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Tel: 353 1 276 1428 Fax: 353 1 276 1561 Email: [email protected]
www.enviro-consult.com
Registered Office as above. Registered Number 243 412
ANNUAL ENVIRONMENTAL REPORT
(AER) 2008
For
P. Carney Ltd.,
Crossakiel, Kells, Co. Meath
IPPC Licence Number: P0402-02
(EEC Ltd. Document Number 1123-01 v2.00)
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 2
Document no. 1123-01 v2.00
QF 1. v2 Document Lead Sheet
Document Title Annual Environmental Review (AER) 2008 (IPPC Licence Ref. P0402-2)
Project No. 1123-00 Document No. 1123-00 v2.00 Client P. Carney Ltd. Address Crossakiel, Kells, Co. Meath
Signed for and on behalf of Issue Status Date Author Environmental
Efficiency Client
2.00 Approved 18/05/2009 RnD
Where it is a requirement that this report be issued to a regulatory or other authority, then the client should sign the appropriate place in the above table and, unless specifically agreed in writing to the contrary, forward copies to the appropriate authority (e.g. EPA).
EEC Project Manager: Bob Sutcliffe, CEng, MIMechE
EEC Document Author: Róisín Ní Dhubhda B.Sc., M.Sc., AIEMA
Conditions relating to the issue of this report:
1. No alteration to this report by third parties is permitted
2. Where this report is reproduced, it shall only be reproduced in full.
3. Reports remain the property of Environmental & Efficiency Consultants
(Ireland) Limited until paid for in full.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 3
Document no. 1123-01 v2.00
TABLE OF CONTENTS
1 Introduction ......................................................................................................... 5 2 Company Information ........................................................................................ 6 3 Copy of the Company Environmental Policy ................................................... 7 4 Site Description.................................................................................................... 8 4.1 Company Profile ............................................................................................8 4.2 Description of Equipment ..............................................................................8 4.3 Manufacturing Process ...................................................................................9
5 Summary of Emissions...................................................................................... 10 5.1 Emissions from Storm Water .......................................................................10 5.2 Emissions to Atmosphere.............................................................................14
6 Waste Management........................................................................................... 17 7 Resource Consumption ..................................................................................... 18 7.1 Water Consumption......................................................................................18 7.2 Energy Consumption....................................................................................19 7.3 Environmental Incidents and Complaints ....................................................19
8 Environmental Management of Activity......................................................... 20 8.1 Report on Environmental Objectives and targets for 2008 ..........................20
9 Licence Specific Reports (IPPC licence PO402-02) ....................................... 30 9.1 Pollution Emissions Register (PER) 2008 ...................................................30 9.2 Determine PERL for site ..............................................................................30 9.3 PER Proposal 2008.......................................................................................32 9.4 Noise Monitoring Report 2008 ....................................................................32 9.5 Bund Integrity ..............................................................................................32 9.6 Tank and pipeline testing report...................................................................32 9.7 Energy Efficiency Audit Report...................................................................33 9.8 Raw Materials Assessment...........................................................................33 9.9 Water minimisation study ............................................................................33 9.10 Environmental Liabilities and financial provisions .....................................34
Figure 5-1: pH Storm Water Results (2005-2008).......................................................11 Figure 5-2: COD Surface Water Results (2005-2008).................................................12 Figure 5-3: Aluminium Storm Water Results (2005-2008) .........................................12 Figure 5-4: Copper Surface Water Results (2005-2008) Note 1 .....................................13 Figure 5-5: Lead Surface Water Results (2004-2008) Note 2 .........................................13
Table 2-1: AER Content.................................................................................................5 Table 2-1 Company details ............................................................................................6 Table 2-2 Summary of IPC licence ................................................................................6 Table 5-1 Parameters and Monitoring Schedule (licence number: P0402-02) ............10 Table 5-2 Emissions to Storm Water – Monitoring results (2005-2008) ...............11 Table 5-3 Air Monitoring Programme A2-1 (IPPC licence PO402-02) ......................15 Table 5-4 Monitoring Results 2008 from Emission Stack A2-1 .............................16 Table 6-1 Waste Generation during 2008 ................................................................17 Table 6-2 Summary of wastes generated in 2008 ....................................................18
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 4
Document no. 1123-01 v2.00
Table 7-0-1 Energy Consumption for 2007-2008:.......................................................19 Table 8-1 Report on Objectives and targets for 2008 ..................................................21 Table 8-2 Objectives and Targets for 2009 ..............................................................23 Table 9-1 PER 2008 .....................................................................................................31 Table 9-2 Environmental liabilities..............................................................................34
Appendix 1 Copy of Certificates of Analysis – Storm water 2008 .........................36 Appendix 2 Copy of Certificates of Analysis – Air Monitoring 2008.....................39 Appendix 3 Copy of Dioxin Monitoring Report – May 2008 .................................44 Appendix 4 Copy of Dioxin Monitoring Report – September 2008........................50 Appendix 5 Tank and pipeline inspection report .....................................................56 Appendix 6 Noise Monitoring Report 2008 ............................................................58 Appendix 7 Energy Audit Report Summary............................................................59 Appendix 8 Emergency Response Plan ...................................................................60 Appendix 9 Accident Prevention Policy..................................................................61
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 5
Document no. 1123-01 v2.00
1 Introduction
P. Carney Ltd was originally licensed by the Agency in April 1999 (Licence No. 402).
However, to accommodate changes in regulations and the installation of an abatement
system, the EPA required the company to request a review. A new licence was
granted by the Agency in August 2006 (P0402-02).
As laid out in Schedule D of IPPC Licence P0402-02, Table 2-1 shows the content
that has to be included in P. Carney Ltd. Annual Environmental Report (AER).
Table 2-1: AER Content
AER Content
• Emissions from the installation.
• Waste management record.
• Resource consumption summary.
• Complaints summary.
• Schedule of Environmental Objectives and Targets.
• Environmental Management Programme – report for previous year.
• Environmental Management Programme – proposal for current year.
• Pollution Emission Register – report for previous year.
• Pollution Emission Register – proposal for current year.
• Noise monitoring report summary.
• Ambient monitoring summary.
• Tank and pipeline testing and inspection report.
• Reported incidents summary.
• Energy efficiency audit report summary.
• Report on the assessment of the efficiency of use of raw materials in processes
and the reduction in waste generated.
• Statement of measures in relation to prevention of environmental damage and
remedial actions (Environmental Liabilities).
• Any other items specified by the Agency.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 6
Document no. 1123-01 v2.00
2 Company Information
Table 2-1 Company details
Company P. Carney Ltd
Address Crossakiel,
Kells.
County / City Co. Meath
Business Manufacturers of Aluminium Ingot,
Copper Granules, and Aluminium
Granules
Employees 36
Contact Name Mr. Declan Clarke
Position Company Manager
Telephone 046 9243634
Fax 046 9243916
Email [email protected]
IPPC Registration Number P0402-02
Table 2-2 Summary of IPC licence
IP(P)C Licence Reg: No. Period
402 (IPC licence) 30/4/1999 – 30/4/2006
PO402-02 (IPPC licence) 30/4/2006 - present
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 7
Document no. 1123-01 v2.00
3 Copy of the Company Environmental Policy
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 8
Document no. 1123-01 v2.00
4 Site Description
4.1 Company Profile
P. Carney Ltd is located on a site in the village of Crossakiel, Co. Meath,
approximately 9 km west of Kells. The company employs 36 people in total and
normally operates on a 5 day week schedule.
P. Carney Ltd is an Irish company established in 1964 and originally was a metal
trader that took in various types scrap metal. The main site process is taking in
aluminium and processing it into aluminium ingots for use in the automotive industry.
There is also a further side to the business that produces copper and aluminium
granules from copper and aluminium cables. The company falls under Class 3.4.2 of
the first schedule of the Protection of the Environment Act, 2003:-
“The production, recovery or processing of non-ferrous metals, their compounds or
other alloys including antimony, arsenic, beryllium, chromium, lead, magnesium,
manganese, phosphorus, selenium, cadmium or mercury, by thermal, chemical or
electrolytic means in installations with a batch capacity exceeding 0.5 tonnes, not
included in paragraph 3.4.1”.
P. Carney Ltd is a TS 16949 (automotive standard) and an ISO 9002 approved
company. The two main processes undertaken onsite comprise the production of the
following:
1. Aluminium Ingots, and
2. Aluminium and Copper Granules.
The company is committed to continuous improvement, which is the core of the
environmental management programme currently in operation at the facility.
4.2 Description of Equipment
The main pieces of equipment are as follows:
• Furnacing equipment with loading and casting machine equipment
• On site weighing facilities
• 3 no. complete granulation systems
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 9
Document no. 1123-01 v2.00
• HGVs, trailers, skips, bins etc for transportation of material
• Forklifts and materials handling equipment
4.3 Manufacturing Process
The company is involved in the manufacture of aluminium ingots for the automotive
industry and the production of copper and aluminium granules.
A summary of the manufacturing process is given below:
High End Quality Scrap
Aluminium and Various Cables
Aluminium (sorted by quality)
Copper and Aluminium Cable
Copper Cable
Aluminium Cable
Furnace
Aluminium Ingot
Granulating
Process
Plastic/Rubber
Copper Granules
Aluminium Granules
Quality Control
Aluminium Ingot Product
Copper Granules Product
Aluminium Granules Product
Sold to horse arenas
Client
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 10
Document no. 1123-01 v2.00
5 Summary of Emissions
The company has the following licensed emissions:
� Emissions to Surface Water
� Emissions to Atmosphere
� Waste Emissions
5.1 Emissions from Storm Water
Emission from Storm Water, monitoring programme
Under Schedule C.2.3 of the IPPC Licence P0402-02, Storm Water Emission
monitoring is required. The monitoring schedule for emissions to storm water is
provided in Table 5-1 below:
Table 5-1 Parameters and Monitoring Schedule (licence number: P0402-02)
Parameter Monitoring Frequency Analysis Method / Technique
COD Bi-annually Standard Method
Aluminium Bi-annually Standard Method
Copper Bi-annually Standard Method
Visual Inspection Weekly Sample and examine for colour
and odour
Emission from storm water, monitoring results
Analysis of emissions to surface water is carried out by Analytical Services and
Environmental Projects (ASEP), Queen’s University, Belfast on the 16th April 2008
and the 29th September 2008. A summary of monitoring results for 2008 is provided
in Table 5-2 along with results for the four previous years. There are no ELVs for
storm water emissions, however results were examined in the context of the Urban
Wastewater Treatment Regulations (S.I. No. 254 of 2001) 2001 and the Water Quality
(Dangerous Substances) Regulations, 2001. No chemical parameter exceeded the
specified limits of these regulations during 2008. Certificates of analysis are provided
in Appendix 1 of this report.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 11
Document no. 1123-01 v2.00
Table 5-2 Emissions to Storm Water – Monitoring results (2005-2008)
Parameters pH COD
(mg/l)
Aluminium
(ppm)
Copper
(ppm)
Lead
(ppm)
Temp
(0C)
2005 7.32 18 0.41 0.062 0.031 N/A
2006 7.4 8 0.01 0.02 0.04 N/A
2006 7.4 4 0.04 0.04 <0.01 6.0
2007 7.7 14 0.02 <0.01 <0.01 20.2
2007 7.0 19 0.29 0.05 0.11 22.8
2008 7.0 18 0.01 0.02 <0.01 21.4
2008 7.0 1.0 0.04 0.03 <0.01 20.8
N/A – Not available The pH readings for the storm water samples are relatively constant and within the
recommended pH 6-9 limit range.
pH Value 2005-2008
7.37.4 7.4
7.7
7 7 7
6.6
6.8
7
7.2
7.4
7.6
7.8
2005 2006 2006 2007 2007 2008 2008
Year
pH Value
Figure 5-1: pH Storm Water Results (2005-2008)
There are no ELVs for storm water emissions. The COD level monitored in April
2008 was similar to 2007 however there was a significant decrease in COD levels as
determined by the September 2008 result. Nonetheless, levels remain within the
levels specified in Urban Wastewater Treatment Regulations (S.I. No. 254 of 2001)
2001.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 12
Document no. 1123-01 v2.00
COD
18
8
4
14
1918
1
0
5
10
15
20
2005 2006 2006 2007 2007 2008 2008
Year
COD Value (mg/l)
Figure 5-2: COD Surface Water Results (2005-2008)
Aluminium
0.41
0.010.04 0.02
0.29
0.010.04
0
0.1
0.2
0.3
0.4
0.5
2005 2006 2006 2007 2007 2008 2008
Year
Al Value (ppm)
Figure 5-3: Aluminium Storm Water Results (2005-2008)
Copper level recording from the second monitoring half of 2008 demonstrated a slight
increase on 2008 first half levels. Results remain within the threshold of 0.05 mg/l as
specified under the Water Quality (Dangerous Substances) Regulations, 2001.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 13
Document no. 1123-01 v2.00
Copper
0
0.02
0.04
0.06
0.08
2005 2006 2006 2007 2007 2008 2008
Year
Cu Value (ppm)
Figure 5-4: Copper Surface Water Results (2005-2008)
Note 1
Note 1 – The value for first sample of 2007 is <0.01ppm
There are no ELVs for storm water emissions. Lead levels in the storm water
monitored during 2008 were <0.01 and within the environmental quality standards
(EQS) for surface waters.
Lead
0
0.02
0.04
0.06
0.08
0.1
0.12
2005 2006 2006 2007 2007 2008 2008
Year
Pb Value (ppm)
Figure 5-5: Lead Surface Water Results (2004-2008)
Note 2
Note 2
Lead values which are not denoted in the graph model are values of <0.01ppm.
2008 values for lead (Pb) are both less than 0.01ppm as indicated in Table 5-2.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 14
Document no. 1123-01 v2.00
Temperature
20.2
22.8
21.4
20.8
18
19
20
21
22
23
2007 2007 2008 2008
Year
Temperature Value
(Celsius)
2007 temperature values are given for comparative purposes only. Temperature values
for 2008 are all within the EPA recommended values of 6-9 pH.
5.2 Emissions to Atmosphere
Emissions to Atmosphere -monitoring programme
In accordance with Schedule C.1.2 of the IPPC Licence, monitoring of emissions to
atmosphere (A2-1) is required for the following parameters:
1. Fluorides (as HF)
2. Chlorine
3. Chlorides
4. Sulphur dioxide (as SO2)
5. Particulates
6. Dioxins
7. NOx
8. CO
A summary of the air monitoring programmes is in Table 5-3 and a summary of the
results and relevant ELVs are given in Table 5-4.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 15
Document no. 1123-01 v2.00
Table 5-3 Air Monitoring Programme A2-1 (IPPC licence PO402-02)
Emission point
reference
Parameters Monitoring
Frequency
Volumes &
Concentrations
Licensed Volume
Particulates Continuously 50 mg/m3
Chlorides (as HCl) Biannually 30 mg/m3
Chlorine (as Cl2) Biannually 5 mg/m3
Fluorides (as HF) Biannually 5 mg/m3
Sulphur dioxide (as SO2) Biannually 350 mg/m3
Dioxins Biannually 0.5 ng I-TEQ/Nm3
NOx Biannually Note 1
A2-1
CO Quarterly Note 1
Note 1: Not Specified
Emissions to atmosphere – Monitoring results
Monitoring on site was carried out during 2008 by ASEP C/O Queens University,
Belfast. The results for 2008 are summarised in Table 5-4. As can be seen from the
results below, none of the emission limit values (ELV) were breached in 2008.
Monitoring reports are provided in Appendix 2 of this report. Dioxin analysis of
emission point A2-1 was carried out in April 2008 and September 2008. The dioxin
level was 0.048 ng TEQ/Nm3 (April 2008) and 0.011 ng TEQ/Nm3 (September 2008).
The monitoring reports are attached in Appendix 3 and Appendix 4.
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 16
Document no. 1123-01 v2.00
Table 5-4 Monitoring Results 2008 from Emission Stack A2-1
April 2008 September 2008 Parameter ELV
Run 1 Run 2 Run 1 Run 2
Flue Temperature (0C) - 93 94 95 97
Stack Flow (m3/h) 29,000 23014 23549 21718 22254
Particulate
(mg/m3)
50 26.9 9.94 10.48 3.41
Mass Flow (kg/h) - 0.619 0.117 0.228 0.076
Oxides of Nitrogen (mg/m3) - <5 <5 6 11
Sulphur Dioxide (mg/m3) 350 <5 <5 <5 <5
Carbon Monoxide (mg/m3) - <5 <5 <5 <5
Hydrogen Chloride (mg/m3) 30 <5 <5 <5 <5
Hydrogen Fluoride (mg/m3) - <1 <1 <1 <1
Chlorine (mg/m3) 5 <1 <1 <1 <1
Copper (mg/m3) - <0.05 <0.05 <0.05 <0.05
Titanium (mg/m3) - <0.05 <0.05 <0.05 <0.05
IPPC Licence Ref. P0402-2: P. Carney Ltd.
Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 17
Document no. 1123-01 v2.00
6 Waste Management
A summary of all wastes generated during 2008 are summarised in Table 6-1 below.
Table 6-1 W
aste Generation during 2008
Waste
EWC No.
Hazardous
Annual
Quantity
(tonnes) 2008
Current Disposal
Waste
Contractor
Destination of
Waste – Onsite or
offsite
Permit /Licence number
of waste contractor
Oil
13 01 01*
Yes
0 Litres
Not applicable in 2008
Enva Portlaoise
Off site
WCP MH2001/107D
Plastic and
Plastic Dust
19 12 04
No
203.860 tonnes D1 Deposit on, in or under
land.
Green Energy
Recycling
Off site
WCP OY08058501
Timber
17 02 01
No
66.440 tonnes
Recycling
R3 Recycling/reclamation of
organic substances which are
not used as solvents
Greenstar
Doherty Waste
Management Ltd
Off site
WCP/MH/2005/63B
WP 2006/48b
General
Waste
20 03 01
No
91.200 tonnes
D1 Deposit on, in or under
land.
Green Energy
Recycling
Off site
WCP OY08058501
IPPC Licence Ref. P0402-2: P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 18
Document no. 1123-01 v2.00
A breakdown of the amount of waste disposed and recovered is provided in Table 6-2
below.
Table 6-2 Summary of wastes generated in 2008
Quantity of wastes Quantity of wastes
disposed on site
Quantity of wastes
disposed off-site
Quantity of waste
recovered off-site
Non-hazardous
wastes
0 361.50 tonnes 66.44 tonnes
Hazardous wastes 0 - -
7 Resource Consumption
This section of the report details the total annual usage levels of water and energy.
7.1 Water Consumption
Water consumption for 2008 is detailed in Table 7-1 below. Water usage primarily
comes from the municipal supply though groundwater from the on site well is used. P.
Carney Ltd. installed metering of groundwater in mid-2007, therefore over the coming
3 years, water consumption will be carefully examined to assess consumption
volumes and determine where improved conservation measures can be applied.
Table 7-1 Water Consumption 2008
Year 2008
Water
Reading
m3
On-site
ground
851
On-site
surface
-
Municipal
supply
1225
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 19
Document No. 1012-01 v1.00
7.2 Energy Consumption
Energy is provided by the following sources at the company namely:
� Oil
� Electricity
� Propane gas
A summary of energy consumption in 2008, in terms of the above, is shown in the
below.
Table 7-0-1 Energy Consumption for 2007-2008:
Source Consumption 2007 Consumption 2008 Units
Oil 901,249 702,763 Litre
Electricity 611,011 566,100 KWh
Propane gas 4,850 4,120 Litre
In 2008, energy consumption decreased significantly at the P. Carney facility. In
2008, oil consumption decreased by 22% whilst propane gas consumption decreased
by 15% over the same period. Electricity consumption at the facility was reduced by
over 7% during 2008, based on the consumption figures of 2007.
7.3 Environmental Incidents and Complaints
Reported Incidents Summary
There were no reported incidents during 2008.
Complaints Summary
There were no complaints from any member of the public or the Local Authority or
EPA during 2008 in relation to environmental matters at the site.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 20
Document No. 1012-01 v1.00
8 Environmental Management of Activity
The company has operated in accordance with the Environmental Management
System (EMS) since 1999. The EMS was updated in 2007 to reflect the new IPPC
licence requirements. As part of EMS, an Environmental Management Programme
(EMP) was formulated, outlining specific environmental objectives and targets for the
company. This section of this report summarises the objectives and targets proposed
for the coming year, 2009. A progress report on the EMP objectives and targets
implemented during 2008 is also provided. The schedule of environmental objectives
and targets has been established taking into account instruction within Condition 2.2.2
of the IPPC Licence.
8.1 Report on Environmental Objectives and targets for 2008
A report on the implementation of the 2008 environmental objectives and targets is
provided in Table 8-1.
P. Carney Ltd.
Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd
21
Document No. 1012-01 v1.00
Table 8-1 Report on Objectives and targets for 2008
Objective
reference No.
Objective
Target/Outcome
Achievem
ent / Additional Comment
1
Water Usage: Monitor
groundwater well abstraction
Monitoring of groundwater abstraction was
ongoing throughout 2008
A meter was installed onsite to monitor
volume of water abstraction from well and
water consumption at the facility
continues to be monitored.
2
Noise: Undertake noise survey in
compliance with licence
requirements
An annual environmental noise survey was
completed in 2008 in compliance with the
IPPC licence.
This report determined that noise levels at
the site were within the specified limits of
the licence, and in accordance with the
recommended levels as specified by the
EPA. This report is included in this AER.
3
Energy efficiency and resource
use: Review energy audit
undertaken at facility in 2007 and
oversee implementation of
recommendations to improve
energy efficiency at the facility e.g.
electricity use.
Continuing assessment of energy and
resources use throughout the facility.
Energy consumption fell significantly in
2008 at the P. Carney facility.
In 2008, oil consumption decreased by
22% whilst propane gas consumption
decreased by 15% over the same period.
4
Update MSDS relating to
hazardous substances in use onsite
e.g. fuels
MSDS were sought for all substances used
onsite.
All MSDS are kept on file in a specified
location in the event of an emergency.
P. Carney Ltd.
Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd
22
Document No. 1012-01 v1.00
Objective
reference No.
Objective
Target/Outcome
Achievem
ent / Additional Comment
5
Improve environmental awareness
amongst staff
Training of staff has been implemented
during 2008
Continue updated training of staff and
ensure all new personnel receive training
upon commencement.
6
Storm water: Continue to conduct
a visual examination of the on site
storm water discharge on a daily
basis in accordance with licence.
Undertaken on a regular basis and is
working successfully.
There have been no incidents reported at
the facility and this system is proving
successful.
7
Undertake a Gap Analysis study to
assess current oil separator on site
with reference to I.S EN 858-
2:2003
Review of the current existing system has
been undertaken by the facility and a report
is pending.
Currently under review
8
Hydro-geological assessment: On
approval of hydro-geological
assessment by the Agency, the
proposal shall be implemented
Proposal submitted to EPA authorities and
P. Carney currently awaiting response.
Currently under review
P. Carney Ltd. Annual Environmental Report 2008
Tel: 353 1 276 1428 Fax: 353 1 276 1561 Email: [email protected]
www.enviro-consult.com
Registered Office as above. Registered Number 243 412
Table 8-2 Objectives and Targets for 2009
Objective
No. Objective Target Date
OT1 Daily storm water inspection of site Ongoing
OT2
Bund integrity test to be undertaken in 2009 under
Condition 3.6.5 of the licence which stipulates such
testing every 3 years.
September 2009
OT3
Inspection and testing of oil tank and transporting
pipelines to be undertaken in 2009 under Condition
8.3.3 of the licence.
September 2009
OT4 Staff environmental training September 2009
OT5
Annual Noise monitoring to be undertaken under
condition 6.13.1 of the licence in accordance with
the EPA guidance document ‘Environmental Noise
Survey Guidance Document’
October 2009
OT6 Monitoring of the groundwater abstraction December 2009
QT7 Review MSDS pertaining to all hazardous materials
used onsite December 2009
OT8 Review of procedures to assess the efficient
operations of the facilities flue gas abatement system December 2009
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 24
Document No. 1012-01 v1.00
Objective 1
Objective Number OT1
Objective Title Undertake a visual inspection of storm water discharge daily
Target Ongoing
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Undertake an examination of storm water discharge daily
to ensure the discharge is free from contamination
Environmental
Manager Daily/ Ongoing
Objective 2
Objective Number OT2
Objective Title Undertake a Bund Integrity test in accordance with Condition 3.6.5 of the IPPC licence
Target June 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Arrange for a bund integrity test to be completed on site in
compliance with IPPC Licence condition 3.6.5
Environmental
Manager September
• Review results to ensure compliance with IPPC licence
conditions
Environmental
Manager September
• *Should the existing bunds be determined to be in breach of
licence conditions, remediation works shall be undertaken in
accordance with the recommendations of the report without
delay. Upon completion of these works, a follow up bund
integrity test shall be undertaken.
Environmental
Manager September (*if required)
• Insert copy of the Bund Integrity Assessment Report in
AER 2010 in accordance with licence conditions
Environmental
Manager March 2010
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 25
Document No. 1012-01 v1.00
Objective 3
Objective Number OT3
Objective Title Undertake an inspection and testing of onsite oil tanks and transporting pipelines in accordance with Condition 8.3.3 of the IPPC licence
Target July 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Arrange for an assessment and testing of all onsite oil tanks
and associated transporting pipelines in accordance with
Condition 8.3.3 of the IPPC licence
Environmental
Manager September
• Review results to ensure compliance with IPPC licence
conditions
Environmental
Manager September
• *Should the existing onsite oil tanks and associated
transporting pipelines be determined to be in breach of
licence conditions, remediation works shall be undertaken in
accordance with the recommendations of the report without
delay. Upon completion of these works, a follow up
assessment shall be undertaken.
Environmental
Manager September (*if required)
• Insert copy of the report in AER 2010 in accordance with
licence conditions
Environmental
Manager March 2010
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 26
Document No. 1012-01 v1.00
Objective 4
Objective Number OT4
Objective Title Improve environmental awareness amongst staff
Target September 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• All staff from management level down to undergo and
update environmental training
Environmental
Manager August 2009
• Ensure all employees are aware of the impacts from
hazardous materials spills on site, and receive appropriate
training on hazardous materials spills or leakages, in
addition to non-hazardous material accidents.
Environmental
Manager August 2009
• All employees should be familiar with the Emergency
Response Procedure and of the appropriate actions to take in
the event of an emergency, and of the relevant emergency
and statutory bodies to contact if such a situation arises.
Environmental
Manager September 2009
• Ensure the Emergency Response Procedure is updated
includes the correct contact details of the EPA (both a
contact number for normal office hours and out of
office/emergency hours). Also include provisions for
minimising the effects of a spill/leakage on the environment
e.g. inspect all spill kits onsite and order new kits if
required.
Environmental
Manager September 2009
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 27
Document No. 1012-01 v1.00
Objective 5
Objective Number OT5
Objective Title Undertake Environmental Noise Survey at the facility
Target October 2009
Responsibility Environmental Manager to contact Environmental Efficiency Consultants Ltd
Plan
Means by which target is to achieved Who Target
• Arrange for environmental noise survey to be completed on
site in compliance with IPPC Licence condition 6.13
Environmental
Manager /
EEC
September 2009
• Review results to ensure compliance with IPPC licence
conditions
Environmental
Manager /
EEC
October2009
• Should noise levels be determined to breach licence
conditions, a review of procedures at the facility should be
implemented to address the issue without delay
Company
Director /
Environmental
Manager
October 2009
(*if licence conditions are breached)
• Insert Environmental Noise Report (2009) in AER 2010
Environmental
Manager /
EEC
March 2010
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 28
Document No. 1012-01 v1.00
Objective 6
Objective Number OT6
Objective Title Water Usage: Maintain a record of the volume of water abstraction (m3) from the groundwater well on site
Target December 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Keep a record of the quantity m3. Environmental Manager Ongoing
• Compare the volume of water usage for with 2008 figures Environmental Manager
December
2009
• Assess quantities of water usage at the facility and
implement a programme to improve water efficiency onsite
Environmental Manager
December
2009
• AER 2010 to report on water consumption at the facility
EEC March 2010
Objective 7
Objective Number OT7
Objective Title Update Material Safety Data Sheets (MSDS) for hazardous substances used onsite e.g. fuel
Target December 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Review all substances used onsite and assess whether
MSDS are available for each
Environmental Manager October
2009
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 29
Document No. 1012-01 v1.00
Means by which target is to achieved Who Target
• Ensure all MSDS onsite are up to date. These should be
reviewed and updated annually.
Environmental Manager November
2009
• Keep all MSDS on file and ensure all staff are aware of
location in the event of an emergency.
Environmental Manager December
2009
Objective 8
Objective Number OT8
Objective Title Review of procedures to assess the efficient operations of the facilities flue gas abatement system
Target December 2009
Responsibility Environmental Manager
Plan
Means by which target is to achieved Who Target
• Review of procedures to assess operation and effectiveness
of the facilities flue gas abatement system
Environmental
Manager June 2009
• Based on the review, the facility to update all procedures
incl. operational & maintenance, to maintain the most
efficient operations of the facilities abatement system
Environmental
Manager August 2009
• Implement any changed or new procedures and provide the
necessary staff training where required
Environmental
Manager
August / September 2009
• Continue with monitoring and recording as stated in the
IPPC licence conditions
Environmental
Manager Ongoing
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 30
Document No. 1012-01 v1.00
9 Licence Specific Reports (IPPC licence PO402-02)
9.1 Pollution Emissions Register (PER) 2008
In accordance with Condition 6.15 Pollution Emissions Register (PER): “The licensee shall
prepare and maintain a PER for the site. The substances to be included in the PER shall be
agreed by the agency each year by reference to the lists specified in the Agency’s’ AER
Guidance Notes. The PER shall be prepared in accordance with any relevant guidelines
issued by the Agency and shall be submitted as part of the AER”.
9.2 Determine PERL for site
Having examined the substances used on site and reviewed the MSDSs for each substance
and compared them with the PERL, the following are the substances are included in the PER.
� Copper – present in copper cables
� Lead – present in cables. Lead containing cables are sometimes present in a
mixed batch of cables purchased. The lead containing cables are segregated for
sale. They are not subject to processing on site.
� Titanium – titanium is added to various grades of aluminium.
P. Carney Ltd.
Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd
31
Document No. 1012-01 v1.00
Table 9-1 PER 2008
Facility Name
P. Carney Ltd.
Register Number:
P0402-02
Reporting Period
1ST Jan 2008 to 31st December 2008
Production Units
Aluminium alloy ingot and copper granules
Employees Number:
36
Pollution Emissions Register
Pollutant
CAS no.
Input (kg)
Gross
Usage
Air (kg)
MOM
Liquid
Effluent Kg
(storm
water)
Note 1
MOM
Waste
(kg)
MOM
Product
Kg
MOM
Recovery
Treated
Un-
accounted
Copper Cu
7440-50-8
448,000
448,000
- -
0.286
C
- -
477,999.71
- -
- -
Cable
containing
Lead
7439-92-1
13,400
13,400
- -
<0.114
C
- -
13,399.88
- -
- -
Titanium
7440-32-6
3,240
3,240
Note 2
- -
C
- -
-
- -
- C: Calculation
Note 1: Based on Met Éireann figures for annual rainfall (942.6mm rainfall/yr) and total surface area of site (1.214 ha or 1,2140.5sqm)
Note 2: Not recorded, trace quantities may be present.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 32
Document No. 1012-01 v1.00
9.3 PER Proposal 2008
It is proposed that during 2009 a review of all materials used on site will be carried
out to ensure that any PERL substances used on site are included. As per 2008 the
following substances will be included in the PER:
� Copper
� Lead
� Titanium
9.4 Noise Monitoring Report 2008
Noise monitoring is required to be undertaken annually under Condition 6.13 of the
licence. A noise monitoring assessment and report was completed by Environmental
Efficiency Consultants (Ire) Ltd and is attached in Appendix 6. The noise monitoring
report determined that P. Carney is not in breach of its IPPC licence as all noise levels
were within the permitted levels.
9.5 Bund Integrity
A bund integrity test was carried out by Environmental Efficiency Consultants in July
2006 and was passed. In accordance with condition 3.6.5 of the licence:
‘The integrity and water tightness of all the bunded structures, tanks and containers
and their resistance to penetration by water or other materials stored therein shall be
tested and demonstrated by the licensee at least once every three years. This testing
shall be carried out in accordance with any guidance published by the Agency’.
The latest bund inspection report carried out at the facility in 2006 and was submitted
to the Agency previously. The next Bund integrity test is required to be undertaken in
2009 in accordance with Condition 3.6.5 of the licence and will be included into the
AER 2010.
9.6 Tank and pipeline testing report
Inspection and testing of oil transporting pipelines was carried out by Cathal Usher,
Plumbing Contractor. Condition 8.3.3 of the licence requires that “The licensee shall
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 33
Document No. 1012-01 v1.00
undertake a programme of testing and inspection of pipelines to ensure that all oil
transporting pipes are tested at least once every three years”. The most recent testing
and inspection was undertaken in August 2006 and the associated inspection report is
available in Appendix 5. In accordance with the licence conditions, testing should
once again be undertaken in 2009 and will be included into the AER 2010.
9.7 Energy Efficiency Audit Report
Environmental Efficiency Consultants have been contracted by P. Carney Ltd. to
carry out an energy audit at their site and premises. This is in accordance with
Condition 7.1 of the IPPC licence. See to view Appendix 7 summary report.
9.8 Raw Materials Assessment
In 2007, an assessment of raw materials was undertaken for P. Carney Ltd by
Environmental Efficiency Consultants to comply with Condition 7.4 of the licence.
This report identified areas where significant raw materials are used / wasted and their
associated waste streams; and gave recommendations in relation to the most
significant issues relating to the site.
With relation to raw materials used onsite, the raw materials are predetermined by the
quantities available for processing, available markets and production capacity of the
plant. As such these raw materials can not be changed. Recyclable materials are
stored separately from material being sent to landfill. The objectives and targets for
2008 has included assessing certain raw materials used onsite with the objective of
reducing the use of raw materials use i.e. water usage. This monitoring programme is
ongoing at the facility.
9.9 Water minimisation study
In compliance with Condition 7.3, a water minimisation study was carried out in
2007. As part of the water minimisation programme, it was recommended that the
water be metered. This was undertaken in 2007 and as part of the objectives and
targets, the water use onsite will continue to be monitored in order to determine use
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 34
Document No. 1012-01 v1.00
and where if any, reductions can be made or improved conservation methods can be
applied. This monitoring programme is ongoing at the facility.
9.10 Environmental Liabilities and financial provisions
A statement of measures in relation to the prevention of environmental damage and
remedial actions (environmental liabilities) is provided in Table 9-2:
Table 9-2 Environmental liabilities
Measures Progress to
date
Environmental Objectives
• Oversee implementation of Objectives and Targets 2009
• Keep a record (noting quantity m3) of all abstractions from groundwater
well on site
• Ensure all the correct waste documentation is present on site
• Undertake bund integrity testing in 2009 in accordance with licence
conditions
• Assess study regarding the current oil separator onsite in with reference to
I.S EN 858-2:2003
• Undertake inspection and testing of oil pipelines in accordance with licence
condition 8.3.3
• Upon response/approval from EPA, carry out hydro-geological assessment
of the site in accordance with Condition 6.12 of the IPPC licence on
confirmation by the EPA to proceed according to proposal Doc. no. 861-14
v2.01.
• Carry out annual noise monitoring survey in accordance with licence
conditions
• Ensure Compliance with Condition 9: Accident Prevention and Emergency
Response
• Continue with the implementation of the updated Environmental
Management System in line with the existing Environmental Management
System.
Ongoing
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 35
Document No. 1012-01 v1.00
Measures Progress to
date
Training
� All staff and new employees are provided with appropriate training
relevant to the individual’s particular job description.
� Records of training are kept and updated as appropriate
Ongoing
Equipment maintenance
� Ensure equipment in use is regularly checked in order to identify and
remedy any faults, which may compromise the health and safety of staff
or have a negative impact on the environment.
Ongoing
Environmental Monitoring
� Continue to monitor emissions to air as required by the IPPC licence
(Reg. No PO.402-02)
� Every effort is made to ensure the emissions are within emission limit
values. Investigations into non-conformances (if any) and ensure that
corrective actions are put in place if emission limit values are exceeded.
Ongoing
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 36
Document No. 1012-01 v1.00
Appendix 1 Copy of Certificates of Analysis – Storm water 2008
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P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 37
Document No. 1012-01 v1.00
P CARNEY Crossakiel Kells Co Meath
A Report To P Carney on the analysis of a water sample.
Our Ref. 08ap053A
Your Ref. Water sample
Sample description 1 x 1l water sample in 1L plastic bottle
Samples Dated -------
Analysis Requested Temp, pH, COD, Al, Cu, Pb
Samples Received 16-4-08
Samples received by Paul Cole
Analysis report Issued 13-5-08
ANALYSIS METHOD / PROCEDURE
The samples as supplied were analysed by meter for temperature by digital thermometer, pH, by HACH for Cod and by ICP for Al, Cu and Pb.
SPECIAL CONDITIONS None. The samples were analysed according to standard operating procedures. DISPOSAL OF SAMPLES
It is our normal policy that the samples will be disposed of two months after the report has been issued. CONTACTS The client should contact Mr. Trevor Sewell with any queries about the analysis report and Ms W McKinney about administration / invoices.
ANALYSIS RESULTS pH 7.0 COD mg/l 18 Temperature 0C 21.4 Al ppm 0.01 Cu ppm 0.02 Pb ppm < 0.01 Compiled By Approved By
-------------------------------- ------------------------- P. Cole R.A.Patrick Technical Director
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 38
Document No. 1012-01 v1.00
P CARNEY Crossakiel Kells Co Meath
A Report To P Carney on the analysis of a water sample.
Our Ref. 08oct011
Your Ref. Water sample
Sample description 1 x 1l water sample in 1L plastic bottle
Samples Dated -------
Analysis Requested Temp, pH, COD, Al, Cu, Pb
Samples Received 29-9-08
Samples received by Paul Cole
Analysis report Issued 14-10-08
ANALYSIS METHOD / PROCEDURE
The samples as supplied were analysed by meter for temperature by digital thermometer, pH, by HACH for Cod and by ICP for Al, Cu and Pb.
SPECIAL CONDITIONS None. The samples were analysed according to standard operating procedures. DISPOSAL OF SAMPLES
It is our normal policy that the samples will be disposed of two months after the report has been issued. CONTACTS The client should contact Mr. Trevor Sewell with any queries about the analysis report and Ms W McKinney about administration / invoices.
ANALYSIS RESULTS pH 7.0 COD mg/l 1.0 Temperature 0C 20.8 Al ppm 0.04 Cu ppm 0.03 Pb ppm < 0.01 Compiled By Approved By
-------------------------------- ------------------------- P. Cole R.A.Patrick Technical Director
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 39
Document No. 1012-01 v1.00
Appendix 2 Copy of Certificates of Analysis – Air Monitoring 2008
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P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 40
Document No. 1012-01 v1.00
Declan Clarke P Carney Ltd. Crossakiel Kells Co. Meath Ireland
Emission Analysis from Stack A2-1 at P. Carney Ltd., Crossakiel.
Emissions from the Stack A2-1 at P. Carney Ltd., Crossakiel were monitored using the following procedures. Particulate: Gravimetric determination, using a BCURA probe under isokinetic conditions Oxides of Nitrogen )
Oxides of Sulphur ) Electrochemical determination using a Kane-May Flue Carbon monoxide ) Gas Analyser Hydrogen Chloride )
Hydrogen Fluoride ) Self indicating adsorption tubes Chlorine ) Sampling was carried out using ports in the stack accessible via a permanent platform. Results Concentrations are quoted under standard conditions: 273
0K, 1.013 kPa,
Particulate was collected on the same filter assembly from the port over a continuous period. Gaseous parameters were determined during the particulate monitoring. Monitoring was carried out on the 17th April 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 41
Document No. 1012-01 v1.00
Smelting Process: Run 1 Run 2 Sample Period: 07.45 – 08.15 08.20 – 08.50 Flue temperature: 93 0C 94 0C Stack Flow: 23014 m3/hr 23549 m3/hr
Particulate: 26.9 mg/m3 9.94 mg/m3
Mass Flow: 0.619 kg/hr 0.117 kg/hr Oxides of Nitrogen: < 5 mg/m3 < 5 mg/m3
Sulphur Dioxide: < 5 mg/m3 < 5 mg/m3 Carbon monoxide: < 5 mg/m3 < 5 mg/m3
Hydrogen Chloride: < 5 mg/m3 < 5 mg/m3
Hydrogen Fluoride: < 1 mg/m3 < 1 mg/m3 Chlorine: < 1 mg/m3 < 1 mg/m3 Copper: < 0.05mg/m3 < 0.05 mg/m3 Titanium: < 0.05 mg/m3 < 0.05 mg/m3
.
______________________ _____________________ Paul Cole Dr. Robin Patrick
Technical Director 11th July, 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 42
Document No. 1012-01 v1.00
Declan Clarke P Carney Ltd. Crossakiel Kells Co. Meath Ireland
Emission Analysis from Stack A2-1 at P. Carney Ltd., Crossakiel.
Emissions from the Stack A2-1 at P. Carney Ltd., Crossakiel were monitored using the following procedures. Particulate: Gravimetric determination, using a BCURA probe under isokinetic conditions Oxides of Nitrogen )
Oxides of Sulphur ) Electrochemical determination using a Kane-May Flue Carbon monoxide ) Gas Analyser Hydrogen Chloride )
Hydrogen Fluoride ) Self indicating adsorption tubes Chlorine ) Sampling was carried out using ports in the stack accessible via a permanent platform. Results Concentrations are quoted under standard conditions: 273
0K, 1.013 kPa,
Particulate was collected on the same filter assembly from the port over a continuous period. Gaseous parameters were determined during the particulate monitoring. Monitoring was carried out on the 29th September 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 43
Document No. 1012-01 v1.00
Smelting Process: Run 1 Run 2 Sample Period: 07.38 – 08.08 08.11 – 08.41 Flue temperature: 95 0C 97 0C Stack Flow: 21718 m3/hr 22254 m3/hr
Particulate: 10.48 mg/m3 3.41 mg/m3
Mass Flow: 0.228 kg/hr 0.076 kg/hr Oxides of Nitrogen: 6 mg/m3 11 mg/m3
Sulphur Dioxide: < 5 mg/m3 < 5 mg/m3 Carbon monoxide: < 5 mg/m3 < 5 mg/m3
Hydrogen Chloride: < 5 mg/m3 < 5 mg/m3
Hydrogen Fluoride: < 1 mg/m3 < 1 mg/m3 Chlorine: < 1 mg/m3 < 1 mg/m3 Copper: < 0.05mg/m3 < 0.05 mg/m3 Titanium: < 0.05 mg/m3 < 0.05 mg/m3
.
______________________ _____________________ Paul Cole Dr. Robin Patrick
Technical Director 4th December, 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 44
Document No. 1012-01 v1.00
Appendix 3 Copy of Dioxin Monitoring Report – May 2008
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P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 45
Document No. 1012-01 v1.00
DIOXIN MONITORING
AT THE
CARNEY SMELTER
A Report to
P CARNEY
Crossakiel
Kells
Co Meath
April, 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 46
Document No. 1012-01 v1.00
1. Introduction
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans, commonly
referred to as dioxins and furans or simply as "dioxins" are produced as by-products
from various chemical manufacturing processes and from combustion processes
where chlorine is present. This group of compounds has a very high toxicity to human
health and consequently very low guideline values have been set for human exposure.
2. Toxic Equivalent Value (TEQ)
There are a great many different isomeric chlorinated species covered by the term
"dioxins". Of these, the most toxic is the 2,3,7,8 tetrachlorodibenzo-p-dioxin. In
relative terms, many other "dioxins" are much less toxic. The accepted convention is
to derive a total toxic equivalent value for any sample relative to the 2,3,7,8 TCDD
which is given a TEQ of unity. This is achieved by applying the relevant agreed toxic
equivalent factor to the concentration of each dioxin and furan species.
3. IPC Licensing
P. Carney operate an aluminium recovery plant at Crossakiel in County Meath. The
operation of the plant is covered by an IPC Licence issued by the Environmental
Protection Agency.
This report presents the results of a monitoring exercise carried out by ASEP in April,
2008
4. Sampling Protocol
Sampling was carried out using a sampling train, compliant with IS EN 1948, which
has been described in detail previously.
5. Sampling Programme
A sample was collected from the smelter at a point after the dust abatement system by
ASEP personnel over an 8 hour period on 14-15 April. Sample details are tabulated
below.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 47
Document No. 1012-01 v1.00
Table 1: Samples
Sampling Period Volume Nm3
23.50 – 07.50 3.105
The sample was delivered directly to the analytical laboratory by a member of staff
from ASEP.
6. Analysis
Analysis was carried out by Envirolab, a specialist "dioxin" laboratory, based in
Manchester. The analytical procedure, which has been detailed previously, involves a
complex extraction, clean-up and concentration programme, followed by multiple ion
high resolution gas chromatography - high resolution mass spectrometry, allied with
UK acceptance criteria (Chemosphere, 21, 999 1990). All laboratory work is
undertaken under fully documented QA/QC control, providing reproducible and
traceable results under the UK UKAS scheme.
7. Results
Results are tabulated below, giving the weights of the various isomers detected in the
samples, together with the toxic equivalent value (derived from NATO/CCMS Toxic
Equivalent Factors). These data were used in conjunction with sampling data (air
volume, temperature and atmospheric pressure) to derive concentrations of "dioxins"
expressed to the standard reference conditions of 273oK and 101.3kPa, dry gas.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 48
Document No. 1012-01 v1.00
Table 2: Dioxin/Furan Content of Stack Emission Samples
( ng total in sample as received)
Envirolab Ref. No 83612
ASEP Ref. No. PC1
2378-TCDD 0.009
Total TCDD 0.58
12378 PeCDD 0.041
Total PeCDD 0.083
123478-HxCDD 0.021
123678-HxCDD 0.042
123789-HxCDD 0.014
Total HxCDD 1.6
1234678-HpCDD 0.51
Total HpCDD 1.5
OCDD 0.37
2378-TCDF 0.014
Total TCDF 2.5
23478-PeCDF 0.16
12378 PeCDF 0.067
Total PeCDF 1.1
123478-HxCDF 0.071
123678-HxCDF 0.070
234678-HxCDF 0.052
123789-HxCDF 0.004
Total HxCDF 0.59
1234678-HpCDF 0.23
1234789-HpCDF 0.046
Total HpCDF < 0.01
OCDF 0.18
I-TEQ (max) 0.15
Note: Total refers to all isomers of the congener group.
ITEQ (max) calculated with “<” values at their reported limits.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 49
Document No. 1012-01 v1.00
8. Emission to Atmosphere
The emission data, corrected to normal temperature and pressure, dry gas is tabulated
below.
Table 3: Emissions to Atmosphere
Sample Volume
in Nm3
Oxygen
%
Dioxin
ng TEQ
Dioxin Emission
in ng TEQ/Nm3
PC1 3.105 20.7 0.15 0.048
No correction has been made for oxygen content.
9. Confidence Limits
The emission standards applicable to "dioxins" emissions push sampling and
analytical techniques to the limit. The difficulty of collecting representative samples,
allied to the complexity of the extraction process, work-up and analytical procedures
results in precision of the order of + 50% at best.
Where the levels recorded above for individual targets are at or below the limit of
detection, in applying the TEQ factors, the approach adopted is to take the “less than”
value as absolute i.e. the worse case.
In determining the final emission to atmosphere, the worse case approach has been
adopted in that no correction has been made for any apparatus blank and “less than”
values have been taken as absolute.
_____________________________________ R.A. Patrick BSc. PhD, FICI, CChem FRSC 22 May, 2008
Technical Director
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 50
Document No. 1012-01 v1.00
Appendix 4 Copy of Dioxin Monitoring Report – September 2008
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P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 51
Document No. 1012-01 v1.00
DIOXIN MONITORING
AT THE
CARNEY SMELTER
A Report to
P CARNEY
Crossakiel
Kells
Co Meath
September, 2008
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 52
Document No. 1012-01 v1.00
1. Introduction
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans, commonly
referred to as dioxins and furans or simply as "dioxins" are produced as by-products
from various chemical manufacturing processes and from combustion processes
where chlorine is present. This group of compounds has a very high toxicity to human
health and consequently very low guideline values have been set for human exposure.
2. Toxic Equivalent Value (TEQ)
There are a great many different isomeric chlorinated species covered by the term
"dioxins". Of these, the most toxic is the 2,3,7,8 tetrachlorodibenzo-p-dioxin. In
relative terms, many other "dioxins" are much less toxic. The accepted convention is
to derive a total toxic equivalent value for any sample relative to the 2,3,7,8 TCDD
which is given a TEQ of unity. This is achieved by applying the relevant agreed toxic
equivalent factor to the concentration of each dioxin and furan species.
3. IPC Licensing
P. Carney operate an aluminium recovery plant at Crossakiel in County Meath. The
operation of the plant is covered by an IPC Licence issued by the Environmental
Protection Agency.
This report presents the results of a monitoring exercise carried out by ASEP in
September, 2008
4. Sampling Protocol
Sampling was carried out using a sampling train, compliant with IS EN 1948, which
has been described in detail previously.
5. Sampling Programme
A sample was collected from the smelter at a point after the dust abatement system by
ASEP personnel over an 8 hour period on 28 – 29 September, 2008. Sample details
are tabulated below.
Table 1: Samples
Sampling Period Volume Nm3
23.25 – 07.25 3.395
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 53
Document No. 1012-01 v1.00
The sample was delivered directly to the analytical laboratory by a member of staff
from ASEP.
6. Analysis
Analysis was carried out by Envirolab, a specialist "dioxin" laboratory, based in
Manchester. The analytical procedure, which has been detailed previously, involves a
complex extraction, clean-up and concentration programme, followed by multiple ion
high resolution gas chromatography - high resolution mass spectrometry, allied with
UK acceptance criteria (Chemosphere, 21, 999 1990). All laboratory work is
undertaken under fully documented QA/QC control, providing reproducible and
traceable results under the UK UKAS scheme.
7. Results
Results are tabulated below, giving the weights of the various isomers detected in the
samples, together with the toxic equivalent value (derived from NATO/CCMS Toxic
Equivalent Factors). These data were used in conjunction with sampling data (air
volume, temperature and atmospheric pressure) to derive concentrations of "dioxins"
expressed to the standard reference conditions of 273oK and 101.3kPa, dry gas.
P. Carney Ltd. Annual Environmental Report 2008
Environmental Efficiency Consultants (Ire) Ltd 54
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Table 2: Dioxin/Furan Content of Stack Emission Samples
( ng total in sample as received)
Envirolab Ref. No 92731
ASEP Ref. No. PC1
2378-TCDD 0.006
12378 PeCDD 0.020
123478-HxCDD 0.033
123678-HxCDD 0.031
123789-HxCDD 0.038
1234678-HpCDD 0.16
OCDD 0.093
2378-TCDF 0.023
23478-PeCDF 0.028
12378 PeCDF 0.020
123478-HxCDF 0.048
123678-HxCDF 0.040
234678-HxCDF 0.072
123789-HxCDF 0.044
1234678-HpCDF 0.23
1234789-HpCDF 0.023
OCDF 0.029
I-TEQ (max) 0.068
Note: ITEQ (max) calculated with “<” values at their reported limits.
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8. Emission to Atmosphere
The emission data, corrected to normal temperature and pressure, dry gas is tabulated
below.
Table 3: Emissions to Atmosphere
Sample Volume
in Nm3
Oxygen
%
Dioxin
ng TEQ
Dioxin Emission
in ng TEQ/Nm3
PC1 6.00 20.7 0.07 0.011
No correction has been made for oxygen content.
9. Confidence Limits
The emission standards applicable to "dioxins" emissions push sampling and
analytical techniques to the limit. The difficulty of collecting representative samples,
allied to the complexity of the extraction process, work-up and analytical procedures
results in precision of the order of + 50% at best.
Where the levels recorded above for individual targets are at or below the limit of
detection, in applying the TEQ factors, the approach adopted is to take the “less than”
value as absolute i.e. the worse case.
In determining the final emission to atmosphere, the worse case approach has been
adopted in that no correction has been made for any apparatus blank and “less than”
values have been taken as absolute.
_____________________________________ R.A. Patrick BSc. PhD, FICI, CChem FRSC 9 January, 2009
Technical Director
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Appendix 5 Tank and pipeline inspection report
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Appendix 6 Noise Monitoring Report 2008
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Appendix 7 Energy Audit Report Summary
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Appendix 8 Emergency Response Plan
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