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Technical discussion of the mechanisms, rates, and causes of color shift and light depreciation in LED Lamps
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Copyright © 2012 Cree, Inc. pg. 3
SSL Quality Begins with the LED Lamp
• LED lamp types, construction• Sources of light degradation• Applications impact• Right LED lamp for the application
Copyright © 2012 Cree, Inc. pg. 4
An LED Lamp is a Complex System
LED Chip:– Determines raw
brightness and efficacy
Phosphor system:– Determines color point,
color quality and color point stability
Package:– Protects the chip and
phosphor– Helps with light and heat
extraction– Primary in determining
LED lifetime
pg. 5Copyright © 2012 Cree, Inc.
Different LED Lamp Architectures
Molded Plastic Package, Silver Lead
Frame
Large COB array, Al, Ag Substrate
Ceramic Substrate, Silicone Dome
“High Bright” LEDs designed for consumer
applications
pg. 6Copyright © 2012 Cree, Inc.
1. Chip Degradation
3. Silicone Encapsulant Degradation
2. Phosphor Degradation
Different Sources of Light Degradation
3 Sources
4. Al, Ag Substrate Degradation
5. Plastic Degradation1. Chip Degradation
3. Silicone Encapsulant Degradation2. Phosphor Degradation
5 Sources
4 Sources
1. Chip Degradation
3. Silicone Encapsulant Degradation
2. Phosphor Degradation
4. Plastic Degradation
pg. 7Copyright © 2012 Cree, Inc.
Time (hours)
% L
FLED Chip Degradation (Generic, all types)
• LED chips actually get brighter over the first 10-20k hours of operation
• Real LED chip degradation is very, very slow…
50,000
100%
90%
80%
70%
pg. 8Copyright © 2012 Cree, Inc.
Time (hours)
% L
FPhosphor Degradation (Generic, all types)
• Phosphors are chemically very stable over time also
50,000
100%
90%
80%
70%
pg. 9Copyright © 2012 Cree, Inc.
Phosphor can peel at the edges, let less blue light through to be converted – color shift, loss of light
Possible Sources of Phosphor Degradation
Phosphor coating is put on chip, generally does not degrade
Micro-delaminations can occur over time, thermal stress –further loss of light, potential for color shift
LED Chip
Phosphor
Illuminated Object
pg. 10Copyright © 2012 Cree, Inc.
Time (hours)
% L
FEncapsulant Degradation (Generic, all types)
• Rapid initial degradation (first 5k hrs), stable long term
50,000
100%
90%
80%
70%
pg. 11Copyright © 2012 Cree, Inc.
Encapsulant Degradation Source
Siloxane (R2SiO)n
OSi OSi OSi OSi
R R R R
R R R R
• Silicone encapsulants theoretically cross-link like this:
• Silicone encapsulants actually cross-link like this:
OSi OSi OSi OSi
R R R R
R R R R
OSi OSi OSi OSi
R Si R R
R O
OSi OSi OSi OSi
R Si R R
R O
OSi OSi OSi OSi
R Si R R
R O
CO
CO2
CH3
COCO2
CH3
CH3
• …and a lot of *stuff* comes off them…• Weight loss can slightly reduce RI, long
stranded polymer chains can turn brown/absorb light…
pg. 12Copyright © 2012 Cree, Inc.
Time (hours)
% L
FPlastic & Metal Substrate Degradation
• Similar degradation profiles, plastic degradation is typically a bit more pronounced
50,000
100%
90%
80%
70% Metal (Al, Ag)Plastic
pg. 13Copyright © 2012 Cree, Inc.
Plastic & Metal Degradation Mechanism
• This LED lamp architecture depends on metal substrate and plastic sidewall reflectivity
• Plastic can degrade under photon bombardment and thermal stress
• Metal can tarnish due to application environmental conditions (moisture, sulfur, etc.)
• Both can reduce LED lamp light output…
pg. 14Copyright © 2012 Cree, Inc.
Time (hours)
% L
FPlastic Degradation in Low Cost Packaging
• Plastic degrades quickly and blocks light in this package architecture
• No metal to reflect the light
50,000
100%
90%
80%
70%
Plastic
pg. 15Copyright © 2012 Cree, Inc.
Time (hours)
% L
FCombined: Ceramic/Silicone Dome
• Typical LM-80 performance at 85°C, med-high current density (chip size dependent)
50,000
100%
90%
80%
70%
LED ChipPhosphorEncapsulantCombined
3 Sources
pg. 16Copyright © 2012 Cree, Inc.
Time (hours)
% L
FCombined: Plastic/Metal LF, Substrate
50,000
100%
90%
80%
70%
LED ChipPhosphorEncapsulantMetal (Al, Ag)PlasticCombined
• Typical LM-80 performance at 85°C, med-high current density (chip size dependent)
5 Sources
pg. 17Copyright © 2012 Cree, Inc.
Time (hours)
% L
FCombined: “High Bright” LEDs
50,000
100%
90%
80%
70%
LED ChipPhosphorEncapsulantPlasticCombined
• Typical LM-80 performance at 85°C, med-high current density (chip size dependent)
4 Sources
pg. 18Copyright © 2012 Cree, Inc.
Time (hours)
% L
FTypical LM-80 Performance by Lamp Type
• Ceramic/Si Dome LED lamp architecture generally have superior Lumen Maintenance vs. Plastic/Metal architectures
• Both can be Lighting-class, always demand the LM-80 report
• HB LED Lamps – demand the LM-80 report
• 5mm lamps – LM-80 is NOT defined
50,000
100%
90%
80%
70%
Ceramic/Silicone Dome
Plastic, Leadframe / COB
5mm LEDs“High Brightness” LEDs
Copyright © 2012 Cree, Inc. pg. 19
Light Degradation at the Application Level
Time zero 1000 hours
Brightness
Color
Copyright © 2012 Cree, Inc. pg. 20
☼ Brightness
This may be OK for some consumer
applications
Copyright © 2012 Cree, Inc. pg. 21
☼ Brightness
Copyright © 2012 Cree, Inc. pg. 22
☼ Brightness
Copyright © 2012 Cree, Inc. pg. 23
☼ Brightness
We don’t typically have this kind of
control on our lights…
pg. 24Copyright © 2012 Cree, Inc.
☼ Hue
pg. 25Copyright © 2012 Cree, Inc.
☼ Hue
pg. 26Copyright © 2012 Cree, Inc.
☼ Hue
pg. 27Copyright © 2012 Cree, Inc.
☼ Hue
No remote control for this either…
Copyright © 2012 Cree, Inc. pg. 28
Is it OK for this Application??
Probably for some
markets, probably NOT
for others
Copyright © 2012 Cree, Inc. pg. 29
Very Application Dependent
As Installed
3 Months Later
You don’t want to be that guy…
Copyright © 2012 Cree, Inc. pg. 30
Select the Right LED For Right SSL Application
• LED lamps are complex systems with different parts that degrade at different rates
• Quality and reliability in SSL applications can be very dependent on the LED lamp architecture
• High Bright and 5mm LEDs should not be used for most Lighting Applications
XLamp XP-E
XLamp MC-E
XLamp XP-G
XLamp MP-L
XLamp XP-C
XLamp MX-6
XLamp ML-E/C/B
XLamp MT-G
XLamp CXA2011
XLamp XB-D
XLamp XT-E
XLamp MT-G2
XLamp XP-G2
XLamp XPE-HEW
XLamp XM-L
XLamp XTE-HV
XLamp XML-HV
XLamp CXA1507/12
XLamp CXA2520/30