recirculation line shown in Figures 13 and 14 This line contains an orifice the

accompanying restrictions offered by the tubes and turns in the flow path to the cap significantly

reduced the emissions from the implanted leak The more open path for vapors is through the

large refueling vent to the low restriction carbon canister This effect could also be a result of

the cap rdquoseeingrdquo an effective vapor space volume equivalent to the volume of the filler neck

Assuming a 2ft 2rdquo diameter filler neck this could amount to frac12 gallon of vapor space Scaling

the uncontrolled result of 232 grams by the Cavalier vapor space vs frac12 gallon results in a diurnal

emission rate of about 1 gram

Alternative Implanted Leak Locations - In order to evaluate the effect of other leak locations

and system configurations on the emissions from small leaks a test plan was included in E-77-2c

that expanded on the data already observed from the tests with leaks implanted in the cap In this

test series a 0020 leak was implanted separately in two new locations in or near the top of the

tank and at the vent line hose connecting to the canister The test vehicles were the same 2002

Dodge Caravan and 2004 Toyota Camry used in the previous testing The previous data from

these vehicles were then compared to the data for the two new leak locations to add to the

understanding of the impact of small leaks on emissions

For the Task 47 assignment the laboratory staff placed (implanted) a 0020 inch internal

diameter hole at various places in the vehiclersquos fuel system Carburetor jets of the 0020 inch


28

internal diameter size were purchased from a local source fixed into a small disc clamped into a

stainless compression fitting and screwed into the desired position

Previous tests had been performed with a similar size ldquoleakrdquo in the vehiclersquos fuel cap The 0020

inch diameter hole was placed in two different locations on each vehicle

1 at the top of the fuel tank in the tank sending unit cover and

2 at the connection to the canister inlet from the fuel tank

Leak Location at the Top of the Tank - Figure 15 shows the fitting in the Caravan (207) cover

with a red arrow pointing to the position of the

ldquoleakrdquo This was sealed when the leak was

moved to the canister inlet

Similarly Figure 16 shows the fitting in position

on the Toyota Camry tank

Figure 15 Caravan Top Tank Leak

Figure xx Camry Top Tank Leak

Figure 16 Camry Top Tank Leak


29

Leak Location at the Canister Inlet - Again Figures 17 and 18 show the implanted leak location

on the Caravan and Camry respectively

Figure 18 Canister Inlet Leak Location for Camry

Figure 17 Canister Vent Leak Location for Caravan


30

Comparison of the Diurnal Permeation Results with Leaks in Various Locations ndash Vehicle 207

Figures 19 and 20 are summary plots of the day one diurnal results for Vehicle 207 using the 10

psi E10 and the 7 psi E10 fuel with the leaks in various locations The ldquono leakrdquo and the ldquofuel

caprdquo leak are from the previous test programs The green and blue traces show a small effect of

the leak while the leak implanted in the top of the tank (red trace) and at the canister inlet (gold

trace) show a much larger effect (compared to the ldquono-leakrdquo condition)

Figure 19 ndash Caravan Diurnal Leak Comparison ndash 10psi E10 Fuel


0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Pe

rme

ati

on

-m

gh

r

Test Time - min

Diurnal Permeation ComparisonVehicle 207 - 2001 Dodge Caravan

No Leak Implanted

0020 Fuel Cap Leak

0020 Top Of Tank Leak

0020 Canister Inlet Leak

10 psi E10 Fuel

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



7 psi E10 Fuel


31

Figures 21 and 22 show the diurnal performance of Vehicle 211 with leaks in various positions

The results were similar to those seen in Figures 19 and 20

Figure 21 ndash Camry Diurnal Leak Comparison ndash 10psi E10 Fuel


0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min

Diurnal Permeation ComparisonVehicle 211 - 2004 Toyota Camry LE

No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel


32

Summary of Task 47


quality modelers









implanted at the fuel cap on the two ORVR-equipped vehicles tested While it was

expected that the permeation emissions from a leak at the top of the tank might be higher

than those from a leak at the fuel cap a similar difference in emissions between an

implanted leak at the canister inlet versus one at the fuel cap was not

Speciation of the Permeation Results

The E-77-2c scope of work request included gas chromatographic speciation of all the vehicle

tests including the static tests the dynamic and the diurnals on both fuel volatilities This

generated a sizable file of test results The detailed speciation summaries are presented at the

end of this report in Appendix II The implanted leak tests on Vehicles 207 and 211 (Task 47)

were also speciated but must be analyzed separately from the Task 45 results as the analysis

contains not only the vehiclersquos permeation but the vapor from the induced leak The next few

pages will be used to explain the projectrsquos file structure and the calculations used to speciate and

calculate the reactivity of the various tests

Basic Speciation File Example - Table 13 is a truncated example of the basic speciation file that

is generated by the laboratory (ATL) While it has been cut off after elution number 26 there are

172 species in the total report plus methanol ethanol and R-134a (refrigerant)14

This selected

file exists as one of the tabs in the project data file set identified as ldquo206cgcxlsrdquo This example

summarizes the results for the 72-hour diurnal results on vehicle 206c ndash Test number 7703 For

the 72-hour test sample bags of the VT-SHED are collected at the start of the diurnal (T0) at 24

hours (T24) at 48 hours (T48) and finally at 72 hours (T72) In this example the results are

summarized for the composite 72-hour test

14

Stating again the permeation performance values used in this report have corrected the FIDrsquos misidentification

of the ethanol molecule and the identified non-fuel components methanol and refrigerant (R-134a) have been

subtracted from the totals


33

Table 13

Speciation File Example

The file is organized in the following fashion Column 1 is the elution number Column

2 is the species name and Column 3 is the CAS Number (with leading zeros as necessary

to maintain a 10 digit format) The CAS number is a unique number created and

maintained by the CAS Registryreg

(httpwwwcasorg) that provides a name and property

resource for recognized substances

The right hand four columns in the figure are the test results The EXCELtrade file contains six or

more digits of precision but the precision in the figure has been reduced for clarity The net

concentration in ppmC is calculated by subtracting (for each species) the start of test

concentrations (T0) from the 72-hour results yielding the net increase in concentration for the

three-day period One could obtain the speciation results for the third day for example by

subtracting the concentrations at T48 from the T72 measurement The net mass for each of the

species is calculated by using appropriate volume concentration and density values The last

two columns are the relative contribution ( of total present) of the species to the total of all the

concentrations measured

Vehicle 206c

Type 72DHB

Test 7703

Detailed Hydrocarbon Speciation Results

Net mass Net conc

Species Name CAS (mg) (ppmC) (mg) (ppmC)

1 Methane 00074-82-8 0000 0000 0 0

2 Ethylene 00074-85-1 1984 0066 0 0

3 Acetylene (Ethyne) 00074-86-2 0000 0000 0 0

4 Ethane 00074-84-0 0000 0000 0 0

5 Propene 00115-07-1 0000 0000 0 0

6 Propane 00074-98-6 24285 0770 0 0

7 Allene (Propadiene) 00463-49-0 0000 0000 0 0

8 Propyne 00074-99-7 0000 0000 0 0

9 2-Methylpropane 00075-28-5 101164 3244 2 2

10 2-Methylpropene amp 1-Butene 00115-11-7+00106-98-9 11280 0375 0 0

11 13-Butadiene 00106-99-0 0428 0015 0 0

12 n-Butane 00106-97-8 320071 10262 6 6

13 22-Dimethylpropane 00463-82-1 0000 0000 0 0

14 t-2-Butene 00624-64-6 0000 0000 0 0

15 1-Butyne 00107-00-6 0000 0000 0 0

16 c-2-Butene 00590-18-1 30919 1027 1 1

17 3-Methyl-1-butene 00563-45-1 0000 0000 0 0

18 2-Methylbutane (Isopentane) 00078-78-4 379667 12258 7 8

19 1-Pentene amp 2-Butyne 00109-67-1+00503-17-3 52231 1799 1 1

20 2-Methyl-1-butene 00563-46-2 62754 2084 1 1

21 n-Pentane 00109-66-0 335100 10819 6 7

22 2-Methyl-13-butadiene 00078-79-5 2469 0084 0 0

23 t-2-Pentene 00646-04-8 162601 5400 3 3

24 33-Dimethyl-1-butene 00558-37-2 0000 0000 0 0

25 c-2-Pentene 00627-20-3 76704 2547 1 2

26 2-Methyl-2-butene 00513-35-9 152719 5071 3 3

72DHB

total


34

Ozone Forming Potential (Reactivity) Methodology - The speciation information is further

analyzed by calculating the composite ozone forming potential of the speciate Table 14 below

illustrates the concept The order of presenting the individual species has been changed by

Table 14

Ozone Forming Potential Methodology

c-12-Dimethylcyclohexane 02207-01-4 333 043 1424

4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618

sec-Butylbenzene 00135-98-8 229 036 0819

14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148

1-Methyl-4-Isobutylbenzene 05161-04-6 382 009 0349

Total 51453 172967 3362

No MIR available use weighted average of 33341

Species CAS No MIR

Composite VOC mg

Ozone mg

Ethanol 00064-17-5 145 101748 1474297 2-Methylbutane (Isopentane) 00078-78-4 135 37967 514406 n-Pentane 00109-66-0 121 33510 407124 n-Butane 00106-97-8 108 32007 344688 Toluene 00108-88-3 393 27947 1096913 2-Methyl-1-pentene amp 1-Hexene 00592-41-6+00763-29-1 530 27263 1444528 Benzene 00071-43-2 069 20586 142938 n-Hexane 00110-54-3 113 18393 208697 n-Heptane 00142-82-5 097 17284 166926 t-2-Pentene 00646-04-8 1047 16260 1702998 2-Methyl-2-butene 00513-35-9 1420 15272 2167853 2-MePentane amp 4-Me-c-2-Pentene 00691-38-3+00107-83-5 140 14670 205061 3-Me-1-Hexene 03404-61-3 427 10391 444084 2-Methylpropane 00075-28-5 118 10116 119030 Methylcyclopentane 00096-37-7 205 8884 182111 22-DiMeHexane 00590-73-8 094 8200 77181 meta- amp para-Xylenes 00108-38-3+00106-42-3 776 7881 611209 c-2-Pentene 00627-20-3 1028 7670 788622 3-Methylpentane 00096-14-0 169 7668 129648 2-Methyl-1-butene 00563-46-2 638 6275 400280 1-Pentene amp 2-Butyne 00109-67-1+00503-17-3 1170 5223 611345 t-2-Hexene 04050-45-7 855 4165 356031 2-Methylhexane 00591-76-4 109 3643 39538 1-Methyl-3-Ethylbenzene 00620-14-4 739 3513 259471 124-TriMeBenz amp t-Butylbenzene 00095-63-6+00098-06-6 537 3293 176785 Cyclohexene amp 3-Methylhexane 00110-83-8+00589-34-4 319 3263 104117 n-Octane 00111-65-9 080 3249 25870 224-TriMePentane (IsoOctane) 00540-84-1 120 3246 38925 c-2-Butene 00590-18-1 1426 3092 440893 1-Methylcyclopentene 00693-89-0 1245 3043 379046

Vehicle 206c - Fuel 9 psi E20 - 3 Day Diurnal - Test 7703 Non Zero Mass Species Sorted By VOC


35

listing the species by decreasing mass in the sample The blue arrow in the middle of the figure

indicates where lines of data were eliminated from the table to keep the figure to a convenient

height In the figure above and typical for the E20 test results the ethanol species has the

highest mass in the sample and thus appears as the first data line The next largest mass is the

isopentane and so on The next column lists the MIR value for that species The Maximum

Incremental Reactivity scale (MIR) scale15

created by William Carter and adopted by CARB

has been used to estimate the equivalent ozone that would be produced by the various species

found in this measurement The report listed in the footnote contains the following quote

The methods and procedure used to derive the MIR scale presented in this report are

comprehensively documented by Carter (2009a) and references therein and those reports

should be consulted for details Briefly the reactivity scale is based on calculations of relative

ozone impacts expressed as mass of additional ozone formed per mass VOC added to the

emissions for various compounds under various atmospheric conditions given a chemical

mechanism for the compounds and other relevant atmospheric species models for various

atmospheric conditions and a modeling and reactivity assessment procedure The methods

atmospheric scenarios and modeling and reactivity assessment procedures were the same as

employed in previous calculations of the MIR scale (Carter 1994a 2000 2003) and are

based on those first developed by Carter (1994ab) with a few modifications as described by

Carter (2000) The only difference between this updated scale and the previous MIR scales of

Carter (2000 2003) concern the chemical mechanism used and the number and types of

VOCs whose ozone impacts are calculated

Multiplying the mass of the individual species by the MIR factor yields the last column the mass

of ozone that might be produced by that mass of speciate The ldquoaverage reactivityrdquo of the sample

is calculated (and shown at the bottom of each file) by summing up the speciated mass and the

estimated ozone mass and dividing the total ozone value by the total VOC (fuel) mass In this

example the average reactivity is 3362 (in grams of ozone per gram of volatile organic

compound)

Reactivity Comparison for Various Fuels and Test Sequences Table 15 offers a summary of

the Vehicle 206c data measured and calculated using the E20 fuel Similar summaries for the

other vehicles appear with the data listings in the Appendix Columns 4 and 6 compare the mass

estimates by two different techniques Column 4 is the mass estimate one would obtain using the

SHED technique Column 6 lists the gas chromatograph mass estimate This technique

accumulates the total mass in the sample from the sum of the individually identified molecules

The first line of data in the figure indicates good correlation 168 mg versus 162 The second

line indicates that the GC measured 17 more in the sample (column 5 GC as of THC =

1169) which is less than one would hope to see Plus or minus 10 in readings is a goal the

author would hope to achieve

15 UPDATED MAXIMUM INCREMENTAL REACTIVITY SCALE FOR REGULATORY

APPLICATIONS William P L Carter College of Engineering Center for Environmental Research

and Technology University of California Riverside CA 92521 March 23 2009 available at

httpciteseerxistpsuedu


36

The last column (Species Present) indicates the number of species identified using the GC

Thirty (30) or more is an indication that there was a high enough level of permeation that the

chromatograph identified Other projects where the permeation level is low (~30 mg) can give a

much lower number of species identified

Table 15

Reactivity Comparison

Summary and Recommendations for Additional Investigations

There are several subjects that are recommended for additional investigation

1 The Tier 2 (Near Zero) vehicles suggest that the effect of ethanol on permeation may be

reduced (or zero) based on the limited number of tests available to date The indication

may change if the Tier 2 vehicles are tested after they are five or more years old

2 The Tier 2 vehicles also show a mixed effect of fuel vapor pressure on permeation

Permeation was higher in many cases with the lower vapor pressure (7 psi E20) fuel The

order of testing was always first on the 9 psi fuel and then a week later on the 7 psi fuel

Should the order have been mixed

3 Is it possible that the newer advanced materials (tanks hoses seals) used in the Tier 2

vehicles are more resistant to changes in permeation and take longer to stabilize than

previously thought

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


37

Acknowledgements

The authors gratefully acknowledge the contributions and support offered by the management and

staff of the Automotive Test Laboratories Inc at Mesa Arizona The E-77 test series was a

significant undertaking of a unique testing regimen and would not have succeeded without their

efforts and dedication

Our sincere thanks are offered to

Greg Barton - President

Kevin Brown - Technician

Brian Hall - Engineer

Stuart Seale - Data and Quality Manager

Kevin Winkler - Engineer

Steering Committee

David Brzezinski US Environmental Protection Agency

Wendy Clark National Renewable Energy Laboratory

Dominic DiCicco Ford Motor Company

King Eng Shell Global Solutions (US)

Jim Frusti Chrysler LLC

Pam Graham Inergy Automotive

Benjamin Hancock California Air Resources Board

Constance Hart US Environmental Protection Agency

Phil Heirigs Chevron Global Downstream

Jeff Jetter Honda RampD Americas Inc

Keith Knoll National Renewable Energy Laboratory

John Koupal US Environmental Protection Agency

David Lax API

Jeffrey E Long California Air Resources Board

Hector Maldonado California Air Resources Board

Mani Natarajan Marathon Oil Company

David Patterson Mitsubishi Motors RampD of America

Charles H Schleyer ExxonMobil Research amp Engineering

Jenny Sigelko Chrysler LLC

Nakia L Simon Chrysler Group LLC

James P Uihlein Chevron Global Downstream

Michael B Viola General Motors RampD Center

Ken Wright ConocoPhillips


38

Appendix I ndash Task 45

Appendix I contains the individual vehicle data and plots that display the fuel vapor pressure

effect on evaporative emission tests run for Task 45 of this program

For each vehicle there are tables of the evaporative test results reactivity results and plots of the

86ordm and 105ordm F static tests the running loss and hot soak test and the cumulative three day diurnal

test


39

Evaporative Test Results

Vehicle 206c

Reactivity Results

2002 Nissan Altima SHED

Corrected Results Canister

Fuel Permeation mgday Loss

Veh psiEtOH Test Type Date Test mghr (Corrected) g

206c 90E20 Static (86) Perm 091509 7685 702 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 091609 7689 1729 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 091709 25795 3308 020

True HS 858 010

72 DHB 65-105 092909 7703

Day 1 19585 000

Day 2 17878 150

Day 3 17010 1000

70E20 Static (86) Perm 101309 7724 938 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 101409 7727 2307 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 102109 25806 5187 000

True HS 1063 000

72 DHB 65-105 111709 7779

Day 1 19439 000

Day 2 17081 020

Day 3 15677 080

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


40

0

20

40

60

80

100

120

140

160

180

200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 206c - 2002 Nissan Altima

9 psi E20 - 7685

7 psi E20 - 7724

0

50

100

150

200

250

300

350

400

450

500

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7689

7 psi E20 - 7727


41

0

100

200

300

400

500

600

700

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 206c - 2002 Nissan Altima

9 psi E20 - 25795

7 psi E20 - 25806

Running Loss Hot Soak

0

1000

2000

3000

4000

5000

6000

7000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 206c - 2002 Nissan Altima

9 psi E20 - 7703

7 psi E20 - 7779


42


Vehicle 208c

Reactivity Results

2002 Chevrolet Trailblazer SHED




208c 90E20 Static (86) Perm 092209 7695 219 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092309 7699 396 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 092409 25798 2415 000

True HS 269 000

72 DHB 65-105 100609 7713

Day 1 5065 000

Day 2 3632 000

Day 3 3319 000

70E20 Static (86) Perm 110309 7750 184 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110409 7755 525 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110509 25812 2785 000

True HS 205 000

72 DHB 65-105 120809 7817

Day 1 5804 000

Day 2 4338 000

Day 3 3754 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

Vehicle 208c


43

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 208c - 2002 Chevrolet Trailblazer

9 psi E20 - 7695

7 psi E20 - 7750

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7699

7 psi E20 - 7755


44

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 208c - 2002 Chevrolet Trailblazer

9 psi E20 - 25798

7 psi E20 - 25812


0

200

400

600

800

1000

1200

1400

1600

1800

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 208c - 2002 Chevrolet Trailblazer

9 psi E20 - 7713

7 psi E20 - 7817


45


Vehicle 209c

Reactivity Results

2004 Chrysler Stratus SHED




209c 90E20 Static (86) Perm 100109 7708 420 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 100209 7710 721 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 100509 25802 3671 000

True HS 719 000

72 DHB 65-105 110309 7753

Day 1 4564 020

Day 2 3383 030

Day 3 3160 090

70E20 Static (86) Perm 120209 7806 235 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 120309 7809 411 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 120409 25819 2560 000

True HS 282 000

72 DHB 65-105 011210 7856

Day 1 6107 000

Day 2 3160 010

Day 3 2581 040

72 DHB 65-105 020910 7881

Day 1 5647 000

Day 2 3771 000

Day 3 2827 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90

Vehicle 209c


46

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 209c - 2004 Chrysler Stratus

9 psi E20 - 7708

7 psi E20 - 7806

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7710

7 psi E20 - 7809


47

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 209c - 2004 Chrysler Stratus

9 psi E20 - 25802

7 psi E20 - 25819


0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 209c - 2004 Chrysler Stratus

9 psi E20 - 7753

7 psi E20 - 7856

7 psi E20 Repeat - 7881


48


Vehicles 210c

Reactivity Results

2004 Chevrolet Impala SHED




210c 90E20 Static (86) Perm 092409 7701 180 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092509 7702 327 000

Press Incr 00

Prs+Fuel Incr 46

Dynamic RL 092809 25799 1943 000

True HS 540 000

72 DHB 65-105 101309 7725

Day 1 3523 030

Day 2 2749 160

Day 3 2977 700

70E20 Static (86) Perm 110509 7758 152 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110609 7761 340 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110909 25813 1246 000

True HS 759 000

72 DHB 65-105 121509 7826

Day 1 3686 050

Day 2 2836 070

Day 3 2711 120

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


49

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 210c - 2004 Chevrolet Impala

9 psi E20 - 7701

7 psi E20 - 7758

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7702

7 psi E20 - 7761


50

0

50

100

150

200

250

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 210c - 2004 Chevrolet Impala

9 psi E20 - 25799

7 psi E20 - 25813


0

200

400

600

800

1000

1200

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 210c - 2004 Chevrolet Impala

9 psi E20 - 7725

7 psi E20 - 7826


51


Vehicle 213c

Reactivity Results

2004 Dodge Ram 1500 SHED




213c 90E20 Static (86) Perm 100809 7718 374 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 102909 7746 751 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 111309 25816 2572 082

True HS 40 005

72 DHB 65-105 120109 7803

Day 1 6442 000

Day 2 5293 000

Day 3 4606 000

70E20 Static (86) Perm 121609 7828 229 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 121709 7830 651 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 121809 25821 1869 000

True HS 334 000

72 DHB 65-105 020210 7872

Day 1 5019 000

Day 2 5384 000

Day 3 5461 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


52

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 213c - 2004 Dodge Ram 1500

9 psi E20 - 7744

7 psi E20 - 7828

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7746

7 psi E20 - 7830


53

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 213c - 2004 Dodge Ram 1500

9 psi E20 - 25816

7 psi E20 - 25821


0

200

400

600

800

1000

1200

1400

1600

1800

2000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 213c - 2004 Dodge Ram 1500

9 psi E20 - 7803

7 psi E20 - 7872


54


Vehicle 221c

Reactivity Results

2000 Mitsubishi Galant SHED




221c 90E20 Static (86) Perm 122409 7840 265 000

Press Incr 6165

Prs+Fuel Incr 6734

Static (105) Perm 122309 7838 723 000

Press Incr 10328

Prs+Fuel Incr 10971

Dynamic RL 122809 25824 1266 000

True HS 95 000

72 DHB 65-105 011910 7859

Day 1 7508 040

Day 2 5847 150

Day 3 5649 400

70E20 Static (86) Perm 020410 7875 394 000

Press Incr 5312

Prs+Fuel Incr 5061

Static (105) Perm 020510 7877 630 000

Press Incr 7462

Prs+Fuel Incr 7806

Dynamic RL 020810 25828 619 000

True HS 25 000

72 DHB 65-105 030210 7906

Day 1 8172 000

Day 2 5442 000

Day 3 4988 070

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


55

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 221c - 2000 Mitsubishi Galant

9 psi E20 - 7840

7 psi E20 - 7875

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7838

7 psi E20 - 7877


56

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 221c - 2000 Mitsubishi Galant

9 psi E20 - 25824

7 psi E20 - 25828


0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 221c -2000 Mitsubishi Galant

9 psi E20 - 7859

7 psi E20 - 7906


57


Vehicle 222c

Reactivity Results

This is the ldquoZero Evaprdquo model tested in this program and has very low emission levels On

many of the speciated tests in the table above the individual species were below the GC

detection limit As such the results appear as 0

2004 Ford Focus SHED




222c 90E20 Static (86) Perm 122909 7843 92 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 123009 7847 69 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 011510 25827 447 000

True HS 76 000

72 DHB 65-105 020210 7871

Day 1 736 000

Day 2 514 000

Day 3 401 040

70E20 Static (86) Perm 022510 7898 69 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 022610 7901 71 000

Press Incr 00

Prs+Fuel Incr 00

72 DHB 65-105 030910 7916

Day 1 655 000

Day 2 427 030

Day 3 395 030

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


58

0

2

4

6

8

10

12

14

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86deg F PermeationVehicle 222c - 2004 Ford Focus

9 psi E20 - 7843

7 psi E20 - 7898

0

2

4

6

8

10

12

14

16

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7847

7 psi E20 - 7901


59

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 222c - 2004 Ford Focus

9 psi E20 - 25827

7 psi E20 -25830


0

50

100

150

200

250

300

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

Three Day DiurnalVehicle 222c - 2004 Ford Focus

9 psi E20 - 7871

7 psi E20 - 7916


60

Appendix II ndash Task 47

Appendix II contains the individual vehicle data and plots that display the effect of leak location

on permeation emissions as run for Task 47 of this program


86ordm F static tests the running loss and hot soak test and the cumulative three day diurnal test with

the implanted leak in the tank top and the canister inlet


61


Vehicle 207c

Reactivity Results

2001 Dodge Caravan SHED




207c 100E10 Static Perm 082709 7661 6102 000

Tank Top (020) Fuel Incr 4353

Dynamic RL 102009 25805 9997 000

Tank Top (020) True HS 14915 000

24 DHB 65-105 090309 7672

Tank Top (020)

65125 000

70E10 Static Perm 091809 7693 5235 000


Dynamic RL 100209 25801 27694 000


24 DHB 65-105 102709 7741

Tank Top (020) 70847 000

100E10 Static Perm 111809 7781 2325 000

Can Inlet (020) Fuel Incr 10837

Dynamic RL 111909 25817 9375 000

Can Inlet (020) True HS 11140 000

24 DHB 65-105 112409 7794

Can Inlet (020) 105198 000

70E10 Static Perm 120909 7819 1448 000


Dynamic RL 121009 25820 11146 000


24 DHB 65-105 122909 7844

Can Inlet (020) 70668 000

Test Fuel Leak Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E10 - 10 psi Tank Top 7661 13923 37072 2663 71

Static E10 - 7 psi Tank Top 7693 8737 25269 2892 70

E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18

Dynamic E10 - 10 psi Tank Top 25805 32476 89876 2767 99

E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104

Total E10 - 7 psi Tank Top 7741 76987 227741 2958 107

E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


62

0

200

400

600

800

1000

1200

1400

1600

1800

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86 F PermeationVehicle 207c - 2001 Dodge Caravan

0020 Imbedded Leak in Top of Fuel Tank

10 psi E10 - 7661

7 psi E10 - 7693

0

100

200

300

400

500

600

700

800

900

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


0020 Imbedded Leak in Canister Inlet

10 psi E10 - 7781

7 psi E10 - 7819


63

0

500

1000

1500

2000

2500

3000

3500

4000

4500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 207c - 2009 Dodge Caravan


10 psi E10 - 25805

7 psi E10 - 25801


0

500

1000

1500

2000

2500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25817

7 psi E10 - 25820



64

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

One Day DiurnalVehicle 207c - 2009 Dodge Caravan


10 psi E10 - 7672

7 psi E10 - 7741

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7794

7 psi E10 - 7844


65


Vehicle 211c

Reactivity Results

2004 Toyota Camry LE SHED




211c 100E10 Static Perm 081209 7636 1925 000


Dynamic RL 081309 25788 8204 000


24 DHB 65-105 081909 7648

Tank Top (020) 89107 3560

70E10 Static Perm 090209 7669 4491 000


Dynamic RL 090309 25793 3418 000


24 DHB 65-105 091009 7681

Tank Top (020) 28842 000

100E10 Static Perm 101909 7732 2247 000


Dynamic RL 102909 25809 153795 000


24 DHB 65-105 111109 7769

Can Inlet (020) 115481 550

70E10 Static (86) Perm 112409 7793 2170 000

Can Inlet (020)Prs+Fuel Incr 7890

Dynamic RL 112509 25818 47103 082



Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E10 - 10 psi Tank Top 7636 7832 802 6278 16694 2659 61

Static E10 - 7 psi Tank Top 7669 10710 1106 11846 38214 3226 70

E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63

Dynamic E10 - 10 psi Tank Top 25788 25206 780 19657 60694 3088 66

E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45

Total E10 - 7 psi Tank Top 7681 28842 1078 31093 97716 3143 80

E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


66

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes

Static 86 F PermeationVehicle 211c - 2004 Toyota Camry LE


10 psi E10 - 7636

7 psi E10 - 7669

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7732

7 psi E10 - 7793


67

0

500

1000

1500

2000

2500

3000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 211c - 2004 Toyota Camry LE


10 psi E10 - 25788

7 psi E10 - 25793


0

2000

4000

6000

8000

10000

12000

14000

16000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25809

7 psi E10 - 25818



68

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs

One Day DiurnalVehicle 211c - 2004 Toyota Camry LE


10 psi E10 - 7648

7 psi E10 - 7681

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7769

7 psi E10 - 7836


69

Appendix III ndash Test Concept

The testing concept and procedures used in this program have evolved throughout the CRC E-77

program series and are included here for reference

The E-77 Test Concept Measuring Leaks Permeation and Diurnal Vapor Losses

CRCrsquos E-77 emission test programs have developed (and strive to continually improve) new

methodologies for understanding and quantifying vehicle evaporative emission rates The

concept partitions and assigns the vehiclersquos contribution to the evaporative emission inventory

into three mechanisms

1 Permeation

2 Tank vapor venting

3 Leaks (with two subsets - Liquid and Vapor)

Permeation is the migration of HC through the various elastomers in a vehicle fuel system16

Previous testing has shown that permeation rate is strongly affected by the materialrsquos

temperature doubling for each 10ordmC (18ordmF) increase in the range of normal summer temperatures

(See among others CRC E-653 report) It is also strongly affected by gasoline composition

especially with ethanol-containing fuels

Tank vapor venting emissions are controlled by fitting a carbon canister to the atmospheric tank

vent Figure A1 is a schematic of a typical early control system During a daily heating period

the temperature of the vehiclersquos fuel tank increases forcing HC vapors from the tank Excess

emissions exceeding the carbon canisterrsquos capacity are vented to the atmosphere

Figure A-1 Control System Schematic

16

ldquoFuel Permeation from Automotive Systems Final Report CRC Project E-65rdquo Haskew Liberty and

McClement September 2004 available on the CRC and California Air Resources Board websites


70

Leaks can be liquid or vapor Mass emissions are measured in a VT SHED or Variable

Temperature Sealed Housing for Evaporative

Determination The SHED test method combines all

three emission mechanisms (leaks diurnal venting and

permeation) into a single test result

The SHED technique involves placing the vehicle in a

sealed enclosure (Figure A2) and calculating the mass

in the enclosure from the volume density and

concentration in the enclosure at the start and end of a

time period The difference between the mass at the

start and end of test is the emission rate eg grams per

unit time

Permeation and tank venting losses are strongly

driven by fuel composition ambient temperature and

ambient temperature change Liquid leaks are not

strongly affected by normal summer temperatures

and are thought to have two components

1 Static leaks occurring while the engine is turned off and the vehicle is stationary

2 Increase in leak rate caused by the system pressure increase during engine operation

Each is described in detail below

1 Static Permeation Testing

The constant temperature (static) permeation rate is measured in a traditional SHED (Constant

temperature) in the following manner

A The fuel tank is drained and filled to 40 tank capacity with the test fuel

B The day before testing the vehicle is driven over four road trips of 75 miles each to

precondition the canister17

(These drives are similar to the LA-4)

C Upon return from the road pre-conditioning the fuel tank is drained and filled to 40

tank capacity with the test fuel18

D Vehicle is parked for 18-22 hours in a controlled temperature environment at test

temperature (86ordmF)

E The vehicle is then moved (without starting) into the test (86ordmF) SHED

F The canister vent is connected to the SHED bulkhead fitting which routes the vapor to

the trap canister outside the SHED

G The tank system pressurization hose is connected

H The fuel pump electrical connection is connected

17

This conditioning can be done in the laboratory on a chassis dynamometer if proper attention is paid to

underbody cooling and unrepresentative fuel tank temperatures are avoided 18

Vehicles with ORVR systems will add the refueling vapors to the canister This is OK

Figure A-2 Sealed Housing for Evaporative

Determination


71

I The SHED is sealed the inside temperature is allowed to stabilize and the test is started

Continuous total hydrocarbon (THC) measurements are made using a FID Ethanol

methanol and R134a concentrations are measured using an INNOVA analyzer All

measurements are made at least every minute for one hour to determine the stabilized

permeation rate

J At the end of the static test (60 minutes) the vehiclersquos vapor system is pressurized to 5

inches of water for thirty minutes Measurements are made to quantify vapor leaks as

determined by a change in the SHED uncorrected mass

K The fuel pump is then energized for 30 minutes while maintaining the 5 inches of water

on the vapor system Liquid leaks are quantified as determined by a change in the SHED

concentrations

The purpose of steps J and K above is to validate that the permeation rate measurement was

made without the presence of any leak ndash either liquid or vapor

2 Running Loss Test (Dynamic Test)

A The vehicle is placed in the RL-SHED and prepared for test (The fuel level and

condition for the dynamic test is the fuel remaining after completion of the static test ndash

40 fresh fill of the appropriate test fuel)

B Outside air source for the engine is connected

C Vehicle exhaust is connected

D Fuel tank thermocouple is connected

E Canister vent is connected to the SHED bulkhead fitting which routes the vapor to the

trap canister outside the SHED

F Vehicle is allowed to stabilize in the RL-SHED at test temperature (86degF) for a minimum

of 12 hours ndash preferably overnight

G Two cycles of the Unified Cycle (LA-92) driving schedule (48 minutes) are driven while

measuring the mass emissions in the SHED Vehicle is allowed to idle (in drive) for 30

seconds between the two cycles Ambient air temperature is maintained (to the extent

possible) at 86degF Fuel tank surface temperature is monitored during vehicle operation It

should increase during the drive from 10 to 18degF to simulate expected on-road

temperature increase Measured mass emissions are corrected using the INNOVA data

for the ethanol methanol and refrigerant emissions

3 Hot Soak19

This procedure is executed immediately following the Running Loss Test procedure

described above

A Engine is turned off transmission selector is placed in park and driver exits the

enclosure using the double door air lock taking care to minimize any air exchange

between the laboratory and the SHED This starts the one hour ldquohot soakrdquo period

19

Our definition is that the ldquohot soakrdquo is the temporary increase in emission rate caused by the vehiclersquos

immediately preceding operation It is the increase in the SHED mass (corrected for EtOH MeOH and R-134a)

over the one hour period minus the previously established ldquostaticrdquo permeation rate


72

B Measurement of mass emissions in the SHED are continued for another 60 minutes (until

time = 108 minutes) correcting for the ethanol methanol and refrigerant mass using the

INNOVA instrument data This ends the hot soak Hot soak emissions are calculated as

the net difference for the one hour hot soak (CorrMass108 ndash CorrMass48 minus the 86degF

static hourly rate all mass rates in mghour)

4 Diurnal Test


B The day before testing the vehicle is to be driven over four road trips of 75 miles each to

precondition the vehicle and the canister


tank capacity with the test fuel

D The vehicle is parked for 18-22 hours in a controlled temperature environment at the

initial diurnal test temperature (65ordmF)

E The SHED is sealed allowed to stabilize at the 65degF temperature and the 3-day

California Diurnal Test is started

F ldquoContinuousrdquo (every 30 seconds) total hydrocarbon (THC) measurements are made using

a FID Ethanol methanol and R134a (refrigerant) concentrations are measured using an

INNOVA analyzer at least every 10 minutes for the duration of the test (72 hours)

Static Permeation Test ndash Leak Validation

If a leak is detected during either the vapor system pressure portion (Step J) or the pump

energized portion (Step K) of the Static Permeation Test procedure it calls into question whether

the permeation rate measurement accurately reflects fuel system permeation or if instead a

combination of permeation and the implied leak was measured If a leak is confirmed the

permeation rate measurement is called into question and an investigation possible remedy and

retest is indicated

The permeation rate measurement must be corrected for the FIDrsquos ethanol misrepresentation and

the presence of non-fuel hydrocarbons (methanol and refrigerant) The leak check however is

made using the change in mass increase in the SHED using the uncorrected FID mass calculation

as the determinate We found that the corrections for ethanol methanol and refrigerant were

introducing ldquonoiserdquo into the trace that we were misinterpreting as leak(s)


73

Figure A-3 represents the calculations made during the inspection of data from a successful test

EXCELrsquoscopy

ldquoSLOPErdquo function is used to calculate the linear regression values based on the FID

calculation for mass for Time 0 to 60 minutes Time 64 to 90 minutes and Time 94 to 120

minutes A 4 minute gap was included between each sequence to establish the new mass

emission rate during the ldquopressure onrdquo (T60 to T90) and the ldquopump energizedrdquo periods

The slope of 706 mghr for the ldquoTank Pressurizedrdquo period in the example above is compared to

the slope of 705 mghr calculated for the permeation rate (or hot soak) period If the ldquoTank

Pressurizedrdquo slope is not more than 10 higher than the 0 to 60 minute permeation rate we

assume that there is no leak present A similar comparison is made for the slope determined

during the ldquopump onrdquo period The choice of a 10 allowance is arbitrary and is used here to

allow for normal and unavoidable test variation

For tests in which the above procedure determines that no leak is present a value of zero is

reported in the test summary for the leak results If a positive value is reported it calls that test

into question and an investigation possible repair and retest is indicated

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

SH

ED

Mass -

mg

Test Time - minutes

Static 105deg F PermeationVehicle 209c - 2004 Chrysler Stratus - 9 psi E20

Steady StatePermeation

Test 7710

Pump Activated

Basic Permeation Rate 105ordm F - 721 mghr (1729 mgday)

Blue line is raw SHED massSteady State Permeation is based on first

hour corrected SHED mass (red line)

Tank Pressurized

Slope = 705 mghr

Slope = 706 mghr

Slope = 761 mghr

Figure A-3 Leak Test


74

Static Permeation Rate Determination

The static permeation rate is determined based on a linear regression through the individual

corrected fuel data points (30 second data) for the first 60 minutes of testing as illustrated by the

corrected FID data shown in the red trace in Figure A-3 above in this case 721 mghour

Dynamic (Running Loss) and Hot Soak Test

The preceding section addressed the concepts of separating the permeation emissions from the

tank venting emissions and establishing the presence or absence of leaks The second part of

this study includes a dynamic test to measure the permeation and tank venting emissions during

vehicle operation (ldquorunning lossesrdquo) and the temporary condition following vehicle operation

known as the ldquohot soakrdquo

This is considered a ldquodynamicrdquo test because the vehicle is driven and the fuel and vapor system

temperatures rise during the test The ambient temperature in the Running Loss SHED during

test was held constant at 86degF while the vehiclersquos fuel system temperature rose during the test

Two 1435 second (239-minute) LA-92 driving cycles were performed consecutively during the

running loss measurements with a 30 second idle in-between During this test tank fuel

temperature was expected to rise by an average approximately 18degF above the initial ambient

temperature The running loss air handling system included a proportional speed under-car

blower operated as a slave to dynamometer speed This apparatus was used during running loss

testing with minor tuning for specific vehicles It is without additional input capable of

reasonable fuel tank temperature control Each vehicle was fitted with a surface-mount

thermocouple at the front of the fuel tank located at approximately the 18th

fill level to measure

the fuel liquid temperature No attempt was made to follow a predefined fuel tank temperature

profile (FTTP) in this program Fuel temperatures were recorded and results are available in the

real-time records


75

Vehicle running loss emissions are measured in a special version of a SHED known as a

Running Loss SHED (RL-SHED)20

shown in Figure A-4 Special features of the RL-SHED

include a sealed chassis dynamometer for simulating vehicle driving loads a sealed outside air

supply for engine intake a sealed exhaust conduit for engine exhaust and an under-chassis fan

for simulating underbody air flow as described above A vehicle is operated inside the RL-SHED

over a chosen driving cycle The increase in HC emissions inside the enclosure are measured

and calculated as mass emissions per 40 CFR sect86163-96 Vehicle testing in an RL-SHED is

complicated by several factors including

1 The engine must be supplied with external induction air

2 The exhaust must be conducted externally without any leaks

3 The load supplied to the vehicle through the chassis dynamometer must not create or

allow external leaks

4 The internal SHED temperature must be maintained while sizable heat is rejected to

the ambient by the running engine and exhaust

5 The cooling air supplied to the radiator must be modulated to represent the vehiclersquos

road speed

6 The underbody (and especially the fuel system) temperature should represent the rate

of rise experienced by a real road-drive

Canister vent losses were isolated from permeation emissions using the technique described

previously The vehiclersquos carbon canister fresh air vent was connected to the outside of the RL-

SHED using a leak-tight Teflonreg hose connected to a small carbon ldquotraprdquo canister located on a

20

See SAE 1999-01-1464 ldquoRunning Loss Emissions from In-Use Vehicles Harold Haskew et al May 1999 for

a more comprehensive discussion of running loss measurement detail Also available as CRC Report 612

Project E35-2 ldquoRunning Loss Emissions from In-Use Vehiclesrdquo available in the engineering report section of

the CRC web-site wwwcrcaoorg

Figure A-4 - Vehicle Installed in Running

Loss SHED SHEDSHED


76

top-loading precision scale outside the SHED The scale precision was 001 grams (10

milligrams) There were no tank venting emissions measured on any of the running loss test

measurements All of the vehicles appeared to be actively ldquopurgingrdquo the vehiclersquos control

canister and drawing fresh air during the test If there were any emissions from the vehiclersquos

canister as might have occurred if there were no vehicle purge or if very high volatility fuels

with excessive vapor generation were used it would have been measured

The Running Loss Driving Cycle consisted of two cycles of the ldquoUnified Driving Cyclerdquo otherwise

known as the LA-92 A velocity versus time plot for one cycle is shown in Figure A-5

The LA-92 cycle takes 24 minutes to complete and covers 98 miles with many speed changes

Two back-to-back cycles were driven the first as a ldquocold startrdquo and the second following a 30

second vehicle idle The ldquocold startrdquo condition was created by soaking the vehicle for a

minimum of 18 hours at 86degF moving it to the stabilized 86degF RL-SHED making the test

connections and then waiting a minimum of one hour before the initial start and run

The SHED emissions were measured during the 48 minutes of engine operation and then

continuously for one hour after the engine was turned off This one hour engine-off duration

was the ldquohot soakrdquo period The total test time is 1 hour and 48 minutes

Figure A-6 shows results from the 9 psi E20 fuel test on Vehicle 209c The horizontal axis is test

time in minutes and the vertical axis is the HC mass measured in the RL-SHED during the test

period

The engine was shut off at the end of the second LA92 drive cycle (~48 minutes) and the

analysis system continued to measure the HC emissions in the SHED for the next 60 minutes

This represented the ldquohot soakrdquo portion of the test

Figure A-5 - Running Loss Driving Cycle

Unified Cycle (LA-92)

0

10

20

30

40

50

60

70

80

0 5 10 15 20 25Test Time - minutes

Spe

ed -

mph

Cycle Time (min) 239

Maximum Speed (mph) 672

Average Speed (mph) 246

Average Non-Zero Speed (mph) 294

Time Zero Speed () 162

Distance (miles) 982


77

The ldquoTruerdquo Hot Soak

The traditional hot soak is determined from the increase in SHED emissions as measured for one

hour following a prescribed drive to heat up the vehicle (2 LA-92 cycles during the Running

Loss Test) Hot soak emissions however have two components one that is caused by the

elevated temperature resulting from the drive and another that results from one hour of static

permeation

To separate these two components and determine the ldquotruerdquo hot soak emissions the following

procedure was used ldquoTraditionalrdquo hot soak emissions were first calculated by subtracting the

ldquostart of hot soakrdquo cumulative SHED hydrocarbon value (ie 2936 mg t = 48 minutes) from

the final cumulative SHED hydrocarbon value (ie 3793 mg t = 108 min) This resulted in a

cumulative SHED hydrocarbon value of 857 mg for the one hour hot soak The previously

determined 86ordmF static permeation value (ie 420 mghr) was then subtracted to arrive at the

ldquotruerdquo hot soak value of 437 mg

In Figure A-6 the static permeation rate is superimposed as a solid blue line on the plot from the

starting point of the hot soak until its end (one hour) While the ldquotraditionalrdquo hot soak would be

calculated as 857 mg the ldquotruerdquo hot soak is determined as 437 mg True hot soak values

reported here were determined in this manner

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100 120

Co

rre

cte

d T

ota

l Fu

el C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes

Running Loss and Hot SoakVehicle 209c - 2004 Chrysler Stratus - 9 psi E20

Test 25802


Running Loss Std =005 gmiThis Test = 0015 gmi

2936 mg

3793 mg

3356 mg

True HS = 437 mghr

Figure A-6 - Running Loss and Hot Soak

Results


78

Diurnal Test

Diurnal permeation was determined by subjecting the vehicle to a three-day period in a

temperature controlled SHED while recording the total hydrocarbon every 30 seconds The

SHED environmental temperature was varied from 65degF to 105degF per the California Diurnal Test

protocol Canister vent losses were isolated from permeation emissions using the technique

described previously The vehiclersquos carbon canister fresh air vent was connected to the outside

of the RL-SHED using a leak-tight Teflonreg hose connected to a small (1 L) carbon ldquotraprdquo

canister located on a top-loading precision scale The scale precision was 001 grams (10

milligrams)

ATLrsquos Speciation Method

ATL has developed a hydrocarbon speciation method that is functionally equivalent to the dual-

GC AQIRP method The AQIRP or ldquoAutoOil Programrdquo test method was first documented in

two SAE papers

1 SAE 920320 Advanced Emission Speciation Methodologies for the AutoOil Air Quality

Improvement Research Program -I Hydrocarbons and Ethers and

2 SAE 920321 Advanced Emissions Speciation Methodologies for the AutoOil Air

Quality Improvement Research Program ndash II Aldehydes Ketones and Alcohols

A later update to the HC and Oxygenates procedures was published as

SAE 930142 Improved Emissions Speciations Methodology for Phase II of the AutoOil

Air Quality Improvement Program Hydrocarbons and Oxygenates

(See also for reference ARBrsquos SOP NO MLD 115 ldquoProcedure for the Determination of Ethers

and Alcohols in Gasoline by Gas Chromatographyrdquo January 2003 and SOP NO MLD 118

ldquoProcedures for the Detailed Hydrocarbon Analysis of Gasolines by Single Column High

Efficiency (Capillary) Column Gas Chromatographyrdquo August 1997)

Instrumentation demands are simplified and overall analysis time is shortened yet high

resolution and sensitivity are still achieved In this single-GCdual column method all

components are separated using on column type and temperature program Analysis time for a

cycle is 65 minutes Each exhaust or evaporative gas sample is simultaneously injected (using a

single sampling from the bag) into two identical columns present in the GC A Varian Model

3400 GC is used for hydrocarbon (HC) analysis The GC is equipped with a dual temperature-

controlled Valco 6-port valve injector dual flame ionization detectors (FID) and dual 60 meter x

032-mm ID fused silica capillary columns with 10micro polydimethylsiloxane stationary phase

(JampW DB-1) One of the injectors uses an 85 microL sampling loop for low sensitivity analysis of

C1-C12 while the other injector either uses a 1000 microL loop for high sensitivity analysis of C4-C

12

(for simultaneous lowhigh sensitivity analysis of a single bag sample) Column A contains a

85microl sample loop (splitless injection) that provides an injection volume that is small enough to

allow resolution of the C1 through C4 hydrocarbons while large enough to retain the highest

sensitivity possible Column B receives a 1000microl splitless injection providing higher sensitivity

for components eluting after isobutane Quantitative comparison of two overlap components


79

(butane and isopentane) provides a quality control measure Data from Column A is used to

detect and quantitate the 12 earliest eluting hydrocarbons with detection limits of 15-25 ppbvC

corresponding to 02-03 mgmi hydrocarbon for FTP stages 1 and 3 and 03-05 mgmi for FTP

stage 2 Data from Column B gives detection limits 0017-004 mgmi HC for components

eluting after isopentane (18th

in elution order) The components eluting between the 9th

and 18th

in elution order have detection limits ranging between the levels listed above for each column

The advantage of this approach is that even for relatively clean vehicles essentially all of the

first 12 species are typically present at levels exceeding the Column A detection limit Those

speciated components that are below the first column detection limit tend to be in the molecular

weight range best suited for the 1000microl injection analysis which provides the limits 0017-004

mgmi HC for components eluting after isopentane (18th

in elution order) where additional

sensitivity is needed In previous work that applied this analysis approach detection limits were

determined to be between 002-006 mgmi for the toxics 13-butadiene and benzene

ATLrsquos hydrocarbon method uses Varian 3600 GCs with dual injectors columns and flame

ionization detectors allowing two similar analyses to be run simultaneously as mentioned

above A Varian Star PC-based (using Microsoft Windowstrade) data system is used for data

acquisition Custom-made software is used for peak identification and converting data into a

Microsoft Exceltrade spreadsheet format A comparison of the total hydrocarbon determined using

the GC versus the CVS (ldquospeciation recoveryrdquo) is used as a quality control measure and ATL

routinely achieves hydrocarbon speciation recoveries ranging from 93 to 105 for lower

emitting vehicles A 23 hydrocarbon component standard mixture is analyzed at the start of each

day on each GC to provide quantifying coefficients and a quality control check on daily

reproducibility of instrument performance


80

Appendix IV ndash Speciation and Reactivity Results

Appendix I contains the individual vehicle data generated from the speciation tests performed on

all the evaporative tests run for this program

For each vehicle there is a summary table reactivity results followed by the speciation results for

each test The data shown for the speciation test is sorted by decreasing VOC mass identified


81

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


82

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4093 59307

Toluene 00108-88-3 393 1167 45800

2-Methylbutane (Isopentane) 00078-78-4 135 1114 15091

n-Pentane 00109-66-0 121 648 7871

1-Methyl-3-Ethylbenzene 00620-14-4 739 630 46563

n-Butane 00106-97-8 108 607 6533

Cyclohexane 00110-82-7 114 552 6281

2-Methyl-1-pentene amp 1-Hexene 00592-41-6+00763-29-1 530 529 28046

Benzene 00071-43-2 069 528 3668

Propane 00074-98-6 046 424 1938

t-2-Pentene 00646-04-8 1047 399 41785

n-Heptane 00142-82-5 097 378 3649

meta- amp para-Xylenes 00108-38-3+00106-42-3 776 376 29140

n-Hexane 00110-54-3 113 371 4207

124-TriMeBenz amp t-Butylbenzene 00095-63-6+00098-06-6 537 293 15716

2-Methyl-2-butene 00513-35-9 1420 284 40369

2-MePentane amp 4-Me-c-2-Pentene 00691-38-3+00107-83-5 140 271 3791

Methylcyclohexane 00108-87-2 156 227 3531

c-2-Pentene 00627-20-3 1028 188 19331

Methylcyclopentane 00096-37-7 205 181 3718

1-Pentene amp 2-Butyne 00109-67-1+00503-17-3 1170 181 21222

3-Methylpentane 00096-14-0 169 170 2882

2-Methyl-1-butene 00563-46-2 638 160 10232

2-Methylpropane 00075-28-5 118 152 1783

Cyclohexene amp 3-Methylhexane 00110-83-8+00589-34-4 319 151 4827


ortho-Xylene 00095-47-6 758 133 10090

2-Methylhexane 00591-76-4 109 119 1287

n-Octane 00111-65-9 080 113 0900

t-2-Hexene 04050-45-7 855 109 9344

n-Propylbenzene 00103-65-1 196 089 1748

135-Trimethylbenzene 00108-67-8 1175 081 9575

23-Dimethylbutane 00079-29-8 090 080 0716

Cyclopentene 00142-29-0 669 076 5114

3-Methyl-c-2-pentene 00922-62-3 1252 073 9169

1-Methylcyclopentene 00693-89-0 1245 071 8838

c-2-Hexene amp 3-MeCyclopentene 07688-21-3+01120-62-3 661 069 4537

224-TriMePentane (IsoOctane) 00540-84-1 120 066 0792

1-Ethyl-2-Methylbenzene 00611-14-3 554 066 3633

244-Trimethyl-2-Pentene 00107-40-4 630 065 4119

3-Methyl-t-2-pentene 00616-12-6 1166 064 7473

2-Methyl-2-pentene 00625-27-4 1103 064 7008

3-Methylheptane 00589-81-1 112 061 0683

c-2-Butene 00590-18-1 1426 059 8461

Vehicle 206c - Fuel 9 psi E20 - 86degF Static - Test 7685

Non Zero Mass Species Sorted By VOC


83

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylpentane 00565-59-3 125 057 0715

23-DiMeHexane amp 23-MeEtPentane 00584-94-1+ 109 050 0545

2-Methylpropene amp 1-Butene 00115-11-7+00106-98-9 794 048 3777


225-Trimethylhexane 03522-94-9 105 045 0474

2-Methylheptane 00592-27-8 097 044 0430

t-3-Hexene amp c-3-Hexene 13269-52-8+07642-09-3 743 039 2934

234-Trimethylpentane 00565-75-3 095 039 0371

t-12-Dimethylcyclopentane 00822-50-4 332 032 1067

c-13-Dimethylcyclopentane 02532-58-3 332 031 1027

Ethylbenzene 00100-41-4 296 028 0831


25-DiMeHexane amp EtCyPentane 00592-13-2+01640-89-7 161 018 0295

24-Dimethylhexane 00589-43-5 161 014 0230

22-Dimethylbutane 00075-83-2 111 013 0147

n-Undecane 01120-21-4 052 003 0017

Total 1620 5411 3340


continued


84

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7732 112029

Toluene 00108-88-3 393 2826 110931


n-Pentane 00109-66-0 121 1669 20279

n-Butane 00106-97-8 108 1531 16491


Benzene 00071-43-2 069 1317 9145


n-Hexane 00110-54-3 113 984 11164

n-Heptane 00142-82-5 097 955 9227

t-2-Pentene 00646-04-8 1047 867 90854



2-Methyl-2-butene 00513-35-9 1420 764 108513

22-DiMeHexane 00590-73-8 094 648 6097

3-Me-1-Hexene 03404-61-3 427 597 25518


2-Methylpropane 00075-28-5 118 483 5687


3-Methylpentane 00096-14-0 169 423 7157

c-2-Pentene 00627-20-3 1028 398 40907

2-Methyl-1-butene 00563-46-2 638 389 24834


Propane 00074-98-6 046 301 1376

ortho-Xylene 00095-47-6 758 277 21014

n-Octane 00111-65-9 080 263 2092



t-2-Hexene 04050-45-7 855 232 19857



23-Dimethylbutane 00079-29-8 090 188 1693

2-Methylhexane 00591-76-4 109 184 1996

c-2-Butene 00590-18-1 1426 177 25239


Ethylbenzene 00100-41-4 296 169 5008


n-Propylbenzene 00103-65-1 196 159 3125

3-Methyl-t-2-pentene 00616-12-6 1166 154 17969

Cyclopentene 00142-29-0 669 132 8836

Cyclopentane 00287-92-3 224 132 2955

2-Methylheptane 00592-27-8 097 126 1223

3-Methyl-c-2-pentene 00922-62-3 1252 120 14989





85

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 112 12354



3-Methylheptane 00589-81-1 112 094 1061






Ethylcyclohexane 01678-91-7 135 063 0847

3 amp 4-Methyl-1-Pentenes 00691-37-2+00760-20-3 578 061 3552


24-Dimethylhexane 00589-43-5 161 057 0919

4-Methyloctane 02216-34-4 085 053 0449

22-Dimethylbutane 00075-83-2 111 051 0570


Unknown 1 340 047 1585

t-14-Dimethylcyclohexane 02207-04-7 340 045 1535

12-Dimethyl-4-Ethylbenzene 00934-80-5 754 044 3289


3-Methyloctane 02216-33-3 088 038 0337

n-Nonane 00111-84-2 068 035 0239




1-Methyl-3-Propylbenzene 01074-43-7 708 011 0776

Total 3466 11867 3424


continued


86

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7327 106160

Toluene 00108-88-3 393 3583 140646


n-Heptane 00142-82-5 097 1994 19258



3-Me-1-Hexene 03404-61-3 427 1676 71615

Benzene 00071-43-2 069 1585 11004

n-Pentane 00109-66-0 121 1566 19031

n-Butane 00106-97-8 108 1325 14268

n-Hexane 00110-54-3 113 1227 13926



22-DiMeHexane 00590-73-8 094 1009 9495



2-Methyl-2-butene 00513-35-9 1420 747 105970

t-2-Pentene 00646-04-8 1047 620 64956


3-Methylpentane 00096-14-0 169 504 8518


Indan 00496-11-7 323 491 15896



Unknown 16 362 481 17425


c-2-Pentene 00627-20-3 1028 439 45108


2-Methylpropane 00075-28-5 118 426 5010

n-Octane 00111-65-9 080 421 3351

2-Methyl-1-butene 00563-46-2 638 400 25494

ortho-Xylene 00095-47-6 758 365 27632

Ethylbenzene 00100-41-4 296 362 10735

2-Methylheptane 00592-27-8 097 360 3479

3-Methylheptane 00589-81-1 112 308 3463



2-Methylhexane 00591-76-4 109 256 2775


23-Dimethylbutane 00079-29-8 090 243 2181


Unknown 22 362 215 7784



Vehicle 206c - Fuel 9 psi E20 - Dynamic - Test 25795



87

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




n-Nonane 00111-84-2 068 189 1293


n-Propylbenzene 00103-65-1 196 187 3660

Cyclopentene 00142-29-0 669 181 12085

3-Methyl-t-2-pentene 00616-12-6 1166 177 20606

3-Methyl-c-2-pentene 00922-62-3 1252 163 20443






244-TMe-1- amp 23-DMe-2-Pentene 00107-39-1+10574-37-5 654 121 7928

14-Diethylbenzene 00105-05-5 439 117 5152

c-2-Butene 00590-18-1 1426 115 16375


2-Methyl-13-butadiene 00078-79-5 1048 114 11930

t-2-Hexene 04050-45-7 855 107 9180

22-Dimethylbutane 00075-83-2 111 103 1150

2-Methyl-2-pentene 00625-27-4 1103 096 10613

4-Methyl-t-2-pentene 00674-76-0 804 094 7554


n-Decane 00124-18-5 059 072 0424


Unknown 1 362 044 1580

Total 4582 17092 3730


continued


88

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 101748 1474297


n-Pentane 00109-66-0 121 33510 407124

n-Butane 00106-97-8 108 32007 344688

Toluene 00108-88-3 393 27947 1096913


Benzene 00071-43-2 069 20586 142938

n-Hexane 00110-54-3 113 18393 208697

n-Heptane 00142-82-5 097 17284 166926

t-2-Pentene 00646-04-8 1047 16260 1702998

2-Methyl-2-butene 00513-35-9 1420 15272 2167853


3-Me-1-Hexene 03404-61-3 427 10391 444084

2-Methylpropane 00075-28-5 118 10116 119030


22-DiMeHexane 00590-73-8 094 8200 77181


c-2-Pentene 00627-20-3 1028 7670 788622

3-Methylpentane 00096-14-0 169 7668 129648

2-Methyl-1-butene 00563-46-2 638 6275 400280


t-2-Hexene 04050-45-7 855 4165 356031

2-Methylhexane 00591-76-4 109 3643 39538




n-Octane 00111-65-9 080 3249 25870


c-2-Butene 00590-18-1 1426 3092 440893


23-Dimethylbutane 00079-29-8 090 2952 26532

Cyclopentene 00142-29-0 669 2922 195335

3-Methyl-t-2-pentene 00616-12-6 1166 2669 311214

Cyclopentane 00287-92-3 224 2540 56827

Propane 00074-98-6 046 2428 11101

3-Methyl-c-2-pentene 00922-62-3 1252 2277 285007


2-Methyl-2-pentene 00625-27-4 1103 1964 216725




ortho-Xylene 00095-47-6 758 1425 107970



Vehicle 206c - Fuel 9 psi E20 - 3 Day Diurnal - Test 7703



89

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 1271 12292

Ethylbenzene 00100-41-4 296 1237 36651

22-Dimethylbutane 00075-83-2 111 1166 12955



3-Methylheptane 00589-81-1 112 1021 11484




n-Propylbenzene 00103-65-1 196 817 16017





n-Nonane 00111-84-2 068 489 3336

Unknown 1 333 488 16281



4-Methyloctane 02216-34-4 085 329 2788



3-Methyloctane 02216-33-3 088 287 2536



33-Dimethylhexane 00563-16-6 115 214 2470

Ethylene 00074-85-1 888 198 17628

t-13 amp c-14-DiMeCyHexane 02207-03-6+00624-29-3 333 178 5925

1-Octene 00111-66-0 314 170 5347

c-2-Heptene 06443-92-1 708 147 10435

Unknown 8 333 147 4886

223-Trimethylbutane 00464-06-2 105 141 1491

Unknown 5 333 132 4386

1-Nonene 00124-11-8 249 122 3031

Unknown 6 333 121 4021

Unknown 16 333 120 4008

Unknown 9 333 118 3924


Isopropylbenzene (Cumene) 00098-82-8 333 116 3880

Indan 00496-11-7 323 104 3374

Styrene 00100-42-5 166 095 1585

24-Dimethylheptane 02213-23-2 126 090 1141

continued


90

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-MeOctane amp 23-DiMeHeptane 03074-71-3+03221-61-2 085 078 0666

Unknown 3 333 072 2404

3-Me-t-3-Hexene amp t-2-Heptene 03899-36-3+14686-13-6 838 071 5945

n-Decane 00124-18-5 059 067 0395


24-DiMeOctane+AlBenz+PrCyHexane04032-94-4+00300-57-2+01678-92-8118 062 0737

Unknown 14 333 055 1850

1-Heptene 00592-76-7 429 051 2194

13-Butadiene 00106-99-0 1245 043 5325


4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


continued


91

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2884 41793


Toluene 00108-88-3 393 1217 47766

Benzene 00071-43-2 069 747 5186




n-Pentane 00109-66-0 121 684 8305

n-Butane 00106-97-8 108 611 6584



n-Hexane 00110-54-3 113 498 5652


n-Heptane 00142-82-5 097 475 4583

Propane 00074-98-6 046 468 2137



2-Methyl-2-butene 00513-35-9 1420 356 50602

t-2-Pentene 00646-04-8 1047 347 36348

ortho-Xylene 00095-47-6 758 323 24490


c-2-Butene 00590-18-1 1426 312 44524



n-Octane 00111-65-9 080 289 2300

n-Propylbenzene 00103-65-1 196 272 5339

Cyclohexane 00110-82-7 114 267 3042

2-Methylhexane 00591-76-4 109 267 2898

23-Dimethylbutane 00079-29-8 090 259 2328

Ethylbenzene 00100-41-4 296 228 6765

t-2-Hexene 04050-45-7 855 227 19378




Cyclopentane 00287-92-3 224 167 3744


3-Methyl-t-2-pentene 00616-12-6 1166 154 17932

2-Methyl-1-butene 00563-46-2 638 150 9546

3-Methyl-c-2-pentene 00922-62-3 1252 146 18246

Cyclopentene 00142-29-0 669 145 9721

2-Methylheptane 00592-27-8 097 144 1394


c-2-Pentene 00627-20-3 1028 135 13873





92

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 131 1478


3-Methylpentane 00096-14-0 169 123 2086


2-Methyl-2-pentene 00625-27-4 1103 122 13422

24-Dimethylhexane 00589-43-5 161 103 1653

Indan 00496-11-7 323 087 2810

22-Dimethylbutane 00075-83-2 111 086 0952

n-Nonane 00111-84-2 068 085 0583







1-MeCyHexene amp 4-MeHeptane 00591-49-1+00589-53-7 386 057 2213





14-Diethylbenzene 00105-05-5 439 045 1982


4-Methyloctane 02216-34-4 085 043 0366

4-Methyl-t-2-pentene 00674-76-0 804 041 3322

Unknown 1 412 034 1408


2-Methylpropane 00075-28-5 118 029 0340

n-Undecane 01120-21-4 052 029 0150





3-Methyloctane 02216-33-3 088 020 0174

Total 2183 9104 4170

No MIR available use weightedaverage of 41197

continued


93

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10102 146374

Toluene 00108-88-3 393 4080 160133

3-Methylnonane 05911-04-6 066 3338 21890




n-Pentane 00109-66-0 121 2300 27949

Benzene 00071-43-2 069 2108 14635


n-Butane 00106-97-8 108 2075 22348

n-Heptane 00142-82-5 097 1777 17164

n-Hexane 00110-54-3 113 1565 17760


t-2-Pentene 00646-04-8 1047 1024 107279

2-Methyl-2-butene 00513-35-9 1420 1009 143288

Cyclohexane 00110-82-7 114 926 10529





3-Methylpentane 00096-14-0 169 568 9606

c-2-Pentene 00627-20-3 1028 498 51245

2-Methyl-1-butene 00563-46-2 638 495 31574



n-Octane 00111-65-9 080 454 3615



ortho-Xylene 00095-47-6 758 403 30538

2-Methylhexane 00591-76-4 109 350 3798

n-Propylbenzene 00103-65-1 196 345 6759

Ethylbenzene 00100-41-4 296 312 9251

t-2-Hexene 04050-45-7 855 307 26270

2-Methylpropane 00075-28-5 118 262 3081

Cyclopentane 00287-92-3 224 250 5589


Cyclopentene 00142-29-0 669 211 14108

Propane 00074-98-6 046 192 0880

3-Methyl-t-2-pentene 00616-12-6 1166 192 22393

n-Nonane 00111-84-2 068 186 1270


23-Dimethylbutane 00079-29-8 090 179 1613






94

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 153 19093

2-Methyl-2-pentene 00625-27-4 1103 141 15538


24-Dimethylhexane 00589-43-5 161 132 2114


2-Methylheptane 00592-27-8 097 128 1233

4-Methyloctane 02216-34-4 085 125 1064

c-2-Butene 00590-18-1 1426 121 17277



3-Methylheptane 00589-81-1 112 109 1223

Indan 00496-11-7 323 104 3361





n-Decane 00124-18-5 059 065 0385



3-Methyloctane 02216-33-3 088 061 0539

13-Diethylbenzene 00141-93-5 708 056 3990




Unknown 1 330 049 1606

22-Dimethylbutane 00075-83-2 111 049 0540


n-Undecane 01120-21-4 052 043 0226

c-2-Heptene 06443-92-1 708 038 2676

2-Methyl-2-Hexene amp c-3-Heptene 02738-19-4+07642-10-6 784 036 2834


Unknown 8 330 025 0836

066 Total 5472 18251 3335


continued


95

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10462 151590

Toluene 00108-88-3 393 5022 197121






n-Heptane 00142-82-5 097 2541 24542

n-Pentane 00109-66-0 121 2430 29518

Benzene 00071-43-2 069 2379 16519

n-Butane 00106-97-8 108 2172 23395

n-Hexane 00110-54-3 113 1979 22456



Cyclohexane 00110-82-7 114 1349 15348




2-Methyl-2-butene 00513-35-9 1420 940 133406

t-2-Pentene 00646-04-8 1047 857 89767

n-Octane 00111-65-9 080 856 6816



3-Methylpentane 00096-14-0 169 706 11929

n-Propylbenzene 00103-65-1 196 696 13630

2-Methyl-1-butene 00563-46-2 638 655 41772


Propane 00074-98-6 046 515 2355

ortho-Xylene 00095-47-6 758 506 38317

Ethylbenzene 00100-41-4 296 497 14716

3-Methylheptane 00589-81-1 112 480 5394

c-2-Pentene 00627-20-3 1028 476 48903

2-Methylhexane 00591-76-4 109 425 4611

2-Methylpropane 00075-28-5 118 404 4753

3-Methyl-c-2-pentene 00922-62-3 1252 401 50144



t-2-Hexene 04050-45-7 855 369 31567

n-Nonane 00111-84-2 068 355 2423

2-Methyl-2-pentene 00625-27-4 1103 349 38516


Cyclopentane 00287-92-3 224 322 7198

2-Methylheptane 00592-27-8 097 317 3071

c-2-Butene 00590-18-1 1426 292 41607




96

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



4-Isopropyltoluene (p-Cymene) 00099-87-6 441 284 12512


Unknown 22 363 272 9893


3-Methyl-t-2-pentene 00616-12-6 1166 269 31312

Methane 00074-82-8 001 265 0037


3-Methyloctane 02216-33-3 088 255 2252






Cyclopentene 00142-29-0 669 208 13880

4-Methyloctane 02216-34-4 085 199 1691


23-Dimethylbutane 00079-29-8 090 188 1688

n-Decane 00124-18-5 059 168 0994


Indan 00496-11-7 323 160 5191



Unknown 18 363 147 5331

c-2-Heptene 06443-92-1 708 137 9666



24-Dimethylhexane 00589-43-5 161 123 1980




22-Dimethylbutane 00075-83-2 111 038 0418

Total 7165 26481 3696


continued


97

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 115502 1673600



n-Butane 00106-97-8 108 26699 287520

n-Pentane 00109-66-0 121 26567 322768

Toluene 00108-88-3 393 23849 936067

n-Heptane 00142-82-5 097 21212 204862

n-Hexane 00110-54-3 113 18520 210141

Benzene 00071-43-2 069 17238 119691



Cyclohexane 00110-82-7 114 9320 106002

t-2-Pentene 00646-04-8 1047 9137 956959

2-Methyl-2-butene 00513-35-9 1420 9120 1294599



3-Methylpentane 00096-14-0 169 6866 116094


c-2-Pentene 00627-20-3 1028 4504 463080


n-Octane 00111-65-9 080 4099 32639

2-Methyl-1-butene 00563-46-2 638 3977 253652


2-Methylhexane 00591-76-4 109 3789 41114



23-Dimethylbutane 00079-29-8 090 2988 26852

t-2-Hexene 04050-45-7 855 2686 229656

Cyclopentane 00287-92-3 224 2314 51777


Propane 00074-98-6 046 2085 9531



2-Methylpropane 00075-28-5 118 1854 21813

Cyclopentene 00142-29-0 669 1830 122352

3-Methyl-t-2-pentene 00616-12-6 1166 1808 210844



2-Methylheptane 00592-27-8 097 1688 16323

3-Methyl-c-2-pentene 00922-62-3 1252 1584 198290

c-2-Butene 00590-18-1 1426 1517 216368



2-Methyl-2-pentene 00625-27-4 1103 1493 164767




98

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 1325 14903

24-Dimethylhexane 00589-43-5 161 1322 21223

ortho-Xylene 00095-47-6 758 1234 93462

Ethylbenzene 00100-41-4 296 1170 34667




n-Propylbenzene 00103-65-1 196 978 19157


22-Dimethylbutane 00075-83-2 111 889 9880


n-Nonane 00111-84-2 068 734 5008




c-2-Heptene 06443-92-1 708 629 44542





4-Methyloctane 02216-34-4 085 439 3726



3-Methyloctane 02216-33-3 088 311 2751

Unknown 1 291 281 8158

33-Dimethylhexane 00563-16-6 115 274 3158


Ethylene 00074-85-1 888 238 21141

1-Octene 00111-66-0 314 226 7093

Unknown 5 291 226 6565




1-Butyne 00107-00-6 605 214 12957


Unknown 8 291 191 5566


1-Nonene 00124-11-8 249 155 3876

Indan 00496-11-7 323 134 4328




continued


99

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Non Zero Mass Species Sorted By VOCcontinued


Unknown 9 291 093 2704

t-4-Octene 14850-23-8 469 088 4141



n-Decane 00124-18-5 059 072 0424


Unknown 6 291 063 1842

t-3-Heptene 14686-14-7 617 058 3603

Unknown 3 291 050 1460

13-Butadiene 00106-99-0 1245 050 6187

c- amp t-4-Nonene 02198-23-4 442 039 1719


1-Heptene 00592-76-7 429 035 1513

n-Undecane 01120-21-4 052 025 0130


Total 48454 142309 2937



100

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

- No Ethanol

Vehicle 208c


101

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


3-Me-1-Hexene 03404-61-3 427 193 8262

Toluene 00108-88-3 393 158 6219


n-Heptane 00142-82-5 097 146 1414


22-DiMeHexane 00590-73-8 094 136 1277

n-Pentane 00109-66-0 121 131 1597



Benzene 00071-43-2 069 109 0753

n-Butane 00106-97-8 108 101 1090

n-Octane 00111-65-9 080 058 0466

n-Hexane 00110-54-3 113 054 0613

2-Methylheptane 00592-27-8 097 048 0466

2-Methylpropane 00075-28-5 118 047 0553


n-Nonane 00111-84-2 068 041 0277

n-Propylbenzene 00103-65-1 196 033 0656

2-Methyl-2-pentene 00625-27-4 1103 032 3544

ortho-Xylene 00095-47-6 758 030 2297


3-Methyl-c-2-pentene 00922-62-3 1252 026 3231



Cyclopentene 00142-29-0 669 022 1454



t-2-Hexene 04050-45-7 855 018 1569

3-Methyl-t-2-pentene 00616-12-6 1166 018 2140

Ethylbenzene 00100-41-4 296 018 0544

t-2-Pentene 00646-04-8 1047 018 1912

3-Methylpentane 00096-14-0 169 018 0298



2-Methylhexane 00591-76-4 109 015 0159

24-Dimethylhexane 00589-43-5 161 013 0203

2-Methyl-2-butene 00513-35-9 1420 011 1589

c-2-Butene 00590-18-1 1426 009 1344



Total 260 956 3672




102

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1745 25291


n-Heptane 00142-82-5 097 769 7424


Benzene 00071-43-2 069 594 4125

Toluene 00108-88-3 393 461 18075

n-Pentane 00109-66-0 121 365 4438


n-Hexane 00110-54-3 113 287 3251

n-Butane 00106-97-8 108 273 2945



22-DiMeHexane 00590-73-8 094 172 1616

2-Methyl-2-butene 00513-35-9 1420 170 24078

3-Me-1-Hexene 03404-61-3 427 156 6681


t-2-Pentene 00646-04-8 1047 139 14606



Cyclopentane 00287-92-3 224 118 2649

n-Octane 00111-65-9 080 108 0863

3-Methylpentane 00096-14-0 169 108 1823


2-Methylpropane 00075-28-5 118 094 1110



c-2-Pentene 00627-20-3 1028 085 8778

3-Methylheptane 00589-81-1 112 085 0956

n-Nonane 00111-84-2 068 084 0576


3-Methyl-t-2-pentene 00616-12-6 1166 078 9114


2-Methyl-1-butene 00563-46-2 638 056 3594

c-2-Butene 00590-18-1 1426 055 7872

ortho-Xylene 00095-47-6 758 051 3872



t-2-Hexene 04050-45-7 855 043 3697


Ethylbenzene 00100-41-4 296 036 1067


Cyclopentene 00142-29-0 669 029 1922






103

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 023 2569


3-Methyl-c-2-pentene 00922-62-3 1252 022 2706



22-Dimethylbutane 00075-83-2 111 010 0117




2-Methylhexane 00591-76-4 109 003 0037



Total 962 2919 3034


continued


104

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 964 37835

t-3-Heptene 14686-14-7 617 854 52708


n-Pentane 00109-66-0 121 709 8608

Benzene 00071-43-2 069 649 4509




3-Me-1-Hexene 03404-61-3 427 425 18160


22-DiMeHexane 00590-73-8 094 403 3797

22-Dimethylpropane 00463-82-1 065 394 2549




4-Methyl-t-2-pentene 00674-76-0 804 349 28047

n-Butane 00106-97-8 108 347 3739

n-Hexane 00110-54-3 113 346 3922

n-Propylbenzene 00103-65-1 196 335 6568

n-Octane 00111-65-9 080 327 2601

3-Methylpentane 00096-14-0 169 304 5148


2-Methylhexane 00591-76-4 109 290 3146

n-Butylbenzene 00104-51-8 229 279 6386

Isobutylbenzene 00538-93-2 422 273 11524

Indan 00496-11-7 323 272 8810

t-2-Pentene 00646-04-8 1047 264 27657

Ethylbenzene 00100-41-4 296 257 7618





2-Methyl-2-butene 00513-35-9 1420 223 31617


2-Methyl-1-butene 00563-46-2 638 193 12303


n-Nonane 00111-84-2 068 187 1276


c-2-Pentene 00627-20-3 1028 156 16054

t-2-Hexene 04050-45-7 855 154 13191

ortho-Xylene 00095-47-6 758 148 11239




105

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



13-Butadiene 00106-99-0 1245 145 18006



2-Methylheptane 00592-27-8 097 134 1296


23-Dimethylbutane 00079-29-8 090 128 1152

4-Methyloctane 02216-34-4 085 127 1079

Unknown 5 422 113 4773





2-Methylpropane 00075-28-5 118 097 1147

Unknown 9 422 092 3896

3-Methyl-t-2-pentene 00616-12-6 1166 076 8865

3-Methyl-c-2-pentene 00922-62-3 1252 074 9238


Cyclopentene 00142-29-0 669 065 4325


14-Diethylbenzene 00105-05-5 439 059 2575

24-Dimethylhexane 00589-43-5 161 052 0828

3-Methyloctane 02216-33-3 088 048 0425

Cyclopentadiene 00542-92-7 689 043 2984




22-Dimethylbutane 00075-83-2 111 009 0104

Total 2199 9732 4426


continued


106

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 40269 583488


n-Pentane 00109-66-0 121 6604 80237

n-Butane 00106-97-8 108 5757 61995


n-Heptane 00142-82-5 097 5013 48416

n-Hexane 00110-54-3 113 4359 49459

Toluene 00108-88-3 393 4128 162007


Benzene 00071-43-2 069 3151 21876


2-Methyl-2-butene 00513-35-9 1420 2458 348891

t-2-Pentene 00646-04-8 1047 2391 250449

2-Methylpropane 00075-28-5 118 2367 27847

Cyclohexane 00110-82-7 114 2317 26356


3-Methylpentane 00096-14-0 169 1942 32835



n-Octane 00111-65-9 080 1226 9760

c-2-Pentene 00627-20-3 1028 1186 121926


2-Methyl-1-butene 00563-46-2 638 1163 74158

2-Methylhexane 00591-76-4 109 1119 12144


t-2-Hexene 04050-45-7 855 759 64866

23-Dimethylbutane 00079-29-8 090 700 6289



2-Methylheptane 00592-27-8 097 569 5503

c-2-Butene 00590-18-1 1426 562 80095

Propane 00074-98-6 046 552 2525

Cyclopentane 00287-92-3 224 552 12353


3-Methyl-t-2-pentene 00616-12-6 1166 518 60429

3-Methylheptane 00589-81-1 112 482 5422

Cyclopentene 00142-29-0 669 479 32026

3-Methyl-c-2-pentene 00922-62-3 1252 469 58697



2-Methyl-2-pentene 00625-27-4 1103 422 46577







107

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Nonane 00111-84-2 068 349 2384

1-Butyne 00107-00-6 605 349 21088





24-Dimethylhexane 00589-43-5 161 299 4801

22-Dimethylbutane 00075-83-2 111 291 3238


ortho-Xylene 00095-47-6 758 271 20538

n-Propylbenzene 00103-65-1 196 263 5151

Ethylbenzene 00100-41-4 296 238 7052



4-Methyloctane 02216-34-4 085 223 1894




3-Methyloctane 02216-33-3 088 154 1363




33-Dimethylhexane 00563-16-6 115 109 1252

Unknown 8 276 087 2398



1-Octene 00111-66-0 314 081 2559


continued


108

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 276 066 1835

Unknown 1 276 065 1794





n-Decane 00124-18-5 059 049 0289

Unknown 5 276 045 1243

c-2-Heptene 06443-92-1 708 040 2835



1-Nonene 00124-11-8 249 019 0476

Total 12981 36292 2796


continued


109

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1522 22047

Toluene 00108-88-3 393 372 14601




n-Butane 00106-97-8 108 252 2718

n-Pentane 00109-66-0 121 229 2778


n-Undecane 01120-21-4 052 208 1088

n-Decane 00124-18-5 059 202 1193

n-Heptane 00142-82-5 097 197 1903

n-Hexane 00110-54-3 113 145 1643

1-Butyne 00107-00-6 605 142 8563

Benzene 00071-43-2 069 136 0943

Cyclohexane 00110-82-7 114 117 1336







3-Methylpentane 00096-14-0 169 077 1305


2-Methylpropane 00075-28-5 118 075 0882

n-Nonane 00111-84-2 068 072 0492

n-Propylbenzene 00103-65-1 196 070 1366



2-Methyl-2-butene 00513-35-9 1420 068 9604

23-Dimethylbutane 00079-29-8 090 061 0546

n-Octane 00111-65-9 080 060 0475


Cyclopentene 00142-29-0 669 054 3587



t-2-Pentene 00646-04-8 1047 046 4844

ortho-Xylene 00095-47-6 758 044 3308

3-Methyl-c-2-pentene 00922-62-3 1252 043 5429

2-Methylheptane 00592-27-8 097 042 0408

3-Methyl-t-2-pentene 00616-12-6 1166 042 4901


2-Methyl-2-pentene 00625-27-4 1103 039 4343


3-Methylheptane 00589-81-1 112 033 0371




110

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 030 3052


Unknown 22 305 027 0835

2-Methylhexane 00591-76-4 109 027 0296


Ethylbenzene 00100-41-4 296 024 0697

24-Dimethylhexane 00589-43-5 161 022 0354




22-Dimethylbutane 00075-83-2 111 011 0126

2-Methyl-1-butene 00563-46-2 638 006 0396


Total 691 2138 3094


continued


111

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1871 27109


Toluene 00108-88-3 393 522 20484


n-Heptane 00142-82-5 097 365 3521

n-Pentane 00109-66-0 121 351 4259

n-Butane 00106-97-8 108 298 3214







Benzene 00071-43-2 069 198 1372

n-Hexane 00110-54-3 113 173 1961



t-2-Pentene 00646-04-8 1047 126 13202

n-Octane 00111-65-9 080 116 0924

2-Methyl-2-butene 00513-35-9 1420 115 16378

Cyclohexane 00110-82-7 114 108 1232


3-Methylpentane 00096-14-0 169 101 1707

2-Methylpropane 00075-28-5 118 075 0884

2-Methylhexane 00591-76-4 109 059 0643

ortho-Xylene 00095-47-6 758 054 4058

2-Methyl-1-butene 00563-46-2 638 053 3361

c-2-Pentene 00627-20-3 1028 043 4388


066 Total 755 2232 2957




112

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 968 37976


n-Pentane 00109-66-0 121 522 6345

n-Heptane 00142-82-5 097 514 4964

Benzene 00071-43-2 069 512 3553





n-Propylbenzene 00103-65-1 196 434 8506




n-Octane 00111-65-9 080 341 2712

n-Hexane 00110-54-3 113 275 3123

n-Nonane 00111-84-2 068 271 1848

13-Butadiene 00106-99-0 1245 247 30791




2-Methylheptane 00592-27-8 097 231 2232

2-Methyl-1-butene 00563-46-2 638 227 14471

c-2-Pentene 00627-20-3 1028 221 22769

n-Butane 00106-97-8 108 194 2085

24-Dimethylhexane 00589-43-5 161 183 2939


Cyclohexane 00110-82-7 114 162 1841


23-Dimethylbutane 00079-29-8 090 150 1345

n-Decane 00124-18-5 059 136 0802


3-Methylpentane 00096-14-0 169 131 2214

2-Methylhexane 00591-76-4 109 104 1128


t-2-Pentene 00646-04-8 1047 070 7355

22-Dimethylbutane 00075-83-2 111 066 0737

3-Methylheptane 00589-81-1 112 066 0741

2-Methyl-2-butene 00513-35-9 1420 059 8434



Ethylbenzene 00100-41-4 296 053 1559




113

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylpropane 00075-28-5 118 022 0260

Total 1666 7311 4389

continued


114

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 42028 608972



n-Heptane 00142-82-5 097 6080 58717

n-Pentane 00109-66-0 121 5160 62696

n-Butane 00106-97-8 108 4881 52569

Toluene 00108-88-3 393 4149 162857

n-Hexane 00110-54-3 113 4113 46667



Benzene 00071-43-2 069 2652 18416


Cyclohexane 00110-82-7 114 2309 26264


3-Methylpentane 00096-14-0 169 1806 30534

n-Octane 00111-65-9 080 1490 11863

2-Methyl-2-butene 00513-35-9 1420 1455 206582

t-2-Pentene 00646-04-8 1047 1430 149744



2-Methylhexane 00591-76-4 109 1276 13844


23-Dimethylbutane 00079-29-8 090 950 8542

2-Methylpropane 00075-28-5 118 905 10645



2-Methyl-1-butene 00563-46-2 638 764 48753

2-Methylheptane 00592-27-8 097 757 7321


c-2-Pentene 00627-20-3 1028 717 73741


3-Methylheptane 00589-81-1 112 591 6648


24-Dimethylhexane 00589-43-5 161 559 8975

t-2-Hexene 04050-45-7 855 500 42751



c-2-Heptene 06443-92-1 708 474 33563



Cyclopentane 00287-92-3 224 382 8551

n-Nonane 00111-84-2 068 368 2512

3-Methyl-c-2-pentene 00922-62-3 1252 366 45829





115

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methyl-t-2-pentene 00616-12-6 1166 347 40413


1-Butyne 00107-00-6 605 314 18981

c-2-Butene 00590-18-1 1426 313 44686


2-Methyl-2-pentene 00625-27-4 1103 298 32930




4-Methyloctane 02216-34-4 085 268 2273

ortho-Xylene 00095-47-6 758 263 19906



Cyclopentene 00142-29-0 669 246 16475

22-Dimethylbutane 00075-83-2 111 235 2609

Propane 00074-98-6 046 234 1071

3-Methyloctane 02216-33-3 088 226 1997

Ethylbenzene 00100-41-4 296 225 6680



n-Propylbenzene 00103-65-1 196 212 4148



33-Dimethylhexane 00563-16-6 115 179 2055





Unknown 8 246 139 3407



continued


116

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



1-Octene 00111-66-0 314 105 3295

Unknown 9 246 086 2117

Unknown 5 246 083 2051





n-Decane 00124-18-5 059 045 0268

1-Nonene 00124-11-8 249 044 1105

Unknown 1 246 032 0778

Total 13019 32482 2495


continued


117

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41 No Ethanol

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90 Repeat

Vehicle 209c


118

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 608 23884

n-Pentane 00109-66-0 121 532 6465

n-Butane 00106-97-8 108 526 5664




n-Hexane 00110-54-3 113 360 4086

Cyclohexane 00110-82-7 114 358 4074

n-Heptane 00142-82-5 097 324 3130


Benzene 00071-43-2 069 227 1573


2-Methyl-2-butene 00513-35-9 1420 214 30383



t-2-Pentene 00646-04-8 1047 199 20808

3-Methylpentane 00096-14-0 169 189 3189



23-Dimethylbutane 00079-29-8 090 134 1208

Ethanol 00064-17-5 145 131 1905


2-Methyl-1-butene 00563-46-2 638 118 7543

Propane 00074-98-6 046 116 0530

2-Methylpropane 00075-28-5 118 112 1317

c-2-Pentene 00627-20-3 1028 110 11307


2-Methylhexane 00591-76-4 109 097 1052

n-Nonane 00111-84-2 068 091 0619

c-2-Butene 00590-18-1 1426 083 11886



n-Propylbenzene 00103-65-1 196 076 1487


n-Octane 00111-65-9 080 066 0525

3-Methylheptane 00589-81-1 112 064 0714


ortho-Xylene 00095-47-6 758 062 4660

t-2-Hexene 04050-45-7 855 057 4874


2-Methyl-2-pentene 00625-27-4 1103 055 6035





119

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 053 0852

3-Methyl-c-2-pentene 00922-62-3 1252 051 6343



3-Methyl-t-2-pentene 00616-12-6 1166 046 5371

Cyclopentene 00142-29-0 669 043 2842



22-Dimethylbutane 00075-83-2 111 035 0390


4-Methyloctane 02216-34-4 085 034 0288




2-Methylheptane 00592-27-8 097 024 0234

Unknown 18 334 023 0782


Indan 00496-11-7 323 020 0636

Ethylbenzene 00100-41-4 296 019 0563

Total 1036 3549 3427


continued


120

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2428 35179


Toluene 00108-88-3 393 689 27059

Cyclohexane 00110-82-7 114 575 6535

n-Pentane 00109-66-0 121 549 6667

n-Butane 00106-97-8 108 465 5009

n-Hexane 00110-54-3 113 438 4971



22-DiMeHexane 00590-73-8 094 335 3152

n-Heptane 00142-82-5 097 311 3006


3-Methylpentane 00096-14-0 169 242 4093

Benzene 00071-43-2 069 227 1575


2-Methyl-2-butene 00513-35-9 1420 197 27914




23-Dimethylbutane 00079-29-8 090 166 1491

2-Methylpropane 00075-28-5 118 149 1756

2-Methylhexane 00591-76-4 109 147 1599

t-2-Pentene 00646-04-8 1047 146 15283




c-2-Pentene 00627-20-3 1028 097 10021

n-Octane 00111-65-9 080 097 0776

Propane 00074-98-6 046 096 0439

n-Nonane 00111-84-2 068 088 0601

2-Methyl-1-butene 00563-46-2 638 082 5199

Indan 00496-11-7 323 078 2534


3-Methylheptane 00589-81-1 112 076 0853


4-Methyloctane 02216-34-4 085 065 0551

ortho-Xylene 00095-47-6 758 065 4918

Unknown 16 271 065 1756





n-Propylbenzene 00103-65-1 196 053 1040

t-2-Hexene 04050-45-7 855 052 4414




121

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 038 0607

Cyclopentene 00142-29-0 669 038 2517


22-Dimethylbutane 00075-83-2 111 037 0408

3-Methyl-t-2-pentene 00616-12-6 1166 036 4207

Ethylbenzene 00100-41-4 296 036 1052




2-Methyl-2-pentene 00625-27-4 1103 033 3675

2-Methylheptane 00592-27-8 097 033 0322

c-2-Butene 00590-18-1 1426 031 4470

3-Methyl-c-2-pentene 00922-62-3 1252 024 3058





Total 1212 3351 2765


continued


122

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 3555 51515

Toluene 00108-88-3 393 2025 79500


3-Me-1-Hexene 03404-61-3 427 1750 74813

n-Heptane 00142-82-5 097 1537 14840



n-Pentane 00109-66-0 121 1178 14313

n-Butane 00106-97-8 108 1174 12645

n-Hexane 00110-54-3 113 1158 13138



22-DiMeHexane 00590-73-8 094 1026 9657





Benzene 00071-43-2 069 791 5491

Propane 00074-98-6 046 552 2523

3-Methylpentane 00096-14-0 169 535 9054



2-Methyl-2-butene 00513-35-9 1420 457 64841

Ethylene 00074-85-1 888 454 40295

Acetylene (Ethyne) 00074-86-2 095 452 4280

2-Methyl-1-butene 00563-46-2 638 448 28551

t-2-Pentene 00646-04-8 1047 448 46880

n-Octane 00111-65-9 080 421 3348


2-Methylpropane 00075-28-5 118 413 4861


c-2-Pentene 00627-20-3 1028 349 35872

n-Propylbenzene 00103-65-1 196 346 6786


2-Methylhexane 00591-76-4 109 331 3591

23-Dimethylbutane 00079-29-8 090 320 2879


ortho-Xylene 00095-47-6 758 312 23613

24-Dimethylhexane 00589-43-5 161 278 4460


2-Methylheptane 00592-27-8 097 265 2568

Ethylbenzene 00100-41-4 296 262 7748

t-2-Hexene 04050-45-7 855 257 21978




123

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







3-Methylheptane 00589-81-1 112 216 2430

2-Methyl-2-pentene 00625-27-4 1103 212 23431

3-Methyl-t-2-pentene 00616-12-6 1166 199 23199

n-Nonane 00111-84-2 068 189 1292

3-Methyl-c-2-pentene 00922-62-3 1252 188 23507




Cyclopentene 00142-29-0 669 120 8051

c-2-Butene 00590-18-1 1426 096 13745



22-Dimethylbutane 00075-83-2 111 085 0940

13-Butadiene 00106-99-0 1245 070 8700


Total 3712 13832 3726


continued


124

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 41433 600356


n-Butane 00106-97-8 108 4042 43529

n-Pentane 00109-66-0 121 3798 46147


Toluene 00108-88-3 393 2636 103457

n-Heptane 00142-82-5 097 2629 25385

n-Hexane 00110-54-3 113 2488 28227


Cyclohexane 00110-82-7 114 1943 22094

Benzene 00071-43-2 069 1923 13349


t-2-Pentene 00646-04-8 1047 1424 149160

2-Methyl-2-butene 00513-35-9 1420 1420 201503


3-Methylpentane 00096-14-0 169 1237 20924


2-Methylpropane 00075-28-5 118 1107 13030

2-Methyl-1-butene 00563-46-2 638 764 48704

c-2-Pentene 00627-20-3 1028 735 75531



n-Octane 00111-65-9 080 674 5365

2-Methylhexane 00591-76-4 109 654 7101



Propane 00074-98-6 046 473 2162

23-Dimethylbutane 00079-29-8 090 451 4053

t-2-Hexene 04050-45-7 855 451 38530

2-Methylheptane 00592-27-8 097 363 3510

Cyclopentane 00287-92-3 224 346 7753

3-Methyl-t-2-pentene 00616-12-6 1166 328 38296


Cyclopentene 00142-29-0 669 296 19762

3-Methylheptane 00589-81-1 112 290 3262

3-Methyl-c-2-pentene 00922-62-3 1252 283 35472

2-Methyl-2-pentene 00625-27-4 1103 279 30766



24-Dimethylhexane 00589-43-5 161 259 4160


22-Dimethylbutane 00075-83-2 111 253 2816





125

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





c-2-Butene 00590-18-1 1426 238 33979





1-Butyne 00107-00-6 605 187 11337



n-Propylbenzene 00103-65-1 196 154 3020

Ethylbenzene 00100-41-4 296 152 4489

4-Methyloctane 02216-34-4 085 149 1267


3-Methyloctane 02216-33-3 088 118 1048


33-Dimethylhexane 00563-16-6 115 113 1300


n-Nonane 00111-84-2 068 112 0762



Unknown 22 249 085 2128


1-Octene 00111-66-0 314 084 2649



Unknown 8 249 077 1927


Unknown 5 249 068 1695

Unknown 6 249 061 1521





4-Methyl-t-2-pentene 00674-76-0 804 055 4393

Unknown 1 249 054 1355

continued


126

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 9 249 048 1203



ortho-Xylene 00095-47-6 758 035 2639



1-Nonene 00124-11-8 249 031 0771

c-2-Heptene 06443-92-1 708 030 2119


Total 9741 24571 2522


continued


127

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2031 29422



Toluene 00108-88-3 393 213 8360

n-Heptane 00142-82-5 097 164 1581

22-DiMeHexane 00590-73-8 094 162 1525




n-Butane 00106-97-8 108 113 1221


Benzene 00071-43-2 069 090 0625

n-Octane 00111-65-9 080 087 0696


n-Pentane 00109-66-0 121 083 1008

Cyclohexane 00110-82-7 114 078 0887


n-Nonane 00111-84-2 068 068 0466




n-Hexane 00110-54-3 113 061 0693

n-Propylbenzene 00103-65-1 196 060 1176

4-Methyloctane 02216-34-4 085 059 0501


2-Methyl-1-butene 00563-46-2 638 056 3568


t-2-Pentene 00646-04-8 1047 051 5304

3-Methyl-c-2-pentene 00922-62-3 1252 048 6030


ortho-Xylene 00095-47-6 758 044 3371


n-Decane 00124-18-5 059 042 0246

1-Butyne 00107-00-6 605 038 2301


2-Methyl-2-butene 00513-35-9 1420 035 4931

23-Dimethylbutane 00079-29-8 090 031 0274



c-2-Pentene 00627-20-3 1028 026 2664

t-2-Hexene 04050-45-7 855 026 2206

2-Methylhexane 00591-76-4 109 026 0279

Ethylbenzene 00100-41-4 296 024 0713




128

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-t-2-pentene 00616-12-6 1166 021 2407

2-Methylheptane 00592-27-8 097 020 0198

3-Methylpentane 00096-14-0 169 020 0337


Cyclopentene 00142-29-0 669 016 1071


3-Methylheptane 00589-81-1 112 010 0108



n-Undecane 01120-21-4 052 003 0017

Total 554 1818 3284


continued


129

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2491 36089


Toluene 00108-88-3 393 351 13795


n-Heptane 00142-82-5 097 246 2378




n-Pentane 00109-66-0 121 181 2205

n-Butane 00106-97-8 108 173 1860

Benzene 00071-43-2 069 159 1107


n-Hexane 00110-54-3 113 128 1449

Propane 00074-98-6 046 123 0563



Cyclohexane 00110-82-7 114 117 1330



3-Methylheptane 00589-81-1 112 081 0911

n-Octane 00111-65-9 080 076 0603

3-Methylpentane 00096-14-0 169 075 1266


t-2-Pentene 00646-04-8 1047 069 7273


n-Propylbenzene 00103-65-1 196 066 1300

2-Methyl-2-pentene 00625-27-4 1103 066 7278


2-Methyl-2-butene 00513-35-9 1420 058 8241

23-Dimethylbutane 00079-29-8 090 056 0505

Ethylbenzene 00100-41-4 296 053 1576

c-2-Heptene 06443-92-1 708 053 3746

4-Methyloctane 02216-34-4 085 053 0449



Unknown 22 299 050 1489


2-Methyl-1-butene 00563-46-2 638 046 2905

2-Methylheptane 00592-27-8 097 045 0434

n-Nonane 00111-84-2 068 044 0300


24-Dimethylhexane 00589-43-5 161 042 0669

2-Methylhexane 00591-76-4 109 039 0424




130

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 039 3979

t-2-Hexene 04050-45-7 855 038 3270


3-Methyl-t-2-pentene 00616-12-6 1166 036 4201

ortho-Xylene 00095-47-6 758 034 2597

c-2-Butene 00590-18-1 1426 034 4788



3-Methyl-c-2-pentene 00922-62-3 1252 030 3747




Cyclopentene 00142-29-0 669 022 1479




22-Dimethylbutane 00075-83-2 111 012 0136

066 Total 786 2397 3050


continued


131

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-DiMeHexane 00590-73-8 094 551 5189

Cyclohexane 00110-82-7 114 550 6259

n-Heptane 00142-82-5 097 503 4856




n-Nonane 00111-84-2 068 399 2724

Ethylene 00074-85-1 888 383 33991


n-Octane 00111-65-9 080 331 2635



Benzene 00071-43-2 069 241 1673

Unknown 22 492 232 11393



3-Methyl-t-2-pentene 00616-12-6 1166 194 22609


Cyclopentene 00142-29-0 669 153 10213




3-Methyl-c-2-pentene 00922-62-3 1252 115 14432

n-Propylbenzene 00103-65-1 196 114 2239

2-Methylheptane 00592-27-8 097 110 1067



Toluene 00108-88-3 393 089 3513

Naphthalene 00091-20-3 328 087 2863

t-2-Hexene 04050-45-7 855 084 7168


3-Methylpentane 00096-14-0 169 070 1179

ortho-Xylene 00095-47-6 758 052 3918


2-Methylhexane 00591-76-4 109 032 0348

Ethylbenzene 00100-41-4 296 018 0548


2-Methyl-2-butene 00513-35-9 1420 005 0770

Total 1074 5493 5117





132

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35670 516847



n-Heptane 00142-82-5 097 3662 35368

n-Butane 00106-97-8 108 3505 37747

Toluene 00108-88-3 393 3492 137050

n-Pentane 00109-66-0 121 3304 40146


n-Hexane 00110-54-3 113 2599 29485



Cyclohexane 00110-82-7 114 1925 21900


Benzene 00071-43-2 069 1738 12068



n-Octane 00111-65-9 080 1569 12491


2-Methylpropane 00075-28-5 118 1256 14781

3-Methylpentane 00096-14-0 169 1206 20398

2-Methyl-2-butene 00513-35-9 1420 1074 152444

23-Dimethylbutane 00079-29-8 090 1069 9609

t-2-Pentene 00646-04-8 1047 1043 109271


2-Methylhexane 00591-76-4 109 864 9372



2-Methylheptane 00592-27-8 097 787 7608


Propane 00074-98-6 046 757 3460

3-Methylheptane 00589-81-1 112 717 8059



n-Nonane 00111-84-2 068 656 4479



c-2-Pentene 00627-20-3 1028 547 56249

24-Dimethylhexane 00589-43-5 161 521 8366

2-Methyl-1-butene 00563-46-2 638 520 33173

4-Methyloctane 02216-34-4 085 502 4255

n-Propylbenzene 00103-65-1 196 453 8879

ortho-Xylene 00095-47-6 758 450 34122

c-2-Heptene 06443-92-1 708 445 31484





133

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






3-Methyloctane 02216-33-3 088 360 3186

t-2-Hexene 04050-45-7 855 339 28984

Ethylbenzene 00100-41-4 296 338 10013

22-Dimethylbutane 00075-83-2 111 326 3618



3-Methyl-t-2-pentene 00616-12-6 1166 269 31374




2-Methyl-2-pentene 00625-27-4 1103 258 28420

Unknown 8 252 242 6098

3-Methyl-c-2-pentene 00922-62-3 1252 236 29551


c-2-Butene 00590-18-1 1426 227 32333


Cyclopentene 00142-29-0 669 218 14591

1-Nonene 00124-11-8 249 212 5282

Unknown 16 252 209 5253



Unknown 9 252 172 4332

1-Octene 00111-66-0 314 161 5055


33-Dimethylhexane 00563-16-6 115 156 1793


n-Decane 00124-18-5 059 141 0832

continued


134

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Indan 00496-11-7 323 126 4071




Unknown 5 252 108 2722

t-4-Octene 14850-23-8 469 092 4292



Unknown 10 252 074 1873




22-Dimethyloctane 15869-87-1 076 049 0367

n-Undecane 01120-21-4 052 044 0229

c-2-Octene 07642-04-8 252 024 0605

Total 11102 28561 2573


continued


135

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 39128 566956



n-Heptane 00142-82-5 097 4118 39773

Toluene 00108-88-3 393 4052 159045

n-Butane 00106-97-8 108 3621 38994

n-Pentane 00109-66-0 121 3567 43335

n-Hexane 00110-54-3 113 3196 36265



Cyclohexane 00110-82-7 114 2313 26313


Benzene 00071-43-2 069 2021 14034


n-Octane 00111-65-9 080 1766 14063



3-Methylpentane 00096-14-0 169 1600 27048



23-Dimethylbutane 00079-29-8 090 1186 10659

2-Methylhexane 00591-76-4 109 1076 11672

2-Methyl-2-butene 00513-35-9 1420 1032 146518

t-2-Pentene 00646-04-8 1047 991 103774



Propane 00074-98-6 046 919 4201

2-Methylpropane 00075-28-5 118 876 10302



2-Methylheptane 00592-27-8 097 759 7340

3-Methylheptane 00589-81-1 112 683 7684

n-Nonane 00111-84-2 068 677 4621



24-Dimethylhexane 00589-43-5 161 607 9741


2-Methyl-1-butene 00563-46-2 638 575 36672


4-Methyloctane 02216-34-4 085 547 4637


c-2-Pentene 00627-20-3 1028 523 53797


Vehicle 209c - Fuel 7 psi E20 - 3 Day Diurnal Repeat - Test 7881



136

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Heptene 06443-92-1 708 419 29626

3-Methyl-c-2-pentene 00922-62-3 1252 379 47426

ortho-Xylene 00095-47-6 758 368 27850



n-Propylbenzene 00103-65-1 196 350 6856

3-Methyloctane 02216-33-3 088 339 3003


t-2-Hexene 04050-45-7 855 329 28138


c-2-Butene 00590-18-1 1426 290 41290

n-Decane 00124-18-5 059 284 1680


Ethylbenzene 00100-41-4 296 279 8257


2-Methyl-2-pentene 00625-27-4 1103 272 29956

3-Methyl-t-2-pentene 00616-12-6 1166 264 30830

Unknown 16 247 252 6216


Unknown 8 247 236 5829


Cyclopentene 00142-29-0 669 225 15030






1-Nonene 00124-11-8 249 194 4832

22-Dimethylbutane 00075-83-2 111 192 2134


1-Octene 00111-66-0 314 162 5092

continued


137

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






Unknown 9 247 147 3619

t-4-Octene 14850-23-8 469 146 6841

33-Dimethylhexane 00563-16-6 115 146 1676


Unknown 5 247 140 3451


Indan 00496-11-7 323 086 2776

n-Undecane 01120-21-4 052 081 0423



22-Dimethyloctane 15869-87-1 076 048 0361

Unknown 1 247 043 1059


Total 12111 30488 2517


continued


138

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


139

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 213 8377

n-Pentane 00109-66-0 121 209 2533

n-Butane 00106-97-8 108 195 2100


n-Heptane 00142-82-5 097 146 1407



2-Methylpropane 00075-28-5 118 119 1401

n-Hexane 00110-54-3 113 119 1345

Cyclohexane 00110-82-7 114 115 1310

Benzene 00071-43-2 069 108 0747

Unknown 23 313 105 3279


t-2-Pentene 00646-04-8 1047 103 10759

n-Octane 00111-65-9 080 096 0765

3-Methylheptane 00589-81-1 112 093 1050

2-Methyl-2-butene 00513-35-9 1420 088 12443



3-Methylpentane 00096-14-0 169 081 1375


4-Methyloctane 02216-34-4 085 074 0632




c-2-Pentene 00627-20-3 1028 060 6196



t-2-Hexene 04050-45-7 855 055 4697

2-Methylhexane 00591-76-4 109 052 0565

2-Methyl-1-butene 00563-46-2 638 045 2839

2-Methylheptane 00592-27-8 097 043 0418




n-Nonane 00111-84-2 068 036 0249

n-Decane 00124-18-5 059 036 0213

n-Propylbenzene 00103-65-1 196 034 0658


3-Methyl-t-2-pentene 00616-12-6 1166 032 3705

22-Dimethyloctane 15869-87-1 076 030 0227






140

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Ethylbenzene 00100-41-4 296 027 0810

2-Methyl-2-pentene 00625-27-4 1103 026 2921

t-4-Octene 14850-23-8 469 026 1220

23-Dimethylbutane 00079-29-8 090 026 0231

14-Diisopropylbenzene 00100-18-5 313 026 0803

ortho-Xylene 00095-47-6 758 025 1927

4-Methyl-t-2-pentene 00674-76-0 804 025 2022

c-2-Heptene 06443-92-1 708 025 1752

3-Methyl-c-2-pentene 00922-62-3 1252 023 2817


1-Butyne 00107-00-6 605 022 1304




1235-Tetramethylbenzene 00527-53-7 926 018 1632


Cyclopentene 00142-29-0 669 016 1068


Unknown 20 313 013 0398


22-Dimethylbutane 00075-83-2 111 010 0109



24-Dimethylhexane 00589-43-5 161 009 0138

Unknown 14 313 008 0265

Total 499 1646 3297


continued


141

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1583 22942


Toluene 00108-88-3 393 612 24017

n-Pentane 00109-66-0 121 486 5903

n-Butane 00106-97-8 108 481 5181

n-Heptane 00142-82-5 097 334 3229





n-Hexane 00110-54-3 113 272 3083

Benzene 00071-43-2 069 268 1861

Cyclohexane 00110-82-7 114 242 2757


2-Methylheptane 00592-27-8 097 200 1932



t-2-Pentene 00646-04-8 1047 171 17927

2-Methylpropane 00075-28-5 118 169 1990

2-Methyl-2-butene 00513-35-9 1420 166 23544

3-Methylpentane 00096-14-0 169 154 2608


c-2-Pentene 00627-20-3 1028 139 14324

2-Methyl-1-butene 00563-46-2 638 135 8633





3-Methyl-c-2-pentene 00922-62-3 1252 096 11960


23-Dimethylbutane 00079-29-8 090 094 0843

3-Methylheptane 00589-81-1 112 090 1017

t-2-Hexene 04050-45-7 855 083 7126


Ethylbenzene 00100-41-4 296 078 2298

n-Octane 00111-65-9 080 076 0607

ortho-Xylene 00095-47-6 758 076 5752


2-Methylhexane 00591-76-4 109 069 0746

2-Methyl-2-pentene 00625-27-4 1103 069 7570

n-Nonane 00111-84-2 068 068 0463

3-Methyl-t-2-pentene 00616-12-6 1166 066 7701






142

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 057 0908

c-2-Butene 00590-18-1 1426 056 7952


n-Propylbenzene 00103-65-1 196 047 0917

Cyclopentene 00142-29-0 669 044 2973




22-Dimethylbutane 00075-83-2 111 035 0385




Total 1098 3753 3417


continued


143

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Cyclohexane 00110-82-7 114 830 9437


Toluene 00108-88-3 393 735 28842

n-Pentane 00109-66-0 121 635 7720

n-Butane 00106-97-8 108 605 6519


n-Heptane 00142-82-5 097 582 5618

Benzene 00071-43-2 069 579 4019







3-Methylpentane 00096-14-0 169 400 6755

n-Propylbenzene 00103-65-1 196 372 7293

2-Methylhexane 00591-76-4 109 361 3923

n-Octane 00111-65-9 080 359 2859

Unknown 22 382 315 12033

n-Hexane 00110-54-3 113 299 3392


t-2-Butene 00624-64-6 1520 280 42605

4-Methyl-t-2-pentene 00674-76-0 804 264 21197

n-Decane 00124-18-5 059 241 1427



Cyclopentene 00142-29-0 669 218 14592



Propane 00074-98-6 046 193 0881

ortho-Xylene 00095-47-6 758 177 13425

24-Dimethylhexane 00589-43-5 161 168 2703



Ethylbenzene 00100-41-4 296 162 4786

2-Methyl-2-butene 00513-35-9 1420 160 22779


4-Methyloctane 02216-34-4 085 145 1233


t-2-Hexene 04050-45-7 855 134 11491





144

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylbutane 00079-29-8 090 132 1189

2-Methyl-2-pentene 00625-27-4 1103 129 14259



n-Nonane 00111-84-2 068 120 0820

22-Dimethylbutane 00075-83-2 111 115 1278

2-Methylheptane 00592-27-8 097 114 1105

3-Methylheptane 00589-81-1 112 109 1224

3-Methyl-t-2-pentene 00616-12-6 1166 096 11152




2-Methyl-1-butene 00563-46-2 638 080 5118

3-Methyl-c-2-pentene 00922-62-3 1252 080 10031

Unknown 18 382 072 2733

t-2-Pentene 00646-04-8 1047 056 5882



c-2-Butene 00590-18-1 1426 019 2640

Total 2130 8389 3939


continued


145

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 31696 459267


n-Pentane 00109-66-0 121 5202 63200

n-Butane 00106-97-8 108 4742 51062


Toluene 00108-88-3 393 3938 154553

n-Heptane 00142-82-5 097 3796 36662

n-Hexane 00110-54-3 113 3616 41031


Benzene 00071-43-2 069 2716 18860


Cyclohexane 00110-82-7 114 2178 24768

2-Methyl-2-butene 00513-35-9 1420 2023 287182

t-2-Pentene 00646-04-8 1047 1945 203758


3-Methylpentane 00096-14-0 169 1693 28633





c-2-Pentene 00627-20-3 1028 991 101902

2-Methyl-1-butene 00563-46-2 638 937 59771


n-Octane 00111-65-9 080 891 7098

2-Methylhexane 00591-76-4 109 887 9631


2-Methylpropane 00075-28-5 118 786 9244

t-2-Hexene 04050-45-7 855 635 54264

23-Dimethylbutane 00079-29-8 090 601 5401

c-2-Butene 00590-18-1 1426 546 77832

Cyclopentane 00287-92-3 224 476 10644

3-Methyl-t-2-pentene 00616-12-6 1166 457 53303


2-Methylheptane 00592-27-8 097 412 3986


Cyclopentene 00142-29-0 669 406 27162

3-Methyl-c-2-pentene 00922-62-3 1252 381 47688

2-Methyl-2-pentene 00625-27-4 1103 378 41721




3-Methylheptane 00589-81-1 112 341 3833






146

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 277 4444



22-Dimethylbutane 00075-83-2 111 254 2820

n-Nonane 00111-84-2 068 246 1676

ortho-Xylene 00095-47-6 758 241 18230



Ethylbenzene 00100-41-4 296 181 5360


Propane 00074-98-6 046 169 0774

n-Propylbenzene 00103-65-1 196 168 3302




4-Methyloctane 02216-34-4 085 137 1163





Indan 00496-11-7 323 120 3878


3-Methyloctane 02216-33-3 088 112 0989

14-Diethylbenzene 00105-05-5 439 098 4322

33-Dimethylhexane 00563-16-6 115 095 1092


n-Undecane 01120-21-4 052 093 0483

11-Dimethylcyclohexane 00590-66-9 112 087 0974

Unknown 9 289 085 2456

Unknown 22 289 085 2454

Unknown 8 289 083 2389

Unknown 16 289 081 2340






t-4-Octene 14850-23-8 469 062 2903

n-Decane 00124-18-5 059 061 0363

continued


147

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 5 289 057 1654

Unknown 1 289 057 1645

c-2-Heptene 06443-92-1 708 056 3942


4-Methyl-t-2-pentene 00674-76-0 804 048 3873


1-Heptene 00592-76-7 429 040 1703

t-3-Heptene 14686-14-7 617 035 2178



1-Nonene 00124-11-8 249 033 0811


c- amp t-4-Nonene 02198-23-4 442 029 1282






13-Butadiene 00106-99-0 1245 014 1729

t-2-Octene amp t-12-DiMeCyHexane 13389-42-9+06876-23-9 592 008 0480

Total 10698 31327 2928


continued


148

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Toluene 00108-88-3 393 129 5070


n-Butane 00106-97-8 108 114 1229

n-Heptane 00142-82-5 097 106 1019


Benzene 00071-43-2 069 094 0655



c-2-Butene 00590-18-1 1426 072 10220



2-Methyl-1-butene 00563-46-2 638 057 3627



n-Pentane 00109-66-0 121 054 0651



Cyclohexane 00110-82-7 114 049 0558

n-Hexane 00110-54-3 113 040 0449


n-Octane 00111-65-9 080 037 0294


3-Methylpentane 00096-14-0 169 032 0549

n-Propylbenzene 00103-65-1 196 030 0591

3-Methylheptane 00589-81-1 112 028 0314

t-2-Hexene 04050-45-7 855 028 2367


2-Methylheptane 00592-27-8 097 025 0246

n-Nonane 00111-84-2 068 023 0160


2-Methylhexane 00591-76-4 109 022 0243

3-Methyl-t-2-pentene 00616-12-6 1166 021 2489

Cyclopentene 00142-29-0 669 018 1231





149

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 016 0260


2-Methyl-2-butene 00513-35-9 1420 015 2102

23-Dimethylbutane 00079-29-8 090 015 0133


ortho-Xylene 00095-47-6 758 012 0934


Ethylbenzene 00100-41-4 296 011 0325

t-2-Pentene 00646-04-8 1047 008 0869



Total 259 1087 4196


continued


150

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2384 34537


Toluene 00108-88-3 393 399 15668

n-Pentane 00109-66-0 121 371 4510




n-Heptane 00142-82-5 097 309 2980

n-Butane 00106-97-8 108 299 3222

n-Hexane 00110-54-3 113 246 2791

Benzene 00071-43-2 069 233 1614




t-2-Pentene 00646-04-8 1047 148 15551

Cyclohexane 00110-82-7 114 146 1657





2-Methyl-2-butene 00513-35-9 1420 115 16375

c-2-Pentene 00627-20-3 1028 113 11626




3-Methylpentane 00096-14-0 169 103 1742

n-Octane 00111-65-9 080 100 0796

2-Methyl-1-butene 00563-46-2 638 083 5318


t-2-Hexene 04050-45-7 855 062 5278

3-Methyl-c-2-pentene 00922-62-3 1252 061 7658


3-Methylheptane 00589-81-1 112 054 0611



2-Methylhexane 00591-76-4 109 051 0548

ortho-Xylene 00095-47-6 758 048 3648

Ethylbenzene 00100-41-4 296 047 1400

n-Propylbenzene 00103-65-1 196 047 0921


24-Dimethylhexane 00589-43-5 161 042 0671

3-Methyl-t-2-pentene 00616-12-6 1166 041 4734






151

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 039 4295

Cyclopentane 00287-92-3 224 038 0856

22-Dimethylbutane 00075-83-2 111 033 0370





n-Nonane 00111-84-2 068 023 0155

23-Dimethylbutane 00079-29-8 090 022 0200

Cyclopentene 00142-29-0 669 018 1224


Unknown 22 324 013 0423

2-Methylheptane 00592-27-8 097 012 0113

Total 951 3138 3302


continued


152

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4516 65430





Toluene 00108-88-3 393 507 19903

Unknown 22 333 400 13307

n-Butane 00106-97-8 108 381 4104


n-Heptane 00142-82-5 097 294 2844

Propane 00074-98-6 046 278 1272

Benzene 00071-43-2 069 271 1880

2-Methylheptane 00592-27-8 097 242 2337

n-Pentane 00109-66-0 121 233 2835

n-Hexane 00110-54-3 113 226 2566


c-2-Butene 00590-18-1 1426 199 28382



n-Nonane 00111-84-2 068 171 1171




c-2-Pentene 00627-20-3 1028 111 11423




n-Octane 00111-65-9 080 085 0679

Cyclohexane 00110-82-7 114 081 0923

2-Methyl-2-butene 00513-35-9 1420 081 11500

2-Methyl-1-butene 00563-46-2 638 081 5168




2-Methyl-2-pentene 00625-27-4 1103 068 7461

3-Methylheptane 00589-81-1 112 064 0719




153

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



t-2-Pentene 00646-04-8 1047 062 6546


ortho-Xylene 00095-47-6 758 053 4033


3-Methyl-c-2-pentene 00922-62-3 1252 047 5926

Ethylbenzene 00100-41-4 296 043 1269

2-Methylpropane 00075-28-5 118 038 0446


Cyclopentene 00142-29-0 669 022 1503

t-2-Hexene 04050-45-7 855 014 1156

3-Methyl-t-2-pentene 00616-12-6 1166 011 1314


23-Dimethylbutane 00079-29-8 090 005 0041

Total 1362 4730 3473


continued


154

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


155

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 914 13240



n-Heptane 00142-82-5 097 320 3090




n-Octane 00111-65-9 080 190 1516




2-Methylheptane 00592-27-8 097 148 1433


2-Methylpropane 00075-28-5 118 118 1392

Toluene 00108-88-3 393 103 4047

n-Nonane 00111-84-2 068 099 0674



3-Methylheptane 00589-81-1 112 072 0810

Benzene 00071-43-2 069 072 0497



Ethylbenzene 00100-41-4 296 054 1611

n-Propylbenzene 00103-65-1 196 051 0994

Indan 00496-11-7 323 046 1487

Unknown 8 380 044 1655

4-Methyloctane 02216-34-4 085 031 0266


ortho-Xylene 00095-47-6 758 025 1916

2-Methylhexane 00591-76-4 109 025 0270

3-Methyloctane 02216-33-3 088 022 0195

t-2-Hexene 04050-45-7 855 022 1856

n-Decane 00124-18-5 059 020 0120



24-Dimethylhexane 00589-43-5 161 010 0159


Unknown 18 380 008 0320


Total 504 1959 3887





156

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5350 77523



Toluene 00108-88-3 393 710 27869


n-Heptane 00142-82-5 097 557 5384

n-Pentane 00109-66-0 121 507 6163




n-Butane 00106-97-8 108 412 4441

Benzene 00071-43-2 069 397 2757

n-Hexane 00110-54-3 113 324 3679






n-Octane 00111-65-9 080 190 1517

2-Methyl-2-butene 00513-35-9 1420 185 26255

Cyclohexane 00110-82-7 114 177 2018

2-Methylpropane 00075-28-5 118 161 1890

t-2-Pentene 00646-04-8 1047 157 16410

3-Methylpentane 00096-14-0 169 153 2584

n-Propylbenzene 00103-65-1 196 130 2552


n-Nonane 00111-84-2 068 105 0717


2-Methylhexane 00591-76-4 109 098 1068

Propane 00074-98-6 046 095 0435

ortho-Xylene 00095-47-6 758 095 7180

2-Methyl-1-butene 00563-46-2 638 091 5809

c-2-Pentene 00627-20-3 1028 087 8898

3-Methyloctane 02216-33-3 088 083 0732


2-Methylheptane 00592-27-8 097 082 0789

4-Methyloctane 02216-34-4 085 082 0692

Cyclopentene 00142-29-0 669 079 5254

Cyclopentane 00287-92-3 224 074 1658

Ethylbenzene 00100-41-4 296 071 2105

n-Decane 00124-18-5 059 065 0381

3-Methylheptane 00589-81-1 112 063 0710

3-Methyl-t-2-pentene 00616-12-6 1166 063 7322

24-Dimethylhexane 00589-43-5 161 062 1002




157

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 061 7585




22-Dimethylbutane 00075-83-2 111 057 0637

t-2-Hexene 04050-45-7 855 056 4804


2-Methyl-2-pentene 00625-27-4 1103 054 5956





Unknown 18 309 046 1407

c-2-Butene 00590-18-1 1426 041 5887






23-Dimethylbutane 00079-29-8 090 023 0203

Total 1716 5398 3145


continued


158

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 1415 20503




n-Heptane 00142-82-5 097 457 4411

n-Nonane 00111-84-2 068 418 2857

n-Octane 00111-65-9 080 391 3117

n-Propylbenzene 00103-65-1 196 390 7648





Unknown 22 429 241 10343



Toluene 00108-88-3 393 138 5398


Ethylbenzene 00100-41-4 296 107 3162

Benzene 00071-43-2 069 106 0733

ortho-Xylene 00095-47-6 758 086 6504

2-Methylhexane 00591-76-4 109 053 0572


Total 1016 4464 4392





159

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 80088 1160459


n-Pentane 00109-66-0 121 4822 58590

n-Heptane 00142-82-5 097 4735 45729

n-Butane 00106-97-8 108 4415 47543


Toluene 00108-88-3 393 3850 151113


n-Hexane 00110-54-3 113 3408 38671


Benzene 00071-43-2 069 3032 21056


2-Methyl-2-butene 00513-35-9 1420 1879 266753


t-2-Pentene 00646-04-8 1047 1856 194423

Cyclohexane 00110-82-7 114 1803 20503

3-Methylpentane 00096-14-0 169 1710 28914

n-Octane 00111-65-9 080 1552 12360




2-Methylhexane 00591-76-4 109 1117 12118


2-Methyl-1-butene 00563-46-2 638 911 58131

c-2-Pentene 00627-20-3 1028 907 93216

2-Methylpropane 00075-28-5 118 779 9171

2-Methylheptane 00592-27-8 097 709 6862

1-Butyne 00107-00-6 605 663 40082


3-Methylheptane 00589-81-1 112 644 7246

t-2-Hexene 04050-45-7 855 637 54462



23-Dimethylbutane 00079-29-8 090 550 4945

3-Methyl-c-2-pentene 00922-62-3 1252 539 67459


n-Nonane 00111-84-2 068 474 3235

Cyclopentane 00287-92-3 224 459 10278




3-Methyl-t-2-pentene 00616-12-6 1166 406 47372

2-Methyl-2-pentene 00625-27-4 1103 376 41453

Cyclopentene 00142-29-0 669 370 24726




160

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




ortho-Xylene 00095-47-6 758 354 26855

4-Methyloctane 02216-34-4 085 354 3006

c-2-Butene 00590-18-1 1426 344 49033



Ethylbenzene 00100-41-4 296 301 8929

n-Propylbenzene 00103-65-1 196 301 5890

3-Methyloctane 02216-33-3 088 295 2606

22-Dimethylbutane 00075-83-2 111 289 3213

24-Dimethylhexane 00589-43-5 161 285 4569




Propane 00074-98-6 046 234 1071







Unknown 8 239 166 3975

Unknown 9 239 161 3846





33-Dimethylhexane 00563-16-6 115 127 1462




continued


161

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Decane 00124-18-5 059 097 0572



c- amp t-4-Nonene 02198-23-4 442 081 3581

c-2-Heptene 06443-92-1 708 079 5569

Unknown 1 239 075 1804

t-4-Octene 14850-23-8 469 075 3530



Unknown 18 239 065 1559

Unknown 5 239 060 1448

Unknown 14 239 055 1326


1-Nonene 00124-11-8 249 048 1191



Indan 00496-11-7 323 034 1102

Total 16190 39290 2427


continued


162

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1993 28873


Toluene 00108-88-3 393 213 8354



n-Butane 00106-97-8 108 130 1400

n-Pentane 00109-66-0 121 129 1569

n-Heptane 00142-82-5 097 123 1191


n-Hexane 00110-54-3 113 116 1316


t-2-Butene 00624-64-6 1520 098 14909



Benzene 00071-43-2 069 089 0619

3-Methylheptane 00589-81-1 112 080 0904

t-2-Pentene 00646-04-8 1047 078 8210



3-Methylpentane 00096-14-0 169 056 0952



Unknown 18 282 048 1351

4-Methyloctane 02216-34-4 085 047 0400


2-Methyl-2-butene 00513-35-9 1420 046 6499

2-Methylhexane 00591-76-4 109 043 0468

c-2-Pentene 00627-20-3 1028 042 4351

t-2-Hexene 04050-45-7 855 041 3497

Cyclohexane 00110-82-7 114 036 0412


c-2-Heptene 06443-92-1 708 035 2475

2-Methyl-1-butene 00563-46-2 638 035 2212

n-Octane 00111-65-9 080 033 0264

23-Dimethylbutane 00079-29-8 090 032 0284





3-Methyl-t-2-pentene 00616-12-6 1166 023 2658


n-Nonane 00111-84-2 068 022 0148

3-Methyl-c-2-pentene 00922-62-3 1252 019 2434





163

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentene 00142-29-0 669 014 0946



n-Propylbenzene 00103-65-1 196 008 0160

24-Dimethylhexane 00589-43-5 161 003 0043

Total 513 1471 2864


continued


164

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4419 64033



Toluene 00108-88-3 393 327 12821

n-Heptane 00142-82-5 097 317 3058

n-Pentane 00109-66-0 121 298 3615

n-Butane 00106-97-8 108 292 3145



n-Hexane 00110-54-3 113 202 2297



Benzene 00071-43-2 069 176 1224



3-Methylpentane 00096-14-0 169 128 2170

Cyclohexane 00110-82-7 114 121 1373

t-2-Pentene 00646-04-8 1047 108 11335

n-Octane 00111-65-9 080 104 0832

23-Dimethylbutane 00079-29-8 090 093 0839

2-Methyl-2-butene 00513-35-9 1420 088 12506


c-2-Pentene 00627-20-3 1028 065 6705

2-Methylheptane 00592-27-8 097 065 0628



2-Methyl-1-butene 00563-46-2 638 060 3850

ortho-Xylene 00095-47-6 758 058 4432

2-Methylhexane 00591-76-4 109 053 0572

3-Methylheptane 00589-81-1 112 044 0500




2-Methyl-2-pentene 00625-27-4 1103 041 4512

Cyclopentene 00142-29-0 669 040 2703

n-Nonane 00111-84-2 068 040 0272


n-Propylbenzene 00103-65-1 196 034 0666



c-2-Heptene 06443-92-1 708 032 2242

c-2-Butene 00590-18-1 1426 030 4304

3-Methyl-t-2-pentene 00616-12-6 1166 027 3205





165

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Ethylbenzene 00100-41-4 296 024 0701

24-Dimethylhexane 00589-43-5 161 020 0324

t-2-Hexene 04050-45-7 855 019 1605



22-Dimethylbutane 00075-83-2 111 016 0174


3-Methyl-c-2-pentene 00922-62-3 1252 010 1259


Total 1033 2530 2449


continued


166

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5963 86398




Toluene 00108-88-3 393 571 22420



n-Pentane 00109-66-0 121 455 5531


Propane 00074-98-6 046 324 1482





Benzene 00071-43-2 069 254 1767


n-Heptane 00142-82-5 097 246 2379


t-2-Pentene 00646-04-8 1047 211 22048


c-2-Butene 00590-18-1 1426 195 27782

Ethylbenzene 00100-41-4 296 168 4985

2-Methyl-1-butene 00563-46-2 638 165 10501

n-Hexane 00110-54-3 113 163 1848

ortho-Xylene 00095-47-6 758 152 11495

Cyclohexane 00110-82-7 114 136 1543

c-2-Pentene 00627-20-3 1028 132 13597


2-Methyl-2-butene 00513-35-9 1420 130 18389

n-Octane 00111-65-9 080 129 1027


3-Methylheptane 00589-81-1 112 115 1296

22-Dimethylbutane 00075-83-2 111 113 1259

n-Butane 00106-97-8 108 111 1191


3-Methylpentane 00096-14-0 169 099 1670


3-Methyl-t-2-pentene 00616-12-6 1166 097 11253

n-Nonane 00111-84-2 068 093 0635


23-Dimethylbutane 00079-29-8 090 091 0816

2-Methylheptane 00592-27-8 097 091 0876

Styrene 00100-42-5 166 085 1415

n-Propylbenzene 00103-65-1 196 085 1659




167

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 068 1091


c-2-Heptene 06443-92-1 708 067 4724

Cyclopentene 00142-29-0 669 058 3856




t-2-Hexene 04050-45-7 855 047 4014

3-Methyl-c-2-pentene 00922-62-3 1252 042 5224



2-Methylhexane 00591-76-4 109 024 0260

Total 1768 6143 3474


continued


168

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 55723 807411



n-Heptane 00142-82-5 097 5981 57761

n-Pentane 00109-66-0 121 4502 54693

n-Butane 00106-97-8 108 3984 42902

n-Hexane 00110-54-3 113 3782 42912


Toluene 00108-88-3 393 3760 147573


Benzene 00071-43-2 069 2573 17862


Cyclohexane 00110-82-7 114 2121 24121




3-Methylpentane 00096-14-0 169 1746 29526

2-Methylhexane 00591-76-4 109 1523 16530

n-Octane 00111-65-9 080 1370 10905

2-Methyl-2-butene 00513-35-9 1420 1332 189048

t-2-Pentene 00646-04-8 1047 1291 135259


23-Dimethylbutane 00079-29-8 090 914 8215


2-Methyl-1-butene 00563-46-2 638 724 46184



c-2-Pentene 00627-20-3 1028 654 67284


1-Butyne 00107-00-6 605 626 37845

2-Methylheptane 00592-27-8 097 598 5783



3-Methylheptane 00589-81-1 112 575 6461

24-Dimethylhexane 00589-43-5 161 569 9133

3-Methyl-c-2-pentene 00922-62-3 1252 520 65089



t-2-Hexene 04050-45-7 855 463 39550

c-2-Heptene 06443-92-1 708 449 31804

n-Decane 00124-18-5 059 419 2479


Cyclopentane 00287-92-3 224 395 8835





169

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




c-2-Butene 00590-18-1 1426 336 47937

3-Methyl-t-2-pentene 00616-12-6 1166 335 39014



2-Methyl-2-pentene 00625-27-4 1103 298 32843


4-Methyloctane 02216-34-4 085 282 2390

n-Nonane 00111-84-2 068 276 1883

Cyclopentene 00142-29-0 669 274 18349


22-Dimethylbutane 00075-83-2 111 262 2916





3-Methyloctane 02216-33-3 088 227 2006

33-Dimethylhexane 00563-16-6 115 217 2497





ortho-Xylene 00095-47-6 758 185 13998

Ethylbenzene 00100-41-4 296 181 5358


n-Propylbenzene 00103-65-1 196 147 2880




Unknown 8 231 112 2592


Unknown 16 231 111 2561

Unknown 5 231 101 2336


c- amp t-4-Nonene 02198-23-4 442 096 4265


Unknown 9 231 085 1963


Unknown 1 231 036 0824


Total 14128 33504 2371


continued


170

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


171

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 8324 89644

2-Methylpropane 00075-28-5 118 7588 89275

Ethanol 00064-17-5 145 5174 74976

n-Pentane 00109-66-0 121 4957 60220




n-Hexane 00110-54-3 113 1782 20226

2-Methyl-2-butene 00513-35-9 1420 1495 212177

Propane 00074-98-6 046 1378 6301

t-2-Pentene 00646-04-8 1047 1321 138329

Toluene 00108-88-3 393 1320 51799

3-Methylpentane 00096-14-0 169 1291 21833

3-Me-1-Hexene 03404-61-3 427 1081 46189


t-3-Heptene 14686-14-7 617 963 59431

2-Methyl-1-butene 00563-46-2 638 894 57049


Benzene 00071-43-2 069 728 5053

c-2-Pentene 00627-20-3 1028 704 72389


23-Dimethylbutane 00079-29-8 090 634 5698

22-DiMeHexane 00590-73-8 094 623 5866



2-Methylhexane 00591-76-4 109 393 4266


c-2-Butene 00590-18-1 1426 385 54865




22-Dimethylbutane 00075-83-2 111 312 3465

Cyclopentane 00287-92-3 224 301 6725

t-2-Hexene 04050-45-7 855 283 24189

14-Diethylbenzene 00105-05-5 439 246 10796

Indan 00496-11-7 323 235 7603

Cyclopentene 00142-29-0 669 222 14854

3-Methyl-t-2-pentene 00616-12-6 1166 218 25428


3-Methyl-c-2-pentene 00922-62-3 1252 216 27097


2-Methylheptane 00592-27-8 097 187 1812





172

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 173 19052

n-Octane 00111-65-9 080 166 1321


n-Propylbenzene 00103-65-1 196 160 3132

ortho-Xylene 00095-47-6 758 156 11834




Ethylbenzene 00100-41-4 296 141 4174





Unknown 5 290 113 3275











Naphthalene 00091-20-3 328 042 1374

Total 7033 20500 2915


continued


173

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 13220 142369

2-Methylpropane 00075-28-5 118 11988 141051

Ethanol 00064-17-5 145 9234 133801

n-Pentane 00109-66-0 121 8302 100866



n-Hexane 00110-54-3 113 2767 31394

2-Methyl-2-butene 00513-35-9 1420 2454 348276

t-2-Pentene 00646-04-8 1047 2145 224611

Propane 00074-98-6 046 2099 9596

3-Methylpentane 00096-14-0 169 2086 35279

n-Heptane 00142-82-5 097 1782 17211


Cyclohexane 00110-82-7 114 1516 17244

2-Methyl-1-butene 00563-46-2 638 1447 92328

22-DiMeHexane 00590-73-8 094 1392 13105

c-2-Pentene 00627-20-3 1028 1194 122782

Toluene 00108-88-3 393 1100 43170

Benzene 00071-43-2 069 1087 7545

23-Dimethylbutane 00079-29-8 090 1032 9271



2-Methylhexane 00591-76-4 109 603 6543

22-Dimethylbutane 00075-83-2 111 570 6332

c-2-Butene 00590-18-1 1426 511 72813

Cyclopentane 00287-92-3 224 491 10983

t-2-Hexene 04050-45-7 855 437 37393


Cyclopentene 00142-29-0 669 367 24548

n-Octane 00111-65-9 080 364 2897

3-Methyl-t-2-pentene 00616-12-6 1166 339 39475

2-Methyl-2-pentene 00625-27-4 1103 326 35978

3-Methyl-c-2-pentene 00922-62-3 1252 325 40724









Unknown 22 253 201 5089





174

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methylheptane 00589-81-1 112 170 1906





24-Dimethylhexane 00589-43-5 161 126 2020



2-Methylheptane 00592-27-8 097 104 1010

n-Propylbenzene 00103-65-1 196 099 1936

ortho-Xylene 00095-47-6 758 097 7318

n-Nonane 00111-84-2 068 092 0630





33-Dimethylhexane 00563-16-6 115 074 0847


Ethylbenzene 00100-41-4 296 067 1991


1-Octene 00111-66-0 314 055 1718



Total 10408 26483 2545


continued


175

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2191 31752


n-Butane 00106-97-8 108 1006 10833

n-Pentane 00109-66-0 121 747 9080

Toluene 00108-88-3 393 701 27531


Unknown 22 328 660 21624


Benzene 00071-43-2 069 489 3398

2-Methylpropane 00075-28-5 118 438 5148

t-2-Pentene 00646-04-8 1047 413 43247

n-Heptane 00142-82-5 097 401 3869

2-Methyl-2-butene 00513-35-9 1420 365 51798




Propane 00074-98-6 046 309 1412





Cyclohexane 00110-82-7 114 257 2927


n-Octane 00111-65-9 080 231 1837



c-2-Pentene 00627-20-3 1028 166 17113



n-Hexane 00110-54-3 113 150 1697



ortho-Xylene 00095-47-6 758 139 10527



c-2-Butene 00590-18-1 1426 130 18467



13-Butadiene 00106-99-0 1245 113 14026

Ethylbenzene 00100-41-4 296 109 3230

t-2-Hexene 04050-45-7 855 098 8420

2-Methyl-1-butene 00563-46-2 638 090 5717

2-Methylhexane 00591-76-4 109 078 0845

23-Dimethylbutane 00079-29-8 090 075 0672




176

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



22-DiMeHexane 00590-73-8 094 069 0650

2-Methyl-2-pentene 00625-27-4 1103 054 5959

2-Methylheptane 00592-27-8 097 052 0507

3-Methyl-t-2-pentene 00616-12-6 1166 051 5927


3-Methylpentane 00096-14-0 169 046 0770


3-Methylheptane 00589-81-1 112 024 0275

Cyclopentene 00142-29-0 669 022 1455


n-Nonane 00111-84-2 068 019 0129

Total 1606 5720 3562


continued


177

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 54709 792723


n-Butane 00106-97-8 108 10917 117569

n-Pentane 00109-66-0 121 9272 112649

2-Methylpropane 00075-28-5 118 7225 85005


Toluene 00108-88-3 393 6283 246616

n-Hexane 00110-54-3 113 4995 56676

n-Heptane 00142-82-5 097 4659 44994

Benzene 00071-43-2 069 4652 32302


2-Methyl-2-butene 00513-35-9 1420 3675 521667

t-2-Pentene 00646-04-8 1047 3631 380251

3-Methylpentane 00096-14-0 169 2779 46981

22-DiMeHexane 00590-73-8 094 2773 26105

Cyclohexane 00110-82-7 114 2771 31519


c-2-Pentene 00627-20-3 1028 1943 199760

2-Methyl-1-butene 00563-46-2 638 1834 117003


Propane 00074-98-6 046 1660 7588


2-Methylhexane 00591-76-4 109 1107 12010


n-Octane 00111-65-9 080 1036 8250


t-2-Hexene 04050-45-7 855 954 81525


23-Dimethylbutane 00079-29-8 090 860 7730


Cyclopentane 00287-92-3 224 748 16744


c-2-Butene 00590-18-1 1426 680 97022

3-Methyl-t-2-pentene 00616-12-6 1166 666 77705

Cyclopentene 00142-29-0 669 665 44433


22-Dimethylbutane 00075-83-2 111 574 6383

3-Methyl-c-2-pentene 00922-62-3 1252 548 68650

2-Methyl-2-pentene 00625-27-4 1103 519 57206

2-Methylheptane 00592-27-8 097 515 4981



1-Butyne 00107-00-6 605 436 26373

3-Methylheptane 00589-81-1 112 403 4535




178

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





ortho-Xylene 00095-47-6 758 345 26142






Ethylbenzene 00100-41-4 296 292 8644


24-Dimethylhexane 00589-43-5 161 289 4646



n-Nonane 00111-84-2 068 234 1599


n-Propylbenzene 00103-65-1 196 198 3881



4-Methyloctane 02216-34-4 085 193 1641



Unknown 1 271 171 4641

33-Dimethylhexane 00563-16-6 115 159 1833






n-Undecane 01120-21-4 052 079 0415

3-Methyloctane 02216-33-3 088 079 0703

Unknown 5 271 076 2052

1-Octene 00111-66-0 314 065 2057





Unknown 8 271 035 0945

Total 17874 48855 2733


continued


179

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 8198 118785

n-Butane 00106-97-8 108 7183 77353


n-Pentane 00109-66-0 121 3595 43676

2-Methylpropane 00075-28-5 118 2766 32545


Propane 00074-98-6 046 2137 9770

n-Hexane 00110-54-3 113 1047 11875


n-Heptane 00142-82-5 097 912 8810

t-2-Pentene 00646-04-8 1047 830 86907

2-Methyl-2-butene 00513-35-9 1420 814 115599


23-Dimethylbutane 00079-29-8 090 556 4999


Benzene 00071-43-2 069 530 3683

2-Methyl-1-butene 00563-46-2 638 507 32336

Toluene 00108-88-3 393 503 19740

3-Methylpentane 00096-14-0 169 472 7984


c-2-Pentene 00627-20-3 1028 393 40363


c-2-Butene 00590-18-1 1426 277 39443



22-Dimethylbutane 00075-83-2 111 214 2380


2-Methylheptane 00592-27-8 097 180 1739

t-2-Hexene 04050-45-7 855 178 15211

n-Octane 00111-65-9 080 172 1368



2-Methylhexane 00591-76-4 109 161 1748



c-2-Heptene 06443-92-1 382 146 5572



Cyclopentene 00142-29-0 669 129 8640

3-Methyl-t-2-pentene 00616-12-6 1166 116 13518


Cyclohexane 00110-82-7 114 092 1044


n-Nonane 00111-84-2 068 087 0593




180

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 086 0966

2-Methyl-2-pentene 00625-27-4 1103 081 8971



24-Dimethylhexane 00589-43-5 161 078 1247








n-Propylbenzene 00103-65-1 196 048 0949


33-Dimethylhexane 00563-16-6 115 031 0359


3-Methyl-c-2-pentene 00922-62-3 1252 027 3427




Ethylbenzene 00100-41-4 296 018 0528

ortho-Xylene 00095-47-6 758 010 0721


Total 4710 11512 2444


continued


181

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 15180 219955


n-Butane 00106-97-8 108 9750 104997

n-Pentane 00109-66-0 121 5514 66989


2-Methylpropane 00075-28-5 118 3609 42461


n-Hexane 00110-54-3 113 2552 28959

Propane 00074-98-6 046 2506 11455

n-Heptane 00142-82-5 097 1866 18025

3-Methylpentane 00096-14-0 169 1624 27461

23-Dimethylbutane 00079-29-8 090 1413 12703

2-Methyl-2-butene 00513-35-9 1420 1376 195359

Toluene 00108-88-3 393 1340 52581

Cyclohexane 00110-82-7 114 1307 14870



t-2-Pentene 00646-04-8 1047 1180 123585


Benzene 00071-43-2 069 965 6703

2-Methyl-1-butene 00563-46-2 638 878 56009

c-2-Pentene 00627-20-3 1028 635 65238

2-Methylhexane 00591-76-4 109 632 6855






22-Dimethylbutane 00075-83-2 111 370 4115


n-Octane 00111-65-9 080 346 2755


c-2-Butene 00590-18-1 1426 336 47966


c-2-Heptene 06443-92-1 708 260 18411

t-2-Hexene 04050-45-7 855 249 21269

24-Dimethylhexane 00589-43-5 161 234 3765






3-Methyl-t-2-pentene 00616-12-6 1166 201 23444

2-Methyl-2-pentene 00625-27-4 1103 200 22011




182

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 193 1865

3-Methylheptane 00589-81-1 112 188 2119

Cyclopentene 00142-29-0 669 180 12031



n-Propylbenzene 00103-65-1 196 157 3073

3-Methyl-c-2-pentene 00922-62-3 1252 146 18216




ortho-Xylene 00095-47-6 758 129 9739




Ethylbenzene 00100-41-4 296 101 3002




n-Nonane 00111-84-2 068 085 0583



4-Methyloctane 02216-34-4 085 082 0694



33-Dimethylhexane 00563-16-6 115 067 0767

n-Decane 00124-18-5 059 066 0389



Total 8664 21100 2435


continued


183

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1732 25089


Benzene 00071-43-2 069 452 3139

c-2-Butene 00590-18-1 1426 376 53628








c-2-Pentene 00627-20-3 1028 072 7386

n-Heptane 00142-82-5 097 059 0568

n-Propylbenzene 00103-65-1 196 048 0947

Ethylbenzene 00100-41-4 296 045 1322


2-Methyl-2-butene 00513-35-9 1420 025 3547

t-2-Hexene 04050-45-7 855 022 1855

ortho-Xylene 00095-47-6 758 015 1110

n-Octane 00111-65-9 080 010 0081

Total 489 2108 4309




184

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 51382 744509



n-Butane 00106-97-8 108 8982 96733

n-Pentane 00109-66-0 121 6997 85011

Toluene 00108-88-3 393 6711 263404

n-Heptane 00142-82-5 097 6680 64513

n-Hexane 00110-54-3 113 5030 57075



Benzene 00071-43-2 069 4022 27924

Cyclohexane 00110-82-7 114 3279 37292




2-Methylpropane 00075-28-5 118 2557 30086


Propane 00074-98-6 046 2432 11116

3-Methylpentane 00096-14-0 169 2416 40845


n-Octane 00111-65-9 080 2194 17472

2-Methyl-2-butene 00513-35-9 1420 2103 298453

t-2-Pentene 00646-04-8 1047 2086 218459


2-Methylhexane 00591-76-4 109 1526 16559

23-Dimethylbutane 00079-29-8 090 1374 12350



2-Methyl-1-butene 00563-46-2 638 1191 75982



c-2-Pentene 00627-20-3 1028 1105 113644

2-Methylheptane 00592-27-8 097 1023 9893


3-Methylheptane 00589-81-1 112 906 10183





24-Dimethylhexane 00589-43-5 161 698 11203

c-2-Heptene 06443-92-1 708 667 47214

n-Nonane 00111-84-2 068 663 4525

t-2-Hexene 04050-45-7 855 648 55398

ortho-Xylene 00095-47-6 758 548 41492




185

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentane 00287-92-3 224 512 11458


n-Propylbenzene 00103-65-1 196 499 9784

4-Methyloctane 02216-34-4 085 497 4216

3-Methyl-t-2-pentene 00616-12-6 1166 485 56599

3-Methyl-c-2-pentene 00922-62-3 1252 456 57109

c-2-Butene 00590-18-1 1426 444 63356


Cyclopentene 00142-29-0 669 416 27787






Ethylbenzene 00100-41-4 296 389 11519

22-Dimethylbutane 00075-83-2 111 378 4206

2-Methyl-2-pentene 00625-27-4 1103 358 39448

Unknown 16 261 356 9264



3-Methyloctane 02216-33-3 088 339 3003




1-Nonene 00124-11-8 249 256 6374

1-Butyne 00107-00-6 605 251 15194

Ethylene 00074-85-1 888 250 22216


Unknown 8 261 234 6089


33-Dimethylhexane 00563-16-6 115 213 2449




1-Octene 00111-66-0 314 195 6137


Unknown 9 261 154 4022

n-Undecane 01120-21-4 052 154 0805

n-Decane 00124-18-5 059 152 0896

Unknown 5 261 142 3689


Indan 00496-11-7 323 131 4230

continued


186

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 6 261 131 3400


Styrene 00100-42-5 166 105 1738



Unknown 1 261 052 1367



Total 18590 49278 2651


continued


187

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


188

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




189

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




190

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Naphthalene 00091-20-3 328 774 25406


t-2-Butene 00624-64-6 1520 371 56453


n-Butane 00106-97-8 108 285 3072

23-Dimethylbutane 00079-29-8 090 248 2230



Toluene 00108-88-3 393 190 7444

2-Methylpropane 00075-28-5 118 166 1951

2-Methylheptane 00592-27-8 097 157 1514

3-Methyl-t-2-pentene 00616-12-6 1166 131 15309

n-Heptane 00142-82-5 097 130 1251


3-Methylpentane 00096-14-0 169 117 1981

24-Dimethylhexane 00589-43-5 161 111 1786


n-Hexane 00110-54-3 113 100 1134


22-Dimethylbutane 00075-83-2 111 082 0916

Ethylbenzene 00100-41-4 296 077 2293

t-2-Pentene 00646-04-8 1047 075 7833

Cyclohexane 00110-82-7 114 074 0842

c-2-Butene 00590-18-1 1426 074 10503

3-Methyl-c-2-pentene 00922-62-3 1252 071 8850

ortho-Xylene 00095-47-6 758 068 5178

n-Pentane 00109-66-0 121 021 0252


Total 486 2222 4570




191

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4628 67056

3-Methylpentane 00096-14-0 169 1507 25484



n-Butane 00106-97-8 108 1101 11855


Toluene 00108-88-3 393 1066 41860

3-Methyl-c-2-pentene 00922-62-3 1252 1066 133427

n-Pentane 00109-66-0 121 935 11363


n-Hexane 00110-54-3 113 210 2385


Total 1468 3932 2678




192

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




193

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




194

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




195

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4926 71372


Toluene 00108-88-3 393 1115 43746

3-Methylpentane 00096-14-0 169 762 12888

n-Butane 00106-97-8 108 725 7805


n-Hexane 00110-54-3 113 611 6931

n-Pentane 00109-66-0 121 583 7083




3-Methyl-c-2-pentene 00922-62-3 1252 205 25608

Total 1211 2325 1920



196


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


197

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 31534 339592

Ethanol 00064-17-5 145 15433 223618

n-Pentane 00109-66-0 121 4575 55584


Toluene 00108-88-3 393 4103 161061

n-Hexane 00110-54-3 113 3924 44527

2-Methyl-2-butene 00513-35-9 1420 3811 540999

t-2-Pentene 00646-04-8 1047 3208 335977

3-Methylpentane 00096-14-0 169 2810 47513

2-Methyl-1-butene 00563-46-2 638 2286 145822

23-Dimethylbutane 00079-29-8 090 2194 19722

c-2-Pentene 00627-20-3 1028 1736 178523




c-2-Butene 00590-18-1 1426 1349 192427

Benzene 00071-43-2 069 1177 8169

Cyclohexane 00110-82-7 114 1082 12310





t-2-Hexene 04050-45-7 855 585 50036

2-Methylhexane 00591-76-4 109 580 6299

Cyclopentene 00142-29-0 669 525 35095

n-Heptane 00142-82-5 097 524 5057

3-Methyl-t-2-pentene 00616-12-6 1166 474 55209


2-Methyl-2-pentene 00625-27-4 1103 432 47686

3-Methyl-c-2-pentene 00922-62-3 1252 408 51020




22-Dimethylbutane 00075-83-2 111 322 3582





24-Dimethylhexane 00589-43-5 161 213 3412


n-Octane 00111-65-9 080 159 1266




0020 Leak at Tank Top


198

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylheptane 00592-27-8 097 131 1270




3-Methylheptane 00589-81-1 112 116 1307




t-3-Heptene 14686-14-7 617 083 5119


ortho-Xylene 00095-47-6 758 079 5957




n-Decane 00124-18-5 249 054 1339




Ethylbenzene 00100-41-4 296 049 1460


Unknown 1 266 034 0906

33-Dimethylhexane 00563-16-6 115 030 0344

n-Propylbenzene 00103-65-1 196 028 0542

n-Nonane 00111-84-2 068 015 0101


4-Methyl-t-2-pentene 00674-76-0 804 002 0184

Total 13923 37072 2663


continued


199

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 79369 854739


Ethanol 00064-17-5 145 38151 552793

Toluene 00108-88-3 393 16580 650783

n-Hexane 00110-54-3 113 13605 154368


3-Methylpentane 00096-14-0 169 7654 129419

n-Pentane 00109-66-0 121 7381 89678

2-Methyl-2-butene 00513-35-9 1420 6466 917894


t-2-Pentene 00646-04-8 1047 5245 549380

23-Dimethylbutane 00079-29-8 090 5099 45823

Benzene 00071-43-2 069 4157 28862


Cyclohexane 00110-82-7 114 3728 42398

2-Methyl-1-butene 00563-46-2 638 3681 234792

Ethylene 00074-85-1 888 3244 288174




c-2-Pentene 00627-20-3 1028 2900 298147



Ethane 00074-84-0 026 2242 5893


c-2-Butene 00590-18-1 1426 1864 265834

2-Methylhexane 00591-76-4 109 1801 19546

n-Heptane 00142-82-5 097 1789 17277




2-Methylpropane 00075-28-5 118 1312 15435


t-2-Hexene 04050-45-7 855 1292 110422

1-Butyne 00107-00-6 605 1288 77894

Propane 00074-98-6 046 1212 5539



3-Methyl-t-2-pentene 00616-12-6 1166 1006 117309


Cyclopentene 00142-29-0 669 970 64866


2-Methyl-2-pentene 00625-27-4 1103 953 105093





200

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 843 105557

n-Octane 00111-65-9 080 804 6403

24-Dimethylhexane 00589-43-5 161 747 11988




13-Butadiene 00106-99-0 1245 683 85018

ortho-Xylene 00095-47-6 758 620 46937

22-Dimethylbutane 00075-83-2 111 614 6826


Ethylbenzene 00100-41-4 296 564 16718


n-Propylbenzene 00103-65-1 196 527 10333







2-Methylheptane 00592-27-8 097 427 4127


3-Methylheptane 00589-81-1 112 420 4718


14-Diethylbenzene 00105-05-5 439 416 18237

n-Decane 00124-18-5 059 401 2372



Unknown 16 275 325 8937



Methane 00074-82-8 001 281 0039


n-Nonane 00111-84-2 068 234 1599

Styrene 00100-42-5 166 234 3891



4-Methyl-t-2-pentene 00674-76-0 804 187 15065

n-Undecane 01120-21-4 052 186 0970

4-Methyloctane 02216-34-4 085 170 1442


c-2-Heptene 06443-92-1 708 149 10568

Unknown 8 275 147 4049

continued


201

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 1 275 144 3964

Unknown 22 275 143 3926


Unknown 5 275 129 3543



Unknown 13 275 118 3236

33-Dimethylhexane 00563-16-6 115 116 1338

1-Nonene 00124-11-8 249 113 2820


3-Methyloctane 02216-33-3 088 101 0889

3-Me-1-Hexene 03404-61-3 427 096 4100


Indan 00496-11-7 323 071 2300

Total 32476 89876 2767


continued


202

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 172274 1855242


Ethanol 00064-17-5 145 69165 1002190

2-Methylpropane 00075-28-5 118 21941 258154

n-Hexane 00110-54-3 113 20456 232106

Toluene 00108-88-3 393 19883 780424


n-Pentane 00109-66-0 121 17100 207749

2-Methyl-2-butene 00513-35-9 1420 14541 2064164

t-2-Pentene 00646-04-8 1047 12530 1312315

3-Methylpentane 00096-14-0 169 12414 209911

23-Dimethylbutane 00079-29-8 090 8996 80848

2-Methyl-1-butene 00563-46-2 638 8314 530308


c-2-Pentene 00627-20-3 1028 6703 689128


Benzene 00071-43-2 069 5731 39795

c-2-Butene 00590-18-1 1426 5522 787420

Cyclohexane 00110-82-7 114 5520 62783




n-Heptane 00142-82-5 097 2763 26680



2-Methylhexane 00591-76-4 109 2596 28167


t-2-Hexene 04050-45-7 855 2303 196844

Cyclopentene 00142-29-0 669 2024 135325




3-Methyl-t-2-pentene 00616-12-6 1166 1818 211970

2-Methyl-2-pentene 00625-27-4 1103 1651 182150


3-Methyl-c-2-pentene 00922-62-3 1252 1509 188858



22-Dimethylbutane 00075-83-2 111 1289 14328

Propane 00074-98-6 046 1286 5880








203

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 965 15494

n-Octane 00111-65-9 080 867 6901






2-Methylheptane 00592-27-8 097 513 4960

Ethylbenzene 00100-41-4 296 509 15068

ortho-Xylene 00095-47-6 758 500 37892

3-Methylheptane 00589-81-1 112 493 5541








n-Propylbenzene 00103-65-1 196 278 5444

4-Methyl-t-2-pentene 00674-76-0 804 268 21529

Unknown 16 250 236 5907

n-Nonane 00111-84-2 068 228 1557





c-2-Heptene 06443-92-1 708 180 12724



4-Methyloctane 02216-34-4 085 159 1351


Unknown 5 250 146 3658

33-Dimethylhexane 00563-16-6 115 145 1668

Unknown 13 250 138 3462

Indan 00496-11-7 565 135 7640


1-Octene 00111-66-0 314 134 4197


Unknown 8 250 128 3196




continued


204

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




t-4-Octene 14850-23-8 469 113 5317

n-Decane 00124-18-5 059 102 0604

14-Diethylbenzene 00105-05-5 439 092 4032

3-Methyloctane 02216-33-3 088 083 0734

1-Nonene 00124-11-8 249 082 2036

Unknown 9 250 082 2039

t-3-Heptene 14686-14-7 617 074 4560

Unknown 3 250 072 1807

n-Undecane 01120-21-4 052 061 0317

1-Heptene 00592-76-7 429 060 2554



Unknown 12 250 046 1154



t-2-Nonene 06434-78-2 250 036 0888


c-2-Octene 07642-04-8 250 026 0651

Unknown 14 250 018 0459

Total 61958 155900 2516


continued


205

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11715 169746

n-Butane 00106-97-8 108 8056 86757

n-Hexane 00110-54-3 113 4667 52958


23-Dimethylbutane 00079-29-8 090 3624 32566

Toluene 00108-88-3 393 3574 140274

2-Methyl-2-butene 00513-35-9 1420 2721 386293

3-Methylpentane 00096-14-0 169 2686 45414

n-Pentane 00109-66-0 121 2659 32300

t-2-Pentene 00646-04-8 1047 2291 239970

2-Methyl-1-butene 00563-46-2 638 1615 103023



Cyclohexane 00110-82-7 114 1325 15069

2-Methylpropane 00075-28-5 118 1261 14840

c-2-Pentene 00627-20-3 1028 1225 125951

Benzene 00071-43-2 069 1002 6959


c-2-Butene 00590-18-1 1426 984 140348




2-Methylhexane 00591-76-4 109 497 5389



t-2-Hexene 04050-45-7 855 436 37281

n-Heptane 00142-82-5 097 390 3765

Cyclopentene 00142-29-0 669 377 25223


3-Methyl-t-2-pentene 00616-12-6 1166 342 39822

2-Methyl-2-pentene 00625-27-4 1103 323 35657


3-Methyl-c-2-pentene 00922-62-3 1252 294 36799




24-Dimethylhexane 00589-43-5 161 213 3421


n-Octane 00111-65-9 080 185 1477








206

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 141 1566



Propane 00074-98-6 046 113 0517




ortho-Xylene 00095-47-6 758 064 4881


4-Methyl-t-2-pentene 00674-76-0 804 060 4791


n-Decane 00124-18-5 059 057 0338

2-Methylheptane 00592-27-8 097 055 0536



Ethylbenzene 00100-41-4 296 053 1579

3-Methylheptane 00589-81-1 112 052 0582


Unknown 5 288 046 1329

4-Methyloctane 02216-34-4 085 043 0365



33-Dimethylhexane 00563-16-6 115 037 0423

3-Methyloctane 02216-33-3 088 032 0283

n-Nonane 00111-84-2 068 023 0155

n-Propylbenzene 00103-65-1 196 015 0294


Total 8737 25269 2892


continued


207

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35389 512774

Benzene 00071-43-2 069 4816 33438

Methane 00074-82-8 001 200 0028

Ethane 00074-84-0 026 1602 4210


Propane 00074-98-6 046 1131 5168

2-Methylpropane 00075-28-5 118 2369 27872

22-Dimethylbutane 00075-83-2 111 986 10951



23-Dimethylbutane 00079-29-8 090 7961 71544

ortho-Xylene 00095-47-6 758 645 48887


3-Methylpentane 00096-14-0 169 11861 200561



Ethylbenzene 00100-41-4 296 495 14670

n-Propylbenzene 00103-65-1 196 538 10537

n-Butane 00106-97-8 108 20573 221556

13-Butadiene 00106-99-0 1245 657 81767





Toluene 00108-88-3 393 16497 647513

n-Pentane 00109-66-0 121 12943 157255


n-Hexane 00110-54-3 113 19250 218427

Cyclohexane 00110-82-7 114 5321 60521


n-Octane 00111-65-9 080 692 5511

n-Nonane 00111-84-2 068 309 2108


n-Decane 00124-18-5 059 301 1780

Cyclopentene 00142-29-0 669 1453 97125

n-Heptane 00142-82-5 097 1831 17681


2-Methyl-2-butene 00513-35-9 1420 10075 1430132




2-Methyl-1-butene 00563-46-2 638 6277 400401






208

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 1065 17101

3-Methylheptane 00589-81-1 112 512 5752

c-2-Butene 00590-18-1 1426 4141 590493



2-Methylhexane 00591-76-4 109 2197 23841


2-Methylheptane 00592-27-8 097 512 4948



3-Methyl-t-2-pentene 00616-12-6 1166 1347 156999


2-Methyl-2-pentene 00625-27-4 1103 1253 138231

c-2-Pentene 00627-20-3 1028 4701 483353


t-2-Pentene 00646-04-8 1047 8504 890689





3-Methyl-c-2-pentene 00922-62-3 1252 1185 148379







t-2-Hexene 04050-45-7 855 1625 138889


Unknown 16 335 352 11791

Unknown 1 335 242 8119

Total 34405 116244 3379


continued


209

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 112868 1635432

n-Butane 00106-97-8 108 58158 626316

n-Hexane 00110-54-3 113 44646 506591


n-Pentane 00109-66-0 121 30821 374457

3-Methylpentane 00096-14-0 169 26164 442392

2-Methyl-2-butene 00513-35-9 1420 25929 3680648

Toluene 00108-88-3 393 23727 931277

t-2-Pentene 00646-04-8 1047 21858 2289338

23-Dimethylbutane 00079-29-8 090 18155 163160

2-Methyl-1-butene 00563-46-2 638 14852 947358



c-2-Pentene 00627-20-3 1028 11711 1204011

Cyclohexane 00110-82-7 114 10272 116827


c-2-Butene 00590-18-1 1426 8497 1211611

Benzene 00071-43-2 069 8447 58652

2-Methylpropane 00075-28-5 118 7517 88450



2-Methylhexane 00591-76-4 109 4449 48279



t-2-Hexene 04050-45-7 855 3861 330080


Cyclopentene 00142-29-0 669 3403 227545

n-Heptane 00142-82-5 097 3263 31514

3-Methyl-t-2-pentene 00616-12-6 1166 3087 359933


2-Methyl-2-pentene 00625-27-4 1103 2833 312515


3-Methyl-c-2-pentene 00922-62-3 1252 2551 319336



22-Dimethylbutane 00075-83-2 111 2302 25580


24-Dimethylhexane 00589-43-5 161 1503 24139

Propane 00074-98-6 046 1456 6658








210

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




1-Butyne 00107-00-6 605 1088 65828

n-Octane 00111-65-9 080 827 6585









2-Methylheptane 00592-27-8 097 486 4701

3-Methylheptane 00589-81-1 112 442 4965

ortho-Xylene 00095-47-6 758 367 27827







Ethylbenzene 00100-41-4 296 241 7138



n-Propylbenzene 00103-65-1 196 204 4004

Unknown 5 295 172 5063

33-Dimethylhexane 00563-16-6 115 164 1888


c-2-Heptene 06443-92-1 708 133 9383

n-Nonane 00111-84-2 068 125 0851

1-Octene 00111-66-0 314 124 3881

Indan 00496-11-7 323 119 3852

t-3-Heptene 14686-14-7 617 114 7031

Ethylene 00074-85-1 888 113 10031

4-Methyloctane 02216-34-4 085 111 0942


Unknown 16 295 101 2970

Unknown 3 295 097 2854

Unknown 6 295 097 2845




Unknown 8 295 081 2388

n-Decane 00124-18-5 059 080 0470

continued


211

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 13 295 079 2322

3-Methyloctane 02216-33-3 088 077 0681


13-Butadiene 00106-99-0 1245 076 9484


1-Heptene 00592-76-7 429 060 2584



Unknown 9 295 047 1372


1-Nonene 00124-11-8 249 039 0967

n-Undecane 01120-21-4 052 039 0202

3-Ethyl-c-2-Pentene 00816-79-5 976 038 3690


3-Methylnonane 295 023 0667




14-Diethylbenzene 00105-05-5 439 016 0705


Unknown 22 295 005 0140

Total 76987 227741 2958


continued


212

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 24872 267848


Ethanol 00064-17-5 145 7522 108992

n-Hexane 00110-54-3 113 2284 25919

Toluene 00108-88-3 393 1833 71943


3-Methylpentane 00096-14-0 169 1742 29458

2-Methyl-2-butene 00513-35-9 1420 1698 240966

n-Pentane 00109-66-0 121 1576 19144

t-2-Pentene 00646-04-8 1047 1511 158229

23-Dimethylbutane 00079-29-8 090 1202 10800


2-Methyl-1-butene 00563-46-2 638 1039 66260


Benzene 00071-43-2 069 892 6192

c-2-Pentene 00627-20-3 1028 805 82752

c-2-Butene 00590-18-1 1426 802 114334

Cyclohexane 00110-82-7 114 799 9092



2-Methylpropane 00075-28-5 118 646 7600

1-Butyne 00107-00-6 605 646 39077




2-Methylhexane 00591-76-4 109 405 4399





Propane 00074-98-6 046 326 1490

t-2-Hexene 04050-45-7 855 306 26148

n-Heptane 00142-82-5 097 305 2946



Cyclopentene 00142-29-0 669 242 16150

3-Methyl-t-2-pentene 00616-12-6 1166 237 27634


3-Methyl-c-2-pentene 00922-62-3 1252 219 27369

ortho-Xylene 00095-47-6 758 215 16278

2-Methyl-2-pentene 00625-27-4 1103 210 23172





0020 Leak at Canister Inlet


213

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 178 1977


24-Dimethylhexane 00589-43-5 161 139 2225

n-Octane 00111-65-9 080 130 1032


Ethylbenzene 00100-41-4 296 119 3519




n-Propylbenzene 00103-65-1 196 104 2036




3-Methylheptane 00589-81-1 112 074 0827






2-Methylheptane 00592-27-8 097 047 0455


n-Nonane 00111-84-2 068 046 0315

Total 7427 20164 2715


continued


214

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 42844 461388


Ethanol 00064-17-5 145 17178 248906

Toluene 00108-88-3 393 10047 394340

n-Hexane 00110-54-3 113 8065 91515


3-Methylpentane 00096-14-0 169 4491 75939

n-Pentane 00109-66-0 121 4370 53093

2-Methyl-2-butene 00513-35-9 1420 3637 516297


23-Dimethylbutane 00079-29-8 090 2956 26564

t-2-Pentene 00646-04-8 1047 2864 299954


Benzene 00071-43-2 069 2591 17991

Cyclohexane 00110-82-7 114 2542 28906



2-Methyl-1-butene 00563-46-2 638 1881 119952

c-2-Butene 00590-18-1 1426 1857 264799

c-2-Pentene 00627-20-3 1028 1775 182543


Ethylene 00074-85-1 888 1636 145343

n-Heptane 00142-82-5 097 1536 14831



Ethane 00074-84-0 026 1261 3314



Methane 00074-82-8 001 1067 0148


2-Methylhexane 00591-76-4 109 1026 11134


Propane 00074-98-6 046 809 3698


t-2-Hexene 04050-45-7 855 760 65002

n-Octane 00111-65-9 080 636 5062


3-Methyl-t-2-pentene 00616-12-6 1166 604 70439


Cyclopentene 00142-29-0 669 555 37098

13-Butadiene 00106-99-0 1245 530 66022







215

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




2-Methyl-2-pentene 00625-27-4 1103 503 55446




ortho-Xylene 00095-47-6 758 427 32375

n-Propylbenzene 00103-65-1 196 425 8330

3-Methyl-c-2-pentene 00922-62-3 1252 419 52480




Ethylbenzene 00100-41-4 296 312 9253

22-Dimethylbutane 00075-83-2 111 306 3401


3-Methylheptane 00589-81-1 112 296 3328


2-Methylpropane 00075-28-5 118 281 3306


24-Dimethylhexane 00589-43-5 161 250 4021

2-Methylheptane 00592-27-8 097 238 2306






Unknown 1 284 172 4890




Total 18066 51521 2852


continued


216

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 316658 3410131


Ethanol 00064-17-5 145 67831 982860

n-Hexane 00110-54-3 113 32071 363900


n-Pentane 00109-66-0 121 25077 304666

2-Methyl-2-butene 00513-35-9 1420 20849 2959520

3-Methylpentane 00096-14-0 169 19682 332790

t-2-Pentene 00646-04-8 1047 17641 1847614

Toluene 00108-88-3 393 15091 592313

23-Dimethylbutane 00079-29-8 090 13982 125657

2-Methyl-1-butene 00563-46-2 638 12182 777050

c-2-Pentene 00627-20-3 1028 9542 981058



2-Methylpropane 00075-28-5 118 7882 92741


Cyclohexane 00110-82-7 114 7483 85109

c-2-Butene 00590-18-1 1426 7117 1014871

Benzene 00071-43-2 069 6155 42735


2-Methylhexane 00591-76-4 109 3304 35857


t-2-Hexene 04050-45-7 855 3007 257097



Cyclopentene 00142-29-0 669 2736 182929


3-Methyl-t-2-pentene 00616-12-6 1166 2425 282759

n-Heptane 00142-82-5 097 2420 23372

2-Methyl-2-pentene 00625-27-4 1103 2238 246882


3-Methyl-c-2-pentene 00922-62-3 1252 2008 251353


22-Dimethylbutane 00075-83-2 111 1932 21463







24-Dimethylhexane 00589-43-5 161 1135 18218






217

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





1-Butyne 00107-00-6 605 772 46679

n-Octane 00111-65-9 080 671 5344



Propane 00074-98-6 046 568 2596





2-Methylheptane 00592-27-8 097 469 4538


3-Methylheptane 00589-81-1 112 433 4866



ortho-Xylene 00095-47-6 758 325 24656




Ethylbenzene 00100-41-4 296 255 7563

n-Propylbenzene 00103-65-1 196 248 4851


n-Nonane 00111-84-2 068 175 1194

Unknown 5 240 166 3989

33-Dimethylhexane 00563-16-6 115 165 1905

n-Decane 00124-18-5 059 164 0967



c-2-Heptene 06443-92-1 708 144 10185



Unknown 16 240 132 3163



4-Methyloctane 02216-34-4 085 108 0916

n-Undecane 01120-21-4 052 106 0553

t-3-Heptene 14686-14-7 617 101 6224


Unknown 3 240 067 1615

1-Heptene 00592-76-7 429 066 2838

13-Butadiene 00106-99-0 1245 060 7523


3-Methyloctane 02216-33-3 088 059 0525

continued


218

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyloctane 02216-33-3 088 059 0525



Unknown 22 240 053 1268

1-Nonene 00124-11-8 249 047 1178

Unknown 8 240 047 1119


Indan 00496-11-7 323 033 1060

14-Diethylbenzene 00105-05-5 439 027 1190

Total 86321 207927 2409


continued


219

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5716 82823

Benzene 00071-43-2 069 818 5680

Propane 00074-98-6 046 141 0644

2-Methylpropane 00075-28-5 118 344 4046


23-Dimethylbutane 00079-29-8 090 819 7363


3-Methylpentane 00096-14-0 169 1189 20098


n-Butane 00106-97-8 108 3676 39588

Toluene 00108-88-3 393 2159 84759

n-Pentane 00109-66-0 121 1545 18766

n-Hexane 00110-54-3 113 2616 29678

2-Methyl-2-butene 00513-35-9 1420 1237 175649



t-2-Pentene 00646-04-8 1047 1196 125262


Total 3415 8597 2517





220

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 13363 193622

Benzene 00071-43-2 069 2498 17342

Methane 00074-82-8 001 1601 0222

Ethane 00074-84-0 026 1146 3013

Ethylene 00074-85-1 888 1976 175570

2-Methylpropane 00075-28-5 118 312 3675

22-Dimethylbutane 00075-83-2 111 419 4659



23-Dimethylbutane 00079-29-8 090 2658 23890

ortho-Xylene 00095-47-6 758 471 35666


3-Methylpentane 00096-14-0 169 4167 70465




Ethylbenzene 00100-41-4 296 483 14312

n-Propylbenzene 00103-65-1 196 549 10766

14-Diethylbenzene 00105-05-5 439 366 16071

n-Butane 00106-97-8 108 6249 67299

13-Butadiene 00106-99-0 1245 678 84410

1-Butyne 00107-00-6 605 843 50998





Toluene 00108-88-3 393 9872 387494

n-Pentane 00109-66-0 121 3931 47757


n-Hexane 00110-54-3 113 7372 83651

Cyclohexane 00110-82-7 114 2206 25094


n-Octane 00111-65-9 080 595 4737

n-Nonane 00111-84-2 068 180 1229

1-Dodecene 00112-41-4 156 142 2220


n-Decane 00124-18-5 059 631 3731

Cyclopentene 00142-29-0 669 568 37986

n-Heptane 00142-82-5 097 940 9074


Indan 00496-11-7 323 222 7175

2-Methyl-2-butene 00513-35-9 1420 3288 466742






221

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






33-Dimethyl-1-butene 00558-37-2 568 092 5207


33-Dimethylhexane 00563-16-6 115 164 1893

2-Methyl-1-butene 00563-46-2 638 1833 116899




24-Dimethylhexane 00589-43-5 161 689 11062

3-Methylheptane 00589-81-1 112 195 2189

c-2-Butene 00590-18-1 1426 1053 150118


2-Methylhexane 00591-76-4 109 1016 11022


2-Methylheptane 00592-27-8 097 452 4375



3-Methyl-t-2-pentene 00616-12-6 1166 664 77449



2-Methyl-2-pentene 00625-27-4 1103 641 70697

c-2-Pentene 00627-20-3 1028 1401 144091


t-2-Pentene 00646-04-8 1047 2698 282558





continued


222

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 649 81193






4-Methyloctane 02216-34-4 085 175 1482




t-2-Hexene 04050-45-7 855 875 74823


c-2-Heptene 06443-92-1 066 121 0790


Unknown 16 342 407 13925

Unknown 13 342 172 5885

Unknown 1 342 111 3781

Total 13962 48361 3464


continued


223

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 93713 1357878

Benzene 00071-43-2 069 8395 58292

Ethylene 00074-85-1 888 385 34170

Propane 00074-98-6 046 2204 10077

2-Methylpropane 00075-28-5 118 9571 112611

22-Dimethylbutane 00075-83-2 111 1771 19683



23-Dimethylbutane 00079-29-8 090 17445 156779

ortho-Xylene 00095-47-6 758 670 50741


3-Methylpentane 00096-14-0 169 25280 427457



Ethylbenzene 00100-41-4 296 381 11287

n-Propylbenzene 00103-65-1 196 340 6654

n-Butane 00106-97-8 108 45349 488366

13-Butadiene 00106-99-0 1245 098 12253

1-Butyne 00107-00-6 605 785 47505






Toluene 00108-88-3 393 27004 1059911

n-Pentane 00109-66-0 121 24220 294263


n-Hexane 00110-54-3 113 42008 476657

Cyclohexane 00110-82-7 114 10300 117149


n-Octane 00111-65-9 080 1207 9611

1-Octene 00111-66-0 314 135 4256

n-Nonane 00111-84-2 068 238 1626


1-Nonene 00124-11-8 249 109 2715

n-Decane 00124-18-5 059 372 2201

Cyclopentene 00142-29-0 669 2697 180349

n-Heptane 00142-82-5 097 3372 32566



Indan 00496-11-7 323 253 8173

2-Methyl-2-butene 00513-35-9 1420 20269 2877200







224

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





33-Dimethylhexane 00563-16-6 115 181 2080

2-Methyl-1-butene 00563-46-2 638 11748 749377




24-Dimethylhexane 00589-43-5 161 2049 32895

3-Methylheptane 00589-81-1 112 880 9892

c-2-Butene 00590-18-1 1426 7564 1078587



2-Methylhexane 00591-76-4 109 4571 49606


2-Methylheptane 00592-27-8 097 923 8932


1-Heptene 00592-76-7 429 108 4612


3-Methyl-t-2-pentene 00616-12-6 1166 3093 360613



2-Methyl-2-pentene 00625-27-4 1103 2810 309980

c-2-Pentene 00627-20-3 1028 9207 946625


t-2-Pentene 00646-04-8 1047 17071 1787966





3-Methyl-c-2-pentene 00922-62-3 1252 2468 308948







3-Methyloctane 02216-33-3 088 167 1477

4-Methyloctane 02216-34-4 085 247 2098





continued


225

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





t-2-Hexene 04050-45-7 855 3716 317667

t-2-Nonene 06434-78-2 290 075 2171

c-2-Heptene 06443-92-1 708 211 14913


t-3-Heptene 14686-14-7 617 198 12193

Unknown 5 290 413 11999

Unknown 16 290 404 11736

Unknown 13 290 190 5520

Unknown 8 290 136 3963

Unknown 3 290 085 2475

Unknown 9 290 084 2439

Total 68582 200436 2923


continued


226


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


227

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 22971 247380


n-Hexane 00110-54-3 113 2483 28180


n-Pentane 00109-66-0 121 1817 22079

3-Methylpentane 00096-14-0 169 1584 26779

2-Methyl-2-butene 00513-35-9 1420 1509 214170

t-2-Pentene 00646-04-8 1047 1269 132895

Toluene 00108-88-3 393 1202 47172

23-Dimethylbutane 00079-29-8 090 1103 9914

c-2-Butene 00590-18-1 1426 904 128849

2-Methyl-1-butene 00563-46-2 638 890 56745



c-2-Pentene 00627-20-3 1028 680 69944

2-Methylpropane 00075-28-5 118 645 7585

t-2-Butene 00624-64-6 1520 536 81392


Cyclohexane 00110-82-7 114 519 5901


Benzene 00071-43-2 069 479 3328





2-Methylhexane 00591-76-4 109 227 2467

t-2-Hexene 04050-45-7 855 211 18015

Cyclopentene 00142-29-0 669 199 13290

n-Heptane 00142-82-5 097 194 1873



3-Methyl-t-2-pentene 00616-12-6 1166 176 20565



3-Methyl-1-butene 00563-45-1 685 153 10520

2-Methyl-2-pentene 00625-27-4 1103 152 16805







22-Dimethylbutane 00075-83-2 111 119 1317





228

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 115 14408

n-Octane 00111-65-9 080 107 0853


ortho-Xylene 00095-47-6 758 102 7756








n-Propylbenzene 00103-65-1 196 046 0903


2-Methylheptane 00592-27-8 097 041 0396



Ethylbenzene 00100-41-4 296 007 0221

24-Dimethylhexane 00589-43-5 161 006 0101

Total 6278 16694 2659


continued


229

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Unknown 22 307 391 12012

Ethanol 00064-17-5 145 1321 19145

Benzene 00071-43-2 069 2139 14852

Propane 00074-98-6 046 397 1816

2-Methylpropane 00075-28-5 118 3636 42785

22-Dimethylbutane 00075-83-2 111 842 9359



23-Dimethylbutane 00079-29-8 090 2973 26719

ortho-Xylene 00095-47-6 758 337 25550


3-Methylpentane 00096-14-0 169 3756 63505


Ethylbenzene 00100-41-4 296 220 6505

n-Propylbenzene 00103-65-1 196 202 3961

n-Butane 00106-97-8 108 56598 609509






Toluene 00108-88-3 393 2903 113947

n-Pentane 00109-66-0 121 5036 61181


n-Hexane 00110-54-3 113 7233 82075

Cyclohexane 00110-82-7 114 3248 36942


n-Octane 00111-65-9 080 252 2004


Cyclopentene 00142-29-0 669 913 61061

n-Heptane 00142-82-5 097 978 9444


2-Methyl-2-butene 00513-35-9 1420 4143 588042




2-Methyl-1-butene 00563-46-2 638 4234 270054




24-Dimethylhexane 00589-43-5 161 832 13366

3-Methylheptane 00589-81-1 112 179 2017

c-2-Butene 00590-18-1 1426 7009 999462





230

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





2-Methylhexane 00591-76-4 109 1400 15189


2-Methylheptane 00592-27-8 097 175 1693



3-Methyl-t-2-pentene 00616-12-6 1166 815 95045



2-Methyl-2-pentene 00625-27-4 1103 777 85750

c-2-Pentene 00627-20-3 1028 3096 318320

t-2-Pentene 00646-04-8 1047 3554 372250





3-Methyl-c-2-pentene 00922-62-3 1252 712 89120




t-2-Hexene 04050-45-7 855 994 84993


Unknown 1 307 061 1868

Total 19657 60694 3088


continued


231

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 307727 3313949


Ethanol 00064-17-5 145 39672 574830

n-Hexane 00110-54-3 113 34020 386019


n-Pentane 00109-66-0 121 28021 340433

3-Methylpentane 00096-14-0 169 22023 372381

2-Methyl-2-butene 00513-35-9 1420 20648 2930948

t-2-Pentene 00646-04-8 1047 17405 1822913

23-Dimethylbutane 00079-29-8 090 16047 144212

Toluene 00108-88-3 393 14387 564695

2-Methyl-1-butene 00563-46-2 638 12969 827211

c-2-Butene 00590-18-1 1426 11793 1681690



c-2-Pentene 00627-20-3 1028 9515 978316

Cyclohexane 00110-82-7 114 9043 102849


Benzene 00071-43-2 069 6756 46910



2-Methylhexane 00591-76-4 109 3473 37687



3-Methyl-t-2-pentene 00616-12-6 1166 2951 344072


2-Methylpropane 00075-28-5 118 2769 32579

Cyclopentene 00142-29-0 669 2682 179344



n-Heptane 00142-82-5 097 2413 23305

2-Methyl-2-pentene 00625-27-4 1103 2292 252898

24-Dimethylhexane 00589-43-5 161 2070 33231

t-2-Hexene 04050-45-7 855 2064 176446

3-Methyl-c-2-pentene 00922-62-3 1252 2063 258275

22-Dimethylbutane 00075-83-2 111 1886 20962







232

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








Propane 00074-98-6 046 400 1829


Ethylbenzene 00100-41-4 296 342 10143

Total 85443 209022 2446


continued


233

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11488 166456

n-Butane 00106-97-8 108 7975 85883

n-Hexane 00110-54-3 113 6913 78445


n-Pentane 00109-66-0 121 4885 59344

3-Methylpentane 00096-14-0 169 4260 72030

2-Methyl-2-butene 00513-35-9 1420 4013 569617

t-2-Pentene 00646-04-8 1047 3313 346941

Toluene 00108-88-3 393 3059 120057

23-Dimethylbutane 00079-29-8 090 2976 26746

2-Methyl-1-butene 00563-46-2 638 2453 156477



c-2-Butene 00590-18-1 1426 1891 269674

c-2-Pentene 00627-20-3 1028 1824 187499

Cyclohexane 00110-82-7 114 1684 19156

t-2-Butene 00624-64-6 1520 1597 242714


2-Methylpropane 00075-28-5 118 1543 18157

Benzene 00071-43-2 069 1143 7936




2-Methylhexane 00591-76-4 109 714 7751



t-2-Hexene 04050-45-7 855 596 50989


Cyclopentene 00142-29-0 669 507 33919

3-Methyl-t-2-pentene 00616-12-6 1166 499 58164


2-Methyl-2-pentene 00625-27-4 1103 459 50603

Propane 00074-98-6 046 439 2008


n-Heptane 00142-82-5 097 430 4150

3-Methyl-c-2-pentene 00922-62-3 1252 414 51810

22-Dimethylbutane 00075-83-2 111 382 4244



24-Dimethylhexane 00589-43-5 161 288 4618







234

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 130 1038



2-Methylheptane 00592-27-8 097 099 0957



3-Methylheptane 00589-81-1 112 083 0929





t-3-Heptene 14686-14-7 617 051 3173



Unknown 5 321 043 1371


Ethylbenzene 00100-41-4 296 040 1173

33-Dimethylhexane 00563-16-6 115 036 0411

ortho-Xylene 00095-47-6 758 035 2689

n-Propylbenzene 00103-65-1 196 035 0690


Total 11846 38214 3226


continued


235

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Butane 00106-97-8 108 7470 80442

n-Hexane 00110-54-3 113 7413 84118

n-Pentane 00109-66-0 121 5151 62576


3-Methylpentane 00096-14-0 169 4543 76808

2-Methyl-2-butene 00513-35-9 1420 4232 600795

t-2-Pentene 00646-04-8 1047 3542 371010

Toluene 00108-88-3 393 3511 137807

23-Dimethylbutane 00079-29-8 090 3268 29366

c-2-Butene 00590-18-1 1426 3176 452906

1-Butyne 00107-00-6 605 2943 178046

2-Methyl-1-butene 00563-46-2 638 2779 177240


c-2-Pentene 00627-20-3 1028 2047 210481


Cyclohexane 00110-82-7 114 1938 22040


2-Methylpropane 00075-28-5 118 1317 15500

Benzene 00071-43-2 069 1229 8533



Ethanol 00064-17-5 145 810 11731



2-Methylhexane 00591-76-4 109 691 7494

t-2-Hexene 04050-45-7 855 621 53050

n-Heptane 00142-82-5 097 579 5588


Cyclopentene 00142-29-0 669 574 38396


2-Methyl-2-pentene 00625-27-4 1103 486 53633



3-Methyl-c-2-pentene 00922-62-3 1252 468 58610

3-Methyl-t-2-pentene 00616-12-6 1166 457 53286


Methane 00074-82-8 001 444 0061

22-Dimethylbutane 00075-83-2 111 431 4788








236

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 328 5262


n-Octane 00111-65-9 080 282 2250


n-Decane 00124-18-5 059 276 1632

Unknown 22 335 234 7864






2-Methylheptane 00592-27-8 097 160 1548

3-Methylheptane 00589-81-1 112 144 1615




n-Propylbenzene 00103-65-1 196 113 2208

Unknown 1 335 094 3164


Indan 00496-11-7 323 084 2722


Ethylbenzene 00100-41-4 296 067 1991

n-Undecane 01120-21-4 052 047 0244

ortho-Xylene 00095-47-6 758 043 3244

Total 13128 44311 3375


continued


237

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 23123 249015

Ethanol 00064-17-5 145 21703 314477

n-Hexane 00110-54-3 113 18050 204804


n-Pentane 00109-66-0 121 13834 168070

3-Methylpentane 00096-14-0 169 11505 194534

2-Methyl-2-butene 00513-35-9 1420 11209 1591055

t-2-Pentene 00646-04-8 1047 9469 991727

23-Dimethylbutane 00079-29-8 090 8278 74396

2-Methyl-1-butene 00563-46-2 638 6814 434644

Toluene 00108-88-3 393 6647 260916


c-2-Pentene 00627-20-3 1028 5152 529739



c-2-Butene 00590-18-1 1426 4525 645316

Cyclohexane 00110-82-7 114 4341 49370

1-Butyne 00107-00-6 605 3288 198937

2-Methylpropane 00075-28-5 118 3175 37353

Benzene 00071-43-2 069 2711 18826



2-Methylhexane 00591-76-4 109 1773 19242




t-2-Hexene 04050-45-7 855 1516 129592

Cyclopentene 00142-29-0 669 1453 97160

3-Methyl-t-2-pentene 00616-12-6 1166 1242 144819


2-Methyl-2-pentene 00625-27-4 1103 1149 126792

3-Methyl-c-2-pentene 00922-62-3 1252 1075 134519


22-Dimethylbutane 00075-83-2 111 1058 11760

n-Heptane 00142-82-5 097 1036 10005






24-Dimethylhexane 00589-43-5 161 606 9728






238

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Propane 00074-98-6 046 476 2175








n-Octane 00111-65-9 080 260 2066






2-Methylheptane 00592-27-8 097 198 1916

Ethylbenzene 00100-41-4 296 198 5852

3-Methylheptane 00589-81-1 112 177 1989


ortho-Xylene 00095-47-6 758 163 12357



Unknown 1 313 123 3845

Unknown 16 313 116 3646

n-Decane 00124-18-5 059 110 0648

n-Propylbenzene 00103-65-1 196 088 1715



Unknown 5 313 070 2205

c-2-Heptene 06443-92-1 708 065 4610

33-Dimethylhexane 00563-16-6 115 065 0749

n-Nonane 00111-84-2 068 049 0335

t-3-Heptene 14686-14-7 617 043 2680


13-Butadiene 00106-99-0 1245 042 5279

4-Methyl-t-2-pentene 00674-76-0 804 021 1722

Methane 00074-82-8 001 008 0001

Total 31093 97716 3143


continued


239

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 39458 424924


Ethanol 00064-17-5 145 10129 146760

2-Methylpropane 00075-28-5 118 5716 67259

n-Hexane 00110-54-3 113 4068 46161


n-Pentane 00109-66-0 121 3154 38314

3-Methylpentane 00096-14-0 169 2555 43201

2-Methyl-2-butene 00513-35-9 1420 2451 347976

t-2-Pentene 00646-04-8 1047 2085 218342

Toluene 00108-88-3 393 2039 80037

23-Dimethylbutane 00079-29-8 090 1831 16453

2-Methyl-1-butene 00563-46-2 638 1510 96290



c-2-Pentene 00627-20-3 1028 1123 115451

Cyclohexane 00110-82-7 114 1042 11856


c-2-Butene 00590-18-1 1426 833 118751

Benzene 00071-43-2 069 781 5423

Propane 00074-98-6 046 619 2830



22-DiMeHexane 00590-73-8 094 513 4827

2-Methylhexane 00591-76-4 109 460 4988

1-Butyne 00107-00-6 605 379 22956

t-2-Hexene 04050-45-7 855 374 31963


t-3-Heptene 14686-14-7 617 351 21645


Cyclopentene 00142-29-0 669 328 21962

3-Methyl-t-2-pentene 00616-12-6 1166 304 35469


2-Methyl-2-pentene 00625-27-4 1103 284 31321



3-Methyl-c-2-pentene 00922-62-3 1252 256 32099


22-Dimethylbutane 00075-83-2 111 222 2468









240

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 5 230 105 2411


Unknown 7 230 082 1885




Unknown 17 230 069 1596


2-Methylheptane 00592-27-8 097 066 0636



n-Propylbenzene 00103-65-1 196 046 0909



n-Nonane 00111-84-2 068 037 0255


ortho-Xylene 00095-47-6 758 027 2080

Unknown 1 230 027 0619


Ethylbenzene 00100-41-4 296 019 0574

c-2-Octene 07642-04-8 230 007 0157

Total 11484 26563 2313


continued


241

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 622650 6705400


Ethanol 00064-17-5 145 124094 1798086

n-Hexane 00110-54-3 113 67518 766114


n-Pentane 00109-66-0 121 46672 567029

3-Methylpentane 00096-14-0 169 41573 702943

2-Methyl-2-butene 00513-35-9 1420 39233 5569075

Toluene 00108-88-3 393 33167 1301796

t-2-Pentene 00646-04-8 1047 32239 3376598

23-Dimethylbutane 00079-29-8 090 29164 262093

2-Methylpropane 00075-28-5 118 23323 274414

2-Methyl-1-butene 00563-46-2 638 22688 1447167



c-2-Pentene 00627-20-3 1028 17645 1814172

Cyclohexane 00110-82-7 114 16882 192015


c-2-Butene 00590-18-1 1426 12775 1821732

Benzene 00071-43-2 069 11664 80988



2-Methylhexane 00591-76-4 109 7254 78719




t-2-Hexene 04050-45-7 855 5835 498847


Cyclopentene 00142-29-0 669 5140 343686

3-Methyl-t-2-pentene 00616-12-6 1166 4795 559045

n-Heptane 00142-82-5 097 4710 45487

2-Methyl-2-pentene 00625-27-4 1103 4548 501761


3-Methyl-c-2-pentene 00922-62-3 1252 4046 506426

22-Dimethylbutane 00075-83-2 111 3825 42506

1-Butyne 00107-00-6 605 3692 223362



Propane 00074-98-6 046 2935 13414


24-Dimethylhexane 00589-43-5 161 2703 43405







242

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 1249 9946



2-Methylheptane 00592-27-8 097 924 8935


3-Methylheptane 00589-81-1 112 747 8400




ortho-Xylene 00095-47-6 758 623 47185



Indan 00496-11-7 323 477 15440



n-Nonane 00111-84-2 068 408 2788

Ethylbenzene 00100-41-4 296 406 12023


n-Propylbenzene 00103-65-1 196 329 6454




Unknown 5 237 273 6466

1-Octene 00111-66-0 314 250 7855

33-Dimethylhexane 00563-16-6 115 231 2665

c-2-Heptene 06443-92-1 708 230 16249

n-Decane 00124-18-5 059 227 1339

t-3-Heptene 14686-14-7 617 214 13214

4-Methyloctane 02216-34-4 085 185 1572

3-Methyloctane 02216-33-3 088 159 1405

14-Diethylbenzene 00105-05-5 439 144 6326

Unknown 3 237 139 3291


1-Heptene 00592-76-7 429 128 5491

Unknown 8 237 120 2850


continued


243

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 22 237 096 2267

13-Butadiene 00106-99-0 1245 092 11436

n-Undecane 01120-21-4 052 084 0439

Unknown 16 237 055 1290

Total 169783 402961 2373


continued


244

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 421885 4543329


Ethanol 00064-17-5 145 63956 926704

n-Hexane 00110-54-3 113 42103 477731


n-Pentane 00109-66-0 121 32695 397223

3-Methylpentane 00096-14-0 169 26461 447417

2-Methyl-2-butene 00513-35-9 1420 26231 3723433

t-2-Pentene 00646-04-8 1047 21783 2281458

23-Dimethylbutane 00079-29-8 090 18965 170438

2-Methyl-1-butene 00563-46-2 638 15351 979200

Toluene 00108-88-3 393 12682 497783


c-2-Pentene 00627-20-3 1028 11853 1218653


2-Methylpropane 00075-28-5 118 9786 115144

Cyclohexane 00110-82-7 114 9561 108746


c-2-Butene 00590-18-1 1426 9027 1287178

Benzene 00071-43-2 069 6124 42524




2-Methylhexane 00591-76-4 109 3992 43324


1-Butyne 00107-00-6 605 3305 199919

Cyclopentene 00142-29-0 669 3296 220392


n-Heptane 00142-82-5 097 2810 27134

2-Methyl-2-pentene 00625-27-4 1103 2648 292135


3-Methyl-t-2-pentene 00616-12-6 1166 2537 295819


22-Dimethylbutane 00075-83-2 111 2430 27002

3-Methyl-c-2-pentene 00922-62-3 1252 2312 289438

t-2-Hexene 04050-45-7 855 2269 193990



24-Dimethylhexane 00589-43-5 161 1392 22345






Total 107832 252202 2339






245

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 6816 73402

n-Hexane 00110-54-3 113 3742 42455


Ethanol 00064-17-5 145 3387 49080

n-Pentane 00109-66-0 121 3097 37631

3-Methylpentane 00096-14-0 169 2395 40491

2-Methyl-2-butene 00513-35-9 1420 2381 337913

t-2-Pentene 00646-04-8 1047 1985 207950

23-Dimethylbutane 00079-29-8 090 1735 15592

Toluene 00108-88-3 393 1702 66802

2-Methyl-1-butene 00563-46-2 638 1455 92799



c-2-Pentene 00627-20-3 1028 1091 112168

Cyclohexane 00110-82-7 114 918 10442


c-2-Butene 00590-18-1 1426 822 117258

Benzene 00071-43-2 069 614 4266



1-Butyne 00107-00-6 605 420 25383

2-Methylpropane 00075-28-5 118 409 4811


2-Methylhexane 00591-76-4 109 397 4310


t-2-Hexene 04050-45-7 855 332 28352

Cyclopentene 00142-29-0 669 320 21388



3-Methyl-t-2-pentene 00616-12-6 1166 278 32432


2-Methyl-2-pentene 00625-27-4 1103 263 28991

n-Heptane 00142-82-5 097 261 2517

3-Methyl-c-2-pentene 00922-62-3 1252 211 26449


22-Dimethylbutane 00075-83-2 111 192 2132











246

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





24-Dimethylhexane 00589-43-5 161 128 2054

Propane 00074-98-6 046 125 0570




n-Octane 00111-65-9 080 098 0779







3-Methylheptane 00589-81-1 112 044 0498

2-Methylheptane 00592-27-8 097 044 0429


ortho-Xylene 00095-47-6 758 035 2631


n-Propylbenzene 00103-65-1 196 031 0598

Ethylbenzene 00100-41-4 296 015 0439

Total 6829 20748 3038


continued


247

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 36810 533364

n-Butane 00106-97-8 108 26480 285167

n-Hexane 00110-54-3 113 21599 245076


n-Pentane 00109-66-0 121 15798 191932

3-Methylpentane 00096-14-0 169 13417 226870

2-Methyl-2-butene 00513-35-9 1420 12566 1783699

t-2-Pentene 00646-04-8 1047 10774 1128460

Toluene 00108-88-3 393 10319 405014

23-Dimethylbutane 00079-29-8 090 9397 84455

2-Methyl-1-butene 00563-46-2 638 7705 491485



c-2-Pentene 00627-20-3 1028 5741 590268

Cyclohexane 00110-82-7 114 5656 64330


c-2-Butene 00590-18-1 1426 4360 621746

Benzene 00071-43-2 069 3722 25841

1-Butyne 00107-00-6 605 3308 200127




2-Methylhexane 00591-76-4 109 2460 26697

2-Methylpropane 00075-28-5 118 2442 28735




t-2-Hexene 04050-45-7 855 1875 160280



Cyclopentene 00142-29-0 669 1630 108972


3-Methyl-t-2-pentene 00616-12-6 1166 1439 167759

2-Methyl-2-pentene 00625-27-4 1103 1392 153551

n-Heptane 00142-82-5 097 1191 11503



3-Methyl-c-2-pentene 00922-62-3 1252 1118 139900

24-Dimethylhexane 00589-43-5 161 1101 17683



22-Dimethylbutane 00075-83-2 111 996 11062





248

Species CAS No MIR

Composite

VOC

mg

Ozone

mg









n-Octane 00111-65-9 080 676 5383



Propane 00074-98-6 046 584 2670


ortho-Xylene 00095-47-6 758 532 40274


n-Propylbenzene 00103-65-1 196 490 9599




3-Methylheptane 00589-81-1 112 429 4820

14-Diethylbenzene 00105-05-5 439 417 18308



2-Methylheptane 00592-27-8 097 275 2658

Indan 00496-11-7 323 271 8760

n-Nonane 00111-84-2 068 254 1733


n-Decane 00124-18-5 059 145 0857

Ethylbenzene 00100-41-4 296 134 3977

Total 38384 118469 3086


continued


249

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 29218 423362

n-Butane 00106-97-8 108 29007 312377

n-Hexane 00110-54-3 113 24380 276633


3-Methylpentane 00096-14-0 169 15596 263709

n-Pentane 00109-66-0 121 15520 188558

2-Methyl-2-butene 00513-35-9 1420 12658 1796850

23-Dimethylbutane 00079-29-8 090 11129 100014

t-2-Pentene 00646-04-8 1047 10500 1099738

Toluene 00108-88-3 393 10002 392585

2-Methyl-1-butene 00563-46-2 638 7489 477698



c-2-Pentene 00627-20-3 1028 5759 592056

Cyclohexane 00110-82-7 114 5744 65330

2-Methylpropane 00075-28-5 118 5722 67323

c-2-Butene 00590-18-1 1426 4971 708857


Benzene 00071-43-2 069 3956 27472

1-Butyne 00107-00-6 605 3534 213821




2-Methylhexane 00591-76-4 109 2413 26182


t-2-Hexene 04050-45-7 855 2057 175842



3-Methyl-t-2-pentene 00616-12-6 1166 1706 198941

Cyclopentene 00142-29-0 669 1599 106896

2-Methyl-2-pentene 00625-27-4 1103 1593 175741


n-Heptane 00142-82-5 097 1492 14408

3-Methyl-c-2-pentene 00922-62-3 1252 1338 167511


22-Dimethylbutane 00075-83-2 111 1217 13527



Propane 00074-98-6 046 992 4536


24-Dimethylhexane 00589-43-5 161 840 13485






250

Species CAS No MIR

Composite

VOC

mg

Ozone

mg












n-Octane 00111-65-9 080 380 3024





3-Methylheptane 00589-81-1 112 287 3222


2-Methylheptane 00592-27-8 097 259 2502

ortho-Xylene 00095-47-6 758 227 17173





Naphthalene 00091-20-3 328 172 5634

Unknown 16 302 169 5123

n-Nonane 00111-84-2 068 152 1040

n-Decane 00124-18-5 059 151 0890

Ethylbenzene 00100-41-4 296 150 4447

Indan 00496-11-7 323 132 4264

n-Propylbenzene 00103-65-1 196 120 2348

4-Methyloctane 02216-34-4 085 118 1002

Unknown 5 302 112 3400


t-3-Heptene 14686-14-7 617 104 6411




14-Diethylbenzene 00105-05-5 439 090 3928

33-Dimethylhexane 00563-16-6 115 083 0954

c-2-Heptene 06443-92-1 708 077 5453

13-Butadiene 00106-99-0 1245 052 6436

Unknown 3 302 036 1101

Total 38356 116460 3036


continued


251

Appendix V ndash Fuel Inspections ndash Previous Programs

E0 E10 E20

Inspection Units Fuel 6 Fuel 7 Fuel 4

API Gravity degAPI 602 585 570

Relative Density 6060degF 07382 07447 07508

DVPE psi 701 730 849

Oxygenates--D4815

MTBE vol 000 000 000

ETBE vol 000 000 000

EtOH vol 000 954 2034

O2 wt 000 353 747

Hydrocarbon Composition

Aromatics vol 221 244 108

Olefins vol 80 88 55

Saturates vol 700 573 234

D86 Distillation

IBP degF 974 1040 1022

5 Evaporated degF 1316 1280 1252











EP degF 3603 3600 3406

Recovery vol 978 978 983

Residue vol 13 10 10

Loss vol 09 12 07

Driveability Index 11199 11015 9898

Data from CRC E-74

CRC E-77-2 Fuel Inspection Results


252

Fuel Units Fuel 6 Fuel 7 Fuel 4

Sulfur Content ppm 29 27 27

Estimated CH Ratio 62090 63323 63252

Est Net Heat of Combustion btulb 18573 18514 18513

Benzene vol 090 100 096

Research Octane Number 932 940 946

Motor Octane Number 838 838 834

(R+M)2 885 889 890





Unclassified vol 115 086 015

Ethanol vol 000 920 2111


CH Ratio 6200 6092 5835

Oxygen wt 0008 1 340 773

Net Heat of Combustion btulb 18703 18016 17160

1 Contains 004 vol MTBE


Oxygen wt 0008 3396 7733

C+H wt 9999 9660 9227

H wt 1389 1362 1350

C wt 8610 8298 7877

Fuel Units 6 7 4

Haltermann D3338 Btulb 18573 18514 18513

Average D3338 Btulb 18579 18514 18491

Oxygen Corrected D3338 Btulb 18579 17860 17103

DHA Btulb 18703 18016 17160

Suppliers Additional Inspections

Net Heat of Combusion -- Btulb

Carbon Hydrogen and Oxygen

Detailed Hydrocarbon Analysis


i

The Coordinating Research Council Inc (CRC) is a non-profit corporation

supported by the petroleum and automotive equipment industries CRC

operates through the committees made up of technical experts from

industry and government who voluntarily participate The four main areas

of research within CRC are air pollution (atmospheric and engineering

studies) aviation fuels lubricants and equipment performance heavy-duty

vehicle fuels lubricants and equipment performance (eg diesel trucks)

and light-duty vehicle fuels lubricants and equipment performance (eg

passenger cars) CRCrsquos function is to provide the mechanism for joint

research conducted by the two industries that will help in determining the

optimum combination of petroleum products and automotive equipment

CRCrsquos work is limited to research that is mutually beneficial to the two

industries involved and all information is available to the public

CRC makes no warranty expressed or implied on the application of

information contained in this report In formulating and approving reports

the appropriate committee of the Coordinating Research Council Inc has

not investigated or considered patents which may apply to the subject

matter Prospective users of the report are responsible for protecting

themselves against liability for infringement of patents


i

Final Report





VEHICLES

CRC E-77-2c

Submitted by

Harold M Haskew PE

Tom Liberty



Milford MI


ii

Table of Contents

Page

Introduction

Background 1


Program Overview

Test Fuels 3

Test Procedures 5























Acknowledgements 37









iii

List of Figures


1 Trap Canister 5























iv

List of Tables


















v

Acronyms
















HC Hydrocarbon























vi

Executive Summary


























Veh Evap Standards















vii






45 plus prior work)













quality modelers



















1




CRC E-77-2c

Introduction












studies





















reg Project No




2






3

Program Overview

Test Fuels





in Appendix V


Haltermann products




MIN MAX

RESULTS


5 ˚F 136

10 ˚F 144

15 ˚F 148

20 ˚F 151

25 ˚F 154

30 ˚F 157

35 ˚F 159

40 ˚F 160

45 ˚F 162

50 ˚F 185 Target only 195 164

55 ˚F 168

60 ˚F 215

65 ˚F 245

70 ˚F 258

75 ˚F 272

80 ˚F 289

85 ˚F 305

90 ˚F 315 325 316

95 ˚F 323




Loss vol Report 05















R+M2 D26992700 870 910 888



4


Haltermann products




MIN MAX

RESULTS


5 ˚F 123

10 ˚F 131

20 ˚F 140

30 ˚F 150

40 ˚F 156

50 ˚F 185 Target only 195 161

60 ˚F 165

70 ˚F 248

80 ˚F 285

90 ˚F 315 325 315

95 ˚F 322




Loss vol Report 14















R+M2 D26992700 870 910 891



5

Test Procedures





















effective


















6

















7

Drain and 40 Fill

with Test Fuel



Drain and 40 Fill

with Test Fuel


Move to SHED


Stabilize at 86degF






Transfer to RL SHED


Stabilize at 86degF



One Hour Hot Soak

Drain and 40 Fill

With Test Fuel



Move to VT-SHED





Drain and 40 Fill

with Next Test Fuel



On Test Fuel


Fuel System


9 psi E20

7 psi E20






8





vehicle




committee
















Table 3













9














yellow shading

Table 4





Fuel Tank

Veh Tank Plastic































E77-2 Program





10



















11










45 plus prior work)









12








0

10

20

30

40

50

60

70


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zer Evap

7

4

77

7

7

6

266

6

6


1

1

0

20

40

60

80

100

120

140


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

4

4

4

4

4

4

22

2

2

22

11



13








202216 See Note 1 7E10 325 00 00 --- --- ---

202216 9E0 178 136 00 --- --- ---

202216 7E0 204 380 00 --- --- ---

202216 9E20 204 00 00 --- --- ---


204 7E10 664 00 00 --- --- ---

204 9E0 338 00 00 --- --- ---

204 7E0 129 00 00 --- --- ---

204 9E20 553 00 00 --- --- ---


205 7E10 596 00 00 --- --- ---

205 9E0 195 00 00 --- --- ---

205 7E0 99 00 00 --- --- ---

205 9E20 462 00 00 --- --- ---


207 7E10 644 00 00 --- --- ---

207 9E0 325 00 00 --- --- ---

207 7E0 401 00 00 --- --- ---

207 9E20 882 00 00 --- --- ---


207L See Note 2 7E10 1468 --- 00 --- --- ---


206b 7E10 1493 00 00 3079 00 00

206b 9E0 611 00 00 1788 00 00

206b 7E0 520 00 00 1181 00 00

206c 9E20 702 00 00 1729 00 00

206c 7E20 938 00 00 2307 00 00


207c See Note 2 7E10 5235 --- 2718 --- --- ---

207c 10E10 2325 --- 10837 --- --- ---

207c 7E10 1448 --- 3727 --- --- ---


208b 7E10 272 00 00 518 00 00

208b 9E0 372 00 00 550 00 91

208b 7E0 248 00 00 645 00 00

208c 9E20 219 00 00 396 00 00

208c 7E20 184 00 00 525 00 00


209b 7E10 286 00 00 541 00 00 E-77-2bc

209b 9E0 234 00 58 295 00 00

209b 7E0 168 19 79 288 00 00

209c 9E20 420 00 00 721 00 00

209c 7E20 235 00 00 411 00 00


220b See Note 3 7E10 504 9122 15724 1820 23090 28945

220b 9E0 1023 23181 28272 18581 35298 51362

220b 7E0 627 13515 16557 2792 22736 30082


221b See Note 4 7E10 227 9307 9710 614 12823 14085

221b 9E0 556 13488 14060 948 16467 17882

221b 7E0 359 9888 9618 668 12159 13438

221c 9E20 265 6165 6734 723 10328 10971

221c 7E20 394 5312 5061 630 7462 7806

Averages


7psi E0 275 7 696 4

9psi E0 376 7 895 4

7psi E10 598 7 1188 4

10psi E10 621 7 1322 4

7psi E20 438 4 968 4

9psi E20 500 7 892 4













Tank Top

Can Inlet


14






211 7E10 94 266 00 --- --- ---

211 9E0 101 00 00 --- --- ---

211 7E0 91 00 00 --- --- ---

211 9E20 558 00 00 --- --- ---


211L See Note 7E10 481 --- 1664 --- --- ---


212 7E10 218 00 00 --- --- ---

212 9E0 32 00 00 --- --- ---

212 7E0 09 00 00 --- --- ---

212 9E20 47 00 00 --- --- ---


214 7E10 239 --- 00 --- --- ---

214 9E0 107 --- 00 --- --- ---

214 7E0 252 --- 00 --- --- ---

214 9E20 168 --- 00 --- --- ---


215 7E10 122 00 00 --- --- ---

215 9E0 85 00 00 --- --- ---

215 7E0 87 00 00 --- --- ---

215 9E20 193 00 00 --- --- ---


210b 7E10 299 00 00 519 00 232

210b 9E0 212 00 40 335 00 48

210b 7E0 187 00 00 355 00 00

210c 9E20 180 00 00 327 00 46

210c 7E20 152 00 00 340 00 00


211c See Note 7E10 4491 --- 2869 --- --- ---

211c 10E10 2247 --- 14727 --- --- ---

211c 7E10 2170 --- 7890 --- --- ---


213b 7E10 296 00 00 822 00 00

213b 9E0 147 00 00 345 00 00

213b 7E0 211 00 00 353 00 00

213c 9E20 298 00 00 751 00 00

213c 7E20 229 00 00 651 00 00

Averages


7psi E0 140 6 354 2

9psi E0 114 6 340 2

7psi E10 211 6 670 2

10psi E10 209 6 884 2

7psi E20 191 2 495 2

9psi E20 241 6 539 2





Tank Top

Can Inlet




222c 7E20 69 00 00 71 00 00 E-77-2bc

Averages


7psi E20 69 1 71 1

9psi E20 92 1 69 1



15












0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

10

5 d

eg

F S

tati

c P

erm

ea

tio

n -

mg

hr



Tier 1

Tier 2

Zero Evap


16











0

50

100

150

200

250

300

350

400

450


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1


0

10

20

30

40

50

60

70

80

90

100


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1



17

Table 7


Veh Eng RL Tru-HS



202216 See Note 1 7E10 1683 192

202216 9E0 1091 254

202216 7E0 787 0

202216 9E20 543 74


204 7E10 2879 297

204 9E0 2492 443

204 7E0 2226 187

204 9E20 2720 134


205 7E10 2328 719

205 9E0 1031 10

205 7E0 671 00

205 9E20 1697 603


207 7E10 8122 1222

207 9E0 8339 58 E-77-2

207 7E0 8425 00

207 9E20 10282 00


207L See Note 2 7E10 11393 5850


206b 7E10 4367 1749

206b 9E0 3656 1025

206b 7E0 2451 688

206c 9E20 3308 858

206c 7E20 5187 1063


207c See Note 2 7E10 27694 5141

207c 10E10 9375 11140

207c 7E10 1146 6102


208b 7E10 2547 773

208b 9E0 2280 379

208b 7E0 1249 750

208c 9E20 2415 269

208c 7E20 2785 205


209b 7E10 2057 245 E-77-2bc

209b 9E0 1444 50

209b 7E0 1662 168

209c 9E20 3671 719

209c 7E20 2560 282


220b See Note 3 7E10 6979 768

220b 9E0 24170 3525

220b 7E0 34473 7071


221b 7E10 1020 405

221b 9E0 1352 290

221b 7E0 1898 425

221c 9E20 1266 95

221c 7E20 619 25

Averages

RL HS Sample

7psi E0 2655 317 7

9psi E0 2942 322 7

7psi E10 3331 773 7

10psi E10 3831 870 7

7psi E20 2788 394 4

9psi E20 3623 382 7






Tank Top

Can Inlet





18

Table 8



Veh Eng RL Tru-HS



211 7E10 563 138

211 9E0 837 153

211 7E0 1046 07

211 9E20 4106 00


211L See Note 7E10 2511 62


212 7E10 2012 00

212 9E0 1158 04

212 7E0 1845 18

212 9E20 1168 49


214 7E10 1057 329

214 9E0 967 521

214 7E0 363 33

214 9E20 1394 56


215 7E10 979 00

215 9E0 811 251

215 7E0 797 225

215 9E20 1025 0


210b 7E10 2183 618

210b 9E0 1711 198

210b 7E0 2160 490

210c 9E20 1943 540

210c 7E20 1246 759


211c See Note 7E10 3418 5894

211c 10E10 153795 19900

211c 7E10 47103 3993


213b 7E10 2431 605

213b 9E0 2031 145

213b 7E0 1351 122

213c 9E20 2572 40

213c 7E20 1869 334

Averages

RL HS Sample

7psi E0 1260 149 6

9psi E0 1253 212 6

7psi E10 1538 282 6

10psi E10 1284 201 6

7psi E20 1558 547 2

9psi E20 2035 198 6




Tank Top

Can Inlet

Veh Eng RL Tru-HS



222c 7E20 683 00 E-77-2bc


19







performance pattern



















0

200

400

600

800

1000

1200

1400

1600


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

9

6

7

2

4

6

7

6

7

6

9

6

11



20







0

500

1000

1500

2000

2500

3000

3500


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

13801

11



21

Table 9


Veh Eng



9E0 4685 --- --- --- E-77


9E0 1504 --- --- ---


202216 See Note 1 7E10 3975 3550 3621 11146

202216 9E0 3270 2667 2746 8683

202216 7E0 2117 2208 2081 6406

202216 9E20 4685 4526 4198 13409


204 7E10 12602 11652 11652 35906

204 9E0 6283 5810 5770 17863

204 7E0 3672 2877 2936 9485

204 9E20 11034 9606 9812 30452


205 7E10 17834 17150 15239 50223

205 9E0 4995 4810 5072 14877 E-77-2

205 7E0 3830 3654 3670 11154

205 9E20 17752 16900 16802 51454


207 7E10 10865 8120 8236 27221

207 9E0 4064 3373 3080 10517

207 7E0 3975 3026 2689 9690

207 9E20 15480 13702 13605 42787


207L See Note 2 7E10 21342 --- --- 21342


206b 7E10 25826 22585 21440 69850

206b 9E0 15000 12856 12508 40364

206b 7E0 11719 9312 8903 29933

206c 9E20 19585 17878 17010 54473

206c 7E20 19439 17081 15677 52197


207c See Note 2 7E10 70847 --- --- ---

207c 10E10 105198 --- --- ---

207c 7E10 70668 --- --- ---


208b 7E10 7806 5104 4494 17405

208b 9E0 7780 5672 5194 18646

208b 7E0 4221 4194 4760 13175

208c 9E20 5065 3632 3319 12015

208c 7E20 5804 4338 3754 13895


209b 7E10 3831 3491 3235 10557

209b 9E0 3278 2505 2243 8026

209b 7E0 3541 2497 2181 8219

209c 9E20 4564 3383 3160 11107

209c 7E20 5877 3465 2704 12046


220b See Note 3 7E10 11776 16121 14831 42728

220b 9E0 67333 58848 70499 196680

220b 7E0 62187 62147 70419 194753


221b 7E10 8947 6767 6180 21894

221b 9E0 7064 5437 5383 17884

221b 7E0 6030 5031 4870 15932

221c 9E20 7508 5847 5649 19004

221c 7E20 8172 5442 4988 18602

Averages


7psi E0 4675 9 13941 7

9psi E0 6072 9 18311 7

7psi E10 12530 7 33294 7

10psi E10 13833 7 138015 7

7psi E20 9823 4 24185 4

9psi E20 11570 7 31613 7










Day 1 Total

Tank Top

Can Inlet


22

Table 10



Veh Eng



211 7E10 2438 1838 1843 6119

211 9E0 1303 1158 1006 3467

211 7E0 2071 1002 874 3947

211 9E20 2850 2218 2034 7101


211L See Note 7E10 6783 --- --- 6783


212 7E10 1848 1002 758 3608

212 9E0 1005 708 574 2287

212 7E0 1016 712 570 2298

212 9E20 1310 833 750 2893


214 7E10 5242 3974 3944 13160

214 9E0 4559 3585 11017 19161

214 7E0 4943 3190 2815 10948

214 9E20 4709 4400 7518 16627


215 7E10 2247 2317 2675 7239

215 9E0 2021 1659 1763 5443

215 7E0 2483 2941 2888 8312

215 9E20 4168 4148 4506 12822


210b 7E10 4451 3883 3591 11925

210b 9E0 4078 3774 3583 11434

210b 7E0 2706 2666 2211 7583

210c 9E20 3523 2749 2977 9250

210c 7E20 3686 2836 2711 9233


213b 7E10 6028 5777 5889 17694

213b 9E0 3463 3284 2928 9675

213b 7E0 3578 2833 2765 9175

213c 9E20 6442 5293 4606 16342

213c 7E20 5019 5384 5461 15864

Averages


7psi E0 2799 6 7044 6

9psi E0 2738 6 8578 6

7psi E10 3709 6 9957 6

10psi E10 4016 6 29741 6

7psi E20 4352 2 12549 2

9psi E20 3833 6 10839 6


Day 1 Total



Veh Eng



222c 9E20 736 514 401 1651 E-77-2bc



23

Summary of Task 45














24

















emissions











12





25






from this test13



Table 11



1996 Cavalier

Test fuel Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)
















13


increase


26




27

Table 12




Test fuel

Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

2001 Dodge Caravan E10 109 213 104

2004 Toyota Camry E10 024 068 044











canister























28

















29






30









0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Pe

rme

ati

on

-m

gh

r

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10 psi E10 Fuel

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



7 psi E10 Fuel


31





0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel


32

Summary of Task 47


quality modelers

























This selected






14





33

Table 13

















Vehicle 206c

Type 72DHB

Test 7703


Net mass Net conc


1 Methane 00074-82-8 0000 0000 0 0

2 Ethylene 00074-85-1 1984 0066 0 0


4 Ethane 00074-84-0 0000 0000 0 0

5 Propene 00115-07-1 0000 0000 0 0

6 Propane 00074-98-6 24285 0770 0 0


8 Propyne 00074-99-7 0000 0000 0 0

9 2-Methylpropane 00075-28-5 101164 3244 2 2


11 13-Butadiene 00106-99-0 0428 0015 0 0

12 n-Butane 00106-97-8 320071 10262 6 6


14 t-2-Butene 00624-64-6 0000 0000 0 0

15 1-Butyne 00107-00-6 0000 0000 0 0

16 c-2-Butene 00590-18-1 30919 1027 1 1

17 3-Methyl-1-butene 00563-45-1 0000 0000 0 0



20 2-Methyl-1-butene 00563-46-2 62754 2084 1 1

21 n-Pentane 00109-66-0 335100 10819 6 7


23 t-2-Pentene 00646-04-8 162601 5400 3 3

24 33-Dimethyl-1-butene 00558-37-2 0000 0000 0 0

25 c-2-Pentene 00627-20-3 76704 2547 1 2

26 2-Methyl-2-butene 00513-35-9 152719 5071 3 3

72DHB

total


34




Table 14



4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


Species CAS No MIR

Composite VOC mg

Ozone mg




35




























compound)
















36





Table 15













previously thought

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


37

Acknowledgements











Steering Committee













David Lax API












38






test


39


Vehicle 206c

Reactivity Results





206c 90E20 Static (86) Perm 091509 7685 702 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 091609 7689 1729 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 091709 25795 3308 020

True HS 858 010

72 DHB 65-105 092909 7703

Day 1 19585 000

Day 2 17878 150

Day 3 17010 1000

70E20 Static (86) Perm 101309 7724 938 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 101409 7727 2307 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 102109 25806 5187 000

True HS 1063 000

72 DHB 65-105 111709 7779

Day 1 19439 000

Day 2 17081 020

Day 3 15677 080

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


40

0

20

40

60

80

100

120

140

160

180

200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7685

7 psi E20 - 7724

0

50

100

150

200

250

300

350

400

450

500

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7689

7 psi E20 - 7727


41

0

100

200

300

400

500

600

700

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25795

7 psi E20 - 25806


0

1000

2000

3000

4000

5000

6000

7000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7703

7 psi E20 - 7779


42


Vehicle 208c

Reactivity Results





208c 90E20 Static (86) Perm 092209 7695 219 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092309 7699 396 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 092409 25798 2415 000

True HS 269 000

72 DHB 65-105 100609 7713

Day 1 5065 000

Day 2 3632 000

Day 3 3319 000

70E20 Static (86) Perm 110309 7750 184 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110409 7755 525 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110509 25812 2785 000

True HS 205 000

72 DHB 65-105 120809 7817

Day 1 5804 000

Day 2 4338 000

Day 3 3754 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

Vehicle 208c


43

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7695

7 psi E20 - 7750

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7699

7 psi E20 - 7755


44

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25798

7 psi E20 - 25812


0

200

400

600

800

1000

1200

1400

1600

1800

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7713

7 psi E20 - 7817


45


Vehicle 209c

Reactivity Results





209c 90E20 Static (86) Perm 100109 7708 420 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 100209 7710 721 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 100509 25802 3671 000

True HS 719 000

72 DHB 65-105 110309 7753

Day 1 4564 020

Day 2 3383 030

Day 3 3160 090

70E20 Static (86) Perm 120209 7806 235 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 120309 7809 411 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 120409 25819 2560 000

True HS 282 000

72 DHB 65-105 011210 7856

Day 1 6107 000

Day 2 3160 010

Day 3 2581 040

72 DHB 65-105 020910 7881

Day 1 5647 000

Day 2 3771 000

Day 3 2827 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90

Vehicle 209c


46

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7708

7 psi E20 - 7806

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7710

7 psi E20 - 7809


47

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25802

7 psi E20 - 25819


0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7753

7 psi E20 - 7856



48


Vehicles 210c

Reactivity Results





210c 90E20 Static (86) Perm 092409 7701 180 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092509 7702 327 000

Press Incr 00

Prs+Fuel Incr 46

Dynamic RL 092809 25799 1943 000

True HS 540 000

72 DHB 65-105 101309 7725

Day 1 3523 030

Day 2 2749 160

Day 3 2977 700

70E20 Static (86) Perm 110509 7758 152 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110609 7761 340 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110909 25813 1246 000

True HS 759 000

72 DHB 65-105 121509 7826

Day 1 3686 050

Day 2 2836 070

Day 3 2711 120

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


49

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7701

7 psi E20 - 7758

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7702

7 psi E20 - 7761


50

0

50

100

150

200

250

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25799

7 psi E20 - 25813


0

200

400

600

800

1000

1200

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7725

7 psi E20 - 7826


51


Vehicle 213c

Reactivity Results





213c 90E20 Static (86) Perm 100809 7718 374 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 102909 7746 751 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 111309 25816 2572 082

True HS 40 005

72 DHB 65-105 120109 7803

Day 1 6442 000

Day 2 5293 000

Day 3 4606 000

70E20 Static (86) Perm 121609 7828 229 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 121709 7830 651 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 121809 25821 1869 000

True HS 334 000

72 DHB 65-105 020210 7872

Day 1 5019 000

Day 2 5384 000

Day 3 5461 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


52

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7744

7 psi E20 - 7828

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7746

7 psi E20 - 7830


53

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25816

7 psi E20 - 25821


0

200

400

600

800

1000

1200

1400

1600

1800

2000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7803

7 psi E20 - 7872


54


Vehicle 221c

Reactivity Results





221c 90E20 Static (86) Perm 122409 7840 265 000

Press Incr 6165

Prs+Fuel Incr 6734

Static (105) Perm 122309 7838 723 000

Press Incr 10328

Prs+Fuel Incr 10971

Dynamic RL 122809 25824 1266 000

True HS 95 000

72 DHB 65-105 011910 7859

Day 1 7508 040

Day 2 5847 150

Day 3 5649 400

70E20 Static (86) Perm 020410 7875 394 000

Press Incr 5312

Prs+Fuel Incr 5061

Static (105) Perm 020510 7877 630 000

Press Incr 7462

Prs+Fuel Incr 7806

Dynamic RL 020810 25828 619 000

True HS 25 000

72 DHB 65-105 030210 7906

Day 1 8172 000

Day 2 5442 000

Day 3 4988 070

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


55

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7840

7 psi E20 - 7875

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7838

7 psi E20 - 7877


56

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25824

7 psi E20 - 25828


0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7859

7 psi E20 - 7906


57


Vehicle 222c

Reactivity Results








222c 90E20 Static (86) Perm 122909 7843 92 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 123009 7847 69 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 011510 25827 447 000

True HS 76 000

72 DHB 65-105 020210 7871

Day 1 736 000

Day 2 514 000

Day 3 401 040

70E20 Static (86) Perm 022510 7898 69 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 022610 7901 71 000

Press Incr 00

Prs+Fuel Incr 00

72 DHB 65-105 030910 7916

Day 1 655 000

Day 2 427 030

Day 3 395 030

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


58

0

2

4

6

8

10

12

14

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7843

7 psi E20 - 7898

0

2

4

6

8

10

12

14

16

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7847

7 psi E20 - 7901


59

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25827

7 psi E20 -25830


0

50

100

150

200

250

300

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7871

7 psi E20 - 7916


60








61


Vehicle 207c

Reactivity Results





207c 100E10 Static Perm 082709 7661 6102 000


Dynamic RL 102009 25805 9997 000


24 DHB 65-105 090309 7672

Tank Top (020)

65125 000

70E10 Static Perm 091809 7693 5235 000


Dynamic RL 100209 25801 27694 000


24 DHB 65-105 102709 7741

Tank Top (020) 70847 000

100E10 Static Perm 111809 7781 2325 000


Dynamic RL 111909 25817 9375 000


24 DHB 65-105 112409 7794

Can Inlet (020) 105198 000

70E10 Static Perm 120909 7819 1448 000


Dynamic RL 121009 25820 11146 000


24 DHB 65-105 122909 7844

Can Inlet (020) 70668 000


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


62

0

200

400

600

800

1000

1200

1400

1600

1800

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7661

7 psi E10 - 7693

0

100

200

300

400

500

600

700

800

900

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7781

7 psi E10 - 7819


63

0

500

1000

1500

2000

2500

3000

3500

4000

4500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25805

7 psi E10 - 25801


0

500

1000

1500

2000

2500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25817

7 psi E10 - 25820



64

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7672

7 psi E10 - 7741

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7794

7 psi E10 - 7844


65


Vehicle 211c

Reactivity Results





211c 100E10 Static Perm 081209 7636 1925 000


Dynamic RL 081309 25788 8204 000


24 DHB 65-105 081909 7648

Tank Top (020) 89107 3560

70E10 Static Perm 090209 7669 4491 000


Dynamic RL 090309 25793 3418 000


24 DHB 65-105 091009 7681

Tank Top (020) 28842 000

100E10 Static Perm 101909 7732 2247 000


Dynamic RL 102909 25809 153795 000


24 DHB 65-105 111109 7769

Can Inlet (020) 115481 550

70E10 Static (86) Perm 112409 7793 2170 000


Dynamic RL 112509 25818 47103 082



Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


66

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7636

7 psi E10 - 7669

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7732

7 psi E10 - 7793


67

0

500

1000

1500

2000

2500

3000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25788

7 psi E10 - 25793


0

2000

4000

6000

8000

10000

12000

14000

16000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25809

7 psi E10 - 25818



68

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7648

7 psi E10 - 7681

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7769

7 psi E10 - 7836


69









1 Permeation













16




70












unit time

























17





Determination


71





permeation rate






concentrations





















3 Hot Soak19


described above




19





72






4 Diurnal Test



















retest is indicated







73


EXCELrsquoscopy














0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

SH

ED

Mass -

mg

Test Time - minutes



Test 7710

Pump Activated




Tank Pressurized

Slope = 705 mghr

Slope = 706 mghr

Slope = 761 mghr



74

























real-time records


75

















road speed






20






Loss SHED SHEDSHED


76



















period






0

10

20

30

40

50

60

70

80


Spe

ed -

mph








77






permeation












0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100 120

Co

rre

cte

d T

ota

l Fu

el C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


Test 25802



2936 mg

3793 mg

3356 mg

True HS = 437 mghr


Results


78

Diurnal Test








milligrams)




two SAE papers






















12







79







and 18th





















80







81

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


82

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4093 59307

Toluene 00108-88-3 393 1167 45800


n-Pentane 00109-66-0 121 648 7871


n-Butane 00106-97-8 108 607 6533

Cyclohexane 00110-82-7 114 552 6281


Benzene 00071-43-2 069 528 3668

Propane 00074-98-6 046 424 1938

t-2-Pentene 00646-04-8 1047 399 41785

n-Heptane 00142-82-5 097 378 3649


n-Hexane 00110-54-3 113 371 4207


2-Methyl-2-butene 00513-35-9 1420 284 40369



c-2-Pentene 00627-20-3 1028 188 19331



3-Methylpentane 00096-14-0 169 170 2882

2-Methyl-1-butene 00563-46-2 638 160 10232

2-Methylpropane 00075-28-5 118 152 1783



ortho-Xylene 00095-47-6 758 133 10090

2-Methylhexane 00591-76-4 109 119 1287

n-Octane 00111-65-9 080 113 0900

t-2-Hexene 04050-45-7 855 109 9344

n-Propylbenzene 00103-65-1 196 089 1748


23-Dimethylbutane 00079-29-8 090 080 0716

Cyclopentene 00142-29-0 669 076 5114

3-Methyl-c-2-pentene 00922-62-3 1252 073 9169






3-Methyl-t-2-pentene 00616-12-6 1166 064 7473

2-Methyl-2-pentene 00625-27-4 1103 064 7008

3-Methylheptane 00589-81-1 112 061 0683

c-2-Butene 00590-18-1 1426 059 8461




83

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








2-Methylheptane 00592-27-8 097 044 0430





Ethylbenzene 00100-41-4 296 028 0831



24-Dimethylhexane 00589-43-5 161 014 0230

22-Dimethylbutane 00075-83-2 111 013 0147

n-Undecane 01120-21-4 052 003 0017

Total 1620 5411 3340


continued


84

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7732 112029

Toluene 00108-88-3 393 2826 110931


n-Pentane 00109-66-0 121 1669 20279

n-Butane 00106-97-8 108 1531 16491


Benzene 00071-43-2 069 1317 9145


n-Hexane 00110-54-3 113 984 11164

n-Heptane 00142-82-5 097 955 9227

t-2-Pentene 00646-04-8 1047 867 90854



2-Methyl-2-butene 00513-35-9 1420 764 108513

22-DiMeHexane 00590-73-8 094 648 6097

3-Me-1-Hexene 03404-61-3 427 597 25518


2-Methylpropane 00075-28-5 118 483 5687


3-Methylpentane 00096-14-0 169 423 7157

c-2-Pentene 00627-20-3 1028 398 40907

2-Methyl-1-butene 00563-46-2 638 389 24834


Propane 00074-98-6 046 301 1376

ortho-Xylene 00095-47-6 758 277 21014

n-Octane 00111-65-9 080 263 2092



t-2-Hexene 04050-45-7 855 232 19857



23-Dimethylbutane 00079-29-8 090 188 1693

2-Methylhexane 00591-76-4 109 184 1996

c-2-Butene 00590-18-1 1426 177 25239


Ethylbenzene 00100-41-4 296 169 5008


n-Propylbenzene 00103-65-1 196 159 3125

3-Methyl-t-2-pentene 00616-12-6 1166 154 17969

Cyclopentene 00142-29-0 669 132 8836

Cyclopentane 00287-92-3 224 132 2955

2-Methylheptane 00592-27-8 097 126 1223

3-Methyl-c-2-pentene 00922-62-3 1252 120 14989





85

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 112 12354



3-Methylheptane 00589-81-1 112 094 1061









24-Dimethylhexane 00589-43-5 161 057 0919

4-Methyloctane 02216-34-4 085 053 0449

22-Dimethylbutane 00075-83-2 111 051 0570


Unknown 1 340 047 1585




3-Methyloctane 02216-33-3 088 038 0337

n-Nonane 00111-84-2 068 035 0239





Total 3466 11867 3424


continued


86

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7327 106160

Toluene 00108-88-3 393 3583 140646


n-Heptane 00142-82-5 097 1994 19258



3-Me-1-Hexene 03404-61-3 427 1676 71615

Benzene 00071-43-2 069 1585 11004

n-Pentane 00109-66-0 121 1566 19031

n-Butane 00106-97-8 108 1325 14268

n-Hexane 00110-54-3 113 1227 13926



22-DiMeHexane 00590-73-8 094 1009 9495



2-Methyl-2-butene 00513-35-9 1420 747 105970

t-2-Pentene 00646-04-8 1047 620 64956


3-Methylpentane 00096-14-0 169 504 8518


Indan 00496-11-7 323 491 15896



Unknown 16 362 481 17425


c-2-Pentene 00627-20-3 1028 439 45108


2-Methylpropane 00075-28-5 118 426 5010

n-Octane 00111-65-9 080 421 3351

2-Methyl-1-butene 00563-46-2 638 400 25494

ortho-Xylene 00095-47-6 758 365 27632

Ethylbenzene 00100-41-4 296 362 10735

2-Methylheptane 00592-27-8 097 360 3479

3-Methylheptane 00589-81-1 112 308 3463



2-Methylhexane 00591-76-4 109 256 2775


23-Dimethylbutane 00079-29-8 090 243 2181


Unknown 22 362 215 7784






87

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




n-Nonane 00111-84-2 068 189 1293


n-Propylbenzene 00103-65-1 196 187 3660

Cyclopentene 00142-29-0 669 181 12085

3-Methyl-t-2-pentene 00616-12-6 1166 177 20606

3-Methyl-c-2-pentene 00922-62-3 1252 163 20443







14-Diethylbenzene 00105-05-5 439 117 5152

c-2-Butene 00590-18-1 1426 115 16375



t-2-Hexene 04050-45-7 855 107 9180

22-Dimethylbutane 00075-83-2 111 103 1150

2-Methyl-2-pentene 00625-27-4 1103 096 10613

4-Methyl-t-2-pentene 00674-76-0 804 094 7554


n-Decane 00124-18-5 059 072 0424


Unknown 1 362 044 1580

Total 4582 17092 3730


continued


88

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 101748 1474297


n-Pentane 00109-66-0 121 33510 407124

n-Butane 00106-97-8 108 32007 344688

Toluene 00108-88-3 393 27947 1096913


Benzene 00071-43-2 069 20586 142938

n-Hexane 00110-54-3 113 18393 208697

n-Heptane 00142-82-5 097 17284 166926

t-2-Pentene 00646-04-8 1047 16260 1702998

2-Methyl-2-butene 00513-35-9 1420 15272 2167853


3-Me-1-Hexene 03404-61-3 427 10391 444084

2-Methylpropane 00075-28-5 118 10116 119030


22-DiMeHexane 00590-73-8 094 8200 77181


c-2-Pentene 00627-20-3 1028 7670 788622

3-Methylpentane 00096-14-0 169 7668 129648

2-Methyl-1-butene 00563-46-2 638 6275 400280


t-2-Hexene 04050-45-7 855 4165 356031

2-Methylhexane 00591-76-4 109 3643 39538




n-Octane 00111-65-9 080 3249 25870


c-2-Butene 00590-18-1 1426 3092 440893


23-Dimethylbutane 00079-29-8 090 2952 26532

Cyclopentene 00142-29-0 669 2922 195335

3-Methyl-t-2-pentene 00616-12-6 1166 2669 311214

Cyclopentane 00287-92-3 224 2540 56827

Propane 00074-98-6 046 2428 11101

3-Methyl-c-2-pentene 00922-62-3 1252 2277 285007


2-Methyl-2-pentene 00625-27-4 1103 1964 216725




ortho-Xylene 00095-47-6 758 1425 107970






89

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 1271 12292

Ethylbenzene 00100-41-4 296 1237 36651

22-Dimethylbutane 00075-83-2 111 1166 12955



3-Methylheptane 00589-81-1 112 1021 11484




n-Propylbenzene 00103-65-1 196 817 16017





n-Nonane 00111-84-2 068 489 3336

Unknown 1 333 488 16281



4-Methyloctane 02216-34-4 085 329 2788



3-Methyloctane 02216-33-3 088 287 2536



33-Dimethylhexane 00563-16-6 115 214 2470

Ethylene 00074-85-1 888 198 17628


1-Octene 00111-66-0 314 170 5347

c-2-Heptene 06443-92-1 708 147 10435

Unknown 8 333 147 4886


Unknown 5 333 132 4386

1-Nonene 00124-11-8 249 122 3031

Unknown 6 333 121 4021

Unknown 16 333 120 4008

Unknown 9 333 118 3924



Indan 00496-11-7 323 104 3374

Styrene 00100-42-5 166 095 1585


continued


90

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 3 333 072 2404


n-Decane 00124-18-5 059 067 0395



Unknown 14 333 055 1850

1-Heptene 00592-76-7 429 051 2194

13-Butadiene 00106-99-0 1245 043 5325


4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


continued


91

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2884 41793


Toluene 00108-88-3 393 1217 47766

Benzene 00071-43-2 069 747 5186




n-Pentane 00109-66-0 121 684 8305

n-Butane 00106-97-8 108 611 6584



n-Hexane 00110-54-3 113 498 5652


n-Heptane 00142-82-5 097 475 4583

Propane 00074-98-6 046 468 2137



2-Methyl-2-butene 00513-35-9 1420 356 50602

t-2-Pentene 00646-04-8 1047 347 36348

ortho-Xylene 00095-47-6 758 323 24490


c-2-Butene 00590-18-1 1426 312 44524



n-Octane 00111-65-9 080 289 2300

n-Propylbenzene 00103-65-1 196 272 5339

Cyclohexane 00110-82-7 114 267 3042

2-Methylhexane 00591-76-4 109 267 2898

23-Dimethylbutane 00079-29-8 090 259 2328

Ethylbenzene 00100-41-4 296 228 6765

t-2-Hexene 04050-45-7 855 227 19378




Cyclopentane 00287-92-3 224 167 3744


3-Methyl-t-2-pentene 00616-12-6 1166 154 17932

2-Methyl-1-butene 00563-46-2 638 150 9546

3-Methyl-c-2-pentene 00922-62-3 1252 146 18246

Cyclopentene 00142-29-0 669 145 9721

2-Methylheptane 00592-27-8 097 144 1394


c-2-Pentene 00627-20-3 1028 135 13873





92

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 131 1478


3-Methylpentane 00096-14-0 169 123 2086


2-Methyl-2-pentene 00625-27-4 1103 122 13422

24-Dimethylhexane 00589-43-5 161 103 1653

Indan 00496-11-7 323 087 2810

22-Dimethylbutane 00075-83-2 111 086 0952

n-Nonane 00111-84-2 068 085 0583












14-Diethylbenzene 00105-05-5 439 045 1982


4-Methyloctane 02216-34-4 085 043 0366

4-Methyl-t-2-pentene 00674-76-0 804 041 3322

Unknown 1 412 034 1408


2-Methylpropane 00075-28-5 118 029 0340

n-Undecane 01120-21-4 052 029 0150





3-Methyloctane 02216-33-3 088 020 0174

Total 2183 9104 4170


continued


93

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10102 146374

Toluene 00108-88-3 393 4080 160133

3-Methylnonane 05911-04-6 066 3338 21890




n-Pentane 00109-66-0 121 2300 27949

Benzene 00071-43-2 069 2108 14635


n-Butane 00106-97-8 108 2075 22348

n-Heptane 00142-82-5 097 1777 17164

n-Hexane 00110-54-3 113 1565 17760


t-2-Pentene 00646-04-8 1047 1024 107279

2-Methyl-2-butene 00513-35-9 1420 1009 143288

Cyclohexane 00110-82-7 114 926 10529





3-Methylpentane 00096-14-0 169 568 9606

c-2-Pentene 00627-20-3 1028 498 51245

2-Methyl-1-butene 00563-46-2 638 495 31574



n-Octane 00111-65-9 080 454 3615



ortho-Xylene 00095-47-6 758 403 30538

2-Methylhexane 00591-76-4 109 350 3798

n-Propylbenzene 00103-65-1 196 345 6759

Ethylbenzene 00100-41-4 296 312 9251

t-2-Hexene 04050-45-7 855 307 26270

2-Methylpropane 00075-28-5 118 262 3081

Cyclopentane 00287-92-3 224 250 5589


Cyclopentene 00142-29-0 669 211 14108

Propane 00074-98-6 046 192 0880

3-Methyl-t-2-pentene 00616-12-6 1166 192 22393

n-Nonane 00111-84-2 068 186 1270


23-Dimethylbutane 00079-29-8 090 179 1613






94

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 153 19093

2-Methyl-2-pentene 00625-27-4 1103 141 15538


24-Dimethylhexane 00589-43-5 161 132 2114


2-Methylheptane 00592-27-8 097 128 1233

4-Methyloctane 02216-34-4 085 125 1064

c-2-Butene 00590-18-1 1426 121 17277



3-Methylheptane 00589-81-1 112 109 1223

Indan 00496-11-7 323 104 3361





n-Decane 00124-18-5 059 065 0385



3-Methyloctane 02216-33-3 088 061 0539

13-Diethylbenzene 00141-93-5 708 056 3990




Unknown 1 330 049 1606

22-Dimethylbutane 00075-83-2 111 049 0540


n-Undecane 01120-21-4 052 043 0226

c-2-Heptene 06443-92-1 708 038 2676



Unknown 8 330 025 0836

066 Total 5472 18251 3335


continued


95

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10462 151590

Toluene 00108-88-3 393 5022 197121






n-Heptane 00142-82-5 097 2541 24542

n-Pentane 00109-66-0 121 2430 29518

Benzene 00071-43-2 069 2379 16519

n-Butane 00106-97-8 108 2172 23395

n-Hexane 00110-54-3 113 1979 22456



Cyclohexane 00110-82-7 114 1349 15348




2-Methyl-2-butene 00513-35-9 1420 940 133406

t-2-Pentene 00646-04-8 1047 857 89767

n-Octane 00111-65-9 080 856 6816



3-Methylpentane 00096-14-0 169 706 11929

n-Propylbenzene 00103-65-1 196 696 13630

2-Methyl-1-butene 00563-46-2 638 655 41772


Propane 00074-98-6 046 515 2355

ortho-Xylene 00095-47-6 758 506 38317

Ethylbenzene 00100-41-4 296 497 14716

3-Methylheptane 00589-81-1 112 480 5394

c-2-Pentene 00627-20-3 1028 476 48903

2-Methylhexane 00591-76-4 109 425 4611

2-Methylpropane 00075-28-5 118 404 4753

3-Methyl-c-2-pentene 00922-62-3 1252 401 50144



t-2-Hexene 04050-45-7 855 369 31567

n-Nonane 00111-84-2 068 355 2423

2-Methyl-2-pentene 00625-27-4 1103 349 38516


Cyclopentane 00287-92-3 224 322 7198

2-Methylheptane 00592-27-8 097 317 3071

c-2-Butene 00590-18-1 1426 292 41607




96

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 22 363 272 9893


3-Methyl-t-2-pentene 00616-12-6 1166 269 31312

Methane 00074-82-8 001 265 0037


3-Methyloctane 02216-33-3 088 255 2252






Cyclopentene 00142-29-0 669 208 13880

4-Methyloctane 02216-34-4 085 199 1691


23-Dimethylbutane 00079-29-8 090 188 1688

n-Decane 00124-18-5 059 168 0994


Indan 00496-11-7 323 160 5191



Unknown 18 363 147 5331

c-2-Heptene 06443-92-1 708 137 9666



24-Dimethylhexane 00589-43-5 161 123 1980




22-Dimethylbutane 00075-83-2 111 038 0418

Total 7165 26481 3696


continued


97

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 115502 1673600



n-Butane 00106-97-8 108 26699 287520

n-Pentane 00109-66-0 121 26567 322768

Toluene 00108-88-3 393 23849 936067

n-Heptane 00142-82-5 097 21212 204862

n-Hexane 00110-54-3 113 18520 210141

Benzene 00071-43-2 069 17238 119691



Cyclohexane 00110-82-7 114 9320 106002

t-2-Pentene 00646-04-8 1047 9137 956959

2-Methyl-2-butene 00513-35-9 1420 9120 1294599



3-Methylpentane 00096-14-0 169 6866 116094


c-2-Pentene 00627-20-3 1028 4504 463080


n-Octane 00111-65-9 080 4099 32639

2-Methyl-1-butene 00563-46-2 638 3977 253652


2-Methylhexane 00591-76-4 109 3789 41114



23-Dimethylbutane 00079-29-8 090 2988 26852

t-2-Hexene 04050-45-7 855 2686 229656

Cyclopentane 00287-92-3 224 2314 51777


Propane 00074-98-6 046 2085 9531



2-Methylpropane 00075-28-5 118 1854 21813

Cyclopentene 00142-29-0 669 1830 122352

3-Methyl-t-2-pentene 00616-12-6 1166 1808 210844



2-Methylheptane 00592-27-8 097 1688 16323

3-Methyl-c-2-pentene 00922-62-3 1252 1584 198290

c-2-Butene 00590-18-1 1426 1517 216368



2-Methyl-2-pentene 00625-27-4 1103 1493 164767




98

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 1325 14903

24-Dimethylhexane 00589-43-5 161 1322 21223

ortho-Xylene 00095-47-6 758 1234 93462

Ethylbenzene 00100-41-4 296 1170 34667




n-Propylbenzene 00103-65-1 196 978 19157


22-Dimethylbutane 00075-83-2 111 889 9880


n-Nonane 00111-84-2 068 734 5008




c-2-Heptene 06443-92-1 708 629 44542





4-Methyloctane 02216-34-4 085 439 3726



3-Methyloctane 02216-33-3 088 311 2751

Unknown 1 291 281 8158

33-Dimethylhexane 00563-16-6 115 274 3158


Ethylene 00074-85-1 888 238 21141

1-Octene 00111-66-0 314 226 7093

Unknown 5 291 226 6565




1-Butyne 00107-00-6 605 214 12957


Unknown 8 291 191 5566


1-Nonene 00124-11-8 249 155 3876

Indan 00496-11-7 323 134 4328




continued


99

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 291 093 2704

t-4-Octene 14850-23-8 469 088 4141



n-Decane 00124-18-5 059 072 0424


Unknown 6 291 063 1842

t-3-Heptene 14686-14-7 617 058 3603

Unknown 3 291 050 1460

13-Butadiene 00106-99-0 1245 050 6187

c- amp t-4-Nonene 02198-23-4 442 039 1719


1-Heptene 00592-76-7 429 035 1513

n-Undecane 01120-21-4 052 025 0130


Total 48454 142309 2937



100

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

- No Ethanol

Vehicle 208c


101

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


3-Me-1-Hexene 03404-61-3 427 193 8262

Toluene 00108-88-3 393 158 6219


n-Heptane 00142-82-5 097 146 1414


22-DiMeHexane 00590-73-8 094 136 1277

n-Pentane 00109-66-0 121 131 1597



Benzene 00071-43-2 069 109 0753

n-Butane 00106-97-8 108 101 1090

n-Octane 00111-65-9 080 058 0466

n-Hexane 00110-54-3 113 054 0613

2-Methylheptane 00592-27-8 097 048 0466

2-Methylpropane 00075-28-5 118 047 0553


n-Nonane 00111-84-2 068 041 0277

n-Propylbenzene 00103-65-1 196 033 0656

2-Methyl-2-pentene 00625-27-4 1103 032 3544

ortho-Xylene 00095-47-6 758 030 2297


3-Methyl-c-2-pentene 00922-62-3 1252 026 3231



Cyclopentene 00142-29-0 669 022 1454



t-2-Hexene 04050-45-7 855 018 1569

3-Methyl-t-2-pentene 00616-12-6 1166 018 2140

Ethylbenzene 00100-41-4 296 018 0544

t-2-Pentene 00646-04-8 1047 018 1912

3-Methylpentane 00096-14-0 169 018 0298



2-Methylhexane 00591-76-4 109 015 0159

24-Dimethylhexane 00589-43-5 161 013 0203

2-Methyl-2-butene 00513-35-9 1420 011 1589

c-2-Butene 00590-18-1 1426 009 1344



Total 260 956 3672




102

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1745 25291


n-Heptane 00142-82-5 097 769 7424


Benzene 00071-43-2 069 594 4125

Toluene 00108-88-3 393 461 18075

n-Pentane 00109-66-0 121 365 4438


n-Hexane 00110-54-3 113 287 3251

n-Butane 00106-97-8 108 273 2945



22-DiMeHexane 00590-73-8 094 172 1616

2-Methyl-2-butene 00513-35-9 1420 170 24078

3-Me-1-Hexene 03404-61-3 427 156 6681


t-2-Pentene 00646-04-8 1047 139 14606



Cyclopentane 00287-92-3 224 118 2649

n-Octane 00111-65-9 080 108 0863

3-Methylpentane 00096-14-0 169 108 1823


2-Methylpropane 00075-28-5 118 094 1110



c-2-Pentene 00627-20-3 1028 085 8778

3-Methylheptane 00589-81-1 112 085 0956

n-Nonane 00111-84-2 068 084 0576


3-Methyl-t-2-pentene 00616-12-6 1166 078 9114


2-Methyl-1-butene 00563-46-2 638 056 3594

c-2-Butene 00590-18-1 1426 055 7872

ortho-Xylene 00095-47-6 758 051 3872



t-2-Hexene 04050-45-7 855 043 3697


Ethylbenzene 00100-41-4 296 036 1067


Cyclopentene 00142-29-0 669 029 1922






103

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 023 2569


3-Methyl-c-2-pentene 00922-62-3 1252 022 2706



22-Dimethylbutane 00075-83-2 111 010 0117




2-Methylhexane 00591-76-4 109 003 0037



Total 962 2919 3034


continued


104

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 964 37835

t-3-Heptene 14686-14-7 617 854 52708


n-Pentane 00109-66-0 121 709 8608

Benzene 00071-43-2 069 649 4509




3-Me-1-Hexene 03404-61-3 427 425 18160


22-DiMeHexane 00590-73-8 094 403 3797





4-Methyl-t-2-pentene 00674-76-0 804 349 28047

n-Butane 00106-97-8 108 347 3739

n-Hexane 00110-54-3 113 346 3922

n-Propylbenzene 00103-65-1 196 335 6568

n-Octane 00111-65-9 080 327 2601

3-Methylpentane 00096-14-0 169 304 5148


2-Methylhexane 00591-76-4 109 290 3146

n-Butylbenzene 00104-51-8 229 279 6386


Indan 00496-11-7 323 272 8810

t-2-Pentene 00646-04-8 1047 264 27657

Ethylbenzene 00100-41-4 296 257 7618





2-Methyl-2-butene 00513-35-9 1420 223 31617


2-Methyl-1-butene 00563-46-2 638 193 12303


n-Nonane 00111-84-2 068 187 1276


c-2-Pentene 00627-20-3 1028 156 16054

t-2-Hexene 04050-45-7 855 154 13191

ortho-Xylene 00095-47-6 758 148 11239




105

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



13-Butadiene 00106-99-0 1245 145 18006



2-Methylheptane 00592-27-8 097 134 1296


23-Dimethylbutane 00079-29-8 090 128 1152

4-Methyloctane 02216-34-4 085 127 1079

Unknown 5 422 113 4773





2-Methylpropane 00075-28-5 118 097 1147

Unknown 9 422 092 3896

3-Methyl-t-2-pentene 00616-12-6 1166 076 8865

3-Methyl-c-2-pentene 00922-62-3 1252 074 9238


Cyclopentene 00142-29-0 669 065 4325


14-Diethylbenzene 00105-05-5 439 059 2575

24-Dimethylhexane 00589-43-5 161 052 0828

3-Methyloctane 02216-33-3 088 048 0425





22-Dimethylbutane 00075-83-2 111 009 0104

Total 2199 9732 4426


continued


106

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 40269 583488


n-Pentane 00109-66-0 121 6604 80237

n-Butane 00106-97-8 108 5757 61995


n-Heptane 00142-82-5 097 5013 48416

n-Hexane 00110-54-3 113 4359 49459

Toluene 00108-88-3 393 4128 162007


Benzene 00071-43-2 069 3151 21876


2-Methyl-2-butene 00513-35-9 1420 2458 348891

t-2-Pentene 00646-04-8 1047 2391 250449

2-Methylpropane 00075-28-5 118 2367 27847

Cyclohexane 00110-82-7 114 2317 26356


3-Methylpentane 00096-14-0 169 1942 32835



n-Octane 00111-65-9 080 1226 9760

c-2-Pentene 00627-20-3 1028 1186 121926


2-Methyl-1-butene 00563-46-2 638 1163 74158

2-Methylhexane 00591-76-4 109 1119 12144


t-2-Hexene 04050-45-7 855 759 64866

23-Dimethylbutane 00079-29-8 090 700 6289



2-Methylheptane 00592-27-8 097 569 5503

c-2-Butene 00590-18-1 1426 562 80095

Propane 00074-98-6 046 552 2525

Cyclopentane 00287-92-3 224 552 12353


3-Methyl-t-2-pentene 00616-12-6 1166 518 60429

3-Methylheptane 00589-81-1 112 482 5422

Cyclopentene 00142-29-0 669 479 32026

3-Methyl-c-2-pentene 00922-62-3 1252 469 58697



2-Methyl-2-pentene 00625-27-4 1103 422 46577







107

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Nonane 00111-84-2 068 349 2384

1-Butyne 00107-00-6 605 349 21088





24-Dimethylhexane 00589-43-5 161 299 4801

22-Dimethylbutane 00075-83-2 111 291 3238


ortho-Xylene 00095-47-6 758 271 20538

n-Propylbenzene 00103-65-1 196 263 5151

Ethylbenzene 00100-41-4 296 238 7052



4-Methyloctane 02216-34-4 085 223 1894




3-Methyloctane 02216-33-3 088 154 1363




33-Dimethylhexane 00563-16-6 115 109 1252

Unknown 8 276 087 2398



1-Octene 00111-66-0 314 081 2559


continued


108

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 276 066 1835

Unknown 1 276 065 1794





n-Decane 00124-18-5 059 049 0289

Unknown 5 276 045 1243

c-2-Heptene 06443-92-1 708 040 2835



1-Nonene 00124-11-8 249 019 0476

Total 12981 36292 2796


continued


109

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1522 22047

Toluene 00108-88-3 393 372 14601




n-Butane 00106-97-8 108 252 2718

n-Pentane 00109-66-0 121 229 2778


n-Undecane 01120-21-4 052 208 1088

n-Decane 00124-18-5 059 202 1193

n-Heptane 00142-82-5 097 197 1903

n-Hexane 00110-54-3 113 145 1643

1-Butyne 00107-00-6 605 142 8563

Benzene 00071-43-2 069 136 0943

Cyclohexane 00110-82-7 114 117 1336







3-Methylpentane 00096-14-0 169 077 1305


2-Methylpropane 00075-28-5 118 075 0882

n-Nonane 00111-84-2 068 072 0492

n-Propylbenzene 00103-65-1 196 070 1366



2-Methyl-2-butene 00513-35-9 1420 068 9604

23-Dimethylbutane 00079-29-8 090 061 0546

n-Octane 00111-65-9 080 060 0475


Cyclopentene 00142-29-0 669 054 3587



t-2-Pentene 00646-04-8 1047 046 4844

ortho-Xylene 00095-47-6 758 044 3308

3-Methyl-c-2-pentene 00922-62-3 1252 043 5429

2-Methylheptane 00592-27-8 097 042 0408

3-Methyl-t-2-pentene 00616-12-6 1166 042 4901


2-Methyl-2-pentene 00625-27-4 1103 039 4343


3-Methylheptane 00589-81-1 112 033 0371




110

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 030 3052


Unknown 22 305 027 0835

2-Methylhexane 00591-76-4 109 027 0296


Ethylbenzene 00100-41-4 296 024 0697

24-Dimethylhexane 00589-43-5 161 022 0354




22-Dimethylbutane 00075-83-2 111 011 0126

2-Methyl-1-butene 00563-46-2 638 006 0396


Total 691 2138 3094


continued


111

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1871 27109


Toluene 00108-88-3 393 522 20484


n-Heptane 00142-82-5 097 365 3521

n-Pentane 00109-66-0 121 351 4259

n-Butane 00106-97-8 108 298 3214







Benzene 00071-43-2 069 198 1372

n-Hexane 00110-54-3 113 173 1961



t-2-Pentene 00646-04-8 1047 126 13202

n-Octane 00111-65-9 080 116 0924

2-Methyl-2-butene 00513-35-9 1420 115 16378

Cyclohexane 00110-82-7 114 108 1232


3-Methylpentane 00096-14-0 169 101 1707

2-Methylpropane 00075-28-5 118 075 0884

2-Methylhexane 00591-76-4 109 059 0643

ortho-Xylene 00095-47-6 758 054 4058

2-Methyl-1-butene 00563-46-2 638 053 3361

c-2-Pentene 00627-20-3 1028 043 4388


066 Total 755 2232 2957




112

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 968 37976


n-Pentane 00109-66-0 121 522 6345

n-Heptane 00142-82-5 097 514 4964

Benzene 00071-43-2 069 512 3553





n-Propylbenzene 00103-65-1 196 434 8506




n-Octane 00111-65-9 080 341 2712

n-Hexane 00110-54-3 113 275 3123

n-Nonane 00111-84-2 068 271 1848

13-Butadiene 00106-99-0 1245 247 30791




2-Methylheptane 00592-27-8 097 231 2232

2-Methyl-1-butene 00563-46-2 638 227 14471

c-2-Pentene 00627-20-3 1028 221 22769

n-Butane 00106-97-8 108 194 2085

24-Dimethylhexane 00589-43-5 161 183 2939


Cyclohexane 00110-82-7 114 162 1841


23-Dimethylbutane 00079-29-8 090 150 1345

n-Decane 00124-18-5 059 136 0802


3-Methylpentane 00096-14-0 169 131 2214

2-Methylhexane 00591-76-4 109 104 1128


t-2-Pentene 00646-04-8 1047 070 7355

22-Dimethylbutane 00075-83-2 111 066 0737

3-Methylheptane 00589-81-1 112 066 0741

2-Methyl-2-butene 00513-35-9 1420 059 8434



Ethylbenzene 00100-41-4 296 053 1559




113

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylpropane 00075-28-5 118 022 0260

Total 1666 7311 4389

continued


114

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 42028 608972



n-Heptane 00142-82-5 097 6080 58717

n-Pentane 00109-66-0 121 5160 62696

n-Butane 00106-97-8 108 4881 52569

Toluene 00108-88-3 393 4149 162857

n-Hexane 00110-54-3 113 4113 46667



Benzene 00071-43-2 069 2652 18416


Cyclohexane 00110-82-7 114 2309 26264


3-Methylpentane 00096-14-0 169 1806 30534

n-Octane 00111-65-9 080 1490 11863

2-Methyl-2-butene 00513-35-9 1420 1455 206582

t-2-Pentene 00646-04-8 1047 1430 149744



2-Methylhexane 00591-76-4 109 1276 13844


23-Dimethylbutane 00079-29-8 090 950 8542

2-Methylpropane 00075-28-5 118 905 10645



2-Methyl-1-butene 00563-46-2 638 764 48753

2-Methylheptane 00592-27-8 097 757 7321


c-2-Pentene 00627-20-3 1028 717 73741


3-Methylheptane 00589-81-1 112 591 6648


24-Dimethylhexane 00589-43-5 161 559 8975

t-2-Hexene 04050-45-7 855 500 42751



c-2-Heptene 06443-92-1 708 474 33563



Cyclopentane 00287-92-3 224 382 8551

n-Nonane 00111-84-2 068 368 2512

3-Methyl-c-2-pentene 00922-62-3 1252 366 45829





115

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methyl-t-2-pentene 00616-12-6 1166 347 40413


1-Butyne 00107-00-6 605 314 18981

c-2-Butene 00590-18-1 1426 313 44686


2-Methyl-2-pentene 00625-27-4 1103 298 32930




4-Methyloctane 02216-34-4 085 268 2273

ortho-Xylene 00095-47-6 758 263 19906



Cyclopentene 00142-29-0 669 246 16475

22-Dimethylbutane 00075-83-2 111 235 2609

Propane 00074-98-6 046 234 1071

3-Methyloctane 02216-33-3 088 226 1997

Ethylbenzene 00100-41-4 296 225 6680



n-Propylbenzene 00103-65-1 196 212 4148



33-Dimethylhexane 00563-16-6 115 179 2055





Unknown 8 246 139 3407



continued


116

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



1-Octene 00111-66-0 314 105 3295

Unknown 9 246 086 2117

Unknown 5 246 083 2051





n-Decane 00124-18-5 059 045 0268

1-Nonene 00124-11-8 249 044 1105

Unknown 1 246 032 0778

Total 13019 32482 2495


continued


117

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41 No Ethanol

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90 Repeat

Vehicle 209c


118

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 608 23884

n-Pentane 00109-66-0 121 532 6465

n-Butane 00106-97-8 108 526 5664




n-Hexane 00110-54-3 113 360 4086

Cyclohexane 00110-82-7 114 358 4074

n-Heptane 00142-82-5 097 324 3130


Benzene 00071-43-2 069 227 1573


2-Methyl-2-butene 00513-35-9 1420 214 30383



t-2-Pentene 00646-04-8 1047 199 20808

3-Methylpentane 00096-14-0 169 189 3189



23-Dimethylbutane 00079-29-8 090 134 1208

Ethanol 00064-17-5 145 131 1905


2-Methyl-1-butene 00563-46-2 638 118 7543

Propane 00074-98-6 046 116 0530

2-Methylpropane 00075-28-5 118 112 1317

c-2-Pentene 00627-20-3 1028 110 11307


2-Methylhexane 00591-76-4 109 097 1052

n-Nonane 00111-84-2 068 091 0619

c-2-Butene 00590-18-1 1426 083 11886



n-Propylbenzene 00103-65-1 196 076 1487


n-Octane 00111-65-9 080 066 0525

3-Methylheptane 00589-81-1 112 064 0714


ortho-Xylene 00095-47-6 758 062 4660

t-2-Hexene 04050-45-7 855 057 4874


2-Methyl-2-pentene 00625-27-4 1103 055 6035





119

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 053 0852

3-Methyl-c-2-pentene 00922-62-3 1252 051 6343



3-Methyl-t-2-pentene 00616-12-6 1166 046 5371

Cyclopentene 00142-29-0 669 043 2842



22-Dimethylbutane 00075-83-2 111 035 0390


4-Methyloctane 02216-34-4 085 034 0288




2-Methylheptane 00592-27-8 097 024 0234

Unknown 18 334 023 0782


Indan 00496-11-7 323 020 0636

Ethylbenzene 00100-41-4 296 019 0563

Total 1036 3549 3427


continued


120

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2428 35179


Toluene 00108-88-3 393 689 27059

Cyclohexane 00110-82-7 114 575 6535

n-Pentane 00109-66-0 121 549 6667

n-Butane 00106-97-8 108 465 5009

n-Hexane 00110-54-3 113 438 4971



22-DiMeHexane 00590-73-8 094 335 3152

n-Heptane 00142-82-5 097 311 3006


3-Methylpentane 00096-14-0 169 242 4093

Benzene 00071-43-2 069 227 1575


2-Methyl-2-butene 00513-35-9 1420 197 27914




23-Dimethylbutane 00079-29-8 090 166 1491

2-Methylpropane 00075-28-5 118 149 1756

2-Methylhexane 00591-76-4 109 147 1599

t-2-Pentene 00646-04-8 1047 146 15283




c-2-Pentene 00627-20-3 1028 097 10021

n-Octane 00111-65-9 080 097 0776

Propane 00074-98-6 046 096 0439

n-Nonane 00111-84-2 068 088 0601

2-Methyl-1-butene 00563-46-2 638 082 5199

Indan 00496-11-7 323 078 2534


3-Methylheptane 00589-81-1 112 076 0853


4-Methyloctane 02216-34-4 085 065 0551

ortho-Xylene 00095-47-6 758 065 4918

Unknown 16 271 065 1756





n-Propylbenzene 00103-65-1 196 053 1040

t-2-Hexene 04050-45-7 855 052 4414




121

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 038 0607

Cyclopentene 00142-29-0 669 038 2517


22-Dimethylbutane 00075-83-2 111 037 0408

3-Methyl-t-2-pentene 00616-12-6 1166 036 4207

Ethylbenzene 00100-41-4 296 036 1052




2-Methyl-2-pentene 00625-27-4 1103 033 3675

2-Methylheptane 00592-27-8 097 033 0322

c-2-Butene 00590-18-1 1426 031 4470

3-Methyl-c-2-pentene 00922-62-3 1252 024 3058





Total 1212 3351 2765


continued


122

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 3555 51515

Toluene 00108-88-3 393 2025 79500


3-Me-1-Hexene 03404-61-3 427 1750 74813

n-Heptane 00142-82-5 097 1537 14840



n-Pentane 00109-66-0 121 1178 14313

n-Butane 00106-97-8 108 1174 12645

n-Hexane 00110-54-3 113 1158 13138



22-DiMeHexane 00590-73-8 094 1026 9657





Benzene 00071-43-2 069 791 5491

Propane 00074-98-6 046 552 2523

3-Methylpentane 00096-14-0 169 535 9054



2-Methyl-2-butene 00513-35-9 1420 457 64841

Ethylene 00074-85-1 888 454 40295


2-Methyl-1-butene 00563-46-2 638 448 28551

t-2-Pentene 00646-04-8 1047 448 46880

n-Octane 00111-65-9 080 421 3348


2-Methylpropane 00075-28-5 118 413 4861


c-2-Pentene 00627-20-3 1028 349 35872

n-Propylbenzene 00103-65-1 196 346 6786


2-Methylhexane 00591-76-4 109 331 3591

23-Dimethylbutane 00079-29-8 090 320 2879


ortho-Xylene 00095-47-6 758 312 23613

24-Dimethylhexane 00589-43-5 161 278 4460


2-Methylheptane 00592-27-8 097 265 2568

Ethylbenzene 00100-41-4 296 262 7748

t-2-Hexene 04050-45-7 855 257 21978




123

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







3-Methylheptane 00589-81-1 112 216 2430

2-Methyl-2-pentene 00625-27-4 1103 212 23431

3-Methyl-t-2-pentene 00616-12-6 1166 199 23199

n-Nonane 00111-84-2 068 189 1292

3-Methyl-c-2-pentene 00922-62-3 1252 188 23507




Cyclopentene 00142-29-0 669 120 8051

c-2-Butene 00590-18-1 1426 096 13745



22-Dimethylbutane 00075-83-2 111 085 0940

13-Butadiene 00106-99-0 1245 070 8700


Total 3712 13832 3726


continued


124

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 41433 600356


n-Butane 00106-97-8 108 4042 43529

n-Pentane 00109-66-0 121 3798 46147


Toluene 00108-88-3 393 2636 103457

n-Heptane 00142-82-5 097 2629 25385

n-Hexane 00110-54-3 113 2488 28227


Cyclohexane 00110-82-7 114 1943 22094

Benzene 00071-43-2 069 1923 13349


t-2-Pentene 00646-04-8 1047 1424 149160

2-Methyl-2-butene 00513-35-9 1420 1420 201503


3-Methylpentane 00096-14-0 169 1237 20924


2-Methylpropane 00075-28-5 118 1107 13030

2-Methyl-1-butene 00563-46-2 638 764 48704

c-2-Pentene 00627-20-3 1028 735 75531



n-Octane 00111-65-9 080 674 5365

2-Methylhexane 00591-76-4 109 654 7101



Propane 00074-98-6 046 473 2162

23-Dimethylbutane 00079-29-8 090 451 4053

t-2-Hexene 04050-45-7 855 451 38530

2-Methylheptane 00592-27-8 097 363 3510

Cyclopentane 00287-92-3 224 346 7753

3-Methyl-t-2-pentene 00616-12-6 1166 328 38296


Cyclopentene 00142-29-0 669 296 19762

3-Methylheptane 00589-81-1 112 290 3262

3-Methyl-c-2-pentene 00922-62-3 1252 283 35472

2-Methyl-2-pentene 00625-27-4 1103 279 30766



24-Dimethylhexane 00589-43-5 161 259 4160


22-Dimethylbutane 00075-83-2 111 253 2816





125

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





c-2-Butene 00590-18-1 1426 238 33979





1-Butyne 00107-00-6 605 187 11337



n-Propylbenzene 00103-65-1 196 154 3020

Ethylbenzene 00100-41-4 296 152 4489

4-Methyloctane 02216-34-4 085 149 1267


3-Methyloctane 02216-33-3 088 118 1048


33-Dimethylhexane 00563-16-6 115 113 1300


n-Nonane 00111-84-2 068 112 0762



Unknown 22 249 085 2128


1-Octene 00111-66-0 314 084 2649



Unknown 8 249 077 1927


Unknown 5 249 068 1695

Unknown 6 249 061 1521





4-Methyl-t-2-pentene 00674-76-0 804 055 4393

Unknown 1 249 054 1355

continued


126

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 9 249 048 1203



ortho-Xylene 00095-47-6 758 035 2639



1-Nonene 00124-11-8 249 031 0771

c-2-Heptene 06443-92-1 708 030 2119


Total 9741 24571 2522


continued


127

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2031 29422



Toluene 00108-88-3 393 213 8360

n-Heptane 00142-82-5 097 164 1581

22-DiMeHexane 00590-73-8 094 162 1525




n-Butane 00106-97-8 108 113 1221


Benzene 00071-43-2 069 090 0625

n-Octane 00111-65-9 080 087 0696


n-Pentane 00109-66-0 121 083 1008

Cyclohexane 00110-82-7 114 078 0887


n-Nonane 00111-84-2 068 068 0466




n-Hexane 00110-54-3 113 061 0693

n-Propylbenzene 00103-65-1 196 060 1176

4-Methyloctane 02216-34-4 085 059 0501


2-Methyl-1-butene 00563-46-2 638 056 3568


t-2-Pentene 00646-04-8 1047 051 5304

3-Methyl-c-2-pentene 00922-62-3 1252 048 6030


ortho-Xylene 00095-47-6 758 044 3371


n-Decane 00124-18-5 059 042 0246

1-Butyne 00107-00-6 605 038 2301


2-Methyl-2-butene 00513-35-9 1420 035 4931

23-Dimethylbutane 00079-29-8 090 031 0274



c-2-Pentene 00627-20-3 1028 026 2664

t-2-Hexene 04050-45-7 855 026 2206

2-Methylhexane 00591-76-4 109 026 0279

Ethylbenzene 00100-41-4 296 024 0713




128

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-t-2-pentene 00616-12-6 1166 021 2407

2-Methylheptane 00592-27-8 097 020 0198

3-Methylpentane 00096-14-0 169 020 0337


Cyclopentene 00142-29-0 669 016 1071


3-Methylheptane 00589-81-1 112 010 0108



n-Undecane 01120-21-4 052 003 0017

Total 554 1818 3284


continued


129

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2491 36089


Toluene 00108-88-3 393 351 13795


n-Heptane 00142-82-5 097 246 2378




n-Pentane 00109-66-0 121 181 2205

n-Butane 00106-97-8 108 173 1860

Benzene 00071-43-2 069 159 1107


n-Hexane 00110-54-3 113 128 1449

Propane 00074-98-6 046 123 0563



Cyclohexane 00110-82-7 114 117 1330



3-Methylheptane 00589-81-1 112 081 0911

n-Octane 00111-65-9 080 076 0603

3-Methylpentane 00096-14-0 169 075 1266


t-2-Pentene 00646-04-8 1047 069 7273


n-Propylbenzene 00103-65-1 196 066 1300

2-Methyl-2-pentene 00625-27-4 1103 066 7278


2-Methyl-2-butene 00513-35-9 1420 058 8241

23-Dimethylbutane 00079-29-8 090 056 0505

Ethylbenzene 00100-41-4 296 053 1576

c-2-Heptene 06443-92-1 708 053 3746

4-Methyloctane 02216-34-4 085 053 0449



Unknown 22 299 050 1489


2-Methyl-1-butene 00563-46-2 638 046 2905

2-Methylheptane 00592-27-8 097 045 0434

n-Nonane 00111-84-2 068 044 0300


24-Dimethylhexane 00589-43-5 161 042 0669

2-Methylhexane 00591-76-4 109 039 0424




130

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 039 3979

t-2-Hexene 04050-45-7 855 038 3270


3-Methyl-t-2-pentene 00616-12-6 1166 036 4201

ortho-Xylene 00095-47-6 758 034 2597

c-2-Butene 00590-18-1 1426 034 4788



3-Methyl-c-2-pentene 00922-62-3 1252 030 3747




Cyclopentene 00142-29-0 669 022 1479




22-Dimethylbutane 00075-83-2 111 012 0136

066 Total 786 2397 3050


continued


131

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-DiMeHexane 00590-73-8 094 551 5189

Cyclohexane 00110-82-7 114 550 6259

n-Heptane 00142-82-5 097 503 4856




n-Nonane 00111-84-2 068 399 2724

Ethylene 00074-85-1 888 383 33991


n-Octane 00111-65-9 080 331 2635



Benzene 00071-43-2 069 241 1673

Unknown 22 492 232 11393



3-Methyl-t-2-pentene 00616-12-6 1166 194 22609


Cyclopentene 00142-29-0 669 153 10213




3-Methyl-c-2-pentene 00922-62-3 1252 115 14432

n-Propylbenzene 00103-65-1 196 114 2239

2-Methylheptane 00592-27-8 097 110 1067



Toluene 00108-88-3 393 089 3513

Naphthalene 00091-20-3 328 087 2863

t-2-Hexene 04050-45-7 855 084 7168


3-Methylpentane 00096-14-0 169 070 1179

ortho-Xylene 00095-47-6 758 052 3918


2-Methylhexane 00591-76-4 109 032 0348

Ethylbenzene 00100-41-4 296 018 0548


2-Methyl-2-butene 00513-35-9 1420 005 0770

Total 1074 5493 5117





132

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35670 516847



n-Heptane 00142-82-5 097 3662 35368

n-Butane 00106-97-8 108 3505 37747

Toluene 00108-88-3 393 3492 137050

n-Pentane 00109-66-0 121 3304 40146


n-Hexane 00110-54-3 113 2599 29485



Cyclohexane 00110-82-7 114 1925 21900


Benzene 00071-43-2 069 1738 12068



n-Octane 00111-65-9 080 1569 12491


2-Methylpropane 00075-28-5 118 1256 14781

3-Methylpentane 00096-14-0 169 1206 20398

2-Methyl-2-butene 00513-35-9 1420 1074 152444

23-Dimethylbutane 00079-29-8 090 1069 9609

t-2-Pentene 00646-04-8 1047 1043 109271


2-Methylhexane 00591-76-4 109 864 9372



2-Methylheptane 00592-27-8 097 787 7608


Propane 00074-98-6 046 757 3460

3-Methylheptane 00589-81-1 112 717 8059



n-Nonane 00111-84-2 068 656 4479



c-2-Pentene 00627-20-3 1028 547 56249

24-Dimethylhexane 00589-43-5 161 521 8366

2-Methyl-1-butene 00563-46-2 638 520 33173

4-Methyloctane 02216-34-4 085 502 4255

n-Propylbenzene 00103-65-1 196 453 8879

ortho-Xylene 00095-47-6 758 450 34122

c-2-Heptene 06443-92-1 708 445 31484





133

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






3-Methyloctane 02216-33-3 088 360 3186

t-2-Hexene 04050-45-7 855 339 28984

Ethylbenzene 00100-41-4 296 338 10013

22-Dimethylbutane 00075-83-2 111 326 3618



3-Methyl-t-2-pentene 00616-12-6 1166 269 31374




2-Methyl-2-pentene 00625-27-4 1103 258 28420

Unknown 8 252 242 6098

3-Methyl-c-2-pentene 00922-62-3 1252 236 29551


c-2-Butene 00590-18-1 1426 227 32333


Cyclopentene 00142-29-0 669 218 14591

1-Nonene 00124-11-8 249 212 5282

Unknown 16 252 209 5253



Unknown 9 252 172 4332

1-Octene 00111-66-0 314 161 5055


33-Dimethylhexane 00563-16-6 115 156 1793


n-Decane 00124-18-5 059 141 0832

continued


134

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Indan 00496-11-7 323 126 4071




Unknown 5 252 108 2722

t-4-Octene 14850-23-8 469 092 4292



Unknown 10 252 074 1873




22-Dimethyloctane 15869-87-1 076 049 0367

n-Undecane 01120-21-4 052 044 0229

c-2-Octene 07642-04-8 252 024 0605

Total 11102 28561 2573


continued


135

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 39128 566956



n-Heptane 00142-82-5 097 4118 39773

Toluene 00108-88-3 393 4052 159045

n-Butane 00106-97-8 108 3621 38994

n-Pentane 00109-66-0 121 3567 43335

n-Hexane 00110-54-3 113 3196 36265



Cyclohexane 00110-82-7 114 2313 26313


Benzene 00071-43-2 069 2021 14034


n-Octane 00111-65-9 080 1766 14063



3-Methylpentane 00096-14-0 169 1600 27048



23-Dimethylbutane 00079-29-8 090 1186 10659

2-Methylhexane 00591-76-4 109 1076 11672

2-Methyl-2-butene 00513-35-9 1420 1032 146518

t-2-Pentene 00646-04-8 1047 991 103774



Propane 00074-98-6 046 919 4201

2-Methylpropane 00075-28-5 118 876 10302



2-Methylheptane 00592-27-8 097 759 7340

3-Methylheptane 00589-81-1 112 683 7684

n-Nonane 00111-84-2 068 677 4621



24-Dimethylhexane 00589-43-5 161 607 9741


2-Methyl-1-butene 00563-46-2 638 575 36672


4-Methyloctane 02216-34-4 085 547 4637


c-2-Pentene 00627-20-3 1028 523 53797





136

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Heptene 06443-92-1 708 419 29626

3-Methyl-c-2-pentene 00922-62-3 1252 379 47426

ortho-Xylene 00095-47-6 758 368 27850



n-Propylbenzene 00103-65-1 196 350 6856

3-Methyloctane 02216-33-3 088 339 3003


t-2-Hexene 04050-45-7 855 329 28138


c-2-Butene 00590-18-1 1426 290 41290

n-Decane 00124-18-5 059 284 1680


Ethylbenzene 00100-41-4 296 279 8257


2-Methyl-2-pentene 00625-27-4 1103 272 29956

3-Methyl-t-2-pentene 00616-12-6 1166 264 30830

Unknown 16 247 252 6216


Unknown 8 247 236 5829


Cyclopentene 00142-29-0 669 225 15030






1-Nonene 00124-11-8 249 194 4832

22-Dimethylbutane 00075-83-2 111 192 2134


1-Octene 00111-66-0 314 162 5092

continued


137

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






Unknown 9 247 147 3619

t-4-Octene 14850-23-8 469 146 6841

33-Dimethylhexane 00563-16-6 115 146 1676


Unknown 5 247 140 3451


Indan 00496-11-7 323 086 2776

n-Undecane 01120-21-4 052 081 0423



22-Dimethyloctane 15869-87-1 076 048 0361

Unknown 1 247 043 1059


Total 12111 30488 2517


continued


138

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


139

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 213 8377

n-Pentane 00109-66-0 121 209 2533

n-Butane 00106-97-8 108 195 2100


n-Heptane 00142-82-5 097 146 1407



2-Methylpropane 00075-28-5 118 119 1401

n-Hexane 00110-54-3 113 119 1345

Cyclohexane 00110-82-7 114 115 1310

Benzene 00071-43-2 069 108 0747

Unknown 23 313 105 3279


t-2-Pentene 00646-04-8 1047 103 10759

n-Octane 00111-65-9 080 096 0765

3-Methylheptane 00589-81-1 112 093 1050

2-Methyl-2-butene 00513-35-9 1420 088 12443



3-Methylpentane 00096-14-0 169 081 1375


4-Methyloctane 02216-34-4 085 074 0632




c-2-Pentene 00627-20-3 1028 060 6196



t-2-Hexene 04050-45-7 855 055 4697

2-Methylhexane 00591-76-4 109 052 0565

2-Methyl-1-butene 00563-46-2 638 045 2839

2-Methylheptane 00592-27-8 097 043 0418




n-Nonane 00111-84-2 068 036 0249

n-Decane 00124-18-5 059 036 0213

n-Propylbenzene 00103-65-1 196 034 0658


3-Methyl-t-2-pentene 00616-12-6 1166 032 3705

22-Dimethyloctane 15869-87-1 076 030 0227






140

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Ethylbenzene 00100-41-4 296 027 0810

2-Methyl-2-pentene 00625-27-4 1103 026 2921

t-4-Octene 14850-23-8 469 026 1220

23-Dimethylbutane 00079-29-8 090 026 0231


ortho-Xylene 00095-47-6 758 025 1927

4-Methyl-t-2-pentene 00674-76-0 804 025 2022

c-2-Heptene 06443-92-1 708 025 1752

3-Methyl-c-2-pentene 00922-62-3 1252 023 2817


1-Butyne 00107-00-6 605 022 1304






Cyclopentene 00142-29-0 669 016 1068


Unknown 20 313 013 0398


22-Dimethylbutane 00075-83-2 111 010 0109



24-Dimethylhexane 00589-43-5 161 009 0138

Unknown 14 313 008 0265

Total 499 1646 3297


continued


141

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1583 22942


Toluene 00108-88-3 393 612 24017

n-Pentane 00109-66-0 121 486 5903

n-Butane 00106-97-8 108 481 5181

n-Heptane 00142-82-5 097 334 3229





n-Hexane 00110-54-3 113 272 3083

Benzene 00071-43-2 069 268 1861

Cyclohexane 00110-82-7 114 242 2757


2-Methylheptane 00592-27-8 097 200 1932



t-2-Pentene 00646-04-8 1047 171 17927

2-Methylpropane 00075-28-5 118 169 1990

2-Methyl-2-butene 00513-35-9 1420 166 23544

3-Methylpentane 00096-14-0 169 154 2608


c-2-Pentene 00627-20-3 1028 139 14324

2-Methyl-1-butene 00563-46-2 638 135 8633





3-Methyl-c-2-pentene 00922-62-3 1252 096 11960


23-Dimethylbutane 00079-29-8 090 094 0843

3-Methylheptane 00589-81-1 112 090 1017

t-2-Hexene 04050-45-7 855 083 7126


Ethylbenzene 00100-41-4 296 078 2298

n-Octane 00111-65-9 080 076 0607

ortho-Xylene 00095-47-6 758 076 5752


2-Methylhexane 00591-76-4 109 069 0746

2-Methyl-2-pentene 00625-27-4 1103 069 7570

n-Nonane 00111-84-2 068 068 0463

3-Methyl-t-2-pentene 00616-12-6 1166 066 7701






142

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 057 0908

c-2-Butene 00590-18-1 1426 056 7952


n-Propylbenzene 00103-65-1 196 047 0917

Cyclopentene 00142-29-0 669 044 2973




22-Dimethylbutane 00075-83-2 111 035 0385




Total 1098 3753 3417


continued


143

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Cyclohexane 00110-82-7 114 830 9437


Toluene 00108-88-3 393 735 28842

n-Pentane 00109-66-0 121 635 7720

n-Butane 00106-97-8 108 605 6519


n-Heptane 00142-82-5 097 582 5618

Benzene 00071-43-2 069 579 4019







3-Methylpentane 00096-14-0 169 400 6755

n-Propylbenzene 00103-65-1 196 372 7293

2-Methylhexane 00591-76-4 109 361 3923

n-Octane 00111-65-9 080 359 2859

Unknown 22 382 315 12033

n-Hexane 00110-54-3 113 299 3392


t-2-Butene 00624-64-6 1520 280 42605

4-Methyl-t-2-pentene 00674-76-0 804 264 21197

n-Decane 00124-18-5 059 241 1427



Cyclopentene 00142-29-0 669 218 14592



Propane 00074-98-6 046 193 0881

ortho-Xylene 00095-47-6 758 177 13425

24-Dimethylhexane 00589-43-5 161 168 2703



Ethylbenzene 00100-41-4 296 162 4786

2-Methyl-2-butene 00513-35-9 1420 160 22779


4-Methyloctane 02216-34-4 085 145 1233


t-2-Hexene 04050-45-7 855 134 11491





144

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylbutane 00079-29-8 090 132 1189

2-Methyl-2-pentene 00625-27-4 1103 129 14259



n-Nonane 00111-84-2 068 120 0820

22-Dimethylbutane 00075-83-2 111 115 1278

2-Methylheptane 00592-27-8 097 114 1105

3-Methylheptane 00589-81-1 112 109 1224

3-Methyl-t-2-pentene 00616-12-6 1166 096 11152




2-Methyl-1-butene 00563-46-2 638 080 5118

3-Methyl-c-2-pentene 00922-62-3 1252 080 10031

Unknown 18 382 072 2733

t-2-Pentene 00646-04-8 1047 056 5882



c-2-Butene 00590-18-1 1426 019 2640

Total 2130 8389 3939


continued


145

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 31696 459267


n-Pentane 00109-66-0 121 5202 63200

n-Butane 00106-97-8 108 4742 51062


Toluene 00108-88-3 393 3938 154553

n-Heptane 00142-82-5 097 3796 36662

n-Hexane 00110-54-3 113 3616 41031


Benzene 00071-43-2 069 2716 18860


Cyclohexane 00110-82-7 114 2178 24768

2-Methyl-2-butene 00513-35-9 1420 2023 287182

t-2-Pentene 00646-04-8 1047 1945 203758


3-Methylpentane 00096-14-0 169 1693 28633





c-2-Pentene 00627-20-3 1028 991 101902

2-Methyl-1-butene 00563-46-2 638 937 59771


n-Octane 00111-65-9 080 891 7098

2-Methylhexane 00591-76-4 109 887 9631


2-Methylpropane 00075-28-5 118 786 9244

t-2-Hexene 04050-45-7 855 635 54264

23-Dimethylbutane 00079-29-8 090 601 5401

c-2-Butene 00590-18-1 1426 546 77832

Cyclopentane 00287-92-3 224 476 10644

3-Methyl-t-2-pentene 00616-12-6 1166 457 53303


2-Methylheptane 00592-27-8 097 412 3986


Cyclopentene 00142-29-0 669 406 27162

3-Methyl-c-2-pentene 00922-62-3 1252 381 47688

2-Methyl-2-pentene 00625-27-4 1103 378 41721




3-Methylheptane 00589-81-1 112 341 3833






146

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 277 4444



22-Dimethylbutane 00075-83-2 111 254 2820

n-Nonane 00111-84-2 068 246 1676

ortho-Xylene 00095-47-6 758 241 18230



Ethylbenzene 00100-41-4 296 181 5360


Propane 00074-98-6 046 169 0774

n-Propylbenzene 00103-65-1 196 168 3302




4-Methyloctane 02216-34-4 085 137 1163





Indan 00496-11-7 323 120 3878


3-Methyloctane 02216-33-3 088 112 0989

14-Diethylbenzene 00105-05-5 439 098 4322

33-Dimethylhexane 00563-16-6 115 095 1092


n-Undecane 01120-21-4 052 093 0483


Unknown 9 289 085 2456

Unknown 22 289 085 2454

Unknown 8 289 083 2389

Unknown 16 289 081 2340






t-4-Octene 14850-23-8 469 062 2903

n-Decane 00124-18-5 059 061 0363

continued


147

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 5 289 057 1654

Unknown 1 289 057 1645

c-2-Heptene 06443-92-1 708 056 3942


4-Methyl-t-2-pentene 00674-76-0 804 048 3873


1-Heptene 00592-76-7 429 040 1703

t-3-Heptene 14686-14-7 617 035 2178



1-Nonene 00124-11-8 249 033 0811


c- amp t-4-Nonene 02198-23-4 442 029 1282






13-Butadiene 00106-99-0 1245 014 1729


Total 10698 31327 2928


continued


148

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Toluene 00108-88-3 393 129 5070


n-Butane 00106-97-8 108 114 1229

n-Heptane 00142-82-5 097 106 1019


Benzene 00071-43-2 069 094 0655



c-2-Butene 00590-18-1 1426 072 10220



2-Methyl-1-butene 00563-46-2 638 057 3627



n-Pentane 00109-66-0 121 054 0651



Cyclohexane 00110-82-7 114 049 0558

n-Hexane 00110-54-3 113 040 0449


n-Octane 00111-65-9 080 037 0294


3-Methylpentane 00096-14-0 169 032 0549

n-Propylbenzene 00103-65-1 196 030 0591

3-Methylheptane 00589-81-1 112 028 0314

t-2-Hexene 04050-45-7 855 028 2367


2-Methylheptane 00592-27-8 097 025 0246

n-Nonane 00111-84-2 068 023 0160


2-Methylhexane 00591-76-4 109 022 0243

3-Methyl-t-2-pentene 00616-12-6 1166 021 2489

Cyclopentene 00142-29-0 669 018 1231





149

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 016 0260


2-Methyl-2-butene 00513-35-9 1420 015 2102

23-Dimethylbutane 00079-29-8 090 015 0133


ortho-Xylene 00095-47-6 758 012 0934


Ethylbenzene 00100-41-4 296 011 0325

t-2-Pentene 00646-04-8 1047 008 0869



Total 259 1087 4196


continued


150

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2384 34537


Toluene 00108-88-3 393 399 15668

n-Pentane 00109-66-0 121 371 4510




n-Heptane 00142-82-5 097 309 2980

n-Butane 00106-97-8 108 299 3222

n-Hexane 00110-54-3 113 246 2791

Benzene 00071-43-2 069 233 1614




t-2-Pentene 00646-04-8 1047 148 15551

Cyclohexane 00110-82-7 114 146 1657





2-Methyl-2-butene 00513-35-9 1420 115 16375

c-2-Pentene 00627-20-3 1028 113 11626




3-Methylpentane 00096-14-0 169 103 1742

n-Octane 00111-65-9 080 100 0796

2-Methyl-1-butene 00563-46-2 638 083 5318


t-2-Hexene 04050-45-7 855 062 5278

3-Methyl-c-2-pentene 00922-62-3 1252 061 7658


3-Methylheptane 00589-81-1 112 054 0611



2-Methylhexane 00591-76-4 109 051 0548

ortho-Xylene 00095-47-6 758 048 3648

Ethylbenzene 00100-41-4 296 047 1400

n-Propylbenzene 00103-65-1 196 047 0921


24-Dimethylhexane 00589-43-5 161 042 0671

3-Methyl-t-2-pentene 00616-12-6 1166 041 4734






151

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 039 4295

Cyclopentane 00287-92-3 224 038 0856

22-Dimethylbutane 00075-83-2 111 033 0370





n-Nonane 00111-84-2 068 023 0155

23-Dimethylbutane 00079-29-8 090 022 0200

Cyclopentene 00142-29-0 669 018 1224


Unknown 22 324 013 0423

2-Methylheptane 00592-27-8 097 012 0113

Total 951 3138 3302


continued


152

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4516 65430





Toluene 00108-88-3 393 507 19903

Unknown 22 333 400 13307

n-Butane 00106-97-8 108 381 4104


n-Heptane 00142-82-5 097 294 2844

Propane 00074-98-6 046 278 1272

Benzene 00071-43-2 069 271 1880

2-Methylheptane 00592-27-8 097 242 2337

n-Pentane 00109-66-0 121 233 2835

n-Hexane 00110-54-3 113 226 2566


c-2-Butene 00590-18-1 1426 199 28382



n-Nonane 00111-84-2 068 171 1171




c-2-Pentene 00627-20-3 1028 111 11423




n-Octane 00111-65-9 080 085 0679

Cyclohexane 00110-82-7 114 081 0923

2-Methyl-2-butene 00513-35-9 1420 081 11500

2-Methyl-1-butene 00563-46-2 638 081 5168




2-Methyl-2-pentene 00625-27-4 1103 068 7461

3-Methylheptane 00589-81-1 112 064 0719




153

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



t-2-Pentene 00646-04-8 1047 062 6546


ortho-Xylene 00095-47-6 758 053 4033


3-Methyl-c-2-pentene 00922-62-3 1252 047 5926

Ethylbenzene 00100-41-4 296 043 1269

2-Methylpropane 00075-28-5 118 038 0446


Cyclopentene 00142-29-0 669 022 1503

t-2-Hexene 04050-45-7 855 014 1156

3-Methyl-t-2-pentene 00616-12-6 1166 011 1314


23-Dimethylbutane 00079-29-8 090 005 0041

Total 1362 4730 3473


continued


154

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


155

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 914 13240



n-Heptane 00142-82-5 097 320 3090




n-Octane 00111-65-9 080 190 1516




2-Methylheptane 00592-27-8 097 148 1433


2-Methylpropane 00075-28-5 118 118 1392

Toluene 00108-88-3 393 103 4047

n-Nonane 00111-84-2 068 099 0674



3-Methylheptane 00589-81-1 112 072 0810

Benzene 00071-43-2 069 072 0497



Ethylbenzene 00100-41-4 296 054 1611

n-Propylbenzene 00103-65-1 196 051 0994

Indan 00496-11-7 323 046 1487

Unknown 8 380 044 1655

4-Methyloctane 02216-34-4 085 031 0266


ortho-Xylene 00095-47-6 758 025 1916

2-Methylhexane 00591-76-4 109 025 0270

3-Methyloctane 02216-33-3 088 022 0195

t-2-Hexene 04050-45-7 855 022 1856

n-Decane 00124-18-5 059 020 0120



24-Dimethylhexane 00589-43-5 161 010 0159


Unknown 18 380 008 0320


Total 504 1959 3887





156

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5350 77523



Toluene 00108-88-3 393 710 27869


n-Heptane 00142-82-5 097 557 5384

n-Pentane 00109-66-0 121 507 6163




n-Butane 00106-97-8 108 412 4441

Benzene 00071-43-2 069 397 2757

n-Hexane 00110-54-3 113 324 3679






n-Octane 00111-65-9 080 190 1517

2-Methyl-2-butene 00513-35-9 1420 185 26255

Cyclohexane 00110-82-7 114 177 2018

2-Methylpropane 00075-28-5 118 161 1890

t-2-Pentene 00646-04-8 1047 157 16410

3-Methylpentane 00096-14-0 169 153 2584

n-Propylbenzene 00103-65-1 196 130 2552


n-Nonane 00111-84-2 068 105 0717


2-Methylhexane 00591-76-4 109 098 1068

Propane 00074-98-6 046 095 0435

ortho-Xylene 00095-47-6 758 095 7180

2-Methyl-1-butene 00563-46-2 638 091 5809

c-2-Pentene 00627-20-3 1028 087 8898

3-Methyloctane 02216-33-3 088 083 0732


2-Methylheptane 00592-27-8 097 082 0789

4-Methyloctane 02216-34-4 085 082 0692

Cyclopentene 00142-29-0 669 079 5254

Cyclopentane 00287-92-3 224 074 1658

Ethylbenzene 00100-41-4 296 071 2105

n-Decane 00124-18-5 059 065 0381

3-Methylheptane 00589-81-1 112 063 0710

3-Methyl-t-2-pentene 00616-12-6 1166 063 7322

24-Dimethylhexane 00589-43-5 161 062 1002




157

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 061 7585




22-Dimethylbutane 00075-83-2 111 057 0637

t-2-Hexene 04050-45-7 855 056 4804


2-Methyl-2-pentene 00625-27-4 1103 054 5956





Unknown 18 309 046 1407

c-2-Butene 00590-18-1 1426 041 5887






23-Dimethylbutane 00079-29-8 090 023 0203

Total 1716 5398 3145


continued


158

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 1415 20503




n-Heptane 00142-82-5 097 457 4411

n-Nonane 00111-84-2 068 418 2857

n-Octane 00111-65-9 080 391 3117

n-Propylbenzene 00103-65-1 196 390 7648





Unknown 22 429 241 10343



Toluene 00108-88-3 393 138 5398


Ethylbenzene 00100-41-4 296 107 3162

Benzene 00071-43-2 069 106 0733

ortho-Xylene 00095-47-6 758 086 6504

2-Methylhexane 00591-76-4 109 053 0572


Total 1016 4464 4392





159

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 80088 1160459


n-Pentane 00109-66-0 121 4822 58590

n-Heptane 00142-82-5 097 4735 45729

n-Butane 00106-97-8 108 4415 47543


Toluene 00108-88-3 393 3850 151113


n-Hexane 00110-54-3 113 3408 38671


Benzene 00071-43-2 069 3032 21056


2-Methyl-2-butene 00513-35-9 1420 1879 266753


t-2-Pentene 00646-04-8 1047 1856 194423

Cyclohexane 00110-82-7 114 1803 20503

3-Methylpentane 00096-14-0 169 1710 28914

n-Octane 00111-65-9 080 1552 12360




2-Methylhexane 00591-76-4 109 1117 12118


2-Methyl-1-butene 00563-46-2 638 911 58131

c-2-Pentene 00627-20-3 1028 907 93216

2-Methylpropane 00075-28-5 118 779 9171

2-Methylheptane 00592-27-8 097 709 6862

1-Butyne 00107-00-6 605 663 40082


3-Methylheptane 00589-81-1 112 644 7246

t-2-Hexene 04050-45-7 855 637 54462



23-Dimethylbutane 00079-29-8 090 550 4945

3-Methyl-c-2-pentene 00922-62-3 1252 539 67459


n-Nonane 00111-84-2 068 474 3235

Cyclopentane 00287-92-3 224 459 10278




3-Methyl-t-2-pentene 00616-12-6 1166 406 47372

2-Methyl-2-pentene 00625-27-4 1103 376 41453

Cyclopentene 00142-29-0 669 370 24726




160

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




ortho-Xylene 00095-47-6 758 354 26855

4-Methyloctane 02216-34-4 085 354 3006

c-2-Butene 00590-18-1 1426 344 49033



Ethylbenzene 00100-41-4 296 301 8929

n-Propylbenzene 00103-65-1 196 301 5890

3-Methyloctane 02216-33-3 088 295 2606

22-Dimethylbutane 00075-83-2 111 289 3213

24-Dimethylhexane 00589-43-5 161 285 4569




Propane 00074-98-6 046 234 1071







Unknown 8 239 166 3975

Unknown 9 239 161 3846





33-Dimethylhexane 00563-16-6 115 127 1462




continued


161

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Decane 00124-18-5 059 097 0572



c- amp t-4-Nonene 02198-23-4 442 081 3581

c-2-Heptene 06443-92-1 708 079 5569

Unknown 1 239 075 1804

t-4-Octene 14850-23-8 469 075 3530



Unknown 18 239 065 1559

Unknown 5 239 060 1448

Unknown 14 239 055 1326


1-Nonene 00124-11-8 249 048 1191



Indan 00496-11-7 323 034 1102

Total 16190 39290 2427


continued


162

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1993 28873


Toluene 00108-88-3 393 213 8354



n-Butane 00106-97-8 108 130 1400

n-Pentane 00109-66-0 121 129 1569

n-Heptane 00142-82-5 097 123 1191


n-Hexane 00110-54-3 113 116 1316


t-2-Butene 00624-64-6 1520 098 14909



Benzene 00071-43-2 069 089 0619

3-Methylheptane 00589-81-1 112 080 0904

t-2-Pentene 00646-04-8 1047 078 8210



3-Methylpentane 00096-14-0 169 056 0952



Unknown 18 282 048 1351

4-Methyloctane 02216-34-4 085 047 0400


2-Methyl-2-butene 00513-35-9 1420 046 6499

2-Methylhexane 00591-76-4 109 043 0468

c-2-Pentene 00627-20-3 1028 042 4351

t-2-Hexene 04050-45-7 855 041 3497

Cyclohexane 00110-82-7 114 036 0412


c-2-Heptene 06443-92-1 708 035 2475

2-Methyl-1-butene 00563-46-2 638 035 2212

n-Octane 00111-65-9 080 033 0264

23-Dimethylbutane 00079-29-8 090 032 0284





3-Methyl-t-2-pentene 00616-12-6 1166 023 2658


n-Nonane 00111-84-2 068 022 0148

3-Methyl-c-2-pentene 00922-62-3 1252 019 2434





163

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentene 00142-29-0 669 014 0946



n-Propylbenzene 00103-65-1 196 008 0160

24-Dimethylhexane 00589-43-5 161 003 0043

Total 513 1471 2864


continued


164

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4419 64033



Toluene 00108-88-3 393 327 12821

n-Heptane 00142-82-5 097 317 3058

n-Pentane 00109-66-0 121 298 3615

n-Butane 00106-97-8 108 292 3145



n-Hexane 00110-54-3 113 202 2297



Benzene 00071-43-2 069 176 1224



3-Methylpentane 00096-14-0 169 128 2170

Cyclohexane 00110-82-7 114 121 1373

t-2-Pentene 00646-04-8 1047 108 11335

n-Octane 00111-65-9 080 104 0832

23-Dimethylbutane 00079-29-8 090 093 0839

2-Methyl-2-butene 00513-35-9 1420 088 12506


c-2-Pentene 00627-20-3 1028 065 6705

2-Methylheptane 00592-27-8 097 065 0628



2-Methyl-1-butene 00563-46-2 638 060 3850

ortho-Xylene 00095-47-6 758 058 4432

2-Methylhexane 00591-76-4 109 053 0572

3-Methylheptane 00589-81-1 112 044 0500




2-Methyl-2-pentene 00625-27-4 1103 041 4512

Cyclopentene 00142-29-0 669 040 2703

n-Nonane 00111-84-2 068 040 0272


n-Propylbenzene 00103-65-1 196 034 0666



c-2-Heptene 06443-92-1 708 032 2242

c-2-Butene 00590-18-1 1426 030 4304

3-Methyl-t-2-pentene 00616-12-6 1166 027 3205





165

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Ethylbenzene 00100-41-4 296 024 0701

24-Dimethylhexane 00589-43-5 161 020 0324

t-2-Hexene 04050-45-7 855 019 1605



22-Dimethylbutane 00075-83-2 111 016 0174


3-Methyl-c-2-pentene 00922-62-3 1252 010 1259


Total 1033 2530 2449


continued


166

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5963 86398




Toluene 00108-88-3 393 571 22420



n-Pentane 00109-66-0 121 455 5531


Propane 00074-98-6 046 324 1482





Benzene 00071-43-2 069 254 1767


n-Heptane 00142-82-5 097 246 2379


t-2-Pentene 00646-04-8 1047 211 22048


c-2-Butene 00590-18-1 1426 195 27782

Ethylbenzene 00100-41-4 296 168 4985

2-Methyl-1-butene 00563-46-2 638 165 10501

n-Hexane 00110-54-3 113 163 1848

ortho-Xylene 00095-47-6 758 152 11495

Cyclohexane 00110-82-7 114 136 1543

c-2-Pentene 00627-20-3 1028 132 13597


2-Methyl-2-butene 00513-35-9 1420 130 18389

n-Octane 00111-65-9 080 129 1027


3-Methylheptane 00589-81-1 112 115 1296

22-Dimethylbutane 00075-83-2 111 113 1259

n-Butane 00106-97-8 108 111 1191


3-Methylpentane 00096-14-0 169 099 1670


3-Methyl-t-2-pentene 00616-12-6 1166 097 11253

n-Nonane 00111-84-2 068 093 0635


23-Dimethylbutane 00079-29-8 090 091 0816

2-Methylheptane 00592-27-8 097 091 0876

Styrene 00100-42-5 166 085 1415

n-Propylbenzene 00103-65-1 196 085 1659




167

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 068 1091


c-2-Heptene 06443-92-1 708 067 4724

Cyclopentene 00142-29-0 669 058 3856




t-2-Hexene 04050-45-7 855 047 4014

3-Methyl-c-2-pentene 00922-62-3 1252 042 5224



2-Methylhexane 00591-76-4 109 024 0260

Total 1768 6143 3474


continued


168

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 55723 807411



n-Heptane 00142-82-5 097 5981 57761

n-Pentane 00109-66-0 121 4502 54693

n-Butane 00106-97-8 108 3984 42902

n-Hexane 00110-54-3 113 3782 42912


Toluene 00108-88-3 393 3760 147573


Benzene 00071-43-2 069 2573 17862


Cyclohexane 00110-82-7 114 2121 24121




3-Methylpentane 00096-14-0 169 1746 29526

2-Methylhexane 00591-76-4 109 1523 16530

n-Octane 00111-65-9 080 1370 10905

2-Methyl-2-butene 00513-35-9 1420 1332 189048

t-2-Pentene 00646-04-8 1047 1291 135259


23-Dimethylbutane 00079-29-8 090 914 8215


2-Methyl-1-butene 00563-46-2 638 724 46184



c-2-Pentene 00627-20-3 1028 654 67284


1-Butyne 00107-00-6 605 626 37845

2-Methylheptane 00592-27-8 097 598 5783



3-Methylheptane 00589-81-1 112 575 6461

24-Dimethylhexane 00589-43-5 161 569 9133

3-Methyl-c-2-pentene 00922-62-3 1252 520 65089



t-2-Hexene 04050-45-7 855 463 39550

c-2-Heptene 06443-92-1 708 449 31804

n-Decane 00124-18-5 059 419 2479


Cyclopentane 00287-92-3 224 395 8835





169

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




c-2-Butene 00590-18-1 1426 336 47937

3-Methyl-t-2-pentene 00616-12-6 1166 335 39014



2-Methyl-2-pentene 00625-27-4 1103 298 32843


4-Methyloctane 02216-34-4 085 282 2390

n-Nonane 00111-84-2 068 276 1883

Cyclopentene 00142-29-0 669 274 18349


22-Dimethylbutane 00075-83-2 111 262 2916





3-Methyloctane 02216-33-3 088 227 2006

33-Dimethylhexane 00563-16-6 115 217 2497





ortho-Xylene 00095-47-6 758 185 13998

Ethylbenzene 00100-41-4 296 181 5358


n-Propylbenzene 00103-65-1 196 147 2880




Unknown 8 231 112 2592


Unknown 16 231 111 2561

Unknown 5 231 101 2336


c- amp t-4-Nonene 02198-23-4 442 096 4265


Unknown 9 231 085 1963


Unknown 1 231 036 0824


Total 14128 33504 2371


continued


170

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


171

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 8324 89644

2-Methylpropane 00075-28-5 118 7588 89275

Ethanol 00064-17-5 145 5174 74976

n-Pentane 00109-66-0 121 4957 60220




n-Hexane 00110-54-3 113 1782 20226

2-Methyl-2-butene 00513-35-9 1420 1495 212177

Propane 00074-98-6 046 1378 6301

t-2-Pentene 00646-04-8 1047 1321 138329

Toluene 00108-88-3 393 1320 51799

3-Methylpentane 00096-14-0 169 1291 21833

3-Me-1-Hexene 03404-61-3 427 1081 46189


t-3-Heptene 14686-14-7 617 963 59431

2-Methyl-1-butene 00563-46-2 638 894 57049


Benzene 00071-43-2 069 728 5053

c-2-Pentene 00627-20-3 1028 704 72389


23-Dimethylbutane 00079-29-8 090 634 5698

22-DiMeHexane 00590-73-8 094 623 5866



2-Methylhexane 00591-76-4 109 393 4266


c-2-Butene 00590-18-1 1426 385 54865




22-Dimethylbutane 00075-83-2 111 312 3465

Cyclopentane 00287-92-3 224 301 6725

t-2-Hexene 04050-45-7 855 283 24189

14-Diethylbenzene 00105-05-5 439 246 10796

Indan 00496-11-7 323 235 7603

Cyclopentene 00142-29-0 669 222 14854

3-Methyl-t-2-pentene 00616-12-6 1166 218 25428


3-Methyl-c-2-pentene 00922-62-3 1252 216 27097


2-Methylheptane 00592-27-8 097 187 1812





172

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 173 19052

n-Octane 00111-65-9 080 166 1321


n-Propylbenzene 00103-65-1 196 160 3132

ortho-Xylene 00095-47-6 758 156 11834




Ethylbenzene 00100-41-4 296 141 4174





Unknown 5 290 113 3275











Naphthalene 00091-20-3 328 042 1374

Total 7033 20500 2915


continued


173

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 13220 142369

2-Methylpropane 00075-28-5 118 11988 141051

Ethanol 00064-17-5 145 9234 133801

n-Pentane 00109-66-0 121 8302 100866



n-Hexane 00110-54-3 113 2767 31394

2-Methyl-2-butene 00513-35-9 1420 2454 348276

t-2-Pentene 00646-04-8 1047 2145 224611

Propane 00074-98-6 046 2099 9596

3-Methylpentane 00096-14-0 169 2086 35279

n-Heptane 00142-82-5 097 1782 17211


Cyclohexane 00110-82-7 114 1516 17244

2-Methyl-1-butene 00563-46-2 638 1447 92328

22-DiMeHexane 00590-73-8 094 1392 13105

c-2-Pentene 00627-20-3 1028 1194 122782

Toluene 00108-88-3 393 1100 43170

Benzene 00071-43-2 069 1087 7545

23-Dimethylbutane 00079-29-8 090 1032 9271



2-Methylhexane 00591-76-4 109 603 6543

22-Dimethylbutane 00075-83-2 111 570 6332

c-2-Butene 00590-18-1 1426 511 72813

Cyclopentane 00287-92-3 224 491 10983

t-2-Hexene 04050-45-7 855 437 37393


Cyclopentene 00142-29-0 669 367 24548

n-Octane 00111-65-9 080 364 2897

3-Methyl-t-2-pentene 00616-12-6 1166 339 39475

2-Methyl-2-pentene 00625-27-4 1103 326 35978

3-Methyl-c-2-pentene 00922-62-3 1252 325 40724









Unknown 22 253 201 5089





174

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methylheptane 00589-81-1 112 170 1906





24-Dimethylhexane 00589-43-5 161 126 2020



2-Methylheptane 00592-27-8 097 104 1010

n-Propylbenzene 00103-65-1 196 099 1936

ortho-Xylene 00095-47-6 758 097 7318

n-Nonane 00111-84-2 068 092 0630





33-Dimethylhexane 00563-16-6 115 074 0847


Ethylbenzene 00100-41-4 296 067 1991


1-Octene 00111-66-0 314 055 1718



Total 10408 26483 2545


continued


175

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2191 31752


n-Butane 00106-97-8 108 1006 10833

n-Pentane 00109-66-0 121 747 9080

Toluene 00108-88-3 393 701 27531


Unknown 22 328 660 21624


Benzene 00071-43-2 069 489 3398

2-Methylpropane 00075-28-5 118 438 5148

t-2-Pentene 00646-04-8 1047 413 43247

n-Heptane 00142-82-5 097 401 3869

2-Methyl-2-butene 00513-35-9 1420 365 51798




Propane 00074-98-6 046 309 1412





Cyclohexane 00110-82-7 114 257 2927


n-Octane 00111-65-9 080 231 1837



c-2-Pentene 00627-20-3 1028 166 17113



n-Hexane 00110-54-3 113 150 1697



ortho-Xylene 00095-47-6 758 139 10527



c-2-Butene 00590-18-1 1426 130 18467



13-Butadiene 00106-99-0 1245 113 14026

Ethylbenzene 00100-41-4 296 109 3230

t-2-Hexene 04050-45-7 855 098 8420

2-Methyl-1-butene 00563-46-2 638 090 5717

2-Methylhexane 00591-76-4 109 078 0845

23-Dimethylbutane 00079-29-8 090 075 0672




176

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



22-DiMeHexane 00590-73-8 094 069 0650

2-Methyl-2-pentene 00625-27-4 1103 054 5959

2-Methylheptane 00592-27-8 097 052 0507

3-Methyl-t-2-pentene 00616-12-6 1166 051 5927


3-Methylpentane 00096-14-0 169 046 0770


3-Methylheptane 00589-81-1 112 024 0275

Cyclopentene 00142-29-0 669 022 1455


n-Nonane 00111-84-2 068 019 0129

Total 1606 5720 3562


continued


177

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 54709 792723


n-Butane 00106-97-8 108 10917 117569

n-Pentane 00109-66-0 121 9272 112649

2-Methylpropane 00075-28-5 118 7225 85005


Toluene 00108-88-3 393 6283 246616

n-Hexane 00110-54-3 113 4995 56676

n-Heptane 00142-82-5 097 4659 44994

Benzene 00071-43-2 069 4652 32302


2-Methyl-2-butene 00513-35-9 1420 3675 521667

t-2-Pentene 00646-04-8 1047 3631 380251

3-Methylpentane 00096-14-0 169 2779 46981

22-DiMeHexane 00590-73-8 094 2773 26105

Cyclohexane 00110-82-7 114 2771 31519


c-2-Pentene 00627-20-3 1028 1943 199760

2-Methyl-1-butene 00563-46-2 638 1834 117003


Propane 00074-98-6 046 1660 7588


2-Methylhexane 00591-76-4 109 1107 12010


n-Octane 00111-65-9 080 1036 8250


t-2-Hexene 04050-45-7 855 954 81525


23-Dimethylbutane 00079-29-8 090 860 7730


Cyclopentane 00287-92-3 224 748 16744


c-2-Butene 00590-18-1 1426 680 97022

3-Methyl-t-2-pentene 00616-12-6 1166 666 77705

Cyclopentene 00142-29-0 669 665 44433


22-Dimethylbutane 00075-83-2 111 574 6383

3-Methyl-c-2-pentene 00922-62-3 1252 548 68650

2-Methyl-2-pentene 00625-27-4 1103 519 57206

2-Methylheptane 00592-27-8 097 515 4981



1-Butyne 00107-00-6 605 436 26373

3-Methylheptane 00589-81-1 112 403 4535




178

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





ortho-Xylene 00095-47-6 758 345 26142






Ethylbenzene 00100-41-4 296 292 8644


24-Dimethylhexane 00589-43-5 161 289 4646



n-Nonane 00111-84-2 068 234 1599


n-Propylbenzene 00103-65-1 196 198 3881



4-Methyloctane 02216-34-4 085 193 1641



Unknown 1 271 171 4641

33-Dimethylhexane 00563-16-6 115 159 1833






n-Undecane 01120-21-4 052 079 0415

3-Methyloctane 02216-33-3 088 079 0703

Unknown 5 271 076 2052

1-Octene 00111-66-0 314 065 2057





Unknown 8 271 035 0945

Total 17874 48855 2733


continued


179

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 8198 118785

n-Butane 00106-97-8 108 7183 77353


n-Pentane 00109-66-0 121 3595 43676

2-Methylpropane 00075-28-5 118 2766 32545


Propane 00074-98-6 046 2137 9770

n-Hexane 00110-54-3 113 1047 11875


n-Heptane 00142-82-5 097 912 8810

t-2-Pentene 00646-04-8 1047 830 86907

2-Methyl-2-butene 00513-35-9 1420 814 115599


23-Dimethylbutane 00079-29-8 090 556 4999


Benzene 00071-43-2 069 530 3683

2-Methyl-1-butene 00563-46-2 638 507 32336

Toluene 00108-88-3 393 503 19740

3-Methylpentane 00096-14-0 169 472 7984


c-2-Pentene 00627-20-3 1028 393 40363


c-2-Butene 00590-18-1 1426 277 39443



22-Dimethylbutane 00075-83-2 111 214 2380


2-Methylheptane 00592-27-8 097 180 1739

t-2-Hexene 04050-45-7 855 178 15211

n-Octane 00111-65-9 080 172 1368



2-Methylhexane 00591-76-4 109 161 1748



c-2-Heptene 06443-92-1 382 146 5572



Cyclopentene 00142-29-0 669 129 8640

3-Methyl-t-2-pentene 00616-12-6 1166 116 13518


Cyclohexane 00110-82-7 114 092 1044


n-Nonane 00111-84-2 068 087 0593




180

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 086 0966

2-Methyl-2-pentene 00625-27-4 1103 081 8971



24-Dimethylhexane 00589-43-5 161 078 1247








n-Propylbenzene 00103-65-1 196 048 0949


33-Dimethylhexane 00563-16-6 115 031 0359


3-Methyl-c-2-pentene 00922-62-3 1252 027 3427




Ethylbenzene 00100-41-4 296 018 0528

ortho-Xylene 00095-47-6 758 010 0721


Total 4710 11512 2444


continued


181

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 15180 219955


n-Butane 00106-97-8 108 9750 104997

n-Pentane 00109-66-0 121 5514 66989


2-Methylpropane 00075-28-5 118 3609 42461


n-Hexane 00110-54-3 113 2552 28959

Propane 00074-98-6 046 2506 11455

n-Heptane 00142-82-5 097 1866 18025

3-Methylpentane 00096-14-0 169 1624 27461

23-Dimethylbutane 00079-29-8 090 1413 12703

2-Methyl-2-butene 00513-35-9 1420 1376 195359

Toluene 00108-88-3 393 1340 52581

Cyclohexane 00110-82-7 114 1307 14870



t-2-Pentene 00646-04-8 1047 1180 123585


Benzene 00071-43-2 069 965 6703

2-Methyl-1-butene 00563-46-2 638 878 56009

c-2-Pentene 00627-20-3 1028 635 65238

2-Methylhexane 00591-76-4 109 632 6855






22-Dimethylbutane 00075-83-2 111 370 4115


n-Octane 00111-65-9 080 346 2755


c-2-Butene 00590-18-1 1426 336 47966


c-2-Heptene 06443-92-1 708 260 18411

t-2-Hexene 04050-45-7 855 249 21269

24-Dimethylhexane 00589-43-5 161 234 3765






3-Methyl-t-2-pentene 00616-12-6 1166 201 23444

2-Methyl-2-pentene 00625-27-4 1103 200 22011




182

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 193 1865

3-Methylheptane 00589-81-1 112 188 2119

Cyclopentene 00142-29-0 669 180 12031



n-Propylbenzene 00103-65-1 196 157 3073

3-Methyl-c-2-pentene 00922-62-3 1252 146 18216




ortho-Xylene 00095-47-6 758 129 9739




Ethylbenzene 00100-41-4 296 101 3002




n-Nonane 00111-84-2 068 085 0583



4-Methyloctane 02216-34-4 085 082 0694



33-Dimethylhexane 00563-16-6 115 067 0767

n-Decane 00124-18-5 059 066 0389



Total 8664 21100 2435


continued


183

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1732 25089


Benzene 00071-43-2 069 452 3139

c-2-Butene 00590-18-1 1426 376 53628








c-2-Pentene 00627-20-3 1028 072 7386

n-Heptane 00142-82-5 097 059 0568

n-Propylbenzene 00103-65-1 196 048 0947

Ethylbenzene 00100-41-4 296 045 1322


2-Methyl-2-butene 00513-35-9 1420 025 3547

t-2-Hexene 04050-45-7 855 022 1855

ortho-Xylene 00095-47-6 758 015 1110

n-Octane 00111-65-9 080 010 0081

Total 489 2108 4309




184

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 51382 744509



n-Butane 00106-97-8 108 8982 96733

n-Pentane 00109-66-0 121 6997 85011

Toluene 00108-88-3 393 6711 263404

n-Heptane 00142-82-5 097 6680 64513

n-Hexane 00110-54-3 113 5030 57075



Benzene 00071-43-2 069 4022 27924

Cyclohexane 00110-82-7 114 3279 37292




2-Methylpropane 00075-28-5 118 2557 30086


Propane 00074-98-6 046 2432 11116

3-Methylpentane 00096-14-0 169 2416 40845


n-Octane 00111-65-9 080 2194 17472

2-Methyl-2-butene 00513-35-9 1420 2103 298453

t-2-Pentene 00646-04-8 1047 2086 218459


2-Methylhexane 00591-76-4 109 1526 16559

23-Dimethylbutane 00079-29-8 090 1374 12350



2-Methyl-1-butene 00563-46-2 638 1191 75982



c-2-Pentene 00627-20-3 1028 1105 113644

2-Methylheptane 00592-27-8 097 1023 9893


3-Methylheptane 00589-81-1 112 906 10183





24-Dimethylhexane 00589-43-5 161 698 11203

c-2-Heptene 06443-92-1 708 667 47214

n-Nonane 00111-84-2 068 663 4525

t-2-Hexene 04050-45-7 855 648 55398

ortho-Xylene 00095-47-6 758 548 41492




185

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentane 00287-92-3 224 512 11458


n-Propylbenzene 00103-65-1 196 499 9784

4-Methyloctane 02216-34-4 085 497 4216

3-Methyl-t-2-pentene 00616-12-6 1166 485 56599

3-Methyl-c-2-pentene 00922-62-3 1252 456 57109

c-2-Butene 00590-18-1 1426 444 63356


Cyclopentene 00142-29-0 669 416 27787






Ethylbenzene 00100-41-4 296 389 11519

22-Dimethylbutane 00075-83-2 111 378 4206

2-Methyl-2-pentene 00625-27-4 1103 358 39448

Unknown 16 261 356 9264



3-Methyloctane 02216-33-3 088 339 3003




1-Nonene 00124-11-8 249 256 6374

1-Butyne 00107-00-6 605 251 15194

Ethylene 00074-85-1 888 250 22216


Unknown 8 261 234 6089


33-Dimethylhexane 00563-16-6 115 213 2449




1-Octene 00111-66-0 314 195 6137


Unknown 9 261 154 4022

n-Undecane 01120-21-4 052 154 0805

n-Decane 00124-18-5 059 152 0896

Unknown 5 261 142 3689


Indan 00496-11-7 323 131 4230

continued


186

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 6 261 131 3400


Styrene 00100-42-5 166 105 1738



Unknown 1 261 052 1367



Total 18590 49278 2651


continued


187

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


188

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




189

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




190

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Naphthalene 00091-20-3 328 774 25406


t-2-Butene 00624-64-6 1520 371 56453


n-Butane 00106-97-8 108 285 3072

23-Dimethylbutane 00079-29-8 090 248 2230



Toluene 00108-88-3 393 190 7444

2-Methylpropane 00075-28-5 118 166 1951

2-Methylheptane 00592-27-8 097 157 1514

3-Methyl-t-2-pentene 00616-12-6 1166 131 15309

n-Heptane 00142-82-5 097 130 1251


3-Methylpentane 00096-14-0 169 117 1981

24-Dimethylhexane 00589-43-5 161 111 1786


n-Hexane 00110-54-3 113 100 1134


22-Dimethylbutane 00075-83-2 111 082 0916

Ethylbenzene 00100-41-4 296 077 2293

t-2-Pentene 00646-04-8 1047 075 7833

Cyclohexane 00110-82-7 114 074 0842

c-2-Butene 00590-18-1 1426 074 10503

3-Methyl-c-2-pentene 00922-62-3 1252 071 8850

ortho-Xylene 00095-47-6 758 068 5178

n-Pentane 00109-66-0 121 021 0252


Total 486 2222 4570




191

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4628 67056

3-Methylpentane 00096-14-0 169 1507 25484



n-Butane 00106-97-8 108 1101 11855


Toluene 00108-88-3 393 1066 41860

3-Methyl-c-2-pentene 00922-62-3 1252 1066 133427

n-Pentane 00109-66-0 121 935 11363


n-Hexane 00110-54-3 113 210 2385


Total 1468 3932 2678




192

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




193

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




194

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




195

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4926 71372


Toluene 00108-88-3 393 1115 43746

3-Methylpentane 00096-14-0 169 762 12888

n-Butane 00106-97-8 108 725 7805


n-Hexane 00110-54-3 113 611 6931

n-Pentane 00109-66-0 121 583 7083




3-Methyl-c-2-pentene 00922-62-3 1252 205 25608

Total 1211 2325 1920



196


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


197

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 31534 339592

Ethanol 00064-17-5 145 15433 223618

n-Pentane 00109-66-0 121 4575 55584


Toluene 00108-88-3 393 4103 161061

n-Hexane 00110-54-3 113 3924 44527

2-Methyl-2-butene 00513-35-9 1420 3811 540999

t-2-Pentene 00646-04-8 1047 3208 335977

3-Methylpentane 00096-14-0 169 2810 47513

2-Methyl-1-butene 00563-46-2 638 2286 145822

23-Dimethylbutane 00079-29-8 090 2194 19722

c-2-Pentene 00627-20-3 1028 1736 178523




c-2-Butene 00590-18-1 1426 1349 192427

Benzene 00071-43-2 069 1177 8169

Cyclohexane 00110-82-7 114 1082 12310





t-2-Hexene 04050-45-7 855 585 50036

2-Methylhexane 00591-76-4 109 580 6299

Cyclopentene 00142-29-0 669 525 35095

n-Heptane 00142-82-5 097 524 5057

3-Methyl-t-2-pentene 00616-12-6 1166 474 55209


2-Methyl-2-pentene 00625-27-4 1103 432 47686

3-Methyl-c-2-pentene 00922-62-3 1252 408 51020




22-Dimethylbutane 00075-83-2 111 322 3582





24-Dimethylhexane 00589-43-5 161 213 3412


n-Octane 00111-65-9 080 159 1266






198

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylheptane 00592-27-8 097 131 1270




3-Methylheptane 00589-81-1 112 116 1307




t-3-Heptene 14686-14-7 617 083 5119


ortho-Xylene 00095-47-6 758 079 5957




n-Decane 00124-18-5 249 054 1339




Ethylbenzene 00100-41-4 296 049 1460


Unknown 1 266 034 0906

33-Dimethylhexane 00563-16-6 115 030 0344

n-Propylbenzene 00103-65-1 196 028 0542

n-Nonane 00111-84-2 068 015 0101


4-Methyl-t-2-pentene 00674-76-0 804 002 0184

Total 13923 37072 2663


continued


199

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 79369 854739


Ethanol 00064-17-5 145 38151 552793

Toluene 00108-88-3 393 16580 650783

n-Hexane 00110-54-3 113 13605 154368


3-Methylpentane 00096-14-0 169 7654 129419

n-Pentane 00109-66-0 121 7381 89678

2-Methyl-2-butene 00513-35-9 1420 6466 917894


t-2-Pentene 00646-04-8 1047 5245 549380

23-Dimethylbutane 00079-29-8 090 5099 45823

Benzene 00071-43-2 069 4157 28862


Cyclohexane 00110-82-7 114 3728 42398

2-Methyl-1-butene 00563-46-2 638 3681 234792

Ethylene 00074-85-1 888 3244 288174




c-2-Pentene 00627-20-3 1028 2900 298147



Ethane 00074-84-0 026 2242 5893


c-2-Butene 00590-18-1 1426 1864 265834

2-Methylhexane 00591-76-4 109 1801 19546

n-Heptane 00142-82-5 097 1789 17277




2-Methylpropane 00075-28-5 118 1312 15435


t-2-Hexene 04050-45-7 855 1292 110422

1-Butyne 00107-00-6 605 1288 77894

Propane 00074-98-6 046 1212 5539



3-Methyl-t-2-pentene 00616-12-6 1166 1006 117309


Cyclopentene 00142-29-0 669 970 64866


2-Methyl-2-pentene 00625-27-4 1103 953 105093





200

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 843 105557

n-Octane 00111-65-9 080 804 6403

24-Dimethylhexane 00589-43-5 161 747 11988




13-Butadiene 00106-99-0 1245 683 85018

ortho-Xylene 00095-47-6 758 620 46937

22-Dimethylbutane 00075-83-2 111 614 6826


Ethylbenzene 00100-41-4 296 564 16718


n-Propylbenzene 00103-65-1 196 527 10333







2-Methylheptane 00592-27-8 097 427 4127


3-Methylheptane 00589-81-1 112 420 4718


14-Diethylbenzene 00105-05-5 439 416 18237

n-Decane 00124-18-5 059 401 2372



Unknown 16 275 325 8937



Methane 00074-82-8 001 281 0039


n-Nonane 00111-84-2 068 234 1599

Styrene 00100-42-5 166 234 3891



4-Methyl-t-2-pentene 00674-76-0 804 187 15065

n-Undecane 01120-21-4 052 186 0970

4-Methyloctane 02216-34-4 085 170 1442


c-2-Heptene 06443-92-1 708 149 10568

Unknown 8 275 147 4049

continued


201

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 1 275 144 3964

Unknown 22 275 143 3926


Unknown 5 275 129 3543



Unknown 13 275 118 3236

33-Dimethylhexane 00563-16-6 115 116 1338

1-Nonene 00124-11-8 249 113 2820


3-Methyloctane 02216-33-3 088 101 0889

3-Me-1-Hexene 03404-61-3 427 096 4100


Indan 00496-11-7 323 071 2300

Total 32476 89876 2767


continued


202

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 172274 1855242


Ethanol 00064-17-5 145 69165 1002190

2-Methylpropane 00075-28-5 118 21941 258154

n-Hexane 00110-54-3 113 20456 232106

Toluene 00108-88-3 393 19883 780424


n-Pentane 00109-66-0 121 17100 207749

2-Methyl-2-butene 00513-35-9 1420 14541 2064164

t-2-Pentene 00646-04-8 1047 12530 1312315

3-Methylpentane 00096-14-0 169 12414 209911

23-Dimethylbutane 00079-29-8 090 8996 80848

2-Methyl-1-butene 00563-46-2 638 8314 530308


c-2-Pentene 00627-20-3 1028 6703 689128


Benzene 00071-43-2 069 5731 39795

c-2-Butene 00590-18-1 1426 5522 787420

Cyclohexane 00110-82-7 114 5520 62783




n-Heptane 00142-82-5 097 2763 26680



2-Methylhexane 00591-76-4 109 2596 28167


t-2-Hexene 04050-45-7 855 2303 196844

Cyclopentene 00142-29-0 669 2024 135325




3-Methyl-t-2-pentene 00616-12-6 1166 1818 211970

2-Methyl-2-pentene 00625-27-4 1103 1651 182150


3-Methyl-c-2-pentene 00922-62-3 1252 1509 188858



22-Dimethylbutane 00075-83-2 111 1289 14328

Propane 00074-98-6 046 1286 5880








203

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 965 15494

n-Octane 00111-65-9 080 867 6901






2-Methylheptane 00592-27-8 097 513 4960

Ethylbenzene 00100-41-4 296 509 15068

ortho-Xylene 00095-47-6 758 500 37892

3-Methylheptane 00589-81-1 112 493 5541








n-Propylbenzene 00103-65-1 196 278 5444

4-Methyl-t-2-pentene 00674-76-0 804 268 21529

Unknown 16 250 236 5907

n-Nonane 00111-84-2 068 228 1557





c-2-Heptene 06443-92-1 708 180 12724



4-Methyloctane 02216-34-4 085 159 1351


Unknown 5 250 146 3658

33-Dimethylhexane 00563-16-6 115 145 1668

Unknown 13 250 138 3462

Indan 00496-11-7 565 135 7640


1-Octene 00111-66-0 314 134 4197


Unknown 8 250 128 3196




continued


204

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




t-4-Octene 14850-23-8 469 113 5317

n-Decane 00124-18-5 059 102 0604

14-Diethylbenzene 00105-05-5 439 092 4032

3-Methyloctane 02216-33-3 088 083 0734

1-Nonene 00124-11-8 249 082 2036

Unknown 9 250 082 2039

t-3-Heptene 14686-14-7 617 074 4560

Unknown 3 250 072 1807

n-Undecane 01120-21-4 052 061 0317

1-Heptene 00592-76-7 429 060 2554



Unknown 12 250 046 1154



t-2-Nonene 06434-78-2 250 036 0888


c-2-Octene 07642-04-8 250 026 0651

Unknown 14 250 018 0459

Total 61958 155900 2516


continued


205

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11715 169746

n-Butane 00106-97-8 108 8056 86757

n-Hexane 00110-54-3 113 4667 52958


23-Dimethylbutane 00079-29-8 090 3624 32566

Toluene 00108-88-3 393 3574 140274

2-Methyl-2-butene 00513-35-9 1420 2721 386293

3-Methylpentane 00096-14-0 169 2686 45414

n-Pentane 00109-66-0 121 2659 32300

t-2-Pentene 00646-04-8 1047 2291 239970

2-Methyl-1-butene 00563-46-2 638 1615 103023



Cyclohexane 00110-82-7 114 1325 15069

2-Methylpropane 00075-28-5 118 1261 14840

c-2-Pentene 00627-20-3 1028 1225 125951

Benzene 00071-43-2 069 1002 6959


c-2-Butene 00590-18-1 1426 984 140348




2-Methylhexane 00591-76-4 109 497 5389



t-2-Hexene 04050-45-7 855 436 37281

n-Heptane 00142-82-5 097 390 3765

Cyclopentene 00142-29-0 669 377 25223


3-Methyl-t-2-pentene 00616-12-6 1166 342 39822

2-Methyl-2-pentene 00625-27-4 1103 323 35657


3-Methyl-c-2-pentene 00922-62-3 1252 294 36799




24-Dimethylhexane 00589-43-5 161 213 3421


n-Octane 00111-65-9 080 185 1477








206

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 141 1566



Propane 00074-98-6 046 113 0517




ortho-Xylene 00095-47-6 758 064 4881


4-Methyl-t-2-pentene 00674-76-0 804 060 4791


n-Decane 00124-18-5 059 057 0338

2-Methylheptane 00592-27-8 097 055 0536



Ethylbenzene 00100-41-4 296 053 1579

3-Methylheptane 00589-81-1 112 052 0582


Unknown 5 288 046 1329

4-Methyloctane 02216-34-4 085 043 0365



33-Dimethylhexane 00563-16-6 115 037 0423

3-Methyloctane 02216-33-3 088 032 0283

n-Nonane 00111-84-2 068 023 0155

n-Propylbenzene 00103-65-1 196 015 0294


Total 8737 25269 2892


continued


207

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35389 512774

Benzene 00071-43-2 069 4816 33438

Methane 00074-82-8 001 200 0028

Ethane 00074-84-0 026 1602 4210


Propane 00074-98-6 046 1131 5168

2-Methylpropane 00075-28-5 118 2369 27872

22-Dimethylbutane 00075-83-2 111 986 10951



23-Dimethylbutane 00079-29-8 090 7961 71544

ortho-Xylene 00095-47-6 758 645 48887


3-Methylpentane 00096-14-0 169 11861 200561



Ethylbenzene 00100-41-4 296 495 14670

n-Propylbenzene 00103-65-1 196 538 10537

n-Butane 00106-97-8 108 20573 221556

13-Butadiene 00106-99-0 1245 657 81767





Toluene 00108-88-3 393 16497 647513

n-Pentane 00109-66-0 121 12943 157255


n-Hexane 00110-54-3 113 19250 218427

Cyclohexane 00110-82-7 114 5321 60521


n-Octane 00111-65-9 080 692 5511

n-Nonane 00111-84-2 068 309 2108


n-Decane 00124-18-5 059 301 1780

Cyclopentene 00142-29-0 669 1453 97125

n-Heptane 00142-82-5 097 1831 17681


2-Methyl-2-butene 00513-35-9 1420 10075 1430132




2-Methyl-1-butene 00563-46-2 638 6277 400401






208

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 1065 17101

3-Methylheptane 00589-81-1 112 512 5752

c-2-Butene 00590-18-1 1426 4141 590493



2-Methylhexane 00591-76-4 109 2197 23841


2-Methylheptane 00592-27-8 097 512 4948



3-Methyl-t-2-pentene 00616-12-6 1166 1347 156999


2-Methyl-2-pentene 00625-27-4 1103 1253 138231

c-2-Pentene 00627-20-3 1028 4701 483353


t-2-Pentene 00646-04-8 1047 8504 890689





3-Methyl-c-2-pentene 00922-62-3 1252 1185 148379







t-2-Hexene 04050-45-7 855 1625 138889


Unknown 16 335 352 11791

Unknown 1 335 242 8119

Total 34405 116244 3379


continued


209

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 112868 1635432

n-Butane 00106-97-8 108 58158 626316

n-Hexane 00110-54-3 113 44646 506591


n-Pentane 00109-66-0 121 30821 374457

3-Methylpentane 00096-14-0 169 26164 442392

2-Methyl-2-butene 00513-35-9 1420 25929 3680648

Toluene 00108-88-3 393 23727 931277

t-2-Pentene 00646-04-8 1047 21858 2289338

23-Dimethylbutane 00079-29-8 090 18155 163160

2-Methyl-1-butene 00563-46-2 638 14852 947358



c-2-Pentene 00627-20-3 1028 11711 1204011

Cyclohexane 00110-82-7 114 10272 116827


c-2-Butene 00590-18-1 1426 8497 1211611

Benzene 00071-43-2 069 8447 58652

2-Methylpropane 00075-28-5 118 7517 88450



2-Methylhexane 00591-76-4 109 4449 48279



t-2-Hexene 04050-45-7 855 3861 330080


Cyclopentene 00142-29-0 669 3403 227545

n-Heptane 00142-82-5 097 3263 31514

3-Methyl-t-2-pentene 00616-12-6 1166 3087 359933


2-Methyl-2-pentene 00625-27-4 1103 2833 312515


3-Methyl-c-2-pentene 00922-62-3 1252 2551 319336



22-Dimethylbutane 00075-83-2 111 2302 25580


24-Dimethylhexane 00589-43-5 161 1503 24139

Propane 00074-98-6 046 1456 6658








210

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




1-Butyne 00107-00-6 605 1088 65828

n-Octane 00111-65-9 080 827 6585









2-Methylheptane 00592-27-8 097 486 4701

3-Methylheptane 00589-81-1 112 442 4965

ortho-Xylene 00095-47-6 758 367 27827







Ethylbenzene 00100-41-4 296 241 7138



n-Propylbenzene 00103-65-1 196 204 4004

Unknown 5 295 172 5063

33-Dimethylhexane 00563-16-6 115 164 1888


c-2-Heptene 06443-92-1 708 133 9383

n-Nonane 00111-84-2 068 125 0851

1-Octene 00111-66-0 314 124 3881

Indan 00496-11-7 323 119 3852

t-3-Heptene 14686-14-7 617 114 7031

Ethylene 00074-85-1 888 113 10031

4-Methyloctane 02216-34-4 085 111 0942


Unknown 16 295 101 2970

Unknown 3 295 097 2854

Unknown 6 295 097 2845




Unknown 8 295 081 2388

n-Decane 00124-18-5 059 080 0470

continued


211

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 13 295 079 2322

3-Methyloctane 02216-33-3 088 077 0681


13-Butadiene 00106-99-0 1245 076 9484


1-Heptene 00592-76-7 429 060 2584



Unknown 9 295 047 1372


1-Nonene 00124-11-8 249 039 0967

n-Undecane 01120-21-4 052 039 0202

3-Ethyl-c-2-Pentene 00816-79-5 976 038 3690






14-Diethylbenzene 00105-05-5 439 016 0705


Unknown 22 295 005 0140

Total 76987 227741 2958


continued


212

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 24872 267848


Ethanol 00064-17-5 145 7522 108992

n-Hexane 00110-54-3 113 2284 25919

Toluene 00108-88-3 393 1833 71943


3-Methylpentane 00096-14-0 169 1742 29458

2-Methyl-2-butene 00513-35-9 1420 1698 240966

n-Pentane 00109-66-0 121 1576 19144

t-2-Pentene 00646-04-8 1047 1511 158229

23-Dimethylbutane 00079-29-8 090 1202 10800


2-Methyl-1-butene 00563-46-2 638 1039 66260


Benzene 00071-43-2 069 892 6192

c-2-Pentene 00627-20-3 1028 805 82752

c-2-Butene 00590-18-1 1426 802 114334

Cyclohexane 00110-82-7 114 799 9092



2-Methylpropane 00075-28-5 118 646 7600

1-Butyne 00107-00-6 605 646 39077




2-Methylhexane 00591-76-4 109 405 4399





Propane 00074-98-6 046 326 1490

t-2-Hexene 04050-45-7 855 306 26148

n-Heptane 00142-82-5 097 305 2946



Cyclopentene 00142-29-0 669 242 16150

3-Methyl-t-2-pentene 00616-12-6 1166 237 27634


3-Methyl-c-2-pentene 00922-62-3 1252 219 27369

ortho-Xylene 00095-47-6 758 215 16278

2-Methyl-2-pentene 00625-27-4 1103 210 23172







213

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 178 1977


24-Dimethylhexane 00589-43-5 161 139 2225

n-Octane 00111-65-9 080 130 1032


Ethylbenzene 00100-41-4 296 119 3519




n-Propylbenzene 00103-65-1 196 104 2036




3-Methylheptane 00589-81-1 112 074 0827






2-Methylheptane 00592-27-8 097 047 0455


n-Nonane 00111-84-2 068 046 0315

Total 7427 20164 2715


continued


214

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 42844 461388


Ethanol 00064-17-5 145 17178 248906

Toluene 00108-88-3 393 10047 394340

n-Hexane 00110-54-3 113 8065 91515


3-Methylpentane 00096-14-0 169 4491 75939

n-Pentane 00109-66-0 121 4370 53093

2-Methyl-2-butene 00513-35-9 1420 3637 516297


23-Dimethylbutane 00079-29-8 090 2956 26564

t-2-Pentene 00646-04-8 1047 2864 299954


Benzene 00071-43-2 069 2591 17991

Cyclohexane 00110-82-7 114 2542 28906



2-Methyl-1-butene 00563-46-2 638 1881 119952

c-2-Butene 00590-18-1 1426 1857 264799

c-2-Pentene 00627-20-3 1028 1775 182543


Ethylene 00074-85-1 888 1636 145343

n-Heptane 00142-82-5 097 1536 14831



Ethane 00074-84-0 026 1261 3314



Methane 00074-82-8 001 1067 0148


2-Methylhexane 00591-76-4 109 1026 11134


Propane 00074-98-6 046 809 3698


t-2-Hexene 04050-45-7 855 760 65002

n-Octane 00111-65-9 080 636 5062


3-Methyl-t-2-pentene 00616-12-6 1166 604 70439


Cyclopentene 00142-29-0 669 555 37098

13-Butadiene 00106-99-0 1245 530 66022







215

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




2-Methyl-2-pentene 00625-27-4 1103 503 55446




ortho-Xylene 00095-47-6 758 427 32375

n-Propylbenzene 00103-65-1 196 425 8330

3-Methyl-c-2-pentene 00922-62-3 1252 419 52480




Ethylbenzene 00100-41-4 296 312 9253

22-Dimethylbutane 00075-83-2 111 306 3401


3-Methylheptane 00589-81-1 112 296 3328


2-Methylpropane 00075-28-5 118 281 3306


24-Dimethylhexane 00589-43-5 161 250 4021

2-Methylheptane 00592-27-8 097 238 2306






Unknown 1 284 172 4890




Total 18066 51521 2852


continued


216

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 316658 3410131


Ethanol 00064-17-5 145 67831 982860

n-Hexane 00110-54-3 113 32071 363900


n-Pentane 00109-66-0 121 25077 304666

2-Methyl-2-butene 00513-35-9 1420 20849 2959520

3-Methylpentane 00096-14-0 169 19682 332790

t-2-Pentene 00646-04-8 1047 17641 1847614

Toluene 00108-88-3 393 15091 592313

23-Dimethylbutane 00079-29-8 090 13982 125657

2-Methyl-1-butene 00563-46-2 638 12182 777050

c-2-Pentene 00627-20-3 1028 9542 981058



2-Methylpropane 00075-28-5 118 7882 92741


Cyclohexane 00110-82-7 114 7483 85109

c-2-Butene 00590-18-1 1426 7117 1014871

Benzene 00071-43-2 069 6155 42735


2-Methylhexane 00591-76-4 109 3304 35857


t-2-Hexene 04050-45-7 855 3007 257097



Cyclopentene 00142-29-0 669 2736 182929


3-Methyl-t-2-pentene 00616-12-6 1166 2425 282759

n-Heptane 00142-82-5 097 2420 23372

2-Methyl-2-pentene 00625-27-4 1103 2238 246882


3-Methyl-c-2-pentene 00922-62-3 1252 2008 251353


22-Dimethylbutane 00075-83-2 111 1932 21463







24-Dimethylhexane 00589-43-5 161 1135 18218






217

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





1-Butyne 00107-00-6 605 772 46679

n-Octane 00111-65-9 080 671 5344



Propane 00074-98-6 046 568 2596





2-Methylheptane 00592-27-8 097 469 4538


3-Methylheptane 00589-81-1 112 433 4866



ortho-Xylene 00095-47-6 758 325 24656




Ethylbenzene 00100-41-4 296 255 7563

n-Propylbenzene 00103-65-1 196 248 4851


n-Nonane 00111-84-2 068 175 1194

Unknown 5 240 166 3989

33-Dimethylhexane 00563-16-6 115 165 1905

n-Decane 00124-18-5 059 164 0967



c-2-Heptene 06443-92-1 708 144 10185



Unknown 16 240 132 3163



4-Methyloctane 02216-34-4 085 108 0916

n-Undecane 01120-21-4 052 106 0553

t-3-Heptene 14686-14-7 617 101 6224


Unknown 3 240 067 1615

1-Heptene 00592-76-7 429 066 2838

13-Butadiene 00106-99-0 1245 060 7523


3-Methyloctane 02216-33-3 088 059 0525

continued


218

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyloctane 02216-33-3 088 059 0525



Unknown 22 240 053 1268

1-Nonene 00124-11-8 249 047 1178

Unknown 8 240 047 1119


Indan 00496-11-7 323 033 1060

14-Diethylbenzene 00105-05-5 439 027 1190

Total 86321 207927 2409


continued


219

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5716 82823

Benzene 00071-43-2 069 818 5680

Propane 00074-98-6 046 141 0644

2-Methylpropane 00075-28-5 118 344 4046


23-Dimethylbutane 00079-29-8 090 819 7363


3-Methylpentane 00096-14-0 169 1189 20098


n-Butane 00106-97-8 108 3676 39588

Toluene 00108-88-3 393 2159 84759

n-Pentane 00109-66-0 121 1545 18766

n-Hexane 00110-54-3 113 2616 29678

2-Methyl-2-butene 00513-35-9 1420 1237 175649



t-2-Pentene 00646-04-8 1047 1196 125262


Total 3415 8597 2517





220

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 13363 193622

Benzene 00071-43-2 069 2498 17342

Methane 00074-82-8 001 1601 0222

Ethane 00074-84-0 026 1146 3013

Ethylene 00074-85-1 888 1976 175570

2-Methylpropane 00075-28-5 118 312 3675

22-Dimethylbutane 00075-83-2 111 419 4659



23-Dimethylbutane 00079-29-8 090 2658 23890

ortho-Xylene 00095-47-6 758 471 35666


3-Methylpentane 00096-14-0 169 4167 70465




Ethylbenzene 00100-41-4 296 483 14312

n-Propylbenzene 00103-65-1 196 549 10766

14-Diethylbenzene 00105-05-5 439 366 16071

n-Butane 00106-97-8 108 6249 67299

13-Butadiene 00106-99-0 1245 678 84410

1-Butyne 00107-00-6 605 843 50998





Toluene 00108-88-3 393 9872 387494

n-Pentane 00109-66-0 121 3931 47757


n-Hexane 00110-54-3 113 7372 83651

Cyclohexane 00110-82-7 114 2206 25094


n-Octane 00111-65-9 080 595 4737

n-Nonane 00111-84-2 068 180 1229

1-Dodecene 00112-41-4 156 142 2220


n-Decane 00124-18-5 059 631 3731

Cyclopentene 00142-29-0 669 568 37986

n-Heptane 00142-82-5 097 940 9074


Indan 00496-11-7 323 222 7175

2-Methyl-2-butene 00513-35-9 1420 3288 466742






221

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






33-Dimethyl-1-butene 00558-37-2 568 092 5207


33-Dimethylhexane 00563-16-6 115 164 1893

2-Methyl-1-butene 00563-46-2 638 1833 116899




24-Dimethylhexane 00589-43-5 161 689 11062

3-Methylheptane 00589-81-1 112 195 2189

c-2-Butene 00590-18-1 1426 1053 150118


2-Methylhexane 00591-76-4 109 1016 11022


2-Methylheptane 00592-27-8 097 452 4375



3-Methyl-t-2-pentene 00616-12-6 1166 664 77449



2-Methyl-2-pentene 00625-27-4 1103 641 70697

c-2-Pentene 00627-20-3 1028 1401 144091


t-2-Pentene 00646-04-8 1047 2698 282558





continued


222

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 649 81193






4-Methyloctane 02216-34-4 085 175 1482




t-2-Hexene 04050-45-7 855 875 74823


c-2-Heptene 06443-92-1 066 121 0790


Unknown 16 342 407 13925

Unknown 13 342 172 5885

Unknown 1 342 111 3781

Total 13962 48361 3464


continued


223

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 93713 1357878

Benzene 00071-43-2 069 8395 58292

Ethylene 00074-85-1 888 385 34170

Propane 00074-98-6 046 2204 10077

2-Methylpropane 00075-28-5 118 9571 112611

22-Dimethylbutane 00075-83-2 111 1771 19683



23-Dimethylbutane 00079-29-8 090 17445 156779

ortho-Xylene 00095-47-6 758 670 50741


3-Methylpentane 00096-14-0 169 25280 427457



Ethylbenzene 00100-41-4 296 381 11287

n-Propylbenzene 00103-65-1 196 340 6654

n-Butane 00106-97-8 108 45349 488366

13-Butadiene 00106-99-0 1245 098 12253

1-Butyne 00107-00-6 605 785 47505






Toluene 00108-88-3 393 27004 1059911

n-Pentane 00109-66-0 121 24220 294263


n-Hexane 00110-54-3 113 42008 476657

Cyclohexane 00110-82-7 114 10300 117149


n-Octane 00111-65-9 080 1207 9611

1-Octene 00111-66-0 314 135 4256

n-Nonane 00111-84-2 068 238 1626


1-Nonene 00124-11-8 249 109 2715

n-Decane 00124-18-5 059 372 2201

Cyclopentene 00142-29-0 669 2697 180349

n-Heptane 00142-82-5 097 3372 32566



Indan 00496-11-7 323 253 8173

2-Methyl-2-butene 00513-35-9 1420 20269 2877200







224

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





33-Dimethylhexane 00563-16-6 115 181 2080

2-Methyl-1-butene 00563-46-2 638 11748 749377




24-Dimethylhexane 00589-43-5 161 2049 32895

3-Methylheptane 00589-81-1 112 880 9892

c-2-Butene 00590-18-1 1426 7564 1078587



2-Methylhexane 00591-76-4 109 4571 49606


2-Methylheptane 00592-27-8 097 923 8932


1-Heptene 00592-76-7 429 108 4612


3-Methyl-t-2-pentene 00616-12-6 1166 3093 360613



2-Methyl-2-pentene 00625-27-4 1103 2810 309980

c-2-Pentene 00627-20-3 1028 9207 946625


t-2-Pentene 00646-04-8 1047 17071 1787966





3-Methyl-c-2-pentene 00922-62-3 1252 2468 308948







3-Methyloctane 02216-33-3 088 167 1477

4-Methyloctane 02216-34-4 085 247 2098





continued


225

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





t-2-Hexene 04050-45-7 855 3716 317667

t-2-Nonene 06434-78-2 290 075 2171

c-2-Heptene 06443-92-1 708 211 14913


t-3-Heptene 14686-14-7 617 198 12193

Unknown 5 290 413 11999

Unknown 16 290 404 11736

Unknown 13 290 190 5520

Unknown 8 290 136 3963

Unknown 3 290 085 2475

Unknown 9 290 084 2439

Total 68582 200436 2923


continued


226


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


227

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 22971 247380


n-Hexane 00110-54-3 113 2483 28180


n-Pentane 00109-66-0 121 1817 22079

3-Methylpentane 00096-14-0 169 1584 26779

2-Methyl-2-butene 00513-35-9 1420 1509 214170

t-2-Pentene 00646-04-8 1047 1269 132895

Toluene 00108-88-3 393 1202 47172

23-Dimethylbutane 00079-29-8 090 1103 9914

c-2-Butene 00590-18-1 1426 904 128849

2-Methyl-1-butene 00563-46-2 638 890 56745



c-2-Pentene 00627-20-3 1028 680 69944

2-Methylpropane 00075-28-5 118 645 7585

t-2-Butene 00624-64-6 1520 536 81392


Cyclohexane 00110-82-7 114 519 5901


Benzene 00071-43-2 069 479 3328





2-Methylhexane 00591-76-4 109 227 2467

t-2-Hexene 04050-45-7 855 211 18015

Cyclopentene 00142-29-0 669 199 13290

n-Heptane 00142-82-5 097 194 1873



3-Methyl-t-2-pentene 00616-12-6 1166 176 20565



3-Methyl-1-butene 00563-45-1 685 153 10520

2-Methyl-2-pentene 00625-27-4 1103 152 16805







22-Dimethylbutane 00075-83-2 111 119 1317





228

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 115 14408

n-Octane 00111-65-9 080 107 0853


ortho-Xylene 00095-47-6 758 102 7756








n-Propylbenzene 00103-65-1 196 046 0903


2-Methylheptane 00592-27-8 097 041 0396



Ethylbenzene 00100-41-4 296 007 0221

24-Dimethylhexane 00589-43-5 161 006 0101

Total 6278 16694 2659


continued


229

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Unknown 22 307 391 12012

Ethanol 00064-17-5 145 1321 19145

Benzene 00071-43-2 069 2139 14852

Propane 00074-98-6 046 397 1816

2-Methylpropane 00075-28-5 118 3636 42785

22-Dimethylbutane 00075-83-2 111 842 9359



23-Dimethylbutane 00079-29-8 090 2973 26719

ortho-Xylene 00095-47-6 758 337 25550


3-Methylpentane 00096-14-0 169 3756 63505


Ethylbenzene 00100-41-4 296 220 6505

n-Propylbenzene 00103-65-1 196 202 3961

n-Butane 00106-97-8 108 56598 609509






Toluene 00108-88-3 393 2903 113947

n-Pentane 00109-66-0 121 5036 61181


n-Hexane 00110-54-3 113 7233 82075

Cyclohexane 00110-82-7 114 3248 36942


n-Octane 00111-65-9 080 252 2004


Cyclopentene 00142-29-0 669 913 61061

n-Heptane 00142-82-5 097 978 9444


2-Methyl-2-butene 00513-35-9 1420 4143 588042




2-Methyl-1-butene 00563-46-2 638 4234 270054




24-Dimethylhexane 00589-43-5 161 832 13366

3-Methylheptane 00589-81-1 112 179 2017

c-2-Butene 00590-18-1 1426 7009 999462





230

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





2-Methylhexane 00591-76-4 109 1400 15189


2-Methylheptane 00592-27-8 097 175 1693



3-Methyl-t-2-pentene 00616-12-6 1166 815 95045



2-Methyl-2-pentene 00625-27-4 1103 777 85750

c-2-Pentene 00627-20-3 1028 3096 318320

t-2-Pentene 00646-04-8 1047 3554 372250





3-Methyl-c-2-pentene 00922-62-3 1252 712 89120




t-2-Hexene 04050-45-7 855 994 84993


Unknown 1 307 061 1868

Total 19657 60694 3088


continued


231

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 307727 3313949


Ethanol 00064-17-5 145 39672 574830

n-Hexane 00110-54-3 113 34020 386019


n-Pentane 00109-66-0 121 28021 340433

3-Methylpentane 00096-14-0 169 22023 372381

2-Methyl-2-butene 00513-35-9 1420 20648 2930948

t-2-Pentene 00646-04-8 1047 17405 1822913

23-Dimethylbutane 00079-29-8 090 16047 144212

Toluene 00108-88-3 393 14387 564695

2-Methyl-1-butene 00563-46-2 638 12969 827211

c-2-Butene 00590-18-1 1426 11793 1681690



c-2-Pentene 00627-20-3 1028 9515 978316

Cyclohexane 00110-82-7 114 9043 102849


Benzene 00071-43-2 069 6756 46910



2-Methylhexane 00591-76-4 109 3473 37687



3-Methyl-t-2-pentene 00616-12-6 1166 2951 344072


2-Methylpropane 00075-28-5 118 2769 32579

Cyclopentene 00142-29-0 669 2682 179344



n-Heptane 00142-82-5 097 2413 23305

2-Methyl-2-pentene 00625-27-4 1103 2292 252898

24-Dimethylhexane 00589-43-5 161 2070 33231

t-2-Hexene 04050-45-7 855 2064 176446

3-Methyl-c-2-pentene 00922-62-3 1252 2063 258275

22-Dimethylbutane 00075-83-2 111 1886 20962







232

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








Propane 00074-98-6 046 400 1829


Ethylbenzene 00100-41-4 296 342 10143

Total 85443 209022 2446


continued


233

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11488 166456

n-Butane 00106-97-8 108 7975 85883

n-Hexane 00110-54-3 113 6913 78445


n-Pentane 00109-66-0 121 4885 59344

3-Methylpentane 00096-14-0 169 4260 72030

2-Methyl-2-butene 00513-35-9 1420 4013 569617

t-2-Pentene 00646-04-8 1047 3313 346941

Toluene 00108-88-3 393 3059 120057

23-Dimethylbutane 00079-29-8 090 2976 26746

2-Methyl-1-butene 00563-46-2 638 2453 156477



c-2-Butene 00590-18-1 1426 1891 269674

c-2-Pentene 00627-20-3 1028 1824 187499

Cyclohexane 00110-82-7 114 1684 19156

t-2-Butene 00624-64-6 1520 1597 242714


2-Methylpropane 00075-28-5 118 1543 18157

Benzene 00071-43-2 069 1143 7936




2-Methylhexane 00591-76-4 109 714 7751



t-2-Hexene 04050-45-7 855 596 50989


Cyclopentene 00142-29-0 669 507 33919

3-Methyl-t-2-pentene 00616-12-6 1166 499 58164


2-Methyl-2-pentene 00625-27-4 1103 459 50603

Propane 00074-98-6 046 439 2008


n-Heptane 00142-82-5 097 430 4150

3-Methyl-c-2-pentene 00922-62-3 1252 414 51810

22-Dimethylbutane 00075-83-2 111 382 4244



24-Dimethylhexane 00589-43-5 161 288 4618







234

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 130 1038



2-Methylheptane 00592-27-8 097 099 0957



3-Methylheptane 00589-81-1 112 083 0929





t-3-Heptene 14686-14-7 617 051 3173



Unknown 5 321 043 1371


Ethylbenzene 00100-41-4 296 040 1173

33-Dimethylhexane 00563-16-6 115 036 0411

ortho-Xylene 00095-47-6 758 035 2689

n-Propylbenzene 00103-65-1 196 035 0690


Total 11846 38214 3226


continued


235

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Butane 00106-97-8 108 7470 80442

n-Hexane 00110-54-3 113 7413 84118

n-Pentane 00109-66-0 121 5151 62576


3-Methylpentane 00096-14-0 169 4543 76808

2-Methyl-2-butene 00513-35-9 1420 4232 600795

t-2-Pentene 00646-04-8 1047 3542 371010

Toluene 00108-88-3 393 3511 137807

23-Dimethylbutane 00079-29-8 090 3268 29366

c-2-Butene 00590-18-1 1426 3176 452906

1-Butyne 00107-00-6 605 2943 178046

2-Methyl-1-butene 00563-46-2 638 2779 177240


c-2-Pentene 00627-20-3 1028 2047 210481


Cyclohexane 00110-82-7 114 1938 22040


2-Methylpropane 00075-28-5 118 1317 15500

Benzene 00071-43-2 069 1229 8533



Ethanol 00064-17-5 145 810 11731



2-Methylhexane 00591-76-4 109 691 7494

t-2-Hexene 04050-45-7 855 621 53050

n-Heptane 00142-82-5 097 579 5588


Cyclopentene 00142-29-0 669 574 38396


2-Methyl-2-pentene 00625-27-4 1103 486 53633



3-Methyl-c-2-pentene 00922-62-3 1252 468 58610

3-Methyl-t-2-pentene 00616-12-6 1166 457 53286


Methane 00074-82-8 001 444 0061

22-Dimethylbutane 00075-83-2 111 431 4788








236

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 328 5262


n-Octane 00111-65-9 080 282 2250


n-Decane 00124-18-5 059 276 1632

Unknown 22 335 234 7864






2-Methylheptane 00592-27-8 097 160 1548

3-Methylheptane 00589-81-1 112 144 1615




n-Propylbenzene 00103-65-1 196 113 2208

Unknown 1 335 094 3164


Indan 00496-11-7 323 084 2722


Ethylbenzene 00100-41-4 296 067 1991

n-Undecane 01120-21-4 052 047 0244

ortho-Xylene 00095-47-6 758 043 3244

Total 13128 44311 3375


continued


237

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 23123 249015

Ethanol 00064-17-5 145 21703 314477

n-Hexane 00110-54-3 113 18050 204804


n-Pentane 00109-66-0 121 13834 168070

3-Methylpentane 00096-14-0 169 11505 194534

2-Methyl-2-butene 00513-35-9 1420 11209 1591055

t-2-Pentene 00646-04-8 1047 9469 991727

23-Dimethylbutane 00079-29-8 090 8278 74396

2-Methyl-1-butene 00563-46-2 638 6814 434644

Toluene 00108-88-3 393 6647 260916


c-2-Pentene 00627-20-3 1028 5152 529739



c-2-Butene 00590-18-1 1426 4525 645316

Cyclohexane 00110-82-7 114 4341 49370

1-Butyne 00107-00-6 605 3288 198937

2-Methylpropane 00075-28-5 118 3175 37353

Benzene 00071-43-2 069 2711 18826



2-Methylhexane 00591-76-4 109 1773 19242




t-2-Hexene 04050-45-7 855 1516 129592

Cyclopentene 00142-29-0 669 1453 97160

3-Methyl-t-2-pentene 00616-12-6 1166 1242 144819


2-Methyl-2-pentene 00625-27-4 1103 1149 126792

3-Methyl-c-2-pentene 00922-62-3 1252 1075 134519


22-Dimethylbutane 00075-83-2 111 1058 11760

n-Heptane 00142-82-5 097 1036 10005






24-Dimethylhexane 00589-43-5 161 606 9728






238

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Propane 00074-98-6 046 476 2175








n-Octane 00111-65-9 080 260 2066






2-Methylheptane 00592-27-8 097 198 1916

Ethylbenzene 00100-41-4 296 198 5852

3-Methylheptane 00589-81-1 112 177 1989


ortho-Xylene 00095-47-6 758 163 12357



Unknown 1 313 123 3845

Unknown 16 313 116 3646

n-Decane 00124-18-5 059 110 0648

n-Propylbenzene 00103-65-1 196 088 1715



Unknown 5 313 070 2205

c-2-Heptene 06443-92-1 708 065 4610

33-Dimethylhexane 00563-16-6 115 065 0749

n-Nonane 00111-84-2 068 049 0335

t-3-Heptene 14686-14-7 617 043 2680


13-Butadiene 00106-99-0 1245 042 5279

4-Methyl-t-2-pentene 00674-76-0 804 021 1722

Methane 00074-82-8 001 008 0001

Total 31093 97716 3143


continued


239

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 39458 424924


Ethanol 00064-17-5 145 10129 146760

2-Methylpropane 00075-28-5 118 5716 67259

n-Hexane 00110-54-3 113 4068 46161


n-Pentane 00109-66-0 121 3154 38314

3-Methylpentane 00096-14-0 169 2555 43201

2-Methyl-2-butene 00513-35-9 1420 2451 347976

t-2-Pentene 00646-04-8 1047 2085 218342

Toluene 00108-88-3 393 2039 80037

23-Dimethylbutane 00079-29-8 090 1831 16453

2-Methyl-1-butene 00563-46-2 638 1510 96290



c-2-Pentene 00627-20-3 1028 1123 115451

Cyclohexane 00110-82-7 114 1042 11856


c-2-Butene 00590-18-1 1426 833 118751

Benzene 00071-43-2 069 781 5423

Propane 00074-98-6 046 619 2830



22-DiMeHexane 00590-73-8 094 513 4827

2-Methylhexane 00591-76-4 109 460 4988

1-Butyne 00107-00-6 605 379 22956

t-2-Hexene 04050-45-7 855 374 31963


t-3-Heptene 14686-14-7 617 351 21645


Cyclopentene 00142-29-0 669 328 21962

3-Methyl-t-2-pentene 00616-12-6 1166 304 35469


2-Methyl-2-pentene 00625-27-4 1103 284 31321



3-Methyl-c-2-pentene 00922-62-3 1252 256 32099


22-Dimethylbutane 00075-83-2 111 222 2468









240

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 5 230 105 2411


Unknown 7 230 082 1885




Unknown 17 230 069 1596


2-Methylheptane 00592-27-8 097 066 0636



n-Propylbenzene 00103-65-1 196 046 0909



n-Nonane 00111-84-2 068 037 0255


ortho-Xylene 00095-47-6 758 027 2080

Unknown 1 230 027 0619


Ethylbenzene 00100-41-4 296 019 0574

c-2-Octene 07642-04-8 230 007 0157

Total 11484 26563 2313


continued


241

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 622650 6705400


Ethanol 00064-17-5 145 124094 1798086

n-Hexane 00110-54-3 113 67518 766114


n-Pentane 00109-66-0 121 46672 567029

3-Methylpentane 00096-14-0 169 41573 702943

2-Methyl-2-butene 00513-35-9 1420 39233 5569075

Toluene 00108-88-3 393 33167 1301796

t-2-Pentene 00646-04-8 1047 32239 3376598

23-Dimethylbutane 00079-29-8 090 29164 262093

2-Methylpropane 00075-28-5 118 23323 274414

2-Methyl-1-butene 00563-46-2 638 22688 1447167



c-2-Pentene 00627-20-3 1028 17645 1814172

Cyclohexane 00110-82-7 114 16882 192015


c-2-Butene 00590-18-1 1426 12775 1821732

Benzene 00071-43-2 069 11664 80988



2-Methylhexane 00591-76-4 109 7254 78719




t-2-Hexene 04050-45-7 855 5835 498847


Cyclopentene 00142-29-0 669 5140 343686

3-Methyl-t-2-pentene 00616-12-6 1166 4795 559045

n-Heptane 00142-82-5 097 4710 45487

2-Methyl-2-pentene 00625-27-4 1103 4548 501761


3-Methyl-c-2-pentene 00922-62-3 1252 4046 506426

22-Dimethylbutane 00075-83-2 111 3825 42506

1-Butyne 00107-00-6 605 3692 223362



Propane 00074-98-6 046 2935 13414


24-Dimethylhexane 00589-43-5 161 2703 43405







242

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 1249 9946



2-Methylheptane 00592-27-8 097 924 8935


3-Methylheptane 00589-81-1 112 747 8400




ortho-Xylene 00095-47-6 758 623 47185



Indan 00496-11-7 323 477 15440



n-Nonane 00111-84-2 068 408 2788

Ethylbenzene 00100-41-4 296 406 12023


n-Propylbenzene 00103-65-1 196 329 6454




Unknown 5 237 273 6466

1-Octene 00111-66-0 314 250 7855

33-Dimethylhexane 00563-16-6 115 231 2665

c-2-Heptene 06443-92-1 708 230 16249

n-Decane 00124-18-5 059 227 1339

t-3-Heptene 14686-14-7 617 214 13214

4-Methyloctane 02216-34-4 085 185 1572

3-Methyloctane 02216-33-3 088 159 1405

14-Diethylbenzene 00105-05-5 439 144 6326

Unknown 3 237 139 3291


1-Heptene 00592-76-7 429 128 5491

Unknown 8 237 120 2850


continued


243

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 22 237 096 2267

13-Butadiene 00106-99-0 1245 092 11436

n-Undecane 01120-21-4 052 084 0439

Unknown 16 237 055 1290

Total 169783 402961 2373


continued


244

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 421885 4543329


Ethanol 00064-17-5 145 63956 926704

n-Hexane 00110-54-3 113 42103 477731


n-Pentane 00109-66-0 121 32695 397223

3-Methylpentane 00096-14-0 169 26461 447417

2-Methyl-2-butene 00513-35-9 1420 26231 3723433

t-2-Pentene 00646-04-8 1047 21783 2281458

23-Dimethylbutane 00079-29-8 090 18965 170438

2-Methyl-1-butene 00563-46-2 638 15351 979200

Toluene 00108-88-3 393 12682 497783


c-2-Pentene 00627-20-3 1028 11853 1218653


2-Methylpropane 00075-28-5 118 9786 115144

Cyclohexane 00110-82-7 114 9561 108746


c-2-Butene 00590-18-1 1426 9027 1287178

Benzene 00071-43-2 069 6124 42524




2-Methylhexane 00591-76-4 109 3992 43324


1-Butyne 00107-00-6 605 3305 199919

Cyclopentene 00142-29-0 669 3296 220392


n-Heptane 00142-82-5 097 2810 27134

2-Methyl-2-pentene 00625-27-4 1103 2648 292135


3-Methyl-t-2-pentene 00616-12-6 1166 2537 295819


22-Dimethylbutane 00075-83-2 111 2430 27002

3-Methyl-c-2-pentene 00922-62-3 1252 2312 289438

t-2-Hexene 04050-45-7 855 2269 193990



24-Dimethylhexane 00589-43-5 161 1392 22345






Total 107832 252202 2339






245

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 6816 73402

n-Hexane 00110-54-3 113 3742 42455


Ethanol 00064-17-5 145 3387 49080

n-Pentane 00109-66-0 121 3097 37631

3-Methylpentane 00096-14-0 169 2395 40491

2-Methyl-2-butene 00513-35-9 1420 2381 337913

t-2-Pentene 00646-04-8 1047 1985 207950

23-Dimethylbutane 00079-29-8 090 1735 15592

Toluene 00108-88-3 393 1702 66802

2-Methyl-1-butene 00563-46-2 638 1455 92799



c-2-Pentene 00627-20-3 1028 1091 112168

Cyclohexane 00110-82-7 114 918 10442


c-2-Butene 00590-18-1 1426 822 117258

Benzene 00071-43-2 069 614 4266



1-Butyne 00107-00-6 605 420 25383

2-Methylpropane 00075-28-5 118 409 4811


2-Methylhexane 00591-76-4 109 397 4310


t-2-Hexene 04050-45-7 855 332 28352

Cyclopentene 00142-29-0 669 320 21388



3-Methyl-t-2-pentene 00616-12-6 1166 278 32432


2-Methyl-2-pentene 00625-27-4 1103 263 28991

n-Heptane 00142-82-5 097 261 2517

3-Methyl-c-2-pentene 00922-62-3 1252 211 26449


22-Dimethylbutane 00075-83-2 111 192 2132











246

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





24-Dimethylhexane 00589-43-5 161 128 2054

Propane 00074-98-6 046 125 0570




n-Octane 00111-65-9 080 098 0779







3-Methylheptane 00589-81-1 112 044 0498

2-Methylheptane 00592-27-8 097 044 0429


ortho-Xylene 00095-47-6 758 035 2631


n-Propylbenzene 00103-65-1 196 031 0598

Ethylbenzene 00100-41-4 296 015 0439

Total 6829 20748 3038


continued


247

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 36810 533364

n-Butane 00106-97-8 108 26480 285167

n-Hexane 00110-54-3 113 21599 245076


n-Pentane 00109-66-0 121 15798 191932

3-Methylpentane 00096-14-0 169 13417 226870

2-Methyl-2-butene 00513-35-9 1420 12566 1783699

t-2-Pentene 00646-04-8 1047 10774 1128460

Toluene 00108-88-3 393 10319 405014

23-Dimethylbutane 00079-29-8 090 9397 84455

2-Methyl-1-butene 00563-46-2 638 7705 491485



c-2-Pentene 00627-20-3 1028 5741 590268

Cyclohexane 00110-82-7 114 5656 64330


c-2-Butene 00590-18-1 1426 4360 621746

Benzene 00071-43-2 069 3722 25841

1-Butyne 00107-00-6 605 3308 200127




2-Methylhexane 00591-76-4 109 2460 26697

2-Methylpropane 00075-28-5 118 2442 28735




t-2-Hexene 04050-45-7 855 1875 160280



Cyclopentene 00142-29-0 669 1630 108972


3-Methyl-t-2-pentene 00616-12-6 1166 1439 167759

2-Methyl-2-pentene 00625-27-4 1103 1392 153551

n-Heptane 00142-82-5 097 1191 11503



3-Methyl-c-2-pentene 00922-62-3 1252 1118 139900

24-Dimethylhexane 00589-43-5 161 1101 17683



22-Dimethylbutane 00075-83-2 111 996 11062





248

Species CAS No MIR

Composite

VOC

mg

Ozone

mg









n-Octane 00111-65-9 080 676 5383



Propane 00074-98-6 046 584 2670


ortho-Xylene 00095-47-6 758 532 40274


n-Propylbenzene 00103-65-1 196 490 9599




3-Methylheptane 00589-81-1 112 429 4820

14-Diethylbenzene 00105-05-5 439 417 18308



2-Methylheptane 00592-27-8 097 275 2658

Indan 00496-11-7 323 271 8760

n-Nonane 00111-84-2 068 254 1733


n-Decane 00124-18-5 059 145 0857

Ethylbenzene 00100-41-4 296 134 3977

Total 38384 118469 3086


continued


249

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 29218 423362

n-Butane 00106-97-8 108 29007 312377

n-Hexane 00110-54-3 113 24380 276633


3-Methylpentane 00096-14-0 169 15596 263709

n-Pentane 00109-66-0 121 15520 188558

2-Methyl-2-butene 00513-35-9 1420 12658 1796850

23-Dimethylbutane 00079-29-8 090 11129 100014

t-2-Pentene 00646-04-8 1047 10500 1099738

Toluene 00108-88-3 393 10002 392585

2-Methyl-1-butene 00563-46-2 638 7489 477698



c-2-Pentene 00627-20-3 1028 5759 592056

Cyclohexane 00110-82-7 114 5744 65330

2-Methylpropane 00075-28-5 118 5722 67323

c-2-Butene 00590-18-1 1426 4971 708857


Benzene 00071-43-2 069 3956 27472

1-Butyne 00107-00-6 605 3534 213821




2-Methylhexane 00591-76-4 109 2413 26182


t-2-Hexene 04050-45-7 855 2057 175842



3-Methyl-t-2-pentene 00616-12-6 1166 1706 198941

Cyclopentene 00142-29-0 669 1599 106896

2-Methyl-2-pentene 00625-27-4 1103 1593 175741


n-Heptane 00142-82-5 097 1492 14408

3-Methyl-c-2-pentene 00922-62-3 1252 1338 167511


22-Dimethylbutane 00075-83-2 111 1217 13527



Propane 00074-98-6 046 992 4536


24-Dimethylhexane 00589-43-5 161 840 13485






250

Species CAS No MIR

Composite

VOC

mg

Ozone

mg












n-Octane 00111-65-9 080 380 3024





3-Methylheptane 00589-81-1 112 287 3222


2-Methylheptane 00592-27-8 097 259 2502

ortho-Xylene 00095-47-6 758 227 17173





Naphthalene 00091-20-3 328 172 5634

Unknown 16 302 169 5123

n-Nonane 00111-84-2 068 152 1040

n-Decane 00124-18-5 059 151 0890

Ethylbenzene 00100-41-4 296 150 4447

Indan 00496-11-7 323 132 4264

n-Propylbenzene 00103-65-1 196 120 2348

4-Methyloctane 02216-34-4 085 118 1002

Unknown 5 302 112 3400


t-3-Heptene 14686-14-7 617 104 6411




14-Diethylbenzene 00105-05-5 439 090 3928

33-Dimethylhexane 00563-16-6 115 083 0954

c-2-Heptene 06443-92-1 708 077 5453

13-Butadiene 00106-99-0 1245 052 6436

Unknown 3 302 036 1101

Total 38356 116460 3036


continued


251


E0 E10 E20




DVPE psi 701 730 849

Oxygenates--D4815

MTBE vol 000 000 000

ETBE vol 000 000 000

EtOH vol 000 954 2034

O2 wt 000 353 747





D86 Distillation

IBP degF 974 1040 1022












EP degF 3603 3600 3406



Loss vol 09 12 07


Data from CRC E-74



252








(R+M)2 885 889 890








CH Ratio 6200 6092 5835

Oxygen wt 0008 1 340 773




Oxygen wt 0008 3396 7733

C+H wt 9999 9660 9227

H wt 1389 1362 1350

C wt 8610 8298 7877

Fuel Units 6 7 4


Average D3338 Btulb 18579 18514 18491


DHA Btulb 18703 18016 17160






i

Final Report





VEHICLES

CRC E-77-2c

Submitted by

Harold M Haskew PE

Tom Liberty



Milford MI


ii

Table of Contents

Page

Introduction

Background 1


Program Overview

Test Fuels 3

Test Procedures 5























Acknowledgements 37









iii

List of Figures


1 Trap Canister 5























iv

List of Tables


















v

Acronyms
















HC Hydrocarbon























vi

Executive Summary


























Veh Evap Standards















vii






45 plus prior work)













quality modelers



















1




CRC E-77-2c

Introduction












studies





















reg Project No




2






3

Program Overview

Test Fuels





in Appendix V


Haltermann products




MIN MAX

RESULTS


5 ˚F 136

10 ˚F 144

15 ˚F 148

20 ˚F 151

25 ˚F 154

30 ˚F 157

35 ˚F 159

40 ˚F 160

45 ˚F 162

50 ˚F 185 Target only 195 164

55 ˚F 168

60 ˚F 215

65 ˚F 245

70 ˚F 258

75 ˚F 272

80 ˚F 289

85 ˚F 305

90 ˚F 315 325 316

95 ˚F 323




Loss vol Report 05















R+M2 D26992700 870 910 888



4


Haltermann products




MIN MAX

RESULTS


5 ˚F 123

10 ˚F 131

20 ˚F 140

30 ˚F 150

40 ˚F 156

50 ˚F 185 Target only 195 161

60 ˚F 165

70 ˚F 248

80 ˚F 285

90 ˚F 315 325 315

95 ˚F 322




Loss vol Report 14















R+M2 D26992700 870 910 891



5

Test Procedures





















effective


















6

















7

Drain and 40 Fill

with Test Fuel



Drain and 40 Fill

with Test Fuel


Move to SHED


Stabilize at 86degF






Transfer to RL SHED


Stabilize at 86degF



One Hour Hot Soak

Drain and 40 Fill

With Test Fuel



Move to VT-SHED





Drain and 40 Fill

with Next Test Fuel



On Test Fuel


Fuel System


9 psi E20

7 psi E20






8





vehicle




committee
















Table 3













9














yellow shading

Table 4





Fuel Tank

Veh Tank Plastic































E77-2 Program





10



















11










45 plus prior work)









12








0

10

20

30

40

50

60

70


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zer Evap

7

4

77

7

7

6

266

6

6


1

1

0

20

40

60

80

100

120

140


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

4

4

4

4

4

4

22

2

2

22

11



13








202216 See Note 1 7E10 325 00 00 --- --- ---

202216 9E0 178 136 00 --- --- ---

202216 7E0 204 380 00 --- --- ---

202216 9E20 204 00 00 --- --- ---


204 7E10 664 00 00 --- --- ---

204 9E0 338 00 00 --- --- ---

204 7E0 129 00 00 --- --- ---

204 9E20 553 00 00 --- --- ---


205 7E10 596 00 00 --- --- ---

205 9E0 195 00 00 --- --- ---

205 7E0 99 00 00 --- --- ---

205 9E20 462 00 00 --- --- ---


207 7E10 644 00 00 --- --- ---

207 9E0 325 00 00 --- --- ---

207 7E0 401 00 00 --- --- ---

207 9E20 882 00 00 --- --- ---


207L See Note 2 7E10 1468 --- 00 --- --- ---


206b 7E10 1493 00 00 3079 00 00

206b 9E0 611 00 00 1788 00 00

206b 7E0 520 00 00 1181 00 00

206c 9E20 702 00 00 1729 00 00

206c 7E20 938 00 00 2307 00 00


207c See Note 2 7E10 5235 --- 2718 --- --- ---

207c 10E10 2325 --- 10837 --- --- ---

207c 7E10 1448 --- 3727 --- --- ---


208b 7E10 272 00 00 518 00 00

208b 9E0 372 00 00 550 00 91

208b 7E0 248 00 00 645 00 00

208c 9E20 219 00 00 396 00 00

208c 7E20 184 00 00 525 00 00


209b 7E10 286 00 00 541 00 00 E-77-2bc

209b 9E0 234 00 58 295 00 00

209b 7E0 168 19 79 288 00 00

209c 9E20 420 00 00 721 00 00

209c 7E20 235 00 00 411 00 00


220b See Note 3 7E10 504 9122 15724 1820 23090 28945

220b 9E0 1023 23181 28272 18581 35298 51362

220b 7E0 627 13515 16557 2792 22736 30082


221b See Note 4 7E10 227 9307 9710 614 12823 14085

221b 9E0 556 13488 14060 948 16467 17882

221b 7E0 359 9888 9618 668 12159 13438

221c 9E20 265 6165 6734 723 10328 10971

221c 7E20 394 5312 5061 630 7462 7806

Averages


7psi E0 275 7 696 4

9psi E0 376 7 895 4

7psi E10 598 7 1188 4

10psi E10 621 7 1322 4

7psi E20 438 4 968 4

9psi E20 500 7 892 4













Tank Top

Can Inlet


14






211 7E10 94 266 00 --- --- ---

211 9E0 101 00 00 --- --- ---

211 7E0 91 00 00 --- --- ---

211 9E20 558 00 00 --- --- ---


211L See Note 7E10 481 --- 1664 --- --- ---


212 7E10 218 00 00 --- --- ---

212 9E0 32 00 00 --- --- ---

212 7E0 09 00 00 --- --- ---

212 9E20 47 00 00 --- --- ---


214 7E10 239 --- 00 --- --- ---

214 9E0 107 --- 00 --- --- ---

214 7E0 252 --- 00 --- --- ---

214 9E20 168 --- 00 --- --- ---


215 7E10 122 00 00 --- --- ---

215 9E0 85 00 00 --- --- ---

215 7E0 87 00 00 --- --- ---

215 9E20 193 00 00 --- --- ---


210b 7E10 299 00 00 519 00 232

210b 9E0 212 00 40 335 00 48

210b 7E0 187 00 00 355 00 00

210c 9E20 180 00 00 327 00 46

210c 7E20 152 00 00 340 00 00


211c See Note 7E10 4491 --- 2869 --- --- ---

211c 10E10 2247 --- 14727 --- --- ---

211c 7E10 2170 --- 7890 --- --- ---


213b 7E10 296 00 00 822 00 00

213b 9E0 147 00 00 345 00 00

213b 7E0 211 00 00 353 00 00

213c 9E20 298 00 00 751 00 00

213c 7E20 229 00 00 651 00 00

Averages


7psi E0 140 6 354 2

9psi E0 114 6 340 2

7psi E10 211 6 670 2

10psi E10 209 6 884 2

7psi E20 191 2 495 2

9psi E20 241 6 539 2





Tank Top

Can Inlet




222c 7E20 69 00 00 71 00 00 E-77-2bc

Averages


7psi E20 69 1 71 1

9psi E20 92 1 69 1



15












0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

10

5 d

eg

F S

tati

c P

erm

ea

tio

n -

mg

hr



Tier 1

Tier 2

Zero Evap


16











0

50

100

150

200

250

300

350

400

450


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1


0

10

20

30

40

50

60

70

80

90

100


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1



17

Table 7


Veh Eng RL Tru-HS



202216 See Note 1 7E10 1683 192

202216 9E0 1091 254

202216 7E0 787 0

202216 9E20 543 74


204 7E10 2879 297

204 9E0 2492 443

204 7E0 2226 187

204 9E20 2720 134


205 7E10 2328 719

205 9E0 1031 10

205 7E0 671 00

205 9E20 1697 603


207 7E10 8122 1222

207 9E0 8339 58 E-77-2

207 7E0 8425 00

207 9E20 10282 00


207L See Note 2 7E10 11393 5850


206b 7E10 4367 1749

206b 9E0 3656 1025

206b 7E0 2451 688

206c 9E20 3308 858

206c 7E20 5187 1063


207c See Note 2 7E10 27694 5141

207c 10E10 9375 11140

207c 7E10 1146 6102


208b 7E10 2547 773

208b 9E0 2280 379

208b 7E0 1249 750

208c 9E20 2415 269

208c 7E20 2785 205


209b 7E10 2057 245 E-77-2bc

209b 9E0 1444 50

209b 7E0 1662 168

209c 9E20 3671 719

209c 7E20 2560 282


220b See Note 3 7E10 6979 768

220b 9E0 24170 3525

220b 7E0 34473 7071


221b 7E10 1020 405

221b 9E0 1352 290

221b 7E0 1898 425

221c 9E20 1266 95

221c 7E20 619 25

Averages

RL HS Sample

7psi E0 2655 317 7

9psi E0 2942 322 7

7psi E10 3331 773 7

10psi E10 3831 870 7

7psi E20 2788 394 4

9psi E20 3623 382 7






Tank Top

Can Inlet





18

Table 8



Veh Eng RL Tru-HS



211 7E10 563 138

211 9E0 837 153

211 7E0 1046 07

211 9E20 4106 00


211L See Note 7E10 2511 62


212 7E10 2012 00

212 9E0 1158 04

212 7E0 1845 18

212 9E20 1168 49


214 7E10 1057 329

214 9E0 967 521

214 7E0 363 33

214 9E20 1394 56


215 7E10 979 00

215 9E0 811 251

215 7E0 797 225

215 9E20 1025 0


210b 7E10 2183 618

210b 9E0 1711 198

210b 7E0 2160 490

210c 9E20 1943 540

210c 7E20 1246 759


211c See Note 7E10 3418 5894

211c 10E10 153795 19900

211c 7E10 47103 3993


213b 7E10 2431 605

213b 9E0 2031 145

213b 7E0 1351 122

213c 9E20 2572 40

213c 7E20 1869 334

Averages

RL HS Sample

7psi E0 1260 149 6

9psi E0 1253 212 6

7psi E10 1538 282 6

10psi E10 1284 201 6

7psi E20 1558 547 2

9psi E20 2035 198 6




Tank Top

Can Inlet

Veh Eng RL Tru-HS



222c 7E20 683 00 E-77-2bc


19







performance pattern



















0

200

400

600

800

1000

1200

1400

1600


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

9

6

7

2

4

6

7

6

7

6

9

6

11



20







0

500

1000

1500

2000

2500

3000

3500


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

13801

11



21

Table 9


Veh Eng



9E0 4685 --- --- --- E-77


9E0 1504 --- --- ---


202216 See Note 1 7E10 3975 3550 3621 11146

202216 9E0 3270 2667 2746 8683

202216 7E0 2117 2208 2081 6406

202216 9E20 4685 4526 4198 13409


204 7E10 12602 11652 11652 35906

204 9E0 6283 5810 5770 17863

204 7E0 3672 2877 2936 9485

204 9E20 11034 9606 9812 30452


205 7E10 17834 17150 15239 50223

205 9E0 4995 4810 5072 14877 E-77-2

205 7E0 3830 3654 3670 11154

205 9E20 17752 16900 16802 51454


207 7E10 10865 8120 8236 27221

207 9E0 4064 3373 3080 10517

207 7E0 3975 3026 2689 9690

207 9E20 15480 13702 13605 42787


207L See Note 2 7E10 21342 --- --- 21342


206b 7E10 25826 22585 21440 69850

206b 9E0 15000 12856 12508 40364

206b 7E0 11719 9312 8903 29933

206c 9E20 19585 17878 17010 54473

206c 7E20 19439 17081 15677 52197


207c See Note 2 7E10 70847 --- --- ---

207c 10E10 105198 --- --- ---

207c 7E10 70668 --- --- ---


208b 7E10 7806 5104 4494 17405

208b 9E0 7780 5672 5194 18646

208b 7E0 4221 4194 4760 13175

208c 9E20 5065 3632 3319 12015

208c 7E20 5804 4338 3754 13895


209b 7E10 3831 3491 3235 10557

209b 9E0 3278 2505 2243 8026

209b 7E0 3541 2497 2181 8219

209c 9E20 4564 3383 3160 11107

209c 7E20 5877 3465 2704 12046


220b See Note 3 7E10 11776 16121 14831 42728

220b 9E0 67333 58848 70499 196680

220b 7E0 62187 62147 70419 194753


221b 7E10 8947 6767 6180 21894

221b 9E0 7064 5437 5383 17884

221b 7E0 6030 5031 4870 15932

221c 9E20 7508 5847 5649 19004

221c 7E20 8172 5442 4988 18602

Averages


7psi E0 4675 9 13941 7

9psi E0 6072 9 18311 7

7psi E10 12530 7 33294 7

10psi E10 13833 7 138015 7

7psi E20 9823 4 24185 4

9psi E20 11570 7 31613 7










Day 1 Total

Tank Top

Can Inlet


22

Table 10



Veh Eng



211 7E10 2438 1838 1843 6119

211 9E0 1303 1158 1006 3467

211 7E0 2071 1002 874 3947

211 9E20 2850 2218 2034 7101


211L See Note 7E10 6783 --- --- 6783


212 7E10 1848 1002 758 3608

212 9E0 1005 708 574 2287

212 7E0 1016 712 570 2298

212 9E20 1310 833 750 2893


214 7E10 5242 3974 3944 13160

214 9E0 4559 3585 11017 19161

214 7E0 4943 3190 2815 10948

214 9E20 4709 4400 7518 16627


215 7E10 2247 2317 2675 7239

215 9E0 2021 1659 1763 5443

215 7E0 2483 2941 2888 8312

215 9E20 4168 4148 4506 12822


210b 7E10 4451 3883 3591 11925

210b 9E0 4078 3774 3583 11434

210b 7E0 2706 2666 2211 7583

210c 9E20 3523 2749 2977 9250

210c 7E20 3686 2836 2711 9233


213b 7E10 6028 5777 5889 17694

213b 9E0 3463 3284 2928 9675

213b 7E0 3578 2833 2765 9175

213c 9E20 6442 5293 4606 16342

213c 7E20 5019 5384 5461 15864

Averages


7psi E0 2799 6 7044 6

9psi E0 2738 6 8578 6

7psi E10 3709 6 9957 6

10psi E10 4016 6 29741 6

7psi E20 4352 2 12549 2

9psi E20 3833 6 10839 6


Day 1 Total



Veh Eng



222c 9E20 736 514 401 1651 E-77-2bc



23

Summary of Task 45














24

















emissions











12





25






from this test13



Table 11



1996 Cavalier

Test fuel Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)
















13


increase


26




27

Table 12




Test fuel

Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

2001 Dodge Caravan E10 109 213 104

2004 Toyota Camry E10 024 068 044











canister























28

















29






30









0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Pe

rme

ati

on

-m

gh

r

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10 psi E10 Fuel

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



7 psi E10 Fuel


31





0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel


32

Summary of Task 47


quality modelers

























This selected






14





33

Table 13

















Vehicle 206c

Type 72DHB

Test 7703


Net mass Net conc


1 Methane 00074-82-8 0000 0000 0 0

2 Ethylene 00074-85-1 1984 0066 0 0


4 Ethane 00074-84-0 0000 0000 0 0

5 Propene 00115-07-1 0000 0000 0 0

6 Propane 00074-98-6 24285 0770 0 0


8 Propyne 00074-99-7 0000 0000 0 0

9 2-Methylpropane 00075-28-5 101164 3244 2 2


11 13-Butadiene 00106-99-0 0428 0015 0 0

12 n-Butane 00106-97-8 320071 10262 6 6


14 t-2-Butene 00624-64-6 0000 0000 0 0

15 1-Butyne 00107-00-6 0000 0000 0 0

16 c-2-Butene 00590-18-1 30919 1027 1 1

17 3-Methyl-1-butene 00563-45-1 0000 0000 0 0



20 2-Methyl-1-butene 00563-46-2 62754 2084 1 1

21 n-Pentane 00109-66-0 335100 10819 6 7


23 t-2-Pentene 00646-04-8 162601 5400 3 3

24 33-Dimethyl-1-butene 00558-37-2 0000 0000 0 0

25 c-2-Pentene 00627-20-3 76704 2547 1 2

26 2-Methyl-2-butene 00513-35-9 152719 5071 3 3

72DHB

total


34




Table 14



4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


Species CAS No MIR

Composite VOC mg

Ozone mg




35




























compound)
















36





Table 15













previously thought

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


37

Acknowledgements











Steering Committee













David Lax API












38






test


39


Vehicle 206c

Reactivity Results





206c 90E20 Static (86) Perm 091509 7685 702 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 091609 7689 1729 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 091709 25795 3308 020

True HS 858 010

72 DHB 65-105 092909 7703

Day 1 19585 000

Day 2 17878 150

Day 3 17010 1000

70E20 Static (86) Perm 101309 7724 938 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 101409 7727 2307 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 102109 25806 5187 000

True HS 1063 000

72 DHB 65-105 111709 7779

Day 1 19439 000

Day 2 17081 020

Day 3 15677 080

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


40

0

20

40

60

80

100

120

140

160

180

200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7685

7 psi E20 - 7724

0

50

100

150

200

250

300

350

400

450

500

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7689

7 psi E20 - 7727


41

0

100

200

300

400

500

600

700

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25795

7 psi E20 - 25806


0

1000

2000

3000

4000

5000

6000

7000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7703

7 psi E20 - 7779


42


Vehicle 208c

Reactivity Results





208c 90E20 Static (86) Perm 092209 7695 219 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092309 7699 396 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 092409 25798 2415 000

True HS 269 000

72 DHB 65-105 100609 7713

Day 1 5065 000

Day 2 3632 000

Day 3 3319 000

70E20 Static (86) Perm 110309 7750 184 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110409 7755 525 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110509 25812 2785 000

True HS 205 000

72 DHB 65-105 120809 7817

Day 1 5804 000

Day 2 4338 000

Day 3 3754 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

Vehicle 208c


43

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7695

7 psi E20 - 7750

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7699

7 psi E20 - 7755


44

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25798

7 psi E20 - 25812


0

200

400

600

800

1000

1200

1400

1600

1800

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7713

7 psi E20 - 7817


45


Vehicle 209c

Reactivity Results





209c 90E20 Static (86) Perm 100109 7708 420 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 100209 7710 721 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 100509 25802 3671 000

True HS 719 000

72 DHB 65-105 110309 7753

Day 1 4564 020

Day 2 3383 030

Day 3 3160 090

70E20 Static (86) Perm 120209 7806 235 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 120309 7809 411 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 120409 25819 2560 000

True HS 282 000

72 DHB 65-105 011210 7856

Day 1 6107 000

Day 2 3160 010

Day 3 2581 040

72 DHB 65-105 020910 7881

Day 1 5647 000

Day 2 3771 000

Day 3 2827 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90

Vehicle 209c


46

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7708

7 psi E20 - 7806

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7710

7 psi E20 - 7809


47

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25802

7 psi E20 - 25819


0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7753

7 psi E20 - 7856



48


Vehicles 210c

Reactivity Results





210c 90E20 Static (86) Perm 092409 7701 180 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092509 7702 327 000

Press Incr 00

Prs+Fuel Incr 46

Dynamic RL 092809 25799 1943 000

True HS 540 000

72 DHB 65-105 101309 7725

Day 1 3523 030

Day 2 2749 160

Day 3 2977 700

70E20 Static (86) Perm 110509 7758 152 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110609 7761 340 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110909 25813 1246 000

True HS 759 000

72 DHB 65-105 121509 7826

Day 1 3686 050

Day 2 2836 070

Day 3 2711 120

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


49

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7701

7 psi E20 - 7758

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7702

7 psi E20 - 7761


50

0

50

100

150

200

250

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25799

7 psi E20 - 25813


0

200

400

600

800

1000

1200

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7725

7 psi E20 - 7826


51


Vehicle 213c

Reactivity Results





213c 90E20 Static (86) Perm 100809 7718 374 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 102909 7746 751 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 111309 25816 2572 082

True HS 40 005

72 DHB 65-105 120109 7803

Day 1 6442 000

Day 2 5293 000

Day 3 4606 000

70E20 Static (86) Perm 121609 7828 229 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 121709 7830 651 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 121809 25821 1869 000

True HS 334 000

72 DHB 65-105 020210 7872

Day 1 5019 000

Day 2 5384 000

Day 3 5461 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


52

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7744

7 psi E20 - 7828

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7746

7 psi E20 - 7830


53

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25816

7 psi E20 - 25821


0

200

400

600

800

1000

1200

1400

1600

1800

2000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7803

7 psi E20 - 7872


54


Vehicle 221c

Reactivity Results





221c 90E20 Static (86) Perm 122409 7840 265 000

Press Incr 6165

Prs+Fuel Incr 6734

Static (105) Perm 122309 7838 723 000

Press Incr 10328

Prs+Fuel Incr 10971

Dynamic RL 122809 25824 1266 000

True HS 95 000

72 DHB 65-105 011910 7859

Day 1 7508 040

Day 2 5847 150

Day 3 5649 400

70E20 Static (86) Perm 020410 7875 394 000

Press Incr 5312

Prs+Fuel Incr 5061

Static (105) Perm 020510 7877 630 000

Press Incr 7462

Prs+Fuel Incr 7806

Dynamic RL 020810 25828 619 000

True HS 25 000

72 DHB 65-105 030210 7906

Day 1 8172 000

Day 2 5442 000

Day 3 4988 070

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


55

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7840

7 psi E20 - 7875

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7838

7 psi E20 - 7877


56

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25824

7 psi E20 - 25828


0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7859

7 psi E20 - 7906


57


Vehicle 222c

Reactivity Results








222c 90E20 Static (86) Perm 122909 7843 92 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 123009 7847 69 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 011510 25827 447 000

True HS 76 000

72 DHB 65-105 020210 7871

Day 1 736 000

Day 2 514 000

Day 3 401 040

70E20 Static (86) Perm 022510 7898 69 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 022610 7901 71 000

Press Incr 00

Prs+Fuel Incr 00

72 DHB 65-105 030910 7916

Day 1 655 000

Day 2 427 030

Day 3 395 030

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


58

0

2

4

6

8

10

12

14

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7843

7 psi E20 - 7898

0

2

4

6

8

10

12

14

16

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7847

7 psi E20 - 7901


59

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25827

7 psi E20 -25830


0

50

100

150

200

250

300

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7871

7 psi E20 - 7916


60








61


Vehicle 207c

Reactivity Results





207c 100E10 Static Perm 082709 7661 6102 000


Dynamic RL 102009 25805 9997 000


24 DHB 65-105 090309 7672

Tank Top (020)

65125 000

70E10 Static Perm 091809 7693 5235 000


Dynamic RL 100209 25801 27694 000


24 DHB 65-105 102709 7741

Tank Top (020) 70847 000

100E10 Static Perm 111809 7781 2325 000


Dynamic RL 111909 25817 9375 000


24 DHB 65-105 112409 7794

Can Inlet (020) 105198 000

70E10 Static Perm 120909 7819 1448 000


Dynamic RL 121009 25820 11146 000


24 DHB 65-105 122909 7844

Can Inlet (020) 70668 000


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


62

0

200

400

600

800

1000

1200

1400

1600

1800

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7661

7 psi E10 - 7693

0

100

200

300

400

500

600

700

800

900

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7781

7 psi E10 - 7819


63

0

500

1000

1500

2000

2500

3000

3500

4000

4500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25805

7 psi E10 - 25801


0

500

1000

1500

2000

2500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25817

7 psi E10 - 25820



64

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7672

7 psi E10 - 7741

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7794

7 psi E10 - 7844


65


Vehicle 211c

Reactivity Results





211c 100E10 Static Perm 081209 7636 1925 000


Dynamic RL 081309 25788 8204 000


24 DHB 65-105 081909 7648

Tank Top (020) 89107 3560

70E10 Static Perm 090209 7669 4491 000


Dynamic RL 090309 25793 3418 000


24 DHB 65-105 091009 7681

Tank Top (020) 28842 000

100E10 Static Perm 101909 7732 2247 000


Dynamic RL 102909 25809 153795 000


24 DHB 65-105 111109 7769

Can Inlet (020) 115481 550

70E10 Static (86) Perm 112409 7793 2170 000


Dynamic RL 112509 25818 47103 082



Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


66

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7636

7 psi E10 - 7669

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7732

7 psi E10 - 7793


67

0

500

1000

1500

2000

2500

3000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25788

7 psi E10 - 25793


0

2000

4000

6000

8000

10000

12000

14000

16000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25809

7 psi E10 - 25818



68

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7648

7 psi E10 - 7681

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7769

7 psi E10 - 7836


69









1 Permeation













16




70












unit time

























17





Determination


71





permeation rate






concentrations





















3 Hot Soak19


described above




19





72






4 Diurnal Test



















retest is indicated







73


EXCELrsquoscopy














0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

SH

ED

Mass -

mg

Test Time - minutes



Test 7710

Pump Activated




Tank Pressurized

Slope = 705 mghr

Slope = 706 mghr

Slope = 761 mghr



74

























real-time records


75

















road speed






20






Loss SHED SHEDSHED


76



















period






0

10

20

30

40

50

60

70

80


Spe

ed -

mph








77






permeation












0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100 120

Co

rre

cte

d T

ota

l Fu

el C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


Test 25802



2936 mg

3793 mg

3356 mg

True HS = 437 mghr


Results


78

Diurnal Test








milligrams)




two SAE papers






















12







79







and 18th





















80







81

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


82

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4093 59307

Toluene 00108-88-3 393 1167 45800


n-Pentane 00109-66-0 121 648 7871


n-Butane 00106-97-8 108 607 6533

Cyclohexane 00110-82-7 114 552 6281


Benzene 00071-43-2 069 528 3668

Propane 00074-98-6 046 424 1938

t-2-Pentene 00646-04-8 1047 399 41785

n-Heptane 00142-82-5 097 378 3649


n-Hexane 00110-54-3 113 371 4207


2-Methyl-2-butene 00513-35-9 1420 284 40369



c-2-Pentene 00627-20-3 1028 188 19331



3-Methylpentane 00096-14-0 169 170 2882

2-Methyl-1-butene 00563-46-2 638 160 10232

2-Methylpropane 00075-28-5 118 152 1783



ortho-Xylene 00095-47-6 758 133 10090

2-Methylhexane 00591-76-4 109 119 1287

n-Octane 00111-65-9 080 113 0900

t-2-Hexene 04050-45-7 855 109 9344

n-Propylbenzene 00103-65-1 196 089 1748


23-Dimethylbutane 00079-29-8 090 080 0716

Cyclopentene 00142-29-0 669 076 5114

3-Methyl-c-2-pentene 00922-62-3 1252 073 9169






3-Methyl-t-2-pentene 00616-12-6 1166 064 7473

2-Methyl-2-pentene 00625-27-4 1103 064 7008

3-Methylheptane 00589-81-1 112 061 0683

c-2-Butene 00590-18-1 1426 059 8461




83

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








2-Methylheptane 00592-27-8 097 044 0430





Ethylbenzene 00100-41-4 296 028 0831



24-Dimethylhexane 00589-43-5 161 014 0230

22-Dimethylbutane 00075-83-2 111 013 0147

n-Undecane 01120-21-4 052 003 0017

Total 1620 5411 3340


continued


84

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7732 112029

Toluene 00108-88-3 393 2826 110931


n-Pentane 00109-66-0 121 1669 20279

n-Butane 00106-97-8 108 1531 16491


Benzene 00071-43-2 069 1317 9145


n-Hexane 00110-54-3 113 984 11164

n-Heptane 00142-82-5 097 955 9227

t-2-Pentene 00646-04-8 1047 867 90854



2-Methyl-2-butene 00513-35-9 1420 764 108513

22-DiMeHexane 00590-73-8 094 648 6097

3-Me-1-Hexene 03404-61-3 427 597 25518


2-Methylpropane 00075-28-5 118 483 5687


3-Methylpentane 00096-14-0 169 423 7157

c-2-Pentene 00627-20-3 1028 398 40907

2-Methyl-1-butene 00563-46-2 638 389 24834


Propane 00074-98-6 046 301 1376

ortho-Xylene 00095-47-6 758 277 21014

n-Octane 00111-65-9 080 263 2092



t-2-Hexene 04050-45-7 855 232 19857



23-Dimethylbutane 00079-29-8 090 188 1693

2-Methylhexane 00591-76-4 109 184 1996

c-2-Butene 00590-18-1 1426 177 25239


Ethylbenzene 00100-41-4 296 169 5008


n-Propylbenzene 00103-65-1 196 159 3125

3-Methyl-t-2-pentene 00616-12-6 1166 154 17969

Cyclopentene 00142-29-0 669 132 8836

Cyclopentane 00287-92-3 224 132 2955

2-Methylheptane 00592-27-8 097 126 1223

3-Methyl-c-2-pentene 00922-62-3 1252 120 14989





85

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 112 12354



3-Methylheptane 00589-81-1 112 094 1061









24-Dimethylhexane 00589-43-5 161 057 0919

4-Methyloctane 02216-34-4 085 053 0449

22-Dimethylbutane 00075-83-2 111 051 0570


Unknown 1 340 047 1585




3-Methyloctane 02216-33-3 088 038 0337

n-Nonane 00111-84-2 068 035 0239





Total 3466 11867 3424


continued


86

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7327 106160

Toluene 00108-88-3 393 3583 140646


n-Heptane 00142-82-5 097 1994 19258



3-Me-1-Hexene 03404-61-3 427 1676 71615

Benzene 00071-43-2 069 1585 11004

n-Pentane 00109-66-0 121 1566 19031

n-Butane 00106-97-8 108 1325 14268

n-Hexane 00110-54-3 113 1227 13926



22-DiMeHexane 00590-73-8 094 1009 9495



2-Methyl-2-butene 00513-35-9 1420 747 105970

t-2-Pentene 00646-04-8 1047 620 64956


3-Methylpentane 00096-14-0 169 504 8518


Indan 00496-11-7 323 491 15896



Unknown 16 362 481 17425


c-2-Pentene 00627-20-3 1028 439 45108


2-Methylpropane 00075-28-5 118 426 5010

n-Octane 00111-65-9 080 421 3351

2-Methyl-1-butene 00563-46-2 638 400 25494

ortho-Xylene 00095-47-6 758 365 27632

Ethylbenzene 00100-41-4 296 362 10735

2-Methylheptane 00592-27-8 097 360 3479

3-Methylheptane 00589-81-1 112 308 3463



2-Methylhexane 00591-76-4 109 256 2775


23-Dimethylbutane 00079-29-8 090 243 2181


Unknown 22 362 215 7784






87

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




n-Nonane 00111-84-2 068 189 1293


n-Propylbenzene 00103-65-1 196 187 3660

Cyclopentene 00142-29-0 669 181 12085

3-Methyl-t-2-pentene 00616-12-6 1166 177 20606

3-Methyl-c-2-pentene 00922-62-3 1252 163 20443







14-Diethylbenzene 00105-05-5 439 117 5152

c-2-Butene 00590-18-1 1426 115 16375



t-2-Hexene 04050-45-7 855 107 9180

22-Dimethylbutane 00075-83-2 111 103 1150

2-Methyl-2-pentene 00625-27-4 1103 096 10613

4-Methyl-t-2-pentene 00674-76-0 804 094 7554


n-Decane 00124-18-5 059 072 0424


Unknown 1 362 044 1580

Total 4582 17092 3730


continued


88

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 101748 1474297


n-Pentane 00109-66-0 121 33510 407124

n-Butane 00106-97-8 108 32007 344688

Toluene 00108-88-3 393 27947 1096913


Benzene 00071-43-2 069 20586 142938

n-Hexane 00110-54-3 113 18393 208697

n-Heptane 00142-82-5 097 17284 166926

t-2-Pentene 00646-04-8 1047 16260 1702998

2-Methyl-2-butene 00513-35-9 1420 15272 2167853


3-Me-1-Hexene 03404-61-3 427 10391 444084

2-Methylpropane 00075-28-5 118 10116 119030


22-DiMeHexane 00590-73-8 094 8200 77181


c-2-Pentene 00627-20-3 1028 7670 788622

3-Methylpentane 00096-14-0 169 7668 129648

2-Methyl-1-butene 00563-46-2 638 6275 400280


t-2-Hexene 04050-45-7 855 4165 356031

2-Methylhexane 00591-76-4 109 3643 39538




n-Octane 00111-65-9 080 3249 25870


c-2-Butene 00590-18-1 1426 3092 440893


23-Dimethylbutane 00079-29-8 090 2952 26532

Cyclopentene 00142-29-0 669 2922 195335

3-Methyl-t-2-pentene 00616-12-6 1166 2669 311214

Cyclopentane 00287-92-3 224 2540 56827

Propane 00074-98-6 046 2428 11101

3-Methyl-c-2-pentene 00922-62-3 1252 2277 285007


2-Methyl-2-pentene 00625-27-4 1103 1964 216725




ortho-Xylene 00095-47-6 758 1425 107970






89

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 1271 12292

Ethylbenzene 00100-41-4 296 1237 36651

22-Dimethylbutane 00075-83-2 111 1166 12955



3-Methylheptane 00589-81-1 112 1021 11484




n-Propylbenzene 00103-65-1 196 817 16017





n-Nonane 00111-84-2 068 489 3336

Unknown 1 333 488 16281



4-Methyloctane 02216-34-4 085 329 2788



3-Methyloctane 02216-33-3 088 287 2536



33-Dimethylhexane 00563-16-6 115 214 2470

Ethylene 00074-85-1 888 198 17628


1-Octene 00111-66-0 314 170 5347

c-2-Heptene 06443-92-1 708 147 10435

Unknown 8 333 147 4886


Unknown 5 333 132 4386

1-Nonene 00124-11-8 249 122 3031

Unknown 6 333 121 4021

Unknown 16 333 120 4008

Unknown 9 333 118 3924



Indan 00496-11-7 323 104 3374

Styrene 00100-42-5 166 095 1585


continued


90

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 3 333 072 2404


n-Decane 00124-18-5 059 067 0395



Unknown 14 333 055 1850

1-Heptene 00592-76-7 429 051 2194

13-Butadiene 00106-99-0 1245 043 5325


4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


continued


91

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2884 41793


Toluene 00108-88-3 393 1217 47766

Benzene 00071-43-2 069 747 5186




n-Pentane 00109-66-0 121 684 8305

n-Butane 00106-97-8 108 611 6584



n-Hexane 00110-54-3 113 498 5652


n-Heptane 00142-82-5 097 475 4583

Propane 00074-98-6 046 468 2137



2-Methyl-2-butene 00513-35-9 1420 356 50602

t-2-Pentene 00646-04-8 1047 347 36348

ortho-Xylene 00095-47-6 758 323 24490


c-2-Butene 00590-18-1 1426 312 44524



n-Octane 00111-65-9 080 289 2300

n-Propylbenzene 00103-65-1 196 272 5339

Cyclohexane 00110-82-7 114 267 3042

2-Methylhexane 00591-76-4 109 267 2898

23-Dimethylbutane 00079-29-8 090 259 2328

Ethylbenzene 00100-41-4 296 228 6765

t-2-Hexene 04050-45-7 855 227 19378




Cyclopentane 00287-92-3 224 167 3744


3-Methyl-t-2-pentene 00616-12-6 1166 154 17932

2-Methyl-1-butene 00563-46-2 638 150 9546

3-Methyl-c-2-pentene 00922-62-3 1252 146 18246

Cyclopentene 00142-29-0 669 145 9721

2-Methylheptane 00592-27-8 097 144 1394


c-2-Pentene 00627-20-3 1028 135 13873





92

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 131 1478


3-Methylpentane 00096-14-0 169 123 2086


2-Methyl-2-pentene 00625-27-4 1103 122 13422

24-Dimethylhexane 00589-43-5 161 103 1653

Indan 00496-11-7 323 087 2810

22-Dimethylbutane 00075-83-2 111 086 0952

n-Nonane 00111-84-2 068 085 0583












14-Diethylbenzene 00105-05-5 439 045 1982


4-Methyloctane 02216-34-4 085 043 0366

4-Methyl-t-2-pentene 00674-76-0 804 041 3322

Unknown 1 412 034 1408


2-Methylpropane 00075-28-5 118 029 0340

n-Undecane 01120-21-4 052 029 0150





3-Methyloctane 02216-33-3 088 020 0174

Total 2183 9104 4170


continued


93

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10102 146374

Toluene 00108-88-3 393 4080 160133

3-Methylnonane 05911-04-6 066 3338 21890




n-Pentane 00109-66-0 121 2300 27949

Benzene 00071-43-2 069 2108 14635


n-Butane 00106-97-8 108 2075 22348

n-Heptane 00142-82-5 097 1777 17164

n-Hexane 00110-54-3 113 1565 17760


t-2-Pentene 00646-04-8 1047 1024 107279

2-Methyl-2-butene 00513-35-9 1420 1009 143288

Cyclohexane 00110-82-7 114 926 10529





3-Methylpentane 00096-14-0 169 568 9606

c-2-Pentene 00627-20-3 1028 498 51245

2-Methyl-1-butene 00563-46-2 638 495 31574



n-Octane 00111-65-9 080 454 3615



ortho-Xylene 00095-47-6 758 403 30538

2-Methylhexane 00591-76-4 109 350 3798

n-Propylbenzene 00103-65-1 196 345 6759

Ethylbenzene 00100-41-4 296 312 9251

t-2-Hexene 04050-45-7 855 307 26270

2-Methylpropane 00075-28-5 118 262 3081

Cyclopentane 00287-92-3 224 250 5589


Cyclopentene 00142-29-0 669 211 14108

Propane 00074-98-6 046 192 0880

3-Methyl-t-2-pentene 00616-12-6 1166 192 22393

n-Nonane 00111-84-2 068 186 1270


23-Dimethylbutane 00079-29-8 090 179 1613






94

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 153 19093

2-Methyl-2-pentene 00625-27-4 1103 141 15538


24-Dimethylhexane 00589-43-5 161 132 2114


2-Methylheptane 00592-27-8 097 128 1233

4-Methyloctane 02216-34-4 085 125 1064

c-2-Butene 00590-18-1 1426 121 17277



3-Methylheptane 00589-81-1 112 109 1223

Indan 00496-11-7 323 104 3361





n-Decane 00124-18-5 059 065 0385



3-Methyloctane 02216-33-3 088 061 0539

13-Diethylbenzene 00141-93-5 708 056 3990




Unknown 1 330 049 1606

22-Dimethylbutane 00075-83-2 111 049 0540


n-Undecane 01120-21-4 052 043 0226

c-2-Heptene 06443-92-1 708 038 2676



Unknown 8 330 025 0836

066 Total 5472 18251 3335


continued


95

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10462 151590

Toluene 00108-88-3 393 5022 197121






n-Heptane 00142-82-5 097 2541 24542

n-Pentane 00109-66-0 121 2430 29518

Benzene 00071-43-2 069 2379 16519

n-Butane 00106-97-8 108 2172 23395

n-Hexane 00110-54-3 113 1979 22456



Cyclohexane 00110-82-7 114 1349 15348




2-Methyl-2-butene 00513-35-9 1420 940 133406

t-2-Pentene 00646-04-8 1047 857 89767

n-Octane 00111-65-9 080 856 6816



3-Methylpentane 00096-14-0 169 706 11929

n-Propylbenzene 00103-65-1 196 696 13630

2-Methyl-1-butene 00563-46-2 638 655 41772


Propane 00074-98-6 046 515 2355

ortho-Xylene 00095-47-6 758 506 38317

Ethylbenzene 00100-41-4 296 497 14716

3-Methylheptane 00589-81-1 112 480 5394

c-2-Pentene 00627-20-3 1028 476 48903

2-Methylhexane 00591-76-4 109 425 4611

2-Methylpropane 00075-28-5 118 404 4753

3-Methyl-c-2-pentene 00922-62-3 1252 401 50144



t-2-Hexene 04050-45-7 855 369 31567

n-Nonane 00111-84-2 068 355 2423

2-Methyl-2-pentene 00625-27-4 1103 349 38516


Cyclopentane 00287-92-3 224 322 7198

2-Methylheptane 00592-27-8 097 317 3071

c-2-Butene 00590-18-1 1426 292 41607




96

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 22 363 272 9893


3-Methyl-t-2-pentene 00616-12-6 1166 269 31312

Methane 00074-82-8 001 265 0037


3-Methyloctane 02216-33-3 088 255 2252






Cyclopentene 00142-29-0 669 208 13880

4-Methyloctane 02216-34-4 085 199 1691


23-Dimethylbutane 00079-29-8 090 188 1688

n-Decane 00124-18-5 059 168 0994


Indan 00496-11-7 323 160 5191



Unknown 18 363 147 5331

c-2-Heptene 06443-92-1 708 137 9666



24-Dimethylhexane 00589-43-5 161 123 1980




22-Dimethylbutane 00075-83-2 111 038 0418

Total 7165 26481 3696


continued


97

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 115502 1673600



n-Butane 00106-97-8 108 26699 287520

n-Pentane 00109-66-0 121 26567 322768

Toluene 00108-88-3 393 23849 936067

n-Heptane 00142-82-5 097 21212 204862

n-Hexane 00110-54-3 113 18520 210141

Benzene 00071-43-2 069 17238 119691



Cyclohexane 00110-82-7 114 9320 106002

t-2-Pentene 00646-04-8 1047 9137 956959

2-Methyl-2-butene 00513-35-9 1420 9120 1294599



3-Methylpentane 00096-14-0 169 6866 116094


c-2-Pentene 00627-20-3 1028 4504 463080


n-Octane 00111-65-9 080 4099 32639

2-Methyl-1-butene 00563-46-2 638 3977 253652


2-Methylhexane 00591-76-4 109 3789 41114



23-Dimethylbutane 00079-29-8 090 2988 26852

t-2-Hexene 04050-45-7 855 2686 229656

Cyclopentane 00287-92-3 224 2314 51777


Propane 00074-98-6 046 2085 9531



2-Methylpropane 00075-28-5 118 1854 21813

Cyclopentene 00142-29-0 669 1830 122352

3-Methyl-t-2-pentene 00616-12-6 1166 1808 210844



2-Methylheptane 00592-27-8 097 1688 16323

3-Methyl-c-2-pentene 00922-62-3 1252 1584 198290

c-2-Butene 00590-18-1 1426 1517 216368



2-Methyl-2-pentene 00625-27-4 1103 1493 164767




98

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 1325 14903

24-Dimethylhexane 00589-43-5 161 1322 21223

ortho-Xylene 00095-47-6 758 1234 93462

Ethylbenzene 00100-41-4 296 1170 34667




n-Propylbenzene 00103-65-1 196 978 19157


22-Dimethylbutane 00075-83-2 111 889 9880


n-Nonane 00111-84-2 068 734 5008




c-2-Heptene 06443-92-1 708 629 44542





4-Methyloctane 02216-34-4 085 439 3726



3-Methyloctane 02216-33-3 088 311 2751

Unknown 1 291 281 8158

33-Dimethylhexane 00563-16-6 115 274 3158


Ethylene 00074-85-1 888 238 21141

1-Octene 00111-66-0 314 226 7093

Unknown 5 291 226 6565




1-Butyne 00107-00-6 605 214 12957


Unknown 8 291 191 5566


1-Nonene 00124-11-8 249 155 3876

Indan 00496-11-7 323 134 4328




continued


99

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 291 093 2704

t-4-Octene 14850-23-8 469 088 4141



n-Decane 00124-18-5 059 072 0424


Unknown 6 291 063 1842

t-3-Heptene 14686-14-7 617 058 3603

Unknown 3 291 050 1460

13-Butadiene 00106-99-0 1245 050 6187

c- amp t-4-Nonene 02198-23-4 442 039 1719


1-Heptene 00592-76-7 429 035 1513

n-Undecane 01120-21-4 052 025 0130


Total 48454 142309 2937



100

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

- No Ethanol

Vehicle 208c


101

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


3-Me-1-Hexene 03404-61-3 427 193 8262

Toluene 00108-88-3 393 158 6219


n-Heptane 00142-82-5 097 146 1414


22-DiMeHexane 00590-73-8 094 136 1277

n-Pentane 00109-66-0 121 131 1597



Benzene 00071-43-2 069 109 0753

n-Butane 00106-97-8 108 101 1090

n-Octane 00111-65-9 080 058 0466

n-Hexane 00110-54-3 113 054 0613

2-Methylheptane 00592-27-8 097 048 0466

2-Methylpropane 00075-28-5 118 047 0553


n-Nonane 00111-84-2 068 041 0277

n-Propylbenzene 00103-65-1 196 033 0656

2-Methyl-2-pentene 00625-27-4 1103 032 3544

ortho-Xylene 00095-47-6 758 030 2297


3-Methyl-c-2-pentene 00922-62-3 1252 026 3231



Cyclopentene 00142-29-0 669 022 1454



t-2-Hexene 04050-45-7 855 018 1569

3-Methyl-t-2-pentene 00616-12-6 1166 018 2140

Ethylbenzene 00100-41-4 296 018 0544

t-2-Pentene 00646-04-8 1047 018 1912

3-Methylpentane 00096-14-0 169 018 0298



2-Methylhexane 00591-76-4 109 015 0159

24-Dimethylhexane 00589-43-5 161 013 0203

2-Methyl-2-butene 00513-35-9 1420 011 1589

c-2-Butene 00590-18-1 1426 009 1344



Total 260 956 3672




102

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1745 25291


n-Heptane 00142-82-5 097 769 7424


Benzene 00071-43-2 069 594 4125

Toluene 00108-88-3 393 461 18075

n-Pentane 00109-66-0 121 365 4438


n-Hexane 00110-54-3 113 287 3251

n-Butane 00106-97-8 108 273 2945



22-DiMeHexane 00590-73-8 094 172 1616

2-Methyl-2-butene 00513-35-9 1420 170 24078

3-Me-1-Hexene 03404-61-3 427 156 6681


t-2-Pentene 00646-04-8 1047 139 14606



Cyclopentane 00287-92-3 224 118 2649

n-Octane 00111-65-9 080 108 0863

3-Methylpentane 00096-14-0 169 108 1823


2-Methylpropane 00075-28-5 118 094 1110



c-2-Pentene 00627-20-3 1028 085 8778

3-Methylheptane 00589-81-1 112 085 0956

n-Nonane 00111-84-2 068 084 0576


3-Methyl-t-2-pentene 00616-12-6 1166 078 9114


2-Methyl-1-butene 00563-46-2 638 056 3594

c-2-Butene 00590-18-1 1426 055 7872

ortho-Xylene 00095-47-6 758 051 3872



t-2-Hexene 04050-45-7 855 043 3697


Ethylbenzene 00100-41-4 296 036 1067


Cyclopentene 00142-29-0 669 029 1922






103

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 023 2569


3-Methyl-c-2-pentene 00922-62-3 1252 022 2706



22-Dimethylbutane 00075-83-2 111 010 0117




2-Methylhexane 00591-76-4 109 003 0037



Total 962 2919 3034


continued


104

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 964 37835

t-3-Heptene 14686-14-7 617 854 52708


n-Pentane 00109-66-0 121 709 8608

Benzene 00071-43-2 069 649 4509




3-Me-1-Hexene 03404-61-3 427 425 18160


22-DiMeHexane 00590-73-8 094 403 3797





4-Methyl-t-2-pentene 00674-76-0 804 349 28047

n-Butane 00106-97-8 108 347 3739

n-Hexane 00110-54-3 113 346 3922

n-Propylbenzene 00103-65-1 196 335 6568

n-Octane 00111-65-9 080 327 2601

3-Methylpentane 00096-14-0 169 304 5148


2-Methylhexane 00591-76-4 109 290 3146

n-Butylbenzene 00104-51-8 229 279 6386


Indan 00496-11-7 323 272 8810

t-2-Pentene 00646-04-8 1047 264 27657

Ethylbenzene 00100-41-4 296 257 7618





2-Methyl-2-butene 00513-35-9 1420 223 31617


2-Methyl-1-butene 00563-46-2 638 193 12303


n-Nonane 00111-84-2 068 187 1276


c-2-Pentene 00627-20-3 1028 156 16054

t-2-Hexene 04050-45-7 855 154 13191

ortho-Xylene 00095-47-6 758 148 11239




105

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



13-Butadiene 00106-99-0 1245 145 18006



2-Methylheptane 00592-27-8 097 134 1296


23-Dimethylbutane 00079-29-8 090 128 1152

4-Methyloctane 02216-34-4 085 127 1079

Unknown 5 422 113 4773





2-Methylpropane 00075-28-5 118 097 1147

Unknown 9 422 092 3896

3-Methyl-t-2-pentene 00616-12-6 1166 076 8865

3-Methyl-c-2-pentene 00922-62-3 1252 074 9238


Cyclopentene 00142-29-0 669 065 4325


14-Diethylbenzene 00105-05-5 439 059 2575

24-Dimethylhexane 00589-43-5 161 052 0828

3-Methyloctane 02216-33-3 088 048 0425





22-Dimethylbutane 00075-83-2 111 009 0104

Total 2199 9732 4426


continued


106

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 40269 583488


n-Pentane 00109-66-0 121 6604 80237

n-Butane 00106-97-8 108 5757 61995


n-Heptane 00142-82-5 097 5013 48416

n-Hexane 00110-54-3 113 4359 49459

Toluene 00108-88-3 393 4128 162007


Benzene 00071-43-2 069 3151 21876


2-Methyl-2-butene 00513-35-9 1420 2458 348891

t-2-Pentene 00646-04-8 1047 2391 250449

2-Methylpropane 00075-28-5 118 2367 27847

Cyclohexane 00110-82-7 114 2317 26356


3-Methylpentane 00096-14-0 169 1942 32835



n-Octane 00111-65-9 080 1226 9760

c-2-Pentene 00627-20-3 1028 1186 121926


2-Methyl-1-butene 00563-46-2 638 1163 74158

2-Methylhexane 00591-76-4 109 1119 12144


t-2-Hexene 04050-45-7 855 759 64866

23-Dimethylbutane 00079-29-8 090 700 6289



2-Methylheptane 00592-27-8 097 569 5503

c-2-Butene 00590-18-1 1426 562 80095

Propane 00074-98-6 046 552 2525

Cyclopentane 00287-92-3 224 552 12353


3-Methyl-t-2-pentene 00616-12-6 1166 518 60429

3-Methylheptane 00589-81-1 112 482 5422

Cyclopentene 00142-29-0 669 479 32026

3-Methyl-c-2-pentene 00922-62-3 1252 469 58697



2-Methyl-2-pentene 00625-27-4 1103 422 46577







107

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Nonane 00111-84-2 068 349 2384

1-Butyne 00107-00-6 605 349 21088





24-Dimethylhexane 00589-43-5 161 299 4801

22-Dimethylbutane 00075-83-2 111 291 3238


ortho-Xylene 00095-47-6 758 271 20538

n-Propylbenzene 00103-65-1 196 263 5151

Ethylbenzene 00100-41-4 296 238 7052



4-Methyloctane 02216-34-4 085 223 1894




3-Methyloctane 02216-33-3 088 154 1363




33-Dimethylhexane 00563-16-6 115 109 1252

Unknown 8 276 087 2398



1-Octene 00111-66-0 314 081 2559


continued


108

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 276 066 1835

Unknown 1 276 065 1794





n-Decane 00124-18-5 059 049 0289

Unknown 5 276 045 1243

c-2-Heptene 06443-92-1 708 040 2835



1-Nonene 00124-11-8 249 019 0476

Total 12981 36292 2796


continued


109

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1522 22047

Toluene 00108-88-3 393 372 14601




n-Butane 00106-97-8 108 252 2718

n-Pentane 00109-66-0 121 229 2778


n-Undecane 01120-21-4 052 208 1088

n-Decane 00124-18-5 059 202 1193

n-Heptane 00142-82-5 097 197 1903

n-Hexane 00110-54-3 113 145 1643

1-Butyne 00107-00-6 605 142 8563

Benzene 00071-43-2 069 136 0943

Cyclohexane 00110-82-7 114 117 1336







3-Methylpentane 00096-14-0 169 077 1305


2-Methylpropane 00075-28-5 118 075 0882

n-Nonane 00111-84-2 068 072 0492

n-Propylbenzene 00103-65-1 196 070 1366



2-Methyl-2-butene 00513-35-9 1420 068 9604

23-Dimethylbutane 00079-29-8 090 061 0546

n-Octane 00111-65-9 080 060 0475


Cyclopentene 00142-29-0 669 054 3587



t-2-Pentene 00646-04-8 1047 046 4844

ortho-Xylene 00095-47-6 758 044 3308

3-Methyl-c-2-pentene 00922-62-3 1252 043 5429

2-Methylheptane 00592-27-8 097 042 0408

3-Methyl-t-2-pentene 00616-12-6 1166 042 4901


2-Methyl-2-pentene 00625-27-4 1103 039 4343


3-Methylheptane 00589-81-1 112 033 0371




110

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 030 3052


Unknown 22 305 027 0835

2-Methylhexane 00591-76-4 109 027 0296


Ethylbenzene 00100-41-4 296 024 0697

24-Dimethylhexane 00589-43-5 161 022 0354




22-Dimethylbutane 00075-83-2 111 011 0126

2-Methyl-1-butene 00563-46-2 638 006 0396


Total 691 2138 3094


continued


111

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1871 27109


Toluene 00108-88-3 393 522 20484


n-Heptane 00142-82-5 097 365 3521

n-Pentane 00109-66-0 121 351 4259

n-Butane 00106-97-8 108 298 3214







Benzene 00071-43-2 069 198 1372

n-Hexane 00110-54-3 113 173 1961



t-2-Pentene 00646-04-8 1047 126 13202

n-Octane 00111-65-9 080 116 0924

2-Methyl-2-butene 00513-35-9 1420 115 16378

Cyclohexane 00110-82-7 114 108 1232


3-Methylpentane 00096-14-0 169 101 1707

2-Methylpropane 00075-28-5 118 075 0884

2-Methylhexane 00591-76-4 109 059 0643

ortho-Xylene 00095-47-6 758 054 4058

2-Methyl-1-butene 00563-46-2 638 053 3361

c-2-Pentene 00627-20-3 1028 043 4388


066 Total 755 2232 2957




112

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 968 37976


n-Pentane 00109-66-0 121 522 6345

n-Heptane 00142-82-5 097 514 4964

Benzene 00071-43-2 069 512 3553





n-Propylbenzene 00103-65-1 196 434 8506




n-Octane 00111-65-9 080 341 2712

n-Hexane 00110-54-3 113 275 3123

n-Nonane 00111-84-2 068 271 1848

13-Butadiene 00106-99-0 1245 247 30791




2-Methylheptane 00592-27-8 097 231 2232

2-Methyl-1-butene 00563-46-2 638 227 14471

c-2-Pentene 00627-20-3 1028 221 22769

n-Butane 00106-97-8 108 194 2085

24-Dimethylhexane 00589-43-5 161 183 2939


Cyclohexane 00110-82-7 114 162 1841


23-Dimethylbutane 00079-29-8 090 150 1345

n-Decane 00124-18-5 059 136 0802


3-Methylpentane 00096-14-0 169 131 2214

2-Methylhexane 00591-76-4 109 104 1128


t-2-Pentene 00646-04-8 1047 070 7355

22-Dimethylbutane 00075-83-2 111 066 0737

3-Methylheptane 00589-81-1 112 066 0741

2-Methyl-2-butene 00513-35-9 1420 059 8434



Ethylbenzene 00100-41-4 296 053 1559




113

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylpropane 00075-28-5 118 022 0260

Total 1666 7311 4389

continued


114

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 42028 608972



n-Heptane 00142-82-5 097 6080 58717

n-Pentane 00109-66-0 121 5160 62696

n-Butane 00106-97-8 108 4881 52569

Toluene 00108-88-3 393 4149 162857

n-Hexane 00110-54-3 113 4113 46667



Benzene 00071-43-2 069 2652 18416


Cyclohexane 00110-82-7 114 2309 26264


3-Methylpentane 00096-14-0 169 1806 30534

n-Octane 00111-65-9 080 1490 11863

2-Methyl-2-butene 00513-35-9 1420 1455 206582

t-2-Pentene 00646-04-8 1047 1430 149744



2-Methylhexane 00591-76-4 109 1276 13844


23-Dimethylbutane 00079-29-8 090 950 8542

2-Methylpropane 00075-28-5 118 905 10645



2-Methyl-1-butene 00563-46-2 638 764 48753

2-Methylheptane 00592-27-8 097 757 7321


c-2-Pentene 00627-20-3 1028 717 73741


3-Methylheptane 00589-81-1 112 591 6648


24-Dimethylhexane 00589-43-5 161 559 8975

t-2-Hexene 04050-45-7 855 500 42751



c-2-Heptene 06443-92-1 708 474 33563



Cyclopentane 00287-92-3 224 382 8551

n-Nonane 00111-84-2 068 368 2512

3-Methyl-c-2-pentene 00922-62-3 1252 366 45829





115

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methyl-t-2-pentene 00616-12-6 1166 347 40413


1-Butyne 00107-00-6 605 314 18981

c-2-Butene 00590-18-1 1426 313 44686


2-Methyl-2-pentene 00625-27-4 1103 298 32930




4-Methyloctane 02216-34-4 085 268 2273

ortho-Xylene 00095-47-6 758 263 19906



Cyclopentene 00142-29-0 669 246 16475

22-Dimethylbutane 00075-83-2 111 235 2609

Propane 00074-98-6 046 234 1071

3-Methyloctane 02216-33-3 088 226 1997

Ethylbenzene 00100-41-4 296 225 6680



n-Propylbenzene 00103-65-1 196 212 4148



33-Dimethylhexane 00563-16-6 115 179 2055





Unknown 8 246 139 3407



continued


116

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



1-Octene 00111-66-0 314 105 3295

Unknown 9 246 086 2117

Unknown 5 246 083 2051





n-Decane 00124-18-5 059 045 0268

1-Nonene 00124-11-8 249 044 1105

Unknown 1 246 032 0778

Total 13019 32482 2495


continued


117

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41 No Ethanol

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90 Repeat

Vehicle 209c


118

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 608 23884

n-Pentane 00109-66-0 121 532 6465

n-Butane 00106-97-8 108 526 5664




n-Hexane 00110-54-3 113 360 4086

Cyclohexane 00110-82-7 114 358 4074

n-Heptane 00142-82-5 097 324 3130


Benzene 00071-43-2 069 227 1573


2-Methyl-2-butene 00513-35-9 1420 214 30383



t-2-Pentene 00646-04-8 1047 199 20808

3-Methylpentane 00096-14-0 169 189 3189



23-Dimethylbutane 00079-29-8 090 134 1208

Ethanol 00064-17-5 145 131 1905


2-Methyl-1-butene 00563-46-2 638 118 7543

Propane 00074-98-6 046 116 0530

2-Methylpropane 00075-28-5 118 112 1317

c-2-Pentene 00627-20-3 1028 110 11307


2-Methylhexane 00591-76-4 109 097 1052

n-Nonane 00111-84-2 068 091 0619

c-2-Butene 00590-18-1 1426 083 11886



n-Propylbenzene 00103-65-1 196 076 1487


n-Octane 00111-65-9 080 066 0525

3-Methylheptane 00589-81-1 112 064 0714


ortho-Xylene 00095-47-6 758 062 4660

t-2-Hexene 04050-45-7 855 057 4874


2-Methyl-2-pentene 00625-27-4 1103 055 6035





119

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 053 0852

3-Methyl-c-2-pentene 00922-62-3 1252 051 6343



3-Methyl-t-2-pentene 00616-12-6 1166 046 5371

Cyclopentene 00142-29-0 669 043 2842



22-Dimethylbutane 00075-83-2 111 035 0390


4-Methyloctane 02216-34-4 085 034 0288




2-Methylheptane 00592-27-8 097 024 0234

Unknown 18 334 023 0782


Indan 00496-11-7 323 020 0636

Ethylbenzene 00100-41-4 296 019 0563

Total 1036 3549 3427


continued


120

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2428 35179


Toluene 00108-88-3 393 689 27059

Cyclohexane 00110-82-7 114 575 6535

n-Pentane 00109-66-0 121 549 6667

n-Butane 00106-97-8 108 465 5009

n-Hexane 00110-54-3 113 438 4971



22-DiMeHexane 00590-73-8 094 335 3152

n-Heptane 00142-82-5 097 311 3006


3-Methylpentane 00096-14-0 169 242 4093

Benzene 00071-43-2 069 227 1575


2-Methyl-2-butene 00513-35-9 1420 197 27914




23-Dimethylbutane 00079-29-8 090 166 1491

2-Methylpropane 00075-28-5 118 149 1756

2-Methylhexane 00591-76-4 109 147 1599

t-2-Pentene 00646-04-8 1047 146 15283




c-2-Pentene 00627-20-3 1028 097 10021

n-Octane 00111-65-9 080 097 0776

Propane 00074-98-6 046 096 0439

n-Nonane 00111-84-2 068 088 0601

2-Methyl-1-butene 00563-46-2 638 082 5199

Indan 00496-11-7 323 078 2534


3-Methylheptane 00589-81-1 112 076 0853


4-Methyloctane 02216-34-4 085 065 0551

ortho-Xylene 00095-47-6 758 065 4918

Unknown 16 271 065 1756





n-Propylbenzene 00103-65-1 196 053 1040

t-2-Hexene 04050-45-7 855 052 4414




121

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 038 0607

Cyclopentene 00142-29-0 669 038 2517


22-Dimethylbutane 00075-83-2 111 037 0408

3-Methyl-t-2-pentene 00616-12-6 1166 036 4207

Ethylbenzene 00100-41-4 296 036 1052




2-Methyl-2-pentene 00625-27-4 1103 033 3675

2-Methylheptane 00592-27-8 097 033 0322

c-2-Butene 00590-18-1 1426 031 4470

3-Methyl-c-2-pentene 00922-62-3 1252 024 3058





Total 1212 3351 2765


continued


122

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 3555 51515

Toluene 00108-88-3 393 2025 79500


3-Me-1-Hexene 03404-61-3 427 1750 74813

n-Heptane 00142-82-5 097 1537 14840



n-Pentane 00109-66-0 121 1178 14313

n-Butane 00106-97-8 108 1174 12645

n-Hexane 00110-54-3 113 1158 13138



22-DiMeHexane 00590-73-8 094 1026 9657





Benzene 00071-43-2 069 791 5491

Propane 00074-98-6 046 552 2523

3-Methylpentane 00096-14-0 169 535 9054



2-Methyl-2-butene 00513-35-9 1420 457 64841

Ethylene 00074-85-1 888 454 40295


2-Methyl-1-butene 00563-46-2 638 448 28551

t-2-Pentene 00646-04-8 1047 448 46880

n-Octane 00111-65-9 080 421 3348


2-Methylpropane 00075-28-5 118 413 4861


c-2-Pentene 00627-20-3 1028 349 35872

n-Propylbenzene 00103-65-1 196 346 6786


2-Methylhexane 00591-76-4 109 331 3591

23-Dimethylbutane 00079-29-8 090 320 2879


ortho-Xylene 00095-47-6 758 312 23613

24-Dimethylhexane 00589-43-5 161 278 4460


2-Methylheptane 00592-27-8 097 265 2568

Ethylbenzene 00100-41-4 296 262 7748

t-2-Hexene 04050-45-7 855 257 21978




123

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







3-Methylheptane 00589-81-1 112 216 2430

2-Methyl-2-pentene 00625-27-4 1103 212 23431

3-Methyl-t-2-pentene 00616-12-6 1166 199 23199

n-Nonane 00111-84-2 068 189 1292

3-Methyl-c-2-pentene 00922-62-3 1252 188 23507




Cyclopentene 00142-29-0 669 120 8051

c-2-Butene 00590-18-1 1426 096 13745



22-Dimethylbutane 00075-83-2 111 085 0940

13-Butadiene 00106-99-0 1245 070 8700


Total 3712 13832 3726


continued


124

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 41433 600356


n-Butane 00106-97-8 108 4042 43529

n-Pentane 00109-66-0 121 3798 46147


Toluene 00108-88-3 393 2636 103457

n-Heptane 00142-82-5 097 2629 25385

n-Hexane 00110-54-3 113 2488 28227


Cyclohexane 00110-82-7 114 1943 22094

Benzene 00071-43-2 069 1923 13349


t-2-Pentene 00646-04-8 1047 1424 149160

2-Methyl-2-butene 00513-35-9 1420 1420 201503


3-Methylpentane 00096-14-0 169 1237 20924


2-Methylpropane 00075-28-5 118 1107 13030

2-Methyl-1-butene 00563-46-2 638 764 48704

c-2-Pentene 00627-20-3 1028 735 75531



n-Octane 00111-65-9 080 674 5365

2-Methylhexane 00591-76-4 109 654 7101



Propane 00074-98-6 046 473 2162

23-Dimethylbutane 00079-29-8 090 451 4053

t-2-Hexene 04050-45-7 855 451 38530

2-Methylheptane 00592-27-8 097 363 3510

Cyclopentane 00287-92-3 224 346 7753

3-Methyl-t-2-pentene 00616-12-6 1166 328 38296


Cyclopentene 00142-29-0 669 296 19762

3-Methylheptane 00589-81-1 112 290 3262

3-Methyl-c-2-pentene 00922-62-3 1252 283 35472

2-Methyl-2-pentene 00625-27-4 1103 279 30766



24-Dimethylhexane 00589-43-5 161 259 4160


22-Dimethylbutane 00075-83-2 111 253 2816





125

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





c-2-Butene 00590-18-1 1426 238 33979





1-Butyne 00107-00-6 605 187 11337



n-Propylbenzene 00103-65-1 196 154 3020

Ethylbenzene 00100-41-4 296 152 4489

4-Methyloctane 02216-34-4 085 149 1267


3-Methyloctane 02216-33-3 088 118 1048


33-Dimethylhexane 00563-16-6 115 113 1300


n-Nonane 00111-84-2 068 112 0762



Unknown 22 249 085 2128


1-Octene 00111-66-0 314 084 2649



Unknown 8 249 077 1927


Unknown 5 249 068 1695

Unknown 6 249 061 1521





4-Methyl-t-2-pentene 00674-76-0 804 055 4393

Unknown 1 249 054 1355

continued


126

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 9 249 048 1203



ortho-Xylene 00095-47-6 758 035 2639



1-Nonene 00124-11-8 249 031 0771

c-2-Heptene 06443-92-1 708 030 2119


Total 9741 24571 2522


continued


127

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2031 29422



Toluene 00108-88-3 393 213 8360

n-Heptane 00142-82-5 097 164 1581

22-DiMeHexane 00590-73-8 094 162 1525




n-Butane 00106-97-8 108 113 1221


Benzene 00071-43-2 069 090 0625

n-Octane 00111-65-9 080 087 0696


n-Pentane 00109-66-0 121 083 1008

Cyclohexane 00110-82-7 114 078 0887


n-Nonane 00111-84-2 068 068 0466




n-Hexane 00110-54-3 113 061 0693

n-Propylbenzene 00103-65-1 196 060 1176

4-Methyloctane 02216-34-4 085 059 0501


2-Methyl-1-butene 00563-46-2 638 056 3568


t-2-Pentene 00646-04-8 1047 051 5304

3-Methyl-c-2-pentene 00922-62-3 1252 048 6030


ortho-Xylene 00095-47-6 758 044 3371


n-Decane 00124-18-5 059 042 0246

1-Butyne 00107-00-6 605 038 2301


2-Methyl-2-butene 00513-35-9 1420 035 4931

23-Dimethylbutane 00079-29-8 090 031 0274



c-2-Pentene 00627-20-3 1028 026 2664

t-2-Hexene 04050-45-7 855 026 2206

2-Methylhexane 00591-76-4 109 026 0279

Ethylbenzene 00100-41-4 296 024 0713




128

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-t-2-pentene 00616-12-6 1166 021 2407

2-Methylheptane 00592-27-8 097 020 0198

3-Methylpentane 00096-14-0 169 020 0337


Cyclopentene 00142-29-0 669 016 1071


3-Methylheptane 00589-81-1 112 010 0108



n-Undecane 01120-21-4 052 003 0017

Total 554 1818 3284


continued


129

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2491 36089


Toluene 00108-88-3 393 351 13795


n-Heptane 00142-82-5 097 246 2378




n-Pentane 00109-66-0 121 181 2205

n-Butane 00106-97-8 108 173 1860

Benzene 00071-43-2 069 159 1107


n-Hexane 00110-54-3 113 128 1449

Propane 00074-98-6 046 123 0563



Cyclohexane 00110-82-7 114 117 1330



3-Methylheptane 00589-81-1 112 081 0911

n-Octane 00111-65-9 080 076 0603

3-Methylpentane 00096-14-0 169 075 1266


t-2-Pentene 00646-04-8 1047 069 7273


n-Propylbenzene 00103-65-1 196 066 1300

2-Methyl-2-pentene 00625-27-4 1103 066 7278


2-Methyl-2-butene 00513-35-9 1420 058 8241

23-Dimethylbutane 00079-29-8 090 056 0505

Ethylbenzene 00100-41-4 296 053 1576

c-2-Heptene 06443-92-1 708 053 3746

4-Methyloctane 02216-34-4 085 053 0449



Unknown 22 299 050 1489


2-Methyl-1-butene 00563-46-2 638 046 2905

2-Methylheptane 00592-27-8 097 045 0434

n-Nonane 00111-84-2 068 044 0300


24-Dimethylhexane 00589-43-5 161 042 0669

2-Methylhexane 00591-76-4 109 039 0424




130

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 039 3979

t-2-Hexene 04050-45-7 855 038 3270


3-Methyl-t-2-pentene 00616-12-6 1166 036 4201

ortho-Xylene 00095-47-6 758 034 2597

c-2-Butene 00590-18-1 1426 034 4788



3-Methyl-c-2-pentene 00922-62-3 1252 030 3747




Cyclopentene 00142-29-0 669 022 1479




22-Dimethylbutane 00075-83-2 111 012 0136

066 Total 786 2397 3050


continued


131

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-DiMeHexane 00590-73-8 094 551 5189

Cyclohexane 00110-82-7 114 550 6259

n-Heptane 00142-82-5 097 503 4856




n-Nonane 00111-84-2 068 399 2724

Ethylene 00074-85-1 888 383 33991


n-Octane 00111-65-9 080 331 2635



Benzene 00071-43-2 069 241 1673

Unknown 22 492 232 11393



3-Methyl-t-2-pentene 00616-12-6 1166 194 22609


Cyclopentene 00142-29-0 669 153 10213




3-Methyl-c-2-pentene 00922-62-3 1252 115 14432

n-Propylbenzene 00103-65-1 196 114 2239

2-Methylheptane 00592-27-8 097 110 1067



Toluene 00108-88-3 393 089 3513

Naphthalene 00091-20-3 328 087 2863

t-2-Hexene 04050-45-7 855 084 7168


3-Methylpentane 00096-14-0 169 070 1179

ortho-Xylene 00095-47-6 758 052 3918


2-Methylhexane 00591-76-4 109 032 0348

Ethylbenzene 00100-41-4 296 018 0548


2-Methyl-2-butene 00513-35-9 1420 005 0770

Total 1074 5493 5117





132

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35670 516847



n-Heptane 00142-82-5 097 3662 35368

n-Butane 00106-97-8 108 3505 37747

Toluene 00108-88-3 393 3492 137050

n-Pentane 00109-66-0 121 3304 40146


n-Hexane 00110-54-3 113 2599 29485



Cyclohexane 00110-82-7 114 1925 21900


Benzene 00071-43-2 069 1738 12068



n-Octane 00111-65-9 080 1569 12491


2-Methylpropane 00075-28-5 118 1256 14781

3-Methylpentane 00096-14-0 169 1206 20398

2-Methyl-2-butene 00513-35-9 1420 1074 152444

23-Dimethylbutane 00079-29-8 090 1069 9609

t-2-Pentene 00646-04-8 1047 1043 109271


2-Methylhexane 00591-76-4 109 864 9372



2-Methylheptane 00592-27-8 097 787 7608


Propane 00074-98-6 046 757 3460

3-Methylheptane 00589-81-1 112 717 8059



n-Nonane 00111-84-2 068 656 4479



c-2-Pentene 00627-20-3 1028 547 56249

24-Dimethylhexane 00589-43-5 161 521 8366

2-Methyl-1-butene 00563-46-2 638 520 33173

4-Methyloctane 02216-34-4 085 502 4255

n-Propylbenzene 00103-65-1 196 453 8879

ortho-Xylene 00095-47-6 758 450 34122

c-2-Heptene 06443-92-1 708 445 31484





133

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






3-Methyloctane 02216-33-3 088 360 3186

t-2-Hexene 04050-45-7 855 339 28984

Ethylbenzene 00100-41-4 296 338 10013

22-Dimethylbutane 00075-83-2 111 326 3618



3-Methyl-t-2-pentene 00616-12-6 1166 269 31374




2-Methyl-2-pentene 00625-27-4 1103 258 28420

Unknown 8 252 242 6098

3-Methyl-c-2-pentene 00922-62-3 1252 236 29551


c-2-Butene 00590-18-1 1426 227 32333


Cyclopentene 00142-29-0 669 218 14591

1-Nonene 00124-11-8 249 212 5282

Unknown 16 252 209 5253



Unknown 9 252 172 4332

1-Octene 00111-66-0 314 161 5055


33-Dimethylhexane 00563-16-6 115 156 1793


n-Decane 00124-18-5 059 141 0832

continued


134

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Indan 00496-11-7 323 126 4071




Unknown 5 252 108 2722

t-4-Octene 14850-23-8 469 092 4292



Unknown 10 252 074 1873




22-Dimethyloctane 15869-87-1 076 049 0367

n-Undecane 01120-21-4 052 044 0229

c-2-Octene 07642-04-8 252 024 0605

Total 11102 28561 2573


continued


135

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 39128 566956



n-Heptane 00142-82-5 097 4118 39773

Toluene 00108-88-3 393 4052 159045

n-Butane 00106-97-8 108 3621 38994

n-Pentane 00109-66-0 121 3567 43335

n-Hexane 00110-54-3 113 3196 36265



Cyclohexane 00110-82-7 114 2313 26313


Benzene 00071-43-2 069 2021 14034


n-Octane 00111-65-9 080 1766 14063



3-Methylpentane 00096-14-0 169 1600 27048



23-Dimethylbutane 00079-29-8 090 1186 10659

2-Methylhexane 00591-76-4 109 1076 11672

2-Methyl-2-butene 00513-35-9 1420 1032 146518

t-2-Pentene 00646-04-8 1047 991 103774



Propane 00074-98-6 046 919 4201

2-Methylpropane 00075-28-5 118 876 10302



2-Methylheptane 00592-27-8 097 759 7340

3-Methylheptane 00589-81-1 112 683 7684

n-Nonane 00111-84-2 068 677 4621



24-Dimethylhexane 00589-43-5 161 607 9741


2-Methyl-1-butene 00563-46-2 638 575 36672


4-Methyloctane 02216-34-4 085 547 4637


c-2-Pentene 00627-20-3 1028 523 53797





136

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Heptene 06443-92-1 708 419 29626

3-Methyl-c-2-pentene 00922-62-3 1252 379 47426

ortho-Xylene 00095-47-6 758 368 27850



n-Propylbenzene 00103-65-1 196 350 6856

3-Methyloctane 02216-33-3 088 339 3003


t-2-Hexene 04050-45-7 855 329 28138


c-2-Butene 00590-18-1 1426 290 41290

n-Decane 00124-18-5 059 284 1680


Ethylbenzene 00100-41-4 296 279 8257


2-Methyl-2-pentene 00625-27-4 1103 272 29956

3-Methyl-t-2-pentene 00616-12-6 1166 264 30830

Unknown 16 247 252 6216


Unknown 8 247 236 5829


Cyclopentene 00142-29-0 669 225 15030






1-Nonene 00124-11-8 249 194 4832

22-Dimethylbutane 00075-83-2 111 192 2134


1-Octene 00111-66-0 314 162 5092

continued


137

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






Unknown 9 247 147 3619

t-4-Octene 14850-23-8 469 146 6841

33-Dimethylhexane 00563-16-6 115 146 1676


Unknown 5 247 140 3451


Indan 00496-11-7 323 086 2776

n-Undecane 01120-21-4 052 081 0423



22-Dimethyloctane 15869-87-1 076 048 0361

Unknown 1 247 043 1059


Total 12111 30488 2517


continued


138

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


139

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 213 8377

n-Pentane 00109-66-0 121 209 2533

n-Butane 00106-97-8 108 195 2100


n-Heptane 00142-82-5 097 146 1407



2-Methylpropane 00075-28-5 118 119 1401

n-Hexane 00110-54-3 113 119 1345

Cyclohexane 00110-82-7 114 115 1310

Benzene 00071-43-2 069 108 0747

Unknown 23 313 105 3279


t-2-Pentene 00646-04-8 1047 103 10759

n-Octane 00111-65-9 080 096 0765

3-Methylheptane 00589-81-1 112 093 1050

2-Methyl-2-butene 00513-35-9 1420 088 12443



3-Methylpentane 00096-14-0 169 081 1375


4-Methyloctane 02216-34-4 085 074 0632




c-2-Pentene 00627-20-3 1028 060 6196



t-2-Hexene 04050-45-7 855 055 4697

2-Methylhexane 00591-76-4 109 052 0565

2-Methyl-1-butene 00563-46-2 638 045 2839

2-Methylheptane 00592-27-8 097 043 0418




n-Nonane 00111-84-2 068 036 0249

n-Decane 00124-18-5 059 036 0213

n-Propylbenzene 00103-65-1 196 034 0658


3-Methyl-t-2-pentene 00616-12-6 1166 032 3705

22-Dimethyloctane 15869-87-1 076 030 0227






140

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Ethylbenzene 00100-41-4 296 027 0810

2-Methyl-2-pentene 00625-27-4 1103 026 2921

t-4-Octene 14850-23-8 469 026 1220

23-Dimethylbutane 00079-29-8 090 026 0231


ortho-Xylene 00095-47-6 758 025 1927

4-Methyl-t-2-pentene 00674-76-0 804 025 2022

c-2-Heptene 06443-92-1 708 025 1752

3-Methyl-c-2-pentene 00922-62-3 1252 023 2817


1-Butyne 00107-00-6 605 022 1304






Cyclopentene 00142-29-0 669 016 1068


Unknown 20 313 013 0398


22-Dimethylbutane 00075-83-2 111 010 0109



24-Dimethylhexane 00589-43-5 161 009 0138

Unknown 14 313 008 0265

Total 499 1646 3297


continued


141

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1583 22942


Toluene 00108-88-3 393 612 24017

n-Pentane 00109-66-0 121 486 5903

n-Butane 00106-97-8 108 481 5181

n-Heptane 00142-82-5 097 334 3229





n-Hexane 00110-54-3 113 272 3083

Benzene 00071-43-2 069 268 1861

Cyclohexane 00110-82-7 114 242 2757


2-Methylheptane 00592-27-8 097 200 1932



t-2-Pentene 00646-04-8 1047 171 17927

2-Methylpropane 00075-28-5 118 169 1990

2-Methyl-2-butene 00513-35-9 1420 166 23544

3-Methylpentane 00096-14-0 169 154 2608


c-2-Pentene 00627-20-3 1028 139 14324

2-Methyl-1-butene 00563-46-2 638 135 8633





3-Methyl-c-2-pentene 00922-62-3 1252 096 11960


23-Dimethylbutane 00079-29-8 090 094 0843

3-Methylheptane 00589-81-1 112 090 1017

t-2-Hexene 04050-45-7 855 083 7126


Ethylbenzene 00100-41-4 296 078 2298

n-Octane 00111-65-9 080 076 0607

ortho-Xylene 00095-47-6 758 076 5752


2-Methylhexane 00591-76-4 109 069 0746

2-Methyl-2-pentene 00625-27-4 1103 069 7570

n-Nonane 00111-84-2 068 068 0463

3-Methyl-t-2-pentene 00616-12-6 1166 066 7701






142

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 057 0908

c-2-Butene 00590-18-1 1426 056 7952


n-Propylbenzene 00103-65-1 196 047 0917

Cyclopentene 00142-29-0 669 044 2973




22-Dimethylbutane 00075-83-2 111 035 0385




Total 1098 3753 3417


continued


143

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Cyclohexane 00110-82-7 114 830 9437


Toluene 00108-88-3 393 735 28842

n-Pentane 00109-66-0 121 635 7720

n-Butane 00106-97-8 108 605 6519


n-Heptane 00142-82-5 097 582 5618

Benzene 00071-43-2 069 579 4019







3-Methylpentane 00096-14-0 169 400 6755

n-Propylbenzene 00103-65-1 196 372 7293

2-Methylhexane 00591-76-4 109 361 3923

n-Octane 00111-65-9 080 359 2859

Unknown 22 382 315 12033

n-Hexane 00110-54-3 113 299 3392


t-2-Butene 00624-64-6 1520 280 42605

4-Methyl-t-2-pentene 00674-76-0 804 264 21197

n-Decane 00124-18-5 059 241 1427



Cyclopentene 00142-29-0 669 218 14592



Propane 00074-98-6 046 193 0881

ortho-Xylene 00095-47-6 758 177 13425

24-Dimethylhexane 00589-43-5 161 168 2703



Ethylbenzene 00100-41-4 296 162 4786

2-Methyl-2-butene 00513-35-9 1420 160 22779


4-Methyloctane 02216-34-4 085 145 1233


t-2-Hexene 04050-45-7 855 134 11491





144

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylbutane 00079-29-8 090 132 1189

2-Methyl-2-pentene 00625-27-4 1103 129 14259



n-Nonane 00111-84-2 068 120 0820

22-Dimethylbutane 00075-83-2 111 115 1278

2-Methylheptane 00592-27-8 097 114 1105

3-Methylheptane 00589-81-1 112 109 1224

3-Methyl-t-2-pentene 00616-12-6 1166 096 11152




2-Methyl-1-butene 00563-46-2 638 080 5118

3-Methyl-c-2-pentene 00922-62-3 1252 080 10031

Unknown 18 382 072 2733

t-2-Pentene 00646-04-8 1047 056 5882



c-2-Butene 00590-18-1 1426 019 2640

Total 2130 8389 3939


continued


145

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 31696 459267


n-Pentane 00109-66-0 121 5202 63200

n-Butane 00106-97-8 108 4742 51062


Toluene 00108-88-3 393 3938 154553

n-Heptane 00142-82-5 097 3796 36662

n-Hexane 00110-54-3 113 3616 41031


Benzene 00071-43-2 069 2716 18860


Cyclohexane 00110-82-7 114 2178 24768

2-Methyl-2-butene 00513-35-9 1420 2023 287182

t-2-Pentene 00646-04-8 1047 1945 203758


3-Methylpentane 00096-14-0 169 1693 28633





c-2-Pentene 00627-20-3 1028 991 101902

2-Methyl-1-butene 00563-46-2 638 937 59771


n-Octane 00111-65-9 080 891 7098

2-Methylhexane 00591-76-4 109 887 9631


2-Methylpropane 00075-28-5 118 786 9244

t-2-Hexene 04050-45-7 855 635 54264

23-Dimethylbutane 00079-29-8 090 601 5401

c-2-Butene 00590-18-1 1426 546 77832

Cyclopentane 00287-92-3 224 476 10644

3-Methyl-t-2-pentene 00616-12-6 1166 457 53303


2-Methylheptane 00592-27-8 097 412 3986


Cyclopentene 00142-29-0 669 406 27162

3-Methyl-c-2-pentene 00922-62-3 1252 381 47688

2-Methyl-2-pentene 00625-27-4 1103 378 41721




3-Methylheptane 00589-81-1 112 341 3833






146

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 277 4444



22-Dimethylbutane 00075-83-2 111 254 2820

n-Nonane 00111-84-2 068 246 1676

ortho-Xylene 00095-47-6 758 241 18230



Ethylbenzene 00100-41-4 296 181 5360


Propane 00074-98-6 046 169 0774

n-Propylbenzene 00103-65-1 196 168 3302




4-Methyloctane 02216-34-4 085 137 1163





Indan 00496-11-7 323 120 3878


3-Methyloctane 02216-33-3 088 112 0989

14-Diethylbenzene 00105-05-5 439 098 4322

33-Dimethylhexane 00563-16-6 115 095 1092


n-Undecane 01120-21-4 052 093 0483


Unknown 9 289 085 2456

Unknown 22 289 085 2454

Unknown 8 289 083 2389

Unknown 16 289 081 2340






t-4-Octene 14850-23-8 469 062 2903

n-Decane 00124-18-5 059 061 0363

continued


147

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 5 289 057 1654

Unknown 1 289 057 1645

c-2-Heptene 06443-92-1 708 056 3942


4-Methyl-t-2-pentene 00674-76-0 804 048 3873


1-Heptene 00592-76-7 429 040 1703

t-3-Heptene 14686-14-7 617 035 2178



1-Nonene 00124-11-8 249 033 0811


c- amp t-4-Nonene 02198-23-4 442 029 1282






13-Butadiene 00106-99-0 1245 014 1729


Total 10698 31327 2928


continued


148

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Toluene 00108-88-3 393 129 5070


n-Butane 00106-97-8 108 114 1229

n-Heptane 00142-82-5 097 106 1019


Benzene 00071-43-2 069 094 0655



c-2-Butene 00590-18-1 1426 072 10220



2-Methyl-1-butene 00563-46-2 638 057 3627



n-Pentane 00109-66-0 121 054 0651



Cyclohexane 00110-82-7 114 049 0558

n-Hexane 00110-54-3 113 040 0449


n-Octane 00111-65-9 080 037 0294


3-Methylpentane 00096-14-0 169 032 0549

n-Propylbenzene 00103-65-1 196 030 0591

3-Methylheptane 00589-81-1 112 028 0314

t-2-Hexene 04050-45-7 855 028 2367


2-Methylheptane 00592-27-8 097 025 0246

n-Nonane 00111-84-2 068 023 0160


2-Methylhexane 00591-76-4 109 022 0243

3-Methyl-t-2-pentene 00616-12-6 1166 021 2489

Cyclopentene 00142-29-0 669 018 1231





149

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 016 0260


2-Methyl-2-butene 00513-35-9 1420 015 2102

23-Dimethylbutane 00079-29-8 090 015 0133


ortho-Xylene 00095-47-6 758 012 0934


Ethylbenzene 00100-41-4 296 011 0325

t-2-Pentene 00646-04-8 1047 008 0869



Total 259 1087 4196


continued


150

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2384 34537


Toluene 00108-88-3 393 399 15668

n-Pentane 00109-66-0 121 371 4510




n-Heptane 00142-82-5 097 309 2980

n-Butane 00106-97-8 108 299 3222

n-Hexane 00110-54-3 113 246 2791

Benzene 00071-43-2 069 233 1614




t-2-Pentene 00646-04-8 1047 148 15551

Cyclohexane 00110-82-7 114 146 1657





2-Methyl-2-butene 00513-35-9 1420 115 16375

c-2-Pentene 00627-20-3 1028 113 11626




3-Methylpentane 00096-14-0 169 103 1742

n-Octane 00111-65-9 080 100 0796

2-Methyl-1-butene 00563-46-2 638 083 5318


t-2-Hexene 04050-45-7 855 062 5278

3-Methyl-c-2-pentene 00922-62-3 1252 061 7658


3-Methylheptane 00589-81-1 112 054 0611



2-Methylhexane 00591-76-4 109 051 0548

ortho-Xylene 00095-47-6 758 048 3648

Ethylbenzene 00100-41-4 296 047 1400

n-Propylbenzene 00103-65-1 196 047 0921


24-Dimethylhexane 00589-43-5 161 042 0671

3-Methyl-t-2-pentene 00616-12-6 1166 041 4734






151

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 039 4295

Cyclopentane 00287-92-3 224 038 0856

22-Dimethylbutane 00075-83-2 111 033 0370





n-Nonane 00111-84-2 068 023 0155

23-Dimethylbutane 00079-29-8 090 022 0200

Cyclopentene 00142-29-0 669 018 1224


Unknown 22 324 013 0423

2-Methylheptane 00592-27-8 097 012 0113

Total 951 3138 3302


continued


152

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4516 65430





Toluene 00108-88-3 393 507 19903

Unknown 22 333 400 13307

n-Butane 00106-97-8 108 381 4104


n-Heptane 00142-82-5 097 294 2844

Propane 00074-98-6 046 278 1272

Benzene 00071-43-2 069 271 1880

2-Methylheptane 00592-27-8 097 242 2337

n-Pentane 00109-66-0 121 233 2835

n-Hexane 00110-54-3 113 226 2566


c-2-Butene 00590-18-1 1426 199 28382



n-Nonane 00111-84-2 068 171 1171




c-2-Pentene 00627-20-3 1028 111 11423




n-Octane 00111-65-9 080 085 0679

Cyclohexane 00110-82-7 114 081 0923

2-Methyl-2-butene 00513-35-9 1420 081 11500

2-Methyl-1-butene 00563-46-2 638 081 5168




2-Methyl-2-pentene 00625-27-4 1103 068 7461

3-Methylheptane 00589-81-1 112 064 0719




153

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



t-2-Pentene 00646-04-8 1047 062 6546


ortho-Xylene 00095-47-6 758 053 4033


3-Methyl-c-2-pentene 00922-62-3 1252 047 5926

Ethylbenzene 00100-41-4 296 043 1269

2-Methylpropane 00075-28-5 118 038 0446


Cyclopentene 00142-29-0 669 022 1503

t-2-Hexene 04050-45-7 855 014 1156

3-Methyl-t-2-pentene 00616-12-6 1166 011 1314


23-Dimethylbutane 00079-29-8 090 005 0041

Total 1362 4730 3473


continued


154

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


155

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 914 13240



n-Heptane 00142-82-5 097 320 3090




n-Octane 00111-65-9 080 190 1516




2-Methylheptane 00592-27-8 097 148 1433


2-Methylpropane 00075-28-5 118 118 1392

Toluene 00108-88-3 393 103 4047

n-Nonane 00111-84-2 068 099 0674



3-Methylheptane 00589-81-1 112 072 0810

Benzene 00071-43-2 069 072 0497



Ethylbenzene 00100-41-4 296 054 1611

n-Propylbenzene 00103-65-1 196 051 0994

Indan 00496-11-7 323 046 1487

Unknown 8 380 044 1655

4-Methyloctane 02216-34-4 085 031 0266


ortho-Xylene 00095-47-6 758 025 1916

2-Methylhexane 00591-76-4 109 025 0270

3-Methyloctane 02216-33-3 088 022 0195

t-2-Hexene 04050-45-7 855 022 1856

n-Decane 00124-18-5 059 020 0120



24-Dimethylhexane 00589-43-5 161 010 0159


Unknown 18 380 008 0320


Total 504 1959 3887





156

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5350 77523



Toluene 00108-88-3 393 710 27869


n-Heptane 00142-82-5 097 557 5384

n-Pentane 00109-66-0 121 507 6163




n-Butane 00106-97-8 108 412 4441

Benzene 00071-43-2 069 397 2757

n-Hexane 00110-54-3 113 324 3679






n-Octane 00111-65-9 080 190 1517

2-Methyl-2-butene 00513-35-9 1420 185 26255

Cyclohexane 00110-82-7 114 177 2018

2-Methylpropane 00075-28-5 118 161 1890

t-2-Pentene 00646-04-8 1047 157 16410

3-Methylpentane 00096-14-0 169 153 2584

n-Propylbenzene 00103-65-1 196 130 2552


n-Nonane 00111-84-2 068 105 0717


2-Methylhexane 00591-76-4 109 098 1068

Propane 00074-98-6 046 095 0435

ortho-Xylene 00095-47-6 758 095 7180

2-Methyl-1-butene 00563-46-2 638 091 5809

c-2-Pentene 00627-20-3 1028 087 8898

3-Methyloctane 02216-33-3 088 083 0732


2-Methylheptane 00592-27-8 097 082 0789

4-Methyloctane 02216-34-4 085 082 0692

Cyclopentene 00142-29-0 669 079 5254

Cyclopentane 00287-92-3 224 074 1658

Ethylbenzene 00100-41-4 296 071 2105

n-Decane 00124-18-5 059 065 0381

3-Methylheptane 00589-81-1 112 063 0710

3-Methyl-t-2-pentene 00616-12-6 1166 063 7322

24-Dimethylhexane 00589-43-5 161 062 1002




157

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 061 7585




22-Dimethylbutane 00075-83-2 111 057 0637

t-2-Hexene 04050-45-7 855 056 4804


2-Methyl-2-pentene 00625-27-4 1103 054 5956





Unknown 18 309 046 1407

c-2-Butene 00590-18-1 1426 041 5887






23-Dimethylbutane 00079-29-8 090 023 0203

Total 1716 5398 3145


continued


158

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 1415 20503




n-Heptane 00142-82-5 097 457 4411

n-Nonane 00111-84-2 068 418 2857

n-Octane 00111-65-9 080 391 3117

n-Propylbenzene 00103-65-1 196 390 7648





Unknown 22 429 241 10343



Toluene 00108-88-3 393 138 5398


Ethylbenzene 00100-41-4 296 107 3162

Benzene 00071-43-2 069 106 0733

ortho-Xylene 00095-47-6 758 086 6504

2-Methylhexane 00591-76-4 109 053 0572


Total 1016 4464 4392





159

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 80088 1160459


n-Pentane 00109-66-0 121 4822 58590

n-Heptane 00142-82-5 097 4735 45729

n-Butane 00106-97-8 108 4415 47543


Toluene 00108-88-3 393 3850 151113


n-Hexane 00110-54-3 113 3408 38671


Benzene 00071-43-2 069 3032 21056


2-Methyl-2-butene 00513-35-9 1420 1879 266753


t-2-Pentene 00646-04-8 1047 1856 194423

Cyclohexane 00110-82-7 114 1803 20503

3-Methylpentane 00096-14-0 169 1710 28914

n-Octane 00111-65-9 080 1552 12360




2-Methylhexane 00591-76-4 109 1117 12118


2-Methyl-1-butene 00563-46-2 638 911 58131

c-2-Pentene 00627-20-3 1028 907 93216

2-Methylpropane 00075-28-5 118 779 9171

2-Methylheptane 00592-27-8 097 709 6862

1-Butyne 00107-00-6 605 663 40082


3-Methylheptane 00589-81-1 112 644 7246

t-2-Hexene 04050-45-7 855 637 54462



23-Dimethylbutane 00079-29-8 090 550 4945

3-Methyl-c-2-pentene 00922-62-3 1252 539 67459


n-Nonane 00111-84-2 068 474 3235

Cyclopentane 00287-92-3 224 459 10278




3-Methyl-t-2-pentene 00616-12-6 1166 406 47372

2-Methyl-2-pentene 00625-27-4 1103 376 41453

Cyclopentene 00142-29-0 669 370 24726




160

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




ortho-Xylene 00095-47-6 758 354 26855

4-Methyloctane 02216-34-4 085 354 3006

c-2-Butene 00590-18-1 1426 344 49033



Ethylbenzene 00100-41-4 296 301 8929

n-Propylbenzene 00103-65-1 196 301 5890

3-Methyloctane 02216-33-3 088 295 2606

22-Dimethylbutane 00075-83-2 111 289 3213

24-Dimethylhexane 00589-43-5 161 285 4569




Propane 00074-98-6 046 234 1071







Unknown 8 239 166 3975

Unknown 9 239 161 3846





33-Dimethylhexane 00563-16-6 115 127 1462




continued


161

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Decane 00124-18-5 059 097 0572



c- amp t-4-Nonene 02198-23-4 442 081 3581

c-2-Heptene 06443-92-1 708 079 5569

Unknown 1 239 075 1804

t-4-Octene 14850-23-8 469 075 3530



Unknown 18 239 065 1559

Unknown 5 239 060 1448

Unknown 14 239 055 1326


1-Nonene 00124-11-8 249 048 1191



Indan 00496-11-7 323 034 1102

Total 16190 39290 2427


continued


162

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1993 28873


Toluene 00108-88-3 393 213 8354



n-Butane 00106-97-8 108 130 1400

n-Pentane 00109-66-0 121 129 1569

n-Heptane 00142-82-5 097 123 1191


n-Hexane 00110-54-3 113 116 1316


t-2-Butene 00624-64-6 1520 098 14909



Benzene 00071-43-2 069 089 0619

3-Methylheptane 00589-81-1 112 080 0904

t-2-Pentene 00646-04-8 1047 078 8210



3-Methylpentane 00096-14-0 169 056 0952



Unknown 18 282 048 1351

4-Methyloctane 02216-34-4 085 047 0400


2-Methyl-2-butene 00513-35-9 1420 046 6499

2-Methylhexane 00591-76-4 109 043 0468

c-2-Pentene 00627-20-3 1028 042 4351

t-2-Hexene 04050-45-7 855 041 3497

Cyclohexane 00110-82-7 114 036 0412


c-2-Heptene 06443-92-1 708 035 2475

2-Methyl-1-butene 00563-46-2 638 035 2212

n-Octane 00111-65-9 080 033 0264

23-Dimethylbutane 00079-29-8 090 032 0284





3-Methyl-t-2-pentene 00616-12-6 1166 023 2658


n-Nonane 00111-84-2 068 022 0148

3-Methyl-c-2-pentene 00922-62-3 1252 019 2434





163

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentene 00142-29-0 669 014 0946



n-Propylbenzene 00103-65-1 196 008 0160

24-Dimethylhexane 00589-43-5 161 003 0043

Total 513 1471 2864


continued


164

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4419 64033



Toluene 00108-88-3 393 327 12821

n-Heptane 00142-82-5 097 317 3058

n-Pentane 00109-66-0 121 298 3615

n-Butane 00106-97-8 108 292 3145



n-Hexane 00110-54-3 113 202 2297



Benzene 00071-43-2 069 176 1224



3-Methylpentane 00096-14-0 169 128 2170

Cyclohexane 00110-82-7 114 121 1373

t-2-Pentene 00646-04-8 1047 108 11335

n-Octane 00111-65-9 080 104 0832

23-Dimethylbutane 00079-29-8 090 093 0839

2-Methyl-2-butene 00513-35-9 1420 088 12506


c-2-Pentene 00627-20-3 1028 065 6705

2-Methylheptane 00592-27-8 097 065 0628



2-Methyl-1-butene 00563-46-2 638 060 3850

ortho-Xylene 00095-47-6 758 058 4432

2-Methylhexane 00591-76-4 109 053 0572

3-Methylheptane 00589-81-1 112 044 0500




2-Methyl-2-pentene 00625-27-4 1103 041 4512

Cyclopentene 00142-29-0 669 040 2703

n-Nonane 00111-84-2 068 040 0272


n-Propylbenzene 00103-65-1 196 034 0666



c-2-Heptene 06443-92-1 708 032 2242

c-2-Butene 00590-18-1 1426 030 4304

3-Methyl-t-2-pentene 00616-12-6 1166 027 3205





165

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Ethylbenzene 00100-41-4 296 024 0701

24-Dimethylhexane 00589-43-5 161 020 0324

t-2-Hexene 04050-45-7 855 019 1605



22-Dimethylbutane 00075-83-2 111 016 0174


3-Methyl-c-2-pentene 00922-62-3 1252 010 1259


Total 1033 2530 2449


continued


166

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5963 86398




Toluene 00108-88-3 393 571 22420



n-Pentane 00109-66-0 121 455 5531


Propane 00074-98-6 046 324 1482





Benzene 00071-43-2 069 254 1767


n-Heptane 00142-82-5 097 246 2379


t-2-Pentene 00646-04-8 1047 211 22048


c-2-Butene 00590-18-1 1426 195 27782

Ethylbenzene 00100-41-4 296 168 4985

2-Methyl-1-butene 00563-46-2 638 165 10501

n-Hexane 00110-54-3 113 163 1848

ortho-Xylene 00095-47-6 758 152 11495

Cyclohexane 00110-82-7 114 136 1543

c-2-Pentene 00627-20-3 1028 132 13597


2-Methyl-2-butene 00513-35-9 1420 130 18389

n-Octane 00111-65-9 080 129 1027


3-Methylheptane 00589-81-1 112 115 1296

22-Dimethylbutane 00075-83-2 111 113 1259

n-Butane 00106-97-8 108 111 1191


3-Methylpentane 00096-14-0 169 099 1670


3-Methyl-t-2-pentene 00616-12-6 1166 097 11253

n-Nonane 00111-84-2 068 093 0635


23-Dimethylbutane 00079-29-8 090 091 0816

2-Methylheptane 00592-27-8 097 091 0876

Styrene 00100-42-5 166 085 1415

n-Propylbenzene 00103-65-1 196 085 1659




167

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 068 1091


c-2-Heptene 06443-92-1 708 067 4724

Cyclopentene 00142-29-0 669 058 3856




t-2-Hexene 04050-45-7 855 047 4014

3-Methyl-c-2-pentene 00922-62-3 1252 042 5224



2-Methylhexane 00591-76-4 109 024 0260

Total 1768 6143 3474


continued


168

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 55723 807411



n-Heptane 00142-82-5 097 5981 57761

n-Pentane 00109-66-0 121 4502 54693

n-Butane 00106-97-8 108 3984 42902

n-Hexane 00110-54-3 113 3782 42912


Toluene 00108-88-3 393 3760 147573


Benzene 00071-43-2 069 2573 17862


Cyclohexane 00110-82-7 114 2121 24121




3-Methylpentane 00096-14-0 169 1746 29526

2-Methylhexane 00591-76-4 109 1523 16530

n-Octane 00111-65-9 080 1370 10905

2-Methyl-2-butene 00513-35-9 1420 1332 189048

t-2-Pentene 00646-04-8 1047 1291 135259


23-Dimethylbutane 00079-29-8 090 914 8215


2-Methyl-1-butene 00563-46-2 638 724 46184



c-2-Pentene 00627-20-3 1028 654 67284


1-Butyne 00107-00-6 605 626 37845

2-Methylheptane 00592-27-8 097 598 5783



3-Methylheptane 00589-81-1 112 575 6461

24-Dimethylhexane 00589-43-5 161 569 9133

3-Methyl-c-2-pentene 00922-62-3 1252 520 65089



t-2-Hexene 04050-45-7 855 463 39550

c-2-Heptene 06443-92-1 708 449 31804

n-Decane 00124-18-5 059 419 2479


Cyclopentane 00287-92-3 224 395 8835





169

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




c-2-Butene 00590-18-1 1426 336 47937

3-Methyl-t-2-pentene 00616-12-6 1166 335 39014



2-Methyl-2-pentene 00625-27-4 1103 298 32843


4-Methyloctane 02216-34-4 085 282 2390

n-Nonane 00111-84-2 068 276 1883

Cyclopentene 00142-29-0 669 274 18349


22-Dimethylbutane 00075-83-2 111 262 2916





3-Methyloctane 02216-33-3 088 227 2006

33-Dimethylhexane 00563-16-6 115 217 2497





ortho-Xylene 00095-47-6 758 185 13998

Ethylbenzene 00100-41-4 296 181 5358


n-Propylbenzene 00103-65-1 196 147 2880




Unknown 8 231 112 2592


Unknown 16 231 111 2561

Unknown 5 231 101 2336


c- amp t-4-Nonene 02198-23-4 442 096 4265


Unknown 9 231 085 1963


Unknown 1 231 036 0824


Total 14128 33504 2371


continued


170

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


171

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 8324 89644

2-Methylpropane 00075-28-5 118 7588 89275

Ethanol 00064-17-5 145 5174 74976

n-Pentane 00109-66-0 121 4957 60220




n-Hexane 00110-54-3 113 1782 20226

2-Methyl-2-butene 00513-35-9 1420 1495 212177

Propane 00074-98-6 046 1378 6301

t-2-Pentene 00646-04-8 1047 1321 138329

Toluene 00108-88-3 393 1320 51799

3-Methylpentane 00096-14-0 169 1291 21833

3-Me-1-Hexene 03404-61-3 427 1081 46189


t-3-Heptene 14686-14-7 617 963 59431

2-Methyl-1-butene 00563-46-2 638 894 57049


Benzene 00071-43-2 069 728 5053

c-2-Pentene 00627-20-3 1028 704 72389


23-Dimethylbutane 00079-29-8 090 634 5698

22-DiMeHexane 00590-73-8 094 623 5866



2-Methylhexane 00591-76-4 109 393 4266


c-2-Butene 00590-18-1 1426 385 54865




22-Dimethylbutane 00075-83-2 111 312 3465

Cyclopentane 00287-92-3 224 301 6725

t-2-Hexene 04050-45-7 855 283 24189

14-Diethylbenzene 00105-05-5 439 246 10796

Indan 00496-11-7 323 235 7603

Cyclopentene 00142-29-0 669 222 14854

3-Methyl-t-2-pentene 00616-12-6 1166 218 25428


3-Methyl-c-2-pentene 00922-62-3 1252 216 27097


2-Methylheptane 00592-27-8 097 187 1812





172

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 173 19052

n-Octane 00111-65-9 080 166 1321


n-Propylbenzene 00103-65-1 196 160 3132

ortho-Xylene 00095-47-6 758 156 11834




Ethylbenzene 00100-41-4 296 141 4174





Unknown 5 290 113 3275











Naphthalene 00091-20-3 328 042 1374

Total 7033 20500 2915


continued


173

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 13220 142369

2-Methylpropane 00075-28-5 118 11988 141051

Ethanol 00064-17-5 145 9234 133801

n-Pentane 00109-66-0 121 8302 100866



n-Hexane 00110-54-3 113 2767 31394

2-Methyl-2-butene 00513-35-9 1420 2454 348276

t-2-Pentene 00646-04-8 1047 2145 224611

Propane 00074-98-6 046 2099 9596

3-Methylpentane 00096-14-0 169 2086 35279

n-Heptane 00142-82-5 097 1782 17211


Cyclohexane 00110-82-7 114 1516 17244

2-Methyl-1-butene 00563-46-2 638 1447 92328

22-DiMeHexane 00590-73-8 094 1392 13105

c-2-Pentene 00627-20-3 1028 1194 122782

Toluene 00108-88-3 393 1100 43170

Benzene 00071-43-2 069 1087 7545

23-Dimethylbutane 00079-29-8 090 1032 9271



2-Methylhexane 00591-76-4 109 603 6543

22-Dimethylbutane 00075-83-2 111 570 6332

c-2-Butene 00590-18-1 1426 511 72813

Cyclopentane 00287-92-3 224 491 10983

t-2-Hexene 04050-45-7 855 437 37393


Cyclopentene 00142-29-0 669 367 24548

n-Octane 00111-65-9 080 364 2897

3-Methyl-t-2-pentene 00616-12-6 1166 339 39475

2-Methyl-2-pentene 00625-27-4 1103 326 35978

3-Methyl-c-2-pentene 00922-62-3 1252 325 40724









Unknown 22 253 201 5089





174

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methylheptane 00589-81-1 112 170 1906





24-Dimethylhexane 00589-43-5 161 126 2020



2-Methylheptane 00592-27-8 097 104 1010

n-Propylbenzene 00103-65-1 196 099 1936

ortho-Xylene 00095-47-6 758 097 7318

n-Nonane 00111-84-2 068 092 0630





33-Dimethylhexane 00563-16-6 115 074 0847


Ethylbenzene 00100-41-4 296 067 1991


1-Octene 00111-66-0 314 055 1718



Total 10408 26483 2545


continued


175

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2191 31752


n-Butane 00106-97-8 108 1006 10833

n-Pentane 00109-66-0 121 747 9080

Toluene 00108-88-3 393 701 27531


Unknown 22 328 660 21624


Benzene 00071-43-2 069 489 3398

2-Methylpropane 00075-28-5 118 438 5148

t-2-Pentene 00646-04-8 1047 413 43247

n-Heptane 00142-82-5 097 401 3869

2-Methyl-2-butene 00513-35-9 1420 365 51798




Propane 00074-98-6 046 309 1412





Cyclohexane 00110-82-7 114 257 2927


n-Octane 00111-65-9 080 231 1837



c-2-Pentene 00627-20-3 1028 166 17113



n-Hexane 00110-54-3 113 150 1697



ortho-Xylene 00095-47-6 758 139 10527



c-2-Butene 00590-18-1 1426 130 18467



13-Butadiene 00106-99-0 1245 113 14026

Ethylbenzene 00100-41-4 296 109 3230

t-2-Hexene 04050-45-7 855 098 8420

2-Methyl-1-butene 00563-46-2 638 090 5717

2-Methylhexane 00591-76-4 109 078 0845

23-Dimethylbutane 00079-29-8 090 075 0672




176

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



22-DiMeHexane 00590-73-8 094 069 0650

2-Methyl-2-pentene 00625-27-4 1103 054 5959

2-Methylheptane 00592-27-8 097 052 0507

3-Methyl-t-2-pentene 00616-12-6 1166 051 5927


3-Methylpentane 00096-14-0 169 046 0770


3-Methylheptane 00589-81-1 112 024 0275

Cyclopentene 00142-29-0 669 022 1455


n-Nonane 00111-84-2 068 019 0129

Total 1606 5720 3562


continued


177

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 54709 792723


n-Butane 00106-97-8 108 10917 117569

n-Pentane 00109-66-0 121 9272 112649

2-Methylpropane 00075-28-5 118 7225 85005


Toluene 00108-88-3 393 6283 246616

n-Hexane 00110-54-3 113 4995 56676

n-Heptane 00142-82-5 097 4659 44994

Benzene 00071-43-2 069 4652 32302


2-Methyl-2-butene 00513-35-9 1420 3675 521667

t-2-Pentene 00646-04-8 1047 3631 380251

3-Methylpentane 00096-14-0 169 2779 46981

22-DiMeHexane 00590-73-8 094 2773 26105

Cyclohexane 00110-82-7 114 2771 31519


c-2-Pentene 00627-20-3 1028 1943 199760

2-Methyl-1-butene 00563-46-2 638 1834 117003


Propane 00074-98-6 046 1660 7588


2-Methylhexane 00591-76-4 109 1107 12010


n-Octane 00111-65-9 080 1036 8250


t-2-Hexene 04050-45-7 855 954 81525


23-Dimethylbutane 00079-29-8 090 860 7730


Cyclopentane 00287-92-3 224 748 16744


c-2-Butene 00590-18-1 1426 680 97022

3-Methyl-t-2-pentene 00616-12-6 1166 666 77705

Cyclopentene 00142-29-0 669 665 44433


22-Dimethylbutane 00075-83-2 111 574 6383

3-Methyl-c-2-pentene 00922-62-3 1252 548 68650

2-Methyl-2-pentene 00625-27-4 1103 519 57206

2-Methylheptane 00592-27-8 097 515 4981



1-Butyne 00107-00-6 605 436 26373

3-Methylheptane 00589-81-1 112 403 4535




178

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





ortho-Xylene 00095-47-6 758 345 26142






Ethylbenzene 00100-41-4 296 292 8644


24-Dimethylhexane 00589-43-5 161 289 4646



n-Nonane 00111-84-2 068 234 1599


n-Propylbenzene 00103-65-1 196 198 3881



4-Methyloctane 02216-34-4 085 193 1641



Unknown 1 271 171 4641

33-Dimethylhexane 00563-16-6 115 159 1833






n-Undecane 01120-21-4 052 079 0415

3-Methyloctane 02216-33-3 088 079 0703

Unknown 5 271 076 2052

1-Octene 00111-66-0 314 065 2057





Unknown 8 271 035 0945

Total 17874 48855 2733


continued


179

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 8198 118785

n-Butane 00106-97-8 108 7183 77353


n-Pentane 00109-66-0 121 3595 43676

2-Methylpropane 00075-28-5 118 2766 32545


Propane 00074-98-6 046 2137 9770

n-Hexane 00110-54-3 113 1047 11875


n-Heptane 00142-82-5 097 912 8810

t-2-Pentene 00646-04-8 1047 830 86907

2-Methyl-2-butene 00513-35-9 1420 814 115599


23-Dimethylbutane 00079-29-8 090 556 4999


Benzene 00071-43-2 069 530 3683

2-Methyl-1-butene 00563-46-2 638 507 32336

Toluene 00108-88-3 393 503 19740

3-Methylpentane 00096-14-0 169 472 7984


c-2-Pentene 00627-20-3 1028 393 40363


c-2-Butene 00590-18-1 1426 277 39443



22-Dimethylbutane 00075-83-2 111 214 2380


2-Methylheptane 00592-27-8 097 180 1739

t-2-Hexene 04050-45-7 855 178 15211

n-Octane 00111-65-9 080 172 1368



2-Methylhexane 00591-76-4 109 161 1748



c-2-Heptene 06443-92-1 382 146 5572



Cyclopentene 00142-29-0 669 129 8640

3-Methyl-t-2-pentene 00616-12-6 1166 116 13518


Cyclohexane 00110-82-7 114 092 1044


n-Nonane 00111-84-2 068 087 0593




180

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 086 0966

2-Methyl-2-pentene 00625-27-4 1103 081 8971



24-Dimethylhexane 00589-43-5 161 078 1247








n-Propylbenzene 00103-65-1 196 048 0949


33-Dimethylhexane 00563-16-6 115 031 0359


3-Methyl-c-2-pentene 00922-62-3 1252 027 3427




Ethylbenzene 00100-41-4 296 018 0528

ortho-Xylene 00095-47-6 758 010 0721


Total 4710 11512 2444


continued


181

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 15180 219955


n-Butane 00106-97-8 108 9750 104997

n-Pentane 00109-66-0 121 5514 66989


2-Methylpropane 00075-28-5 118 3609 42461


n-Hexane 00110-54-3 113 2552 28959

Propane 00074-98-6 046 2506 11455

n-Heptane 00142-82-5 097 1866 18025

3-Methylpentane 00096-14-0 169 1624 27461

23-Dimethylbutane 00079-29-8 090 1413 12703

2-Methyl-2-butene 00513-35-9 1420 1376 195359

Toluene 00108-88-3 393 1340 52581

Cyclohexane 00110-82-7 114 1307 14870



t-2-Pentene 00646-04-8 1047 1180 123585


Benzene 00071-43-2 069 965 6703

2-Methyl-1-butene 00563-46-2 638 878 56009

c-2-Pentene 00627-20-3 1028 635 65238

2-Methylhexane 00591-76-4 109 632 6855






22-Dimethylbutane 00075-83-2 111 370 4115


n-Octane 00111-65-9 080 346 2755


c-2-Butene 00590-18-1 1426 336 47966


c-2-Heptene 06443-92-1 708 260 18411

t-2-Hexene 04050-45-7 855 249 21269

24-Dimethylhexane 00589-43-5 161 234 3765






3-Methyl-t-2-pentene 00616-12-6 1166 201 23444

2-Methyl-2-pentene 00625-27-4 1103 200 22011




182

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 193 1865

3-Methylheptane 00589-81-1 112 188 2119

Cyclopentene 00142-29-0 669 180 12031



n-Propylbenzene 00103-65-1 196 157 3073

3-Methyl-c-2-pentene 00922-62-3 1252 146 18216




ortho-Xylene 00095-47-6 758 129 9739




Ethylbenzene 00100-41-4 296 101 3002




n-Nonane 00111-84-2 068 085 0583



4-Methyloctane 02216-34-4 085 082 0694



33-Dimethylhexane 00563-16-6 115 067 0767

n-Decane 00124-18-5 059 066 0389



Total 8664 21100 2435


continued


183

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1732 25089


Benzene 00071-43-2 069 452 3139

c-2-Butene 00590-18-1 1426 376 53628








c-2-Pentene 00627-20-3 1028 072 7386

n-Heptane 00142-82-5 097 059 0568

n-Propylbenzene 00103-65-1 196 048 0947

Ethylbenzene 00100-41-4 296 045 1322


2-Methyl-2-butene 00513-35-9 1420 025 3547

t-2-Hexene 04050-45-7 855 022 1855

ortho-Xylene 00095-47-6 758 015 1110

n-Octane 00111-65-9 080 010 0081

Total 489 2108 4309




184

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 51382 744509



n-Butane 00106-97-8 108 8982 96733

n-Pentane 00109-66-0 121 6997 85011

Toluene 00108-88-3 393 6711 263404

n-Heptane 00142-82-5 097 6680 64513

n-Hexane 00110-54-3 113 5030 57075



Benzene 00071-43-2 069 4022 27924

Cyclohexane 00110-82-7 114 3279 37292




2-Methylpropane 00075-28-5 118 2557 30086


Propane 00074-98-6 046 2432 11116

3-Methylpentane 00096-14-0 169 2416 40845


n-Octane 00111-65-9 080 2194 17472

2-Methyl-2-butene 00513-35-9 1420 2103 298453

t-2-Pentene 00646-04-8 1047 2086 218459


2-Methylhexane 00591-76-4 109 1526 16559

23-Dimethylbutane 00079-29-8 090 1374 12350



2-Methyl-1-butene 00563-46-2 638 1191 75982



c-2-Pentene 00627-20-3 1028 1105 113644

2-Methylheptane 00592-27-8 097 1023 9893


3-Methylheptane 00589-81-1 112 906 10183





24-Dimethylhexane 00589-43-5 161 698 11203

c-2-Heptene 06443-92-1 708 667 47214

n-Nonane 00111-84-2 068 663 4525

t-2-Hexene 04050-45-7 855 648 55398

ortho-Xylene 00095-47-6 758 548 41492




185

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentane 00287-92-3 224 512 11458


n-Propylbenzene 00103-65-1 196 499 9784

4-Methyloctane 02216-34-4 085 497 4216

3-Methyl-t-2-pentene 00616-12-6 1166 485 56599

3-Methyl-c-2-pentene 00922-62-3 1252 456 57109

c-2-Butene 00590-18-1 1426 444 63356


Cyclopentene 00142-29-0 669 416 27787






Ethylbenzene 00100-41-4 296 389 11519

22-Dimethylbutane 00075-83-2 111 378 4206

2-Methyl-2-pentene 00625-27-4 1103 358 39448

Unknown 16 261 356 9264



3-Methyloctane 02216-33-3 088 339 3003




1-Nonene 00124-11-8 249 256 6374

1-Butyne 00107-00-6 605 251 15194

Ethylene 00074-85-1 888 250 22216


Unknown 8 261 234 6089


33-Dimethylhexane 00563-16-6 115 213 2449




1-Octene 00111-66-0 314 195 6137


Unknown 9 261 154 4022

n-Undecane 01120-21-4 052 154 0805

n-Decane 00124-18-5 059 152 0896

Unknown 5 261 142 3689


Indan 00496-11-7 323 131 4230

continued


186

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 6 261 131 3400


Styrene 00100-42-5 166 105 1738



Unknown 1 261 052 1367



Total 18590 49278 2651


continued


187

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


188

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




189

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




190

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Naphthalene 00091-20-3 328 774 25406


t-2-Butene 00624-64-6 1520 371 56453


n-Butane 00106-97-8 108 285 3072

23-Dimethylbutane 00079-29-8 090 248 2230



Toluene 00108-88-3 393 190 7444

2-Methylpropane 00075-28-5 118 166 1951

2-Methylheptane 00592-27-8 097 157 1514

3-Methyl-t-2-pentene 00616-12-6 1166 131 15309

n-Heptane 00142-82-5 097 130 1251


3-Methylpentane 00096-14-0 169 117 1981

24-Dimethylhexane 00589-43-5 161 111 1786


n-Hexane 00110-54-3 113 100 1134


22-Dimethylbutane 00075-83-2 111 082 0916

Ethylbenzene 00100-41-4 296 077 2293

t-2-Pentene 00646-04-8 1047 075 7833

Cyclohexane 00110-82-7 114 074 0842

c-2-Butene 00590-18-1 1426 074 10503

3-Methyl-c-2-pentene 00922-62-3 1252 071 8850

ortho-Xylene 00095-47-6 758 068 5178

n-Pentane 00109-66-0 121 021 0252


Total 486 2222 4570




191

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4628 67056

3-Methylpentane 00096-14-0 169 1507 25484



n-Butane 00106-97-8 108 1101 11855


Toluene 00108-88-3 393 1066 41860

3-Methyl-c-2-pentene 00922-62-3 1252 1066 133427

n-Pentane 00109-66-0 121 935 11363


n-Hexane 00110-54-3 113 210 2385


Total 1468 3932 2678




192

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




193

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




194

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




195

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4926 71372


Toluene 00108-88-3 393 1115 43746

3-Methylpentane 00096-14-0 169 762 12888

n-Butane 00106-97-8 108 725 7805


n-Hexane 00110-54-3 113 611 6931

n-Pentane 00109-66-0 121 583 7083




3-Methyl-c-2-pentene 00922-62-3 1252 205 25608

Total 1211 2325 1920



196


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


197

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 31534 339592

Ethanol 00064-17-5 145 15433 223618

n-Pentane 00109-66-0 121 4575 55584


Toluene 00108-88-3 393 4103 161061

n-Hexane 00110-54-3 113 3924 44527

2-Methyl-2-butene 00513-35-9 1420 3811 540999

t-2-Pentene 00646-04-8 1047 3208 335977

3-Methylpentane 00096-14-0 169 2810 47513

2-Methyl-1-butene 00563-46-2 638 2286 145822

23-Dimethylbutane 00079-29-8 090 2194 19722

c-2-Pentene 00627-20-3 1028 1736 178523




c-2-Butene 00590-18-1 1426 1349 192427

Benzene 00071-43-2 069 1177 8169

Cyclohexane 00110-82-7 114 1082 12310





t-2-Hexene 04050-45-7 855 585 50036

2-Methylhexane 00591-76-4 109 580 6299

Cyclopentene 00142-29-0 669 525 35095

n-Heptane 00142-82-5 097 524 5057

3-Methyl-t-2-pentene 00616-12-6 1166 474 55209


2-Methyl-2-pentene 00625-27-4 1103 432 47686

3-Methyl-c-2-pentene 00922-62-3 1252 408 51020




22-Dimethylbutane 00075-83-2 111 322 3582





24-Dimethylhexane 00589-43-5 161 213 3412


n-Octane 00111-65-9 080 159 1266






198

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylheptane 00592-27-8 097 131 1270




3-Methylheptane 00589-81-1 112 116 1307




t-3-Heptene 14686-14-7 617 083 5119


ortho-Xylene 00095-47-6 758 079 5957




n-Decane 00124-18-5 249 054 1339




Ethylbenzene 00100-41-4 296 049 1460


Unknown 1 266 034 0906

33-Dimethylhexane 00563-16-6 115 030 0344

n-Propylbenzene 00103-65-1 196 028 0542

n-Nonane 00111-84-2 068 015 0101


4-Methyl-t-2-pentene 00674-76-0 804 002 0184

Total 13923 37072 2663


continued


199

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 79369 854739


Ethanol 00064-17-5 145 38151 552793

Toluene 00108-88-3 393 16580 650783

n-Hexane 00110-54-3 113 13605 154368


3-Methylpentane 00096-14-0 169 7654 129419

n-Pentane 00109-66-0 121 7381 89678

2-Methyl-2-butene 00513-35-9 1420 6466 917894


t-2-Pentene 00646-04-8 1047 5245 549380

23-Dimethylbutane 00079-29-8 090 5099 45823

Benzene 00071-43-2 069 4157 28862


Cyclohexane 00110-82-7 114 3728 42398

2-Methyl-1-butene 00563-46-2 638 3681 234792

Ethylene 00074-85-1 888 3244 288174




c-2-Pentene 00627-20-3 1028 2900 298147



Ethane 00074-84-0 026 2242 5893


c-2-Butene 00590-18-1 1426 1864 265834

2-Methylhexane 00591-76-4 109 1801 19546

n-Heptane 00142-82-5 097 1789 17277




2-Methylpropane 00075-28-5 118 1312 15435


t-2-Hexene 04050-45-7 855 1292 110422

1-Butyne 00107-00-6 605 1288 77894

Propane 00074-98-6 046 1212 5539



3-Methyl-t-2-pentene 00616-12-6 1166 1006 117309


Cyclopentene 00142-29-0 669 970 64866


2-Methyl-2-pentene 00625-27-4 1103 953 105093





200

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 843 105557

n-Octane 00111-65-9 080 804 6403

24-Dimethylhexane 00589-43-5 161 747 11988




13-Butadiene 00106-99-0 1245 683 85018

ortho-Xylene 00095-47-6 758 620 46937

22-Dimethylbutane 00075-83-2 111 614 6826


Ethylbenzene 00100-41-4 296 564 16718


n-Propylbenzene 00103-65-1 196 527 10333







2-Methylheptane 00592-27-8 097 427 4127


3-Methylheptane 00589-81-1 112 420 4718


14-Diethylbenzene 00105-05-5 439 416 18237

n-Decane 00124-18-5 059 401 2372



Unknown 16 275 325 8937



Methane 00074-82-8 001 281 0039


n-Nonane 00111-84-2 068 234 1599

Styrene 00100-42-5 166 234 3891



4-Methyl-t-2-pentene 00674-76-0 804 187 15065

n-Undecane 01120-21-4 052 186 0970

4-Methyloctane 02216-34-4 085 170 1442


c-2-Heptene 06443-92-1 708 149 10568

Unknown 8 275 147 4049

continued


201

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 1 275 144 3964

Unknown 22 275 143 3926


Unknown 5 275 129 3543



Unknown 13 275 118 3236

33-Dimethylhexane 00563-16-6 115 116 1338

1-Nonene 00124-11-8 249 113 2820


3-Methyloctane 02216-33-3 088 101 0889

3-Me-1-Hexene 03404-61-3 427 096 4100


Indan 00496-11-7 323 071 2300

Total 32476 89876 2767


continued


202

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 172274 1855242


Ethanol 00064-17-5 145 69165 1002190

2-Methylpropane 00075-28-5 118 21941 258154

n-Hexane 00110-54-3 113 20456 232106

Toluene 00108-88-3 393 19883 780424


n-Pentane 00109-66-0 121 17100 207749

2-Methyl-2-butene 00513-35-9 1420 14541 2064164

t-2-Pentene 00646-04-8 1047 12530 1312315

3-Methylpentane 00096-14-0 169 12414 209911

23-Dimethylbutane 00079-29-8 090 8996 80848

2-Methyl-1-butene 00563-46-2 638 8314 530308


c-2-Pentene 00627-20-3 1028 6703 689128


Benzene 00071-43-2 069 5731 39795

c-2-Butene 00590-18-1 1426 5522 787420

Cyclohexane 00110-82-7 114 5520 62783




n-Heptane 00142-82-5 097 2763 26680



2-Methylhexane 00591-76-4 109 2596 28167


t-2-Hexene 04050-45-7 855 2303 196844

Cyclopentene 00142-29-0 669 2024 135325




3-Methyl-t-2-pentene 00616-12-6 1166 1818 211970

2-Methyl-2-pentene 00625-27-4 1103 1651 182150


3-Methyl-c-2-pentene 00922-62-3 1252 1509 188858



22-Dimethylbutane 00075-83-2 111 1289 14328

Propane 00074-98-6 046 1286 5880








203

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 965 15494

n-Octane 00111-65-9 080 867 6901






2-Methylheptane 00592-27-8 097 513 4960

Ethylbenzene 00100-41-4 296 509 15068

ortho-Xylene 00095-47-6 758 500 37892

3-Methylheptane 00589-81-1 112 493 5541








n-Propylbenzene 00103-65-1 196 278 5444

4-Methyl-t-2-pentene 00674-76-0 804 268 21529

Unknown 16 250 236 5907

n-Nonane 00111-84-2 068 228 1557





c-2-Heptene 06443-92-1 708 180 12724



4-Methyloctane 02216-34-4 085 159 1351


Unknown 5 250 146 3658

33-Dimethylhexane 00563-16-6 115 145 1668

Unknown 13 250 138 3462

Indan 00496-11-7 565 135 7640


1-Octene 00111-66-0 314 134 4197


Unknown 8 250 128 3196




continued


204

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




t-4-Octene 14850-23-8 469 113 5317

n-Decane 00124-18-5 059 102 0604

14-Diethylbenzene 00105-05-5 439 092 4032

3-Methyloctane 02216-33-3 088 083 0734

1-Nonene 00124-11-8 249 082 2036

Unknown 9 250 082 2039

t-3-Heptene 14686-14-7 617 074 4560

Unknown 3 250 072 1807

n-Undecane 01120-21-4 052 061 0317

1-Heptene 00592-76-7 429 060 2554



Unknown 12 250 046 1154



t-2-Nonene 06434-78-2 250 036 0888


c-2-Octene 07642-04-8 250 026 0651

Unknown 14 250 018 0459

Total 61958 155900 2516


continued


205

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11715 169746

n-Butane 00106-97-8 108 8056 86757

n-Hexane 00110-54-3 113 4667 52958


23-Dimethylbutane 00079-29-8 090 3624 32566

Toluene 00108-88-3 393 3574 140274

2-Methyl-2-butene 00513-35-9 1420 2721 386293

3-Methylpentane 00096-14-0 169 2686 45414

n-Pentane 00109-66-0 121 2659 32300

t-2-Pentene 00646-04-8 1047 2291 239970

2-Methyl-1-butene 00563-46-2 638 1615 103023



Cyclohexane 00110-82-7 114 1325 15069

2-Methylpropane 00075-28-5 118 1261 14840

c-2-Pentene 00627-20-3 1028 1225 125951

Benzene 00071-43-2 069 1002 6959


c-2-Butene 00590-18-1 1426 984 140348




2-Methylhexane 00591-76-4 109 497 5389



t-2-Hexene 04050-45-7 855 436 37281

n-Heptane 00142-82-5 097 390 3765

Cyclopentene 00142-29-0 669 377 25223


3-Methyl-t-2-pentene 00616-12-6 1166 342 39822

2-Methyl-2-pentene 00625-27-4 1103 323 35657


3-Methyl-c-2-pentene 00922-62-3 1252 294 36799




24-Dimethylhexane 00589-43-5 161 213 3421


n-Octane 00111-65-9 080 185 1477








206

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 141 1566



Propane 00074-98-6 046 113 0517




ortho-Xylene 00095-47-6 758 064 4881


4-Methyl-t-2-pentene 00674-76-0 804 060 4791


n-Decane 00124-18-5 059 057 0338

2-Methylheptane 00592-27-8 097 055 0536



Ethylbenzene 00100-41-4 296 053 1579

3-Methylheptane 00589-81-1 112 052 0582


Unknown 5 288 046 1329

4-Methyloctane 02216-34-4 085 043 0365



33-Dimethylhexane 00563-16-6 115 037 0423

3-Methyloctane 02216-33-3 088 032 0283

n-Nonane 00111-84-2 068 023 0155

n-Propylbenzene 00103-65-1 196 015 0294


Total 8737 25269 2892


continued


207

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35389 512774

Benzene 00071-43-2 069 4816 33438

Methane 00074-82-8 001 200 0028

Ethane 00074-84-0 026 1602 4210


Propane 00074-98-6 046 1131 5168

2-Methylpropane 00075-28-5 118 2369 27872

22-Dimethylbutane 00075-83-2 111 986 10951



23-Dimethylbutane 00079-29-8 090 7961 71544

ortho-Xylene 00095-47-6 758 645 48887


3-Methylpentane 00096-14-0 169 11861 200561



Ethylbenzene 00100-41-4 296 495 14670

n-Propylbenzene 00103-65-1 196 538 10537

n-Butane 00106-97-8 108 20573 221556

13-Butadiene 00106-99-0 1245 657 81767





Toluene 00108-88-3 393 16497 647513

n-Pentane 00109-66-0 121 12943 157255


n-Hexane 00110-54-3 113 19250 218427

Cyclohexane 00110-82-7 114 5321 60521


n-Octane 00111-65-9 080 692 5511

n-Nonane 00111-84-2 068 309 2108


n-Decane 00124-18-5 059 301 1780

Cyclopentene 00142-29-0 669 1453 97125

n-Heptane 00142-82-5 097 1831 17681


2-Methyl-2-butene 00513-35-9 1420 10075 1430132




2-Methyl-1-butene 00563-46-2 638 6277 400401






208

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 1065 17101

3-Methylheptane 00589-81-1 112 512 5752

c-2-Butene 00590-18-1 1426 4141 590493



2-Methylhexane 00591-76-4 109 2197 23841


2-Methylheptane 00592-27-8 097 512 4948



3-Methyl-t-2-pentene 00616-12-6 1166 1347 156999


2-Methyl-2-pentene 00625-27-4 1103 1253 138231

c-2-Pentene 00627-20-3 1028 4701 483353


t-2-Pentene 00646-04-8 1047 8504 890689





3-Methyl-c-2-pentene 00922-62-3 1252 1185 148379







t-2-Hexene 04050-45-7 855 1625 138889


Unknown 16 335 352 11791

Unknown 1 335 242 8119

Total 34405 116244 3379


continued


209

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 112868 1635432

n-Butane 00106-97-8 108 58158 626316

n-Hexane 00110-54-3 113 44646 506591


n-Pentane 00109-66-0 121 30821 374457

3-Methylpentane 00096-14-0 169 26164 442392

2-Methyl-2-butene 00513-35-9 1420 25929 3680648

Toluene 00108-88-3 393 23727 931277

t-2-Pentene 00646-04-8 1047 21858 2289338

23-Dimethylbutane 00079-29-8 090 18155 163160

2-Methyl-1-butene 00563-46-2 638 14852 947358



c-2-Pentene 00627-20-3 1028 11711 1204011

Cyclohexane 00110-82-7 114 10272 116827


c-2-Butene 00590-18-1 1426 8497 1211611

Benzene 00071-43-2 069 8447 58652

2-Methylpropane 00075-28-5 118 7517 88450



2-Methylhexane 00591-76-4 109 4449 48279



t-2-Hexene 04050-45-7 855 3861 330080


Cyclopentene 00142-29-0 669 3403 227545

n-Heptane 00142-82-5 097 3263 31514

3-Methyl-t-2-pentene 00616-12-6 1166 3087 359933


2-Methyl-2-pentene 00625-27-4 1103 2833 312515


3-Methyl-c-2-pentene 00922-62-3 1252 2551 319336



22-Dimethylbutane 00075-83-2 111 2302 25580


24-Dimethylhexane 00589-43-5 161 1503 24139

Propane 00074-98-6 046 1456 6658








210

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




1-Butyne 00107-00-6 605 1088 65828

n-Octane 00111-65-9 080 827 6585









2-Methylheptane 00592-27-8 097 486 4701

3-Methylheptane 00589-81-1 112 442 4965

ortho-Xylene 00095-47-6 758 367 27827







Ethylbenzene 00100-41-4 296 241 7138



n-Propylbenzene 00103-65-1 196 204 4004

Unknown 5 295 172 5063

33-Dimethylhexane 00563-16-6 115 164 1888


c-2-Heptene 06443-92-1 708 133 9383

n-Nonane 00111-84-2 068 125 0851

1-Octene 00111-66-0 314 124 3881

Indan 00496-11-7 323 119 3852

t-3-Heptene 14686-14-7 617 114 7031

Ethylene 00074-85-1 888 113 10031

4-Methyloctane 02216-34-4 085 111 0942


Unknown 16 295 101 2970

Unknown 3 295 097 2854

Unknown 6 295 097 2845




Unknown 8 295 081 2388

n-Decane 00124-18-5 059 080 0470

continued


211

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 13 295 079 2322

3-Methyloctane 02216-33-3 088 077 0681


13-Butadiene 00106-99-0 1245 076 9484


1-Heptene 00592-76-7 429 060 2584



Unknown 9 295 047 1372


1-Nonene 00124-11-8 249 039 0967

n-Undecane 01120-21-4 052 039 0202

3-Ethyl-c-2-Pentene 00816-79-5 976 038 3690






14-Diethylbenzene 00105-05-5 439 016 0705


Unknown 22 295 005 0140

Total 76987 227741 2958


continued


212

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 24872 267848


Ethanol 00064-17-5 145 7522 108992

n-Hexane 00110-54-3 113 2284 25919

Toluene 00108-88-3 393 1833 71943


3-Methylpentane 00096-14-0 169 1742 29458

2-Methyl-2-butene 00513-35-9 1420 1698 240966

n-Pentane 00109-66-0 121 1576 19144

t-2-Pentene 00646-04-8 1047 1511 158229

23-Dimethylbutane 00079-29-8 090 1202 10800


2-Methyl-1-butene 00563-46-2 638 1039 66260


Benzene 00071-43-2 069 892 6192

c-2-Pentene 00627-20-3 1028 805 82752

c-2-Butene 00590-18-1 1426 802 114334

Cyclohexane 00110-82-7 114 799 9092



2-Methylpropane 00075-28-5 118 646 7600

1-Butyne 00107-00-6 605 646 39077




2-Methylhexane 00591-76-4 109 405 4399





Propane 00074-98-6 046 326 1490

t-2-Hexene 04050-45-7 855 306 26148

n-Heptane 00142-82-5 097 305 2946



Cyclopentene 00142-29-0 669 242 16150

3-Methyl-t-2-pentene 00616-12-6 1166 237 27634


3-Methyl-c-2-pentene 00922-62-3 1252 219 27369

ortho-Xylene 00095-47-6 758 215 16278

2-Methyl-2-pentene 00625-27-4 1103 210 23172







213

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 178 1977


24-Dimethylhexane 00589-43-5 161 139 2225

n-Octane 00111-65-9 080 130 1032


Ethylbenzene 00100-41-4 296 119 3519




n-Propylbenzene 00103-65-1 196 104 2036




3-Methylheptane 00589-81-1 112 074 0827






2-Methylheptane 00592-27-8 097 047 0455


n-Nonane 00111-84-2 068 046 0315

Total 7427 20164 2715


continued


214

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 42844 461388


Ethanol 00064-17-5 145 17178 248906

Toluene 00108-88-3 393 10047 394340

n-Hexane 00110-54-3 113 8065 91515


3-Methylpentane 00096-14-0 169 4491 75939

n-Pentane 00109-66-0 121 4370 53093

2-Methyl-2-butene 00513-35-9 1420 3637 516297


23-Dimethylbutane 00079-29-8 090 2956 26564

t-2-Pentene 00646-04-8 1047 2864 299954


Benzene 00071-43-2 069 2591 17991

Cyclohexane 00110-82-7 114 2542 28906



2-Methyl-1-butene 00563-46-2 638 1881 119952

c-2-Butene 00590-18-1 1426 1857 264799

c-2-Pentene 00627-20-3 1028 1775 182543


Ethylene 00074-85-1 888 1636 145343

n-Heptane 00142-82-5 097 1536 14831



Ethane 00074-84-0 026 1261 3314



Methane 00074-82-8 001 1067 0148


2-Methylhexane 00591-76-4 109 1026 11134


Propane 00074-98-6 046 809 3698


t-2-Hexene 04050-45-7 855 760 65002

n-Octane 00111-65-9 080 636 5062


3-Methyl-t-2-pentene 00616-12-6 1166 604 70439


Cyclopentene 00142-29-0 669 555 37098

13-Butadiene 00106-99-0 1245 530 66022







215

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




2-Methyl-2-pentene 00625-27-4 1103 503 55446




ortho-Xylene 00095-47-6 758 427 32375

n-Propylbenzene 00103-65-1 196 425 8330

3-Methyl-c-2-pentene 00922-62-3 1252 419 52480




Ethylbenzene 00100-41-4 296 312 9253

22-Dimethylbutane 00075-83-2 111 306 3401


3-Methylheptane 00589-81-1 112 296 3328


2-Methylpropane 00075-28-5 118 281 3306


24-Dimethylhexane 00589-43-5 161 250 4021

2-Methylheptane 00592-27-8 097 238 2306






Unknown 1 284 172 4890




Total 18066 51521 2852


continued


216

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 316658 3410131


Ethanol 00064-17-5 145 67831 982860

n-Hexane 00110-54-3 113 32071 363900


n-Pentane 00109-66-0 121 25077 304666

2-Methyl-2-butene 00513-35-9 1420 20849 2959520

3-Methylpentane 00096-14-0 169 19682 332790

t-2-Pentene 00646-04-8 1047 17641 1847614

Toluene 00108-88-3 393 15091 592313

23-Dimethylbutane 00079-29-8 090 13982 125657

2-Methyl-1-butene 00563-46-2 638 12182 777050

c-2-Pentene 00627-20-3 1028 9542 981058



2-Methylpropane 00075-28-5 118 7882 92741


Cyclohexane 00110-82-7 114 7483 85109

c-2-Butene 00590-18-1 1426 7117 1014871

Benzene 00071-43-2 069 6155 42735


2-Methylhexane 00591-76-4 109 3304 35857


t-2-Hexene 04050-45-7 855 3007 257097



Cyclopentene 00142-29-0 669 2736 182929


3-Methyl-t-2-pentene 00616-12-6 1166 2425 282759

n-Heptane 00142-82-5 097 2420 23372

2-Methyl-2-pentene 00625-27-4 1103 2238 246882


3-Methyl-c-2-pentene 00922-62-3 1252 2008 251353


22-Dimethylbutane 00075-83-2 111 1932 21463







24-Dimethylhexane 00589-43-5 161 1135 18218






217

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





1-Butyne 00107-00-6 605 772 46679

n-Octane 00111-65-9 080 671 5344



Propane 00074-98-6 046 568 2596





2-Methylheptane 00592-27-8 097 469 4538


3-Methylheptane 00589-81-1 112 433 4866



ortho-Xylene 00095-47-6 758 325 24656




Ethylbenzene 00100-41-4 296 255 7563

n-Propylbenzene 00103-65-1 196 248 4851


n-Nonane 00111-84-2 068 175 1194

Unknown 5 240 166 3989

33-Dimethylhexane 00563-16-6 115 165 1905

n-Decane 00124-18-5 059 164 0967



c-2-Heptene 06443-92-1 708 144 10185



Unknown 16 240 132 3163



4-Methyloctane 02216-34-4 085 108 0916

n-Undecane 01120-21-4 052 106 0553

t-3-Heptene 14686-14-7 617 101 6224


Unknown 3 240 067 1615

1-Heptene 00592-76-7 429 066 2838

13-Butadiene 00106-99-0 1245 060 7523


3-Methyloctane 02216-33-3 088 059 0525

continued


218

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyloctane 02216-33-3 088 059 0525



Unknown 22 240 053 1268

1-Nonene 00124-11-8 249 047 1178

Unknown 8 240 047 1119


Indan 00496-11-7 323 033 1060

14-Diethylbenzene 00105-05-5 439 027 1190

Total 86321 207927 2409


continued


219

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5716 82823

Benzene 00071-43-2 069 818 5680

Propane 00074-98-6 046 141 0644

2-Methylpropane 00075-28-5 118 344 4046


23-Dimethylbutane 00079-29-8 090 819 7363


3-Methylpentane 00096-14-0 169 1189 20098


n-Butane 00106-97-8 108 3676 39588

Toluene 00108-88-3 393 2159 84759

n-Pentane 00109-66-0 121 1545 18766

n-Hexane 00110-54-3 113 2616 29678

2-Methyl-2-butene 00513-35-9 1420 1237 175649



t-2-Pentene 00646-04-8 1047 1196 125262


Total 3415 8597 2517





220

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 13363 193622

Benzene 00071-43-2 069 2498 17342

Methane 00074-82-8 001 1601 0222

Ethane 00074-84-0 026 1146 3013

Ethylene 00074-85-1 888 1976 175570

2-Methylpropane 00075-28-5 118 312 3675

22-Dimethylbutane 00075-83-2 111 419 4659



23-Dimethylbutane 00079-29-8 090 2658 23890

ortho-Xylene 00095-47-6 758 471 35666


3-Methylpentane 00096-14-0 169 4167 70465




Ethylbenzene 00100-41-4 296 483 14312

n-Propylbenzene 00103-65-1 196 549 10766

14-Diethylbenzene 00105-05-5 439 366 16071

n-Butane 00106-97-8 108 6249 67299

13-Butadiene 00106-99-0 1245 678 84410

1-Butyne 00107-00-6 605 843 50998





Toluene 00108-88-3 393 9872 387494

n-Pentane 00109-66-0 121 3931 47757


n-Hexane 00110-54-3 113 7372 83651

Cyclohexane 00110-82-7 114 2206 25094


n-Octane 00111-65-9 080 595 4737

n-Nonane 00111-84-2 068 180 1229

1-Dodecene 00112-41-4 156 142 2220


n-Decane 00124-18-5 059 631 3731

Cyclopentene 00142-29-0 669 568 37986

n-Heptane 00142-82-5 097 940 9074


Indan 00496-11-7 323 222 7175

2-Methyl-2-butene 00513-35-9 1420 3288 466742






221

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






33-Dimethyl-1-butene 00558-37-2 568 092 5207


33-Dimethylhexane 00563-16-6 115 164 1893

2-Methyl-1-butene 00563-46-2 638 1833 116899




24-Dimethylhexane 00589-43-5 161 689 11062

3-Methylheptane 00589-81-1 112 195 2189

c-2-Butene 00590-18-1 1426 1053 150118


2-Methylhexane 00591-76-4 109 1016 11022


2-Methylheptane 00592-27-8 097 452 4375



3-Methyl-t-2-pentene 00616-12-6 1166 664 77449



2-Methyl-2-pentene 00625-27-4 1103 641 70697

c-2-Pentene 00627-20-3 1028 1401 144091


t-2-Pentene 00646-04-8 1047 2698 282558





continued


222

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 649 81193






4-Methyloctane 02216-34-4 085 175 1482




t-2-Hexene 04050-45-7 855 875 74823


c-2-Heptene 06443-92-1 066 121 0790


Unknown 16 342 407 13925

Unknown 13 342 172 5885

Unknown 1 342 111 3781

Total 13962 48361 3464


continued


223

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 93713 1357878

Benzene 00071-43-2 069 8395 58292

Ethylene 00074-85-1 888 385 34170

Propane 00074-98-6 046 2204 10077

2-Methylpropane 00075-28-5 118 9571 112611

22-Dimethylbutane 00075-83-2 111 1771 19683



23-Dimethylbutane 00079-29-8 090 17445 156779

ortho-Xylene 00095-47-6 758 670 50741


3-Methylpentane 00096-14-0 169 25280 427457



Ethylbenzene 00100-41-4 296 381 11287

n-Propylbenzene 00103-65-1 196 340 6654

n-Butane 00106-97-8 108 45349 488366

13-Butadiene 00106-99-0 1245 098 12253

1-Butyne 00107-00-6 605 785 47505






Toluene 00108-88-3 393 27004 1059911

n-Pentane 00109-66-0 121 24220 294263


n-Hexane 00110-54-3 113 42008 476657

Cyclohexane 00110-82-7 114 10300 117149


n-Octane 00111-65-9 080 1207 9611

1-Octene 00111-66-0 314 135 4256

n-Nonane 00111-84-2 068 238 1626


1-Nonene 00124-11-8 249 109 2715

n-Decane 00124-18-5 059 372 2201

Cyclopentene 00142-29-0 669 2697 180349

n-Heptane 00142-82-5 097 3372 32566



Indan 00496-11-7 323 253 8173

2-Methyl-2-butene 00513-35-9 1420 20269 2877200







224

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





33-Dimethylhexane 00563-16-6 115 181 2080

2-Methyl-1-butene 00563-46-2 638 11748 749377




24-Dimethylhexane 00589-43-5 161 2049 32895

3-Methylheptane 00589-81-1 112 880 9892

c-2-Butene 00590-18-1 1426 7564 1078587



2-Methylhexane 00591-76-4 109 4571 49606


2-Methylheptane 00592-27-8 097 923 8932


1-Heptene 00592-76-7 429 108 4612


3-Methyl-t-2-pentene 00616-12-6 1166 3093 360613



2-Methyl-2-pentene 00625-27-4 1103 2810 309980

c-2-Pentene 00627-20-3 1028 9207 946625


t-2-Pentene 00646-04-8 1047 17071 1787966





3-Methyl-c-2-pentene 00922-62-3 1252 2468 308948







3-Methyloctane 02216-33-3 088 167 1477

4-Methyloctane 02216-34-4 085 247 2098





continued


225

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





t-2-Hexene 04050-45-7 855 3716 317667

t-2-Nonene 06434-78-2 290 075 2171

c-2-Heptene 06443-92-1 708 211 14913


t-3-Heptene 14686-14-7 617 198 12193

Unknown 5 290 413 11999

Unknown 16 290 404 11736

Unknown 13 290 190 5520

Unknown 8 290 136 3963

Unknown 3 290 085 2475

Unknown 9 290 084 2439

Total 68582 200436 2923


continued


226


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


227

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 22971 247380


n-Hexane 00110-54-3 113 2483 28180


n-Pentane 00109-66-0 121 1817 22079

3-Methylpentane 00096-14-0 169 1584 26779

2-Methyl-2-butene 00513-35-9 1420 1509 214170

t-2-Pentene 00646-04-8 1047 1269 132895

Toluene 00108-88-3 393 1202 47172

23-Dimethylbutane 00079-29-8 090 1103 9914

c-2-Butene 00590-18-1 1426 904 128849

2-Methyl-1-butene 00563-46-2 638 890 56745



c-2-Pentene 00627-20-3 1028 680 69944

2-Methylpropane 00075-28-5 118 645 7585

t-2-Butene 00624-64-6 1520 536 81392


Cyclohexane 00110-82-7 114 519 5901


Benzene 00071-43-2 069 479 3328





2-Methylhexane 00591-76-4 109 227 2467

t-2-Hexene 04050-45-7 855 211 18015

Cyclopentene 00142-29-0 669 199 13290

n-Heptane 00142-82-5 097 194 1873



3-Methyl-t-2-pentene 00616-12-6 1166 176 20565



3-Methyl-1-butene 00563-45-1 685 153 10520

2-Methyl-2-pentene 00625-27-4 1103 152 16805







22-Dimethylbutane 00075-83-2 111 119 1317





228

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 115 14408

n-Octane 00111-65-9 080 107 0853


ortho-Xylene 00095-47-6 758 102 7756








n-Propylbenzene 00103-65-1 196 046 0903


2-Methylheptane 00592-27-8 097 041 0396



Ethylbenzene 00100-41-4 296 007 0221

24-Dimethylhexane 00589-43-5 161 006 0101

Total 6278 16694 2659


continued


229

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Unknown 22 307 391 12012

Ethanol 00064-17-5 145 1321 19145

Benzene 00071-43-2 069 2139 14852

Propane 00074-98-6 046 397 1816

2-Methylpropane 00075-28-5 118 3636 42785

22-Dimethylbutane 00075-83-2 111 842 9359



23-Dimethylbutane 00079-29-8 090 2973 26719

ortho-Xylene 00095-47-6 758 337 25550


3-Methylpentane 00096-14-0 169 3756 63505


Ethylbenzene 00100-41-4 296 220 6505

n-Propylbenzene 00103-65-1 196 202 3961

n-Butane 00106-97-8 108 56598 609509






Toluene 00108-88-3 393 2903 113947

n-Pentane 00109-66-0 121 5036 61181


n-Hexane 00110-54-3 113 7233 82075

Cyclohexane 00110-82-7 114 3248 36942


n-Octane 00111-65-9 080 252 2004


Cyclopentene 00142-29-0 669 913 61061

n-Heptane 00142-82-5 097 978 9444


2-Methyl-2-butene 00513-35-9 1420 4143 588042




2-Methyl-1-butene 00563-46-2 638 4234 270054




24-Dimethylhexane 00589-43-5 161 832 13366

3-Methylheptane 00589-81-1 112 179 2017

c-2-Butene 00590-18-1 1426 7009 999462





230

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





2-Methylhexane 00591-76-4 109 1400 15189


2-Methylheptane 00592-27-8 097 175 1693



3-Methyl-t-2-pentene 00616-12-6 1166 815 95045



2-Methyl-2-pentene 00625-27-4 1103 777 85750

c-2-Pentene 00627-20-3 1028 3096 318320

t-2-Pentene 00646-04-8 1047 3554 372250





3-Methyl-c-2-pentene 00922-62-3 1252 712 89120




t-2-Hexene 04050-45-7 855 994 84993


Unknown 1 307 061 1868

Total 19657 60694 3088


continued


231

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 307727 3313949


Ethanol 00064-17-5 145 39672 574830

n-Hexane 00110-54-3 113 34020 386019


n-Pentane 00109-66-0 121 28021 340433

3-Methylpentane 00096-14-0 169 22023 372381

2-Methyl-2-butene 00513-35-9 1420 20648 2930948

t-2-Pentene 00646-04-8 1047 17405 1822913

23-Dimethylbutane 00079-29-8 090 16047 144212

Toluene 00108-88-3 393 14387 564695

2-Methyl-1-butene 00563-46-2 638 12969 827211

c-2-Butene 00590-18-1 1426 11793 1681690



c-2-Pentene 00627-20-3 1028 9515 978316

Cyclohexane 00110-82-7 114 9043 102849


Benzene 00071-43-2 069 6756 46910



2-Methylhexane 00591-76-4 109 3473 37687



3-Methyl-t-2-pentene 00616-12-6 1166 2951 344072


2-Methylpropane 00075-28-5 118 2769 32579

Cyclopentene 00142-29-0 669 2682 179344



n-Heptane 00142-82-5 097 2413 23305

2-Methyl-2-pentene 00625-27-4 1103 2292 252898

24-Dimethylhexane 00589-43-5 161 2070 33231

t-2-Hexene 04050-45-7 855 2064 176446

3-Methyl-c-2-pentene 00922-62-3 1252 2063 258275

22-Dimethylbutane 00075-83-2 111 1886 20962







232

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








Propane 00074-98-6 046 400 1829


Ethylbenzene 00100-41-4 296 342 10143

Total 85443 209022 2446


continued


233

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11488 166456

n-Butane 00106-97-8 108 7975 85883

n-Hexane 00110-54-3 113 6913 78445


n-Pentane 00109-66-0 121 4885 59344

3-Methylpentane 00096-14-0 169 4260 72030

2-Methyl-2-butene 00513-35-9 1420 4013 569617

t-2-Pentene 00646-04-8 1047 3313 346941

Toluene 00108-88-3 393 3059 120057

23-Dimethylbutane 00079-29-8 090 2976 26746

2-Methyl-1-butene 00563-46-2 638 2453 156477



c-2-Butene 00590-18-1 1426 1891 269674

c-2-Pentene 00627-20-3 1028 1824 187499

Cyclohexane 00110-82-7 114 1684 19156

t-2-Butene 00624-64-6 1520 1597 242714


2-Methylpropane 00075-28-5 118 1543 18157

Benzene 00071-43-2 069 1143 7936




2-Methylhexane 00591-76-4 109 714 7751



t-2-Hexene 04050-45-7 855 596 50989


Cyclopentene 00142-29-0 669 507 33919

3-Methyl-t-2-pentene 00616-12-6 1166 499 58164


2-Methyl-2-pentene 00625-27-4 1103 459 50603

Propane 00074-98-6 046 439 2008


n-Heptane 00142-82-5 097 430 4150

3-Methyl-c-2-pentene 00922-62-3 1252 414 51810

22-Dimethylbutane 00075-83-2 111 382 4244



24-Dimethylhexane 00589-43-5 161 288 4618







234

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 130 1038



2-Methylheptane 00592-27-8 097 099 0957



3-Methylheptane 00589-81-1 112 083 0929





t-3-Heptene 14686-14-7 617 051 3173



Unknown 5 321 043 1371


Ethylbenzene 00100-41-4 296 040 1173

33-Dimethylhexane 00563-16-6 115 036 0411

ortho-Xylene 00095-47-6 758 035 2689

n-Propylbenzene 00103-65-1 196 035 0690


Total 11846 38214 3226


continued


235

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Butane 00106-97-8 108 7470 80442

n-Hexane 00110-54-3 113 7413 84118

n-Pentane 00109-66-0 121 5151 62576


3-Methylpentane 00096-14-0 169 4543 76808

2-Methyl-2-butene 00513-35-9 1420 4232 600795

t-2-Pentene 00646-04-8 1047 3542 371010

Toluene 00108-88-3 393 3511 137807

23-Dimethylbutane 00079-29-8 090 3268 29366

c-2-Butene 00590-18-1 1426 3176 452906

1-Butyne 00107-00-6 605 2943 178046

2-Methyl-1-butene 00563-46-2 638 2779 177240


c-2-Pentene 00627-20-3 1028 2047 210481


Cyclohexane 00110-82-7 114 1938 22040


2-Methylpropane 00075-28-5 118 1317 15500

Benzene 00071-43-2 069 1229 8533



Ethanol 00064-17-5 145 810 11731



2-Methylhexane 00591-76-4 109 691 7494

t-2-Hexene 04050-45-7 855 621 53050

n-Heptane 00142-82-5 097 579 5588


Cyclopentene 00142-29-0 669 574 38396


2-Methyl-2-pentene 00625-27-4 1103 486 53633



3-Methyl-c-2-pentene 00922-62-3 1252 468 58610

3-Methyl-t-2-pentene 00616-12-6 1166 457 53286


Methane 00074-82-8 001 444 0061

22-Dimethylbutane 00075-83-2 111 431 4788








236

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 328 5262


n-Octane 00111-65-9 080 282 2250


n-Decane 00124-18-5 059 276 1632

Unknown 22 335 234 7864






2-Methylheptane 00592-27-8 097 160 1548

3-Methylheptane 00589-81-1 112 144 1615




n-Propylbenzene 00103-65-1 196 113 2208

Unknown 1 335 094 3164


Indan 00496-11-7 323 084 2722


Ethylbenzene 00100-41-4 296 067 1991

n-Undecane 01120-21-4 052 047 0244

ortho-Xylene 00095-47-6 758 043 3244

Total 13128 44311 3375


continued


237

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 23123 249015

Ethanol 00064-17-5 145 21703 314477

n-Hexane 00110-54-3 113 18050 204804


n-Pentane 00109-66-0 121 13834 168070

3-Methylpentane 00096-14-0 169 11505 194534

2-Methyl-2-butene 00513-35-9 1420 11209 1591055

t-2-Pentene 00646-04-8 1047 9469 991727

23-Dimethylbutane 00079-29-8 090 8278 74396

2-Methyl-1-butene 00563-46-2 638 6814 434644

Toluene 00108-88-3 393 6647 260916


c-2-Pentene 00627-20-3 1028 5152 529739



c-2-Butene 00590-18-1 1426 4525 645316

Cyclohexane 00110-82-7 114 4341 49370

1-Butyne 00107-00-6 605 3288 198937

2-Methylpropane 00075-28-5 118 3175 37353

Benzene 00071-43-2 069 2711 18826



2-Methylhexane 00591-76-4 109 1773 19242




t-2-Hexene 04050-45-7 855 1516 129592

Cyclopentene 00142-29-0 669 1453 97160

3-Methyl-t-2-pentene 00616-12-6 1166 1242 144819


2-Methyl-2-pentene 00625-27-4 1103 1149 126792

3-Methyl-c-2-pentene 00922-62-3 1252 1075 134519


22-Dimethylbutane 00075-83-2 111 1058 11760

n-Heptane 00142-82-5 097 1036 10005






24-Dimethylhexane 00589-43-5 161 606 9728






238

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Propane 00074-98-6 046 476 2175








n-Octane 00111-65-9 080 260 2066






2-Methylheptane 00592-27-8 097 198 1916

Ethylbenzene 00100-41-4 296 198 5852

3-Methylheptane 00589-81-1 112 177 1989


ortho-Xylene 00095-47-6 758 163 12357



Unknown 1 313 123 3845

Unknown 16 313 116 3646

n-Decane 00124-18-5 059 110 0648

n-Propylbenzene 00103-65-1 196 088 1715



Unknown 5 313 070 2205

c-2-Heptene 06443-92-1 708 065 4610

33-Dimethylhexane 00563-16-6 115 065 0749

n-Nonane 00111-84-2 068 049 0335

t-3-Heptene 14686-14-7 617 043 2680


13-Butadiene 00106-99-0 1245 042 5279

4-Methyl-t-2-pentene 00674-76-0 804 021 1722

Methane 00074-82-8 001 008 0001

Total 31093 97716 3143


continued


239

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 39458 424924


Ethanol 00064-17-5 145 10129 146760

2-Methylpropane 00075-28-5 118 5716 67259

n-Hexane 00110-54-3 113 4068 46161


n-Pentane 00109-66-0 121 3154 38314

3-Methylpentane 00096-14-0 169 2555 43201

2-Methyl-2-butene 00513-35-9 1420 2451 347976

t-2-Pentene 00646-04-8 1047 2085 218342

Toluene 00108-88-3 393 2039 80037

23-Dimethylbutane 00079-29-8 090 1831 16453

2-Methyl-1-butene 00563-46-2 638 1510 96290



c-2-Pentene 00627-20-3 1028 1123 115451

Cyclohexane 00110-82-7 114 1042 11856


c-2-Butene 00590-18-1 1426 833 118751

Benzene 00071-43-2 069 781 5423

Propane 00074-98-6 046 619 2830



22-DiMeHexane 00590-73-8 094 513 4827

2-Methylhexane 00591-76-4 109 460 4988

1-Butyne 00107-00-6 605 379 22956

t-2-Hexene 04050-45-7 855 374 31963


t-3-Heptene 14686-14-7 617 351 21645


Cyclopentene 00142-29-0 669 328 21962

3-Methyl-t-2-pentene 00616-12-6 1166 304 35469


2-Methyl-2-pentene 00625-27-4 1103 284 31321



3-Methyl-c-2-pentene 00922-62-3 1252 256 32099


22-Dimethylbutane 00075-83-2 111 222 2468









240

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 5 230 105 2411


Unknown 7 230 082 1885




Unknown 17 230 069 1596


2-Methylheptane 00592-27-8 097 066 0636



n-Propylbenzene 00103-65-1 196 046 0909



n-Nonane 00111-84-2 068 037 0255


ortho-Xylene 00095-47-6 758 027 2080

Unknown 1 230 027 0619


Ethylbenzene 00100-41-4 296 019 0574

c-2-Octene 07642-04-8 230 007 0157

Total 11484 26563 2313


continued


241

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 622650 6705400


Ethanol 00064-17-5 145 124094 1798086

n-Hexane 00110-54-3 113 67518 766114


n-Pentane 00109-66-0 121 46672 567029

3-Methylpentane 00096-14-0 169 41573 702943

2-Methyl-2-butene 00513-35-9 1420 39233 5569075

Toluene 00108-88-3 393 33167 1301796

t-2-Pentene 00646-04-8 1047 32239 3376598

23-Dimethylbutane 00079-29-8 090 29164 262093

2-Methylpropane 00075-28-5 118 23323 274414

2-Methyl-1-butene 00563-46-2 638 22688 1447167



c-2-Pentene 00627-20-3 1028 17645 1814172

Cyclohexane 00110-82-7 114 16882 192015


c-2-Butene 00590-18-1 1426 12775 1821732

Benzene 00071-43-2 069 11664 80988



2-Methylhexane 00591-76-4 109 7254 78719




t-2-Hexene 04050-45-7 855 5835 498847


Cyclopentene 00142-29-0 669 5140 343686

3-Methyl-t-2-pentene 00616-12-6 1166 4795 559045

n-Heptane 00142-82-5 097 4710 45487

2-Methyl-2-pentene 00625-27-4 1103 4548 501761


3-Methyl-c-2-pentene 00922-62-3 1252 4046 506426

22-Dimethylbutane 00075-83-2 111 3825 42506

1-Butyne 00107-00-6 605 3692 223362



Propane 00074-98-6 046 2935 13414


24-Dimethylhexane 00589-43-5 161 2703 43405







242

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 1249 9946



2-Methylheptane 00592-27-8 097 924 8935


3-Methylheptane 00589-81-1 112 747 8400




ortho-Xylene 00095-47-6 758 623 47185



Indan 00496-11-7 323 477 15440



n-Nonane 00111-84-2 068 408 2788

Ethylbenzene 00100-41-4 296 406 12023


n-Propylbenzene 00103-65-1 196 329 6454




Unknown 5 237 273 6466

1-Octene 00111-66-0 314 250 7855

33-Dimethylhexane 00563-16-6 115 231 2665

c-2-Heptene 06443-92-1 708 230 16249

n-Decane 00124-18-5 059 227 1339

t-3-Heptene 14686-14-7 617 214 13214

4-Methyloctane 02216-34-4 085 185 1572

3-Methyloctane 02216-33-3 088 159 1405

14-Diethylbenzene 00105-05-5 439 144 6326

Unknown 3 237 139 3291


1-Heptene 00592-76-7 429 128 5491

Unknown 8 237 120 2850


continued


243

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 22 237 096 2267

13-Butadiene 00106-99-0 1245 092 11436

n-Undecane 01120-21-4 052 084 0439

Unknown 16 237 055 1290

Total 169783 402961 2373


continued


244

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 421885 4543329


Ethanol 00064-17-5 145 63956 926704

n-Hexane 00110-54-3 113 42103 477731


n-Pentane 00109-66-0 121 32695 397223

3-Methylpentane 00096-14-0 169 26461 447417

2-Methyl-2-butene 00513-35-9 1420 26231 3723433

t-2-Pentene 00646-04-8 1047 21783 2281458

23-Dimethylbutane 00079-29-8 090 18965 170438

2-Methyl-1-butene 00563-46-2 638 15351 979200

Toluene 00108-88-3 393 12682 497783


c-2-Pentene 00627-20-3 1028 11853 1218653


2-Methylpropane 00075-28-5 118 9786 115144

Cyclohexane 00110-82-7 114 9561 108746


c-2-Butene 00590-18-1 1426 9027 1287178

Benzene 00071-43-2 069 6124 42524




2-Methylhexane 00591-76-4 109 3992 43324


1-Butyne 00107-00-6 605 3305 199919

Cyclopentene 00142-29-0 669 3296 220392


n-Heptane 00142-82-5 097 2810 27134

2-Methyl-2-pentene 00625-27-4 1103 2648 292135


3-Methyl-t-2-pentene 00616-12-6 1166 2537 295819


22-Dimethylbutane 00075-83-2 111 2430 27002

3-Methyl-c-2-pentene 00922-62-3 1252 2312 289438

t-2-Hexene 04050-45-7 855 2269 193990



24-Dimethylhexane 00589-43-5 161 1392 22345






Total 107832 252202 2339






245

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 6816 73402

n-Hexane 00110-54-3 113 3742 42455


Ethanol 00064-17-5 145 3387 49080

n-Pentane 00109-66-0 121 3097 37631

3-Methylpentane 00096-14-0 169 2395 40491

2-Methyl-2-butene 00513-35-9 1420 2381 337913

t-2-Pentene 00646-04-8 1047 1985 207950

23-Dimethylbutane 00079-29-8 090 1735 15592

Toluene 00108-88-3 393 1702 66802

2-Methyl-1-butene 00563-46-2 638 1455 92799



c-2-Pentene 00627-20-3 1028 1091 112168

Cyclohexane 00110-82-7 114 918 10442


c-2-Butene 00590-18-1 1426 822 117258

Benzene 00071-43-2 069 614 4266



1-Butyne 00107-00-6 605 420 25383

2-Methylpropane 00075-28-5 118 409 4811


2-Methylhexane 00591-76-4 109 397 4310


t-2-Hexene 04050-45-7 855 332 28352

Cyclopentene 00142-29-0 669 320 21388



3-Methyl-t-2-pentene 00616-12-6 1166 278 32432


2-Methyl-2-pentene 00625-27-4 1103 263 28991

n-Heptane 00142-82-5 097 261 2517

3-Methyl-c-2-pentene 00922-62-3 1252 211 26449


22-Dimethylbutane 00075-83-2 111 192 2132











246

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





24-Dimethylhexane 00589-43-5 161 128 2054

Propane 00074-98-6 046 125 0570




n-Octane 00111-65-9 080 098 0779







3-Methylheptane 00589-81-1 112 044 0498

2-Methylheptane 00592-27-8 097 044 0429


ortho-Xylene 00095-47-6 758 035 2631


n-Propylbenzene 00103-65-1 196 031 0598

Ethylbenzene 00100-41-4 296 015 0439

Total 6829 20748 3038


continued


247

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 36810 533364

n-Butane 00106-97-8 108 26480 285167

n-Hexane 00110-54-3 113 21599 245076


n-Pentane 00109-66-0 121 15798 191932

3-Methylpentane 00096-14-0 169 13417 226870

2-Methyl-2-butene 00513-35-9 1420 12566 1783699

t-2-Pentene 00646-04-8 1047 10774 1128460

Toluene 00108-88-3 393 10319 405014

23-Dimethylbutane 00079-29-8 090 9397 84455

2-Methyl-1-butene 00563-46-2 638 7705 491485



c-2-Pentene 00627-20-3 1028 5741 590268

Cyclohexane 00110-82-7 114 5656 64330


c-2-Butene 00590-18-1 1426 4360 621746

Benzene 00071-43-2 069 3722 25841

1-Butyne 00107-00-6 605 3308 200127




2-Methylhexane 00591-76-4 109 2460 26697

2-Methylpropane 00075-28-5 118 2442 28735




t-2-Hexene 04050-45-7 855 1875 160280



Cyclopentene 00142-29-0 669 1630 108972


3-Methyl-t-2-pentene 00616-12-6 1166 1439 167759

2-Methyl-2-pentene 00625-27-4 1103 1392 153551

n-Heptane 00142-82-5 097 1191 11503



3-Methyl-c-2-pentene 00922-62-3 1252 1118 139900

24-Dimethylhexane 00589-43-5 161 1101 17683



22-Dimethylbutane 00075-83-2 111 996 11062





248

Species CAS No MIR

Composite

VOC

mg

Ozone

mg









n-Octane 00111-65-9 080 676 5383



Propane 00074-98-6 046 584 2670


ortho-Xylene 00095-47-6 758 532 40274


n-Propylbenzene 00103-65-1 196 490 9599




3-Methylheptane 00589-81-1 112 429 4820

14-Diethylbenzene 00105-05-5 439 417 18308



2-Methylheptane 00592-27-8 097 275 2658

Indan 00496-11-7 323 271 8760

n-Nonane 00111-84-2 068 254 1733


n-Decane 00124-18-5 059 145 0857

Ethylbenzene 00100-41-4 296 134 3977

Total 38384 118469 3086


continued


249

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 29218 423362

n-Butane 00106-97-8 108 29007 312377

n-Hexane 00110-54-3 113 24380 276633


3-Methylpentane 00096-14-0 169 15596 263709

n-Pentane 00109-66-0 121 15520 188558

2-Methyl-2-butene 00513-35-9 1420 12658 1796850

23-Dimethylbutane 00079-29-8 090 11129 100014

t-2-Pentene 00646-04-8 1047 10500 1099738

Toluene 00108-88-3 393 10002 392585

2-Methyl-1-butene 00563-46-2 638 7489 477698



c-2-Pentene 00627-20-3 1028 5759 592056

Cyclohexane 00110-82-7 114 5744 65330

2-Methylpropane 00075-28-5 118 5722 67323

c-2-Butene 00590-18-1 1426 4971 708857


Benzene 00071-43-2 069 3956 27472

1-Butyne 00107-00-6 605 3534 213821




2-Methylhexane 00591-76-4 109 2413 26182


t-2-Hexene 04050-45-7 855 2057 175842



3-Methyl-t-2-pentene 00616-12-6 1166 1706 198941

Cyclopentene 00142-29-0 669 1599 106896

2-Methyl-2-pentene 00625-27-4 1103 1593 175741


n-Heptane 00142-82-5 097 1492 14408

3-Methyl-c-2-pentene 00922-62-3 1252 1338 167511


22-Dimethylbutane 00075-83-2 111 1217 13527



Propane 00074-98-6 046 992 4536


24-Dimethylhexane 00589-43-5 161 840 13485






250

Species CAS No MIR

Composite

VOC

mg

Ozone

mg












n-Octane 00111-65-9 080 380 3024





3-Methylheptane 00589-81-1 112 287 3222


2-Methylheptane 00592-27-8 097 259 2502

ortho-Xylene 00095-47-6 758 227 17173





Naphthalene 00091-20-3 328 172 5634

Unknown 16 302 169 5123

n-Nonane 00111-84-2 068 152 1040

n-Decane 00124-18-5 059 151 0890

Ethylbenzene 00100-41-4 296 150 4447

Indan 00496-11-7 323 132 4264

n-Propylbenzene 00103-65-1 196 120 2348

4-Methyloctane 02216-34-4 085 118 1002

Unknown 5 302 112 3400


t-3-Heptene 14686-14-7 617 104 6411




14-Diethylbenzene 00105-05-5 439 090 3928

33-Dimethylhexane 00563-16-6 115 083 0954

c-2-Heptene 06443-92-1 708 077 5453

13-Butadiene 00106-99-0 1245 052 6436

Unknown 3 302 036 1101

Total 38356 116460 3036


continued


251


E0 E10 E20




DVPE psi 701 730 849

Oxygenates--D4815

MTBE vol 000 000 000

ETBE vol 000 000 000

EtOH vol 000 954 2034

O2 wt 000 353 747





D86 Distillation

IBP degF 974 1040 1022












EP degF 3603 3600 3406



Loss vol 09 12 07


Data from CRC E-74



252








(R+M)2 885 889 890








CH Ratio 6200 6092 5835

Oxygen wt 0008 1 340 773




Oxygen wt 0008 3396 7733

C+H wt 9999 9660 9227

H wt 1389 1362 1350

C wt 8610 8298 7877

Fuel Units 6 7 4


Average D3338 Btulb 18579 18514 18491


DHA Btulb 18703 18016 17160






ii

Table of Contents

Page

Introduction

Background 1


Program Overview

Test Fuels 3

Test Procedures 5























Acknowledgements 37









iii

List of Figures


1 Trap Canister 5























iv

List of Tables


















v

Acronyms
















HC Hydrocarbon























vi

Executive Summary


























Veh Evap Standards















vii






45 plus prior work)













quality modelers



















1




CRC E-77-2c

Introduction












studies





















reg Project No




2






3

Program Overview

Test Fuels





in Appendix V


Haltermann products




MIN MAX

RESULTS


5 ˚F 136

10 ˚F 144

15 ˚F 148

20 ˚F 151

25 ˚F 154

30 ˚F 157

35 ˚F 159

40 ˚F 160

45 ˚F 162

50 ˚F 185 Target only 195 164

55 ˚F 168

60 ˚F 215

65 ˚F 245

70 ˚F 258

75 ˚F 272

80 ˚F 289

85 ˚F 305

90 ˚F 315 325 316

95 ˚F 323




Loss vol Report 05















R+M2 D26992700 870 910 888



4


Haltermann products




MIN MAX

RESULTS


5 ˚F 123

10 ˚F 131

20 ˚F 140

30 ˚F 150

40 ˚F 156

50 ˚F 185 Target only 195 161

60 ˚F 165

70 ˚F 248

80 ˚F 285

90 ˚F 315 325 315

95 ˚F 322




Loss vol Report 14















R+M2 D26992700 870 910 891



5

Test Procedures





















effective


















6

















7

Drain and 40 Fill

with Test Fuel



Drain and 40 Fill

with Test Fuel


Move to SHED


Stabilize at 86degF






Transfer to RL SHED


Stabilize at 86degF



One Hour Hot Soak

Drain and 40 Fill

With Test Fuel



Move to VT-SHED





Drain and 40 Fill

with Next Test Fuel



On Test Fuel


Fuel System


9 psi E20

7 psi E20






8





vehicle




committee
















Table 3













9














yellow shading

Table 4





Fuel Tank

Veh Tank Plastic































E77-2 Program





10



















11










45 plus prior work)









12








0

10

20

30

40

50

60

70


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zer Evap

7

4

77

7

7

6

266

6

6


1

1

0

20

40

60

80

100

120

140


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

4

4

4

4

4

4

22

2

2

22

11



13








202216 See Note 1 7E10 325 00 00 --- --- ---

202216 9E0 178 136 00 --- --- ---

202216 7E0 204 380 00 --- --- ---

202216 9E20 204 00 00 --- --- ---


204 7E10 664 00 00 --- --- ---

204 9E0 338 00 00 --- --- ---

204 7E0 129 00 00 --- --- ---

204 9E20 553 00 00 --- --- ---


205 7E10 596 00 00 --- --- ---

205 9E0 195 00 00 --- --- ---

205 7E0 99 00 00 --- --- ---

205 9E20 462 00 00 --- --- ---


207 7E10 644 00 00 --- --- ---

207 9E0 325 00 00 --- --- ---

207 7E0 401 00 00 --- --- ---

207 9E20 882 00 00 --- --- ---


207L See Note 2 7E10 1468 --- 00 --- --- ---


206b 7E10 1493 00 00 3079 00 00

206b 9E0 611 00 00 1788 00 00

206b 7E0 520 00 00 1181 00 00

206c 9E20 702 00 00 1729 00 00

206c 7E20 938 00 00 2307 00 00


207c See Note 2 7E10 5235 --- 2718 --- --- ---

207c 10E10 2325 --- 10837 --- --- ---

207c 7E10 1448 --- 3727 --- --- ---


208b 7E10 272 00 00 518 00 00

208b 9E0 372 00 00 550 00 91

208b 7E0 248 00 00 645 00 00

208c 9E20 219 00 00 396 00 00

208c 7E20 184 00 00 525 00 00


209b 7E10 286 00 00 541 00 00 E-77-2bc

209b 9E0 234 00 58 295 00 00

209b 7E0 168 19 79 288 00 00

209c 9E20 420 00 00 721 00 00

209c 7E20 235 00 00 411 00 00


220b See Note 3 7E10 504 9122 15724 1820 23090 28945

220b 9E0 1023 23181 28272 18581 35298 51362

220b 7E0 627 13515 16557 2792 22736 30082


221b See Note 4 7E10 227 9307 9710 614 12823 14085

221b 9E0 556 13488 14060 948 16467 17882

221b 7E0 359 9888 9618 668 12159 13438

221c 9E20 265 6165 6734 723 10328 10971

221c 7E20 394 5312 5061 630 7462 7806

Averages


7psi E0 275 7 696 4

9psi E0 376 7 895 4

7psi E10 598 7 1188 4

10psi E10 621 7 1322 4

7psi E20 438 4 968 4

9psi E20 500 7 892 4













Tank Top

Can Inlet


14






211 7E10 94 266 00 --- --- ---

211 9E0 101 00 00 --- --- ---

211 7E0 91 00 00 --- --- ---

211 9E20 558 00 00 --- --- ---


211L See Note 7E10 481 --- 1664 --- --- ---


212 7E10 218 00 00 --- --- ---

212 9E0 32 00 00 --- --- ---

212 7E0 09 00 00 --- --- ---

212 9E20 47 00 00 --- --- ---


214 7E10 239 --- 00 --- --- ---

214 9E0 107 --- 00 --- --- ---

214 7E0 252 --- 00 --- --- ---

214 9E20 168 --- 00 --- --- ---


215 7E10 122 00 00 --- --- ---

215 9E0 85 00 00 --- --- ---

215 7E0 87 00 00 --- --- ---

215 9E20 193 00 00 --- --- ---


210b 7E10 299 00 00 519 00 232

210b 9E0 212 00 40 335 00 48

210b 7E0 187 00 00 355 00 00

210c 9E20 180 00 00 327 00 46

210c 7E20 152 00 00 340 00 00


211c See Note 7E10 4491 --- 2869 --- --- ---

211c 10E10 2247 --- 14727 --- --- ---

211c 7E10 2170 --- 7890 --- --- ---


213b 7E10 296 00 00 822 00 00

213b 9E0 147 00 00 345 00 00

213b 7E0 211 00 00 353 00 00

213c 9E20 298 00 00 751 00 00

213c 7E20 229 00 00 651 00 00

Averages


7psi E0 140 6 354 2

9psi E0 114 6 340 2

7psi E10 211 6 670 2

10psi E10 209 6 884 2

7psi E20 191 2 495 2

9psi E20 241 6 539 2





Tank Top

Can Inlet




222c 7E20 69 00 00 71 00 00 E-77-2bc

Averages


7psi E20 69 1 71 1

9psi E20 92 1 69 1



15












0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

10

5 d

eg

F S

tati

c P

erm

ea

tio

n -

mg

hr



Tier 1

Tier 2

Zero Evap


16











0

50

100

150

200

250

300

350

400

450


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1


0

10

20

30

40

50

60

70

80

90

100


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1



17

Table 7


Veh Eng RL Tru-HS



202216 See Note 1 7E10 1683 192

202216 9E0 1091 254

202216 7E0 787 0

202216 9E20 543 74


204 7E10 2879 297

204 9E0 2492 443

204 7E0 2226 187

204 9E20 2720 134


205 7E10 2328 719

205 9E0 1031 10

205 7E0 671 00

205 9E20 1697 603


207 7E10 8122 1222

207 9E0 8339 58 E-77-2

207 7E0 8425 00

207 9E20 10282 00


207L See Note 2 7E10 11393 5850


206b 7E10 4367 1749

206b 9E0 3656 1025

206b 7E0 2451 688

206c 9E20 3308 858

206c 7E20 5187 1063


207c See Note 2 7E10 27694 5141

207c 10E10 9375 11140

207c 7E10 1146 6102


208b 7E10 2547 773

208b 9E0 2280 379

208b 7E0 1249 750

208c 9E20 2415 269

208c 7E20 2785 205


209b 7E10 2057 245 E-77-2bc

209b 9E0 1444 50

209b 7E0 1662 168

209c 9E20 3671 719

209c 7E20 2560 282


220b See Note 3 7E10 6979 768

220b 9E0 24170 3525

220b 7E0 34473 7071


221b 7E10 1020 405

221b 9E0 1352 290

221b 7E0 1898 425

221c 9E20 1266 95

221c 7E20 619 25

Averages

RL HS Sample

7psi E0 2655 317 7

9psi E0 2942 322 7

7psi E10 3331 773 7

10psi E10 3831 870 7

7psi E20 2788 394 4

9psi E20 3623 382 7






Tank Top

Can Inlet





18

Table 8



Veh Eng RL Tru-HS



211 7E10 563 138

211 9E0 837 153

211 7E0 1046 07

211 9E20 4106 00


211L See Note 7E10 2511 62


212 7E10 2012 00

212 9E0 1158 04

212 7E0 1845 18

212 9E20 1168 49


214 7E10 1057 329

214 9E0 967 521

214 7E0 363 33

214 9E20 1394 56


215 7E10 979 00

215 9E0 811 251

215 7E0 797 225

215 9E20 1025 0


210b 7E10 2183 618

210b 9E0 1711 198

210b 7E0 2160 490

210c 9E20 1943 540

210c 7E20 1246 759


211c See Note 7E10 3418 5894

211c 10E10 153795 19900

211c 7E10 47103 3993


213b 7E10 2431 605

213b 9E0 2031 145

213b 7E0 1351 122

213c 9E20 2572 40

213c 7E20 1869 334

Averages

RL HS Sample

7psi E0 1260 149 6

9psi E0 1253 212 6

7psi E10 1538 282 6

10psi E10 1284 201 6

7psi E20 1558 547 2

9psi E20 2035 198 6




Tank Top

Can Inlet

Veh Eng RL Tru-HS



222c 7E20 683 00 E-77-2bc


19







performance pattern



















0

200

400

600

800

1000

1200

1400

1600


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

9

6

7

2

4

6

7

6

7

6

9

6

11



20







0

500

1000

1500

2000

2500

3000

3500


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

13801

11



21

Table 9


Veh Eng



9E0 4685 --- --- --- E-77


9E0 1504 --- --- ---


202216 See Note 1 7E10 3975 3550 3621 11146

202216 9E0 3270 2667 2746 8683

202216 7E0 2117 2208 2081 6406

202216 9E20 4685 4526 4198 13409


204 7E10 12602 11652 11652 35906

204 9E0 6283 5810 5770 17863

204 7E0 3672 2877 2936 9485

204 9E20 11034 9606 9812 30452


205 7E10 17834 17150 15239 50223

205 9E0 4995 4810 5072 14877 E-77-2

205 7E0 3830 3654 3670 11154

205 9E20 17752 16900 16802 51454


207 7E10 10865 8120 8236 27221

207 9E0 4064 3373 3080 10517

207 7E0 3975 3026 2689 9690

207 9E20 15480 13702 13605 42787


207L See Note 2 7E10 21342 --- --- 21342


206b 7E10 25826 22585 21440 69850

206b 9E0 15000 12856 12508 40364

206b 7E0 11719 9312 8903 29933

206c 9E20 19585 17878 17010 54473

206c 7E20 19439 17081 15677 52197


207c See Note 2 7E10 70847 --- --- ---

207c 10E10 105198 --- --- ---

207c 7E10 70668 --- --- ---


208b 7E10 7806 5104 4494 17405

208b 9E0 7780 5672 5194 18646

208b 7E0 4221 4194 4760 13175

208c 9E20 5065 3632 3319 12015

208c 7E20 5804 4338 3754 13895


209b 7E10 3831 3491 3235 10557

209b 9E0 3278 2505 2243 8026

209b 7E0 3541 2497 2181 8219

209c 9E20 4564 3383 3160 11107

209c 7E20 5877 3465 2704 12046


220b See Note 3 7E10 11776 16121 14831 42728

220b 9E0 67333 58848 70499 196680

220b 7E0 62187 62147 70419 194753


221b 7E10 8947 6767 6180 21894

221b 9E0 7064 5437 5383 17884

221b 7E0 6030 5031 4870 15932

221c 9E20 7508 5847 5649 19004

221c 7E20 8172 5442 4988 18602

Averages


7psi E0 4675 9 13941 7

9psi E0 6072 9 18311 7

7psi E10 12530 7 33294 7

10psi E10 13833 7 138015 7

7psi E20 9823 4 24185 4

9psi E20 11570 7 31613 7










Day 1 Total

Tank Top

Can Inlet


22

Table 10



Veh Eng



211 7E10 2438 1838 1843 6119

211 9E0 1303 1158 1006 3467

211 7E0 2071 1002 874 3947

211 9E20 2850 2218 2034 7101


211L See Note 7E10 6783 --- --- 6783


212 7E10 1848 1002 758 3608

212 9E0 1005 708 574 2287

212 7E0 1016 712 570 2298

212 9E20 1310 833 750 2893


214 7E10 5242 3974 3944 13160

214 9E0 4559 3585 11017 19161

214 7E0 4943 3190 2815 10948

214 9E20 4709 4400 7518 16627


215 7E10 2247 2317 2675 7239

215 9E0 2021 1659 1763 5443

215 7E0 2483 2941 2888 8312

215 9E20 4168 4148 4506 12822


210b 7E10 4451 3883 3591 11925

210b 9E0 4078 3774 3583 11434

210b 7E0 2706 2666 2211 7583

210c 9E20 3523 2749 2977 9250

210c 7E20 3686 2836 2711 9233


213b 7E10 6028 5777 5889 17694

213b 9E0 3463 3284 2928 9675

213b 7E0 3578 2833 2765 9175

213c 9E20 6442 5293 4606 16342

213c 7E20 5019 5384 5461 15864

Averages


7psi E0 2799 6 7044 6

9psi E0 2738 6 8578 6

7psi E10 3709 6 9957 6

10psi E10 4016 6 29741 6

7psi E20 4352 2 12549 2

9psi E20 3833 6 10839 6


Day 1 Total



Veh Eng



222c 9E20 736 514 401 1651 E-77-2bc



23

Summary of Task 45














24

















emissions











12





25






from this test13



Table 11



1996 Cavalier

Test fuel Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)
















13


increase


26




27

Table 12




Test fuel

Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

2001 Dodge Caravan E10 109 213 104

2004 Toyota Camry E10 024 068 044











canister























28

















29






30









0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Pe

rme

ati

on

-m

gh

r

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10 psi E10 Fuel

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



7 psi E10 Fuel


31





0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel


32

Summary of Task 47


quality modelers

























This selected






14





33

Table 13

















Vehicle 206c

Type 72DHB

Test 7703


Net mass Net conc


1 Methane 00074-82-8 0000 0000 0 0

2 Ethylene 00074-85-1 1984 0066 0 0


4 Ethane 00074-84-0 0000 0000 0 0

5 Propene 00115-07-1 0000 0000 0 0

6 Propane 00074-98-6 24285 0770 0 0


8 Propyne 00074-99-7 0000 0000 0 0

9 2-Methylpropane 00075-28-5 101164 3244 2 2


11 13-Butadiene 00106-99-0 0428 0015 0 0

12 n-Butane 00106-97-8 320071 10262 6 6


14 t-2-Butene 00624-64-6 0000 0000 0 0

15 1-Butyne 00107-00-6 0000 0000 0 0

16 c-2-Butene 00590-18-1 30919 1027 1 1

17 3-Methyl-1-butene 00563-45-1 0000 0000 0 0



20 2-Methyl-1-butene 00563-46-2 62754 2084 1 1

21 n-Pentane 00109-66-0 335100 10819 6 7


23 t-2-Pentene 00646-04-8 162601 5400 3 3

24 33-Dimethyl-1-butene 00558-37-2 0000 0000 0 0

25 c-2-Pentene 00627-20-3 76704 2547 1 2

26 2-Methyl-2-butene 00513-35-9 152719 5071 3 3

72DHB

total


34




Table 14



4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


Species CAS No MIR

Composite VOC mg

Ozone mg




35




























compound)
















36





Table 15













previously thought

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


37

Acknowledgements











Steering Committee













David Lax API












38






test


39


Vehicle 206c

Reactivity Results





206c 90E20 Static (86) Perm 091509 7685 702 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 091609 7689 1729 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 091709 25795 3308 020

True HS 858 010

72 DHB 65-105 092909 7703

Day 1 19585 000

Day 2 17878 150

Day 3 17010 1000

70E20 Static (86) Perm 101309 7724 938 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 101409 7727 2307 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 102109 25806 5187 000

True HS 1063 000

72 DHB 65-105 111709 7779

Day 1 19439 000

Day 2 17081 020

Day 3 15677 080

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


40

0

20

40

60

80

100

120

140

160

180

200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7685

7 psi E20 - 7724

0

50

100

150

200

250

300

350

400

450

500

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7689

7 psi E20 - 7727


41

0

100

200

300

400

500

600

700

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25795

7 psi E20 - 25806


0

1000

2000

3000

4000

5000

6000

7000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7703

7 psi E20 - 7779


42


Vehicle 208c

Reactivity Results





208c 90E20 Static (86) Perm 092209 7695 219 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092309 7699 396 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 092409 25798 2415 000

True HS 269 000

72 DHB 65-105 100609 7713

Day 1 5065 000

Day 2 3632 000

Day 3 3319 000

70E20 Static (86) Perm 110309 7750 184 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110409 7755 525 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110509 25812 2785 000

True HS 205 000

72 DHB 65-105 120809 7817

Day 1 5804 000

Day 2 4338 000

Day 3 3754 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

Vehicle 208c


43

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7695

7 psi E20 - 7750

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7699

7 psi E20 - 7755


44

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25798

7 psi E20 - 25812


0

200

400

600

800

1000

1200

1400

1600

1800

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7713

7 psi E20 - 7817


45


Vehicle 209c

Reactivity Results





209c 90E20 Static (86) Perm 100109 7708 420 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 100209 7710 721 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 100509 25802 3671 000

True HS 719 000

72 DHB 65-105 110309 7753

Day 1 4564 020

Day 2 3383 030

Day 3 3160 090

70E20 Static (86) Perm 120209 7806 235 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 120309 7809 411 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 120409 25819 2560 000

True HS 282 000

72 DHB 65-105 011210 7856

Day 1 6107 000

Day 2 3160 010

Day 3 2581 040

72 DHB 65-105 020910 7881

Day 1 5647 000

Day 2 3771 000

Day 3 2827 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90

Vehicle 209c


46

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7708

7 psi E20 - 7806

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7710

7 psi E20 - 7809


47

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25802

7 psi E20 - 25819


0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7753

7 psi E20 - 7856



48


Vehicles 210c

Reactivity Results





210c 90E20 Static (86) Perm 092409 7701 180 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092509 7702 327 000

Press Incr 00

Prs+Fuel Incr 46

Dynamic RL 092809 25799 1943 000

True HS 540 000

72 DHB 65-105 101309 7725

Day 1 3523 030

Day 2 2749 160

Day 3 2977 700

70E20 Static (86) Perm 110509 7758 152 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110609 7761 340 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110909 25813 1246 000

True HS 759 000

72 DHB 65-105 121509 7826

Day 1 3686 050

Day 2 2836 070

Day 3 2711 120

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


49

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7701

7 psi E20 - 7758

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7702

7 psi E20 - 7761


50

0

50

100

150

200

250

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25799

7 psi E20 - 25813


0

200

400

600

800

1000

1200

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7725

7 psi E20 - 7826


51


Vehicle 213c

Reactivity Results





213c 90E20 Static (86) Perm 100809 7718 374 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 102909 7746 751 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 111309 25816 2572 082

True HS 40 005

72 DHB 65-105 120109 7803

Day 1 6442 000

Day 2 5293 000

Day 3 4606 000

70E20 Static (86) Perm 121609 7828 229 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 121709 7830 651 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 121809 25821 1869 000

True HS 334 000

72 DHB 65-105 020210 7872

Day 1 5019 000

Day 2 5384 000

Day 3 5461 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


52

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7744

7 psi E20 - 7828

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7746

7 psi E20 - 7830


53

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25816

7 psi E20 - 25821


0

200

400

600

800

1000

1200

1400

1600

1800

2000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7803

7 psi E20 - 7872


54


Vehicle 221c

Reactivity Results





221c 90E20 Static (86) Perm 122409 7840 265 000

Press Incr 6165

Prs+Fuel Incr 6734

Static (105) Perm 122309 7838 723 000

Press Incr 10328

Prs+Fuel Incr 10971

Dynamic RL 122809 25824 1266 000

True HS 95 000

72 DHB 65-105 011910 7859

Day 1 7508 040

Day 2 5847 150

Day 3 5649 400

70E20 Static (86) Perm 020410 7875 394 000

Press Incr 5312

Prs+Fuel Incr 5061

Static (105) Perm 020510 7877 630 000

Press Incr 7462

Prs+Fuel Incr 7806

Dynamic RL 020810 25828 619 000

True HS 25 000

72 DHB 65-105 030210 7906

Day 1 8172 000

Day 2 5442 000

Day 3 4988 070

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


55

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7840

7 psi E20 - 7875

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7838

7 psi E20 - 7877


56

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25824

7 psi E20 - 25828


0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7859

7 psi E20 - 7906


57


Vehicle 222c

Reactivity Results








222c 90E20 Static (86) Perm 122909 7843 92 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 123009 7847 69 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 011510 25827 447 000

True HS 76 000

72 DHB 65-105 020210 7871

Day 1 736 000

Day 2 514 000

Day 3 401 040

70E20 Static (86) Perm 022510 7898 69 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 022610 7901 71 000

Press Incr 00

Prs+Fuel Incr 00

72 DHB 65-105 030910 7916

Day 1 655 000

Day 2 427 030

Day 3 395 030

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


58

0

2

4

6

8

10

12

14

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7843

7 psi E20 - 7898

0

2

4

6

8

10

12

14

16

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7847

7 psi E20 - 7901


59

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25827

7 psi E20 -25830


0

50

100

150

200

250

300

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7871

7 psi E20 - 7916


60








61


Vehicle 207c

Reactivity Results





207c 100E10 Static Perm 082709 7661 6102 000


Dynamic RL 102009 25805 9997 000


24 DHB 65-105 090309 7672

Tank Top (020)

65125 000

70E10 Static Perm 091809 7693 5235 000


Dynamic RL 100209 25801 27694 000


24 DHB 65-105 102709 7741

Tank Top (020) 70847 000

100E10 Static Perm 111809 7781 2325 000


Dynamic RL 111909 25817 9375 000


24 DHB 65-105 112409 7794

Can Inlet (020) 105198 000

70E10 Static Perm 120909 7819 1448 000


Dynamic RL 121009 25820 11146 000


24 DHB 65-105 122909 7844

Can Inlet (020) 70668 000


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


62

0

200

400

600

800

1000

1200

1400

1600

1800

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7661

7 psi E10 - 7693

0

100

200

300

400

500

600

700

800

900

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7781

7 psi E10 - 7819


63

0

500

1000

1500

2000

2500

3000

3500

4000

4500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25805

7 psi E10 - 25801


0

500

1000

1500

2000

2500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25817

7 psi E10 - 25820



64

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7672

7 psi E10 - 7741

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7794

7 psi E10 - 7844


65


Vehicle 211c

Reactivity Results





211c 100E10 Static Perm 081209 7636 1925 000


Dynamic RL 081309 25788 8204 000


24 DHB 65-105 081909 7648

Tank Top (020) 89107 3560

70E10 Static Perm 090209 7669 4491 000


Dynamic RL 090309 25793 3418 000


24 DHB 65-105 091009 7681

Tank Top (020) 28842 000

100E10 Static Perm 101909 7732 2247 000


Dynamic RL 102909 25809 153795 000


24 DHB 65-105 111109 7769

Can Inlet (020) 115481 550

70E10 Static (86) Perm 112409 7793 2170 000


Dynamic RL 112509 25818 47103 082



Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


66

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7636

7 psi E10 - 7669

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7732

7 psi E10 - 7793


67

0

500

1000

1500

2000

2500

3000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25788

7 psi E10 - 25793


0

2000

4000

6000

8000

10000

12000

14000

16000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25809

7 psi E10 - 25818



68

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7648

7 psi E10 - 7681

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7769

7 psi E10 - 7836


69









1 Permeation













16




70












unit time

























17





Determination


71





permeation rate






concentrations





















3 Hot Soak19


described above




19





72






4 Diurnal Test



















retest is indicated







73


EXCELrsquoscopy














0

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80

100

120

140

160

0 20 40 60 80 100 120

SH

ED

Mass -

mg

Test Time - minutes



Test 7710

Pump Activated




Tank Pressurized

Slope = 705 mghr

Slope = 706 mghr

Slope = 761 mghr



74

























real-time records


75

















road speed






20






Loss SHED SHEDSHED


76



















period






0

10

20

30

40

50

60

70

80


Spe

ed -

mph








77






permeation












0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100 120

Co

rre

cte

d T

ota

l Fu

el C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


Test 25802



2936 mg

3793 mg

3356 mg

True HS = 437 mghr


Results


78

Diurnal Test








milligrams)




two SAE papers






















12







79







and 18th





















80







81

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


82

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4093 59307

Toluene 00108-88-3 393 1167 45800


n-Pentane 00109-66-0 121 648 7871


n-Butane 00106-97-8 108 607 6533

Cyclohexane 00110-82-7 114 552 6281


Benzene 00071-43-2 069 528 3668

Propane 00074-98-6 046 424 1938

t-2-Pentene 00646-04-8 1047 399 41785

n-Heptane 00142-82-5 097 378 3649


n-Hexane 00110-54-3 113 371 4207


2-Methyl-2-butene 00513-35-9 1420 284 40369



c-2-Pentene 00627-20-3 1028 188 19331



3-Methylpentane 00096-14-0 169 170 2882

2-Methyl-1-butene 00563-46-2 638 160 10232

2-Methylpropane 00075-28-5 118 152 1783



ortho-Xylene 00095-47-6 758 133 10090

2-Methylhexane 00591-76-4 109 119 1287

n-Octane 00111-65-9 080 113 0900

t-2-Hexene 04050-45-7 855 109 9344

n-Propylbenzene 00103-65-1 196 089 1748


23-Dimethylbutane 00079-29-8 090 080 0716

Cyclopentene 00142-29-0 669 076 5114

3-Methyl-c-2-pentene 00922-62-3 1252 073 9169






3-Methyl-t-2-pentene 00616-12-6 1166 064 7473

2-Methyl-2-pentene 00625-27-4 1103 064 7008

3-Methylheptane 00589-81-1 112 061 0683

c-2-Butene 00590-18-1 1426 059 8461




83

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








2-Methylheptane 00592-27-8 097 044 0430





Ethylbenzene 00100-41-4 296 028 0831



24-Dimethylhexane 00589-43-5 161 014 0230

22-Dimethylbutane 00075-83-2 111 013 0147

n-Undecane 01120-21-4 052 003 0017

Total 1620 5411 3340


continued


84

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7732 112029

Toluene 00108-88-3 393 2826 110931


n-Pentane 00109-66-0 121 1669 20279

n-Butane 00106-97-8 108 1531 16491


Benzene 00071-43-2 069 1317 9145


n-Hexane 00110-54-3 113 984 11164

n-Heptane 00142-82-5 097 955 9227

t-2-Pentene 00646-04-8 1047 867 90854



2-Methyl-2-butene 00513-35-9 1420 764 108513

22-DiMeHexane 00590-73-8 094 648 6097

3-Me-1-Hexene 03404-61-3 427 597 25518


2-Methylpropane 00075-28-5 118 483 5687


3-Methylpentane 00096-14-0 169 423 7157

c-2-Pentene 00627-20-3 1028 398 40907

2-Methyl-1-butene 00563-46-2 638 389 24834


Propane 00074-98-6 046 301 1376

ortho-Xylene 00095-47-6 758 277 21014

n-Octane 00111-65-9 080 263 2092



t-2-Hexene 04050-45-7 855 232 19857



23-Dimethylbutane 00079-29-8 090 188 1693

2-Methylhexane 00591-76-4 109 184 1996

c-2-Butene 00590-18-1 1426 177 25239


Ethylbenzene 00100-41-4 296 169 5008


n-Propylbenzene 00103-65-1 196 159 3125

3-Methyl-t-2-pentene 00616-12-6 1166 154 17969

Cyclopentene 00142-29-0 669 132 8836

Cyclopentane 00287-92-3 224 132 2955

2-Methylheptane 00592-27-8 097 126 1223

3-Methyl-c-2-pentene 00922-62-3 1252 120 14989





85

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 112 12354



3-Methylheptane 00589-81-1 112 094 1061









24-Dimethylhexane 00589-43-5 161 057 0919

4-Methyloctane 02216-34-4 085 053 0449

22-Dimethylbutane 00075-83-2 111 051 0570


Unknown 1 340 047 1585




3-Methyloctane 02216-33-3 088 038 0337

n-Nonane 00111-84-2 068 035 0239





Total 3466 11867 3424


continued


86

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7327 106160

Toluene 00108-88-3 393 3583 140646


n-Heptane 00142-82-5 097 1994 19258



3-Me-1-Hexene 03404-61-3 427 1676 71615

Benzene 00071-43-2 069 1585 11004

n-Pentane 00109-66-0 121 1566 19031

n-Butane 00106-97-8 108 1325 14268

n-Hexane 00110-54-3 113 1227 13926



22-DiMeHexane 00590-73-8 094 1009 9495



2-Methyl-2-butene 00513-35-9 1420 747 105970

t-2-Pentene 00646-04-8 1047 620 64956


3-Methylpentane 00096-14-0 169 504 8518


Indan 00496-11-7 323 491 15896



Unknown 16 362 481 17425


c-2-Pentene 00627-20-3 1028 439 45108


2-Methylpropane 00075-28-5 118 426 5010

n-Octane 00111-65-9 080 421 3351

2-Methyl-1-butene 00563-46-2 638 400 25494

ortho-Xylene 00095-47-6 758 365 27632

Ethylbenzene 00100-41-4 296 362 10735

2-Methylheptane 00592-27-8 097 360 3479

3-Methylheptane 00589-81-1 112 308 3463



2-Methylhexane 00591-76-4 109 256 2775


23-Dimethylbutane 00079-29-8 090 243 2181


Unknown 22 362 215 7784






87

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




n-Nonane 00111-84-2 068 189 1293


n-Propylbenzene 00103-65-1 196 187 3660

Cyclopentene 00142-29-0 669 181 12085

3-Methyl-t-2-pentene 00616-12-6 1166 177 20606

3-Methyl-c-2-pentene 00922-62-3 1252 163 20443







14-Diethylbenzene 00105-05-5 439 117 5152

c-2-Butene 00590-18-1 1426 115 16375



t-2-Hexene 04050-45-7 855 107 9180

22-Dimethylbutane 00075-83-2 111 103 1150

2-Methyl-2-pentene 00625-27-4 1103 096 10613

4-Methyl-t-2-pentene 00674-76-0 804 094 7554


n-Decane 00124-18-5 059 072 0424


Unknown 1 362 044 1580

Total 4582 17092 3730


continued


88

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 101748 1474297


n-Pentane 00109-66-0 121 33510 407124

n-Butane 00106-97-8 108 32007 344688

Toluene 00108-88-3 393 27947 1096913


Benzene 00071-43-2 069 20586 142938

n-Hexane 00110-54-3 113 18393 208697

n-Heptane 00142-82-5 097 17284 166926

t-2-Pentene 00646-04-8 1047 16260 1702998

2-Methyl-2-butene 00513-35-9 1420 15272 2167853


3-Me-1-Hexene 03404-61-3 427 10391 444084

2-Methylpropane 00075-28-5 118 10116 119030


22-DiMeHexane 00590-73-8 094 8200 77181


c-2-Pentene 00627-20-3 1028 7670 788622

3-Methylpentane 00096-14-0 169 7668 129648

2-Methyl-1-butene 00563-46-2 638 6275 400280


t-2-Hexene 04050-45-7 855 4165 356031

2-Methylhexane 00591-76-4 109 3643 39538




n-Octane 00111-65-9 080 3249 25870


c-2-Butene 00590-18-1 1426 3092 440893


23-Dimethylbutane 00079-29-8 090 2952 26532

Cyclopentene 00142-29-0 669 2922 195335

3-Methyl-t-2-pentene 00616-12-6 1166 2669 311214

Cyclopentane 00287-92-3 224 2540 56827

Propane 00074-98-6 046 2428 11101

3-Methyl-c-2-pentene 00922-62-3 1252 2277 285007


2-Methyl-2-pentene 00625-27-4 1103 1964 216725




ortho-Xylene 00095-47-6 758 1425 107970






89

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 1271 12292

Ethylbenzene 00100-41-4 296 1237 36651

22-Dimethylbutane 00075-83-2 111 1166 12955



3-Methylheptane 00589-81-1 112 1021 11484




n-Propylbenzene 00103-65-1 196 817 16017





n-Nonane 00111-84-2 068 489 3336

Unknown 1 333 488 16281



4-Methyloctane 02216-34-4 085 329 2788



3-Methyloctane 02216-33-3 088 287 2536



33-Dimethylhexane 00563-16-6 115 214 2470

Ethylene 00074-85-1 888 198 17628


1-Octene 00111-66-0 314 170 5347

c-2-Heptene 06443-92-1 708 147 10435

Unknown 8 333 147 4886


Unknown 5 333 132 4386

1-Nonene 00124-11-8 249 122 3031

Unknown 6 333 121 4021

Unknown 16 333 120 4008

Unknown 9 333 118 3924



Indan 00496-11-7 323 104 3374

Styrene 00100-42-5 166 095 1585


continued


90

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 3 333 072 2404


n-Decane 00124-18-5 059 067 0395



Unknown 14 333 055 1850

1-Heptene 00592-76-7 429 051 2194

13-Butadiene 00106-99-0 1245 043 5325


4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


continued


91

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2884 41793


Toluene 00108-88-3 393 1217 47766

Benzene 00071-43-2 069 747 5186




n-Pentane 00109-66-0 121 684 8305

n-Butane 00106-97-8 108 611 6584



n-Hexane 00110-54-3 113 498 5652


n-Heptane 00142-82-5 097 475 4583

Propane 00074-98-6 046 468 2137



2-Methyl-2-butene 00513-35-9 1420 356 50602

t-2-Pentene 00646-04-8 1047 347 36348

ortho-Xylene 00095-47-6 758 323 24490


c-2-Butene 00590-18-1 1426 312 44524



n-Octane 00111-65-9 080 289 2300

n-Propylbenzene 00103-65-1 196 272 5339

Cyclohexane 00110-82-7 114 267 3042

2-Methylhexane 00591-76-4 109 267 2898

23-Dimethylbutane 00079-29-8 090 259 2328

Ethylbenzene 00100-41-4 296 228 6765

t-2-Hexene 04050-45-7 855 227 19378




Cyclopentane 00287-92-3 224 167 3744


3-Methyl-t-2-pentene 00616-12-6 1166 154 17932

2-Methyl-1-butene 00563-46-2 638 150 9546

3-Methyl-c-2-pentene 00922-62-3 1252 146 18246

Cyclopentene 00142-29-0 669 145 9721

2-Methylheptane 00592-27-8 097 144 1394


c-2-Pentene 00627-20-3 1028 135 13873





92

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 131 1478


3-Methylpentane 00096-14-0 169 123 2086


2-Methyl-2-pentene 00625-27-4 1103 122 13422

24-Dimethylhexane 00589-43-5 161 103 1653

Indan 00496-11-7 323 087 2810

22-Dimethylbutane 00075-83-2 111 086 0952

n-Nonane 00111-84-2 068 085 0583












14-Diethylbenzene 00105-05-5 439 045 1982


4-Methyloctane 02216-34-4 085 043 0366

4-Methyl-t-2-pentene 00674-76-0 804 041 3322

Unknown 1 412 034 1408


2-Methylpropane 00075-28-5 118 029 0340

n-Undecane 01120-21-4 052 029 0150





3-Methyloctane 02216-33-3 088 020 0174

Total 2183 9104 4170


continued


93

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10102 146374

Toluene 00108-88-3 393 4080 160133

3-Methylnonane 05911-04-6 066 3338 21890




n-Pentane 00109-66-0 121 2300 27949

Benzene 00071-43-2 069 2108 14635


n-Butane 00106-97-8 108 2075 22348

n-Heptane 00142-82-5 097 1777 17164

n-Hexane 00110-54-3 113 1565 17760


t-2-Pentene 00646-04-8 1047 1024 107279

2-Methyl-2-butene 00513-35-9 1420 1009 143288

Cyclohexane 00110-82-7 114 926 10529





3-Methylpentane 00096-14-0 169 568 9606

c-2-Pentene 00627-20-3 1028 498 51245

2-Methyl-1-butene 00563-46-2 638 495 31574



n-Octane 00111-65-9 080 454 3615



ortho-Xylene 00095-47-6 758 403 30538

2-Methylhexane 00591-76-4 109 350 3798

n-Propylbenzene 00103-65-1 196 345 6759

Ethylbenzene 00100-41-4 296 312 9251

t-2-Hexene 04050-45-7 855 307 26270

2-Methylpropane 00075-28-5 118 262 3081

Cyclopentane 00287-92-3 224 250 5589


Cyclopentene 00142-29-0 669 211 14108

Propane 00074-98-6 046 192 0880

3-Methyl-t-2-pentene 00616-12-6 1166 192 22393

n-Nonane 00111-84-2 068 186 1270


23-Dimethylbutane 00079-29-8 090 179 1613






94

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 153 19093

2-Methyl-2-pentene 00625-27-4 1103 141 15538


24-Dimethylhexane 00589-43-5 161 132 2114


2-Methylheptane 00592-27-8 097 128 1233

4-Methyloctane 02216-34-4 085 125 1064

c-2-Butene 00590-18-1 1426 121 17277



3-Methylheptane 00589-81-1 112 109 1223

Indan 00496-11-7 323 104 3361





n-Decane 00124-18-5 059 065 0385



3-Methyloctane 02216-33-3 088 061 0539

13-Diethylbenzene 00141-93-5 708 056 3990




Unknown 1 330 049 1606

22-Dimethylbutane 00075-83-2 111 049 0540


n-Undecane 01120-21-4 052 043 0226

c-2-Heptene 06443-92-1 708 038 2676



Unknown 8 330 025 0836

066 Total 5472 18251 3335


continued


95

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10462 151590

Toluene 00108-88-3 393 5022 197121






n-Heptane 00142-82-5 097 2541 24542

n-Pentane 00109-66-0 121 2430 29518

Benzene 00071-43-2 069 2379 16519

n-Butane 00106-97-8 108 2172 23395

n-Hexane 00110-54-3 113 1979 22456



Cyclohexane 00110-82-7 114 1349 15348




2-Methyl-2-butene 00513-35-9 1420 940 133406

t-2-Pentene 00646-04-8 1047 857 89767

n-Octane 00111-65-9 080 856 6816



3-Methylpentane 00096-14-0 169 706 11929

n-Propylbenzene 00103-65-1 196 696 13630

2-Methyl-1-butene 00563-46-2 638 655 41772


Propane 00074-98-6 046 515 2355

ortho-Xylene 00095-47-6 758 506 38317

Ethylbenzene 00100-41-4 296 497 14716

3-Methylheptane 00589-81-1 112 480 5394

c-2-Pentene 00627-20-3 1028 476 48903

2-Methylhexane 00591-76-4 109 425 4611

2-Methylpropane 00075-28-5 118 404 4753

3-Methyl-c-2-pentene 00922-62-3 1252 401 50144



t-2-Hexene 04050-45-7 855 369 31567

n-Nonane 00111-84-2 068 355 2423

2-Methyl-2-pentene 00625-27-4 1103 349 38516


Cyclopentane 00287-92-3 224 322 7198

2-Methylheptane 00592-27-8 097 317 3071

c-2-Butene 00590-18-1 1426 292 41607




96

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 22 363 272 9893


3-Methyl-t-2-pentene 00616-12-6 1166 269 31312

Methane 00074-82-8 001 265 0037


3-Methyloctane 02216-33-3 088 255 2252






Cyclopentene 00142-29-0 669 208 13880

4-Methyloctane 02216-34-4 085 199 1691


23-Dimethylbutane 00079-29-8 090 188 1688

n-Decane 00124-18-5 059 168 0994


Indan 00496-11-7 323 160 5191



Unknown 18 363 147 5331

c-2-Heptene 06443-92-1 708 137 9666



24-Dimethylhexane 00589-43-5 161 123 1980




22-Dimethylbutane 00075-83-2 111 038 0418

Total 7165 26481 3696


continued


97

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 115502 1673600



n-Butane 00106-97-8 108 26699 287520

n-Pentane 00109-66-0 121 26567 322768

Toluene 00108-88-3 393 23849 936067

n-Heptane 00142-82-5 097 21212 204862

n-Hexane 00110-54-3 113 18520 210141

Benzene 00071-43-2 069 17238 119691



Cyclohexane 00110-82-7 114 9320 106002

t-2-Pentene 00646-04-8 1047 9137 956959

2-Methyl-2-butene 00513-35-9 1420 9120 1294599



3-Methylpentane 00096-14-0 169 6866 116094


c-2-Pentene 00627-20-3 1028 4504 463080


n-Octane 00111-65-9 080 4099 32639

2-Methyl-1-butene 00563-46-2 638 3977 253652


2-Methylhexane 00591-76-4 109 3789 41114



23-Dimethylbutane 00079-29-8 090 2988 26852

t-2-Hexene 04050-45-7 855 2686 229656

Cyclopentane 00287-92-3 224 2314 51777


Propane 00074-98-6 046 2085 9531



2-Methylpropane 00075-28-5 118 1854 21813

Cyclopentene 00142-29-0 669 1830 122352

3-Methyl-t-2-pentene 00616-12-6 1166 1808 210844



2-Methylheptane 00592-27-8 097 1688 16323

3-Methyl-c-2-pentene 00922-62-3 1252 1584 198290

c-2-Butene 00590-18-1 1426 1517 216368



2-Methyl-2-pentene 00625-27-4 1103 1493 164767




98

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 1325 14903

24-Dimethylhexane 00589-43-5 161 1322 21223

ortho-Xylene 00095-47-6 758 1234 93462

Ethylbenzene 00100-41-4 296 1170 34667




n-Propylbenzene 00103-65-1 196 978 19157


22-Dimethylbutane 00075-83-2 111 889 9880


n-Nonane 00111-84-2 068 734 5008




c-2-Heptene 06443-92-1 708 629 44542





4-Methyloctane 02216-34-4 085 439 3726



3-Methyloctane 02216-33-3 088 311 2751

Unknown 1 291 281 8158

33-Dimethylhexane 00563-16-6 115 274 3158


Ethylene 00074-85-1 888 238 21141

1-Octene 00111-66-0 314 226 7093

Unknown 5 291 226 6565




1-Butyne 00107-00-6 605 214 12957


Unknown 8 291 191 5566


1-Nonene 00124-11-8 249 155 3876

Indan 00496-11-7 323 134 4328




continued


99

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 291 093 2704

t-4-Octene 14850-23-8 469 088 4141



n-Decane 00124-18-5 059 072 0424


Unknown 6 291 063 1842

t-3-Heptene 14686-14-7 617 058 3603

Unknown 3 291 050 1460

13-Butadiene 00106-99-0 1245 050 6187

c- amp t-4-Nonene 02198-23-4 442 039 1719


1-Heptene 00592-76-7 429 035 1513

n-Undecane 01120-21-4 052 025 0130


Total 48454 142309 2937



100

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

- No Ethanol

Vehicle 208c


101

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


3-Me-1-Hexene 03404-61-3 427 193 8262

Toluene 00108-88-3 393 158 6219


n-Heptane 00142-82-5 097 146 1414


22-DiMeHexane 00590-73-8 094 136 1277

n-Pentane 00109-66-0 121 131 1597



Benzene 00071-43-2 069 109 0753

n-Butane 00106-97-8 108 101 1090

n-Octane 00111-65-9 080 058 0466

n-Hexane 00110-54-3 113 054 0613

2-Methylheptane 00592-27-8 097 048 0466

2-Methylpropane 00075-28-5 118 047 0553


n-Nonane 00111-84-2 068 041 0277

n-Propylbenzene 00103-65-1 196 033 0656

2-Methyl-2-pentene 00625-27-4 1103 032 3544

ortho-Xylene 00095-47-6 758 030 2297


3-Methyl-c-2-pentene 00922-62-3 1252 026 3231



Cyclopentene 00142-29-0 669 022 1454



t-2-Hexene 04050-45-7 855 018 1569

3-Methyl-t-2-pentene 00616-12-6 1166 018 2140

Ethylbenzene 00100-41-4 296 018 0544

t-2-Pentene 00646-04-8 1047 018 1912

3-Methylpentane 00096-14-0 169 018 0298



2-Methylhexane 00591-76-4 109 015 0159

24-Dimethylhexane 00589-43-5 161 013 0203

2-Methyl-2-butene 00513-35-9 1420 011 1589

c-2-Butene 00590-18-1 1426 009 1344



Total 260 956 3672




102

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1745 25291


n-Heptane 00142-82-5 097 769 7424


Benzene 00071-43-2 069 594 4125

Toluene 00108-88-3 393 461 18075

n-Pentane 00109-66-0 121 365 4438


n-Hexane 00110-54-3 113 287 3251

n-Butane 00106-97-8 108 273 2945



22-DiMeHexane 00590-73-8 094 172 1616

2-Methyl-2-butene 00513-35-9 1420 170 24078

3-Me-1-Hexene 03404-61-3 427 156 6681


t-2-Pentene 00646-04-8 1047 139 14606



Cyclopentane 00287-92-3 224 118 2649

n-Octane 00111-65-9 080 108 0863

3-Methylpentane 00096-14-0 169 108 1823


2-Methylpropane 00075-28-5 118 094 1110



c-2-Pentene 00627-20-3 1028 085 8778

3-Methylheptane 00589-81-1 112 085 0956

n-Nonane 00111-84-2 068 084 0576


3-Methyl-t-2-pentene 00616-12-6 1166 078 9114


2-Methyl-1-butene 00563-46-2 638 056 3594

c-2-Butene 00590-18-1 1426 055 7872

ortho-Xylene 00095-47-6 758 051 3872



t-2-Hexene 04050-45-7 855 043 3697


Ethylbenzene 00100-41-4 296 036 1067


Cyclopentene 00142-29-0 669 029 1922






103

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 023 2569


3-Methyl-c-2-pentene 00922-62-3 1252 022 2706



22-Dimethylbutane 00075-83-2 111 010 0117




2-Methylhexane 00591-76-4 109 003 0037



Total 962 2919 3034


continued


104

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 964 37835

t-3-Heptene 14686-14-7 617 854 52708


n-Pentane 00109-66-0 121 709 8608

Benzene 00071-43-2 069 649 4509




3-Me-1-Hexene 03404-61-3 427 425 18160


22-DiMeHexane 00590-73-8 094 403 3797





4-Methyl-t-2-pentene 00674-76-0 804 349 28047

n-Butane 00106-97-8 108 347 3739

n-Hexane 00110-54-3 113 346 3922

n-Propylbenzene 00103-65-1 196 335 6568

n-Octane 00111-65-9 080 327 2601

3-Methylpentane 00096-14-0 169 304 5148


2-Methylhexane 00591-76-4 109 290 3146

n-Butylbenzene 00104-51-8 229 279 6386


Indan 00496-11-7 323 272 8810

t-2-Pentene 00646-04-8 1047 264 27657

Ethylbenzene 00100-41-4 296 257 7618





2-Methyl-2-butene 00513-35-9 1420 223 31617


2-Methyl-1-butene 00563-46-2 638 193 12303


n-Nonane 00111-84-2 068 187 1276


c-2-Pentene 00627-20-3 1028 156 16054

t-2-Hexene 04050-45-7 855 154 13191

ortho-Xylene 00095-47-6 758 148 11239




105

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



13-Butadiene 00106-99-0 1245 145 18006



2-Methylheptane 00592-27-8 097 134 1296


23-Dimethylbutane 00079-29-8 090 128 1152

4-Methyloctane 02216-34-4 085 127 1079

Unknown 5 422 113 4773





2-Methylpropane 00075-28-5 118 097 1147

Unknown 9 422 092 3896

3-Methyl-t-2-pentene 00616-12-6 1166 076 8865

3-Methyl-c-2-pentene 00922-62-3 1252 074 9238


Cyclopentene 00142-29-0 669 065 4325


14-Diethylbenzene 00105-05-5 439 059 2575

24-Dimethylhexane 00589-43-5 161 052 0828

3-Methyloctane 02216-33-3 088 048 0425





22-Dimethylbutane 00075-83-2 111 009 0104

Total 2199 9732 4426


continued


106

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 40269 583488


n-Pentane 00109-66-0 121 6604 80237

n-Butane 00106-97-8 108 5757 61995


n-Heptane 00142-82-5 097 5013 48416

n-Hexane 00110-54-3 113 4359 49459

Toluene 00108-88-3 393 4128 162007


Benzene 00071-43-2 069 3151 21876


2-Methyl-2-butene 00513-35-9 1420 2458 348891

t-2-Pentene 00646-04-8 1047 2391 250449

2-Methylpropane 00075-28-5 118 2367 27847

Cyclohexane 00110-82-7 114 2317 26356


3-Methylpentane 00096-14-0 169 1942 32835



n-Octane 00111-65-9 080 1226 9760

c-2-Pentene 00627-20-3 1028 1186 121926


2-Methyl-1-butene 00563-46-2 638 1163 74158

2-Methylhexane 00591-76-4 109 1119 12144


t-2-Hexene 04050-45-7 855 759 64866

23-Dimethylbutane 00079-29-8 090 700 6289



2-Methylheptane 00592-27-8 097 569 5503

c-2-Butene 00590-18-1 1426 562 80095

Propane 00074-98-6 046 552 2525

Cyclopentane 00287-92-3 224 552 12353


3-Methyl-t-2-pentene 00616-12-6 1166 518 60429

3-Methylheptane 00589-81-1 112 482 5422

Cyclopentene 00142-29-0 669 479 32026

3-Methyl-c-2-pentene 00922-62-3 1252 469 58697



2-Methyl-2-pentene 00625-27-4 1103 422 46577







107

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Nonane 00111-84-2 068 349 2384

1-Butyne 00107-00-6 605 349 21088





24-Dimethylhexane 00589-43-5 161 299 4801

22-Dimethylbutane 00075-83-2 111 291 3238


ortho-Xylene 00095-47-6 758 271 20538

n-Propylbenzene 00103-65-1 196 263 5151

Ethylbenzene 00100-41-4 296 238 7052



4-Methyloctane 02216-34-4 085 223 1894




3-Methyloctane 02216-33-3 088 154 1363




33-Dimethylhexane 00563-16-6 115 109 1252

Unknown 8 276 087 2398



1-Octene 00111-66-0 314 081 2559


continued


108

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 276 066 1835

Unknown 1 276 065 1794





n-Decane 00124-18-5 059 049 0289

Unknown 5 276 045 1243

c-2-Heptene 06443-92-1 708 040 2835



1-Nonene 00124-11-8 249 019 0476

Total 12981 36292 2796


continued


109

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1522 22047

Toluene 00108-88-3 393 372 14601




n-Butane 00106-97-8 108 252 2718

n-Pentane 00109-66-0 121 229 2778


n-Undecane 01120-21-4 052 208 1088

n-Decane 00124-18-5 059 202 1193

n-Heptane 00142-82-5 097 197 1903

n-Hexane 00110-54-3 113 145 1643

1-Butyne 00107-00-6 605 142 8563

Benzene 00071-43-2 069 136 0943

Cyclohexane 00110-82-7 114 117 1336







3-Methylpentane 00096-14-0 169 077 1305


2-Methylpropane 00075-28-5 118 075 0882

n-Nonane 00111-84-2 068 072 0492

n-Propylbenzene 00103-65-1 196 070 1366



2-Methyl-2-butene 00513-35-9 1420 068 9604

23-Dimethylbutane 00079-29-8 090 061 0546

n-Octane 00111-65-9 080 060 0475


Cyclopentene 00142-29-0 669 054 3587



t-2-Pentene 00646-04-8 1047 046 4844

ortho-Xylene 00095-47-6 758 044 3308

3-Methyl-c-2-pentene 00922-62-3 1252 043 5429

2-Methylheptane 00592-27-8 097 042 0408

3-Methyl-t-2-pentene 00616-12-6 1166 042 4901


2-Methyl-2-pentene 00625-27-4 1103 039 4343


3-Methylheptane 00589-81-1 112 033 0371




110

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 030 3052


Unknown 22 305 027 0835

2-Methylhexane 00591-76-4 109 027 0296


Ethylbenzene 00100-41-4 296 024 0697

24-Dimethylhexane 00589-43-5 161 022 0354




22-Dimethylbutane 00075-83-2 111 011 0126

2-Methyl-1-butene 00563-46-2 638 006 0396


Total 691 2138 3094


continued


111

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1871 27109


Toluene 00108-88-3 393 522 20484


n-Heptane 00142-82-5 097 365 3521

n-Pentane 00109-66-0 121 351 4259

n-Butane 00106-97-8 108 298 3214







Benzene 00071-43-2 069 198 1372

n-Hexane 00110-54-3 113 173 1961



t-2-Pentene 00646-04-8 1047 126 13202

n-Octane 00111-65-9 080 116 0924

2-Methyl-2-butene 00513-35-9 1420 115 16378

Cyclohexane 00110-82-7 114 108 1232


3-Methylpentane 00096-14-0 169 101 1707

2-Methylpropane 00075-28-5 118 075 0884

2-Methylhexane 00591-76-4 109 059 0643

ortho-Xylene 00095-47-6 758 054 4058

2-Methyl-1-butene 00563-46-2 638 053 3361

c-2-Pentene 00627-20-3 1028 043 4388


066 Total 755 2232 2957




112

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 968 37976


n-Pentane 00109-66-0 121 522 6345

n-Heptane 00142-82-5 097 514 4964

Benzene 00071-43-2 069 512 3553





n-Propylbenzene 00103-65-1 196 434 8506




n-Octane 00111-65-9 080 341 2712

n-Hexane 00110-54-3 113 275 3123

n-Nonane 00111-84-2 068 271 1848

13-Butadiene 00106-99-0 1245 247 30791




2-Methylheptane 00592-27-8 097 231 2232

2-Methyl-1-butene 00563-46-2 638 227 14471

c-2-Pentene 00627-20-3 1028 221 22769

n-Butane 00106-97-8 108 194 2085

24-Dimethylhexane 00589-43-5 161 183 2939


Cyclohexane 00110-82-7 114 162 1841


23-Dimethylbutane 00079-29-8 090 150 1345

n-Decane 00124-18-5 059 136 0802


3-Methylpentane 00096-14-0 169 131 2214

2-Methylhexane 00591-76-4 109 104 1128


t-2-Pentene 00646-04-8 1047 070 7355

22-Dimethylbutane 00075-83-2 111 066 0737

3-Methylheptane 00589-81-1 112 066 0741

2-Methyl-2-butene 00513-35-9 1420 059 8434



Ethylbenzene 00100-41-4 296 053 1559




113

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylpropane 00075-28-5 118 022 0260

Total 1666 7311 4389

continued


114

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 42028 608972



n-Heptane 00142-82-5 097 6080 58717

n-Pentane 00109-66-0 121 5160 62696

n-Butane 00106-97-8 108 4881 52569

Toluene 00108-88-3 393 4149 162857

n-Hexane 00110-54-3 113 4113 46667



Benzene 00071-43-2 069 2652 18416


Cyclohexane 00110-82-7 114 2309 26264


3-Methylpentane 00096-14-0 169 1806 30534

n-Octane 00111-65-9 080 1490 11863

2-Methyl-2-butene 00513-35-9 1420 1455 206582

t-2-Pentene 00646-04-8 1047 1430 149744



2-Methylhexane 00591-76-4 109 1276 13844


23-Dimethylbutane 00079-29-8 090 950 8542

2-Methylpropane 00075-28-5 118 905 10645



2-Methyl-1-butene 00563-46-2 638 764 48753

2-Methylheptane 00592-27-8 097 757 7321


c-2-Pentene 00627-20-3 1028 717 73741


3-Methylheptane 00589-81-1 112 591 6648


24-Dimethylhexane 00589-43-5 161 559 8975

t-2-Hexene 04050-45-7 855 500 42751



c-2-Heptene 06443-92-1 708 474 33563



Cyclopentane 00287-92-3 224 382 8551

n-Nonane 00111-84-2 068 368 2512

3-Methyl-c-2-pentene 00922-62-3 1252 366 45829





115

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methyl-t-2-pentene 00616-12-6 1166 347 40413


1-Butyne 00107-00-6 605 314 18981

c-2-Butene 00590-18-1 1426 313 44686


2-Methyl-2-pentene 00625-27-4 1103 298 32930




4-Methyloctane 02216-34-4 085 268 2273

ortho-Xylene 00095-47-6 758 263 19906



Cyclopentene 00142-29-0 669 246 16475

22-Dimethylbutane 00075-83-2 111 235 2609

Propane 00074-98-6 046 234 1071

3-Methyloctane 02216-33-3 088 226 1997

Ethylbenzene 00100-41-4 296 225 6680



n-Propylbenzene 00103-65-1 196 212 4148



33-Dimethylhexane 00563-16-6 115 179 2055





Unknown 8 246 139 3407



continued


116

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



1-Octene 00111-66-0 314 105 3295

Unknown 9 246 086 2117

Unknown 5 246 083 2051





n-Decane 00124-18-5 059 045 0268

1-Nonene 00124-11-8 249 044 1105

Unknown 1 246 032 0778

Total 13019 32482 2495


continued


117

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41 No Ethanol

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90 Repeat

Vehicle 209c


118

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 608 23884

n-Pentane 00109-66-0 121 532 6465

n-Butane 00106-97-8 108 526 5664




n-Hexane 00110-54-3 113 360 4086

Cyclohexane 00110-82-7 114 358 4074

n-Heptane 00142-82-5 097 324 3130


Benzene 00071-43-2 069 227 1573


2-Methyl-2-butene 00513-35-9 1420 214 30383



t-2-Pentene 00646-04-8 1047 199 20808

3-Methylpentane 00096-14-0 169 189 3189



23-Dimethylbutane 00079-29-8 090 134 1208

Ethanol 00064-17-5 145 131 1905


2-Methyl-1-butene 00563-46-2 638 118 7543

Propane 00074-98-6 046 116 0530

2-Methylpropane 00075-28-5 118 112 1317

c-2-Pentene 00627-20-3 1028 110 11307


2-Methylhexane 00591-76-4 109 097 1052

n-Nonane 00111-84-2 068 091 0619

c-2-Butene 00590-18-1 1426 083 11886



n-Propylbenzene 00103-65-1 196 076 1487


n-Octane 00111-65-9 080 066 0525

3-Methylheptane 00589-81-1 112 064 0714


ortho-Xylene 00095-47-6 758 062 4660

t-2-Hexene 04050-45-7 855 057 4874


2-Methyl-2-pentene 00625-27-4 1103 055 6035





119

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 053 0852

3-Methyl-c-2-pentene 00922-62-3 1252 051 6343



3-Methyl-t-2-pentene 00616-12-6 1166 046 5371

Cyclopentene 00142-29-0 669 043 2842



22-Dimethylbutane 00075-83-2 111 035 0390


4-Methyloctane 02216-34-4 085 034 0288




2-Methylheptane 00592-27-8 097 024 0234

Unknown 18 334 023 0782


Indan 00496-11-7 323 020 0636

Ethylbenzene 00100-41-4 296 019 0563

Total 1036 3549 3427


continued


120

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2428 35179


Toluene 00108-88-3 393 689 27059

Cyclohexane 00110-82-7 114 575 6535

n-Pentane 00109-66-0 121 549 6667

n-Butane 00106-97-8 108 465 5009

n-Hexane 00110-54-3 113 438 4971



22-DiMeHexane 00590-73-8 094 335 3152

n-Heptane 00142-82-5 097 311 3006


3-Methylpentane 00096-14-0 169 242 4093

Benzene 00071-43-2 069 227 1575


2-Methyl-2-butene 00513-35-9 1420 197 27914




23-Dimethylbutane 00079-29-8 090 166 1491

2-Methylpropane 00075-28-5 118 149 1756

2-Methylhexane 00591-76-4 109 147 1599

t-2-Pentene 00646-04-8 1047 146 15283




c-2-Pentene 00627-20-3 1028 097 10021

n-Octane 00111-65-9 080 097 0776

Propane 00074-98-6 046 096 0439

n-Nonane 00111-84-2 068 088 0601

2-Methyl-1-butene 00563-46-2 638 082 5199

Indan 00496-11-7 323 078 2534


3-Methylheptane 00589-81-1 112 076 0853


4-Methyloctane 02216-34-4 085 065 0551

ortho-Xylene 00095-47-6 758 065 4918

Unknown 16 271 065 1756





n-Propylbenzene 00103-65-1 196 053 1040

t-2-Hexene 04050-45-7 855 052 4414




121

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 038 0607

Cyclopentene 00142-29-0 669 038 2517


22-Dimethylbutane 00075-83-2 111 037 0408

3-Methyl-t-2-pentene 00616-12-6 1166 036 4207

Ethylbenzene 00100-41-4 296 036 1052




2-Methyl-2-pentene 00625-27-4 1103 033 3675

2-Methylheptane 00592-27-8 097 033 0322

c-2-Butene 00590-18-1 1426 031 4470

3-Methyl-c-2-pentene 00922-62-3 1252 024 3058





Total 1212 3351 2765


continued


122

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 3555 51515

Toluene 00108-88-3 393 2025 79500


3-Me-1-Hexene 03404-61-3 427 1750 74813

n-Heptane 00142-82-5 097 1537 14840



n-Pentane 00109-66-0 121 1178 14313

n-Butane 00106-97-8 108 1174 12645

n-Hexane 00110-54-3 113 1158 13138



22-DiMeHexane 00590-73-8 094 1026 9657





Benzene 00071-43-2 069 791 5491

Propane 00074-98-6 046 552 2523

3-Methylpentane 00096-14-0 169 535 9054



2-Methyl-2-butene 00513-35-9 1420 457 64841

Ethylene 00074-85-1 888 454 40295


2-Methyl-1-butene 00563-46-2 638 448 28551

t-2-Pentene 00646-04-8 1047 448 46880

n-Octane 00111-65-9 080 421 3348


2-Methylpropane 00075-28-5 118 413 4861


c-2-Pentene 00627-20-3 1028 349 35872

n-Propylbenzene 00103-65-1 196 346 6786


2-Methylhexane 00591-76-4 109 331 3591

23-Dimethylbutane 00079-29-8 090 320 2879


ortho-Xylene 00095-47-6 758 312 23613

24-Dimethylhexane 00589-43-5 161 278 4460


2-Methylheptane 00592-27-8 097 265 2568

Ethylbenzene 00100-41-4 296 262 7748

t-2-Hexene 04050-45-7 855 257 21978




123

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







3-Methylheptane 00589-81-1 112 216 2430

2-Methyl-2-pentene 00625-27-4 1103 212 23431

3-Methyl-t-2-pentene 00616-12-6 1166 199 23199

n-Nonane 00111-84-2 068 189 1292

3-Methyl-c-2-pentene 00922-62-3 1252 188 23507




Cyclopentene 00142-29-0 669 120 8051

c-2-Butene 00590-18-1 1426 096 13745



22-Dimethylbutane 00075-83-2 111 085 0940

13-Butadiene 00106-99-0 1245 070 8700


Total 3712 13832 3726


continued


124

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 41433 600356


n-Butane 00106-97-8 108 4042 43529

n-Pentane 00109-66-0 121 3798 46147


Toluene 00108-88-3 393 2636 103457

n-Heptane 00142-82-5 097 2629 25385

n-Hexane 00110-54-3 113 2488 28227


Cyclohexane 00110-82-7 114 1943 22094

Benzene 00071-43-2 069 1923 13349


t-2-Pentene 00646-04-8 1047 1424 149160

2-Methyl-2-butene 00513-35-9 1420 1420 201503


3-Methylpentane 00096-14-0 169 1237 20924


2-Methylpropane 00075-28-5 118 1107 13030

2-Methyl-1-butene 00563-46-2 638 764 48704

c-2-Pentene 00627-20-3 1028 735 75531



n-Octane 00111-65-9 080 674 5365

2-Methylhexane 00591-76-4 109 654 7101



Propane 00074-98-6 046 473 2162

23-Dimethylbutane 00079-29-8 090 451 4053

t-2-Hexene 04050-45-7 855 451 38530

2-Methylheptane 00592-27-8 097 363 3510

Cyclopentane 00287-92-3 224 346 7753

3-Methyl-t-2-pentene 00616-12-6 1166 328 38296


Cyclopentene 00142-29-0 669 296 19762

3-Methylheptane 00589-81-1 112 290 3262

3-Methyl-c-2-pentene 00922-62-3 1252 283 35472

2-Methyl-2-pentene 00625-27-4 1103 279 30766



24-Dimethylhexane 00589-43-5 161 259 4160


22-Dimethylbutane 00075-83-2 111 253 2816





125

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





c-2-Butene 00590-18-1 1426 238 33979





1-Butyne 00107-00-6 605 187 11337



n-Propylbenzene 00103-65-1 196 154 3020

Ethylbenzene 00100-41-4 296 152 4489

4-Methyloctane 02216-34-4 085 149 1267


3-Methyloctane 02216-33-3 088 118 1048


33-Dimethylhexane 00563-16-6 115 113 1300


n-Nonane 00111-84-2 068 112 0762



Unknown 22 249 085 2128


1-Octene 00111-66-0 314 084 2649



Unknown 8 249 077 1927


Unknown 5 249 068 1695

Unknown 6 249 061 1521





4-Methyl-t-2-pentene 00674-76-0 804 055 4393

Unknown 1 249 054 1355

continued


126

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 9 249 048 1203



ortho-Xylene 00095-47-6 758 035 2639



1-Nonene 00124-11-8 249 031 0771

c-2-Heptene 06443-92-1 708 030 2119


Total 9741 24571 2522


continued


127

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2031 29422



Toluene 00108-88-3 393 213 8360

n-Heptane 00142-82-5 097 164 1581

22-DiMeHexane 00590-73-8 094 162 1525




n-Butane 00106-97-8 108 113 1221


Benzene 00071-43-2 069 090 0625

n-Octane 00111-65-9 080 087 0696


n-Pentane 00109-66-0 121 083 1008

Cyclohexane 00110-82-7 114 078 0887


n-Nonane 00111-84-2 068 068 0466




n-Hexane 00110-54-3 113 061 0693

n-Propylbenzene 00103-65-1 196 060 1176

4-Methyloctane 02216-34-4 085 059 0501


2-Methyl-1-butene 00563-46-2 638 056 3568


t-2-Pentene 00646-04-8 1047 051 5304

3-Methyl-c-2-pentene 00922-62-3 1252 048 6030


ortho-Xylene 00095-47-6 758 044 3371


n-Decane 00124-18-5 059 042 0246

1-Butyne 00107-00-6 605 038 2301


2-Methyl-2-butene 00513-35-9 1420 035 4931

23-Dimethylbutane 00079-29-8 090 031 0274



c-2-Pentene 00627-20-3 1028 026 2664

t-2-Hexene 04050-45-7 855 026 2206

2-Methylhexane 00591-76-4 109 026 0279

Ethylbenzene 00100-41-4 296 024 0713




128

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-t-2-pentene 00616-12-6 1166 021 2407

2-Methylheptane 00592-27-8 097 020 0198

3-Methylpentane 00096-14-0 169 020 0337


Cyclopentene 00142-29-0 669 016 1071


3-Methylheptane 00589-81-1 112 010 0108



n-Undecane 01120-21-4 052 003 0017

Total 554 1818 3284


continued


129

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2491 36089


Toluene 00108-88-3 393 351 13795


n-Heptane 00142-82-5 097 246 2378




n-Pentane 00109-66-0 121 181 2205

n-Butane 00106-97-8 108 173 1860

Benzene 00071-43-2 069 159 1107


n-Hexane 00110-54-3 113 128 1449

Propane 00074-98-6 046 123 0563



Cyclohexane 00110-82-7 114 117 1330



3-Methylheptane 00589-81-1 112 081 0911

n-Octane 00111-65-9 080 076 0603

3-Methylpentane 00096-14-0 169 075 1266


t-2-Pentene 00646-04-8 1047 069 7273


n-Propylbenzene 00103-65-1 196 066 1300

2-Methyl-2-pentene 00625-27-4 1103 066 7278


2-Methyl-2-butene 00513-35-9 1420 058 8241

23-Dimethylbutane 00079-29-8 090 056 0505

Ethylbenzene 00100-41-4 296 053 1576

c-2-Heptene 06443-92-1 708 053 3746

4-Methyloctane 02216-34-4 085 053 0449



Unknown 22 299 050 1489


2-Methyl-1-butene 00563-46-2 638 046 2905

2-Methylheptane 00592-27-8 097 045 0434

n-Nonane 00111-84-2 068 044 0300


24-Dimethylhexane 00589-43-5 161 042 0669

2-Methylhexane 00591-76-4 109 039 0424




130

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 039 3979

t-2-Hexene 04050-45-7 855 038 3270


3-Methyl-t-2-pentene 00616-12-6 1166 036 4201

ortho-Xylene 00095-47-6 758 034 2597

c-2-Butene 00590-18-1 1426 034 4788



3-Methyl-c-2-pentene 00922-62-3 1252 030 3747




Cyclopentene 00142-29-0 669 022 1479




22-Dimethylbutane 00075-83-2 111 012 0136

066 Total 786 2397 3050


continued


131

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-DiMeHexane 00590-73-8 094 551 5189

Cyclohexane 00110-82-7 114 550 6259

n-Heptane 00142-82-5 097 503 4856




n-Nonane 00111-84-2 068 399 2724

Ethylene 00074-85-1 888 383 33991


n-Octane 00111-65-9 080 331 2635



Benzene 00071-43-2 069 241 1673

Unknown 22 492 232 11393



3-Methyl-t-2-pentene 00616-12-6 1166 194 22609


Cyclopentene 00142-29-0 669 153 10213




3-Methyl-c-2-pentene 00922-62-3 1252 115 14432

n-Propylbenzene 00103-65-1 196 114 2239

2-Methylheptane 00592-27-8 097 110 1067



Toluene 00108-88-3 393 089 3513

Naphthalene 00091-20-3 328 087 2863

t-2-Hexene 04050-45-7 855 084 7168


3-Methylpentane 00096-14-0 169 070 1179

ortho-Xylene 00095-47-6 758 052 3918


2-Methylhexane 00591-76-4 109 032 0348

Ethylbenzene 00100-41-4 296 018 0548


2-Methyl-2-butene 00513-35-9 1420 005 0770

Total 1074 5493 5117





132

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35670 516847



n-Heptane 00142-82-5 097 3662 35368

n-Butane 00106-97-8 108 3505 37747

Toluene 00108-88-3 393 3492 137050

n-Pentane 00109-66-0 121 3304 40146


n-Hexane 00110-54-3 113 2599 29485



Cyclohexane 00110-82-7 114 1925 21900


Benzene 00071-43-2 069 1738 12068



n-Octane 00111-65-9 080 1569 12491


2-Methylpropane 00075-28-5 118 1256 14781

3-Methylpentane 00096-14-0 169 1206 20398

2-Methyl-2-butene 00513-35-9 1420 1074 152444

23-Dimethylbutane 00079-29-8 090 1069 9609

t-2-Pentene 00646-04-8 1047 1043 109271


2-Methylhexane 00591-76-4 109 864 9372



2-Methylheptane 00592-27-8 097 787 7608


Propane 00074-98-6 046 757 3460

3-Methylheptane 00589-81-1 112 717 8059



n-Nonane 00111-84-2 068 656 4479



c-2-Pentene 00627-20-3 1028 547 56249

24-Dimethylhexane 00589-43-5 161 521 8366

2-Methyl-1-butene 00563-46-2 638 520 33173

4-Methyloctane 02216-34-4 085 502 4255

n-Propylbenzene 00103-65-1 196 453 8879

ortho-Xylene 00095-47-6 758 450 34122

c-2-Heptene 06443-92-1 708 445 31484





133

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






3-Methyloctane 02216-33-3 088 360 3186

t-2-Hexene 04050-45-7 855 339 28984

Ethylbenzene 00100-41-4 296 338 10013

22-Dimethylbutane 00075-83-2 111 326 3618



3-Methyl-t-2-pentene 00616-12-6 1166 269 31374




2-Methyl-2-pentene 00625-27-4 1103 258 28420

Unknown 8 252 242 6098

3-Methyl-c-2-pentene 00922-62-3 1252 236 29551


c-2-Butene 00590-18-1 1426 227 32333


Cyclopentene 00142-29-0 669 218 14591

1-Nonene 00124-11-8 249 212 5282

Unknown 16 252 209 5253



Unknown 9 252 172 4332

1-Octene 00111-66-0 314 161 5055


33-Dimethylhexane 00563-16-6 115 156 1793


n-Decane 00124-18-5 059 141 0832

continued


134

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Indan 00496-11-7 323 126 4071




Unknown 5 252 108 2722

t-4-Octene 14850-23-8 469 092 4292



Unknown 10 252 074 1873




22-Dimethyloctane 15869-87-1 076 049 0367

n-Undecane 01120-21-4 052 044 0229

c-2-Octene 07642-04-8 252 024 0605

Total 11102 28561 2573


continued


135

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 39128 566956



n-Heptane 00142-82-5 097 4118 39773

Toluene 00108-88-3 393 4052 159045

n-Butane 00106-97-8 108 3621 38994

n-Pentane 00109-66-0 121 3567 43335

n-Hexane 00110-54-3 113 3196 36265



Cyclohexane 00110-82-7 114 2313 26313


Benzene 00071-43-2 069 2021 14034


n-Octane 00111-65-9 080 1766 14063



3-Methylpentane 00096-14-0 169 1600 27048



23-Dimethylbutane 00079-29-8 090 1186 10659

2-Methylhexane 00591-76-4 109 1076 11672

2-Methyl-2-butene 00513-35-9 1420 1032 146518

t-2-Pentene 00646-04-8 1047 991 103774



Propane 00074-98-6 046 919 4201

2-Methylpropane 00075-28-5 118 876 10302



2-Methylheptane 00592-27-8 097 759 7340

3-Methylheptane 00589-81-1 112 683 7684

n-Nonane 00111-84-2 068 677 4621



24-Dimethylhexane 00589-43-5 161 607 9741


2-Methyl-1-butene 00563-46-2 638 575 36672


4-Methyloctane 02216-34-4 085 547 4637


c-2-Pentene 00627-20-3 1028 523 53797





136

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Heptene 06443-92-1 708 419 29626

3-Methyl-c-2-pentene 00922-62-3 1252 379 47426

ortho-Xylene 00095-47-6 758 368 27850



n-Propylbenzene 00103-65-1 196 350 6856

3-Methyloctane 02216-33-3 088 339 3003


t-2-Hexene 04050-45-7 855 329 28138


c-2-Butene 00590-18-1 1426 290 41290

n-Decane 00124-18-5 059 284 1680


Ethylbenzene 00100-41-4 296 279 8257


2-Methyl-2-pentene 00625-27-4 1103 272 29956

3-Methyl-t-2-pentene 00616-12-6 1166 264 30830

Unknown 16 247 252 6216


Unknown 8 247 236 5829


Cyclopentene 00142-29-0 669 225 15030






1-Nonene 00124-11-8 249 194 4832

22-Dimethylbutane 00075-83-2 111 192 2134


1-Octene 00111-66-0 314 162 5092

continued


137

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






Unknown 9 247 147 3619

t-4-Octene 14850-23-8 469 146 6841

33-Dimethylhexane 00563-16-6 115 146 1676


Unknown 5 247 140 3451


Indan 00496-11-7 323 086 2776

n-Undecane 01120-21-4 052 081 0423



22-Dimethyloctane 15869-87-1 076 048 0361

Unknown 1 247 043 1059


Total 12111 30488 2517


continued


138

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


139

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 213 8377

n-Pentane 00109-66-0 121 209 2533

n-Butane 00106-97-8 108 195 2100


n-Heptane 00142-82-5 097 146 1407



2-Methylpropane 00075-28-5 118 119 1401

n-Hexane 00110-54-3 113 119 1345

Cyclohexane 00110-82-7 114 115 1310

Benzene 00071-43-2 069 108 0747

Unknown 23 313 105 3279


t-2-Pentene 00646-04-8 1047 103 10759

n-Octane 00111-65-9 080 096 0765

3-Methylheptane 00589-81-1 112 093 1050

2-Methyl-2-butene 00513-35-9 1420 088 12443



3-Methylpentane 00096-14-0 169 081 1375


4-Methyloctane 02216-34-4 085 074 0632




c-2-Pentene 00627-20-3 1028 060 6196



t-2-Hexene 04050-45-7 855 055 4697

2-Methylhexane 00591-76-4 109 052 0565

2-Methyl-1-butene 00563-46-2 638 045 2839

2-Methylheptane 00592-27-8 097 043 0418




n-Nonane 00111-84-2 068 036 0249

n-Decane 00124-18-5 059 036 0213

n-Propylbenzene 00103-65-1 196 034 0658


3-Methyl-t-2-pentene 00616-12-6 1166 032 3705

22-Dimethyloctane 15869-87-1 076 030 0227






140

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Ethylbenzene 00100-41-4 296 027 0810

2-Methyl-2-pentene 00625-27-4 1103 026 2921

t-4-Octene 14850-23-8 469 026 1220

23-Dimethylbutane 00079-29-8 090 026 0231


ortho-Xylene 00095-47-6 758 025 1927

4-Methyl-t-2-pentene 00674-76-0 804 025 2022

c-2-Heptene 06443-92-1 708 025 1752

3-Methyl-c-2-pentene 00922-62-3 1252 023 2817


1-Butyne 00107-00-6 605 022 1304






Cyclopentene 00142-29-0 669 016 1068


Unknown 20 313 013 0398


22-Dimethylbutane 00075-83-2 111 010 0109



24-Dimethylhexane 00589-43-5 161 009 0138

Unknown 14 313 008 0265

Total 499 1646 3297


continued


141

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1583 22942


Toluene 00108-88-3 393 612 24017

n-Pentane 00109-66-0 121 486 5903

n-Butane 00106-97-8 108 481 5181

n-Heptane 00142-82-5 097 334 3229





n-Hexane 00110-54-3 113 272 3083

Benzene 00071-43-2 069 268 1861

Cyclohexane 00110-82-7 114 242 2757


2-Methylheptane 00592-27-8 097 200 1932



t-2-Pentene 00646-04-8 1047 171 17927

2-Methylpropane 00075-28-5 118 169 1990

2-Methyl-2-butene 00513-35-9 1420 166 23544

3-Methylpentane 00096-14-0 169 154 2608


c-2-Pentene 00627-20-3 1028 139 14324

2-Methyl-1-butene 00563-46-2 638 135 8633





3-Methyl-c-2-pentene 00922-62-3 1252 096 11960


23-Dimethylbutane 00079-29-8 090 094 0843

3-Methylheptane 00589-81-1 112 090 1017

t-2-Hexene 04050-45-7 855 083 7126


Ethylbenzene 00100-41-4 296 078 2298

n-Octane 00111-65-9 080 076 0607

ortho-Xylene 00095-47-6 758 076 5752


2-Methylhexane 00591-76-4 109 069 0746

2-Methyl-2-pentene 00625-27-4 1103 069 7570

n-Nonane 00111-84-2 068 068 0463

3-Methyl-t-2-pentene 00616-12-6 1166 066 7701






142

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 057 0908

c-2-Butene 00590-18-1 1426 056 7952


n-Propylbenzene 00103-65-1 196 047 0917

Cyclopentene 00142-29-0 669 044 2973




22-Dimethylbutane 00075-83-2 111 035 0385




Total 1098 3753 3417


continued


143

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Cyclohexane 00110-82-7 114 830 9437


Toluene 00108-88-3 393 735 28842

n-Pentane 00109-66-0 121 635 7720

n-Butane 00106-97-8 108 605 6519


n-Heptane 00142-82-5 097 582 5618

Benzene 00071-43-2 069 579 4019







3-Methylpentane 00096-14-0 169 400 6755

n-Propylbenzene 00103-65-1 196 372 7293

2-Methylhexane 00591-76-4 109 361 3923

n-Octane 00111-65-9 080 359 2859

Unknown 22 382 315 12033

n-Hexane 00110-54-3 113 299 3392


t-2-Butene 00624-64-6 1520 280 42605

4-Methyl-t-2-pentene 00674-76-0 804 264 21197

n-Decane 00124-18-5 059 241 1427



Cyclopentene 00142-29-0 669 218 14592



Propane 00074-98-6 046 193 0881

ortho-Xylene 00095-47-6 758 177 13425

24-Dimethylhexane 00589-43-5 161 168 2703



Ethylbenzene 00100-41-4 296 162 4786

2-Methyl-2-butene 00513-35-9 1420 160 22779


4-Methyloctane 02216-34-4 085 145 1233


t-2-Hexene 04050-45-7 855 134 11491





144

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylbutane 00079-29-8 090 132 1189

2-Methyl-2-pentene 00625-27-4 1103 129 14259



n-Nonane 00111-84-2 068 120 0820

22-Dimethylbutane 00075-83-2 111 115 1278

2-Methylheptane 00592-27-8 097 114 1105

3-Methylheptane 00589-81-1 112 109 1224

3-Methyl-t-2-pentene 00616-12-6 1166 096 11152




2-Methyl-1-butene 00563-46-2 638 080 5118

3-Methyl-c-2-pentene 00922-62-3 1252 080 10031

Unknown 18 382 072 2733

t-2-Pentene 00646-04-8 1047 056 5882



c-2-Butene 00590-18-1 1426 019 2640

Total 2130 8389 3939


continued


145

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 31696 459267


n-Pentane 00109-66-0 121 5202 63200

n-Butane 00106-97-8 108 4742 51062


Toluene 00108-88-3 393 3938 154553

n-Heptane 00142-82-5 097 3796 36662

n-Hexane 00110-54-3 113 3616 41031


Benzene 00071-43-2 069 2716 18860


Cyclohexane 00110-82-7 114 2178 24768

2-Methyl-2-butene 00513-35-9 1420 2023 287182

t-2-Pentene 00646-04-8 1047 1945 203758


3-Methylpentane 00096-14-0 169 1693 28633





c-2-Pentene 00627-20-3 1028 991 101902

2-Methyl-1-butene 00563-46-2 638 937 59771


n-Octane 00111-65-9 080 891 7098

2-Methylhexane 00591-76-4 109 887 9631


2-Methylpropane 00075-28-5 118 786 9244

t-2-Hexene 04050-45-7 855 635 54264

23-Dimethylbutane 00079-29-8 090 601 5401

c-2-Butene 00590-18-1 1426 546 77832

Cyclopentane 00287-92-3 224 476 10644

3-Methyl-t-2-pentene 00616-12-6 1166 457 53303


2-Methylheptane 00592-27-8 097 412 3986


Cyclopentene 00142-29-0 669 406 27162

3-Methyl-c-2-pentene 00922-62-3 1252 381 47688

2-Methyl-2-pentene 00625-27-4 1103 378 41721




3-Methylheptane 00589-81-1 112 341 3833






146

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 277 4444



22-Dimethylbutane 00075-83-2 111 254 2820

n-Nonane 00111-84-2 068 246 1676

ortho-Xylene 00095-47-6 758 241 18230



Ethylbenzene 00100-41-4 296 181 5360


Propane 00074-98-6 046 169 0774

n-Propylbenzene 00103-65-1 196 168 3302




4-Methyloctane 02216-34-4 085 137 1163





Indan 00496-11-7 323 120 3878


3-Methyloctane 02216-33-3 088 112 0989

14-Diethylbenzene 00105-05-5 439 098 4322

33-Dimethylhexane 00563-16-6 115 095 1092


n-Undecane 01120-21-4 052 093 0483


Unknown 9 289 085 2456

Unknown 22 289 085 2454

Unknown 8 289 083 2389

Unknown 16 289 081 2340






t-4-Octene 14850-23-8 469 062 2903

n-Decane 00124-18-5 059 061 0363

continued


147

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 5 289 057 1654

Unknown 1 289 057 1645

c-2-Heptene 06443-92-1 708 056 3942


4-Methyl-t-2-pentene 00674-76-0 804 048 3873


1-Heptene 00592-76-7 429 040 1703

t-3-Heptene 14686-14-7 617 035 2178



1-Nonene 00124-11-8 249 033 0811


c- amp t-4-Nonene 02198-23-4 442 029 1282






13-Butadiene 00106-99-0 1245 014 1729


Total 10698 31327 2928


continued


148

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Toluene 00108-88-3 393 129 5070


n-Butane 00106-97-8 108 114 1229

n-Heptane 00142-82-5 097 106 1019


Benzene 00071-43-2 069 094 0655



c-2-Butene 00590-18-1 1426 072 10220



2-Methyl-1-butene 00563-46-2 638 057 3627



n-Pentane 00109-66-0 121 054 0651



Cyclohexane 00110-82-7 114 049 0558

n-Hexane 00110-54-3 113 040 0449


n-Octane 00111-65-9 080 037 0294


3-Methylpentane 00096-14-0 169 032 0549

n-Propylbenzene 00103-65-1 196 030 0591

3-Methylheptane 00589-81-1 112 028 0314

t-2-Hexene 04050-45-7 855 028 2367


2-Methylheptane 00592-27-8 097 025 0246

n-Nonane 00111-84-2 068 023 0160


2-Methylhexane 00591-76-4 109 022 0243

3-Methyl-t-2-pentene 00616-12-6 1166 021 2489

Cyclopentene 00142-29-0 669 018 1231





149

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 016 0260


2-Methyl-2-butene 00513-35-9 1420 015 2102

23-Dimethylbutane 00079-29-8 090 015 0133


ortho-Xylene 00095-47-6 758 012 0934


Ethylbenzene 00100-41-4 296 011 0325

t-2-Pentene 00646-04-8 1047 008 0869



Total 259 1087 4196


continued


150

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2384 34537


Toluene 00108-88-3 393 399 15668

n-Pentane 00109-66-0 121 371 4510




n-Heptane 00142-82-5 097 309 2980

n-Butane 00106-97-8 108 299 3222

n-Hexane 00110-54-3 113 246 2791

Benzene 00071-43-2 069 233 1614




t-2-Pentene 00646-04-8 1047 148 15551

Cyclohexane 00110-82-7 114 146 1657





2-Methyl-2-butene 00513-35-9 1420 115 16375

c-2-Pentene 00627-20-3 1028 113 11626




3-Methylpentane 00096-14-0 169 103 1742

n-Octane 00111-65-9 080 100 0796

2-Methyl-1-butene 00563-46-2 638 083 5318


t-2-Hexene 04050-45-7 855 062 5278

3-Methyl-c-2-pentene 00922-62-3 1252 061 7658


3-Methylheptane 00589-81-1 112 054 0611



2-Methylhexane 00591-76-4 109 051 0548

ortho-Xylene 00095-47-6 758 048 3648

Ethylbenzene 00100-41-4 296 047 1400

n-Propylbenzene 00103-65-1 196 047 0921


24-Dimethylhexane 00589-43-5 161 042 0671

3-Methyl-t-2-pentene 00616-12-6 1166 041 4734






151

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 039 4295

Cyclopentane 00287-92-3 224 038 0856

22-Dimethylbutane 00075-83-2 111 033 0370





n-Nonane 00111-84-2 068 023 0155

23-Dimethylbutane 00079-29-8 090 022 0200

Cyclopentene 00142-29-0 669 018 1224


Unknown 22 324 013 0423

2-Methylheptane 00592-27-8 097 012 0113

Total 951 3138 3302


continued


152

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4516 65430





Toluene 00108-88-3 393 507 19903

Unknown 22 333 400 13307

n-Butane 00106-97-8 108 381 4104


n-Heptane 00142-82-5 097 294 2844

Propane 00074-98-6 046 278 1272

Benzene 00071-43-2 069 271 1880

2-Methylheptane 00592-27-8 097 242 2337

n-Pentane 00109-66-0 121 233 2835

n-Hexane 00110-54-3 113 226 2566


c-2-Butene 00590-18-1 1426 199 28382



n-Nonane 00111-84-2 068 171 1171




c-2-Pentene 00627-20-3 1028 111 11423




n-Octane 00111-65-9 080 085 0679

Cyclohexane 00110-82-7 114 081 0923

2-Methyl-2-butene 00513-35-9 1420 081 11500

2-Methyl-1-butene 00563-46-2 638 081 5168




2-Methyl-2-pentene 00625-27-4 1103 068 7461

3-Methylheptane 00589-81-1 112 064 0719




153

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



t-2-Pentene 00646-04-8 1047 062 6546


ortho-Xylene 00095-47-6 758 053 4033


3-Methyl-c-2-pentene 00922-62-3 1252 047 5926

Ethylbenzene 00100-41-4 296 043 1269

2-Methylpropane 00075-28-5 118 038 0446


Cyclopentene 00142-29-0 669 022 1503

t-2-Hexene 04050-45-7 855 014 1156

3-Methyl-t-2-pentene 00616-12-6 1166 011 1314


23-Dimethylbutane 00079-29-8 090 005 0041

Total 1362 4730 3473


continued


154

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


155

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 914 13240



n-Heptane 00142-82-5 097 320 3090




n-Octane 00111-65-9 080 190 1516




2-Methylheptane 00592-27-8 097 148 1433


2-Methylpropane 00075-28-5 118 118 1392

Toluene 00108-88-3 393 103 4047

n-Nonane 00111-84-2 068 099 0674



3-Methylheptane 00589-81-1 112 072 0810

Benzene 00071-43-2 069 072 0497



Ethylbenzene 00100-41-4 296 054 1611

n-Propylbenzene 00103-65-1 196 051 0994

Indan 00496-11-7 323 046 1487

Unknown 8 380 044 1655

4-Methyloctane 02216-34-4 085 031 0266


ortho-Xylene 00095-47-6 758 025 1916

2-Methylhexane 00591-76-4 109 025 0270

3-Methyloctane 02216-33-3 088 022 0195

t-2-Hexene 04050-45-7 855 022 1856

n-Decane 00124-18-5 059 020 0120



24-Dimethylhexane 00589-43-5 161 010 0159


Unknown 18 380 008 0320


Total 504 1959 3887





156

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5350 77523



Toluene 00108-88-3 393 710 27869


n-Heptane 00142-82-5 097 557 5384

n-Pentane 00109-66-0 121 507 6163




n-Butane 00106-97-8 108 412 4441

Benzene 00071-43-2 069 397 2757

n-Hexane 00110-54-3 113 324 3679






n-Octane 00111-65-9 080 190 1517

2-Methyl-2-butene 00513-35-9 1420 185 26255

Cyclohexane 00110-82-7 114 177 2018

2-Methylpropane 00075-28-5 118 161 1890

t-2-Pentene 00646-04-8 1047 157 16410

3-Methylpentane 00096-14-0 169 153 2584

n-Propylbenzene 00103-65-1 196 130 2552


n-Nonane 00111-84-2 068 105 0717


2-Methylhexane 00591-76-4 109 098 1068

Propane 00074-98-6 046 095 0435

ortho-Xylene 00095-47-6 758 095 7180

2-Methyl-1-butene 00563-46-2 638 091 5809

c-2-Pentene 00627-20-3 1028 087 8898

3-Methyloctane 02216-33-3 088 083 0732


2-Methylheptane 00592-27-8 097 082 0789

4-Methyloctane 02216-34-4 085 082 0692

Cyclopentene 00142-29-0 669 079 5254

Cyclopentane 00287-92-3 224 074 1658

Ethylbenzene 00100-41-4 296 071 2105

n-Decane 00124-18-5 059 065 0381

3-Methylheptane 00589-81-1 112 063 0710

3-Methyl-t-2-pentene 00616-12-6 1166 063 7322

24-Dimethylhexane 00589-43-5 161 062 1002




157

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 061 7585




22-Dimethylbutane 00075-83-2 111 057 0637

t-2-Hexene 04050-45-7 855 056 4804


2-Methyl-2-pentene 00625-27-4 1103 054 5956





Unknown 18 309 046 1407

c-2-Butene 00590-18-1 1426 041 5887






23-Dimethylbutane 00079-29-8 090 023 0203

Total 1716 5398 3145


continued


158

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 1415 20503




n-Heptane 00142-82-5 097 457 4411

n-Nonane 00111-84-2 068 418 2857

n-Octane 00111-65-9 080 391 3117

n-Propylbenzene 00103-65-1 196 390 7648





Unknown 22 429 241 10343



Toluene 00108-88-3 393 138 5398


Ethylbenzene 00100-41-4 296 107 3162

Benzene 00071-43-2 069 106 0733

ortho-Xylene 00095-47-6 758 086 6504

2-Methylhexane 00591-76-4 109 053 0572


Total 1016 4464 4392





159

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 80088 1160459


n-Pentane 00109-66-0 121 4822 58590

n-Heptane 00142-82-5 097 4735 45729

n-Butane 00106-97-8 108 4415 47543


Toluene 00108-88-3 393 3850 151113


n-Hexane 00110-54-3 113 3408 38671


Benzene 00071-43-2 069 3032 21056


2-Methyl-2-butene 00513-35-9 1420 1879 266753


t-2-Pentene 00646-04-8 1047 1856 194423

Cyclohexane 00110-82-7 114 1803 20503

3-Methylpentane 00096-14-0 169 1710 28914

n-Octane 00111-65-9 080 1552 12360




2-Methylhexane 00591-76-4 109 1117 12118


2-Methyl-1-butene 00563-46-2 638 911 58131

c-2-Pentene 00627-20-3 1028 907 93216

2-Methylpropane 00075-28-5 118 779 9171

2-Methylheptane 00592-27-8 097 709 6862

1-Butyne 00107-00-6 605 663 40082


3-Methylheptane 00589-81-1 112 644 7246

t-2-Hexene 04050-45-7 855 637 54462



23-Dimethylbutane 00079-29-8 090 550 4945

3-Methyl-c-2-pentene 00922-62-3 1252 539 67459


n-Nonane 00111-84-2 068 474 3235

Cyclopentane 00287-92-3 224 459 10278




3-Methyl-t-2-pentene 00616-12-6 1166 406 47372

2-Methyl-2-pentene 00625-27-4 1103 376 41453

Cyclopentene 00142-29-0 669 370 24726




160

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




ortho-Xylene 00095-47-6 758 354 26855

4-Methyloctane 02216-34-4 085 354 3006

c-2-Butene 00590-18-1 1426 344 49033



Ethylbenzene 00100-41-4 296 301 8929

n-Propylbenzene 00103-65-1 196 301 5890

3-Methyloctane 02216-33-3 088 295 2606

22-Dimethylbutane 00075-83-2 111 289 3213

24-Dimethylhexane 00589-43-5 161 285 4569




Propane 00074-98-6 046 234 1071







Unknown 8 239 166 3975

Unknown 9 239 161 3846





33-Dimethylhexane 00563-16-6 115 127 1462




continued


161

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Decane 00124-18-5 059 097 0572



c- amp t-4-Nonene 02198-23-4 442 081 3581

c-2-Heptene 06443-92-1 708 079 5569

Unknown 1 239 075 1804

t-4-Octene 14850-23-8 469 075 3530



Unknown 18 239 065 1559

Unknown 5 239 060 1448

Unknown 14 239 055 1326


1-Nonene 00124-11-8 249 048 1191



Indan 00496-11-7 323 034 1102

Total 16190 39290 2427


continued


162

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1993 28873


Toluene 00108-88-3 393 213 8354



n-Butane 00106-97-8 108 130 1400

n-Pentane 00109-66-0 121 129 1569

n-Heptane 00142-82-5 097 123 1191


n-Hexane 00110-54-3 113 116 1316


t-2-Butene 00624-64-6 1520 098 14909



Benzene 00071-43-2 069 089 0619

3-Methylheptane 00589-81-1 112 080 0904

t-2-Pentene 00646-04-8 1047 078 8210



3-Methylpentane 00096-14-0 169 056 0952



Unknown 18 282 048 1351

4-Methyloctane 02216-34-4 085 047 0400


2-Methyl-2-butene 00513-35-9 1420 046 6499

2-Methylhexane 00591-76-4 109 043 0468

c-2-Pentene 00627-20-3 1028 042 4351

t-2-Hexene 04050-45-7 855 041 3497

Cyclohexane 00110-82-7 114 036 0412


c-2-Heptene 06443-92-1 708 035 2475

2-Methyl-1-butene 00563-46-2 638 035 2212

n-Octane 00111-65-9 080 033 0264

23-Dimethylbutane 00079-29-8 090 032 0284





3-Methyl-t-2-pentene 00616-12-6 1166 023 2658


n-Nonane 00111-84-2 068 022 0148

3-Methyl-c-2-pentene 00922-62-3 1252 019 2434





163

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentene 00142-29-0 669 014 0946



n-Propylbenzene 00103-65-1 196 008 0160

24-Dimethylhexane 00589-43-5 161 003 0043

Total 513 1471 2864


continued


164

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4419 64033



Toluene 00108-88-3 393 327 12821

n-Heptane 00142-82-5 097 317 3058

n-Pentane 00109-66-0 121 298 3615

n-Butane 00106-97-8 108 292 3145



n-Hexane 00110-54-3 113 202 2297



Benzene 00071-43-2 069 176 1224



3-Methylpentane 00096-14-0 169 128 2170

Cyclohexane 00110-82-7 114 121 1373

t-2-Pentene 00646-04-8 1047 108 11335

n-Octane 00111-65-9 080 104 0832

23-Dimethylbutane 00079-29-8 090 093 0839

2-Methyl-2-butene 00513-35-9 1420 088 12506


c-2-Pentene 00627-20-3 1028 065 6705

2-Methylheptane 00592-27-8 097 065 0628



2-Methyl-1-butene 00563-46-2 638 060 3850

ortho-Xylene 00095-47-6 758 058 4432

2-Methylhexane 00591-76-4 109 053 0572

3-Methylheptane 00589-81-1 112 044 0500




2-Methyl-2-pentene 00625-27-4 1103 041 4512

Cyclopentene 00142-29-0 669 040 2703

n-Nonane 00111-84-2 068 040 0272


n-Propylbenzene 00103-65-1 196 034 0666



c-2-Heptene 06443-92-1 708 032 2242

c-2-Butene 00590-18-1 1426 030 4304

3-Methyl-t-2-pentene 00616-12-6 1166 027 3205





165

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Ethylbenzene 00100-41-4 296 024 0701

24-Dimethylhexane 00589-43-5 161 020 0324

t-2-Hexene 04050-45-7 855 019 1605



22-Dimethylbutane 00075-83-2 111 016 0174


3-Methyl-c-2-pentene 00922-62-3 1252 010 1259


Total 1033 2530 2449


continued


166

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5963 86398




Toluene 00108-88-3 393 571 22420



n-Pentane 00109-66-0 121 455 5531


Propane 00074-98-6 046 324 1482





Benzene 00071-43-2 069 254 1767


n-Heptane 00142-82-5 097 246 2379


t-2-Pentene 00646-04-8 1047 211 22048


c-2-Butene 00590-18-1 1426 195 27782

Ethylbenzene 00100-41-4 296 168 4985

2-Methyl-1-butene 00563-46-2 638 165 10501

n-Hexane 00110-54-3 113 163 1848

ortho-Xylene 00095-47-6 758 152 11495

Cyclohexane 00110-82-7 114 136 1543

c-2-Pentene 00627-20-3 1028 132 13597


2-Methyl-2-butene 00513-35-9 1420 130 18389

n-Octane 00111-65-9 080 129 1027


3-Methylheptane 00589-81-1 112 115 1296

22-Dimethylbutane 00075-83-2 111 113 1259

n-Butane 00106-97-8 108 111 1191


3-Methylpentane 00096-14-0 169 099 1670


3-Methyl-t-2-pentene 00616-12-6 1166 097 11253

n-Nonane 00111-84-2 068 093 0635


23-Dimethylbutane 00079-29-8 090 091 0816

2-Methylheptane 00592-27-8 097 091 0876

Styrene 00100-42-5 166 085 1415

n-Propylbenzene 00103-65-1 196 085 1659




167

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 068 1091


c-2-Heptene 06443-92-1 708 067 4724

Cyclopentene 00142-29-0 669 058 3856




t-2-Hexene 04050-45-7 855 047 4014

3-Methyl-c-2-pentene 00922-62-3 1252 042 5224



2-Methylhexane 00591-76-4 109 024 0260

Total 1768 6143 3474


continued


168

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 55723 807411



n-Heptane 00142-82-5 097 5981 57761

n-Pentane 00109-66-0 121 4502 54693

n-Butane 00106-97-8 108 3984 42902

n-Hexane 00110-54-3 113 3782 42912


Toluene 00108-88-3 393 3760 147573


Benzene 00071-43-2 069 2573 17862


Cyclohexane 00110-82-7 114 2121 24121




3-Methylpentane 00096-14-0 169 1746 29526

2-Methylhexane 00591-76-4 109 1523 16530

n-Octane 00111-65-9 080 1370 10905

2-Methyl-2-butene 00513-35-9 1420 1332 189048

t-2-Pentene 00646-04-8 1047 1291 135259


23-Dimethylbutane 00079-29-8 090 914 8215


2-Methyl-1-butene 00563-46-2 638 724 46184



c-2-Pentene 00627-20-3 1028 654 67284


1-Butyne 00107-00-6 605 626 37845

2-Methylheptane 00592-27-8 097 598 5783



3-Methylheptane 00589-81-1 112 575 6461

24-Dimethylhexane 00589-43-5 161 569 9133

3-Methyl-c-2-pentene 00922-62-3 1252 520 65089



t-2-Hexene 04050-45-7 855 463 39550

c-2-Heptene 06443-92-1 708 449 31804

n-Decane 00124-18-5 059 419 2479


Cyclopentane 00287-92-3 224 395 8835





169

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




c-2-Butene 00590-18-1 1426 336 47937

3-Methyl-t-2-pentene 00616-12-6 1166 335 39014



2-Methyl-2-pentene 00625-27-4 1103 298 32843


4-Methyloctane 02216-34-4 085 282 2390

n-Nonane 00111-84-2 068 276 1883

Cyclopentene 00142-29-0 669 274 18349


22-Dimethylbutane 00075-83-2 111 262 2916





3-Methyloctane 02216-33-3 088 227 2006

33-Dimethylhexane 00563-16-6 115 217 2497





ortho-Xylene 00095-47-6 758 185 13998

Ethylbenzene 00100-41-4 296 181 5358


n-Propylbenzene 00103-65-1 196 147 2880




Unknown 8 231 112 2592


Unknown 16 231 111 2561

Unknown 5 231 101 2336


c- amp t-4-Nonene 02198-23-4 442 096 4265


Unknown 9 231 085 1963


Unknown 1 231 036 0824


Total 14128 33504 2371


continued


170

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


171

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 8324 89644

2-Methylpropane 00075-28-5 118 7588 89275

Ethanol 00064-17-5 145 5174 74976

n-Pentane 00109-66-0 121 4957 60220




n-Hexane 00110-54-3 113 1782 20226

2-Methyl-2-butene 00513-35-9 1420 1495 212177

Propane 00074-98-6 046 1378 6301

t-2-Pentene 00646-04-8 1047 1321 138329

Toluene 00108-88-3 393 1320 51799

3-Methylpentane 00096-14-0 169 1291 21833

3-Me-1-Hexene 03404-61-3 427 1081 46189


t-3-Heptene 14686-14-7 617 963 59431

2-Methyl-1-butene 00563-46-2 638 894 57049


Benzene 00071-43-2 069 728 5053

c-2-Pentene 00627-20-3 1028 704 72389


23-Dimethylbutane 00079-29-8 090 634 5698

22-DiMeHexane 00590-73-8 094 623 5866



2-Methylhexane 00591-76-4 109 393 4266


c-2-Butene 00590-18-1 1426 385 54865




22-Dimethylbutane 00075-83-2 111 312 3465

Cyclopentane 00287-92-3 224 301 6725

t-2-Hexene 04050-45-7 855 283 24189

14-Diethylbenzene 00105-05-5 439 246 10796

Indan 00496-11-7 323 235 7603

Cyclopentene 00142-29-0 669 222 14854

3-Methyl-t-2-pentene 00616-12-6 1166 218 25428


3-Methyl-c-2-pentene 00922-62-3 1252 216 27097


2-Methylheptane 00592-27-8 097 187 1812





172

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 173 19052

n-Octane 00111-65-9 080 166 1321


n-Propylbenzene 00103-65-1 196 160 3132

ortho-Xylene 00095-47-6 758 156 11834




Ethylbenzene 00100-41-4 296 141 4174





Unknown 5 290 113 3275











Naphthalene 00091-20-3 328 042 1374

Total 7033 20500 2915


continued


173

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 13220 142369

2-Methylpropane 00075-28-5 118 11988 141051

Ethanol 00064-17-5 145 9234 133801

n-Pentane 00109-66-0 121 8302 100866



n-Hexane 00110-54-3 113 2767 31394

2-Methyl-2-butene 00513-35-9 1420 2454 348276

t-2-Pentene 00646-04-8 1047 2145 224611

Propane 00074-98-6 046 2099 9596

3-Methylpentane 00096-14-0 169 2086 35279

n-Heptane 00142-82-5 097 1782 17211


Cyclohexane 00110-82-7 114 1516 17244

2-Methyl-1-butene 00563-46-2 638 1447 92328

22-DiMeHexane 00590-73-8 094 1392 13105

c-2-Pentene 00627-20-3 1028 1194 122782

Toluene 00108-88-3 393 1100 43170

Benzene 00071-43-2 069 1087 7545

23-Dimethylbutane 00079-29-8 090 1032 9271



2-Methylhexane 00591-76-4 109 603 6543

22-Dimethylbutane 00075-83-2 111 570 6332

c-2-Butene 00590-18-1 1426 511 72813

Cyclopentane 00287-92-3 224 491 10983

t-2-Hexene 04050-45-7 855 437 37393


Cyclopentene 00142-29-0 669 367 24548

n-Octane 00111-65-9 080 364 2897

3-Methyl-t-2-pentene 00616-12-6 1166 339 39475

2-Methyl-2-pentene 00625-27-4 1103 326 35978

3-Methyl-c-2-pentene 00922-62-3 1252 325 40724









Unknown 22 253 201 5089





174

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methylheptane 00589-81-1 112 170 1906





24-Dimethylhexane 00589-43-5 161 126 2020



2-Methylheptane 00592-27-8 097 104 1010

n-Propylbenzene 00103-65-1 196 099 1936

ortho-Xylene 00095-47-6 758 097 7318

n-Nonane 00111-84-2 068 092 0630





33-Dimethylhexane 00563-16-6 115 074 0847


Ethylbenzene 00100-41-4 296 067 1991


1-Octene 00111-66-0 314 055 1718



Total 10408 26483 2545


continued


175

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2191 31752


n-Butane 00106-97-8 108 1006 10833

n-Pentane 00109-66-0 121 747 9080

Toluene 00108-88-3 393 701 27531


Unknown 22 328 660 21624


Benzene 00071-43-2 069 489 3398

2-Methylpropane 00075-28-5 118 438 5148

t-2-Pentene 00646-04-8 1047 413 43247

n-Heptane 00142-82-5 097 401 3869

2-Methyl-2-butene 00513-35-9 1420 365 51798




Propane 00074-98-6 046 309 1412





Cyclohexane 00110-82-7 114 257 2927


n-Octane 00111-65-9 080 231 1837



c-2-Pentene 00627-20-3 1028 166 17113



n-Hexane 00110-54-3 113 150 1697



ortho-Xylene 00095-47-6 758 139 10527



c-2-Butene 00590-18-1 1426 130 18467



13-Butadiene 00106-99-0 1245 113 14026

Ethylbenzene 00100-41-4 296 109 3230

t-2-Hexene 04050-45-7 855 098 8420

2-Methyl-1-butene 00563-46-2 638 090 5717

2-Methylhexane 00591-76-4 109 078 0845

23-Dimethylbutane 00079-29-8 090 075 0672




176

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



22-DiMeHexane 00590-73-8 094 069 0650

2-Methyl-2-pentene 00625-27-4 1103 054 5959

2-Methylheptane 00592-27-8 097 052 0507

3-Methyl-t-2-pentene 00616-12-6 1166 051 5927


3-Methylpentane 00096-14-0 169 046 0770


3-Methylheptane 00589-81-1 112 024 0275

Cyclopentene 00142-29-0 669 022 1455


n-Nonane 00111-84-2 068 019 0129

Total 1606 5720 3562


continued


177

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 54709 792723


n-Butane 00106-97-8 108 10917 117569

n-Pentane 00109-66-0 121 9272 112649

2-Methylpropane 00075-28-5 118 7225 85005


Toluene 00108-88-3 393 6283 246616

n-Hexane 00110-54-3 113 4995 56676

n-Heptane 00142-82-5 097 4659 44994

Benzene 00071-43-2 069 4652 32302


2-Methyl-2-butene 00513-35-9 1420 3675 521667

t-2-Pentene 00646-04-8 1047 3631 380251

3-Methylpentane 00096-14-0 169 2779 46981

22-DiMeHexane 00590-73-8 094 2773 26105

Cyclohexane 00110-82-7 114 2771 31519


c-2-Pentene 00627-20-3 1028 1943 199760

2-Methyl-1-butene 00563-46-2 638 1834 117003


Propane 00074-98-6 046 1660 7588


2-Methylhexane 00591-76-4 109 1107 12010


n-Octane 00111-65-9 080 1036 8250


t-2-Hexene 04050-45-7 855 954 81525


23-Dimethylbutane 00079-29-8 090 860 7730


Cyclopentane 00287-92-3 224 748 16744


c-2-Butene 00590-18-1 1426 680 97022

3-Methyl-t-2-pentene 00616-12-6 1166 666 77705

Cyclopentene 00142-29-0 669 665 44433


22-Dimethylbutane 00075-83-2 111 574 6383

3-Methyl-c-2-pentene 00922-62-3 1252 548 68650

2-Methyl-2-pentene 00625-27-4 1103 519 57206

2-Methylheptane 00592-27-8 097 515 4981



1-Butyne 00107-00-6 605 436 26373

3-Methylheptane 00589-81-1 112 403 4535




178

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





ortho-Xylene 00095-47-6 758 345 26142






Ethylbenzene 00100-41-4 296 292 8644


24-Dimethylhexane 00589-43-5 161 289 4646



n-Nonane 00111-84-2 068 234 1599


n-Propylbenzene 00103-65-1 196 198 3881



4-Methyloctane 02216-34-4 085 193 1641



Unknown 1 271 171 4641

33-Dimethylhexane 00563-16-6 115 159 1833






n-Undecane 01120-21-4 052 079 0415

3-Methyloctane 02216-33-3 088 079 0703

Unknown 5 271 076 2052

1-Octene 00111-66-0 314 065 2057





Unknown 8 271 035 0945

Total 17874 48855 2733


continued


179

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 8198 118785

n-Butane 00106-97-8 108 7183 77353


n-Pentane 00109-66-0 121 3595 43676

2-Methylpropane 00075-28-5 118 2766 32545


Propane 00074-98-6 046 2137 9770

n-Hexane 00110-54-3 113 1047 11875


n-Heptane 00142-82-5 097 912 8810

t-2-Pentene 00646-04-8 1047 830 86907

2-Methyl-2-butene 00513-35-9 1420 814 115599


23-Dimethylbutane 00079-29-8 090 556 4999


Benzene 00071-43-2 069 530 3683

2-Methyl-1-butene 00563-46-2 638 507 32336

Toluene 00108-88-3 393 503 19740

3-Methylpentane 00096-14-0 169 472 7984


c-2-Pentene 00627-20-3 1028 393 40363


c-2-Butene 00590-18-1 1426 277 39443



22-Dimethylbutane 00075-83-2 111 214 2380


2-Methylheptane 00592-27-8 097 180 1739

t-2-Hexene 04050-45-7 855 178 15211

n-Octane 00111-65-9 080 172 1368



2-Methylhexane 00591-76-4 109 161 1748



c-2-Heptene 06443-92-1 382 146 5572



Cyclopentene 00142-29-0 669 129 8640

3-Methyl-t-2-pentene 00616-12-6 1166 116 13518


Cyclohexane 00110-82-7 114 092 1044


n-Nonane 00111-84-2 068 087 0593




180

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 086 0966

2-Methyl-2-pentene 00625-27-4 1103 081 8971



24-Dimethylhexane 00589-43-5 161 078 1247








n-Propylbenzene 00103-65-1 196 048 0949


33-Dimethylhexane 00563-16-6 115 031 0359


3-Methyl-c-2-pentene 00922-62-3 1252 027 3427




Ethylbenzene 00100-41-4 296 018 0528

ortho-Xylene 00095-47-6 758 010 0721


Total 4710 11512 2444


continued


181

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 15180 219955


n-Butane 00106-97-8 108 9750 104997

n-Pentane 00109-66-0 121 5514 66989


2-Methylpropane 00075-28-5 118 3609 42461


n-Hexane 00110-54-3 113 2552 28959

Propane 00074-98-6 046 2506 11455

n-Heptane 00142-82-5 097 1866 18025

3-Methylpentane 00096-14-0 169 1624 27461

23-Dimethylbutane 00079-29-8 090 1413 12703

2-Methyl-2-butene 00513-35-9 1420 1376 195359

Toluene 00108-88-3 393 1340 52581

Cyclohexane 00110-82-7 114 1307 14870



t-2-Pentene 00646-04-8 1047 1180 123585


Benzene 00071-43-2 069 965 6703

2-Methyl-1-butene 00563-46-2 638 878 56009

c-2-Pentene 00627-20-3 1028 635 65238

2-Methylhexane 00591-76-4 109 632 6855






22-Dimethylbutane 00075-83-2 111 370 4115


n-Octane 00111-65-9 080 346 2755


c-2-Butene 00590-18-1 1426 336 47966


c-2-Heptene 06443-92-1 708 260 18411

t-2-Hexene 04050-45-7 855 249 21269

24-Dimethylhexane 00589-43-5 161 234 3765






3-Methyl-t-2-pentene 00616-12-6 1166 201 23444

2-Methyl-2-pentene 00625-27-4 1103 200 22011




182

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 193 1865

3-Methylheptane 00589-81-1 112 188 2119

Cyclopentene 00142-29-0 669 180 12031



n-Propylbenzene 00103-65-1 196 157 3073

3-Methyl-c-2-pentene 00922-62-3 1252 146 18216




ortho-Xylene 00095-47-6 758 129 9739




Ethylbenzene 00100-41-4 296 101 3002




n-Nonane 00111-84-2 068 085 0583



4-Methyloctane 02216-34-4 085 082 0694



33-Dimethylhexane 00563-16-6 115 067 0767

n-Decane 00124-18-5 059 066 0389



Total 8664 21100 2435


continued


183

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1732 25089


Benzene 00071-43-2 069 452 3139

c-2-Butene 00590-18-1 1426 376 53628








c-2-Pentene 00627-20-3 1028 072 7386

n-Heptane 00142-82-5 097 059 0568

n-Propylbenzene 00103-65-1 196 048 0947

Ethylbenzene 00100-41-4 296 045 1322


2-Methyl-2-butene 00513-35-9 1420 025 3547

t-2-Hexene 04050-45-7 855 022 1855

ortho-Xylene 00095-47-6 758 015 1110

n-Octane 00111-65-9 080 010 0081

Total 489 2108 4309




184

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 51382 744509



n-Butane 00106-97-8 108 8982 96733

n-Pentane 00109-66-0 121 6997 85011

Toluene 00108-88-3 393 6711 263404

n-Heptane 00142-82-5 097 6680 64513

n-Hexane 00110-54-3 113 5030 57075



Benzene 00071-43-2 069 4022 27924

Cyclohexane 00110-82-7 114 3279 37292




2-Methylpropane 00075-28-5 118 2557 30086


Propane 00074-98-6 046 2432 11116

3-Methylpentane 00096-14-0 169 2416 40845


n-Octane 00111-65-9 080 2194 17472

2-Methyl-2-butene 00513-35-9 1420 2103 298453

t-2-Pentene 00646-04-8 1047 2086 218459


2-Methylhexane 00591-76-4 109 1526 16559

23-Dimethylbutane 00079-29-8 090 1374 12350



2-Methyl-1-butene 00563-46-2 638 1191 75982



c-2-Pentene 00627-20-3 1028 1105 113644

2-Methylheptane 00592-27-8 097 1023 9893


3-Methylheptane 00589-81-1 112 906 10183





24-Dimethylhexane 00589-43-5 161 698 11203

c-2-Heptene 06443-92-1 708 667 47214

n-Nonane 00111-84-2 068 663 4525

t-2-Hexene 04050-45-7 855 648 55398

ortho-Xylene 00095-47-6 758 548 41492




185

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentane 00287-92-3 224 512 11458


n-Propylbenzene 00103-65-1 196 499 9784

4-Methyloctane 02216-34-4 085 497 4216

3-Methyl-t-2-pentene 00616-12-6 1166 485 56599

3-Methyl-c-2-pentene 00922-62-3 1252 456 57109

c-2-Butene 00590-18-1 1426 444 63356


Cyclopentene 00142-29-0 669 416 27787






Ethylbenzene 00100-41-4 296 389 11519

22-Dimethylbutane 00075-83-2 111 378 4206

2-Methyl-2-pentene 00625-27-4 1103 358 39448

Unknown 16 261 356 9264



3-Methyloctane 02216-33-3 088 339 3003




1-Nonene 00124-11-8 249 256 6374

1-Butyne 00107-00-6 605 251 15194

Ethylene 00074-85-1 888 250 22216


Unknown 8 261 234 6089


33-Dimethylhexane 00563-16-6 115 213 2449




1-Octene 00111-66-0 314 195 6137


Unknown 9 261 154 4022

n-Undecane 01120-21-4 052 154 0805

n-Decane 00124-18-5 059 152 0896

Unknown 5 261 142 3689


Indan 00496-11-7 323 131 4230

continued


186

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 6 261 131 3400


Styrene 00100-42-5 166 105 1738



Unknown 1 261 052 1367



Total 18590 49278 2651


continued


187

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


188

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




189

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




190

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Naphthalene 00091-20-3 328 774 25406


t-2-Butene 00624-64-6 1520 371 56453


n-Butane 00106-97-8 108 285 3072

23-Dimethylbutane 00079-29-8 090 248 2230



Toluene 00108-88-3 393 190 7444

2-Methylpropane 00075-28-5 118 166 1951

2-Methylheptane 00592-27-8 097 157 1514

3-Methyl-t-2-pentene 00616-12-6 1166 131 15309

n-Heptane 00142-82-5 097 130 1251


3-Methylpentane 00096-14-0 169 117 1981

24-Dimethylhexane 00589-43-5 161 111 1786


n-Hexane 00110-54-3 113 100 1134


22-Dimethylbutane 00075-83-2 111 082 0916

Ethylbenzene 00100-41-4 296 077 2293

t-2-Pentene 00646-04-8 1047 075 7833

Cyclohexane 00110-82-7 114 074 0842

c-2-Butene 00590-18-1 1426 074 10503

3-Methyl-c-2-pentene 00922-62-3 1252 071 8850

ortho-Xylene 00095-47-6 758 068 5178

n-Pentane 00109-66-0 121 021 0252


Total 486 2222 4570




191

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4628 67056

3-Methylpentane 00096-14-0 169 1507 25484



n-Butane 00106-97-8 108 1101 11855


Toluene 00108-88-3 393 1066 41860

3-Methyl-c-2-pentene 00922-62-3 1252 1066 133427

n-Pentane 00109-66-0 121 935 11363


n-Hexane 00110-54-3 113 210 2385


Total 1468 3932 2678




192

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




193

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




194

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




195

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4926 71372


Toluene 00108-88-3 393 1115 43746

3-Methylpentane 00096-14-0 169 762 12888

n-Butane 00106-97-8 108 725 7805


n-Hexane 00110-54-3 113 611 6931

n-Pentane 00109-66-0 121 583 7083




3-Methyl-c-2-pentene 00922-62-3 1252 205 25608

Total 1211 2325 1920



196


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


197

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 31534 339592

Ethanol 00064-17-5 145 15433 223618

n-Pentane 00109-66-0 121 4575 55584


Toluene 00108-88-3 393 4103 161061

n-Hexane 00110-54-3 113 3924 44527

2-Methyl-2-butene 00513-35-9 1420 3811 540999

t-2-Pentene 00646-04-8 1047 3208 335977

3-Methylpentane 00096-14-0 169 2810 47513

2-Methyl-1-butene 00563-46-2 638 2286 145822

23-Dimethylbutane 00079-29-8 090 2194 19722

c-2-Pentene 00627-20-3 1028 1736 178523




c-2-Butene 00590-18-1 1426 1349 192427

Benzene 00071-43-2 069 1177 8169

Cyclohexane 00110-82-7 114 1082 12310





t-2-Hexene 04050-45-7 855 585 50036

2-Methylhexane 00591-76-4 109 580 6299

Cyclopentene 00142-29-0 669 525 35095

n-Heptane 00142-82-5 097 524 5057

3-Methyl-t-2-pentene 00616-12-6 1166 474 55209


2-Methyl-2-pentene 00625-27-4 1103 432 47686

3-Methyl-c-2-pentene 00922-62-3 1252 408 51020




22-Dimethylbutane 00075-83-2 111 322 3582





24-Dimethylhexane 00589-43-5 161 213 3412


n-Octane 00111-65-9 080 159 1266






198

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylheptane 00592-27-8 097 131 1270




3-Methylheptane 00589-81-1 112 116 1307




t-3-Heptene 14686-14-7 617 083 5119


ortho-Xylene 00095-47-6 758 079 5957




n-Decane 00124-18-5 249 054 1339




Ethylbenzene 00100-41-4 296 049 1460


Unknown 1 266 034 0906

33-Dimethylhexane 00563-16-6 115 030 0344

n-Propylbenzene 00103-65-1 196 028 0542

n-Nonane 00111-84-2 068 015 0101


4-Methyl-t-2-pentene 00674-76-0 804 002 0184

Total 13923 37072 2663


continued


199

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 79369 854739


Ethanol 00064-17-5 145 38151 552793

Toluene 00108-88-3 393 16580 650783

n-Hexane 00110-54-3 113 13605 154368


3-Methylpentane 00096-14-0 169 7654 129419

n-Pentane 00109-66-0 121 7381 89678

2-Methyl-2-butene 00513-35-9 1420 6466 917894


t-2-Pentene 00646-04-8 1047 5245 549380

23-Dimethylbutane 00079-29-8 090 5099 45823

Benzene 00071-43-2 069 4157 28862


Cyclohexane 00110-82-7 114 3728 42398

2-Methyl-1-butene 00563-46-2 638 3681 234792

Ethylene 00074-85-1 888 3244 288174




c-2-Pentene 00627-20-3 1028 2900 298147



Ethane 00074-84-0 026 2242 5893


c-2-Butene 00590-18-1 1426 1864 265834

2-Methylhexane 00591-76-4 109 1801 19546

n-Heptane 00142-82-5 097 1789 17277




2-Methylpropane 00075-28-5 118 1312 15435


t-2-Hexene 04050-45-7 855 1292 110422

1-Butyne 00107-00-6 605 1288 77894

Propane 00074-98-6 046 1212 5539



3-Methyl-t-2-pentene 00616-12-6 1166 1006 117309


Cyclopentene 00142-29-0 669 970 64866


2-Methyl-2-pentene 00625-27-4 1103 953 105093





200

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 843 105557

n-Octane 00111-65-9 080 804 6403

24-Dimethylhexane 00589-43-5 161 747 11988




13-Butadiene 00106-99-0 1245 683 85018

ortho-Xylene 00095-47-6 758 620 46937

22-Dimethylbutane 00075-83-2 111 614 6826


Ethylbenzene 00100-41-4 296 564 16718


n-Propylbenzene 00103-65-1 196 527 10333







2-Methylheptane 00592-27-8 097 427 4127


3-Methylheptane 00589-81-1 112 420 4718


14-Diethylbenzene 00105-05-5 439 416 18237

n-Decane 00124-18-5 059 401 2372



Unknown 16 275 325 8937



Methane 00074-82-8 001 281 0039


n-Nonane 00111-84-2 068 234 1599

Styrene 00100-42-5 166 234 3891



4-Methyl-t-2-pentene 00674-76-0 804 187 15065

n-Undecane 01120-21-4 052 186 0970

4-Methyloctane 02216-34-4 085 170 1442


c-2-Heptene 06443-92-1 708 149 10568

Unknown 8 275 147 4049

continued


201

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 1 275 144 3964

Unknown 22 275 143 3926


Unknown 5 275 129 3543



Unknown 13 275 118 3236

33-Dimethylhexane 00563-16-6 115 116 1338

1-Nonene 00124-11-8 249 113 2820


3-Methyloctane 02216-33-3 088 101 0889

3-Me-1-Hexene 03404-61-3 427 096 4100


Indan 00496-11-7 323 071 2300

Total 32476 89876 2767


continued


202

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 172274 1855242


Ethanol 00064-17-5 145 69165 1002190

2-Methylpropane 00075-28-5 118 21941 258154

n-Hexane 00110-54-3 113 20456 232106

Toluene 00108-88-3 393 19883 780424


n-Pentane 00109-66-0 121 17100 207749

2-Methyl-2-butene 00513-35-9 1420 14541 2064164

t-2-Pentene 00646-04-8 1047 12530 1312315

3-Methylpentane 00096-14-0 169 12414 209911

23-Dimethylbutane 00079-29-8 090 8996 80848

2-Methyl-1-butene 00563-46-2 638 8314 530308


c-2-Pentene 00627-20-3 1028 6703 689128


Benzene 00071-43-2 069 5731 39795

c-2-Butene 00590-18-1 1426 5522 787420

Cyclohexane 00110-82-7 114 5520 62783




n-Heptane 00142-82-5 097 2763 26680



2-Methylhexane 00591-76-4 109 2596 28167


t-2-Hexene 04050-45-7 855 2303 196844

Cyclopentene 00142-29-0 669 2024 135325




3-Methyl-t-2-pentene 00616-12-6 1166 1818 211970

2-Methyl-2-pentene 00625-27-4 1103 1651 182150


3-Methyl-c-2-pentene 00922-62-3 1252 1509 188858



22-Dimethylbutane 00075-83-2 111 1289 14328

Propane 00074-98-6 046 1286 5880








203

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 965 15494

n-Octane 00111-65-9 080 867 6901






2-Methylheptane 00592-27-8 097 513 4960

Ethylbenzene 00100-41-4 296 509 15068

ortho-Xylene 00095-47-6 758 500 37892

3-Methylheptane 00589-81-1 112 493 5541








n-Propylbenzene 00103-65-1 196 278 5444

4-Methyl-t-2-pentene 00674-76-0 804 268 21529

Unknown 16 250 236 5907

n-Nonane 00111-84-2 068 228 1557





c-2-Heptene 06443-92-1 708 180 12724



4-Methyloctane 02216-34-4 085 159 1351


Unknown 5 250 146 3658

33-Dimethylhexane 00563-16-6 115 145 1668

Unknown 13 250 138 3462

Indan 00496-11-7 565 135 7640


1-Octene 00111-66-0 314 134 4197


Unknown 8 250 128 3196




continued


204

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




t-4-Octene 14850-23-8 469 113 5317

n-Decane 00124-18-5 059 102 0604

14-Diethylbenzene 00105-05-5 439 092 4032

3-Methyloctane 02216-33-3 088 083 0734

1-Nonene 00124-11-8 249 082 2036

Unknown 9 250 082 2039

t-3-Heptene 14686-14-7 617 074 4560

Unknown 3 250 072 1807

n-Undecane 01120-21-4 052 061 0317

1-Heptene 00592-76-7 429 060 2554



Unknown 12 250 046 1154



t-2-Nonene 06434-78-2 250 036 0888


c-2-Octene 07642-04-8 250 026 0651

Unknown 14 250 018 0459

Total 61958 155900 2516


continued


205

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11715 169746

n-Butane 00106-97-8 108 8056 86757

n-Hexane 00110-54-3 113 4667 52958


23-Dimethylbutane 00079-29-8 090 3624 32566

Toluene 00108-88-3 393 3574 140274

2-Methyl-2-butene 00513-35-9 1420 2721 386293

3-Methylpentane 00096-14-0 169 2686 45414

n-Pentane 00109-66-0 121 2659 32300

t-2-Pentene 00646-04-8 1047 2291 239970

2-Methyl-1-butene 00563-46-2 638 1615 103023



Cyclohexane 00110-82-7 114 1325 15069

2-Methylpropane 00075-28-5 118 1261 14840

c-2-Pentene 00627-20-3 1028 1225 125951

Benzene 00071-43-2 069 1002 6959


c-2-Butene 00590-18-1 1426 984 140348




2-Methylhexane 00591-76-4 109 497 5389



t-2-Hexene 04050-45-7 855 436 37281

n-Heptane 00142-82-5 097 390 3765

Cyclopentene 00142-29-0 669 377 25223


3-Methyl-t-2-pentene 00616-12-6 1166 342 39822

2-Methyl-2-pentene 00625-27-4 1103 323 35657


3-Methyl-c-2-pentene 00922-62-3 1252 294 36799




24-Dimethylhexane 00589-43-5 161 213 3421


n-Octane 00111-65-9 080 185 1477








206

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 141 1566



Propane 00074-98-6 046 113 0517




ortho-Xylene 00095-47-6 758 064 4881


4-Methyl-t-2-pentene 00674-76-0 804 060 4791


n-Decane 00124-18-5 059 057 0338

2-Methylheptane 00592-27-8 097 055 0536



Ethylbenzene 00100-41-4 296 053 1579

3-Methylheptane 00589-81-1 112 052 0582


Unknown 5 288 046 1329

4-Methyloctane 02216-34-4 085 043 0365



33-Dimethylhexane 00563-16-6 115 037 0423

3-Methyloctane 02216-33-3 088 032 0283

n-Nonane 00111-84-2 068 023 0155

n-Propylbenzene 00103-65-1 196 015 0294


Total 8737 25269 2892


continued


207

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35389 512774

Benzene 00071-43-2 069 4816 33438

Methane 00074-82-8 001 200 0028

Ethane 00074-84-0 026 1602 4210


Propane 00074-98-6 046 1131 5168

2-Methylpropane 00075-28-5 118 2369 27872

22-Dimethylbutane 00075-83-2 111 986 10951



23-Dimethylbutane 00079-29-8 090 7961 71544

ortho-Xylene 00095-47-6 758 645 48887


3-Methylpentane 00096-14-0 169 11861 200561



Ethylbenzene 00100-41-4 296 495 14670

n-Propylbenzene 00103-65-1 196 538 10537

n-Butane 00106-97-8 108 20573 221556

13-Butadiene 00106-99-0 1245 657 81767





Toluene 00108-88-3 393 16497 647513

n-Pentane 00109-66-0 121 12943 157255


n-Hexane 00110-54-3 113 19250 218427

Cyclohexane 00110-82-7 114 5321 60521


n-Octane 00111-65-9 080 692 5511

n-Nonane 00111-84-2 068 309 2108


n-Decane 00124-18-5 059 301 1780

Cyclopentene 00142-29-0 669 1453 97125

n-Heptane 00142-82-5 097 1831 17681


2-Methyl-2-butene 00513-35-9 1420 10075 1430132




2-Methyl-1-butene 00563-46-2 638 6277 400401






208

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 1065 17101

3-Methylheptane 00589-81-1 112 512 5752

c-2-Butene 00590-18-1 1426 4141 590493



2-Methylhexane 00591-76-4 109 2197 23841


2-Methylheptane 00592-27-8 097 512 4948



3-Methyl-t-2-pentene 00616-12-6 1166 1347 156999


2-Methyl-2-pentene 00625-27-4 1103 1253 138231

c-2-Pentene 00627-20-3 1028 4701 483353


t-2-Pentene 00646-04-8 1047 8504 890689





3-Methyl-c-2-pentene 00922-62-3 1252 1185 148379







t-2-Hexene 04050-45-7 855 1625 138889


Unknown 16 335 352 11791

Unknown 1 335 242 8119

Total 34405 116244 3379


continued


209

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 112868 1635432

n-Butane 00106-97-8 108 58158 626316

n-Hexane 00110-54-3 113 44646 506591


n-Pentane 00109-66-0 121 30821 374457

3-Methylpentane 00096-14-0 169 26164 442392

2-Methyl-2-butene 00513-35-9 1420 25929 3680648

Toluene 00108-88-3 393 23727 931277

t-2-Pentene 00646-04-8 1047 21858 2289338

23-Dimethylbutane 00079-29-8 090 18155 163160

2-Methyl-1-butene 00563-46-2 638 14852 947358



c-2-Pentene 00627-20-3 1028 11711 1204011

Cyclohexane 00110-82-7 114 10272 116827


c-2-Butene 00590-18-1 1426 8497 1211611

Benzene 00071-43-2 069 8447 58652

2-Methylpropane 00075-28-5 118 7517 88450



2-Methylhexane 00591-76-4 109 4449 48279



t-2-Hexene 04050-45-7 855 3861 330080


Cyclopentene 00142-29-0 669 3403 227545

n-Heptane 00142-82-5 097 3263 31514

3-Methyl-t-2-pentene 00616-12-6 1166 3087 359933


2-Methyl-2-pentene 00625-27-4 1103 2833 312515


3-Methyl-c-2-pentene 00922-62-3 1252 2551 319336



22-Dimethylbutane 00075-83-2 111 2302 25580


24-Dimethylhexane 00589-43-5 161 1503 24139

Propane 00074-98-6 046 1456 6658








210

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




1-Butyne 00107-00-6 605 1088 65828

n-Octane 00111-65-9 080 827 6585









2-Methylheptane 00592-27-8 097 486 4701

3-Methylheptane 00589-81-1 112 442 4965

ortho-Xylene 00095-47-6 758 367 27827







Ethylbenzene 00100-41-4 296 241 7138



n-Propylbenzene 00103-65-1 196 204 4004

Unknown 5 295 172 5063

33-Dimethylhexane 00563-16-6 115 164 1888


c-2-Heptene 06443-92-1 708 133 9383

n-Nonane 00111-84-2 068 125 0851

1-Octene 00111-66-0 314 124 3881

Indan 00496-11-7 323 119 3852

t-3-Heptene 14686-14-7 617 114 7031

Ethylene 00074-85-1 888 113 10031

4-Methyloctane 02216-34-4 085 111 0942


Unknown 16 295 101 2970

Unknown 3 295 097 2854

Unknown 6 295 097 2845




Unknown 8 295 081 2388

n-Decane 00124-18-5 059 080 0470

continued


211

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 13 295 079 2322

3-Methyloctane 02216-33-3 088 077 0681


13-Butadiene 00106-99-0 1245 076 9484


1-Heptene 00592-76-7 429 060 2584



Unknown 9 295 047 1372


1-Nonene 00124-11-8 249 039 0967

n-Undecane 01120-21-4 052 039 0202

3-Ethyl-c-2-Pentene 00816-79-5 976 038 3690






14-Diethylbenzene 00105-05-5 439 016 0705


Unknown 22 295 005 0140

Total 76987 227741 2958


continued


212

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 24872 267848


Ethanol 00064-17-5 145 7522 108992

n-Hexane 00110-54-3 113 2284 25919

Toluene 00108-88-3 393 1833 71943


3-Methylpentane 00096-14-0 169 1742 29458

2-Methyl-2-butene 00513-35-9 1420 1698 240966

n-Pentane 00109-66-0 121 1576 19144

t-2-Pentene 00646-04-8 1047 1511 158229

23-Dimethylbutane 00079-29-8 090 1202 10800


2-Methyl-1-butene 00563-46-2 638 1039 66260


Benzene 00071-43-2 069 892 6192

c-2-Pentene 00627-20-3 1028 805 82752

c-2-Butene 00590-18-1 1426 802 114334

Cyclohexane 00110-82-7 114 799 9092



2-Methylpropane 00075-28-5 118 646 7600

1-Butyne 00107-00-6 605 646 39077




2-Methylhexane 00591-76-4 109 405 4399





Propane 00074-98-6 046 326 1490

t-2-Hexene 04050-45-7 855 306 26148

n-Heptane 00142-82-5 097 305 2946



Cyclopentene 00142-29-0 669 242 16150

3-Methyl-t-2-pentene 00616-12-6 1166 237 27634


3-Methyl-c-2-pentene 00922-62-3 1252 219 27369

ortho-Xylene 00095-47-6 758 215 16278

2-Methyl-2-pentene 00625-27-4 1103 210 23172







213

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 178 1977


24-Dimethylhexane 00589-43-5 161 139 2225

n-Octane 00111-65-9 080 130 1032


Ethylbenzene 00100-41-4 296 119 3519




n-Propylbenzene 00103-65-1 196 104 2036




3-Methylheptane 00589-81-1 112 074 0827






2-Methylheptane 00592-27-8 097 047 0455


n-Nonane 00111-84-2 068 046 0315

Total 7427 20164 2715


continued


214

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 42844 461388


Ethanol 00064-17-5 145 17178 248906

Toluene 00108-88-3 393 10047 394340

n-Hexane 00110-54-3 113 8065 91515


3-Methylpentane 00096-14-0 169 4491 75939

n-Pentane 00109-66-0 121 4370 53093

2-Methyl-2-butene 00513-35-9 1420 3637 516297


23-Dimethylbutane 00079-29-8 090 2956 26564

t-2-Pentene 00646-04-8 1047 2864 299954


Benzene 00071-43-2 069 2591 17991

Cyclohexane 00110-82-7 114 2542 28906



2-Methyl-1-butene 00563-46-2 638 1881 119952

c-2-Butene 00590-18-1 1426 1857 264799

c-2-Pentene 00627-20-3 1028 1775 182543


Ethylene 00074-85-1 888 1636 145343

n-Heptane 00142-82-5 097 1536 14831



Ethane 00074-84-0 026 1261 3314



Methane 00074-82-8 001 1067 0148


2-Methylhexane 00591-76-4 109 1026 11134


Propane 00074-98-6 046 809 3698


t-2-Hexene 04050-45-7 855 760 65002

n-Octane 00111-65-9 080 636 5062


3-Methyl-t-2-pentene 00616-12-6 1166 604 70439


Cyclopentene 00142-29-0 669 555 37098

13-Butadiene 00106-99-0 1245 530 66022







215

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




2-Methyl-2-pentene 00625-27-4 1103 503 55446




ortho-Xylene 00095-47-6 758 427 32375

n-Propylbenzene 00103-65-1 196 425 8330

3-Methyl-c-2-pentene 00922-62-3 1252 419 52480




Ethylbenzene 00100-41-4 296 312 9253

22-Dimethylbutane 00075-83-2 111 306 3401


3-Methylheptane 00589-81-1 112 296 3328


2-Methylpropane 00075-28-5 118 281 3306


24-Dimethylhexane 00589-43-5 161 250 4021

2-Methylheptane 00592-27-8 097 238 2306






Unknown 1 284 172 4890




Total 18066 51521 2852


continued


216

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 316658 3410131


Ethanol 00064-17-5 145 67831 982860

n-Hexane 00110-54-3 113 32071 363900


n-Pentane 00109-66-0 121 25077 304666

2-Methyl-2-butene 00513-35-9 1420 20849 2959520

3-Methylpentane 00096-14-0 169 19682 332790

t-2-Pentene 00646-04-8 1047 17641 1847614

Toluene 00108-88-3 393 15091 592313

23-Dimethylbutane 00079-29-8 090 13982 125657

2-Methyl-1-butene 00563-46-2 638 12182 777050

c-2-Pentene 00627-20-3 1028 9542 981058



2-Methylpropane 00075-28-5 118 7882 92741


Cyclohexane 00110-82-7 114 7483 85109

c-2-Butene 00590-18-1 1426 7117 1014871

Benzene 00071-43-2 069 6155 42735


2-Methylhexane 00591-76-4 109 3304 35857


t-2-Hexene 04050-45-7 855 3007 257097



Cyclopentene 00142-29-0 669 2736 182929


3-Methyl-t-2-pentene 00616-12-6 1166 2425 282759

n-Heptane 00142-82-5 097 2420 23372

2-Methyl-2-pentene 00625-27-4 1103 2238 246882


3-Methyl-c-2-pentene 00922-62-3 1252 2008 251353


22-Dimethylbutane 00075-83-2 111 1932 21463







24-Dimethylhexane 00589-43-5 161 1135 18218






217

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





1-Butyne 00107-00-6 605 772 46679

n-Octane 00111-65-9 080 671 5344



Propane 00074-98-6 046 568 2596





2-Methylheptane 00592-27-8 097 469 4538


3-Methylheptane 00589-81-1 112 433 4866



ortho-Xylene 00095-47-6 758 325 24656




Ethylbenzene 00100-41-4 296 255 7563

n-Propylbenzene 00103-65-1 196 248 4851


n-Nonane 00111-84-2 068 175 1194

Unknown 5 240 166 3989

33-Dimethylhexane 00563-16-6 115 165 1905

n-Decane 00124-18-5 059 164 0967



c-2-Heptene 06443-92-1 708 144 10185



Unknown 16 240 132 3163



4-Methyloctane 02216-34-4 085 108 0916

n-Undecane 01120-21-4 052 106 0553

t-3-Heptene 14686-14-7 617 101 6224


Unknown 3 240 067 1615

1-Heptene 00592-76-7 429 066 2838

13-Butadiene 00106-99-0 1245 060 7523


3-Methyloctane 02216-33-3 088 059 0525

continued


218

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyloctane 02216-33-3 088 059 0525



Unknown 22 240 053 1268

1-Nonene 00124-11-8 249 047 1178

Unknown 8 240 047 1119


Indan 00496-11-7 323 033 1060

14-Diethylbenzene 00105-05-5 439 027 1190

Total 86321 207927 2409


continued


219

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5716 82823

Benzene 00071-43-2 069 818 5680

Propane 00074-98-6 046 141 0644

2-Methylpropane 00075-28-5 118 344 4046


23-Dimethylbutane 00079-29-8 090 819 7363


3-Methylpentane 00096-14-0 169 1189 20098


n-Butane 00106-97-8 108 3676 39588

Toluene 00108-88-3 393 2159 84759

n-Pentane 00109-66-0 121 1545 18766

n-Hexane 00110-54-3 113 2616 29678

2-Methyl-2-butene 00513-35-9 1420 1237 175649



t-2-Pentene 00646-04-8 1047 1196 125262


Total 3415 8597 2517





220

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 13363 193622

Benzene 00071-43-2 069 2498 17342

Methane 00074-82-8 001 1601 0222

Ethane 00074-84-0 026 1146 3013

Ethylene 00074-85-1 888 1976 175570

2-Methylpropane 00075-28-5 118 312 3675

22-Dimethylbutane 00075-83-2 111 419 4659



23-Dimethylbutane 00079-29-8 090 2658 23890

ortho-Xylene 00095-47-6 758 471 35666


3-Methylpentane 00096-14-0 169 4167 70465




Ethylbenzene 00100-41-4 296 483 14312

n-Propylbenzene 00103-65-1 196 549 10766

14-Diethylbenzene 00105-05-5 439 366 16071

n-Butane 00106-97-8 108 6249 67299

13-Butadiene 00106-99-0 1245 678 84410

1-Butyne 00107-00-6 605 843 50998





Toluene 00108-88-3 393 9872 387494

n-Pentane 00109-66-0 121 3931 47757


n-Hexane 00110-54-3 113 7372 83651

Cyclohexane 00110-82-7 114 2206 25094


n-Octane 00111-65-9 080 595 4737

n-Nonane 00111-84-2 068 180 1229

1-Dodecene 00112-41-4 156 142 2220


n-Decane 00124-18-5 059 631 3731

Cyclopentene 00142-29-0 669 568 37986

n-Heptane 00142-82-5 097 940 9074


Indan 00496-11-7 323 222 7175

2-Methyl-2-butene 00513-35-9 1420 3288 466742






221

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






33-Dimethyl-1-butene 00558-37-2 568 092 5207


33-Dimethylhexane 00563-16-6 115 164 1893

2-Methyl-1-butene 00563-46-2 638 1833 116899




24-Dimethylhexane 00589-43-5 161 689 11062

3-Methylheptane 00589-81-1 112 195 2189

c-2-Butene 00590-18-1 1426 1053 150118


2-Methylhexane 00591-76-4 109 1016 11022


2-Methylheptane 00592-27-8 097 452 4375



3-Methyl-t-2-pentene 00616-12-6 1166 664 77449



2-Methyl-2-pentene 00625-27-4 1103 641 70697

c-2-Pentene 00627-20-3 1028 1401 144091


t-2-Pentene 00646-04-8 1047 2698 282558





continued


222

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 649 81193






4-Methyloctane 02216-34-4 085 175 1482




t-2-Hexene 04050-45-7 855 875 74823


c-2-Heptene 06443-92-1 066 121 0790


Unknown 16 342 407 13925

Unknown 13 342 172 5885

Unknown 1 342 111 3781

Total 13962 48361 3464


continued


223

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 93713 1357878

Benzene 00071-43-2 069 8395 58292

Ethylene 00074-85-1 888 385 34170

Propane 00074-98-6 046 2204 10077

2-Methylpropane 00075-28-5 118 9571 112611

22-Dimethylbutane 00075-83-2 111 1771 19683



23-Dimethylbutane 00079-29-8 090 17445 156779

ortho-Xylene 00095-47-6 758 670 50741


3-Methylpentane 00096-14-0 169 25280 427457



Ethylbenzene 00100-41-4 296 381 11287

n-Propylbenzene 00103-65-1 196 340 6654

n-Butane 00106-97-8 108 45349 488366

13-Butadiene 00106-99-0 1245 098 12253

1-Butyne 00107-00-6 605 785 47505






Toluene 00108-88-3 393 27004 1059911

n-Pentane 00109-66-0 121 24220 294263


n-Hexane 00110-54-3 113 42008 476657

Cyclohexane 00110-82-7 114 10300 117149


n-Octane 00111-65-9 080 1207 9611

1-Octene 00111-66-0 314 135 4256

n-Nonane 00111-84-2 068 238 1626


1-Nonene 00124-11-8 249 109 2715

n-Decane 00124-18-5 059 372 2201

Cyclopentene 00142-29-0 669 2697 180349

n-Heptane 00142-82-5 097 3372 32566



Indan 00496-11-7 323 253 8173

2-Methyl-2-butene 00513-35-9 1420 20269 2877200







224

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





33-Dimethylhexane 00563-16-6 115 181 2080

2-Methyl-1-butene 00563-46-2 638 11748 749377




24-Dimethylhexane 00589-43-5 161 2049 32895

3-Methylheptane 00589-81-1 112 880 9892

c-2-Butene 00590-18-1 1426 7564 1078587



2-Methylhexane 00591-76-4 109 4571 49606


2-Methylheptane 00592-27-8 097 923 8932


1-Heptene 00592-76-7 429 108 4612


3-Methyl-t-2-pentene 00616-12-6 1166 3093 360613



2-Methyl-2-pentene 00625-27-4 1103 2810 309980

c-2-Pentene 00627-20-3 1028 9207 946625


t-2-Pentene 00646-04-8 1047 17071 1787966





3-Methyl-c-2-pentene 00922-62-3 1252 2468 308948







3-Methyloctane 02216-33-3 088 167 1477

4-Methyloctane 02216-34-4 085 247 2098





continued


225

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





t-2-Hexene 04050-45-7 855 3716 317667

t-2-Nonene 06434-78-2 290 075 2171

c-2-Heptene 06443-92-1 708 211 14913


t-3-Heptene 14686-14-7 617 198 12193

Unknown 5 290 413 11999

Unknown 16 290 404 11736

Unknown 13 290 190 5520

Unknown 8 290 136 3963

Unknown 3 290 085 2475

Unknown 9 290 084 2439

Total 68582 200436 2923


continued


226


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


227

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 22971 247380


n-Hexane 00110-54-3 113 2483 28180


n-Pentane 00109-66-0 121 1817 22079

3-Methylpentane 00096-14-0 169 1584 26779

2-Methyl-2-butene 00513-35-9 1420 1509 214170

t-2-Pentene 00646-04-8 1047 1269 132895

Toluene 00108-88-3 393 1202 47172

23-Dimethylbutane 00079-29-8 090 1103 9914

c-2-Butene 00590-18-1 1426 904 128849

2-Methyl-1-butene 00563-46-2 638 890 56745



c-2-Pentene 00627-20-3 1028 680 69944

2-Methylpropane 00075-28-5 118 645 7585

t-2-Butene 00624-64-6 1520 536 81392


Cyclohexane 00110-82-7 114 519 5901


Benzene 00071-43-2 069 479 3328





2-Methylhexane 00591-76-4 109 227 2467

t-2-Hexene 04050-45-7 855 211 18015

Cyclopentene 00142-29-0 669 199 13290

n-Heptane 00142-82-5 097 194 1873



3-Methyl-t-2-pentene 00616-12-6 1166 176 20565



3-Methyl-1-butene 00563-45-1 685 153 10520

2-Methyl-2-pentene 00625-27-4 1103 152 16805







22-Dimethylbutane 00075-83-2 111 119 1317





228

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 115 14408

n-Octane 00111-65-9 080 107 0853


ortho-Xylene 00095-47-6 758 102 7756








n-Propylbenzene 00103-65-1 196 046 0903


2-Methylheptane 00592-27-8 097 041 0396



Ethylbenzene 00100-41-4 296 007 0221

24-Dimethylhexane 00589-43-5 161 006 0101

Total 6278 16694 2659


continued


229

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Unknown 22 307 391 12012

Ethanol 00064-17-5 145 1321 19145

Benzene 00071-43-2 069 2139 14852

Propane 00074-98-6 046 397 1816

2-Methylpropane 00075-28-5 118 3636 42785

22-Dimethylbutane 00075-83-2 111 842 9359



23-Dimethylbutane 00079-29-8 090 2973 26719

ortho-Xylene 00095-47-6 758 337 25550


3-Methylpentane 00096-14-0 169 3756 63505


Ethylbenzene 00100-41-4 296 220 6505

n-Propylbenzene 00103-65-1 196 202 3961

n-Butane 00106-97-8 108 56598 609509






Toluene 00108-88-3 393 2903 113947

n-Pentane 00109-66-0 121 5036 61181


n-Hexane 00110-54-3 113 7233 82075

Cyclohexane 00110-82-7 114 3248 36942


n-Octane 00111-65-9 080 252 2004


Cyclopentene 00142-29-0 669 913 61061

n-Heptane 00142-82-5 097 978 9444


2-Methyl-2-butene 00513-35-9 1420 4143 588042




2-Methyl-1-butene 00563-46-2 638 4234 270054




24-Dimethylhexane 00589-43-5 161 832 13366

3-Methylheptane 00589-81-1 112 179 2017

c-2-Butene 00590-18-1 1426 7009 999462





230

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





2-Methylhexane 00591-76-4 109 1400 15189


2-Methylheptane 00592-27-8 097 175 1693



3-Methyl-t-2-pentene 00616-12-6 1166 815 95045



2-Methyl-2-pentene 00625-27-4 1103 777 85750

c-2-Pentene 00627-20-3 1028 3096 318320

t-2-Pentene 00646-04-8 1047 3554 372250





3-Methyl-c-2-pentene 00922-62-3 1252 712 89120




t-2-Hexene 04050-45-7 855 994 84993


Unknown 1 307 061 1868

Total 19657 60694 3088


continued


231

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 307727 3313949


Ethanol 00064-17-5 145 39672 574830

n-Hexane 00110-54-3 113 34020 386019


n-Pentane 00109-66-0 121 28021 340433

3-Methylpentane 00096-14-0 169 22023 372381

2-Methyl-2-butene 00513-35-9 1420 20648 2930948

t-2-Pentene 00646-04-8 1047 17405 1822913

23-Dimethylbutane 00079-29-8 090 16047 144212

Toluene 00108-88-3 393 14387 564695

2-Methyl-1-butene 00563-46-2 638 12969 827211

c-2-Butene 00590-18-1 1426 11793 1681690



c-2-Pentene 00627-20-3 1028 9515 978316

Cyclohexane 00110-82-7 114 9043 102849


Benzene 00071-43-2 069 6756 46910



2-Methylhexane 00591-76-4 109 3473 37687



3-Methyl-t-2-pentene 00616-12-6 1166 2951 344072


2-Methylpropane 00075-28-5 118 2769 32579

Cyclopentene 00142-29-0 669 2682 179344



n-Heptane 00142-82-5 097 2413 23305

2-Methyl-2-pentene 00625-27-4 1103 2292 252898

24-Dimethylhexane 00589-43-5 161 2070 33231

t-2-Hexene 04050-45-7 855 2064 176446

3-Methyl-c-2-pentene 00922-62-3 1252 2063 258275

22-Dimethylbutane 00075-83-2 111 1886 20962







232

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








Propane 00074-98-6 046 400 1829


Ethylbenzene 00100-41-4 296 342 10143

Total 85443 209022 2446


continued


233

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11488 166456

n-Butane 00106-97-8 108 7975 85883

n-Hexane 00110-54-3 113 6913 78445


n-Pentane 00109-66-0 121 4885 59344

3-Methylpentane 00096-14-0 169 4260 72030

2-Methyl-2-butene 00513-35-9 1420 4013 569617

t-2-Pentene 00646-04-8 1047 3313 346941

Toluene 00108-88-3 393 3059 120057

23-Dimethylbutane 00079-29-8 090 2976 26746

2-Methyl-1-butene 00563-46-2 638 2453 156477



c-2-Butene 00590-18-1 1426 1891 269674

c-2-Pentene 00627-20-3 1028 1824 187499

Cyclohexane 00110-82-7 114 1684 19156

t-2-Butene 00624-64-6 1520 1597 242714


2-Methylpropane 00075-28-5 118 1543 18157

Benzene 00071-43-2 069 1143 7936




2-Methylhexane 00591-76-4 109 714 7751



t-2-Hexene 04050-45-7 855 596 50989


Cyclopentene 00142-29-0 669 507 33919

3-Methyl-t-2-pentene 00616-12-6 1166 499 58164


2-Methyl-2-pentene 00625-27-4 1103 459 50603

Propane 00074-98-6 046 439 2008


n-Heptane 00142-82-5 097 430 4150

3-Methyl-c-2-pentene 00922-62-3 1252 414 51810

22-Dimethylbutane 00075-83-2 111 382 4244



24-Dimethylhexane 00589-43-5 161 288 4618







234

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 130 1038



2-Methylheptane 00592-27-8 097 099 0957



3-Methylheptane 00589-81-1 112 083 0929





t-3-Heptene 14686-14-7 617 051 3173



Unknown 5 321 043 1371


Ethylbenzene 00100-41-4 296 040 1173

33-Dimethylhexane 00563-16-6 115 036 0411

ortho-Xylene 00095-47-6 758 035 2689

n-Propylbenzene 00103-65-1 196 035 0690


Total 11846 38214 3226


continued


235

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Butane 00106-97-8 108 7470 80442

n-Hexane 00110-54-3 113 7413 84118

n-Pentane 00109-66-0 121 5151 62576


3-Methylpentane 00096-14-0 169 4543 76808

2-Methyl-2-butene 00513-35-9 1420 4232 600795

t-2-Pentene 00646-04-8 1047 3542 371010

Toluene 00108-88-3 393 3511 137807

23-Dimethylbutane 00079-29-8 090 3268 29366

c-2-Butene 00590-18-1 1426 3176 452906

1-Butyne 00107-00-6 605 2943 178046

2-Methyl-1-butene 00563-46-2 638 2779 177240


c-2-Pentene 00627-20-3 1028 2047 210481


Cyclohexane 00110-82-7 114 1938 22040


2-Methylpropane 00075-28-5 118 1317 15500

Benzene 00071-43-2 069 1229 8533



Ethanol 00064-17-5 145 810 11731



2-Methylhexane 00591-76-4 109 691 7494

t-2-Hexene 04050-45-7 855 621 53050

n-Heptane 00142-82-5 097 579 5588


Cyclopentene 00142-29-0 669 574 38396


2-Methyl-2-pentene 00625-27-4 1103 486 53633



3-Methyl-c-2-pentene 00922-62-3 1252 468 58610

3-Methyl-t-2-pentene 00616-12-6 1166 457 53286


Methane 00074-82-8 001 444 0061

22-Dimethylbutane 00075-83-2 111 431 4788








236

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 328 5262


n-Octane 00111-65-9 080 282 2250


n-Decane 00124-18-5 059 276 1632

Unknown 22 335 234 7864






2-Methylheptane 00592-27-8 097 160 1548

3-Methylheptane 00589-81-1 112 144 1615




n-Propylbenzene 00103-65-1 196 113 2208

Unknown 1 335 094 3164


Indan 00496-11-7 323 084 2722


Ethylbenzene 00100-41-4 296 067 1991

n-Undecane 01120-21-4 052 047 0244

ortho-Xylene 00095-47-6 758 043 3244

Total 13128 44311 3375


continued


237

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 23123 249015

Ethanol 00064-17-5 145 21703 314477

n-Hexane 00110-54-3 113 18050 204804


n-Pentane 00109-66-0 121 13834 168070

3-Methylpentane 00096-14-0 169 11505 194534

2-Methyl-2-butene 00513-35-9 1420 11209 1591055

t-2-Pentene 00646-04-8 1047 9469 991727

23-Dimethylbutane 00079-29-8 090 8278 74396

2-Methyl-1-butene 00563-46-2 638 6814 434644

Toluene 00108-88-3 393 6647 260916


c-2-Pentene 00627-20-3 1028 5152 529739



c-2-Butene 00590-18-1 1426 4525 645316

Cyclohexane 00110-82-7 114 4341 49370

1-Butyne 00107-00-6 605 3288 198937

2-Methylpropane 00075-28-5 118 3175 37353

Benzene 00071-43-2 069 2711 18826



2-Methylhexane 00591-76-4 109 1773 19242




t-2-Hexene 04050-45-7 855 1516 129592

Cyclopentene 00142-29-0 669 1453 97160

3-Methyl-t-2-pentene 00616-12-6 1166 1242 144819


2-Methyl-2-pentene 00625-27-4 1103 1149 126792

3-Methyl-c-2-pentene 00922-62-3 1252 1075 134519


22-Dimethylbutane 00075-83-2 111 1058 11760

n-Heptane 00142-82-5 097 1036 10005






24-Dimethylhexane 00589-43-5 161 606 9728






238

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Propane 00074-98-6 046 476 2175








n-Octane 00111-65-9 080 260 2066






2-Methylheptane 00592-27-8 097 198 1916

Ethylbenzene 00100-41-4 296 198 5852

3-Methylheptane 00589-81-1 112 177 1989


ortho-Xylene 00095-47-6 758 163 12357



Unknown 1 313 123 3845

Unknown 16 313 116 3646

n-Decane 00124-18-5 059 110 0648

n-Propylbenzene 00103-65-1 196 088 1715



Unknown 5 313 070 2205

c-2-Heptene 06443-92-1 708 065 4610

33-Dimethylhexane 00563-16-6 115 065 0749

n-Nonane 00111-84-2 068 049 0335

t-3-Heptene 14686-14-7 617 043 2680


13-Butadiene 00106-99-0 1245 042 5279

4-Methyl-t-2-pentene 00674-76-0 804 021 1722

Methane 00074-82-8 001 008 0001

Total 31093 97716 3143


continued


239

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 39458 424924


Ethanol 00064-17-5 145 10129 146760

2-Methylpropane 00075-28-5 118 5716 67259

n-Hexane 00110-54-3 113 4068 46161


n-Pentane 00109-66-0 121 3154 38314

3-Methylpentane 00096-14-0 169 2555 43201

2-Methyl-2-butene 00513-35-9 1420 2451 347976

t-2-Pentene 00646-04-8 1047 2085 218342

Toluene 00108-88-3 393 2039 80037

23-Dimethylbutane 00079-29-8 090 1831 16453

2-Methyl-1-butene 00563-46-2 638 1510 96290



c-2-Pentene 00627-20-3 1028 1123 115451

Cyclohexane 00110-82-7 114 1042 11856


c-2-Butene 00590-18-1 1426 833 118751

Benzene 00071-43-2 069 781 5423

Propane 00074-98-6 046 619 2830



22-DiMeHexane 00590-73-8 094 513 4827

2-Methylhexane 00591-76-4 109 460 4988

1-Butyne 00107-00-6 605 379 22956

t-2-Hexene 04050-45-7 855 374 31963


t-3-Heptene 14686-14-7 617 351 21645


Cyclopentene 00142-29-0 669 328 21962

3-Methyl-t-2-pentene 00616-12-6 1166 304 35469


2-Methyl-2-pentene 00625-27-4 1103 284 31321



3-Methyl-c-2-pentene 00922-62-3 1252 256 32099


22-Dimethylbutane 00075-83-2 111 222 2468









240

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 5 230 105 2411


Unknown 7 230 082 1885




Unknown 17 230 069 1596


2-Methylheptane 00592-27-8 097 066 0636



n-Propylbenzene 00103-65-1 196 046 0909



n-Nonane 00111-84-2 068 037 0255


ortho-Xylene 00095-47-6 758 027 2080

Unknown 1 230 027 0619


Ethylbenzene 00100-41-4 296 019 0574

c-2-Octene 07642-04-8 230 007 0157

Total 11484 26563 2313


continued


241

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 622650 6705400


Ethanol 00064-17-5 145 124094 1798086

n-Hexane 00110-54-3 113 67518 766114


n-Pentane 00109-66-0 121 46672 567029

3-Methylpentane 00096-14-0 169 41573 702943

2-Methyl-2-butene 00513-35-9 1420 39233 5569075

Toluene 00108-88-3 393 33167 1301796

t-2-Pentene 00646-04-8 1047 32239 3376598

23-Dimethylbutane 00079-29-8 090 29164 262093

2-Methylpropane 00075-28-5 118 23323 274414

2-Methyl-1-butene 00563-46-2 638 22688 1447167



c-2-Pentene 00627-20-3 1028 17645 1814172

Cyclohexane 00110-82-7 114 16882 192015


c-2-Butene 00590-18-1 1426 12775 1821732

Benzene 00071-43-2 069 11664 80988



2-Methylhexane 00591-76-4 109 7254 78719




t-2-Hexene 04050-45-7 855 5835 498847


Cyclopentene 00142-29-0 669 5140 343686

3-Methyl-t-2-pentene 00616-12-6 1166 4795 559045

n-Heptane 00142-82-5 097 4710 45487

2-Methyl-2-pentene 00625-27-4 1103 4548 501761


3-Methyl-c-2-pentene 00922-62-3 1252 4046 506426

22-Dimethylbutane 00075-83-2 111 3825 42506

1-Butyne 00107-00-6 605 3692 223362



Propane 00074-98-6 046 2935 13414


24-Dimethylhexane 00589-43-5 161 2703 43405







242

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 1249 9946



2-Methylheptane 00592-27-8 097 924 8935


3-Methylheptane 00589-81-1 112 747 8400




ortho-Xylene 00095-47-6 758 623 47185



Indan 00496-11-7 323 477 15440



n-Nonane 00111-84-2 068 408 2788

Ethylbenzene 00100-41-4 296 406 12023


n-Propylbenzene 00103-65-1 196 329 6454




Unknown 5 237 273 6466

1-Octene 00111-66-0 314 250 7855

33-Dimethylhexane 00563-16-6 115 231 2665

c-2-Heptene 06443-92-1 708 230 16249

n-Decane 00124-18-5 059 227 1339

t-3-Heptene 14686-14-7 617 214 13214

4-Methyloctane 02216-34-4 085 185 1572

3-Methyloctane 02216-33-3 088 159 1405

14-Diethylbenzene 00105-05-5 439 144 6326

Unknown 3 237 139 3291


1-Heptene 00592-76-7 429 128 5491

Unknown 8 237 120 2850


continued


243

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 22 237 096 2267

13-Butadiene 00106-99-0 1245 092 11436

n-Undecane 01120-21-4 052 084 0439

Unknown 16 237 055 1290

Total 169783 402961 2373


continued


244

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 421885 4543329


Ethanol 00064-17-5 145 63956 926704

n-Hexane 00110-54-3 113 42103 477731


n-Pentane 00109-66-0 121 32695 397223

3-Methylpentane 00096-14-0 169 26461 447417

2-Methyl-2-butene 00513-35-9 1420 26231 3723433

t-2-Pentene 00646-04-8 1047 21783 2281458

23-Dimethylbutane 00079-29-8 090 18965 170438

2-Methyl-1-butene 00563-46-2 638 15351 979200

Toluene 00108-88-3 393 12682 497783


c-2-Pentene 00627-20-3 1028 11853 1218653


2-Methylpropane 00075-28-5 118 9786 115144

Cyclohexane 00110-82-7 114 9561 108746


c-2-Butene 00590-18-1 1426 9027 1287178

Benzene 00071-43-2 069 6124 42524




2-Methylhexane 00591-76-4 109 3992 43324


1-Butyne 00107-00-6 605 3305 199919

Cyclopentene 00142-29-0 669 3296 220392


n-Heptane 00142-82-5 097 2810 27134

2-Methyl-2-pentene 00625-27-4 1103 2648 292135


3-Methyl-t-2-pentene 00616-12-6 1166 2537 295819


22-Dimethylbutane 00075-83-2 111 2430 27002

3-Methyl-c-2-pentene 00922-62-3 1252 2312 289438

t-2-Hexene 04050-45-7 855 2269 193990



24-Dimethylhexane 00589-43-5 161 1392 22345






Total 107832 252202 2339






245

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 6816 73402

n-Hexane 00110-54-3 113 3742 42455


Ethanol 00064-17-5 145 3387 49080

n-Pentane 00109-66-0 121 3097 37631

3-Methylpentane 00096-14-0 169 2395 40491

2-Methyl-2-butene 00513-35-9 1420 2381 337913

t-2-Pentene 00646-04-8 1047 1985 207950

23-Dimethylbutane 00079-29-8 090 1735 15592

Toluene 00108-88-3 393 1702 66802

2-Methyl-1-butene 00563-46-2 638 1455 92799



c-2-Pentene 00627-20-3 1028 1091 112168

Cyclohexane 00110-82-7 114 918 10442


c-2-Butene 00590-18-1 1426 822 117258

Benzene 00071-43-2 069 614 4266



1-Butyne 00107-00-6 605 420 25383

2-Methylpropane 00075-28-5 118 409 4811


2-Methylhexane 00591-76-4 109 397 4310


t-2-Hexene 04050-45-7 855 332 28352

Cyclopentene 00142-29-0 669 320 21388



3-Methyl-t-2-pentene 00616-12-6 1166 278 32432


2-Methyl-2-pentene 00625-27-4 1103 263 28991

n-Heptane 00142-82-5 097 261 2517

3-Methyl-c-2-pentene 00922-62-3 1252 211 26449


22-Dimethylbutane 00075-83-2 111 192 2132











246

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





24-Dimethylhexane 00589-43-5 161 128 2054

Propane 00074-98-6 046 125 0570




n-Octane 00111-65-9 080 098 0779







3-Methylheptane 00589-81-1 112 044 0498

2-Methylheptane 00592-27-8 097 044 0429


ortho-Xylene 00095-47-6 758 035 2631


n-Propylbenzene 00103-65-1 196 031 0598

Ethylbenzene 00100-41-4 296 015 0439

Total 6829 20748 3038


continued


247

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 36810 533364

n-Butane 00106-97-8 108 26480 285167

n-Hexane 00110-54-3 113 21599 245076


n-Pentane 00109-66-0 121 15798 191932

3-Methylpentane 00096-14-0 169 13417 226870

2-Methyl-2-butene 00513-35-9 1420 12566 1783699

t-2-Pentene 00646-04-8 1047 10774 1128460

Toluene 00108-88-3 393 10319 405014

23-Dimethylbutane 00079-29-8 090 9397 84455

2-Methyl-1-butene 00563-46-2 638 7705 491485



c-2-Pentene 00627-20-3 1028 5741 590268

Cyclohexane 00110-82-7 114 5656 64330


c-2-Butene 00590-18-1 1426 4360 621746

Benzene 00071-43-2 069 3722 25841

1-Butyne 00107-00-6 605 3308 200127




2-Methylhexane 00591-76-4 109 2460 26697

2-Methylpropane 00075-28-5 118 2442 28735




t-2-Hexene 04050-45-7 855 1875 160280



Cyclopentene 00142-29-0 669 1630 108972


3-Methyl-t-2-pentene 00616-12-6 1166 1439 167759

2-Methyl-2-pentene 00625-27-4 1103 1392 153551

n-Heptane 00142-82-5 097 1191 11503



3-Methyl-c-2-pentene 00922-62-3 1252 1118 139900

24-Dimethylhexane 00589-43-5 161 1101 17683



22-Dimethylbutane 00075-83-2 111 996 11062





248

Species CAS No MIR

Composite

VOC

mg

Ozone

mg









n-Octane 00111-65-9 080 676 5383



Propane 00074-98-6 046 584 2670


ortho-Xylene 00095-47-6 758 532 40274


n-Propylbenzene 00103-65-1 196 490 9599




3-Methylheptane 00589-81-1 112 429 4820

14-Diethylbenzene 00105-05-5 439 417 18308



2-Methylheptane 00592-27-8 097 275 2658

Indan 00496-11-7 323 271 8760

n-Nonane 00111-84-2 068 254 1733


n-Decane 00124-18-5 059 145 0857

Ethylbenzene 00100-41-4 296 134 3977

Total 38384 118469 3086


continued


249

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 29218 423362

n-Butane 00106-97-8 108 29007 312377

n-Hexane 00110-54-3 113 24380 276633


3-Methylpentane 00096-14-0 169 15596 263709

n-Pentane 00109-66-0 121 15520 188558

2-Methyl-2-butene 00513-35-9 1420 12658 1796850

23-Dimethylbutane 00079-29-8 090 11129 100014

t-2-Pentene 00646-04-8 1047 10500 1099738

Toluene 00108-88-3 393 10002 392585

2-Methyl-1-butene 00563-46-2 638 7489 477698



c-2-Pentene 00627-20-3 1028 5759 592056

Cyclohexane 00110-82-7 114 5744 65330

2-Methylpropane 00075-28-5 118 5722 67323

c-2-Butene 00590-18-1 1426 4971 708857


Benzene 00071-43-2 069 3956 27472

1-Butyne 00107-00-6 605 3534 213821




2-Methylhexane 00591-76-4 109 2413 26182


t-2-Hexene 04050-45-7 855 2057 175842



3-Methyl-t-2-pentene 00616-12-6 1166 1706 198941

Cyclopentene 00142-29-0 669 1599 106896

2-Methyl-2-pentene 00625-27-4 1103 1593 175741


n-Heptane 00142-82-5 097 1492 14408

3-Methyl-c-2-pentene 00922-62-3 1252 1338 167511


22-Dimethylbutane 00075-83-2 111 1217 13527



Propane 00074-98-6 046 992 4536


24-Dimethylhexane 00589-43-5 161 840 13485






250

Species CAS No MIR

Composite

VOC

mg

Ozone

mg












n-Octane 00111-65-9 080 380 3024





3-Methylheptane 00589-81-1 112 287 3222


2-Methylheptane 00592-27-8 097 259 2502

ortho-Xylene 00095-47-6 758 227 17173





Naphthalene 00091-20-3 328 172 5634

Unknown 16 302 169 5123

n-Nonane 00111-84-2 068 152 1040

n-Decane 00124-18-5 059 151 0890

Ethylbenzene 00100-41-4 296 150 4447

Indan 00496-11-7 323 132 4264

n-Propylbenzene 00103-65-1 196 120 2348

4-Methyloctane 02216-34-4 085 118 1002

Unknown 5 302 112 3400


t-3-Heptene 14686-14-7 617 104 6411




14-Diethylbenzene 00105-05-5 439 090 3928

33-Dimethylhexane 00563-16-6 115 083 0954

c-2-Heptene 06443-92-1 708 077 5453

13-Butadiene 00106-99-0 1245 052 6436

Unknown 3 302 036 1101

Total 38356 116460 3036


continued


251


E0 E10 E20




DVPE psi 701 730 849

Oxygenates--D4815

MTBE vol 000 000 000

ETBE vol 000 000 000

EtOH vol 000 954 2034

O2 wt 000 353 747





D86 Distillation

IBP degF 974 1040 1022












EP degF 3603 3600 3406



Loss vol 09 12 07


Data from CRC E-74



252








(R+M)2 885 889 890








CH Ratio 6200 6092 5835

Oxygen wt 0008 1 340 773




Oxygen wt 0008 3396 7733

C+H wt 9999 9660 9227

H wt 1389 1362 1350

C wt 8610 8298 7877

Fuel Units 6 7 4


Average D3338 Btulb 18579 18514 18491


DHA Btulb 18703 18016 17160






iii

List of Figures


1 Trap Canister 5























iv

List of Tables


















v

Acronyms
















HC Hydrocarbon























vi

Executive Summary


























Veh Evap Standards















vii






45 plus prior work)













quality modelers



















1




CRC E-77-2c

Introduction












studies





















reg Project No




2






3

Program Overview

Test Fuels





in Appendix V


Haltermann products




MIN MAX

RESULTS


5 ˚F 136

10 ˚F 144

15 ˚F 148

20 ˚F 151

25 ˚F 154

30 ˚F 157

35 ˚F 159

40 ˚F 160

45 ˚F 162

50 ˚F 185 Target only 195 164

55 ˚F 168

60 ˚F 215

65 ˚F 245

70 ˚F 258

75 ˚F 272

80 ˚F 289

85 ˚F 305

90 ˚F 315 325 316

95 ˚F 323




Loss vol Report 05















R+M2 D26992700 870 910 888



4


Haltermann products




MIN MAX

RESULTS


5 ˚F 123

10 ˚F 131

20 ˚F 140

30 ˚F 150

40 ˚F 156

50 ˚F 185 Target only 195 161

60 ˚F 165

70 ˚F 248

80 ˚F 285

90 ˚F 315 325 315

95 ˚F 322




Loss vol Report 14















R+M2 D26992700 870 910 891



5

Test Procedures





















effective


















6

















7

Drain and 40 Fill

with Test Fuel



Drain and 40 Fill

with Test Fuel


Move to SHED


Stabilize at 86degF






Transfer to RL SHED


Stabilize at 86degF



One Hour Hot Soak

Drain and 40 Fill

With Test Fuel



Move to VT-SHED





Drain and 40 Fill

with Next Test Fuel



On Test Fuel


Fuel System


9 psi E20

7 psi E20






8





vehicle




committee
















Table 3













9














yellow shading

Table 4





Fuel Tank

Veh Tank Plastic































E77-2 Program





10



















11










45 plus prior work)









12








0

10

20

30

40

50

60

70


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zer Evap

7

4

77

7

7

6

266

6

6


1

1

0

20

40

60

80

100

120

140


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

4

4

4

4

4

4

22

2

2

22

11



13








202216 See Note 1 7E10 325 00 00 --- --- ---

202216 9E0 178 136 00 --- --- ---

202216 7E0 204 380 00 --- --- ---

202216 9E20 204 00 00 --- --- ---


204 7E10 664 00 00 --- --- ---

204 9E0 338 00 00 --- --- ---

204 7E0 129 00 00 --- --- ---

204 9E20 553 00 00 --- --- ---


205 7E10 596 00 00 --- --- ---

205 9E0 195 00 00 --- --- ---

205 7E0 99 00 00 --- --- ---

205 9E20 462 00 00 --- --- ---


207 7E10 644 00 00 --- --- ---

207 9E0 325 00 00 --- --- ---

207 7E0 401 00 00 --- --- ---

207 9E20 882 00 00 --- --- ---


207L See Note 2 7E10 1468 --- 00 --- --- ---


206b 7E10 1493 00 00 3079 00 00

206b 9E0 611 00 00 1788 00 00

206b 7E0 520 00 00 1181 00 00

206c 9E20 702 00 00 1729 00 00

206c 7E20 938 00 00 2307 00 00


207c See Note 2 7E10 5235 --- 2718 --- --- ---

207c 10E10 2325 --- 10837 --- --- ---

207c 7E10 1448 --- 3727 --- --- ---


208b 7E10 272 00 00 518 00 00

208b 9E0 372 00 00 550 00 91

208b 7E0 248 00 00 645 00 00

208c 9E20 219 00 00 396 00 00

208c 7E20 184 00 00 525 00 00


209b 7E10 286 00 00 541 00 00 E-77-2bc

209b 9E0 234 00 58 295 00 00

209b 7E0 168 19 79 288 00 00

209c 9E20 420 00 00 721 00 00

209c 7E20 235 00 00 411 00 00


220b See Note 3 7E10 504 9122 15724 1820 23090 28945

220b 9E0 1023 23181 28272 18581 35298 51362

220b 7E0 627 13515 16557 2792 22736 30082


221b See Note 4 7E10 227 9307 9710 614 12823 14085

221b 9E0 556 13488 14060 948 16467 17882

221b 7E0 359 9888 9618 668 12159 13438

221c 9E20 265 6165 6734 723 10328 10971

221c 7E20 394 5312 5061 630 7462 7806

Averages


7psi E0 275 7 696 4

9psi E0 376 7 895 4

7psi E10 598 7 1188 4

10psi E10 621 7 1322 4

7psi E20 438 4 968 4

9psi E20 500 7 892 4













Tank Top

Can Inlet


14






211 7E10 94 266 00 --- --- ---

211 9E0 101 00 00 --- --- ---

211 7E0 91 00 00 --- --- ---

211 9E20 558 00 00 --- --- ---


211L See Note 7E10 481 --- 1664 --- --- ---


212 7E10 218 00 00 --- --- ---

212 9E0 32 00 00 --- --- ---

212 7E0 09 00 00 --- --- ---

212 9E20 47 00 00 --- --- ---


214 7E10 239 --- 00 --- --- ---

214 9E0 107 --- 00 --- --- ---

214 7E0 252 --- 00 --- --- ---

214 9E20 168 --- 00 --- --- ---


215 7E10 122 00 00 --- --- ---

215 9E0 85 00 00 --- --- ---

215 7E0 87 00 00 --- --- ---

215 9E20 193 00 00 --- --- ---


210b 7E10 299 00 00 519 00 232

210b 9E0 212 00 40 335 00 48

210b 7E0 187 00 00 355 00 00

210c 9E20 180 00 00 327 00 46

210c 7E20 152 00 00 340 00 00


211c See Note 7E10 4491 --- 2869 --- --- ---

211c 10E10 2247 --- 14727 --- --- ---

211c 7E10 2170 --- 7890 --- --- ---


213b 7E10 296 00 00 822 00 00

213b 9E0 147 00 00 345 00 00

213b 7E0 211 00 00 353 00 00

213c 9E20 298 00 00 751 00 00

213c 7E20 229 00 00 651 00 00

Averages


7psi E0 140 6 354 2

9psi E0 114 6 340 2

7psi E10 211 6 670 2

10psi E10 209 6 884 2

7psi E20 191 2 495 2

9psi E20 241 6 539 2





Tank Top

Can Inlet




222c 7E20 69 00 00 71 00 00 E-77-2bc

Averages


7psi E20 69 1 71 1

9psi E20 92 1 69 1



15












0

50

100

150

200

250

300

350

0 20 40 60 80 100 120 140 160

10

5 d

eg

F S

tati

c P

erm

ea

tio

n -

mg

hr



Tier 1

Tier 2

Zero Evap


16











0

50

100

150

200

250

300

350

400

450


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1


0

10

20

30

40

50

60

70

80

90

100


Av

era

ge

Pe

rme

ati

on

Ra

te -

mg

hr

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

1

1



17

Table 7


Veh Eng RL Tru-HS



202216 See Note 1 7E10 1683 192

202216 9E0 1091 254

202216 7E0 787 0

202216 9E20 543 74


204 7E10 2879 297

204 9E0 2492 443

204 7E0 2226 187

204 9E20 2720 134


205 7E10 2328 719

205 9E0 1031 10

205 7E0 671 00

205 9E20 1697 603


207 7E10 8122 1222

207 9E0 8339 58 E-77-2

207 7E0 8425 00

207 9E20 10282 00


207L See Note 2 7E10 11393 5850


206b 7E10 4367 1749

206b 9E0 3656 1025

206b 7E0 2451 688

206c 9E20 3308 858

206c 7E20 5187 1063


207c See Note 2 7E10 27694 5141

207c 10E10 9375 11140

207c 7E10 1146 6102


208b 7E10 2547 773

208b 9E0 2280 379

208b 7E0 1249 750

208c 9E20 2415 269

208c 7E20 2785 205


209b 7E10 2057 245 E-77-2bc

209b 9E0 1444 50

209b 7E0 1662 168

209c 9E20 3671 719

209c 7E20 2560 282


220b See Note 3 7E10 6979 768

220b 9E0 24170 3525

220b 7E0 34473 7071


221b 7E10 1020 405

221b 9E0 1352 290

221b 7E0 1898 425

221c 9E20 1266 95

221c 7E20 619 25

Averages

RL HS Sample

7psi E0 2655 317 7

9psi E0 2942 322 7

7psi E10 3331 773 7

10psi E10 3831 870 7

7psi E20 2788 394 4

9psi E20 3623 382 7






Tank Top

Can Inlet





18

Table 8



Veh Eng RL Tru-HS



211 7E10 563 138

211 9E0 837 153

211 7E0 1046 07

211 9E20 4106 00


211L See Note 7E10 2511 62


212 7E10 2012 00

212 9E0 1158 04

212 7E0 1845 18

212 9E20 1168 49


214 7E10 1057 329

214 9E0 967 521

214 7E0 363 33

214 9E20 1394 56


215 7E10 979 00

215 9E0 811 251

215 7E0 797 225

215 9E20 1025 0


210b 7E10 2183 618

210b 9E0 1711 198

210b 7E0 2160 490

210c 9E20 1943 540

210c 7E20 1246 759


211c See Note 7E10 3418 5894

211c 10E10 153795 19900

211c 7E10 47103 3993


213b 7E10 2431 605

213b 9E0 2031 145

213b 7E0 1351 122

213c 9E20 2572 40

213c 7E20 1869 334

Averages

RL HS Sample

7psi E0 1260 149 6

9psi E0 1253 212 6

7psi E10 1538 282 6

10psi E10 1284 201 6

7psi E20 1558 547 2

9psi E20 2035 198 6




Tank Top

Can Inlet

Veh Eng RL Tru-HS



222c 7E20 683 00 E-77-2bc


19







performance pattern



















0

200

400

600

800

1000

1200

1400

1600


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

9

6

7

2

4

6

7

6

7

6

9

6

11



20







0

500

1000

1500

2000

2500

3000

3500


Av

era

ge

Pe

rme

ati

on

-m

g

Test Fuel


Tier 1

Tier 2

Zero Evap

7

6

7

2

4

6

7

6

7

6

7

6

13801

11



21

Table 9


Veh Eng



9E0 4685 --- --- --- E-77


9E0 1504 --- --- ---


202216 See Note 1 7E10 3975 3550 3621 11146

202216 9E0 3270 2667 2746 8683

202216 7E0 2117 2208 2081 6406

202216 9E20 4685 4526 4198 13409


204 7E10 12602 11652 11652 35906

204 9E0 6283 5810 5770 17863

204 7E0 3672 2877 2936 9485

204 9E20 11034 9606 9812 30452


205 7E10 17834 17150 15239 50223

205 9E0 4995 4810 5072 14877 E-77-2

205 7E0 3830 3654 3670 11154

205 9E20 17752 16900 16802 51454


207 7E10 10865 8120 8236 27221

207 9E0 4064 3373 3080 10517

207 7E0 3975 3026 2689 9690

207 9E20 15480 13702 13605 42787


207L See Note 2 7E10 21342 --- --- 21342


206b 7E10 25826 22585 21440 69850

206b 9E0 15000 12856 12508 40364

206b 7E0 11719 9312 8903 29933

206c 9E20 19585 17878 17010 54473

206c 7E20 19439 17081 15677 52197


207c See Note 2 7E10 70847 --- --- ---

207c 10E10 105198 --- --- ---

207c 7E10 70668 --- --- ---


208b 7E10 7806 5104 4494 17405

208b 9E0 7780 5672 5194 18646

208b 7E0 4221 4194 4760 13175

208c 9E20 5065 3632 3319 12015

208c 7E20 5804 4338 3754 13895


209b 7E10 3831 3491 3235 10557

209b 9E0 3278 2505 2243 8026

209b 7E0 3541 2497 2181 8219

209c 9E20 4564 3383 3160 11107

209c 7E20 5877 3465 2704 12046


220b See Note 3 7E10 11776 16121 14831 42728

220b 9E0 67333 58848 70499 196680

220b 7E0 62187 62147 70419 194753


221b 7E10 8947 6767 6180 21894

221b 9E0 7064 5437 5383 17884

221b 7E0 6030 5031 4870 15932

221c 9E20 7508 5847 5649 19004

221c 7E20 8172 5442 4988 18602

Averages


7psi E0 4675 9 13941 7

9psi E0 6072 9 18311 7

7psi E10 12530 7 33294 7

10psi E10 13833 7 138015 7

7psi E20 9823 4 24185 4

9psi E20 11570 7 31613 7










Day 1 Total

Tank Top

Can Inlet


22

Table 10



Veh Eng



211 7E10 2438 1838 1843 6119

211 9E0 1303 1158 1006 3467

211 7E0 2071 1002 874 3947

211 9E20 2850 2218 2034 7101


211L See Note 7E10 6783 --- --- 6783


212 7E10 1848 1002 758 3608

212 9E0 1005 708 574 2287

212 7E0 1016 712 570 2298

212 9E20 1310 833 750 2893


214 7E10 5242 3974 3944 13160

214 9E0 4559 3585 11017 19161

214 7E0 4943 3190 2815 10948

214 9E20 4709 4400 7518 16627


215 7E10 2247 2317 2675 7239

215 9E0 2021 1659 1763 5443

215 7E0 2483 2941 2888 8312

215 9E20 4168 4148 4506 12822


210b 7E10 4451 3883 3591 11925

210b 9E0 4078 3774 3583 11434

210b 7E0 2706 2666 2211 7583

210c 9E20 3523 2749 2977 9250

210c 7E20 3686 2836 2711 9233


213b 7E10 6028 5777 5889 17694

213b 9E0 3463 3284 2928 9675

213b 7E0 3578 2833 2765 9175

213c 9E20 6442 5293 4606 16342

213c 7E20 5019 5384 5461 15864

Averages


7psi E0 2799 6 7044 6

9psi E0 2738 6 8578 6

7psi E10 3709 6 9957 6

10psi E10 4016 6 29741 6

7psi E20 4352 2 12549 2

9psi E20 3833 6 10839 6


Day 1 Total



Veh Eng



222c 9E20 736 514 401 1651 E-77-2bc



23

Summary of Task 45














24

















emissions











12





25






from this test13



Table 11



1996 Cavalier

Test fuel Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)
















13


increase


26




27

Table 12




Test fuel

Baseline

emissions

(gmsday)

Emissions with

0020rdquo leak

(gmsday)

Increase in

emissions

(gmsday)

2001 Dodge Caravan E10 109 213 104

2004 Toyota Camry E10 024 068 044











canister























28

















29






30









0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Pe

rme

ati

on

-m

gh

r

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10 psi E10 Fuel

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



7 psi E10 Fuel


31





0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

5 m

in R

un

nin

g A

ve

rag

e P

erm

ea

tio

n -

mg

hr

Test Time - min


No Leak Implanted

0020 Fuel Cap Leak



10psi E10 Fuel


32

Summary of Task 47


quality modelers

























This selected






14





33

Table 13

















Vehicle 206c

Type 72DHB

Test 7703


Net mass Net conc


1 Methane 00074-82-8 0000 0000 0 0

2 Ethylene 00074-85-1 1984 0066 0 0


4 Ethane 00074-84-0 0000 0000 0 0

5 Propene 00115-07-1 0000 0000 0 0

6 Propane 00074-98-6 24285 0770 0 0


8 Propyne 00074-99-7 0000 0000 0 0

9 2-Methylpropane 00075-28-5 101164 3244 2 2


11 13-Butadiene 00106-99-0 0428 0015 0 0

12 n-Butane 00106-97-8 320071 10262 6 6


14 t-2-Butene 00624-64-6 0000 0000 0 0

15 1-Butyne 00107-00-6 0000 0000 0 0

16 c-2-Butene 00590-18-1 30919 1027 1 1

17 3-Methyl-1-butene 00563-45-1 0000 0000 0 0



20 2-Methyl-1-butene 00563-46-2 62754 2084 1 1

21 n-Pentane 00109-66-0 335100 10819 6 7


23 t-2-Pentene 00646-04-8 162601 5400 3 3

24 33-Dimethyl-1-butene 00558-37-2 0000 0000 0 0

25 c-2-Pentene 00627-20-3 76704 2547 1 2

26 2-Methyl-2-butene 00513-35-9 152719 5071 3 3

72DHB

total


34




Table 14



4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


Species CAS No MIR

Composite VOC mg

Ozone mg




35




























compound)
















36





Table 15













previously thought

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


37

Acknowledgements











Steering Committee













David Lax API












38






test


39


Vehicle 206c

Reactivity Results





206c 90E20 Static (86) Perm 091509 7685 702 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 091609 7689 1729 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 091709 25795 3308 020

True HS 858 010

72 DHB 65-105 092909 7703

Day 1 19585 000

Day 2 17878 150

Day 3 17010 1000

70E20 Static (86) Perm 101309 7724 938 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 101409 7727 2307 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 102109 25806 5187 000

True HS 1063 000

72 DHB 65-105 111709 7779

Day 1 19439 000

Day 2 17081 020

Day 3 15677 080

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


40

0

20

40

60

80

100

120

140

160

180

200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7685

7 psi E20 - 7724

0

50

100

150

200

250

300

350

400

450

500

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7689

7 psi E20 - 7727


41

0

100

200

300

400

500

600

700

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25795

7 psi E20 - 25806


0

1000

2000

3000

4000

5000

6000

7000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7703

7 psi E20 - 7779


42


Vehicle 208c

Reactivity Results





208c 90E20 Static (86) Perm 092209 7695 219 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092309 7699 396 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 092409 25798 2415 000

True HS 269 000

72 DHB 65-105 100609 7713

Day 1 5065 000

Day 2 3632 000

Day 3 3319 000

70E20 Static (86) Perm 110309 7750 184 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110409 7755 525 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110509 25812 2785 000

True HS 205 000

72 DHB 65-105 120809 7817

Day 1 5804 000

Day 2 4338 000

Day 3 3754 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

Vehicle 208c


43

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7695

7 psi E20 - 7750

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7699

7 psi E20 - 7755


44

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25798

7 psi E20 - 25812


0

200

400

600

800

1000

1200

1400

1600

1800

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7713

7 psi E20 - 7817


45


Vehicle 209c

Reactivity Results





209c 90E20 Static (86) Perm 100109 7708 420 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 100209 7710 721 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 100509 25802 3671 000

True HS 719 000

72 DHB 65-105 110309 7753

Day 1 4564 020

Day 2 3383 030

Day 3 3160 090

70E20 Static (86) Perm 120209 7806 235 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 120309 7809 411 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 120409 25819 2560 000

True HS 282 000

72 DHB 65-105 011210 7856

Day 1 6107 000

Day 2 3160 010

Day 3 2581 040

72 DHB 65-105 020910 7881

Day 1 5647 000

Day 2 3771 000

Day 3 2827 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90

Vehicle 209c


46

0

10

20

30

40

50

60

70

80

90

100

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7708

7 psi E20 - 7806

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7710

7 psi E20 - 7809


47

0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25802

7 psi E20 - 25819


0

200

400

600

800

1000

1200

1400

1600

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7753

7 psi E20 - 7856



48


Vehicles 210c

Reactivity Results





210c 90E20 Static (86) Perm 092409 7701 180 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 092509 7702 327 000

Press Incr 00

Prs+Fuel Incr 46

Dynamic RL 092809 25799 1943 000

True HS 540 000

72 DHB 65-105 101309 7725

Day 1 3523 030

Day 2 2749 160

Day 3 2977 700

70E20 Static (86) Perm 110509 7758 152 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 110609 7761 340 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 110909 25813 1246 000

True HS 759 000

72 DHB 65-105 121509 7826

Day 1 3686 050

Day 2 2836 070

Day 3 2711 120

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


49

0

5

10

15

20

25

30

35

40

45

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7701

7 psi E20 - 7758

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7702

7 psi E20 - 7761


50

0

50

100

150

200

250

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25799

7 psi E20 - 25813


0

200

400

600

800

1000

1200

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7725

7 psi E20 - 7826


51


Vehicle 213c

Reactivity Results





213c 90E20 Static (86) Perm 100809 7718 374 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 102909 7746 751 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 111309 25816 2572 082

True HS 40 005

72 DHB 65-105 120109 7803

Day 1 6442 000

Day 2 5293 000

Day 3 4606 000

70E20 Static (86) Perm 121609 7828 229 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 121709 7830 651 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 121809 25821 1869 000

True HS 334 000

72 DHB 65-105 020210 7872

Day 1 5019 000

Day 2 5384 000

Day 3 5461 000

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


52

0

10

20

30

40

50

60

70

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7744

7 psi E20 - 7828

0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7746

7 psi E20 - 7830


53

0

50

100

150

200

250

300

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25816

7 psi E20 - 25821


0

200

400

600

800

1000

1200

1400

1600

1800

2000

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7803

7 psi E20 - 7872


54


Vehicle 221c

Reactivity Results





221c 90E20 Static (86) Perm 122409 7840 265 000

Press Incr 6165

Prs+Fuel Incr 6734

Static (105) Perm 122309 7838 723 000

Press Incr 10328

Prs+Fuel Incr 10971

Dynamic RL 122809 25824 1266 000

True HS 95 000

72 DHB 65-105 011910 7859

Day 1 7508 040

Day 2 5847 150

Day 3 5649 400

70E20 Static (86) Perm 020410 7875 394 000

Press Incr 5312

Prs+Fuel Incr 5061

Static (105) Perm 020510 7877 630 000

Press Incr 7462

Prs+Fuel Incr 7806

Dynamic RL 020810 25828 619 000

True HS 25 000

72 DHB 65-105 030210 7906

Day 1 8172 000

Day 2 5442 000

Day 3 4988 070

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


55

0

100

200

300

400

500

600

700

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7840

7 psi E20 - 7875

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7838

7 psi E20 - 7877


56

0

20

40

60

80

100

120

140

160

180

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25824

7 psi E20 - 25828


0

500

1000

1500

2000

2500

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7859

7 psi E20 - 7906


57


Vehicle 222c

Reactivity Results








222c 90E20 Static (86) Perm 122909 7843 92 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 123009 7847 69 000

Press Incr 00

Prs+Fuel Incr 00

Dynamic RL 011510 25827 447 000

True HS 76 000

72 DHB 65-105 020210 7871

Day 1 736 000

Day 2 514 000

Day 3 401 040

70E20 Static (86) Perm 022510 7898 69 000

Press Incr 00

Prs+Fuel Incr 00

Static (105) Perm 022610 7901 71 000

Press Incr 00

Prs+Fuel Incr 00

72 DHB 65-105 030910 7916

Day 1 655 000

Day 2 427 030

Day 3 395 030

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


58

0

2

4

6

8

10

12

14

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7843

7 psi E20 - 7898

0

2

4

6

8

10

12

14

16

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes


9 psi E20 - 7847

7 psi E20 - 7901


59

0

10

20

30

40

50

60

70

80

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


9 psi E20 - 25827

7 psi E20 -25830


0

50

100

150

200

250

300

0 10 20 30 40 50 60 70

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs


9 psi E20 - 7871

7 psi E20 - 7916


60








61


Vehicle 207c

Reactivity Results





207c 100E10 Static Perm 082709 7661 6102 000


Dynamic RL 102009 25805 9997 000


24 DHB 65-105 090309 7672

Tank Top (020)

65125 000

70E10 Static Perm 091809 7693 5235 000


Dynamic RL 100209 25801 27694 000


24 DHB 65-105 102709 7741

Tank Top (020) 70847 000

100E10 Static Perm 111809 7781 2325 000


Dynamic RL 111909 25817 9375 000


24 DHB 65-105 112409 7794

Can Inlet (020) 105198 000

70E10 Static Perm 120909 7819 1448 000


Dynamic RL 121009 25820 11146 000


24 DHB 65-105 122909 7844

Can Inlet (020) 70668 000


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


62

0

200

400

600

800

1000

1200

1400

1600

1800

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7661

7 psi E10 - 7693

0

100

200

300

400

500

600

700

800

900

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7781

7 psi E10 - 7819


63

0

500

1000

1500

2000

2500

3000

3500

4000

4500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25805

7 psi E10 - 25801


0

500

1000

1500

2000

2500

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25817

7 psi E10 - 25820



64

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7672

7 psi E10 - 7741

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7794

7 psi E10 - 7844


65


Vehicle 211c

Reactivity Results





211c 100E10 Static Perm 081209 7636 1925 000


Dynamic RL 081309 25788 8204 000


24 DHB 65-105 081909 7648

Tank Top (020) 89107 3560

70E10 Static Perm 090209 7669 4491 000


Dynamic RL 090309 25793 3418 000


24 DHB 65-105 091009 7681

Tank Top (020) 28842 000

100E10 Static Perm 101909 7732 2247 000


Dynamic RL 102909 25809 153795 000


24 DHB 65-105 111109 7769

Can Inlet (020) 115481 550

70E10 Static (86) Perm 112409 7793 2170 000


Dynamic RL 112509 25818 47103 082



Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


66

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7636

7 psi E10 - 7669

0

200

400

600

800

1000

1200

0 20 40 60 80 100 120

5 m

in R

un

nin

g A

vg

Co

rrecte

d S

HE

D M

ass -

mg

Test Time - minutes



10 psi E10 - 7732

7 psi E10 - 7793


67

0

500

1000

1500

2000

2500

3000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25788

7 psi E10 - 25793


0

2000

4000

6000

8000

10000

12000

14000

16000

0 20 40 60 80 100

5 m

in R

un

nin

g A

vg

C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes



10 psi E10 - 25809

7 psi E10 - 25818



68

0

1000

2000

3000

4000

5000

6000

7000

8000

9000

10000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7648

7 psi E10 - 7681

0

2000

4000

6000

8000

10000

12000

14000

0 5 10 15 20 25

Cu

mu

lati

ve

Pe

rme

ati

on

-m

g

Test Time - hrs



10 psi E10 - 7769

7 psi E10 - 7836


69









1 Permeation













16




70












unit time

























17





Determination


71





permeation rate






concentrations





















3 Hot Soak19


described above




19





72






4 Diurnal Test



















retest is indicated







73


EXCELrsquoscopy














0

20

40

60

80

100

120

140

160

0 20 40 60 80 100 120

SH

ED

Mass -

mg

Test Time - minutes



Test 7710

Pump Activated




Tank Pressurized

Slope = 705 mghr

Slope = 706 mghr

Slope = 761 mghr



74

























real-time records


75

















road speed






20






Loss SHED SHEDSHED


76



















period






0

10

20

30

40

50

60

70

80


Spe

ed -

mph








77






permeation












0

50

100

150

200

250

300

350

400

450

0 20 40 60 80 100 120

Co

rre

cte

d T

ota

l Fu

el C

um

ula

tiv

e P

erm

ea

tio

n -

mg

Test Time - minutes


Test 25802



2936 mg

3793 mg

3356 mg

True HS = 437 mghr


Results


78

Diurnal Test








milligrams)




two SAE papers






















12







79







and 18th





















80







81

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7685 1680 965 1620 5411 3340 60

Static E20 - 7 psi 7724 1867 1169 2183 9104 4170 77

105deg F E20 - 9 psi 7689 3492 993 3466 11867 3424 70

Static E20 - 7 psi 7727 4547 1204 5472 18251 3335 78

Dynamic E20 - 9 psi 25795 4206 1090 4582 17092 3730 69

E20 - 7 psi 25806 6151 1165 7165 26481 3696 75

DHB E20 - 9 psi 7703 54473 945 51453 172967 3362 101

Total E20 - 7 psi 7779 52197 928 48454 142309 2937 102

Vehicle 206c


82

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4093 59307

Toluene 00108-88-3 393 1167 45800


n-Pentane 00109-66-0 121 648 7871


n-Butane 00106-97-8 108 607 6533

Cyclohexane 00110-82-7 114 552 6281


Benzene 00071-43-2 069 528 3668

Propane 00074-98-6 046 424 1938

t-2-Pentene 00646-04-8 1047 399 41785

n-Heptane 00142-82-5 097 378 3649


n-Hexane 00110-54-3 113 371 4207


2-Methyl-2-butene 00513-35-9 1420 284 40369



c-2-Pentene 00627-20-3 1028 188 19331



3-Methylpentane 00096-14-0 169 170 2882

2-Methyl-1-butene 00563-46-2 638 160 10232

2-Methylpropane 00075-28-5 118 152 1783



ortho-Xylene 00095-47-6 758 133 10090

2-Methylhexane 00591-76-4 109 119 1287

n-Octane 00111-65-9 080 113 0900

t-2-Hexene 04050-45-7 855 109 9344

n-Propylbenzene 00103-65-1 196 089 1748


23-Dimethylbutane 00079-29-8 090 080 0716

Cyclopentene 00142-29-0 669 076 5114

3-Methyl-c-2-pentene 00922-62-3 1252 073 9169






3-Methyl-t-2-pentene 00616-12-6 1166 064 7473

2-Methyl-2-pentene 00625-27-4 1103 064 7008

3-Methylheptane 00589-81-1 112 061 0683

c-2-Butene 00590-18-1 1426 059 8461




83

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








2-Methylheptane 00592-27-8 097 044 0430





Ethylbenzene 00100-41-4 296 028 0831



24-Dimethylhexane 00589-43-5 161 014 0230

22-Dimethylbutane 00075-83-2 111 013 0147

n-Undecane 01120-21-4 052 003 0017

Total 1620 5411 3340


continued


84

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7732 112029

Toluene 00108-88-3 393 2826 110931


n-Pentane 00109-66-0 121 1669 20279

n-Butane 00106-97-8 108 1531 16491


Benzene 00071-43-2 069 1317 9145


n-Hexane 00110-54-3 113 984 11164

n-Heptane 00142-82-5 097 955 9227

t-2-Pentene 00646-04-8 1047 867 90854



2-Methyl-2-butene 00513-35-9 1420 764 108513

22-DiMeHexane 00590-73-8 094 648 6097

3-Me-1-Hexene 03404-61-3 427 597 25518


2-Methylpropane 00075-28-5 118 483 5687


3-Methylpentane 00096-14-0 169 423 7157

c-2-Pentene 00627-20-3 1028 398 40907

2-Methyl-1-butene 00563-46-2 638 389 24834


Propane 00074-98-6 046 301 1376

ortho-Xylene 00095-47-6 758 277 21014

n-Octane 00111-65-9 080 263 2092



t-2-Hexene 04050-45-7 855 232 19857



23-Dimethylbutane 00079-29-8 090 188 1693

2-Methylhexane 00591-76-4 109 184 1996

c-2-Butene 00590-18-1 1426 177 25239


Ethylbenzene 00100-41-4 296 169 5008


n-Propylbenzene 00103-65-1 196 159 3125

3-Methyl-t-2-pentene 00616-12-6 1166 154 17969

Cyclopentene 00142-29-0 669 132 8836

Cyclopentane 00287-92-3 224 132 2955

2-Methylheptane 00592-27-8 097 126 1223

3-Methyl-c-2-pentene 00922-62-3 1252 120 14989





85

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 112 12354



3-Methylheptane 00589-81-1 112 094 1061









24-Dimethylhexane 00589-43-5 161 057 0919

4-Methyloctane 02216-34-4 085 053 0449

22-Dimethylbutane 00075-83-2 111 051 0570


Unknown 1 340 047 1585




3-Methyloctane 02216-33-3 088 038 0337

n-Nonane 00111-84-2 068 035 0239





Total 3466 11867 3424


continued


86

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 7327 106160

Toluene 00108-88-3 393 3583 140646


n-Heptane 00142-82-5 097 1994 19258



3-Me-1-Hexene 03404-61-3 427 1676 71615

Benzene 00071-43-2 069 1585 11004

n-Pentane 00109-66-0 121 1566 19031

n-Butane 00106-97-8 108 1325 14268

n-Hexane 00110-54-3 113 1227 13926



22-DiMeHexane 00590-73-8 094 1009 9495



2-Methyl-2-butene 00513-35-9 1420 747 105970

t-2-Pentene 00646-04-8 1047 620 64956


3-Methylpentane 00096-14-0 169 504 8518


Indan 00496-11-7 323 491 15896



Unknown 16 362 481 17425


c-2-Pentene 00627-20-3 1028 439 45108


2-Methylpropane 00075-28-5 118 426 5010

n-Octane 00111-65-9 080 421 3351

2-Methyl-1-butene 00563-46-2 638 400 25494

ortho-Xylene 00095-47-6 758 365 27632

Ethylbenzene 00100-41-4 296 362 10735

2-Methylheptane 00592-27-8 097 360 3479

3-Methylheptane 00589-81-1 112 308 3463



2-Methylhexane 00591-76-4 109 256 2775


23-Dimethylbutane 00079-29-8 090 243 2181


Unknown 22 362 215 7784






87

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




n-Nonane 00111-84-2 068 189 1293


n-Propylbenzene 00103-65-1 196 187 3660

Cyclopentene 00142-29-0 669 181 12085

3-Methyl-t-2-pentene 00616-12-6 1166 177 20606

3-Methyl-c-2-pentene 00922-62-3 1252 163 20443







14-Diethylbenzene 00105-05-5 439 117 5152

c-2-Butene 00590-18-1 1426 115 16375



t-2-Hexene 04050-45-7 855 107 9180

22-Dimethylbutane 00075-83-2 111 103 1150

2-Methyl-2-pentene 00625-27-4 1103 096 10613

4-Methyl-t-2-pentene 00674-76-0 804 094 7554


n-Decane 00124-18-5 059 072 0424


Unknown 1 362 044 1580

Total 4582 17092 3730


continued


88

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 101748 1474297


n-Pentane 00109-66-0 121 33510 407124

n-Butane 00106-97-8 108 32007 344688

Toluene 00108-88-3 393 27947 1096913


Benzene 00071-43-2 069 20586 142938

n-Hexane 00110-54-3 113 18393 208697

n-Heptane 00142-82-5 097 17284 166926

t-2-Pentene 00646-04-8 1047 16260 1702998

2-Methyl-2-butene 00513-35-9 1420 15272 2167853


3-Me-1-Hexene 03404-61-3 427 10391 444084

2-Methylpropane 00075-28-5 118 10116 119030


22-DiMeHexane 00590-73-8 094 8200 77181


c-2-Pentene 00627-20-3 1028 7670 788622

3-Methylpentane 00096-14-0 169 7668 129648

2-Methyl-1-butene 00563-46-2 638 6275 400280


t-2-Hexene 04050-45-7 855 4165 356031

2-Methylhexane 00591-76-4 109 3643 39538




n-Octane 00111-65-9 080 3249 25870


c-2-Butene 00590-18-1 1426 3092 440893


23-Dimethylbutane 00079-29-8 090 2952 26532

Cyclopentene 00142-29-0 669 2922 195335

3-Methyl-t-2-pentene 00616-12-6 1166 2669 311214

Cyclopentane 00287-92-3 224 2540 56827

Propane 00074-98-6 046 2428 11101

3-Methyl-c-2-pentene 00922-62-3 1252 2277 285007


2-Methyl-2-pentene 00625-27-4 1103 1964 216725




ortho-Xylene 00095-47-6 758 1425 107970






89

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 1271 12292

Ethylbenzene 00100-41-4 296 1237 36651

22-Dimethylbutane 00075-83-2 111 1166 12955



3-Methylheptane 00589-81-1 112 1021 11484




n-Propylbenzene 00103-65-1 196 817 16017





n-Nonane 00111-84-2 068 489 3336

Unknown 1 333 488 16281



4-Methyloctane 02216-34-4 085 329 2788



3-Methyloctane 02216-33-3 088 287 2536



33-Dimethylhexane 00563-16-6 115 214 2470

Ethylene 00074-85-1 888 198 17628


1-Octene 00111-66-0 314 170 5347

c-2-Heptene 06443-92-1 708 147 10435

Unknown 8 333 147 4886


Unknown 5 333 132 4386

1-Nonene 00124-11-8 249 122 3031

Unknown 6 333 121 4021

Unknown 16 333 120 4008

Unknown 9 333 118 3924



Indan 00496-11-7 323 104 3374

Styrene 00100-42-5 166 095 1585


continued


90

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 3 333 072 2404


n-Decane 00124-18-5 059 067 0395



Unknown 14 333 055 1850

1-Heptene 00592-76-7 429 051 2194

13-Butadiene 00106-99-0 1245 043 5325


4-Methyl-t-2-pentene 00674-76-0 804 040 3190

c- amp t-4-Nonene 02198-23-4 442 037 1618


14-Diethylbenzene 00105-05-5 439 023 0997

3-Ethyl-c-2-Pentene 00816-79-5 976 022 2148


Total 51453 172967 3362


continued


91

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2884 41793


Toluene 00108-88-3 393 1217 47766

Benzene 00071-43-2 069 747 5186




n-Pentane 00109-66-0 121 684 8305

n-Butane 00106-97-8 108 611 6584



n-Hexane 00110-54-3 113 498 5652


n-Heptane 00142-82-5 097 475 4583

Propane 00074-98-6 046 468 2137



2-Methyl-2-butene 00513-35-9 1420 356 50602

t-2-Pentene 00646-04-8 1047 347 36348

ortho-Xylene 00095-47-6 758 323 24490


c-2-Butene 00590-18-1 1426 312 44524



n-Octane 00111-65-9 080 289 2300

n-Propylbenzene 00103-65-1 196 272 5339

Cyclohexane 00110-82-7 114 267 3042

2-Methylhexane 00591-76-4 109 267 2898

23-Dimethylbutane 00079-29-8 090 259 2328

Ethylbenzene 00100-41-4 296 228 6765

t-2-Hexene 04050-45-7 855 227 19378




Cyclopentane 00287-92-3 224 167 3744


3-Methyl-t-2-pentene 00616-12-6 1166 154 17932

2-Methyl-1-butene 00563-46-2 638 150 9546

3-Methyl-c-2-pentene 00922-62-3 1252 146 18246

Cyclopentene 00142-29-0 669 145 9721

2-Methylheptane 00592-27-8 097 144 1394


c-2-Pentene 00627-20-3 1028 135 13873





92

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 131 1478


3-Methylpentane 00096-14-0 169 123 2086


2-Methyl-2-pentene 00625-27-4 1103 122 13422

24-Dimethylhexane 00589-43-5 161 103 1653

Indan 00496-11-7 323 087 2810

22-Dimethylbutane 00075-83-2 111 086 0952

n-Nonane 00111-84-2 068 085 0583












14-Diethylbenzene 00105-05-5 439 045 1982


4-Methyloctane 02216-34-4 085 043 0366

4-Methyl-t-2-pentene 00674-76-0 804 041 3322

Unknown 1 412 034 1408


2-Methylpropane 00075-28-5 118 029 0340

n-Undecane 01120-21-4 052 029 0150





3-Methyloctane 02216-33-3 088 020 0174

Total 2183 9104 4170


continued


93

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10102 146374

Toluene 00108-88-3 393 4080 160133

3-Methylnonane 05911-04-6 066 3338 21890




n-Pentane 00109-66-0 121 2300 27949

Benzene 00071-43-2 069 2108 14635


n-Butane 00106-97-8 108 2075 22348

n-Heptane 00142-82-5 097 1777 17164

n-Hexane 00110-54-3 113 1565 17760


t-2-Pentene 00646-04-8 1047 1024 107279

2-Methyl-2-butene 00513-35-9 1420 1009 143288

Cyclohexane 00110-82-7 114 926 10529





3-Methylpentane 00096-14-0 169 568 9606

c-2-Pentene 00627-20-3 1028 498 51245

2-Methyl-1-butene 00563-46-2 638 495 31574



n-Octane 00111-65-9 080 454 3615



ortho-Xylene 00095-47-6 758 403 30538

2-Methylhexane 00591-76-4 109 350 3798

n-Propylbenzene 00103-65-1 196 345 6759

Ethylbenzene 00100-41-4 296 312 9251

t-2-Hexene 04050-45-7 855 307 26270

2-Methylpropane 00075-28-5 118 262 3081

Cyclopentane 00287-92-3 224 250 5589


Cyclopentene 00142-29-0 669 211 14108

Propane 00074-98-6 046 192 0880

3-Methyl-t-2-pentene 00616-12-6 1166 192 22393

n-Nonane 00111-84-2 068 186 1270


23-Dimethylbutane 00079-29-8 090 179 1613






94

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 153 19093

2-Methyl-2-pentene 00625-27-4 1103 141 15538


24-Dimethylhexane 00589-43-5 161 132 2114


2-Methylheptane 00592-27-8 097 128 1233

4-Methyloctane 02216-34-4 085 125 1064

c-2-Butene 00590-18-1 1426 121 17277



3-Methylheptane 00589-81-1 112 109 1223

Indan 00496-11-7 323 104 3361





n-Decane 00124-18-5 059 065 0385



3-Methyloctane 02216-33-3 088 061 0539

13-Diethylbenzene 00141-93-5 708 056 3990




Unknown 1 330 049 1606

22-Dimethylbutane 00075-83-2 111 049 0540


n-Undecane 01120-21-4 052 043 0226

c-2-Heptene 06443-92-1 708 038 2676



Unknown 8 330 025 0836

066 Total 5472 18251 3335


continued


95

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 10462 151590

Toluene 00108-88-3 393 5022 197121






n-Heptane 00142-82-5 097 2541 24542

n-Pentane 00109-66-0 121 2430 29518

Benzene 00071-43-2 069 2379 16519

n-Butane 00106-97-8 108 2172 23395

n-Hexane 00110-54-3 113 1979 22456



Cyclohexane 00110-82-7 114 1349 15348




2-Methyl-2-butene 00513-35-9 1420 940 133406

t-2-Pentene 00646-04-8 1047 857 89767

n-Octane 00111-65-9 080 856 6816



3-Methylpentane 00096-14-0 169 706 11929

n-Propylbenzene 00103-65-1 196 696 13630

2-Methyl-1-butene 00563-46-2 638 655 41772


Propane 00074-98-6 046 515 2355

ortho-Xylene 00095-47-6 758 506 38317

Ethylbenzene 00100-41-4 296 497 14716

3-Methylheptane 00589-81-1 112 480 5394

c-2-Pentene 00627-20-3 1028 476 48903

2-Methylhexane 00591-76-4 109 425 4611

2-Methylpropane 00075-28-5 118 404 4753

3-Methyl-c-2-pentene 00922-62-3 1252 401 50144



t-2-Hexene 04050-45-7 855 369 31567

n-Nonane 00111-84-2 068 355 2423

2-Methyl-2-pentene 00625-27-4 1103 349 38516


Cyclopentane 00287-92-3 224 322 7198

2-Methylheptane 00592-27-8 097 317 3071

c-2-Butene 00590-18-1 1426 292 41607




96

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 22 363 272 9893


3-Methyl-t-2-pentene 00616-12-6 1166 269 31312

Methane 00074-82-8 001 265 0037


3-Methyloctane 02216-33-3 088 255 2252






Cyclopentene 00142-29-0 669 208 13880

4-Methyloctane 02216-34-4 085 199 1691


23-Dimethylbutane 00079-29-8 090 188 1688

n-Decane 00124-18-5 059 168 0994


Indan 00496-11-7 323 160 5191



Unknown 18 363 147 5331

c-2-Heptene 06443-92-1 708 137 9666



24-Dimethylhexane 00589-43-5 161 123 1980




22-Dimethylbutane 00075-83-2 111 038 0418

Total 7165 26481 3696


continued


97

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 115502 1673600



n-Butane 00106-97-8 108 26699 287520

n-Pentane 00109-66-0 121 26567 322768

Toluene 00108-88-3 393 23849 936067

n-Heptane 00142-82-5 097 21212 204862

n-Hexane 00110-54-3 113 18520 210141

Benzene 00071-43-2 069 17238 119691



Cyclohexane 00110-82-7 114 9320 106002

t-2-Pentene 00646-04-8 1047 9137 956959

2-Methyl-2-butene 00513-35-9 1420 9120 1294599



3-Methylpentane 00096-14-0 169 6866 116094


c-2-Pentene 00627-20-3 1028 4504 463080


n-Octane 00111-65-9 080 4099 32639

2-Methyl-1-butene 00563-46-2 638 3977 253652


2-Methylhexane 00591-76-4 109 3789 41114



23-Dimethylbutane 00079-29-8 090 2988 26852

t-2-Hexene 04050-45-7 855 2686 229656

Cyclopentane 00287-92-3 224 2314 51777


Propane 00074-98-6 046 2085 9531



2-Methylpropane 00075-28-5 118 1854 21813

Cyclopentene 00142-29-0 669 1830 122352

3-Methyl-t-2-pentene 00616-12-6 1166 1808 210844



2-Methylheptane 00592-27-8 097 1688 16323

3-Methyl-c-2-pentene 00922-62-3 1252 1584 198290

c-2-Butene 00590-18-1 1426 1517 216368



2-Methyl-2-pentene 00625-27-4 1103 1493 164767




98

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 1325 14903

24-Dimethylhexane 00589-43-5 161 1322 21223

ortho-Xylene 00095-47-6 758 1234 93462

Ethylbenzene 00100-41-4 296 1170 34667




n-Propylbenzene 00103-65-1 196 978 19157


22-Dimethylbutane 00075-83-2 111 889 9880


n-Nonane 00111-84-2 068 734 5008




c-2-Heptene 06443-92-1 708 629 44542





4-Methyloctane 02216-34-4 085 439 3726



3-Methyloctane 02216-33-3 088 311 2751

Unknown 1 291 281 8158

33-Dimethylhexane 00563-16-6 115 274 3158


Ethylene 00074-85-1 888 238 21141

1-Octene 00111-66-0 314 226 7093

Unknown 5 291 226 6565




1-Butyne 00107-00-6 605 214 12957


Unknown 8 291 191 5566


1-Nonene 00124-11-8 249 155 3876

Indan 00496-11-7 323 134 4328




continued


99

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 291 093 2704

t-4-Octene 14850-23-8 469 088 4141



n-Decane 00124-18-5 059 072 0424


Unknown 6 291 063 1842

t-3-Heptene 14686-14-7 617 058 3603

Unknown 3 291 050 1460

13-Butadiene 00106-99-0 1245 050 6187

c- amp t-4-Nonene 02198-23-4 442 039 1719


1-Heptene 00592-76-7 429 035 1513

n-Undecane 01120-21-4 052 025 0130


Total 48454 142309 2937



100

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7695 399 653 260 956 3672 41

Static E20 - 7 psi 7750 381 1815 691 2138 3094 57

105deg F E20 - 9 psi 7699 808 1190 962 2919 3034 56

Static E20 - 7 psi 7755 941 802 755 2232 2957 29

Dynamic E20 - 9 psi 25798 2421 908 2199 9732 4426 71

E20 - 7 psi 25812 2300 724 1666 7311 4389 48

DHB E20 - 9 psi 7713 12015 1080 12981 36292 2796 85

Total E20 - 7 psi 7817 13895 937 13019 32482 2495 85

- No Ethanol

Vehicle 208c


101

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


3-Me-1-Hexene 03404-61-3 427 193 8262

Toluene 00108-88-3 393 158 6219


n-Heptane 00142-82-5 097 146 1414


22-DiMeHexane 00590-73-8 094 136 1277

n-Pentane 00109-66-0 121 131 1597



Benzene 00071-43-2 069 109 0753

n-Butane 00106-97-8 108 101 1090

n-Octane 00111-65-9 080 058 0466

n-Hexane 00110-54-3 113 054 0613

2-Methylheptane 00592-27-8 097 048 0466

2-Methylpropane 00075-28-5 118 047 0553


n-Nonane 00111-84-2 068 041 0277

n-Propylbenzene 00103-65-1 196 033 0656

2-Methyl-2-pentene 00625-27-4 1103 032 3544

ortho-Xylene 00095-47-6 758 030 2297


3-Methyl-c-2-pentene 00922-62-3 1252 026 3231



Cyclopentene 00142-29-0 669 022 1454



t-2-Hexene 04050-45-7 855 018 1569

3-Methyl-t-2-pentene 00616-12-6 1166 018 2140

Ethylbenzene 00100-41-4 296 018 0544

t-2-Pentene 00646-04-8 1047 018 1912

3-Methylpentane 00096-14-0 169 018 0298



2-Methylhexane 00591-76-4 109 015 0159

24-Dimethylhexane 00589-43-5 161 013 0203

2-Methyl-2-butene 00513-35-9 1420 011 1589

c-2-Butene 00590-18-1 1426 009 1344



Total 260 956 3672




102

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1745 25291


n-Heptane 00142-82-5 097 769 7424


Benzene 00071-43-2 069 594 4125

Toluene 00108-88-3 393 461 18075

n-Pentane 00109-66-0 121 365 4438


n-Hexane 00110-54-3 113 287 3251

n-Butane 00106-97-8 108 273 2945



22-DiMeHexane 00590-73-8 094 172 1616

2-Methyl-2-butene 00513-35-9 1420 170 24078

3-Me-1-Hexene 03404-61-3 427 156 6681


t-2-Pentene 00646-04-8 1047 139 14606



Cyclopentane 00287-92-3 224 118 2649

n-Octane 00111-65-9 080 108 0863

3-Methylpentane 00096-14-0 169 108 1823


2-Methylpropane 00075-28-5 118 094 1110



c-2-Pentene 00627-20-3 1028 085 8778

3-Methylheptane 00589-81-1 112 085 0956

n-Nonane 00111-84-2 068 084 0576


3-Methyl-t-2-pentene 00616-12-6 1166 078 9114


2-Methyl-1-butene 00563-46-2 638 056 3594

c-2-Butene 00590-18-1 1426 055 7872

ortho-Xylene 00095-47-6 758 051 3872



t-2-Hexene 04050-45-7 855 043 3697


Ethylbenzene 00100-41-4 296 036 1067


Cyclopentene 00142-29-0 669 029 1922






103

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 023 2569


3-Methyl-c-2-pentene 00922-62-3 1252 022 2706



22-Dimethylbutane 00075-83-2 111 010 0117




2-Methylhexane 00591-76-4 109 003 0037



Total 962 2919 3034


continued


104

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 964 37835

t-3-Heptene 14686-14-7 617 854 52708


n-Pentane 00109-66-0 121 709 8608

Benzene 00071-43-2 069 649 4509




3-Me-1-Hexene 03404-61-3 427 425 18160


22-DiMeHexane 00590-73-8 094 403 3797





4-Methyl-t-2-pentene 00674-76-0 804 349 28047

n-Butane 00106-97-8 108 347 3739

n-Hexane 00110-54-3 113 346 3922

n-Propylbenzene 00103-65-1 196 335 6568

n-Octane 00111-65-9 080 327 2601

3-Methylpentane 00096-14-0 169 304 5148


2-Methylhexane 00591-76-4 109 290 3146

n-Butylbenzene 00104-51-8 229 279 6386


Indan 00496-11-7 323 272 8810

t-2-Pentene 00646-04-8 1047 264 27657

Ethylbenzene 00100-41-4 296 257 7618





2-Methyl-2-butene 00513-35-9 1420 223 31617


2-Methyl-1-butene 00563-46-2 638 193 12303


n-Nonane 00111-84-2 068 187 1276


c-2-Pentene 00627-20-3 1028 156 16054

t-2-Hexene 04050-45-7 855 154 13191

ortho-Xylene 00095-47-6 758 148 11239




105

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



13-Butadiene 00106-99-0 1245 145 18006



2-Methylheptane 00592-27-8 097 134 1296


23-Dimethylbutane 00079-29-8 090 128 1152

4-Methyloctane 02216-34-4 085 127 1079

Unknown 5 422 113 4773





2-Methylpropane 00075-28-5 118 097 1147

Unknown 9 422 092 3896

3-Methyl-t-2-pentene 00616-12-6 1166 076 8865

3-Methyl-c-2-pentene 00922-62-3 1252 074 9238


Cyclopentene 00142-29-0 669 065 4325


14-Diethylbenzene 00105-05-5 439 059 2575

24-Dimethylhexane 00589-43-5 161 052 0828

3-Methyloctane 02216-33-3 088 048 0425





22-Dimethylbutane 00075-83-2 111 009 0104

Total 2199 9732 4426


continued


106

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 40269 583488


n-Pentane 00109-66-0 121 6604 80237

n-Butane 00106-97-8 108 5757 61995


n-Heptane 00142-82-5 097 5013 48416

n-Hexane 00110-54-3 113 4359 49459

Toluene 00108-88-3 393 4128 162007


Benzene 00071-43-2 069 3151 21876


2-Methyl-2-butene 00513-35-9 1420 2458 348891

t-2-Pentene 00646-04-8 1047 2391 250449

2-Methylpropane 00075-28-5 118 2367 27847

Cyclohexane 00110-82-7 114 2317 26356


3-Methylpentane 00096-14-0 169 1942 32835



n-Octane 00111-65-9 080 1226 9760

c-2-Pentene 00627-20-3 1028 1186 121926


2-Methyl-1-butene 00563-46-2 638 1163 74158

2-Methylhexane 00591-76-4 109 1119 12144


t-2-Hexene 04050-45-7 855 759 64866

23-Dimethylbutane 00079-29-8 090 700 6289



2-Methylheptane 00592-27-8 097 569 5503

c-2-Butene 00590-18-1 1426 562 80095

Propane 00074-98-6 046 552 2525

Cyclopentane 00287-92-3 224 552 12353


3-Methyl-t-2-pentene 00616-12-6 1166 518 60429

3-Methylheptane 00589-81-1 112 482 5422

Cyclopentene 00142-29-0 669 479 32026

3-Methyl-c-2-pentene 00922-62-3 1252 469 58697



2-Methyl-2-pentene 00625-27-4 1103 422 46577







107

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Nonane 00111-84-2 068 349 2384

1-Butyne 00107-00-6 605 349 21088





24-Dimethylhexane 00589-43-5 161 299 4801

22-Dimethylbutane 00075-83-2 111 291 3238


ortho-Xylene 00095-47-6 758 271 20538

n-Propylbenzene 00103-65-1 196 263 5151

Ethylbenzene 00100-41-4 296 238 7052



4-Methyloctane 02216-34-4 085 223 1894




3-Methyloctane 02216-33-3 088 154 1363




33-Dimethylhexane 00563-16-6 115 109 1252

Unknown 8 276 087 2398



1-Octene 00111-66-0 314 081 2559


continued


108

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 9 276 066 1835

Unknown 1 276 065 1794





n-Decane 00124-18-5 059 049 0289

Unknown 5 276 045 1243

c-2-Heptene 06443-92-1 708 040 2835



1-Nonene 00124-11-8 249 019 0476

Total 12981 36292 2796


continued


109

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1522 22047

Toluene 00108-88-3 393 372 14601




n-Butane 00106-97-8 108 252 2718

n-Pentane 00109-66-0 121 229 2778


n-Undecane 01120-21-4 052 208 1088

n-Decane 00124-18-5 059 202 1193

n-Heptane 00142-82-5 097 197 1903

n-Hexane 00110-54-3 113 145 1643

1-Butyne 00107-00-6 605 142 8563

Benzene 00071-43-2 069 136 0943

Cyclohexane 00110-82-7 114 117 1336







3-Methylpentane 00096-14-0 169 077 1305


2-Methylpropane 00075-28-5 118 075 0882

n-Nonane 00111-84-2 068 072 0492

n-Propylbenzene 00103-65-1 196 070 1366



2-Methyl-2-butene 00513-35-9 1420 068 9604

23-Dimethylbutane 00079-29-8 090 061 0546

n-Octane 00111-65-9 080 060 0475


Cyclopentene 00142-29-0 669 054 3587



t-2-Pentene 00646-04-8 1047 046 4844

ortho-Xylene 00095-47-6 758 044 3308

3-Methyl-c-2-pentene 00922-62-3 1252 043 5429

2-Methylheptane 00592-27-8 097 042 0408

3-Methyl-t-2-pentene 00616-12-6 1166 042 4901


2-Methyl-2-pentene 00625-27-4 1103 039 4343


3-Methylheptane 00589-81-1 112 033 0371




110

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 030 3052


Unknown 22 305 027 0835

2-Methylhexane 00591-76-4 109 027 0296


Ethylbenzene 00100-41-4 296 024 0697

24-Dimethylhexane 00589-43-5 161 022 0354




22-Dimethylbutane 00075-83-2 111 011 0126

2-Methyl-1-butene 00563-46-2 638 006 0396


Total 691 2138 3094


continued


111

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1871 27109


Toluene 00108-88-3 393 522 20484


n-Heptane 00142-82-5 097 365 3521

n-Pentane 00109-66-0 121 351 4259

n-Butane 00106-97-8 108 298 3214







Benzene 00071-43-2 069 198 1372

n-Hexane 00110-54-3 113 173 1961



t-2-Pentene 00646-04-8 1047 126 13202

n-Octane 00111-65-9 080 116 0924

2-Methyl-2-butene 00513-35-9 1420 115 16378

Cyclohexane 00110-82-7 114 108 1232


3-Methylpentane 00096-14-0 169 101 1707

2-Methylpropane 00075-28-5 118 075 0884

2-Methylhexane 00591-76-4 109 059 0643

ortho-Xylene 00095-47-6 758 054 4058

2-Methyl-1-butene 00563-46-2 638 053 3361

c-2-Pentene 00627-20-3 1028 043 4388


066 Total 755 2232 2957




112

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Toluene 00108-88-3 393 968 37976


n-Pentane 00109-66-0 121 522 6345

n-Heptane 00142-82-5 097 514 4964

Benzene 00071-43-2 069 512 3553





n-Propylbenzene 00103-65-1 196 434 8506




n-Octane 00111-65-9 080 341 2712

n-Hexane 00110-54-3 113 275 3123

n-Nonane 00111-84-2 068 271 1848

13-Butadiene 00106-99-0 1245 247 30791




2-Methylheptane 00592-27-8 097 231 2232

2-Methyl-1-butene 00563-46-2 638 227 14471

c-2-Pentene 00627-20-3 1028 221 22769

n-Butane 00106-97-8 108 194 2085

24-Dimethylhexane 00589-43-5 161 183 2939


Cyclohexane 00110-82-7 114 162 1841


23-Dimethylbutane 00079-29-8 090 150 1345

n-Decane 00124-18-5 059 136 0802


3-Methylpentane 00096-14-0 169 131 2214

2-Methylhexane 00591-76-4 109 104 1128


t-2-Pentene 00646-04-8 1047 070 7355

22-Dimethylbutane 00075-83-2 111 066 0737

3-Methylheptane 00589-81-1 112 066 0741

2-Methyl-2-butene 00513-35-9 1420 059 8434



Ethylbenzene 00100-41-4 296 053 1559




113

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylpropane 00075-28-5 118 022 0260

Total 1666 7311 4389

continued


114

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 42028 608972



n-Heptane 00142-82-5 097 6080 58717

n-Pentane 00109-66-0 121 5160 62696

n-Butane 00106-97-8 108 4881 52569

Toluene 00108-88-3 393 4149 162857

n-Hexane 00110-54-3 113 4113 46667



Benzene 00071-43-2 069 2652 18416


Cyclohexane 00110-82-7 114 2309 26264


3-Methylpentane 00096-14-0 169 1806 30534

n-Octane 00111-65-9 080 1490 11863

2-Methyl-2-butene 00513-35-9 1420 1455 206582

t-2-Pentene 00646-04-8 1047 1430 149744



2-Methylhexane 00591-76-4 109 1276 13844


23-Dimethylbutane 00079-29-8 090 950 8542

2-Methylpropane 00075-28-5 118 905 10645



2-Methyl-1-butene 00563-46-2 638 764 48753

2-Methylheptane 00592-27-8 097 757 7321


c-2-Pentene 00627-20-3 1028 717 73741


3-Methylheptane 00589-81-1 112 591 6648


24-Dimethylhexane 00589-43-5 161 559 8975

t-2-Hexene 04050-45-7 855 500 42751



c-2-Heptene 06443-92-1 708 474 33563



Cyclopentane 00287-92-3 224 382 8551

n-Nonane 00111-84-2 068 368 2512

3-Methyl-c-2-pentene 00922-62-3 1252 366 45829





115

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methyl-t-2-pentene 00616-12-6 1166 347 40413


1-Butyne 00107-00-6 605 314 18981

c-2-Butene 00590-18-1 1426 313 44686


2-Methyl-2-pentene 00625-27-4 1103 298 32930




4-Methyloctane 02216-34-4 085 268 2273

ortho-Xylene 00095-47-6 758 263 19906



Cyclopentene 00142-29-0 669 246 16475

22-Dimethylbutane 00075-83-2 111 235 2609

Propane 00074-98-6 046 234 1071

3-Methyloctane 02216-33-3 088 226 1997

Ethylbenzene 00100-41-4 296 225 6680



n-Propylbenzene 00103-65-1 196 212 4148



33-Dimethylhexane 00563-16-6 115 179 2055





Unknown 8 246 139 3407



continued


116

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



1-Octene 00111-66-0 314 105 3295

Unknown 9 246 086 2117

Unknown 5 246 083 2051





n-Decane 00124-18-5 059 045 0268

1-Nonene 00124-11-8 249 044 1105

Unknown 1 246 032 0778

Total 13019 32482 2495


continued


117

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7708 945 1096 1036 3549 3427 62

Static E20 - 7 psi 7806 523 1059 554 1818 3284 54

105deg F E20 - 9 psi 7710 1510 803 1212 3351 2765 65

Static E20 - 7 psi 7809 873 901 786 2397 3050 60

Dynamic E20 - 9 psi 25802 3793 979 3712 13832 3726 62

E20 - 7 psi 25819 2518 426 1074 5493 5117 41 No Ethanol

DHB E20 - 9 psi 7753 11107 877 9741 24571 2522 88

Total E20 - 7 psi 7856 11847 937 11102 28561 2573 89

E20 - 7 psi 7881 12246 989 12111 30488 2517 90 Repeat

Vehicle 209c


118

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 608 23884

n-Pentane 00109-66-0 121 532 6465

n-Butane 00106-97-8 108 526 5664




n-Hexane 00110-54-3 113 360 4086

Cyclohexane 00110-82-7 114 358 4074

n-Heptane 00142-82-5 097 324 3130


Benzene 00071-43-2 069 227 1573


2-Methyl-2-butene 00513-35-9 1420 214 30383



t-2-Pentene 00646-04-8 1047 199 20808

3-Methylpentane 00096-14-0 169 189 3189



23-Dimethylbutane 00079-29-8 090 134 1208

Ethanol 00064-17-5 145 131 1905


2-Methyl-1-butene 00563-46-2 638 118 7543

Propane 00074-98-6 046 116 0530

2-Methylpropane 00075-28-5 118 112 1317

c-2-Pentene 00627-20-3 1028 110 11307


2-Methylhexane 00591-76-4 109 097 1052

n-Nonane 00111-84-2 068 091 0619

c-2-Butene 00590-18-1 1426 083 11886



n-Propylbenzene 00103-65-1 196 076 1487


n-Octane 00111-65-9 080 066 0525

3-Methylheptane 00589-81-1 112 064 0714


ortho-Xylene 00095-47-6 758 062 4660

t-2-Hexene 04050-45-7 855 057 4874


2-Methyl-2-pentene 00625-27-4 1103 055 6035





119

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 053 0852

3-Methyl-c-2-pentene 00922-62-3 1252 051 6343



3-Methyl-t-2-pentene 00616-12-6 1166 046 5371

Cyclopentene 00142-29-0 669 043 2842



22-Dimethylbutane 00075-83-2 111 035 0390


4-Methyloctane 02216-34-4 085 034 0288




2-Methylheptane 00592-27-8 097 024 0234

Unknown 18 334 023 0782


Indan 00496-11-7 323 020 0636

Ethylbenzene 00100-41-4 296 019 0563

Total 1036 3549 3427


continued


120

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2428 35179


Toluene 00108-88-3 393 689 27059

Cyclohexane 00110-82-7 114 575 6535

n-Pentane 00109-66-0 121 549 6667

n-Butane 00106-97-8 108 465 5009

n-Hexane 00110-54-3 113 438 4971



22-DiMeHexane 00590-73-8 094 335 3152

n-Heptane 00142-82-5 097 311 3006


3-Methylpentane 00096-14-0 169 242 4093

Benzene 00071-43-2 069 227 1575


2-Methyl-2-butene 00513-35-9 1420 197 27914




23-Dimethylbutane 00079-29-8 090 166 1491

2-Methylpropane 00075-28-5 118 149 1756

2-Methylhexane 00591-76-4 109 147 1599

t-2-Pentene 00646-04-8 1047 146 15283




c-2-Pentene 00627-20-3 1028 097 10021

n-Octane 00111-65-9 080 097 0776

Propane 00074-98-6 046 096 0439

n-Nonane 00111-84-2 068 088 0601

2-Methyl-1-butene 00563-46-2 638 082 5199

Indan 00496-11-7 323 078 2534


3-Methylheptane 00589-81-1 112 076 0853


4-Methyloctane 02216-34-4 085 065 0551

ortho-Xylene 00095-47-6 758 065 4918

Unknown 16 271 065 1756





n-Propylbenzene 00103-65-1 196 053 1040

t-2-Hexene 04050-45-7 855 052 4414




121

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 038 0607

Cyclopentene 00142-29-0 669 038 2517


22-Dimethylbutane 00075-83-2 111 037 0408

3-Methyl-t-2-pentene 00616-12-6 1166 036 4207

Ethylbenzene 00100-41-4 296 036 1052




2-Methyl-2-pentene 00625-27-4 1103 033 3675

2-Methylheptane 00592-27-8 097 033 0322

c-2-Butene 00590-18-1 1426 031 4470

3-Methyl-c-2-pentene 00922-62-3 1252 024 3058





Total 1212 3351 2765


continued


122

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 3555 51515

Toluene 00108-88-3 393 2025 79500


3-Me-1-Hexene 03404-61-3 427 1750 74813

n-Heptane 00142-82-5 097 1537 14840



n-Pentane 00109-66-0 121 1178 14313

n-Butane 00106-97-8 108 1174 12645

n-Hexane 00110-54-3 113 1158 13138



22-DiMeHexane 00590-73-8 094 1026 9657





Benzene 00071-43-2 069 791 5491

Propane 00074-98-6 046 552 2523

3-Methylpentane 00096-14-0 169 535 9054



2-Methyl-2-butene 00513-35-9 1420 457 64841

Ethylene 00074-85-1 888 454 40295


2-Methyl-1-butene 00563-46-2 638 448 28551

t-2-Pentene 00646-04-8 1047 448 46880

n-Octane 00111-65-9 080 421 3348


2-Methylpropane 00075-28-5 118 413 4861


c-2-Pentene 00627-20-3 1028 349 35872

n-Propylbenzene 00103-65-1 196 346 6786


2-Methylhexane 00591-76-4 109 331 3591

23-Dimethylbutane 00079-29-8 090 320 2879


ortho-Xylene 00095-47-6 758 312 23613

24-Dimethylhexane 00589-43-5 161 278 4460


2-Methylheptane 00592-27-8 097 265 2568

Ethylbenzene 00100-41-4 296 262 7748

t-2-Hexene 04050-45-7 855 257 21978




123

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







3-Methylheptane 00589-81-1 112 216 2430

2-Methyl-2-pentene 00625-27-4 1103 212 23431

3-Methyl-t-2-pentene 00616-12-6 1166 199 23199

n-Nonane 00111-84-2 068 189 1292

3-Methyl-c-2-pentene 00922-62-3 1252 188 23507




Cyclopentene 00142-29-0 669 120 8051

c-2-Butene 00590-18-1 1426 096 13745



22-Dimethylbutane 00075-83-2 111 085 0940

13-Butadiene 00106-99-0 1245 070 8700


Total 3712 13832 3726


continued


124

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 41433 600356


n-Butane 00106-97-8 108 4042 43529

n-Pentane 00109-66-0 121 3798 46147


Toluene 00108-88-3 393 2636 103457

n-Heptane 00142-82-5 097 2629 25385

n-Hexane 00110-54-3 113 2488 28227


Cyclohexane 00110-82-7 114 1943 22094

Benzene 00071-43-2 069 1923 13349


t-2-Pentene 00646-04-8 1047 1424 149160

2-Methyl-2-butene 00513-35-9 1420 1420 201503


3-Methylpentane 00096-14-0 169 1237 20924


2-Methylpropane 00075-28-5 118 1107 13030

2-Methyl-1-butene 00563-46-2 638 764 48704

c-2-Pentene 00627-20-3 1028 735 75531



n-Octane 00111-65-9 080 674 5365

2-Methylhexane 00591-76-4 109 654 7101



Propane 00074-98-6 046 473 2162

23-Dimethylbutane 00079-29-8 090 451 4053

t-2-Hexene 04050-45-7 855 451 38530

2-Methylheptane 00592-27-8 097 363 3510

Cyclopentane 00287-92-3 224 346 7753

3-Methyl-t-2-pentene 00616-12-6 1166 328 38296


Cyclopentene 00142-29-0 669 296 19762

3-Methylheptane 00589-81-1 112 290 3262

3-Methyl-c-2-pentene 00922-62-3 1252 283 35472

2-Methyl-2-pentene 00625-27-4 1103 279 30766



24-Dimethylhexane 00589-43-5 161 259 4160


22-Dimethylbutane 00075-83-2 111 253 2816





125

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





c-2-Butene 00590-18-1 1426 238 33979





1-Butyne 00107-00-6 605 187 11337



n-Propylbenzene 00103-65-1 196 154 3020

Ethylbenzene 00100-41-4 296 152 4489

4-Methyloctane 02216-34-4 085 149 1267


3-Methyloctane 02216-33-3 088 118 1048


33-Dimethylhexane 00563-16-6 115 113 1300


n-Nonane 00111-84-2 068 112 0762



Unknown 22 249 085 2128


1-Octene 00111-66-0 314 084 2649



Unknown 8 249 077 1927


Unknown 5 249 068 1695

Unknown 6 249 061 1521





4-Methyl-t-2-pentene 00674-76-0 804 055 4393

Unknown 1 249 054 1355

continued


126

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 9 249 048 1203



ortho-Xylene 00095-47-6 758 035 2639



1-Nonene 00124-11-8 249 031 0771

c-2-Heptene 06443-92-1 708 030 2119


Total 9741 24571 2522


continued


127

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2031 29422



Toluene 00108-88-3 393 213 8360

n-Heptane 00142-82-5 097 164 1581

22-DiMeHexane 00590-73-8 094 162 1525




n-Butane 00106-97-8 108 113 1221


Benzene 00071-43-2 069 090 0625

n-Octane 00111-65-9 080 087 0696


n-Pentane 00109-66-0 121 083 1008

Cyclohexane 00110-82-7 114 078 0887


n-Nonane 00111-84-2 068 068 0466




n-Hexane 00110-54-3 113 061 0693

n-Propylbenzene 00103-65-1 196 060 1176

4-Methyloctane 02216-34-4 085 059 0501


2-Methyl-1-butene 00563-46-2 638 056 3568


t-2-Pentene 00646-04-8 1047 051 5304

3-Methyl-c-2-pentene 00922-62-3 1252 048 6030


ortho-Xylene 00095-47-6 758 044 3371


n-Decane 00124-18-5 059 042 0246

1-Butyne 00107-00-6 605 038 2301


2-Methyl-2-butene 00513-35-9 1420 035 4931

23-Dimethylbutane 00079-29-8 090 031 0274



c-2-Pentene 00627-20-3 1028 026 2664

t-2-Hexene 04050-45-7 855 026 2206

2-Methylhexane 00591-76-4 109 026 0279

Ethylbenzene 00100-41-4 296 024 0713




128

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-t-2-pentene 00616-12-6 1166 021 2407

2-Methylheptane 00592-27-8 097 020 0198

3-Methylpentane 00096-14-0 169 020 0337


Cyclopentene 00142-29-0 669 016 1071


3-Methylheptane 00589-81-1 112 010 0108



n-Undecane 01120-21-4 052 003 0017

Total 554 1818 3284


continued


129

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2491 36089


Toluene 00108-88-3 393 351 13795


n-Heptane 00142-82-5 097 246 2378




n-Pentane 00109-66-0 121 181 2205

n-Butane 00106-97-8 108 173 1860

Benzene 00071-43-2 069 159 1107


n-Hexane 00110-54-3 113 128 1449

Propane 00074-98-6 046 123 0563



Cyclohexane 00110-82-7 114 117 1330



3-Methylheptane 00589-81-1 112 081 0911

n-Octane 00111-65-9 080 076 0603

3-Methylpentane 00096-14-0 169 075 1266


t-2-Pentene 00646-04-8 1047 069 7273


n-Propylbenzene 00103-65-1 196 066 1300

2-Methyl-2-pentene 00625-27-4 1103 066 7278


2-Methyl-2-butene 00513-35-9 1420 058 8241

23-Dimethylbutane 00079-29-8 090 056 0505

Ethylbenzene 00100-41-4 296 053 1576

c-2-Heptene 06443-92-1 708 053 3746

4-Methyloctane 02216-34-4 085 053 0449



Unknown 22 299 050 1489


2-Methyl-1-butene 00563-46-2 638 046 2905

2-Methylheptane 00592-27-8 097 045 0434

n-Nonane 00111-84-2 068 044 0300


24-Dimethylhexane 00589-43-5 161 042 0669

2-Methylhexane 00591-76-4 109 039 0424




130

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Pentene 00627-20-3 1028 039 3979

t-2-Hexene 04050-45-7 855 038 3270


3-Methyl-t-2-pentene 00616-12-6 1166 036 4201

ortho-Xylene 00095-47-6 758 034 2597

c-2-Butene 00590-18-1 1426 034 4788



3-Methyl-c-2-pentene 00922-62-3 1252 030 3747




Cyclopentene 00142-29-0 669 022 1479




22-Dimethylbutane 00075-83-2 111 012 0136

066 Total 786 2397 3050


continued


131

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-DiMeHexane 00590-73-8 094 551 5189

Cyclohexane 00110-82-7 114 550 6259

n-Heptane 00142-82-5 097 503 4856




n-Nonane 00111-84-2 068 399 2724

Ethylene 00074-85-1 888 383 33991


n-Octane 00111-65-9 080 331 2635



Benzene 00071-43-2 069 241 1673

Unknown 22 492 232 11393



3-Methyl-t-2-pentene 00616-12-6 1166 194 22609


Cyclopentene 00142-29-0 669 153 10213




3-Methyl-c-2-pentene 00922-62-3 1252 115 14432

n-Propylbenzene 00103-65-1 196 114 2239

2-Methylheptane 00592-27-8 097 110 1067



Toluene 00108-88-3 393 089 3513

Naphthalene 00091-20-3 328 087 2863

t-2-Hexene 04050-45-7 855 084 7168


3-Methylpentane 00096-14-0 169 070 1179

ortho-Xylene 00095-47-6 758 052 3918


2-Methylhexane 00591-76-4 109 032 0348

Ethylbenzene 00100-41-4 296 018 0548


2-Methyl-2-butene 00513-35-9 1420 005 0770

Total 1074 5493 5117





132

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35670 516847



n-Heptane 00142-82-5 097 3662 35368

n-Butane 00106-97-8 108 3505 37747

Toluene 00108-88-3 393 3492 137050

n-Pentane 00109-66-0 121 3304 40146


n-Hexane 00110-54-3 113 2599 29485



Cyclohexane 00110-82-7 114 1925 21900


Benzene 00071-43-2 069 1738 12068



n-Octane 00111-65-9 080 1569 12491


2-Methylpropane 00075-28-5 118 1256 14781

3-Methylpentane 00096-14-0 169 1206 20398

2-Methyl-2-butene 00513-35-9 1420 1074 152444

23-Dimethylbutane 00079-29-8 090 1069 9609

t-2-Pentene 00646-04-8 1047 1043 109271


2-Methylhexane 00591-76-4 109 864 9372



2-Methylheptane 00592-27-8 097 787 7608


Propane 00074-98-6 046 757 3460

3-Methylheptane 00589-81-1 112 717 8059



n-Nonane 00111-84-2 068 656 4479



c-2-Pentene 00627-20-3 1028 547 56249

24-Dimethylhexane 00589-43-5 161 521 8366

2-Methyl-1-butene 00563-46-2 638 520 33173

4-Methyloctane 02216-34-4 085 502 4255

n-Propylbenzene 00103-65-1 196 453 8879

ortho-Xylene 00095-47-6 758 450 34122

c-2-Heptene 06443-92-1 708 445 31484





133

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






3-Methyloctane 02216-33-3 088 360 3186

t-2-Hexene 04050-45-7 855 339 28984

Ethylbenzene 00100-41-4 296 338 10013

22-Dimethylbutane 00075-83-2 111 326 3618



3-Methyl-t-2-pentene 00616-12-6 1166 269 31374




2-Methyl-2-pentene 00625-27-4 1103 258 28420

Unknown 8 252 242 6098

3-Methyl-c-2-pentene 00922-62-3 1252 236 29551


c-2-Butene 00590-18-1 1426 227 32333


Cyclopentene 00142-29-0 669 218 14591

1-Nonene 00124-11-8 249 212 5282

Unknown 16 252 209 5253



Unknown 9 252 172 4332

1-Octene 00111-66-0 314 161 5055


33-Dimethylhexane 00563-16-6 115 156 1793


n-Decane 00124-18-5 059 141 0832

continued


134

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Indan 00496-11-7 323 126 4071




Unknown 5 252 108 2722

t-4-Octene 14850-23-8 469 092 4292



Unknown 10 252 074 1873




22-Dimethyloctane 15869-87-1 076 049 0367

n-Undecane 01120-21-4 052 044 0229

c-2-Octene 07642-04-8 252 024 0605

Total 11102 28561 2573


continued


135

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 39128 566956



n-Heptane 00142-82-5 097 4118 39773

Toluene 00108-88-3 393 4052 159045

n-Butane 00106-97-8 108 3621 38994

n-Pentane 00109-66-0 121 3567 43335

n-Hexane 00110-54-3 113 3196 36265



Cyclohexane 00110-82-7 114 2313 26313


Benzene 00071-43-2 069 2021 14034


n-Octane 00111-65-9 080 1766 14063



3-Methylpentane 00096-14-0 169 1600 27048



23-Dimethylbutane 00079-29-8 090 1186 10659

2-Methylhexane 00591-76-4 109 1076 11672

2-Methyl-2-butene 00513-35-9 1420 1032 146518

t-2-Pentene 00646-04-8 1047 991 103774



Propane 00074-98-6 046 919 4201

2-Methylpropane 00075-28-5 118 876 10302



2-Methylheptane 00592-27-8 097 759 7340

3-Methylheptane 00589-81-1 112 683 7684

n-Nonane 00111-84-2 068 677 4621



24-Dimethylhexane 00589-43-5 161 607 9741


2-Methyl-1-butene 00563-46-2 638 575 36672


4-Methyloctane 02216-34-4 085 547 4637


c-2-Pentene 00627-20-3 1028 523 53797





136

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



c-2-Heptene 06443-92-1 708 419 29626

3-Methyl-c-2-pentene 00922-62-3 1252 379 47426

ortho-Xylene 00095-47-6 758 368 27850



n-Propylbenzene 00103-65-1 196 350 6856

3-Methyloctane 02216-33-3 088 339 3003


t-2-Hexene 04050-45-7 855 329 28138


c-2-Butene 00590-18-1 1426 290 41290

n-Decane 00124-18-5 059 284 1680


Ethylbenzene 00100-41-4 296 279 8257


2-Methyl-2-pentene 00625-27-4 1103 272 29956

3-Methyl-t-2-pentene 00616-12-6 1166 264 30830

Unknown 16 247 252 6216


Unknown 8 247 236 5829


Cyclopentene 00142-29-0 669 225 15030






1-Nonene 00124-11-8 249 194 4832

22-Dimethylbutane 00075-83-2 111 192 2134


1-Octene 00111-66-0 314 162 5092

continued


137

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






Unknown 9 247 147 3619

t-4-Octene 14850-23-8 469 146 6841

33-Dimethylhexane 00563-16-6 115 146 1676


Unknown 5 247 140 3451


Indan 00496-11-7 323 086 2776

n-Undecane 01120-21-4 052 081 0423



22-Dimethyloctane 15869-87-1 076 048 0361

Unknown 1 247 043 1059


Total 12111 30488 2517


continued


138

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7701 452 1105 499 1646 3297 70

Static E20 - 7 psi 7758 351 738 259 1087 4196 48

105deg F E20 - 9 psi 7702 685 1602 1098 3753 3417 56

Static E20 - 7 psi 7761 687 1383 951 3138 3302 57

Dynamic E20 - 9 psi 25799 2017 1056 2130 8389 3939 63

E20 - 7 psi 25813 1908 714 1362 4730 3473 49

DHB E20 - 9 psi 7725 9250 1157 10698 31327 2928 106

Total E20 - 7 psi 7826 9233 978 9030 23034 2551 74

Vehicle 210c


139

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Toluene 00108-88-3 393 213 8377

n-Pentane 00109-66-0 121 209 2533

n-Butane 00106-97-8 108 195 2100


n-Heptane 00142-82-5 097 146 1407



2-Methylpropane 00075-28-5 118 119 1401

n-Hexane 00110-54-3 113 119 1345

Cyclohexane 00110-82-7 114 115 1310

Benzene 00071-43-2 069 108 0747

Unknown 23 313 105 3279


t-2-Pentene 00646-04-8 1047 103 10759

n-Octane 00111-65-9 080 096 0765

3-Methylheptane 00589-81-1 112 093 1050

2-Methyl-2-butene 00513-35-9 1420 088 12443



3-Methylpentane 00096-14-0 169 081 1375


4-Methyloctane 02216-34-4 085 074 0632




c-2-Pentene 00627-20-3 1028 060 6196



t-2-Hexene 04050-45-7 855 055 4697

2-Methylhexane 00591-76-4 109 052 0565

2-Methyl-1-butene 00563-46-2 638 045 2839

2-Methylheptane 00592-27-8 097 043 0418




n-Nonane 00111-84-2 068 036 0249

n-Decane 00124-18-5 059 036 0213

n-Propylbenzene 00103-65-1 196 034 0658


3-Methyl-t-2-pentene 00616-12-6 1166 032 3705

22-Dimethyloctane 15869-87-1 076 030 0227






140

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Ethylbenzene 00100-41-4 296 027 0810

2-Methyl-2-pentene 00625-27-4 1103 026 2921

t-4-Octene 14850-23-8 469 026 1220

23-Dimethylbutane 00079-29-8 090 026 0231


ortho-Xylene 00095-47-6 758 025 1927

4-Methyl-t-2-pentene 00674-76-0 804 025 2022

c-2-Heptene 06443-92-1 708 025 1752

3-Methyl-c-2-pentene 00922-62-3 1252 023 2817


1-Butyne 00107-00-6 605 022 1304






Cyclopentene 00142-29-0 669 016 1068


Unknown 20 313 013 0398


22-Dimethylbutane 00075-83-2 111 010 0109



24-Dimethylhexane 00589-43-5 161 009 0138

Unknown 14 313 008 0265

Total 499 1646 3297


continued


141

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1583 22942


Toluene 00108-88-3 393 612 24017

n-Pentane 00109-66-0 121 486 5903

n-Butane 00106-97-8 108 481 5181

n-Heptane 00142-82-5 097 334 3229





n-Hexane 00110-54-3 113 272 3083

Benzene 00071-43-2 069 268 1861

Cyclohexane 00110-82-7 114 242 2757


2-Methylheptane 00592-27-8 097 200 1932



t-2-Pentene 00646-04-8 1047 171 17927

2-Methylpropane 00075-28-5 118 169 1990

2-Methyl-2-butene 00513-35-9 1420 166 23544

3-Methylpentane 00096-14-0 169 154 2608


c-2-Pentene 00627-20-3 1028 139 14324

2-Methyl-1-butene 00563-46-2 638 135 8633





3-Methyl-c-2-pentene 00922-62-3 1252 096 11960


23-Dimethylbutane 00079-29-8 090 094 0843

3-Methylheptane 00589-81-1 112 090 1017

t-2-Hexene 04050-45-7 855 083 7126


Ethylbenzene 00100-41-4 296 078 2298

n-Octane 00111-65-9 080 076 0607

ortho-Xylene 00095-47-6 758 076 5752


2-Methylhexane 00591-76-4 109 069 0746

2-Methyl-2-pentene 00625-27-4 1103 069 7570

n-Nonane 00111-84-2 068 068 0463

3-Methyl-t-2-pentene 00616-12-6 1166 066 7701






142

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



24-Dimethylhexane 00589-43-5 161 057 0908

c-2-Butene 00590-18-1 1426 056 7952


n-Propylbenzene 00103-65-1 196 047 0917

Cyclopentene 00142-29-0 669 044 2973




22-Dimethylbutane 00075-83-2 111 035 0385




Total 1098 3753 3417


continued


143

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Cyclohexane 00110-82-7 114 830 9437


Toluene 00108-88-3 393 735 28842

n-Pentane 00109-66-0 121 635 7720

n-Butane 00106-97-8 108 605 6519


n-Heptane 00142-82-5 097 582 5618

Benzene 00071-43-2 069 579 4019







3-Methylpentane 00096-14-0 169 400 6755

n-Propylbenzene 00103-65-1 196 372 7293

2-Methylhexane 00591-76-4 109 361 3923

n-Octane 00111-65-9 080 359 2859

Unknown 22 382 315 12033

n-Hexane 00110-54-3 113 299 3392


t-2-Butene 00624-64-6 1520 280 42605

4-Methyl-t-2-pentene 00674-76-0 804 264 21197

n-Decane 00124-18-5 059 241 1427



Cyclopentene 00142-29-0 669 218 14592



Propane 00074-98-6 046 193 0881

ortho-Xylene 00095-47-6 758 177 13425

24-Dimethylhexane 00589-43-5 161 168 2703



Ethylbenzene 00100-41-4 296 162 4786

2-Methyl-2-butene 00513-35-9 1420 160 22779


4-Methyloctane 02216-34-4 085 145 1233


t-2-Hexene 04050-45-7 855 134 11491





144

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



23-Dimethylbutane 00079-29-8 090 132 1189

2-Methyl-2-pentene 00625-27-4 1103 129 14259



n-Nonane 00111-84-2 068 120 0820

22-Dimethylbutane 00075-83-2 111 115 1278

2-Methylheptane 00592-27-8 097 114 1105

3-Methylheptane 00589-81-1 112 109 1224

3-Methyl-t-2-pentene 00616-12-6 1166 096 11152




2-Methyl-1-butene 00563-46-2 638 080 5118

3-Methyl-c-2-pentene 00922-62-3 1252 080 10031

Unknown 18 382 072 2733

t-2-Pentene 00646-04-8 1047 056 5882



c-2-Butene 00590-18-1 1426 019 2640

Total 2130 8389 3939


continued


145

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 31696 459267


n-Pentane 00109-66-0 121 5202 63200

n-Butane 00106-97-8 108 4742 51062


Toluene 00108-88-3 393 3938 154553

n-Heptane 00142-82-5 097 3796 36662

n-Hexane 00110-54-3 113 3616 41031


Benzene 00071-43-2 069 2716 18860


Cyclohexane 00110-82-7 114 2178 24768

2-Methyl-2-butene 00513-35-9 1420 2023 287182

t-2-Pentene 00646-04-8 1047 1945 203758


3-Methylpentane 00096-14-0 169 1693 28633





c-2-Pentene 00627-20-3 1028 991 101902

2-Methyl-1-butene 00563-46-2 638 937 59771


n-Octane 00111-65-9 080 891 7098

2-Methylhexane 00591-76-4 109 887 9631


2-Methylpropane 00075-28-5 118 786 9244

t-2-Hexene 04050-45-7 855 635 54264

23-Dimethylbutane 00079-29-8 090 601 5401

c-2-Butene 00590-18-1 1426 546 77832

Cyclopentane 00287-92-3 224 476 10644

3-Methyl-t-2-pentene 00616-12-6 1166 457 53303


2-Methylheptane 00592-27-8 097 412 3986


Cyclopentene 00142-29-0 669 406 27162

3-Methyl-c-2-pentene 00922-62-3 1252 381 47688

2-Methyl-2-pentene 00625-27-4 1103 378 41721




3-Methylheptane 00589-81-1 112 341 3833






146

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 277 4444



22-Dimethylbutane 00075-83-2 111 254 2820

n-Nonane 00111-84-2 068 246 1676

ortho-Xylene 00095-47-6 758 241 18230



Ethylbenzene 00100-41-4 296 181 5360


Propane 00074-98-6 046 169 0774

n-Propylbenzene 00103-65-1 196 168 3302




4-Methyloctane 02216-34-4 085 137 1163





Indan 00496-11-7 323 120 3878


3-Methyloctane 02216-33-3 088 112 0989

14-Diethylbenzene 00105-05-5 439 098 4322

33-Dimethylhexane 00563-16-6 115 095 1092


n-Undecane 01120-21-4 052 093 0483


Unknown 9 289 085 2456

Unknown 22 289 085 2454

Unknown 8 289 083 2389

Unknown 16 289 081 2340






t-4-Octene 14850-23-8 469 062 2903

n-Decane 00124-18-5 059 061 0363

continued


147

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 5 289 057 1654

Unknown 1 289 057 1645

c-2-Heptene 06443-92-1 708 056 3942


4-Methyl-t-2-pentene 00674-76-0 804 048 3873


1-Heptene 00592-76-7 429 040 1703

t-3-Heptene 14686-14-7 617 035 2178



1-Nonene 00124-11-8 249 033 0811


c- amp t-4-Nonene 02198-23-4 442 029 1282






13-Butadiene 00106-99-0 1245 014 1729


Total 10698 31327 2928


continued


148

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Toluene 00108-88-3 393 129 5070


n-Butane 00106-97-8 108 114 1229

n-Heptane 00142-82-5 097 106 1019


Benzene 00071-43-2 069 094 0655



c-2-Butene 00590-18-1 1426 072 10220



2-Methyl-1-butene 00563-46-2 638 057 3627



n-Pentane 00109-66-0 121 054 0651



Cyclohexane 00110-82-7 114 049 0558

n-Hexane 00110-54-3 113 040 0449


n-Octane 00111-65-9 080 037 0294


3-Methylpentane 00096-14-0 169 032 0549

n-Propylbenzene 00103-65-1 196 030 0591

3-Methylheptane 00589-81-1 112 028 0314

t-2-Hexene 04050-45-7 855 028 2367


2-Methylheptane 00592-27-8 097 025 0246

n-Nonane 00111-84-2 068 023 0160


2-Methylhexane 00591-76-4 109 022 0243

3-Methyl-t-2-pentene 00616-12-6 1166 021 2489

Cyclopentene 00142-29-0 669 018 1231





149

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 016 0260


2-Methyl-2-butene 00513-35-9 1420 015 2102

23-Dimethylbutane 00079-29-8 090 015 0133


ortho-Xylene 00095-47-6 758 012 0934


Ethylbenzene 00100-41-4 296 011 0325

t-2-Pentene 00646-04-8 1047 008 0869



Total 259 1087 4196


continued


150

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2384 34537


Toluene 00108-88-3 393 399 15668

n-Pentane 00109-66-0 121 371 4510




n-Heptane 00142-82-5 097 309 2980

n-Butane 00106-97-8 108 299 3222

n-Hexane 00110-54-3 113 246 2791

Benzene 00071-43-2 069 233 1614




t-2-Pentene 00646-04-8 1047 148 15551

Cyclohexane 00110-82-7 114 146 1657





2-Methyl-2-butene 00513-35-9 1420 115 16375

c-2-Pentene 00627-20-3 1028 113 11626




3-Methylpentane 00096-14-0 169 103 1742

n-Octane 00111-65-9 080 100 0796

2-Methyl-1-butene 00563-46-2 638 083 5318


t-2-Hexene 04050-45-7 855 062 5278

3-Methyl-c-2-pentene 00922-62-3 1252 061 7658


3-Methylheptane 00589-81-1 112 054 0611



2-Methylhexane 00591-76-4 109 051 0548

ortho-Xylene 00095-47-6 758 048 3648

Ethylbenzene 00100-41-4 296 047 1400

n-Propylbenzene 00103-65-1 196 047 0921


24-Dimethylhexane 00589-43-5 161 042 0671

3-Methyl-t-2-pentene 00616-12-6 1166 041 4734






151

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 039 4295

Cyclopentane 00287-92-3 224 038 0856

22-Dimethylbutane 00075-83-2 111 033 0370





n-Nonane 00111-84-2 068 023 0155

23-Dimethylbutane 00079-29-8 090 022 0200

Cyclopentene 00142-29-0 669 018 1224


Unknown 22 324 013 0423

2-Methylheptane 00592-27-8 097 012 0113

Total 951 3138 3302


continued


152

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4516 65430





Toluene 00108-88-3 393 507 19903

Unknown 22 333 400 13307

n-Butane 00106-97-8 108 381 4104


n-Heptane 00142-82-5 097 294 2844

Propane 00074-98-6 046 278 1272

Benzene 00071-43-2 069 271 1880

2-Methylheptane 00592-27-8 097 242 2337

n-Pentane 00109-66-0 121 233 2835

n-Hexane 00110-54-3 113 226 2566


c-2-Butene 00590-18-1 1426 199 28382



n-Nonane 00111-84-2 068 171 1171




c-2-Pentene 00627-20-3 1028 111 11423




n-Octane 00111-65-9 080 085 0679

Cyclohexane 00110-82-7 114 081 0923

2-Methyl-2-butene 00513-35-9 1420 081 11500

2-Methyl-1-butene 00563-46-2 638 081 5168




2-Methyl-2-pentene 00625-27-4 1103 068 7461

3-Methylheptane 00589-81-1 112 064 0719




153

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



t-2-Pentene 00646-04-8 1047 062 6546


ortho-Xylene 00095-47-6 758 053 4033


3-Methyl-c-2-pentene 00922-62-3 1252 047 5926

Ethylbenzene 00100-41-4 296 043 1269

2-Methylpropane 00075-28-5 118 038 0446


Cyclopentene 00142-29-0 669 022 1503

t-2-Hexene 04050-45-7 855 014 1156

3-Methyl-t-2-pentene 00616-12-6 1166 011 1314


23-Dimethylbutane 00079-29-8 090 005 0041

Total 1362 4730 3473


continued


154

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7744 654 771 504 1959 3887 39

Static E20 - 7 psi 7828 472 1087 513 1471 2864 49

105deg F E20 - 9 psi 7746 1480 1160 1716 5398 3145 65

Static E20 - 7 psi 7830 1292 800 1033 2530 2449 53

Dynamic E20 - 9 psi 25816 2268 448 1016 4464 4392 23

E20 - 7 psi 25821 1394 1269 1768 6143 3474 57

DHB E20 - 9 psi 7803 16342 991 16190 39290 2427 92

Total E20 - 7 psi 7872 15864 891 14128 33504 2371 82

Vehicle 213c


155

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 914 13240



n-Heptane 00142-82-5 097 320 3090




n-Octane 00111-65-9 080 190 1516




2-Methylheptane 00592-27-8 097 148 1433


2-Methylpropane 00075-28-5 118 118 1392

Toluene 00108-88-3 393 103 4047

n-Nonane 00111-84-2 068 099 0674



3-Methylheptane 00589-81-1 112 072 0810

Benzene 00071-43-2 069 072 0497



Ethylbenzene 00100-41-4 296 054 1611

n-Propylbenzene 00103-65-1 196 051 0994

Indan 00496-11-7 323 046 1487

Unknown 8 380 044 1655

4-Methyloctane 02216-34-4 085 031 0266


ortho-Xylene 00095-47-6 758 025 1916

2-Methylhexane 00591-76-4 109 025 0270

3-Methyloctane 02216-33-3 088 022 0195

t-2-Hexene 04050-45-7 855 022 1856

n-Decane 00124-18-5 059 020 0120



24-Dimethylhexane 00589-43-5 161 010 0159


Unknown 18 380 008 0320


Total 504 1959 3887





156

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5350 77523



Toluene 00108-88-3 393 710 27869


n-Heptane 00142-82-5 097 557 5384

n-Pentane 00109-66-0 121 507 6163




n-Butane 00106-97-8 108 412 4441

Benzene 00071-43-2 069 397 2757

n-Hexane 00110-54-3 113 324 3679






n-Octane 00111-65-9 080 190 1517

2-Methyl-2-butene 00513-35-9 1420 185 26255

Cyclohexane 00110-82-7 114 177 2018

2-Methylpropane 00075-28-5 118 161 1890

t-2-Pentene 00646-04-8 1047 157 16410

3-Methylpentane 00096-14-0 169 153 2584

n-Propylbenzene 00103-65-1 196 130 2552


n-Nonane 00111-84-2 068 105 0717


2-Methylhexane 00591-76-4 109 098 1068

Propane 00074-98-6 046 095 0435

ortho-Xylene 00095-47-6 758 095 7180

2-Methyl-1-butene 00563-46-2 638 091 5809

c-2-Pentene 00627-20-3 1028 087 8898

3-Methyloctane 02216-33-3 088 083 0732


2-Methylheptane 00592-27-8 097 082 0789

4-Methyloctane 02216-34-4 085 082 0692

Cyclopentene 00142-29-0 669 079 5254

Cyclopentane 00287-92-3 224 074 1658

Ethylbenzene 00100-41-4 296 071 2105

n-Decane 00124-18-5 059 065 0381

3-Methylheptane 00589-81-1 112 063 0710

3-Methyl-t-2-pentene 00616-12-6 1166 063 7322

24-Dimethylhexane 00589-43-5 161 062 1002




157

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 061 7585




22-Dimethylbutane 00075-83-2 111 057 0637

t-2-Hexene 04050-45-7 855 056 4804


2-Methyl-2-pentene 00625-27-4 1103 054 5956





Unknown 18 309 046 1407

c-2-Butene 00590-18-1 1426 041 5887






23-Dimethylbutane 00079-29-8 090 023 0203

Total 1716 5398 3145


continued


158

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 1415 20503




n-Heptane 00142-82-5 097 457 4411

n-Nonane 00111-84-2 068 418 2857

n-Octane 00111-65-9 080 391 3117

n-Propylbenzene 00103-65-1 196 390 7648





Unknown 22 429 241 10343



Toluene 00108-88-3 393 138 5398


Ethylbenzene 00100-41-4 296 107 3162

Benzene 00071-43-2 069 106 0733

ortho-Xylene 00095-47-6 758 086 6504

2-Methylhexane 00591-76-4 109 053 0572


Total 1016 4464 4392





159

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 80088 1160459


n-Pentane 00109-66-0 121 4822 58590

n-Heptane 00142-82-5 097 4735 45729

n-Butane 00106-97-8 108 4415 47543


Toluene 00108-88-3 393 3850 151113


n-Hexane 00110-54-3 113 3408 38671


Benzene 00071-43-2 069 3032 21056


2-Methyl-2-butene 00513-35-9 1420 1879 266753


t-2-Pentene 00646-04-8 1047 1856 194423

Cyclohexane 00110-82-7 114 1803 20503

3-Methylpentane 00096-14-0 169 1710 28914

n-Octane 00111-65-9 080 1552 12360




2-Methylhexane 00591-76-4 109 1117 12118


2-Methyl-1-butene 00563-46-2 638 911 58131

c-2-Pentene 00627-20-3 1028 907 93216

2-Methylpropane 00075-28-5 118 779 9171

2-Methylheptane 00592-27-8 097 709 6862

1-Butyne 00107-00-6 605 663 40082


3-Methylheptane 00589-81-1 112 644 7246

t-2-Hexene 04050-45-7 855 637 54462



23-Dimethylbutane 00079-29-8 090 550 4945

3-Methyl-c-2-pentene 00922-62-3 1252 539 67459


n-Nonane 00111-84-2 068 474 3235

Cyclopentane 00287-92-3 224 459 10278




3-Methyl-t-2-pentene 00616-12-6 1166 406 47372

2-Methyl-2-pentene 00625-27-4 1103 376 41453

Cyclopentene 00142-29-0 669 370 24726




160

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




ortho-Xylene 00095-47-6 758 354 26855

4-Methyloctane 02216-34-4 085 354 3006

c-2-Butene 00590-18-1 1426 344 49033



Ethylbenzene 00100-41-4 296 301 8929

n-Propylbenzene 00103-65-1 196 301 5890

3-Methyloctane 02216-33-3 088 295 2606

22-Dimethylbutane 00075-83-2 111 289 3213

24-Dimethylhexane 00589-43-5 161 285 4569




Propane 00074-98-6 046 234 1071







Unknown 8 239 166 3975

Unknown 9 239 161 3846





33-Dimethylhexane 00563-16-6 115 127 1462




continued


161

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Decane 00124-18-5 059 097 0572



c- amp t-4-Nonene 02198-23-4 442 081 3581

c-2-Heptene 06443-92-1 708 079 5569

Unknown 1 239 075 1804

t-4-Octene 14850-23-8 469 075 3530



Unknown 18 239 065 1559

Unknown 5 239 060 1448

Unknown 14 239 055 1326


1-Nonene 00124-11-8 249 048 1191



Indan 00496-11-7 323 034 1102

Total 16190 39290 2427


continued


162

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1993 28873


Toluene 00108-88-3 393 213 8354



n-Butane 00106-97-8 108 130 1400

n-Pentane 00109-66-0 121 129 1569

n-Heptane 00142-82-5 097 123 1191


n-Hexane 00110-54-3 113 116 1316


t-2-Butene 00624-64-6 1520 098 14909



Benzene 00071-43-2 069 089 0619

3-Methylheptane 00589-81-1 112 080 0904

t-2-Pentene 00646-04-8 1047 078 8210



3-Methylpentane 00096-14-0 169 056 0952



Unknown 18 282 048 1351

4-Methyloctane 02216-34-4 085 047 0400


2-Methyl-2-butene 00513-35-9 1420 046 6499

2-Methylhexane 00591-76-4 109 043 0468

c-2-Pentene 00627-20-3 1028 042 4351

t-2-Hexene 04050-45-7 855 041 3497

Cyclohexane 00110-82-7 114 036 0412


c-2-Heptene 06443-92-1 708 035 2475

2-Methyl-1-butene 00563-46-2 638 035 2212

n-Octane 00111-65-9 080 033 0264

23-Dimethylbutane 00079-29-8 090 032 0284





3-Methyl-t-2-pentene 00616-12-6 1166 023 2658


n-Nonane 00111-84-2 068 022 0148

3-Methyl-c-2-pentene 00922-62-3 1252 019 2434





163

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentene 00142-29-0 669 014 0946



n-Propylbenzene 00103-65-1 196 008 0160

24-Dimethylhexane 00589-43-5 161 003 0043

Total 513 1471 2864


continued


164

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4419 64033



Toluene 00108-88-3 393 327 12821

n-Heptane 00142-82-5 097 317 3058

n-Pentane 00109-66-0 121 298 3615

n-Butane 00106-97-8 108 292 3145



n-Hexane 00110-54-3 113 202 2297



Benzene 00071-43-2 069 176 1224



3-Methylpentane 00096-14-0 169 128 2170

Cyclohexane 00110-82-7 114 121 1373

t-2-Pentene 00646-04-8 1047 108 11335

n-Octane 00111-65-9 080 104 0832

23-Dimethylbutane 00079-29-8 090 093 0839

2-Methyl-2-butene 00513-35-9 1420 088 12506


c-2-Pentene 00627-20-3 1028 065 6705

2-Methylheptane 00592-27-8 097 065 0628



2-Methyl-1-butene 00563-46-2 638 060 3850

ortho-Xylene 00095-47-6 758 058 4432

2-Methylhexane 00591-76-4 109 053 0572

3-Methylheptane 00589-81-1 112 044 0500




2-Methyl-2-pentene 00625-27-4 1103 041 4512

Cyclopentene 00142-29-0 669 040 2703

n-Nonane 00111-84-2 068 040 0272


n-Propylbenzene 00103-65-1 196 034 0666



c-2-Heptene 06443-92-1 708 032 2242

c-2-Butene 00590-18-1 1426 030 4304

3-Methyl-t-2-pentene 00616-12-6 1166 027 3205





165

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Ethylbenzene 00100-41-4 296 024 0701

24-Dimethylhexane 00589-43-5 161 020 0324

t-2-Hexene 04050-45-7 855 019 1605



22-Dimethylbutane 00075-83-2 111 016 0174


3-Methyl-c-2-pentene 00922-62-3 1252 010 1259


Total 1033 2530 2449


continued


166

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5963 86398




Toluene 00108-88-3 393 571 22420



n-Pentane 00109-66-0 121 455 5531


Propane 00074-98-6 046 324 1482





Benzene 00071-43-2 069 254 1767


n-Heptane 00142-82-5 097 246 2379


t-2-Pentene 00646-04-8 1047 211 22048


c-2-Butene 00590-18-1 1426 195 27782

Ethylbenzene 00100-41-4 296 168 4985

2-Methyl-1-butene 00563-46-2 638 165 10501

n-Hexane 00110-54-3 113 163 1848

ortho-Xylene 00095-47-6 758 152 11495

Cyclohexane 00110-82-7 114 136 1543

c-2-Pentene 00627-20-3 1028 132 13597


2-Methyl-2-butene 00513-35-9 1420 130 18389

n-Octane 00111-65-9 080 129 1027


3-Methylheptane 00589-81-1 112 115 1296

22-Dimethylbutane 00075-83-2 111 113 1259

n-Butane 00106-97-8 108 111 1191


3-Methylpentane 00096-14-0 169 099 1670


3-Methyl-t-2-pentene 00616-12-6 1166 097 11253

n-Nonane 00111-84-2 068 093 0635


23-Dimethylbutane 00079-29-8 090 091 0816

2-Methylheptane 00592-27-8 097 091 0876

Styrene 00100-42-5 166 085 1415

n-Propylbenzene 00103-65-1 196 085 1659




167

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 068 1091


c-2-Heptene 06443-92-1 708 067 4724

Cyclopentene 00142-29-0 669 058 3856




t-2-Hexene 04050-45-7 855 047 4014

3-Methyl-c-2-pentene 00922-62-3 1252 042 5224



2-Methylhexane 00591-76-4 109 024 0260

Total 1768 6143 3474


continued


168

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 55723 807411



n-Heptane 00142-82-5 097 5981 57761

n-Pentane 00109-66-0 121 4502 54693

n-Butane 00106-97-8 108 3984 42902

n-Hexane 00110-54-3 113 3782 42912


Toluene 00108-88-3 393 3760 147573


Benzene 00071-43-2 069 2573 17862


Cyclohexane 00110-82-7 114 2121 24121




3-Methylpentane 00096-14-0 169 1746 29526

2-Methylhexane 00591-76-4 109 1523 16530

n-Octane 00111-65-9 080 1370 10905

2-Methyl-2-butene 00513-35-9 1420 1332 189048

t-2-Pentene 00646-04-8 1047 1291 135259


23-Dimethylbutane 00079-29-8 090 914 8215


2-Methyl-1-butene 00563-46-2 638 724 46184



c-2-Pentene 00627-20-3 1028 654 67284


1-Butyne 00107-00-6 605 626 37845

2-Methylheptane 00592-27-8 097 598 5783



3-Methylheptane 00589-81-1 112 575 6461

24-Dimethylhexane 00589-43-5 161 569 9133

3-Methyl-c-2-pentene 00922-62-3 1252 520 65089



t-2-Hexene 04050-45-7 855 463 39550

c-2-Heptene 06443-92-1 708 449 31804

n-Decane 00124-18-5 059 419 2479


Cyclopentane 00287-92-3 224 395 8835





169

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




c-2-Butene 00590-18-1 1426 336 47937

3-Methyl-t-2-pentene 00616-12-6 1166 335 39014



2-Methyl-2-pentene 00625-27-4 1103 298 32843


4-Methyloctane 02216-34-4 085 282 2390

n-Nonane 00111-84-2 068 276 1883

Cyclopentene 00142-29-0 669 274 18349


22-Dimethylbutane 00075-83-2 111 262 2916





3-Methyloctane 02216-33-3 088 227 2006

33-Dimethylhexane 00563-16-6 115 217 2497





ortho-Xylene 00095-47-6 758 185 13998

Ethylbenzene 00100-41-4 296 181 5358


n-Propylbenzene 00103-65-1 196 147 2880




Unknown 8 231 112 2592


Unknown 16 231 111 2561

Unknown 5 231 101 2336


c- amp t-4-Nonene 02198-23-4 442 096 4265


Unknown 9 231 085 1963


Unknown 1 231 036 0824


Total 14128 33504 2371


continued


170

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7840 6496 1083 7033 20500 2915 69

Static E20 - 7 psi 7875 5394 873 4710 11512 2444 67

105deg F E20 - 9 psi 7838 11469 907 10408 26483 2545 68

Static E20 - 7 psi 7877 8510 1018 8664 21100 2435 72

Dynamic E20 - 9 psi 25824 1372 1170 1606 5720 3562 55

E20 - 7 psi 25828 914 535 489 2108 4309 20

DHB E20 - 9 psi 7859 19004 940 17874 48855 2733 81

Total E20 - 7 psi 7906 18602 999 18590 49278 2651 94

Vehicle 221c


171

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 8324 89644

2-Methylpropane 00075-28-5 118 7588 89275

Ethanol 00064-17-5 145 5174 74976

n-Pentane 00109-66-0 121 4957 60220




n-Hexane 00110-54-3 113 1782 20226

2-Methyl-2-butene 00513-35-9 1420 1495 212177

Propane 00074-98-6 046 1378 6301

t-2-Pentene 00646-04-8 1047 1321 138329

Toluene 00108-88-3 393 1320 51799

3-Methylpentane 00096-14-0 169 1291 21833

3-Me-1-Hexene 03404-61-3 427 1081 46189


t-3-Heptene 14686-14-7 617 963 59431

2-Methyl-1-butene 00563-46-2 638 894 57049


Benzene 00071-43-2 069 728 5053

c-2-Pentene 00627-20-3 1028 704 72389


23-Dimethylbutane 00079-29-8 090 634 5698

22-DiMeHexane 00590-73-8 094 623 5866



2-Methylhexane 00591-76-4 109 393 4266


c-2-Butene 00590-18-1 1426 385 54865




22-Dimethylbutane 00075-83-2 111 312 3465

Cyclopentane 00287-92-3 224 301 6725

t-2-Hexene 04050-45-7 855 283 24189

14-Diethylbenzene 00105-05-5 439 246 10796

Indan 00496-11-7 323 235 7603

Cyclopentene 00142-29-0 669 222 14854

3-Methyl-t-2-pentene 00616-12-6 1166 218 25428


3-Methyl-c-2-pentene 00922-62-3 1252 216 27097


2-Methylheptane 00592-27-8 097 187 1812





172

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methyl-2-pentene 00625-27-4 1103 173 19052

n-Octane 00111-65-9 080 166 1321


n-Propylbenzene 00103-65-1 196 160 3132

ortho-Xylene 00095-47-6 758 156 11834




Ethylbenzene 00100-41-4 296 141 4174





Unknown 5 290 113 3275











Naphthalene 00091-20-3 328 042 1374

Total 7033 20500 2915


continued


173

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 13220 142369

2-Methylpropane 00075-28-5 118 11988 141051

Ethanol 00064-17-5 145 9234 133801

n-Pentane 00109-66-0 121 8302 100866



n-Hexane 00110-54-3 113 2767 31394

2-Methyl-2-butene 00513-35-9 1420 2454 348276

t-2-Pentene 00646-04-8 1047 2145 224611

Propane 00074-98-6 046 2099 9596

3-Methylpentane 00096-14-0 169 2086 35279

n-Heptane 00142-82-5 097 1782 17211


Cyclohexane 00110-82-7 114 1516 17244

2-Methyl-1-butene 00563-46-2 638 1447 92328

22-DiMeHexane 00590-73-8 094 1392 13105

c-2-Pentene 00627-20-3 1028 1194 122782

Toluene 00108-88-3 393 1100 43170

Benzene 00071-43-2 069 1087 7545

23-Dimethylbutane 00079-29-8 090 1032 9271



2-Methylhexane 00591-76-4 109 603 6543

22-Dimethylbutane 00075-83-2 111 570 6332

c-2-Butene 00590-18-1 1426 511 72813

Cyclopentane 00287-92-3 224 491 10983

t-2-Hexene 04050-45-7 855 437 37393


Cyclopentene 00142-29-0 669 367 24548

n-Octane 00111-65-9 080 364 2897

3-Methyl-t-2-pentene 00616-12-6 1166 339 39475

2-Methyl-2-pentene 00625-27-4 1103 326 35978

3-Methyl-c-2-pentene 00922-62-3 1252 325 40724









Unknown 22 253 201 5089





174

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methylheptane 00589-81-1 112 170 1906





24-Dimethylhexane 00589-43-5 161 126 2020



2-Methylheptane 00592-27-8 097 104 1010

n-Propylbenzene 00103-65-1 196 099 1936

ortho-Xylene 00095-47-6 758 097 7318

n-Nonane 00111-84-2 068 092 0630





33-Dimethylhexane 00563-16-6 115 074 0847


Ethylbenzene 00100-41-4 296 067 1991


1-Octene 00111-66-0 314 055 1718



Total 10408 26483 2545


continued


175

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 2191 31752


n-Butane 00106-97-8 108 1006 10833

n-Pentane 00109-66-0 121 747 9080

Toluene 00108-88-3 393 701 27531


Unknown 22 328 660 21624


Benzene 00071-43-2 069 489 3398

2-Methylpropane 00075-28-5 118 438 5148

t-2-Pentene 00646-04-8 1047 413 43247

n-Heptane 00142-82-5 097 401 3869

2-Methyl-2-butene 00513-35-9 1420 365 51798




Propane 00074-98-6 046 309 1412





Cyclohexane 00110-82-7 114 257 2927


n-Octane 00111-65-9 080 231 1837



c-2-Pentene 00627-20-3 1028 166 17113



n-Hexane 00110-54-3 113 150 1697



ortho-Xylene 00095-47-6 758 139 10527



c-2-Butene 00590-18-1 1426 130 18467



13-Butadiene 00106-99-0 1245 113 14026

Ethylbenzene 00100-41-4 296 109 3230

t-2-Hexene 04050-45-7 855 098 8420

2-Methyl-1-butene 00563-46-2 638 090 5717

2-Methylhexane 00591-76-4 109 078 0845

23-Dimethylbutane 00079-29-8 090 075 0672




176

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



22-DiMeHexane 00590-73-8 094 069 0650

2-Methyl-2-pentene 00625-27-4 1103 054 5959

2-Methylheptane 00592-27-8 097 052 0507

3-Methyl-t-2-pentene 00616-12-6 1166 051 5927


3-Methylpentane 00096-14-0 169 046 0770


3-Methylheptane 00589-81-1 112 024 0275

Cyclopentene 00142-29-0 669 022 1455


n-Nonane 00111-84-2 068 019 0129

Total 1606 5720 3562


continued


177

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 54709 792723


n-Butane 00106-97-8 108 10917 117569

n-Pentane 00109-66-0 121 9272 112649

2-Methylpropane 00075-28-5 118 7225 85005


Toluene 00108-88-3 393 6283 246616

n-Hexane 00110-54-3 113 4995 56676

n-Heptane 00142-82-5 097 4659 44994

Benzene 00071-43-2 069 4652 32302


2-Methyl-2-butene 00513-35-9 1420 3675 521667

t-2-Pentene 00646-04-8 1047 3631 380251

3-Methylpentane 00096-14-0 169 2779 46981

22-DiMeHexane 00590-73-8 094 2773 26105

Cyclohexane 00110-82-7 114 2771 31519


c-2-Pentene 00627-20-3 1028 1943 199760

2-Methyl-1-butene 00563-46-2 638 1834 117003


Propane 00074-98-6 046 1660 7588


2-Methylhexane 00591-76-4 109 1107 12010


n-Octane 00111-65-9 080 1036 8250


t-2-Hexene 04050-45-7 855 954 81525


23-Dimethylbutane 00079-29-8 090 860 7730


Cyclopentane 00287-92-3 224 748 16744


c-2-Butene 00590-18-1 1426 680 97022

3-Methyl-t-2-pentene 00616-12-6 1166 666 77705

Cyclopentene 00142-29-0 669 665 44433


22-Dimethylbutane 00075-83-2 111 574 6383

3-Methyl-c-2-pentene 00922-62-3 1252 548 68650

2-Methyl-2-pentene 00625-27-4 1103 519 57206

2-Methylheptane 00592-27-8 097 515 4981



1-Butyne 00107-00-6 605 436 26373

3-Methylheptane 00589-81-1 112 403 4535




178

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





ortho-Xylene 00095-47-6 758 345 26142






Ethylbenzene 00100-41-4 296 292 8644


24-Dimethylhexane 00589-43-5 161 289 4646



n-Nonane 00111-84-2 068 234 1599


n-Propylbenzene 00103-65-1 196 198 3881



4-Methyloctane 02216-34-4 085 193 1641



Unknown 1 271 171 4641

33-Dimethylhexane 00563-16-6 115 159 1833






n-Undecane 01120-21-4 052 079 0415

3-Methyloctane 02216-33-3 088 079 0703

Unknown 5 271 076 2052

1-Octene 00111-66-0 314 065 2057





Unknown 8 271 035 0945

Total 17874 48855 2733


continued


179

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 8198 118785

n-Butane 00106-97-8 108 7183 77353


n-Pentane 00109-66-0 121 3595 43676

2-Methylpropane 00075-28-5 118 2766 32545


Propane 00074-98-6 046 2137 9770

n-Hexane 00110-54-3 113 1047 11875


n-Heptane 00142-82-5 097 912 8810

t-2-Pentene 00646-04-8 1047 830 86907

2-Methyl-2-butene 00513-35-9 1420 814 115599


23-Dimethylbutane 00079-29-8 090 556 4999


Benzene 00071-43-2 069 530 3683

2-Methyl-1-butene 00563-46-2 638 507 32336

Toluene 00108-88-3 393 503 19740

3-Methylpentane 00096-14-0 169 472 7984


c-2-Pentene 00627-20-3 1028 393 40363


c-2-Butene 00590-18-1 1426 277 39443



22-Dimethylbutane 00075-83-2 111 214 2380


2-Methylheptane 00592-27-8 097 180 1739

t-2-Hexene 04050-45-7 855 178 15211

n-Octane 00111-65-9 080 172 1368



2-Methylhexane 00591-76-4 109 161 1748



c-2-Heptene 06443-92-1 382 146 5572



Cyclopentene 00142-29-0 669 129 8640

3-Methyl-t-2-pentene 00616-12-6 1166 116 13518


Cyclohexane 00110-82-7 114 092 1044


n-Nonane 00111-84-2 068 087 0593




180

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



3-Methylheptane 00589-81-1 112 086 0966

2-Methyl-2-pentene 00625-27-4 1103 081 8971



24-Dimethylhexane 00589-43-5 161 078 1247








n-Propylbenzene 00103-65-1 196 048 0949


33-Dimethylhexane 00563-16-6 115 031 0359


3-Methyl-c-2-pentene 00922-62-3 1252 027 3427




Ethylbenzene 00100-41-4 296 018 0528

ortho-Xylene 00095-47-6 758 010 0721


Total 4710 11512 2444


continued


181

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 15180 219955


n-Butane 00106-97-8 108 9750 104997

n-Pentane 00109-66-0 121 5514 66989


2-Methylpropane 00075-28-5 118 3609 42461


n-Hexane 00110-54-3 113 2552 28959

Propane 00074-98-6 046 2506 11455

n-Heptane 00142-82-5 097 1866 18025

3-Methylpentane 00096-14-0 169 1624 27461

23-Dimethylbutane 00079-29-8 090 1413 12703

2-Methyl-2-butene 00513-35-9 1420 1376 195359

Toluene 00108-88-3 393 1340 52581

Cyclohexane 00110-82-7 114 1307 14870



t-2-Pentene 00646-04-8 1047 1180 123585


Benzene 00071-43-2 069 965 6703

2-Methyl-1-butene 00563-46-2 638 878 56009

c-2-Pentene 00627-20-3 1028 635 65238

2-Methylhexane 00591-76-4 109 632 6855






22-Dimethylbutane 00075-83-2 111 370 4115


n-Octane 00111-65-9 080 346 2755


c-2-Butene 00590-18-1 1426 336 47966


c-2-Heptene 06443-92-1 708 260 18411

t-2-Hexene 04050-45-7 855 249 21269

24-Dimethylhexane 00589-43-5 161 234 3765






3-Methyl-t-2-pentene 00616-12-6 1166 201 23444

2-Methyl-2-pentene 00625-27-4 1103 200 22011




182

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



2-Methylheptane 00592-27-8 097 193 1865

3-Methylheptane 00589-81-1 112 188 2119

Cyclopentene 00142-29-0 669 180 12031



n-Propylbenzene 00103-65-1 196 157 3073

3-Methyl-c-2-pentene 00922-62-3 1252 146 18216




ortho-Xylene 00095-47-6 758 129 9739




Ethylbenzene 00100-41-4 296 101 3002




n-Nonane 00111-84-2 068 085 0583



4-Methyloctane 02216-34-4 085 082 0694



33-Dimethylhexane 00563-16-6 115 067 0767

n-Decane 00124-18-5 059 066 0389



Total 8664 21100 2435


continued


183

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 1732 25089


Benzene 00071-43-2 069 452 3139

c-2-Butene 00590-18-1 1426 376 53628








c-2-Pentene 00627-20-3 1028 072 7386

n-Heptane 00142-82-5 097 059 0568

n-Propylbenzene 00103-65-1 196 048 0947

Ethylbenzene 00100-41-4 296 045 1322


2-Methyl-2-butene 00513-35-9 1420 025 3547

t-2-Hexene 04050-45-7 855 022 1855

ortho-Xylene 00095-47-6 758 015 1110

n-Octane 00111-65-9 080 010 0081

Total 489 2108 4309




184

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 51382 744509



n-Butane 00106-97-8 108 8982 96733

n-Pentane 00109-66-0 121 6997 85011

Toluene 00108-88-3 393 6711 263404

n-Heptane 00142-82-5 097 6680 64513

n-Hexane 00110-54-3 113 5030 57075



Benzene 00071-43-2 069 4022 27924

Cyclohexane 00110-82-7 114 3279 37292




2-Methylpropane 00075-28-5 118 2557 30086


Propane 00074-98-6 046 2432 11116

3-Methylpentane 00096-14-0 169 2416 40845


n-Octane 00111-65-9 080 2194 17472

2-Methyl-2-butene 00513-35-9 1420 2103 298453

t-2-Pentene 00646-04-8 1047 2086 218459


2-Methylhexane 00591-76-4 109 1526 16559

23-Dimethylbutane 00079-29-8 090 1374 12350



2-Methyl-1-butene 00563-46-2 638 1191 75982



c-2-Pentene 00627-20-3 1028 1105 113644

2-Methylheptane 00592-27-8 097 1023 9893


3-Methylheptane 00589-81-1 112 906 10183





24-Dimethylhexane 00589-43-5 161 698 11203

c-2-Heptene 06443-92-1 708 667 47214

n-Nonane 00111-84-2 068 663 4525

t-2-Hexene 04050-45-7 855 648 55398

ortho-Xylene 00095-47-6 758 548 41492




185

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Cyclopentane 00287-92-3 224 512 11458


n-Propylbenzene 00103-65-1 196 499 9784

4-Methyloctane 02216-34-4 085 497 4216

3-Methyl-t-2-pentene 00616-12-6 1166 485 56599

3-Methyl-c-2-pentene 00922-62-3 1252 456 57109

c-2-Butene 00590-18-1 1426 444 63356


Cyclopentene 00142-29-0 669 416 27787






Ethylbenzene 00100-41-4 296 389 11519

22-Dimethylbutane 00075-83-2 111 378 4206

2-Methyl-2-pentene 00625-27-4 1103 358 39448

Unknown 16 261 356 9264



3-Methyloctane 02216-33-3 088 339 3003




1-Nonene 00124-11-8 249 256 6374

1-Butyne 00107-00-6 605 251 15194

Ethylene 00074-85-1 888 250 22216


Unknown 8 261 234 6089


33-Dimethylhexane 00563-16-6 115 213 2449




1-Octene 00111-66-0 314 195 6137


Unknown 9 261 154 4022

n-Undecane 01120-21-4 052 154 0805

n-Decane 00124-18-5 059 152 0896

Unknown 5 261 142 3689


Indan 00496-11-7 323 131 4230

continued


186

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



Unknown 6 261 131 3400


Styrene 00100-42-5 166 105 1738



Unknown 1 261 052 1367



Total 18590 49278 2651


continued


187

Test Fuel Test No

Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present

86deg F E20 - 9 psi 7843 111 00 00 00 0000 0

Static E20 - 7 psi 7898 105 00 00 00 0000 0

105deg F E20 - 9 psi 7847 153 00 00 00 0000 0

Static E20 - 7 psi 7901 148 00 00 00 0000 0

Dynamic E20 - 9 psi 25827 512 950 486 2222 4570 28

E20 - 7 psi 25830 380 00 00 00 0000 0

DHB E20 - 9 psi 7871 1651 889 1468 3932 2678 12

Total E20 - 7 psi 7916 1477 819 1211 2325 1920 12

Vehicle 222c


188

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




189

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




190

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Naphthalene 00091-20-3 328 774 25406


t-2-Butene 00624-64-6 1520 371 56453


n-Butane 00106-97-8 108 285 3072

23-Dimethylbutane 00079-29-8 090 248 2230



Toluene 00108-88-3 393 190 7444

2-Methylpropane 00075-28-5 118 166 1951

2-Methylheptane 00592-27-8 097 157 1514

3-Methyl-t-2-pentene 00616-12-6 1166 131 15309

n-Heptane 00142-82-5 097 130 1251


3-Methylpentane 00096-14-0 169 117 1981

24-Dimethylhexane 00589-43-5 161 111 1786


n-Hexane 00110-54-3 113 100 1134


22-Dimethylbutane 00075-83-2 111 082 0916

Ethylbenzene 00100-41-4 296 077 2293

t-2-Pentene 00646-04-8 1047 075 7833

Cyclohexane 00110-82-7 114 074 0842

c-2-Butene 00590-18-1 1426 074 10503

3-Methyl-c-2-pentene 00922-62-3 1252 071 8850

ortho-Xylene 00095-47-6 758 068 5178

n-Pentane 00109-66-0 121 021 0252


Total 486 2222 4570




191

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4628 67056

3-Methylpentane 00096-14-0 169 1507 25484



n-Butane 00106-97-8 108 1101 11855


Toluene 00108-88-3 393 1066 41860

3-Methyl-c-2-pentene 00922-62-3 1252 1066 133427

n-Pentane 00109-66-0 121 935 11363


n-Hexane 00110-54-3 113 210 2385


Total 1468 3932 2678




192

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




193

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




194

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Total 00 00 0000




195

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 4926 71372


Toluene 00108-88-3 393 1115 43746

3-Methylpentane 00096-14-0 169 762 12888

n-Butane 00106-97-8 108 725 7805


n-Hexane 00110-54-3 113 611 6931

n-Pentane 00109-66-0 121 583 7083




3-Methyl-c-2-pentene 00922-62-3 1252 205 25608

Total 1211 2325 1920



196


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7781 7427 20164 2715 65

E10 - 7 psi Can Inlet 7819 3415 8597 2517 18


E10 - 7 psi Tank Top 25801 34405 116244 3379 76

E10 - 10 psi Can Inlet 25817 18066 51521 2852 71

E10 - 7 psi Can Inlet 25820 13962 48361 3464 90

DHB E10 - 10 psi Tank Top 7672 61958 155900 2516 104


E10 - 10 psi Can Inlet 7794 86321 207927 2409 94

E10 - 7 psi Can Inlet 7844 68582 200436 2923 97

Vehicle 207c


197

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 31534 339592

Ethanol 00064-17-5 145 15433 223618

n-Pentane 00109-66-0 121 4575 55584


Toluene 00108-88-3 393 4103 161061

n-Hexane 00110-54-3 113 3924 44527

2-Methyl-2-butene 00513-35-9 1420 3811 540999

t-2-Pentene 00646-04-8 1047 3208 335977

3-Methylpentane 00096-14-0 169 2810 47513

2-Methyl-1-butene 00563-46-2 638 2286 145822

23-Dimethylbutane 00079-29-8 090 2194 19722

c-2-Pentene 00627-20-3 1028 1736 178523




c-2-Butene 00590-18-1 1426 1349 192427

Benzene 00071-43-2 069 1177 8169

Cyclohexane 00110-82-7 114 1082 12310





t-2-Hexene 04050-45-7 855 585 50036

2-Methylhexane 00591-76-4 109 580 6299

Cyclopentene 00142-29-0 669 525 35095

n-Heptane 00142-82-5 097 524 5057

3-Methyl-t-2-pentene 00616-12-6 1166 474 55209


2-Methyl-2-pentene 00625-27-4 1103 432 47686

3-Methyl-c-2-pentene 00922-62-3 1252 408 51020




22-Dimethylbutane 00075-83-2 111 322 3582





24-Dimethylhexane 00589-43-5 161 213 3412


n-Octane 00111-65-9 080 159 1266






198

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






2-Methylheptane 00592-27-8 097 131 1270




3-Methylheptane 00589-81-1 112 116 1307




t-3-Heptene 14686-14-7 617 083 5119


ortho-Xylene 00095-47-6 758 079 5957




n-Decane 00124-18-5 249 054 1339




Ethylbenzene 00100-41-4 296 049 1460


Unknown 1 266 034 0906

33-Dimethylhexane 00563-16-6 115 030 0344

n-Propylbenzene 00103-65-1 196 028 0542

n-Nonane 00111-84-2 068 015 0101


4-Methyl-t-2-pentene 00674-76-0 804 002 0184

Total 13923 37072 2663


continued


199

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 79369 854739


Ethanol 00064-17-5 145 38151 552793

Toluene 00108-88-3 393 16580 650783

n-Hexane 00110-54-3 113 13605 154368


3-Methylpentane 00096-14-0 169 7654 129419

n-Pentane 00109-66-0 121 7381 89678

2-Methyl-2-butene 00513-35-9 1420 6466 917894


t-2-Pentene 00646-04-8 1047 5245 549380

23-Dimethylbutane 00079-29-8 090 5099 45823

Benzene 00071-43-2 069 4157 28862


Cyclohexane 00110-82-7 114 3728 42398

2-Methyl-1-butene 00563-46-2 638 3681 234792

Ethylene 00074-85-1 888 3244 288174




c-2-Pentene 00627-20-3 1028 2900 298147



Ethane 00074-84-0 026 2242 5893


c-2-Butene 00590-18-1 1426 1864 265834

2-Methylhexane 00591-76-4 109 1801 19546

n-Heptane 00142-82-5 097 1789 17277




2-Methylpropane 00075-28-5 118 1312 15435


t-2-Hexene 04050-45-7 855 1292 110422

1-Butyne 00107-00-6 605 1288 77894

Propane 00074-98-6 046 1212 5539



3-Methyl-t-2-pentene 00616-12-6 1166 1006 117309


Cyclopentene 00142-29-0 669 970 64866


2-Methyl-2-pentene 00625-27-4 1103 953 105093





200

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 843 105557

n-Octane 00111-65-9 080 804 6403

24-Dimethylhexane 00589-43-5 161 747 11988




13-Butadiene 00106-99-0 1245 683 85018

ortho-Xylene 00095-47-6 758 620 46937

22-Dimethylbutane 00075-83-2 111 614 6826


Ethylbenzene 00100-41-4 296 564 16718


n-Propylbenzene 00103-65-1 196 527 10333







2-Methylheptane 00592-27-8 097 427 4127


3-Methylheptane 00589-81-1 112 420 4718


14-Diethylbenzene 00105-05-5 439 416 18237

n-Decane 00124-18-5 059 401 2372



Unknown 16 275 325 8937



Methane 00074-82-8 001 281 0039


n-Nonane 00111-84-2 068 234 1599

Styrene 00100-42-5 166 234 3891



4-Methyl-t-2-pentene 00674-76-0 804 187 15065

n-Undecane 01120-21-4 052 186 0970

4-Methyloctane 02216-34-4 085 170 1442


c-2-Heptene 06443-92-1 708 149 10568

Unknown 8 275 147 4049

continued


201

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 1 275 144 3964

Unknown 22 275 143 3926


Unknown 5 275 129 3543



Unknown 13 275 118 3236

33-Dimethylhexane 00563-16-6 115 116 1338

1-Nonene 00124-11-8 249 113 2820


3-Methyloctane 02216-33-3 088 101 0889

3-Me-1-Hexene 03404-61-3 427 096 4100


Indan 00496-11-7 323 071 2300

Total 32476 89876 2767


continued


202

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 172274 1855242


Ethanol 00064-17-5 145 69165 1002190

2-Methylpropane 00075-28-5 118 21941 258154

n-Hexane 00110-54-3 113 20456 232106

Toluene 00108-88-3 393 19883 780424


n-Pentane 00109-66-0 121 17100 207749

2-Methyl-2-butene 00513-35-9 1420 14541 2064164

t-2-Pentene 00646-04-8 1047 12530 1312315

3-Methylpentane 00096-14-0 169 12414 209911

23-Dimethylbutane 00079-29-8 090 8996 80848

2-Methyl-1-butene 00563-46-2 638 8314 530308


c-2-Pentene 00627-20-3 1028 6703 689128


Benzene 00071-43-2 069 5731 39795

c-2-Butene 00590-18-1 1426 5522 787420

Cyclohexane 00110-82-7 114 5520 62783




n-Heptane 00142-82-5 097 2763 26680



2-Methylhexane 00591-76-4 109 2596 28167


t-2-Hexene 04050-45-7 855 2303 196844

Cyclopentene 00142-29-0 669 2024 135325




3-Methyl-t-2-pentene 00616-12-6 1166 1818 211970

2-Methyl-2-pentene 00625-27-4 1103 1651 182150


3-Methyl-c-2-pentene 00922-62-3 1252 1509 188858



22-Dimethylbutane 00075-83-2 111 1289 14328

Propane 00074-98-6 046 1286 5880








203

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




24-Dimethylhexane 00589-43-5 161 965 15494

n-Octane 00111-65-9 080 867 6901






2-Methylheptane 00592-27-8 097 513 4960

Ethylbenzene 00100-41-4 296 509 15068

ortho-Xylene 00095-47-6 758 500 37892

3-Methylheptane 00589-81-1 112 493 5541








n-Propylbenzene 00103-65-1 196 278 5444

4-Methyl-t-2-pentene 00674-76-0 804 268 21529

Unknown 16 250 236 5907

n-Nonane 00111-84-2 068 228 1557





c-2-Heptene 06443-92-1 708 180 12724



4-Methyloctane 02216-34-4 085 159 1351


Unknown 5 250 146 3658

33-Dimethylhexane 00563-16-6 115 145 1668

Unknown 13 250 138 3462

Indan 00496-11-7 565 135 7640


1-Octene 00111-66-0 314 134 4197


Unknown 8 250 128 3196




continued


204

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




t-4-Octene 14850-23-8 469 113 5317

n-Decane 00124-18-5 059 102 0604

14-Diethylbenzene 00105-05-5 439 092 4032

3-Methyloctane 02216-33-3 088 083 0734

1-Nonene 00124-11-8 249 082 2036

Unknown 9 250 082 2039

t-3-Heptene 14686-14-7 617 074 4560

Unknown 3 250 072 1807

n-Undecane 01120-21-4 052 061 0317

1-Heptene 00592-76-7 429 060 2554



Unknown 12 250 046 1154



t-2-Nonene 06434-78-2 250 036 0888


c-2-Octene 07642-04-8 250 026 0651

Unknown 14 250 018 0459

Total 61958 155900 2516


continued


205

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11715 169746

n-Butane 00106-97-8 108 8056 86757

n-Hexane 00110-54-3 113 4667 52958


23-Dimethylbutane 00079-29-8 090 3624 32566

Toluene 00108-88-3 393 3574 140274

2-Methyl-2-butene 00513-35-9 1420 2721 386293

3-Methylpentane 00096-14-0 169 2686 45414

n-Pentane 00109-66-0 121 2659 32300

t-2-Pentene 00646-04-8 1047 2291 239970

2-Methyl-1-butene 00563-46-2 638 1615 103023



Cyclohexane 00110-82-7 114 1325 15069

2-Methylpropane 00075-28-5 118 1261 14840

c-2-Pentene 00627-20-3 1028 1225 125951

Benzene 00071-43-2 069 1002 6959


c-2-Butene 00590-18-1 1426 984 140348




2-Methylhexane 00591-76-4 109 497 5389



t-2-Hexene 04050-45-7 855 436 37281

n-Heptane 00142-82-5 097 390 3765

Cyclopentene 00142-29-0 669 377 25223


3-Methyl-t-2-pentene 00616-12-6 1166 342 39822

2-Methyl-2-pentene 00625-27-4 1103 323 35657


3-Methyl-c-2-pentene 00922-62-3 1252 294 36799




24-Dimethylhexane 00589-43-5 161 213 3421


n-Octane 00111-65-9 080 185 1477








206

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 141 1566



Propane 00074-98-6 046 113 0517




ortho-Xylene 00095-47-6 758 064 4881


4-Methyl-t-2-pentene 00674-76-0 804 060 4791


n-Decane 00124-18-5 059 057 0338

2-Methylheptane 00592-27-8 097 055 0536



Ethylbenzene 00100-41-4 296 053 1579

3-Methylheptane 00589-81-1 112 052 0582


Unknown 5 288 046 1329

4-Methyloctane 02216-34-4 085 043 0365



33-Dimethylhexane 00563-16-6 115 037 0423

3-Methyloctane 02216-33-3 088 032 0283

n-Nonane 00111-84-2 068 023 0155

n-Propylbenzene 00103-65-1 196 015 0294


Total 8737 25269 2892


continued


207

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 35389 512774

Benzene 00071-43-2 069 4816 33438

Methane 00074-82-8 001 200 0028

Ethane 00074-84-0 026 1602 4210


Propane 00074-98-6 046 1131 5168

2-Methylpropane 00075-28-5 118 2369 27872

22-Dimethylbutane 00075-83-2 111 986 10951



23-Dimethylbutane 00079-29-8 090 7961 71544

ortho-Xylene 00095-47-6 758 645 48887


3-Methylpentane 00096-14-0 169 11861 200561



Ethylbenzene 00100-41-4 296 495 14670

n-Propylbenzene 00103-65-1 196 538 10537

n-Butane 00106-97-8 108 20573 221556

13-Butadiene 00106-99-0 1245 657 81767





Toluene 00108-88-3 393 16497 647513

n-Pentane 00109-66-0 121 12943 157255


n-Hexane 00110-54-3 113 19250 218427

Cyclohexane 00110-82-7 114 5321 60521


n-Octane 00111-65-9 080 692 5511

n-Nonane 00111-84-2 068 309 2108


n-Decane 00124-18-5 059 301 1780

Cyclopentene 00142-29-0 669 1453 97125

n-Heptane 00142-82-5 097 1831 17681


2-Methyl-2-butene 00513-35-9 1420 10075 1430132




2-Methyl-1-butene 00563-46-2 638 6277 400401






208

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






24-Dimethylhexane 00589-43-5 161 1065 17101

3-Methylheptane 00589-81-1 112 512 5752

c-2-Butene 00590-18-1 1426 4141 590493



2-Methylhexane 00591-76-4 109 2197 23841


2-Methylheptane 00592-27-8 097 512 4948



3-Methyl-t-2-pentene 00616-12-6 1166 1347 156999


2-Methyl-2-pentene 00625-27-4 1103 1253 138231

c-2-Pentene 00627-20-3 1028 4701 483353


t-2-Pentene 00646-04-8 1047 8504 890689





3-Methyl-c-2-pentene 00922-62-3 1252 1185 148379







t-2-Hexene 04050-45-7 855 1625 138889


Unknown 16 335 352 11791

Unknown 1 335 242 8119

Total 34405 116244 3379


continued


209

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 112868 1635432

n-Butane 00106-97-8 108 58158 626316

n-Hexane 00110-54-3 113 44646 506591


n-Pentane 00109-66-0 121 30821 374457

3-Methylpentane 00096-14-0 169 26164 442392

2-Methyl-2-butene 00513-35-9 1420 25929 3680648

Toluene 00108-88-3 393 23727 931277

t-2-Pentene 00646-04-8 1047 21858 2289338

23-Dimethylbutane 00079-29-8 090 18155 163160

2-Methyl-1-butene 00563-46-2 638 14852 947358



c-2-Pentene 00627-20-3 1028 11711 1204011

Cyclohexane 00110-82-7 114 10272 116827


c-2-Butene 00590-18-1 1426 8497 1211611

Benzene 00071-43-2 069 8447 58652

2-Methylpropane 00075-28-5 118 7517 88450



2-Methylhexane 00591-76-4 109 4449 48279



t-2-Hexene 04050-45-7 855 3861 330080


Cyclopentene 00142-29-0 669 3403 227545

n-Heptane 00142-82-5 097 3263 31514

3-Methyl-t-2-pentene 00616-12-6 1166 3087 359933


2-Methyl-2-pentene 00625-27-4 1103 2833 312515


3-Methyl-c-2-pentene 00922-62-3 1252 2551 319336



22-Dimethylbutane 00075-83-2 111 2302 25580


24-Dimethylhexane 00589-43-5 161 1503 24139

Propane 00074-98-6 046 1456 6658








210

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




1-Butyne 00107-00-6 605 1088 65828

n-Octane 00111-65-9 080 827 6585









2-Methylheptane 00592-27-8 097 486 4701

3-Methylheptane 00589-81-1 112 442 4965

ortho-Xylene 00095-47-6 758 367 27827







Ethylbenzene 00100-41-4 296 241 7138



n-Propylbenzene 00103-65-1 196 204 4004

Unknown 5 295 172 5063

33-Dimethylhexane 00563-16-6 115 164 1888


c-2-Heptene 06443-92-1 708 133 9383

n-Nonane 00111-84-2 068 125 0851

1-Octene 00111-66-0 314 124 3881

Indan 00496-11-7 323 119 3852

t-3-Heptene 14686-14-7 617 114 7031

Ethylene 00074-85-1 888 113 10031

4-Methyloctane 02216-34-4 085 111 0942


Unknown 16 295 101 2970

Unknown 3 295 097 2854

Unknown 6 295 097 2845




Unknown 8 295 081 2388

n-Decane 00124-18-5 059 080 0470

continued


211

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 13 295 079 2322

3-Methyloctane 02216-33-3 088 077 0681


13-Butadiene 00106-99-0 1245 076 9484


1-Heptene 00592-76-7 429 060 2584



Unknown 9 295 047 1372


1-Nonene 00124-11-8 249 039 0967

n-Undecane 01120-21-4 052 039 0202

3-Ethyl-c-2-Pentene 00816-79-5 976 038 3690






14-Diethylbenzene 00105-05-5 439 016 0705


Unknown 22 295 005 0140

Total 76987 227741 2958


continued


212

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 24872 267848


Ethanol 00064-17-5 145 7522 108992

n-Hexane 00110-54-3 113 2284 25919

Toluene 00108-88-3 393 1833 71943


3-Methylpentane 00096-14-0 169 1742 29458

2-Methyl-2-butene 00513-35-9 1420 1698 240966

n-Pentane 00109-66-0 121 1576 19144

t-2-Pentene 00646-04-8 1047 1511 158229

23-Dimethylbutane 00079-29-8 090 1202 10800


2-Methyl-1-butene 00563-46-2 638 1039 66260


Benzene 00071-43-2 069 892 6192

c-2-Pentene 00627-20-3 1028 805 82752

c-2-Butene 00590-18-1 1426 802 114334

Cyclohexane 00110-82-7 114 799 9092



2-Methylpropane 00075-28-5 118 646 7600

1-Butyne 00107-00-6 605 646 39077




2-Methylhexane 00591-76-4 109 405 4399





Propane 00074-98-6 046 326 1490

t-2-Hexene 04050-45-7 855 306 26148

n-Heptane 00142-82-5 097 305 2946



Cyclopentene 00142-29-0 669 242 16150

3-Methyl-t-2-pentene 00616-12-6 1166 237 27634


3-Methyl-c-2-pentene 00922-62-3 1252 219 27369

ortho-Xylene 00095-47-6 758 215 16278

2-Methyl-2-pentene 00625-27-4 1103 210 23172







213

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




22-Dimethylbutane 00075-83-2 111 178 1977


24-Dimethylhexane 00589-43-5 161 139 2225

n-Octane 00111-65-9 080 130 1032


Ethylbenzene 00100-41-4 296 119 3519




n-Propylbenzene 00103-65-1 196 104 2036




3-Methylheptane 00589-81-1 112 074 0827






2-Methylheptane 00592-27-8 097 047 0455


n-Nonane 00111-84-2 068 046 0315

Total 7427 20164 2715


continued


214

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 42844 461388


Ethanol 00064-17-5 145 17178 248906

Toluene 00108-88-3 393 10047 394340

n-Hexane 00110-54-3 113 8065 91515


3-Methylpentane 00096-14-0 169 4491 75939

n-Pentane 00109-66-0 121 4370 53093

2-Methyl-2-butene 00513-35-9 1420 3637 516297


23-Dimethylbutane 00079-29-8 090 2956 26564

t-2-Pentene 00646-04-8 1047 2864 299954


Benzene 00071-43-2 069 2591 17991

Cyclohexane 00110-82-7 114 2542 28906



2-Methyl-1-butene 00563-46-2 638 1881 119952

c-2-Butene 00590-18-1 1426 1857 264799

c-2-Pentene 00627-20-3 1028 1775 182543


Ethylene 00074-85-1 888 1636 145343

n-Heptane 00142-82-5 097 1536 14831



Ethane 00074-84-0 026 1261 3314



Methane 00074-82-8 001 1067 0148


2-Methylhexane 00591-76-4 109 1026 11134


Propane 00074-98-6 046 809 3698


t-2-Hexene 04050-45-7 855 760 65002

n-Octane 00111-65-9 080 636 5062


3-Methyl-t-2-pentene 00616-12-6 1166 604 70439


Cyclopentene 00142-29-0 669 555 37098

13-Butadiene 00106-99-0 1245 530 66022







215

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




2-Methyl-2-pentene 00625-27-4 1103 503 55446




ortho-Xylene 00095-47-6 758 427 32375

n-Propylbenzene 00103-65-1 196 425 8330

3-Methyl-c-2-pentene 00922-62-3 1252 419 52480




Ethylbenzene 00100-41-4 296 312 9253

22-Dimethylbutane 00075-83-2 111 306 3401


3-Methylheptane 00589-81-1 112 296 3328


2-Methylpropane 00075-28-5 118 281 3306


24-Dimethylhexane 00589-43-5 161 250 4021

2-Methylheptane 00592-27-8 097 238 2306






Unknown 1 284 172 4890




Total 18066 51521 2852


continued


216

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 316658 3410131


Ethanol 00064-17-5 145 67831 982860

n-Hexane 00110-54-3 113 32071 363900


n-Pentane 00109-66-0 121 25077 304666

2-Methyl-2-butene 00513-35-9 1420 20849 2959520

3-Methylpentane 00096-14-0 169 19682 332790

t-2-Pentene 00646-04-8 1047 17641 1847614

Toluene 00108-88-3 393 15091 592313

23-Dimethylbutane 00079-29-8 090 13982 125657

2-Methyl-1-butene 00563-46-2 638 12182 777050

c-2-Pentene 00627-20-3 1028 9542 981058



2-Methylpropane 00075-28-5 118 7882 92741


Cyclohexane 00110-82-7 114 7483 85109

c-2-Butene 00590-18-1 1426 7117 1014871

Benzene 00071-43-2 069 6155 42735


2-Methylhexane 00591-76-4 109 3304 35857


t-2-Hexene 04050-45-7 855 3007 257097



Cyclopentene 00142-29-0 669 2736 182929


3-Methyl-t-2-pentene 00616-12-6 1166 2425 282759

n-Heptane 00142-82-5 097 2420 23372

2-Methyl-2-pentene 00625-27-4 1103 2238 246882


3-Methyl-c-2-pentene 00922-62-3 1252 2008 251353


22-Dimethylbutane 00075-83-2 111 1932 21463







24-Dimethylhexane 00589-43-5 161 1135 18218






217

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





1-Butyne 00107-00-6 605 772 46679

n-Octane 00111-65-9 080 671 5344



Propane 00074-98-6 046 568 2596





2-Methylheptane 00592-27-8 097 469 4538


3-Methylheptane 00589-81-1 112 433 4866



ortho-Xylene 00095-47-6 758 325 24656




Ethylbenzene 00100-41-4 296 255 7563

n-Propylbenzene 00103-65-1 196 248 4851


n-Nonane 00111-84-2 068 175 1194

Unknown 5 240 166 3989

33-Dimethylhexane 00563-16-6 115 165 1905

n-Decane 00124-18-5 059 164 0967



c-2-Heptene 06443-92-1 708 144 10185



Unknown 16 240 132 3163



4-Methyloctane 02216-34-4 085 108 0916

n-Undecane 01120-21-4 052 106 0553

t-3-Heptene 14686-14-7 617 101 6224


Unknown 3 240 067 1615

1-Heptene 00592-76-7 429 066 2838

13-Butadiene 00106-99-0 1245 060 7523


3-Methyloctane 02216-33-3 088 059 0525

continued


218

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyloctane 02216-33-3 088 059 0525



Unknown 22 240 053 1268

1-Nonene 00124-11-8 249 047 1178

Unknown 8 240 047 1119


Indan 00496-11-7 323 033 1060

14-Diethylbenzene 00105-05-5 439 027 1190

Total 86321 207927 2409


continued


219

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 5716 82823

Benzene 00071-43-2 069 818 5680

Propane 00074-98-6 046 141 0644

2-Methylpropane 00075-28-5 118 344 4046


23-Dimethylbutane 00079-29-8 090 819 7363


3-Methylpentane 00096-14-0 169 1189 20098


n-Butane 00106-97-8 108 3676 39588

Toluene 00108-88-3 393 2159 84759

n-Pentane 00109-66-0 121 1545 18766

n-Hexane 00110-54-3 113 2616 29678

2-Methyl-2-butene 00513-35-9 1420 1237 175649



t-2-Pentene 00646-04-8 1047 1196 125262


Total 3415 8597 2517





220

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 13363 193622

Benzene 00071-43-2 069 2498 17342

Methane 00074-82-8 001 1601 0222

Ethane 00074-84-0 026 1146 3013

Ethylene 00074-85-1 888 1976 175570

2-Methylpropane 00075-28-5 118 312 3675

22-Dimethylbutane 00075-83-2 111 419 4659



23-Dimethylbutane 00079-29-8 090 2658 23890

ortho-Xylene 00095-47-6 758 471 35666


3-Methylpentane 00096-14-0 169 4167 70465




Ethylbenzene 00100-41-4 296 483 14312

n-Propylbenzene 00103-65-1 196 549 10766

14-Diethylbenzene 00105-05-5 439 366 16071

n-Butane 00106-97-8 108 6249 67299

13-Butadiene 00106-99-0 1245 678 84410

1-Butyne 00107-00-6 605 843 50998





Toluene 00108-88-3 393 9872 387494

n-Pentane 00109-66-0 121 3931 47757


n-Hexane 00110-54-3 113 7372 83651

Cyclohexane 00110-82-7 114 2206 25094


n-Octane 00111-65-9 080 595 4737

n-Nonane 00111-84-2 068 180 1229

1-Dodecene 00112-41-4 156 142 2220


n-Decane 00124-18-5 059 631 3731

Cyclopentene 00142-29-0 669 568 37986

n-Heptane 00142-82-5 097 940 9074


Indan 00496-11-7 323 222 7175

2-Methyl-2-butene 00513-35-9 1420 3288 466742






221

Species CAS No MIR

Composite

VOC

mg

Ozone

mg






33-Dimethyl-1-butene 00558-37-2 568 092 5207


33-Dimethylhexane 00563-16-6 115 164 1893

2-Methyl-1-butene 00563-46-2 638 1833 116899




24-Dimethylhexane 00589-43-5 161 689 11062

3-Methylheptane 00589-81-1 112 195 2189

c-2-Butene 00590-18-1 1426 1053 150118


2-Methylhexane 00591-76-4 109 1016 11022


2-Methylheptane 00592-27-8 097 452 4375



3-Methyl-t-2-pentene 00616-12-6 1166 664 77449



2-Methyl-2-pentene 00625-27-4 1103 641 70697

c-2-Pentene 00627-20-3 1028 1401 144091


t-2-Pentene 00646-04-8 1047 2698 282558





continued


222

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





3-Methyl-c-2-pentene 00922-62-3 1252 649 81193






4-Methyloctane 02216-34-4 085 175 1482




t-2-Hexene 04050-45-7 855 875 74823


c-2-Heptene 06443-92-1 066 121 0790


Unknown 16 342 407 13925

Unknown 13 342 172 5885

Unknown 1 342 111 3781

Total 13962 48361 3464


continued


223

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Ethanol 00064-17-5 145 93713 1357878

Benzene 00071-43-2 069 8395 58292

Ethylene 00074-85-1 888 385 34170

Propane 00074-98-6 046 2204 10077

2-Methylpropane 00075-28-5 118 9571 112611

22-Dimethylbutane 00075-83-2 111 1771 19683



23-Dimethylbutane 00079-29-8 090 17445 156779

ortho-Xylene 00095-47-6 758 670 50741


3-Methylpentane 00096-14-0 169 25280 427457



Ethylbenzene 00100-41-4 296 381 11287

n-Propylbenzene 00103-65-1 196 340 6654

n-Butane 00106-97-8 108 45349 488366

13-Butadiene 00106-99-0 1245 098 12253

1-Butyne 00107-00-6 605 785 47505






Toluene 00108-88-3 393 27004 1059911

n-Pentane 00109-66-0 121 24220 294263


n-Hexane 00110-54-3 113 42008 476657

Cyclohexane 00110-82-7 114 10300 117149


n-Octane 00111-65-9 080 1207 9611

1-Octene 00111-66-0 314 135 4256

n-Nonane 00111-84-2 068 238 1626


1-Nonene 00124-11-8 249 109 2715

n-Decane 00124-18-5 059 372 2201

Cyclopentene 00142-29-0 669 2697 180349

n-Heptane 00142-82-5 097 3372 32566



Indan 00496-11-7 323 253 8173

2-Methyl-2-butene 00513-35-9 1420 20269 2877200







224

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





33-Dimethylhexane 00563-16-6 115 181 2080

2-Methyl-1-butene 00563-46-2 638 11748 749377




24-Dimethylhexane 00589-43-5 161 2049 32895

3-Methylheptane 00589-81-1 112 880 9892

c-2-Butene 00590-18-1 1426 7564 1078587



2-Methylhexane 00591-76-4 109 4571 49606


2-Methylheptane 00592-27-8 097 923 8932


1-Heptene 00592-76-7 429 108 4612


3-Methyl-t-2-pentene 00616-12-6 1166 3093 360613



2-Methyl-2-pentene 00625-27-4 1103 2810 309980

c-2-Pentene 00627-20-3 1028 9207 946625


t-2-Pentene 00646-04-8 1047 17071 1787966





3-Methyl-c-2-pentene 00922-62-3 1252 2468 308948







3-Methyloctane 02216-33-3 088 167 1477

4-Methyloctane 02216-34-4 085 247 2098





continued


225

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





t-2-Hexene 04050-45-7 855 3716 317667

t-2-Nonene 06434-78-2 290 075 2171

c-2-Heptene 06443-92-1 708 211 14913


t-3-Heptene 14686-14-7 617 198 12193

Unknown 5 290 413 11999

Unknown 16 290 404 11736

Unknown 13 290 190 5520

Unknown 8 290 136 3963

Unknown 3 290 085 2475

Unknown 9 290 084 2439

Total 68582 200436 2923


continued


226


Bag

THC

mg

GC as

of

THC

GC

VOC

mg

Ozone

mg Reactivity

Species

Present



E10 - 10 psi Can Inlet 7732 11271 1019 11484 26563 2313 65

E10 - 7 psi Can Inlet 7793 8192 834 6829 20748 3038 63


E10 - 7 psi Tank Top 25793 13119 1001 13128 44311 3375 70

E10 - 10 psi Can Inlet 25809 145183 1169 169783 402961 2373 89

E10 - 7 psi Can Inlet 25818 43845 875 38384 118469 3086 69

DHB E10 - 10 psi Tank Top 7648 89107 959 85443 209022 2446 45


E10 - 10 psi Can Inlet 7769 115481 934 107832 252202 2339 44

E10 - 7 psi Can Inlet 7836 40280 952 38356 116460 3036 83

Vehicle 211c


227

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 22971 247380


n-Hexane 00110-54-3 113 2483 28180


n-Pentane 00109-66-0 121 1817 22079

3-Methylpentane 00096-14-0 169 1584 26779

2-Methyl-2-butene 00513-35-9 1420 1509 214170

t-2-Pentene 00646-04-8 1047 1269 132895

Toluene 00108-88-3 393 1202 47172

23-Dimethylbutane 00079-29-8 090 1103 9914

c-2-Butene 00590-18-1 1426 904 128849

2-Methyl-1-butene 00563-46-2 638 890 56745



c-2-Pentene 00627-20-3 1028 680 69944

2-Methylpropane 00075-28-5 118 645 7585

t-2-Butene 00624-64-6 1520 536 81392


Cyclohexane 00110-82-7 114 519 5901


Benzene 00071-43-2 069 479 3328





2-Methylhexane 00591-76-4 109 227 2467

t-2-Hexene 04050-45-7 855 211 18015

Cyclopentene 00142-29-0 669 199 13290

n-Heptane 00142-82-5 097 194 1873



3-Methyl-t-2-pentene 00616-12-6 1166 176 20565



3-Methyl-1-butene 00563-45-1 685 153 10520

2-Methyl-2-pentene 00625-27-4 1103 152 16805







22-Dimethylbutane 00075-83-2 111 119 1317





228

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




3-Methyl-c-2-pentene 00922-62-3 1252 115 14408

n-Octane 00111-65-9 080 107 0853


ortho-Xylene 00095-47-6 758 102 7756








n-Propylbenzene 00103-65-1 196 046 0903


2-Methylheptane 00592-27-8 097 041 0396



Ethylbenzene 00100-41-4 296 007 0221

24-Dimethylhexane 00589-43-5 161 006 0101

Total 6278 16694 2659


continued


229

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

Unknown 22 307 391 12012

Ethanol 00064-17-5 145 1321 19145

Benzene 00071-43-2 069 2139 14852

Propane 00074-98-6 046 397 1816

2-Methylpropane 00075-28-5 118 3636 42785

22-Dimethylbutane 00075-83-2 111 842 9359



23-Dimethylbutane 00079-29-8 090 2973 26719

ortho-Xylene 00095-47-6 758 337 25550


3-Methylpentane 00096-14-0 169 3756 63505


Ethylbenzene 00100-41-4 296 220 6505

n-Propylbenzene 00103-65-1 196 202 3961

n-Butane 00106-97-8 108 56598 609509






Toluene 00108-88-3 393 2903 113947

n-Pentane 00109-66-0 121 5036 61181


n-Hexane 00110-54-3 113 7233 82075

Cyclohexane 00110-82-7 114 3248 36942


n-Octane 00111-65-9 080 252 2004


Cyclopentene 00142-29-0 669 913 61061

n-Heptane 00142-82-5 097 978 9444


2-Methyl-2-butene 00513-35-9 1420 4143 588042




2-Methyl-1-butene 00563-46-2 638 4234 270054




24-Dimethylhexane 00589-43-5 161 832 13366

3-Methylheptane 00589-81-1 112 179 2017

c-2-Butene 00590-18-1 1426 7009 999462





230

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





2-Methylhexane 00591-76-4 109 1400 15189


2-Methylheptane 00592-27-8 097 175 1693



3-Methyl-t-2-pentene 00616-12-6 1166 815 95045



2-Methyl-2-pentene 00625-27-4 1103 777 85750

c-2-Pentene 00627-20-3 1028 3096 318320

t-2-Pentene 00646-04-8 1047 3554 372250





3-Methyl-c-2-pentene 00922-62-3 1252 712 89120




t-2-Hexene 04050-45-7 855 994 84993


Unknown 1 307 061 1868

Total 19657 60694 3088


continued


231

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 307727 3313949


Ethanol 00064-17-5 145 39672 574830

n-Hexane 00110-54-3 113 34020 386019


n-Pentane 00109-66-0 121 28021 340433

3-Methylpentane 00096-14-0 169 22023 372381

2-Methyl-2-butene 00513-35-9 1420 20648 2930948

t-2-Pentene 00646-04-8 1047 17405 1822913

23-Dimethylbutane 00079-29-8 090 16047 144212

Toluene 00108-88-3 393 14387 564695

2-Methyl-1-butene 00563-46-2 638 12969 827211

c-2-Butene 00590-18-1 1426 11793 1681690



c-2-Pentene 00627-20-3 1028 9515 978316

Cyclohexane 00110-82-7 114 9043 102849


Benzene 00071-43-2 069 6756 46910



2-Methylhexane 00591-76-4 109 3473 37687



3-Methyl-t-2-pentene 00616-12-6 1166 2951 344072


2-Methylpropane 00075-28-5 118 2769 32579

Cyclopentene 00142-29-0 669 2682 179344



n-Heptane 00142-82-5 097 2413 23305

2-Methyl-2-pentene 00625-27-4 1103 2292 252898

24-Dimethylhexane 00589-43-5 161 2070 33231

t-2-Hexene 04050-45-7 855 2064 176446

3-Methyl-c-2-pentene 00922-62-3 1252 2063 258275

22-Dimethylbutane 00075-83-2 111 1886 20962







232

Species CAS No MIR

Composite

VOC

mg

Ozone

mg








Propane 00074-98-6 046 400 1829


Ethylbenzene 00100-41-4 296 342 10143

Total 85443 209022 2446


continued


233

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 11488 166456

n-Butane 00106-97-8 108 7975 85883

n-Hexane 00110-54-3 113 6913 78445


n-Pentane 00109-66-0 121 4885 59344

3-Methylpentane 00096-14-0 169 4260 72030

2-Methyl-2-butene 00513-35-9 1420 4013 569617

t-2-Pentene 00646-04-8 1047 3313 346941

Toluene 00108-88-3 393 3059 120057

23-Dimethylbutane 00079-29-8 090 2976 26746

2-Methyl-1-butene 00563-46-2 638 2453 156477



c-2-Butene 00590-18-1 1426 1891 269674

c-2-Pentene 00627-20-3 1028 1824 187499

Cyclohexane 00110-82-7 114 1684 19156

t-2-Butene 00624-64-6 1520 1597 242714


2-Methylpropane 00075-28-5 118 1543 18157

Benzene 00071-43-2 069 1143 7936




2-Methylhexane 00591-76-4 109 714 7751



t-2-Hexene 04050-45-7 855 596 50989


Cyclopentene 00142-29-0 669 507 33919

3-Methyl-t-2-pentene 00616-12-6 1166 499 58164


2-Methyl-2-pentene 00625-27-4 1103 459 50603

Propane 00074-98-6 046 439 2008


n-Heptane 00142-82-5 097 430 4150

3-Methyl-c-2-pentene 00922-62-3 1252 414 51810

22-Dimethylbutane 00075-83-2 111 382 4244



24-Dimethylhexane 00589-43-5 161 288 4618







234

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 130 1038



2-Methylheptane 00592-27-8 097 099 0957



3-Methylheptane 00589-81-1 112 083 0929





t-3-Heptene 14686-14-7 617 051 3173



Unknown 5 321 043 1371


Ethylbenzene 00100-41-4 296 040 1173

33-Dimethylhexane 00563-16-6 115 036 0411

ortho-Xylene 00095-47-6 758 035 2689

n-Propylbenzene 00103-65-1 196 035 0690


Total 11846 38214 3226


continued


235

Species CAS No MIR

Composite

VOC

mg

Ozone

mg



n-Butane 00106-97-8 108 7470 80442

n-Hexane 00110-54-3 113 7413 84118

n-Pentane 00109-66-0 121 5151 62576


3-Methylpentane 00096-14-0 169 4543 76808

2-Methyl-2-butene 00513-35-9 1420 4232 600795

t-2-Pentene 00646-04-8 1047 3542 371010

Toluene 00108-88-3 393 3511 137807

23-Dimethylbutane 00079-29-8 090 3268 29366

c-2-Butene 00590-18-1 1426 3176 452906

1-Butyne 00107-00-6 605 2943 178046

2-Methyl-1-butene 00563-46-2 638 2779 177240


c-2-Pentene 00627-20-3 1028 2047 210481


Cyclohexane 00110-82-7 114 1938 22040


2-Methylpropane 00075-28-5 118 1317 15500

Benzene 00071-43-2 069 1229 8533



Ethanol 00064-17-5 145 810 11731



2-Methylhexane 00591-76-4 109 691 7494

t-2-Hexene 04050-45-7 855 621 53050

n-Heptane 00142-82-5 097 579 5588


Cyclopentene 00142-29-0 669 574 38396


2-Methyl-2-pentene 00625-27-4 1103 486 53633



3-Methyl-c-2-pentene 00922-62-3 1252 468 58610

3-Methyl-t-2-pentene 00616-12-6 1166 457 53286


Methane 00074-82-8 001 444 0061

22-Dimethylbutane 00075-83-2 111 431 4788








236

Species CAS No MIR

Composite

VOC

mg

Ozone

mg







24-Dimethylhexane 00589-43-5 161 328 5262


n-Octane 00111-65-9 080 282 2250


n-Decane 00124-18-5 059 276 1632

Unknown 22 335 234 7864






2-Methylheptane 00592-27-8 097 160 1548

3-Methylheptane 00589-81-1 112 144 1615




n-Propylbenzene 00103-65-1 196 113 2208

Unknown 1 335 094 3164


Indan 00496-11-7 323 084 2722


Ethylbenzene 00100-41-4 296 067 1991

n-Undecane 01120-21-4 052 047 0244

ortho-Xylene 00095-47-6 758 043 3244

Total 13128 44311 3375


continued


237

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 23123 249015

Ethanol 00064-17-5 145 21703 314477

n-Hexane 00110-54-3 113 18050 204804


n-Pentane 00109-66-0 121 13834 168070

3-Methylpentane 00096-14-0 169 11505 194534

2-Methyl-2-butene 00513-35-9 1420 11209 1591055

t-2-Pentene 00646-04-8 1047 9469 991727

23-Dimethylbutane 00079-29-8 090 8278 74396

2-Methyl-1-butene 00563-46-2 638 6814 434644

Toluene 00108-88-3 393 6647 260916


c-2-Pentene 00627-20-3 1028 5152 529739



c-2-Butene 00590-18-1 1426 4525 645316

Cyclohexane 00110-82-7 114 4341 49370

1-Butyne 00107-00-6 605 3288 198937

2-Methylpropane 00075-28-5 118 3175 37353

Benzene 00071-43-2 069 2711 18826



2-Methylhexane 00591-76-4 109 1773 19242




t-2-Hexene 04050-45-7 855 1516 129592

Cyclopentene 00142-29-0 669 1453 97160

3-Methyl-t-2-pentene 00616-12-6 1166 1242 144819


2-Methyl-2-pentene 00625-27-4 1103 1149 126792

3-Methyl-c-2-pentene 00922-62-3 1252 1075 134519


22-Dimethylbutane 00075-83-2 111 1058 11760

n-Heptane 00142-82-5 097 1036 10005






24-Dimethylhexane 00589-43-5 161 606 9728






238

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Propane 00074-98-6 046 476 2175








n-Octane 00111-65-9 080 260 2066






2-Methylheptane 00592-27-8 097 198 1916

Ethylbenzene 00100-41-4 296 198 5852

3-Methylheptane 00589-81-1 112 177 1989


ortho-Xylene 00095-47-6 758 163 12357



Unknown 1 313 123 3845

Unknown 16 313 116 3646

n-Decane 00124-18-5 059 110 0648

n-Propylbenzene 00103-65-1 196 088 1715



Unknown 5 313 070 2205

c-2-Heptene 06443-92-1 708 065 4610

33-Dimethylhexane 00563-16-6 115 065 0749

n-Nonane 00111-84-2 068 049 0335

t-3-Heptene 14686-14-7 617 043 2680


13-Butadiene 00106-99-0 1245 042 5279

4-Methyl-t-2-pentene 00674-76-0 804 021 1722

Methane 00074-82-8 001 008 0001

Total 31093 97716 3143


continued


239

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 39458 424924


Ethanol 00064-17-5 145 10129 146760

2-Methylpropane 00075-28-5 118 5716 67259

n-Hexane 00110-54-3 113 4068 46161


n-Pentane 00109-66-0 121 3154 38314

3-Methylpentane 00096-14-0 169 2555 43201

2-Methyl-2-butene 00513-35-9 1420 2451 347976

t-2-Pentene 00646-04-8 1047 2085 218342

Toluene 00108-88-3 393 2039 80037

23-Dimethylbutane 00079-29-8 090 1831 16453

2-Methyl-1-butene 00563-46-2 638 1510 96290



c-2-Pentene 00627-20-3 1028 1123 115451

Cyclohexane 00110-82-7 114 1042 11856


c-2-Butene 00590-18-1 1426 833 118751

Benzene 00071-43-2 069 781 5423

Propane 00074-98-6 046 619 2830



22-DiMeHexane 00590-73-8 094 513 4827

2-Methylhexane 00591-76-4 109 460 4988

1-Butyne 00107-00-6 605 379 22956

t-2-Hexene 04050-45-7 855 374 31963


t-3-Heptene 14686-14-7 617 351 21645


Cyclopentene 00142-29-0 669 328 21962

3-Methyl-t-2-pentene 00616-12-6 1166 304 35469


2-Methyl-2-pentene 00625-27-4 1103 284 31321



3-Methyl-c-2-pentene 00922-62-3 1252 256 32099


22-Dimethylbutane 00075-83-2 111 222 2468









240

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





Unknown 5 230 105 2411


Unknown 7 230 082 1885




Unknown 17 230 069 1596


2-Methylheptane 00592-27-8 097 066 0636



n-Propylbenzene 00103-65-1 196 046 0909



n-Nonane 00111-84-2 068 037 0255


ortho-Xylene 00095-47-6 758 027 2080

Unknown 1 230 027 0619


Ethylbenzene 00100-41-4 296 019 0574

c-2-Octene 07642-04-8 230 007 0157

Total 11484 26563 2313


continued


241

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 622650 6705400


Ethanol 00064-17-5 145 124094 1798086

n-Hexane 00110-54-3 113 67518 766114


n-Pentane 00109-66-0 121 46672 567029

3-Methylpentane 00096-14-0 169 41573 702943

2-Methyl-2-butene 00513-35-9 1420 39233 5569075

Toluene 00108-88-3 393 33167 1301796

t-2-Pentene 00646-04-8 1047 32239 3376598

23-Dimethylbutane 00079-29-8 090 29164 262093

2-Methylpropane 00075-28-5 118 23323 274414

2-Methyl-1-butene 00563-46-2 638 22688 1447167



c-2-Pentene 00627-20-3 1028 17645 1814172

Cyclohexane 00110-82-7 114 16882 192015


c-2-Butene 00590-18-1 1426 12775 1821732

Benzene 00071-43-2 069 11664 80988



2-Methylhexane 00591-76-4 109 7254 78719




t-2-Hexene 04050-45-7 855 5835 498847


Cyclopentene 00142-29-0 669 5140 343686

3-Methyl-t-2-pentene 00616-12-6 1166 4795 559045

n-Heptane 00142-82-5 097 4710 45487

2-Methyl-2-pentene 00625-27-4 1103 4548 501761


3-Methyl-c-2-pentene 00922-62-3 1252 4046 506426

22-Dimethylbutane 00075-83-2 111 3825 42506

1-Butyne 00107-00-6 605 3692 223362



Propane 00074-98-6 046 2935 13414


24-Dimethylhexane 00589-43-5 161 2703 43405







242

Species CAS No MIR

Composite

VOC

mg

Ozone

mg










n-Octane 00111-65-9 080 1249 9946



2-Methylheptane 00592-27-8 097 924 8935


3-Methylheptane 00589-81-1 112 747 8400




ortho-Xylene 00095-47-6 758 623 47185



Indan 00496-11-7 323 477 15440



n-Nonane 00111-84-2 068 408 2788

Ethylbenzene 00100-41-4 296 406 12023


n-Propylbenzene 00103-65-1 196 329 6454




Unknown 5 237 273 6466

1-Octene 00111-66-0 314 250 7855

33-Dimethylhexane 00563-16-6 115 231 2665

c-2-Heptene 06443-92-1 708 230 16249

n-Decane 00124-18-5 059 227 1339

t-3-Heptene 14686-14-7 617 214 13214

4-Methyloctane 02216-34-4 085 185 1572

3-Methyloctane 02216-33-3 088 159 1405

14-Diethylbenzene 00105-05-5 439 144 6326

Unknown 3 237 139 3291


1-Heptene 00592-76-7 429 128 5491

Unknown 8 237 120 2850


continued


243

Species CAS No MIR

Composite

VOC

mg

Ozone

mg




Unknown 22 237 096 2267

13-Butadiene 00106-99-0 1245 092 11436

n-Undecane 01120-21-4 052 084 0439

Unknown 16 237 055 1290

Total 169783 402961 2373


continued


244

Species CAS No MIR

Composite

VOC

mg

Ozone

mg

n-Butane 00106-97-8 108 421885 4543329


Ethanol 00064-17-5 145 63956 926704

n-Hexane 00110-54-3 113 42103 477731


n-Pentane 00109-66-0 121 32695 397223

3-Methylpentane 00096-14-0 169 26461 447417

2-Methyl-2-butene 00513-35-9 1420 26231 3723433

t-2-Pentene 00646-04-8 1047 21783 2281458

23-Dimethylbutane 00079-29-8 090 18965 170438

2-Methyl-1-butene 00563-46-2 638 15351 979200

Toluene 00108-88-3 393 12682 497783


c-2-Pentene 00627-20-3 1028 11853 1218653


2-Methylpropane 00075-28-5 118 9786 115144

Cyclohexane 00110-82-7 114 9561 108746


c-2-Butene 00590-18-1 1426 9027 1287178

Benzene 00071-43-2 069 6124 42524




2-Methylhexane 00591-76-4 109 3992 43324


1-Butyne 00107-00-6 605 3305 199919

Cyclopentene 00142-29-0 669 3296 220392


n-Heptane 00142-82-5 097 2810 27134

2-Methyl-2-pentene 00625-27-4 1103 2648 292135


3-Methyl-t-2-pentene 00616-12-6 1166 2537 295819


22-Dimethylbutane 00075-83-2 111 2430 27002

3-Methyl-c-2-pentene 00922-62-3 1252 2312 289438

t-2-Hexene 04050-45-7 855 2269 193990



24-Dimethylhexane 00589-43-5 161 1392 22345






Total 107832 252202 2339






245

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


n-Butane 00106-97-8 108 6816 73402

n-Hexane 00110-54-3 113 3742 42455


Ethanol 00064-17-5 145 3387 49080

n-Pentane 00109-66-0 121 3097 37631

3-Methylpentane 00096-14-0 169 2395 40491

2-Methyl-2-butene 00513-35-9 1420 2381 337913

t-2-Pentene 00646-04-8 1047 1985 207950

23-Dimethylbutane 00079-29-8 090 1735 15592

Toluene 00108-88-3 393 1702 66802

2-Methyl-1-butene 00563-46-2 638 1455 92799



c-2-Pentene 00627-20-3 1028 1091 112168

Cyclohexane 00110-82-7 114 918 10442


c-2-Butene 00590-18-1 1426 822 117258

Benzene 00071-43-2 069 614 4266



1-Butyne 00107-00-6 605 420 25383

2-Methylpropane 00075-28-5 118 409 4811


2-Methylhexane 00591-76-4 109 397 4310


t-2-Hexene 04050-45-7 855 332 28352

Cyclopentene 00142-29-0 669 320 21388



3-Methyl-t-2-pentene 00616-12-6 1166 278 32432


2-Methyl-2-pentene 00625-27-4 1103 263 28991

n-Heptane 00142-82-5 097 261 2517

3-Methyl-c-2-pentene 00922-62-3 1252 211 26449


22-Dimethylbutane 00075-83-2 111 192 2132











246

Species CAS No MIR

Composite

VOC

mg

Ozone

mg





24-Dimethylhexane 00589-43-5 161 128 2054

Propane 00074-98-6 046 125 0570




n-Octane 00111-65-9 080 098 0779







3-Methylheptane 00589-81-1 112 044 0498

2-Methylheptane 00592-27-8 097 044 0429


ortho-Xylene 00095-47-6 758 035 2631


n-Propylbenzene 00103-65-1 196 031 0598

Ethylbenzene 00100-41-4 296 015 0439

Total 6829 20748 3038


continued


247

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 36810 533364

n-Butane 00106-97-8 108 26480 285167

n-Hexane 00110-54-3 113 21599 245076


n-Pentane 00109-66-0 121 15798 191932

3-Methylpentane 00096-14-0 169 13417 226870

2-Methyl-2-butene 00513-35-9 1420 12566 1783699

t-2-Pentene 00646-04-8 1047 10774 1128460

Toluene 00108-88-3 393 10319 405014

23-Dimethylbutane 00079-29-8 090 9397 84455

2-Methyl-1-butene 00563-46-2 638 7705 491485



c-2-Pentene 00627-20-3 1028 5741 590268

Cyclohexane 00110-82-7 114 5656 64330


c-2-Butene 00590-18-1 1426 4360 621746

Benzene 00071-43-2 069 3722 25841

1-Butyne 00107-00-6 605 3308 200127




2-Methylhexane 00591-76-4 109 2460 26697

2-Methylpropane 00075-28-5 118 2442 28735




t-2-Hexene 04050-45-7 855 1875 160280



Cyclopentene 00142-29-0 669 1630 108972


3-Methyl-t-2-pentene 00616-12-6 1166 1439 167759

2-Methyl-2-pentene 00625-27-4 1103 1392 153551

n-Heptane 00142-82-5 097 1191 11503



3-Methyl-c-2-pentene 00922-62-3 1252 1118 139900

24-Dimethylhexane 00589-43-5 161 1101 17683



22-Dimethylbutane 00075-83-2 111 996 11062





248

Species CAS No MIR

Composite

VOC

mg

Ozone

mg









n-Octane 00111-65-9 080 676 5383



Propane 00074-98-6 046 584 2670


ortho-Xylene 00095-47-6 758 532 40274


n-Propylbenzene 00103-65-1 196 490 9599




3-Methylheptane 00589-81-1 112 429 4820

14-Diethylbenzene 00105-05-5 439 417 18308



2-Methylheptane 00592-27-8 097 275 2658

Indan 00496-11-7 323 271 8760

n-Nonane 00111-84-2 068 254 1733


n-Decane 00124-18-5 059 145 0857

Ethylbenzene 00100-41-4 296 134 3977

Total 38384 118469 3086


continued


249

Species CAS No MIR

Composite

VOC

mg

Ozone

mg


Ethanol 00064-17-5 145 29218 423362

n-Butane 00106-97-8 108 29007 312377

n-Hexane 00110-54-3 113 24380 276633


3-Methylpentane 00096-14-0 169 15596 263709

n-Pentane 00109-66-0 121 15520 188558

2-Methyl-2-butene 00513-35-9 1420 12658 1796850

23-Dimethylbutane 00079-29-8 090 11129 100014

t-2-Pentene 00646-04-8 1047 10500 1099738

Toluene 00108-88-3 393 10002 392585

2-Methyl-1-butene 00563-46-2 638 7489 477698



c-2-Pentene 00627-20-3 1028 5759 592056

Cyclohexane 00110-82-7 114 5744 65330

2-Methylpropane 00075-28-5 118 5722 67323

c-2-Butene 00590-18-1 1426 4971 708857


Benzene 00071-43-2 069 3956 27472

1-Butyne 00107-00-6 605 3534 213821




2-Methylhexane 00591-76-4 109 2413 26182


t-2-Hexene 04050-45-7 855 2057 175842



3-Methyl-t-2-pentene 00616-12-6 1166 1706 198941

Cyclopentene 00142-29-0 669 1599 106896

2-Methyl-2-pentene 00625-27-4 1103 1593 175741


n-Heptane 00142-82-5 097 1492 14408

3-Methyl-c-2-pentene 00922-62-3 1252 1338 167511


22-Dimethylbutane 00075-83-2 111 1217 13527



Propane 00074-98-6 046 992 4536


24-Dimethylhexane 00589-43-5 161 840 13485






250

Species CAS No MIR

Composite

VOC

mg

Ozone

mg












n-Octane 00111-65-9 080 380 3024





3-Methylheptane 00589-81-1 112 287 3222


2-Methylheptane 00592-27-8 097 259 2502

ortho-Xylene 00095-47-6 758 227 17173





Naphthalene 00091-20-3 328 172 5634

Unknown 16 302 169 5123

n-Nonane 00111-84-2 068 152 1040

n-Decane 00124-18-5 059 151 0890

Ethylbenzene 00100-41-4 296 150 4447

Indan 00496-11-7 323 132 4264

n-Propylbenzene 00103-65-1 196 120 2348

4-Methyloctane 02216-34-4 085 118 1002

Unknown 5 302 112 3400


t-3-Heptene 14686-14-7 617 104 6411




14-Diethylbenzene 00105-05-5 439 090 3928

33-Dimethylhexane 00563-16-6 115 083 0954

c-2-Heptene 06443-92-1 708 077 5453

13-Butadiene 00106-99-0 1245 052 6436

Unknown 3 302 036 1101

Total 38356 116460 3036


continued


251


E0 E10 E20




DVPE psi 701 730 849

Oxygenates--D4815

MTBE vol 000 000 000

ETBE vol 000 000 000

EtOH vol 000 954 2034

O2 wt 000 353 747





D86 Distillation

IBP degF 974 1040 1022












EP degF 3603 3600 3406



Loss vol 09 12 07


Data from CRC E-74



252








(R+M)2 885 889 890








CH Ratio 6200 6092 5835

Oxygen wt 0008 1 340 773




Oxygen wt 0008 3396 7733

C+H wt 9999 9660 9227

H wt 1389 1362 1350

C wt 8610 8298 7877

Fuel Units 6 7 4


Average D3338 Btulb 18579 18514 18491


DHA Btulb 18703 18016 17160





Documents

CRC Report No. E-77-2c STUDY TO - Coordinating Research Council