Upload
noah-warren
View
217
Download
1
Embed Size (px)
Citation preview
Alvaro M. Gonzalez Vogel
Puu 0.4400 Environmental Engineering 1
WET FILM (PACKED TOWER) SCRUBBERSApplication in the chemical synthesis of chlorine dioxide
November 25th, 2015
INTRODUCTION
Variables affect absorption efficiency: Gas velocity, Liquid injection rate, Packing size, Packing height.
• Liquid phase scrubber + packing material.• Both phases provide energy for the gas-liquid contact.• The packing material to provide a large contact area
between the phases, turbulent mixing, and sufficient residence time for the gas to contact the liquid.
• Particles may accumulate, plugging the void spaces in the packed beds.
• Wet-film scrubbers are not used when particle removal is the only concern.
TOWER DESIGN
Countercurrent flow Cocurrent flow
Crosscurrent arrangement
PACKING MATERIAL
• Packing material provides a large surface for contact of the gas and liquid phase.
• The size, quantity, shape, and material would depend on the following characteristic: Cost, low pressure drop, corrosion resistance, Large specific area, Mechanical strength, Weight, Arrangement.
Trademark packing material
EXHAUST GAS AND LIQUID DISTRIBUTION
Perforated tube distributor
Trough and weir distributor
Exhaust Gas Distribution:
Addition of support trays (plates or grids) for the packing material Distribution baffle.
Liquid Distribution:
• Even distribution of liquid phase to avoid flooding
• Three types: Perforated tube, weir distributor, and spray nozzles.
PULP BLEACHING
Chlorine dioxide
ClO2 SYNTHESISChemical Process
ClO2 SYNTHESISChemical Process
ClO2 SYNTHESISBulk absorption of ClO2
Chlorine dioxide Absorber:
• Super Intalox ®, Ceramic Saddles• Bottom section: 2 inches diameter.• Top section: 1 inch diameter Higher
surface area.• Fresh water from the middle, diluate ClO2
(2 g/l) from the top of the absorber.• Final ClO2 concentration: 8 g/l.• Exhaust gas is send to a vacuum ejector
and then to the scrubber for full recovery of ClO2.
ClO2 SYNTHESISAbsorption of residual ClO2
Chlorine dioxide Scrubber:
• Super Intalox ®, Plastic Saddles• Bottom section: 2 inches diameter.• Top section: 1 inch diameter Higher
surface area.• Intermediate gap for homogenization of
gas and reduction of clogging.• Final ClO2 concentration: 2 g/l.• Exhaust gas is send to the atmosphere.
ClO2 SYNTHESISConclusions
Chlorine dioxide Recovery:
• High removal efficiency is required (expensive chemical)• No particles in the exhaust gas• Good solubility of chlorine dioxide gas in water• Oxidant and acidic compound
2 Stage scrubber system seems to be a good design for full recovery of ClO2
Removal efficiency impact on a pulping mill economy
Chlorine dioxide 2.5 US$/kg
Consumption 15 kg/BDt
Daily prodction 3,000 BDt/d
Annual production 1,065,000 BDt/y
39,937,500 MUS$/y
-5% recovery 1,996,875 MUS$/y