Embed Size (px)
Citation preview
ANALISE BIODIESEL – (Diego)
Figura 1: Cromatograma.6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
1.1
1.2
1.3
(x10,000,000)TIC
1 2
3
4 5
67
8
9
Peak
Ret. time
Start time
End time
Area %
Name
1 6.13 6.07 6.20 0.39 Tetradecanoic acid, metil ester
2 9.08 8.97 9.20 0.69 9-hexadecenoic acid, metil ester
3 9.50 9.32 9.55 15.97 Hexadecanoic acid, metil ester
4 11.04 10.95 11.17 0.50 10,13-eicosadienoic acid, metil ester
5 11.54 11.45 11.66 0.48 Heptadecanoic acid, metil ester
6 14.06 13.36 14.12 63.31 8,11-octadecadeinoic acid, metil ester
7 14.21 14.13 14.32 14.97 7-octadecenoic acid, metil ester
8 14.38 14.32 14.45 0.54 9,12,15-octadecatrienoic acid, metil ester
9 14.60 14.47 14.66 3.15 Octadecanoic acid, metil ester
Tabela 1: Identificação dos picos do cromatograma.
Figura 2: Fragmentograma do pico 1.
Figura 3: Fragmentograma do pico 2.
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 2400.0
25.0
50.0
75.0
100.0
%
74
87
1435543199101 12997 157 185 211111 17132 242
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 2400.0
25.0
50.0
75.0
100.0
%
55
69
837497
41
110
123152
137236194135
32 165 207179 218
Figura 4: Fragmentograma do pico 3.
Figura 5: Fragmentograma do pico 4.
50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.00.0
25.0
50.0
75.0
100.0
%
74
87
1434355 227
129101 185171 199 239 270157115 213125 27231 255
30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 2500.0
25.0
50.0
75.0
100.0
%
815567
96
41
110111 123
135152 166 25032 208
206
Figura 6: Fragmentograma do pico 5.
Figura 7: Fragmentograma do pico 6.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.00.0
25.0
50.0
75.0
100.0
%
74
87
14343 55101 129 241185 199
111 157 171 25532 227213 284
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
6781
55 95
41
109
123150
262164178 294220191 205 235 24531
Figura 8: Fragmentograma do pico 7.
Figura 9: Fragmentograma do pico 8.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
55
6941
8397
111264123
222138 180166 235207193 29624631 278
50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.00.0
25.0
50.0
75.0
100.0
%
79
67
95
55
41108
121135
149
173163 191 236 264222180
Figura 10: Fragmentograma do pico 9.
25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 225.0 250.0 275.0 300.00.0
25.0
50.0
75.0
100.0
%
74
87
143
4325555 199129101 185157 298241111 267171 22731
