Amet,Tm Sample Eu Ghs Clp Sds

7/31/2019 Amet,Tm Sample Eu Ghs Clp Sds

1/21

SAMPLE EU SAFETY DATA SHEET_ENaccording to Regulation (EC) No 1907/2006 (REACH)

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 21Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/ 03/2012

1.1 Identification of the substance or mixture1.1.1 Mixture name : Fendell Cleaning Solvent Blend No. 31.1.2 Product/SDS Code : FCSB No. 31.1.3 Product description : Mixture of solvents.

1.2 Uses of the mixture and uses advised against1.2.1 Uses of the mixture : Flushing of proprietary filling equipments.1.2.2 Uses advised against : For industrial use only. Not for home use.

1.3 Company Identification1.3.1 Manufacturer/Supplier : Sao Boso Chemical Company, Ltd.1.3.2 Contact information

Street address : Fendell Industrial Park3729 Bensonville Hwy, # A-1Any town, Our State, 12345-6789U.S.A

Telephone number : 1-(877)-ABC-EFGHTelefax number : 1-(877)-ABC-EFKL

1.3.3 E-mail of contact person : [email protected]

1.4 Emergency telephone number (s) : CHEMTREC: 1-800-424-9300 (USA)Poison Control Center: 1-800-222-1222 (USA)National Response Center: 1-800-424-8802 (USA)

1.4.1 Further information obtainable from : Product StewardMonday to Friday: 6 am - 6 pm (Pacific Time)

2.1 Classification of the substance or mixtureProduct definition : Mixture.

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]

Flammable liquids, Category 2, H225Acute toxicity (dermal), Category 4, H312Acute toxicity (inhalation), Category 4, H332Acute toxicity (oral), Category 4, H302Aspiration hazard, Category 1, H304Skin corrosion/irritation, Category 2, H315Serious eye damage/Eye irritation, Category 1, H318

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

2. HAZARDS IDENTIFICATION


2/21

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 2 of 21Product Code: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

Reproductive toxicity D, Category 2, H361dSpecific Target Organ Toxicity Single exposure:Respiratory tract irritation, Category 3, H335Specific Target Organ Toxicity Single exposure:

Narcotic effects, Category 3, H336Specific Target Organ Toxicity Repeated exposure, Category 2, H373

2.1.2 Classification of the mixture according to European Directives 1999/45/EC or 67/548/EEC

Highly flammable liquid and vapour. Irritating to eyes and respiratory tract.Harmful by inhalation, in contact with skin and if swallowed.

Risk Phrases: (R-) 10, 11, 20/21, 22, 36, 37/38, 38, 41, 48/20, 63, 65, 66, 67

Safety Phrases: (S-) 2, 7, 7/9, 9, 13, 16, 24/25, 25, 26, 36/37, 37/39, 46, 62

Hazard symbol(s)F : Flammable.Xi : Irritant.Xn : Harmful.

2.1.3 Additional Information

See section 16.

2.2 Label elements2.2.1 Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]

Product identifier: Mixture

Hazard components for labeling: 3-Butanone, n-Butanol, Toluene, Xylene

Hazard Pictograms

Signal word: Danger

Hazard statement(s)

H225 : Highly flammable liquid and vapour.H302 : Harmful if swallowed.H304 : May be fatal if swallowed and enters airways.H312 : Harmful in contact with skin.H315 : Causes skin irritation.H318 : Cause serious eye damage.


3/21

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 3 of 21Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

H332 : Harmful if inhaled.H335 : May cause respiratory irritation.H336 : May cause drowsiness or dizziness.H361d : Suspected of damaging the unborn child.

H373 : May cause damage to organ(s) through prolonged or repeatedexposure

Precautionary statement(s)P210 : Keep away from heat/sparks/open flames/hot surfaces No

smoking.P233 : Keep container tightly closed.P261 : Avoid breathing dust/fume/gas/mist/vapours/spray.P264 : Wash hands with soap and plenty of water after handling.P280 : Wear protective gloves/protective clothing/eye protection/face

protection.P310 : Immediately call a POISON CENTER or doctor/physician.

P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.P501 : Dispose of contents/container to be in accordance with

local/regional/national regulations.2.3 Other hazards

Substance meets the criteria : No.for PBT according toRegulation (EC) No 1207/2006, : P: Not available. B: Not available. T: No.Annex XIII

Substance meets the criteria : Not available.forvPvB according to

Regulation (EC) No 1207/2006,Annex XIII

Other hazards which do not : Repeated exposure may cause skin dryness or cracking.result in classification

This product is classified as dangerous according to Directive 1999/45/EC and its amendments.

3.1 Description of the substance/mixture : Mixture of solvents.

3. COMPOSITION/INFORMATION ON INGREDIENTS


4/21


Hazardous ingredients

Chemical/

SubstanceName

CAS

No.

EC No. Index No. RRN* Weight

(%)

Classification

67/548/EEC Regulation (EC)

No. 1272/2008[CLP]

Type

3-Butanone 78-93-3 201-159-0 606-002-00-3 - 40 60 F; R11Xi; R36-66-67

Flam. Liq. 2,H225Eye irrit. 2,H319STOT SE 3,H336EUH066

[1]

[2]

n-Butanol 71-36-3 200-751-6

603-004-00-6

- 30 60 R10Xn; R22Xi; R37/38,R41, R67

Flam. Liq. 3,H226Acute Tox. 4*H302STOT SE 3H335Skin Irrit. 2H315Eye Dam. 1H318STOT SE 3H336

[1]

[2]

Ethanol 64-17-5 200-578-

6

603-002-00-

5

- 10 40 F; R11 Flam. Liq. 2

H225

[2]

Isopropanol 67-63-0 200-661-7 603-117-00-0 - 10 20 F, R11Xi; R36, R67

Flam. Liq. 2H225Eye Irrit. 2H319STOT SE 3H336

[1]

[2]

Toluene 108-88-3 203-625-9 601-021-00-3 - 1 5 F; R11Repr. Cat. 3R63

Xn; R48/20,R65Xi; R38, R67

Flam. Liq. 2H225Repr. 2

H361d***Asp. Tox. 1H304STOT RE 2H373**

Skin Irrit. 2H315STOT SE 3H336

[1]

[2]

Table continued on next page.


5/21


Chemical/Substance

Name

CAS No. EC No. Index No. RRN* Weight (%)

Classification

67/548/EEC Regulation (EC)No. 1272/2008[

CLP]

Type

Xylene 1330-20-7 215-535-7 601-022-00-9 - 1 5 R10Xi; R38

See Section 16

for the fulltext of the R-

phrases

declared

above.

Flam. Liq. 3H226Acute Tox. 4*

H332Acute Tox. 4*

H312Skin Irrit. 2H315

See Section 2

for the fulltext of the H-

statements

declared

above.

[1]

[2]

*RRN: REACH Registration Number.

3.2 Additional information

[1] Substance classified with a health or environmental hazard

[2] Substance with a workplace exposure limit[3] Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII[4] Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

4.1 Description of first aid measures

4.1.1 General information : General first aid measures should be followed. In case of

persistent adverse effects, seek immediate medical attention.Remove contaminated clothing and shoes promptly, and washthoroughly before re-use.

4.1.2 Following inhalation : NOTE: Reports have associated repeated and prolongedoccupational overexposure to solvents with permanent brainand nervous system damage. Intentional misuse by deliberatelyconcentrating and inhaling the contents may be harmful or fatal.

: Emergency responders should use positive air suppliedrespiratory protection when removing the victim from area.

4. FIRST AID MEASURES


6/21

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 6 of 21Product No: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

Remove person to fresh air. If not breathing, administer CPRuntil help arrives, or the victim starts to breathe on their own.Give artificial respiration if breathing has stopped. Seek medicalattention immediately.

4.1.3 Following skin contact : If exposure occurs, immediately flush the affected areathoroughly with water for at least 15 minutes. Use soap ifavailable. Remove contaminated clothing, including shoes, afterflushing has begun. Wash clothing before re-use. If irritationpersists, seek medical attention.

4.1.4 Following eye contact : Immediately flush affected eye with water for at least 20minutes. ilt the head to prevent chemical from transferring tothe unaffected eye. Seek medical attention without delay afterflushing.

4.1.5 Following ingestion : DO NOT INDUCE VOMITING if swallowed. Rinse mouth outwith water. Dilute with milk or water. Never give anything todrink if the victim is unconscious or having convulsions. Seekmedical attention immediately. Contact Poison Control Center atonce.

4.1.6 Self protection of the first aider : Appropriate personal protective attire should be worn.

4.1.7 Note to the doctor : Suitable medical intervention should be provided based onsymptoms.

4.2 Most important symptoms and : Irritating to eyes, skin, and respiratory tract upon exposure. Higheffects, both acute and delayed vapour concentrations are irritating to eyes, nose, throat, and

lungs; may cause unconsciousness or other signs of centralnervous system depression. Frequent or prolonged skin contactmay irritate the skin and cause skin rash (dermatitis). May causeskin sensitization, an allergic reaction which becomes evident onre-exposure to this material. Small amounts of this liquid may bedrawn into the lungs by either swallowing or vomiting. This maycause severe and delayed health effects such as inflammation ofthe lungs (pulmonary edema) and infection of the bronchi

(bronchopneumonia). Ingestion may cause irritation of digestivetrack and diarrhea.

4.3 Indication of any immediate : Always get immediate medical attention/advice when symptomsmedical attention and special persist.treatment needed

5. FIRE FIGHTING MEASURES


7/21


Fire Fighting Measures : The following applies to 3-ButanoneFLASHPOINT: 26oFSPECIFC GRAVITY: 0.806 @ 68o FEXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%.

AUTOIGNITION TEMPERATURE: 961.0oF.

5.1 Extinguishing media

Suitable extinguishing media : Either allow fire to burn out under controlled conditions, orextinguish with alcohol type or all purpose type foam, or drychemical powder. Try to cover liquid spills with appropriatefoam. Use water spray to cool fire exposed surfaces. Avoidspraying water directly into storage containers due to danger ofboilover. Shut off fuel to fire if possible to do so without hazard.If a spill has not ignited, use water spray to disperse the vapours.

Unsuitable extinguishing media : Do not use high volume water jet.

5.2 Special hazards arising from : Flammable liquid; may release vapours that form flammablethe mixture mixtures when temperatures are at or above the flash point.

There is a danger of explosion when container is heated or infire. Toxic gases will form upon combustion. Vapour maymay accumulate in low or confined areas or travel to aconsiderable distance to a source of ignition and flash back.Avoid runoff into storm sewers and ditches.

Hazardous combustion products : Smoke, fumes, oxides of carbon, irritating or toxic vapours orgases.

5.3 Advice for fire-fighters

Protective equipment for : Respiratory and eye protection gear is required for firefire fighters fighting personnel. Full protective equipment (Bunker Gear)

and a self-contained breathing apparatus (SCBA) should beused for all indoor fires and any significant outdoor fires. Useportable fire extinguisher for small outdoor fires. Use of SCBAmay not be required.

5.4 Additional information : Exposure to decomposition products may cause healthhazards. Cool containers exposed to fire with water spray.Move unexposed containers from fire area if this can be donewithout risk.

6.1 Personal precautions, protective equipment and emergency procedures6.1.1 For non-emergency personnel :

6. ACCIDENTAL RELEASE MEASURES


8/21


Protective equipment : Wear suitable personal protective equipment (e.g. clothing,gloves, safety goggles, and mask/respirator). Ensure adequateventilation; remove all sources of ignition. Notify theappropriate authorities immediately.

Emergency procedures : Eliminate ignition source. Shut off leak if safe to do so. Takeall additional action necessary to prevent and remedy theadverse effects of the spill. Isolate hazard area and deny entryto unauthorized or unprotected personnel. Contain spilled liquidwith sand or earth. DO NOT use combustible materials such assaw dust. Absorb spill with an inert material (e.g., sand or earth).Then place in a chemical waste container.

6.1.2 For emergency responders : Respiratory and eye protection gear is required for emergencypersonal protective equipment responders. Full protective equipment (Bunker Gear) and a

self-contained breathing apparatus (SCBA) should be used forall indoor fires and any significant outdoor fires. Use portablefire extinguisher for small outdoor fires. Use of SCBA may notbe required.

6.2 Environmental precautions : Avoid dispersal of spilt material and runoff into soil, stormsewers and ditches which lead to natural waterways, or theimmediate environment. Inform the relevant authorities if theproduct has entered into the environment.

6.2 Methods of containment and cleaning up6.3.1 On water : If spill in water, remove from water surface by skimming

or with suitable absorbent material and place in appropriatedisposal container. If allowed by local environmentalregulatory agencies, you may use a suitable dispersant.

6.3.2 On ground/floor : Contain spill and absorb with an inert material (e.g., dry sand orearth). Then place in an appropriate waste container for disposalaccording to local regulations. Large spills should be disposed ofvia a licensed waste disposal establishment/contractor.

6.3.3 Other information : Contaminated absorbent material may pose similar hazard as thespill product.6.4 Reference to other sections

See Section 1 for emergency contact information.See Section 8 for information on appropriate personnel protective equipment.See Section 13 for additional disposal information.

7.1 Precautions for safe handling

7. HANDLING AND STORAGE


9/21


7.1.1 Protective measures : Wear appropriate personal protective equipment. Do not get ineyes, on skin, or on clothing. Do not breathe vapour or mist.Do not eat, drink, or smoke when using this product. Use onlywith adequate ventilation. Keep away from sources of ignition.

Keep only in original container. Keep tightly closed when notin use. Do not reuse container. Avoid release to the environ-ment.

7.1.2 Advice on general occupational : Avoid eating, drinking and smoking in areas where this producthygiene is handled, used and stored. Wash hands before eating, drinking

and smoking, and at the end of the working period. Contamina-ted work clothing and protective equipment should not bebrought into eating, smoking and drinking areas. Wash soiledclothing before re-using.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and : Store at ambient/room temperature. Protect from extreme coldstorage conditions and heat. Store in a segregated and approved area. Store away

from strong oxidizing agents. Loosen closure cautiously withnon-sparking tools before opening. Keep only in original con-tainer. Store and use away from sparks, heat, open flames andother ignition sources. Ground and bond containers and recei-ving equipment. Store locked up. Store away from direct sun-light in a dry, cool and well-ventilated area. Containers thathave been opened must be carefully resealed and kept upright

to prevent leakage. Ground and bond containers whentransferring material. Ventilation required along storage floor.

Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plasticbottles and containers.

7.3 Specific end use(s)Recommendations : For industrial use only.

Industrial sector specific : Not available.solutions

There is no workplace exposure data available on the product itself. Data for a solvent in the mixture isprovided for EU member countries where available.

8.1 Control parameters8.1.1 Occupational Exposure Limits (OELs) :

8. EXPOSURE CONTROL/PERSONAL PROTECTION


10/21


Workplace Occupational Exposure Limit(s) -OELsOccupational Exposure Limit Values

(3-Butanone)EC No.: 201-159-0CAS No.: 78-93-3Chemical Name:

3-Butanone

Long term limit

(8-hour TWA)

Short term limit

(15-minutes period)Country ppm mg/m3 ppm mg/m3

Limit value type

Austria 100 295 200 590 MAKBelgium 200 600 300 900 VLEPBulgaria - 590 - 1000 OEL (MH Decree No 13/2003)Croatia 200 600 300 900 EU OEL (TWA/STEL)Czech Republic 203.4 600 305.1 900 PEL, NPK-PDenmark 50 145 100 290 OELEstonia 200 600 300 900 EU OEL (TWA/STEL)Finland - - 100 300 OEL (HTP-arvot)France 200 600 300 900 VLEsGermany 200 600 200 600 MAKGreece 200 600 300 900 EU OELHungary - 600 - 900 K, CKIreland 200 600 300 900 OELV (NAOSH, 8/2007)Italy 200 600 300 900 ACGIHLatvia 67 200 300 900 AERLithuania 200 600 300 900 IPRV, TPRVNetherlands - 590 - 900 MAC-TGGNorway 75 220 - - Gjennomsnittsverdier (average values)Poland - 450 - 900 NDS, NDSCh

Portugal 200 - 300 - VLE-MP, VLE-CDRomania 63 200 101 300 VLA (TWA, STEL)Slovakia 200 600 - 900 NPELSpain 200 600 300 900 VLA-ED, VLA-ECSweden 50 150 100 300 NGV, KTVSwitzerland 200 590 200 590 VME, VLETurkey 200 600 300 900 TWA, STELUnited Kingdom 200 600 300 899 WEL (EH40/2005)Note: Users should refer to the literature for OELs data on other components of this product.

Recommended monitoring : If this product contains ingredients with exposure limits,

procedures personal, workplace atmosphere or biological monitoring maybe required to determine the effectiveness of the ventilation orother control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to EuropeanStandard EN 689 for methods for the assessment of exposureby inhalation of chemical agents and national guidancedocuments for methods for the determination of hazardoussubstances.


11/21


Derived effect levels [DNEL] : See occupational exposure limits table for guidance.

Predicted effect concentrations : Not available.(PNEC Summary)

8.1 Exposure controls8.1.1 Appropriate engineering : Provide adequate local exhaust ventilation to maintain worker

controls below exposure limits. The use of mechanical ventilationcontrols is recommended whenever this product is used in aconfined space, is heated above ambient temperatures, or isagitated. Use explosion-proof ventilation equipment.

8.2 Personal protective equipment (http://www.chemie.de/tools/gebotszeichen/ )(Directives and Amendments) (93/68/EEC, 93/95/EEC, and 96/58/EC)

8.2.1 Eye and face protection : Safety eyewear complying with an approved standard should beused when a risk assessment indicates this is necessary to avoidexposure to liquid splashes, mist, or dust.

8.2.2 Skin protectionHand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handlingchemical products if a risk assessment indicates this in necessary.

Body protection : Personal protective equipment for the body should be selectedbased on the task being performed and the risks involved and

should be approved by a specialist before handling this product.

Other skin protection : Appropriate footwear and any additional skin protection mea-sures should be selected based on the task being performed andthe risks involved and should be approved by a specialist beforehandling this product.

8.3 Respiratory protection : Use approved respiratory protection equipment. Respiratorselection should be based on the form and concentration ofcontaminants in the air and in accordance with local regulations.

8.4 Environmental exposure : Emission from ventilation or work process equipment should becontrols checked to ensure they comply with the requirements of envi-ronmental protection legislation. Ensure that emission is at theacceptable level.

9.1 Information on physical and chemical propertiesPhysical state : Liquid.Colour : Characteristic.Odour : Solvent odour.

9. PHYSICAL AND CHEMICAL PROPERTIES


12/21


Odour threshold : Not determined.pH : Not available .Melting/freezing point [o F] : Not available.

Initial boiling point/range [o F] : Not available.

Flash point [o F] : Not available.Evaporation rate (n-Butyl Acetate : Not available.= 1)Flammability (solid, gas) : Not available.Upper flammability : Not available.Lower flammability : Not available.Vapour pressure, mm Hg @ 75 o F : Not available.Vapour density (Air = 1) : Not available .Relative density : Not available.Solubility in water, Wt % @ 68 o F : Not available.Partition coefficient: n- : Not available.

Octanol/waterAuto-ignition temperature : Not available.Decomposition temperature : Not applicable.Viscosity of Liquid, CST @ 25o C : Not available.Explosive properties : Not available.Oxidizing properties : Not available.

9.2 Other information : Mixture has not been tested.

10.1 Reactivity : Highly flammable. Avoid ignition sources. Strong oxidizingagents.

10.2 Chemical stability : Stable under normal conditions.

10.3 Possibility of hazardous reactions : Hazardous polymerization will not occur.

10.4 Conditions to avoid : Open flames and sources of ignition.

10.5 Incompatible materials : Strong oxidizing agents.

10.6 Hazardous decomposition products : Burning can produce oxides of carbon.

11.1 Information on toxicological effects

11.1.2 Mixture : There are no data available on the product itself. Data on asubstance in the mixture is provided.

11.1.2.1 : Relevant effects:

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION


13/21


(a) Acute toxicity :Substance name: Test Species Route of Administration Dose/Result Exposure Remark

LD50 Rat Oral > 636 mg/kg - -Toluene LDLO Human Oral 50 mg/kg - -

LC50 Mouse Inhalation vapour 6405 -7436 ppm 6 hour (s) -TCLO Human Inhalation vapour 200 ppm - -LD50 Rabbit Dermal 12124 mg/kg - -LD50 Mouse Intra-peritoneum (i.p.) 66 mg/kg - -LD50 Rat Intra venous (i.v.) 1960 mg/kg - -

Identifiers:

EC No.: 203-625-9CAS No.: 108-88-3Index No.: 601-021-00-3

LC50 Rat Inhalation vapour 28.1 mg/l 4 hour (s) -Conclusion/Summary : Vapours may cause drowsiness and dizziness.Refer to the literature for toxicology data on other components of this product.(b) Irritation

Inhalation : May cause irritation to the nose, throat, and lungs. Highvapor concentrations may cause unconsciousness or othersigns of central nervous system depression.

Skin contact : Frequent or prolonged contact may irritate the skin andcause skin rash (dermatitis). May cause skin sensitization,an allergic reaction which becomes evident on re-exposureto this material.

Eye contact : Severely irritating. If not removed promptly will injure eyetissue, which may result in permanent damage.

Ingestion : May cause irritation of the digestive tract and diarrhea.

(c) Corrosivity : Severely irritating to eyes. Repeated exposure may cause skindryness or cracking.

(d) Sensitization : May cause skin sensitization and or respiratory system irritationdue to extended exposure of the preparation above stated occu-pational exposure limits.

(e) Single dose toxicity : No data available.

(f) Repeated dose toxicity : No data available.

(g) Carcinogenicity : No known significant effects or critical hazards.

(h) Mutagenicity : No information but adverse effects unlikely.

(i) Toxicity for reproduction : No known significant effects or critical hazards.

11.1.2.2 CMR effects : No known significant effects or critical hazards.(carcinogenic, mutagenic ortoxic for reproduction)


14/21


11.2 Potential adverse health effects : Small amounts of this liquid may be drawn into the lungs byeither swallowing or vomiting. This may cause severe anddelayed health effects such as inflammation of the lungs (pulmonary edema) and infection of the bronchi(broncho-

pneumonia). Ingestion may cause irritation to the digestivetract or diarrhea.

11.3 Potential chronic health effects : There is no evidence that exposure to 3-Butanone alonecauses progressive or irreversible neurotoxic effects.However, simultaneous over-exposure to 3-Butanone andn-Hexane can potentiate the known irreversible neurotoxiceffects of n-Hexane. There is no reported human evidencethat these neurotoxic effects occur when exposure to bothchemicals is maintained below established regulatory limits.

11.4 Other information : The mixture is not likely to be carcinogen in humans.

Note: Ecological testing has not been done on the product. Ecotoxicological information on components ofthis product is presented below.

12.1 Toxicity :

3-Butanone [CAS#: 78-93-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)

Acute fish toxicity LC50 96 hour (s) Pimephales promelas 3220Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna > 520Acute algae toxicity EC3 7 days Scenedesmus quadricauda 4300

n-Butanol [CAS#: 71-36-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC50 96 hour (s) Pimephales promelas < 1630Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 1983Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 500

Ethanol [CAS#: 64-17-5]

Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC50 96 hour (s) Alburnus alburnus 10000 - 11500Acute Daphnia toxicity LC50 48 hour (s) Daphnia magna 9268 - 14221Acute algae toxicity EC50 Not specified Chlorella pyrenoidosa 9310

Isopropanol [CAS#: 67-63-0]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC50 96 hour (s) Pimephales promelas 9640Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 13299Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 1000

12. ECOLOGICAL INFORMATION


15/21


Toluene [CAS#: 108-88-3]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC50 96 hour (s) Pimephales promelas 28Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 11.5

Acute algae toxicity EC50 48 hour (s) Scenedesmus subspicatus 125 - 160

Xylene [CAS #: 1330-20-7]Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)Acute fish toxicity LC50 96 hour (s) Cyprinus carpio > 780Acute invertebrate toxicity LC50 48 hour (s) Palaemonetes pugio 0.85Acute algae toxicity Mortality Unknown Scenedesmus quadricauda > 200

12.2 Persistence and degradability : No data available for this product.

(Biochemical Oxygen Demand BOD values)

Substance name Quantity Degradation rate (%) Incubation time Evaluation (inoculum)3-Butanone Unknown 83 5 days Sewagen-Butanol Unknown 66 5 days Sewage sludgeEthanol 10 mg/l 74 5 days Filtered sewage seedIsopropanol 10 mg/l 78* 20 days Filtered sewage seedToluene Unknown Completely Short duration Sewage seedXylene Isomers 72 20 days Activated sewage

* Theoretical Oxygen Demand (ThOD) value.

12.3 Bioaccumulative potential : No data available for this product.(BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimateSubstance name Estimated BCF log Kow Remarks3-Butanone 3 0.29 Low bioaccumulationn-Butanol 3 0.88 Low bioaccumulationEthanol 3 -0.31 Low bioaccumulationIsopropanol 3 0.05 Low bioaccumulationToluene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulationXylene 6 23.4 3.2 Low bioaccumulation

12.4 Mobility in soil : No data available for this product.

Koc The soil absorption coefficientSubstance name Koc value Remarks (soil mobility)3-Butanone 29 Very high mobilityn-Butanol 72 High mobilityEthanol 1 Very high mobilityIsopropanol 25 Very high mobilityToluene variable High to moderate mobilityXylene 39 365 for individual isomers Very high to moderate mobility


16/21


12.5 Results of PBT andvPvB assessmentPBT :No data available.vPvB : No data available.

12.6 Other adverse effects : No known significant effects or critical hazards.

13.1 Waste treatment methodsProductMethods of disposal : The generation of waste should be avoided or minimized

whenever possible. Empty containers or liners may retainsome product residues. This material and its container mustbe disposed of in a safe way. Waste product residue should notbe disposed of via the foul sewer. Consult an expert on the dis-

posal of recovered and surplus material. Incinerate, or recoverby distillation. Ensure disposal is in compliance with currentgovernment requirements and ensure conformity with localauthority regulations.

Packaging wasteMethods of disposal : The generation of waste should be avoided or minimized

whenever possible. Waste packaging should be recycled, ordispose of according to state and local authority regulations.Consult your State/Local Land Waste Management Authority.

Waste codes/ waste designation : 08 03 99* : waste not otherwise specified.

according to EWC/AVV 15 01 01 : paper and cardboard packaging.15 01 02 : plastic packaging.

: The listed waste numbers according to the European Waste Code(EWC) are intended as recommendation for users. The finalclassification has to be worked out together with the local wastedisposal company/authority.

Note: An asterisk [*] next to the a code (08 03 99*) indicates itis a hazardous waste.

Special precautions : This material and its container must be disposed of according tolocal authority regulations. Empty containers or packaging maycontain some product residue. Avoid dispersal of spilt materialand runoff to come in contact with soil, waterways, drains andsewers.

Transportation information is provided on the next page.

13. DISPOSAL CONSIDERATIONS

14. TRANSPORTATION INFORMATION


17/21


ADR/RID ADN/ADNR IMDG ICAO-TI/IATA-DGR

14.1 UN No. 1210 1210 1210 121014.2 Proper ShippingName

Printing InkRelated Material



Printing Ink RelatedMaterial

14.3 Transport hazardclass 3 3 3 314.4 Classificationcode F1 F1 F1 F114.5 Packing group II II II II14.6 Hazard label

14.7 Environmentalhazard No No

Marinepollutant: No No

14.8 Specialprovision(s) 163640C 163640C 163 Not available

AdditionalInformation

Hazardidentificationnumber

33

EAC 3Y

TransportCategory

2

Ltd. QtyLQ6

Excpt. QtyE2

PackagingP001, PP1, MP19

Portable Tanksand Bulk Cont.T4; TP1, TP8

Tunnel codeD/E

-

-

Ltd. QtyLQ6

Excpt. Qty.E2

-

-

-

-

Emergencyschedules

(EmS)

FireF-E

SpillageS-D

Ltd. Qty5l

Excpt. QtyE2

-

-

-

Passenger and Cargo

AircraftQuantity limitation:

1.0L

Packing instructions:Y341

353 5.0L

Cargo Aircraft onlyQuantity limitation:

60.0 L

Packaging instruction:364

-

-

14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.


18/21

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 18 of 21Product No: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU Regulation (EC) No. 1907/2006 (REACH)

REACH Status : In compliance.

Annex XIV List of substances subject to authorization

Substances of Very High Concern Candidate List

: None of the components in the mixture are listed.

Annex XVII Restriction on the manufacture, placing on the market and use of certain dangeroussubstances, mixtures and articles :

: Contains Toluene (Note: product is not for sale to the generalpublic and is not intended for use in adhesives and spray paints.)

Other EU regulationsEuropean inventory : All components are listed or exempt.

Endocrine Disrupters : Components not listed (http://www.chemsec.org/list/sin-list-20)[EU Directive 2000/60/EC, Annex X and Regulation (EEC)

No. 793/93]

Integrated Pollution Prevention : Components not listed.and Control List (IPPC) Air

Integrated Pollution Prevention : Components not listed.and Control List (IPPC) Water

International regulations

Chemical Weapons Convention List

Schedule I Chemicals


Schedule II Chemicals


Schedule III ChemicalsNot listed Not listed Not listed

15.2 Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for thisproduct.

15. REGULATORY INFORMATION


19/21


NOTE : This Safety Data Sheet was created as a guide, teaching aid

and training tool for freelance safety data sheet writers. Themixture is fictitious and information in the document is basedon suggestions in the Guidance on the Compilation of SafetyData Sheets. The document does not purport to be a legal adviceon compiling EU safety data sheets. Guidance on theCompilation of Safety Data Sheets for the European Union isnormative.

Product : The product has been classified and marked in accordance withEU Directives/Ordinance on Hazardous Materials.

16.1 Indication of changesDate of previous issue : No previous validation.Revisions : To comply with Regulation (EC) No 1272/2008 [CLP/GHS]Nature of version : Conforms to Regulation (EC) 1907/2006 (REACH)Version : 1.00Date of issue : July 03, 2012Prepared by : Theodore M. Amet, Regulatory Research Analyst.

16.2 Abbreviations and acronymsADN: Accord europen relative au transport international des marchandises dangereuses par voie denavigation intrieure.

ADNR: Accord europen relative au transport international des marchandises dangereuses par marinesur le RhinADR: Accord europen sur le transport des merchandises dangereuses par route (European Agreementconcerning the International Carriage of Dangerous Goods by Road)AVV (Austria): Abfallverzeichnis-VerordnungBG RCI (Germany): Berufsgenossenschaft Rohstoffe und chemische IndustrieCAS: Chemical Abstracts ServiceCDC: Centers for Disease Control and PreventionCLP: Regulation on the Classification, Labelling, and Packaging of substances and mixtures1

D/H: Danger/HazardDGR: Dangerous Goods Regulation

DPD: Dangerous Preparations Directive (Directive 1999/45/EC).DSD: Dangerous Substances Directive (Directive 67/548/EEC).EC: European CommissionEHS: Environment, Health, and Safety

1CLP Document - REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT ANDOF THE COUNCIL of 16 December, 2008 on classification, labeling, and packaging of substancesand mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC and amendingRegulation (EC) No 1907/2006.

16. OTHER INFORMATION


20/21


EINECS: European Inventory of Existing Commercial chemicals SubstancesEmS: Emergency ScheduleESIS: Existing chemical Substances Information SystemEU: European Union

GHS: Globally Harmonized System of Classification and Labelling of ChemicalsHSDB: Hazardous Substances Data BankIARC: International Agency for Research on CancerIATA: International Air Transport AssociationICAO: International Civil Aviation OrganizationIBC Code: International Code for the Construction and equipment of Ships Carrying DangerousChemicals in BulkIUCLID DB: International Uniform Chemical Information DatabaseTI: Technical Instructions for the Safe Transport of Dangerous Goods by Air

16.3 Full text of Risk and Hazard Phrases/Codes in Section 2

Risk (R)-phrase(s)R11 : Highly flammable.R20/21 : Harmful by inhalation and in contact with skin.R22 : Harmful if swallowed.R36 : Irritating to eyes.R37/38 : Irritating to respiratory system and skin.R38 : Irritating to skin.R41 : Risk of serious damage to eyes.R48/20 : Harmful: danger of serious damage to health by prolonged exposure

through inhalation.

R63 : Possible risk of harm to the unborn child.R65 : Harmful: may cause lung damage if swallowed.R66 : Repeated exposure may cause skin dryness or cracking.R67 : Vapours may cause drowsiness and dizziness.

Safety (S)-phrase(s)S2 : Keep out of the reach of children.S7/9 : Keep container tightly closed and in a well ventilated place.S13 : Keep away from food, drink and animal feedingstuff.S16 : Keep away from sources of ignition No smoking.S24/25 : Avoid contact with skin and eyes.

S26 : In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice.S36/37 : Wear suitable protective clothing and gloves.S37/39 : Wear suitable gloves and eye/face protection.S46 : If swallowed, seek medical advice immediately and show this container

or label.S62 : If swallowed, do not induce vomiting: seek medical advice immediately

and show this container or label.


21/21


16.3 Key literature references :and sources of data

ECHA (European Chemicals Agency)

http://echa.europa.eu/ESIS (Existing chemical Substances Information System)http://ecb.jrc.ec.europa.eu/esis/.GESTIS International Limit values Databasehttp://www.dguv.de/ifa/en/gestis/limit_values/index.jspGuidance for downstream usershttp://guidance.echa.europa.eu/docs/guidance_document/du_en.pdfGuidance on information requirements and chemical safety assessment, Chapter R.12: Use descriptor systemhttp://guidance.echa.europa.eu/docs/guidance_document/information_requirements_r12_en.pdfGuidance on the compilation of safe data sheetshttp://guidance.echa.europa.eu/docs/draft_documents/draft_guidance_on_safety_data_sheets_20100324.pdf

TOXNET: Toxicology Data Network.http://toxnet.nlm.nih.govInformation from technical literatureInternet researchSuppliers (Material) Safety Data Sheets.

DISCLAIMER

This guide was compiled as a service to freelance EU Safety Data Sheets writers. It neither reflects the views ofothers, nor does it endorse one link over the other. Internet links cited in this guide and views expressed in thevarious sections are mine alone. Information in this document is based on data gathered from many sites. No

warranty is expressed regarding the accuracy of data obtained from various chemical, health, toxicological, andenvironmental databases. Responsibility for the accuracy and completeness of information contained hereinrests with users who must satisfy themselves that the data is appropriate for their needs. It is always a goodpractice to consult a sectional expert when writing sections of the safety data sheets to clarify and simplifytechnical matters.

END OF SAMPLE SAFETY DATA SHEET

Documents

Amet,Tm Sample Eu Ghs Clp Sds