CORPORATION Environmental Services · field trip report hunterstown road superfund site straben township, pennsylvania tes viii u.s. environmental protection agency office of waste

CORPORATIONEnvironmental Services

53 Darby RoadPaoli, PA 19301

Telephone: 215-889-3900Fax: 215-889-9474

Mr. Frank VavraU.S. Environmental Protection Agency841 Chestnut StreetPhiladelphia, Pennsylvania 19107

Subject: Field Trip Report Soil Sampling TaskHunterstown Road SiteContract No. 68-W9-0005Work Assignment No. C03016November 22, 1991

Dear Mr. Vavra;

Please find enclosed the field trip report for the additionalsoil sampling task conducted by Dynamac at the subject site onOctober 28, 1991.

If you have any questions or comments, please contact either KirkMcCutcheon or myself at (215) 889-3900.

submitted

Carl RodzewichProject Manager

cc: Ms. Donna McGowan, U.S. EPA Region III CERCLA RPOMr. Robert Stecik, Jr., Dynamac, Paoli OperationsMr. Kirk McCutcheon, Dynamac, Paoli Operations

Corporate Headquarters: The Dynamac Building, 2275 Research Boulevard, Suite 500, Rockville, Ml£{2pf 5£3g ) 368

FIELD TRIP REPORTHUNTERSTOWN ROAD SUPERFUND SITESTRABEN TOWNSHIP, PENNSYLVANIA

TES VIII

U.S. ENVIRONMENTAL PROTECTION AGENCYOffice of Waste Program Enforcement

Philadelphia, PA 19107

Work Assignment No.EPA RegionSite No.Contract No.Dynamac No.Prepared ByWork Assignment ManagerTelephone No.EPA Primary ContactTelephone No.Date Prepared

C03016III3PE168-W9-0005P019-C01Dynamac CorperationCarl Rodzewich(215)889-3900Frank Vavra(215)597-0676November 22, 1991

PREPARES) BY REVIEWED BY

Carl Rodzewich Kirk McCutcheonProject Manager Manager Geoscience

Department

AR3Q6369

1.0 INTRODUCTION

Dynamac Corporation (Dynamac) recieved Work Assignment (WA) No.C03016 from the U.S. Environmental Protection Agency (EPA) RegionIII office, under contract No. 68-W9-0005 (TES VIII), to providecompliance oversight of Potentially Responsible Parties (PRPs)during a PRP-lead Remedial Investigation/Feasibility Study (RI/FS)at the Hunterstown Road Superfund Site (the Site) located inStraben Township, Adams County, Pennsylvania. Paul C. RizzoAssociates, Inc. (PCR) has been contracted by the PRPs to conductthe RI/FS. As part of the Work Assignment, Dynamac was tasked byEPA to collect soil samples from specific off-Site locations. Thisfield trip report summarizes the sample collection effort, providesmaps of the sample locations, and provides a sample log for futurereference.

1.1 Facility Description

The Site is located 1.5 miles northeast of Gettysburg in StrabenTownship, Adams County, Pennsylvania. The Site occupiesapproximately 22 acres and is located on both sides of HunterstownRoad directly north of the Hunterstown Road/Shealer Roadintersection. Three unnamed tributaries to Rock Creek are adjacentto portions of the Site. The streams, in reference to the Site, arenamed the West, Middle, and East Streams. The Site contains sevenareas of concern: the Former Drum Burial Area No. 1, the FormerDrum Burial Area No. 2, the North Cornfield, the South Cornfield,the Former Lagoon, the Stressed Vegetation Area, and the BorrowArea.

Wastes were deposited at the Site by Frederick Shealer, theproperty owner. The wastes disposed at the Site include solvents,paint sludges, clay sludges, septic tank sludges, and asbestosinsulation. The disposal methods incuded direct dumping, burial,and spray application.

Investigations by the Pennsylvania Department of EnvironmentalResources (PADER), EPA, and PCR have shown elevated concentrationsof the metals: arsenic, chromium, nickel, and zinc, and thevolatile organics: trichloroethylene, 1,1,1-trichloroethane, 1,1-dichloroethylene, chloroform, toluene, ethylbenzene, and methylenechloride.

AR306370

2.0 SAMPLING ASSIGNMENT

On October 7, 1991 Dynamac, as requested by EPA WAM Mr. FrankVavra, submitted a draft statment of work for an additionalsampling activity at the Hunterstown Road Site. The task was inresponse to concerns raised by Mr. Donald Waddel, an adjacentproperty owner. Mr. Waddel alleged that contaminated soils from theformer bed of Middle Stream had been moved to an area adjacent tohis house during land grading operations initiated by himself.Middle Stream had been shown to have been contaminated byactivities at the subject site. Dynamac was to coordinate, with Mr.Waddel, a site visit that was to include the collection of two soilsamples. The sample locations were to be determined by the propertyowner. The samples were to be analysed for metals and volatileorganics.

On Thursday October 17, 1991, Dynamac personnel Carl Rodzewich andDavid Schock met with Mr. Waddel at his home. Mr. Waddel escortedDynamac to the area of concern and identified the locations that hewished sampled. Permission to obtain a background sample from anarea behind his home was obtained.

On October 18, 1991 EPA primary contact Frank Vavra contactedDynamac to add the collection of two additional soil samples to thework assignment. The purpose of the additional samples was todetermine if contaminents had migrated via air dispersion to nearbyresidential properties during the spray application of wastes atthe subject site. The samples were to be analyed for metals. Theactual locations of the samples were determined during a meetingbetween Dynamac and Mr. Vavra on October 23, 1991.

On October 28, 1991, Dynamac personnel Carl Rodzewich and ThomasGreenman completed the sampling assignment. A total of 8 samplesincluding trip blank, rinsate sample, and duplicate sample wereobtained during the visit. The soil samples were obtained from thepredetermined locations and no deviations to the sample locationswere noted. Please refer to the attached sample location map andsample log for a description of the samples.

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AR306372

SAMPLE LOCATION

HUNTERSTOWN ROAD SUPERFUND SITERESIDENTIAL SOIL SAMPLING TASK

SAMPLE LOCATION MAPDYNAMAC INTERNATIONAL INC.

8R306373

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY* REGION

, CENTRAL REGIONAL LABORATORY839 BESTGATE ROAD

ANNAPOLIS, MARYLAND 21401(301) 266-9180

DATE : February 4, 1992

SUBJECT : Region III Data QA Review

FROM : Theresa A. SimpsonRegion III ESAT RPO (3ES31)

TO : Frank VavraRegional Project Manager (3HW23)

Attached is the inorganic data validation report for the Hunterstown RoadSite (Case 17336) completed by the Region III Environmental ServicesAssistance Team (ESAT) contractor under the direction of Region III ESD.

If you have any questions regarding this review, please call me.

Attachment

cc: Carl Rodzewich, DynamacEdward Kantor, EMSL-LVRegional CLP TPO: Stevie Wilding Region: III Lab Code: BETZPA

TID File: 03911020 Task 1099

revised 03/91

Environmental Services Division

Engineering & Sciences CompanyEnvironmental Services Assistance TeamsRegion 3

1419 Forest Drive, Suite 104Annapolis, Maryland 21403

DATE: JANUARY 31, 1992

SUBJECT: INORGANIC DATA VALIDATION, case 17336SITE: HUNTERSTOWN ROAD

FROM: 0»^SIROOS MOSTAGHIMlAl MAHBOOBEH MECANIC^V INORGANIC DATA REVIEWER SENIOR OVERSIGHT CHEMIST

TO: TERRY SIMPSONESAT REGIONAL PROJECT OFFICER

THRU: JULIE ZALIKOWSKI -ESAT ASSISTANT TEAM MANAGER

OVERVIEW

The set of samples for Case 17336 consisted of six soil(6) samples and one (1) associated rinsate blank whichwere analyzed according to the Contract laboratoryProgram (CLP) Routine Analytical Services (RAS) .

SUMMARY

All analytes were successfully analyzed in all samples.Areas of concern with respect to data usability arelisted according to the seriousness of the problem.These include:

MINOR ISSUES

Several blanks had reported results for analytes thatwere >IDL. The reported results for the analytes inthe affected samples which are <5X the blankconcentrations may be biased high and therefore, havebeen qualified "B" on the data summary forms assummarized in the following table:

Analyte Sample type Type of blank

Al, Ca, Fe, Na aqueous preparation

Na soil Preparation

Se soil continuingcalibration (CCB)

fiR306375

page 2 of 3

The ICP serial dilution result was outside of the 10%control limit for the Zn analyte in the soil samples.The reported results for this analyte in the soil

__________samples_haYe been qualified MJM.

The matrix spike recovery was below the lower controllimit (<75%) for the Sb and Se analytes in the soilsamples. The quantitation limit and reported resultsfor these analytes in the soil samples may be biasedlow and have been qualified "UL" and "L" respectively,except when superseded by the "B" qualifier because ofthe blank contamination.

The laboratory duplicate result for the Mn analyte inthe soil samples was outside the control limit,(RPD>20%). The reported results for this analyte inthe soil samples have been qualified estimated, "J".

Replicate method of standard addition analyses wereperformed for As in samples MCDL41 and MCDL45. Thecorrelation coefficients of the MSAs in both sampleswere less than 0.995. The reported results for As inthese samples have been qualified estimated, "J".

Several analytical spike recoveries were low (<85%) forthe Se and Tl analytes. The reported results andquantitation limits may be biased low and therefore,have been qualified "L" and "UL" respectively, for theTl analyte in the affected samples. The data for Sehave already been qualified "L" because of a low matrixspike recovery as previously mentioned.

NOTES

The laboratory duplicate results were outside thecontractual control limits of 20% RPD or ± CRDL for theCu and Mg analytes. However, the technical controllimits of 35% RPD or ± 2xCRDL set in the FunctionalGuidelines, were not exceeded for these analytes.Therefore, Cu and Mg were not qualified on the datasummary forms.

The data was reviewed in accordance with the National FunctionalGuidelines with modifications for use within Region III forEvaluating Inorganic Analyses.

SR306376

\INFORMATION REGARDING REPORT CONTENT

page 3 of 3

OTable 1A is a summary of qualifiers added to theJLaboratory's results during validation.

ATTACHMENTS

TABLE 1A SUMMARY OF QUALIFICATIONS ON DATA SUMMARY AFTERDATA VALIDATION

TABLE IB CODES USED IN 'MMENTS COLUMN

TABLE 2 GLOSSARY OF DATA QUALIFIERS CODES

TABLE 3 DATA SUMMARY FORMS

APPENDIX A RESULTS REPORTED BY LABORATORY FORM Is

APPENDIX B TPO REPORT

APPENDIX C SUPPORT DOCUMENTATIONSM201A01.HR

AR3Q6377

TABLE IX

SUMMARY OF QUALIFIERS ON DATA SUMMARYAFTER DATA VALIDATION

NON-POSITIVE DETECTED

ANALYTE SAMPLE AFFECTED VALUES VALUES BIAS COMMENTS*

Al MCDL47 B High A (30.4 ug/L)

Sb All soil samples L UL Low B (33.4%)

As MCDL41 and MCDL45 J C (0.9903,0.9904)

Ca MCDL47 B High A (82.5 ug/L)

Fe MCDL47 B High A (43.8 ug/L)

Mn All soil samples J High D (91.1%)

Se MCDL41 - MCDL43 B High A (1.1 ug/L)B (71.9%)

MCDL46 L Low B (71.9%)

MCDL44 - MCDL45 L LOW B (71.9%)E (79.0, 81.0%)

Na All soil samples B High A (35.3 mg/Kg)

MCDL47 B High A (346.1 ug/L)

Tl MCDL41, MCDL42, L UL Low E (79.2-83.0%)MCDL44, MCDL47

Zn All soil samples J F (51.0%)

*See explanation of comments on Table IB.

HR3Q6378

_______________ TABLE IB

CODES USED IN COMMENTS COLUMN

A = The preparation or continuing calibration blank had a result >IDL(the result is in parentheses) and the reported results were <5X theblank. The reported results may be biased high.

B = Because of a low matrix spike sample recovery (% recovery is inparentheses), the reported results may be biased low.

C = The correlation coefficients of MSAs were less than 0.995 (the higherresult is in parentheses). The reported results are estimated.

D — The laboratory duplicate result was outside of the control limit (theresult is in parentheses), the reported results are estimated.

E = The analytical spike recovery was less than 85% (the results are inparentheses). The reported results and the quantitation limits maybe biased low.

F = The ICP serial dilution was outside of the control limit (the resul'is in parentheses), the reported results are estimated.

AR306379

TABLE 2

GLOSSARY-OF-BATA QUALIFIER CODES (INORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

U = Not detected. The associated number indicatesapproximate sample concentration necessary to bedetected.

(NO CODE) = Confirmed identification.

B = Not detected substantially above the levelreported in laboratory or field blanks.

R = Unreliable result. Analyte may or may not bepresent in the sample. Supporting data necessaryto confirm result.

CODES RELATED TO QUANTITATION(can be used for both positive"results and sample quantitationlimits):

J = Analyte Present. Reported value may not beaccurate or precise.

K = Analyte present. Reported value may be biasedhigh. Actual value is expected to be lower.

L = Analyte present. Reported value may be biasedlow. Actual value is expected to be higher.

[] = Analyte present. As values approach the IDL thequantitation may not be accurate.

UJ = Not detected, quantitation limit may be inaccurateor imprecise.

UL = Not detected, quantitation limit is probablyhigher.

OTHER CODES

Q = No analytical result.

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APPENDIX A

RESULTS REPORTED BY LABORATORY

FORM 1*3

AR306383

U.S. EPA - CLPEPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEETMCDL41

Lab Name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082

Lab Code: BETZPA Case No.: 17336 SAS No.: SDG No.: MCDL41

Matrix (soil/water): SOIL Lab Sample ID: MCDL41

Level llow/med) : ~~~~~~LOW~~———___ Date Received: 10/30/91% Solids: 81.5

Concentration Units (ug/L or mg/kg dry weight): MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-274'40-22-47440-23-57440-28-07440-62-27440-66-6

AnalyteAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration24200.00

3.403.9091.00.96.43

4330.0036.2020.70165.00

43200.0029.10

4960.00785.00

.0923.80

1290.00.44.96

83.30.32

101.00101.00

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Color After: YELLOW Clarity After: Artifacts: YESComments:SMALL ROOTS

FORM I - IN 7/88

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1INORGANIC ANALYSIS DATA SHEET

MCDL42Lab Name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082


Matrix (soil/water): SOIL Lab Sample ID: MCDL42•Level~(Tow/ned> : "LOW "~——:—•--——_ Date Received: 10/30/91

* Solids: 82.0Concentration Units (ug/L or mg/kg dry weight): MG/KG

•

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

AnalyteAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumchromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration25700,00

3.502.80

109.00.94.48

4070.0035.4022.60130.00

34300.0040.70

5070.001350.00

.0824.00

1600.00.29.96

98,90.31

81.80121.00

C

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PPFPPPPPPPPPPPCVPPFPPFPPNR

Color Before: GREY Clarity Before: Texture: MEDIUMColor After: YELLOW Clarity After: Artifacts: YESComments:SMALL ROOTS

FORM I - IN 7/88

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Matrix (soil/water): SOIL Lab Sample ID: MCDL43Level -(low/med) : ——LOW — —-- Date Received: 10/30/91% Solids: 82.2


GAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumchromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

20800.003.004,0090.50.88.48

3390.0033.0016.50106.00

24800,0071.70

4980.00752.00

.0821.30

1110.00.29.95

78.50.24

58.4084.00

C

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Color Before: GREY Clarity Before: Texture: MEDIUMColor After: YELLOW Clarity After: Artifacts: YES

Comments:SMALL ROOTS & ROCKS

FORM I - IN 7/88

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Matrix (soil/water): SOIL Lab Sample ID: MCDL44Level (low/med) : LOW —-— ._ Date Received: 10/30/91

% Solids: 73.2


CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-39-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6


Concentration

20700.003.802.90

123.001.00.54

1710.0026.2023.7018.10

23600,0055.00

4290.002110.00

.1117.30

1330.00.67

1.1074.60

.2746.8075.00

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Color After: YELLOW Clarity After: Artifacts: YESComments:SMALL ROOTS fit ROCKS

FORM I - IN 7/88

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Matrix (soil/water): SOIL Lab Sample ID: MCDL45Xever~(Tow7med) : LOW————^—__ : Date Received: 10/30/91

% Solids: 80.3Concentration Units (ug/L or mg/kg dry weight): MG/KG

CAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-37439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6

AnalyteAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumchromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide


3.103.40

112.00.78,49

4050.0023.1013.1014.90

18000.0022.80

3420.00918.00

.0914.00

1580.00.59.98

98.10.39

37.6064.50

C

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Color After: YELLOW Clarity After: Artifacts: YES


FORM I - IN 7/88

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U.^ EPA - CLPEPA SAMPLE NO,



Lab Code: BET2PA Case No.: 17336 SAS No.: SDG No.: MCDL41

Matrix (soil/water) : SOIL Lab Sample ID: MCDL46Level ~t±bw/med) - " ~~~ £OW — —- .. __ Date Received: 10/30/91% Solids: 74.7 j

jConcentration Units (ug/L or mg/kg dry weight) : MG/KG t

GAS No.

7429-90-57440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-37439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23-57440-28-07440-62-27440-66-6



3.103.60

294.001.50.52

2190.0026.3017.5016.00

21600,0014.10

2850.002230.00

.1016.70

2340.00.39

1.00132.00

.2645.6092.80

C

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U

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Color After: YELLOW Clarity After: Artifacts: YESComments:SMALL ROOTS

FORM I - IN 7/88

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INORGANIC ANALYSIS DATA SHEETI M C D L 4 7Lab Name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082


Matrix (soil/water): WATER Lab Sample ID: MCDL47Level" (low/med) : LOW — — - - . _ _ Date Received: 10/30/91% Solids: 0.0

Concentration Units (ug/L or mg/kg dry weight): UG/L

CAS No.

7429-90-5 .7440-36-07440-38-27440-39-37440-41-77440-43-97440-70-27440-47-37440-48-47440-50-87439-89-67439-92-17439-95-47439-96-57439-97-67440-02-07440-09-77782-49-27440-22-47440-23 -57440-28-07440-62-27440-66-6

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltcopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

Concentration

35.6012.001.001.001.002.00

129.002.003.003.0013.901.0027.001.00.20

6.00590.00

1.004.00

358.001.003.005.00

C

BUUuuuBUuuBUUUUUuuuBUUB

Q

W

M

pPFPPPPPPPPFPPCVPPFPPFPPNR

00008

Color Before: COLORLESS Clarity Before: CLEAR Texture:Color After: COLORLESS Clarity After: CLEAR Artifacts:Comments:

FORM I - IN 7/88

fin* A cnrr OM Jt-br 7fi )7 UPP t?<;t77_ece_cTTT. -1-31

APPENDIX B

TPO REPORT

AR30639I

Page 1 of 2

TPO: [ ] ACTION [X] PYI Region III

INORGANIC REGIONAL DATA ASSESSMENT SUMMARY

CASE NO: 17336 " yr7-z—LABORATORY: BETZPASDG NO: MCDL41 DATA USER: Stevie WildingSOW: 7/88 . REVIEW COMPLETION DATE: 1/27/92NO. OF SAMPLES: Six (6) MATRIX: Soil

REVIEWER: ESAT

ICP AA Hg CYANIDE

1. HOLDING TIMES _0_ _O_ _O_

2. INITIAL CALIBRATIONS _0_ _O_ _O_ _ _

3. CONTINUING CALIBRATIONS _O_ _O_ _O_ _ _

4. FIELD BLANKS (F=NOT APPLICABLE) _O_ _O_ _O_ _ _

5. LABORATORY BLANKS _X_ _X_ _O_ _ _

ICS _0_

7. LCS _0_ _0_

8. DUPLICATE ANALYSIS _X_ _O_ _O_ _ _

9. MATRIX SPIKE _X_ _X_ _O_ _ _

10. MSA • _X_

11. SERIAL DILUTION _X_

12. SAMPLE VERIFICATION _0_ _O__ _0_ _ _

13. REGIONAL QC(F-NOT APPLICABLE) _F_ _F_ _F_ _ _

14. OVERALL ASSESSMENT _X_ _X_ _O_ _ _0 = No problems or minor problems that do not affect data usabilityX 3 No more than about 5X of the data points are qualified as either estimated or unusable.H = More than about 5X of the data points are qualified as estimated.Z « More than about 5X of the data points are qualified as unusable.A z TPO action requested; use in conjunction uith one of the above codes.

TPO ACTION ITEMS:

AREAS OF CONCERN: Documentation attached (See followina oacres)

\

AR3Q6392

Page 2 of 2

TPO: [ ] ACTION [X] FYI Region III

INORGANIC REGIONAL DATA ASSESSMENT SUMMARY

CASE NO: ..12336.—-_____...__ _ LABORATORY: BETZPASDG NO: MCDL46 " ATA USER: Stevie'WildingSOW: 7/88 REVIEW COMPLETION DATE: 1/27/92NO. OF SAMPLES: One (1) MATRIX: Water

REVIEWER: ESAT

ICP AA Hg CYANIDE

1. HOLDING TIMES _0_ _0_ _0_ _ _

2. INITIAL CALIBRATIONS _O_ __O_ _0_ _ _

3. CONTINUING CALIBRATIONS _O_ _O_ _O_ _ _

4. FIELD BLANKS(F=NOT APPLICABLE) _O_ _O_ _O_ _ _

5. LABORATORY BLANKS _M_ _O_ _O_ _ __

6. ICS _O_

7. LCS _O_ _O_

8. DUPLICATE ANALYSIS _O_ _O_ _O_ _ _

9. MATRIX SPIKE _O_ _O_ _O_ __ _

10. MSA _0_

11. SERIAL DILUTION _0_

12. SAMPLE VERIFICATION _0_ _O_ _O_ _ _

13. REGIONAL QC(F-NOT APPLICABLE) _F_ _F_ _F_ _ _

1 4 . OVERALL ASSESSMENT M O O

<»

TPO

0 No problems or minor problems that do not affect data usabilityX No more than about 5X of the data points are qualified as either estimated or unusable.M More than about 5% of the data points are qualified as estimated.Z More than about 5X of the data points are qualified as unusable.A TPO action requested; use in conjunction with one of the above codes.ACTION ITEMS:

AREAS OF CONCERN: Documentation attached (See followincr paaes)

m

AR306393

APPENDIX C

SUPPORT DOCUMENTATION

U.S. EPA - CLP

3BLANKS

Lab name: BETZ LABORATORIES TREVOSE—— Contract: 68-D9-0082

Lab code: BETZPA Case No.: 17336 SAS No.: SDG No.: MCDL41

Preparation Blank Matrix (soil/water): SOIL

Preparation Blank Concentration Units (ug/L or mg/kg): MG/KG

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

InitialCalib.Blank(ug/L) C

20.012.01.0

-1.31.02.0

25.02.03.03.06.010.027.01.0.2

6.0590.01.14.0

84.81.03.01.1

UUuBUUUUUUUUUuuuuBUBUUB

Continuing CalibrationBlank (ug/L)

1 C 2 C 3 C

20.012.01.0

-1.41.02.0

25.02.03.03.06.8

10.027.01.0.2

6.0590.01.04.0

25.01.03.01.0

UUuBUuuuuuBUuuuuuuuuuuu

26.812.01.01.01.02.0

25.02.03.03.0

13.410.027.01.2.2

6.0590.01.14.0

25.01.03.01.0

BUUUUuuuuuBUUBUUUJLUuuuu

30.612.01.01.01.02.025.02.03.03.014.710.027.01.4

6.0590.01.04.0

-26.41.03.01.0.

BUUuuuuuuuBUUB

UUuuBUUU

Prepa-rationBlank C

5.2202.400.200.236.200.400

16.110.772.600.600

5.6722.0005.400.200.100

1.200118.000

.200

.80035.348

.200

.600

.404

BUBBUUBBUUBUUUUUUUUBUUB

M

P~PFPPPPPPPPPPPcvppFPPFPPNR

FORM III - IN 7/88

00021

AR306395

U.S. EPA - CLP

3BLANKS

Lab name: BETZ LABORATORIES TRE'VOSE—- Contract: 68-D9-0082


Preparation Blank Matrix (soil/water): WATERPreparation Blank Concentration Units (ug/L or mg/kg): UG/L

AnalyteAluminumAntimonyArsenicBarium

I Beryllium•CadmiumBalciumrchromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide


-----

.2 U


1 C 2 C 3 C

30.612.01.01.01.02.0

25.02.03.03.013.310.027.01.0.2

6.0590.01.04.0

-26.41.03.01.4

BUUUUUUUUUBUUUUUUUUBUUB

1.0

.2

U

U

Prepa-rationBlank C

30.40012.0001.0001.0001.0002.00082.5002.0003.0003.00043.800

27.0001.000-.2006.000

590.0001.0004.000

346.1001.0003.0001.000

BUUUUUBUuuB

UuuuuuBUUU

M

PPFPPPPPPPPPPPcvppFPPFPPNR

FORM III - IN 7/88

00022

AR306396

U.S. EPA - CLP

3BLANKS

Lab name: BETZ LABORATORIES TRlVOSE-——-Contract: 68-D9-0082


Preparation Blank Matrix (soil/water): WATER

Preparation Blank Concentration Units (ug/L or mg/kg): UG/L

Analyte



12.01.0

1.0

r.o

uu

u

u


1 C 2 C 3 C

12.01.0

1.0

1.0

uu

u

u

12.01.0

1.0

1.0

uu

u

u

1.0

1.0

u

u

FORM TTT - TN

Prepa-rationBlank C

1.000 B

*7,

M

mpFNRNRNRNRNRNRNRNRFNRNRNRNRNRNRNRNRFNRNRNR

/as

00023

SR3Q6397

i»

U.S. EPA - CLP

3BLANKS

Lab name: BETZ LABORATORIES TREVOSE—-— Contract: 68-D9-0082


Preparation Blank Matrix (soil/water):Preparation Blank Concentration Units (ug/L or mg/kg):

AnalyteAluminumAntimonyArsenicBariumyieryllium•admiumKalcium[ChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide


1.0 U

_


1 C 2 C 3 C

1.0

1.0

U

U

1.0 U 1.0 u

-

Prepa-rationBlank C M

NRNRFNRNRNRNRNRNRNRNRFNRNRNRNRNRNRNRNRNRNRNRNR

00024

HR306398

FORM III - IN 7/88

U.S. EPA - CLP

3BLANKS

Lab name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082


Preparation Blank Matrix (soil/water):

Preparation Blank Concentration Units (ug/L or mg/kg):

Analyte




1 C 2 C 3 C

1.0 u

Prepa-rationBlank C M

NRNRFNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNRNR

FORM III - IN 7/88

00025

AR3Q6399

U.S. EPA - CLP

5A EPA SAMPLE NO.SPIKE SAMPLE RECOVERY

MCDL43SLab Name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082

Lab _Code_:__BETZPA___ Case No.: 17336 SAS No.: . SDG No.: MCDL41

Matrix: SOIL ~~ Level (low/med): LOW

% Solids for Sample: 82.2Concentration Units (ug/L or mg/kg dry weight): MG/KG

AnalyteAluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobalt[CopperKdBignesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZincCyanide

ControlLimit%R

75-12575-12575-12575-12575-125

75-12575-12575-125

75-125

75-12575-125

75-12575-125

75-12575-12575-125

Spiked SampleResult (SSR) C

42.862911.4021555.181111.857711.8744

78.9013131.8663162.8477

184.6763

1310.5625.3564

133.5623

2.003711.0610

11.3306178.1189195.3437

SampleResult (SR) C

3.00324.015690.5014

.8754

.4771

33.004216.4735106.3475

71.7284

752.4379.0811

21.3396

.2862

.9542

.238558.363284.0036

B

BU

U

BU

B

SpikeAdded (SA)

119.279.54

477.0811.9311.93

47.71119.2759.63

119.27

119.27.41

119.27

2.3911.93

11.93119.27119.27

%R

( ~23,4~1 T . 4™97^492.199.5

96.296.794.8

94.7

468.086.994.1

£^JL.9_92!?

93.0100.493.4

Q

Nz~*

&

M

|RFPPPNRPPPNRPNRPCVPNTJ)FPNRFPPNR


FORM V (Part 1) - IN

00028

U.S. EPA - CLP

9 EPA SAMPLEICP SERIAL DILUTIONS

MCDL43LLab -NameT—BETZ"LABORATORIES•TREVOSE Contract: 68-D9-0082


Matrix (soil/water): SOIL Level (low/med): LOW

Concentration Units: ug/L

Analyte

AluminumAntimonyArsenicBariumBerylliumCadmiumCalciumChromiumCobaltCopperIronLeadMagnesiumManganeseMercuryNickelPotassiumSeleniumSilverSodiumThalliumVanadiumZinc

Initial SampleResult (I) C

87189.5212.59

379.403.672.00

14220.23138.3669.06445.83

104173.51300.70

20866.523154.37

89.464649.26

4.00329.14

244.67352.16

B

BU

B

UB

SerialDilutionResult (S) C

92588.2565.95

388.555.0010.00

15343.10143.6074.70'484.90

107727.85364.50

21979.703275.70

93.954621.85

20.001089.30

257.65531.60

B

BUUB

B

B

BB

UB

%Differ-ence

6.2423.8

2.4100.0

. 7.93.88.28.83.421.25.33.8

5.0.6

231.0

5JC5.U07

Q

E

M

PP

PPPPPPPPPPP

PP

PP

PP

FORM IX - IN7/88

00034

fiR306t40

U.S. EPA - CLPEPA SAMPLE NO

6DUPLICATES

MCDL43DLab Name: BETZ LABORATORIES TREVOSE Contract: 68-D9-0082

Lab Code: BETZPA Case No.: "17336.- ' SAS No.: SDG No.: MCDL41

Matrix (water/soil): SOIL Level (low/med): LOW% Solids for Sample: 82.2 % Solids for Duplicate: 81.0


Analyte


ControlLimit '

2.447.7

1192.7

11.9

1192.7

9.5

11.9

Sample (S) C

20798.03443.00324.015690.5014.8754.4771

3392.068633.004216.4735106.3475

24849.365571.7284

4977.4629752.4379

.081121.3396

1109.0263.2862.9542

78.5125.2385

58.363284.0036

B

BU

U

BBUBB

Duplicate (D) C

22474.18302.86255.9136

127.12421.0520.4771

3934.402038.356924.3667144.3252

30479.850775.4735

6383.57902012.0414

.083925.9267968.0335

.2385

.954284.2827

.238564.391088.2997

U

BU

U

BBUBU

%RPD

7.7200.038.233.718.3

14.815.038.730.320.45.1

24.8C9T7T=~: in •

19.413.618.2

7.1200.09.85.0

,-"

Q

*

**

M


00030

AR306l*02

FORM VI - IN7/88

,.,.

U.S. EPA - CLP

8Standard Addition Results



Concentration Units: ug/LEPASampleNo.

MCDL41MCDL41MCDL43MCDL43MCDL43DMCDL43DMCDL45MCDL45

An

ASASASASASASASAS

0 ADDABS

.093

.0944108.099.143.141.078.076

1 ADDCON ABS

10.0010.0010.0010.0010.0010.0010.0010.00

.124

.130

.138

.150

.182

.186

.110

.107

2 ADDCON ABS

20.0020.0020.0020.0020.0020.0020.0020.00

.187

.210

.203

.218

.238

.245

.182

.018

3 ADDCON ABS

30.0030.0030.0030.0030.0030.0030.0030.00

.247

.255

.271

.269

.301

.305

.228

.238

FinalCone.

16.015.617.516.825.824.813.611.9

r.9903.9897.9868.9984.9947.9979.9904.9887

Q

-.-•f+

•f

++

•

FORM VIII - IN 7/88

00033

AR3G6i*03

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