1999 aldehydes

aldehydes (acyclic compounds)P 0170

50 - 078A Convenient Strategy for the Synthesis of β,γ-Unsaturated Alde-hydes and Acids. A Construction of Skipped Dienes. — Cleavageof diols of type (I) with Pb(OAc)4 provides β,γ-unsaturated aldehydes (II),useful as precursors for eicosanoid products such as arachidonic acid esters(V). — (SAHA, GOUTAM; BASU, MANAS K.; KIM, SEONGJIN; JUNG,YOUNG-JU; ADIYAMA, YURDANUR; ADIYAMAN, MUSTAFA; POWELL,WILLIAM S.; FITZGERALD, GARRET A.; ROKACH, JOSHUA; TetrahedronLett. 40 (1999) 40, 7179-7183; Claude Pepper Inst., Dep. Chem., Fla. Inst.Technol., Melbourne, FL 32901, USA; EN)

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