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January 2020
Annual Environmental Report (AER) 2019 Queens Island
Prepared by
Bombardier Aerostructures & Engineering Services Short Brothers Plc Airport road, Queen’s Island, Belfast, BT3 9DZ Permit Reference: P0135/06A
Acknowledgement
Contents Amendment Record This report has been issued and amended as follows:
Version Date Approval
Rev:
This report has been reviewed and approved by the following Bombardier personnel:
_ Dr Colette Eastwood,
Table of Contents
Description Page No.
Executive Summary 1 Section 1.0: Introduction 2 Section 2.0: Solvent Reduction Scheme 3 Section 3.0: Air Emission Results 6 Section 4.0: Review of Fugitive Emissions 7 Section 5.0: Water Emission Results 8 Section 6.0: SPMP Summary 9 Section 7.0: Reports Summary
Section 7.1: Environmental Management System (EMS) Targets 10 Section 7.3: Energy Efficiency Review 11 Section 7.2: Pollution Inventory Report (PIR) 13
Appendix Appendix I Air Emission Reports Appendix II Water Emission Reports Appendix III NIW Compliance Reports Appendix IV Pollution Inventory Report (PIR)
1
Executive Summary
The following report contains information required to be submitted by Bombardier Aerostructures and Engineering Services, Short Brothers Plc (BA) to the regulating agency, Northern Ireland Environment Agency (NIEA), as per the Bombardier Aerospace Pollution Prevention and Control (PPC) Permit No P0135/06A. Each section relates to a specific reporting condition outlined in the permit. The structure follows the requirements for annual reporting. Third party reports, spreadsheets or tables, such as external laboratory results and waste spreadsheets are presented in the appendix section at the end of the report. This report demonstrates full environmental compliance with Permit P0135/06A.
2
Section 1.0: Introduction
1.1 Introduction
During 2019 Bombardier Aerostructures and Engineering Services, Short Brothers Plc (BA) made significant investment, and deployed substantial resources, in addressing all aspects of emissions to air, water and land at its Queen’s Island facility. Areas targeted include:
Tonnage of hazardous waste generated decreased by 5%
Tonnage of non-hazardous waste decreased by 3%
Total waste decreased by 4%
Total VOC decreased by 5% Annual production hours decreased by 3% in 2019 compared to 2018. The application of LEAN principles through the Achieving Excellence System (AES), which is deployed
at all BA facilities, and the continued rigid implementation of our Environmental Management System
(EMS) have contributed greatly to continual improvement. These systems are driving improvement
projects that will bring BA to the next level of compliance and efficiency.
Significant environmental improvement projects in 2019 included:
Refurbishment of Derwent WWTP Facility at C04
Management of Change project software developed further
Critical Equipment List and PPM reviews (all sites)
HAZOPS for the following:
Kurion Plant Regen Mods
Penetrant Flaw Detection (PFD) Process
CETLAB & M&P Pilot Line
S02 LEV
Cleanline Chemical Additions & Modifications
NI Water records show that all BA discharges were within its trade effluent compliance range in 2019
except for 1 parameter, suspended solids at AFF1 in November. A subsequent review of operations in
house monitoring data, and consideration of the NIW sampling protocol concluded that the high
suspended solids was erroneous and therefore is currently being appealed with NIW Trade Effluent
Department.
3
Section 2.0: Solvent Reduction Scheme
Continued improvements were made in 2019 on reducing overall solvent usage at the Queen’s Island facility. Volatile Organic Compound (VOC) reductions can be attributed to;
A modified Diastone-DLS wipe on a new cloth type rolled out (reduced solvent content of 10%)
Ongoing test programme of A2519 zero solvent wipe at BAS to be used at all sites for general cleaning and cleaning prior to painting on composites.
Continued use of solvent recycler at C88 Paintshop has further reduced consumption of Brushwash and contributed to VOC emission reduction.
Senior Management led engagement with solvent reduction initiatives
Wipe access at Tool Cribs / stores has improved reporting process via Business Warehouse aiding analysis of solvent consumption across all sites
Effective and correct use of VOC containing materials (wipes and thinners for correct applications, reduced solvent waste e.g. wipes- keeping container lids closed) highlighted via Bgreen and awareness training programmes.
Training of paintshop operators on site by Safetykleen (paint gun cleaning) specialists
Solvent focussed Process Control Specification (PCS) checks at Daily Morning Meetings (DMM)
Bombardier demonstrated compliance with the Solvent Reduction Scheme for 2019. An actual emission ratio of 0.44 vs target emission of 0.58. The target emission for 2019 was 23,222kgs of VOC, and BA’s actual emission for 2019 was 17,535kgs VOC, see table 1.0 below.
Table 1.0 – BA Solvent Reduction Scheme results 2019
ACTUAL EMISSION
SOLVENT (kgs VOC) 32,834 17,535
SOLIDS (kgs) 40,038
COMPLIANCE YES/NO YES
0.58
0.44
SOLVENT REDUCTION SCHEME
0.58 x Total Solids Target Emission
23,222 23,222
Table 2.0 – Comparison of target emission vs actual emission
Target Emission
Kgs
Actual Emission
kgs
(Target vs Actual ) % change
2017 23,709 22,203 -6%
2018 22,491 18,890 -15%
2019 23,222 17,535 -7%
4
At each of the Environmental Working Groups (EWG), solvent management has a dedicated section which is discussed in great detail. Site specific reports are generated for each meeting with targets reviewed and deviations (if any) scrutinised. The data is split into the four solvent use activities: Product Coating, Product Cleaning, Equipment Cleaning, Tool Coating and charted versus target. The sites find this report extremely useful as it allows them to dissect, at a local, level procurement trends, repeat ordering and target solvents which are consumed in high volumes. Target solvents are those which either have proliferated or can be reduced through the application of specific recovery or reduction technologies. The main target solvents identified in previous years on the Queen’s Island site included Brushwash, perchloroethylene (PCE) and thinners. These solvents are monitored monthly and reported at EWG’s. Where applicable they are eliminated or substituted for a lower VOC alternative. From 2018, new ‘target solvents’ have been identified. These include solvents that account for higher proportions of VOC emissions or where there is considered to be opportunity for reduction. Reduction initiatives are highlighted in the section below.
Table 3.0 – Comparison of newly identified target solvent usage 2018 – 2019
Product 2018 2019 % Diff (2018 vs 2019)
Brushwash 6060.60 4422.60 -27.0%
Safetykleen 1600.36 1274.90 -20.3%
Diestone SRM 5102.15 5552.40 8.8%
Diestone Med 4157.37 4318.50 3.9%
Diestone Lrg 148.01 245.34 65.8%
Total 17068.49 15813.74 -7.4%
Figure 1.0 – Comparison of Target Solvent usage 2018 – 2019
As evident in Figure 1.0, Brushwash has decreased. This has been aided by the consistent audits conducted by the Environmental Department, solvent Process Control Specification (PCS) checks and the introduction of the solvent recycler in 2016. Use of Brushwash has been eliminated at C97 Paintshop with painters instead using Safetykleen.
5
Even with C97 increasing consumption of Safetykleen at its Paintshop, Safetykleen consumption across Queens Island has decreased by 20%. This correlates with a reduction in throughput at the paint shops however ongoing annual training of the operators on the use of the gun cleaning equipment has brought solvent reductions.
Diestone DLS & SRM consumption has increased collectively by 8% across Queens Island. This is attributed to a 32% increase in production hours at WPU Facility. Increased awareness of solvent use and a 10% reduction in solvent content of wipes has helped offset this increase. Although a 66% increase in Diestone DLS Lrg wipes is noted this accounts for only 97kg and attributed to the A220 contract specifically requiring large wipes. Continued focus for 2020 is to target Diestone DLS as it is the only approved solvent on the A220 contract worked in WPU. Initiatives are underway with M&P and the solvent wipe distributer to explore low / no VOC alternatives. This project is ongoing.
Further initiatives are planned for 2020 and include;
Continued monitoring of storage and disposal of solvent based cleaning materials.
Complete test programme and secure approval for use of A2519 zero solvent wipe to be used at all sites for general cleaning and cleaning prior to painting on composites.
Ongoing engagement with M&P team to identify, approve and introduce low VOC alternatives to substitute and / or eliminate use of high VOC materials. Focus on Diastone DLS wipes which are extremely volatile and emit a large volume of VOC. Also, further work with suppliers to reduce solvent content of already approved wipes on site.
Exploring use of different cloth materials used in solvent wipes for different applications.
Use of a low VOC solvent or other technology to remove rubber maskant from hooks used at Robotic Spray.
Enhanced audit protocol for ordering, delivering, storing, issuing, disposal and use of solvent based cleaning materials.
Best Alternative Technologies - Investigate potential alternatives for surface cleaning solvents and spray gun cleaners.
It is envisaged that the implementation of initiatives outlined above will lead to further solvent and VOC reductions throughout 2020.
6
Section 3.0: Air Emissions Results
BA engaged a third party contractor, Socotec Ltd, to carry out all discrete air monitoring at the designated emission points agreed with the regulator for 2019:
A39 - Solvent Recovery Plant
M29 - C97 Manual Line Extraction
M30 - C97 Manual Line Extraction
M31 - C97 Manual Line Extraction Socotec are an MCERT accredited contractor that conforms to the guidelines set out for air monitoring from stack emissions. Temporary access to M1 standard scaffold platforms were erected to facilitate the sampling regime where permanent platforms were not available. Both the external and internal results for emissions testing showed full compliance with the emission limit values set out in the PPC Permit. The external reports can be found in appendix II and the internal Continuous Emissions Monitoring (CEM) results from the Solvent Recovery Plant (SRP) are in table 4.0 below. A continuous emission monitor Gas Chromatography Flame Ionising Detector (GC-FID) is installed on the outlet of the Solvent Recovery Plant (SRP). This was serviced once and calibrated twice in 2019. No exceedances were recorded for VOC (expressed as PCE) in 2019 as can be seen in table 4.0, the average daily concentration for each month is recorded. BA have remained below the permitted limits of 20 mg/m3 daily average & 30 mg/m3 hourly average. The final outlet is the discharge to atmosphere.
Table 4.0 – Monthly Summary of CEMS Emission Concentrations from Solvent Recovery Plant at C04 2019
Year Month
Final Outlet (Avg Daily concentration mg/m3)
PPC Limit 20 mg/m3
2019 JAN 0.02
2019 FEB 0.02
2019 MAR 0.03
2019 APRIL 0.02
2019 MAY 0.03
2019 JUNE 0.08
2019 JULY 0.02
2019 AUG 0.02
2019 SEPT 0.01
2019 OCT 0.01
2019 NOV 0.02
2019 DEC 0.01
7
Section 4.0: Review of Fugitive Emissions
Fugitive emissions at the facility arise from solvents contained in paints, sprays, wipes and cleaning chemicals. The quantity of emission from these sources is calculated using the DEFRA solvent management plan guidance tool. The total fugitive emissions for 2019 from these sources are calculated at 17,247 kg/VOC (Figure 2.0). This figure has decreased by 3% since 2018.
Figure 2.0 – Review of fugitive emissions 2017 – 2019
8
Section 5.0: Water Emission Results
BA engaged with Northern Ireland Water (NIW) in 2019 with the goal of establishing discharge consents
for all process emissions to the foul system at Queens Island with revised limits to align with the Queens
Island permit. This is currently underway. A revised Trade Effluent discharge consent from NI Water
was received for AFF1 due to increased discharge volumes.
Emissions data demonstrates that BA were 100% compliant in 2019 at No.48 emission points as per
internal monitoring regime. Results can be found in Appendix II attached.
NI Water completed 12 rounds of monthly sampling at our main emission points arising at our Queen’s
Island Facility based effluent treatment plants; MFF1 and AFF1. Results can be found in Appendix III
attached.
NI Water records show that all BA discharges were within its trade effluent compliance range in 2019
except for 1 parameter, suspended solids at AFF1 in November. A subsequent review of operations in
house monitoring data, and consideration of the NIW sampling protocol concluded that the high
suspended solids was erroneous and therefore is currently being appealed with NIW Trade Effluent
Department.
9
Section 6.0: SPMP Summary
Site Protection and Monitoring Programme (SPMP) for BA, Queen’s Island installation was submitted to
the NIEA as part of Pollution Prevention Control (PPC) Permit No P0135/06A, authorising the operation
of the Queen’s Island facility.
The programme was revised and updated with procedures and systems in place at BA to ensure (as far
as reasonable practicable) effective prevention of pollution to land throughout the life of the installation.
A complete review of all BA plant, operations and activities were carried out by the Environmental
Department in order to establish the potential pollution pathways to land. All areas and processes where
a potential pollution pathway exists were reviewed within the SPMP
Another focus during 2019 was to review and update the list of SPMP bunds / sumps and the frequency
of bund checks, either weekly or monthly, as based on level of risk. This review also enabled any new
processes to be included within the overall SPMP design programme for Queen’s Island. Bund
numbering was reviewed and new bund labels were obtained and attached to all bunds.
In 2019 a critical equipment procedure was developed. The purpose of this procedure was to define
arrangements for the identification, evaluation and management of equipment that is considered critical
to environmental protection. This is an extensive programme of works and expected to be completed by
December 2020.
Bund integrity testing commenced across all Bombardier sites as per BS 8007:1987 Environmental
Protection Agency ‘Guidance Note on Storage and Transfer of Materials for Scheduled Activities’. All
bunds / sumps were risk assessed, scored, ranked in level of risk then scheduled with a masterplan
developed due to be completed in 2021. A report will be produced for each test and saved on a shared
drive. Findings are communicated to the team with actions arising being resolved via Facilities
Helpdesk.
From week 27 SPMP summary findings were not only communicated daily to area owners but also
incorporated into a weekly report. See Table 5. This is communicated to Department leads in an
attempt to better track and encourage close out. This has been well received by various functions
throughout the organisation resulting in improved housekeeping, waste management etc.
Table 5.0 – Example of weekly SPMP Summary Report
Area Issue First Observed Action Comments
Machine ShopLiquid/coolant in IBC bund at cylindrical briquette machine
(~10%)Week 44
Assembly Paint
WasteKemfast paint / brushw ash deliveries not stored aw ay Week 49
C97 Paint w aste
Bund door left open allow ing rainw ater ingress, paint slops not
decanted, cardboard cage containing mixed w aste and
recyclables
Week 50
Machine Shop sw arf along w all at Makino #3 - poor housekeeping Week 50
SRP/Nederman Sw arf spill around nederman and SRP bund Week 49
SRP/Nederman Missing perspex screen on Nederman unit Week 50
Newtownards
Airport West
Queens Island
Week 50
SPMP Weekly Summary Report
10
Section 7.0: Annual Reports
7.1 Environmental Management System (EMS)
BA have operated an EMS which has been certified to ISO 14001 since 1998 and awarded to ISO14001:2015 standard in December 2016. The organisation uses the EMS to systematically identify the environmental risks, potential impacts and compliance requirements that need to be managed by our business. The EMS ensures that regular reviews of BA operations identify the most significant environmental aspects and provides the information to establish targets which deliver continual improvement. 2018 baselines were used for ongoing environmental and energy reduction targets for 2019. These targets are key to the establishment of the environmental management plans and action plans that deliver environmental continuous improvements across all operations. At BA sites the EMS is maintained at each business unit by cross functional Environmental Working Groups (EWG’s). The EWG’s in each area consist of production managers, functional managers, maintenance and all other stakeholders whose activities have the potential to impact on the environment. Targets are set for each business unit that are consistent with the targets imposed by Bombardier Inc., whilst also addressing the significant environmental issues at each business unit. Environmental Management Plans (EMPs) are developed by each EWG to help achieve the objectives and targets set for the sites. EMPs are shared out across its functional teams to improve awareness and ownership across the business. The Environmental Department provide templates and support to ensure a consistent and effective approach. Progress against targets is monitored comprehensively in a variety of ways including GRACIS (corporate tool) reporting, senior management reviews and regularly at local working groups. Example of Main Factory Environmental Management Plan
ENVIRONMENTAL MASTERPLANS 2019 2019 WPU
EMP REF SITE SPECIFIC TARGET PLAN MANAGER % START END REF COMPANY TARGET REF POLICY COMMITMENT
EMP1Ensure actual tonnage of hazardous waste generated remains below a
1.6% increase 100% 01-Jan-19 31-Dec-19 1Reduce normalised non-hazardous and hazardous waste by1%
of 2013 levels in 2018 4 Conserve natural resources
EMP2Ensure actual tonnage of non-hazardous waste generated remains below
a 14% increase 100% 01-Jan-19 31-Dec-192
Reduce normalised non-hazardous and hazardous waste by1%
of 2013 levels in 2018 4 Conserve natural resources
EMP3 Ensure actual VOC emissions remain below the 2% increase (6813kg) 100% 01-Jan-19 31-Dec-19 3 Reduce VOC emissions by 6 % of 2017 levels in 2018 Communicate & raise awareness
EMP4Target 0.5 hrs environmental training in 2019 (162 hours)
100% 01-Jan-19 31-Dec-194
Deliver 30mins of environmental training per head 4 Conserve natural resources
BUSINESS UNIT / FUNCTION
The EMS is subject to regular external audits. In June and December of 2019, two surveillance audits were carried out by the external auditor (LRQA). No non-conformances were raised during these visits which is considered to be a significant achievement given the scale and diversity of BA activities. In addition, BA Belfast participates annually in the BITC Northern Ireland Environmental Benchmarking Survey. This survey measures environmental management and performance. The company was awarded Top performer with ‘platinum status’ in the annual benchmarking survey for the third year running. This is considered to be further recognition of the robust arrangements in place for delivering compliance and continual improvements.
11
7.2 Energy Efficiency – Schedule 4
BA has a 5 year energy strategy to utilise onsite power generation for maximum reduction of fossil fuel dependency, hence reducing CO2 emissions, energy costs and supporting long term competitiveness. Renewable technologies through power purchase agreements (PPA) include:
Photovoltaic panels at Wing Production Unit
Biomethane combustion engines
Energy from waste plant
Detailed below is information relating to the site’s energy consumption as well as a breakdown per fuel type. It also includes a summary of improvement projects that have been initiated with a view to reducing energy usage and carbon/ greenhouse gas emissions across the site. The efficient use of energy and the increased use of renewable and low carbon technologies is a key part of BA strategy for the future. The high cost of energy and the drive to reduce greenhouse gas emissions requires BA to continue the improvement plans already undertaken, results of which can be seen in Tables 6.0 & 7.0. The improvement plans (listed under ‘Equipment Upgrades’) identified and introduced this year will further reduce the energy related carbon footprint.
Table 6.0 lists the energy consumption in 2019 for electricity, gas and oil.
Table S4.1 Energy Consumption
Delivered MWh Primary MWh Tonne / MWh % of total
Electricity 27,427 71,310 18,227 64.32
Gas 54,607 54,607 10,040 35.43
Oil 164 164 42 0.15
Other- LPG 130 130 28 0.10
Table 7.0 shows the changes in type and amount of energy consumed over the past 3 years.
Electricity
(MWh) Gas
(MWh) Oil (litres)
2015 29,299 55,982 25,305
2016 26,073 51,262 22,710
2017 27,048 50,455 49,075
2018 28,349 56,830 78,200
2019 27,427 54,607 15,275
2019 saw a decrease in consumption of electricity and gas. This is primarily due to the decrease in heating requirements during Q1 and 3% reduction in hours worked. Headline reductions include:
Oil consumption reduced by 80%
Gas consumption reduced by 4%
Electricity consumption reduced by 3%
12
Oil consumption saw the largest reduction. This is because in 2018 the Wartsilla (CHP Engine) was exporting energy to the grid due to a transformer failure. This engine when operating consumes approx. 1000 litres of oil per hour. 46,800 litres oil were consumed exporting energy to the grid during this time.
EU ETS Variation in 2019 saw the addition of emission sources for Queens Island Permit (UN-N-IN-12121) increasing the overall capacity to 91MWh.
Energy Monitoring
Site energy consumption reports are generated weekly & monthly by the energy department via an online energy management tool and distributed to all Production Managers (Figure 3.0). Information is reviewed and fed back at Environmental Working Groups. Opportunities for improvement are reported to the Energy Department and logged on the Register of Opportunities.
Monthly energy (Electricity) usage reports for use at EWG’s:
Figure 3.0
Any issues or discrepancies with the data will be discussed at the site’s EWG meeting to identify causes of the abnormal consumption and potential corrective actions. Energy monitoring is an essential tool in providing visibility to the main stakeholders and managers across the sites. The Queen’s Island site was registered and is fully compliant under the Energy Savings Opportunity Scheme (ESOS). An energy survey was completed in 2019. The identified opportunities have been incorporated into the organisation ‘Opportunities Register’ for progression.
Equipment Upgrades
2019 has seen the continued upgrading of equipment to more energy efficient systems where necessary. Specific projects completed this year include;
1. Boiler 5 economiser replaced at the Main boiler house to increase boiler efficiency
2. Steam plumes from passing Ogden pumps repaired and replaced to further improve condensate return to the main boiler house
13
3. Reinstate weekend compressor capability in Main Factory, Machine Shop
4. Implement more control of the C97 manual line dryer by the operations staff to the production hours - 2/3rds cost & energy savings
Training & Awareness
Energy Training overview with FM Shift Operators to highlight opportunities and raise awareness
Energy Management Essentials course for FM Services team to provide tools to better control energy on Bombardier sites
Compulsory energy walkover (all sites) with Environmental Dep, FM representatives, Operations Managers & Production Managers. Findings communicated via EWG’s and tracked using a ‘Register of Opportunities’.
7.6 Pollution Inventory Report (PIR) PIR report is in appendix IV. This report contains information on the emissions to air, land and water from the permitted facility; there are some variations in the report compared to 2018 figures;
o Water Copper emissions reduced by 70% Chromium emissions reduced by 26% Nickel emissions reduced by 61% Zinc emissions increased by 19%
o Waste
Non-hazardous waste disposed reduced by 12% Hazardous waste recovered reduced by 10% Other waste disposed (non-haz) increased by 15% Other waste recovered (non-haz) reduced by 3%
o Energy
Gas consumption decreased by 4% Electricity consumption decreased by 3% Oil consumption decreased by 80% Water consumption decreased by 18%
A1
SUMMARY OF RELEASES INTO AIR
Operator: Short Brothers PLC Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Release Point: A39
Signed on behalf of the Operator Date: 10/01/20
Date
Pollutant
Pollutant
Limit Value (mg/m3)
Pollutant
Measured Value (mg/Nm3)
Average Temperature
(oC)
Volume Flow
(m3/hr)
Average Velocity
(m/s)
24th – 25th Sept
Total Particulate Matter
50 0.95 41 10362 9.8
Total VOC
(as Perchloroethylene) 20 5.78 41 10362 9.8
A1
SUMMARY OF RELEASES INTO AIR
Operator: Short Brothers PLC Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Release Point: M29
Date
Pollutant
Pollutant
Limit Value (mg/m3)
Pollutant
Measured Value (mg/Nm3)
Average Temperature
(oC)
Volume Flow
(m3/hr)
Average Velocity
(m/s)
24th – 25th Sept
Heavy Metals n/a 0.138 26 9356 7.8
Hydrogen Chloride 10 0.02 26 9356 7.8
Hydrogen Flouride 2 0.10 26 9356 7.8
Signed on behalf of the Operator Date: 10/01/20
A1
SUMMARY OF RELEASES INTO AIR
Operator: Short Brothers PLC Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Release Point: M30
Date
Pollutant
Pollutant
Limit Value (mg/m3)
Pollutant
Measured Value (mg/Nm3)
Average Temperature
(oC)
Volume Flow
(m3/hr)
Average Velocity
(m/s)
24th – 25th Sept
Heavy Metals n/a 0.02 28 6449 9.1
Hydrogen Chloride 10 0.06 28 6449 9.1
Hydrogen Flouride 2 0.03 28 6449 9.1
Signed on behalf of the Operator Date: 10/01/20
A1
SUMMARY OF RELEASES INTO AIR Operator: Short Brothers PLC Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Release Point: M31
Date
Pollutant
Pollutant
Limit Value (mg/m3)
Pollutant
Measured Value (mg/Nm3)
Average Temperature
(oC)
Volume Flow
(m3/hr)
Average Velocity
(m/s)
24th – 25th Sept
Chromium n/a 0.007 30 28810 8.4
Hydrogen Chloride 10 0.11 30 28810 8.4
Hydrogen Flouride 2 0.04 30 28810 8.4
Signed on behalf of the Operator Date: 10/01/20
SOCOTEC Job Number:Report Date:Version: 1Report By: Matthew GreenMCERTS Number: MM 04 499MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Signature:
Sampling Date(s):24th - 25th September 2019
14th November 2019LEK 11848
BT3 9DZ
Queens Island
Bombardier Aerospace
Belfast
Release Point: M29
Your contact at SOCOTEC LTD
Operator & Address:
Airport Road
2-4 Langlands PlaceKelvin South Business Park
East KilbrideG75 0YF
Tel: 01355 246 730Fax: 01355 249 669
Permit Reference:PPC (NI) Permit: P0135/06A
David HayBusiness Manager - North
Tel: 01355 246 730Email: [email protected]
STACK EMISSIONS MONITORING REPORT
SOCOTEC UK Reporting Template v5 Page 1 of 30
SOCOTEC UK LTD
www.socotec.co.uk
EXECUTIVE SUMMARY
Stack Emissions Monitoring Objectives
- Plant
- Operator
- Stack Emissions Monitoring Test House
Emissions Summary
Monitoring Times
Process Details
Monitoring Methods
Analytical Methods
- Sampling Methods with Subsequent Analysis
- On-Site Testing
Sampling Location
- Sampling Plane Validation Criteria
- Duct Characteristics
- Sampling Lines & Sample Points
- Sampling Platform
- Sampling Location / Platform Improvement Recommendations
Sampling and Analytical Method Deviations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
Page 2 of 30
Bombardier AerospaceBelfastM29
LEK 11848 / Version 124th - 25th September 2019
PPC (NI) Permit: P0135/06A
SOCOTEC UK LTD
www.socotec.co.uk
Plant
M29
Operator
Bombardier Aerospace
Airport Road
Queens Island
Belfast
BT3 9DZ
PPC (NI) Permit: P0135/06A
Stack Emissions Monitoring Test House
SOCOTEC - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015
Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC LTD.
MONITORING OBJECTIVES
SOCOTEC LTD were commissioned by Bombardier Aerospace to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.
Bombardier Aerospace operates a extraction from baths on manual line process at Belfast which is subject to PPC (NI) Permit P0135/06A, under thePollution Prevention and Control (Industrial Emissions) Regulations (Northern Ireland) 2013.
EXECUTIVE SUMMARY
The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's PPC (NI) Permit, P0135/06A.
Page 3 of 30
Bombardier AerospaceBelfastM29
LEK 11848 / Version 124th - 25th September 2019
PPC (NI) Permit: P0135/06A
SOCOTEC UK LTD
www.socotec.co.uk
Parameter Units Result Calculated Uncertainty
+/-Heavy Metals mg/m³ 0.138 0.009 -Heavy Metals Emission Rate g/hr 1.151 0.079 -Hydrogen Chloride mg/m³ 0.02 0.007 10Hydrogen Chloride Emission Rate g/hr 0.21 0.063 -Hydrogen Fluoride mg/m³ 0.10 0.021 2Hydrogen Fluoride Emission Rate g/hr 0.87 0.177 -Moisture % 0.38 0.06 - P
Stack Gas Temperature oC 26 - -Stack Gas Velocity m/s 7.8 0.18 -Gas Volumetric Flow Rate (Actual) m³/hr 9356 476 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 8473 431 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 8441 429 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 8473 431 -
Emission Limit Value (ELV)
P
EMISSIONS SUMMARY
Reference conditions are 273K, 101.3kPa without correction for water vapour
EXECUTIVE SUMMARY
ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.
P
P
MCERTS accredited
result
P
Page 4 of 30
Bombardier AerospaceBelfastM29
LEK 11848 / Version 124th - 25th September 2019
PPC (NI) Permit: P0135/06A
SOCOTEC UK LTD
www.socotec.co.uk
Heavy Metals Run 1Hydrogen Chloride Run 1Hydrogen Fluoride Run 1 30 minutes
MONITORING TIMES
60 minutes
Sampling TimesSampling Date(s)Parameter
EXECUTIVE SUMMARY
Sampling Duration
24 September 201915:54 - 16:2424 September 201916:29 - 16:59 30 minutes
12:20 -24 September 2019
24 September 2019 12:52 - 13:52
Preliminary Stack Traverse
Page 5 of 30
Bombardier AerospaceBelfastM29
LEK 11848 / Version 124th - 25th September 2019
PPC (NI) Permit: P0135/06A
SOCOTEC UK LTD
www.socotec.co.uk
Description of process Extraction From Baths on Manual Line
Continuous or batch Continuous
Product Details Aerospace Components
Part of batch to be monitored (if applicable) N/A
Normal load, throughput or continuous rating Normal Operation
Fuel used during monitoring N/A
Abatement None
Plume Appearance None
Process Details
EXECUTIVE SUMMARY
PROCESS DETAILS
Parameter
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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MUProcedure Method (LOD) +/- % Result +/- % ELV
Heavy Metals AE 108 1015 Yes 0.002 mg/m³ 6.9% N/A - No ELV
Hydrogen Chloride
AE 111 1015 Yes 0.002 mg/m³ 30.3% 0.07%
Hydrogen Fluoride
AE 113 1015 Yes 0.005 mg/m³ 20.3% 1.04%
Moisture AE 105 1015 Yes 0.03% 15.62% N/A - No ELV
Velocity AE 154 1015 Yes 5 Pa 2.3% N/A - No ELV
Volumetric Flow Rate
AE 154 1015 Yes - 5.1% N/A - No ELV
MONITORING METHODS
SRM - BS EN ISO 16911-1
SRM - BS EN ISO 16911-1
Method
SRM - BS ISO 15713
Standard Reference Method / Alternative Method
BS EN 14790 has been validated over a range of 4 - 40%. It is however the prefered method of the Environment Agency for concentrations below 4%
SRM - BS EN 14790
The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environment Agency Technical Guidance Note (Monitoring) M2.
SRM - BS EN 1911
SRM - BS EN 14385
Monitoring Methods
EXECUTIVE SUMMARY
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Heavy Metals ASC/SOP/117 1252 Yes SOCOTEC (Bretby)
ASC41282 8 Weeks
Hydrogen Chloride
ASC/SOP/110 1252 Yes SOCOTEC (Bretby)
ASC41283 8 Weeks
Hydrogen Fluoride
ASC/SOP/110 1252 Yes SOCOTEC (Bretby)
ASC41283 8 Weeks
Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period
Analysis Location
Moisture AE 105 1015 YesSOCOTEC (East
Kilbride)- -
ON-SITE TESTING
Analysis Report number
UKAS Accredited Lab Analysis
The following tables list the analytical methods employed together with the custody details. Unless otherwise stated the samples are archived at the analysis lab location.
Analysis LabArchivePeriod
UKAS Lab Number
Analytical Procedure
Analytical TechniqueSpecies
SAMPLING METHODS WITH SUBSEQUENT ANALYSIS
Gravimetric
Ion Chromatography
Ion Chromatography
Analytical Methods
Inductively coupled Plasma - Mass Spectrometry
Analytical Technique
EXECUTIVE SUMMARY
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Sampling Plane Validation Criteria Value Units Requirement Compliant Method
Lowest Differential Pressure 39 Pa >= 5 Pa Yes BS EN 15259
Lowest Gas Velocity 7.3 m/s - - -
Highest Gas Velocity 8.3 m/s - - -
Ratio of Gas Velocities 1.1 : 1 < 3 : 1 Yes BS EN 15259
Mean Velocity 7.8 m/s - - -
Maximum angle of flow with regard to duct axis <15 o < 15o Yes BS EN 15259
No local negative flow Yes - - Yes BS EN 15259
Value Units Isokinetic
Shape Circular -
Depth 0.65 m Sample port size 4" BSP -
Width - m Number of lines used 1 -
Area 0.33 m2 Number of points / line 4 -
Port Depth 110 mm Duct orientation Vertical -Filtration In Stack -
General Platform Information
Permanent / Temporary Platform / Ground level / Floor Level / Roof
Inside / Outside
M1 Platform requirements
Is there a sufficient working area so work can be performed in a compliant manner
Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)
Platform has vertical base boards (approximately 0.25 m high)
Platform has removable chains / self closing gates at the top of ladders
Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m
Sampling Platform Improvement Recommendations (if applicable)
Yes
Inside
Yes
No
No
SAMPLING LINES & POINTS
Yes
DUCT CHARACTERISTICS
EXECUTIVE SUMMARY
Permanent
Where possible a second sample port should be installed at 90o to the current sample port and the platform extended to meet all the requirements asspecified in EA Guidance Note M1.
SAMPLING LOCATION
Yes
SAMPLING PLATFORM
Non-Iso & Gases
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Sample Points
Only one sample line is available for the testing to be carried out, therefore the number of points sampled on this available line will bedoubled in accordance with the standard.
Sampling & Analytical Method Deviations
EXECUTIVE SUMMARY
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APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
APPENDICES
CONTENTS
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SOCOTEC UKAS Lab MCERTSTechnical Number AccreditedProcedure Method
AE 108 1015 Yes 1AE 111 1015 Yes 1AE 113 1015 Yes 1AE 105 1015 Yes 1AE 154 1015 Yes 1
Method
Hydrogen ChlorideHydrogen Fluoride
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
Number of Samples
Standard Reference Method / Alternative Method
SRM - BS EN 1911 SRM - BS EN 14385
SRM - BS EN ISO 16911-1SRM - BS EN 14790
SRM - BS ISO 15713MoistureVelocity
Species
MONITORING SCHEDULE
Heavy Metals
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Equipment I.D. Equipment I.D. Equipment I.D.
LEK 9.28 / 9.35 - LEK 15.21
LEK 9.25 / 9.38 - LEK 20.31
LEK 9.25 9.38 - -
LEK 9.25 / 9.38 - -
LEK 17.21 - -
LEK 13.16 - LEK 1.14
LEK 6.18 - LEK LNO 03-CD
- - -
- - -
- - -
LEK 6.18 - -
- - -
LEK 23.18 - -
- - -
- - -
LEK 15.1D - -
- - -
- - -
LEK 24.7 - -
NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.
Cylinder I.D Number
Supplier ppm %Analytical
Tolerance +/- %
- - - - -
Level Expiry TE1 TE2 TE3 TE4 H&S
Andrew O'Neill MM 08 985MCERTS Level
2Mar-20 Sep-20 Mar-22 Mar-20 Sep-20 Oct-23
Callum Montgomery
MM 16 1399MCERTS Level
1Nov-22 Mar-24 - - - Nov-22
Site Balance
5m Heated Line (1)
Small DGM
Heated Line Controller (1)
Site temperature Logger
Inclinometer (Swirl Device)
STACK EMISSIONS MONITORING TEAM
Chiller (JCT/MAK 10)
1m Heated Line (2)
Mass Flow Controller
Thermo FID
Digital Temperature Meter
Servomex
Probe Thermocouple
MFC Display module
Box Thermocouples Tape Measure
Extractive Sampling
Equipment
Horiba PG-250 Analyser
Equipment
Control Box DGM Laboratory Balance
Instrumental Analyser/s
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
CALIBRATEABLE EQUIPMENT CHECKLISTMiscellaneous
Personnel
CALIBRATION GASES
FTIR Heater Box for Heated Line
1m Heated Line (3)
Callipers
20m Heated Line (2)
Anemometer
Dioxins Cond. Thermocouple 10m Heated Line (1)
MONITORING TEAM
Heated Line Controller (2)
Meter In Thermocouple Stopwatch
MCERTS Number
TE / H&S Qualifications and Expiry DateMCERTS
Probe
Probe Thermocouple
Stackmaster
Meter Out Thermocouple
Control Box Timer
Stack Thermocouple
1m Heated Line (1)
L-Pitot
Oven Box
Probe JCT Heated Head Filter
Digital Micromanometer
Bernath 3006 FID Protractor
FT-IR Oven Box
Signal 3030 FID
-
S-Pitot
FT-IR Gasmet
Barometer
Equipment
Ecophysics NOx Analyser
Heater Controller
Last Impinger Arm
Gas (traceable to ISO 17025)
10m Heated Line (2)
15m Heated Line (1)
20m Heated Line (1)
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.0020 - 1.15
- - -Reference conditions are 273K, 101.3kPa without correction for water vapour
LOD Concentration Emission Uncertainty UKASmg/m³ mg/m³ Rate g/hr % Accredited0.00037 0.00850 0.071 13% P
0.00044 0.00226 0.019 38% P
0.00121 0.12686 1.061 18% P
0.00201 0.13762 1.151 6.9% -
Reference conditions are 273K, 101.3kPa without correction for water vapour
0.1376
Field Blank
Concentration
HEAVY METALS SOLID & VAPOUR PHASES COMBINED
12:52 - 13:52 24 September 2019
Metals
INDIVIDUAL METALS SUMMARY - SOLID & VAPOUR PHASES COMBINED
Sampling Times Test
Nickel
TOTAL HEAVY METALS COMBINED
Run 1
Sum of Heavy Metals
Zinc
mg/m³
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
0.0033-
Chromium
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00031 6.00 0.00627 0.00005 2.13090 0.002230.00042 2.00 0.00209 0.00002 0.16400 0.000170.00052 120.00 0.12548 0.00069 1.31200 0.00137
0.00125 128.00 0.13385 0.00075 3.60690 0.00377
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
Laboratory Result
0.95630.9563
Sum of Heavy Metals
Metals
HEAVY METALS - RUN 1 SUMMARY
PARTICULATE PHASE
Nickel
Laboratory Result
Zinc
Chromium
VAPOUR PHASE
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00031 0.60 0.00063 0.00005 0.11 0.000120.00042 1.00 0.00105 0.00002 0.02 0.000020.00052 0.50 0.00052 0.00069 0.92 0.00096
0.00125 2.10 0.00220 0.00075 1.05 0.00110
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
HEAVY METALS - BLANK SUMMARY
Laboratory Result
Sum of Heavy Metals
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Nickel
Laboratory Result
0.9563
Zinc
0.9563
Chromium
VAPOUR PHASEMetals PARTICULATE PHASE
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ISOKINETIC SAMPLING EQUATIONS RUN 1 Heavy Metals
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb kPa 100.50 CO2 % 0.03Stack static pressure, Pstatic Pa -21.00 O2 % 20.90Ps = Pb + (Pstatic) kPa 100.48 Total % 20.93
N2 (100 -Total) % 79.07Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.84
Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms
g H
₂
0 by Non Iso Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 28.80Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs
Volume of gas metered dry, Vmstd Velocity pressure coefficient, Cp 0.888Mean of velocity heads, DPavg Pa 44.10
Volume of gas sample through gas meter, Vm m3 1.09 Mean stack gas temperature, Ts K 299.00
Gas meter correction factor, Yd 0.97 Gas density (wet, ambient), pMean dry gas meter temperature, Tm K 302.08 p=(Ms*Ps)/(8.314*Ts) kg/m3 1.164Mean pressure drop across orifice, DH mmH2O 36.67 Stack Velocity, Vs
m/s 7.73Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 0.95 Actual flow of stack gas, Qa
Area of stack, As m2 0.33Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 153.9
Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 0.9563 Conversion factor (K/mm.Hg)
Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 138.8 (Ts)
No @O2ref No O2 Ref (Ts)
% oxygen measured in gas stream, act%O2 20.90 Qstw = (Qa)Ps(0.3592) Wet 139% oxygen reference condition 21 (Ts)
O2 Ref = 21.0 - act%O2 No O2 Ref Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 7.0
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Nozzle area, An mm2 38.5Moisture content, Bwo Total sampling time, q min 60.0
%I = (4.6398E6)(Ts)(Vmstd) % 98.6Bwo = Vwstd 0.0038 (Ps)(Vs)(An)(q)(1-Bwo)
% 0.38Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes
O2 Reference Factor
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Vmstd + Vwstd
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Tm + 273
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Moisture trap weight increase,Vlc
𝑉𝑠=𝐶𝑝√(∆𝐷𝑃𝑎𝑣𝑔/𝑝)
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litre/min litre/min litre/min mm Hg litre/min litre/min17.7 0.04 0.04 -228.6 0.35 Yes
Isokinetic Criterion Compliance
mm °CQuartz Fibre 47 180 Yes
Parameter Total 3rd Absorber Absorption Required Pass / Failug ug Efficiency (%) %
Chromium Run 1 8.13090 0.71 91 90 N/A - No ELVNickel Run 1 2.16400 0.06 97 90 N/A - No ELVZinc Run 1 121.31200 ND 100 90 N/A - No ELV
Temperature during storage /
transit <25°C
Isokinetic Variation
HEAVY METALS ABSORBTION EFFICIENCY
Maximum Filtration
Temperature
Absorption Solutions - MetalsMetals
Leak Tests Acceptable
Filter Material
Leak Test Results
HEAVY METALS QA CHECKLIST
Post-sampling Leak Rate
Acceptable Isokineticity
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Run 1 Yes
Run 1
%
Filtration / Temp
Maximum Vacuum
Mean Sampling Rate
Acceptable Leak Rate
Pre-sampling Leak Rate
Run 1 3.3% Nitric Acid, 1.5% Hydrogen Peroxide
Filter Size
Type of Absorbers - Metals
Run 1
Glass
98.6
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.002 10 0.21
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.5 16.1 0.01 0.01 0.32 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A Glass
Parameter Total IMP C Absorptionug ug Efficiency %
11.97 2.02 83
Temperature during storage / transit <25°C
Run 1
16:29 - 16:5924 September 2019
Mean Sampling Rate
mg/m³Concentration
N/A- < 1mg/m³
0.025
0.005
HYDROGEN CHLORIDE SUMMARY
Max. Filtration Temp.
Leak Tests Acceptable?
Sampling Times
Acceptable ?Efficiency %
HPLC Water
-
Acceptable leak rate
Run 1
Type of Absorbers
Acceptable Absorption
95
Absorption Solutions
Post sampling leak rate
HYDROGEN CHLORIDE QUALITY ASSURANCE CHECKLIST
Total Sample Volume @ ref
Conditions
Pre sampling leak rate
Test
Absorption Efficiency
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
HYDROGEN CHLORIDE ABSORPTION EFFICIENCY
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.005 2 0.87
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.4 14.4 0.01 0.01 0.29 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A PE
Parameter Total IMP C Absorptionug ug Efficiency %
44.6 5.8 87
Temperature during storage / transit <25°C
0.103
Post sampling leak rate
Run 1
Sampling Times
0.1N Sodium Hydroxide
Type of Absorbers
Concentrationmg/m³
-
Acceptable Absorption Absorption Efficiency
N/A- < 1mg/m³
Test
15:54 - 16:2424 September 2019
Acceptable leak rate
Total Sample Volume @ ref
Conditions
HYDROGEN FLUORIDE SUMMARY
Pre sampling leak rate
Absorption Solutions
HYDROGEN FLUORIDE ABSORPTION EFFICIENCY
Efficiency %
Run 1
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Leak Tests Acceptable?
Max. Filtration Temp.
95
0.010
Mean Sampling Rate
HYDROGEN FLUORIDE QUALITY ASSURANCE CHECKLIST
Acceptable ?
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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty
kg kg kg % % %
Run 1 3.2101 3.2116 0.0015 0.4 0.03 15.6
Test NumberSampling Duration
Total Volume Sampled
Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate
mins l l/min l/min l/min l/min
Run 1 30 484 16.1 0.01 0.01 0.32 Yes
Stack Diameter / Depth, D 0.65 m
Stack Width, W - m
Stack Area, A 0.33 m2
Average stack gas temperature 26 oC
Stack static pressure -0.021 kPa
Barometric Pressure 100.5 kPa
Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3
M p % Vol r pi % Vol r pi
CO2 44 1.963059 0.028571 0.000286 0.000561 0.028462 0.000285 0.000559
O2 32 1.427679 20.900000 0.209000 0.298385 20.819667 0.208197 0.297238
N2 28 1.249219 79.071429 0.790714 0.987775 78.767501 0.787675 0.983979
H2O 18 0.803070 - - - 0.384370 0.003844 0.003087
Where: p = M / 22.41 pi = r x p
Determinand
Dry Density (STP), P STD
Wet Density (STP), P STW
Dry Density (Actual), P Actual
Average Wet Density (Actual), P ActualW
Where:
P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)
P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)
PRELIMINARY STACK SURVEY
Leak Tests Acceptable?
1.164
kg/m3
Units
Moisture Quality Assurance
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1.2849
kg/m31.2867
kg/m3
Stack Characteristics
MOISTURE CALCULATIONS
Stack Gas Composition & Molecular Weights
Moisture Determination - Non Isokinetic
15:54 - 16:24 24 September 2019
Result
kg/m3
Calculation of Stack Gas Densities
Sampling Time and Date
1.1653
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TRAVERSE 1
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.02 39.2 4.0 26 7.3 2.4 - <152 0.05 44.1 4.5 26 7.7 2.6 - <153 0.10 41.7 4.3 26 7.5 2.5 - <154 0.15 44.1 4.5 26 7.7 2.6 - <155 0.22 46.6 4.8 26 7.9 2.6 - <156 0.43 46.6 4.8 26 7.9 2.6 - <157 0.50 49.0 5.0 26 8.1 2.7 - <158 0.55 51.5 5.3 26 8.3 2.8 - <159 0.60 46.6 4.8 26 7.9 2.6 - <15
10 0.63 44.1 4.5 26 7.7 2.6 - <15Mean - 45.3 4.6 26 7.8 2.6 - -
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -
Mean - - - - - - - -
Start Value End Value Difference Start Value End Value DifferencemmH2O mmH2O % mmH2O mmH2O %
Run 1 99 98 1.0 Pass 122 120 1.6 Pass
RunStagnation
(Pa)Reference
(Pa)Difference
(Pa)
Outcome(Permitted +/- 10 Pa)
Run 1 -20 -21 1.0 Pass
Sampling Line B
12:2024 September 2019
To complete a compliant pitot leak check a pressure of over 80 mmH
₂
O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.
S-Type Pitot Stagnation Check
OutcomePre Traverse Leak Rate
Run
PITOT LEAK CHECKPost Traverse Leak Rate
Sampling Line A
Outcome
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Time of Survey
Volumetric Flow Rate
(actual)
Date of Survey
Velocity Measurement Device: S-Type Pitot
Volumetric Flow Rate
(actual)
PRELIMINARY STACK SURVEY
PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST
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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant
Lowest Differential Pressure Pa >= 5 Pa Yes
Lowest Gas Velocity m/s - -
Highest Gas Velocity m/s - -
Ratio of Gas Velocities - < 3 : 1 Yes
Maximum angle of flow with regard to duct axis o < 15o Yes
No local negative flow - - Yes
Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)
Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998
Average Stack Gas Velocity, Va 7.8 m/s
Duct gas flow conditions Actual Reference UnitsTemperature 26 0 oCTotal Pressure 100.479 101.3 kPaOxygen 20.9 21 %Moisture 0.38 0.38 %Pitot tube calibration coefficient, Kpt 0.89
Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2
Gas Volumetric Flowrate (Actual), QActual m3/hr
Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr
Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr
Gas Volumetric Flowrate (REF), QRef m3/hr
Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((21 - O2a) / (21 - O2s))
Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol
7.83
8441
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Plane Validation Criteria
<15
Calculation of Stack Gas Velocity, V
Calculation of Stack Gas Volumetric Flowrate, Q
93568473
8473
7.3
1.1
PRELIMINARY STACK SURVEY (CONTINUED)
Yes
8.3
39
Result
0.33
Result
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Value UnitsStack Depth 0.65 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.33 m2 - - - -
Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o
1 7.7 0.05 < 152 25.0 0.16 < 153 75.0 0.49 < 154 92.3 0.60 < 15
- - - -
- - - -
- - - -
- - - -- - - -- - - -- - - -- - - -
- - - -
- - - -- - - -- - - -
Isokinetic sampling point - - - -Isokinetic sampling points not used - - - -Non Isokinetic/Gases sampling point - - - -
- - - -
SAMPLING LOCATION
Non-Isokinetic/Gases Sampling
Isokinetic Sampling
STACK DIAGRAMAPPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Line A
1
2
3
4
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Concentration in impinger
Leak
m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%Run 1 0.001 2.0 0.50 1.0 0.10 0.0003 -as a % 0.10 0.73 0.50 1.0 - 3.00 0.23compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ - mg mg/m³ mgRun 1 0.9487 - 131.6069 0.0002 - -MU as mg/m3
0.0018 - 0.0020 0.0002 0.00391 0.0048MU as % 1.3399 - 1.4601 0.1308 2.84167 -
0.01 mg/m³ 6.93 % Result N/A % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
LeakO2 Correction
MEASUREMENT UNCERTAINTY BUDGET - HEAVY METALS
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Volume (STP) Mass of Heavy Metals
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Combined uncertainty
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.003 -as a % 0.066 0.658 0.498 1.000 - 0.035 0.062compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.4320 0.0210 - 0.00001 - -MU as mg/m3
0.0003 0.0035 - 0.00001 0.0012 0.0037MU as % 1.2984 14.2896 - 0.0359 4.8 -
0.01 mg/m³ 30.26 % Result 0.07 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN CHLORIDE
LeakO2 Correction
Sampled Gas Temp
Sampled Volume
Run
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
LeakLimit of Detection
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Oxygen Content
Sampled Gas Humidity
Sampled Gas Pressure
Mass of Hydrogen Chloride
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.006 -as a % 0.066 0.658 0.498 1.000 - 0.411 0.069compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.3869 0.0775 - 0.00004 - -MU as mg/m3
0.0013 0.0082 - 0.00004 0.0063 0.0104MU as % 1.2984 8.0065 - 0.0400 6.1 -
0.02 mg/m³ 20.30 % Result 1.04 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN FLUORIDE
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass of Hydrogen Fluoride
Sampled Gas Pressure
Sampled Gas Temp
Sampled Volume
Volume (STP) Combined uncertainty
LeakLimit of Detection
Oxygen Content
Sampled Gas Humidity
LeakO2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Run
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %
MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.0003 2.0 0.50 1.0 N/A -as a % 0.07 0.67 0.50 1.0 N/A 0.06compliant? Yes Yes Yes Yes N/A Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 0.44 1500 1.0 1.11 57.7 -MU as % v/v 0.01 0.03 - 0.0001 0.02 0.03MU as % 1.30 6.67 - 0.04 3.85 -
0.06 % v/v 15.62 %Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - MOISTURE
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Leak Combined uncertainty
O2 Correction
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass Gained
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7.8 m/s9356 m³/hr
Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination
Uncertainty of pitot tube coefficient - 0.010
Uncertainty of mean local dynamic pressures - 0.54
Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes
Range of measurment device pa 1000
Resolution pa 1.00
Calibration uncertainty pa 8.49<1% of Value or 20
Pa whichever is greater
Yes
Drift % range 0.10
Linearity % range 0.06 <2% of value Yes
Uncertainty of gas density determination
Uncertainty of molar mass determination kg/mol 0.00003Uncertainty of temperature measurement K 1.53 <1% of value Yes
Uncertainty of absolute pressure in the duct pa 513
Uncertainty associated with the estimate of density - 0.007
Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001
m/s0.090.18
%1.22.3
m³/hr243476
%2.65.1
Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Note - The expanded uncertainty uses a coverage factor of k = 2.
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE
Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval
Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions
Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval
Note - The expanded uncertainty uses a coverage factor of k = 2.
Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval
Measurement Uncertainty Volumetric Flow Rate
Expanded uncertainty at a 95% Confidence Interval
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https://www.surveymonkey.co.uk/r/CAE_customer_feedback_weblink
END OF REPORT
Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on
the following
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SOCOTEC Job Number:Report Date:Version: 1Report By: Matthew GreenMCERTS Number: MM 04 499MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Signature:
Sampling Date(s):24th - 25th September 2019
14th November 2019LEK 11848
BT3 9DZ
Queens Island
Bombardier Aerospace
Belfast
Release Point: M30
Your contact at SOCOTEC LTD
Operator & Address:
Airport Road
2-4 Langlands PlaceKelvin South Business Park
East KilbrideG75 0YF
Tel: 01355 246 730Fax: 01355 249 669
Permit Reference:PPC (NI) Permit: P0135/06A
David HayBusiness Manager - North
Tel: 01355 246 730Email: [email protected]
STACK EMISSIONS MONITORING REPORT
SOCOTEC UK Reporting Template v5 Page 1 of 30
SOCOTEC UK LTD
www.socotec.co.uk
EXECUTIVE SUMMARY
Stack Emissions Monitoring Objectives
- Plant
- Operator
- Stack Emissions Monitoring Test House
Emissions Summary
Monitoring Times
Process Details
Monitoring Methods
Analytical Methods
- Sampling Methods with Subsequent Analysis
- On-Site Testing
Sampling Location
- Sampling Plane Validation Criteria
- Duct Characteristics
- Sampling Lines & Sample Points
- Sampling Platform
- Sampling Location / Platform Improvement Recommendations
Sampling and Analytical Method Deviations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
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Plant
M30
Operator
Bombardier Aerospace
Airport Road
Queens Island
Belfast
BT3 9DZ
PPC (NI) Permit: P0135/06A
Stack Emissions Monitoring Test House
SOCOTEC - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015
Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC LTD.
MONITORING OBJECTIVES
SOCOTEC LTD were commissioned by Bombardier Aerospace to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.
Bombardier Aerospace operates a extraction from baths on manual line process at Belfast which is subject to PPC (NI) Permit P0135/06A, under thePollution Prevention and Control (Industrial Emissions) Regulations (Northern Ireland) 2013.
EXECUTIVE SUMMARY
The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's PPC (NI) Permit, P0135/06A.
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Parameter Units Result Calculated Uncertainty
+/-Heavy Metals mg/m³ 0.020 0.004 -Heavy Metals Emission Rate g/hr 0.101 0.019 -Hydrogen Chloride mg/m³ 0.06 0.008 10Hydrogen Chloride Emission Rate g/hr 0.33 0.046 -Hydrogen Fluoride mg/m³ 0.03 0.015 2Hydrogen Fluoride Emission Rate g/hr 0.17 0.088 -Moisture % 3.74 0.11 - P
Stack Gas Temperature oC 28 - -Stack Gas Velocity m/s 9.1 0.21 -Gas Volumetric Flow Rate (Actual) m³/hr 6449 328 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 5807 295 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 5589 284 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 5807 295 -
Emission Limit Value (ELV)
P
EMISSIONS SUMMARY
Reference conditions are 273K, 101.3kPa without correction for water vapour
EXECUTIVE SUMMARY
ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.
P
P
MCERTS accredited
result
P
Page 4 of 30
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Heavy Metals Run 1Hydrogen Chloride Run 1Hydrogen Fluoride Run 1 30 minutes
MONITORING TIMES
60 minutes
Sampling TimesSampling Date(s)Parameter
EXECUTIVE SUMMARY
Sampling Duration
24 September 201912:55 - 13:2524 September 201913:35 - 14:05 30 minutes
12:30 -24 September 2019
24 September 2019 14:27 - 15:27
Preliminary Stack Traverse
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Description of process Extraction From Baths on Manual Line
Continuous or batch Continuous
Product Details Aerospace Components
Part of batch to be monitored (if applicable) N/A
Normal load, throughput or continuous rating Normal Operation
Fuel used during monitoring N/A
Abatement None
Plume Appearance None
Process Details
EXECUTIVE SUMMARY
PROCESS DETAILS
Parameter
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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MUProcedure Method (LOD) +/- % Result +/- % ELV
Heavy Metals AE 108 1015 Yes 0.002 mg/m³ 19.2% N/A - No ELV
Hydrogen Chloride
AE 111 1015 Yes 0.002 mg/m³ 14.1% 0.08%
Hydrogen Fluoride
AE 113 1015 Yes 0.004 mg/m³ 51.5% 0.76%
Moisture AE 105 1015 Yes 0.03% 3.00% N/A - No ELV
Velocity AE 154 1015 Yes 5 Pa 2.3% N/A - No ELV
Volumetric Flow Rate
AE 154 1015 Yes - 5.1% N/A - No ELV
MONITORING METHODS
SRM - BS EN ISO 16911-1
SRM - BS EN ISO 16911-1
Method
SRM - BS ISO 15713
Standard Reference Method / Alternative Method
BS EN 14790 has been validated over a range of 4 - 40%. It is however the prefered method of the Environment Agency for concentrations below 4%
SRM - BS EN 14790
The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environment Agency Technical Guidance Note (Monitoring) M2.
SRM - BS EN 1911
SRM - BS EN 14385
Monitoring Methods
EXECUTIVE SUMMARY
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Heavy Metals ASC/SOP/117 1252 Yes SOCOTEC (Bretby)
ASC41282 8 Weeks
Hydrogen Chloride
ASC/SOP/110 1252 Yes SOCOTEC (Bretby)
ASC41283 8 Weeks
Hydrogen Fluoride
ASC/SOP/110 1252 Yes SOCOTEC (Bretby)
ASC41283 8 Weeks
Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period
Analysis Location
Moisture AE 105 1015 YesSOCOTEC (East
Kilbride)- -
ON-SITE TESTING
Analysis Report number
UKAS Accredited Lab Analysis
The following tables list the analytical methods employed together with the custody details. Unless otherwise stated the samples are archived at the analysis lab location.
Analysis LabArchivePeriod
UKAS Lab Number
Analytical Procedure
Analytical TechniqueSpecies
SAMPLING METHODS WITH SUBSEQUENT ANALYSIS
Gravimetric
Ion Chromatography
Ion Chromatography
Analytical Methods
Inductively coupled Plasma - Mass Spectrometry
Analytical Technique
EXECUTIVE SUMMARY
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Sampling Plane Validation Criteria Value Units Requirement Compliant Method
Lowest Differential Pressure 54 Pa >= 5 Pa Yes BS EN 15259
Lowest Gas Velocity 8.6 m/s - - -
Highest Gas Velocity 9.6 m/s - - -
Ratio of Gas Velocities 1.1 : 1 < 3 : 1 Yes BS EN 15259
Mean Velocity 9.1 m/s - - -
Maximum angle of flow with regard to duct axis <15 o < 15o Yes BS EN 15259
No local negative flow Yes - - Yes BS EN 15259
Value Units Isokinetic
Shape Circular -
Depth 0.50 m Sample port size 4" BSP -
Width - m Number of lines used 1 -
Area 0.20 m2 Number of points / line 4 -
Port Depth 90 mm Duct orientation Vertical -Filtration In Stack -
General Platform Information
Permanent / Temporary Platform / Ground level / Floor Level / Roof
Inside / Outside
M1 Platform requirements
Is there a sufficient working area so work can be performed in a compliant manner
Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)
Platform has vertical base boards (approximately 0.25 m high)
Platform has removable chains / self closing gates at the top of ladders
Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m
Sampling Platform Improvement Recommendations (if applicable)
No
Inside
Yes
No
No
SAMPLING LINES & POINTS
No
DUCT CHARACTERISTICS
EXECUTIVE SUMMARY
Permanent
Where possible a second sample port should be installed at 90o to the current sample port and the platform extended to meet all the requirements asspecified in EA Guidance Note M1.
SAMPLING LOCATION
Yes
SAMPLING PLATFORM
Non-Iso & Gases
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Sample Points
Only one sample line is available for the testing to be carried out, therefore the number of points sampled on this available line will bedoubled in accordance with the standard.
Sampling & Analytical Method Deviations
EXECUTIVE SUMMARY
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APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
APPENDICES
CONTENTS
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SOCOTEC UKAS Lab MCERTSTechnical Number AccreditedProcedure Method
AE 108 1015 Yes 1AE 111 1015 Yes 1AE 113 1015 Yes 1AE 105 1015 Yes 1AE 154 1015 Yes 1
Method
Hydrogen ChlorideHydrogen Fluoride
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
Number of Samples
Standard Reference Method / Alternative Method
SRM - BS EN 1911 SRM - BS EN 14385
SRM - BS EN ISO 16911-1SRM - BS EN 14790
SRM - BS ISO 15713MoistureVelocity
Species
MONITORING SCHEDULE
Heavy Metals
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Equipment I.D. Equipment I.D. Equipment I.D.
LEK 9.28 / 9.35 - LEK 15.21
LEK 9.25 / 9.38 - LEK 20.31
LEK 9.25 9.38 - -
LEK 9.25 / 9.38 - -
LEK 17.21 - -
LEK 13.16 - LEK 1.14
LEK 6.18 - LEK LNO 03-CD
- - -
- - -
- - -
LEK 6.18 - -
- - -
LEK 23.18 - -
- - -
- - -
LEK 15.1D - -
- - -
- - -
LEK 24.7 - -
NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.
Cylinder I.D Number
Supplier ppm %Analytical
Tolerance +/- %
- - - - -
Level Expiry TE1 TE2 TE3 TE4 H&S
Andrew O'Neill MM 08 985MCERTS Level
2Mar-20 Sep-20 Mar-22 Mar-20 Sep-20 Oct-23
Callum Montgomery
MM 16 1399MCERTS Level
1Nov-22 Mar-24 - - - Nov-22
Site Balance
5m Heated Line (1)
Small DGM
Heated Line Controller (1)
Site temperature Logger
Inclinometer (Swirl Device)
STACK EMISSIONS MONITORING TEAM
Chiller (JCT/MAK 10)
1m Heated Line (2)
Mass Flow Controller
Thermo FID
Digital Temperature Meter
Servomex
Probe Thermocouple
MFC Display module
Box Thermocouples Tape Measure
Extractive Sampling
Equipment
Horiba PG-250 Analyser
Equipment
Control Box DGM Laboratory Balance
Instrumental Analyser/s
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
CALIBRATEABLE EQUIPMENT CHECKLISTMiscellaneous
Personnel
CALIBRATION GASES
FTIR Heater Box for Heated Line
1m Heated Line (3)
Callipers
20m Heated Line (2)
Anemometer
Dioxins Cond. Thermocouple 10m Heated Line (1)
MONITORING TEAM
Heated Line Controller (2)
Meter In Thermocouple Stopwatch
MCERTS Number
TE / H&S Qualifications and Expiry DateMCERTS
Probe
Probe Thermocouple
Stackmaster
Meter Out Thermocouple
Control Box Timer
Stack Thermocouple
1m Heated Line (1)
L-Pitot
Oven Box
Probe JCT Heated Head Filter
Digital Micromanometer
Bernath 3006 FID Protractor
FT-IR Oven Box
Signal 3030 FID
-
S-Pitot
FT-IR Gasmet
Barometer
Equipment
Ecophysics NOx Analyser
Heater Controller
Last Impinger Arm
Gas (traceable to ISO 17025)
10m Heated Line (2)
15m Heated Line (1)
20m Heated Line (1)
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.0018 - 0.10
- - -Reference conditions are 273K, 101.3kPa without correction for water vapour
LOD Concentration Emission Uncertainty UKASmg/m³ mg/m³ Rate g/hr % Accredited0.00034 0.00664 0.034 14% P
0.00041 0.00205 0.011 40% P
0.00102 0.01087 0.056 21% P
0.00177 0.01956 0.101 19.2% -
Reference conditions are 273K, 101.3kPa without correction for water vapour
0.0196
Field Blank
Concentration
HEAVY METALS SOLID & VAPOUR PHASES COMBINED
14:27 - 15:27 24 September 2019
Metals
INDIVIDUAL METALS SUMMARY - SOLID & VAPOUR PHASES COMBINED
Sampling Times Test
Nickel
TOTAL HEAVY METALS COMBINED
Run 1
Sum of Heavy Metals
Zinc
mg/m³
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
0.0031-
Chromium
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00030 5.50 0.00545 0.00004 1.19870 0.001190.00040 2.00 0.00198 0.00001 0.07028 0.000070.00050 9.90 0.00981 0.00053 1.06360 0.00105
0.00119 17.40 0.01725 0.00058 2.33258 0.00231
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
Laboratory Result
1.00871.0087
Sum of Heavy Metals
Metals
HEAVY METALS - RUN 1 SUMMARY
PARTICULATE PHASE
Nickel
Laboratory Result
Zinc
Chromium
VAPOUR PHASE
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00030 0.60 0.00059 0.00004 0.11 0.000110.00040 1.00 0.00099 0.00001 0.02 0.000020.00050 0.50 0.00050 0.00053 0.92 0.00091
0.00119 2.10 0.00208 0.00058 1.05 0.00104
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
HEAVY METALS - BLANK SUMMARY
Laboratory Result
Sum of Heavy Metals
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Nickel
Laboratory Result
1.0087
Zinc
1.0087
Chromium
VAPOUR PHASEMetals PARTICULATE PHASE
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ISOKINETIC SAMPLING EQUATIONS RUN 1 Heavy Metals
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb kPa 100.50 CO2 % 0.03Stack static pressure, Pstatic Pa -21.00 O2 % 20.90Ps = Pb + (Pstatic) kPa 100.48 Total % 20.93
N2 (100 -Total) % 79.07Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.84
Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms
g H
₂
0 by Non Iso Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 28.43Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs
Volume of gas metered dry, Vmstd Velocity pressure coefficient, Cp 0.888Mean of velocity heads, DPavg Pa 47.37
Volume of gas sample through gas meter, Vm m3 1.12 Mean stack gas temperature, Ts K 301.00
Gas meter correction factor, Yd 0.97 Gas density (wet, ambient), pMean dry gas meter temperature, Tm K 303.58 p=(Ms*Ps)/(8.314*Ts) kg/m3 1.142Mean pressure drop across orifice, DH mmH2O 39.31 Stack Velocity, Vs
m/s 8.09Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 0.97 Actual flow of stack gas, Qa
Area of stack, As m2 0.20Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 95.3
Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 1.0087 Conversion factor (K/mm.Hg)
Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 82.5 (Ts)
No @O2ref No O2 Ref (Ts)
% oxygen measured in gas stream, act%O2 20.90 Qstw = (Qa)Ps(0.3592) Wet 86% oxygen reference condition 21 (Ts)
O2 Ref = 21.0 - act%O2 No O2 Ref Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 7.0
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Nozzle area, An mm2 38.5Moisture content, Bwo Total sampling time, q min 60.0
%I = (4.6398E6)(Ts)(Vmstd) % 100.1Bwo = Vwstd 0.0374 (Ps)(Vs)(An)(q)(1-Bwo)
% 3.74Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes
O2 Reference Factor
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Vmstd + Vwstd
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Tm + 273
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Moisture trap weight increase,Vlc
𝑉𝑠=𝐶𝑝√(∆𝐷𝑃𝑎𝑣𝑔/𝑝)
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litre/min litre/min litre/min mm Hg litre/min litre/min18.1 0.03 0.03 -254 0.36 Yes
Isokinetic Criterion Compliance
mm °CQuartz Fibre 47 180 Yes
Parameter Total 3rd Absorber Absorption Required Pass / Failug ug Efficiency (%) %
Chromium Run 1 6.69870 0.19 97 90 N/A - No ELVNickel Run 1 2.07028 0.02 99 90 N/A - No ELVZinc Run 1 10.96360 ND 100 90 N/A - No ELV
Temperature during storage /
transit <25°C
Isokinetic Variation
HEAVY METALS ABSORBTION EFFICIENCY
Maximum Filtration
Temperature
Absorption Solutions - MetalsMetals
Leak Tests Acceptable
Filter Material
Leak Test Results
HEAVY METALS QA CHECKLIST
Post-sampling Leak Rate
Acceptable Isokineticity
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Run 1 Yes
Run 1
%
Filtration / Temp
Maximum Vacuum
Mean Sampling Rate
Acceptable Leak Rate
Pre-sampling Leak Rate
Run 1 3.3% Nitric Acid, 1.5% Hydrogen Peroxide
Filter Size
Type of Absorbers - Metals
Run 1
Glass
100.1
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.002 10 0.33
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.5 16.3 0.01 0.01 0.33 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A Glass
Parameter Total IMP C Absorptionug ug Efficiency %
28.79 9.54 67
Temperature during storage / transit <25°C
Run 1
13:35 - 14:0524 September 2019
Mean Sampling Rate
mg/m³Concentration
N/A- < 1mg/m³
0.057
0.005
HYDROGEN CHLORIDE SUMMARY
Max. Filtration Temp.
Leak Tests Acceptable?
Sampling Times
Acceptable ?Efficiency %
HPLC Water
-
Acceptable leak rate
Run 1
Type of Absorbers
Acceptable Absorption
95
Absorption Solutions
Post sampling leak rate
HYDROGEN CHLORIDE QUALITY ASSURANCE CHECKLIST
Total Sample Volume @ ref
Conditions
Pre sampling leak rate
Test
Absorption Efficiency
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
HYDROGEN CHLORIDE ABSORPTION EFFICIENCY
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.004 2 0.17
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.5 14.8 0.02 0.02 0.30 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A PE
Parameter Total IMP C Absorptionug ug Efficiency %
13.51 ND 100
Temperature during storage / transit <25°C
0.029
Post sampling leak rate
Run 1
Sampling Times
0.1N Sodium Hydroxide
Type of Absorbers
Concentrationmg/m³
-
Acceptable Absorption Absorption Efficiency
Yes
Test
12:55 - 13:2524 September 2019
ND - None Detected
Acceptable leak rate
Total Sample Volume @ ref
Conditions
HYDROGEN FLUORIDE SUMMARY
Pre sampling leak rate
Absorption Solutions
HYDROGEN FLUORIDE ABSORPTION EFFICIENCY
Efficiency %
Run 1
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Leak Tests Acceptable?
Max. Filtration Temp.
95
0.009
Mean Sampling Rate
HYDROGEN FLUORIDE QUALITY ASSURANCE CHECKLIST
Acceptable ?
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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty
kg kg kg % % %
Run 1 3.1998 3.2153 0.0155 3.7 0.03 3.0
Test NumberSampling Duration
Total Volume Sampled
Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate
mins l l/min l/min l/min l/min
Run 1 30 497 16.6 0.02 0.02 0.33 Yes
Stack Diameter / Depth, D 0.50 m
Stack Width, W - m
Stack Area, A 0.20 m2
Average stack gas temperature 28 oC
Stack static pressure 0.062 kPa
Barometric Pressure 100.5 kPa
Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3
M p % Vol r pi % Vol r pi
CO2 44 1.963059 0.028571 0.000286 0.000561 0.027502 0.000275 0.000540
O2 32 1.427679 20.900000 0.209000 0.298385 20.117700 0.201177 0.287216
N2 28 1.249219 79.071429 0.790714 0.987775 76.111737 0.761117 0.950802
H2O 18 0.803070 - - - 3.743060 0.037431 0.030059
Where: p = M / 22.41 pi = r x p
Determinand
Dry Density (STP), P STD
Wet Density (STP), P STW
Dry Density (Actual), P Actual
Average Wet Density (Actual), P ActualW
Where:
P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)
P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)
PRELIMINARY STACK SURVEY
Leak Tests Acceptable?
1.142
kg/m3
Units
Moisture Quality Assurance
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1.2686
kg/m31.2867
kg/m3
Stack Characteristics
MOISTURE CALCULATIONS
Stack Gas Composition & Molecular Weights
Moisture Determination - Non Isokinetic
12:55 - 13:25 24 September 2019
Result
kg/m3
Calculation of Stack Gas Densities
Sampling Time and Date
1.1585
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TRAVERSE 1
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.01 63.7 6.5 28 9.4 1.8 - <152 0.04 62.2 6.4 28 9.3 1.8 - <153 0.07 63.7 6.5 28 9.4 1.8 - <154 0.11 66.2 6.8 28 9.6 1.9 - <155 0.17 63.7 6.5 28 9.4 1.8 - <156 0.33 58.8 6.0 28 9.0 1.8 - <157 0.39 61.3 6.3 28 9.2 1.8 - <158 0.43 53.9 5.5 28 8.6 1.7 - <159 0.46 56.4 5.8 28 8.8 1.7 - <15
10 0.49 53.9 5.5 28 8.6 1.7 - <15Mean - 60.4 6.2 28 9.1 1.8 - -
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -
Mean - - - - - - - -
Start Value End Value Difference Start Value End Value DifferencemmH2O mmH2O % mmH2O mmH2O %
Run 1 122 120 1.6 Pass 116 115 0.9 Pass
RunStagnation
(Pa)Reference
(Pa)Difference
(Pa)
Outcome(Permitted +/- 10 Pa)
Run 1 60 62 -2.0 Pass
Sampling Line B
12:3024 September 2019
To complete a compliant pitot leak check a pressure of over 80 mmH
₂
O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.
S-Type Pitot Stagnation Check
OutcomePre Traverse Leak Rate
Run
PITOT LEAK CHECKPost Traverse Leak Rate
Sampling Line A
Outcome
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Time of Survey
Volumetric Flow Rate
(actual)
Date of Survey
Velocity Measurement Device: S-Type Pitot
Volumetric Flow Rate
(actual)
PRELIMINARY STACK SURVEY
PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST
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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant
Lowest Differential Pressure Pa >= 5 Pa Yes
Lowest Gas Velocity m/s - -
Highest Gas Velocity m/s - -
Ratio of Gas Velocities - < 3 : 1 Yes
Maximum angle of flow with regard to duct axis o < 15o Yes
No local negative flow - - Yes
Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)
Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998
Average Stack Gas Velocity, Va 9.1 m/s
Duct gas flow conditions Actual Reference UnitsTemperature 28 0 oCTotal Pressure 100.562 101.3 kPaOxygen 20.9 21 %Moisture 3.74 3.74 %Pitot tube calibration coefficient, Kpt 0.89
Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2
Gas Volumetric Flowrate (Actual), QActual m3/hr
Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr
Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr
Gas Volumetric Flowrate (REF), QRef m3/hr
Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((21 - O2a) / (21 - O2s))
Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol
9.12
5589
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Plane Validation Criteria
<15
Calculation of Stack Gas Velocity, V
Calculation of Stack Gas Volumetric Flowrate, Q
64495807
5807
8.6
1.1
PRELIMINARY STACK SURVEY (CONTINUED)
Yes
9.6
54
Result
0.20
Result
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Value UnitsStack Depth 0.50 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.20 m2 - - - -
Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o
1 10.0 0.05 < 152 25.0 0.13 < 153 75.0 0.38 < 154 90.0 0.45 < 15
- - - -
- - - -
- - - -
- - - -- - - -- - - -- - - -- - - -
- - - -
- - - -- - - -- - - -
Isokinetic sampling point - - - -Isokinetic sampling points not used - - - -Non Isokinetic/Gases sampling point - - - -
- - - -
SAMPLING LOCATION
Non-Isokinetic/Gases Sampling
Isokinetic Sampling
STACK DIAGRAMAPPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Line A
1
2
3
4
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Concentration in impinger
Leak
m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%Run 1 0.001 2.0 0.50 1.0 0.10 0.0003 -as a % 0.10 0.73 0.50 1.0 - 3.00 0.17compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ - mg mg/m³ mgRun 1 1.0008 - 19.7326 0.00002 - -MU as mg/m3
0.0003 - 0.0018 0.00002 0.00056 0.0019MU as % 1.3395 - 9.0459 0.0958 2.84167 -
0.004 mg/m³ 19.15 % Result N/A % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
LeakO2 Correction
MEASUREMENT UNCERTAINTY BUDGET - HEAVY METALS
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Volume (STP) Mass of Heavy Metals
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Combined uncertainty
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.003 -as a % 0.064 0.660 0.498 1.000 - 0.028 0.061compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.4541 0.0562 - 0.00002 - -MU as mg/m3
0.0007 0.0028 - 0.00002 0.0027 0.0040MU as % 1.2994 5.0126 - 0.0354 4.8 -
0.01 mg/m³ 14.12 % Result 0.08 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN CHLORIDE
LeakO2 Correction
Sampled Gas Temp
Sampled Volume
Run
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
LeakLimit of Detection
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Oxygen Content
Sampled Gas Humidity
Sampled Gas Pressure
Mass of Hydrogen Chloride
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.006 -as a % 0.064 0.662 0.498 1.000 - 0.366 0.135compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.4134 0.0225 - 0.0000 - -MU as mg/m3
0.0004 0.0073 - 0.0000 0.0018 0.0076MU as % 1.3005 25.0025 - 0.0781 6.1 -
0.02 mg/m³ 51.54 % Result 0.76 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN FLUORIDE
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass of Hydrogen Fluoride
Sampled Gas Pressure
Sampled Gas Temp
Sampled Volume
Volume (STP) Combined uncertainty
LeakLimit of Detection
Oxygen Content
Sampled Gas Humidity
LeakO2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Run
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %
MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.0003 2.0 0.50 1.0 N/A -as a % 0.07 0.66 0.50 1.0 N/A 0.12compliant? Yes Yes Yes Yes N/A Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 0.45 15500 1.0 21.8 57.7 -MU as % v/v 0.05 0.03 - 0.003 0.01 0.06MU as % 1.30 0.65 - 0.07 0.37 -
0.12 % v/v 3.00 %Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - MOISTURE
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Leak Combined uncertainty
O2 Correction
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass Gained
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9.1 m/s6449 m³/hr
Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination
Uncertainty of pitot tube coefficient - 0.010
Uncertainty of mean local dynamic pressures - 0.63
Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes
Range of measurment device pa 1000
Resolution pa 1.00
Calibration uncertainty pa 10.66<1% of Value or 20
Pa whichever is greater
Yes
Drift % range 0.10
Linearity % range 0.06 <2% of value Yes
Uncertainty of gas density determination
Uncertainty of molar mass determination kg/mol 0.00003Uncertainty of temperature measurement K 1.54 <1% of value Yes
Uncertainty of absolute pressure in the duct pa 513
Uncertainty associated with the estimate of density - 0.007
Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001
m/s0.110.21
%1.22.3
m³/hr167328
%2.65.1
Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Note - The expanded uncertainty uses a coverage factor of k = 2.
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE
Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval
Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions
Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval
Note - The expanded uncertainty uses a coverage factor of k = 2.
Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval
Measurement Uncertainty Volumetric Flow Rate
Expanded uncertainty at a 95% Confidence Interval
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https://www.surveymonkey.co.uk/r/CAE_customer_feedback_weblink
END OF REPORT
Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on
the following
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SOCOTEC Job Number:Report Date:Version: 1Report By: Matthew GreenMCERTS Number: MM 04 499MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Signature:
Sampling Date(s):24th - 25th September 2019
14th November 2019LEK 11848
BT3 9DZ
Queens Island
Bombardier Aerospace
Belfast
Release Point: M31
Your contact at SOCOTEC LTD
Operator & Address:
Airport Road
2-4 Langlands PlaceKelvin South Business Park
East KilbrideG75 0YF
Tel: 01355 246 730Fax: 01355 249 669
Permit Reference:PPC (NI) Permit: P0135/06A
David HayBusiness Manager - North
Tel: 01355 246 730Email: [email protected]
STACK EMISSIONS MONITORING REPORT
SOCOTEC UK Reporting Template v5 Page 1 of 30
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EXECUTIVE SUMMARY
Stack Emissions Monitoring Objectives
- Plant
- Operator
- Stack Emissions Monitoring Test House
Emissions Summary
Monitoring Times
Process Details
Monitoring Methods
Analytical Methods
- Sampling Methods with Subsequent Analysis
- On-Site Testing
Sampling Location
- Sampling Plane Validation Criteria
- Duct Characteristics
- Sampling Lines & Sample Points
- Sampling Platform
- Sampling Location / Platform Improvement Recommendations
Sampling and Analytical Method Deviations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
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Bombardier AerospaceBelfastM31
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Plant
M31
Operator
Bombardier Aerospace
Airport Road
Queens Island
Belfast
BT3 9DZ
PPC (NI) Permit: P0135/06A
Stack Emissions Monitoring Test House
SOCOTEC - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015
Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC LTD.
MONITORING OBJECTIVES
SOCOTEC LTD were commissioned by Bombardier Aerospace to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.
Bombardier Aerospace operates a extraction from baths on manual line process at Belfast which is subject to PPC (NI) Permit P0135/06A, under thePollution Prevention and Control (Industrial Emissions) Regulations (Northern Ireland) 2013.
EXECUTIVE SUMMARY
The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's PPC (NI) Permit, P0135/06A.
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Parameter Units Result Calculated Uncertainty
+/-Chromium mg/m³ 0.007 0.001 -Chromium Emission Rate g/hr 0.165 0.020 -Hydrogen Chloride mg/m³ 0.11 0.013 10Hydrogen Chloride Emission Rate g/hr 2.74 0.328 -Hydrogen Fluoride mg/m³ 0.04 0.015 2Hydrogen Fluoride Emission Rate g/hr 1.09 0.390 -Moisture % 0.10 0.06 - P
Stack Gas Temperature oC 30 - -Stack Gas Velocity m/s 8.4 0.20 -Gas Volumetric Flow Rate (Actual) m³/hr 28810 1465 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 25766 1311 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 25741 1309 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 25766 1311 -
Emission Limit Value (ELV)
P
EMISSIONS SUMMARY
Reference conditions are 273K, 101.3kPa without correction for water vapour
EXECUTIVE SUMMARY
ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.
P
P
MCERTS accredited
result
P
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Heavy Metals Run 1Hydrogen Chloride Run 1Hydrogen Fluoride Run 1 30 minutes
MONITORING TIMES
60 minutes
Sampling TimesSampling Date(s)Parameter
EXECUTIVE SUMMARY
Sampling Duration
24 September 201914:29 - 14:5924 September 201915:07 - 15:37 30 minutes
12:40 -24 September 2019
24 September 2019 15:53 - 16:53
Preliminary Stack Traverse
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Description of process Extraction From Baths on Manual Line
Continuous or batch Continuous
Product Details Aerospace Components
Part of batch to be monitored (if applicable) N/A
Normal load, throughput or continuous rating Normal Operation
Fuel used during monitoring N/A
Abatement None
Plume Appearance None
Process Details
EXECUTIVE SUMMARY
PROCESS DETAILS
Parameter
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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MUProcedure Method (LOD) +/- % Result +/- % ELV
Heavy Metals AE 108 1015 Yes 0 mg/m³ 12.2% N/A - No ELV
Hydrogen Chloride
AE 111 1015 Yes 0.002 mg/m³ 12% 0.13%
Hydrogen Fluoride
AE 113 1015 Yes 0.004 mg/m³ 35.6% 0.76%
Moisture AE 105 1015 Yes 0.02% 57.79% N/A - No ELV
Velocity AE 154 1015 Yes 5 Pa 2.3% N/A - No ELV
Volumetric Flow Rate
AE 154 1015 Yes - 5.1% N/A - No ELV
MONITORING METHODS
SRM - BS EN ISO 16911-1
SRM - BS EN ISO 16911-1
Method
SRM - BS ISO 15713
Standard Reference Method / Alternative Method
BS EN 14790 has been validated over a range of 4 - 40%. It is however the prefered method of the Environment Agency for concentrations below 4%
SRM - BS EN 14790
The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environment Agency Technical Guidance Note (Monitoring) M2.
SRM - BS EN 1911
SRM - BS EN 14385
Monitoring Methods
EXECUTIVE SUMMARY
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Heavy Metals ASC/SOP/117 1252 Yes SOCOTEC (Bretby)
ASC41282 8 Weeks
Hydrogen Chloride
ASC/SOP/110 1252 YesSOCOTEC (Bretby)
ASC41283 8 Weeks
Hydrogen Fluoride
ASC/SOP/110 1252 YesSOCOTEC (Bretby)
ASC41283 8 Weeks
Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period
Analysis Location
Moisture AE 105 1015 YesSOCOTEC (East
Kilbride)- -
ON-SITE TESTING
Analysis Report number
UKAS Accredited Lab Analysis
The following tables list the analytical methods employed together with the custody details. Unless otherwise stated the samples are archived at the analysis lab location.
Analysis LabArchivePeriod
UKAS Lab Number
Analytical Procedure
Analytical TechniqueSpecies
SAMPLING METHODS WITH SUBSEQUENT ANALYSIS
Gravimetric
Ion Chromatography
Ion Chromatography
Analytical Methods
Inductively coupled Plasma - Mass Spectrometry
Analytical Technique
EXECUTIVE SUMMARY
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Sampling Plane Validation Criteria Value Units Requirement Compliant Method
Lowest Differential Pressure 39 Pa >= 5 Pa Yes BS EN 15259
Lowest Gas Velocity 7.3 m/s - - -
Highest Gas Velocity 9.2 m/s - - -
Ratio of Gas Velocities 1.3 : 1 < 3 : 1 Yes BS EN 15259
Mean Velocity 8.4 m/s - - -
Maximum angle of flow with regard to duct axis <15 o < 15o Yes BS EN 15259
No local negative flow Yes - - Yes BS EN 15259
Value Units Isokinetic
Shape Circular -
Depth 1.10 m Sample port size 4" BSP -
Width - m Number of lines used 1 -
Area 0.95 m2 Number of points / line 4 -
Port Depth 130 mm Duct orientation Vertical -Filtration In Stack -
General Platform Information
Permanent / Temporary Platform / Ground level / Floor Level / Roof
Inside / Outside
M1 Platform requirements
Is there a sufficient working area so work can be performed in a compliant manner
Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)
Platform has vertical base boards (approximately 0.25 m high)
Platform has removable chains / self closing gates at the top of ladders
Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m
Sampling Platform Improvement Recommendations (if applicable)
No
Inside
Yes
No
No
SAMPLING LINES & POINTS
No
DUCT CHARACTERISTICS
EXECUTIVE SUMMARY
Temporary
Where possible a second sample port should be installed at 90o to the current sample port and the platform extended to meet all the requirements asspecified in EA Guidance Note M1.
SAMPLING LOCATION
Yes
SAMPLING PLATFORM
Non-Iso & Gases
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Sample Points
Only one sample line is available for the testing to be carried out, therefore the number of points sampled on this available line will bedoubled in accordance with the standard.
Sampling & Analytical Method Deviations
EXECUTIVE SUMMARY
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APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
APPENDICES
CONTENTS
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SOCOTEC UKAS Lab MCERTSTechnical Number AccreditedProcedure Method
AE 108 1015 Yes 1AE 111 1015 Yes 1AE 113 1015 Yes 1AE 105 1015 Yes 1AE 154 1015 Yes 1
Method
Hydrogen ChlorideHydrogen Fluoride
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
Number of Samples
Standard Reference Method / Alternative Method
SRM - BS EN 1911 SRM - BS EN 14385
SRM - BS EN ISO 16911-1SRM - BS EN 14790
SRM - BS ISO 15713MoistureVelocity
Species
MONITORING SCHEDULE
Heavy Metals
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Equipment I.D. Equipment I.D. Equipment I.D.
LEK 9.28 / 9.35 - LEK 15.21
LEK 9.25 / 9.38 - LEK 20.31
LEK 9.25 9.38 - -
LEK 9.25 / 9.38 - -
LEK 17.21 - -
LEK 13.16 - LEK 1.14
LEK 6.18 - LEK LNO 03-CD
- - -
- - -
- - -
LEK 6.18 - -
- - -
LEK 23.18 - -
- - -
- - -
LEK 15.1D - -
- - -
- - -
LEK 24.7 - -
NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.
Cylinder I.D Number
Supplier ppm %Analytical
Tolerance +/- %
- - - - -
Level Expiry TE1 TE2 TE3 TE4 H&S
Andrew O'Neill MM 08 985MCERTS Level
2Mar-20 Sep-20 Mar-22 Mar-20 Sep-20 Oct-23
Callum Montgomery
MM 16 1399MCERTS Level
1Nov-22 Mar-24 - - - Nov-22
Site Balance
5m Heated Line (1)
Small DGM
Heated Line Controller (1)
Site temperature Logger
Inclinometer (Swirl Device)
STACK EMISSIONS MONITORING TEAM
Chiller (JCT/MAK 10)
1m Heated Line (2)
Mass Flow Controller
Thermo FID
Digital Temperature Meter
Servomex
Probe Thermocouple
MFC Display module
Box Thermocouples Tape Measure
Extractive Sampling
Equipment
Horiba PG-250 Analyser
Equipment
Control Box DGM Laboratory Balance
Instrumental Analyser/s
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
CALIBRATEABLE EQUIPMENT CHECKLISTMiscellaneous
Personnel
CALIBRATION GASES
FTIR Heater Box for Heated Line
1m Heated Line (3)
Callipers
20m Heated Line (2)
Anemometer
Dioxins Cond. Thermocouple 10m Heated Line (1)
MONITORING TEAM
Heated Line Controller (2)
Meter In Thermocouple Stopwatch
MCERTS Number
TE / H&S Qualifications and Expiry DateMCERTS
Probe
Probe Thermocouple
Stackmaster
Meter Out Thermocouple
Control Box Timer
Stack Thermocouple
1m Heated Line (1)
L-Pitot
Oven Box
Probe JCT Heated Head Filter
Digital Micromanometer
Bernath 3006 FID Protractor
FT-IR Oven Box
Signal 3030 FID
-
S-Pitot
FT-IR Gasmet
Barometer
Equipment
Ecophysics NOx Analyser
Heater Controller
Last Impinger Arm
Gas (traceable to ISO 17025)
10m Heated Line (2)
15m Heated Line (1)
20m Heated Line (1)
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.0003 - 0.17
- - -Reference conditions are 273K, 101.3kPa without correction for water vapour
LOD Concentration Emission Uncertainty UKASmg/m³ mg/m³ Rate g/hr % Accredited0.00034 0.00663 0.165 13% P
Reference conditions are 273K, 101.3kPa without correction for water vapour
0.0066
Field Blank
Concentration
HEAVY METALS SOLID & VAPOUR PHASES COMBINED
15:53 - 16:53 24 September 2019
Metals
INDIVIDUAL METALS SUMMARY - SOLID & VAPOUR PHASES COMBINED
Sampling Times TestTOTAL HEAVY METALS COMBINED
Run 1
mg/m³
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
0.0007-
Chromium
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00030 4.80 0.00475 0.00004 1.90190 0.00188
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
Laboratory Result
1.01081.0108
Metals
HEAVY METALS - RUN 1 SUMMARY
PARTICULATE PHASELaboratory
Result
Chromium
VAPOUR PHASE
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
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Stack LOD Concentration Stack LOD Concentrationmg/m³ mg/m³
ug mg/m³ ug mg/m³0.00030 0.60 0.00059 0.00004 0.11 0.00011
Volume Sampled m3
Reference conditions are 273K, 101.3kPa without correction for water vapour
HEAVY METALS - BLANK SUMMARY
Laboratory Result
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Laboratory Result
1.01081.0108Chromium
VAPOUR PHASEMetals PARTICULATE PHASE
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ISOKINETIC SAMPLING EQUATIONS RUN 1 Heavy Metals
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb kPa 100.50 CO2 % 0.03Stack static pressure, Pstatic Pa -21.00 O2 % 20.90Ps = Pb + (Pstatic) kPa 100.48 Total % 20.93
N2 (100 -Total) % 79.07Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.84
Vol. of water vapour collected, Vwstd Molecular weight of wet gas, Ms
g H
₂
0 by Non Iso Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 28.83Vwstd = (0.001246)(Vlc) m3 - Velocity of stack gas, Vs
Volume of gas metered dry, Vmstd Velocity pressure coefficient, Cp 0.888Mean of velocity heads, DPavg Pa 48.39
Volume of gas sample through gas meter, Vm m3 1.16 Mean stack gas temperature, Ts K 302.67
Gas meter correction factor, Yd 0.97 Gas density (wet, ambient), pMean dry gas meter temperature, Tm K 303.25 p=(Ms*Ps)/(8.314*Ts) kg/m3 1.151Mean pressure drop across orifice, DH mmH2O 39.91 Stack Velocity, Vs
m/s 8.14Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.01 Actual flow of stack gas, Qa
Area of stack, As m2 0.95Volume of gas metered wet, Vmstw Qa = (60)(As)(Vs) m³/min 464.3
Total flow of stack gas, QVmstw = Vmstd + Vwstd m3 1.0108 Conversion factor (K/mm.Hg)
Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 414.8 (Ts)
No @O2ref No O2 Ref (Ts)
% oxygen measured in gas stream, act%O2 20.90 Qstw = (Qa)Ps(0.3592) Wet 415% oxygen reference condition 21 (Ts)
O2 Ref = 21.0 - act%O2 No O2 Ref Percent isokinetic, %I 21.0 - ref%O2 Nozzle diameter, Dn mm 7.0
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Nozzle area, An mm2 38.5Moisture content, Bwo Total sampling time, q min 60.0
%I = (4.6398E6)(Ts)(Vmstd) % 100.2Bwo = Vwstd 0.0010 (Ps)(Vs)(An)(q)(1-Bwo)
% 0.10Moisture by FTIR % - Acceptable isokinetic range 95% to 115% Yes
O2 Reference Factor
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
Vmstd + Vwstd
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Tm + 273
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
Moisture trap weight increase,Vlc
𝑉𝑠=𝐶𝑝√(∆𝐷𝑃𝑎𝑣𝑔/𝑝)
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litre/min litre/min litre/min mm Hg litre/min litre/min18.8 0.02 0.02 -254 0.38 Yes
Isokinetic Criterion Compliance
mm °CQuartz Fibre 47 180 Yes
Parameter Total 3rd Absorber Absorption Required Pass / Failug ug Efficiency (%) %
Chromium Run 1 6.70190 0.83 88 90 N/A - No ELV
Temperature during storage /
transit <25°C
Isokinetic Variation
HEAVY METALS ABSORBTION EFFICIENCY
Maximum Filtration
Temperature
Absorption Solutions - MetalsMetals
Leak Tests Acceptable
Filter Material
Leak Test Results
HEAVY METALS QA CHECKLIST
Post-sampling Leak Rate
Acceptable Isokineticity
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Run 1 Yes
Run 1
%
Filtration / Temp
Maximum Vacuum
Mean Sampling Rate
Acceptable Leak Rate
Pre-sampling Leak Rate
Run 1 3.3% Nitric Acid, 1.5% Hydrogen Peroxide
Filter Size
Type of Absorbers - Metals
Run 1
Glass
100.2
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.002 10 2.74
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.5 17.1 0.02 0.02 0.34 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A Glass
Parameter Total IMP C Absorptionug ug Efficiency %
54.449 ND 100
Temperature during storage / transit <25°C
Run 1
15:07 - 15:3724 September 2019
Mean Sampling Rate
mg/m³Concentration
Yes
0.11
0.005
HYDROGEN CHLORIDE SUMMARY
Max. Filtration Temp.
Leak Tests Acceptable?
Sampling Times
Acceptable ?Efficiency %
HPLC Water
-
Acceptable leak rate
Run 1
Type of Absorbers
Acceptable Absorption
95
Absorption Solutions
ND - None Detected
Post sampling leak rate
HYDROGEN CHLORIDE QUALITY ASSURANCE CHECKLIST
Total Sample Volume @ ref
Conditions
Pre sampling leak rate
Test
Absorption Efficiency
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
HYDROGEN CHLORIDE ABSORPTION EFFICIENCY
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.00 2 1.09
Field Blank - - -
Reference conditions are 273K, 101.3kPa without correction for water vapour
Leak Test Results
m³ l/min l/min l/min l/min
Run 1 0.5 15.1 0.02 0.02 0.30 Yes
Filter Material Filter Sizemm
°C
Run 1 Quartz Fibre 47 150 N/A PE
Parameter Total IMP C Absorptionug ug Efficiency %
19.233 2.763 86
Temperature during storage / transit <25°C
0.04
Post sampling leak rate
Run 1
Sampling Times
0.1N Sodium Hydroxide
Type of Absorbers
Concentrationmg/m³
-
Acceptable Absorption Absorption Efficiency
N/A- < 1mg/m³
Test
14:29 - 14:5924 September 2019
Acceptable leak rate
Total Sample Volume @ ref
Conditions
HYDROGEN FLUORIDE SUMMARY
Pre sampling leak rate
Absorption Solutions
HYDROGEN FLUORIDE ABSORPTION EFFICIENCY
Efficiency %
Run 1
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Leak Tests Acceptable?
Max. Filtration Temp.
95
0.01
Mean Sampling Rate
HYDROGEN FLUORIDE QUALITY ASSURANCE CHECKLIST
Acceptable ?
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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty
kg kg kg % % %
Run 1 3.1858 3.1862 0.0004 0.1 0.02 57.8
Test NumberSampling Duration
Total Volume Sampled
Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate
mins l l/min l/min l/min l/min
Run 1 30 507 16.9 0.02 0.02 0.34 Yes
Stack Diameter / Depth, D 1.10 m
Stack Width, W - m
Stack Area, A 0.95 m2
Average stack gas temperature 30 oC
Stack static pressure 0.054 kPa
Barometric Pressure 100.5 kPa
Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3
M p % Vol r pi % Vol r pi
CO2 44 1.963059 0.028571 0.000286 0.000561 0.028543 0.000285 0.000560
O2 32 1.427679 20.900000 0.209000 0.298385 20.879456 0.208795 0.298092
N2 28 1.249219 79.071429 0.790714 0.987775 78.993706 0.789937 0.986805
H2O 18 0.803070 - - - 0.098295 0.000983 0.000789
Where: p = M / 22.41 pi = r x p
Determinand
Dry Density (STP), P STD
Wet Density (STP), P STW
Dry Density (Actual), P Actual
Average Wet Density (Actual), P ActualW
Where:
P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)
P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)
PRELIMINARY STACK SURVEY
Leak Tests Acceptable?
1.150
kg/m3
Units
Moisture Quality Assurance
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1.2862
kg/m31.2867
kg/m3
Stack Characteristics
MOISTURE CALCULATIONS
Stack Gas Composition & Molecular Weights
Moisture Determination - Non Isokinetic
14:29 - 14:59 24 September 2019
Result
kg/m3
Calculation of Stack Gas Densities
Sampling Time and Date
1.1508
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TRAVERSE 1
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.03 56.4 5.8 30 8.8 8.4 - <152 0.09 58.8 6.0 30 9.0 8.5 - <153 0.16 61.3 6.3 30 9.2 8.7 - <154 0.25 56.4 5.8 30 8.8 8.4 - <155 0.38 53.9 5.5 30 8.6 8.2 - <156 0.72 49.0 5.0 30 8.2 7.8 - <157 0.85 51.5 5.3 30 8.4 8.0 - <158 0.94 49.0 5.0 30 8.2 7.8 - <159 1.01 44.1 4.5 30 7.8 7.4 - <15
10 1.07 39.2 4.0 30 7.3 7.0 - <15Mean - 51.9 5.3 30 8.4 8.0 - -
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -
Mean - - - - - - - -
Start Value End Value Difference Start Value End Value DifferencemmH2O mmH2O % mmH2O mmH2O %
Run 1 111 110 0.9 Pass 128 126 1.6 Pass
RunStagnation
(Pa)Reference
(Pa)Difference
(Pa)
Outcome(Permitted +/- 10 Pa)
Run 1 53 54 -1.0 Pass
Sampling Line B
12:4024 September 2019
To complete a compliant pitot leak check a pressure of over 80 mmH
₂
O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.
S-Type Pitot Stagnation Check
OutcomePre Traverse Leak Rate
Run
PITOT LEAK CHECKPost Traverse Leak Rate
Sampling Line A
Outcome
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Time of Survey
Volumetric Flow Rate
(actual)
Date of Survey
Velocity Measurement Device: S-Type Pitot
Volumetric Flow Rate
(actual)
PRELIMINARY STACK SURVEY
PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST
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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant
Lowest Differential Pressure Pa >= 5 Pa Yes
Lowest Gas Velocity m/s - -
Highest Gas Velocity m/s - -
Ratio of Gas Velocities - < 3 : 1 Yes
Maximum angle of flow with regard to duct axis o < 15o Yes
No local negative flow - - Yes
Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)
Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998
Average Stack Gas Velocity, Va 8.4 m/s
Duct gas flow conditions Actual Reference UnitsTemperature 30 0 oCTotal Pressure 100.554 101.3 kPaOxygen 20.9 21 %Moisture 0.10 0.10 %Pitot tube calibration coefficient, Kpt 0.89
Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2
Gas Volumetric Flowrate (Actual), QActual m3/hr
Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr
Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr
Gas Volumetric Flowrate (REF), QRef m3/hr
Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((21 - O2a) / (21 - O2s))
Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol
8.42
25741
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Plane Validation Criteria
<15
Calculation of Stack Gas Velocity, V
Calculation of Stack Gas Volumetric Flowrate, Q
2881025766
25766
7.3
1.3
PRELIMINARY STACK SURVEY (CONTINUED)
Yes
9.2
39
Result
0.95
Result
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Value UnitsStack Depth 1.10 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.95 m2 - - - -
Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o
1 6.7 0.07 < 152 25.0 0.28 < 153 75.0 0.83 < 154 93.3 1.03 < 15
- - - -
- - - -
- - - -
- - - -- - - -- - - -- - - -- - - -
- - - -
- - - -- - - -- - - -
Isokinetic sampling point - - - -Isokinetic sampling points not used - - - -Non Isokinetic/Gases sampling point - - - -
- - - -
SAMPLING LOCATION
Non-Isokinetic/Gases Sampling
Isokinetic Sampling
STACK DIAGRAMAPPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Line A
1
2
3
4
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Concentration in impinger
Leak
m³ K kPa % by volume % by volume mg %MU required <=2% <2.5 k <=1% <=1% <=5% <5% <=2%Run 1 0.001 2.0 0.50 1.0 0.10 0.0002 -as a % 0.10 0.73 0.50 1.0 - 3.00 0.11compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ - mg mg/m³ mgRun 1 1.0028 - 6.7019 0.000004 - -MU as mg/m3
0.0001 - 0.0003 0.000004 0.00021 0.0004MU as % 1.3395 - 5.0583 0.0615 3.12500 -
0.001 mg/m³ 12.19 % Result N/A % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
LeakO2 Correction
MEASUREMENT UNCERTAINTY BUDGET - HEAVY METALS
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Volume (STP) Mass of Heavy Metals
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Combined uncertainty
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.003 -as a % 0.067 0.658 0.498 1.000 - 0.036 0.117compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.4570 0.0795 - 0.0001 - -MU as mg/m3
0.0014 0.0036 - 0.0001 0.0051 0.0064MU as % 1.2984 3.3546 - 0.0676 4.8 -
0.01 mg/m³ 12.00 % Result 0.13 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN CHLORIDE
LeakO2 Correction
Sampled Gas Temp
Sampled Volume
Run
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
LeakLimit of Detection
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Oxygen Content
Sampled Gas Humidity
Sampled Gas Pressure
Mass of Hydrogen Chloride
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m³ K kPa % by volume % by volume % by mass %MU required <=2% <2.5 k <=1% <=1% <=5% < 5% of ELV <=2%Run 1 0.0003 2.000 0.500 1.000 0.100 0.006 -as a % 0.067 0.658 0.498 1.000 - 0.354 0.133compliant? Yes Yes Yes Yes N/A Yes Yes
Run LabUncertainty
m³ mg - mg/m³ mgRun 1 0.4035 0.0330 - 0.00003 - -MU as mg/m3
0.0006 0.0071 - 0.00003 0.0026 0.0076MU as % 1.2984 16.6706 - 0.0766 6.1 -
0.02 mg/m³ 35.60 % Result 0.76 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
MEASUREMENT UNCERTAINTY BUDGET - NON-ISOKINETIC HYDROGEN FLUORIDE
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass of Hydrogen Fluoride
Sampled Gas Pressure
Sampled Gas Temp
Sampled Volume
Volume (STP) Combined uncertainty
LeakLimit of Detection
Oxygen Content
Sampled Gas Humidity
LeakO2 Correction
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Run
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %
MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.0003 2.0 0.50 1.0 N/A -as a % 0.07 0.66 0.50 1.0 N/A 0.12compliant? Yes Yes Yes Yes N/A Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 0.45 400 1.0 0.54 57.7 -MU as % v/v 0.001 0.02 - 0.0001 0.01 0.03MU as % 1.30 25.0 - 0.07 14.4 -
0.06 % v/v 57.79 %Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Volume (STP)
MEASUREMENT UNCERTAINTY BUDGET - MOISTURE
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
Leak Combined uncertainty
O2 Correction
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Mass Gained
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8.4 m/s28810 m³/hr
Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination
Uncertainty of pitot tube coefficient - 0.010
Uncertainty of mean local dynamic pressures - 0.58
Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes
Range of measurment device pa 1000
Resolution pa 1.00
Calibration uncertainty pa 9.44<1% of Value or 20
Pa whichever is greater
Yes
Drift % range 0.10
Linearity % range 0.06 <2% of value Yes
Uncertainty of gas density determination
Uncertainty of molar mass determination kg/mol 0.00003Uncertainty of temperature measurement K 1.55 <1% of value Yes
Uncertainty of absolute pressure in the duct pa 513
Uncertainty associated with the estimate of density - 0.007
Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001
m/s0.100.20
%1.22.3
m³/hr748
1465
%2.65.1
Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
Combined uncertainty
Note - The expanded uncertainty uses a coverage factor of k = 2.
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE
Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval
Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions
Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval
Note - The expanded uncertainty uses a coverage factor of k = 2.
Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval
Measurement Uncertainty Volumetric Flow Rate
Expanded uncertainty at a 95% Confidence Interval
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SOCOTEC UK LTD
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https://www.surveymonkey.co.uk/r/CAE_customer_feedback_weblink
END OF REPORT
Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on
the following
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Bombardier AerospaceBelfastM31
LEK 11848 / Version 124th - 25th September 2019
PPC (NI) Permit: P0135/06A
SOCOTEC Job Number:Report Date:Version: 1Report By: Matthew GreenMCERTS Number: MM 04 499MCERTS Level: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Report Approved By: Andrew O'NeillMCERTS Number: MM 08 985Business Title: MCERTS Level 2 - Team LeaderTechnical Endorsements: 1, 2, 3 & 4
Signature:
Email: [email protected]
2-4 Langlands PlaceKelvin South Business Park
East KilbrideG75 0YF
Tel: 01355 246 730Fax: 01355 249 669
Permit Reference:PPC (NI) Permit: P0135/06A
David HayBusiness Manager - North
Tel: 01355 246 730
Your contact at SOCOTEC LTD
Operator & Address:
Airport Road
BT3 9DZ
Queens Island
Bombardier Aerospace
Belfast
Release Point: A39
Sampling Date(s):24th - 25th September 2019
14th November 2019LEK 11848
STACK EMISSIONS MONITORING REPORT
SOCOTEC UK Reporting Template v5 Page 1 of 26
SOCOTEC UK LTD
www.socotec.co.uk
EXECUTIVE SUMMARY
Stack Emissions Monitoring Objectives
- Plant
- Operator
- Stack Emissions Monitoring Test House
Emissions Summary
Monitoring Times
Process Details
Monitoring Methods
Analytical Methods
- Sampling Methods with Subsequent Analysis
- On-Site Testing
Sampling Location
- Sampling Plane Validation Criteria
- Duct Characteristics
- Sampling Lines & Sample Points
- Sampling Platform
- Sampling Location / Platform Improvement Recommendations
Sampling and Analytical Method Deviations
APPENDICES
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
Page 2 of 26
Bombardier AerospaceBelfastA39
LEK 11848 / Version 124th - 25th September 2019
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SOCOTEC UK LTD
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Plant
A39
Operator
Bombardier Aerospace
Airport Road
Queens Island
Belfast
BT3 9DZ
PPC (NI) Permit: P0135/06A
Stack Emissions Monitoring Test House
SOCOTEC - East Kilbride Laboratory2-4 Langlands PlaceKelvin South Business ParkEast KilbrideG75 0YFUKAS and MCERTS Accreditation Number: 1015
Opinions and interpretations expressed herein are outside the scope of UKAS accreditation.MCERTS accredited results will only be claimed where both the sampling and analytical stages are UKAS accredited.This test report shall not be reproduced, except in full, without written approval of SOCOTEC LTD.
MONITORING OBJECTIVES
SOCOTEC LTD were commissioned by Bombardier Aerospace to carry out stack emissions monitoring to determine the release of prescribed pollutantsfrom the following Plant under normal operating conditions.
Bombardier Aerospace operates a solvent recovery process at Belfast which is subject to PPC (NI) Permit P0135/06A, under the Pollution Preventionand Control (Industrial Emissions) Regulations (Northern Ireland) 2013.
EXECUTIVE SUMMARY
The results of these tests shall be used to demonstrate compliance with a set of emission limit values for prescribed pollutants as specified in thePlant's PPC (NI) Permit, P0135/06A.
Page 3 of 26
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Parameter Units Result Calculated Uncertainty
+/-Total Particulate Matter mg/m³ 0.95 0.33 10Particulate Emission Rate g/hr 8.68 3.05 -Total Volatile Organic Compounds (As Perchloroethylene) mg/m³ 5.78 8.97 20Total Volatile Organic Compounds Emission Rate (As Perchloroethylene) g/hr 51.71 80.31 -Moisture % 0.34 0.02 - P
Stack Gas Temperature oC 41 - -Stack Gas Velocity m/s 9.8 0.23 -Gas Volumetric Flow Rate (Actual) m³/hr 10362 528 -Gas Volumetric Flow Rate (STP, Wet) m³/hr 8950 456 -Gas Volumetric Flow Rate (STP, Dry) m³/hr 8919 454 -Gas Volumetric Flow Rate at Reference Conditions m³/hr 8950 456 -
MCERTS accredited
result
ND = None Detected,Results at or below the limit of detection are highlighted by bold italic text.The above volumetric flow rate is calculated using data from the preliminary survey. Mass emissions for non isokinetic tests are calculated using these values. For all isokinetic testing the mass emission is calculated using test specific flow data and not the above values.
EXECUTIVE SUMMARY
EMISSIONS SUMMARY
Reference conditions are 273K, 101.3kPa without correction for water vapour
P
P
P
Emission Limit Value (ELV)
Page 4 of 26
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Total Particulate Matter Run 1Total Volatile Organic Compounds Run 1 25 September 2019 11:26 - 12:26Preliminary Stack Traverse 25 September 2019 11:00
60 minutes-
25 September 2019 11:26 - 12:26
Sampling TimesSampling Date(s)Parameter
EXECUTIVE SUMMARY
Sampling Duration
60 minutes
MONITORING TIMES
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Description of process Solvent Recovery
Continuous or batch Continuous
Product Details Aircraft Components
Part of batch to be monitored (if applicable) N/A
Normal load, throughput or continuous rating Normal Operation
Fuel used during monitoring N/A
Abatement Scrubber
Plume Appearance None
PROCESS DETAILS
Parameter
EXECUTIVE SUMMARY
Process Details
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Species SOCOTEC UKAS Lab MCERTS Limit of Calculated CalculatedTechnical Number Accredited Detection MU MUProcedure Method (LOD) +/- % Result +/- % ELV
Total Particulate Matter
AE 104 1015 Yes 0.17 mg/m³ 35.1% 3.3%
Total Volatile Organic Compounds AE 102 1015 Yes 0.64 mg/m³ 155.3% 6.5%
Moisture AE 105 1015 Yes 0.01% 7.27% N/A - No ELV
Velocity AE 154 1015 Yes 5 Pa 2.3% N/A - No ELV
Volumetric Flow Rate
AE 154 1015 Yes - 5.1% N/A - No ELV
SRM - BS EN 13284-1
SRM - BS EN 12619:2013
EXECUTIVE SUMMARY
Monitoring Methods
The selection of standard reference / alternative methods employed by SOCOTEC is determined, wherever possible by the hierarchy of methodselection outlined in Environment Agency Technical Guidance Note (Monitoring) M2.
SRM - BS EN ISO 16911-1
MethodStandard Reference Method /
Alternative Method
BS EN 14790 has been validated over a range of 4 - 40%. It is however the prefered method of the Environment Agency for concentrations below 4%
SRM - BS EN 14790
SRM - BS EN ISO 16911-1
MONITORING METHODS
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Total Particulate Matter
AE 106 1015 YesSOCOTEC (East
Kilbride)N/A 8 Weeks
- - - - - - -
Species Analytical UKAS Lab MCERTS Laboratory Data ArchiveProcedure Number Accredited Archive Period
Analysis LocationTotal Volatile Orangic
Compounds AE 102 1015 YesSOCOTEC (East
Kilbride)SOCOTEC (East
Kilbride)5 years
Moisture AE 105 1015 YesSOCOTEC (East
Kilbride)- -
EXECUTIVE SUMMARY
Analytical Technique
Analytical Methods
Gravimetric
-
Flame Ionisation Detection
Gravimetric
The following tables list the analytical methods employed together with the custody details. Unless otherwise stated the samples are archived at the analysis lab location.
Analysis LabArchivePeriod
UKAS Lab Number
Analytical Procedure
Analytical TechniqueSpecies
SAMPLING METHODS WITH SUBSEQUENT ANALYSIS
UKAS Accredited Lab Analysis
Analysis Report number
ON-SITE TESTING
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Sampling Plane Validation Criteria Value Units Requirement Compliant Method
Lowest Differential Pressure 59 Pa >= 5 Pa Yes BS EN 15259
Lowest Gas Velocity 9.1 m/s - - -
Highest Gas Velocity 10.5 m/s - - -
Ratio of Gas Velocities 1.2 : 1 < 3 : 1 Yes BS EN 15259
Mean Velocity 9.8 m/s - - -
Maximum angle of flow with regard to duct axis <15 o < 15o Yes BS EN 15259
No local negative flow Yes - - Yes BS EN 15259
Value Units Isokinetic
Shape Circular -
Depth 0.61 m Sample port size 3" BSP 10mm Hole
Width - m Number of lines used 1 1
Area 0.29 m2 Number of points / line 4 1
Port Depth 80 mm Duct orientation Vertical VerticalIn Stack -
General Platform Information
Permanent / Temporary Platform / Ground level / Floor Level / Roof
Inside / Outside
M1 Platform requirements
Is there a sufficient working area so work can be performed in a compliant manner
Platform has 2 levels of handrails (approximately 0.5 m & 1.0 m high)
Platform has vertical base boards (approximately 0.25 m high)
Platform has removable chains / self closing gates at the top of ladders
Handrail / obstructions do not hamper insertion of sampling equipmentDepth of Platform = >Stack depth / diameter + wall and port thickness + 1.5m
Sampling Platform Improvement Recommendations (if applicable)
SAMPLING PLATFORM
Non-Iso & Gases
Yes
DUCT CHARACTERISTICS
EXECUTIVE SUMMARY
Permanent
One sample port overhangs the railings making it not suitable for testing. Where possible the sample platform should be modified to allow for samplingon this line.
SAMPLING LOCATION
Yes
Filtration for TPM
No
SAMPLING LINES & POINTS
Yes
N/A
Outside
Yes
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Sample Points
Sampling & Analytical Method Deviations
EXECUTIVE SUMMARY
Only one sample line is available for the testing to be carried out, therefore the number of points sampled on this available line will bedoubled in accordance with the standard.
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APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
APPENDIX 3 - Measurement Uncertainty Budget Calculations
CONTENTS
APPENDICES
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SOCOTEC UKAS Lab MCERTSTechnical Number AccreditedProcedure Method
AE 104 1015 Yes 1
AE 102 1015 Yes 1
AE 105 1015 Yes 1AE 154 1015 Yes 1
MoistureVelocity
Species
MONITORING SCHEDULE
Total Particulate Matter
Total Volatile Organic Compounds
SRM - BS EN 13284-1
SRM - BS EN 12619:2013
SRM - BS EN ISO 16911-1SRM - BS EN 14790
Standard Reference Method / Alternative Method
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
Number of Samples
Method
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Equipment I.D. Equipment I.D. Equipment I.D.
LEK 9.28 - LEK 15.21
LEK 9.25 - LEK 20.31
LEK 9.25 - -
LEK 9.25 - -
LEK 17.21 - -
LEK 13.16 - LEK 1.14
LEK 6.18 - LEK LNO 03-CD
- LEK 8.27 -
- - -
- - -
LEK 6.18 - -
- - -
LEK 23.18 - -
- LEK 8.30 -
- - -
LEK 15.1D - -
- - LEK 8.30
- - -
LEK 24.7 - -
NOTE: If the equipment I.D is represented by a dash (-), then this piece of equipment has not been used for this test.
Cylinder I.D Number
Supplier ppm %Analytical
Tolerance +/- %
Propane LEK 192 BOC 80.2 - 2.0- - - - -
Level Expiry TE1 TE2 TE3 TE4 H&S
Andrew O'Neill MM 08 985MCERTS Level
2Mar-20 Sep-20 Mar-22 Mar-20 Sep-20 Oct-23
Callum Montgomery
MM 16 1399MCERTS Level
1Nov-22 Mar-24 - - - Nov-22
10m Heated Line (2)
15m Heated Line (1)
20m Heated Line (1)
Gas (traceable to ISO 17025)
Barometer
Equipment
Ecophysics NOx Analyser
Heater Controller
Last Impinger Arm
S-Pitot
FT-IR Gasmet
Meter In Thermocouple Stopwatch
MCERTS Number
TE / H&S Qualifications and Expiry DateMCERTS
Probe
Probe Thermocouple
Stackmaster
Meter Out Thermocouple
Control Box Timer
Stack Thermocouple
1m Heated Line (1)
L-Pitot
Oven Box
Probe JCT Heated Head Filter
Digital Micromanometer
Bernath 3006 FID Protractor
FT-IR Oven Box
Signal 3030 FID
-
Personnel
CALIBRATION GASES
FTIR Heater Box for Heated Line
1m Heated Line (3)
Callipers
20m Heated Line (2)
Anemometer
Dioxins Cond. Thermocouple 10m Heated Line (1)
MONITORING TEAM
Heated Line Controller (2)
Instrumental Analyser/s
APPENDIX 1 - Monitoring Schedule, Calibration Checklist & Monitoring Team
CALIBRATEABLE EQUIPMENT CHECKLISTMiscellaneous
Control Box DGM Laboratory Balance
Equipment
Horiba PG-250 Analyser
1m Heated Line (2)
Mass Flow Controller
Thermo FID
Digital Temperature Meter
Servomex
Probe Thermocouple
MFC Display module
Box Thermocouples Tape Measure
Extractive Sampling
Equipment
Chiller (JCT/MAK 10)Site Balance
5m Heated Line (1)
Small DGM
Heated Line Controller (1)
Site temperature Logger
Inclinometer (Swirl Device)
STACK EMISSIONS MONITORING TEAM
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Uncertainty ELV Emissionmg/m³ mg/m³ Rate g/hr
0.33 10 8.68
Blank - - -Reference conditions are 273K, 101.3kPa without correction for water vapour
TestFilter & Probe Rinse Number
Filter Start Weight
Filter End Weight
Mass Gained on Filter
Probe Rinse Start Weight
Probe Rinse End Weight
Mass Gained on Probe
Combined Total Mass Gained
g g g g g g gRun 1 AC 0187 0.09850 0.09850 0.00000 201.96050 201.96170 0.00120 0.00120If total mass gained is less than the LOD then the LOD is reported
TestFilter & Probe
NumberFilter Start
WeightFilter End
WeightMass Gained
FilterProbe Start
WeightProbe End
WeightMass Gained
ProbeCombined Total
Mass Gained
g g g g g g gRun 1 AC 0190 0.09805 0.09805 0.00000 188.60010 188.60030 0.00020 0.00021If total mass gained is less than the LOD then the LOD is reported
-
Acetone Blank Value
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Run 1
Concentration
0.17
mg/m³Sampling Times
2.0 10
FILTER INFORMATION
11:26 - 12:2625 September 2019
0.95
TOTAL PARTICULATE MATTER SUMMARYParameter
mg/lAcceptable Value
mg/l
BLANKS
SAMPLES
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ISOKINETIC SAMPLING EQUATIONS - RUN 1 TPM
Absolute pressure of stack gas, Ps Molecular weight of dry gas, Md
Barometric pressure, Pb Kpa 100.7 CO2 % 0.03Stack static pressure, Pstatic pa -68 O2 % 20.90Ps = Pb + Pstatic Kpa 100.6 Total % 20.93
N2 (100 -Total) % 79.07Vol. of water vapour collected, Vwstd Md = 0.44(%CO2)+0.32(%O2)+0.28(%N2) 28.84
g 3.4 Molecular weight of wet gas, Ms
Vwstd = (0.001246)(Vlc) m3 0.0042364 Ms = Md(1 - Bwo) + 18(Bwo) g/gmol 28.80Volume of gas metered dry, Vmstd Actual flow of stack gas, Qa
Volume of gas sample through gas meter, Vm m3 1.491 Area of stack, As m2 0.29
Gas meter correction factor, Yd 0.916 Qa = (60)(As)(Vs) m³/min 175.8Mean dry gas meter temperature, Tm K 297 Total flow of stack gas, QMean pressure drop across orifice, DH mmH2O 57.366 Conversion factor (K/mm.Hg) 0.3592
Vmstd = (0.3592)(Vm)(Pb+(DH/13.6))(Yd) m3 1.255 Qstd = (Qa)Ps(0.3592)(1-Bwo) Dry 151.3 (Ts)
Volume of gas metered wet, Vmstw @O2ref No O2 RefVmstw = Vmstd + Vwstd m3 1.2591 (Ts)
Qstw = (Qa)Ps(0.3592) Wet 151.82 (Ts)
No Percent isokinetic, %INozzle diameter, Dn mm 7.00
% oxygen measured in gas stream, act%O2 20.9 Nozzle area, An mm2 38.49% oxygen reference condition 21 Total sampling time, q min 60
No O2 Ref %I = (4.6398E6)(Ts)(Vmstd) % 105.0 (Ps)(Vs)(An)(q)(1-Bwo)
Vmstd@X%oxygen = (Vmstd) (O2 Ref) m3 No O2 Ref Acceptable isokinetic range 95% to 115% YesMoisture content, Bwo Particulate Concentration, CBwo = Vwstd 0.0034 Mass collected on filter, Mf g 0.00000
% 0.34 Mass collected in probe, Mp g 0.00120Moisture by FTIR % - Total mass collected, Mn g 0.00120Velocity of stack gas, Vs Cwet = Mn mg/m³ 0.953Velocity pressure coefficient, Cp 0.90 Vmstw
Mean of velocity heads, DPavg Pa 68.60 Cdry = Mn mg/m³ 0.956Mean stack gas temperature, Ts K 314 Vmstd
Gas density (wet, ambient), p Cdry@X%O2 = Mn mg/m³ No O2 Refp=(Ms*Ps)/(8.314*Ts) kg/m3 1.110Stack Velocity, Vs Particulate Emission Rates, E
m/s 10.03 E = [(Cwet)(Qstw)(60)] / 1000 8.68
Vmstd@X%oxygen
QstdO2 = (Qa)Ps(0.3592)(1-Bwo)(O2REF)
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Is the process burning hazardous waste? (If yes, no favourable oxygen correction)
O2 Reference Factor
Moisture trap weight increase,Vlc
Tm
Vmstd + Vwstd
O2 Ref = 21.0 - act%O2
21.0 - ref%O2
Vol. of gas metered at O2 Ref. Cond., Vmstd@X%O2
𝑉𝑠=𝐶𝑝√(∆𝐷𝑃𝑎𝑣𝑔/𝑝)
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litre/min litre/min litre/min mm Hg litre/minRun 1 22.76 0.02 0.02 -203.2 0.46 Yes
% mg/m³ mg/m³Run 1 104.96 Yes Run 1 0.17 0.5 Yes
Acceptable isokinetic range 95% to 115% The above is based on both the Filter and rinse uncertainty
mg/m3 mg/m3 mg/m3 mg/m3
mm °CRun 1 Glass Fibre 47 41
Acceptable Blank Value
Yes
Run
180
Maximum Vacuum
Run
5% ELV
160
Pre-use Filter Conditioning Temperature
Max Filtration Temperature
°C
BLANK VALUE
0.17
WEIGHING BALANCE UNCERTAINTYISOKINETICITYAcceptable Isokineticity
Filter SizeFilter Material
Run
Run
Overall Blank Acceptable
Post-use Filter Conditioning Temperature
1.0
Acceptable Leak Rate
Blank 1
Leak Tests Acceptable?
Run
LEAK RATEPost-sampling
Leak Rate
°C
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Result
FILTERS
Daily Emission Limit Value
Isokinetic Variation
Pre-sampling Leak Rate
Mean Sampling Rate
TOTAL PARTICULATE MATTER QUALITY ASSURANCE CHECKLIST
10
LOD < 5% ELV
Overall Blank Value
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LOD ELV Emissionmg/m³ mg/m³ Rate g/hr
0.40 20 51.71
Reference conditions are 273K, 101.3kPa without correction for water vapour
DateStart TimeEnd Time
Gas Gas Conc Range Instrument Instrument Instrument Zero Down Span down Leak Rate(ppm) Zero Reading Span Reading Zero Reading line reading line reading (%)
Propane 80.2 100 0.41 80.2 0.39 0.37 80.0 0.22Zero and Span gas contained 19.98% Oxygen
DateStart TimeEnd Time
GasMean Raw
Value Zero down Span down Zero Drift Span Drift Corrected Values
ppm line reading line reading (%) (%) ppm / %
Propane 0.52 0.30 79.6 -0.11 -0.68 O ON/A - not corrected
Reference conditions are 273K, 101.3kPa without correction for water vapour
mg/m³
TOTAL VOLATILE ORGANIC COMPOUNDS SUMMARY
TOTAL VOLATILE ORGANIC COMPOUNDS EMISSIONS CHART
Run 1
11:05
11:26 - 12:26 25 September 2019
25 September 2019
INSTRUMENTAL SPAN & ZERO CHECKS
Test
Corrected for Zero Drift
Corrected for Span Drift
POST-SAMPLING CALIBRATION CHECKS25 September 201912:3012:40
11:20
5.78
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Times
PRE-SAMPLING CALIBRATION CHECKS
Concentration
0.0
5.0
10.0
15.0
20.0
25.0
11
:26
11
:28
11
:30
11
:32
11
:34
11
:36
11
:38
11
:40
11
:42
11
:44
11
:46
11
:48
11
:50
11
:52
11
:54
11
:56
11
:58
12
:00
12
:02
12
:04
12
:06
12
:08
12
:10
12
:12
12
:14
12
:16
12
:18
12
:20
12
:22
12
:24
12
:26
Co
nce
ntr
atio
n m
g/m
³
Time
Concentration ELV
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Test Number Start Weight End Weight Total gain Concentration LOD Uncertainty
kg kg kg % % %
Run 1 3.0713 3.0747 0.0034 0.3 0.01 7.3
Test NumberSampling Duration
Total Volume Sampled
Sampling Rate Start Leak Rate End Leak RateAcceptable Leak Rate
mins l l/min l/min l/min l/min
Run 1 60 1259 22.8 0.02 0.02 0.46 Yes
Stack Diameter / Depth, D 0.61 m
Stack Width, W - m
Stack Area, A 0.29 m2
Average stack gas temperature 41 oC
Stack static pressure -0.068 kPa
Barometric Pressure 100.7 kPa
Component Molar Density Conc Dry Volume Dry Conc Conc Wet Volume Wet ConcMass kg/m3 Dry Fraction kg/m3 Wet Fraction kg/m3
M p % Vol r pi % Vol r pi
CO2 44 1.963059 0.028571 0.000286 0.000561 0.028475 0.000285 0.000559
O2 32 1.427679 20.900000 0.209000 0.298385 20.829678 0.208297 0.297381
N2 28 1.249219 79.071429 0.790714 0.987775 78.805378 0.788054 0.984452
H2O 18 0.803070 - - - 0.336469 0.003365 0.002702
Where: p = M / 22.41 pi = r x p
Determinand
Dry Density (STP), P STD
Wet Density (STP), P STW
Dry Density (Actual), P Actual
Average Wet Density (Actual), P ActualW
Where:
P STD = sum of component concentrations, kg/m3 (not including water vapour) P Actual = P STD x (Ts / Ps) x (Pa / Ta)
P STW = (P STD + pi of H2O) / (1 + (pi of H2O / 0.8036)) P ActualW = P STW x (Ts / Ps) x (Pa / Ta)
Calculation of Stack Gas Densities
Sampling Time and Date
1.1113
Stack Gas Composition & Molecular Weights
Moisture Determination - Isokinetic
11:26 - 12:2625 September 2019
Result
kg/m3
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
1.2851
kg/m31.2867
kg/m3
Stack Characteristics
Moisture Quality Assurance
MOISTURE CALCULATIONS
PRELIMINARY STACK SURVEY
Leak Tests Acceptable?
1.110
kg/m3
Units
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TRAVERSE 1
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
1 0.02 58.8 6.0 41 9.1 2.7 - <152 0.05 63.7 6.5 41 9.4 2.8 - <153 0.09 66.2 6.8 41 9.6 2.8 - <154 0.14 63.7 6.5 41 9.4 2.8 - <155 0.21 68.6 7.0 41 9.8 2.9 - <156 0.40 71.1 7.3 41 10.0 2.9 - <157 0.47 73.5 7.5 41 10.1 3.0 - <158 0.52 76.0 7.8 41 10.3 3.0 - <159 0.56 73.5 7.5 41 10.1 3.0 - <15
10 0.59 78.4 8.0 41 10.5 3.1 - <15Mean - 69.3 7.1 41 9.8 2.9 - -
Traverse Distance DP pt DP pt Temp Velocity O2 Angle
Point into Pa mmH2O oC m/s % of Swirl
duct (m)(average of 3
readings)(average of 3
readings)m³/s Vol o
- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -- - - - - - - - -
Mean - - - - - - - -
Start Value End Value Difference Start Value End Value DifferencemmH2O mmH2O % mmH2O mmH2O %
Run 1 111 110 0.9 Pass 128 126 1.6 Pass
RunStagnation
(Pa)Reference
(Pa)Difference
(Pa)
Outcome(Permitted +/- 10 Pa)
Run 1 -66 -68 2.0 Pass
PRELIMINARY STACK SURVEY QUALITY ASSURANCE CHECKLIST
Velocity Measurement Device: S-Type Pitot
Volumetric Flow Rate
(actual)
PRELIMINARY STACK SURVEY
Volumetric Flow Rate
(actual)
Date of Survey
Sampling Line A
Outcome
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Post Traverse Leak Rate
Time of Survey
To complete a compliant pitot leak check a pressure of over 80 mmH
₂
O (or 800 Pa) is applied and the pressure drop monitored over 5 mins. A drop of less than 5% must be observed.
S-Type Pitot Stagnation Check
OutcomePre Traverse Leak Rate
Run
PITOT LEAK CHECK
Sampling Line B
11:0025 September 2019
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EA Technical Guidance Note (Monitoring) M1 Units Requirement Compliant
Lowest Differential Pressure Pa >= 5 Pa Yes
Lowest Gas Velocity m/s - -
Highest Gas Velocity m/s - -
Ratio of Gas Velocities - < 3 : 1 Yes
Maximum angle of flow with regard to duct axis o < 15o Yes
No local negative flow - - Yes
Velocity at Traverse Point, V = Kpt x (1-e) * Ö(2 * DP pt / P ActualW)
Where:Kpt = Pitot tube calibration coefficient(1-e) = Compressibility correction factor, assumed at a constant 0.998
Average Stack Gas Velocity, Va 9.8 m/s
Duct gas flow conditions Actual Reference UnitsTemperature 41 0 oCTotal Pressure 100.632 101.3 kPaOxygen 20.9 21 %Moisture 0.34 0.34 %Pitot tube calibration coefficient, Kpt 0.88
Gas Volumetric Flowrate UnitsAverage Stack Gas Velocity (Va) m/sStack Area (A) m2
Gas Volumetric Flowrate (Actual), QActual m3/hr
Gas Volumetric Flowrate (STP, Wet), QSTP m3/hr
Gas Volumetric Flowrate (STP, Dry), QSTP,Dry m3/hr
Gas Volumetric Flowrate (REF), QRef m3/hr
Where:QActual = Va x A x 3600QSTP = Q (Actual) x (Ts / Ta) x (Pa / Ps) x 3600QSTP,Dry = Q (STP) / (100 - (100 / Ma)) x 3600QRef = Q (STP) x ((100 - Ma) / (100 - Ms)) x ((21 - O2a) / (21 - O2s))
Nomenclature:Ts = Absolute Temperature, Standard Conditions, 273 KPs = Absolute Pressure, Standard Conditions, 101.3 kPaTa = Absolute Temperature, Actual Conditions, KPa = Absolute Pressure, Actual Conditions, kPaMa = Water vapour, Actual Conditions, % VolMs = Water vapour, Reference Conditions, % VolO2a = Oxygen, Actual Conditions, % VolO2s = Oxygen, Reference Conditions, % Vol
Yes
10.5
59
Result
0.29
Result
8950
8950
9.1
1.2
PRELIMINARY STACK SURVEY (CONTINUED)
<15
Calculation of Stack Gas Velocity, V
Calculation of Stack Gas Volumetric Flowrate, Q
10362
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Sampling Plane Validation Criteria
9.85
8919
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Value UnitsStack Depth 0.61 m Sampling Distance Distance into UnitsStack Width - m Point (% of Depth) StackArea 0.29 m2 A 50 0.31 m
Sampling Distance Distance into SwirlPoint (% of Depth) Stack (m) o
1 8.2 0.05 < 152 25.0 0.15 < 153 75.0 0.46 < 154 91.8 0.56 < 15
- - - -
- - - -
- - - -
- - - -- - - -- - - -- - - -- - - -
- - - -
- - - -- - - -- - - -
Isokinetic sampling point - - - -Isokinetic sampling points not used - - - -Non Isokinetic/Gases sampling point - - - -
- - - -
APPENDIX 2 - Summaries, Calculations, Raw Data and Charts
Isokinetic Sampling
STACK DIAGRAM
Non-Isokinetic/Gases Sampling
SAMPLING LOCATION
Sampling Line A
1
2
3
4
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Limit of Detection
Leak Uncollected Mass
m³ K kPa % by volume % by volume % by mass % mgMU required < 2% < 2% < 1% < 1% < 10% < 5% of ELV < 2% < 10% of ELVRun 1 0.001 2.0 0.50 1.0 N/A 0.2100 - -as a % 0.08 0.64 0.50 1.0 N/A 1.66789 0.09 0.002compliant? Yes Yes Yes Yes N/A Yes Yes Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 1.08 1.2000 1.0 0.000 0.0001 -MU as mg/m3 0.01 0.1668 - 0.000 0.0001 0.17MU as % 1.29 17.5000 - 0.051 0.0101 -
0.33 mg/m³ 35.09 % Result 3.34 % ELV
(k is a coverage factor which gives a 95% confidence in the quoted figures)Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
LeakO2 Correction
APPENDIX 3 - Measurement Uncertainty Budget Calculations
Combined uncertainty
Volume (STP) Mass of particulate
MEASUREMENT UNCERTAINTY BUDGET - TOTAL PARTICULATE MATTER
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
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Run Sampled Volume
Sampled Gas Temp
Sampled Gas Pressure
Sampled Gas Humidity
Oxygen Content
Leak
m³ K kPa % by volume % by volume %MU required < 2% < 2% < 1% < 1% < 10% < 2%Run 1 0.001 2.0 0.50 1.0 N/A -as a % 0.08 0.64 0.50 1.0 N/A 0.09compliant? Yes Yes Yes Yes N/A Yes
Run UncollectedMass
m³ mg - mg/m³ mgRun 1 1.08 3400 1.0 1.37 58 -MU as % v/v 0.00 0.01 - 0.00 0.006 0.01MU as % 1.29 2.94 - 0.05 1.70 -
0.02 % v/v 7.27 %
MEASUREMENT UNCERTAINTY BUDGET - MOISTURE
Combined uncertainty
LeakO2 CorrectionMass GainedVolume (STP)
APPENDIX 3 - Measurement Uncertainty Budget Calculations
R1 - Uncertainty expressed at a 95% confidence level (where k = 2)
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0.8 mg/m3
20 mg/m3
128.32 mg/m3
160 mg/m3
Performance characteristics Value MU Met?38 Yes60 -60 -60 -
0.25 Yes0.15 Yes0.70 Yes-0.11 Yes-0.68 Yes0.02 Yes0.80 Yes0.01 Yes0.10 Yes0.22 Yes1.0 Yes
Uncertaintyur0ursufit
u0druspresuapresutempuvoltuleakucalib
uf
0.84 mg/m3
0.67 mg/m3
1.31 mg/m3
6.53 % ELV
1.31 mg/m3
155.29 % valueReference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
-
Expanded uncertainty expressed with a level of confidence of 95%
Uncertainty in factor
% full scale/10K
Expanded uncertainty
Units specification
< 0.1%vol /10 volt
Number of readings in measurement
<2 % range
% of full scale/3 kPa
Drift
Measured Concentration
0.00
ambient temperature dependence
seconds
Zero drift
Repeatability at zero
Performance characteristic
Expanded uncertainty expressed with a level of confidence of 95%
Lack of fit
<1 % range
MEASUREMENT UNCERTAINTY BUDGET - VOLATILE ORGANIC COMPOUNDS RUN 1
< 2% of valueUncertainty of calibration gaslosses in the line (leak) < 2% of span gas value
losses in the line (leak)
<2 % / 3 kPa
% of valuedependence on voltage
<3% range / 10 K% of full scale/2 kPaatmospheric pressure dependence
-
Logger sampling interval
Repeatability at span levelDeviation from linearity
<2% range / 24hr
<3% / 2 kPa
minutes
volume or pressure flow dependence
atmopsheric pressure dependence
% of value
Standard deviation of repeatability at zero
APPENDIX 3 - Measurement Uncertainty Budget Calculations
<2% range / 24hr% full scale
<180
Range
% of value
seconds
% full scale/10V
Response time
0.00
0.00
Measurement uncertainty Measured Concentration
% full scale
volume or pressure flow dependence
Measurement period-
<2 % range
Calibration Gas ConcentrationLimit
-
Span drift
% full scale
0.02Standard deviation of repeatability at span level
% full scale
0.04
0.65
Value of uncertainty quantity
Uncertainty of calibration gas
ambient temperature dependence
Combined uncertainty
0.00Dependence on voltage 0.14
Expanded uncertainty expressed with a level of confidence of 95%
0.02
-0.07
0.00
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9.8 m/s10362 m³/hr
Performance Characteristics & Source of Value Units Values Requirement CompliantUncertainty of Local Gas Velocity Determination
Uncertainty of pitot tube coefficient - 0.010
Uncertainty of mean local dynamic pressures - 0.69
Factor loading, function of the number of measurements. 3 readings 0.591 minimum 3 Yes
Range of measurment device pa 1000
Resolution pa 1.00
Calibration uncertainty pa 11.95<1% of Value or 20
Pa whichever is greater
Yes
Drift % range 0.10
Linearity % range 0.06 <2% of value Yes
Uncertainty of gas density determination
Uncertainty of molar mass determination kg/mol 0.00003Uncertainty of temperature measurement K 1.60 <1% of value Yes
Uncertainty of absolute pressure in the duct pa 513
Uncertainty associated with the estimate of density - 0.007
Uncertainty associated with the measurement of local velocity - 0.0001Uncertainty associated with the measurement of mean velocity - 0.0001
m/s0.120.23
%1.22.3
m³/hr269528
%2.65.1
Expanded Measurement Uncertainty of Volumetric Flow Rate at a 95% Confidence IntervalExpressed as a % of the Measured Volumetric Flow RateExpanded uncertainty at a 95% Confidence Interval
Measured Velocity at Actual Conditions Measured Volumetric Flow rate at Actual Conditions
Measurement Uncertainty - VelocityCombined uncertaintyExpanded uncertainty at a 95% Confidence Interval
Note - The expanded uncertainty uses a coverage factor of k = 2.
Expanded Measurement Uncertainty of Velocity at a 95% Confidence IntervalExpressed as a % of the Measured VelocityExpanded uncertainty at a 95% Confidence Interval
Measurement Uncertainty Volumetric Flow Rate
Expanded uncertainty at a 95% Confidence Interval
APPENDIX 3 - Measurement Uncertainty Budget Calculations
MEASUREMENT UNCERTAINTY BUDGET - VELOCITY & VOLUMETRIC FLOW RATE
Combined uncertainty
Note - The expanded uncertainty uses a coverage factor of k = 2.
Reference – SOCOTEC Technical Procedure AE150 Estimation of Uncertainty of Measurement
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END OF REPORT
Thank you for choosing SOCOTEC for your environmental monitoring needs. We hope our services have met your requirements and that you are fully satisfied with your experience of working with us, we really do value your custom and would welcome your feedback. We would appreciate it if you could take a moment to complete a short online questionnaire so that we can improve our operations and address any areas that have not met with your expectations, by clicking on
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QI S1 & W1 Report 2019
Permit No P0135/06A
S1 RELEASES TO SEWER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Effluent Treatment Plant MFF1
Date
pH
Suspended
Solids
(mg/l)
Set COD
(mg/l)
Total Metals
(mg/l)
Total Chromium
(mg/l)
Hexavalent
Chromium (mg/l)
Limits
≥5 and ≤10
400
3,000
10
3
1
January 6.85 23 111 0.246 0.090 0.054
February 6.96 12 160 0.078 0.073 0.005
March 7.11 17 108 0.428 0.410 0.010
April 6.73 13 65 0.070 0.010 0.003
May 7.11 23 42 0.298 0.021 0.014
June 6.93 11 54 0.293 0.018 0.007
July 7.64 10 73 0.171 0.076 0.007
August 6.87 19 51 0.839 0.540 0.003
September 6.98 28 38 1.282 0.830 0.024
October 6.81 16 44 0.661 0.418 0.003
November 6.76 12 70 0.529 0.526 0.003
December 7.24 15 44 0.173 0.102 0.003
Note: Signed on behalf of the Operator. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
S1 RELEASES TO SEWER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Effluent Treatment Plant MFF3
Date
pH
Suspended
Solids
(mg/l)
Set COD
(mg/l)
Total Metals
(mg/l)
Total Chromium
(mg/l)
Hexavalent
Chromium (mg/l)
Limits
≥5 and ≤10
400
3000
10
3
1
January 8.02 10 341 0.010 0.010 0.030
April 6.28 10 46 0.050 0.001 0.015
July 9.36 10 2220 0.114 0.001 0.007
October 8.31 7 672 0.091 0.001 0.003
Note:
Signed on behalf of the Operator.. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
S1 RELEASES TO SEWER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Vapour Blast (MFF4)
Date
pH
Suspended
Solids
(mg/l)
Set COD
(mg/l)
Total Metals
(mg/l)
Total Chromium
(mg/l)
Hexavalent
Chromium (mg/l)
Limits
≥5 and ≤10
400
3000
10
3
1
January 7.92 57 12 0.048 0.010 0.015
April 7.89 21 10 0.079 0.010 0.003
July 7.69 18 15 0.125 0.010 0.003
October 7.93 12 25 0.189 0.011 0.030
Note:
Signed on behalf of the Operator. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
S1 RELEASES TO SEWER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Boiler House (Boiler Blow Down) PE1 (MFF5)
Date
pH
Suspended
Solids
(mg/l)
Set COD
(mg/l)
Total Metals
(mg/l)
Total Chromium
(mg/l)
Hexavalent
Chromium (mg/l)
Limits
≥5 and ≤10
400
3000
10
3
1
January 8.3 61 40 0.174 0.010 0.003
April 7.7 10 21 0.073 0.010 0.003
July 8.4 11 8 0.148 0.010 0.004
October 7.1 14 1110 2.805 0.002 0.030
Signed on behalf of the Operator Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
W1 RELEASES TO WATER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Compressor 1 (MFS2)
Date
pH
Suspended
Solids
(mg/l)
Visible Oil &
Grease
Limits
≥6 & ≤9
50
None Visible
January 7.0 10 None
April 6.6 10 None
July 7.1 25 None
October 6.3 15 None
Signed on behalf of the Operator.. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
W1 RELEASES TO WATER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Main Factory Compressor 2 (MFS3)
Date
pH
Suspended
Solids
(mg/l)
Visible Oil &
Grease
Limits
≥6 & ≤9
50
None Visible
February 6.9 15 None
April 8.1 10 None
July 7.1 10 None
December 7.5 3 None
Signed on behalf of the Operator.. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
S1 RELEASES TO SEWER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Airport Factory Effluent Treatment Plant (AFF1)
Date
pH
Suspended
Solids
(mg/l)
Set COD
(mg/l)
Total Metals
(mg/l)
Total Chromium
(mg/l)
Hexavalent
Chromium (mg/l)
Limits
≥5 and ≤10
400
3,000
10
3
1
January 8.0 160 1634 1.560 0.420 0.030
February 7.7 95 23 0.588 0.260 0.009
March 7.8 33 13 0.727 0.710 0.083
April 6.9 10 70 0.900 0.010 0.003
May 8.0 11 11 0.285 0.010 0.003
June 7.9 31 13 0.285 0.010 0.003
July 7.6 31 16 0.675 0.140 0.018
August 6.9 45 69 0.603 0.270 0.089
September 9.8 60 7 0.974 0.028 0.003
October 7.8 157 47 0.139 0.029 0.030
November 7.8 226 63 1.242 1.17 0.072
December 7.24 15 44 0.813 0.018 0.030
Note
Signed on behalf of the Operator.. Date: 02/01/2020
QI S1 & W1 Report 2019
Permit No P0135/06A
W1 RELEASES TO WATER
Release Summary for Short Brother PLC
Permit Number: P0135/06A
Location: 3 Airport Road, Queens Island, Belfast, BT3 9DZ
Emissions Point: Airport Factory Compressor 3 (AFS2)
Date
pH
Suspended
Solids
(mg/l)
Visible Oil &
Grease
Limits
≥6 and ≤9
50
None Visible
January 7.9 10 None
April 6.9 10 None
July 7.4 14 None
October 7.9 3 None
Signed on behalf of the Operator.. Date: 02/01/2020
Code: T34110 Form No. TE 34
Northern Ireland Water is a trademark of Northern Ireland Water Limited, incorporated in Northern Ireland, Registered Number: NI054463, Registered Office: Westland House, Old Westland Road, Belfast, BT14 6TE.
Page 1 of 1
Northern Ireland Water
Environmental Regulation
Westland House
40 Old Westland Road
Belfast
BT14 6TE
Tel: 03457 44 00 88
www.niwater.com
Bombardier Aerospace C04 Main Factory Airport Road Queen's Island Belfast BT3 9DZ
Your Ref:
Our Ref: T34110
Date: 15th January 2020 Dear Mr Conlon, Trade Effluent Compliance A recent compliance assessment has indicated that over the 12 month period, January to
December 2019, your discharge was deemed to be compliant, as 90% of all parameter
results, or above, were within the specified limits of your trade effluent Consent.
Please ensure that your trade effluent discharge is kept within the specified limits
throughout 2020.
If you have any queries or require further information, please do not hesitate to contact me
on 028 90 354 813 extension 20283.
Yours faithfully Naomi Ferres Trade Effluent Officer
Trade Effluent Sample DetailsDate from: 01-Jan-19 Date to: 31-Dec-19
Bombardier Aerospace -ETP C04 Sample Point
Bombardier Aerospace ETP C04
Belfast
BT3 9DZ
Airport Road
Queen's Island
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Ammonia AUDITT34110TES-19-284254206-Feb-2019 100mg/l as N0.41Ammonia AUDITT34110TES-19-284864007-Feb-2019 100mg/l as N0.31Ammonia AUDITT34110TES-19-285996906-Mar-2019 100mg/l as N0.40Ammonia AUDITT34110TES-19-287173704-Apr-2019 100mg/l as N0.47Ammonia AUDITT34110TES-19-289366121-Jun-2019 100mg/l as N0.44Ammonia AUDITT34110TES-19-290687325-Jun-2019 100mg/l as N<0.22Ammonia AUDITT34110TES-19-292082214-Aug-2019 100mg/l as N<0.22Ammonia AUDITT34110TES-19-295354524-Sep-2019 100mg/l as N7.79Ammonia AUDITT34110TES-19-296405417-Oct-2019 100mg/l as N0.45Ammonia AUDITT34110TES-19-298566421-Nov-2019 100mg/l as N<0.22Ammonia AUDITT34110TES-19-299362005-Dec-2019 100mg/l as N0.38
Average mg/l as NParameter Count
111
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Chemical Oxygen Demand Settled AUDITT34110TES-19-284254206-Feb-2019 1000mg/l O235.1Chemical Oxygen Demand Settled AUDITT34110TES-19-284864007-Feb-2019 1000mg/l O235.2Chemical Oxygen Demand Settled AUDITT34110TES-19-285996906-Mar-2019 1000mg/l O245.4Chemical Oxygen Demand Settled AUDITT34110TES-19-287173704-Apr-2019 1000mg/l O270.4Chemical Oxygen Demand Settled AUDITT34110TES-19-289366121-Jun-2019 1000mg/l O2192.0Chemical Oxygen Demand Settled AUDITT34110TES-19-290687325-Jun-2019 1000mg/l O222.8Chemical Oxygen Demand Settled AUDITT34110TES-19-292082214-Aug-2019 1000mg/l O230.0Chemical Oxygen Demand Settled AUDITT34110TES-19-295354524-Sep-2019 1000mg/l O2177.2Chemical Oxygen Demand Settled AUDITT34110TES-19-296405417-Oct-2019 1000mg/l O277.2Chemical Oxygen Demand Settled AUDITT34110TES-19-298566421-Nov-2019 1000mg/l O2139.6Chemical Oxygen Demand Settled AUDITT34110TES-19-299362005-Dec-2019 1000mg/l O240.4
Average mg/l O2Parameter Count
7911
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Hydrogen Ion AUDITT34110TES-19-284254206-Feb-2019 105pH value8.82Hydrogen Ion AUDITT34110TES-19-284864007-Feb-2019 105pH value8.96Hydrogen Ion AUDITT34110TES-19-285996906-Mar-2019 105pH value9.17Hydrogen Ion AUDITT34110TES-19-287173704-Apr-2019 105pH value9.34Hydrogen Ion AUDITT34110TES-19-289366121-Jun-2019 105pH value8.11Hydrogen Ion AUDITT34110TES-19-290687325-Jun-2019 105pH value8.86Hydrogen Ion AUDITT34110TES-19-292082214-Aug-2019 105pH value7.47Hydrogen Ion AUDITT34110TES-19-295354524-Sep-2019 105pH value7.10Hydrogen Ion AUDITT34110TES-19-296405417-Oct-2019 105pH value8.47Hydrogen Ion AUDITT34110TES-19-298566421-Nov-2019 105pH value8.95Hydrogen Ion AUDITT34110TES-19-299362005-Dec-2019 105pH value9.20
Parameter Count 11
Page 1 of 2
All analysis is carried out according to the relevant NI Water inhouse methods
Result values in red bold type have failed their permitted consent conditions
Trade Effluent Sample DetailsDate from: 01-Jan-19 Date to: 31-Dec-19
Bombardier Aerospace -ETP C04 Sample Point
Bombardier Aerospace ETP C04
Belfast
BT3 9DZ
Airport Road
Queen's Island
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Suspended Solids AUDITT34110TES-19-284254206-Feb-2019 400mg/l128.0Suspended Solids AUDITT34110TES-19-284864007-Feb-2019 400mg/l154.0Suspended Solids AUDITT34110TES-19-285996906-Mar-2019 400mg/l149.0Suspended Solids AUDITT34110TES-19-287173704-Apr-2019 400mg/l74.0Suspended Solids AUDITT34110TES-19-289366121-Jun-2019 400mg/l105.0Suspended Solids AUDITT34110TES-19-290687325-Jun-2019 400mg/l62.0Suspended Solids AUDITT34110TES-19-292082214-Aug-2019 400mg/l34.0Suspended Solids AUDITT34110TES-19-295354524-Sep-2019 400mg/l66.0Suspended Solids AUDITT34110TES-19-296405417-Oct-2019 400mg/l203.0Suspended Solids AUDITT34110TES-19-298566421-Nov-2019 400mg/l1208.0Suspended Solids AUDITT34110TES-19-299362005-Dec-2019 400mg/l114.0
Average mg/lParameter Count
20911
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Total Heavy Metals AUDITT34110TES-19-284254206-Feb-2019 10000ug/l<970Total Heavy Metals AUDITT34110TES-19-284864007-Feb-2019 10000ug/l<790Total Heavy Metals AUDITT34110TES-19-285996906-Mar-2019 10000ug/l<780Total Heavy Metals AUDITT34110TES-19-287173704-Apr-2019 10000ug/l<1500Total Heavy Metals AUDITT34110TES-19-289366121-Jun-2019 10000ug/l<680Total Heavy Metals AUDITT34110TES-19-290687325-Jun-2019 10000ug/l<370Total Heavy Metals AUDITT34110TES-19-292082214-Aug-2019 10000ug/l<120Total Heavy Metals AUDITT34110TES-19-295354524-Sep-2019 10000ug/l<1100Total Heavy Metals AUDITT34110TES-19-296405417-Oct-2019 10000ug/l<1200Total Heavy Metals AUDITT34110TES-19-298566421-Nov-2019 10000ug/l<1100Total Heavy Metals AUDITT34110TES-19-299362005-Dec-2019 10000ug/l<1700
Average ug/lParameter Count
011
Reported by: 10-Jan-20
Trade Effluent Officer
Naomi Ferres
Page 2 of 2
All analysis is carried out according to the relevant NI Water inhouse methods
Result values in red bold type have failed their permitted consent conditions
Code: T34109 Form No. TE 34
Northern Ireland Water is a trademark of Northern Ireland Water Limited, incorporated in Northern Ireland, Registered Number: NI054463, Registered Office: Westland House, Old Westland Road, Belfast, BT14 6TE.
Page 1 of 1
Northern Ireland Water
Environmental Regulation
Westland House
40 Old Westland Road
Belfast
BT14 6TE
Tel: 03457 44 00 88
www.niwater.com
Bombardier Aerospace C97 Main Factory Airport Road Queen's Island Belfast BT3 9DZ
Your Ref:
Our Ref: T34109
Date: 15th January 2020 Dear Mr Conlon, Trade Effluent Compliance A recent compliance assessment has indicated that over the 12 month period, January to
December 2019, your discharge was deemed to be compliant, as 90% of all parameter
results, or above, were within the specified limits of your trade effluent Consent.
Please ensure that your trade effluent discharge is kept within the specified limits
throughout 2020.
If you have any queries or require further information, please do not hesitate to contact me
on 028 90 354 813 extension 20283.
Yours faithfully Naomi Ferres Trade Effluent Officer
Trade Effluent Sample DetailsDate from: 01-Jan-19 Date to: 31-Dec-19
Bombardier Aerospace ETP C97 Sample Point
Bombardier Aerospace ETP C97
Belfast
BT3 9DZ
Airport Road,
Queens Island,
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Ammonia AUDITT34109TES-19-284254306-Feb-2019 100mg/l as N<0.22Ammonia AUDITT34109TES-19-284864107-Feb-2019 100mg/l as N<0.22Ammonia AUDITT34109TES-19-285997006-Mar-2019 100mg/l as N<0.22Ammonia AUDITT34109TES-19-287173804-Apr-2019 100mg/l as N<0.22Ammonia AUDITT34109TES-19-289366221-Jun-2019 100mg/l as N2.76Ammonia AUDITT34109TES-19-290687425-Jun-2019 100mg/l as N<0.22Ammonia AUDITT34109TES-19-292083114-Aug-2019 100mg/l as N0.58Ammonia AUDITT34109TES-19-295355224-Sep-2019 100mg/l as N0.57Ammonia AUDITT34109TES-19-296405917-Oct-2019 100mg/l as N2.95Ammonia AUDITT34109TES-19-299363205-Dec-2019 100mg/l as N1.16
Average mg/l as NParameter Count
110
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Chemical Oxygen Demand Settled AUDITT34109TES-19-284254306-Feb-2019 1000mg/l O2144.0Chemical Oxygen Demand Settled AUDITT34109TES-19-284864107-Feb-2019 1000mg/l O2140.0Chemical Oxygen Demand Settled AUDITT34109TES-19-285997006-Mar-2019 1000mg/l O2146.8Chemical Oxygen Demand Settled AUDITT34109TES-19-287173804-Apr-2019 1000mg/l O2146.0Chemical Oxygen Demand Settled AUDITT34109TES-19-289366221-Jun-2019 1000mg/l O271.2Chemical Oxygen Demand Settled AUDITT34109TES-19-290687425-Jun-2019 1000mg/l O2151.2Chemical Oxygen Demand Settled AUDITT34109TES-19-292083114-Aug-2019 1000mg/l O244.8Chemical Oxygen Demand Settled AUDITT34109TES-19-295355224-Sep-2019 1000mg/l O2151.2Chemical Oxygen Demand Settled AUDITT34109TES-19-296405917-Oct-2019 1000mg/l O2120.4Chemical Oxygen Demand Settled AUDITT34109TES-19-299363205-Dec-2019 1000mg/l O290.0
Average mg/l O2Parameter Count
12110
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Hydrogen Ion AUDITT34109TES-19-284254306-Feb-2019 105pH value7.35Hydrogen Ion AUDITT34109TES-19-284864107-Feb-2019 105pH value7.51Hydrogen Ion AUDITT34109TES-19-285997006-Mar-2019 105pH value7.48Hydrogen Ion AUDITT34109TES-19-287173804-Apr-2019 105pH value7.25Hydrogen Ion AUDITT34109TES-19-289366221-Jun-2019 105pH value7.38Hydrogen Ion AUDITT34109TES-19-290687425-Jun-2019 105pH value7.27Hydrogen Ion AUDITT34109TES-19-292083114-Aug-2019 105pH value9.38Hydrogen Ion AUDITT34109TES-19-295355224-Sep-2019 105pH value8.56Hydrogen Ion AUDITT34109TES-19-296405917-Oct-2019 105pH value7.24Hydrogen Ion AUDITT34109TES-19-299363205-Dec-2019 105pH value7.64
Parameter Count 10
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Suspended Solids AUDITT34109TES-19-284254306-Feb-2019 400mg/l33.0Suspended Solids AUDITT34109TES-19-284864107-Feb-2019 400mg/l46.0
Page 1 of 2
All analysis is carried out according to the relevant NI Water inhouse methods
Result values in red bold type have failed their permitted consent conditions
Trade Effluent Sample DetailsDate from: 01-Jan-19 Date to: 31-Dec-19
Bombardier Aerospace ETP C97 Sample Point
Bombardier Aerospace ETP C97
Belfast
BT3 9DZ
Airport Road,
Queens Island,
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Suspended Solids AUDITT34109TES-19-285997006-Mar-2019 400mg/l<13.7Suspended Solids AUDITT34109TES-19-287173804-Apr-2019 400mg/l38.0Suspended Solids AUDITT34109TES-19-289366221-Jun-2019 400mg/l17.0Suspended Solids AUDITT34109TES-19-290687425-Jun-2019 400mg/l18.0Suspended Solids AUDITT34109TES-19-292083114-Aug-2019 400mg/l198.0Suspended Solids AUDITT34109TES-19-295355224-Sep-2019 400mg/l218.0Suspended Solids AUDITT34109TES-19-296405917-Oct-2019 400mg/l107.0Suspended Solids AUDITT34109TES-19-299363205-Dec-2019 400mg/l22.0
Average mg/lParameter Count
7010
Sample Date Sample ID Parameter Reason Code MaxMinUnitsResult
Total Heavy Metals AUDITT34109TES-19-284254306-Feb-2019 10000ug/l<390Total Heavy Metals AUDITT34109TES-19-284864107-Feb-2019 10000ug/l<440Total Heavy Metals AUDITT34109TES-19-285997006-Mar-2019 10000ug/l<84Total Heavy Metals AUDITT34109TES-19-287173804-Apr-2019 10000ug/l<310Total Heavy Metals AUDITT34109TES-19-289366221-Jun-2019 10000ug/l<150Total Heavy Metals AUDITT34109TES-19-290687425-Jun-2019 10000ug/l<100Total Heavy Metals AUDITT34109TES-19-292083114-Aug-2019 10000ug/l<1300Total Heavy Metals AUDITT34109TES-19-295355224-Sep-2019 10000ug/l<1500Total Heavy Metals AUDITT34109TES-19-296405917-Oct-2019 10000ug/l<830Total Heavy Metals AUDITT34109TES-19-299363205-Dec-2019 10000ug/l<560
Average ug/lParameter Count
010
Reported by: 07-Jan-20
Trade Effluent Officer
Naomi Ferres
Page 2 of 2
All analysis is carried out according to the relevant NI Water inhouse methods
Result values in red bold type have failed their permitted consent conditions
Q79/1 V0 Pollution Inventory Reporting
Pollution Inventory reporting form Annual releases to air, controlled waters, land and off-site transfers in wastewater and of waste The Pollution Prevention and Control (Industrial Emissions) Regulations (NI) 2013 Regulation (EC) No 166/2006 concerning the establishment of a European Pollutant Release and Transfer Register (E-PRTR Regulations)
Please read through this form and the guidance notes carefully before you start to fill it in. You can get general and sector-specific guidance on completing this form from www.doeni.gov.uk/niea/pollution-home/pol-emission-reg.htm. To fill in this form you'll need:
• Details of your chemical releases to theenvironment • Details of your chemical transfers inwastewater • Details of your waste transfers• PI reporting guidance• Relevant sector specific guidance note (ifavailable)
We issue this form to enable collection of information from you annually on the quantities of specified substances released to air, waters and land, the quantities of specified substances transferred off-site in wastewater and the quantities of waste transferred off-site.
Once we have collected and processed the release and transfer data, it is made available to the general public through our Public Registers and submitted to the European Pollutant Release and Transfer Register (E-PRTR).
Who is required to complete this form?
You need to complete this form if you operate a PPC process and are regulated by us or if you operate a process listed in Annex 1 of the E-PRTR Regulations.
Completed forms must be submitted to us by 31st January following each reporting year. Please see our website for further information on these requirements.
How to fill in the form? Everyone must fill in part 1. Then fill in the other parts of the form that apply to you. Finally, complete the qualification notes and the declaration on page 16.
Format of the PI form The form consists of eight parts:
• Part 1 - About the operator and site• Part 2 - Releases to air• Part 3 - Releases to land• Part 4 - Releases to waters• Part 5 - Off-site transfers in wastewater• Part 6 - Off-site waste transfers• Part 7 - Waste transfers to other countries• Part 8 - Qualification and declaration
However you send us the information, make sure you keep a copy for your own records.
Q79/1 V0 Pollution Inventory Reporting
How to contact us If you need help filling in the form, please contact the person who sent you it or call our general enquiries number shown below. General enquiries: 02890 569299 (Mon–Fri 8–6) Email: [email protected] Website: www.doeni.gov.uk/niea If you are happy with our service, please tell us. It helps us to identify good practice and encourages our staff. If you’re not happy with our service, please tell us how we can improve it. Please tell us if you need information in a different language or format (for example, in large print) so we can keep in touch with you more easily.
The Data Protection Act 1998 We, the NI Environment Agency, will process the information you provide to create, maintain and publish your Pollution Inventory report, comply with the E-PRTR and so that we can:
• deal with your application;• make sure you keep to the conditions of thelicence, permit or registration; • process renewals; and• keep the public registers up to date.
We may also process or release the information to: • offer you documents or services relating toenvironmental matters; • consult the public, public organisations andother organisations; • carry out research and development work onenvironmental issues; • provide information from the public register toanyone who asks; • prevent anyone from breaking environmentallaw, investigate cases where environmental law may have been broken, and take any action that is needed; • assess whether customers are satisfied withour service, and to improve our service; and • respond to requests for information under theFreedom of Information Act 2000 and the Environmental Information Regulations 2004 (if the Data Protection Act allows).
We may pass the information on to our agents or representatives to do these things for us.
Part 1 About you and your site 1.1 Authorisation, licence or permit number
1.2 Operator’s details Operator’s name - Authorisation, licence or permit holder
Site Name
Site Address
Postcode
1.3 Contact Details Title First Name Last Name Position
Contact numbers, please include area code Phone Fax Mobile Email
1.4 NACE and NOSE-P codes NACE codes refer to main economic activity. NOSE-P codes refer to release sources. See the associated guidance notes for specific codes.
• 4-figure NACE code for the maineconomic activity
• 5-figure NOSE-P code for the mainpolluting process carried out on site
• other relevant NOSE-P codes for otherpolluting processes on the site
2 of 16
P0135/06A
Bombardier
Queens Island
Airport Road,Queens Island,Belfast
BT3 9DZ
Dr
Colette
Eastwood
Environmental Manager
028 90733569
028 90733202
2 5 1 6
1 0 5 1 0
Q79/1 V0 Pollution Inventory Reporting
1.5 Calendar year this report covers
The next five questions ask for information on a voluntary basis.
1.6 How many employees did you have at 31 December of the reporting year?
1.7 How long was your site operational for during the reporting year?
hours 1.8 What was the total annual output from your main economic activity during the reporting year? Product of the main activity
quantity Units used, for example kWh, tonnes:
1.9 What was your annual consumption of the following during the reporting year? Electricity MWh Gas MWh Oil MWh Coal MWh Water cubic metres
1.10 Please give your email and/or web address for enquiries from the public Email
Web
1.11 Confidentiality The form enables you to say whether you consider any (or all) of the information you are providing is confidential.
If you consider some of the information is confidential: • tick the appropriate box below• list any supporting documents submitted in the
appropriate box in the section below• tick the Confidentiality box next to the
appropriate items on the form.
If you claim confidentiality for all the information you give on the form: • you do not need to tick the Confidentiality box
for each release or transfer• tick the appropriate box in the Confidentiality
section below• please ensure your written justification covers
all the information given in the form• list any supporting documents submitted in the
appropriate box in the section below.If you do not enclose a written justification for each item included in the confidentiality claim, we are likely to reject it straight away. We will determine your claim for confidentiality within a period of 28 days from the date of the application or within an agreed longer period.
I am enclosing documents to prove that: • some of the information is confidential: I have
ticked the appropriate boxes on the form• all of the information is confidential
Please list the documents you are including to support your claim. Continue on a separate sheet if you need to.
1.12 How to calculate releases to the environment When you fill in the reporting form: • your total release figure should include
fugitive and notifiable releases. If the totalrelease figure is below the reportingthreshold it should be reported as ‘brt’.
• you must provide a separate figure for anynotifiable releases and transfers if you hold apermit or authorisation which requiresspecific notification to us.
This does not apply to sites operating solely under a waste management licence. • write ‘n/a’ (not applicable) against
substances not released.
3 of 16
2019
27,427
54,607
15,275
133,306
Q79/1 V0 Pollution Inventory Reporting
Part 2 Releases to air * see guidance document for further information on the method names to be reported.** combined threshold Total releases column: n/a = not applicable; brt = below reporting threshold; releases = annual mass of substance Please refer to the guidance notes for more information about:
• method M, C, E (measurement, calculation, estimation)• notifiable releases• detailed method
Metric units allowable are: kt (kilotonnes), t (tonnes), kg (kilogrammes), g (grammes), mg (milligrammes)
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Inorganics 7664-41-7 Ammonia 1,000 1332-21-4 Asbestos 1
124-38-9 Carbon dioxide 10,000,000**
124-38-9 Carbon dioxide from qualifying renewable fuel source (reportable)
630-08-0 Carbon monoxide 100,000 74-90-8 Hydrogen cyanide 100
10024-97-2 Nitrous oxide 10,000 2551-62-4 Sulphur hexafluoride 10
Organics 309-00-2 Aldrin 1 120-12-7 Anthracene 10
71-43-2 Benzene 1,000 50-32-8 Benzo(a)pyrene 1
205-99-2 Benzo(b)fluoranthene 1 207-08-9 Benzo(k)fluoranthene 1 106-99-0 Butadiene (1,3-
Butadiene) 100
56-23-5 Carbon tetrachloride (tetrachloromethane)
10
57-74-9 Chlordane 1 143-50-0 Chlordecone 1
67-66-3 Chloroform (Trichloromethane)
100
50-29-3 Dichlorodiphenyl-trichloroethane (DDT)
1
75-09-2 Dichloromethane (DCM) (Methylene chloride)
1,000
60-57-1 Dieldrin 1 117-81-7 Di(ethylhexyl)-
phthalate (DEHP) 10
72-20-8 Endrin 1 107-06-2 Ethylene dichloride
(1,2-Dichloroethane) 1,000
75-21-8 Ethylene oxide (1,2-Epoxyethane)
1,000
76-44-8 Heptachlor 1 36355-1-8 Hexabromobiphenyl 0.1
118-74-1 Hexachlorobenzene 1 608-73-1 Hexachlorocyclo-
hexane- all isomers 1
4 of 16
t
kg
C
C
C_ETS
C_IPCC
28,348.00
35.40
t
kg
release
brt
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
193-39-5 Indeno (1,2,3-cd)pyrene
1
58-89-9 Lindane 1 74-82-8 Methane 10,000 71-55-6 Methyl chloroform
(1,1,1-trichloroethane)
10
2385-85-5 Mirex 1 91-20-3 Naphthalene 100
608-93-5 Pentachlorobenzene 1 87-86-5 Pentachlorophenol 1 79-34-5 Tetrachloroethane
(1,1,2,2-tetrachloroethane)
10
127-18-4 Tetrachloroethylene 100 8001-35-2 Toxaphene 1
12002-48-1 Trichlorobenzene - all isomers
1
79-01-6 Trichloroethylene 1,000 75-01-4 Vinyl chloride 1,000
Metals and compounds reported as mass of metal 7440-38-2 Arsenic 1 7440-43-9 Cadmium 1 7440-47-3 Chromium 10 7440-50-8 Copper 10 7439-92-1 Lead 100 7439-97-6 Mercury 1 7440-02-0 Nickel 10 7782-49-2 Selenium 100 7440-66-6 Zinc 100
Other substance groups reported as total mass unless otherwise stated Chlorine & inorganic compounds- as HCl 10,000 Chlorofluorocarbons (CFCs) 1 Dioxins & furans (PCDDs/PCDFs) - as I-TEQ
0.00001
Dioxins & furans (PCDDs/PCDFs) - as WHO-TEQ
0.00001
Fluorine & inorganic compounds - as HF 1,000 Halons 1 Hydrochlorofluorocarbons (HCFCs) 1 Hydrofluorocarbons (HFCs) 100 Nitrogen oxides - NO & NO2 as NO2 100,000 Non-methane volatile organic compounds (NMVOCs)
10,000
Particulate matter - PM2.5 1,000 Particulate matter - PM10 1,000 Particulate matter - total 10,000 Perfluorocarbons (PFCs) 10 Polychlorinated biphenyls (PCBs) 0.1 Polychlorinated biphenyls as WHO-TEQ 0.00001 Polycyclic aromatic hydrocarbons (PAHs)
5
Sulphur oxides - SO2 & SO3 as SO2 100,000
5 of 16
100,000 Sulphur dioxide
kg
kg
kg
kg
kg
kg
kg
kg
C
C
C
C
C
C
C
C
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
62.49
287.63
3.96
1.05
5.68
66.77
287.63
2,625.45
kg
kg
kg
kg
kg
kg
kg
kg
releases
brt
brt
brt
brt
brt
brt
brt
Q79/1 V0 Pollution Inventory Reporting
Part 3 Releases to land * see guidance document for further information on the method names to be reported.** combined threshold Total releases column: n/a = not applicable; brt = below reporting threshold; releases = annual mass of substance Please refer to the guidance notes for more information about:
• method M, C, E (measurement, calculation, estimation)• notifiable releases• detailed method
Metric units allowable are: kt (kilotonnes), t (tonnes), kg (kilogrammes), g (grammes), mg (milligrammes)
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Inorganics 1332-21-4 Asbestos 1
Organics 15972-60-8 Alachlor 1
309-00-2 Aldrin 1 120-12-7 Anthracene 1
1912-24-9 Atrazine 1 71-43-2 Benzene 200** 50-32-8 Benzo(a)pyrene 1
205-99-2 Benzo(b)fluoranthene 1 207-08-9 Benzo(k)fluoranthene 1
57-74-9 Chlordane 1 143-50-0 Chlordecone 1 470-90-6 Chlorfenvinphos 1
2921-88-2 Chlorpyrifos 1 50-29-3 Dichlorodiphenyl-
trichloroethane (DDT) 1
75-09-2 Dichloromethane (DCM) (Methylene chloride)
10
60-57-1 Dieldrin 1 117-81-7 Di(ethylhexyl)-
phthalate (DEHP) 1
330-54-1 Diuron 1 115-29-7 Endosuflan 1
72-20-8 Endrin 1 100-41-4 Ethyl benzene 200** 107-06-2 Ethylene dichloride
(1,2-Dichloroethane) 10
75-21-8 Ethylene oxide (1,2-Epoxyethane)
10
76-44-8 Heptachlor 1 36355-1-8 Hexabromobiphenyl 0.1
118-74-1 Hexachlorobenzene 1 87-68-3 Hexachlorobutadiene 1
608-73-1 Hexachlorocyclo-hexane- all isomers
1
193-39-5 Indeno (1,2,3-cd)pyrene
1
34123-59-6 Isoproturon 1 58-89-9 Lindane 1
2385-85-5 Mirex 1
6 of 16
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
91-20-3 Naphthalene 10 608-93-5 Pentachlorobenzene 1
87-86-5 Pentachlorophenol 1 122-34-9 Simazine 1 108-88-3 Toluene 200**
8001-35-2 Toxaphene 1 1582-09-8 Triflualin 1
75-01-4 Vinyl chloride 10 1330-20-7 Xylene - all isomers 200**
Metals and compounds reported as mass of metal 7440-38-2 Arsenic 5 7440-43-9 Cadmium 5 7440-47-3 Chromium 50 7440-50-8 Copper 50 7439-92-1 Lead 20 7439-97-6 Mercury 1 7440-02-0 Nickel 20 7440-66-6 Zinc 100
Other substance groups reported as total mass unless otherwise stated Brominated diphenylethers - penta, octa & deca
1
Chlorides - as Cl 2,000,000 Cyanides - as CN 50 Dioxins & furans (PCDDs/PCDFs) - as I-TEQ
0.0001
Dioxins & furans (PCDDs/PCDFs) - as WHO-TEQ
0.0001
Fluorides - as F 2,000 Halogenated organic compounds - as AOX
1,000
Nitrogen 50,000 Nonylphenol & nonylphenol ethoxylates
1
Organotin compounds - as SN 50 Phenols - phenol & simple substituted - as C
20
Phosphorus 5,000 Polycyclic aromatic hydrocarbons (PAHs)
5
Polychlorinated biphenyls (PCBs) 1 Polychlorinated biphenyls (PCBs) as WHO-TEQ
0.0001
Short chain (C10-C13) chlorinated paraffins (SCCPs)
1
Tributyltin & compounds - as TBT 1 Triphenyltin & compounds - as TPT 1
7 of 16
Q79/1 V0 Pollution Inventory Reporting
Part 4 Releases to waters * see guidance document for further information on the method names to be reported.** combined threshold TBA = to be advised Total releases column: n/a = not applicable; brt = below reporting threshold; releases = annual mass of substance Please refer to the guidance notes for more information about:
• method M, C, E (measurement, calculation, estimation)• notifiable releases• detailed method
Metric units allowable are: kt (kilotonnes), t (tonnes), kg (kilogrammes), g (grammes), mg (milligrammes)
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Inorganics 1332-21-4 Asbestos 0.1
Organics 74070-46-5 Aclonifen TBC 15792-60-8 Alachlor 0.1
309-00-2 Aldrin 0.0005 120-12-7 Anthracene 0.1
1912-24-9 Atrazine 0.05 71-43-2 Benzene 10 50-32-8 Benzo(a)pyrene 1
205-99-2 Benzo(b)fluoranthene 1 191-24-2 Benzo(g,h,i)perylene 0.1 207-08-9 Benzo(k)fluoranthene 1
42576-02-3 Bifenox TBA 56-23-5 Carbon tetrachloride
(tetrachloromethane) 1
57-74-9 Chlordane 0.1 143-50-0 Chlordecone 0.1 470-90-6 Chlorfenvinphos 0.1
67-66-3 Chloroform (Trichloromethane)
5
2921-88-2 Chlorpyrifos 0.1 28159-98-0 Cybutryne TBA 52315-07-8 Cypermethrin 0.005
50-29-3 Dichlorodiphenyl-trichloroethane (DDT)
0.0005
75-09-2 Dichloromethane (DCM) (Methylene chloride)
10
62-73-7 Dichlorvos 0.0005 15307-86-5 Diclofenac TBA
115-32-2 Dicofol TBA 60-57-1 Dieldrin 0.0005
117-81-7 Di(2-ethylhexyl)-phthalate (DEHP)
0.1
330-54-1 Diuron 0.05 115-29-7 Endosuflan 0.0005
72-20-8 Endrin 0.0005 50-28-2 17-beta-estradiol (E2) TBA
8 of 16
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
57-63-6 17-alpha-ethinylestradiol (EE2)
TBA
100-41-4 Ethyl benzene 10 107-06-2 Ethylene dichloride
(1,2-Dichloroethane) 10
75-21-8 Ethylene oxide (1,2-Epoxyethane)
1
206-44-0 Fluoranthene 0.1 76-44-8 Heptachlor (&
heptachlor epoxide) 0.1
36355-1-8 Hexabromobiphenyl 0.1 25637-99-4 Hexabromocyclo-
dodecane 0.1
118-74-1 Hexachlorobenzene 0.01 87-68-3 Hexachlorobutadiene 0.1
608-73-1 Hexachlorocyclo-hexane- all isomers
0.01
465-73-6 Isodrin 0.0005 34123-59-6 Isoproturon 0.01
58-89-9 Lindane 0.1 2385-85-5 Mirex 0.1
91-20-3 Naphthalene 10 608-93-5 Pentachlorobenzene 0.1
87-86-5 Pentachlorophenol 0.05 1763-23-1 Perfluorooctane
sulphonic acid & its derivatives (PFOS)
0.1
124495-18-7
Quinoxyfen TBA
122-34-9 Simazine 1 127-18-4 Tetrachloroethylene 1 886-50-0 Terbutryn TBA 108-88-3 Toluene 10
8001-35-2 Toxaphene 0.1 12002-48-1 Trichlorobenzene - all
isomers 0.01
79-01-6 Trichloroethylene 1 1582-09-8 Triflualin 0.001
75-01-4 Vinyl chloride 1 1330-20-7 Xylene - all isomers 10
Metals and compounds reported as mass of metal 7440-38-2 Arsenic 5 7440-43-9 Cadmium 1 7440-47-3 Chromium 20 7440-50-8 Copper 20 7439-89-6 Iron 1,000 7439-92-1 Lead 20 7439-97-6 Mercury 0.1 7440-02-0 Nickel 20 7440-66-6 Zinc 100
9 of 16
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Other substance groups reported as total mass unless otherwise stated Brominated diphenylethers - tetra-, penta-, hexa-, hepta-, octa- and deca-BDE
0.1
Chlorides - as Cl 2,000,000 Cyanides - as CN 50 Dioxins & furans (PCDDs/PCDFs) - as I-TEQ
0.0001
Dioxins & furans (PCDDs/PCDFs) - as WHO-TEQ
0.0001
Fluorides - as F 2,000 Halogenated organic compounds - as AOX
1,000
Nitrogen 50,000 Nonylphenol & nonylphenol ethoxylates
1
Octylphenol & octylphenol ethoxylates
1
Organotin compounds - as SN 5 Phenols - phenol & simple substituted - as C
20
Phosphorus 5,000 Polycyclic aromatic hydrocarbons (PAHs)
5
Polychlorinated biphenyls (PCBs) 0.001 Polychlorinated biphenyls as WHO-TEQ
0.0001
Short chain (C10-C13) chlorinated paraffins (SCCPs)
0.1
Total organic carbon (TOC) 50,000 Tributyltin & compounds - as TBT 0.005 Triphenyltin & compounds - as TPT 0.1
10 of 16
Q79/1 V0 Pollution Inventory Reporting
Part 5 Off-site transfers in waste water * see guidance document for further information on the method names to be reported.TBA = to be advised Total releases column: n/a = not applicable; brt = below reporting threshold; releases = annual mass of substance Please refer to the guidance notes for more information about:
• method M, C, E (measurement, calculation, estimation)• notifiable releases• detailed method
Metric units allowable are: kt (kilotonnes), t (tonnes), kg (kilogrammes), g (grammes), mg (milligrammes)
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Inorganics 1332-21-4 Asbestos 0.1
Organics 74070-46-5 Aclonifen TBA 15972-60-8 Alachlor 0.1
309-00-2 Aldrin 0.0005 120-12-7 Anthracene 0.1
1912-24-9 Atrazine 0.05 71-43-2 Benzene 10 50-32-8 Benzo(a)pyrene 1
205-99-2 Benzo(b)fluoranthene 1 191-24-2 Benzo(g,h,i)perylene 0.1 207-08-9 Benzo(k)fluoranthene 1
42576-02-3 Bifenox TBA 56-23-5 Carbon tetrachloride
(tetrachloromethane) 1
57-74-9 Chlordane 0.1 143-50-0 Chlordecone 0.1 470-90-6 Chlorfenvinphos 0.1
67-66-3 Chloroform (Trichloromethane)
5
2921-88-2 Chlorpyrifos 0.1 28159-98-0 Cybutryne TBA 52315-07-8 Cypermethrin 0.005
50-29-3 Dichlorodiphenyl-trichloroethane (DDT)
0.0005
75-09-2 Dichloromethane (DCM) (Methylene chloride)
10
62-73-7 Dichlorvos TBA 15307-86-5 Diclofenac TBA
115-32-2 Dicofol TBA 60-57-1 Dieldrin 0.0005
117-81-7 Di(ethylhexyl)-phthalate (DEHP)
0.1
330-54-1 Diuron 0.05 115-29-7 Endosuflan 0.0005
72-20-8 Endrin 0.0005 50-28-2 17-beta-estradiol (E2) TBA
11 of 16
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
57-63-6 17-alpha-ethinylestradiol (EE2)
TBA
100-41-4 Ethyl benzene 10 107-06-2 Ethylene dichloride
(1,2-Dichloroethane) 10
75-21-8 Ethylene oxide (1,2-Epoxyethane)
1
206-44-0 Fluoranthene 0.1 76-44-8 Heptachlor (&
heptachlor epoxide) 0.1
36355-1-8 Hexabromobiphenyl 0.1 25637-99-4 Hexabromocyclo-
dodecane 0.1
118-74-1 Hexachlorobenzene 0.01 87-68-3 Hexachlorobutadiene 0.1
608-73-1 Hexachlorocyclo-hexane- all isomers
0.01
465-73-6 Isodrin 0.0005 34123-59-6 Isoproturon 0.01
58-89-9 Lindane 0.1 2385-85-5 Mirex 0.1
91-20-3 Naphthalene 10 608-93-5 Pentachlorobenzene 0.1
87-86-5 Pentachlorophenol 0.05 1763-23-1 Perfluorooctane
sulphonic acid & its derivatives (PFOS)
0.1
124495-18-7
Quinoxyfen TBA
122-34-9 Simazine 1 127-18-4 Tetrachloroethylene 1 886-50-0 Terbutryn TBA 108-88-3 Toluene 10
8001-35-2 Toxaphene 0.1 12002-48-1 Trichlorobenzene - all
isomers 0.01
79-01-6 Trichloroethylene 1 1582-09-8 Triflualin 0.001
75-01-4 Vinyl chloride 1 1330-20-7 Xylene - all isomers 10
Metals and compounds reported as mass of metal 7440-38-2 Arsenic 5 7440-43-9 Cadmium 1 7440-47-3 Chromium 20 7440-50-8 Copper 20 7439-89-6 Iron 1,000 7439-92-1 Lead 20 7439-97-6 Mercury 0.1 7440-02-0 Nickel 20 7440-66-6 Zinc 100
12 of 16
kg
kg
kg
kg
kg
kg
C
C
C
C
C
C
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
C_IPCC
0.0
0.27
14.72
1.32
0.21
0.64
kg
kg
kg
kg
kg
kg
brt
brt
brt
brt
brt
brt
Q79/1 V0 Pollution Inventory Reporting
CAS no. Substance Reporting thresholds
in kg
Total releases (including notifiable releases) Notifiable releases Confidential? Justification must be provided
Common Name (Alternative Name)
n/a, brt or releases
Metric Unit
Method M, C or E
Detailed method*
Releases only
Metric Unit
Other substance groups reported as total mass unless otherwise stated Brominated diphenylethers - tetra-, penta-, hexa-, hepta-, octa- and deca-BDE
0.1
Chlorides - as Cl 2,000,000 Cyanides - as CN 50 Dioxins & furans (PCDDs/PCDFs) - as I-TEQ
0.0001
Dioxins & furans (PCDDs/PCDFs) - as WHO-TEQ
0.0001
Fluorides - as F 2,000 Halogenated organic compounds - as AOX
1,000
Nitrogen 50,000 Nonylphenol & nonylphenol ethoxylates
1
Octylphenol & octylphenol ethoxylates
1
Organotin compounds - as SN 5 Phenols - phenol & simple substituted - as C
20
Phosphorus 5,000 Polycyclic aromatic hydrocarbons (PAHs)
5
Polychlorinated biphenyls (PCBs) 0.001 Polychlorinated biphenyls (PCBs) as WHO-TEQ
0.0001
Short chain (C10-C13) chlorinated paraffins (SCCPs)
0.1
Total organic carbon (TOC) 50,000 Tributyltin & compounds - as TBT 0.005 Triphenyltin & compounds - as TPT 0.1
13 of 16
Q79/1 V0 Pollution Inventory Reporting
Part 6 Off-site waste transfers *see guidance document for further information on the method names to be reported.For the calendar year, report the total annual tonnage of hazardous or other waste transferred off-site in the appropriate table cell.
Reporting thresholds The total of all hazardous waste transfers should be reported regardless of tonnage. For other waste, an annual reporting threshold of 5 tonnes applies. If the tonnage is below this threshold, insert “brt” in the cell. Hazardous wastes are identified in the EWC by an asterisk against the code number. Liquid transfers to a wastewater treatment works should be reported as substance specific releases to wastewater.
Waste Type Tonnes Method Detailed method* Confidential Justification must be provided.
M, C or E
Hazardous waste disposed (00 00 01)
Hazardous waste recovered (00 00 02)
Other waste disposed (Non-hazardous 00 00 03)
Other waste recovered (Non-hazardous 00 00 04)
14 of 16
39.36130.64
444.42
1223.77
MM
M
M
M_WEIGHM_WEIGH
M_WEIGH
M_WEIGH
Q33/10 V7 Pollution Inventory Reporting
Part 7 Hazardous Waste Transfers to other countries For the calendar year
7.1 Report any transfers of hazardous waste for disposal or recovery to outside the UK. There is no reporting threshold.
Quantity tonnes
Operation disposal recovery Method weighing calculation estimation
Name of recoverer/disposer
Company address of recoverer/disposer
Country Address of actual recovery/disposal site receiving the waste transfer
Country
7.2 Give details of further transfers to other countries Quantity
tonnes Operation disposal recovery Method weighing calculation estimation
Name of recoverer/disposer
Company address of recoverer/disposer
Country
Address of actual recovery/disposal site receiving the waste transfer
Country
Continue on a separate sheet if you need to.
15 of 16
Q79/1 V0 Pollution Inventory Reporting
Part 8 Qualification and declaration
8.1 Qualification notes
Please advise why releases and transfers have changed from previous years. Continue on a separate sheet if you need to.
8.2 Declaration If you deliberately make a statement that is false or misleading, you may be liable to prosecution. I declare that as far as I know, the information on this form is true. Tick this box to confirm that you understand and agree with the declaration above.
Name Title First Name Last Name Position
Today’s date (DD/MM/YY)
8.3 What happens next Send the filled in form and any other documents to the NI Environment Agency’s office. Remember to keep a copy for your records.
16 of 16
Electricity -3%Gas -4%Oil -80%Water -18%
Haz Waste Disposed -12%Haz Waste Recovered -10%Other waste disposed (non-haz) +15%Other waste recovered (non-haz) +3%
Dr
Colette
Eastwood
Environmental Manager
31/01/20