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  • 7/28/2019 B. Hilton - Alstom CCS Portfolio and Cost Analysis

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    Robert G. Hilton

    June 18. 2013

    Alstom CCS Portfolio and CostAnalysis

    RECS- Research Experience in

    Carbon Sequestration, Birmingham,AL

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Equipment & services for powergeneration

    Alstom Thermal PowerEquipment & services for rail transport

    Alstom Transport

    Three main activities in 4 sectors*

    Equipment & services for powertransmissionAlstom GridAlstom Renewable Power

    * Organisation as of 4 July 2011Alstom CO2 Capture Systems - P 2

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CO2 capture technologiesInitially developed for CCS on Power Generation

    Source: Vattenfall

    Pre-combustion(New only)

    Power Plant with CO2 capture

    Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)

    Alstom CO2 Capture Systems - P 3

    Alstom focuses on post and oxy to also address installedbase

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Technologies developed by Alstom

    CO2 capture technologies pursued by Alstom

    Post-combustion Oxy-combustion(New + retrofit) (New + retrofit)

    Advanced Amines Process Chilled Ammonia Process Oxy-combustion with ASU

    Alstom CO2 Capture Systems - P 4

    Regenerative Calcium Cycle(RCC)

    Chemical Looping Combustion(CLC)

    2ndGeneration

    2ndGeneration

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CO2-EOR

    Carbonates

    Methanol

    Urea

    Underground

    permanent

    Storage

    Food industry

    CO2capture unit

    Industrial fluegas with CO2:

    Power Steel mill Cement factory Refinery Methanol

    plant, Ethanol plant Fertilizer plant etc

    Classic CCS(Saline Aquifers ordepleted Oil & Gasfields)

    CCU Chemicalusage

    Current prospectsin Fertilizer andcarbonates

    CO2-EOR : hugepotential in the USA

    CO2 utilizationCaptured CO2 for EOR or Chemical Production

    CCU and EOR can stimulate CO2 capture market through valuation of CO2

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Advanced Amine ProcessTechnology Overview

    Advantages

    Proven in natural gas & syngaspurification

    CO2 capture from flue gas is a newapplication

    More efficient capture of CO2 and lesssolvent degradation than MEA

    Higher tolerance against oxygen & tracecontaminants

    Source: Alstom

    Principle

    An amine based solvent reacts with theCO2 in the flue gas

    Raising the temperature reverses thisreaction, the CO2 is released and the

    solvent recycled

    A strong team to develop a new application

    Alstom CO2 Capture Systems - P 6

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Pilot CommercialIndustrial / ValidationLarge-scale

    demonstration

    University of TexasUSA

    2007 2009 2011

    Advanced Amine ProcessUpdate on Alstom roadmap

    Dow Chemical Co.USA - 2MWth, Coal

    EdF Le HavreFrance - 5 MWth,Coal

    Tests completedIn operation

    Moving forward to scale-up the technologyAlstom CO2 Capture Systems - P 7

    2020 &

    beyond

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Advanced Amine ProcessC2A2Field Pilot - Le Havre (France)

    Designed to capture 25 t CO2/ day,90% CO2 capture

    Advanced flow scheme & operationvalidation

    Flue gas: slipstream from 600 MWecoal plant (EdF host facility)

    French funding by ADEME Project schedule

    - Overall 2010-2013 program- Now in commissioning / start-up- Test from Q1 13 to Q1 14 (1

    year)

    Alstom CO2 Capture Systems - P 9

    EdF Le Havre coal power plant(field pilot represented in

    orange)

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Principle

    Ammonium carbonate solution reacts withCO2 of cooled flue gas to form ammoniumbicarbonate

    Raising the temperature reverses thisreaction, pressurized CO2 is released, thesolution is recycled

    Chilled Ammonia ProcessTechnology Overview

    Advantages

    High CO2 purity Tolerant to oxygen and flue gas

    impurities Stable reagent, no degradation nor

    emission of trace contaminants

    Low-cost, globally available reagentAlstom CO2 Capture Systems - P 10

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Roadmap to commercialization

    Test Rigs ValidationPilots

    CommercialIndustrialPilots

    Large-scaledemonstration

    Alstom

    Vaxj

    Sweden0.25 MWth

    We Energies

    Pleasant PrairieUSA - 5 MWth, Coal

    EoN KarlshamnSweden - 5 MWth, Oil

    AEP MountaineerUSA - 58 MWth, Coal

    TCM MongstadNorway - 40 MWth, Gas

    Getica Turceni FeasibilityRomania - >250 MWe net, Lignite

    2006 2008 2009

    Testssuc

    cessful

    Tests completed Key TargetsIn Operation

    Chilled Ammonia ProcessUpdate on Alstom roadmap

    CO2 Capture Mongstad (CCM)Norway- 280 MWe + 350 MWth,CCPP

    Alstom CO2 Capture Systems - P 11

    2020 &beyond

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Chilled Ammonia ProcessWe Energies Field Pilot Pleasant Prairie (WI, USA)

    Operational June 2008 Oct 2009 7700+ hours of operation on flue gas

    from PRB Coal through completion ofprogram in Oct 2009

    Proof of Concept technology validation:90% CO2 capture efficiencyNH3 slip from DCC2 (~5 ppm)99+% CO2 purity; >10 ppm NH3;

    >2,000 ppm H2O

    Functional unit operationsConfirmation of process design toolsConfirmation of equipment design

    methodsCO2 Field Pilot at Pleasant

    Prairie

    Alstom CO2 Capture Systems - P 12

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Chilled Ammonia ProcessField Pilot - Karlshamn (Sweden)

    Designed to capture over 1,600 kg CO2/hr(~15,000 tonnes/yr at full capacity)

    Operational Apr 2009 Test phase completed in 2010 Flue gases from sulfur fuel oil and from gas

    combustion tested Located less than 60 miles (90 km) from

    Alstoms Global Technology Center in Vaxjo

    Proof of Concept technology validation:- 90% CO2 capture efficiency- NH

    3slip from DCC2 (~5 ppm)

    - 99+% CO2 purity;

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Designed to capture & store 100,000 tCO2/year Commenced engineering and permitting Oct07 First CO2 captured in Sept 09, Captured CO2 sequestered into through two wells on

    the plant property, first injection started 1st of

    October 2009Alstom responsible for CAP island (others by AEP) Test completed and succesful:

    Approx 52000 tons of CO2 capturedApprox 37000 tons of CO2 storedCO2 product quality : 99.94%Capture rate: 90% validatedLow ammonia emissions observed

    Chilled Ammonia ProcessValidation Pilot - AEP Mountaineer (WV, USA)

    Alstoms Chilled Ammonia Process atAEPs PPTests completed - Technology validated Ready for scale-up

    Alstom CO2 Capture Systems - P 14

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Chilled Ammonia ProcessDemonstration project at Turceni

    Integrated CCS demo: 1.5 Mtpa CO2 Capture: 85% minimum capture Transport: onshore pipeline Storage: deep saline aquifers (>800m) within

    a radius of 50 km

    Developers-Operators: Capture: Turceni Energy Complex Transport: Transgaz Storage: Romgaz

    Technical Consortium: Project Management and Technical &

    Financial Consultant: ISPE (Institute forStudies and Power Engineering)

    Capture Plant: Alstom Storage: GeoEcoMar, Schlumberger

    Alstom feasibility study completedTurceni Power Plant4x330 MW

    Alstom CO2 Capture Systems - P 15

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    16

    LTS USC PC Power Plant with CAP PCCPlot Plan

    LTS CAP PCC Plant Area

    CO2 RegenerationArea

    Back-PressureTurbine

    EvaporativeCondenser

    Flue Gas Cooling &CO2 AbsorptionArea

    CO2 Compression

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS on GasPost-combustion CO2 Capture solution for Combined Cycles

    Gas-fired power plants with CCS - 6/27/13 - P 17

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    European CO2 Technology Centre Mongstad(TCM)

    Flue gases from natural gas-fired CCPP anda catalytic cracker (refinery)

    Designed to capture 80 000 tons CO2/year Cold commissioning initiated on some

    systems that are mechanically complete

    Currently in commissioning / start-up phase

    CCS DevelopmentsCAP on Gas Validation Pilot Mongstadt, Norway 54 MWth

    Gas-fired power plants with CCS - 6/27/13 - P 18

    Post-combustion CO2 capture (Chilled Ammonia) technology

    validation on-going for application to gas-fired power plants

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    European CO2 Technology Centre Mongstad NorwayChilled Ammonia Process

    Unique Validation Features / Expectations Main validation facility for CO2 Capture

    Mongstad

    CO2 Sources: Flue gases from natural gas CHP plant Off-gases from the RCC

    Validation plant, designed to capture: 80 ktons CO2/year (RCC) & 22 ktons CO2/year

    (CHP)

    First CAP pilot on industrial source Incorporation of know how from previous pilots Compact and efficient layout (1300 m2) Commissioning performed Testing on-going

    Mongstad supports CAP validation on gas & industrialAlstom CO2 Capture Systems - P 19

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Conservative assumption based on today's CCStechnology and fully independent, not integrated auxiliary

    system

    Power Island

    Additional cooling towers for CCS plant

    Cooler / Blower

    CO2 Capture Plant

    ColumnAbsorption

    ColumnRegeneration

    FGR loop

    CCS on GasCapture Ready: KA26 plant arrangement example

    Gas-fired power plants with CCS - 6/27/13 - P 20

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Oxy-Combustion ProcessTechnology Overview

    Advantages ReliabilityAdaptable to all boiler types and fuels Rapid scale-up to 1,000 MWe range Offers options for operational

    flexibility Retrofit in Oxy can be addressed Higher efficiency with supercritical/

    ultra-supercritical cycles

    Principle

    Fuel is burned in a mixture of oxygen and re-circulated flue-gas. Due to the absenceof Nitrogen, the resulting flue gas is enriched in CO2

    After water condensing and further purification, CO2 is compressed and send tostorage

    Alstom CO2 Capture Systems - P 21

    A robust and competitive solution

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Moving forward to scale-up the technology

    Oxy-Combustion ProcessUpdate on Alstom roadmap

    Alstom CO2 Capture Systems - P 22

    Targeted

    Commercial

    2020 &beyond

    White Rose 426MWe g - Selby(UK)

    1990s

    R&D and Labscale Large scaledemonstration

    Inoperation

    Alstom BSFUSA - 15 MWth,

    VattenfallSchwarze PumpeGermany - 30 MWth,

    Total LacqFrance - 30 MWth,

    GPU mobile pilot

    Pilots

    2008 2012

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    (source: Vattenfall)Schwarze Pumpe Pilot

    Oxy-Combustion ProcessVattenfall Schwarze Pumpe 30 MWth pilot

    Experience makes successpossible

    Objective

    Demonstration of the technology pathat pilot scale

    Alstom-Scope

    Oxy-boiler, ESP and othercomponents

    Technology Partnership withVattenfall

    Status of Operation Start of operation: Sept 2008 Test with Alstom Burners completed

    Alstom CO2 Capture Systems - P 23

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Main features

    Retrofit to oxy-combustion of a 30 MWthexisting boiler (natural gas)

    Located in SW of France Oxy-combustion process started Jul 09 End test expected end 2012 (18 mths

    extension of the original programme)

    Approx 120,000 t CO2 to be stored in adepleted gas field

    ALSTOM scope : Boiler retrofit30 MWt retrofitted Boiler Lacq,

    France

    (source: Total)

    First fully integrated CCS with pipeline transportation &storage

    Oxy-Combustion ProcessTOTAL Lacq - 30 MWth Pilot

    Alstom CO2 Capture Systems - P 24

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    15 MWth Boiler SimulationFacility : multi-burner,tangentially-fired

    Flexible operatingconditions :Air & oxy-firing, gas recycleconfiguration, oxygeninjection, firing system design

    Generation ofdetaileddesign and performance

    data : Combustion,emissions, heat transfer, ashdeposition, corrosion;

    Project start : 2008,Duration : 5 years

    Project Team:Alstom, DOE NETL, ICCI NDIC

    Utility Advisory Group :

    Oxy-Combustion ProcessAlstom Windsor 15 MW Pilot

    Alstom CO2 Capture Systems - P 25

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Oxy-Combustion ProcessGPU Pilot Tests in Alstoms CCS test centers

    FTIRGas

    Analysis

    Controlroom

    GPU in Windsor

    GPU at the CCS test center Vaxjo

    PurificationPilot

    CompressionPilotVxj (Sweden) : synthetic gas test

    program

    Drying and cryogenic-purification Behaviour of SOx and NOx during

    compression Dryer operation and desiccant and

    regeneration

    Mobile GPU Pilot in operation since2011

    Windsor (CT-US) : coal & synthetic flue gastests

    Drying, Ash, Hg and other heavy metals,VOC and cryogenic-purification

    Behaviour of SOx and NOx duringcompression

    Co-adsorption behaviour of SOx and NOx indesiccant and regenerationGPU pilot : an extensive validation programme

    Alstom CO2 Capture Systems - P 26

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Oxy-Combustion ProcessThe White Rose large scale OXY-Demo project, UK

    Largest Oxyfuel CCS Demo

    A new modern ultra-supercritical426MWe Gross Oxy-fuel Power Plant

    Clean power generation with theentire flue gas treated to capture 2Million t/y CO2

    Biomass co-firing option leading tozero (or negative!) CO2 emissions

    Anchor project for National Grids(NG) regional CO2 transport &

    offshore storage network Project development activities on-

    going

    Selected as one of the two preferredbidders for a FEED study under theUK CCS competition (1 Billion GBP

    funding).

    Location: DraxPower Station,

    North Yorkshire,UK

    Project Promoters

    Oxy-fuel Power Plant CO2 Transport& Storage

    ALSTOM DRAX NATIONAL GRIDBOC-Linde

    Alstom CO2 Capture Systems - P 27

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS-evaluation of 2nd generation technologiesChemical Looping Combustion (CLC)

    A promising breakthrough technology

    Advantages

    Potential for low CoE and low energypenalty by limiting the cryogenic ASU of 1stgeneration oxy process;

    Development from Alstoms CFBexperience.

    Principle OPERATION IN OXY-COMBUSTION Combustion occurs in an atmosphere free of nitrogen. In the Air Reactor, a solid carrier

    absorbs oxygen from the air and is conveyed to the Fuel Reactor where the oxygen isreleased and combustion with the fuel occurs. Solid carrier is then taken back to the AirReactor, closing the loop.

    Oxygen carriers can be metal oxide or limestone-based. Alstom works on both types.

    Status 2 pilots in operation :

    1 MWt (CLAIR in DarmstadtUniversity-Germany-RFCS funding) 3 MWt (Alstom Lab Windsor CT

    sponsored by US DoE)

    Alstom CO2 Capture Systems - P 28

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS-evaluation of 2nd generation technologiesRegenerative Calcium Cycle (RCC)

    A new post-combustion system with potential for Power andIndustry

    Advantages Promising energy penalty and CoE; RCC produces Power : no loss of net electrical output (value for retrofit and industry) Widely used feedstock, potential synergies with industries like cement).

    Principle A POST-COMBUSTION SYSTEM In the Carbonator, CO2 from the flue gas reacts with lime (CaO) forming limestone. In the

    Calciner, limestone is converted into lime and CO2, pure CO2 can then be easily captured;

    Status 1 pilots in operation : 1 MWt (LISA in Darmstadt University-Germany-RFCS funding)

    CARBONATOR

    CaO + CO2 CaCO3

    CALCINER

    CaCO3 CaO + CO2

    CO2-lean flue gasPure CO2 +

    H2OMake-up CaCO3

    (limestone)

    Coal

    Pure O2

    CaOdeactivated lime

    CaCO3

    CaO

    Flue gas from powerplant or industry

    Lime is taken back to thecarbonator, closing theloop.

    Alstom CO2 Capture Systems - P 29

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CompletedTESTS COMPLETE

    AEP MountaineerUSA 58 MWthChilled Ammonia, Coal

    EoN KarlshamnSweden - 5 MWthChilled Ammonia, Fuel

    WE - Energie

    USA WI - 5 MWthChilled Ammonia, Coal

    DOW Chemical Co.USA, WV

    Adv. Amines - Coal

    CCS is happening

    OPERATING

    Vattenfall SchwarzePumpe, Germany30 MWth, Oxy - Lignite

    Total LacqFrance - 30 MWthOxy - Gas

    Alstom BSF Windsor

    US - 15 MWthOxy - Coals

    2nd Gen

    DOE/Alstom WindsorUS - 3 MWthChemical Looping, Coal

    Alstom Labs Vxj

    Sweden 0.25 MWthPost C.-multi purpose

    RFCS EU - DarmstadtGermany - 1 MWthChemical Looping - Coal

    2nd Gen

    TCM Mongstad Norway40 MWth, Chilled Ammonia,CHP & Refinery Offgas (RCC)

    Alstom GPU Pilot (Mobile)0.3 MWth

    OPERATING COMMISSIONING

    EDF Le HavreFrance - 5 MWth Adv.

    Adv. Amines - Coal

    LARGE-SCALE PROJECTS(under development)

    White Rose CCS ProjectUK - 426 MWeOxy Hardcoal

    CCM Mongstad(Gas Turbine based CHP)Norway 280 MWe + 350 M WthChilled Ammonia

    Getica - CET TurceniRomania - >250 MWeChilled Ammonia-Lignite

    CCS : a competitive clean power option February 11th, 2012 - P 30

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty isgiven or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS experience: 16 pilots/demos

    Component manufacturer

    Alstom know-how for a solidCoE study on CCS PP

    IntroductionAlstom Cost of Electricity study on CCS

    Plant integration experience(supply of turnkey power plants)Tests complete

    VattenfallSchwarze-

    Pumpe Germany-30 MWthOxy- Lig nite

    Dow ChemicalCo.

    US-2MWth

    Adv.Amines- coal

    Datang- ChinaOxy 350 MWelignite,

    Post 350 MWeeq. coal

    AlstomBSFWindsor

    US- 15 MWthOxy - coals

    Getica - CET TurceniRoumania >250MWeChilled

    ammonia - Lignite

    PGE BelchatowPoland 260 MWe

    Adv.Amines- Lignite

    DOE/AlstomWindsorUS 3 MWth

    Chemical looping-

    coal

    2nd Gen

    NER300

    NER300

    SelectedforreceivingEEPR funding

    NER300: AppliedforEUETSNewEntrantReservefunding

    EoNKarlshamnSweden - 5 MWth

    ChilledAmmoniaFueloil

    WE EnergieUS- 5 MWth

    ChilledAmmonia, Coal

    AEP MountaineerUS- 58 MWth

    ChilledAmmonia, coal

    TotalLacqFrance- 30 MWth

    Oxy- Gas

    Operating

    AlstomLabsVxjSweden 0.25 MWth

    Post C. multipurpose

    Large-scaleprojects-underdevelopment

    WhiteRoseCCSProjectUK- 426 MWe

    Oxy coal

    NER300

    Incommissioning /start-up

    TCM MongstadNorway- 40 MWth

    ChilledAmmonia - Gas

    EDF LeHavreFrance 5 MWth

    Adv.Amines- Coal

    RFCSEU -DarmstadtGermany 1 MWth

    Chemical looping- coal

    2 Gen

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS Cost of Electricity studyMain assumptions

    Reference plants: Coal & Lignite (without CCS)

    Realistic set of assumptions by region

    Base case at 7450 hrs per a. plus sensitivity analysis Performance improvement considered (e.g. double reheat ST) Cycle arrangement in 2020/30: 300b-600C-620C

    EUR NAM SEA

    Fuel type Bituminous Raw Lignite Dried Lignite PRB coal Bituminous

    Fuel heating value KJ/Kg LHV 24 930 10 278 21 283 20 425 20 896

    Carbon content UB mass% 65% 31% 57% 56% 53%

    Fuel price 2011 Euro/t 78,2 24,3 24,3 25,7 53,4

    Euro/GJ 3,14 2,37 2,13 1,26 2,56

    Cycle argt 2020/30 bar/C/C 300b/600/620C 272b/600/605C 300b/600/620C 300b/600/620C 300b/600/620C

    Cooling type C 13C - Direct C 18C - Direct C 18C - Direct C 19C - CT 28C - Direct C

    Net Output MWe net 837 1 000 1 000 837 837

    Net eff. 15/20/30 % LHV 46.2/48/48.4 % 44/-/- % w HR 47,6/48,8/49 % 44/46.2/46.7 % 41/42.7/43 %

    EPC 2015/20/30 /KW net 1421/1518/1518 1583/-/- 2070/2200/2200 1612/1722/1722 814/869/869

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Hardcoal CCS power plantEnergy Penalty (EP)

    Energy penalty (EP) = (Ref PP net MWe CCS PP net MWe)(Ref PP net MWe)

    Performance improvement and cooling temperature impacts

    SEAEUR NAM&

    Note : 90% capture of CCS PP CO2 emission, CCS plant and Reference plant at same net

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    EURCoE /MWh net

    Hardcoal CCS power plantCoE base case (with T&S, without CO2 price)

    NAM SEA

    All with T&S, on-shore saline aquifer: impact on CoE: 4,8 to 7,2 /MWh netEUR 2032: CCS => +45% increase in CoE; NAM/SEA: lower CoE

    CoE /MWh net CoE /MWh net

    30

    40

    50

    60

    70

    80

    90

    2015 2020 2025 2030 2035

    Oxy

    Post

    Ref PP

    +45%

    (Post)

    73,5 /MWh

    (Post)

    30

    40

    50

    60

    70

    80

    90

    2015 2020 2025 2030 2035

    Oxy

    Post

    Ref PP

    30

    40

    50

    60

    70

    80

    90

    2015 2020 2025 2030 2035

    Oxy

    Post

    Ref PP

    64 /MWh

    (Post)62 /MWh

    (Post)

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Hardcoal CCS power plantFuel, Capex/Opex and T&S contribution in CoE

    POSTREF

    / MWh net

    NAMEUR

    POSTREF POSTREF

    SEA

    CoE Ref Plant & Incremental CCS in 2032

    Regional differences in Fuel, Capex/Opex costs

    High capex, expensive coal Cheap coal, lower efficiency Low Capex, expensive coal

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    50,5

    73,5+45%

    40,5

    64

    T&S

    Fuel

    Capex+Opex

    40

    62

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    -10% -5% 0% 5% 10%

    CCS Opex

    Re-boiler duty (1,8 GJ/tCO2)

    CO2 compression

    CCS Capex

    Capex Storage

    Ref plt net efficiency (48,4%)

    Energy penalty (15,5% of Ref net)

    Capex Transport (200 km)

    Capture rate (90%)

    WACC w/o inflation (6%)

    Economic life (25 yrs)

    Fuel cost (78,2 /t)

    20 yrs40 yrs

    -25% +25%

    1,75 GJ 2,0 GJ

    -20% 5%

    -10% 10%

    -10% 10%

    -35% 50%

    EP 14,7% EP 16,8%

    Eff 49,4% Eff 47,4%

    -50% 50%

    Rate 80% Rate 92,7%

    Wacc 7%

    Base case

    Wacc 5,5%

    CCSConventional plant contribution

    73,5 /MWh 77,2 /MWh69,8 /MWh

    Hardcoal CCS power plantSensitivity analysis - CoE 2032 Europe

    Base case: Post amine,on-shore T&S,no CO2 price

    Fuel cost, Economic life, WACC have a strong impact

    EUR 2032

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Gas Reference Combined-Cycle Power Plants (without CCS)

    CCS Cost of Electricity studyMain assumptions

    Combined cycles realistic set of assumptions

    Base case combined cycle at 6570 hrs per a. Performance improvement considered

    EUR NAM SEA

    Fuel type Natural gas Natural gas Natural gas

    Fuel heating value KJ/Kg LHV 50 000 50 000 50 000

    Carbon content mass% 75% 75% 75%

    Fuel price 2011 Euro/GJ 7,2 2,8 3,8 (subs.)

    Cycle argt 2020/30 1-1 SS 2-1 MS 1-1 SS

    Cooling type C 13C - Direct C 19C - CT 28C - Direct C

    Net Output 15/20/30 MWe net 600/650/700 850/900/950 538/583/628

    Net eff. 15/20/30 % LHV 61/62/63 % 60/61/62 % 60/61/62 %

    EPC cost 15/20/30 /KW net 558/544/529 452/441/429 473/461/449

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Gas Combined Cycle CCS Power PlantCoE base case (with T&S, without CO2 price)

    EURCoE /MWh net NAM SEACoE /MWh net CoE /MWh net

    Lowest gas price at 2,8 /GJ Subsidized gas price 3,8 /GJ=> offsets Capex advantage

    Gas price at 7,2 Euro/GJ

    -5 % reduction with FGR

    Difference in gas price between regions drives CoE level

    Note : 90% capture of CCS PP CO2 emissions, CCS plant net output de-rated vs Reference plant (energy penalty)

    25

    30

    35

    4045

    50

    55

    60

    65

    70

    75

    80

    2015 2020 2025 2030 2035

    Post FGR, 90% capt

    Ref plant

    25

    30

    35

    4045

    50

    55

    60

    65

    70

    75

    80

    2015 2020 2025 2030 2035

    Post FGR, 90% capt

    Ref plant

    25

    30

    35

    4045

    50

    55

    60

    65

    70

    75

    80

    2015 2020 2025 2030 2035

    Post FGR, 90% capt

    Ref plant

    COE - NAM COE - ASIACOE - EUROPE

    Ref plant

    Ref plant

    Ref plant+28%

    +42%

    +32%

    68,5/MWh )

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    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    POSTREF POSTREF POSTREF

    Gas Combined Cycle CCS Power PlantFuel contribution in CoE

    NAMEUR SEA

    / MWh net CoE Ref Plant & Incremental CCS in 2032

    Smaller % increase in CoE than for coal due tohigher fuel cost contribution

    0

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    53,6

    68,5+28%

    26,6

    37,7+42%

    Fuel

    Capex+O&M+T&S

    34,4

    45,4+32%

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    ALSTOM 2013. All rights reserved. Information contained in this document is indicative only. No representation or warranty is

    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    -15% -10% -5% 0% 5% 10% 15%

    CCS OpexCO2 compression

    Re-boiler duty (1,8 GJ/tCO2)

    Capex Storage

    CCS Capex

    Capex Transport (200 km)

    Ref plt net efficiency (63%)

    Energy penalty (10,1%)

    WACC w/o infl. (5,95%)

    Capture rate (90%)

    Economic life (20 yrs)

    Fuel cost ( 7.2 /GJ)

    68,5 /MWh

    16 yrs25 yrs

    -25% +25%

    1,75 GJ 2,0 GJ

    -20% 5%-10% 10%

    -10% 10%

    -35% 50%

    EP 9, 4% EP 11,1%

    Eff 64% Eff 62%

    -50% 50%

    70% 92,7%

    Wacc 5,5% Wacc 6,85%

    72 /MWh61,6 /MWhBase case

    CCSConventional plant contribution

    Gas price will remain an essential sensitivity parameter

    Gas Combined Cycle CCS Power PlantSensitivity analysis on CoE 2032

    Base case: Post aminew FGR, on-shore T&S,

    no CO2 price

    EUR 2032

    Note: w CO2 price 82/t => +4.3% on CoE => 71,5 /MWh

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    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    CCS is already competitive on coal and gas from 2017 tocomplement other low carbon alternatives to reduce CO2

    footprint

    Low carbon technologies in Europe in the next 5years

    Source : Alstom analysis 2012. CCS w Post amine 2017 costs, reference value with on shore T&S, CO2 price and Flue Gas Recirculation for CCS Gas CC.Upper range includes off-shore storage. CoE do not include externalities of Intermittent power (Back-up cost, balancing cost, grid enhancement if required)

    7986

    0

    50

    100

    150

    200

    250

    300

    Hardcoal w

    CCS Post

    2017

    Gas CCPP

    w CCS

    2017

    Nuclear Hydro Geo-

    thermal

    Wind

    Onshore

    Wind

    Offshore

    Solar

    Thermal

    Solar PV

    0

    50

    100

    150

    200

    250

    300

    / MWhCoE Low Carbon technologies New PP over next 5 years

    Reference case

    EUROPE

    Low case

    CSP Tower

    with storage

    no stor.

    4 hrs sto

    Up to 45cents/kWh

    (82 for Ref

    CCS Oxy)

    Alstom CO2 Capture Systems - P 41

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    given or should be relied on that it is complete or correct or will apply to any particular project. This will depend on the technical andcommercial circumstances. It is provided without liability and is subject to change without notice. Reproduction, use or disclosure tothird parties, without express written authority, is strictly prohibited.

    Conclusion

    Alstom: a key partner in CCS!

    Fossil Plants will still remain for several decades Reducing CO2emissions from these plants is an

    absolute need to limit global warming to 2 C (thecurrent path leads to 6C !)

    CCS is the only alternative to significantly reduce fossilplant CO2. It is competitive and affordable on both gasand coal

    Alstom is currently developingCO2 capturetechnologiesand is on the good path to commercialisethe technology before 2020

    Alstom CO2 Capture Systems - P 42

    Large scale demonstrations must happen now to validate the technology ontime

    Pro-activeness on reduction targets, regulations and policy instruments areneeded to support demonstration and early commercial phase (ex: FITs,capacity mechanism...)

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