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CHEM 5331 Advanced Organic Chemistry

CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

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Page 1: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

CHEM 5331 Advanced Organic Chemistry

Page 2: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

I.  BONDING IN ORGANIC COMPOUNDS (What is a “bond”? Do “bonds” exist in organic compounds?)

Group Page

Page 3: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?
Page 4: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

II. STRUCTURE OF ORGANIC COMPOUNDS USING VALENCE BOND APPROACH (How stable is a compound? How reactive is a compound? What is the “relative” rate between compounds?)

Page 5: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?
Page 6: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS (Is there an intermediate? If there is an intermediate, what is the structure? Where is charge located in a transition state?)

Page 7: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?

IV. CASE STUDEIS FOR TYPES OF MECHANISMS (Is a particular mechanism “allowed” to occur? If a particular mechanism does occur,

what conditions will accelerate the reaction rate?)

Page 8: CHEM 5331 Advanced Organic Chemistrybiewerm/TOC.pdf · III. DIFFERENTIATING POSSIBLE REACTION MECHANISMS! (Is there an intermediate? If there is an intermediate, what is the structure?