Abbreviated Material Safety Data Sheets (MSDSs)fjetland.cm.utexas.edu/courses/organiclab/Safety/msds.pdfAbbreviated Material Safety Data Sheets (MSDSs) The abbreviated MSDSs provided

Abbreviated Material Safety Data Sheets (MSDSs)

The abbreviated MSDSs provided for each compound listed in the fol lowing Table of Contents

contain only the basic chemical, physical, and toxicological data needed to answer Pre-Lab questions

and to prepare Tables of Reactants and Products for the experiments in “Experimental Organic

Chemistry: A Miniscale and Microscale Approach, 3 rd Ed.” Should you wish more complete

information regarding the chemicals with which you are working, consult a source containing the

full MSDS. Information provided regarding first-aid procedures generally describes only the initial

steps that should be taken should an accident occur.

Disclaimer

Neither the authors, The University of Texas at Austin, nor Thomson Learning, Inc. , assumes

responsibility for the accuracy of any of the data provided in the abbreviated Material Safety Data Sheets.

Acetamide

CAS No. PS Color Odor FP BP MP d VP VD Sol60-35-5 solid colorless distinct 174 221 80–82 1.159 10 @

105N/A 200%

Types ofHazard/Exposure

Acute Hazards/Symptoms Prevention First Aid/Fire

Fire Slight fire hazard. Avoid heat, sparks,flames.

Regular dry chemical,carbon dioxide, water,regular foam.

Inhalation Irritation, drowsiness, fatigue, nausea,acidosis and skin eruptions.

Ventilation, localexhaust.

Remove from exposureimmediately, get medicalattention.

Skin Irritation. Protective gloves andclothing.

Remove contaminatedclothes and jewelry,thoroughly wash skin withwater.

Eyes Irritation, corneal damage. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Drowsiness, fatigue, nausea, acidosisand skin eruptions.

Do not eat or drink inthe laboratory.

Contact physicianimmediately; if vomitingoccurs, keep head lowerthan hips.

Carcinogenicity Suspected carcinogen. Mutagenicity Not a known mutagen.

For more detailed information consult the Material Safety Data Sheet for this compound.

Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flashpoint (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = meltingpoint (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specifiedtemperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A= not available or not applicable.

4-Acetamidobenzenesulfonamide

CAS No. PS Color Odor FP BP MP d VP VD Sol121-61-9 solid off-white N/A N/A N/A 219 N/A N/A N/A slightly soluble



Fire Flammable, emits toxic fumes underfire conditions.

Avoid heat, sparks,flames.

Water spray, carbondioxide, dry chemicalpowder or appropriatefoam.

Inhalation May be harmful if inhaled. Ventilation, localexhaust.

Remove to fresh air. Ifbreathing is difficult, giveoxygen.

Skin May be irritating to the skin. Protective gloves andclothing.

Immediately flush skinwith soap and copiousamounts of water for atleast 15 minutes. Removecontaminated clothing.

Eyes Dust, vapor, or mist may be irritatingto the eyes.

Safety goggles..

Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion May be harmful if swallowed. Do not eat or drink inthe laboratory.

If swallowed wash outmouth with water. Call aphysician.

Carcinogenicity Not a known carcinogen. Mutagenicity Not a known mutagen.


Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =vapor density (g/mL); Sol = solubility in water; N/A = not available or not applicable.

4-Acetamidobenzenesulfonyl Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol

121-60-8 solid tan acetic acid-like

N/A N/A 145–148

N/A N/A N/A decomposes



Fire Moderate fire hazard. No flames, no sparks,no contact with hotsurfaces.

Carbon dioxide, drychemical powder, or foam.

Inhalation Corrosive material, chemical burns,coughing, wheezing, laryngitis,headache, and vomiting.


Remove from exposureimmediately; get medicalattention immediately.

Skin Corrosive material, chemical burns. Protective gloves andclothing.

Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, and get medicalattention immediately.

Eyes Corrosive material, chemical burns. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Corrosive material, convulsions, muscleweakness, and symptoms as describedin acute ingestion.


If vomiting occurs, keephead lower than hips; getmedical attention, ifneeded.



Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or notapplicable.

Acetanilide


103-84-4 solid white odorless 169 304 114 1.219 1 @114

4.7 0.5%




Regular dry chemical,carbon dioxide, water,regular foam

Inhalation Irritation, eczematous skin eruptions,poisoning as in ingestion.


Remove from exposureimmediately; getimmediate medicalattention.

Skin Irritation, contact dermatitis, skineruptions due to systemic poisoning

Protective gloves andclothing.


Eyes Irritation Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Nausea, vomiting, sweating, gastricirritation, chills, brown-black urine,skin rash, hypotension,methemoglobinemia. Severe cases:hypothermia, and circulatory orrespiratory failure.


If vomiting occurs keephead lower than hips, getmedical attention, ifneeded.

Carcinogenicity Not a known carcinogen. Mutagenicity Possible mutagen.



Acetic Acid


64-19-7 liquid colorless vinegary 39 118 N/A 1.049 11.8 @20

2.07 soluble



Fire Moderate fire hazard., vapors or gasesmay ignite at distant ignition sources.

No flames, no sparks,no contact with hotsurfaces.

Regular dry chemical,carbon dioxide, water,regular foam, alcoholresistant foam

Inhalation Irritation, pharyngeal edema, chronicbronchitis, coughing, shortness ofbreath, laryngitis, pulmonary edema,and hypotension



Skin Irritation, pain, erythema, blisters,burns and superficial destruction of theskin; readily absorbed through theskin.


Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, get medicalattention immediately.

Eyes Irritation, lacrimation, corneal erosion,opacification, iritis, and possibly lossof sight

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Severe ulceronecrotic lesions, strictureof the esophagus, perforation of theesophagus and pylorus, diarrhea,shock, vomiting, abdominal spasms,thirst, rapid and weak pulse, slow andshallow breathing, laryngitis,bronchitis, pulmonary edema.


Contact physicianimmediately. Give largeamounts of water or milkand allow vomiting tooccur; when vomitingoccurs, keep head lowerthan hips.




Acetic Anhydride


108-24-7 liquid colorless vinegary 54 138–140 -73 1.082 10 @36

3.52 reacts



Fire Moderate fire hazard., vapors or gasesmay ignite at distant ignition sources,contact with water or moist air maygenerate flammable and/or toxic gases.


Carbon dioxide, regulardry chemical, alcoholresistant foam

Inhalation Severe irritation, cough, choking,wheezing, chest pain, and pulmonaryedema, which may be fatal.



Skin Irritation, white, wrinkled skin,blisters, and severe burns.



Eyes Pain, lacrimation, photophobia, andblurred vision. Corneal andconjunctival edema, iritis, cornealerosion, and opacity may be delayedeffects.


Ingestion Severe burns of the mouth, esophagus,and stomach with pain, difficultyswallowing, nausea, vomiting, anddiarrhea.


Contact physicianimmediately; give largeamounts of water or milk,and allow vomiting tooccur; when vomitingoccurs keep head lowerthan hips.

Carcinogenicity Not a known carcinogen Mutagenicity Not a known mutagen.



Acetone


67-64-1 liquid colorless minty,sweet

-17 56 -94 0.791 180 @20

2.0 soluble



Fire SEVERE fire hazard., vapors or gasesmay ignite at distant ignition sources.

No flames, no sparks,no contact with hotsources

Alcohol resistant foam,carbon dioxide, regular drychemical, water

Inhalation Irritation, dryness of the mouth andthroat, restlessness, anorexia,vomiting, slow, irregular respiration,slow, weak pulse, liver and kidneydamage, central nervous systemdepression with weakness of the legs,headache, nausea and a general feelingof malaise.


Remove from exposureimmediately; get medicalattention.

Skin Irritation, cellular damage to the outerlayers of the epithelium with edemaand hyperemia, small amounts may beabsorbed through intact skin.



Eyes Irritation, corneal epithelial,conjunctival, stinging sensation, anddamage to eyes.


Ingestion Fruity odor of the breath and mucousmembrane, gastroenteric irritation,flushed cheeks, shallow respiration,latent period followed by restlessness,diarrhea, nausea and vomiting.


Contact physicianimmediately. If vomitingoccurs, keep head lowerthan hips.




p-Acetophenetidide (Phenacetin)


62-44-2 crystallinepowder

white odorless N/A decomposes 134–135

N/A N/A N/A 1 g/1310 mL



Fire Slightly flammable. No open flames. Water spray, dry chemical,alcohol foam, or carbondioxide.

Inhalation Cyanosis, dizziness, respiratorydepression.

Local exhaust orbreathing protection.

Remove to fresh air. Getmedical attention.

Skin Possibly a mild irritant. Protective glovesand clothing.

Immediately flush skinwith plenty of soap andwater for at least 15 min.while removingcontaminated clothing andshoes. Get medicalattention.

Eyes Possibly irritating to eye tissues. Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 min., liftinglower and upper eyelidsoccasionally. Get medicalattention immediately.

Ingestion Moderately toxic, causes cyanosis,dizziness, respiratory depression. Cardiacarrest may occur. May result in liver andkidney damage.

Do not eat or drinkin the laboratory.

Induce vomitingimmediately as directed bymedical personnel. Call aphysician immediately.

Carcinogenicity Possible carcinogen. Mutagenicity Not a known mutagen.



Acetophenone


98-86-2 liquid colorless floral 82 203 19-20 1.030 1 @ 15 4.14 0.55% @ 20





Inhalation Irritation, coughing and centralnervous system depression withheadache, dizziness, and narcosis.



Skin Irritation, redness, pain, and mildburns.



Eyes Severe reaction with only transientoptical irregularity of the cornealepithelium.


Ingestion Sore throat, abdominal pain, nauseaand central nervous system depressionwith headache, dizziness, and narcosis.






Adipic Acid


124-04-9 crystallinesolid

white odorless 196 337 150–152

1.360 1 @159.5

5.04 1.4 g/ 100mL



Fire Combustible. No open flames. Powder, water spray,foam, carbon dioxide.

Inhalation Cough. Labored breathing. Sore throat. Local exhaust orbreathingprotection.

Fresh air, rest. Refer formedical attention.

Skin Redness. Protective glovesand clothing.

Remove contaminatedclothes. Rinse skin withplenty of water or shower.

Eyes Redness and pain. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifpossible; seek medicalattention.

Ingestion N/A Do not eat ordrink in thelaboratory.

Rinse mouth. Rest. Referfor medical attention.




Alumina


1344-28-1 solid white odorless N/A 2980 2053–2072

3.965@ 25

1 @2158

N/A insoluble



Fire Negligible fire hazard. N/A Use extinguishing agentsappropriate forsurrounding fire.

Inhalation Coughing, shortness of breath,respiratory tract irritation due tomechanical action, and exacerbation ofsymptoms in persons with impairedpulmonary function.



Skin Irritant dermatitis, pruritis. Protective gloves andclothing.


Eyes Irritation, redness, and possiblyswelling of the conjunctiva.


Ingestion N/A Do not eat or drink inthe laboratory.


Carcinogenicity Possible carcinogen Mutagenicity Not a known mutagen.



Aluminum Chloride


7446-70-0 solid white pungent N/A N/A 190 @1900

2.44@ 25

1 @100

N/A reacts



Fire Negligible fire hazard. N/A Carbon dioxide, regular drychemical.

Inhalation Forms corrosive hydrochloric acid oncontact with moisture, coughing,choking, pain in the nose, mouth andthroat and burns of the mucousmembranes. Symptoms may includetightness in the chest, frothy sputum,cyanosis, and dizziness.


Remove from exposureimmediately, get medicalattention immediately.

Skin Severe irritation, pain, and possiblyburns.



Eyes Redness, pain, blurred vision, andcorneal burns.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately,continue to wash eyeswith water.

Ingestion Burning pain in the mouth and throat,severe burns of the mucousmembranes, discoloration of thetissues, swallowing and speech may bedifficult, vomiting, diarrhea,hemolysis, kidney damage, and liverdamage with jaundice.


Give water or milk; ifvomiting occurs, keephead lower than hips; getmedical attentionimmediately.



Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.

4-Aminobenzoic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol150-13-0 solid white N/A N/A N/A 188–189 1.374 N/A N/A 5.39 g/L



Fire Emits toxic fumes under fireconditions.

No open flames orsparks.

Water spray, Carbondioxide, dry chemicalpowder or appropriatefoam.

Inhalation May be harmful if inhaled. Irritatingto respiratory system. Do not breathein dust.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Seek medicaladvice.

Skin Causes skin irritation. May causesensitization by skin contact.


Immediately flush skinwith soap and copiousamounts of water for atleast 15 minutes.

Eyes Causes eye irritation Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.

Ingestion Harmful if swallowed. Do not eat or drink inthe laboratory.





Ammonium Hydroxide


1336-21-6 liquid colorless pungent,sharp

N/A 36 N/A 0.90 115 @20

1.2 soluble




Inhalation Irritation, swelling of the lips,restlessness, runny nose, headache,salivation, nausea, vomiting, difficultyin speaking, decreased respiratoryfunction, and inflammation, or edemaof the larynx.



Skin Severe pain, stinging sensation, severeburns and vesiculation, and possiblybrownish stains.



Eyes Severe pain, loss of corneal epitheliumdespite irrigation, swelling of theeyelids, and increased intraocularpressure. Corneal anesthesia ispossible, allowing damage to occurbefore warning discomfort is felt.


Ingestion Immediate pain, circumoral burns,corrosion of the mucous membranes,profuse salivation, inability toswallow or speak. Shock with markedhypotension, weak and rapid pulse,shallow respiration, and clammy skinmay occur.


Do not induce vomiting;give large amounts ofwater or milk; whenvomiting occurs keep headlower than hips; getmedical attentionimmediately.




Aniline


62-53-3 liquid colorless fishy 70 184 N/A 1.022 0.6 @20

3.2 3.5%





Regular dry chemical,carbon dioxide, regularfoam, alcohol resistantfoam

Inhalation May cause effects as described underingestion.



Skin Irritation, sensitization dermatitis,readily absorbed through the skin, anda small amount absorbed from clothesor shoes may cause toxic symptoms asdescribed in acute ingestion.



Eyes Redness, pain, and possible cornealdamage.


Ingestion Headache, nausea, vomiting, chest orabdominal pain, dryness of the throat,cyanosis, lips, tongue and mucousmembranes may be navy blue to blackand the skin may appear slate gray,central nervous system effects mayinclude confusion, irritability, vertigo,numbness of extremities, pain injoints, and drowsiness. Anilinecrosses the placental barrier andexposure during pregnancy may affectthe fetus.


Contact physicianimmediately; if vomitingoccurs, keep head lowerthan hips; get medicalattention immediately.

Carcinogenicity Possible carcinogen. Mutagenicity Possible mutagen.



trans-p-Anisalacetophenone

CAS No. PS Color Odor FP BP MP d VP VD Sol959-33-1 solid yellow N/A N/A N/A 73–76 N/A N/A N/A insoluble



Fire Flammable. Emits toxic fumes underfire conditions.



Inhalation Irritant, may be harmful if inhaled. Ventilation, localexhaust.


Skin Irritant, may be harmful to the skin. Protective gloves andclothing.


Eyes Vapor or mist is irritating to the eyes,may be harmful.

Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advise.






p-Anisaldehyde


123-11-5 liquid colorless floral 116 118–121

-1 1.119–1.123

133.5@ 73

4.7 slightlysoluble



Fire Slight fire hazard. Avoid heat, flames,sparks


Inhalation N/A Ventilation, localexhaust.




Eyes N/A Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

IngestionDo not eat or drink inthe laboratory.





Anisole


100-66-3 liquid colorless licorice-like

43 155 N/A 0.9961 10@

42.2

3.7 insoluble



Fire Moderate fire hazard., vapors or gasesmay ignite at distant ignition sources



Inhalation Irritation, dizziness, or suffocation Ventilation, localexhaust.


Skin Irritation Protective gloves andclothing.



IngestionDo not eat or drink inthe laboratory.

If vomiting occurs, keephead lower than hips, getmedical attention, ifneeded.




Azobenzene


103-33-3 solid orange N/A >143 293 69 1.203 1 @103

N/A insoluble





Inhalation Coughing, shortness of breath,dizziness, dullness, bluish skin, andfaintness.



Skin Irritation, possibly absorbed throughintact skin with dizziness, dullness,bluish skin and faintness, allsymptoms of methemoglobenimia.



Eyes Irritation, redness, and pain. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, dizziness, dullness,bluish skin, faintness, andmethemoglobinemia.


Contact physicianimmediately; if vomitingoccurs, keep head lowerthan hips; get medicalattention.




1,1’–Azobis(cyclohexanecarbonitrile)

CAS No. PS Color Odor FP BP MP d VP VD Sol2094-98-6 solid white N/A N/A N/A 115–118 N/A N/A N/A insoluble



Fire Flammable. Capable of creating adust explosion. Container explosionmay occur under fire conditions.Emits toxic fumes under fireconditions.


Smother with dry sand,limestone, or clay. AClass D extinguisher maybe used.

Inhalation May be harmful if inhaled. Irritatingto respiratory system. Prolongedexposure can cause nausea, headache,and vomiting.



Skin Irritating to the skin. Protective gloves andclothing.


Eyes Irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






Benzaldehyde


100-52-7 liquid colorless almond-like

63 178 -26 1.0415@ 10

1 @26.2

3.65 0.29%






Inhalation Sore throat, and coughing, centralnervous system depression withnausea, vomiting, headache,lightheadedness.



Skin irritation, redness, pain, weak localanesthesia, possible absorptionthrough the skin.



Eyes Irritation, lacrimation, redness, pain,and eye injury.


Ingestion Sore throat, central nervous systemdepression, nausea, vomiting,abdominal pain, headache, dizziness,dullness, convulsions, and respiratoryfailure.


Contact physicianimmediately; if vomitingoccurs, keep head lowerthan hips; get medicalattention immediately.




Benzamide


55-21-0 solid colorless N/A 180 288 130 1.341 N/A N/A 1.35%







Skin N/A Protective gloves andclothing.


Eyes N/A Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Headache, shortness of breath,dullness, drowsiness, nausea,vomiting, and central nervous systemdepression.






Benzanilide

CAS No. PS Color Odor FP BP MP d VP VD Sol93-98-1 solid colorless N/A N/A 117–119 N/A 1.315 N/A N/A insoluble







Skin May be absorbed through the skin Protective gloves andclothing.







Abbreviations:CAS No. = Chemical Abstracts Service Registry Number; PS = physicalstate; FP = flash point (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated;MP = melting point (°C); d = density or specific gravity (g/mL); VP = vapor pressure(torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol =solubility in water; N/A = not available or not applicable.

Benzenesulfonyl Chloride


98-09-9 liquid colorless N/A 132 251–252 dec

14.5 1.4 1.3 @20

N/A reacts



Fire Negligible fire hazard., slightexplosion hazard

N/A Regular dry chemical,regular foam, water

Inhalation Acidic corrosive action: sore throat,coughing, choking, weakness andlabored breathing, tightness in thechest, dizziness, cyanosis, and lowblood pressure.



Skin Redness, pain, and serious burns. Protective gloves andclothing.


Eyes Irritation, burns, and permanentcorneal damage.


Ingestion Severe burning pain in the mouth,throat and abdomen, nausea, vomiting,diarrhea, sudden drop in bloodpressure.


Contact physicianimmediately; give largeamounts of water or milk,allow vomiting to occur;when vomiting occurs,keep head lower than hips;get medical attentionimmediately.




Benzilic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol76-93-7 powder white N/A N/A 187 150–153 N/A N/A N/A 1.758 g/L






Inhalation Harmful by inhalation. Ventilation, localexhaust.


Skin May cause skin irritation. Protective gloves andclothing.


Eyes May cause eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.


If swallowed, wash outmouth with water. Call aphysician.

Carcinogenicity Not a known carcinogen Mutagenicity Not a known mutagen



Benzoic Acid


65-85-0 solid white varyingsharp

121 249 122 1.2659@ 15

1 @ 96 4.2 2.9% @ 20





Inhalation Irritation, sore throat, and coughing Ventilation, localexhaust.


Skin Irritation and redness Protective gloves andclothing.


Eyes Irritation and redness Safety goggles. Thoroughly wash eyeswith water for severalminutes, remove contactlenses if possible, andseek medical attentionimmediately.

Ingestion Sore throat, gastric pain, nausea,vomiting, and allergic reactions






Benzoyl Chloride


98-88-4 liquid colorless pungent 68 197 N/A 1.211 1 @ 32 4.88 decomposes





Carbon dioxide, regular drychemical

Inhalation Irritation, burns, sore throat, coughing,labored breathing, pulmonary edema,liver and kidney damage.


Remove from exposureimmediately; keep warmand at rest, get medicalattention immediately.

Skin Irritation, redness, pain, and burns. Protective gloves andclothing.


Eyes Irritation, redness, pain, blurred vision,and severe eye burns.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water.

Ingestion Immediate pain and severe burns ofmucous membranes of the mouth andthroat and gastrointestinal tract,nausea, vomiting, abdominal pain,diarrhea, and central nervous systemdepression.


If person conscious, givewater or milk; if vomitingoccurs, keep head lowerthan hips; get medicalattention immediately.




Benzyl Bromide

CAS No. PS Color Odor FP BP MP d VP VD Sol100-39-0 liquid colorless N/A 86 198–199 -3 – -1 1.439 0.242

@175.8 insoluble



Fire Water hydrolyzes material liberatingacidic gas that in contact with metalsurfaces can generate flammable and/orexplosive hydrogen gas. Emits toxicfumes under fire conditions.


Carbon dioxide, drychemical powder orappropriate foam. Do notuse water.

Inhalation Do not breathe vapor. Symptoms mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache nausea and vomiting.Target organ; central nervous system.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Get medicalattention immediately.

Skin Do not get on skin. Material isextremely destructive to tissue of theupper mucous membranes. Symptomsmay include burning sensation,coughing, wheezing, laryngitis,shortness of breath, headache nausea andvomiting.



Eyes Do not get in eyes. Lachrymator. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion Harmful if swallowed. Symptoms mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache nausea and vomiting.


If swallowed, wash outmouth with waterprovided person isconscious. Call aphysician.




Benzyltriphenylphosphonium Chloride


1100-88-5 solid off-white faint >299 N/A 300 1.18@ 25

N/A N/A moderatelysoluble





Inhalation Ventilation, localexhaust.


Skin Absorption through skin: depression,diarrhea or irritability.



Eyes Irritation, death in animals. Safety goggles. Thoroughly wash eyeswith water for severalminutes, remove contactlenses if possible, andseek medical attentionimmediately.

Ingestion Depression, labored breathing,diarrhea; kidneys, liver, and lungs maybe affected.


Contact physicianimmediately; if vomitingoccurs, keep head lowerthan hips.




Bicyclo[2.2.1]hept-5-en-cis-endo-2,3-dicarboxylic Acid


3853-88-1 solid colorless N/A N/A N/A 191–193

N/A N/A N/A slightly soluble





Inhalation Irritation* Ventilation, localexhaust.


Skin Irritation* Protective gloves andclothing.


Eyes Irritation* Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.



Carcinogenicity Not a known carcinogen.* Mutagenicity Not a known mutagen.*

*Toxicological information for the listed chemical is not available. Information given pertains to cyclohexane-cis-1,2-dicarboxylic acid and is intended to be used for comparison of a similar compound. Other effects may resultfrom contact, inhalation, or ingestion.


Bicyclo[2.2.1]hept-5-en-endo-2,3-dicarboxylic Anhydride


129-64-6 solid white N/A N/A N/A 164–165

1.417 N/A N/A reacts



Fire SEVERE fire hazard. No flames, no sparks,no contact with hotsurfaces.

Regular dry chemical,sand, earth, regular foam.

Inhalation Irritation, runny or stuffy nose,wheezing, asthmatic symptoms, centralnervous system depression, headache,nausea, and vomiting.



Skin Irritation, absorption through skin maycause central nervous systemdepression, headache, nausea, andvomiting.



Eyes Symptoms as given in acute skincontact.


Ingestion Symptoms as given in acute inhalation. Do not eat or drink inthe laboratory.





Borane-THF Solution


14044-65-6 liquid colorless irritating -17 >69 N/A 0.898 N/A N/A reacts



Fire Severe fire hazard. No flames, no sparks,no contact with hotsurfaces.


Inhalation Irritation, headache, nausea, andvomiting.





Eyes Irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Headache, nausea, and vomiting. Do not eat or drink inthe laboratory.





Bromine


7726-95-6 liquid brown tored

irritating N/A 59 N/A 3.12 175 @20

7.14 4%



Fire Negligible fire hazard., may ignite orexplode on contact with combustiblematerials.

Avoid contact withcombustible materials

Regular dry chemical,carbon dioxide, regularfoam

Inhalation Irritation, copious mucous secretion,coughing, nosebleeds, and headache.Delayed symptoms: nausea, diarrheaand abdominal pains, pulmonaryedema, pneumonitis or pneumonia.



Skin Cooling sensation, burning sensation,redness, pain, brown discoloration,blisters, discharging pustules,destructive burns and deep-seatedulcers.



Eyes Redness, pain, blurred vision, burns,lacrimation, photophobia, loss ofvision


Ingestion Burns of the mouth, throat andstomach, brown discoloration andcorrosion of the tongue and mucousmembranes, sore throat, and vomiting.


Contact physicianimmediately; give largeamounts of water or milkand allow vomiting tooccur; when vomitingoccurs, keep head lowerthan hips.




4-Bromoacetanilide

CAS No. PS Color Odor FP BP MP d VP VD Sol103-88-8 solid off-

whiteN/A N/A N/A 167–169 1.717 N/A N/A insoluble






Inhalation May be irritating if inhaled. Ventilation, localexhaust.




Eyes Vapor or mist is irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion Toxic, harmful if swallowed. Do not eat or drink inthe laboratory.





Bromobenzene


108-86-1 liquid colorless pleasant 51 156 N/A 1.49 3 @ 20 5.41 0.045%




No heat, no flames, nosparks

Alcohol resistant foam,carbon dioxide, regular drychemical, water.

Inhalation Irritation, headache, sore throat,coughing, shortness of breath, nausea,vomiting, and dizziness.



Skin Irritation, redness, abdominal pain,nausea, vomiting, diarrhea, headache,dullness, and central nervous systemeffects.


Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, get medicalattention.


Ingestion Headache, abdominal pain,gastrointestinal irritation, nausea,vomiting, diarrhea, dizziness, andcentral nervous system effects.






1-Bromobutane


109-65-9 liquid colorless N/A 22 99-101 N/A 1.3 150@ 25

4.7 insoluble



Fire SEVERE fire hazard. No open flames, nosparks, no contactwith hot surfaces.Vapors or gases mayignite at distantignition sources.


Inhalation Irritation of mucous membranes,narcosis



Skin Irritation, burns Protective gloves andclothing.

Remove contaminatedclothes and jewelry.Thoroughly wash skinwith water. Get medicalattention immediately.

Eyes Irritation Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention.

Ingestion Gastrointestinal disturbances, possiblynarcosis.


If vomiting occurs keephead lower than hips. Getmedical attentionimmediately.




1-Bromoethylbenzene

CAS No. PS Color Odor FP BP MP d VP VD Sol585-71-7 liquid color-

lessN/A 81 94 @ 16

torr49.5–50.5 1.356 N/A N/A insoluble



Fire Combustible Avoid heat, sparks,flames.


Inhalation Irritating to respiratory system. Vaporor mist is irritating to the mucousmembranes and respiratory tract.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea and vomiting.



Skin Harmful if absorbed through skin.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea and vomiting.



Eyes Vapor or mist is irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advise.

Ingestion Harmful if swallowed. Symptomsmay include burning sensation,coughing, wheezing, laryngitis,shortness of breath, headache nauseaand vomiting.






2-Bromohexane

CAS No. PS Color Odor FP BP MP d VP VD Sol111-25-1 liquid colorless N/A 135 154–158 -85 1.176 <10 5.7 insoluble



Fire Combustible. Emits toxic fumesunder fire conditions.*



Inhalation May be harmful if inhaled. Irritatingto respiratory system.*



Skin Irritating to the skin.* Protective gloves andclothing.


Eyes Irritating to the eyes.* Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion May be harmful if swallowed.* Do not eat, drink, orsmoke during work.



* Toxicological information for the listed chemical is not available. Information given pertains to 1-bromohexaneand is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation,or ingestion.


2-Bromonitrobenzene


577-19-5 solid yellow distinct >110 261 40–42 1.62 N/A 7.0 almostinsoluble



Fire Slight fire hazard. Avoid heat, flames,and sparks.

Regular dry chemical,regular foam, water

Inhalation Irritation. If sufficient amounts areabsorbed, methemoglobinemia mayoccur.



Skin Irritation. Skin absorption may occurand may result in methemoglobinemiaas detailed in ingestion.




Ingestion Nausea and vomiting, abdominal pain,coma, and paralysis.






4-Bromonitrobenzene


586-78-7 solid off-white N/A N/A 255–256 125–127 1.934 N/A N/A insoluble




Regular dry chemical,regular foam, water

Inhalation Irritation and possibly conditionsdetailed in inhalation



Skin Irritation, skin absorption may occurand may result in conditions detailedin inhalation.




Ingestion Nausea and vomiting, abdominal pain,confusion, irritability, tremor, memoryloss, anorexia, emaciation, headache,slurred speech, conjunctivitis






4-Bromophenol


106-41-2 solid white tooff-white

N/A N/A 235–236 64–68 1.840@ 15

negli-gible

N/A >10%





Inhalation Irritation Ventilation, localexhaust.


Skin Irritation, depigmentation Protective gloves andclothing.



Ingestion Rapidly absorbed from thegastroenteric tract, nausea andvomiting, abdominal pain.






1-Bromopropane


106-94-5 liquid colorless N/A 22 71 -110 1.353 100@18

4.25 0.25 g/100mL:



Fire Flammable liquid and vapor. NO open flames orsparks.

Dry chemical, alcoholfoam or carbon dioxide.Water may be ineffective.

Inhalation Causes irritation to the respiratorytract. Symptoms may includecoughing, shortness of breath. Acentral nervous system depressant.

Local exhaust. Remove to fresh air. Ifbreathing is difficult, giveoxygen. Get medicalattention.

Skin Causes irritation to skin. Symptomsinclude redness, itching, and pain.

Protective gloves andclothing..

Immediately flush skinwith plenty of water for atleast 15 minutes. Removecontaminated clothing andshoes. Get medicalattention.

Eyes Causes irritation, redness, and pain. Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftingupper and lower eyelidsoccasionally. Get medicalattention.

Ingestion Causes irritation to the gastrointestinaltract. Symptoms may include nausea,vomiting and diarrhea.


Give large amounts ofwater to drink. Getmedical attention.




4-Bromo-2-chloroacetanilide

CAS No. PS Color Odor FP BP MP d VP VD Sol3460-23-9 solid colorless N/A N/A N/A 151 N/A N/A N/A insoluble



Fire Moderate fire hazard. No flames, no sparks,no contact with hotsurfaces


Inhalation Irritation, may be harmful.* Ventilation, localexhaust.


Skin Irritation, may be harmful if absorbedthrough skin.*



Eyes Irritation.* Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Irritation, may be harmful.* Do not eat or drink inthe laboratory.



*Toxicological information for the listed chemical is not available. Information given pertains to 2-chloroacetanilide andis intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, oringestion.

Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP= boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specificgravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air(1.0); Sol = solubility in water; N/A = not available or not applicable.

4-Bromo-2-chloroaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol38762-41-3 solid colorless N/A N/A N/A 70–72 N/A N/A N/A insoluble



Fire Low fire hazard. Avoid heat, sparks,flames.


Inhalation Harmful if inhaled. Ventilation, localexhaust.


Skin Harmful if in contact with skin. Protective gloves andclothing.


Eyes Harmful to eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.


If swallowed, wash outmouth with water.




4-Bromo-2-chloro-6-iodoaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol147-82-0 liquid beige N/A N/A 300 120–122 N/A N/A N/A insoluble



Fire Emits toxic fumes under fireconditions. *



Inhalation Highly Toxic if inhaled. * Ventilation, localexhaust.


Skin Toxic if absorbed through skin. Causesskin irritation. *



Eyes Harmful to the eyes. * Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion Highly toxic if swallowed. * Do not eat or drink inthe laboratory.


Carcinogenicity Carcinogen * Mutagenicity Not a known mutagen.*

* Toxicological information for the listed chemical is not available. Information given pertains to 2,4,6-tribromoaniline and is intended to be used for comparison of a similar compound. Other effects may result fromcontact, inhalation, or ingestion.


1-Bromo-3-chloro-5-iodobenzene

CAS No. PS Color Odor FP BP MP d VP VD Sol13101-40-1 solid colorless N/A N/A N/A 85.8 N/A N/A N/A insoluble



Fire Moderate fire hazard. No flames, no sparks,no contact with hotsurfaces


Inhalation Respiratory tract effects, central nervoussystem, effects, and possibly corrosion.*


Remove from exposureimmediately, artificialrespiration if needed; getmedical attention.

Skin Irritation, possibly corrosion.* Protective gloves andclothing.


Eyes Lacrimation, irritation, and possiblycorrosion.*





*Toxicological information for the listed chemical is not available. Information given pertains to 1,3,5-tribromobenzeneand is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, oringestion.


2-Bromo-2-methylbutane


507-36-8 liquid colorless N/A 4 107 N/A 1.182 N/A N/A N/A



Fire Severe fire hazard; vapors may ignite atdistant ignition sources.


Carbon dioxide, drychemical powder, foam,water.

Inhalation May be harmful. Ventilation, localexhaust.


Skin Irritation, may be harmful if absorbedthrough skin.



Eyes Irritation, may be harmful. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion May be harmful. Do not eat or drink inthe laboratory.





1-Butanol


71-36-3 liquid colorless irritating 29 117 N/A 0.81 6.5@ 25

2.55 7.7%






Inhalation 25 ppm: irritation. At 50 ppm: sorethroat, coughing, nausea, and centralnervous system depression withheadache and dizziness.



Skin irritation with redness and dryness,may be absorbed through skin


Remove contaminatedclothes and jewelry.Thoroughly wash skinwith water.

Eyes moderate temporary injury Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediatly.

Ingestion abdominal pain, nausea, vomiting, anddiarrhea. High doses: completeparalysis, reduction of bodytemperature and respiration.


Contact physicianimmediately. If vomitingoccurs, keep head lowerthan hips; get medicalattention immediately.




2-Butanol


78-92-2 liquid colorless strong,pleasant

24 94 -115 0.81 13 @20

2.6 15 g/ 100mL.



Fire Flammable. No flames, no sparks,no contact with hotsufaces

Foam, powder, alcohol-resistant foam, waterspray, carbon dioxide.

Inhalation Dizziness. Drowsiness. Headache. Local exhaust. Fresh air, rest. Refer formedical attention.

Skin Dry skin. Protective gloves andclothing..


Eyes Redness. Pain. Blurred vision. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifpossible; seek medicalattention.

Ingestion Dizziness. Drowsiness. Headache. Do not eat or drink inthe laboratory.

Rinse mouth. Give plentyof water to drink. Refer formedical attention.




2-Butanone


78-93-3 liquid colorless sharp,mint-like

-9 80 -86 .805 78 @20

2.5 29 g/ 100mL



Fire Highly flammable. No flames, nosparks, no contactwith hot sufaces

Powder, AFFF, foam,carbon dioxide.

Inhalation Cough. Dizziness. Dullness. Headache.Nausea. Shortness of breath.Unconsciousness. Vomiting.

Local exhaust. Fresh air, rest. Refer formedical attention.

Skin MAY BE ABSORBED! Redness. Protective glovesand clothing.


Eyes Redness. Pain. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifeasily possible; seekmedical attention.

Ingestion Dizziness. Drowsiness. Headache. Do not eat or drinkin the laboratory.

Rinse mouth. Give plentyof water to drink. Refer formedical attention.




3-Buten-2-one


78-94-4 liquid colorless irritating -6 81 N/A 0.842 120 @34

1.3 soluble




No flames, no sparks,no contact with hotsufaces


Inhalation Coughing, choking, pain, burns,pulmonary edema, tightness in thechest, cyanosis, dizziness, low bloodpressure; central nervous systemdepression, headache, nausea, andvomiting.


Remove from exposureimmediately; keep warmand at rest; get medicalattention immediately.

Skin Irritation, pain, burns; absorptionthrough the skin may cause centralnervous system depression, headache,dizziness, nausea, vomiting.



Eyes Irritation, pain, and burns. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to was eyes withwater until medical helparrives.

Ingestion Immediate pain and severe burns,discoloration of the tissues,swallowing and speech may bedifficult or impossible, and shock.


Give water or milk; ifvomiting occurs, keephead lower than hips; getmedical attentionimmediately.




n-Butyl Acetate


123-86-4 liquid colorless mild, fruity 26 126 -77 .8826 15 @25

4.0 ca. 0.7%



Fire Highly flammable. No flames, no sparks,no contact with hotsufaces


Inhalation Cough. Dizziness. Dullness. Headache.Nausea.

Local exhaust orbreathing protection.


Skin Dry skin. Redness. Protective gloves andclothing.




Rinse mouth. Do notinduce vomiting. Rest.Refer for medicalattention.




tert-Butyl Peroxybenzoate

CAS No. PS Color Odor FP BP MP d VP VD Sol614-45-9 liquid colorless

to lightyellow

N/A 93 75–76 @0.2 torr

8 1.021 3.36@ 50

6.7 insoluble



Fire Flammable. Contact may cause fire,may accelerate fires. Emits toxicfumes under fire conditions.

No open flames orsparks. No Smoking.

Carbon dioxide, drychemical powder orappropriate foam.



Skin May be harmful if absorbed throughskin.



Eyes May be harmful to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






n-Butylbenzene

CAS No. PS Color Odor FP BP MP d VP VD Sol104-51-8 liquid colorless mild

aromatic54 182–183 -88 0.86 N/A N/A insoluble



Fire Combustible and flammable liquid.Emits toxic fumes under fireconditions.



Inhalation May be harmful by inhalation. Donot breathe vapor.



Skin May be harmful absorbed throughskin.









sec-Butylbenzene


aromatic45 173–174 -75 0.863 4 N/A N/A






Inhalation Harmful if inhaled. Irritating torespiratory system.











tert-Butylbenzene


aromatic34 169 -58 0.867 4.79

@37.7

3.16@

169

insoluble





Carbon dioxide, drychemical powder orappropriate foam. Watermay cool, but notextinguish.






Eyes May be harmful to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






Calcium Chloride


10043-52-4 solid colorless N/A N/A >1600 782 2.15@ 25

N/A N/A 74.5% @ 20




Inhalation Irritation, coughing, and shortness ofbreath.



Skin Severe irritation, erythema, blistering,exfoliation, and ulceration.



Eyes Irritation, redness, pain, and superficialinjury.


Ingestion Abdominal spasms, nausea,gastrointestinal tract or cardiovascularirregularities.






Calcium Hypochlorite

CAS No. PS Color Odor FP BP MP d VP VD Sol7778-54-3 granular

powderoff–white N/A N/A N/A 100 2.350 N/A N/A decomposes



Fire Contact with other material may causefire. Contact with combustiblematerial may cause fire. Contact withwater liberates a toxic gas. Emitstoxic fumes under fire conditions.



Inhalation Harmful if inhaled. Irritating torespiratory system. Do not breathe indust. Symptoms of exposure mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache, nausea, andvomiting.



Skin Causes skin irritation. Causes burns. Protective gloves andclothing.


Eyes Causes severe eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.

Ingestion Harmful if swallowed. Symptoms ofexposure may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.






Carbon, Decolorizing


7440-44-0 solid black odorless N/A N/A N/A 1.8–2.1

1 @3586

N/A insoluble



Fire Severe fire hazard., may ignite onexposure to air.

No flames, no sparks,no contact with hotsufaces

Regular dry chemical,sand, earth, regular foam,water

Inhalation Mucous membrane irritation Ventilation, localexhaust.










Carvone


2244-16-8 liquid colorless spice-like 98 230 N/A 0.9608 N/A N/A insoluble



Fire Moderate fire hazard. No flames, no sparks,no contact with hotsufaces.


Inhalation Irritation. Ventilation, localexhaust.


Skin Erythema, skin absorption may occur. Protective gloves andclothing.



Ingestion Do not eat or drink inthe laboratory.





Carvone 2,4-Dinitrophenylhydrazone

CAS No. PS Color Odor FP BP MP d VP VD Sol1567-89-1 solid red N/A N/A N/A 126–128 N/A N/A N/A insoluble



Fire Non-flammable. Emits toxic fumesunder fire conditions.



Inhalation May be harmful if inhaled. Veryirritating to respiratory system.






Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






Celite


61790-53-2 solid white tooff-white

odorless N/A 2230 1700 1.9–2.35

none N/A insoluble




Inhalation Physical discomfort of the upperrespiratory tract, coughing, silicosis.



Skin Mechanical irritation. Protective gloves andclothing.


Eyes Mechanical irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Chemically and biologically inert oningestion.






Ceric Ammonium Nitrate


16774-21-3 solid yellow tored

odorless N/A N/A N/A N/A N/A N/A 142.6% @ 25





Water

Inhalation Severe irritation, sore throat,coughing, and shortness of breath.



Skin Irritation, redness, and pain. Protective gloves andclothing.



Ingestion Burning sensation, abdominal pain,nausea, vomiting, and diarrhea.






4-Chlorobenzaldehyde


104-88-1 solid white N/A 87 213–214 45 1.196@ 61

N/A N/A slightlysoluble





Inhalation Irritation, tracheobronchitis,pulmonary edema, bronchopneumonia,and bronchospasms.



Skin Irritation, erythema, swelling, nerveirritation, hyperemia, andpigmentation.



Eyes Strong irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.






4-Chloroacetanilide

CAS No. PS Color Odor FP BP MP d VP VD Sol539-03-7 powder white N/A N/A 331.3–

332.4 @740

177–179 1.385 N/A N/A insoluble



Fire Low fire hazard. Emits toxic fumesunder fire conditions.



Inhalation Irritant if inhaled. Ventilation, localexhaust.


Skin Irritant to skin. Protective gloves andclothing.


Eyes Irritant to eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.






Chloroacetyl Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol79-04-9 liquid colorless N/A N/A 105–106 -22 1.418 60 3.9 decomposes





Dry chemical, foam, orcarbon dioxide.

Inhalation Toxic. Corrosive. Lachrymator.Toxic by inhalation. Inhalation mayresult in spasm, inflammation, andedema of the larynx and bronchi,chemical pneumonitis and pulmonaryedema.



Skin Harmful if in contact with skin.Causes burns.



Eyes Harmful to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion Toxic if swallowed. Exposure toand/or consumption of alcohol mayincrease toxic effects. Exposure cancause, burning sensation, wheezing,laryngitis, shortness of breath,headache, coughing, nausea, andvomiting .






Chlorobenzene


108-90-7 liquid colorless almond-like

28 132 -45 1.107 11.8@ 25

3.9 insoluble



Fire Flammable. Gives off irritating or toxicfumes (or gases) in a fire.

No flames, nosparks, no contactwith hot sufaces.

Powder, water spray,foam, carbon dioxide.

Inhalation Drowsiness. Headache. Nausea.Uconsciousness.

Ventilation, localexhaust., orbreathing protection.


Skin Redness. Roughness. Protective glovesand clothing.

First rinse with plenty ofwater, then removecontaminated clothes andrinse again. Refer formedical attention.

Eyes Redness. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifpossible; seek medicalattention.

Ingestion Abdominal pain. Do not eat or drinkin the laboratory.

Rinse mouth. Refer formedical attention.




2-Chlorobenzoic acid

CAS No. PS Color Odor FP BP MP d VP VD Sol118-91-2 solid white N/A 173 285 138–140 1.54 0.189

@101N/A slightly soluble
















4-Chlorobenzoic Acid


74-11-3 solid colorless N/A 238 N/A 239-241 1.541@ 24

N/A N/A soluble







Skin Irritation, absoption may occur Protective gloves andclothing.








4-Chlorobenzyl Alcohol


873-76-7 solid white N/A N/A 234 70–72 N/A N/A N/A poorly soluble




Carbon dioxide, drychemical powder, foam,water.












1-Chlorobutane


109-69-3 liquid colorless unpleasant -9 78 -123 0.89 80@20

3.2 insoluble



Fire Highly flammable. Gives off irritatingor toxic fumes (or gases) in a fire.

No flames, no sparks,no contact with hotsufaces.


Inhalation Cough. Drowsiness. Sore throat. Local exhaust. Fresh air, rest. Refer formedical attention.

Skin Redness. Protective gloves andclothing.



Ingestion Abdominal cramps. Nausea. Do not eat or drink inthe laboratory.





-Chloro-2,6-dimethylacetanilide







Inhalation Irritating, may be harmful if inhaled. Ventilation, localexhaust.


Skin Irritating, may be harmful if absorbedthrough the skin.



Eyes Irritating, may be harmful to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






2-Chloro-2-methylbutane


594-36-5 liquid colorless N/A -9 85–86 -73 0.866 N/A N/A slightlysoluble



Fire SEVERE fire hazard. Vapors or gasesmay ignite at distant ignition sources.



Inhalation Irritation, narcotic Ventilation, localexhaust.


Skin Irritation, central nervous systemdepression




Ingestion Narcotic Do not eat or drink inthe laboratory.





Chloroform


67-66-3 liquid colorless sweet N/A 60.5–61.5

-63 1.492 160 @20

4.12 0.82% @ 20



Fire Negligible fire hazard. N/A Regular dry chemical,regular foam, water.

Inhalation Irritation, central nervous systemdepression may be preceded byexcitation and inebriation, dizziness,headache, fatigue, salivation, nausea,and vomiting.



Skin Inflammation, destruction of theepithelium, moderate necrosis; someabsorption possible, resulting inweight loss and degenerative kidneychanges.



Eyes Burning pain, lacrimation, redness,damage to corneal epithelium.


Ingestion Burning of the mouth, throat,esophagus, and stomach, nausea,vomiting, diarrhea, cyanosis, musclecramps, irregular respiration,respiratory failure, and liver damage.



Carcinogenicity Suspect carcinogen. Mutagenicity Possible mutagen.



Chloroplatinic Acid


16941-12-1

solid brownish-yellow

odorless N/A 115 60 2.43 N/A 18 very soluble



Fire Not considered to be a fire hazard. Keep away from steeland other commonmetals.

Water spray, carbondioxide, or dry powder.

Inhalation Exposure can cause severe allergiesaffecting the nose, skin and lungs.Irritation and even ulcers can developin the nose. May cause platinosis.Symptoms include wheezing,coughing, tightness of the chest,shortness of breath, cyanosis, andpronounced asthmatic symptoms.

Ventilation, localexhaust., or breathingprotection.

Remove to fresh air. If notbreathing, give artificialrespiration. If breathing isdifficult, give oxygen. Getmedical attention.

Skin May cause platinosis; symptoms mayinclude severe irritation, eczema,urticaria, itching, and dermatitis. Maycause skin allergy.


Immediately flush skinwith plenty of soap andwater. Removecontaminated clothing andshoes. Get medicalattention.

Eyes May cause irritation, itching, andconjunctival vasodilation.

Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftinglower and upper eyelidsoccasionally. Get medicalattention immediately.

Ingestion May cause vomiting and bloodydiarrhea.


Induce vomitingimmediately as directed bymedical personnel. Getmedical attention.




Chlorosulfonic Acid


7790-94-5 liquid colorless pungent N/A 158 N/A 1.753 1 @ 20 4.02 reacts



Fire Negligible fire hazard., reacts violentlywith water.

N/A Carbon dioxide, regulardry chemical.

Inhalation Severe mucous membrane irritation,coughing, choking, headache,dizziness and weakness.



Skin Severe irritation, pain, burns, andbrownish or yellowish stains



Eyes Corneal and conjunctival edema, iritis,corneal erosion and opacity, pain,blurred vision, and photophobia.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible; seek medicalattention immediately, andcontinue to wash eyeswith water.

Ingestion Severe burning pain in the mouth,throat and abdomen, nausea, vomiting,diarrhea, and bloody stools.


Contact physicianimmediately; give largeamounts of water or milk;allow vomiting to occur;when vomiting occurs,keep head lower than hips.




Chromic Anhydride


1333-82-0 solid dark red odorless N/A decomposes 197 2.7 N/A N/A 63 g/100 mL



Fire Not combustible but enhancescombustion of other substances. Manyreactions may cause fire or explosion.

No contact withcombustiblesubstances andreducing agents.


Inhalation Cough. Labored breathing. Shortness ofbreath. Sore throat. Wheezing.

Avoid inhalation offine dust and mist.Ventilation (not ifpowder), localexhaust.


Skin Redness. Skin burns. Pain. Protective glovesand clothing.


Eyes Redness. Pain. Permanent loss ofvision. Severe deep burns.

Safety goggles. First rinse with plenty ofwater for several minutes(remove contact lenses ifeasily possible), then taketo a doctor.

Ingestion Abdominal cramps. Do not eat or drinkin the laboratory.

Rinse mouth. Do notinduce vomiting. Giveplenty of water to drink.Refer for medicalattention.

Carcinogenicity Known carcinogen. Mutagenicity Possible mutagen.



Cinnamaldehyde


104-55-2 oily liquid yellowish cinnamon 71 248 -80 1.05 0.03@ 25

4.6 slightly soluble



Fire Combustible liquid. Fire hazard whenexposed to heat or flame.

No flames, nosparks, no contactwith hot sufaces.


Inhalation Causes irritation to the respiratory tract.Symptoms may include coughing orshortness of breath.


Remove to fresh air. If notbreathing, give artificialrespiration. If breathing isdifficult, give oxygen. Getmedical attention.

Skin Causes irritation to skin. Symptomsinclude redness, itching, and pain. Maycause allergic reaction in sensitiveindividuals.

Protective glovesand clothing.

Remove any contaminatedclothing. Wash skin withsoap or mild detergent andwater for at least 15minutes. Get medicalattention if irritationdevelops or persists.

Eyes Causes irritation, redness, and pain. Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftinglower and upper eyelidsoccasionally. Get medicalattention immediately.

Ingestion May cause vomiting and bloodydiarrhea.


If swallowed, do notinduce vomiting. Givelarge quantities of water.Get medical attention.




trans-Cinnamic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol140-10-3 solid white N/A N/A 300 132–135 1.248 N/A N/A 0.446 g/L

















N-Cinnamyl-m-nitroaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol22774-96-5 solid N/A N/A N/A N/A 115 N/A N/A N/A insoluble



Fire NA* Avoid heat, sparks,flames.


Inhalation NA* Ventilation, localexhaust.


Skin NA* Protective gloves andclothing.


Eyes NA* Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion NA* Do not eat or drink inthe laboratory.


Carcinogenicity N/A* Mutagenicity N/A*

* Toxicological information for the listed chemical is not available; refer to aniline and m-nitroaniline.


N-Cinnamylidene-m-nitroaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol22856-77-5 solid N/A N/A N/A N/A 92 N/A N/A N/A insoluble



Fire NA* Avoid heat, sparks,flames.


Inhalation NA* Ventilation, localexhaust.


Skin NA* Protective gloves andclothing.


Eyes NA* Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion NA* Do not eat or drink inthe laboratory.


Carcinogenicity NA* Mutagenicity NA*

* Toxicological information for the listed chemical is not available; refer to cinnamaldehyde and m-nitroaniline.


Citral


5392-40-5 liquid colorless sharplemon-

like

90 207 N/A 0.88 N/A N/A insoluble inwater



Fire Not considered a fire hazard. Keep away from openflames and sparks.

Carbon dioxide, drychemical, Universal-TypeFoam.

Inhalation May be irritating if inhaled. Ventilation or localexhaust.

Remove from the exposureto fresh air. Contact aphysician as necessary.

Skin May be irritating to skin. Protective gloves andclothing.

Remove any contaminatedclothing or shoes. Washaffected areas thoroughlywith soap and water for atleast 15 minutes. Contacta physician as necessary.

Eyes May be irritating to eyes. Safety goggles. Flush immediately withclean water for at least 15minutes. Contact aphysician immediately.

Ingestion May be harmful if swallowed. Do not eat or drink inthe laboratory..

Give water to dilute.Contact a physicianimmediately.




Cupric Acetate


6046-93-1 solid green N/A N/A N/A 250 (dec) 1.882 N/A 6.9 7.2%





Inhalation Sore throat, coughing, shortness ofbreath, digestive disorders, fever, andillness similar to the common cold,with sensations of chills and stuffinessof the head.



Skin Redness, pain, and irritation. Protective gloves andclothing.


Eyes Redness, pain, blurred vision,possibly conjunctivitis, cornealulcerations, and turbidity.


Ingestion Sore throat, salivation, abdominalpain, vomiting, diarrhea, andhemorrhagic gastritis.


Give water or milk; ifvomiting occurs, keephead lower than hips.




Cupric Sulfate


7758-98-7 solid blue,(pentahy-

drate)

N/A N/A N/A 200 3.603 N/A N/A 14.3% @ 0



Fire Negligible fire hazard. N/A Regular dry chemical,carbon dioxide, water,regular foam

Inhalation Sore throat, coughing, shortness ofbreath, chest pain, a metallic taste,spasm, inflammation, edema of larynxand bronchi, headache, nausea,chemical pneumonitis, pulmonaryedema, and laryngitis. Corrosive tomucous membranes.



Skin Redness, pain, itching,papulovesicular and eczematoidlesions, and corrosive to skin.



Eyes Irritation, redness, pain, blurredvision, and corrosive to eyes. Copperdeposition in the cornea.


Ingestion Sore throat, gastroenteric pain, bluediscoloration of gums and tongue,hepatic cirrhesis, brain damage,demyelination.


Give water or milk; ifvomiting occurs, keephead lower than hips; seekimmediate medicalattention.




Cyclododecanol


1724-39-6 solid white N/A N/A 125 @12 torr

77–78 0.961 N/A N/A slightly



Fire Slight fire hazard. No flames, no sparks,no contact with hotsufaces.


Inhalation No specific data available, possiblycentral nervous system depression.



Skin Irritation, possibly skin absorption andallergic dermatitis.




Ingestion No specific data available, possiblycentral nervous system depression.






Cyclododecanone


830-13-7 solid white N/A 118 106 60 0.906 0.8 @20

N/A 45 ppm @ 20





Inhalation No signs of toxicity reported. Ventilation, localexhaust.










Cyclohexane


110-82-7 liquid colorless sweet -18 80.7 6.5 0.779 95 @20

2.90 insoluble



Fire SEVERE fire hazard., moderateexplosion hazard, vapors or gases mayignite at distant ignition sources.


Regular dry chemical,carbon dioxide, water forcooling, regular foam.

Inhalation Irritation, central nervous systemdepression with headache, dizziness,dullness, nausea, vomiting,degenerative changes in the heart,lungs, liver, kidneys, and brain.



Skin Irritation, redness, and dryness. Protective gloves andclothing.


Eyes Irritation, tearing, redness, andconjunctivitis.


Ingestion Central nervous system depression;aspiration may result in chemicalpneumonitis.


Contact physicianimmediately. Give wateror milk; if vomitingoccurs, keep head lowerthan hips.




Cyclohexane-cis-1,2-dicarboxylic Acid


610-09-3 solid white N/A N/A N/A 193–195

N/A N/A N/A slightly soluble















cis-1,2-Cyclohexanediol

CAS No. PS Color Odor FP BP MP d VP VD Sol1792-81-0 solid white N/A N/A 117@14 99-101 1.183 N/A N/A soluble



Fire Fire possible at elevated temperaturesor by contact with an ignition source.Emits toxic fumes under fireconditions.



Inhalation Irritant to respiratory system Ventilation, localexhaust.




Eyes Irritant to eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids occasionally.Seek medical advice.






Cyclohexanol


108-93-0 liquid colorless pungent 67 160 20–22 0.948 1.0 @21

3.5 soluble





Regular dry chemical,carbon dioxide, water,regular foam, alcoholresistant foam.

Inhalation Irritation, central nervous systemdepression, dizziness, drowsiness,headache, nausea, and vomiting.



Skin Irritation, defatting of the skin,absorption may lead to central nervoussystem depression, headache,dizziness, drowsiness, nausea, andvomiting.



Eyes Irritation, redness, pain. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Irritation, coughing, abdominal pain,diarrhea, central nervous systemdepression, headache, weakness,dizziness, drowsiness, nausea, andvomiting.


If vomiting occurs, keephead lower than hips; getimmediate medicalattention.




Cyclohexanone


108-94-1 liquid colorless minty,sweet

46 155 -47 0.947 2 @ 20 3.4 slightlysoluble





Alcohol resistant foam,carbon dioxide, regular drychemical.

Inhalation Irritation, changes in the sense ofsmell, respiratory system changes,narcosis, central nervous systemdepression, headache, dizziness,lethargy, and unconsciousness.



Skin Irritation, burns, labored breathing,hypnotic signs, defatting,dermatitis,and peritoneal and intestinalcongestion.



Eyes Irritation, pain, redness, lacrimation,and corneal injury.


Ingestion Coughing, central nervous systemdepression, dullness, gastrointestinalirritation, and unconsciousness.






Cyclohexanone Semicarbazone

CAS No. PS Color Odor FP BP MP d VP VD Sol1589-61-3 solid colorless NA NA NA 167 1.223 NA NA 6 g/L



Fire Flammable, emits toxic fumes underfire conditions.*



Inhalation May be harmful if inhaled.* Ventilation, localexhaust.


Skin May be irritating to the skin.* Protective gloves andclothing.


Eyes Dust, vapor, or mist may be irritatingto the eyes.*


Ingestion May be harmful if swallowed.* Do not eat or drink inthe laboratory.



* Toxicological information for the listed chemical is not available. Information given pertains to acetonesemicarbazone and is intended to be used for comparison of a similar compound. Other effects may result fromcontact, inhalation, or ingestion.


Cyclohexene


110-83-8 liquid colorless sweet -20 82 -104 0.8102 67 @20

2.8 insoluble




NO flames, NOsparks, NO contactwith hot surfaces.

Carbon dioxide, regular drychemical, water.

Inhalation Irritation, central nervous systemdepression, headache, dizziness,drowsiness, labored breathing, andkidney and liver damage.


Remove from exposureimmediately, keep warmand at rest. get medicalattention immediately.

Skin Defatting of the skin, redness, andburning sensation.



Eyes Redness and irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Nausea, labored breathing, centralnervous system involvement,pulmonary aspiration, and pneumonia.


If vomiting occurs, keephead lower than hips;contact physicianimmediately.




4-Cyclohexene-cis-1,2-dicarboxylic Acid


935-79-5 solid colorless N/A N/A N/A 103–104

N/A N/A N/A partially soluble





Inhalation Sore throat and coughing.* Ventilation, localexhaust.


Skin Irritation.* Protective gloves andclothing.


Eyes Redness, pain, and irritation.* Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Irritation of the throat and abdominalspasms.*




*Toxicological information for the listed chemical is not available. Information given pertains to phthalic acid andis intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, oringestion.


1,3-Cyclopentadiene


542-92-7 liquid colorless petroleumodor

25 40 N/A 0.8021 249@ 12

2.3 insoluble






Inhalation Irritation, headache, dizziness,dullness, and central nervous systemeffects.


Remove from exposure;get medical attention

Skin Irritation, local redness Protective gloves andclothing.

Remove contaminatedclothes and jewelry.Thoroughly wash skinwith water. Seek medicalattention if needed.

Eyes Irritation, redness, pain Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, nausea Do not eat or drink inthe laboratory.

If vomiting occurs, keephead lower than hips. Getmedical attention ifneeded.




Decanedioyl Dichloride

CASNo.

PS Color Odor FP BP MP d VP VD Sol

111-19-3 liquid color-less

pungentodor

>110 168 @ 12 torr N/A 1.121 N/A N/A decomposes




Carbon dioxide, regular drychemical

Inhalation Irritation, coughing, choking, pain,burns, pulmonary edema, and tightnessin the chest.


Remove from exposureimmediately, keep warmand at rest get medicalattention immediately.

Skin Irritation, pain, burns Protective glovesand clothing.


Eyes Irritation, pain, burns Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water.

Ingestion Pain, severe burns, discoloration of thetissues, and swallowing and speech maybe difficult or impossible.






Dibasic Potassium Phosphate


7758-11-4 crystals orpowder

white odorless N/A N/A >465 N/A N/A N/A 150 g/100 mL



Fire Not considered a fire hazard. Avoid open flamesand sparks.

Use any means suitable forextinguishing surroundingfire.

Inhalation Not expected to be a health hazard. Ventilation, localexhaust., or breathingprotection.

Remove to fresh air. Getmedical attention for anybreathing difficulty.

Skin No adverse effects expected. Protective gloves andclothing.

Wash exposed area withsoap and water. Getmedical advice if irritationdevelops.

Eyes No adverse effects expected but dustmay cause mechanical irritation.

Safety goggles. Wash thoroughly withrunning water. Getmedical advice if irritationdevelops.

Ingestion Symptoms may include vomiting,lethargy, diarrhea, blood chemistryeffects, cardiac effects and centralnervous system effects.


If swallowed, give severalglasses of water to drinkto dilute. If large amountswere swallowed orsymptoms occur, getmedical advice.




o-Dichlorobenzene


95-50-1 viscousliquid

paleyellow

odorless 66 180 -17 1.006 1.2 torr@ 20

5.1 practicallyinsoluble



Fire Combustible. No flames, nosparks, no contactwith hot surfaces.


Inhalation Cough. Drowsiness. Sore throat.Unconsciousness.

Ventilation, localexhaust., orbreathing protection.


Skin Redness. Burning sensation. Symptomsmay be delayed. Blisters.


Remove contaminatedclothes. Rinse skin withplenty of water or shower.Refer for medicalattention.

Eyes Redness. Pain. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifeasily possible. Seekmedical attention.

Ingestion Burning sensation. Diarrhea. Nausea.Vomiting.






1,2-Dichlorobutane


616-21-7 liquid colorless N/A 26 125 N/A 1.112 28 N/A insoluble



Fire Flammable liquid. Emits toxic fumesunder fire conditions. Vapor maytravel considerable distance to ignitionsource and flash back.



Inhalation Avoid breathing vapor. Harmful ifinhaled. Symptoms of exposure mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache, nausea, andvomiting.



Skin Causes skin irritation. May beharmful if absorbed through skin.



Eyes Causes eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.



If swallowed wash outmouth with water.




1,3-Dichlorobutane

CAS No. PS Color Odor FP BP MP d VP VD Sol1190-22-3 liquid colorless N/A 30 134 N/A 1.115 N/A N/A insoluble






Inhalation Avoid breathing vapor. Harmful ifinhaled. Symptoms of exposure mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache, nausea, andvomiting.



Skin Harmful if absorbed through skin. Protective gloves andclothing.


Eyes Lachrymator. Causes eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.







1,4-Dichlorobutane

CAS No. PS Color Odor FP BP MP d VP VD Sol110-56-5 liquid colorless NA 39 161–163 -38 1.160 NA NA insoluble

















Dichloromethane


75-09-2 liquid colorless sweet none 40 -97 1.325 400 @ 24

2.9 1.32% @ 20




Carbon dioxide, regulardry chemical, and water.

Inhalation Irritation, lightheadedness, dizziness,tingling, numbness of the extremities,sensation of heat, sensation of fullnessin the head, drunkenness, mentalconfusion, nausea, headache, andfatigue.



Skin Irritation, possibly burns, skinabsorption may occur causing effectsdetailed in inhalation.



Eyes Pain, and extreme irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Rapid, then slowed respiration,gastrointestinal ulceration andhemorrhage, and unconsciousness,central nervous system depression, andliver and kidney damage.



Carcinogenicity Known carcinogen. Mutagenicity Possible mutagen.



Dicyclopentadiene


77-73-6 solid colorless pungent 32 164–172 dec

32-35 0.979@ 20

1.4 @20

4.6 insoluble



Fire Severe fire hazard., vapors or gasesmay ignite at distant ignition sources.



Inhalation Irritation of mucous membranes andupper respiratory tract, headache,vomiting, nausea, dizziness, sneezing,coughing, and narcotic effects.



Skin Severe irritation and redness. Protective gloves andclothing.


Eyes Irritation, smarting, redness, and pain. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, nausea, and focalhemorrhage of the kidney, intestine,stomach, bladder, and lung.


Contact a physicianimmediately. Give wateror milk; if vomitingoccurs, keep head lowerthan hips.




Diethylamine

CAS No. PS Color Odor FP BP MP d VP VD Sol109-89-7 liquid colorless fish-like -29 55 -50 0.707 731 2.5 soluble



Fire Flammable. Emits toxic fumes underfire conditions. Vapor may travelconsiderable distance to source ofignition and flashback. Container mayexplode under fire conditions.



Inhalation Toxic. Corrosive. Lachrymator. Toxicby inhalation. Inhalation may result inspasm, inflammation, and edema of thelarynx and bronchi, chemicalpneumonitis and pulmonary edema.



Skin Harmful if in contact with skin.Causes burns.




Ingestion Toxic if swallowed. Exposure to and/orconsumption of alcohol may increasetoxic effects. Exposure can cause,burning sensation, wheezing,laryngitis, shortness of breath,headache, coughing, nausea, andvomiting .






Diethyl Benzylphosphonate


1080-32-6 liquid colorless N/A 109 106–108

N/A 1.095 N/A N/A insoluble




Carbon dioxide, regularchemical powder, foam,water












Diethyl Ether


60-29-7 liquid colorless sweet -40 35 -116 0.7 442 @20

2.6 6.9%



Fire Severe fire hazard., severe explosionhazard, may form explosive peroxides,vapors or gases may ignite at distantignition sources.



Inhalation Central nervous system depressionwith drowsiness, dizziness, nausea,headache, and lowering of the pulseand body temperature.



Skin Irritation, defatting, and drying of theskin.



Eyes Painful inflammation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Central nervous system depressionwith nausea, vomiting, drowsiness,dizziness; stomach may becomepromptly distended, which may hinderbreathing


Contact physicianimmediately.




N,N-Diethyl-2,6-dimethylacetanilide

CAS No. PS Color Odor FP BP MP d VP VD Sol137-58-6 solid white N/A 71.1 180–182

@ 466–69 N/A N/A N/A insoluble








Skin Harmful if absorbed through the skin. Protective gloves andclothing.


Eyes May be irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.





Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP= boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specificgravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density (g/mL); Sol= solubility in water; N/A = not available or not applicable.

Diethylene Glycol


111-46-6 viscousliquid

colorless odorless 124 245 -6.5 1.12 1 @91.8

3.66 infinitelysoluble



Fire Combustible. No flames, no sparks,no contact with hotsurfaces.

Powder, alcohol-resistantfoam, water in largeamounts, carbon dioxide.

Inhalation Cough. Dizziness. Ventilation, localexhaust.

Remove from exposureimmediately; fresh air,rest.


Remove contaminatedclothes. Rinse and thenwash skin with water andsoap.

Eyes Redness. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifeasily possible; seekmedical attention.

Ingestion Abdominal pain. Nausea. Vomiting.Dizziness. Drowsiness.Unconsciousness. Confusion.


Rinse mouth. Give aslurry of activated charcoalin water to drink. Refer formedical attention.




Dimethyl Fumarate


624-49-7 solid colorlessto white

odorless N/A 192–193

104–107 1.37 N/A N/A almostinsoluble




Regular dry chemical,carbon dioxide, regularfoam.

Inhalation Irritation, coughing, and dyspnea. Ventilation, localexhaust.


Skin Irritation and redness. Protective gloves andclothing.



Ingestion Relatively non-toxic; large amountsmay cause sore throat, vomiting, andabdominal pain.






Dimethyl Maleate


624-48-6 liquid colorless N/A 91 204–205

N/A 1.152 1 @45.7

4.97 insoluble




Regular dry chemical,carbon dioxide, regularfoam.

Inhalation Irritation, coughing, and dyspnea. Ventilation, localexhaust.


Skin Irritation, redness, and pain. Protective gloves andclothing.


Eyes Irritation, redness, pain, and cornealerosion.


Ingestion Sore throat, abdominal pain, andvomiting.






Dimethyl Sulfoxide

CAS No. PS Color Odor FP BP MP d VP VD Sol67-68-5 liquid colorless N/A 87 189 18.4 1.100 0.42 2.7 miscible



Fire Combustible liquid. Emits toxicfumes under fire conditions. Can reactviolently with several reagents. Whenheated above boiling point,formaldehyde, methyl mercaptan, andsulfur dioxide are evolved.





Skin Readily absorbed through skin. Avoidcontact with DMSO solutionscontaining toxic material. DMSOmay carry such materials into thebody.









2,6-Dimethylaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol87-62-7 liquid pale yellow N/A 91 214@739 10–12 0.984 <0.01 N/A N/A



Fire Combustible. Emits toxic fumesunder fire conditions. Container mayexplode under fire conditions.


Water spray, Drychemical, foam, or carbondioxide.

Inhalation Highly Toxic. Toxic by inhalation. Ventilation, localexhaust.


Skin Toxic if in contact with skin. Protective gloves andclothing.


Eyes Irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advise.

Ingestion Toxic if swallowed. Do not eat or drink inthe laboratory.

If swallowed wash outmouth with waterprovided person isconscious. Call aphysician.

Carcinogenicity Possible cancinogen. Mutagenicity Not a known mutagen.



2-(2,4-Dimethylbenzoyl)benzoic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol577-56-0 powder white odorless N/A N/A 116–118 N/A N/A N/A insoluble



Fire Emits toxic fumes under fireconditions.*


Water spray, dry chemical,foam, or carbon dioxide.



Skin May irritate the skin.* Protective gloves andclothing.


Eyes May irritate the eyes.* Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.



Carcinogenicity Not a known carcinogen.* Mutagenicity Not a known mutagen.

* Toxicological information for the listed chemical is not available. Information given pertains to 2-acetylbenzoicacid and is intended to be used for comparison of a similar compound. Other effects may result from contact,inhalation, or ingestion.


N,N-Dimethylformamide


68-12-2 liquid colorless pungent,fishy

58 153 -61 0.94 2.7 torr@ 20

2.5 miscible



Fire Flammable. Gives off irritating ortoxic fumes (or gases) in a fire.

No flames, no sparks,no contact with hotsurfaces. No contactwith oxidizing agents.

Powder, alcohol-resistantfoam, water spray, carbondioxide.

Inhalation Abdominal pain. Diarrhea. Nausea.Vomiting. Nervous agitation. Facialflushing. Alcohol intolerance.


Fresh air, rest. Artificialrespiration if indicated.Refer for medicalattention.

Skin MAY BE ABSORBED! Dry skin.Redness. Roughness.


Remove contaminatedclothes. Rinse and thenwash skin with water andsoap. Refer for medicalattention.


Ingestion Abdominal pain. Diarrhea. Nausea.Vomiting. Nervous agitation. Facialflushing. Alcohol intolerance.






4,4-Dimethyl-2-cyclohexen-1-one


1073-13-8 liquid colorless N/A 64 72–73.5

N/A 0.944 N/A N/A poorly soluble





Inhalation May be harmful Ventilation, localexhaust.


Skin Irritation, may be harmful if absorbedthrough skin




Ingestion May be harmful Do not eat or drink inthe laboratory.


Carcinogenicity Not a known carcinogen. Mutagenicity Possiblemutagen.



2,6-Dimethylnitrobenzene

CAS No. PS Color Odor FP BP MP d VP VD Sol81-20-9 liquid light yellow N/A 87 225 14–16 1.112 N/A N/A insoluble



Fire Combustible liquid. Emits toxic fumesunder fire conditions.



Inhalation Highly toxic if inhaled. Ventilation, localexhaust.


Skin Toxic if absorbed through skin. Causesskin irritation.




Ingestion May be fatal if swallowed. Do not eat, drink, orsmoke during work.




Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specificgravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density (g/mL); Sol =solubility in water; N/A = not available or not applicable.

1,3-Dinitrobenzene

CAS No. PS Color Odor FP BP MP d VP VD Sol99-65-0 powder orange N/A N/A 297 88–90 1.368 N/A N/A 0.808 g/L



Fire May be shock sensitive. Emits toxicfumes under fire conditions. Capableof creating a dust explosion. Mayexplode when heated.



Inhalation Highly Toxic by inhalation, danger ofcumulative effect, risk of irreversibleeffects.



Skin May be fatal if absorbed through skin.Causes cyanosis, which may bedelayed 2–4 hours.




Ingestion Symptoms of exposure may includeburning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache, nausea, andvomiting.






3,5-Dinitrobenzoic Acid


99-34-3 solid white N/A N/A N/A 205–207 N/A N/A N/A 0.1–1.0%















3,5-Dinitrobenzoyl Chloride


99-33-2 solid yellow pungent N/A 196 69–71 1.33 9–12@ 196

7.6–8.0

decomposes




Regular dry chemical,regular foam.

Inhalation Spasm, inflammation, and edema ofthe larynx and bronchi, chemicalpneumonitis, and pulmonary edema.



Skin Corrosive Protective gloves andclothing.


Eyes Corrosive Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, get medicalattention immediatly,continue washing withwater.

Ingestion Corrosive Do not eat or drink inthe laboratory.

Contact physicianimmediately; give largeamounts of water or milk,allow vomiting to occur;when vomiting occurs,keep head lower than hips.




2,4-Dinitrophenylhydrazine


119-26-6 solid orange N/A 209 N/A N/A N/A N/A N/A 0.1-1%



Fire Severe fire hazard., severe explosionhazard.

Avoid friction, shock,and heat

Flood with water, if nowater is available use drychemical or earth.

Inhalation Irritation, cyanosis, nausea, centralnervous system effects with tremors,excitability, and convulsions.



Skin Irritation, skin absorption may occur.Sensitization dermatitis may occur inpreviously exposed persons. Ifsufficient amounts are absorbed,systemic toxicity may occur asdetailed in acute inhalation.



Eyes Irritation . Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention.

Ingestion Systemic toxicity may occur asdetailed in acute inhalation.






1,4-Dioxane

CAS No. PS Color Odor FP BP MP d VP VD Sol123-91-1 liquid colorless sweet 12 100–102 11.8 1.034 40 3 soluble



Fire Flammable, may form explosiveperoxides.



Inhalation Harmful to respiratory system Ventilation, localexhaust.




Eyes Irritant to eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids occasionally.Seek medical advice.

Ingestion Harmful if swallowed. Symptomsinclude nausea, vomiting, anorexia,weakness, dizziness, vertigo, headacheand sweating.



Carcinogenicity Probable carcinogen Mutagenicity Not a known mutagen.



Diphenyl Ether


101-84-8 solid colorless unpleasant 115 259 26–30 1.073 0.0213@ 20

5.8 0.0021%




Regular dry chemical,carbon dioxide. Water orfoam may cause frothing.

Inhalation Irritation, nausea. Ventilation, localexhaust.





Ingestion Nausea, vomiting, sore throat,abdominal pain, and diarrhea .






Diphenylacetylene


501-65-5 solid white N/A N/A 170 @19

59–61 N/A N/A N/A insoluble




Carbon dioxide, regularchemical powder, foam,water.







Ingestion May be harmfu.l Do not eat or drink inthe laboratory.





Disodium Hydrogen Phosphate


7558-79-4 granularsolid

colorless odorless N/A N/A 48.1 1.7 N/A N/A soluble



Fire Not considered to be a fire hazard. N/A Use any means suitable forextinguishing surroundingfire.

Inhalation May cause irritation to the respiratorytract. Symptoms may includecoughing and shortness of breath.



Skin May cause irritation with redness andpain.


Immediately flush skinwith plenty of water for atleast 15 minutes. Removecontaminated clothing andshoes. Get medicalattention if irritationdevelops.

Eyes May cause irritation, redness and pain. Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftingupper and lower eyelidsoccasionally. Get medicalattention if irritationpersists.

Ingestion Symptoms may include vomiting,lethargy, diarrhea, blood chemistryeffects, heart disturbances and centralnervous system effects.






Dry Ice


124-38-9 solid white none none -79 -78.5 1.56@ -79

569 @-82

1.52 1.6%



Fire Negligible fire hazard. N/A Use extinguishing agentsappropriate forsurrounding fire

Inhalation Acidic taste, headache, vertigo, nausea,labored breathing, weakness,drowsiness, mental confusion, increasein blood pressure, pulse, andrespiratory rate, visual disturbances,profuse perspiration, general feeling ofdiscomfort, and loss of consciousness.



Skin Frostbite with redness, tingling, pain,numbness, hard and white skin, andblisters.


Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, warm affected areaswith warm water, and getmedical help if needed.

Eyes Stinging, frostbite, redness, pain, andblurred vision.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately,continue to wash eyeswith water until medicalhelp arrives.

Ingestion Frostbite. Do not eat or drink inthe laboratory.





Ethanol


64-17-5 liquid colorless alcoholic 13 78 N/A 0.7893 40 torr@ 19

1.59 soluble






Inhalation Irritation, central nervous systemdepression with headache, stupor,fatigue, dizziness, drowsiness,dullness, lassitude, and loss ofappetite may occur.



Skin Redness, burning, contact dermatitis,skin absorption may occur.



Eyes Immediate burning, stinging, reflexclosure of the lids, tearing, andtemporary injury of the cornealepithelium.


Ingestion Emotional lability, decreasedinhibitions, exhilaration, boastfulness,belligerency, visual impairment,muscular incoordination, sensorydisturbances, dilated pupils, rapidpulse, nausea, vomiting, sweating,drowsiness, and stupor.






Ethyl Acetate


141-78-6 liquid colorle ss fruity -3 76.5–77.5

-84 0.902 73 @20

3 8.7%






Inhalation Irritation, headache, coughing,dizziness, drowsiness, shortness ofbreath, narcotic effects, andunconsciousness.



Skin Irritation, redness, and defatting actionon the skin.



Eyes Irritation, redness, pain, andlacrimation.


Ingestion Sore throat, abdominal pain, diarrhea,central nervous system depression,dizziness, headache, fatigue,drowsiness, and unconsciousness.






Ethyl 4-Aminobenzoate

CAS No. PS Color Odor FP BP MP d VP VD Sol94-09-7 solid white odorless N/A N/A 88-90 1.11 N/A N/A slightly soluble



Fire Noncombustible. Emits toxic fumesunder fire conditions.


Use extinguishing agentsappropriate forsurrounding fire.







If swallowed wash outmouth with waterprovided person isconscious .Call aphysician.




Ethylbenzene


100-41-4 liquid colorless distinct 22 136 N/A 0.8670 7.1 @20

3.7 0.015%






Inhalation Severe irritation, cough, fatigue,depression, dizziness, and headache.



Skin Irritation, inflammation, 1st or 2nddegree burns; absorption through skinmay cause systemic toxicity.



Eyes Irritation and lacrimation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, nausea, vomiting,aspiration with extensive edema andhemorrhage of lung tissue.


Contact physicianimmediately. Give wateror milk; if vomitingoccurs, keep head lowerthan hip.




Ferric Chloride


10025-77-1 solid yellow unpleasant N/A 280–285

37 1.82 1 N/A 91.9% @ 20




Inhalation Severe respiratory tract irritation, sorethroat, cough, and labored breathing.



Skin Severe irritation, pain, and burns. Protective gloves andclothing.


Eyes Redness, pain, blurred vision,lacrimation, corneal injury and burns.


Ingestion Abdominal pain, prolonged vomiting,watery and then tarry diarrhea, intensedehydration, shock, cyanosis, rapidrespiration, drowsiness, and dilatedpupils.






Ferrous Ammonium Sulfate


10045-89-3 crystals pale blue-green

odorless N/A N/A 110-112 1.86 N/A >1 26.9 g/100 mL



Fire Not considered to be a fire hazard. No open flames orsparks.


Inhalation Causes irritation to the respiratorytract. Symptoms may includecoughing, shortness of breath.


Remove to fresh air. Getmedical attention.



Immediately flush skinwith plenty of water for atleast 15 minutes. Removecontaminated clothing andshoes. Get medicalattention.

Eyes Causes irritation, redness, and pain. Safety goggles.. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftingupper and lower eyelidsoccasionally. Get medicalattention.

Ingestion Causes irritation to the gastrointestinaltract. Symptoms may include nausea,vomiting and diarrhea. Low toxicity insmall quantities but larger dosagesmay cause nausea, vomiting, diarrhea,and black stool. Pink urinediscoloration is a strong indicator ofiron poisoning.






Fluorene



N/A N/A 298 114–116 1.202 10 @146

N/A 0.2 ppm









Eyes Irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention.

Ingestion Irritation. Do not eat or drink inthe laboratory.





9-Fluorenone


486-25-9 solid yellow N/A 163 342 80–8 3 1.13 N/A N/A insoluble







Skin Irritation, tumors, and may be harmfulif absorbed through skin.









Fluorescein

CAS No. PS Color Odor FP BP MP d VP VD Sol2321-07-5 powder orange-

brownN/A N/A N/A 320 N/A N/A N/A 0.05g/100g



Fire Emits toxic fumes under fireconditions













Formic Acid


64-18-6 liquid colorless pungent 69 100.8 8.5 1.2 23 @20

1.6 miscible





Regular dry chemical,carbon dioxide, regularfoam, alcohol resistantfoam.

Inhalation Irritation, throat discomfort,lightheadedness, nausea, cough,rhinitis, nasal discharge, corrosion,dyspnea, bronchitis, pulmonaryedema, shock, and death.


Remove from exposureimmediately, keep warmand at rest, get medicalattention immediately.

Skin Irritation, redness, pain, corrosion,subsequent dermatitis, second degreeburns, blistering, vesiculation, keloidformation, and absorbed through theskin producing severe toxic effects.



Eyes Irritation, lacrimation, acuteinflammation of the eyes,conjunctivitis, keratitis, pain, redness,blurred vision, burns, tissue damage,and permanent corneal scarring.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water until medicalhelp arrives.

Ingestion Burning sensation in the mouth,salivation, corrosion of the glottis,esophagus, and stomach, abdominalpain, nausea, diarrhea, and difficultybreathing.


Contact a physicianimmediately. Give wateror milk; if vomitingoccurs, keep head lowerthan hips.




D-Fructose

CAS No. PS Color Odor FP BP MP d VP VD Sol57-48-7 solid colorless odorless N/A N/A 119–122 1.60 N/A N/A soluble
















2-Furaldehyde

CAS No. PS Color Odor FP BP MP d VP VD Sol98-01-1 liquid light

yellowN/A 58 162 -36 1.160 1.7 3.31 77.833 g/L



Fire Combustible liquid. Emits toxicfumes under fire conditions.



Inhalation Toxic by inhalation. Do not breathevapor. May cause sensitization byinhalation. Symptoms may includeburning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache nausea and vomiting.May cause nervous systemdisturbances.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Seek medicalattention.

Skin Toxic in contact with skin. Causesburns and may cause sensitizationwith contact. May cause allergicreactions and photosensitivity.



Eyes Irrritant and causes burns. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.

Ingestion Toxic if swallowed. Symptoms mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache nausea and vomiting.May cause nervous systemdisturbances.






2-Furaldehyde Semicarbazone

CAS No. PS Color Odor FP BP MP d VP VD Sol2411-74-7 solid off-white odorless N/A N/A 202 N/A N/A N/A poorly soluble



Fire Flammable, emits toxic fumes underfire conditions.*





Skin May be irritating to the skin.* Protective gloves andclothing.


Eyes Dust, vapor, or mist may be irritatingto the eyes.*





* Toxicological information for the listed chemical is not available. Information given pertains to acetonesemicarbazone and is intended to be used for comparison of a similar compound. Other effects may result fromcontact, inhalation, or ingestion.


D-Glucose


50-99-7 crystals orpowder

colorlessor white

odorless N/A N/A 83 1.56 N/A N/A 1 g/1.1 mL



Fire Not considered to be a fire hazard. No open flames orsparks.


Inhalation No adverse health effects expectedfrom inhalation.


Not expected to requirefirst aid measures.

Skin Not expected to be a health hazardfrom skin exposure.


Not expected to requirefirst aid measures.

Eyes No adverse effects expected but dustmay cause mechanical irritation.


Ingestion Extremely large oral dosages mayproduce gastrointestinal disturbances.


Give several glasses ofwater to drink to dilute. Iflarge amounts wereswallowed, get medicaladvice.




tris-[3-(Heptafluoropropylhydroxymethylene)-(+)-camphorato]europium

CAS No. PS Color Odor FP BP MP d VP VD Sol34788-82-4 solid yellow N/A N/A N/A 156–158 N/A N/A N/A N/A








Skin May irritate skin. Protective gloves andclothing.


Eyes Vapor or mist may be harmful to theeyes.







Heptane


142-82-5 liquid colorless mild,gasoline-

like

-4 91 -91 0.697 40 torr@ 20

3.5 insoluble



Fire Severe fire hazard No flames, no sparks,no contact with hotsurfaces.

Powder, AFFF, foam,carbon dioxide. NO water.

Inhalation Dullness. Headache. Ventilation, localexhaust.


Skin Dry skin. Protective gloves andclothing.

Remove contaminatedclothes. Rinse and thenwash skin with water andsoap. Refer for medicalattention. Wear protectivegloves and clothing. whenadministering first aid.


Ingestion Abdominal cramps. Burningsensation. Nausea. Vomiting.


Rinse mouth. Do notinduce vomiting. Rest.Refer for medicalattention.




Hexane

CAS No. PS Color Odor FP BP MP d VP VD Sol110-54-3,107-83-5

liquid colorless hydrocarbon-like

-7 69 -95 0.660 125 3 slightly soluble



Fire Severe fire hazard; vapor may travelconsiderable distance to ignition sourceand flash back.

No flames, nosparks, no contactwith hot surfaces.


Inhalation Toxic by inhalation. Vapor is irritatingto the upper respiratory track. Symptomsmay include headache, dizziness, andnausea.



Skin May cause skin irritation. Protective glovesand clothing.


Eyes May causes eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids occasionally.Seek medical advice.

Ingestion Toxic by ingestion. Symptoms mayinclude headache, dizziness and nausea.


If swallowed, wash outmouth with water.




1,6-Hexanediamine


6055-52-3 solid colorless fishy N/A 204–205 41–42 N/A N/A N/A soluble



Fire Slight fire hazard. Avoid heat, flames,and sparks



Remove from exposureimmediately; get medicalattention


Remove contaminatedclothes and jewelry;thoroughly wash skin withwater.

Eyes Irritation Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediatly.

Ingestion Not available Do not eat or drink inthe laboratory.

If vomiting occurs, keephead lower than hips; getmedical attention ifneeded.




1-Hexene


592-41-6 liquid colorless faint,pleasant

-26 63 -140 0.67 310torr @

20

3.0 negligible





Inhalation Cough. Dizziness. Drowsiness. Sorethroat. Unconsciousness. Vomiting.



Skin Dry skin. Redness. Protective gloves andclothing..

Remove contaminatedclothes. Rinse and thenwash skin with water orshower. Refer for medicalattention.


Ingestion Cough. Dizziness. Drowsiness. Sorethroat. Unconsciousness. Vomiting.


Rinse mouth. Do notinduce vomiting. Refer formedical attention.




Hydrobromic Acid, Concentrated


10035-10-6 liquid colorlessto yellow

irritating N/A 74 @100torr

N/A 1.5 N/A 2.8 miscible




Inhalation Irritation, coughing, choking, burns ofthe mucous membranes, headache,nausea, pulmonary edema, tightness inthe chest, dizziness, and weak, rapidpulse.



Skin Severe pain, burns, and brownish oryellowish stains



Eyes Pain, lacrimation, photophobia, burns,and blindness

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention, and continue towash eyes with water untilmedical help arrives.

Ingestion Immediate pain, difficulty or inabilityto swallow or speak, respiratorydistress, thirst, nausea, vomiting,diarrhea, weak, rapid pulse, andshallow respiration.






Hydrochloric Acid Solutions (9-37%)


7647-01-0(HydrogenChloride)

liquid colorlessor yellow

irritating N/A 65.5–110

N/A 1.07–1.18

30 @20

1.3 soluble




Inhalation Burning of the throat, coughing,choking, inflammation, ulceration ofthe nose, throat or larynx, bronchitis,pneumonia, palpitations, andheadache.



Skin Severe irritation, inflammation,ulceration, necrosis, chemical burns,shock, rapid pulse, sweating, andcollapse.



Eyes Severe irritation, conjunctivitis,corneal necrosis, and burns withimpairment or permanent loss ofvision.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention, continue towash eyes with water.

Ingestion Burns of the mouth, throat, esophagusand stomach, pain, uneasiness, nausea,salivation, vomiting, diarrhea, chills,shock and intense thirst.






Hydrogen Peroxide (30%)


7722-84-1 liquid colorless pungent N/A 126 -40 1.11 23.3 @20

1 100%



Fire Negligible fire hazard.; may ignite orexplode on contact with combustiblematerials.


Water

Inhalation Irritation, sore throat, coughing,shortness of breath, systemicpoisoning, headache, dizziness,vomiting, diarrhea, and numbness.



Skin Irritation, tingling and whitening ofthe skin, erythema or vesicleformation, severe burns, ulceration.



Eyes Redness, stinging, tearing, blurredvision, severe corneal or conjunctivalulceration, blindness.


Ingestion Irritation and injury to the mouth andthroat, distention of the esophagus andstomach, and stomach and chest pains.






Hydroxylamine Hydrochloride


5470-11-1 crystals colorless odorless N/A N/A 152 1.67 N/A N/A 83 g/100 mL



Fire Not combustible. Gives off irritatingor toxic fumes (or gases) in a fire.

N/A Use extinguishing agentsappropriate forsurrounding fire.

Inhalation Blue lips or fingernails. Blue skin.Headache. Dizziness. Nausea.Confusion. Convulsions.Unconsciousness.



Skin Redness. Pain. Protective gloves andclothing.

Remove contaminatedclothes. Rinse skin withplenty of water or shower.Refer for medicalattention.


Ingestion Blue lips or finger nails. Blue skin.Headache. Dizziness. Nausea.Confusion. Convulsions.Unconsciousness.


Rinse mouth. Give aslurry of activated charcoalin water to drink. Refer formedical attention.




Iodine


7553-56-2 solid purple toblack

pungent N/A 184.4 113.5 4.93 0.305@ 25

8.8 0.03% @ 20






Inhalation Severe irritation of the mucousmembranes, severe cough, headache,and feeling of tightness inthe chest.



Skin Brown discoloration of the skin withmarked erythema, desquamation, andvesiculation with weeping andcrusting.


Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, get medical helpimmediately.

Eyes Burning sensation, irritation, andlacrimation.


Ingestion Inflammation and corrosion of thegastrointestinal tract, browndiscoloration of the lips and mucousmembranes, a burning sensation,nausea, severe vomiting, diarrhea,intense thirst, metallic taste, fever,delirium, and stupor.


Contact physicianimmediately. Give milkthen starch solution; ifvomiting occurs, keephead lower than hips.




Iodine Monochloride


7790-99-0 solid red pungent N/A N/A 27.2 3.240 N/A N/A decomposes




Inhalation Sore throat, coughing, laboredbreathing, fatigue, respiratoryirritation, and pulmonary edema.



Skin Irritation and burns. Protective gloves andclothing.


Eyes Potent lacrimator, burning, and cornealinjury.


Ingestion Sore throat, labored breathing,gastrointestinal irritation, abdominalpain, nausea, and vomiting.






Isobutylbenzene


aromatic54 173 -51 0.853 4.22 N/A insoluble



Fire Combustible and flammable. No flames, no sparks,no contact with hotsurfaces.












(-)-Isopinocampheol


25465-65-0 solid white N/A 93 219 52–55 N/A N/A N/A N/A















Isopropylbenzene


98-82-8 liquid colorless aromatic 31 152.4 -962 0.862 3.2 @20

4.2 insoluble



Fire Highly flammable. No flames, no sparks,no contact with hotsurfaces.


Inhalation Ataxia. Cough. Dizziness. Drowsiness.Headache. Sore throat. Unconsciousness.


Fresh air, rest. Half-upright position. Refer formedical attention.

Skin Dry skin Protective gloves andclothing.


Eyes Redness. Pain Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifpossible; seek medicalattention.

Ingestion Ataxia. Cough. Dizziness. Drowsiness.Headache. Sore throat. Unconsciousness.


Rinse mouth. Do notinduce vomiting. Refer formedical attention.




Isopropylxylenes

CAS No. PS Color Odor FP BP MP d VP VD SolN/A liquid colorless mild

aromaticN/A 193–216 N/A 0.85 N/A N/A insoluble



Fire Combustible liquid. No flames, no sparks,no contact with hotsurfaces.


Inhalation May be harmful if inhaled. Irritatingto respiratory system. Prolongedexposure can cause nausea, headache,and vomiting.



Skin Irritating to the skin. May causedrying, cracking and redness.



Eyes Irritating to the eyes. May causeredness and stinging.


Ingestion May be harmful if swallowed. Maycause irritation to the gastrointestinaltract.






Lead Acetate


301-04-2 solid white pungent N/A N/A 280 3.25 N/A N/A 44.3%




Inhalation Metallic taste, thirst, a burningsensation in the mouth and throat,excessive salivation, abdominal pain,vomiting, fatigue, sleep disturbances,dullness.






Ingestion Symptoms as described in inhalation. Do not eat or drink inthe laboratory.

Contact physicianimmediately. If vomitingoccurs, keep head lowerthan hips. Get medicalattention.




Magnesium


7439-95-4 solid white odorless N/A 1107 649 1.7 @5

1 @621

N/A reacts




Regular dry chemical,sand, lime, soda ash.

Inhalation Burning sensation, coughing,wheezing, laryngitis, headache.



Skin Severe local lesions if particlesperforate the skin or gain accessthrough cuts.



Eyes Formation of hydrogen bubbles. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Gastrointestinal irritation, nausea,vomiting, chills, fever, muscle andjoint pain, anorexia, abdominal pain,and diarrhea.






Maleic Anhydride


108-31-6 solid colorless irritating 103 200 54–56 1.314@ 60

1 @ 44 3.4 reacts




Alcohol resistant foam,carbon dioxide.

Inhalation Irritation; fumes cause: burningsensation in the throat, coughing, andvomiting.



Skin Irritation, inflammation, blistering,burns, and possibly absorbed throughskin.



Eyes Irritation, severe burns; fumes causeconjunctivitis, corneal damage oredema, photophobia, double vision,and lacrimation.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water until medicalhelp arrives.

Ingestion Corrosion, sore throat, abdominalpain, nausea, and vomiting.






Mercuric Oxide


21908-53-2 powder orange-red or

orange-yellow

odorless N/A N/A 500 11.14 N/A N/A insoluble



Fire Substance is a strong oxidizer and itsheat of reaction with reducing agentsor combustibles may cause ignition.Upon heating it decomposes to formoxygen, which increases theflammability of combustibles.



Inhalation Causes irritation to the respiratorytract. Symptoms include sore throat,coughing, pain, tightness in chest,breathing difficulties, shortness ofbreath and headache. Pneumonitis maydevelop. Can be absorbed throughinhalation with symptoms to parallelingestion.



Skin Causes irritation. Symptoms includeredness and pain. May cause burns.May cause sensitization. Can beabsorbed through the skin withsymptoms to parallel ingestion.


Immediately flush skinwith plenty of water for atleast 15 minutes whileremoving contaminatedclothing and shoes. Getmedical attentionimmediately.

Eyes Causes irritation and burns to eyes.Symptoms include redness, pain,blurred vision; may cause serious andpermanent eye damage.


Ingestion Highly toxic! Average lethal dose forinorganic mercury salts is about 1gram. May cause burning of the mouthand pharynx, abdominal pain,vomiting, corrosive ulceration, bloodydiarrhea.


Induce vomitingimmediately as directed bymedical personnel. Getmedical attentionimmediately.




Methanol


67-56-1 liquid colorless alcohol-like

11 64.6–64.7

-98 0.7914 97.25@ 20

1.11 soluble






Inhalation Irritation, coughing, unsteady gait,twitching, constipation, numbness andshooting pains in the hands andforearms.



Skin Irritation, skin absorption may lead tometabolic acidosis and effects on theeyes and central nervous system givenin acute ingestion.



Eyes Irritation, violent inflammation of theconjunctiva, and epithelial defects onthe cornea.


Ingestion Inebriation, drowsiness, coughing,headache, dullness, weakness, vertigo,dizziness, nausea, vomiting,occasional diarrhea, and blindness.






Methyl Acetoacetate

CAS No. PS Color Odor FP BP MP d VP VD Sol105-45-3 liquid colorless sweet 69 169–170 -80 1.076 N/A 4 soluble



Fire Combustible liquid. Avoid heat, sparks,flames.


Inhalation Irritating to respiratory system. Ventilation, localexhaust.




Eyes Can cause blindness. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids occasionally.Seek medical advice.






Methyl Benzoate


93-58-3 liquid colorless fruity 82 198–199

-12 1.094 1 @ 39 4.68 0.016%






Inhalation Irritation, sore throat, and coughing. Ventilation, localexhaust.




Eyes Redness, pain, and irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, vomiting, diarrhea,and depression.






Methyl Iodide

CAS No. PS Color Odor FP BP MP d VP VD Sol74-88-4 liquid colorless acrid N/A 42 -66.1 2.28 400 @

254.9 14 g/100 mL



Fire Not considered to be a fire hazard. Firemay produce poisonous or irritatinggases.


Dry chemical, foam,carbon dioxide, or waterspray.

Inhalation Inhalation of vapors can irritate therespiratory tract. Overexposure mayproduce symptoms of vertigo, deliriumand mental disturbances. Othersymptoms may include slurred speech,drowsiness, coughing, nausea andvomiting.



Skin Causes irritation, rash and blisterformation. Prolonged contact can causeskin burns. Can be absorbed through skinwith toxic effects.


Immediately flush skinwith plenty of soap andwater for at least 15minutes while removingcontaminated clothing andshoes. Get medicalattention, immediately.

Eyes Vapors can cause irritation. Splashesmay cause severe irritation with eyedamage.


Ingestion Ingestion may damage the gastro-intestinal tract. Severe intoxication canoccur with symptoms of central nervoussystem depression.


Induce vomitingimmediately as directed bymedical personnel. Getmedical attentionimmediately.



Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flashpoint (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = meltingpoint (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specifiedtemperature (°C); VD = vapor density relative to air (1.0); Sol = solubility in water; N/A= not available or not applicable.

Methyl Isobutyrate

CAS No. PS Color Odor FP BP MP d VP VD Sol547-63-7 liquid colorless fruity 3 90 N/A 0.891 N/A N/A slightly soluble



Fire Flammable liquid. Avoid heat, sparks,flames.


Inhalation May be harmful by inhalation. Ventilation, localexhaust.




Eyes May cause eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids occasionally.Seek medical advice.






3-Methylbenzoic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol99-94-5 solid white odorless N/A 274–275 180–182 1.27 N/A N/A 0.33 g/L









Skin Irritant. Protective gloves andclothing.


Eyes Vapor or mist may be irritating to theeyes.







(+/-)- -Methylbenzylamine

CAS No. PS Color Odor FP BP MP d VP VD Sol618-36-0 liquid colorless N/A 79 185 @

756 torr-65 0.940 N/A N/A poorly soluble






Inhalation Extremely destructive to tissue of themucous membranes and upperrespiratory tract. Symptoms mayinclude burning sensation, coughing,wheezing, laryngitis, shortness ofbreath, headache nausea and vomiting.



Skin Harmful if absorbed through skin.Extremely destructive to tissue ofskin. Causes burns.




Ingestion Harmful if swallowed. Symptomsmay include burning sensation,coughing, wheezing, laryngitis,shortness of breath, headache nauseaand vomiting.






Methylcyclohexane


108-87-2 liquid colorless sweet -3 101 -126–-126.3

0.77 37 @20

3.4 insoluble



Fire Severe fire hazard., moderate explosionhazard, vapors or gases may ignite atdistant ignition sources.



Inhalation Irritation, light-headedness, drowsiness,lacrimation, salivation, laboredbreathing, diarrhea, and liver andkidney damage.



Skin Irritation, hardening, ulceration, anddefatting.


Remove contaminatedclothes and jewelry,thoroughly wash skin withwater, get medicalattention.

Eyes Conjunctival congestion. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Irritation, lethargy, severe diarrhea,liver and kidney damage, andcirculatory collapse.






2-Methylpropanal


78-84-2 liquid colorless pungent -25 63–64 -65 0.7938 66 @25

2.5 slightlysoluble






Inhalation Irritation, central nervous systemdepression, and symptoms similar toalcohol intoxication.



Skin Irritation, burns, lethal amounts maybe absorbed through skin.



Eyes Lacrimation, irritation, burns. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Central nervous system depression andsymptoms similar to alcoholintoxication.






Methyltrioctylammonium Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol5137-55-3 viscous

liquidcolorlessto paleorange

N/A 109 N/A N/A 0.884 N/A N/A partially soluble






Inhalation Harmful by inhalation. Symptoms ofexposure may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.

Ventilation, localexhaust











2-Methyl-2-butanol


75-85-4 liquid colorless distinct 21 102 -12 0.805 10 @17.2

3.0 slightlysoluble





Alcohol resistant foam,carbon dioxide, regular drychemical, water forcooling

Inhalation Headache, dizziness, nausea, vomiting,diarrhea, coughing, shortness of breath,excitement and delirium.


Remove from exposureimmediately, keep warmand at rest, artificialrespiration if needed; getmedical attention.

Skin Irritation. May be absorbed through theskin, causing headache, dizziness,nausea, vomiting, flushing, rapid pulseand respiration, drop in blood pressure,and unconsciousness.



Eyes Conjunctivitis, double vision andirritation. May be absorbed, causingheadache, dizziness, cough, shortnessof breath, vomiting, excitement anddelirium.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention.

Ingestion Nausea, vomiting, diarrhea, headache,shortness of breath, cough, dizziness,excitement and delirium followed bycoma.






2-Methyl-1-butene


563-46-2 liquid colorless unpleasant <-7 31-32 N/A 0.6504 N/A 2.4 insoluble





Alcohol resistant foam,carbon dioxide, regular drychemical, water forcooling

Inhalation Irritation, central nervous systemdepression, asphyxia


Remove from exposureimmediately, keep warmand at rest, artificialrespiration if needed; getmedical attentionimmediatly.




Ingestion Irritation to the gastrointestinal tract;aspiration into the lungs may causedeath due to chemical pneumonitis.


Contact physicianimmediately. If vomitingoccurs, keep head lowerthan hips;




2-Methyl-2-butene


513-35-9 liquid colorless unpleasant -20 37–38 -134 0.663 N/A 2.4 slightlysoluble



Fire SEVERE fire hazard. Vapors or gasesmay ignite at distant ignition sources


Alcohol resistant foam,carbon dioxide, regular drychemical, water forcooling.

Inhalation Irritation, central nervous systemdepression with dizziness,disorientation, headache, vomiting andnausea; respiratory and cardiacdepression, burning sensation.


Remove from exposureimmediately, keep warmand at rest; get medicalattention immediately.

Skin Erythema Protective gloves andclothing.



Ingestion Diarrhea and central nervous systemdepression with labored breathing andrespiratory failure. Aspiration mayresult in chemical pneumonitis.






2-Methyl-3-butyn-2-ol


115-19-5 liquid colorless N/A 25 104 2.6 0.868 N/A N/A miscible



Fire Flammable liquid and vapor. No flames, no sparks,no contact with hotsurfaces.

Carbon dioxide or drychemical powder. Do notuse water.

Inhalation Causes irritation to respiratory tractand mucous membranes.


Remove to fresh air.

Skin Can irritate skin. Protective gloves andclothing.

Flush with water. Usesoap if no burns haveoccured.

Eyes Can irritate eyes. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Causes irritation to mucousmembranes.


Requires antidote. Contacta physician.




2-Methyl-3-heptanol

CAS No. PS Color Odor FP BP MP d VP VD Sol14979-39-6 liquid colorless N/A 54 98–99 @

75 torrN/A 0.827 N/A N/A slightly soluble



Fire Combustible. Flammable.* Avoid heat, sparks,flames.


Inhalation May be harmful if inhaled. Irritating torespiratory system.*



Skin Irritating to the skin.* Protective gloves andclothing.


Eyes Irritating to the eyes.* Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.




* Toxicological information for the listed chemical is not available. Information given pertains to 4-methyl-3-heptanol and is intended to be used for comparison of a similar compound. Other effects mayresult from contact, inhalation, or ingestion.

Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flashpoint (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapordensity (g/mL); Sol = solubility in water; N/A = not available or not applicable.

4-Methyl-2-pentanol


108-11-2 liquid colorless sweet 41 132 -90 0.802 2.8 @20

3.53 1.7% @ 20



Fire Moderate fire hazard.; vapors or gasesmay ignite at distant ignition sources.


Regular dry chemical,carbon dioxide, regularfoam, alcohol resistantfoam

Inhalation Irritation, sore throat, coughing,headache, shortness of breath, andcentral nervous system depression withweakness, nausea, vomiting andfatigue.



Skin Irritation with redness and pain,absorbed through the skin and maycause central nervous systemdepression with weakness, dizziness,drowsiness, nausea, vomiting andfatigue.



Eyes Redness, pain, and blurred vision. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal pain, vomiting, diarrhea,and central nervous system depression.


If vomiting occurs, keephead lower than hips, getimmediate medicalattention.




2-Methyl-1-pentene


763-29-1 liquid colorless N/A -9 62 -136 0.682 325 @37.7

N/A insoluble




Carbon dioxide, regularchemical powder, foam,water for cooling.












4-Methyl-1-pentene


691-37-2 liquid colorless N/A -7 53–54 N/A 0.6642 424 @38

2.9 N/A




Regular dry chemical,carbon dioxide, water forcooling, regular foam

Inhalation Irritation and may cause centralnervous system depression withvomiting, dyspnea, cyanosis, vertigo,incoordination, and loss ofconsciousness.






Ingestion No specific data available; centralnervous system depression may occur.


Get medical attentionimmediately.




4-Methyl-2-pentene


4461-48-7 liquid N/A N/A <-7 56–59 N/A 0.669 N/A 2.90 insoluble



Fire Severe fire hazard., vapors or gases mayignite at distant ignition sources.



Inhalation Irritation, possible narcotic and maycause central nervous system depressionwith vomiting, dyspnea, cyanosis,vertigo, incoordination, loss ofconsciousness, and even death at highconcentrations.


Remove from exposureimmediately; get medicalattention



Eyes Irritation. Safety goggles. Thoroughly wash eyeswith water for severalminutes, remove contactlenses if possible, andseek medical attentionimmediately.

Ingestion No specific data available; centralnervous system depression may occur.


Get medical attentionimmediately




2-Methyl-1-propanol


78-83-1 liquid clear sweetand

musty

28 108 -108 0.803 8.8 @20

2.6 9.5 g/100mL water



Fire Flammable liquid and vapor No flames, nosparks, no contactwith hot surfaces.

Dry chemical, foam orcarbon dioxide.

Inhalation Causes irritation to respiratory tract.Effects from overexposure includeheadache, dizziness, muscle weakness,drowsiness, incoordination, confusion,and coma.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Call a physician.

Skin Skin contact causes irritation, redness,and pain. May be absorbed through theskin; symptoms of absorption may besimilar to those from ingestion.


Remove any contaminatedclothing. Wash skin withsoap or mild detergent andwater for at least 15minutes. Get medicalattention if irritationdevelops or persists.

Eyes Vapors cause irritation, redness, andblurred vision. Splashes may causesevere irritation or eye damage.


Ingestion Ingestion may cause nausea, vomiting,and diarrhea.


Induce vomitingimmediately as directed bymedical personnel.




2-Methyl-2-propanol

CAS No. PS Color Odor FP BP MP d VP VD Sol75-65-0 liquid colorless N/A 11 83 25–26 0.775 44 2.5 N/A
















Naphthalene


91-20-3 N/A N/A mothball-like

N/A 218 80.5 0.963 N/A 4.4 N/A



Fire Severe fire hazard.; explosion possible. No flames, no sparks,no contact with hotsurfaces.


Inhalation Irritation, headache, nausea, vomiting,abdominal cramps, diarrhea, edema,perspiration, and confusion.



Skin Irritation and severe dermatitis. Protective gloves andclothing.


Eyes Irritation, conjunctivitis, injury to thecornea, cataracts, and diminishedvisual acuity.


Ingestion Abdominal cramps, nausea, vomiting,diarrhea, headache, profuseperspiration, bladder irritation,hemolytic anemia, hemoglobinuria,convulsions, liver injury with jaundiceand acute renal failure.


If vomiting occurs, keephead lower than hips; getmedical attentionimmediately.




2-Naphthalenesulfonic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol120-18-3 solid colorless N/A N/A N/A 124–125 1.441 N/A N/A slightly soluble



Fire Reacts violently with water. Emitstoxic fumes under fire conditions. Mayaccelerate combustion. Contact withother material may cause fire.



Inhalation Harmful if inhaled. . Inhalation mayresult in spasm, inflammation, andedema of the larynx and bronchi,chemical pneumonitis and pulmonaryedema.



Skin Harmful if absorbed through skin.Irritating to the skin. Causes burns.May cause allergic skin reaction.



Eyes Harmful to the eyes. Extremelydestructive to tissue in eyes.


Ingestion May be fatal if swallowed. . Exposurecan cause, burning sensation, wheezing,laryngitis, shortness of breath,headache, coughing, nausea, andvomiting .

Do not eat, drink, orsmoke during work.


Carcinogenicity Carcinogen Mutagenicity Not a known mutagen.



1-Naphthol


90-15-3 crystallinepowder

white phenolic N/A 278–280

95–96 1.10 1 @ 94 4.5 very slightlysoluble



Fire Slight fire hazard. No flames, no sparks,no contact with hotsurfaces.

Water spray, dry chemical,alcohol foam, or carbondioxide.

Inhalation Causes irritation to the respiratorytract. Symptoms may includecoughing, shortness of breath.Inhalation may result in symptomsand problems similar to ingestion.



Skin May cause severe irritation, redness,and pain. May be absorbed through theskin with symptoms parallelingingestion and causing kidney damage.Local action may cause peeling of theskin which may be followed bypersistent pigmentation.


Immediately flush skinwith plenty of soap andwater for at least 15minutes while removingcontaminated clothing andshoes. Get medicalattention.

Eyes Causes irritation, redness, pain, andinjury to the cornea and lens of theeyes.


Ingestion Large doses may cause crampyabdominal pain, nausea, vomiting,sweating, intense thirst, cyanosis.






2-Naphthol


135-19-3 solid white distinctmothball-

like

153 285-286 122-123 1.2 3.6 @130

4.97 slightlysoluble





Inhalation Sweating, intense thirst, nausea,vomiting, diarrhea, hyperactivity,stupor, hypotension, hyperapnea, andabdominal pain.



Skin Blanching, erythema, tissuedestruction, may be absorbed to causeeffect as given under inhalation.



Eyes Irritation, redness, and pain. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyes.

Ingestion May cause effects as given underinhalation.


Contact physicianimmediately. If vomitingoccurs, keep head lowerthan hips; get medicalattention.




1-Naphthyl Isocyanate


86-84-0 liquid colorless faint 109 267 @ 760 torr

N/A 1.177 N/A 5.8 decomposes




Regular dry chemical,carbon dioxide, regularfoam

Inhalation Irritation, coughing, chest pains,difficulty breathing, allergic respiratoryreaction, and unconsciousness.



Skin Allergic skin reaction, irritation, pain,and possibly burns.



Eyes Irritation, pain, and burn . Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water.

Ingestion Bile stasis and the cessation of bileflow.






Nitric Acid, Concentrated


7697-37-2 liquid colorlessto yellow

distinct N/A 100 N/A 1.36–1.41

45 @25

1 soluble





Regular dry chemical,soda ash, water.

Inhalation Severe respiratory irritation, coughing,choking, yellowish burns of themucous membranes, headache, andnausea.



Skin Severe pain, burns, yellowish stains. Protective gloves andclothing.


Eyes Pain, lacrimation, photophobia, burns,blindness.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention, and continue towash eyes with water.

Ingestion Corrosion of the mucous membranesof the mouth, throat and esophagus,immediate pain and difficulty orinability to swallow or speak,vomiting, and diarrhea.






Nitric Acid, Fuming


Nitric Acid7697-37-2NitrogenDioxide

10102-44-0

liquid yellow tored

N/A N/A 100 N/A 1.4 62 torr@ 25

1 miscible





Regular dry chemical,soda ash, water.

Inhalation Nitric Acid: coughing, headache,dizziness, and weakness. Delayedsymptoms: dryness of the throat andnose, and chest pain or tightness.Nitrogen Dioxide: usually nosymptoms at time of exposure.Delayed symptoms: fatigue,uneasiness, restlessness, and cough.



Skin Nitric Acid: immediate severe andpenetrating burns, staining the skinyellow or yellowish-brown. NitrogenDioxide: severe irritation, pain,yellow-brown discoloration, andburns.



Eyes Nitric Acid: pain, photophobia,tearing, edema, corneal ulceration, andsevere burns. Nitrogen Dioxide: severeirritation with redness, pain, blurredvision, edema of the eyelids, cornealulceration, and burns.

Safety goggles. Thoroughly wash eyeswith water for severalmin., remove contactlenses if possible, seekmedical attentionimmediately, and continueto wash eyes with water.

Ingestion Nitric Acid: immediate pain in themouth, throat, and stomach, nausea,vomiting, and diarrhea. NitrogenDioxide: acid taste, nausea, andvomiting.






3-Nitroaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol99-09-2 solid yellow N/A N/A 304 112–114 1.43 N/A N/A 0.089 g/L






Inhalation Harmful by inhalation. May causecyanosis; onset may be delayed 2-4hours.



Skin May be fatal if absorbed through skin. Protective gloves andclothing.



Ingestion May cause cyanosis; onset may bedelayed for 2–4 hours.






4-Nitroaniline

CAS No. PS Color Odor FP BP MP d VP VD Sol100-01-6 solid pale

yellowN/A 164 260 @

100 torr149–151 1.424 N/A N/A slightly soluble






Inhalation Exposure can cause, headache,unconsciousness, coughing, chestpains, difficulty breathing, nausea,cyanosis, ataxia, diarrhea, andvomiting .



Skin Toxic if in contact with skin. Protective gloves andclothing.



Ingestion Toxic if swallowed. Exposure toand/or consumption of alcohol mayincrease toxic effects. Exposure cancause, headache, unconsciousness,coughing, chest pains, difficultybreathing, nausea, cyanosis, ataxia,diarrhea, and vomiting.


If swallowed wash outmouth with waterprovided person isconscious .Call aphysician.




Nitrobenzene


98-95-3 oilyliquid

paleyellow

almond-like 88 211 -5.7 1.2 1 @44.4

4.3 practicallyinsoluble



Fire Combustible. Gives off irritating ortoxic fumes (or gases) in a fire.


Powder, alcohol-resistantfoam, water spray, carbondioxide.

Inhalation Blue lips or fingernails. Blue skin.Dizziness. Headache. Nausea.Unconsciousness. Weakness.



Skin MAY BE ABSORBED! Blue lips orfingernails. Blue skin.


Remove contaminatedclothes. Rinse and thenwash skin with water orshower. Refer for medicalattention.

Eyes Vapors cause eye irritation. Splashescause severe irritation, possible cornealburns and eye damage.

Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifeasily possible; seekmedical attention.

Ingestion May cause headache, shallow respiration,dizziness, vomiting, weakness, andblood pressure falls.


Rinse mouth. Inducevomiting. Rest. Refer formedical attention.




Norbornene


498-66-8 solid N/A sharp -14 96 44–46 N/A N/A N/A insoluble
















exo-Norborneol


497-37-0 solid white N/A N/A 176–177

124-126 N/A N/A N/A slightly soluble
















Nylon-6,10

CAS No. PS Color Odor FP BP MP d VP VD Sol9008-66-6 solid white N/A N/A N/A N/A 1.040 N/A N/A insoluble






Inhalation May be harmful by inhalation. Do notbreathe vapor.











Petroleum ether 30-60

CAS No. PS Color Odor FP BP MP d VP VD Sol68476-50-6 liquid colorless hydrocarbon -46 30–40 N/A N/A N/A N/A insoluble



Fire Severe fire hazard; vapor may travelconsiderable distance to ignitionsource and flash back, containerexplosion may occur under fireconditions.



Inhalation May be harmful if inhaled. Vapor isirritating to the upper respiratory track.





Eyes May causes eye irritation. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.

Ingestion May be harmful if swallowed.Symptoms of exposure may includeCNS depression and diarrhea.


If swallowed, wash outmouth with water. Seekmedical attention.




Phenol


108-95-2 solid colorlessor white

tar-like 79 182 40–42 1.071 0.35 @25

3.24 6.7%





Regular dry chemical,regular foam, alcoholresistant foam.

Inhalation Severe irritation of the mucousmembranes, profuse sweating,headache, intense thirst, nausea,vomiting, abdominal pain, anddiarrhea.



Skin Local anesthesia, skin necrosis,painless burns due to damage to nerveendings, readily absorbed through theskin causing symptoms given ininhalation.



Eyes Severe irritation, redness, pain, blurredvision, severe blindness, and loss ofthe eye.


Ingestion Burning of the mouth and throat,abdominal pain, pale face, contractedor dilated pupils, circulatory collapse,tachypnea, paralysis, convulsions,coma, jaundice, necrosis of mouth andgastrointestinal tract.






Phenolphthalein

CAS No. PS Color Odor FP BP MP d VP VD Sol77-09-8 solid colorless N/A N/A N/A 261 1.3 N/A N/A soluble















Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flashpoint (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = meltingpoint (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specifiedtemperature (°C); VD = vapor density (g/mL); Sol = solubility in water; N/A = notavailable or not applicable.

Phenylhydrazine


100-63-0 liquid colorless faintaromatic

88 243.5 19 1.1 1 @71.8

3.7 slightly solublein hot water



Fire Combustible. Gives off irritating or toxicfumes (or gases) in a fire.


Water spray, alcohol-resistant foam, powder,carbon dioxide.

Inhalation Coughing. Labored breathing. Sore throat.Cyanosis.



Skin MAY BE ABSORBED! Dry skin. Redness.Pain.


Remove contaminatedclothes. Rinse skin withplenty of water or shower.Seek medical attention.


Ingestion Abdominal pain. Diarrhea. Nausea.Vomiting. Weakness. Vertigo.


Rest. Refer for medicalattention.




Phenylhydrazine hydrochloride

CAS No. PS Color Odor FP BP MP d VP VD Sol59-88-1 solid white N/A N/A N/A 250 N/A N/A N/A soluble










Eyes Vapor or mist is irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids often. Seekmedical advice.



Carcinogenicity Carcinogen Mutagenicity Not a known mutagen.


Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flashpoint (°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = meltingpoint (°C); d = density or specific gravity (g/mL); VP = vapor pressure (torr) at specifiedtemperature (°C); VD = vapor density (g/mL); Sol = solubility in water; N/A = notavailable or not applicable.

Phenyl Isocyanate

CAS No. PS Color Odor FP BP MP d VP VD Sol103-71-9 liquid colorless N/A 51 62–64 -30 1.093 2.8 N/A decomposes



Fire Flammable. Combustible. Emitstoxic fumes under fire conditions.



Inhalation Very toxic if inhaled. May causesensitization.

Ventilation, localexhaust


Skin Very toxic in contact with skin. Maycause sensitization. Causes burns.



Eyes Lachrymator. Vapor or mist isirritating to the eyes.







Phenylmagnesium Bromide

CAS No. PS Color Odor FP BP MP d VP VD Sol100-58-3 solid white N/A -17 N/A N/A 1.14 N/A N/A decomposes



Fire Highly flammable. Emits toxic fumesunder fire conditions. Ignites oncontact with water.



Inhalation Harmful if inhaled. Very irritating torespiratory system.



Skin Caustic will burn skin. Protective gloves andclothing.


Eyes Vapor or mist burns eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.



Carcinogenicity Probable carcinogen Mutagenicity Not a known mutagen.



Phthalic Anhydride

CAS No. PS Color Odor FP BP MP d VP VD Sol85-44-9 solid white N/A N/A 284 131–133 1.494 <0.01 5.1 decomposes






Inhalation May be harmful if inhaled. Irritatingto respiratory system.












Picric Acid

CASNo.


88-89-1 crystallinesolid

yellow odorless 150 explodesabove 300

122 1.77 N/A N/A moderate (1-10%)



Fire Flammable solid. Dangerous fire hazard.when exposed to heat or flame.


Fight fire from protectedlocation or maximumpossible distance. Do notuse carbon dioxide orhalogenated extinguishingagents.

Inhalation Causes irritation to the respiratory tract.Symptoms may include coughing,shortness of breath. Systemic poisoningcan cause headache, dizziness, nausea,vomiting, abdominal pain and diarrhea.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Get medicalattention.

Skin Causes irritation to skin. Symptomsinclude redness, itching, and pain. Maycause allergic skin reactions. May beabsorbed through the skin with possiblesystemic effects.


Immediately flush skinwith plenty of water for atleast 15 minutes whileremoving contaminatedclothing and shoes. Getmedical attention. Keepcontaminated clothing wetafter removing.

Eyes Fume is irritating to the eyes. Splashescan cause eye injury.


Ingestion Causes irritation to the gastrointestinaltract. Symptoms may include nausea,vomiting and diarrhea. Other symptomsmay parallel those from inhalation.


If swallowed, do notinduce vomiting. Givelarge quantities of water.Get medical attention.




(+)- -Pinene


7785-70-8 liquid colorless petroleum-like

32 154–156

N/A 0.857–0.862

N/A N/A insoluble






Inhalation Irritation, destruction to tissue,burning sensation, coughing,wheezing, shortness of breath,dizziness, headache, nausea, andvomiting.



Skin Irritation, dermal eruptions, and maybe absorbed through skin and causeeffects as detailed in inhalation.



Eyes Irritation and burning sensation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Effects as detailed in inhalation. Do not eat or drink inthe laboratory.





Polystyrene



odorless 345–360

N/A 86-91 1.04–1.13

N/A N/A insoluble





Inhalation Irritation and coughing. Ventilation, localexhaust.





Ingestion Irritation. Do not eat or drink inthe laboratory.





Potassium Bromide

CAS No. PS Color Odor FP BP MP d VP VD Sol7758-02-3 solid white odorless N/A 1435 734 2.750 <0.01 N/A soluble




NA Use extinguishing agentsappropriate forsurrounding fire.













Potassium tert-Butoxide

CAS No. PS Color Odor FP BP MP d VP VD Sol865-47-4 solid white N/A N/A N/A 256 to

258 (dec)1.850 1 @

220N/A N/A









Skin Caustic, may burn skin. Protective gloves andclothing.









Potassium Carbonate


584-08-7 solid colorlessor white

odorless N/A decomposes 891 2.29 N/A N/A 112% @ 20




Inhalation Irritation, coughing, choking, pain,burns of the mucous membranes, andpulmonary edema.



Skin Severe pain, burns, and brownish stains. Protective glovesand clothing.


Eyes Pain, burns, edema, cornealopacification, permanent opacity, andblindness.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately,continue to wash eyeswith water.

Ingestion Immediate pain, corrosion of the mucousmembranes, shortness of breath,laryngitis, headache, nausea, vomiting,profuse salivation, and difficulty orinability to swallow or speak.






Potassium Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol7447-40-7 solid white N/A N/A 1420 770 1.984 N/A N/A soluble












Safety goggles. Immediately flush eyeswith copious amounts ofwater, lifting upper andlower lids often. Seekmedical advice.






Potassium Ferricyanide

CAS No. PS Color Odor FP BP MP d VP VD Sol13746-66-2 solid orange N/A N/A N/A N/A 1.850 N/A N/A soluble

















Potassium Fluoride

CAS No. PS Color Odor FP BP MP d VP VD Sol7789-23-

3solid white N/A N/A 1505 860 2.480 N/A 2 soluble





Inhalation May be harmful if inhaled. Veryirritating to respiratory system.












Potassium Hydroxide


1310-58-3 solid off-white odorless N/A 1316 360 2.044 1.0 @719

N/A 52%




Inhalation Irritation, coughing, choking, pain,burns of the mucous membranes, andtightness in the chest.



Skin Severe pain, burns, and brownish stains. Protective glovesand clothing.


Eyes Pain, burns, edema, destruction ofepithelium, permanent opacity, andblindness.


Ingestion Immediate pain, corrosion of the mucousmembranes, profuse salivation, anddifficulty or inability to swallow orspeak.






Potassium Iodide



odorless N/A 1330 681 3.13@ 15

1 @745

N/A 127.5%




Inhalation Irritation, coughing, and chestdiscomfort.



Skin Pimples, boils, hives, blisters, black andblue spots.



Eyes Irritation, redness, pain, corrosive. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Gastrointestinal upset, nausea, andvomiting.


Contact physicianimmediately. Give milkthen starch solution; ifvomiting occurs, keephead lower than hips.




Potassium Permanganate


7722-64-7 solid N/A N/A N/A N/A N/A N/A N/A N/A soluble




Avoid contact withcombustiblematerials.


Inhalation Irritation, labored breathing, choking,pain in the nose, mouth and throat, andburns of the mucous membranes.



Skin Burns, redness, and pain. Protective glovesand clothing.


Eyes Burns, redness, pain, lacrimation, andblurred vision.


Ingestion Inflammation, nausea, vomiting, anddifficulty speaking or swallowing.Overexposure can cause anemia andkidney damage.






1-Propanol


71-23-8 liquid clear alcohol 23 97 -127 0.804 21 @25

2.07 infinitelysoluble



Fire Severe fire hazard. Vapors or gasesmay ignite at distant ignition sources.


Water spray, dry chemical,alcohol foam, or carbondioxide.

Inhalation Vapors have a mild narcotic effect andact as an upper respiratory tract irritant.Symptoms may include irritation ofthe eyes, nose, and throat, drowsiness,headache, and uncoordination.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Call a physician.

Skin Defatting agent. May cause skinirritation. Skin absorption may occurwith symptoms paralleling those frominhalation exposure.


In case of contact,immediately flush skinwith plenty of water for atleast 15 minutes. Removecontaminated clothing andshoes. Call a physician.

Eyes Vapors are irritating to the eyes.Splashes may cause severe irritation,with stinging, tearing, redness andpain.


Ingestion May cause nausea, vomiting,drowsiness, gastrointestinal pain,cramps and diarrhea.






2-Propanol


67-63-0 liquid colorless alcoholic 12 82.4 -89.5 0.7855 40 @24

2.1 soluble



Fire Severe fire hazard. Vapors or gasesmay ignite at distant ignition sources.



Inhalation Irritation, chest tightness, wheezing,and large amounts may causesymptoms similar to acute ingestion.



Skin Irritation, contact dermatitis, and largeamounts may result in symptomssimilar to acute ingestion.



Eyes Irritation, transitory injury,conjunctivitis, iritis, and cornealopacity.


Ingestion Abdominal pain, nausea, vomiting,and hemorrhage, hypoglycemia,tenderness and edema of muscles, andarrhythmias, vomiting with aspirationmay cause aspiration pneumonia.Central nervous system depressionmay occur with headache anddizziness.






Propylene Glycol

CASNo.


57-55-6 oily liquid clear odorless 23 99 -59 1.0361 0.129@ 25

2.6 miscible



Fire Can support combustion. No flames, no sparks,no contact with hotsurfaces.

Dry chemical, foam, wateror carbon dioxide.

Inhalation No adverse health effects viainhalation.


Remove to fresh air. Notexpected to require first-aid measures.

Skin Mild irritant and defatting agent,especially on prolonged contact.


Remove any contaminatedclothing. Wash skin withsoap and water for at least15 minutes. Get medicalattention if irritationdevelops or persists.

Eyes May cause transitory stinging andtearing.

Safety goggles. In case of contact,immediately flush eyeswith plenty of water for atleast 15 minutes, liftingupper and lower eyelidsoccasionally. Call aphysician if irritationpersists.

Ingestion Relatively non-toxic. Ingestion ofsizable amount (over 100ml) maycause some gastrointestinal upset andtemporary central nervous systemdepression. Effects appear more severein individuals with kidney problems.


Not expected to requirefirst aid measures. Giveseveral glasses of water todrink to dilute. If largeamounts were swallowed,get medical advice.




Pyridine


110-86-1 liquid colorless N/A 20 115–

116

N/A 0.978 18 @20

2.72 soluble






Inhalation Irritation, unpleasant taste in themouth, narcosis, dizziness,drowsiness, and headache.



Skin Redness, irritation, burns,photosensitivity and sensitizationreactions, and subdermal hemorrhages.



Eyes Irritation and corneal damage. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Nausea, fatigue, mental depression,vomiting, and diarrhea.






Resorcinol

CAS No. PS Color Odor FP BP MP d VP VD Sol108-46-3 solid white N/A 170 280 110–113 1.327 1 3.8 220%


















p-Rosaniline Hydrochloride (Basic Fuchsin)

CAS No. PS Color Odor FP BP MP d VP VD Sol569-61-9 solid green N/A N/A N/A 250 1.22 N/A N/A 0.1-0.5 g/100

mL














Carcinogenicity Possible carcinogen Mutagenicity Possible mutagen



Salicylamide

CAS No. PS Color Odor FP BP MP d VP VD Sol65-45-2 solid white N/A N/A 181.5 @

14 torr140–144 1.351 N/A N/A 2.511 g/L


















Salicylic Acid

CASNo.


69-72-7 finecrystals

white odorlessto slightphenolic

157 211 157–159

1.44 1 torr @114

4.8 1 g/460 mL



Fire Combustible. No flames, no sparks,no contact with hotsurfaces.

Carbon dioxide, waterspray, powder.

Inhalation Cough. Sore throat. Ventilation, localexhaust.




Eyes Redness, pain. Safety goggles. First rinse with plenty ofwater for several minutes;remove contact lenses ifeasily possible; seekmedical attention.

Ingestion Nausea, vomiting, ear ringing. Do not eat or drink inthe laboratory.

Rinse mouth. Inducevomiting. Refer formedical attention.




Semicarbazide Hydrochloride


563-41-7 solid white N/A N/A N/A N/A N/A N/A N/A soluble




Carbon dioxide, regulardry chemical.

Inhalation Nausea, vomiting, fever, headache,hypotension, weakness, and fatigue.





Eyes Redness and irritation Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Nausea, vomiting, sore throat,abdominal pain, and diarrhea.


Contact physicianimmediately. Give largeamounts of water oractivated charcoal slurry;when vomiting occurs,keep head lower than hips.




Silicon Dioxide

CAS No. PS Color Odor FP BP MP d VP VD Sol112926-00-8 solid white odorless N/A N/A N/A 2.6 N/A N/A N/A




N/A Use extinguishing agentsappropriate forsurrounding fire.






Eyes Dust is irritating to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






Silver Nitrate


7761-88-8 liquid colorless N/A N/A 440 212 4.352 N/A N/A soluble






Inhalation Irritation, sore throat, coughing andshortness of breath, headache, nausea,vomiting.


Remove from exposureimmediately, keep warmand at rest, and getmedical attentionimmediately.

Skin Irritation, redness, pain, ulceration,and discoloration.



Eyes Irritation, redness, pain, burns,discoloration, and blindness.


Ingestion Burning mouth and throat, salivation,violent abdominal pain and rigidity,diarrhea, headache, nausea, vomiting,and cyanosis.


Contact physicianimmediately. Give saltwater; if vomiting occurs,keep head lower than hips.




Sodium


7440-23-5 metal light,silverywhite

odorless 115 881.7 97.8 0.968 1.2 @400

0.003 decomposesviolently in

water



Fire Flammable solid, water reactive. Canreact vigorously with water, steam,acids to release flammable/explosivehydrogen. Dangerous in presence ofoxidants. May ignite spontaneously inmoist air or oxygen. May re-igniteafter fire is extinguished.

Avoid open flames orsparks. Keep fromwater.

Use dry soda ash, dry salt,sand, graphite powder ormetal-fire-extinguishingdry powder such as Met-L-X™. Do not use water,foam, carbon dioxide, drychemical, or chlorinatedfire extinguishers.

Inhalation Inhalation produces damaging effectson the mucous membranes and upperrespiratory tract. Symptoms mayinclude irritation of the nose andthroat, and labored breathing.


If inhaled, remove to freshair. Get medical attentionimmediately.

Skin Corrosive, can cause serious burns dueto almost immediate reaction withwater, especially on moist skin. Ifmetal ignites, very deep burns andtissue destruction can occur.


Wipe off excess materialfrom skin thenimmediately flush skinwith plenty of water for atleast 15 minutes. Removecontaminated clothing andshoes. Get medicalattention.

Eyes Corrosive. May cause redness, pain,blurred vision, and damage fromsevere alkali burns.


Ingestion Extremely dangerous, corrosivematerial. Will react immediately withsaliva to cause serious burns andpossible local combustion.


If swallowed, do notinduce vomiting. Givelarge quantities of water.Get medical attentionimmediately.




Sodium Acetate


127-09-3 solid N/A N/A N/A N/A 324decomposes

1.528 N/A N/A soluble





Inhalation Irritation, coughing, and shortness ofbreath






Ingestion Abdominal pain and vomiting Do not eat or drink inthe laboratory.





Sodium Acetate, Trihydrate


6131-90-4 solid N/A odorless N/A 123 58 1.45 N/A N/A 76.2% @ 0











Ingestion Abdominal pain and vomiting. Do not eat or drink inthe laboratory.





Sodium Bicarbonate


144-55-8 solid white odorless N/A N/A 300 2.159 N/A N/A 10%




Inhalation Irritation, sore throat, and coughing. Ventilation, localexhaust.





Ingestion Irritation of the mouth, esophagus, andstomach. Alkalosis.






Sodium Bisulfite


7631-90-5 solid white N/A N/A decomposes decomposes 1.32 N/A N/A soluble




Inhalation Irritation, sore throat, coughing, andshortness of breath.



Skin Irritation, corrosion. Protective gloves andclothing.


Eyes Irritation, corrosion, and grayness andirregularity of the corneal epithelium.


Ingestion Irritation of the stomach, abdominalpain, and nausea. Those withpreexisting respiratory conditions mayexperience hypersensitivity: symptomsinclude bronchospasm, gastrointestinaldisturbances, hypotension, and shock.






Sodium Borohydride


16940-66-2 solid white,off-white

odorless 318 N/A 300–400decomposes

1.074

N/A 1.3 55% @ 25




Regular dry chemical,sand, lime, soda ash

Inhalation Severe irritation, sore throat, coughing,shortness of breath, and headache



Skin Chemical and thermal burns, fatalsystemic poisoning due to skinabsorption



Eyes Severe irritation and chemical andthermal burns


Ingestion Sore throat, abdominal pain, diarrhea,headache, dizziness, and corrosion ofthe gastric mucosa.






Sodium Bromide


7647-15-6 solid white odorless N/A 1390 755 3.210 1 @806

N/A 116% @ 50




Inhalation Irritation, rashes (especially acne,furunculosis).


Remove from exposureimmediately. Get medicalattention.

Skin Irritation, rashes (especially acne,furunculosis).


Remove contaminatedclothing, jewelry, andshoes immediately.Thoroughly wash withwater.

Eyes N/A Safety goggles. Thoroughly wash eyeswith water for severalminutes, remove contactlenses if possible, andseek medical attentionimmediately.

Ingestion Immediate abdominal pain, nausea,vomiting, kidney damage, systemicpoisoning, paralysis, and coma.


If vomiting occurs, keephead lower than hips. Getmedical attention.




Sodium Carbonate


497-19-8 crystal-line

powder,crystals

colorlessto white

odorless N/A decomposes 851 2.536 N/A N/A 7.1% @ 0







Skin Irritation and redness Protective glovesand clothing.


Eyes Severe irritation, redness, pain, andblurred vision


Ingestion Corrosion of the gastric mucosa, sorethroat, gastrointestinal disturbances,nausea, vomiting, abdominal pain, anddiarrhea.






Sodium Chlorate


7775-09-9 solid white N/A N/A decomposes 248-261

2.49 N/A N/A 79g/100mL@ 0




Avoid contactwith combustiblematerials


Inhalation Irritation with sore throat, coughing,headache, dizziness, and faintness.



Skin Irritation. Protective glovesand clothing.


Eyes Irritation. Safety goggles. Thoroughly wash eyeswith water for severalminutes, remove contactlenses if possible, andseek medical attentionimmediately.

Ingestion Irritation of the gastrointestinal mucosa,abdominal pain, nausea, vomiting, anddiarrhea.

Do not eat ordrink in thelaboratory.





Sodium Chloride


7647-14-5 crystallinepowde

colorlessto white

odorless N/A 1413 801 2.165 N/A N/A 35.7% @ 0




Inhalation Coughing, dryness, and sore throat. Ventilation, localexhaust.


Skin Irritation Protective glovesand clothing.


Eyes Redness, pain, irritation and a stingingsensation


Ingestion Dryness of mucous membranes, a violentinflammatory reaction in thegastrointestinal tract, and ulceration if verylarge doses are taken.






Sodium Citrate, Dihydrate

CAS No. PS Color Odor FP BP MP d VP VD Sol6132-04-3 solid white N/A N/A N/A >300 N/A N/A N/A soluble

















Sodium Dichromate, Dihydrate

CAS No. PS Color Odor FP BP MP d VP VD Sol7789-12-0 solid red to

orange N/A N/A N/A 91 2.350 N/A N/A soluble



Fire Flammable. Emits toxic fumes underfire conditions. Vigorously supportscombustion.



Inhalation Harmful if inhaled, toxic. Ventilation, localexhaust.


Skin Irritating to the skin, may cause burns.May be toxic



Eyes Irritating to the eyes. May be toxic Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.



Carcinogenicity Carcinogenic Mutagenicity Not a known mutagen.



Sodium Hydroxide


1310-73-2 solid white odorless N/A 1390 318 2.130 100 @1111

>1 soluble




Inhalation Irritation, sore throat, burningsensation, laryngitis, coughing,destruction of mucous membranes,headache, nausea, vomiting, anddelayed pulmonary edema.



Skin Redness, cutaneous burns, and skinfissures.



Eyes Disintegration and sloughing ofconjunctival and corneal epithelium,corneal opacification, edema,ulceration, and blindness.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention, continue towash eyes with water.

Ingestion Corrosion of the lips, mouth, tongueand pharynx, severe esophageal andabdominal pain, and vomiting.






Sodium Hypochlorite


7681-52-9 liquid yellow,green

chlorine-like

N/A N/A N/A 1.097 17.5@ 20

N/A 100%






Inhalation Severe burns, severe bronchialirritation, sore throat, blistering,coughing, nausea, and laboredbreathing.



Skin Redness, pain, blistering, itchyeczema, and chemical burns.



Eyes Severe pain, hemorrhages, cornealopacification, edema, ulceration, andblindness.

Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention, and continue towash eyes with water.

Ingestion Inflammation of the mouth anddigestive system, circulatory collapse,confusion, delirium, and drop in bloodpressure.


Contact physicianimmediately. Do notinduce vomiting; givemilk; if vomiting occurs,keep head lower than hips.




Sodium Iodide


7681-82-5 crystals,powder

colorlessto white

odorless N/A 1304 661 3.67 1 @767

N/A 184%




Inhalation Irritation. Prolonged exposure mayproduce iodism in sensitiveindividuals.






Ingestion Enlargement of salivary glands orlymph glands.






Sodium Lead Alloy

CAS No. PS Color Odor FP BP MP d VP VD Sol12740-44-2

solid gray N/A N/A N/A N/A N/A N/A N/A decomposes



Fire Extremely flammable, reacts violentlywith water, liberating extremelyflammable gasses.

No open flames orsparks, protect frommoisture.

Use approved class Dextinguisher or smotherwith dry sand; do not usewater or CO2.

Inhalation Harmful if inhaled. Very irritating torespiratory system, causes burns.



Skin Very caustic, causes burns. Protective gloves andclothing.


Eyes Vapor or mist very caustic to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.






Sodium Nitrite


7632-00-0 solid colorlessto yellow

odorless N/A N/A 271 2.168@ 0

N/A N/A 82% @ 15



FireNegligible fire hazard., may ignite orexplode on contact with combustiblematerials.



Inhalation Irritation, sore throat, and shortness ofbreath.



Skin Redness and irritation. Protective gloves andclothing.


Eyes Irritation and dilation of pupils. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Gastrointestinal irritation with nausea,vomiting, diarrhea, and abdominalpains, dizziness, confusion, andlethargy.


If vomiting occurs, keephead lower than hips; turnhead to side, and getmedical attentionimmediately.




Sodium Nitroprusside

CAS No. PS Color Odor FP BP MP d VP VD Sol13755-38-9

solid dark red N/A N/A N/A N/A 1.720 N/A N/A soluble





Use extinguishing mediaappropriate to surroundingfire.

Inhalation Highly toxic, may be fatal if inhaled. Ventilation, localexhaust.


Skin Highly toxic, may be fatal if absorbedthrough skin.



Eyes Vapor or mist is highly toxic. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advise.

Ingestion Highly toxic, may be fatal ifswallowed.






Sodium Sulfate


7757-82-6 crystals,powder

white odorless N/A N/A 884 2.671 N/A N/A 17% @ 20









Ingestion Diarrhea, fluid loss, blood in stools,and hypotension.



Carcinogenicity Known carcinogen. Mutagenicity Known mutagen.



(E)-Stilbene

CAS No. PS Color Odor FP BP MP d VP VD Sol103-30-0 solid colorless N/A N/A 305–307 122–125 0.970 N/A N/A almost

insoluble






Remove from exposureimmediately. Get medicalattention.


Remove contaminatedclothing, jewelry, andshoes immediately.Thoroughly wash withwater.

Eyes Irritation, itching, lacrimation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seekimmediate medicalattention.


If vomiting occurs, keephead lower than hips. Getmedical attention.




(Z)-Stilbene


645-49-8 liquid paleyellow

N/A >110 82-84 -5 1.02 N/A N/A insoluble










Eyes Irritation. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seekimmediate medicalattention.






d,l-Stilbene Dibromide




Fire Emits toxic fumes under fireconditions.*

Avoid flames, sparks,and contact with hotsurfaces


Inhalation May be harmful if inhaled. Vapor isirritating to respiratory system.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.*



Skin May cause skin irritation.* Protective gloves andclothing.


Eyes Lachrymator. Vapor or mist isirritating to the eyes.*


Ingestion May be harmful if swallowed.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.*



Carcinogenicity Not a known carcinogen.* Mutagenicity Not a known carcinogen*

*Toxicological information for the listed chemical is not available. Information given pertains to meso-stilbenedibromide and is intended to be used for comparison of a similar compound. Other effects may result fromcontact, inhalation, or ingestion.


meso-Stilbene Dibromide

CAS No. PS Color Odor FP BP MP d VP VD Sol13440-24-9 solid white N/A N/A N/A 241 N/A N/A N/A insoluble




Avoid flames, sparks,and contact with hotsurfaces


Inhalation May be harmful if inhaled. Vapor isirritating to respiratory system.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.





Eyes Lachrymator. Vapor or mist isirritating to the eyes.


Ingestion May be harmful if swallowed.Symptoms may include burningsensation, coughing, wheezing,laryngitis, shortness of breath,headache, nausea, and vomiting.



Carcinogenicity Not a known carcinogen Mutagenicity Not a known carcinogen



Styrene


100-42-5 liquid colorless varying 31 145–146 -31 0.909 10 @31

3.6 0.02%



Fire SEVERE fire hazard., vapors or gases mayignite at distant ignition sources.

No flames, nosparks, nocontact with hotsurfaces.


Inhalation Irritation, headache, fatigue, difficulty inconcentrating, central nervous systemdepression, nausea, weakness, dizziness,and inertia.



Skin Irritation, redness, cracking, inflammation,defatting and degreasing of the skin;absorption may result in symptoms givenin inhalation.



Eyes Irritation, redness, pain, lacrimation,blurred vision, and slight reversible cornealdamage.


Ingestion Irritation of the mouth, throat, andgastrointestinal tract, and symptoms givenin inhalation.



Carcinogenicity Suspected carcinogen. Mutagenicity Known mutagen.



Succinic Acid

CAS No. PS Color Odor FP BP MP d VP VD Sol110-15-6 solid whit e N/A N/A 235 187–190 1.55 0.009 N/A 56.5 g/L






Inhalation Irritating if inhaled, may be toxic. Ventilation, localexhaust.


Skin Irritating to the skin, may be harmful. Protective gloves andclothing.


Eyes Vapor or mist is severely irritating tothe eyes.







Sucrose


57-50-1 crystals N/A characteristiccaramel

N/A N/A 160–

186

1.59 N/A N/A 1.5 g/0.5 mL



Fire Not considered to be a fire hazard. N/A Use extinguishing agentsappropriate forsurrounding fire.

Inhalation Not expected to be a health hazard.Nuisance dust. Inhalation of highconcentrations may cause coughing andupper respiratory tract irritation.



Skin No adverse effects expected. Protective glovesand clothing.

Not expected to requirefirst-aid measures.

Eyes No adverse effects expected but dust maycause mechanical irritation.


Ingestion Extremely large oral dosages may producegastrointestinal disturbances.


If large amounts wereswallowed, give water todrink and get medicaladvice.




Sulfanilamide


63-74-1 solid white odorless N/A N/A 165–167

1.08 N/A N/A 7.5%




Inhalation Harmful. Ventilation, localexhaust.


Skin Irritation. Protective glovesand clothing.



Ingestion Cyanosis, anorexia, vomiting, dizziness,and drowsiness.


Contact physicianimmediately. Givesodium bicarbonatesolution; if vomitingoccurs, keep head lowerthan hips.




3-Sulfolene


77-79-2 crystals off-white

N/A 109 N/A 65–66 N/A N/A N/A soluble





Inhalation May be harmful Ventilation, localexhaust.


Skin Irritation, may be harmful if absorbedthrough skin




Ingestion May be harmful Do not eat or drink inthe laboratory.





Sulfuric Acid, Fuming


Sulfuric acid7664-93-9

Sulfur trioxide7446-11-9

liquid yellow pungent N/A 100 N/A 1.84 1 <0.3 reactsviolently




Inhalation Sore throat, labored breathing, coughing,choking, chronic respiratory tractdamage, and chronic bronchitis.



Skin Severe irritation, pain, and burns. Protective glovesand clothing.


Eyes Severe damage and blindness. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, seek medicalattention immediately, andcontinue to wash eyeswith water.

Ingestion Serious burns of the mouth andesophagus, pain in the abdomen,vomiting, and diarrhea.



Carcinogenicity Known carcinogen. Mutagenicity Not a known mutagen.



Sulfuric Acid Solutions


7664-93-9 liquid colorless N/A N/A 100 N/A 1.84 1 <0.3 soluble




Avoid contactwith combustiblematerials


Inhalation Irritation, shallower and more rapidbreathing, sneezing, a burning or ticklingsensation in the nose and throat, andcough.



Skin Second and third degree skin burns,necrosis, charring, and shock.



Eyes Burning or stinging sensation, lacrimation,blurred vision, and conjunctivalcongestion.


Ingestion Burning pain in the mouth, throat,esophagus and abdomen, nausea, andvomiting.






Sulfuryl Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol7791-25-

5liquid colorless

to paleyellow

sharp none 68–70 -54 1.680 100@

17.8

4.65 decomposes



Fire Flammable, reacts violently withwater. Emits toxic and extremelyflammable fumes under fireconditions.


Extinguish with drychemical extinguisher; donot use water.

Inhalation Extremely destructive to mucousmembranes, may be fatal if inhaled.



Skin Causes burns, may be fatal if absorbedthrough skin.



Eyes Vapor or mist is very damaging to theeyes.


Ingestion May be fatal if swallowed. Do not eat or drink inthe laboratory.





L-Tartaric acid

CAS No. PS Color Odor FP BP MP d VP VD Sol87-69-4 solid white N/A 150 N/A 170–172 1.760 N/A N/A soluble



Fire Fire possible at elevated temperaturesor by contact with an ignition source.Emits toxic fumes under fireconditions.



Inhalation Irritant to respiratory system Ventilation, localexhaust.




Eyes Irritant to eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids occasionally.Seek medical advice.






Tetrachloroethylene

CAS No. PS Color Odor FP BP MP d VP VD Sol127-18-4 liquid none N/A None 121 -22 1.623 19 5.83 0.165 g/L




N/A Use extinguishing mediaappropriate to surroundingmaterials.











Thionyl Chloride


7719-09-7 clear, paleyellow

pungent N/A 76 -105 1.64 100@ 21

N/A decomposes

Types ofHazard/Exposur

e


Fire Not considered to be a fire hazard. May reactviolently with water or moist air. Can liberateflammable hydrogen gas when in contact withmetal and moisture.

N/A Use extinguishing agentsappropriate for surroundingfire.

Inhalation Corrosive. Extremely destructive to tissues ofthe mucous membranes and upper respiratorytract. Symptoms may include burningsensation, coughing, wheezing, laryngitis,shortness of breath, headache, nausea andvomiting.


Remove to fresh air. Getmedical attention immediately.

Skin Corrosive. Liquid contact may causeblistering burns, irritation, and pain. Vaporsmay be severely irritating to the skin.


Wipe off excess material fromskin then immediately flushskin with water for at least 15minutes while removingcontaminated clothing andshoes. Get medical attentionimmediately.

Eyes Corrosive! Vapors are irritating and may causedamage to the eyes. Contact may cause severeburns and permanent eye damage.

Safety goggles. Immediately flush eyes withplenty of water for at least 15minutes, lifting lower andupper eyelids occasionally. Getmedical attention immediately.

Ingestion Corrosive. May cause burning pain in throat,abdominal pain, nausea, and vomiting.


If swallowed, do not inducevomiting. Give largequantities of water. Getmedical attention immediately.



ations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boilingpoint (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP= vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility inwater; N/A = not available or not applicable.

Tin


7440-31-5 granules orflakes

silvery odorless N/A 2507 231.9 7.31 1 @1609

N/A insoluble



Fire Fine dust dispersed in air in sufficientconcentrations, and in the presence of anignition source is a potential dustexplosion hazard.

No open flames. Dry sand, graphite,dolomite, sodiumchloride. Never use water,halogenated agents, orclass A, B, or Cextinguishers.

Inhalation No adverse effects expected but dust maycause mechanical irritation.


Not expected to requirefirst-aid measures.Remove to fresh air. Getmedical attention for anybreathing difficulty.

Skin No adverse effects expected. May causemild irritation and redness.


Not expected to requirefirst aid measures. Washexposed area with soapand water. Get medicaladvice if irritationdevelops.

Eyes No adverse effects expected but dust maycause mechanical irritation.


Ingestion Large doses may cause nausea, vomiting,and diarrhea.


Induce vomitingimmediately as directed bymedical personnel.




Tin (II) Chloride

CAS No. PS Color Odor FP BP MP d VP VD Sol7772-99-8 solid off-white N/A N/A 652 246 3.950 N/A N/A decomposes



Fire Nonflammable. No open flames orsparks, protect frommoisture.

Media appropriate forsurrounding fire.Extinguish with drychemical powder.

Inhalation Extremely destructive to mucousmembranes and lungs.



Skin Corrosive, causes burns. Protective gloves andclothing.


Eyes Extremely destructive to the eyes. Safety goggles. Immediately flush eyeswith copious amounts ofwater lifting upper andlower lids often. Seekmedical advice.


If swallowed, wash outmouth with waterprovided person isconscious. Call aphysician.




Toluene


108-88-3 liquid colorless distinct 4 110.6 -93 0.865 22 @20

3.2 0.05% @ 20




No flames, nosparks, nocontact with hotsurfaces.

Regular dry chemical,carbon dioxide, water forcooling, regular foam

Inhalation Fatigue, weakness, confusion, headache,nausea, and drowsiness.



Skin Irritation and drying. Protective glovesand clothing.


Eyes Irritation and corneal burns. Safety goggles. Thoroughly wash eyeswith water for several min,remove contact lenses ifpossible, and seek medicalattention immediately.

Ingestion Abdominal spasms, systemic effects givenin inhalation, coughing, and gagging.


Contact physicianimmediately. If vomitingoccurs keep, head lowerthan hips.




p-Toluidine

CAS No. PS Color Odor FP BP MP d VP VD Sol106-49-0 solid colorless fish-like 88 200 44–46 0.973 N/A 3.9 0.664 g/L















Carcinogenicity Possible carcinogen Mutagenicity Possible mutagen



Triethylene Glycol

CAS No. PS Color Odor FP BP MP d VP VD Sol112-27-6 liquid colorless N/A 165 285 -7 1.125 <0.01 5.2 soluble

















Trimyristin

CAS No. PS Color Odor FP BP MP d VP VD Sol555-45-3 liquid colorless N/A >110 N/A 56–58 1.080 <0.01 8.95 Insoluble

















Triphenylmethanol


76-84-6 solid colorlessto off-white

N/A N/A 380 164 1.1999 N/A N/A insoluble



Fire Slight fire hazard. No flames, nosparks, nocontact with hotsurfaces.




Skin May be harmful. Protective glovesand clothing.



Ingestion May be harmful. Do not eat ordrink in thelaboratory.





Urea

CASNo.


57-13-6 crystalsor

powder

white ammonia-like

N/A Decomposes 135 1.32 N/A N/A N/A



Fire Not considered to be a fire hazard. N/A Use any means suitable forextinguishing surroundingfire.

Inhalation Causes irritation to the respiratory tract.Symptoms may include coughing,shortness of breath. May be absorbed intothe bloodstream with symptoms similar toingestion.


Remove to fresh air. Ifbreathing is difficult, giveoxygen. Get medicalattention.



Immediately flush skinwith plenty of water for atleast 15 minutes whileremoving contaminatedclothing and shoes. Getmedical attention ifsymptoms occur.

Eyes Causes irritation, redness, and pain. Safety goggles. Immediately flush eyeswith plenty of water for atleast 15 minutes, liftinglower and upper eyelidsoccasionally. Get medicalattention immediately.

Ingestion Causes irritation to the gastrointestinaltract. Symptoms may include nausea,vomiting and diarrhea. May also causeheadache, confusion and electrolytedepletion.






m-Xylene


108-38-3 liquid clear aromatic 26 138 -48 0.86 9 @ 20 3.7 insoluble






Inhalation Inhalation of vapors may be irritatingto the nose and throat. Inhalation ofhigh concentrations may result innausea, vomiting, headache, ringing inthe ears, and severe breathingdifficulties that may be delayed inonset..


If inhaled, remove to freshair. If breathing isdifficult, give oxygen.Call a physician.

Skin Skin contact results in loss of naturaloils and often results in a characteristicdermatitis. May be absorbed throughthe skin.





Ingestion Ingestion causes burning sensation inmouth and stomach, nausea, vomitingand salivation.


Aspiration hazard. Ifswallowed, do not inducevomiting. Give largequantities of water. Getmedical attentionimmediately. If vomitingoccurs, keep head belowhips.




p-Xylene


106-42-3 liquid clear aromatic 27.2 138 13–14 0.86 9 torr @20

3.7 insoluble





Dry chemical, foam orcarbon dioxide..

Inhalation Inhalation of vapors may be irritating tothe nose and throat. Inhalation of highconcentrations may result in nausea,vomiting, headache, ringing in the ears,and severe breathing difficulties that maybe delayed in onset.


If inhaled, remove to freshair. If breathing isdifficult, give oxygen.Call a physician.

Skin Skin contact results in loss of naturaloils and often results in a characteristicdermatitis. May be absorbed through theskin.





Ingestion Ingestion causes burning sensation inmouth and stomach, nausea, vomitingand salivation..

Do not eat, drink, orsmoke during work.

Aspiration hazard. Ifswallowed, do not inducevomiting. Give largequantities of water; ifvomiting occurs, keephead below hips. Getmedical attentionimmediately.




Xylenes


1330-20-7 liquid clear aromatic 9 137–140 -25 0.86 8 @ 20 3.7 insoluble






Inhalation Inhalation of vapors may be irritating to thenose and throat.

Ventilation, localexhaust., orbreathingprotection.

If inhaled, remove to freshair. If breathing is difficult,give oxygen. Call aphysician.

Skin Skin contact results in loss of natural oilsand often results in a characteristicdermatitis. May be absorbed through skin.


Immediately flush skin withplenty of soap and water forat least 15 minutes whileremoving contaminatedclothing and shoes. Getmedical attention.

Eyes Vapors cause eye irritation. Splashes causesevere irritation, possible corneal burns andeye damage.

Safety goggles. Immediately flush eyes withplenty of water for at least15 minutes. Get medicalattention immediately.

Ingestion Ingestion causes burning sensation in mouthand stomach, nausea, vomiting andsalivation. Minute amounts aspirated intothe lungs can produce a severe hemorrhagicpneumonitis with severe pulmonary injuryor death.

Do not eat or drinkin the laboratory

Aspiration hazard. Ifswallowed, do not inducevomiting. Give largequantities of water. Ifvomiting occurs, keep headbelow hips.



ations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point (°C); BP = boilingpoint (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific gravity (g/mL); VP= vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0); Sol = solubility inwater; N/A = not available or not applicable.

Zinc Chloride


7646-85-7 crystals white odorless N/A 732 293 2.91 1 N/A 432%




Inhalation Irritation, metallic taste, lacrimation, sorethroat, hoarseness, chest pain, soreness,nausea, abdominal pain, and vomiting.



Skin Irritation, redness, pain, papular andprimary dermatitis, chemical burns, boils,and ulceration.



Eyes Irritation, pain, redness, blurred vision,corneal burns, ulceration, conjunctivitis,dermatitis, and iritis.


Ingestion Irritation of mucous membranes, corrosion,swollen lips, sore throat, chest pain,nausea, vomiting, and bloody diarrhea.






Documents

Abbreviated Material Safety Data Sheets (MSDSs)fjetland.cm.utexas.edu/courses/organiclab/Safety/msds.pdfAbbreviated Material Safety Data Sheets (MSDSs) The abbreviated MSDSs provided