Breakthrough TechnologiesBreakthrough TechnologiesFor Downstream Oil IndustryFor Downstream Oil Industry

Co

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Co

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2. Breakthrough Technologies

Alternative Energy- Biofuels- Hydrogen-CNG- CTL / Gasification- Shale Oil

Biotechnology

Polymers & Petrochemicals

TechnicalServices

Refinery Technology- FCC/HD - Catalyst- Pipelines (iPIG)

Lubricant

Technology

Nanotechnology

Fuel Additives

IndianOil-R&D

• 52 Pilot Plants

• 61 Research and Technology Partners

• 332 Patents filed till date

• 200 Effective Patents

• 231 Scientists

IndianOil-R&D At a Glance

IISc

BARC

DCE

NCCRIITM

IndianOil-R&DIndianOil-R&D COLLABORATIVE RESEARCHCOLLABORATIVE RESEARCH

IITD

Co

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Co

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nts 1. IndianOil R&D

2. Breakthrough Technologies

Indmax

• Indadept•Kero HDT

Food Grade Hexane

IndianOilR&D

TECHNOLOGY BASKETTECHNOLOGY BASKET

Catalyst

Sweetening Process CFC

• Delayed Coking• Indalin

• DHDT• Isom

Needle Coke

Indmax Technology- Resid to LPG, Light Olefins & High Octane Gasoline

Technology demonstrated in 2003Can process wide variety of feedstocks including Atmospheric Residue and Vacuum Residue with CCR upto 11 wt%

High flexibility to produce LPG, Gasoline and diesel.

Employs proprietary catalyst formulationTypical product yields

LPG 35-50 wt% (Propylene 45-50wt% in LPG) Gasoline 20-40 wt% (High octane 98+) Diesel 15-25 wt%

INDMAX unit at GR (100,000 TPA)

BRPL (0.74)

Paradip (4.0)

INDMAX

Guwahati

(0.1)

Worldwide licensing through Lummus Technology Inc., USA

Proposals submitted to various refineries globally– Takreer, Ras Tanura, Idemitsu, Japan, OMV, Austria (Aug’08), PTTAR, Thailand (Sep’08)

Digboi (0.1)

Polymer Grade Hexane (PGH) /Food Grade Hexane (FGH)

Joint Technology Licensing with EIL

28,000 TPA Unit operational at Gujarat Refinery

1 Unit (20,000 TPA) licensed to Bhatinda Refinery

PGH and FGH from PGH and FGH from paraffinic Naphtha and paraffinic Naphtha and raffinate from Aromatic raffinate from Aromatic Extraction UnitExtraction Unit

Benzene Reduction Benzene Reduction

Feed : 1.3-4 %Feed : 1.3-4 %

Product : < 100 ppmProduct : < 100 ppm

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DHDT Technology

• Can upgrade straight run as well as cracked diesel

streams • Sulphur reduction from ~1.8% to less than 50/ 10 ppm

• Cetane improvement by 7-10 units

• Proprietary catalyst

• Joint licensing with Engineers India Ltd.

• 1.2 MMTPA unit under construction at Bongaigaon

Refinery. Commissioning in Mar, 2010

• 5.0 MMTPA unit under implementation at Paradip

Refinery based on process data input from IOC R&D

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INDAdept ProcessAdsorptive Deep desulphurisation

• Only novel adsorptive, low

cost, efficient deep desulphurisation technology for both Gasoline and Diesel

• Proprietary adsorbent in hydrogen environment

• Two reactors operated in

swing mode of adsorption and regeneration

Adsorption Regeneration

H2

AirN2

Diesel

1 2

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INDAdept Process

INDAdeptD

• S reduction from 500 to < 10 ppm• No change in cetane & other properties• H2 consumption 0.1 wt% only

INDAdeptG

• S reduction from 1000 to < 10 ppm• RON reduction of ~ 2 units• H2 consumption 0.2 wt% • Suitable for treating Coker/ FCC gasoline• Employs single reaction step

Category – Technical Development “Hydro-Processing Technology for Green Fuels

World Petroleum Congress Award

Chairman, IOCL Receiving the Award from King of Spain: WPC 2008

INDALIN+ Value addition from Naphtha/Condensate

– 50-55% LPG with <3% olefins meeting Auto Grade spec.

– 17-34% High Octane Gasoline (95+) with 95% Sulphur reduction

– 25-30% BTX in gasoline– Can also handle gas oil range feed stocks– No external hydrogen supply and feed

desulfurization– Proprietary catalyst– Process developed for upgrading

condensate to Propylene/ Ethylene / LPG for Saudi Aramco. Propylene yield ~18% on feed.

Delayed Coker

• Joint Licensing with EIL

Needle Coke Commercialized at GR in 2003

Licensed to BGR in 2003 & NRL in 2007

Value addition ~ $700-800 per MT of Needle Coke

Light Naphtha Isomerisation•Joint licensing with EIL•Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010

Other TechnologiesOther Technologies

Light Naphtha Isomerisation•Joint licensing with EIL•Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010

Other TechnologiesOther Technologies

FCC catalyst and additive technology (i-Max series) for

LPG & Propylene enhancement

• ZSM-5 additives (i-MAX, i-MAX Super, i-MAX Supreme

and i-MAX Ultra)- Used in IOC and non-IOC refineries in

India

• Propylene selective ZSM-5 additive

• Metal Passivator additive for RFCC units

FCC & RFCC Catalysts & Additives

DHDT Catalyst

Commercial demonstration of INDICAT-DH-IV

• Demonstrated at CPCL in Jun, 09

• Consistent performance with Diesel meeting Euro-IV/V

quality

• 88- 90% Desulphurisation in VGO mode

• Delta Diesel Cetane (Product- Feed) of 7 units under 55

Kg/cm2g

• FCC & RFCC (FCC MOD)• Hydrocracker (HC MOD)• CRU (REF MOD)• Diesel-hydrodesulphurisation (DHDS-MOD)• Delayed Coker • Hydrogen Generation Unit

Used for Troubleshooting, Optimization, Process design, catalyst evaluation and Technology development

PROCESS SIMULATORSPROCESS SIMULATORS

TECHNICAL SOLUTIONSTECHNICAL SOLUTIONS

• Right Fit Technology Selection & Licensing

• Revamp of Process Units• Catalyst Management

– FCC/Hydroprocessing– Catalyst Selection– Catalyst Health Monitoring– Remaining Life Prediction

• Process Optimisation• Troubleshooting• Static Equipment Inspection Services• Unit Turnaround Management

• SERVO-LI Lubricity improver for diesel – Excellent Lubricity Performance– Biodegradable source– Good Storage Stability

• SERVO-AO : for gasoline – Excellent Oxidation Stability– High Storage Life– Minimum Treat Cost

• MFA for diesel – High Performance– Component in Premium Diesel

FUEL ADDITIVESFUEL ADDITIVES

BioremediationOiliVorous-S

Oily sludge site before treatment

Oily sludge site after treatment

•Bio-Process for bioremediation of oily sludge using OiliVorous-S bacteria.

•In use at refineries, marketing & pipeline installations at both IOC & Non-IOC locations since 1994.

•Bioremediation carried out both on sea and on-shore.

•Good results obtained on sea using bacteria, especially designed to weather high salt concentration.

Before treatment After treatment

Bioremediation of oil contaminated water at Duliajan

(Assam)

BioremediationOiliVorous-S

Automobile Industry

Textile

Chemical

Railways

CementAviation

Defence

Steel

LubricantTechnology

LUBRICANTS LUBRICANTS The TECHNOLOGY BASKETThe TECHNOLOGY BASKET

SERVO Lubricants Covering:•Automotive oils

• Rail Road Oil • Marine Oil• Industrial lubricants • Metal Working oils • Jute Batching Oils• Rubber Process oils • Agro spray oils • High Performance Greases• Synthetic Lubricants

More than 4000 formulations accounting for

~ 800 commercial grades

With strong R&D backup, SERVO holds 38% National Lube Business

About 200 New and Revised formulations

every year

• High performance engine oils meeting latest

API, ACEA, JIS and OEM customized

specifications

• Gas Engine Oils

• Energy efficient, long life industrial lubricants

& greases

• Synthetic compressor, gear, specialty

lubricants

• NSF listed food grade lubricants & greases

• Biodegradable lubricants

LUBRICANTS LUBRICANTS TECHNOLOGY BASKETTECHNOLOGY BASKET

Marine Oils

Servo RR 606MGFirst ever Multi-grade RR Oil in India

Indian Railways saved

over $ 200 million since 2000

LUBRICANTS LUBRICANTS RAILROAD OILRAILROAD OIL

AFRICA 2008• Total Energy Consumption: 453 Mmtoe (4% of world

consumption)

• Total Proven Oil Reserves: 125.6 Billion barrels (10% of world reserves)

• Crude Oil Production: 10.3 million bopd (12.5% of world oil production)

• Total Oil Consumption: 2.9 million bopd (3.4% of world consumption)

• Total Refining Capacity: 3.2 million bopd ( 3.65% of world refining capacity)

AFRICA 2008

Th bpd

0

200

400

600

800

1000

1200

1400

LT Dist MD Dist FO Others

‘000

bpd 666

1232

429554

0

10

20

30

40

50

60

70

80

0

5

10

15

20

25

30

35

AFRICA 2030

Product Deficit Product Surplus

LP

G

MS

Je

tKe

ro

H

SD

Oth

ers

T

ota

l

5

24

3

38

1

71

Na

ph

tha

F

O

To

tal

11

25

36

Figs in MMTPA

Net Product Deficit:35 MMTPA

33

Diesel Quality worldwideDiesel Quality worldwide

Our Offering

Novel Technologies, Technological Solutions & Technical Services for :– Refinery Revamp/ Modernization– Setting up Green Field Refineries, and Installations,– Efficiency , Productivity & Profitability Improvement,

Energy Conservation etc

– Value Addition – Product Quality Improvement– Reliability Enhancement– Product, Crude Oil & Gas Pipleines – Environment Protection– Collaborative R&D