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Atoms and the Periodic Table

Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

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Page 1: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atoms and the Periodic Table

Page 2: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atom

Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons

Region outside the nucleus contains electrons

Page 3: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Sub-Atomic Particles

Particle Mass Charge Location

(amu)

Proton 1 + 1 Nucleus

Electron 1/1835 - 1 Outside nucleus

Neutron 1 0 Nucleus

Page 4: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atomic number (Z) is the number of protons in an atom

The number of protons determines the identity of the element

Mass number (A) is the total number of protons and neutrons in an atom

Page 5: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atom X

Mass number Charge A C

X Z

Atomic number

X is atomic symbol

Page 6: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

An atom has 47 protons, 61 neutrons and 47 electrons.

What is its atomic number?

What is its mass number?

What is its charge?

What element is it?

What is its atomic mass?

Page 7: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Ag

Mass number Charge47p + 61n 108 0 47p+ + 47 e-

Ag47 p 47

Atomic number

Ag atomic symbol

Page 8: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

31

X 15

atomic number

mass number

number of protons

number of electrons

number of neutrons

element symbol

Page 9: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

31

X 15

atomic number 15

mass number 31

number of protons 15

number of electrons 15

number of neutrons 31-15 = 16

element symbol P

Page 10: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Isotopes

Isotopes are atoms of the same element that have different numbers of neutrons

Isotopes have different masses

Isotopes of an element have the same chemical properties.

Page 11: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Isotope Protons Neutrons Mass # Name

12C 6 6 12 Carbon-12

13C 6 7 13 Carbon-13

14C 6 8 14 Carbon-14

Page 12: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

C-14 is radioactive.

Radioactive isotopes have the same chemical properties as other isotopes of the same element

Page 13: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atomic Mass of an Atom

Each proton and neutron has a mass of approximately 1 amu

For C-13, mass would be:

6 protons x 1amu/proton = 6 amu7 neutrons x 1 amu/neutron = 7 amu

Mass of C-13 atom = 13 amu

Page 14: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atomic Mass Unit (amu)

Atomic Mass Unit is defined as 1/12 the mass of the 12C (C-12) isotope of carbon

Page 15: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atomic Mass of Element

Often called atomic weight

Atomic mass of an element is weighted average of the masses of each isotope

Need to know abundance of each isotope to calculate atomic mass

Page 16: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Chlorine occurs as two isotopes Cl-35 and Cl-37

75.77% Cl-35 (or 0.7577)

24.23% Cl-37 (or 0.2423)

0.7577 x 35 amu = 26.52 amu

0.2423 x 37 amu = 8.965 amu

Cl Atomic mass = 35.49 amu

Page 17: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Calculate the atomic mass of Imaginarium

90 % occurs as Im-200

10 % occurs as Im-210

Page 18: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Calculate the atomic mass of Imaginarium

90 % occurs as Im-200

10 % occurs as Im-210

0.90 x 200 amu = 180 amu

0.10 x 210 amu = 21 amu

mass of “average” 201 amu

atom

Page 19: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atom

Neutral atom has equal number of protons and electrons

+ charges = - charges

Overall charge of zero (neutral)

Page 20: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Ions

Atom can gain or lose electrons to form ion

Gain electrons → negative ion (anion)

+ charges < - charges → - ion

Lose electrons → positive ion (cation)

+ charges > - charges → + ion

Page 21: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside
Page 22: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Atoms are so small that we cannot easily measure distances

Can measure energy (in form of light):

Spectroscopy

Can think of entire electromagnetic spectrum as if it were light

Page 23: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Electromagnetic Radiation

Travels at speed of light: 3.0 x 108 m/s

Travels as waves --- Wavelength (λ) and Energy inversely

relatedSmall λ -- High energyLong λ -- Low energy

Spectrum can be divided into regions based on wavelength and energy

Page 24: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

The Wave Nature of Light• All waves have a characteristic

wavelength, , and amplitude, A.

• The frequency, , of a wave is the number of cycles which pass a point in one second.

• The speed of a wave, v, is given by its frequency multiplied by its wavelength:

v = • For light, speed = c.

Page 25: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Fig. 2.10

Page 26: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Emission Spectrum

Pass electricity through vacuum tube that has gas phase atoms

Specific wavelengths of light are emitted

Each element emits characteristic wavelengths

Page 27: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Visible light spectrum is continuous

Emission spectrum is discontinuous

Only certain bands seen

(allowed energy amounts – quanta)

Page 28: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Fig. 2.11

Page 29: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Bohr Atom

• Electrons are found in “orbits” around the nucleus

• Each “orbit” is called a principal energy level (n) --- or shell

• The higher the energy level, the farther out from the nucleus it is

• The higher the energy level, the greater the energy of the electrons in it

Page 30: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Bohr Atom

Electrons can only have certain allowed amounts of energy

Quantum: a discrete amount of energy

Photon: a packet of energy (light)

Page 31: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside
Page 32: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Ground state:Electrons in lowest possible energy level

Excited state:Electron has absorbed energy and been promoted to a higher energy level (farther from nucleus)

Relaxation occurs when electron emits energy and goes into a lower energy level (closer to nucleus)

Only specific amounts of energy can be absorbed or emitted (quantum of energy)

Page 33: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside
Page 34: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

If energy emitted corresponds to a visible wavelength, we see it as a colored line in the emission spectrum

The pattern is unique for each element

Bohr’s model worked for Hydrogen, but not for more complicated atoms (more e-)

Page 35: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Fig. 2.11

Page 36: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside
Page 37: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

http://astro.u-strasbg.fr/~koppen/discharge/

Page 38: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

• Ne red

• Ar blue

• Hg blue

• Na yellow

Page 39: Atoms and the Periodic Table. Atom Nucleus located in center of atom is small, dense and positively charged. Contains protons and neutrons Region outside

Principal Energy Level Element # e- 1 2 3 4

H 1 1He 2 2Li 3 2 1Be 4 2 2C 6 2 4F 9 2 7Ne 10 2 8Na 11 2 8 1Mg 12 2 8 2Cl 17 2 8 7Ar 18 2 8 8K 19 2 8 8 1