l �.,._, ..... ·······-·- .- .. , -·---�·- ·--- . .... .. ·- . ,, .. . .

80701

lMitlll IMft nt !9 7 • ,.�-- .. ,--.--- r-.•- "'�T- -r- ,.. r--aT?-,1-..1,_

I•! • I -� � � .,1 I •• • - I" t a -

dmXm fillf8'1TW61fdlW6b I Chemis I

ec:,eo::d: * q3f>�iik11:, O�f>= eooc::,:, qia,.* 0®® 9<dm o,ac::, 8� 08 Bzrl az:,fo c,!),* t.Bme • gcd,:nf>ce> � eooc:1zrlm.* w mdf; cmea,ma - et;Q NIIC!WI).

(@JlOOIOOJ

* cdc<1 b� &81:21 =�meat e!>'9& !>c:mm qom,a, 8c.:1zrlm.* cmmd o,aec4 egoeo � qiaSI q•m= c�= eoiel!ie®d O l!ic::,f>mm.

t!lllll� li1161Jdr(J) IDfillllfl�pf/lUIT60tb 1wohours

* 1 Se> SO emmf � �= gcdmc.,c> (1), (2), (3). (4), (5) c:,m �O{!m" 86t"'! acsd ,cmad �­S�d e1to:fd:, �m. �r.o eaJm0 OflG 8Qom Odaem � C,C,,: IIM!IOmd (X) etme; �

=�Ora f>3'3 &or.o R = 8.314J ic-1 mo1-1

q1DG:>:>!><JK1:f �c.:m,c., NA.

= 6.022 x 1«>23 mo1-1

�etzrl� �c::, h = 6.626 x 10-34 J s q3Clte4tNc4 gc,t>cnc.:, c = 3 x 1a8m s-1

1. cd®:>1§� !>�eoc., 8� o •o:>hm<t<d '«:fee 9�0· qmaSc:, Di� @o &ld9 =G !)�:030ico o�<9<4.

o> t1�m=0 d��!>. (2) �o ®Bts,m.. (3) �d= Cit@�•. (4) ctadzrl �f4e>Szrl. (5) '"'zs.16 �8.

2. c,ma, q4a eo9@zrlQec::,zrl 8m q®m !)(!)zrl&, qmam !)tsfc,m �?CO

2, BF

3, PF

3, CF

4, XeF

4, SF

6

(1) ac.,ci ® q19oea 9t!lc., e1eocoac @zrlwm qio.(2) Sc.,g ® q�CIE> 00md eo1£>c::,zrl qic.(3) Sc.,� ® qi§ qlllfc>= �ec., q�mc::, 0m=0S.(4) Sc:,g ® qi§ ��9t!lc::, c.9!).(5) Cf� � o®41imf c!JO� ®Q:i, 06'®31§ c,qO �z:neod C1<9Cmf�m amd ooa.

3. c,lDC) 'i{�m c,oc,9c::,:Jcs,<9c4 IUPAC m:>t>c::, q®mf �?

yffO H-C•C-�H-CH-CH CH

OH 2 3

(1) 4-fonnylhex-�-yn-3-ol(3) 2-ethyl-3-hydroxy4-ynepentanal(5) 2-ethyl-3-hydroxypent-4-ynal

4. mSOdd� e>afSr.:11d41i qf>dt):if> -1 f>i:dC9z:'1,

(2) 4-fonnyl-3-hydroxybex-l-yne(4) 3-hydroxy4-ethyl-l-ynepentanal

(I) N204 (2) NP (3) N0

2F (4) NH

3 (5) NH

20H

5. .®O:i, �D DD:> @c:,,:,maSI �� ct<9C=f�m aa,d o:i,:>®aSlc.:i o�mS =d m�®zrl ommc::, !) qiSq4aoe IDtf;)c::,m B'3oc::,,:iJ qic. do:, mil,( 1) �c::,. ez:n:r�. S-19C:f. (2) 9�@c.,, T - eoic)c:i, S-eeo:r.(3) �c::,. @c.,:,maSI Sd8£>3z:D:>6, T - IDtc)c::,. (4) z:i,8c:i @Ms,:ks:>=36, MD:f&z:n, T • t0tc:ic.,.(5) �ale.,, mc!c., @-z:'114�36. S-c.9CO:f.

6. q1CH>:f253c.,9 mSO<J.�O CfCOS clll�c,d ,. mSOd'dzrl !>:>af>, lilmfSozrl �o i:s:,:, cc O:,rlc, =�82rl =�:Jam•eeo !)ec.,:Jdmc., �- eoS®c Glll.flod0c9c:4 , eo:i 8f;)me9<:f � q10®:r�c:ie mSo.t50 240 g l,c»c.:1:fcmQ !l<!J'®mCOtC!Nim �� 03a 8EXS C.,o@:i,:,O 0��.CH= l,N= 14,0= 16, eo9Sc cal4&� � coo ec:iml9c4' 0:>e �e �= c,68:,f) eao 22.4�.)(1) 33.6 (2) 67.2 (3) 100.8 (4) 134.4 (5) 2352

-2-

7. AX =o-_ BX2 "'� c:SeC!JQ� qdo !)aaC9Qm SX}ll ef>.fm. �=ii. r:n:,@)6 Gal�� �&3 SX}lla» cs;i.&=Bi9!>2m K c.,io K @!). AX &3 �ll� p f>m qcc::S BX2 Ea �e qmc:, q �. c,mf C,mf eE>-eoc.o c,&3 eoomadm

•P1 '1'2

K K S:>DC!iic., c,®m c®�B-a,m:>D�e cnB !)a r.t1, =

[ ;�2

] 9!) me, oa>c =� &>:>Sm q®mf �E>t� � �.,

l A(aq) j B(aq) (1) p = q2 (2) p2

= q· (3)· 4p = q2 (4) p = 4q2 (S) p = 21/'8. mfa:16 io:> mf�c., 0:>o«a •e&io c9@zrl0c,c.,m 8m qi>m E>a>mBc., qmam (9!) �?

(1) &.,g ® mfa:>t5c., o:>oaa ee:Jeo N2

f>�f> eo®m c»CDG cal� � gB@Q:> =c::SS.(2) mf.:&, o:>oaa ee:JeoE>e sE>:>o= c,s q:>f>t1cCltd® trtl!n mfa:>c::S 90:Jeof>e s&.>or:nf)� OO:> E>ta "'·(3) mf113c::S •C�CD!>C �E>m q�z:l>d'41i <DmfBI� �® qaf>tsm�S cnB =•�c., O:>o(i ee� "® qll>QQmD Do.»

�:f E>ta "'·(4) !:If.,&, c:1:>oaa 90:feo c:i:>trm Sc.,g ® ioS�coBc:> 9� eo�® •!).c�> moa <!te!:llo 1D8�c8!:lVe ,:>f>llm:>f> !$:IS� c:1mc;c> E>tl5 �-

9. S&�e (Li) coaec:> <1��"'0 Citl!tmm =� m:i,arot,, q:>C9c::S:beic.,,(Li. Z = 3 !D:> =�=• oc::S®31§= mzrlec., = 7)(1) +3 a c®:im "'· (2) +3 o 00:1 qQ co. (3) +3 c:> Do.» E>tt, c:,.( 4) + 7 a c®:>m "'· (S) + 7 c:> f)c:>:> qQ "'·

10. � cnB G�= � Cof>at:I) 'ii� m:iomc.,mJ � 01:l)a) c.,®qac,c:,f)c., of>BI.2S03(g) ¢ 2SOig) + 01(g)

"® clH!idf>C9d � u,:>dmc., �a q®md Oig) 9®:>6c:= "m,q z:l>d'm e�. =®�8z:i,m:>f)c.,D m1f>m c,�4a oa

�c! =®a:;8mc:,f)� e; qmc.,o c,mc.,m�m:mf®=f> f)fil:> Cf.� q� &.am•m �m z:a®= �? (1) gB@� m®qB-a,1:1>3 �r.,cc., (2) c,<:wBC9d � &>me.,(3) o<oB<»d cnB SOig) 9®:>-eoc.o (4) o<cJl!ne9d ·cnB SOig) g®3-eoc.o(5) o<oBc.c:f c,tB Oig) 9®:>-eic.,

11. mSOc::Som !)n•c.,m&3 o-N-O •=41i"' c,9@moc,c.,m OiDm =«tinm qemf mam C9!) �?+ - 3- 3- + -(1) N02 > N02 > N02 > N0

4 (2) N0

4 > N02 > N02 > N02

+ - 3- 3- - + (3) N02 > N02 > N02 > N04

(4) N04

> N02 > N02 > N02+ - 3-(5) N01 > N02 > N0

4 > N01

20 12. e:>e�mf �a<Dl> q:>�:bec4 � r:ne� (470 nm) cmoc::SQD 6.0 J mmfe� ��E>S. �� 1.0x 10c:Smmc., BM> =«tU>:> e:>9e!> et11:>0®41i �c.,mf Cite!!'"' � �?(1) 2.4s (2) 7.1 s (3) 8.Ss (4) 9.2s (5) 10.Ss

13. gB@c.,:>E>mf 298 K !03 100 kPa ec:>med ' edE>aioB<o f)zn q� �" lfCDS c� � CD:> �- &>� 'td!>c.,oB(w ezn:>C9!). CH)® gB@c.,:>E> mc;io:> 298 K &3 ' coo 100 kPa &>� ' c,ma, m«crs,m qf>af mae � 'i?

(1) (2) (3) (4) (5)

AG AH AS

14. •�!rlm:> X m®tB �!>= ®�S=, mmCc., �-='i!D:> c,a,c, c.,'iu,m ia@lc., u,:,&, z:l>d'm e�. odf>, &jf>:>mc., qc:>o� 06®:>f> V Dm �� ts>:>d�c::mi da,astc::x., m

1 <9C= ��m c�. c,moe, &,@ f):>a)Q IJf>d � u,:,c:Smc.,

C9m:>�mm:> X f>:>9C9f>m gd!>:1 =� m2 ee= S�m e�. !)� o.m,c., C,CD ·�mm:> �f) C.,z,) � �1:11@>Gal41i� (n CD:> 8c:>zn<9d (P) Otf>J:D&. &,g O.,Cec.,6o aozr.,df)c., d �. oCDa, mCiU>ffl qt>zn gm,<DZSX., ®@m•m:>�mm:> f>:>�� ®�Bts, d� Cc»:> �S �?

dRT(1) p

(2) [ ""i -("'i -dV}]RTPV

(5) [ "'i -( ""i - dV)] RTPV

AL/2017/02/S-l - 3.. .

15. &sitl):i=h ,ae qeec:iBm v1 o6®3f>=f, c,=�8c e@e tl)c®c:i&:rl v

2 o6®x>= =®CD 819 !Sa(N)m cEnd=feiz:11

� �m e�. � tf8eec:i@ ax, gSe tl)d� �z:11 e:,:,2'%4Jii �<9!>i,m c1 coo c2 �. �@e CfSe0e.:1@

qee �m �c.,mc:, K1 �D. dnda= s:>E>4Jii<9c:1@ pH q(l)c., pK. -1 ti):, pK

1 + 1 ql:S)d' c,E)aro:, (1)1�®c> me ou:,c

e�a:>m ,f:l®m gz:i,:,mmQ ®@m c., c2, v. c:,a, v

2 �ax, ��� c.,8a)zrll,;)z:n:,f) e@� c,_?

(1)

(4)

..!.. < C2V2 10 C1\'i � C2V2

< 10

j_ < C1V. -C2V2 < 1010 C2V1

(2)

(5)

1 ct� -< ,10 c1 "1 - c2 v2

CV. l<-1_1 <10

c2v2

< 10 (3) 1 c2v2

10 < CV. <10

I 1

(5)

17. <1m:z, eos eB,@c:,:,E)m, q:Jdetl)z:s, faez:n:,E) R0

ti):, e!)C!) �c:,z:nc:, k et>. (f:lde«>= =:imsEQ SO% Sm q� '1 !)agB@c.,:,� e�v v�ed.

(1) k (2) ¼ (3) ½ (4) � (5) �

18. Ni2+(aq, 1.0 M) /Ni(s) ax, Cu2+(aq, 1.0 M) /Cu(s) q� �. e�dQ=f ®@m ID:i ef>41i �m co8ci>m0�m � c;jc.,:,Q. � �ZM>m e,. =-� � �:,f) ax,"®® qtso � <!t<jC> e,8@m0� !)c) �� q:Jdetl)z::D �c:, f>�.

(E' 2.1.. •. =-0.24V c!D E'

2 1. =+ o.34v)

Ni /1'41 Cu •,cu

(1) Ni2.(aq) + Cu(s) - Ni(s) + eu2•caq)(2) Cu2+(aq) + Ni(s) - Cu(s) + Ni

,,.(aq)

(3) eu2•(aq) + Ni(s) - Cu(s) + Ni2+(aq)

(4) eu2•(aq) + Ni(s) - Cu(s) + Ni2+(aq)(5) Cu(s) + Ni(s) - Cu2•(aq) + Ni2+(aq) + 4e

; o.oov ; +0.58 V; -0.58 V; o.oov ; +0.58V

19. ·C:J®d cll41i�' com f.)SqQ!)m �c:,8!) (1205) D:J@m �m:iz:ikoS!> =� gS@c.,:, =� c:iam�C9CO:dc,S!) too qaiem e:,:,�S. f>:ie C:J9c,ec:it.:D (ftB =oam .e:i.m:ac,S!) � @t� C�tl):, e®Q u,:,!}m

3 =s wt=>, S.Odm f>:ie c,:,8oec.,=f I205qt.)o<Q �= � c.,!>:,, ��OU>tedm qc.:,em d8c:.:1 KI�4JiiQz:i,E> (��

KI (ftl:S).) �=q =dm e�. et�m �41ic:, &roe:, �&it1)Q ee= <K,Y:, 0.005 mot dm-3 Na S O �4JiiQ=f c®CD-" 2 2 3 q�®:>omai =c:Sm e,. q�» � Na

2s

20

3·o0'®:if> I0.00cm3 .t,. � t.,:J9c,e� =:iam e®:ie�S!> c:1�41ic:,

(ppm E>8m') E>�, (C = 12, 0 = 16, f:>3Q c:,Sr:,e� comz:sIDc., = 1.40 x 10-i3 g cm-i3)(1) 100 (2) 250 (3) 500 (4) 700 (5) 1000

20. c,d{')t1 � �la t.,o� d&m�zsf OU>C �a:,m r:Q@)m E)C!)i,fBc:, � E>m•m �?(1) Sc:,� &>afS=cS4Jii qE>d63 -2 Sc:> +6 o6:,cc:,d qiB qeebS. (2) �ar �c�ar ee= so

3 ccib �8m e,:ims H

2S0

4 =®Cl> s e84i� cde.

(3) 1!>mSz:s>:t<1� e,m tilt!fS11:1�=f � ��:id'dc)® S02 c:> @c:,:, � I.Dlz:::D,(4) &:ie g®H&Qm(M)m s �11:1mc:, � qee �SE>ec> <t:,c:,= <!l't). cs> =z,% H

2so 4 o eae qeec:,=. &)af�= e,m �e=:>d'r:DQ=f c,ec, @<-,3 =s I.DlC>,

21. 298 K Ea·�. N2(g) + 3 F

2(g) - 2 NF

3(g) � "'4(too 6.H0 =-263 kJ mor1 �. NsN m:i N-F @trlCm !,e11c>m

�m=tdS q(l)Qc:,z,f Sg<9E)@z,1 946 kJ mol-1 too '1:12 kJ mol-1 at�. F-F Ei>mCtnatc:4 amczn &c>m �zrlm1(�8 qa:,c:,(kJ mol-1 E>8zrl) E>��. (1) -423 (2) -393 (3) -141 (4) 141 (5) 423

AL/2017 /02/S-1 -4-

22. 3d - ��� �CGf>ll eo9@mO�m oeoe> t1®m D<Dm8c:i CJC1DD et> 'i?(1) Sc. 11 c,eo Zn !)£)ex, too� �tsmmc., em:>tS>68.(2) 3d - 9<S>�� iCSD» CMX1fi �h eaf�dtD e!>.(3) Mn. q:i98m,, cui� c:om � ti>tsfcoSE:> �S.(4) 3d - 0<D:1�C9!> Sc.,g ® 1esf>11 qqe6m qQ® sD:ior:nc., 41ded Zn D "'·(5) V @ Qm Ci>z::sfSz:n641i qOdc,:, +2 SD +5 ocm,c.,r:s, cnm.

2.1. 3NO(g) � N02(g) + N20(g) gB� COC'ia:>3 om0> c,:,c, 6cox.,m 'ida, � c,t0>.

AH0 = 35 kJ mo1-1 AH0

, = 80 lcJ mo1-1 , A"J. = 90 lcJ mol-1 /N02(&) IN20(1) NO(&)

11eoc, gB@c.,:iD co�m:i oeoc, COCccom q®m �:>ID"' mme � 'i? (1) 6H0 =-155 kJ mol-1 Dm qc,6 CG!Hlimt:)Q f;tt::> !)®af Cl®ID � co®�m:, �� tp<DQ � �.

<i> 611° = 155 kJ mol-1 Dm qm6 �GHliafDc., f)i!) "®af e.,@)a) glil@Q:iet) co®�:, �c.,� qmc., q� �.(3) 611° = -25 kJ mo1-1 !>m qm6 clli41idf>c., f)i!) !)®cf co®ID gii@c:,:iet) eo®q&,m,:, &� qmc., � �­( 4) 611° = 25 kJ mo1-1 !>m qm6 clHlim00 f)i!) "®cf t.O®m � co®qSc,c:, �'-'C>C9d q(!)c.') qg et>.(5) aH0 = -155 kJ mol-t Om qe>d cal� f)i!) "®af co®<D m®qSc,c:, l&,m<9d qmc., f>t� el>.

24. oeoa, �mc9f:>m eB@c.,:iE> c,e=mm.

0 �-CH2

a-Q Br2fFeBr3

N -o (2) �-

-CH2

-0

Br

(4

) o-1---CH,� Br

0

(5) �-CH2-a-O-Br

_rJ. -0(3) Br�-CH2-0

25. Ae.,o�:fa:,c., UAIH4

e:,s«, e8@c,:,:, t!ld B e@:i �a. AD 00:, 8u,:x48=, "'· a. 0-5 °C � NaN02'HCI coSCD 8&,9

=e !)c) N2

f:)z::sf0> �- A c:,u, B �® cn-®:J&.o AgN03

c,@)(D glilp t!ld q!>dcNlo e@:i �. A Iii f>,amc., �IDl='•·

CONH2

(1) ��CH C=CH 2 -

2

(5) H2-i-CH3

26. !)ec,:Jm dC,6� z::sf•c., "® 8@@c; 0 8m q®m !>CJ>m8c:i C1111D et) �?

NH2

(3) �

2

�-�-CH. 2 8 3

(1) !>eeo:b:d ci®<D =ec�c�:IC96:a3Qlm (CFCs) eoaaf) ® gS@Q:i t!ld � crc,csc., dac., =dS.(2) oaa!> oa�c., ®cc> IR t9641i eBm "® !)� d�C9Q� r:iJlic.o � ®ilm �<Dtmc9!),(3) !><M.,:fm dC,6ed =•0 � mc;eo:i eo�c�m (HFCs) 'i:)Qr:D et>.(4) �oe�e zSCS4lil ens !>D !>(9C):fm ere,� eDSm �m �� �QD ui:,o� '9D.

(5) c10· f:lz::sfm @Cliff.) �trl o®41otsr !>eeo:b:d �6c9d z::sfa0 � f% �.

AL/2017/02/S-I -5 - .

27: !>�d 00��:i, �c.,d qc; � !>m AIF:-(aq) + 3e-+ Al(s) + 6 F-(aq) � 9B@ai:if> e.,S@mQ9Qm omm e.,"eom q®d a,am e!) �.,

2'.

(1) Al e>dSr:lld� �.(2) AIF!"° ®dSCl>d41iQ e!>.(3) Al e @dSr:lld.ei q� -3 Sc> O �� •E>me4 9!).(4) F- ®dB�=c.,d eoe., @co,:, ts>d'S.

(5) F- @dSeode!ic., 9!).

p Q (1) CH3MgBr , · R(l)W

qJeom 't(t:'lb!>m gB@c.,:i q��®�'3 P, Q e.,es> RS f>'9m Bg�@m !>�ec4,

OH (1) CH

3CH

2&cHO , CH3CH=CHCHO ,

· OH(2) CHJHCH

2CHO , CH

3CH=CHCHO

OH _J

H3 (3) CHiHcH

2CHO CH

2-=C::HCH

2CHO CH

2==CH-CH

2 HOH

fH3

(4) CH36!cH

2CHO , CH3CH=CHCHO , CH

3CH==CH-CHOH

OH � (5) CH

3CHi�HCHO , CH

3CH-CHCHO , CH

3CH==CH-tHOH

elD:,to:,!)m, cj@tj e amd':IE>t1mm c!h:nm,c.:, !>mem,

(I) ''S-<l-I:. CH CHJ-

(4) 1� <

CH,

t CH2

H

30. lese:>i,c.,ts, =e:io cc>eom 6t�'3 �!>., q-im. (N)@) tiesE>:i,C9Q'3 r=e:,o c,c)es>m c9@mQc,c.,m OCl)r:l) . e:l«tei>mq®m !>mmBc., qa,am et, �?(1) S 1, S2

eoo G =e:io c®qSmC):i!)ec.i ot>Bm T, P mdd!> t>z:id qtm.(2) S

1,S

2eoo Lts>�:>0 C!®qSti,� ot>Bm T,Pmddf> t>ts1d qim.

(3) s2, L w:, G =e:io =®l::;8m� oDSm T ,Ptndd!> t>=d qim.(4) S

1,L w:i G=e:io c®q8ti,c:>E)ec4 oDBm T,Pcdd!> t>=d q-im.

(5) =e:ic �=c> Ot� mei2:s>r:lf e.,®qSti,cx>Ckf ot>Bm T, P cdaro qmdz:i,e:,e e,c)�me 'i{de!),

p,

SI

s2v ;.,--/V G

'-------+T

AL/2017/02/S-I -6-

• qoc, 31 Sc) 40 c»C>d f!ld f!lz:sf 9<dmc., eoc;i:oo , 41S (a), (b), (c) t.0eo (d) a,m g8£nd eomd qqe9dzrl, f!l=d ea,:Jf>t� e,oci):x,:,t)d <M>:J �f>t� C.,. �� 9@£>:,oa,/gSf.>:,d � "1'6 �:Jd:, (5)mtft.

(a) eoeo (b) o®.eid �Ot� me (1) ®m "(b) eoeo (c) o®eid �!>t� me (2) ®m "(c) ceo (d) o®4!id �!>t� me (3) ®m "(d) =eo (a) o®eid �Ot� _me (4) ®m "eE>md e@f>36 t.Oo@»oE>= ea,:J t.Oo�znc.,r:,J ctcoo �Ot� zn8 (5) ®c �

Gm6 o,a<!tc:)e "1=9f>m e�d 0� � =6zrlm. � coec,d �

(1) (2) . (3) (4) (5) (c) e.,u, (d)

o®Ciz:d�Ot�'3

31. T 1, T 2 (T 2 > T 1) c.,m eai-emmf>c.:sm e"e=e � t.0t0 �c.,m 8f:>mec4 �A(g);:: B(g) e g@@a,:, g®341iic., (extent of reaction) =®m ce®m@Sd <Dr:IJSC9Qe !)Oemai dto eoou,eme 4idf>:l inm. oeom � 418 qSmf)(!)m&,/ OCDzrlS Cit®® g@@c.,x> C0tit03 4'&dC � "?(a) T 2 e ' eo®z:aSmi:oo &,mc.o T 1 e ' a 00:, !)<D:,e �.(b) e@@c.,30 m:10:>f>e<D:r.c, �.(c) e@@c.:,30 t.0t;U>:> Om �S0 q(!)a,z:sf 41m.(d) gS@c.,:JO 0):J04i3"'CI �.

Br HBr I

32. �CliiCH = CHz ---=a.--• �CHiCH � + Cf'3ClliClliClliBr

p Q

afllldsaiV:16 Qo@:z,:,f)z:if �

CDo�:fdtDc=iS CN>:f ��a

. - -Y.---/ - - - -- - - --- -

--1;-7 ----- --�·

I -

tfer>m �=f):, (f18 98@c.,:JO t.O'il:00 omm � q18 OC!>zrl.S08m e&dC f)z,bm q8z:sf �? /q@)m c1f>:J �? (a) a,®® gS@c.,30 �8�8= q:i=em �.(b) P 9� �ec., �.(c) 98@c.,:1� os� 8�, =��1Doc.,mc.,r:,J =1e<.(d) Q 9ll:1m �ec., �.

33. oeom e3Citom f>mm.S =:it:sh @c.,308 eo®eo6d eoe@tsro�m �. em q@)m f)C!)m.ak., / f>CDmS e&dC � (i?(a) KOH «s:>�c r:s,d G(id-t eo@zrl ��f>S.(b) dots<D @c.,:if>8Clte4 � S03 e@:i �� so2 eo:i 02 � c,B@c.,30 =4:c110:, � &>m -aiddf> q:n@eoc., ��.(c) Cltt.O:,d� 7c!l®�m K

2C0

3 eoocded•41iQ e1s 1101e1.

(d) f:>�md •=•"' w:>!,z:Mc.,zrl Na 2§Wo�mec4 � Na 1103 �m � gS@c.,:, ISt5® Vte1=1!)eo =1•z:n:Jf>fD3 41em:Jf:> � 9:J!'6c.,i!im CK>m=6 (fllS>.

34. @'9-&,!>6 e.s@c.m>ci 00:im ® ec,lm s� f>m &,f)<j t.O'iU>:J c,ma, q®m f)a)� / f>mmal ell® !)c) ® � Cf!) tr?(a) f!le q4a=c:,E)c., � eoo@::i:,:,f)z:sf �.(b) f!l@ q4a=c:if>c., eB� eo®dc eoso 003 !>t� �.(c) f!)@ ta,am:if> ®c c,Scda, gB@c.,»E>e taem:JO 6'i:i of>a.(d) f!l@ q4a=c:if>c., gB@c.,:,Cltf)@ Bc.o06 eoo@l:l:IOc> eo®:im �.

35. q:M9C=>C., Iii)�� � CH_.

eo®ID Cl2 e.s@c.,:, diee98 � e, ...eee f)f;):,m @) �f;) 'll.s � Bc.of>6 OU)a) "11Hf>m�Sirl q®z:sf (i? / q®m c1!):, �?ca> °C"3 + c1

2 - c�c1 + ct" Cb) ·c"3 · + a· - c�a

Cc) CH4

+ cl°

- C"30 + H. (d) a· + u· - Ha-36. NH

3 m:i NF

3 mecimo�m 8m q®m OCDmtic.,/OCDm61 � � �?

(a) NH3

c> f>f;):, NF..}

� cizrlQm �md 6=�41iic., �tsf>e �.(b) NH

3 c> f>!):, &te.:> �f> 5�41ien:!f NF

3 c> 41m.

(c) NH3

c> f>O., NF3

9cile �6= tOGf®m �.

(d) NH3

@ N 1!0:1 H 4Q6 � mt41iic:> �=d NF3 � Na F qDd �!> � � ¢D dan .e).

AL/2017i02IS-I -7-

· 37, 1000 K � 2 NO(g) + Brig) ¢ 2 NOBr(g) �!> eDCc"'° c®q8J:ll1:113 �Qmc., 1.25 x 10-2 mol-1 dm3 e!).�® c� ' e,ma, =�mm q@)m 9=:,aac:1/� � et) �? (a) =Sq8m � NO(g) a>:> Br

2(g) � qrfi! � cpoa � �IXXI �C:I Bc.,mc.:,

80 mol dm-3 �-(b) e,8z:u8m �63 NOBr(g)etJ@E> 416\ � q:,oe �E> �a>:> c®qi&,)a,:, &.,� 80moldm...., �. (c) =Sz:oSa, � NO(g) a>o Br

2(g) e§@E> 416! � l!fOC'S 98@<:,x> CCIU>O oo®qSa,.r:,x, &ax.,

1.25 x I 0-2 mot-1 dm3 et>.(d) =®q8m � NOBr(g) 9tl@fl 418 c,md q:,oe � �a>:i ci>qSzs,1:1>:1 153c;,ax:i

1.25 x 10-2 mot-1 dm3 �.

38, � � S'1Jm �q .. ftS=, 9B@c,,:,E)=f e,S&m� oa>m �r:om q®m f>mmfi!c.,/E>mmfi! � � �y (a) g8@<..,:)(ff)e e&ir .... � ��.l&Q z:s,d'm e� � �= f)z,fc,z,.f g8@c=,c.,m63 e.,:,�.e. c,@):,m t;! t,o

08.&. . . (b) gB@c.,� c�41i q� 1 : 3 Elm &) gB@c.,�63 o&.41i=f®z:s,0 �c., =>dm e� 90S qm �­(c) �z:if gB� t.:1:>mS.flic., q�z:K> .f)En e.,mco�d®=E> !)m:ie E>Qc,c.,z,t f>t!) Om !)E) sfi!@co:190&;

&� "® gB�e =:tirls41ictam e:rvx=rc e!).Cd) �c.om cal4&�, gB@c.,= qE>oaa �em@ 06@:>o c,� =e !5c> gB@c.=, cp:1>d'·\D� tnB � es,�x>

E>t!> c,t).3'. omm CCrU>m q®m O\DmBai/f)c!)mB e®Bc,i .amem (�!)m') eoecm:1 � et) (i? .

(rce3eo:,gem (a) Baig ® =:iam od®Hi§ "· cec.,z:i, seas.

(b) Baig® =:iam z:s,:,S)m @mQmf)e �CI) �mrs,c> e.,i):,m �-(c} Baig® m>:iSlm mS!ld'om ci)mQ� �G) �mea c:,®3t,) et>.(d) �mt$ C-C-C @mQm �Gc=f 120° ·z:if e!l.

40, 0:1'9 � co9@mQatc.,z,.f OCDm � c,18 z:;Sm f)c!)mak� / f)c!)mlil eEJir.dC e!) �?

(a) de �z:i,mGlE>e c,1S cc!t9<."tc> �c:tm:J8ai H2S 63 9mE>=il.

(b) NO(g) ®@m SOig), SOig} @00 06�mmc:1 !)® Ze =>OS.(c) � c,mQm �mm<td ' Boom NO(g) � ,•t1K-'=f -e= effl3t:11en.(d) �tt<D&e� tnB SOzCg) CJZl4a CH!)� 8@m 11Dm et>.

• qc=> 41 Sa SO CM:D=f "1:1 "" eafmc, =«tl:03 gz:n:,m � @t@m �6od =>d 4tm. �® 9=:im a«>ec.,c> acm(aS eCJ>tSC90fl39d oeoa, f>�E>63 (itdcK>m � (1), (2), (3), (4) c,u, (5) c.,m g8�:>®8m eOd' 961E>:>c:Sc:1 �·a ec:fd:icmmc:S o,a.ai@ cl'm •eco CZll'ta r:1102:lfm.

gm8ldm �GIDICB � CjlllJCllm (1) C,1:1))5 et>. C,r:lll) �m qmd', oS�f>t8} gz:s,:iaac., 253E>t� E> 0U>'t3 �a.(2) C:,1:1))5 <9!1. c,r:lll) �m m§d os�E>i� �" 253E>t� E> � � • (3) e.,c,:z, (9!). q=au, et>. (4) qe:,c:z, at). e,a)]S et>. (5) (JC,J:1))5 .t). 'ftlSl!llS .t).

Cd&,egmar.n �QIIDIJlal 41. @S=a@e� q"'m�e C-0 @mQm =� et,. a&!,:,ci)e9� qcomco dc):,9 c,@>99=c 0,Br:o

qmt:D =•ea• �®d c,!),

42. HOCH2�Br � Ocd @:>0:i:,ed � Mg =®m 11>�Sd z:D3d!>Qtsf qE>oaa c:,ceclm c@m

gB@c.,:, e®m ©mo!> sfi!e:id'z:i,co=f ea�e es ®m:i!l gSz:D:id'z:DQ gS@c.,:, •m:it:1)6'6. C92'):JU>1z51 co.

43. �GZ> caUocfo.d � 2Hig) + CO(g) ;: CH3 OH(g) &m cal� � d'e:x:s�= c®z:;Smai�@

=®qBc ��e e!lmc.:i E>t!3 ao-.sm � C1!1S O:>e@co e�e.co= 8Dmco E>t!3 �<98 � S�c ��:,me., �qeic) � e!). eoam:>O � Om � e£il@c.,x> s, et>.

AL/2017/02/S-1 -8-

44.

45.

46.

47.

48.

4,.

50.

celQe QIID1Q �QID3CIC.II

II z:s,:,df;)CJtd eoe� cs» =�mOOe s:>f)l)tS)3f) qc.,a§kD C)o�z:I) �:om,f) �� eoeem mr:sfak., r»d�C!td omsc> c.,m !)a qQf>m lfD)c:S �==S� Sm � c:S41i:> o!>S. =c;a:i:i �c.,D !kSi<D 1530'!:d•..&oz:d er.�s.

'f�MSe cns,(96� (fteNmf>e !:Sl:l@m 110:> �!)(Sdm oc:1®31!§ qm6 !)�r:,fea@c.,:,i:s,:,O'r:sff)c., cneBmVea VO., CJ� "'· c:11141iz:D:>f)c,c.,&, �m= q� �= a,�moe

C-H &mOmOe Ql_@)Qmx)c., tff:) "'·

eooDam eo:idmc.,z:d � 418 de &.,lie, =��!)zsx., !>m f:lo!>az::D o<t)61c.,d e>@m q�,..c., r::DS m:,c,c., !)a qoa o6eocs�e �m� E>t!) �- qoo o6�5' m:>C®c., E>emc., Dt!5 ts>CSS.

NaOH �o�m�c.:f , u:,:i!,m Vm ooe -=� ooe � co�m om qc.,m Dd&"' oaec., =i�� qacsc.:1 co:i c,1c»m� q�dQ c,c.,m V<:1,&c., =io.ic.,m ��t !)Sa 116> •too�S. oaec.,Bm ee>m =>d' cnm,

2-:butene 036'@®:im eo®:>f)�m:>f) "°m!>S. �.m� �ts04lit g61&9@ em:>f)m DljllO �Dm 2-butenc eoc;m:i Bae., IIO'{D.

=:>Sd GIHlid� � MnS(s) e de� s:,f):om:>f) pH S2-(aq) ,esoe q8ec.,t11 coo�� ts:1d8<., �.

CJCDQ @lm de;:> •z:oooDS.

d-<N>O� §eso;z,e>e sf>:>o=> s-<K>� 1esf>:ef>e d�.t> §etDllf>e � &mom =1�.e � sE>:>ol:D!>ea 00:1 f>t!5 "'· !)d¢:)2')G)a, �. =er=, d mm s Cl� (ftal,

***

1

2

3

4

5

6

7

-

1

H

3

Li 11 Na

19

K

37

Rb

55

Cs 87 Fr

4 Be

12

Ma

20

Ca

38

Sr

56

Ba

88 Ra

21 22 Sc Ti

39 40 y Zr

La- 72

Lu Bf Ac- 104

Lr Rf

51 58

La Ce

89 90 Ac Tb

23 24 25 26 27

V Cr Mn Fe Co 41 42 43 44 45

Nb Mo Tc Ra Rh

73 74 75 76 77 Ta w Re Os Ir 105 106 107 108 109 Db Sa Bh Bs Mt

59 60 61 62 63

Pr Nd Pm Sm Ea

91 92 93 94 95

Pa u Np Pa Am

-

2

Be

5 6 7 8 9 10

B C N 0 F Ne

13 14 lS 16 17 18

Al SI p s Cl Ar

28 29 30 31 32 33 34 35 36 NI Ca Zn Ga Ge Ju Se Br Kr

46 47 48 49 so SI 52 53 54 Pd Atr Cd In Sn Sb 'le I Xe

78 79 ·80 81 82 83 84 85 86

Pt Aa a. Tl Pb Bi Po At Rn

llO lll 112 113

Uan Uaa Uab Uat ...

64 65 66 67 68 gJ 70 71

Gd Tb Dy. Bo Er Tm Yb La

96 'Tl 98 99 100 101 102 103

Cm Bk Cl Es Fm Md No Lr