north sea landfill - Records Collections

65287

ANALYTICAL DATA REPORT PACKAGE for

NORTH SEA LANDFILL TOWN OF SOUTHAMPTON

DECEMBER 1987

Submitted by: S

H2M LAI9S, INC

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o o o HOLZMACHER, McLEMDON and MURRELL, P.C. Consullino Engineers, Envlronmeflla* Scientists, Architects artd Plartners Melville, N.Y. Wverheed, N.Y. Fairfield, N.J.

nÂi LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY 11747 • 516-694-3040

ENVIRONMENTAL end INDUSTRIAL ANALYTICAL SERVICES

A N A L Y T I C A L DATA PACKAGE FOR

TOWN OF SOUTHAriPTON N o r t h Sea L a n d f i l l

AQUEOUS SAf^PLES X.PU X.BN X . A E X . F P

TDS, P.P. METALS & DISS. P.P. METALS

CN, PHEN, N02r.3. I.HS? TOC

MW »1A MW «1B

Field Equip. Trip Blank

Blank

765569 765571 765573 765575 765577

765570 765572 76 5574. 765576

AQUEOUS SAMPLES

MW #6 MW #2 MW *»4C Field Equip. Blank MW «4A MW «4.B Trip Blank

X. X, .PU X.BN .AE X . P F

765608 765610 765612 765614 765616 765618 765620

TDS, P.P. METALS & DISS. P.P. METALS

C.N ,_.__PH.E N,... _.N0 2 z S i , N H3 _ T O C_

765609 765611 765613 765615 765617 765619

AQUEOUS SAMPLE;S

MW «3A MW «3B MW n2>c Field Equip. Blank Trip Blank

X. X. .PU X.BN .AE X.PP

765680 765683 765684 765686 765688

FE, MN, DISS. FE &. MN TDS, P.P. METALS & DISS. P.P. METLAS

C N , P H E N , N02r3. NH3, TOC

7656S1 7656S2 765685 765687

Note: Trip Blanks were tested for X.PU only. cn PI >

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t iZk i LAES, INC.

TABLE OF CONTENTS

I. Non-Conformance Summary Report (Case Narrative)

II. QC Summary

III. Sample Data Package

IV. Standards Data Package

V. Raw QC Data Package

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l i 2 M LACS, INC.

I. Non-Conformance Summary (Case Narrative)

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l i2M LABS, INC. 575 BROAO HOLLOW ROAO. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL, PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

CASE NARRATIVE FOR PUGEABLE ORGANICS

No p r o b l e m s were e n c o u n t e r e d w i t h t h e a n a l y s i s o f t h e s e s a m p l e s .

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m \ J t J ^ \ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHEa McLENDON and MURRELL PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

CASE NARRATIVE FOR BASE/NEUTRAL ACID SAMPLES

MW2 acid fraction was re-extracted due to poor surrogate recoveries for the acidic surrogates. The re-extraction showed the presence of petroleum hydrocarbons which were not found in the original extract. MWIC matrix spike and flWlC matrix spike duplicate also contained petroleum hydrocarbons but none were found in the sample extract. The surrogate recoveries of all compounds were similar so it did not appear to be due to low recoveries in certain extracts. MW3A also contained petroleum hydrocarbons. There were no petroleum hydrocarbons found in the method blank so it did not appear to be due to contamination,

1,13-Tetradecadiene and an early eluting unknown were found in the method blank and in several samples. Bis-2-ethyl hexyl phthalate was also found in all method blanks and in all samples.

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m \ M J ^ % LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

CASE NARRATIVE FOR

PESTICIDES/PCB'S

No linearity data could be obtained for aldrin on the secondary column because it fused with a contamination peak.

The 2% retention time shift for DBG was exceeded for the runs of blanks #228, #230 and #468, the sample 4C and matrix spike IC. Windows for identification were adjusted accordingly for those runs.

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li!2Ai LACS, INC.

CASE NARRATIVE FOR METALS

ICf" analysis was performed on ARL 3410 ICP. Furnace cinalysis was performed on Varian GTA-96 graphite furnace and Mercury was analyzed using the manual cold vapor method. Due to ICP malfunction, the last group of samples. North Sea 19 was analyzed on Perkin Elmer 2380 AA. All problems are as follows:

Selenium: (total) Sample 765574 - MW «1C required dilution therefore tne matrix spike was not calculated. Results reported flagged with "N" and "E".

Mercury: (dissolved) Problems were encountered with the following samples: 765572 - MW ttlB, 765574 - MW «1C, 765609 - MW #6, 765613 - MW #4C, 765685 - MW «3C, The laboratory filtering apparatus was contaminated and results for dissolved Mercury were significantly higher than results for total Mercury. No contamination occurred in field filtered samples. After decontamination of the laboratory filtering apparatus, the above samples were refiltered and reanalyzed. Results reported are less than 0.2 ug/1.

Lead: (total) Duplicate Methods of Standard Additions were required on samples: 765572 - MW «1B, 765611 - MW «2 and 765685 - MW #3C. The second correlation coefficient was greater than 0.995, results reported flagged wit •| "s". Sample 765681 - MW **3A the second correlation coefficient was 0.994, this result was reported flagged with "-i-". Single Methods of Standard Additions was performed on ?.ample: 765682 - MW #5B. Correlation coefficient was greater than 0.995, result reported flagged with "s".

L.eciO: (dissolved) Single Metho.ds of Standar-d Additions were performed on samples: 765570 - MW #1A and 765572 -MW **1B. Both correlation coefficients were greater than 0.995. Results reported flagged with "s".

Samples with increased detection limits required dilutions. Results were multiplied by the corresponding dilution factors and reported.

No problems were encountered with tfi remaining analytes. CO All data meets quality assurance and quality control m requirements.

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t i2/H LACS, INC.

I I . OC Summary

1. Surrogate Recovery Form 2. MS/MSD Form 5. Method Blank Reports 4. 6C/MS Tuning Form 5. Initial and Continuing Calibration Verification (inorganic) 6. Blank (Inorganic) 7. ICP Interference Check Sample 8. Spike Sample Recovery (inorganic) 9. Duplicates(inorganic)

10. Instrument Detection Limits and Laboratory Control Sample (inorganic)

11. Standard Addition Results 12. Holding Times (inorganic) 13. Instrument Detection Limits (inorganic) 14. ICP Interelement Correction Factors 15. ICP Linear Ranges

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL. P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Kater S u r r o g a t e Percen t Recovery Sumniary

Sample IToluene Number I d-8

; 88-110 12/14/871 60 ug/1 624 100 Inst Blkl 108 MW «1A 1 101 nu »16 ! 105 riW »1C ! 108 tiu «ic ns 103 MW »1C MSO 101 Field Blk 106 Trip Blkl 109

r

12/16/871 Cal Ck Std 100 Inst Blkl 97 MW »6 1 100 MW «4C 1 97 Field Blk 97 MW »2 1 102 MW »4A 1 95

1 1

12/16/871 50 ug/1 624 100 Inst Blkl 96 MW «4B ; 89 Trip Blkl 92 MW #3A 1 94 MW «3S I 97 MW «3C 1 90 Field Blk 93 Trip Blkl 91

... _ „ ... 1

Broitiof lu-obenzene ..8 8.-.11.5...

100 92 90 90 97 90 92 95 90

100 112 106 99 109 110 112

100 103 106 99 99 92 101 101 108

1,2-Oi- 1 12 Fluo-I chloro- iNitrobe-l robi ITerphen-ethane-d41nzene-d5|phenol |yl d-14 78-114 1 35-114 1 43-1161 33-141

100 1 I 1 79 1 I 1 81 t 1 1 87 1 1 1 85 ! 1 1 84 1 1 1 83 1 1 1 93 1 1 79 1 1 1

100 1 1 1 112 1 1 1 106 1 1 1 105 1 1 1 112 1 1 ! 106 1 1 ! 110 1 1 1

100 i 1 1 101 1 ; 1 96 1 1 1 97 ! I 1 99 I I 1 97 ! I 95 1 1 1

1 96 1 I 1 1 97 1 I 1 1 ) 1

(1) Phenol d-5

1 2,4,6-2-FluoroItribromo-phenol Iphenol 21-100 I 10-123

[ -—•'

1 1

1 1

I 1

1 1

i

. L . . ( 1

t 1

1 1

I 1

1 1

1 1

1 1

1 I

1 1

1 1

1 1

I 1

1

( 1

) I

1 1

Oibutyll chlor- 1 endate I _._.24-154;

1

' V a l u e s are * * A d v i s o r y

outsi limit

de of contract required OC limits s only

CoiDiDents:

Volatiles: 0 out of 75 ; outside OC limits Semi-Volatiles: out of ; outside OC limits Pesticides: out of : outside OC limits

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m \ j L J ^ \ LABS, INC. 575 BROAO HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040


Water Surrogate Percent Recovery Summary

SaiTiple Number

Toluene d-8 88-110

MWIA

MWIB

MWIC

MWICMS

MWlCMSDi

Field Blk!

MW6

MW2

MW4C

Field Blk!

MW4A

MW4B

MW3A

MW3B

MW3C

Field Blk!

Meth. Blk 228

Meth. Blk 229

Meth. Blk 230

Bromoflu-obenzene

88-115

1,2-Di-chloro-ethane-d4 78-114

Nitrobe-nrene-d5 35-114

79 1

82 71 87 68 78 87 60 73 75 91 69 78 80 49 86 55 80 54

2 Fluo-l robi 1

phenol ; 43-116!

91 !

89 !

76 1

96 1

78 !

87 i

114 !

85 !

96 !

103 1

118* 1

96 1

80 !

94 1

49 !

103 1

63 !

107 1

65 i

! 1

*Values are outside of contract required QC limits ** Advisory limits only

Terphen-yl d-14 33-141

87

72

65

104

81

100

81

90

98

111

94

101

91

. 41

80

66

100

65

(1) Phenol d-5 10-94

41

45

43

59

68

40

40

64

45

46

47

46

44

48

42

45

79

45

91

2-Fluoro phenol 21-100

65 1

67 i

68 70 i

81 57 55 76 65 67 68 63 58 62 65 68 93 63 89

2,4,6-tribromo-phenol 10-123

40 41 37 44 52 39 73 54 76 78 78 64 62 64 59 48 92 75 113

Volatiles: out of ; outside QC limits Semi-Volatiles: 1 out of 114; outside QC limits Pesticides: out of ; outside QC limits

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t H H LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER. McLENDON and MURRELL. PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Water S u r r o g a t e Percent Recpyer^ Jy.ll'i.^.ry

Samp Le Njrrber

' o i u e n e d-8

88-110

F i e l d B l k . MU_ «6._ 1. MW. «48..._....L MU tt3A 1

F i e l d ...Bl.k_ MU' «3c ; MW J 4 A ;_ MU_tt3B.._ 1. MW #2 I

F i j l _d .Blk !l.lt.hpd _Bl_k__229. MW »4C I MW OJA 1 MW « i 6 I Method B lk 228 1. ' t i .h 0i3_...B_l_k __4 6 8..

My_.lll"Ili MW_|.1C.._MS.D MW SIC MS' Mecnod Blk 230

I 1,2-Di- 1 12 Fluo-l (1) Bromoflu-1chloro- iNitrobe-l robi 1Terphen-1 Phenol 12-Fluoro obenzene 1ethane-d4 I nzene-d51 phenol lyl d-14 1 d-5 Iphenol

88-115 1 78-114 I 35-114 1 43-1161 3.3-141 ..1.1.0-94 1. 2.1-1.00

2,4,6-ribromo' henol 10-123

ID i c le

ibuty11 h 10 r -naate 24-1544*

-12„_ 124. .1.97*. 144

'Values are outside of contract required QC liaits

'' Advisory limits only

150._.. _236*

-530*. 251*

1 1 I I 1

I _ _ I !. ! 1 . 7 "' '" I "i ' I I .. I... . .1. _ ! J._

452* 3.63.*_ 282.*. 36 7*

114 31i-*-J 9

.387*., "64a*

Volatiles: out of ; outside OC limits Semi-Volatiles: out ot ; outside OC limits Pesticides: 13 out of 20; outside OC limits

Comments: *High Rec_o.yer.y .Due to DI.O.P I.n.terf..ere.nce.. in tn >

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER, McLENDON and MU R R E L L P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Soil Matr_ix Spike/Hatrix Spike Duplicate Recovery

Saiple ID: MW «1C Cone. Spikel Scan Compound AddedCug/kg) 1

1,1-Oichloroethene 50 Trichloroethene 50

VOA Chlorobenzene 50 Toluene 50 Benzene 50

l,2ji.4-Trichloroben2ene Acenaphthene 2,4-Dinitrotoluene

B/N Pyrene N-NitrosoDi-n-Propylamine 1,4-Oichlorobenzene

Pentachlorophenol Phenol

Acid 2-Chlorophenol 4-Chloro-3-MethyIphenol 4-Nitrophenol

Lindane Heptachlor Aldrin

Pest Dieldrin Endrin 4,4'-0DT

Sample Result

5U 5U 5U 2J 5U

- -

'Cone IMS

46 43 59 49 44

I *! IRecl

92 86 118 98 88

Cone MSO

49 42 _59 48 44

iRec

98 84

_.l 18 96

RPD

6 2 0 2 0

'—-OC RPD 1

I 221 I 24 1 1 211

.i.Jh. 1 211

! 231 1 191 1 471 ! 361 1 38! ! 27!

1 471 1 351 1 501 1 33! 1 501

1 501 1 311 1 43 1 1 38 1 1 451 1 501

Limits--1 Recovery 1

59-172 1 62-137 1 60-133 1 59-139 1 66-142 1

38-107 1 31-137 1 28-89 1 35-142 1 41-126 1 28-104 1

17-109 1 26-90 1 25-102 1 26-103 1 11-114 1

46-127 1 35-130 1 34-132 1 31-134 1 42-139 1 23-134 1

* Asterisked values are outside OC limits.

RPO: VOAs 0 out of 5; B/N out of ;

Acid out of ; Pest out of ;

outside OC limits outside OC limits outside OC limits outside OC limits

Recovery: VOAs 0 out of 10; outside QC limits B/N out of ; outside OC limits

Acid out of ; outside QC limits Pest out of ; outside QC limits

Coaaents:

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H2M. LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELU PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Water M a t r i x S p i k e / M a t r i x S p i k e D u p l i c a t e R e c o v e r y

Sample I.D, MVIC Scan Compound

1,1-Dichloroethene Trichloroethene

VOA Chlorobenzene Toluene Benzene

1,2,4-Trichlorobenzene Acenaphthene 2 ,4-Din i t ro to luene

B/N Pyrene N-NitrosoDi-n-Propylamine 1,4-Dichlorobenzene

Pentachlorophenol Phenol

Acid 2-Chlorophenol 4-Chloro-3-Methylphenol 4-Nitrophenol

Lindane Heptachlor Aldrin

Pest Dieldrin Endrin 4,4"-DDT

Cone, Spike! Sample Cone. % Cone. % QC Limits! Added(\ig/1) Result MS Rec, KSD Rec RPD!RPD!Recovery 1

210 200 200 200 210 200

400 400 440 400 400

0 0 0 0 0 0

0 0 0 0 0

140 160 170 200 140 160

130 230 280 220 140

67 82 84 101 68 78

32 58 63 55 36

110 130 140 140 120 120

160 280 320 260 170

52 67 72 71 58 58

41 69 73 66 43

25 20 15 35* 16 29*

25 17 15 18 18

14 14 13 13 11

28 31 38 31 38 28

50 42 40 42 50

15 20 22 18 21 27

61-145 71-120 75-130 76-125 76-127

39-98 46-118 24-96 26-127 41-116 36-97

9-103 12-89 27-123 23-97 10-80

56-123 40-131 40-120 52-126 56-121 38-127

* Asterisked values are ou ts ide QC l i a i t s .

RPD: VOAs B/N

Acid Pest

out of ; 2 out of 6;

0 out of out of

5;

outs ide QC l i a i t s ou t s ide QC l i m i t s ou ts ide QC l im i t s ou t s ide QC l im i t s

Recovery: VOAs out of ; ou ts ide QC l i m i t s B/N 0 out of 12; ou ts ide QC l i m i t s

Acid 0 out of 10; ou ts ide QC l i m i t s Pest out of ; ou ts ide QC l i m i t s

Comments; tn

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m \ M J ^ % LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY 11747 • 516-694-3040

ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Water M a t r i x S p i k e / M a t r i x Spike D u p l i c a t e Recovery

Sample ID : MW ttlC Scan ComDound

Cone. S p i k e ! Sample iConcI t | ConcI %'. 1 OC L i m i t s - -Add£d(u9 /kg) ; Sesux: IMS IReci MSD I Rec 1 R = D i R.' D I f tecovery

1 , 1 - D i c h l o r o e t h e n e T r i c h i o r o e t h e n e

yOA Chlprobenzene _ Toluene Benzene

14 I 61-14 5 14 ; 71-120. 13 1 .7 5-130. .13; 76-125_ i l l 76-127

1 , 2 ,..4 -...I..r..,i..Pf ..,l.orP.b.en2.e.ne_„ _ _ Acenaphthej ie . 2 , 4-J3in. . i txoto luene D i - n - .bu t..y 1 p h t h a l a t e

B/N P..y._r .e.ne _ _._ N-Ni t rosopj . ; ;Mi-Prqpyla^^ 1 , 4 -p ic .h lo roben2ene

J 8 I .3.9-98 31 : 46-llJ-_38.1... 2.4-96 401 11-1_17. iLl_.26-127 38 1 „4lj:11.6 28 1 36-97

. J ' l D l a CI1..I.0 ro P_hje .n 01_ Phenol

Acid 2-Chlorophenol 4-Chloro-3-Methylpheno1_ 4-Nitrophenol

_5CLI _....9-1.03_ _42.1_i2-J^_._ \ o i 27.-12'3 ..2 1., 23-:..9.7 . 50! 10-60

Lindane HeptBchl.qr Aldrin _

Pestpieidrin Endrin

' 4 V'i '-OPlII**^^

05U .05U..

.l.,P.U..

IM.. 66

32 80 0.37 P..-.. 1.7. 0.20 0.99 0v31... 1. 20

43 50 99

• 3 gl

120

p. 18

0- 92 ,0..: 72 .. 1.39 * 1

93

92

?Q... 39

13 2.5' "5 7

J I ' "I's

.15., 2C

I '-^ J-i

1.8.J ...21... 2 7

5.6-.113_ 40-131 40-12c 52.-1.26 56-121 32-127

Asterisked values are outside OC limits.

9.PD: V P A s out of ; B/N out of ;

Acid out of ; Pest 2 out of 6;

outside QC limits outside OC limits outside QC limits outside QC limits

Recovery VOAs B/N

Acid Pest

out of ; ou: 0: out of

2 out of 12

outside OC limits ; ou:sio' OC licit; ; cjtside QC limit-; outside OC limit;

Comments: **Unknown found in sample quantified,..as p.p'-p_DT

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n i H LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040


Method Blank Summary

IFile iDate of 1 IID

PU7842

PU7853

PU7862

12/14/87

12/16/87

12/16/87

IConc. I Inst. 1 C.A.S. Compound Analysis! Scan I Matrix 1 Level I No. I Number |(HSL,TIC,or Unknown) 1 Cone 1 Units ICRDL!

132 332 15 50

319

122 11

H20

H20

H20

Lou

0WA«1

0WA»1

0WA«1

75-09-2 71-43-2 124-38-9

71-43-2

75-09-2 124-38-9

Methylene Chloride Benzene Carbon dioxide Unknown

Benzene

Methylene Chloride Carbon Dioxide

6 2J 20J 29J

2J

4J

9J

us/1

ug/1

ug/1

5U 5U

5U

5U

Comments: in PI >

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i-aM LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


IFile IDate of ! IScan llnst. IID

P3809

P3792

P3799

1 Analysis!Fraction 1 Matrix 1 No,

12/17/87

12/16/87

12/17/87

BNA

BNA

BNA

H20

H20

H20

1511

183 1148

1515

185 1250

1512

184

ID

HP#2

HPI2

HP#2

C.A.S. 1 Compound Number !(HSL,TIC,or Unknown) ! Cone I Units!CRDL

117817

117817

21964498

117817

Bis(2-ethylhexyl)-phthalate

Unknown Unknown


Unknown 1,13-Tetradecadiene


Unknown

41 12J 12J

25 50J 10 J

38 14J

ug/1

ug/1

ug/1

10

10

10

Comments tn PI >

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m l j t / ^ m LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY. 11747 • 516-694-3040

HOLZMACHEa McLENDON and MURRELL. P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


I F i l e IDate of I I I C o n c . l l n s t , I ID I A n a l y s i s l F r a c t i o n i M a t r i x 1 Leve l 1 No.

Method Blank

229 Method Blank

468

Method Blank 230

Method Blank

228

12/23/87

12/23/87

Pest

Pest

Pest

Pest

H20

H20

H20

H20

Low

Low

Low

Low

Tracor 550

Tracor 550

Tracor 550

Tracor 550

C.A.S. 1 Compound

Number l(HSL,TIC,or Unknown) 1 Cone 1 Units ICRDL1

No Compound Found

Unknown Unknown

No Compound Found

No Compound Found

0.2U

0 .45J 0 .54J

0 . 2 U

0 . 2 U

u g / 1

Comments: in tn >

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f i2Ai LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER. McLENDON and MURRELL. P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

GC/nS TUNING AND MASS CALIBRATION Bromofluorobenzene (BFB) for Initial Calibration

Case No.-vol- Contractor H2M LABS INC. Instrument ID 0WA«1 Date/Time S/27/86

Lab I.D. PU6261 09:51

m/e

173^ 174

Ion Abundance Criteria 15.0 - 40.0% of the base peak

% Rel. Abundance 1 28.6 I

30.0 - 60.0% of the base peak 54, 3 Base peak,100% relative abundance 5.0 -9.0% of the base peak

.100 8.2

Le ss_tj arn JI. 0% _pjf^ 1 ^ base peak \ 0 Greater than 50.0% of the base peak ! 89,1

175

176

5,0 - 9,0% of mass 174 .6,_7 (7.5) Greater than 95,0%, but less than 1 101,0% of mass 174 . 185,3 (95.7)

177 5,0 - 9.0% of mass 176 5.8 (6.8)

1 - Value in parenthesis is % mass 174, 2 - Value in parenthesis is % mass 176.

THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWING SAMPLES, BLANKS, AND STANDARDS.

Sample I.D. Inst Blank

Lab I.D. No. iQjste _AnBlj^zjsdi IJTi^js qf._An_al>^s.ijs ' PU6262 ' j 8 /27 /86 " 1_1" ' ' 10:09

5.0 JJ9/i_H.SL PU6263 20 ug/1 HSL ipol ug/ i . . HSL isp ug/1 HSL 2.0 ug/1 HSL 100 ug /L HSL 15l3....!4S!/.L.t!.SL.

PU6264. .l=IJ62j65. F'U6266' .PU6267. 'pij626.8^ F='U6269

200 "ug/l." HSLT PU6270

1 1 : 3 2 2:„.42 .3.:.4i5 5:04 6 : 04 7:. 1.2 S:..Q^. 9". '^y

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t U M LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040


GC/MS TUNING AND MASS CALIBRATION Bromofluorobenzene (BFBj for Initial Calibration

Case No.-vol- Contractor H2M LABS INC. Lab I.D. PU6277 Instrument ID 0WA«1 Date/Time 8/28/86 09:31

m/e Ion Abundance Criteria 50 1 15.0 - 40.0% of the base peak. 75 _?5 96 1Z3_ 174

175

176

% Rel. Abundance 1 22.9

30.0 - 60.0% of the base peak 43.5 Base peak, 1 p.O%.__re 1^^ 5,0 -9.0% of the base peak

_log 8 ,8

Less than 1.0% of the base peak O Greater than 50,0% of the base peak 74,8

5.0 - 9.0% of mass 174 5.1 (6.8) Greater than 95.0%, but less than 1 101.0% of mass 174 172.6 (97.1)

177 5,0 - 9.0% of mass 176 4,7 (6,5)

1 - Value in parenthesis is % mass 174, 2 - Value in parenthesis is % mass 176.


Sample I.D. 20 ug/1 DCB 50 ug/1 DCB 150 ug/1 DCB

Lab I.D, No. PU6278 PU6279 PU6280

Date Analyzed 8/28/86

" •'

Time of Analysis 1 09:49 1 11:01 1 12:04 1

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY 11747 • 516-694-3040


GC/MS TUNING AND MASS CALIBRATION 4-Bromofluorobenzene (BFB)

Case Inst Lab

m/e ..50.. ,.Z5_... ,.?5_ '961 1.73 174

.175,

1.Z6..

177

No.-vol- Contractor H2M LABS INC. Contract N Sea Landfill rument ID 0WA#1 Date/Time 12/14/87 16:50 ID PU7840 Data Release Authorized ^Y • J.2SkvJ^djj:s.^~:i..:.,:^.^

Ion Abundance Criteria % Rel. Abundance .....L 1.5....p..- 40.0% of the b.a.se p.eak !_ 31..? 1 1 30.0 - 60.0% of the base peak 1 52.9 j Base peak, 100% relative abundance 1 5.0 -9,0% of the base peak 1 Less than 1.0% of the base peak 1 Greater than 50,0% of the base peak 1

100 1 6.7 1 0 1

66. 1 1

5.0 - 9.0% of mass 174 Greater than 95.0%, but less than 101.0% of mass 174

5.p - 9.0% of mass 176

.__5..8 L8.,.8) 1'

63.5 (96. 1)

4.1 (6.5)

1 - Value in parenthesis is % mass 174. 2 - Value in parenthesis is % mass 176.


Sample. I ..D, _ Standard Instr. Blank MW lA MW IB MW IC MW IC MS MW IC MSD Field Blank Trip Blank

Lab I.D. No. PU7S'41 PU7842 PU7S43 PU7S44

IDate Analyzed 1 12/14/87 1 "

• • { -

PU7S45 1 PU7S46 PU7847 PU7848 PU7849

1 12/15/87

'', '.V - - ~

1 "

1 ;

..., <

17:56 ' 19: 15 20:32

_..21..:..48 23:06 00:20 01 :36 02:53 04: 10

's.is

1

1 t

1

1

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Case No,-vol- Contractor H2M LABS INC. Contract N Sea Landfill Instrument ID 0WA#1 Date/Time 12/16/87 05:00 Lab ID PU7851 Data Release Authorized By:

m/e Ion Abundance Criteria

££^y^^

Abundance 50 75 95 96 173 174

175

176

177

1 15.0 - 40.0% of the base peak 1 30.0 - 60.0% of the base peak 1 Base peak, 100% relative abundance 1 5.0 -9.0% of the base peak 1 Less than 1.0% of the base peak 1 Greater than 50.0% of the base peak

1 5 . 0 - 9 , 0 % of mass 174 1 Greater than 95.0%, but less than 1 101.0% of mass 174

1 5,0 - 9.0% of mass 176

1 1 1

1 1 1

1

1

1 1

1 4.

!66.

! 4.

2

5

0

31.8 ! 51.9 1 100 1 6.6 I 0 1

66. 2 1 1 1

(6.3) 1 1 1

(100.4) 1 2 1

(6.0) 1


THIS PERFORMANCE TUNE APPLIES TO THE FOLLOWING SAMPLES, STANDARDS.

BLANKS, AND

Sample I.D. Standard Instr. Blank MW «6 MW #2 MW *t4c Equip. Field Blank MW «4C

L

—

Bb I.D. No. PU7852 PU7853 PU7854

IDate Analyzed IT 1 12/16/87 1 1 " 1

1 " 1 1 J

PU7855 1 " 1 PU7856 PU7S57 PU7858

1 " 1

1 " 1

1 " 1

1 1

TJ.me. of Analysis Io5jJ^TZT--Z. ....... O. 1.01... 06j:50' P7.:3'5i... .08:28 09_:_19

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H2H, LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Case No.-vol- Contractor H2M LABS INC. Contract Instrument ID 0WA«1 Date/Time 12/16/87 10:54 Lab ID PU7859 Data Release Authorized By:

N Sea Landfill

m/e 50_. 75_

-^5_ - ?6. i.73._

1J?4_.

.1.25..

.1.76..

177

Ion Abundance Criteria 15.0 - 40.0% of the bas^ peak_ 3P,_p _ -. 60. g.% of .t he base. .j?.eak Base peak, 100% relative abundance

Abundance _....28..5.... .,..: _j4.9. i . 100

5.0 -9.0% of the base peak Less than 1.0% of the base peak

6.9

Greater than 50.0% of the base peak

5.0 - 9.0% of mass 174

73.4

Greater than 95.0%, but less than 101.0% of mass 174 _

1 6.6.. _(9.^g.)__.. 1

172.2 (98.4)

5.0 - 9.0% of mass 176 4.7 (6,5)



S.annp 1 e I.D. 50 ug/1 6 24 I n s t r_. Blank MW «4B.1I Trip Blank MW «3A MW «3B MW «3C Field Bl.ank. Trip Blank

J Ls.t)_I. D., No.__\pBlê_AnaJ.yzed± Analysis PU7860 .P.U7862 PU7iB63 F='U7864 ...P.y.7S.6.5... F'U7866 PU7867 ..PLJ.7S68.. PU7869

12/16/87 .11 l.24_ 12.: 39. 14:05 15.:..2 5.. 16:42 18:00 1'5'.:2P 20:36 21 : 52

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l)>cin»fatri|lwyl|lMifliiiia OFTFP)

Cau Ml. SOII-UL tm Contrtetar WH U S INC. Centract ND. EM 1%/V

iMtrtMut 10 HP(2 Oa<t / T IM 11 7/17 U:44

Lab 10 >CF144::81 Ort« A I IMM tetWiza^ By: Q ^ / ' ^ ' j ^ K i

1 •/{ 1 im ABIHMC CRIIGRM 1 1 1 j f 1 )a.o 1 68 1 Uas 1 (9 1 MSt 1 71 1 Uss 1 127 1 i i . 9 • I 197 1 less (

- iQ,OX0lHul98 thM 2.A t f MM 49 &9 reiatm ikmimet tlvM 2.tt • twmt i t • 40.n af am 191 hM l . t t at MM 198

1 198 1 b«s« ptak, IMI r«l«(iv« dbmima 1 199 1 5.0 -I 275 1 10.0 -1 }i5 t greatc

9.0«QrMul98 ?0.n«fMMl98

r thM l . m af Mas 198 i ' U \ 1 present, but leu tkM MSS 40 1 442 1 greate 1 44J 1 17.0 -1 1

r than 4|.t t of MSS 198 2}.8«orM3s442

rais KJfVMHi Tuc tmss n nc nULiUlC SMfliS, BUNS M sniDwos.

1 a m i 10. 1 ueio ITtl 16 44 SMC Orri Hn44 110 u a / m l 1 25 u a / m l 1 40 UQ/ml I 60 u q / m l 1 80 u q / m l

H3L P^ ' i f i ' i H3T. p-^âf i H 3 I . P . l ' iR? H 3 L P 3 5 a a H 3 L P 3 5 8 9

1 ^ MELATItC l a M w a 1 1 1 1 5J.77 » 1 I .N « 1 79.M

: 1 l . l l OK 1 44.51 OK 1 1.88 » 1 m . % 9 « 1 7.45 « 1 11.82 OK 1 2.11 K 1 1.41 (X 1 41.71 OK 1 12.0} GK 1

( i.N) t l 1

c 8.11) n 1

(19.51) 12 1

11 - U I I M ia parMthMH is t M M 49.

12 - Ui lw ia parMtlMsis is t CMS 442.

LMIE.(r.««LYSK.I. 1 11/27/17 1 1 i n / 7 7 / R 7 1 1 l n / 9 7 / R 7 1 1 i n / 9 7 / R 7 1 1 l n / 9 7 / R 7 1 1 i n / 7 7 / R 7 1

_TllfJDFjlNt«IS_l U:44 1 17 . no 1 T R . r m 1 1 q . n n 1 1 Q.c^fi 1 9 n . s i 1

1 1 I I I 1 1 1 1 1 1 1 , 1 1 I I I

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GC/tS TIMING fifC HASS DIIBMTION

OacafluorotriphMylphosphiM (DFTFP)

(Use No. S01I-UOL BNA Contractor H2n U«S INC. Contract No. EPA 12/87

InstruMnt ID iff*t2 Date / TiM 12/16/87 18:82

r

Lab ID >DF164::B1 Data Ralease Authorized By:

1 B/Z 1 1 1

ION MUMMCE CRITERIA

1 51 1 30.0 - 6 l . l t of Mss 196

1-^8 1 1 69 1

1 70 1

less thM 2 . n of MSS 69 relative less thM 2.OK of

MSS 69 abundance

aass 69

1 127 1 40.0 - 61.81 of aau 198

1 197 1

1 198 1 1 199 1

1 275 1 1 365 1 1 441 1

t 442 1 1 443 1

t 1

less thM 1.8« of aeu 198

base peak, llOt relative abundance 5.8 - 9.81 ef aoM 198 10.0 - 3I.8« of MSS 198 greater thM l.OOt of MSS 198 present, but less than MSS 443 greater thM 40.0) of MSS 198 17.0 - 23.8« of MSS 442

THIS PERFORtWa TUC «miES TD TIC

FOLLWINC SMFLES, BUMS MD STMCWDS.

1 S M H f ID 1

i2U.nsi 125 u^

U OFTPP I_>0F1< r / m l H.e-t

i B l a n k 229 1 IMW6 IMW2 IMW4C i F i e l d IMW4A IMW4B lB lan ]< IMW3A IMW3B IMW3C j F i e l c

I B l a n k !

: 230 1

[ B l a n k i

ue ID 4

P3791 P3792 P3793 P3794 P3795 P3796 P3797 P3798 P3799 P 3 8 0 0 P 3 8 0 1

--P3802 P3803

1 vBJiim fOHxta 1 ! 1 i 58.42 OK 1 0.08 OK 1 80.86 1 8.80 OK 1 43.44 OK i 0.88 OK 1 108.88 OK 1 6.52 » 1 20.07 OK 1 1.72 OK 1 8.53 OK 1 61.08 OK 1 11.25 «

( 0.00) t l 1

( 0.00) t l 1

(18.43) t2 1

t l - Ualue in parMthesis is X MSS 69. t2 - Ualue in perMthesis is % MSS 442.

1 DATE_OF_flM(tYSIS_ 1 12/16/87

1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 6 / 8 7 1 1 2 / 1 7 / R 7 1 1 2 / 1 7 / R 7 1 1 P / 1 7 / f l 7 1 1 1 2 / 1 7 / f l 7 1 1 1 2 / 1 7 / 8 7 1 1 1 2 / 1 7 / 8 7 1

I I I I

1 TlIC OF ANALYSIS 1 1 18:82 1 1 I R . l f i 1 1 1 9 . 1 7 1 1 2 n - l ^ 1

2 1 . O R 1 7 7 : 0 / 1 1 2.3 r n n 1 2 3 . S 7 1 n n - t ; ? 1 m .dR 1 n ^ . / L ' ^ 1

0 3 . 4 T 1 n 4 r 3 7 1 0=5.34 1

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http://6l.lt

cc/ns nniNE AND mss CALIBRATION

OaceflwretriphonylphosphiM (OFTPP)

C

c

Case Ik). SEHI-UOL BNA Contrxtor H2n U«5 INC. Cmtract No. EPA 12/87

InstruMnt 10 ll>«2 Date / T iM 12/17/87 21:33

Lab ID >0F165::Bl Data Release Authorized By: S ^ ' ^ A A J ^

I B/Z

I 51 68

'69 f i

127 197 198 199

I 275 i 365 I 441 I 442 I 443

1 ION ABINMCE CRITERIA 1 WELATIUE Af idCAia 1 1 1 1

1 30.8 - 60.8«of MSS 198 1 57.86 OK 1 1 less than 2.8« of M S S 69 1 8.88 OK ( 8.00) t l 1 1 MSS 69 re lat ive abundance 1 86.31 1 1 less than 2.9% of M S S 69 1 1.37 (K (1.586) t l t 1 40.0 - 60.8«of aass 198 1 46.69 OK 1 1 less t h M 1.8« of MSS 198 1 0.81 OK 1 1 base peak, l l t t re la t ive abundance 1 100.81 OK 1 1 5.0 - 9.811 of aau 198 1 6.27 OK 1 1 10.0 - 30.8«of aass 198 1 17.44 OK 1 t greater thM 1.08« of M S S 198 1 1.81 OK 1 1 present, but less than M S S 443 1 7.28 OK i 1 greater than 40.0« of M S S 198 1 50.22 OK 1 1 17.0 • 23.011 of MSS 442 1 10.66 OK (21.23) t2 1 1 1 1

THIS PERFORMANCE TUC APPLIES TO TIC FOLLOyiNG SAfPLES, BLAIKS AK) STAICAROS.

I _LAB_I0_ I SAIRE ID I2UL IS 44 OFTPP I >CF165

12? uq/ml HSC P380R

t l - Ualue in paren t2 - Ualue in parm

OATÔF ANALYSIS 12/17/87__

IMSJA, P 3 8 n 9

I IMWIB

_EiairL P3fin

IMWIC P 3 R 1 ? IMWICMS IMWICMSD

P3813 P3814

I F i e l d B l a n k i IMW2 A c i d I I I

P3815 P3816

1 2 / 1 7 / 8 7

hesis is % MSS 69. hesis is % MSS 442.

JIIC.OF ANflLYSIS. _21:33

T 2 / 1 7 / R 7

17 /17 /87 1 ? / l g / 8 7 1? /T« /«7 12/1R/R7 1 2 / l R / f l 7

-LZZiaZfli -L2Ziaza2.

49 ??;S? 3 3 i 4 7 O O i U m -40 n?:3fi n3;32 04:29 n ^ ' 7 ^ PJ

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Form lift-

Q. C. R e p o r t No. IV<^^ ( l )

INITIAL AND CONTINUING CALIBRATION VERIFICATIONS

LAB NAME fe YTl LAX^'\ ' ^ ^ C CASE NO. ^Jdr€ fTf S > ( ^ I ' ^ ' ^ l

\ \ SOW NO.

DAT

Coir

Met

1.

2 .

3 .

4 .

5 .

0 .

7 .

b .

y .

lU.

1 1 .

12 .

1 3 .

U .

15 .

l b .

17.

l o .

l y .

2U.

2 1 .

22 .

2 3 .

L ^ l I

pound

a l s :

Aluminum

Antimony

A r s e n i c

bar ium

Bery l l i um

Cadmium

Calcium

Chromium

Cobal t

Copper

I r on

Lead

Magnesium

Manganese

Mercury

Nicke l

Po ta s s ium

Selenium

S i l v e r

Sodium

Tha l l i um

Vanadium

Zinc

Oclier:

Cyanide

I n i t i a l C a l i b .

True Value

/2P^

S O

looo I OOO

"Vooo

^ o o o ^DOOO

3 b

?>ooo s-.o

Hooo

s o -d<oto

^ £ >

40DD

4 0

Found

n s-i

^40 ^ b O

\mo

4S^^ l"??©© 53

^^^0 C l

^3?o

4^ R^C)

^s:

3(>ô

3^-

1

ZR

fS^ IDT-,

^ 4 -^ ^

100

< ^ % r

9 H lot

q^ 102. ^3

9t 93

ô

^1>

^ ?

UNITS: Ug/L

Cont inu ing C a l i b r a t i o n ' ^

True Value

/OO S-O

looo looo

Zooo

BÔO Z^660

SO

,^060 s.o

^6(>^

5 0 5 0 0 O

s

^ O C D

i 50

Found

109 44

lA^SO loao

Z(30

6 l ^ ^ 20^60

5? ,

3126 S.2.

9^9^

4 ^ 5CO/5

ZR

/^? ^ 2 -

16 10^

16^

(62 lo^ \f>k^

I D ^ lot/ 60

^ ^

/60

4^ ô

4540 i /î

1 4 ^ q ^

Found

103O I6Z6

ÎZ^

f^/20 7DSLD0

5 Z

3iq-o 5.£)

-hîo

ZR

163 /6Z

10^

IDZ-11 ID^

10^ /ro

^

i 4 ^ 1^4-

W ^ 1/00 1 (

f i -^3^1^?

iMethodî

F -P

P P

P

P P P

P 1 cou?

p

p p

F 1 t 1 i p

1 1 1

f 1 1

1 1 ^ I n i t i a l C a l i b r a t i o n Source HîHgr ^ Cont inu ing C a l i b r a t i o n Source \/fymtf^

C o n t r o l L i m i t s : Mercury and Tin BU-12U; Other Metals 9U-11U; Cyanide b5-115

I n d i c a t e A n a l y t i c a l Method Used: P - ICP; A - Flame AA; F - Furnace AA

b - y

CO p]

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F o m I I E>

Q. C. R e p o r t No. b A ^ ( D


LAB NAME H ^ f T ) L A / ^ J N C CASE NO. f x l ^ i e m "Rf^ H - ( ^

SOW NO.

DATL UNITS: ug /L Compound

Metals:

1. Aluminum

2. Antimony

3. Arsenic

A. barium

5. Beryllium

b. Cadmium

7. Calcium

a. Chromium

y. Cobalt

10. Copper

11. Iron

12. Lead

13. Magnesium

14. Manganese

15. Mercury

lb. Nickel

17, Potassium

lo. Selenium

CO'%-fiij

True Value

5 o

S.D

S O ly. Silver

2U. Sodium

21. Thallium

22. Vanadium

23. Zinc

Ot)ier:

Cyanide

; . Calib

Found

5V

s,o

4^

,i

u

lOi

lOO

^ b

Continuing Calibration'^

True Value

So

Found

55

ZR

Ho

1 i 1

Found ZR

1

f

1 1

Method^

f

COcP

1 P

i

L

1 1 1 1 i 1

i i l 1 f f

1 1

I n i t i a l Cal ibra t ion Source ^ Continuing Calibration Source^

^ Control Limits : Mercury and Tin tiU-12U; Other Metals 90-110; Cyanide «5-115

^ I n d i c a t e A n a l y t i c a l Method Used: F - ICP; A - Flame AA; F - F u r n a c e AA

b - 9

to tn

o o to

o o to CD

Ll

LJ

L l

L i

H

J

U

U LJ

LJ i

L l

L l

Form I I

Q. C. Report No. t ) A ^ ^


LAB NAME H ^ r V \ l A f t ^ 3:tNlCL CASE NO. K \ S \ = 1 ( ^ 1 ^ - / 9

SOW NO.

DAI L C » . | \ \ X

Compound

Met

1.

2 .

3 .

A.

5 .

b .

7.

ts.

y .

lU.

1 1 .

12.

13 .

14.

15.

l b .

17.

16.

l y .

20 .

2 1 .

22 .

2 3 .

a l s :

Aluminum

Antimony

A r s e n i c

bar ium

B e r v l l i u m

Cadmium

Calcium

Chromium

Coba l t

Copper 1

I ron

U a d

Magnesium

Manganese

Mercury

Nicke l

Po ta s s ium

Selenium

S i l v e r

Sodium

Tha l l i um

Vanadium

Zinc

O t h e r :

Cyanide

V I n i t i a l C a l i b

True Value

WO SO

\0OD

1606

dôoo

SObO 700O SO

30D6 ^.0

aooo

SD a 060

SD

4006

Found

^ ' ^

€ 4

qô ^^2 .

c ^ ^

5;(=i-o \^lrO

so

3126

4.3 l^SO

4 ^ R l o

45r

432/:>

. i

ZR

-?? / t ) ^

*=?> ^ ?

q 4

16^ 0\1_

lOO

(O^

f^ ^

^t ^

9(?

icr^

UNIT!

Con

True Value

lOO

%0

106 <5 1666

^056

SOOC

^ D O O SO

5 0 0 0 S.D

tooo

50

<9or)o

s o

466 6

1

s: ug/L t i n u l n j Ca l i b r a t i on ' ^

Found

^ 3 4 t

1026

"M l

nic)

^ ^ 0 l ^ ' S ^

so

3 6 6 ^ t.o Wc;

4 b '

I ZO

4s:

ZR

^ 3 92.

1 2 ^

^1

Id? ^

1 ^

joo \IQ

"t ^D

^t

*1f?

45sD 116

i 1

Found

.

m 6

ZR

' ^ Z .

1 1

EO i i b d

1 i 1

Method*!

F P

<^

a

4

4 4 P

ft ^ i ^ . ^ ^

P 1 1 ft 1 1 1 P t

1 i fr 1 1 II I

1 1 1 1

PI

o o to

o o to U3

' I n i t i a l C a l i b r a t i o n Source FTS'rtPiP Cont inuing Ca l ib ra t ion Sou^ceIv^ft<A/3nl^ \/cy\ \}-CC<>

^ Con t ro l L i m i t s : Mercury and Tin tiO-12U; Other Metals 90-110; Cyanide b5-113

^ I n d i c a t e A n a l y t i c a l Method Used: P - ICP; A - Flame AA; F - Furnace AA

J J J J J J J J I

J f I

J J J -I J

Form I I ^

Q. C. Report No. Dl^v^ ( 1 )

INITIAL AND CONTINUING CALIBRATION VERIFICATION^

LAB NAME W S ( ^ LVVe^S ' 3 ; | N C ^ CASE NO. t S/?^ /7 - /9

SOW NO.

DATE 5 . / / / V ;

Compound

M e t a l s :

1. Aluminum

2 . Antimony

3 . A r s e n i c

A. bar ium

5 . Be rv l l i um

b . Cadmium

7. Calcium

b . Chromium

9 . Cobal t

10. Copper

1 1 . I ron

12. Lead

13 , Magnesium

14, Manganese

15, Mercury

l b . Nicke l

17. Po tass ium

l o . Selenium

19. S i l v e r

20 . Sodium

2 1 . Tha l l i um

22 . Vanadium

2 3 . Zinc

O t h e r :

Cvanide

I n i t i a l C a l i b

True Value

Ion so

So

50

^ 0

Found

^ ^

51

Fn

Sl

S 3

.1

ZR

f<4 162

|D0

102

/ ^ ;

UNITS: ug/L

Cont inuing Ca l i b r a t i on ' ^

True Value

lOC^

SO

60

5^6

s-o

Found

9/ 4f;

S 2 -

41-

ss-

M

9/ 96

l o M

=14

110

1 1

Found

5 3

ZR

I tb

i 1 1 1

?tethod*i

}=-

F

F

i

F 1 1 1 1 1 F i

1 i i 1

i 1 1 r 1 f 1 1

in PI

o o

o o Cd

o

^ I n i t i a l C a l i b r a t i o n Source^Tkrtf=g Cont inuing C a l i b r a t i o n Sourcets^pz/iQw^f Vfr\T\]y/fr

^ Cont ro l L i m i t s : Mercury and Tin BO-120; Other Metals 90-110; Cyanide tJ5-115

^ I n d i c a t e A n a l y t i c a l Method Used: F - ICP; A - Flame AA; F - Furnace AA

J J s J J -I J J J J J i

J

Form 11 E>

Q. C. Report No. p ^ > ^ ^


LAB NAME RbLM L f t ^ X r ^ CASE NO. r O S t 9 f i \ l - - \ ^

SOW NO.

DATE 3 . ] \ ] n

Compound

M e t a l s :

1 . ' Aluminum

2 . Antimony

3 . A r s e n i c

A. bar ium

5 . Be ry l l i um

0 . Cadmium

7. Calcium

ti. Chromium

y . Cobal t

10 . Copper

1 1 . I r on

12. Lead

1 3 . Magnesium

14. Man>5anese

15 . f-iercury

l b . Nicke l

17. Po tass ium

l o . Selenium

l y . S i l v e r

2 0 . Sodiuai

2 1 . Tha l l ium

True Value

SD

22 . Vanadium

2 3 . Zinc

O t h e r :

Cyanide

. zCal lb

Found

4^?

. ^

XR

%

UNITS: Ug/L

Cont inu ing C a l i b r a t i o n ' ^

True Value

50

1

Found

4"

XR

^ b

i 1

Found ZR

1 1 i 1 i i 1 1 f 1

Method*!

P

1

1 1 1 1 1 1

1 1

1 1 Continuing Calibration Source ^ Initial Calibration Source

S Control Limits: Mercury and Tin ttO-120; Other Metals 90-110; Cyanide bb- 115

if)

tn

o o to

I n d i c a t e A n a l y t i c a l Method Used: P - ICP; A - Flame AA; F - Furnace AA

O O U)

^ )

Form I I I

g . C. Report No. Dfrv.^ 0

BLANKS

LAB NAME' f^^rn I . ^ R 5 nWC CASE NO. ^ y . S & A n ' / 9 DATE A ) ) ^

Compound

M e t a l s :

1 . Aluminum

2 . Antimony

3 . Ar sen i c

A. Barium

5 . b e r y l l i u m

6 . Cadmium

7 . Calcium

ti. Chromium

9 . Cobal t

10 . Copper

1 1 . I ron

12 . Lead

1 3 . Magnesium

lA. Manganese

1 5 . Mercury

l b . Nickel

17 . Po tass ium

l b . Selenium

1 9 . S i l v e r

2U. Sodium

2 1 . Tha l l ium

2 2 . Vanadium

2 3 . Zinc

Othe r :

Cyanide ^ Repor t ing Un

.

I n i t i a l C a l i b r a t i o n Blank Value

<LbO < l o

< ^

<S'

< l o

<as' < ô <<r

< 5 o <^.2_ <:ô

< < -

<C}D

 d)

®

<S) ® ^

(3) < ^

(9

© ©

a) Q

/L ; s o l i c

^^0 ^10

< ^

<s-

< I D

<iar < 5 L O

< ^

^ ^ o <.0.7^

^ ^ O

<€-^ i O

^ [ O

^ 2 o

1 mg/kg

a - 10

P r e p a r a t i o n Blank M a t r i x :

1

M a t r i x :

2

&Xbo (AXio

^ < . ^

^ « < -

^ ^ ) < . I 0

cp<ic?s-(D<ao

& ) « ^

(^<P6 Kiie

(^<^n

^ < 5 r Ok.;^

C^<io

r^x iz^

IFB Amend. One

'

r/

P

o o M

O O CJ M

*

m m

Form I I I

y. C. Report No. JVjyj (£)

BLANKS

LAB NAME H o ^ m L Q - s s . r ^ r v i C .

D A T E ^ ) ^ ] ^ CASE NO. N) .SgA l4 -l^

UNITS o<a|P

Compound

M e t a l s :

1 . Aluminum

2 . Antimony

3 . A r s e n i c

A. bar ium

5 . b e r v l l i u m

b . Cadmium

7 . Calcium

b . Chromium

9 . Coba l t

10 . Copper

1 1 . I r on

12 . U a d

1 3 . Magnesium

14 . J-langanese

1 5 . Mercury

l b . N icke l

17 . P o t a s s i u m

l b . Se len ium

19 . S i l v e r

2 0 . Sodium

2 1 . Tha l l i um

2 2 . Vanadium

2 3 . Zinc

O t h e r :

Cvanide

I n i t i a l t C a l i b r a t i o n Blank Value

<LfoO 

Contd

1

(4i) (2P

< $ -

< ^

<^ iO

<ias ' < i ^ O

#

< 2 ^ 0

@

< W6

(h' < { 0

(9

yô

inuing C a l i b r a t i o n Blank Value

2 . 3 A 1

^ h b

<L10

< ^

<o.rL^

<5r

<\o

P r e p a r a t i o n Blank M a t r i x : flams,

1

M a t r i x : F u r r v i t s . |

2

C^<i(.b ^ </0

Cf^<2.'^ ^ < 2 6

( S ^ < ^

\(S>^zo NY^

:P< <V£)

ft)<:^ ^ Q \SS 3rv)C-DATE j / , ; s v

D ^ ^ ^

CASE NO. N . ^ l ^ ¥ ^

"''ITS ^ ^ 1 0^

l - ^ ' l ^

Compound

M e t a l s :

1 . Aluminum

2 . Antimony

3 . A r s e n i c

4 . bar ium


b . Cadmium

7 . Calcium

ti. Chromium

9 . Coba l t

10 . Copper

1 1 . I ron

12 . U a d

1 3 . hiagnesium

14 . t-iangancse

1 5 . Mercury

l b . N icke l

17 . P o t a s s i u m

16 . Se lenium

1 9 . S i l v e r

2u . Sodium

2 1 . Tha l l i um

2 2 . Vanadium

2 3 . Zinc

O t h e r :

Cvanide • Hct n r ^ r r i n (T U n

I n i t i a l C a l i b r a t i o n Blank Value

< h O ^ 1 0

^'T

<[t>

Cont inuing C a l i b r a t i o n Blank Value

1 2 . 3 A

^

(5?

®

&

/ I . o ^ l < /

^ ( P O

^ \ 0

< ^

^10

4 m.i / U r .

P r e p a r a t i o n Blank M a t r i x :

1

M a t r i x :

2

(S)^ô (i)<io

a > < ^

® < 1 0

B - 10

O O K)

IFb Amend, One Q O CJ

HVtfM

1 1 1

n n n n n n

Form IV

Q. C. Report No.

ICP INTERFERENCE CHECK SAMPLE

LAB NAME U ^ LlAi^S. ^ I s f C . CASE NO. {\l . ^ ^ R l l ' / < 1

I Check Sample I .D. X T 3

DATE ^ j l / ? F Check Sample Source J / 1 ^ ^ / 7 /C

Uni ts : ug/L Vihrures :iyir.

Com

Met

1 .

2 .

3 .

4 .

5 .

b .

7 .

8 .

9 .

10 .

1 1 .

12 .

1 3 .

lA.

1 5 .

16 .

17 .

l b .

1 9 .

20 .

2 1 .

2 2 .

2 3 .

pound

a l s :

Aluminum

Antimony

A r s e n i c

Barium

b e r y l l i u m

Cadmium

Calcium

Chromium

Coba l t

Copper

I r on

U a d

Magnesium

Manganese

Mercury

N i c k e l

P o t a s s i u m

Selenium

S i l v e r

Sodium

Tha l l i um

Vanadium

Zinc

O t h e r :

Cont ro l Mean

^ 3 ^ ^ 0

H*lo

I^ IO

\?<^6 ^ 3 5 00 0

1 ^ 3 ^

11-60

9^d

L i m i t s i S t d . Dev.

'/.itSO

0 A b 2 . omi

o.sqi^

0. S 2_ 0M9

o.ssa.

i.oô

O.bs;:?-

,.£Ii^

True^

5 3 ^ 0

ÔOO

9uc>oo

cJOOO Bi^DdC

aooo

<aODO

^ 6 0 O

I n i t i a l Observed

â<fo 1^30

I ^ i 6

19*70 2 L ^ O O 6

I ^ 3 o

l ^ ^ O

l ^ô

ZR

too ^

161

166 106

]C6

163

<^^

F i n a l Observed

aôo 3.160

Rto

ao.^/^ 3fSi^<30

l ^ ^ 6

l ' § 3 ^

| ^ ^ 6

ZR

169-16?

163

16"^ \&H

163

1D«^

l ' ^ ^

1 ^ Mean value based on n - ( 7^) «

' True value of EPA ICP Interference Check Sample or cont rac tor standard.

cn tn >

o o to

o o CJ CJl

B - 11 IFb Amend One.

n n n n n n

fl fl fl fl i

fl p

I

Form V

Q. C. Report No.

SPIKE SAMPLE RECOVERY

LAB NAME K ^ T V l L t ^ g , S T r > ^ . CASE NO. ^ ) S f c ^ l ^ " ! ^

DATE liar Matrix / \ 6 0 g n & O J

EPA Sample No. fhUJ-fcl- i C Lab Sample ID No. =^6>SrS '^V Units Og{}(2

Compound

M e t a l s : 1 . Aluminum

2 . Antimony

3 . A r s e n i c

A. Barium

5 . B e r y l l i u m

6. Cadmium

7 . Calcium

8. Chromium

9 . Coba l t

10. Copper

1 1 . I r o n

12 . Lead

13 . Magnesium

14. Manganese

15 . Mercury

16. N icke l

17. Po ta s s ium

Iti . Selenium

19. S i l v e r

20 . Sodium

2 1 . Tha l l i um

22 . Vanadium

2 3 . Z inc

O t h e r :

Cyanide

Con t ro l L imi t ZR

75-125

-

-

M

••

M

M

-

••

M

M

n

M

-

M

-

M

-

M

M

M

-

-

• f

Spiked Sample Resu l t (SSR)

\OC\

\s-

B o 4 0

PÔ

.^/OO 10O66

4fi

3 ^ o i .q

4 ^ 6

K)C I D O

l ^

,31 O

1%

Sample Resu l t (SR)

'

^ ( : > 0

<:io

- i lS" - s-

l'§D

r ^ a o ^106 9i^

a^Lo O.M 1^6

- ^ / O

<H0

no

</(b

Spiked Added (SA)

lOO

^ O

vSo 56

I60

a S O 106(3

3 D

isro l.O

4 o o

(OD

a o

^ D ^

a o

ZRi

lOS ^s-

/6o 8 6

lOO

NX ^

^ s r

( 0 ^ (06 ^ 3

160

'Sir

160

^ o ^ ZR - ((SSR - SR)/SAJ X 100

"N"- out of c o n t r o l

NR - Not r e q u i r e d

Comments: N/Q - S ^ y V t ^ ^ <2.gDvj'> e t f O b ' l L v j n ^ M ^ SJC>T C A U i \J C ^ T i ^ T >

b - 12

CO PI >

O O

o o CJ

cn

II

fl fl fl fl fl fl fl fl fl fl n n n n n

•

Fom V

Q. C. Report No.

SPIKE SAMPLE RECOVERY

LAB NAME ffi iTVI L K ^ J T ^ S , Z L f \ / C

DATE ^ ^ | | ^ 8 :

Matrix { ^ ( k M ^ C n ^ — C f ^ ^ ^ j i l ^ ^

CASE NO. ^ / > S ( r 4 t 9 - 1 ^ EPA Sample No. n n V # /C2 U b Sample ID No. ^ ^ £ S 1 2 2 ^ Units .\ja j j f

Compound

M e t a l s : 1 . Aluminum

2 . Antimony

3 . A r s e n i c

A. Barium

5 . Bery l l ium

6. Cadmium

7. Calcium

8. Chromium

9 . Cobal t

10 . Copper

1 1 . I r o n

12. Lead

13 . Magnesium

14. Manganese

15 . Mercury

16. Nicke l

17. Potass ium

l b . Selenium

19. S i l v e r

20 . Sodium

2 1 . Thal l ium

22 . Vanadium

2 3 . Zinc

O t h e r :

Cyanide

C o n t r o l L imi t ZR

75-125 ••

••

M

M

••

-

••

H

M

••

-

-

••

••

••

"

"

•«

-

••

"

••

"

Spiked Sample R e s u l t (SSR)

^l l b

SO Ao

I20

?)60 1106 Sl>

Ibo Mif 4oo

^

loo

\ ^

aso

Sample R e s u l t (SR)

•

^ G c ^ <\t>

<<r ^s -

< ^ ] 6

4 o Ibo

b

<âo

^ 4 o

<S' < ^ / 6

< / 0

30

Spiked Added (SA)

l o o 5 o

S O S O

l o c

3. 0 1 6 6 CD

ZO

IS'O

4oo '

10 l O o

ao

2 . 0 0

ZRl

^ / ^ 6

/OO ^ o

/zo

ioV <=M4 IOC

16^

/OC

^ 0 /OO

96

no

^ %R - USSR - SR)/SA] x 100

"N"- out of c o n t r o l

N R ' - Not r e q u i r e d

Comments: - f ^ /OSof^ ' i / ' . i /PTOT" S q * ^ p W V^C>\\/yv\0 , S t ^ ^ COJML n a Y r^?L-Vi v/g

B - 12

cn PI

o o

o o CJ <1

fl fl fl fl fl fl fl fl

Form VI

Q. C. R e p o r t No .

DUPLICATES

LAB NAME U^YV\ L 4 G g -QirJCl

DATE

Matrix 4 6 u g O O < ;

CASE NO. | V ) S g l 4 \ l - i 9 EPA Sample No. » V i U ) # \ r . ~ Lab Sample ID N T T ^ ^ ^ S ^ ^

Unlts O A | J 2

Compound

M e t a l s : 1. Aluminum

2 . Antimony

3 . A r s e n i c

4 . Barium


6. Cadmium

7. Calcium

8. Chromium

9. Cobal t

10. Copper

1 1 . I ron

12. Lead

13 . Magnesium

14. Manganese

15 . Mercury

16. Nicke l

17. Po tass ium

l b . Selenium

l y . S i l v e r

20 . Sodium

2 1 . Tha l l ium

22 . Vanadium

2 3 . Zinc

Other :

Cvanide

C o n t r o l Limit^

t f c o i l D

-»• — - 5&

i S -

^ 5 > - 0 - / ,

•t :LO'A

•tao-A i ^ o ' A

i a ^ - / . ^ 0 , 1 ^ t ^ o

^ S D ± \ 0

- t \ o

t a o - A

^ l O

Sample(S)

.

-d 4 0

- c / o

^ C d ^

\ ^ o

aô ^160

^ ^

^ ^ o O-W \ ; io

^ s o ^ l O

^ \ o

no



a 

tXl

* Out of C o n t r o l

^ To be added a t a l a t e r d a t e . ^ RPD - (JS

NC - Non c a l c u l a b l e RPD due t o v a l u e ( s ) l e s s than CRDL

B - 13

D | / ( ( S * D ) / 2 ) ] X 100

in PI >

o o

o o CJ CD

file:///l-i9

Form VI

Q. C. Report No.

DUPLICATES

LAB NAME W ^ m b 4 B>S ^pJC.

a / . l 9 ^ DATE

CASE NO. N / .S t f 4 - l l - - 1 ^ EPA Sample No. rAixiSr \(L Lab Sample ID No. •=^foC"S'?4-Unlts 0^ / jg .

Matrix A-Qo(F 60S ( j^^^rJe^) Compound

M e t a l s : 1. Aluminum

2 . Antimony

3 . A r s e n i c

4 . Barium


6 . Cadmium

7. Calcium

8. Chromium

9. Coba l t

10. Copper

1 1 . I r on

12. Lead

13 . Magnesium

14. Manganese

15, Mercury

16. N icke l

17. Po tass ium

l b . Selenium

19. S i l v e r

20 . Sodium

2 1 . Tha l l i um

22. Vanadium

23 . Zinc

O t h e r :

Cyanide

C o n t r o l Limit^

t 6 , 0 t l 6

• i ^ ^

tr

i i o

"-a^ •tP-o'A

t<r

^ ; i o yie ^ 4 o

±S t f O

±10

t S i o

Sample(S)

^ 6 o < l O

^ S "

-i r

< i i o

4 0 I t o S"

^ ^ o

<L<4o

< S" <dio

< iO

36

Dupllcate(D)

^ 6 . 0

- ^ l O

•CS-^ 5 -

IO

3o l6o

C,

^<^ o

^Ho

<s-<c/<?

^ i O

3o

RPD2

rsiC Ke

r iC

(NiC

Nb<2

a: o

OK

NC

NC

h J C

NC

NC

O

* Out of Control

i To be added at a later date. 2 Rpc - [|s - D|/((S + D)/2)] x lUO

NC - Non calculable RPD due to value(s) less than CRDL

B 13

in tn >

o o

o o CJ

Form Vll

Q.C. Report No.

INSTRUMENT DETECTION LIMITS A1,'D

LABORATORY CONTROL SAMPLE

l^B NAME ^ : ) , m Ltf-f2>S : Z f s C ^ CASE NO. \ ] S . ( : ^ l l i ^ DATE ;a//te^ LCS KO.

KIK - Uot r e q u i r e d

Compound

I l e t a l s : 1. Aluminum

2. Antimony

3 . A r s e n i c

4. Barium

5 . Be ry l l i um

b . Cadmium

7. Calcium

ti. Chromium

9. Cobal t

10. Copper

1 1 . I ron

12. Lead

13. Magnesium

14. i langanese

15. . ' lercury

16. Kicke l

17. Potass ium

18. Selenium

19. S i l v e r

20. Sodium

2 1 , Tha l l ium

22. Vanadium

23. Zinc

O t h e r :

Cvanide

Requi red D e t e c t i o n L i m i t s (CRDD-ug/ l

200

60

10

200

5

5

5000

10

50

25

100

5

5000

15

0.2

40

5000

5

10

5000

10

50

20

10

Ins t rument D e t e c t i o n L imi t s ( l D L ) - u g / l ICP/AA Furnace

IDi 'Ajec / lOfVSeil^M ^ U m /

0,^ l.s-

d.b

l.*+ l i b

0.^ O.T-

\.-L

1.8

O . b

NR

>6Jato /^-n^-Oil

5 =)

5

S"

6

I;K

U b Con t ro l Sample />ii /L~^ mg/kg ^>»—(«rrcle one)

True Found ZR

IDO SO

I OOO

1006>

ZDOO

ÔOb

2D00O S o

Soco s.o

^ 0 6 0

5 0 StOOQ

5 0

KODO

^ w 4^

qzo ^ 3 0

I^SO

4g56 X^ôb

5W

^ H " ^

^2_

^ 3

H^

^ i 43 icjr

1 3^SO ^ ? S.l 102-i

T/^0 9o i i

4 ^ ^V I'Sô q44

4^

?D^JO

^?

^3

B - 14

O O

O

Form VIII

LAB NAME

UATL X

Us^m hl'Rr

EPA Sample if

^<^SS13. HS5?^ ^(o'în

kfc^tll ?fc^ fe%l

^ ^ b ^ l

TiS b'gfT

•:?'t>?7fe9s

It^Sto ?fcS59;j

btsbfiz

i

c lement

?b Pb ?b Pb Pb Pb

Pb Pb

D.Pb

D.Pb

Ph

(^.C Repoi r t No.

STANDARD ADDITION RESULTS

/ i-^-ftS TLr\;(*. cASi

Matr ix

Afiifezws t l

II

i>

l l

11

I I

i i

l l

II

II

0 ADD A b S .

9.^1

3 ^ ^ l^b I b ^

air 3 0 0

a%;:

51^3 Zcf\

\ \ c ^

m

1 ADD CON.

10

10 10

10

10 10

(0

10 10

lo

IO

ABS-^

4<?3 4afc

am .513

K)^ ^ %

3S6 ^ ^ ^

Z ^

9 ^ ^

Rt.

: NO. ^ ) ^ f c ? 4 R - | ^

UMTS ; ug/L

2 ADD CON.

ao 50 ao ZO

2 0

Zo ID

2 6

ao c ^

cÔ

ABS.'^

Sfco

flf.4 ^ • ^

aâ Bi<=r

4a3) 4a^ 4a> 3 ^

3|6?

aj^-

3 ADD CON.

3o ,3n 3 0

J o

3o

3o

;V)

3<?

3 o

30

30

AbS.^

W3 •t.l4-46? ^S'^ 411 4fc8 ^ 6 0 5 6 3 .

4/^ 39:;^ 30/

FINAL CON. 3

aae —

a ^

S o —

4 ^ 3o ^V R

1

r*

pe^ .'S\\ ' ^ «

p ^

°pa.

fi9s

. ^

.w .ffS

. 7 ^

1

(D

-tS)

r :P (p ^

(p

1 ^

' -Hatrix abbreviations: Low Solid, Lb; Medium Solid, MS; Low Aqueous, LA; Medium pi Aqueous, MA.

• CuN i s the c o n c e n t r a t i o n added, AbS. i s the ins t rument readout in absorbance or c o n c e n t r a t i o n .

• C o n c e n t r a t i o n as_ de te rmined by MSA *" r " i s the c o r r e l a t i o n c o e f f i c i e n t , -t- - c o r r e l a t i o n c o e f f i c i e n t I s ou t s ide of c o n t r o l window of U.yy5.

B - 15 1Kb Amend. Une

O O

O O 4^

K.ikrf««rftM

r r

fl fl fl fl fl

h h h i

r fl fl

Form X

QC Report No.

HOLDING TIMES

LAB NAME ftayVj L A R S 3 N ( L

DATE a . \ \ t o '. CASE NO. N^>St?)4 I l - I R

EPA Sample No.

I-^S 5^0 sqa s^ s^b b09 61/ bl3 L i ^

\

Ion W^ AS I ^ % 1 t^

^ b^l

Matrix

Adfiyeîc^

1 1

\

Date Received

l3ll^lA«-

1

\ f

Mercury Prep Date

ujikUfi^-

f

J

Mercury Holding Tlmel 1 (Days)

( ^

I

V f

CN Prep Date

jajis-/?! 1

.

/ 1

V

CN Holding Tlme^

(Days)

( ^ •Ot^ '

1

1

1

^ h o l d i n g time i s de f ined a s number of days between the da te r e c e i v e d and the sample p r e p a r a t i o n d a t e . ^ , ,

B - 17 IFb Amend One.

to tn >

O O to

O O *.

Form XI (Quarterly)

INSTRUHENT DET&CTION LIMITS

^

lAB NAME ^ \ A Lr9BS 3 N C DATE a.|||^

(lCP/Il*mt AA (Circle One) Model Wuaber ftg^ ^ ^ / D Furnace AA H m b e r ^ ^ j ^ - ^ ^

Eleaent

I4 AIuBlnum

2. Antimony

3. Arsenic

A. Barium

5. Beryllium

6. Cadmium

7. Calcium

6. Chromium

y. CobaJ.t

10. Copper

11. Iron

12. Lead

Wavelength dm)

566.g'S^

m.-^s^ ^Q^MO^ 53tj,%;

3;^f,S02.

qa5.b?3

;ioS.S4'L

^ ^ ^ € ^

2^."=1^0

?w^. ~ ^

CRDL (ug/L)

200

60

10

200

5

5

5000

10

50

25

100

5

IDL (ug/L)

(S> 6 ^

1

0.-)

I'iT

^6 ;).b

I . M

j ' h ^ ' ( % )

Eleaent

13.-Magne>iua

14. Manganeae

15. Mercury

16. Nickel

17. Potaasiua

18. Selenium

19. Silver

20. Sodlua

21. Thalliua

22. Vanadium

23. Zinc

Wavelength (nm)

Z^.^1^ ;^=ihi

5^8 .^ ' 3: /.tOV

/f . ^y

s:;f^.o6^

s ^ " ^ ^

5;3'5ir^

CRDL (ug/L)

5000

IS

0.2

40

5000

5

10

5000

10

50

20

lOL (ug/L)

^ . q

0.^

< 0 . ' ^

/ . a

^(s^

I'ft +

f^

•6

Footnotes: • Indicate the Instrument for which the IDL applies with a "P" (for ICP), an "A" (for Flame AA), or «n(3^(for Furnace AA) behind the lUL value.

• Indicate elements coaaonly run with background correction (AA) with a "b" behind the analytical wavielength.

• If acre than one ICP/Flane or Furnace AA la used, submit separate Forms XI-XIII for each Instrument.

COMMENTS:

in tn >

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Form XII (Quarterly)

ICP Interelement Correction Factors

LABORATORY n ^ \ ^ \ CQfeS ZT (M( ICP Model Nuaber fl^CÂlc

Analyte

* 1. Antimony

2. Arsenic

3. Barium

A. Beryllium

5. Cadmium

6. Chromiilm

7. Cobalt

8. Copper

9. Uad

10. Manganese

11. Mercury

12. Nickel

13. Potassium

lA. Selenium

15. Silver

16. Sodium

17. Thallium

18. Vanadium

Is. Zinc

' •

Analyte Wavelength

(nm)

1 Intereleaent Correction Factors for

Al

^ni

Ca

^M'

Fe

'Aw '

"4

M}

3>/c'

M«

•

NH

?'A/?i

i Mt ' i i

A M '

1

! 1

1 t • 1

COMMENTS:

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t Form XIII (Quarterly)

ICP Linear Ranges

LAB NAME ^ n ' ^ L A B S - Z T T ^ r ICP Mode

DATE ^ ' ' ' ^ A * - [

A n a l y t e

1. Aluminum

2 . Antimony

3 . A r s e n i c

A. Barium


6 . Cadmium

7. Calcium

8 . Chromium

9 . Coba l t

10. Copper

1 1 . I r o n

12. U a d

F o o t n o t e s :

COMMENTS:

Integrat ion Tiae

(Seconds)

CD k)f

Mfl

Nf^

CO (D Q G) Mfl

0 Q Nfl

. I n d l u l

' 1 ^

- • < . • . *

Cooeca-t r a t ion

(ug/L)

3O0 r > o o

10,OOO

3o,nors

?r^,nor,

30O ncY i '

1 0 0 m A

3 D 0 , / ^ A

Analyte-

13. Kagneaiua

14. Manganese

15. Mercury

16. Nickel

17. Potaasiua

18. Selenium

19. Silver

20. ScxJluffl

21. Thalliua

22. Vanadlua

23. Zinc

.c elcaeata not analjaed bf i

> J -

1 Nuaber f \ ( lL 3 ^ ( 0

In tegra t ion Tiae

(Seconda)

CD

x/ft

roR

© Nfl

Nft

ro • MA

H f\

Ki A

CO

Concent r a t i o n

(ug/L)

' 00 ,OCy-N

y^^mr)

2 0 . c ^ , O

3oo Or>r

CP with the notation "NA".

;-'5.*;':v-:

- . . . ; * » •

Lab Manager

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fri2M LACS, INC.

Ill, Sample Dsta Package

1. Reports for scans:

X ._ x,„

1. . x.,_ X ^

GC/MS Volatiles GC/MS Extractabies Pesticides/PCB's GC Volatiles Inorganics

2. Reporting Packages for Individual Samples

a. Chain of Custody and Documents b. Raw D a t a

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1 Form 1

U .S . EPA Con t r ac t L a b o r a t o r y Program Sample Manageaent Of f i ce P .O. Box bib - A l e x a n d r i a , VA 22313 703/557-2A90 FTS: 8-557-2A9U

EPA Sample No.

Date ^ - 1 - ^ ^

INORGANIC ANALYSIS DATA SHEET

LAB NA.ME > ^ m ] A 9 & r \ r ^ P _ CASE NO. ( ^ ^ m S f ^ i J ' ^ 7

SOW NO. U b Rece ip t Date JbL J*^ I ^

LAb SAMPLE ID. NO. QC REPORT NO.

C o n c e n t r a t i o n :

M a t r i x : Water

Elements I d e n t i f i e d and Measured

Low

Soil

Medium

Sludge Other

1. Aluminum

2. Antimony

3. Arsenic

4. barium

5. Beryllium

6. Cadmium

7. Calcium

8. Chromium

9. Cobalt

10. Copper

11. Iron

12. Uad

Cyanide

ug/L or mg/kg dry weight (Circle One)

13. Magnesium

lA. Manganese

15. Mercury

16. Nickel

17.

lb.

19.

2U.

21.

22.

23.

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Precent Solids (2)

Footnotes: For reporting results to EPA, standard result qualifiers are used as defined on Cover Page. Additional flags or footnotes explaining results are encouraged. Definition of such flags must be explicit and contained on Cover Page, however.

Comments: ^ < t ^ ^ O W ^ Dvls'H- t ^ V i M X ^ V l ^ (î^^ÔUTS ..S t ^

I WA \,A(^ ^ ^ C e.e-pO(^S-

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B - b

IFB Amend. One

DATA REPORTING QUALIFIERS

Value - If the result is a value greater than or equal to the detection limit, report the value.

U - Indicates compound was analyzed -For but not detected. Report the minimum detection limit -for the sample with the U (e.g., lOU) based on necessary concentration/dilution actions. (This is not necessarily the instrument detection limit.) The footnote should read: U-compound was analyzed for but not detected. The number is the minimum attainable detection limit for the sample.

J - Indicates an estimated value. This flag is used either when estimating a concentration for tentatively identified compounds where a 1:1 response is assumed or when the mass spectral data indicates the presence of a compound that meets the identification criteria but the result is less than the specified detection limit but greater than zero (e.g.: If limit of detection is 10 ug/1 and a concentration of 3 ug/1 is calculated^ report as 3J.)

C - This flag applies to pesticide parameters where the identification has been confirmed by GC/MS. Single component pesticides >10 ng/ul in the final extract should be confirmed by GC/MS.

B - This flag is used when the analyte is found in the blank as well as a sample. It indicates possible/probable blank contamination and warns the data user to take appropriate action.

Other - Other specific flags and footnotes may be required to properly define the results. If used, they must be fully described and such description attached to the data summary report.

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U.S. EPA C o n t r a c t U b o r a t o r y Program Sample Management Off ice P.O. Box 818 - A l e x a n d r i a , VA 22313 703 /557-2490 FTS: 8-557-2A90

SOU No.

COVER PAGE INORGANIC ANALYSES DATA PACKAGE

Date a/)/^r

Ub Name ^ T V ^ L A ^ ^f<>C Case No. tO-SiCflfi ) ^ - l ^

Q.C. Report No.

Sample Numbers

EPA No. U b ID No.

53a Ii24i _S^k.'

W\ L v ^ \ C t^sJ*v\^D

AV3^Z^ {VM>o-riA(L

^ a . 0 ^C^v3>f Û\C Nt/ ^ I C Comments:

fe-isQl

^ / / fiY 4^/3

EPA No.

irYiu)»4f3

TScVD FQSJ.(^ But .

U b ID No.

1 f/7 S

^^Z-.^15 4. Ele

i

ICP i n t e r e l e m e n t and background c o r r e c t i o n s a p p l i e d ? Yes X ô .

If y e s , c o r r e c t i o n s a p p l i e d before or a f t e r X g e n e r a t i o n of raw d a t a .

F o o t n o t e s :

l.'R - Not required by contract at this time Form 1: Value - If the result Is a value greater than or equal to the instrument

detecion limit but less than the contract-required detection limit, report the value in brackets (i.e., (lOJ). Indicate the analytical method used with P (for ICP), A (for Flame AA) or F (for Furnace AA).

- Indicates element was analyzed for but not detected. Report with the instrument detection limit value (e.g., lOU).

- Indicates a value estimated or not reported due to the presence of interference. Explanatory note included on cover page.

- Indicates value determined by Method of Standard Addition. - Indicates spike sample recovery is not within control limits. - Indicates duplicate analysis is not within control limits. - Indicates the correlation coefficient for method of standard addition is

less than 0.995 - Indicates duplicate injection results exceeded control limits.



O O

O O

HIM LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL, PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Town of Southampton Hampton Road Southampton, NY 11968

Sample Lab No. 765569 Date Collected: 12/07/S7 Date Received: 12/08/87 Point: MW «1A Hr: 1100 North Sea Landfill

Date Anal: 12/14/87 Cone./Oil. factor: 1.1 Cone: Low

RESULTS FOR PRIORITY POLLUTANTS ANALYSIS PURGEABLE ORGANICS

Scan # C A . S. Number

74-74-75-75-

131 75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-

331 71-10061-

110-75-

127-79-

108-108-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--OO--43--01--75--25--18--54--88--90--41--72--50--46-

•3

-9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 •1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1.3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/1

lOU lOU lOU lOU 12B 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U

IBJ 5U lOU 5U 5U 5U 5U 5U 5U 5U 5U 5U

Date Reported: 12/30/87 3k?t:3t:3icak9k;X3lcX»;]«c:*:7t:3t;X:'c

CO

tn

o o NJ

rohn J. Moiioy, P.E. 'Laboratory Director

O o c;i o

l i2Ai LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW «1A

765569

Tentatively Identified Compounds

1

C.A.S. 1 Number I Compound Name 124-38-9!Carbon dioxide

!Unknown

1

— |- --- - - - - - -

% Probability Fit IRFit 100 1 82

1

- — - - • -

• • - -

_.

—

1 Estimated 1 Scan 1 Concentration; » 1 ug/1 1 15 1 25J,B 1 49 1 26J,B

1 1

I 1

1 1

1 t

1 1 1 1

1 1

1 1

1 I 1 1

t t

1 1

1 1

1 1

) 1 1 1

1 t

r 1

1 1 t t

t t

1 1 1 1

i I

1 1

1 1

Date Reported: 12/31/87

* : * * * * X * i c K * . * A i ^ * i

c * A A >K A

i hn J. Molloy, P.E. Laboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY 11747 • 516-694-3040



Scan C.A.S. Number 65-75-9

108-95-2 111-44-4 95-57-8

541-75-1 106-46-7 95-50-1

N-Nitrosodimethylamine Phenol bis(2-Chloroethyl)ether 2-Chlorophenol l,3-0ichlorcDen2ene 1,4-Oichlorobenzene l,2-Dichloroben2ene

39638329 bis(2-chloroisopropy1)ether 621-64-7 N-Nitroso-Di-n-Propylamine

67-72-1 Hexachloroethane 98-95-5 Nitrobenzene 78-59-1 Isophorone 88-75-5 2-Nitrophenol

105-67-9 2,4-DiiBethylphenol

111-91-1 bis(2-Chloroethoxy)Methane 120-85-2 2,4-Dichlorophenol 120-82-1 1,2,4-Trichlorobenrene 91-20-3 Naphthalene

87-68-3 Hexachlorobutadiene 59-50-7 4-Chloro-3-Hcthylphenol

77-47-4 Hexachlorocyclopentadiene 88-06-2 2,4,6-Trichlorophenol

91-58-7 2-Chloronaphthalene

131-11-3 Dimethyl Phthalate 208-96-8 Acenaphthylene

(1) - Cannot be separated from diphenylamine


Sampl Date

Date

Type: Point North Cone. Date

ug/1 lOU lOU lOU lOU IQU lOU

.e Lab Number 765569

Collected Received:

: 12/7/87 12/8/87

niscellaneous :: HW «1A Hr: 1100 1 Sea Landfill Factor: 500 Cone.: Low

Ext: 12/09/87 Date Anal: 12/17/87 C. A.S. Number 83-32-9

51-28-5 100-02-7

121-14-2

606-20-2 84-66-2

lOU 7005-72-3 lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

lOU lOU

lOU lOU

lOU

lOU lOU

amine

86-73-7

534-52-1 86-30-6

101-55-3

118-74-1 87-86-5 85-01-8 120-12-7

84-74-2 206-44-0 129-QO-O

85-68-7 91-94-1 56-55-3

117-81-7 218-01-9 117-84-0 205-99-2 207-08-9 50-32-8

193-39-5 53-70-3 191-24-2 92-87-5

Acenaphthene

2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene

2,6-Oinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether

Fluorene 4, 6-Dinitro-2-ricthy Iphenol N-Nitrososdiphenylamine(l)

4-Bromophenyl-phenylether

Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Oi-n-Butylphthalate Fluoranthene Pyrene

Butylbenzylphthalate 3,3'-Dichlorobenzidine Ben2o(a}Anthracene bis{2-Ethylhexyl)Phthalate

Chrysene Di-n-Octyl Phthalate Benzo(b)Fluoranthene Benzo(k)Fluoranthene Benzo(a)Pyrene IndenoCl,2,3-cd)Pyrene Dibenzo(a,h)Anthracene Benzo(g,h,i)Perylene

Benzidine

* K * * * l i * t t * * * * l l

X X

l ^ j T l f A J i « « » * * « « « «

1,'John J. Moiioy, P.E. Laboratory Director

ug/1 lOU SOU SOU IDU lOU lOU lOU lOU 50U lOU

lOU lOU

sou lOU lOU lOU lOU lOU

lOU 20U lOU 19B lOU lOU lOU lOU lOU lOU lOU lOU

sou

Scan

1512

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Town o f S o u t h a m p t o n Hampton Road S o u t h a m p t o n , NY 11968

Sample Lab No. 765569 MW «1A


C. A.S. 1 1 Number 1 Compound Name 1

— !Unknown 1 2196449811,13-Tetradecadiene 1

'

>

" • .

1

% 1 Probability I

Fit 1

67 ! ...._ . ,

Scan 1

... A .1 183 !

1246 I

Estimated 1 Concentration I

ug/1 1 54J,B ! 42J !

1 1

1 1

1

I

1 I

1

1

1 t

1

1

1

1 1

1 1

1

1

1

1 1 1 1

; 1 1 I t 1

1 t

t (

1 1

Date Reported: 01/05/88 J^n J. Moiioy, P.E, aboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765569 Date Collected: 12/7/87 Date Received: 12/8/87 Type: Miscellaneous Point: MW **1A Hr : 1100 North Sea Landfill Concentration: Low Cone. Factor: 333 Date Ext. 12/09/87 Date Anal. 12/23/87

C.A.S. NUMBE

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5

Vi = Volume Vs = Volume Vt = Volume Ws = Weight

R

alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Heptachlor Aldrin Heptachlor Epoxidi Endosulfan I Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-DDD Endosulfan Sulfati 4,4'-DDT Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

of extract injected of water extracti of total extract

ed (m

of sample extracted

Vs = 500 mL Vt = 1.5mL


Vi

?

e

(uL) (mL) L) (g)

= 5 uL

ug/1

0. 05U 0. 05U 0.05U 0.05U 0. 05U 0.05U 0.05U 0. 05U 0. lOU 0. lOU 0. lOU 0. lOU 0. lOU 0. lOU 0. lOU 0. SOU 0. lOU

0. sou 1. 0 u

0. sou 0. sou 0. 50U 0. SOU 0.50U 1. 0 u 1. 0 u

Ws =

*)««********«** A *

•t\/<6vv-5nr*

g

JAhn J. Molloy, P.E. Laboratory Director

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t U M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765569 MW « 1 A


C. A . S . Number

1 i RT ; E s t i m a t e d 1 I 1 « 1 C o n c e n t r a t i o n !

Compound Name ! F r a c t i o n ! m in ! u g / 1 ! Unknown 1 P e s t 1 2 . 8 2 I 0 . 3 6 J 1

1 I I 1

1 I I 1 1 I I t 1 t 1 1 1 I I 1 1 I I 1 1 I I 1

1 ! 1 1 1 I I 1 1 I I 1 t I t 1

1 I I 1

1 I I 1

! ! ! ! 1 I t t 1 I I 1 1 I t 1 1 I I 1

1 I I 1

1 ! ! 1 ! ! 1 ! 1 i ; !

! ! 1 1 1 1 ! 1

Date Reported: 01/07/88 i'ohn J. Molloy, P.E. Laboratory Director

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fi!2Ai l i 2 M LABS, INC. Environmental Testing Laboratories

576 Broad Hollow Road, Melville, New York 11747-5076 • <B16) 694-3040

•AC, OF

LABORATORY REPORT

/*

Water/

CLIENT'S NAME AND ADDRESS

Waste Water Laboratory • Hazardous Waste Laboratory • Air Test Pilot Plant Studies and Other Analytical Services

TOWN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTONf NY 119A8

PARAMETER RESULT

PARAMETER RESULT

ng Laboratory

TYPE OF SAMPLE - MISCELLANEOUS DATE COLLECTED - 1 2 / 7 / 8 7

MU • l A ( 1 1 0 0 HRS.) NORTH SEA LANDFILL FULL CLP R COC

PARAMETER RESULT

PARAMETER

LAB NO, 7AS370 PRn. lFCT NO. SHMP flAOS 1 A

COLLECTED BY VH 03 ^ DATE RECEIVED - 1 2 / B /87

RESULT

A N T I MONY

ARSENIC BERYL

LIUM

CADMIUM CHROM-

Tim

COPPER

LEAD

MERCURY

NICKEL

R

A l l . RESUI. T.nOL COLOR APC t

THEI o n n n

<A0 ,0 »

<]100.#

< 5 . 0 0 #

1 0 , 0 *

9 0 . 0 *

I S O . *

5 2 . 0 •

0 . 3 0 *

< 4 0 . 0 *

EMARKS - B I I . I

TS IN ( M f i / L ) I BACT. T. FE( » ODOR; TURB

FECAL STREP r n u n t n u u m

SELENIUM

SILVER THAL

LIUM

7INC

TRON MANOA-

NESE D I S S .

ANTIM. D I S S .

ARSENIC D I 8 BERYLLIUM

D I S S . < S . 0 0 * |0g" CADMIUM

1 0 . 0 «

< 1 0 . 0 *

I R O . *

IB f lOO ft

8 4 0 . *

< A 0 . 0 •

< 1 0 . 0 •

< 5 . 0 0 t

D I S S . CHROH >

D ISS . COPPER

D I S S . LEAD

D I S S . HFRr i lRY

P I S S . NICKEL

D I S S . SELEN.

D I S 8 . ^ , SILVER

D I S S . THALL.

< 5 . 0 0 *

<ioio #

< 2 5 . 0 *

.10. 0 * S

o.:»o«

< 4 0 . 0 •

<s.oot

< 1 0 , 0 *

< 1 0 . 0 •

.S I REPORTS :CI.V

E.XCEPT AS NOTED BY * (UG/L ) OR % (PERCENT : A L COLI (MPN/IOOML) [DITY R PH (UNITS)

(COUNTS/ML) 5) SETT .SOL IDS(ML /L )

LIMITED TO THE PRICE OF THE SE RVICE RENDERED AND PAID.

D I S S . ZINC

D I S S . IRON

D I S S . HANG.

CYANIDE

PHENOLS N02-N +

H03-N AMMONIA (NH3-N) T . DISS

SOLIDS T . ORG.

CARBON

) AND

^ ,

1 0 0 . •

2 2 0 , *

3 9 0 . *

< 1 0 . 0 •

< 1 . 0 0 »

0 . 2 0

0 . 1 7

9 0 . 0

2 . 4 0

DATE REPORTED 1 / 2 8 / B 8

_ _ _ ^ ^ _ _ LABORATORY OTRECTOB "^

H2Ai LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER, McLENDON anct MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765571 Date Collected: 12/07/87 Date Received: 12/08/87 Point: MW ttlB Hr: 1340 North Sea Land-Pill

Date Anal: 12/l i./87 Conc./Dil. factor: 1.1 Cone: Low


Scan # C A . S. Number

74.-74.-

75-75-

131 75-75-75-

156-227 67-

107-75-71-56-75-70-

10061-79-

124.-79-71-

10061-110-75-

127-79-

108-1D8-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--00--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Oichlorobenzene 1,4-Dichlorobenzene

uo/1

lOU lOU lOU lOU lOB 5U 5U 5U IJ 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U

lOU 5U 5U 5U 5U 5U 5U 5U 5U 5U cn

PI

Date Reported: 12/30/87 *A:3K3kX:*c3k:3i;X3*cA:«c:*::**3tc

/^' L ohn J. Molloy, P.E. Laboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW «1B

765571


1

C_. A.^S, _ ! Number 1 Compound Name 124-38-91 Carbon dioxide

!Unknown 1

1

1

1

(

! % 1 !Probability! ! Fit IRFit 1 : 100 1 S3 ! ! — 1 — I

- |--- -- 1 1 . 1

1

Scan ! « ! 16 1 49 1

1

I

1 1

1

\ I

1

1 1

Estimated 1 .XP.n^^Pt rati on 1

ug/l 1 14J,B 1 2.5J_,.B._ ._...„.l.

1 1

1 . ..„. .'

1 t

i

\ ^ .._._L

L.

\ \ 1

1 1 t 1 j

1 1 !,, _ • — ! -

1 ' 1 ! I

1 ' ! I 1

1 ' 1 1 1

1

1 1

1

1 1 ^„.

,

1

I

1

I

1 , 1 1 1

1 1

1 I

1 1

1 _ 1

1 1 1 1

1 1

1 1

1 1

1 1 1 _ ....

1

,, ,

1

1

I 1

t t

1

] 1 1

_ ! . t

**************

Date Reported: 12/31/87 M'- -

x x x * x * x * *

ohn J. Molloy, P.E. aboratory Director

cn tn >

o o to

o o cn

H2M. LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELU PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


can C.A.S. « Number

65-108-111-

95-5 i l -106-

95-

•75--95-• i . i -

• 5 7 -

-73--46-•50-

39638329 621-64

67-98-78-88-

105-

k - 7

-72--95-•59-•75-•67-

•9

•2 • i

•8 •1 -7 -1 b N

-1 -3 • 1

-5 •9

Sample La Date Coll Date Rece Type: flis Point: nu North Sea Cone. Fac Date Ext:

C A

N-NitrosodiiTiethylamine Phenol

bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Dichloroben2ene l,i-Dichlorobenzene 1,2-Dichlorobenzene

is(2-chloroisopropyl)ether -Nitroso-Di-n-Propylamine

Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2, 4-Diinethylphenol

111-91-1 bis(2-Chloroethoxy)Methane 120-83-2 2,4-Dichlorophenol 120-82-1 1,2,4-Trichlorobenzene 91-20-3 Naphthalene

ug/1

lOU lOU lOU

lOU lOU lOU

lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

Num

83-51-

100-121-

606-84-

lOU 7005-lOU 86-

534-

86-

101-118-87-85-

120-84-

206-129-

b N ect ive eel «1 La

tor 12

.S. ber 32-28-02-14-20-66-72-73-52-30-

umber 765571 ed: 12/7/87 d: 12/8/87

laneous B Hr: 1340 ndfill : 500 Cone. : Low /09/87 Date Anal: 12/18/87

9 Acenaphthene 5 2,4-Dinitrophenol 7 4-Nitrophenol

2 2,4-Dinitrotoluene

2 2,6-Dinitrotoluene 2 Diethylphthalate 3 4-Chlorophenyl-phenylether 7 Fluorene 1 4 ,6 -D in i t ro -2 - f1e thy lpheno l 6 N-Nitrososdiphenylamine (1)

55-3 4-Broinophenyl-phenylether 74-1 Hexachlorobenzene 86-5 Pentachlorophenol 01-8 Phenanthrene 12-7 Anthracene 74-2 Di-n-Butylphthalate 44-0 Fluoranthene 00-0 Pyrene

ug/i Scan lOU 50U SOU

lOU lOU lOU lOU lOU 50U lOU

lOU lOU 50U lOU lOU lOU lOU lOU

87-68-3 Hexachlorobutadiene lOU 59-50-7 4-Chloro-3-nethylphenol lOU

77-47-4 Hexachlorocyclopentadiene lOU

88-06-2 2,4,6-Trichlorophenol lOU

91-58-7 2-Chloronaphthaiene lOU

131-11-3 Dimethyl Phthalate lOU

208-96-8 Acenaphthylene lOU


85-68-7 Butylbenzylphthalate lOU

91-94-1 3,3'-Dichlorobenzidine 20U 56-55-3 Benzo(a)Anthracene lOU

117-81-7 bis(2-Ethylhexyl)Phthalate 37B

218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Ben2o(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2,3-cd)Pyrene lOU 53-70-3 Dibenzo(a.h)Anthracene lOU

191-24-2 BenzoCg.h,i)Peryiene lOU 92-87-5 Benzidine SOU

* t t * * t t * * * * i t * *


^ h n J. Molloy, P.E. 'Laboratory Director

1510

cn PI >

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o o Ul

l i2M LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765571 MW #1B


1 I % 1 1 Estimated 1 C.A.S. 1 [Probability 1 Scan 1 Concentration! Number I Compound Name 1 Fit 1 # 1 ug/i

(Unknown ! ! 181 ! 66J,B 2196449S11,13-Tetradecadiene ! 86 1 1244 I 34J

1 Unknown I 1 1560 ! lOJ

1 I I I

- •

•

1 1

1 1

I f

1

1

1

1 1 1

* c : k : k * * * : t c : > c : t c - ^ : ' c * * *

Date Reported: 01/05/88 ôhn J. Molloy, P.E. Laboratory Director

cn PI >

o o

O O cn o

HIM LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY 11747 • 516-694-3040



Sample Lab No. 765571 Date Collected: 12/7/87 Date Received: 12/8/87 Type: Miscellaneous Point: MW «1B Hr: 1340 North Sea Landfill Concentration: Low Cone. Factor: 333 Date Ext. 12/09/87 Date Anal. 12/23/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 5S-S9-S 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11D96-82-5

alpha-BHC beta-BHC delta-BHC garnma-BHC (Lindane) Heptachlor Aldrin Heptachlor Epoxide Endosulfan I Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-ODD Endosulfan Sulfate 4,4'-DDT Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0. lOU O. lOU 0. lOU 0. lOU 0. lOU 0. lOU 0. lOU 0.50U 0. lOU 0.50U 1.0 U 0.50U 0.50U

0. SOU 0.50U 0.50U 1. 0 U 1.0 U

Vi = Volume of extract injected (uL) Vs = Volume of water exrracted (mL) Vt = Volume of total extract (mL) :-;s = Weight of sample extracted (g)

Vs = 500 mL Vt = 1.5 ml


Vi 5 u L Ws =

* * * * * * * ^ i ^ * * * * *

ryy]/i4jU * j r a t * * * * * sfc * * * * * *

cn PI >

o o

John J. Molloy, P.E. Laboratory Director

O O CP

l i2Ai LABS, INC. 575 BROAD HOCLOW ROAD. MELVILLE. NY 11747 • 516-694-3040


Town of Southampton hlampton Road Southampton, NY 11968

Sample Lab No. MW #1B

765571


1 1 ! RT I Estimated | C.A.S. ! 1 I « ! Concentration! Number 1 Compound Name 1 Fraction ! min i ug/1 !

!Unknown ! Pest !10.521! 0.53J ! 1 Unknown 1 Pest !11.150! 0.27J ! 1 Unknown 1 Pest !16.319! 0.76J ! 1 Unknown 1 Pest !17.329! 0.22J \ 1 Unknown 1 Pest 125.844 1 1.0 J

! ! ! ! 1

! : .._ I,...._... .1 _... _ - . 1 ! ! I 1 _. ,. L. ! ! I.._..._... .L - _ ...._ -.1 ! 1 1 . 1 ..._.... _. „„.._.;.

Date Reported: 01/07/88 : * * * *"ik * * * * *

)hn J. Molloy, P.E. Laboratory Director

cn PI >

o o

O O cn

ti!2M iC •AG! OF

LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melville, New York 11747-5076 • (516) 694-3040 LABORATORY

REPORT

r CLIENT'S NAME AND ADDRESS

Pilot Plant Studies and Other Analytical Services

TOWN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTOHi NY 119A8

PARAMETER RESULT

PARAMETER RESULT

TYPE OF SAMPLE - MISCELLANEOUS DATE COLLECTED - 12/ 7/87

MU tlB (13<10 HRS.) NORTH SEA LANDFILL FULL CLP t roc

PARAMETER RESULT

PARAMETER

LAB NO. 7A5572 PPn IFCT Mfl. CJMMP flAOf? 1 A

COLLECTED BY MH 03 DATE RECEIVED - 12/ 8/87

Rt:SULT 1

ANTIMONY

ARRFMir

1 BERYLLIUM

CADMIUM CHROM

IUM

COPPER

LEAD

MERCURY

NICKEL

<A0,0 t

< i n . n a

<5.00*

10.0 •

AO.O •

260.t

227. •^

0.50*

A O t O •

SELENIUM

PTI UFR THALLIUM

ZINC

IRON MANOA-ME8E DISS. AHTIM. DISS.

ARSENIC DIS BERYLLIUM

REMARKS - BILLS t REPOR"

ALL RESULTS IN (MQ/L) EXCEPT AS T.COLI BACT. f. FECAL COLI COLOR* ODORf TURBIDITY t. PH APC I FECAL STREP <COUNTS/»

L ' ^ ' " ' ' ^ ^f^^" ""«HOS) SETT

<S.OO*N)^

^'lO.ft «

<10.0 t

2A0.*

21000 •

S40.*

<A0.0 «

<10.0 •

<5.00*

rsiCLv

NOTtD BY • (MPN/IOOML) (UNITS)

ID ,SOLinS(ML/l

DISS. CADMIUM DISS.

rHROHt DIBS.

COPPER DISS* LEAD DISS.

MERCURY PISS. NICKEL DISS. SELEN. DISS.

SILVER DISS. THALL.

(UG/L) OR

.)

10.0 *

90.0 *

SO.O *

2i.o t<;

<0.20t

<40.0 #

<5.00»

<10.0 t

<10.0 •

Z (PERCENT

DISS. 7INC

DISS. TRON

DISS. MAHG.

CYANIDE

PHENOLS N02-N + N03-N

AMMONIA (HH3-N) T. DISS SOLIDS T. ORO. CARBON

) AND t —~^

• O.O t

370. •

<20.0 *

<10.0 #

<i.00t

<0.10

<0.02

200.

2.10

DATE REPORTED I/2B/88 |

LABORATORY DIRECTOR j

£900 300 V3S L BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

f i2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHEa McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765573 Date Collected: 12/07/87 Date Received: 12/08/87 Point: MW «1C Hr: 1530 North Sea Landfill

Date Anal: 12/1^/87 Conc./Dil. factor: 1.1 Cone: Low


Scan # C. A. S. Number ug/1

74-87-3 Chloromethane lOU 74-83-9 Bromomethane lOU 75-01-4 Vinyl Chloride lOU 75-00-3 Chloroethane lOU

131 75-09-2 Methylene Chloride 156 75-35-4 1,1-Dichloroethene 5U 75-34-3 1,1-Dichloroethane 5U 156-60-5 cis/trans-1,2-Dichloroethene 5U

228 67-66-3 Chloroform IJ 107-02-2 1,2-Dichloroethane 5U 75-69-4 Trichlorofluoromethane 5U 71-55-6 1,1,1-Trichloroethane 5U 56-23-5 Carbon tetrachloride 5U 75-27-4 Bromodichloromethane 5U 70-87-5 1,2-Dichloropropane 5U

10061-02-6 trans-l,3-Dichloropropene 5U 79-01-6 Trichloroethene 5U 124-48-1 Dibromochloromethane 5U 79-00-5 1,1,2-Trichloroethane 5U 71-43-2 Benzene 5U

10061-01-5 cis-1,3-Dichloropropene 5U 110-75-6 2-Chloroethylvinylether lOU 75-25-2 Bromoform 5U 127-18-4 Tetrachloroethene 5U 79-34-5 1,1,2,2-Tetrachloroethane 5U

458 108-88-3 Toluene 2J 1O8-90-7 Chlorobenzene 5U 100-41-4 Ethylbenzene 5U 541-72-1 1,3-Dichlorobenzene 5U 95-50-1 1,2-Dichlorobenzene 5U

106-46-7 1,4-Dichlorobenzene 5U

Date Reported: 12/31/87 j k r x a t t x s i : * * * * * * * * : * : * : *

in tn >

o o

lohn J. Molloy, P.E. Laboratory Director

O o CD

ti2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW «1C

765573


] C,,A.__S_,.. __...,1 Number | Compound Name 124-38-91 Carbon dioxide

1 Unknown I

1

1

t

1

1 1

1

1

1 1

1

t

1

1

1

\ t 1

1 1

1

I

% Probability Fit !RFit 100 1 74

— — _ -..

Scan 1 n , 16 , 49

Estimated 1 Concentration|

ug/1 : 12J,B 1

__,. 25J., B I

1 1 1 >

1 . 1 1

1 1 t

- • - - -

( » 1

1 1

- - - - -7

1 1 J-

_ • - -

1

1 t 1

- - - -

— - —

1

( t

1 1

i

1

1

'. 1 1

**************

Date Reported: 12/31/87 aohn J. Molloy, P.E. Laboratory Director

Ul PI >

O O

O O cn Ul

li2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Scan «

C . A . S .

Number 65-75 -9

108-95-2 111-44-4

95 -57 -8 541-73-1 106-46-7

9 5 - 5 0 - 1 39638329 b 621 -64 -7 N

6 7 - 7 2 - 1 98 -95 -3 7 8 - 5 9 - 1 8 8 - 7 5 - 5

105-67-9

N - N i t r o s o d i m e t h y l a m i n e Phenol b i s t 2 - C h l o r o e t h y l ) e t h e r 2 - C h l o r o p h e n o i 1 , 3 - D i c h l o r c b e n 2 e n e 1 , 4 - D i c h l o r o b e n z e n e 1 , 2 - D i c h l o r o b e n z e n e

i s ( 2 - c h l o r o i s o p r o p y l ) e t h e r - N i t r o s o - D i - n - P r o p y l a m i n e

Hexach lo roe thane N i t r obenzene Isophorone 2 - N i t r o p h e n o l 2 , 4 - D i i n e t h y l p h e n o l

Sample Lab Num Date C o l l e c t e d Date Rece i ved : Type: M i s c e l i a P o i n t : nu «1C No r th Sea Land Cone. F a c t o r : Date E x t : 12/0

C.A.S. u g / 1 Number lOU 83 -32 -9 lOU 51-28-5 lOU 100-02-7 lOU 121-14-2 lOU 606-20 -2 lOU 84 -66 -2 lOU 7005-72-3

1 1 1 - 9 1 - 1 b i s ( 2 - C h l o r o e t h e x y ) M e t h a n e 120-83 -2 2 , 4 - D i c h l o r o p h e n o l 1 2 0 - 8 2 - 1 1 , 2 , 4 - T r i c h l o r o b e n z e n e

9 1 - 2 0 - 3 Naphtha lene

ber 765573 : 12 /7 /87

12 /8 /87 neous

Hr : 1530 f i l l 500 Cone. : Low

lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

86-73-7 534-52-1 86-30-6

101-55-3 118-74-1 87-86-5 85-01-8

120-12-7 84-74-2

206-44-0 129-00-0

9/87 Date Anal: 12/18/87

Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2, 6-0initrotolL;ene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-riethylphenol N-Nitrososdiphcnylamine{l)

4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene

uo/1 lOU SOU SOU lOU lOU lOU lOU lOU SOU lOU

lOU lOU SOU lOU lOU lOU lOU lOU

Scan

87-68-3 Hexachlorobutadiene lOU 59-50-7 4-Chloro-3-l1ethylphenol lOU



91-S8-7 2-Chloronaphthalene lOU

131-11-3 Diaethyl Phthalate lOU


85-68-7 Butylbenzylphthalate lOU 91-94-1 3,3'-Dichlorobenzidine 20U 56-55-3 Ben2o(a)Anthracene lOU

117-81-7 bis(2-Ethylhexyl)PhthBlate 82B 218-01-9 Chrysene lOU 117-84-0 Oi-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2,3-cd)Pyrene lOU 53-70-3 Dibenzo(a,h)Anthracene lOU

191-24-2 Benzo(fl,h,i)Perylene lOU 92-87-5 Benzidine SOU



: « « X >

lohn J . M o l l o y , P.E. L a b o r a t o r y D i r e c t o r

1513

in tn

o o to

o o Ch

tw^ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040




765573


C.A.S. ! Number i Compound Name

!Unknown I Unknown

1

% Probability

Fit Scan

n 183 649

Estimated 1 Concentration!

ug/1 60J,B ! 42J !

1

t

t 1

1

I

1 t

1

I 1

1

1

I

1

1 1

1

1

1

1 1

( 1

1 1

i

r 1 1


* * * * * * * * * * * * * *

* *3r« * * * * * * * * * *

J«ihn J . M o l l o y , P.E, l l a b o r a t o r y D i r e c t o r

tn >

O O

o o

f i2Ai LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765573 Date Collected: 12/7/87 Date Received: 12/S/87 Type: Miscellaneous Point: MW #1C Hr: 1530 North Sea Landfill Concentration: Low Cone. Factor: 333 Date Ext. 12/09/87 Date Anal. 12/23/87

C.A.S. NUMBER

519-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Heptachlor Aldrin Heptachlor Epoxide Endosulfan I Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-DDD Endosulfan Sulfate 4,4'-DDT Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

of extract injected (uL) of water extracted (mL) of total extract (mL) of sample extracted (g)

us

0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0, 1, 1.

l / l

05U 05U 05U 05U G5U 05U 05U 05U lOU lOU lOU lOU-lOU , lOU , lOU SOU . lOU , SOU .0 U

. sou , sou . sou . sou .sou .0 u . 0 u

vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

************** * *

* X * * *

./6'ohn J. Molloy, P.E. Laboratory Director /

in PI >

o o Is)

o o cn CO

H2Ai LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765573 MW #1C

T e n t a t i v e l y I d e n t i f i e d Compounds

! 1 ! RT ! E s t i m a t e d 1 C . A . S . ! 1 ] !• ! C o n c e n t r a t i o n ! Number ! Compound Name I F r a c t i o n ! m i n ! u g / 1 |

!Unknown 1 P e s t ! 3 . 9 6 0 ! 0 . 4 7 J | 1 Unknown ! P e s t 115 .937 1 0 . 6 6 J 1 1 Unknown ! P e s t 1 1 9 . 2 9 1 ! 0 . 3 1 J ! :Unknown 1 P e s t 1 3 4 . 4 7 4 ! 0 . 6 6 J ! 1 ! ! ! 1 t I I I 1

1 1 1 1 1 1 ! 1 1 1 • 1 1 1 1 1 1 1 1 1 1 I I I 1 1 ,,.,. . , ! 1 1 1 1 I I I 1

... ... . 1 . _._ . t . „ 1 1 1 1 I I I 1

...J., _,. 1 ., ,. 1 1 1

1 I I I 1 _ 1 1 I I 1

1 I I I 1

! I 1 1 1 „. _... L _ .„ _. .. - - ! _.._ L... .....J.,... ___ .. .1

1 1 1 1 _ _i ._.... .- . ._. ..-_L ._ y 1 ...., ,.._ 1

D a t e R e p o r t e d : 0 1 / 0 7 / 6 8 )hn J . M o l l o y , P .E .

- a b o r a t o r y D i r e c t o r

U) PI >

O O to

O o ID

t i2A i l i 2 y H LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melville, New York 11 747-5076 • (516) 694-3040

Water/Waste Water Laboratory • Hazardous Waste Laboratorv • Air Testing Laboratory Pilot Plant Studiet and Other Analytical Services

,'AR.. OF

LABORATORY REPORT

LAB NO. 7A5f574

( CLIENTS NAME AND ADDRESS

TOWN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTON^ NY 11948

PARAMETER RESULT

PARAMETER RESULT


MU flC (1530 HRS.) NORTH SEA LANDFILL FULL CLP f. COC

PARAMETER RESULT

PARAMETER

COLLECTED BY VH 03 DATE RECEIVED - 12/ 8/87

RESULT

ANTIMONY

ARSENIC BERYL

LIUM

CAnMIUM CHROM

IUM

COPPER

LEAD

MERCURY

NICKEL

<A0.0 #

<10.0 •

<5.00*

.S. 00»

lflO.»

220.*

29.0 t

0.40f

120.t

SELENIUM

SILVER THALLIUM

7TNC

IRON HANSA-

NESE DISS.

ANTIM, DJ8S.


<50.0 \ ^ i ^

<10.0 •

<10.0 •

110.*

9100 *

220.*

<A0.0 t

<10.0 t

<5.00f

DISS. CADMIUM

DISS. CHROM. DISS.

COPPER DISS. LEAD

DISS. MERCURY

0188. NICKEL DISS.

SELEN. DI88*

SILVER DISS.

THALL.

REMARKS - BILLS % REPORTS:nLV

ALL RESULTS IH (MO/L) EXCEPT AS NOTED BY t (UG/L) OR T.COLI BACT. R FECAL COLI (MPN/IOOML) COLOR; ODOR» TURBIDITY \ PH (UNITS) APC f. FECAL STREP (COUNTS/ML)

"IMHOS) SETT.SOIIDSIMI./L)

<S.00#

<10.0 *

40.0 #

A.00*

<0.20*

<40.0 •

<5.00t

<10.0 •

<10.0 t

Z (PERCENT

DISS. ZINC

DISS* IRON

DISS. MANR.

CYANIDE

PHENOLS N02-N +

N03-N AMMONIA (NH3-N) T. DISS SOLIDS

T. ORO. CARBON

) AND

y ^ / y ^

30.0 #

lAO.t

<20.0 t

<10.0 *

3.00*

0.40

<0.02

140.

3.80

DATE REPORTED 1/28/88

LABORATORY DIRECTOR

OZOO 2 0 0 V3S '' '-'- BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

t i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER. McLENDON and MURRELL, PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES

Town of Southampton Sample Lab No. 765575 Hampton Road Date Collected: 12/07/87 Southampton, NY 11968 Date Received: 12/08/87

Point: Field Equip. Blank Hr: 1430 North Sea Landfill

Date Anal: 12/14/87 Conc./Dil. factor: 1.1 Cone: Low


Scan n C.A.S. Number ug/1

74-87-3 Chloromethane lOU 74-83-9 Bromomethane lOU 75-01-4 Vinyl Chloride lOU 75-00-3 Chloroethane lOU

131 75-09-2 Methylene Chloride 4JB 75-35-4 1,1-Oichloroethene 5U 75-34-3 1,1-Dichloroethane 5U 156-60-5 cis/trans-1,2-Dichloroethene 5U 67-66-3 Chloroform 5U 107-02-2 1.2-Dichloroethane 5U 75-69-4 Trichlorofluoromethane 5U 71-55-6 1, 1,1-Trichloroethane 5U 56-23-5 Carbon tetrachloride 5U 75-27-4 Bromodichloromethane 5U 70-87-5 1,2-Dichloropropane 5U

10061-02-6 trans-l, 3-Dichloropropene 5U 79-01-6 Trichloroethene 5U 124-48-1 Dibromochloromethane SU 79-00-5 1,1,2-Trichloroethane SU 71-43-2 Benzene 5U

10061-01-5 cis-1,3-Dichloropropene 5U 110-75-6 2-Chloroethylvinylether lOU 75-25-2 Bromoform 5U 127-18-4 Tetrachloroethene 5U 79-34-5 1,1,2,2-Tetrachloroethane 5U 108-88-3 Toluene 5U 108-90-7 Chlorobenzene 5U 100-41-4 Ethylbenzene 5U 541-72-1 1,3-Dichlorobenzene SU 95-50-1 1,2-Dichlorobenzene 5U 106-46-7 1,4-Dichlorobenzene 5U

cn Date Reported: 12/31/87 *«***x***x***** * ^

O O to

3hn J. Molloy, P.E. Laboratory Director O

O

HIM. LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. F i e l d B l a n k

765575


C.. A. S..„_ .., 1 Number 1 Compound Name

1 No Unknowns Found

% 1 1 E.sti mated 1 Probability! Scan 1 Concentration I Fit IRFit 1 n 1 ug/1 ! — 1 — 1 — 1 SU !

t i l 1 1 ( 1 1

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1 1 1 t

1 1 1

1 1 1 1 1 1 1 1 1

1 1 1

1 1 t

1 1 1 1 1 1 1 1 1

1 1 1 t 1 1 1 1 1 t 1 1 1 1 1

1 1 1

t 1 1 1 t 1

I 1 1 1 1 1 1 1 > 1 t 1

1 1 1 1 t 1 1 1

1 1 1

* * * * * * * * * * * * * *

D a t e R e p o r t e d : 1 2 / 3 1 / 8 7 in J . M o l l o y , P .E .

a b o r a t o r y D i r e c t o r

in m >

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t H H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Scan C. A .S . Number 6 5 - 7 5 -

108-95 -l l l - i . 6 . -

9 5 - 5 7 -5 4 1 - 7 3 -106-46 -

9 5 - 5 0 -39638329 621 -64 -7

6 7 - 7 2 -9 8 - 9 5 -7 8 - 5 9 -8 8 - 7 5 -

105 -67 -

N - N i t r o s o d i m e t h y l a m i n e Phenol b i s ( 2 - C h l o r o e t h y l ) e t h e r 2 - C h l o r o p h e n o l 1 , 3 - D i c h l o r o b e n z e n e 1 , 4 - D i c h l o r o b e n z e n e 1 , 2 - D i c h l o r o b e n z e n e

b i s ( 2 - c h l o r o i s o p r o p y l ) e t h e r N - N i t r o s o - D i - n - P r o p y l a m i n e 1 Hexach lo roe thane

N i t r obenzene I sophorone 2 - N i t r o p h e n o l 2 , 4 - D i m e t h y l p h e n o l

111 -91 -1 b i s ( 2 - C h l o r o e t h o x y ) M e t h a n e 120-83-2 2 , 4 - D i c h l o r o p h e n o l 120 -82 -1 1 , 2 , 4 - T r i c h l o r o b e n z e n e

91 -20 -3 Naphtha lene

Sample La Date C o l l Date Rece Type: Mis P o i n t : F i Nor th Sea Cone. Fac Date E x t :

C. A Num 83-5 1 -

100-1 2 1 -606-

84-7005-

86-534-

8 6 -

ug/1 lOU lOU lOU lOU lOU lOU lOU lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

b N ec t i v e ee l e l d

La t o r

12 . S . ber 32-2 8 -02 -14-20-6 6 -72 -73-52-30 -

uraber 765575 e d : 12 /7 /87 d : 12 /8 /87 laneous

Equipment Blank n d f i l l Hr ; 1430 : 500 Cone . : Lou / 0 9 / 8 7 Date A n a l ; 12/18/87

9 Acenaphthene 5 2,4-Dinitrophenol 7 4-Nitrophenol 2 2,4-Dinitrotoluene 2 2,6-Dinitrotoluene 2 Diethylphthalate 3 4-Chlorophenyl-phenylether 7 Fluorene 1 4,6-Dinitro-2-Methylphenol 6 N-Nitrososdiphenylamine (1)

101-55-3 4-Bromophenyl-phenylether 118-74-1 Hexachlorobenzene 87-86-5 Pentachlorophenol 85-01-8 Phenanthrene

120-12-7 Anthracene 84-74-2 Oi-n-Butylphthalate

206-44-0 Fluoranthene 129-00-0 Pyrene

ug/1 Scan lOU SOU SOU lOU ICU lOU lOU lOU SOU lOU

lOU lOU sou lOU lOU lOU lOU lOU

87-68-3 Hexachlorobutadiene lOU 59-50-7 4-Chloro-3-Methylphenol lOU

77-47-4 Hexachlorocyclopentadiene lOU 88-06-2 2,4,6-Trichlorophenol lOU

91-58-7 2-Chloronaphthalene lOU

131-11-3 Dimethyl Phthalate lOU 208-96-8 Acenaphthylene lOU

85-68-7 Butylbenzylphthalate lOU 91-94-1 3,3'-Dichlorobenzidine 20U 56-55-3 Benzo(a)Anthracene lOU

117-81-7 bis(2-Ethylhexyl)Phth8late 360B 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2,3-cd)Pyrene lOU 53-70-3 Dibenzo(a,h)Anthracene lOU

191-24-2 Benzo(g,h,i)Perylene lOU 92-87-5 Benzidine 8DU

(1) - Cannot be separated •froin diphenylamine


x x x x x x x x x x x x x x

ôhn J . M o l l o y , P.E. l a b o r a t o r y D i r e c t o r

1516

Ul PI >

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m \ J u ^ \ LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL. PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765575 Field Equipment Blank


1 1 * 1 ! Estimated ! C.A.S. 1 !Probability 1 Scan 1 Concentration! Number I Compound Name 1 Fit 1 « ! ug/1 1

1 Unknown 1 ! 183 ! 15J,.B . ._ ! 2196449811,13-Tetradecadiene I 89 | 1246 1 190J ! 190478591Phosphonic acid 1 1 1 1

1 dioctadecyl ester 1 71 ! 1263 ! 12J I

I I I I 1

" 1 I I I 1

***:x*A*>lc3«:*:***:*

Date Reported: 01/05/88 lohn J. Molloy, P.E. Laboratory Director

PI >

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rdM LABS, INC. 575 BROAO HOLLOW ROAO, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765575 Date Collected: 12/7/87 Date Received: 12/8/87 Type: Miscellaneous Hr: 1430 Point: Field Equipment Blank North Sea Landfill Concentration: Low Cone. Factor: 333 Date Ext. 12/09/87 Date Anal. 12/23/87

C.A.S. NUMBER

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


alpha-BHC beta-BHC delta-BHC gamma-BHC Heptachlor Aldrin Heptachlor Endosulfan Dieldrin 4,4'-DDE Endrin Endosulfan 4,4'-ODD Endosulfan 4,4'-DDT Methoxychl Endrin Ket Chlordane Toxaphene

(Lindane)

Epoxide I

II

Sulfate

or one

Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

of extract injected (uL) of water extracted (mL) of total extract (mL) of sample ex tracted (g)

us

0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1, 1.

l / l

05U 05U 05U 05U 05U 05U 05U 05U lOU lOU lOU lOU lOU , lOU , lOU SOU , lOU

.sou ,0 u sou , sou , sou , sou , sou .0 u .0 u

Vs = 500 mL Vt = 1.5 ml


V i = 5 u L Ws =

* * * * * * * * * * * * * *

ihMM^

g

^fcihn J . M o l l o y , P . E . ' ' L . a b o r a t o r y D i r e c t o r

cn tn

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cn

li!2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040


Town of Southampton hiampton Road Southampton, NY 11968



1 1 1 RT 1 Estimated I C.A.S. 1 1 I t t ! Concentration! Number 1 Compound Name 1 Fraction 1 min 1 ug/1 1

1 No Unknowns Found 1 Pest 1 — 1 0.2U !

- - \ - - - |-- -| 1 " - -- ••— \


**************

* a b * * * * * * * * * * * *

:fh )hn J. Molloy, P.E. Laboratory Director

CO PI

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WilM. l i 2 y H LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melville, New York 11747-5076 • (516) 694-3040

Water/Waste Water Laboratory • Hazardous Waste Laboratory • Air Testing Laboratory Pilot Plant Studies and Other Analytical Services

iPAC 01

LABORATORY REPORT

LAB NO. 7A5f57& p p n iFPT > jn . PUMP P A n ^ i A _


TOWN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTONf NY 11948

TYPE OF SAMPLE - MISCELLANEOUS COLLECTED BY VH 03 DATE COLLECTED - 12/ 7/B7 DATE RECEIVED - 12/ 8/87

FIELD EQUIPMENT Bl ANK <M:<0 HRS.) NORTH SEA LANDFILL FULL CLP f. COC

PARAM-ETER RF.3ULT

PARAM-ETER RESULT

PARAM-ETER RESULT

ANTIMONY <A0.0 t

SELEN- T. DISS lUM <5»Q0tMe SOLIDS 00

ARSENIC <I0.0 • SILVER <10.0 % T. ORO* CARBON <0*05

BERYL-LIUH < f i ^ O O *

THAL-LIUM < X f l t ^ t

AMMONIA (NH3-N? <0.Q2

CADMIUM <5.00* ZtNC ?0.0 » CHROM-

liiil <10.Q * IRON 180«t

COPPER 80.0 t HAHOA-

HESE <20.0 •

LEAD 10.0 * CYANIDE <10.0 t

MERCURY <0.20» PHENOLS <1.00#

NICKEL <40.0 t N02-N +

NU3-N <0.10

REMARKS - BILLS ?. REPORTS :CLV

ALL RESULTS IN (MR/L) EXCEPT AS NOTED BY f (UG/L) OR Z (PERCENT) AND r.COLI BACT. f. FECAL COLI (MPN/IOOML) COl.ORi ODOR» TURBIDITY R PH (UNITS) • " 9. FECAL STREP (COUNTS/ML)

MOS) SETT.SOLIDS(MI /L) ^ ^ 0 0 3 0 0 V3S

DATE REPORTED l / 2 f l / B B

L BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

li!2Ai LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL. P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765577 Date Collected: 12/07/87 Date Received: 12/08/87 Point: Trip Blank North Sea Landfill



Scan « C A . S. Number

74-74-75-75-75-75-75-

156-67-

107-

-87--83--01--00--09-•35--34-•60--66--02-

75-69-71--55-56-23-75-70-

10061-79-

124-79-

310 71-10061-

110-75-

127-79-

108-108-100-541-95-

106-

-27--87--02--01--48--00--43--01--75--25--18--34--88--90--41--72--50--46-

• 3

• 9

• 4

-3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1, l-Trichloroeth'ane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,S-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/l

lOU lOU lOU lOU 5U 5U 5U 5U 5U 5U 5U 5U 5U 5U SU 5U SU 5U 5U

IBJ SU lOU SU SU 5U 5U 5U 5U 5U 5U SU


* * A * X X *

fohn J. Molloy, P.E. Laboratory Director

CO tn >

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H2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL, PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. Trip Blank

765577


C.A.S. ! Number ! Compound Name

!Unknown

1 1

;

% !.,. , Probability! Scan _ Fit IRFit l' "# — 1 — 1 49

1 1 1 1

1

1 t

1 1

1 t

1 t

1

1 1 1

1

1

1

1

1 1

1 I

1 1

1 1

1 t

1

1

1

1 1

( ( 1 1 1 1

Estimated | Concentration 1

ug/1 1 16J,B 1

I

1

1 1 1

1

1 1 1 1

1 r t 1

1 1

1 I

1

1 1 1 1

1

1

1 t 1 1

1

**«***»;****x**

Date Reported: 12/31/87 )hn J. Molloy, P.E.

'Laboratory Director

in PI >

O O

o o 10

H^M LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765608 Date Collected: 12/08/87 Date Received: 12/09/87 Point: MW «6 Hr: 0930 North Sea Landfill



Scan tt C.A.S. Number ug/1

74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 75-35-4 75-34-3

156-60-5 67-66-3

107-02-2 75-69-4 71-55-6 56-23-5 75-27-4 70-87-5

10061-02-6 79-01-6

124-48-1 79-00-5 71-43-2

10061-01-5 llD-75-6 75-25-2

127-18-4 79-34-5

444 108-88-3 108-90-7 100-41-4 541-72-1 95-50-1

106-46-7

Chloromethane lOU Bromomethane lOU Vinyl Chloride lOU Chloroethane lOU Methylene Chloride 5U 1,1-Dichloroethene 5U 1,1-Dichloroethane 5U cis/trans-1,2-Dichloroethene 5U Chloroform 5U 1,2-Dichloroethane 5U Trichlorofluoromethane 5U 1,1,1-Trichloroethane 5U Carbon tetrachloride 5U Bromodichloromethane 5U 1,2-Dichloropropane SU trans-l,3-Dichloropropene 5U Trichloroethene SU Dibromochloromethane 5U 1,1,2-Trichloroethane 5U Benzene 5U cis-1,3-Dichloropropene 5U 2-Criloroethy Iviny lether IDU Bromoform 5U Tetrachloroethene 5U 1,1,2,2-Tetrachloroethane 5U Toluene 2J Chlorobenzene 5U Ethylbenzene 5U 1,3-Dichlorobenzene SU 1,2-Dichlorobenzene 5U 1,4-Dichlorobenzene 5U


^ John J. Molloy, P.E Laboratory Director

CO tn

o o to

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o

m \ M J ^ \ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. MW «6

765608


C.A.S.

• "

"

Compound Name No Unknowns Found

~ - - —

1 % 1 1 Probability 1 1 Fit IRFit I

1 1 1

1 1 •

1 1

1 1

1 1

1 1

1 1

Scan 1 n ! — 1

.

" 1 1 _ ; :"• 1 _ . L.

""" ^T'""' 1 . _ . . . ; . . 1 ! 1 I 1 1 1 1 .. L 1 1 L

"' Y" 1 1

' "

1

1

1

1

1

1

1

1 1 . .._.

1 ... _...i

t

1

Estimated 1 Concentration 1

llu9/l...l .' .....L 5U 1

( 1

1 I

t t

1

I

1 t

1 1

1 I

I

1

... . . - '-1 1

1 _. ^ t...

1 „ _ . '..

1 1

1

1 I

1 1

' - ..-.- - .- - - .- '-1 1

1 1

1 1

1 1 1 1

1 „ _.. -.. ~ —'-

* » ! X * * « * « » * « « * *

Date Reported: 12/31/87 yohn 3. Molloy, P.E. Laboratory Director

CD PI >

O O

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m l J L J ^ \ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Scan i

C.A.S. Number 65-75-9

108-95-2 1 1 1 - 4 4 - 4

95-57-8 5 4 1 - 7 3 - 1 106-46-7

9 5 - 5 0 - 1 39638329 b 621-64-7 N

6 7 - 7 2 - 1 98 -95-3 7 8 - 5 9 - 1 88 -75 -5

105-67-9

N - N i t r o s o d i a e t h y l a m i n e Phenol b i s ( 2 - C h l o r o e t h y l ) e t h e r 2 - C h l o r o p h e n o l l , 3 - D i c h l o r o b e n 2 e n e 1 ,4 -D i ch l o robenzene 1 ,2 -D i ch l o robenzene

i s ( 2 - c h l o r o i s o p r o p y 1 ) e t h e r N i t r o s o - D i - n - P r o p y l a m i n e

Hexach lo roe thane N i t r obenzene I sophorone 2 - N i t r o p h e n o l 2, 4 - D i i i i e t h y l p h e n o l

Sample Lab Num Date C o l l e c t e d Date R e c e i v e d : Type: M i s c e l i a P o i n t : riW «6 N o r t h Sea Land Cone. F a c t o r : Date E x t : 12 /1

C .A .S . u g / 1 Number lOU 83 -32 -9 lOU 5 1 - 2 8 - 5 lOU 100-02-7 lOU 121-14 -2 lOU 606 -20 -2 lOU 8 4 - 6 6 - 2 lOU 7005 -72 -3

111 -91 -1 b i s ( 2 - C h l o r o e t h o x y ) r i e t h a n e 120-83-2 2 , 4 - D i c h l o r o p h e n o l 120 -82 -1 1 , 2 , 4 - T r i c h l o r o b e n z e n e

91-20-3 Naphtha lene

ber 765608 : 12/8/S7

12 /9 /87 neous Hr: 0930 f i l l 500 Cone. : Low 1/87 Date Anal: 12/16/87

Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Oinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether

lOU 86-73-7 Fluorene lOU 534-52-1 4,6-Dinitro-2-riethylphenol lOU 86-30-6 N-Nitrososdiphenylamine(l) lOU lOU 101-55-3 4-Bromophenyl-phenylether lOU 118-74-1 Hexachlorobenzene lOU 87-86-5 Pentachlorophenol

85-01-8 Phenanthrene lOU 120-12-7 Anthracene lOU 84-74-2 Oi-n-Butylphthalate lOU 206-44-0 Fluoranthene lOU 129-00-0 Pyrene

uo/l Scan lOU SOU SOU lOU lOU lOU lOU lOU sou lOU









117-81-7 bis(2-Ethylhexyl)Phthalate 828 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2,3-cd]Pyrene lOU 53-70-3 Dibenzo(a,h)AnthrBcene lOU

191-24-2 Benzo(g,h,iJPerylene lOU 92-87-5 Benzidine SOU

1516

(1) Cannot be separated f r o m diphenylamine

Date Reported; 01/05/88

X * X X * * * » * * * * * *

ViidJîfyrmnr rohn J . Mo l l oy , P.E.

' L a b o r a t o r y D i r e c t o r

cn PI >

O O




Sample Lab No, MW «6

765608


1 1 % ! 1 E s t i m a t e d 1 C . A . S . 1 1 P r o b a b i l i t y 1 Scan ! C o n c e n t r a t i o n ! Number 1 Compound Name 1 F i t 1 tt 1 u g / 1 1

!Unknown 1 1 185 ! 6 6 J , B I 142621 I H e x a n o i c a c i d I 60 I 671 2 1 9 6 4 4 9 8 ! 1 , 1 3 - T e t r a d e c a d i e n e 1 93 ! 1248

1 l O J 1 1 4 6 J , B 1

1 1 1 1 1 1 I I I 1

1 I I I 1 1 1 1 I 1 1 1 1 1 1 1 1 1 . 1

_^. _. :i _ - 1 - _ _ .1

Date Reported: 01/05/88 * if *Â * * * * * * * * * *

ohn J- Molloy, t p. E. aboratory Director

cn PI >

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m r \ j t / ^ \ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765608 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «6 Hr : 0930 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBER

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5



of extract injected (uL) of water extracted (mL) of total extract (mL) of sample extracted (g)

ug/1

0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 1.

05U 05U 05U 05U 05U 05U 05U 05U lOU lOU lOU . lOU lOU lOU lOU SOU lOU sou 0 u sou sou sou sou sou 0 u 0 u

Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =•

**************

3^r^ J. Molloy, P.E. Laboratory Director

cn PI >

o o

O O CD

ti2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765608 MW «6


1 1

Number 1 Compound Name ! Fractio

1 RT 1 Estimated 1 1 # 1 Concentration!

1 1 min 1 ug/1 1 1 No Unknowns Found 1 Pest i — 1 0-2U 1 r 1

1 1 1 1 _ . 1 1

\ - - • - - | — — ;

1 I I I ( 1 1 1 1 1

1 1 1 . t ... 1

1 ! ! ! 1 t I I I 1

1 . , , , . ! „ ,, ,' ' ,.,, .,. !

I I I I J I I I I t

1 I I I t

t .,. .,! . ,, ,, ,, », ,, , ' , '

I I I I t

I I I I 1

1 I I I J

1 . ..... . , ..i ....._ _ 1 .J. __L 1 . ... .._ : _ ! 1 ._ L 1 I I I 1

1 1 1 1 1

**************

,o . Date Reported: 01/07/88 J, :************

.ôhn J. Molloy, P.E. Laboratory Director

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ran. l i 2 y H LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melvil le, New York 11747-5076 • (516) 694-3040

Water/Waste Water Laboratory • Hazardous Waste Laboratory • Air Testing Laboratory

•A(J OF

LABORATORY REPORT

f CLIENT'S NAME AND ADDRESS


TOWN OF HOUTHAMPTON

HAMPTON ROAD

S O U T H A H P T O H J NY 1 1 9 A 8

PARAMETER RESULT

PARAMETER RESULT

TYPE OF SAMPLE - MISCELLANEOUS DATE COLLECTED - 1 2 / B / B 7

MW t A (09;<0 H R S . ) NORTH SEA L A N D F I L L F U L L CLP R COC

PARAMETER RESULT

PARAMETER

LAB HO, 7Ar jA09 PR-n I F n M A . ejHMP RAO'^ 1 {

COLLECTED BY VH O i ^ DATE R K C E I V F D - 1 2 / ? / f i 7

RESULT

A N T I MONY

ARSENIC B E R Y L

L I U M

C A r i H T I I M

CHROMIUM

COPPER

LEAD

MERCURY

N I C K E L

< A 0 . 0 #

< 1 0 . 0 •

< 5 . 0 0 »

1 0 . 0 *

SO.O ft

1 3 0 • •

i M . O t

0 , 7 0 *

AO.O «

S E L E N IUM

S I L V E R T H A L

L I U M

• / INC

IRON HANRA-

NFSE D I S S .

A N T I M , D I S S .

ARSENIC D I S B E R Y L L I U M

REMARKS - D H L S 8 REPOR

ALL RESULTS I N ( M f i / L ) EXCEPT AS T . n U L I BACT. f. FECAL C O L I COLORi UDORf T U R D I D I T Y f. PH APC ?. FECAL STREP ( C O U N T S / I

••MHOS) SETT

D I S S . < f 5 0 . 0 t l O e CADMIUM

< 1 0 . 0 »

< 1 0 . 0 t

flO.O ft

l A S O O »

8 5 0 , •

< A 0 . 0 t

< 1 0 . 0 i

< : ) . 0 0 t

rs:ci. V

NOTKD BY » ( M P N / I O O M L )

( U N I I S ) i l ) .sni.U'fjtfu./

D I S K . CHROM.

D I S S . COPPER

D I S S , t F A D

D I S S . MERCURY

D I S S . N I C K E L

D I S S . S E L E N .

S I L V E R D I S S .

T H A L L .

< 5 . 0 0 #

< 1 0 . 0 *

550,0 *

^ S . O O *

< : o . 5 0 *

<no.o •

< 5 . 0 0 *

< 1 0 . 0 •

< 1 0 , 0 •

( U O / L ) OR Z (PERCENT

D I S S . Z I N C

D I S S . IRON

D I S S . MANG.

CYANIDE

PHFMOI S N 0 2 - N +

HO.T-N AMMONIA ( N H 3 - N )

r. Diss S O L I D S

T . ORO. CARBON

) AND

Ti

1 0 . 0 t

1 7 0 . •

1 9 0 . #

< 1 0 . 0 ft

< 1 . 0 0 *

7 . A 0

0 . 0 6

2 1 0 .

1 0 . 4

DATE REPORTED 2 / 5 / 8 8

LABORATORY DIRECTOR

9 9 0 0 2 0 0 V3S lALL BE UMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

l i2Ai LABS, INC. 575 BROAO HOLLOW ROAO. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765610 Date Collected: 12/08/87 Date Received: 12/09/87 Point: MW #2 Hr: 1100 North Sea Landfill




74-74-75-75-75-75-75-

156-67-

107-75-

252 71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

108-108-lOO-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--00--45--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-ChloroethyIvinyletner Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/1

lOU lOU lOU lOU 5U 5U 5U 5U 5U 5U 5U 9

5U 5U 5U 5U 5U 5U 5U 5U 5U

lOU 5U 5U 5U 5U 5U 5U 5U 5U 5U


JpHn J . Molloy, P.E. Laboratory Director

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li2M LABS, INC. 575 BROAO HOLLOW ROAO, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW «2

765610


1 1 * 1 __ 1 ^ Est . imated I C.A.S. 1 1 P r o b a b i l i t y 1 Scan 1 C o n c e n t r a t i o n ' , Number 1 Compound Name 1 F i t

I No Unknowns Found I 1 1 1 1

1 I

RFi t 1 « 1 u g / l 1 — I — ! 5U 1

1 1 1

1 I 1

1 I I I 1

1 l i t 1 1 I I I 1 1 I I I 1 1 I I I 1

1 I I I 1 1 I I I 1 1 I I I ( 1 I I I 1 1 I I I 1 1 I I I 1 1 1 ( 1 1 1 I I I r 1 I I I 1 t I I I t 1 I I I 1 1 I I I 1 1 I I I 1

1 1 1 1 1 1 I I I 1

1 I I I 1

1 I I I 1 1 1 1 1 1

I I ! 1 1 1 1 ! 1 1 _ .1

• 1

1 1

- • • - \ - ; - - \

D a t e R e p o r t e d : 1 2 / 3 1 / 8 7

* * * * * * * * * * * * * *

* * . * . * . * . - k * » m * . * .


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H2Ai LABS, INC. 575 BROAO HOLLOW ROAD. MELVILLE, NY 11747 • 516-694-3040


Town of Southaapton Hampton Road Southampton, NY 11968

Saaple La Date C o l l Date Rece Type: Mis P o i n t : nu Nor th Sea Cone. Fac

Scan C.A.S. Number 65 -75 -

108-95-1 1 1 - 4 4 -

9 5 - 5 7 -5 4 1 - 7 3 -106-46-

9 5 - 5 0 -39638329 621 -64 -7

6 7 - 7 2 -9 8 - 9 5 -7 8 - 5 9 -8 8 - 7 5 -

105-67-

N - N i t r o s o d i m e t h y l a m i n e Phenol b i s ( 2 - C h l o r o e t h y l ) e t h e r 2 - C h l o r o p h e n o l 1 , 3 - D i c h l o r o b e n z e n e 1 , 4 - D i c h l o r o b e n z e n e l , 2 - D i c h l o r o b e n 2 e n e

b i s ( 2 - c h l o r o i s o p r o p y l ) e t h e r N - N i t r o s o - D i - n - P r o p y l a m i n e 1 Hexach lo roe thane

N i t r o b e n z e n e I sopho rone 2 - N i t r o p h e n o l 2 , 4 - D i m e t h y l p h e n o l

111 -91 -1 b i s ( 2 - C h l o r o e t h o x y ) M e t h a n e 120-83-2 2 , 4 - D i c h l o r o p h e n o l 120 -82 -1 1 , 2 , 4 - T r i c h l o r o b e n z e n e

91 -20 -3 Naph tha lene

Date

u g / 1 lOU lOU lOU lOU lOU lOU lOU lOU lOU IQU lOU lOU lOU lOU

lOU lOU lOU lOU

E x t : C A Num 83-5 1 -

1 0 0 -1 2 1 -606-

84 -7005-

8 6 -534-

8 6 -

1 0 1 -118-

87-85-

120-84-

206-129-

b N ec t i v e e e l

tt2 La

t o r 12

. S . ber 32 -2 8 -0 2 -14-20 -66 -7 2 -73 -52 -3 0 -

umber 765610 e d : 1 2 / 8 / 8 7 d : 1 2 / 9 / 8 7 l aneous

Hr : 1100 n d f i l l : 500 Cone.: /ll, 12/18/87

Low Date Anal: 12/16,

9 Acenaphthene 5 2,4-Dinitrophenol 7 4-Nitrophenol 2 2,4-Dinitrotoluene 2 2,6-Dinitrotoluene 2 Diethylphthalate 5 4-Chlorophenyl-phenylether 7 Fluorene 1 4,6-Dinitro-2-Methylphenol 6 N-Nitrososdiphenylamined)

55-3 4-Broaopheniyl-phenylether 74-1 Hexachlorobenzene 86-5 Pentachlorophenol 01-8 Phenanthrene 12-7 Anthracene 74-2 Di-n-ButylPhthalate 44-0 Fluoranthene 00-0 Pyrene

12/18/87

ug/1 Scan lOU sou sou lOU lOU lOU lOU lOU SOU lOU


i l )


77-47-4 Hexachlorocyclopentadiene lOU 88-06-2 2,4,6-Trichlorophenol lOU


131-11-3 Diaethyl Phthalate lOU 208-96-8 Acenaphthylene lOU


85-68-7 Butylbenzylphthalate lOU 91-94-1 3,3'-0ichlorobenzidine 20U 56-55-3 Benzo(a)Anthracene IQU

117-81-7 bis(2-Ethylhexyl)Phthalate 30B 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2,3-ed)Pyrene lOU 53-70-3 Dibenzola,h)Anthracene lOU

191-24-2 Benzo(g,h, DPerylene lOU 92-87-5 Benzidine SOU

Cannot be separated from diphenylamine


: x x x x x x x x x

Shn J . M o l l o y , P.E. O-aboratory D i r e c t o r

1514

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f U M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. MW tt2

765610


1 l_ % I 1 Estimated 1 C.A.S. 1 1 Probability 1 Scan ! Concentration! Number 1 Compound Name \ Fit 1 # 1 ug/1 1 P3794 Base/Neutral 1 1 1 !

1 Unknown 1 ! 71 ! 88J ! 1 Unknown 1 1 184 1 56J,B ! I Unknown 1 | 235 1 130J I 1 Unknown 1 1 358 ! 26J 1

219644981 1,13-Tetradecadiene 1 99 I 1247 ! aOJ,B 1

P3816 Acid 1 1 ! 1 629992 iPentacosane | 86 1 1203 1 22J 1 143282 1(z)-9-Octadecen-l-011 78 1 1242 1 46J |

1 Unknown 1 ! 1342 1 28J 1 1 Unknown I I 1441 ! 16J 1 I Unknown 1 1 1498 1 20J 1 1 Unknown 1 1 1546 1 24J 1

630079 1Pentatriacontane 1 86 I 1559 1 40J 1 630068 IHexatriacontane 1 78 1 1593 1 20J 1

1 Unknown 1 1 1639 1 36J 1 1 Unknown 1 ! 1781 ! 22J 1

3 i ; A A * A 7 k A > l c ] i c 9 i c > k ? t 3 k 3 k

Date Reported: 01/05/88 X * * * « « >c X » »

ohn J. Molloy, P.E. aboratory Director

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Sample Lab No. 765610 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «2 Hr: 1100 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor; 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U^ O. lOU O. lOU 0. l O U ^ 0. lOLT O. lOU O. lOU 0. lOU O. SOU O. lOU 0.50U 1.0 U

o. sou 0. sou 0. sou 0. sou 0.50U 1. 0 u 1.0 u

Vi = Volume of extract injected (uL) Vs « Volume of water extracted (mL) Vt = Volume of total extract (mL) Ws = Weight of sample extracted (g)

Vs = 500 mL Vt = 1.5 ml


V i = 5 u L Ws =

> » : > l : » : * * : * * > c * > i r * * * *

•irw. w A^r*: 3r$*3ic * * ;

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^4ohn J. Molloy, P.E. Laboratory Director

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rnlMJ^m LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765610 MW #2


C.A.S. Number

• — • •

-

i ' 1 1

1 1 1 1

1 Compound Name 1 !Unknown 1 1 1 1 1 1 1 1 J 1 1 1 1

[ 1 1 1

1 1

1 „....»

1 1

1 1

1 1

t 1

1 1

1

t 1

Fraction Pest

~

- - — — -

- - • • — - - -

1 RT ! _.Ejs.t.i,mated 1. 1 *t !_Concentrat ion 1 1 min 1 ug/1 1

1 5.21 ! 0.4J 1 1 1 1

1 1 1. 1 1 I 1 i ! 1 1 1

1 1 1 1 1 1 1 1 1

...1 . . . . 1 ._ .!..

1 1 1

1 1 1 1 1 L. 1 1 1 1 1 1

1 1 1 1 1 1

1 1 1 1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 1 1

1 1 1 1 1 1 1 t 1

1 1 1 1 1 1 1 1 1 1 1 1. 1 1 1

• , .- - !...

*

Date Reported: 01/07/88 lUlM

* * * * * * * * * * * * * x

•2oHr\ J . M o l l o y , P .E . t L a b o r a t o r y D i r e c t o r

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t U M t i M i LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melvi l le, New York 11747-5076 • (516) 694-3040


•A(> OF

LABORATORY REPORT

LAB NO, 7656X1 PRn.lFHT Mni SHriP RftQS UL.,


TOWN OF HOUTH/^MPTON

HAMPTON ROAD

SOUTHAMPTONf NY XX96B


MW f'A (1100 HRS.) NORTH SEA LANDFILL FULL CLP t, COC

COLLECTED BY </H 03 DATE RECEIk'ED - 12/ 9/87

PARA 5-ETER RESULT

PARAM-ETER RESULT

PARAM-FTER RtvSUl.T

PARAM-t.TRR REPUI-T

ANTI-MQNY <;6Q>Q t

SELEN- DISS. lUM <5<).0 tffc" CADMIUM 20.0 •

DISK. ZINC llO.t

ARSENIC <1Q.Q t SILVER DISS.

70.0 • CHROM. S30.* DISS. IRON 22300 *

BERYLLIUM <'o>00f

THALLIUM •ooo.t

DISS. COPPER 8H0.«

DISS. HANG. 1100 *

CADMIUM 20 >0 • ZINC 110.» DISS. LEAD IAS.* CYANIDE -e S>5C0 • CHROM-

*720 • iR\m ^?.7f>f) t DISS.

MERCURY O.BO» PHENOLS <i.OOt

COPPER BOO.t MANGA- DISS. N02-N + NESE -1900 f NICKEL 200.• N03-N .1,40

LEAD DISS.

254. fS ANTIM. <60.0 f DISS.

SELEN. <!).00t AMMONIA <HH3-N) 0. 25

MERCURY 1.30» DISS.

ARSENIC <1Q.0 # DISS. SILVER 30.0 f

T. DISS SOLIDS 4.60%

NICKEL 150.t DIS BERYLLIUM :5.00#

DISS. THALL. <100,*

T. ORG. CARBON 7,30

REMARKS - BILLS % REPORTSICLV

ALL RESULTS IN (MG/L) EXCEPT AS NOTED BY * (UO/L) UR X (PERCENT) AND T.COLI BACT. I FFCAL COLI (MPN/IOOML) COLOR* ODORf TURBIDITY f. PH (UNITS) APC t, FFCAL STREP (COUNTS/ML)

__ - ^..Muos) SFTT.SOI . IDS(ML/L> THl C600 200 V3S IE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

DATE REPORTED 2/ 5/RR

H2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765612 Date Collected: 12/08/87 Date Received: 12/09/87 Point: MW «4C H r : 1610 North Sea Landfill



Scan » C. A.S. Number ug/1

450

74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 75-35-4 75-34-3

156-60-5 67-66-3

107-02-2 75-69-4 71-55-6 56-23-5 75-27-4 70-87-5

1OO61-02-6 79-01-6

124-48-1 79-00-5 71-43-2

10061-01-5 110-75-6 75-25-2

127-18-4 79-34-5

108-88-3 108-90-7 100-41-4 541-72-1 95-50-1

106-46-7

Chloromethane lOU Bromomethane lOU Vinyl Chloride lOU Chloroethane lOU Methylene Chloride 5U 1,1-Dichloroethene 5U 1,1-Dichloroethane 5U cis/trans-1,2-Dichloroethene 5U Chloroform 5U 1,2-Dichloroethane 5U Trichlorofluoromethane 5U 1, 1,1-Trichloroethane 5U Carbon tetrachloride 5U Bromodichloromethane 5U 1,2-Dichloropropane 5U trans-l,3-Dichloropropene 5U Trichloroethene 5U Dibromochloromethane 5U 1,1,2-Trichloroethane 5U Benzene 5U cis-1, 3-Dichloropropene 5U 2-Chloroethylvinylether lOU Bromoform 5U Tetrachloroethene 5U 1,1, 2, 2-Tetrachloroethane 5U Toluene 2J Chlorobenzene 5U Ethylbenzene su 1,3-Dichlorobenzene SU 1, 2-Dichlorobenzene 5U 1,4-Dichlorobenzene 5U

Date Reported: 12/31/87 :***************

>r» Ue^<.1^ * * * * *

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7ohn J. Molloy, P.E. Laboratory Director O

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H2Ai LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765612 MW «4C


C, A. S._ Number

Probability! Scan _ (^mpound_ Name No Unknowns Found

Fit RFit

Est i m a t e d j

..Qpn9..!rX'.?.EMt,i.ODJ LJS./J. I

5U


X *

;rohn J. Molloy, P.E. 'Laboratory Director

CO

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H2M LABS, INC. 575 BROAO HOLLOW ROAD. MELVILLE, NY 11747 • 516-694-3040



Scan

i

C.A.S. Number 65-75-9 108-95-2 111-44-4 95-57-8

541-73-1 106-46-7 95-50-1

39638329 bi 621-64-7 N-

67-72-1 98-95-3 78-59-1 88-75-5 105-67-9

N-Nitrosodimethylaaine Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1, 3-Dichlorobenzene 1,4-Oichlorobcnzene 1,2-Dichlorobenzene

s(2-chloroisopropyllether Nitroso-Di-n-Propyl amine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-DiBethylphenol

Sample La Date Coll Date Rece Type: Mis Point: MW North Sea Cone. Fac Date Ext:

C. A Num 83-51-

100-121-606-84


ug/1 ICU lOU lOU lOU lOU lOU lOU 7005-lOU lOU lOU lOU lOU lOU lOU

lou-lOU lOU lOU

86-534-

86-

101-118-67-

85-120-84-

206-129-

b Numb ected: ived: cellan

i4C Landf

tor: 5

12/11 .S. ber 32-9 28-5 02-7 14-2 20-2 66-2 72-3 73-7 52-1 30-6

55-3 74-1 86-5 01-8 12-7 74-2 44-0 00-0

er 765612 12/8/87

12/9/87 ecus Hr: 1610 ill 00 Cone. : Low /87 Date Anal: 12/16/87

Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-Methylphenol N-Nitrososdiphenylamine(l)


Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene

Di-n-Butylphthalate Fluoranthene Pyrene

ug/1 Scan lOU SOU SOU lOU lOU lOU lOU lOU SOU

lOU


87-68-3 Hexachlorobutadiene lOU 59-50-7 4-Chloro-3-Hethylphenol lOU








85-68-7 Butylbenzylphthalate lOU 91-94-1 3,3'-Dichlorobenzidine 20U

56-55-3 Benzo(a)Anthracene lOU

117-81-7 bis(2-Ethylhexyl)Phthalate 380B 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)FluorBnthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU 193-39-5 Indeno(l.2,3-cd]Pyrene lOU 53-70-3 Dibenzo(a,h)Anthracene lOU 191-24-2 Benzo(g.h,i )Perylene lOU 92-87-5 Benzidine 80U

//John J. Molloy, P.E, Laboratory Director

1517

CO tn >

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o o cn

WilH LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765612 MW «4C


1 ! % 1 C . A. S. 1 1 F'rpbabi IJLt_y„l. Number 1 Compound Name 1 Fit 1

1 Unknown 1 _ !_ 2196449811,13-Tetradecadiene 1 86 1

1 • '

, _ 1 ^ _ ^ _ _J_

1 i • 1 < 1

1 • ' ( 1 !_ 1 1 ' 1 I . „ !.

« ! 183 !

_.12^fL^_ \

1 1 < 1 ) <

1 1 1

1 1 t 1 1 _ _ _ . I . 1 I > 1 1 1

I I • 1 1 ! - - - - -t > 1

1 1 • 1 1 \ 1 t > 1 t 1 1 • • 1 1 . „ _ .»

1 ) • 1 ( •

1 t 1 1 1 ' 1 1 . _. ! 1 • < 1 1 1

1 • '

1 • ' 1 1 1

Estimated 1 Concentration|

ug/1 1 38J,B ! 9S J B

1 1 1

1 1

1

1 1

1

1 1

1 1 1 1

1 1

1

1

1

1 ( 1 ^ J 1 1 t 1

1 1

1 1

1 1 1 t 1 ( 1 __ __ _ !.. 1 1 1 _ 1


*:

'ohn J . M o l l o y , P.E. a b o r a t o r y D i rêc tor

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f i 2A i LABS, INC. 575 BROAO HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765612 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW #4C Hr: 1610 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-S 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U 0.05U O. lOU O. lOU 0. lOU 0. lOU

lOU lOU lOU SOU

O. lOU

0. sou o u sou sou sou sou sou

1.0 u 1. o u

0. o. 0. o.

Vi = Volume of extract injected (uL) Vs = Volume of water extracted (mL) Vt = Volume of total extract (mL) Ws = Weight of sample extracted (g)

Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

**************

V'tyjA.CH. - ^ * * */* ********** John J. Molloy, P.E. Laboratory Director

CO M >

O O

O O

03

f i2M LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW #40

765612


1

C.._A.S..^ 1 Number 1 Compound Name

1 Unknown 1 Unknown

-.-- _ lynknown _ _ _ ^ 1 Unknown 1

1 1

1 1

1 1

1 1

1 t

1 1 1

1 1

1

t 1

1 t

1 RT i Estimated 1 I # I Concentration!

Fraction 1 min 1 Ljg/1 1 Pest 1 3.1651 0.30J 1 Pest 1 7.897! 0.35J 1 Pest 116.647 1 0.30J 1 Pest 125.498! 0.34J 1

t t 1 I I 1

1 1 1 ., _ 1 1 1

1 1 1

1 1 1 ... 1 1 1

1 1 1

1 1 1 1 1 1 ) 1 1

1 t 1

1 ) t 1 1 I

1 1 1 I 1 1

1 t 1

1 1 1 1 1 1

1 1 1 1 1 1

t 1 1 ..._ 1 1 1

1 1 1 ) 1 )

1 1 1 ^ . 1 1 1

**************

Date Reported: 01/07/88 * Cuat^^—-— * */* *********** Tohn J. Molloy, P.E. Laboratory Director

CO PI

o o NJ

O O CD CD

l i2Ai ' •AG' OF


575 Broad Hollow Road, Melvil le, New York 11747-5076 • (516)694-3040

Water/Waste Water Laboratorv • Hazardous Waste Laboratory • Air Testing Laboratory

LABORATORY REPORT

/ ^ CLIENT'S NAME AND ADDRESS


TOWN OF SOUTHAMPTON

HAMPTON ROAO

SOUTHAMPTONf NY 1J.96B

PARAM-FTFR RESULT

PARAM-FTFR PF.qiii T


MU t'iC (lAlO HRS.) NORTH SEA LANDFILL FULL CLP % COC

PARAN-FTFR RFfilll T

PARAM-FTFR

LAB NO. 745A13 PRn.lFPT wn. RHMP BAOS IA

COLLECTED BY VH 03 ^ DATE RECEIVED - 12/ 9/87

RFRIII T

ANTIMONY

ARSENIC BERYLLIUM

CATiMTIIM CHROM

IUM

COPPER

LEAD

MERCURY

NICKEL

<A0.0 •

<10.0 •

<f5.00»

^•^StAO*

20.0 t

<25.0 •

10.0 •

0.20*

<40,0 •

SELENIUM

SILVER THALLIUM

7TNr

IRON MANGANESE

DISS. ANTIM. DISS.


<S.OO#Nt

<10.0

<10.0

40^0

2A00

AO.O

<A0.0

<10.0

<fi.OO*

REMARKS - BILLS f. REPORTSICLV

ALL RESULTS IN (MG/L> EXCEPT AS NOTFB BY • T.COLI BACT. f. FECAL COl I (MPN/IOOML) COLOR; ODOR» TURBIBITY ?. PH (UNITS) APC R FECAL STREP (COUNTS/ML)

^- "IHHOS) SETT.SOLItiS(ML/

DISS. CADMIUM <S.00#

DISS. CHROM. 10.0 * DISS. COPPER SO.O * DISS. 1FAn VK.OO*

DISS. MERCURY <0.20t

DISS. NICKEL <40.0 # DISS.

SELEN. <5.00* DISS. SILVER <10.0 • DISS. THALL. <10.0 •

(UQ/L) OR X (PERCENT

-)

DISS. ZINC

DISS. IRON

DISS. MANG.

rYAMTDF

PHENOLS N02-N + N03-N

AMMONIA (HH.l-N) T. DISS SOLIDS T. ORG. CARBON

) AND

y-

30.0 *

130.*

<20.0 #

<10.0 *

<1^00»

0.20

<0.02

140.

0.A7

DATE REPORTED 2/ R/B0

^ r-LABORATORV DIRECTOR

TH 00 TO 300 V^Q 3E LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

li2M LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765614 Date Collected: 12/08/87 Date Received: 12/09/87 Point: Field Equip. Blank North Sea Landfill



Scan

260

n « C A . S. Number

74-74-75-75-75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

108-108-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--Ol--48--00--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/1

lOU lOU lOU lOU SU 5U 5U 5U 5U 5U 5U 3J 5U 5U 5U 5U 5U 5U SU 5U SU

lOU 5U 5U 5U 5U 5U 5U 5U 5U SU

Date Reported: 12/31/87 ****************

CO tn

o o to

JiOhn J. Molloy, P.E. Laboratory Director

O M O

H^M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY. 11747 • 516-694-3040



Sample Lab No. Field Blank

765614


C.A.S. 1 Number I Compound Name

! Unknown

! % 1 1 Probability 1 1 Fit IRFit 1 1 1

1 I 1

1 1 1 1 , r 1 1

1 1 1 1

1 1

• 1

1 1 .._. _

..._1 _ _

Scan ! n ! 23

,.„

,. ,

1

1 1

1

1

t

\

Estimated 1 Concentration 1 .., U9/1 _. 1.

32J 1 1

1 1

1 1

t

.„.. „,_ K I

1

1 1

1

I

1

1 1

1

1

1

1 1

r

1

1

1 1 t 1 1 1

1 1

1 I

] 1 ; 1 1 1

1 1 1 1

**************

Date Reported: 12/51/87 .^^JU W^Tih^-' * * * X * // .Pohn J. Molloy, P.E, 'Laboratory Director

to tn >

o o to

o NJ

tHH. LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER. McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES



108-95-2 111-44-4 95-57-8

541-73-1 106-46-7 95-50-1

39638329 b 621-64-7 N

67-72-1 98-95-3

78-59-1 88-75-5 105-67-9

N-Nitrosodimethylamine Phenol bis(2-Chloroethyl)ether 2-Chlorophenol l,3-Dichloroben2enf l,4-Dichloroben2ene 1,2-Dichiorobenzene

is(2-chioroisopropyl)ether -Nitroso-Di-n-Propylamine

Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Oiiiiethylphenol


Sampl

Date Date Type: Point North Cone. Date

ug/1 lOU lOU lOU lOU lOU lOU lOU 7 lOU lOU lOU

lOU

lOU lOU lOU

lOU lOU lOU

lOU

e Lab Num Collected Received:

Miscelia : Field E Sea Land Factor:

Ext: 12/1

C.A.S. Number 83-32-9

51-28-5 100-02-7 121-14-2 606-20-2

84-66-2 005-72-3 86-73-7

534-52-1

86-30-6

101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2

206-44-0 129-00-0

ber 765614 : 12/8/87

12/9/87 neous quipment Blank fill 500 Cone. : Low 1/87 Date Anal; 12/16/87

Acenaphthene

2.4-Dinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate 4-Chlorophcnyl-phenylether Fluorene 4,6-Dinitro-2-Methylphenol N-Nitrososdiphenylamine(1)


Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene

ug/1 lOU SOU

sou IGU lOU lOU lOU lOU

sou lOU


Scan

1)




91-58-7 2-Chloronaphthalene IDU




117-81-7 bis(2-Ethylhexyl)Phthalate SOB 218-01-9 Chrysene IQU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Ben2o(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU 193-39-5 Indeno(l,2,3-cd)Pyrene lOU 53-70-3 Dibenzo(a,h)Anthracene lOU

191-24-2 Benzo(g,h,i)Perylene lOU 92-87-5 Benzidine SOU




'UL(k^

"John J . Mol loy. P.E. Laboratory D i rec to r

1515

(f) tn

o o to

o CJ

l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY. 11747 • 516-€94-3040





1 1 * ! I Estimated C.A.S. ! !Probability 1 Scan ! Concentration Number ! Compound Name 1 Fit ! « ! ug/1

1 Unknown 1 ! 186 ! 52J,B 21964498!1,13-Tetradecadiene ! 89 1 1248 ! 56J,B

1 1 1 1


* * * * * * * * * * * * * * * *

: * *r * * * * * * * * *

^ h n J . M o l l o y , P.E. L a b o r a t o r y D i r -ec to r

iSi Fl >

o O KI

O

o

H2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765614 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: Field Equipment Blank North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBER

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5



of extract injected CuL) of water extracted (mL) of total extract (mL) of sample extracted (g)

ug/1

0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 1.

05U 05U 05U G5U 05U 05U 05U 05U lOU IDU lOU lOU lOU , lOU . lOU • SOU , lOU . SOU ,0 U . SOU

.sou , SOU

. sou

. sou

.0 u

.0 u

Vs = 500 mL Vt = 1.5 ml


V i = 5 uL Ws =

* * * * * * * * * * * * * *

* * * * * * jhn J . M o l l o y , P .E .

l a b o r a t o r y D i r e c t o r

cn tn >

o o to

o o Ul

i i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

OLZMACHER, McLENDON and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES




C., A., s ! 1 Number I Compound Name 1 Fraction

1 No Unknowns Found 1 Pest

;-•- - — 1 — - —

1 _i ,.._ .. .. ! 1 _ -. 1 - L __.. __

RT 1 Estimated 1 tt 1 Concentration!

min 1 ug/1 1 1 0.20U 1 1 1

1 „..,. „ L

1 1 1 1

t 1 1 _ _ _^ _ I

1 1 1 1

1 1 t 1

1 1 t (

1 1 1 1

1 1

1 t 1 t

1 1

1 1 i <

1 1

; ;

1 1 1 t

1 1 t 1 >

1 1 1

1 1 !

1 1 1 1 1 1

**************

Date Reported: 01/07/88 djkc^^ ********* J. Molloy, P.E.

Laboratory Director

CO tn

O O to

O. Ch

ruM. t i 2 y H LABS, INC. Environmental Testing Laboratories


Water/Waste Water Laboratory • Hazardous Waste Laboratory * Air Testing Laboratory Pilot Plant Studies and Other Analytical Services

.-ÂR. OF


TOWN OF SOUTHAMPTON

HAMPTON ROAD


LABORATORY REPORT

LAB NO. 7A5A15 PRO.IFCT NO. SHMP BAOB LA


FIELD EQUIPMENT BLANK NORTH SEA LANDFILL FULL CLP t COC

COLLECTED BY VH OJ! DATE RECEIVED - 12/ 9/87

PARAM-ETER RESULT

PARAM-F.TER RF^mUrT

PARAM-R.i;ÛLT

ANTI-HQNY <6Q>Q f

SELEN- T. DISS lUM <5.Q0tM(r SOLIDS <5«0Q

•MMHin <31Q.Q • SILVER <HOtQ t T. ORO. CARBON <QtQ5

BERYL-LIUM <S.QOt

THAL-LlUh <3l<>tQ t

MANOA-NFSE AO.O f

XAMliiiL <5.00» iim j ^ O t P f CHROM

IUM 20.0 • IRON 350.«

COPPER AO.O • CYANIDE <10.0 #

LEAD 10.0 t PHENOLS <1.00#

MERCURY <0,20t N02-H + H03-N <0.10

NICKEL AMMONIA

<4Q.O • (NH3-N) <0.02

REMARKS - BILLS R REPORTS:CLV

ALL RESULTS IN (MO/L) EXCEPT AS NOTED BY • (UG/L) OR X (PERCENT) AND T.COLI BACT. % FF.CAL COLI (MPN/IOOML) COLOR; ODOR; TURBIDITY S PH (UNITS)

—RFP (COUNTS/ML) ÔTO 300 V3S IHOS) SFTT. SOLItiS( ML/L)

THE LIABILM T u r I i t . . . . . . . lALL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

DATE REPORTED 2/ 5/BP

H2H LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER McLENDON and MURRELL. PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765616 Date Collected: 12/08/87 Date Received: 12/09/87 Point: MW «4A Hr: 1415 North Sea Landfill



Scan « C A . .S. Number

74-74-75-75-75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

108-108-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--00--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7


ug/1

lOU lOU lOU lOU 5U 5U 5U 5U SU 5U 5U 5U SU 5U 5U 5U SU 5U 5U 5U 5U lOU 5U 5U 5U 5U 5U 5U 5U 5U 5U

Date Reported: 12/31/87 **************** o o

* * * * * 3Str^n 3 . M o l l o y , P . E . L a b o r a t o r y D i r e c t o r

O 03


HOLZMACHER, M C L E N D O N and MURRELL, P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. MW « 4 A

765616


C.A.S. Number Compound Name

No Unknowns Found

% 1 I Estimated 1 Probability I Scan I Concentration! Fit IRFit ! « 1 ug/1 ,' -" ! ~ 1 — ; 5U 1

I I I 1 i l l i

1 ! 1 1 1 1

1 1 1 1 1 1

1 1 1 1 1 1

1 1 1 > > 1 1 1 1 1 1 1

1 1 1

1 t 1

1 t 1 1 1 t

1 1 1 t 1 1

I 1 I

I I I 1 1 1 t t 1

1 1 1 1 1 1 1 1 1

1 1 1 1 t

1 1 1 1 1 1 1 1 <

1 1 1 1 1 >

1 1 1 1 1 1

* * * * * * * * * * * * * *

Date Reported: 12/31/87 * «/* ***********

,T:6hn J. Molloy, P.E. Laboratory Director in

cn >

o o

o I — o iX)

t \1M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Scan «

C.f L S .

Number 6 5 -

108 -

1 1 1 -9 5 -

5 4 1 -

106 -

95-

•75-•95-• 4 i -

- 57 -

•73 -

-46 -

-50 -

• 9

• 2

• i .

• 8

-1 -7

-1

N-Nitrosodimethylamine Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene

39638329 bis(2-chloroisopropyl)ether 621-64-7 N-Nitroso-Oi-n-Propylamine

67-72-1 Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol

Sample Lab N Date Collect Date Receive Type: ttiscel Point: nw #4 North Sea La Cone. Factor Date Ext: 12

C.A.S. ug/1 Number lOU 83-32-lOU 51-28-lOU 100-02-lOU 121-14-lOU 606-20-lOU 84-66-lOU 7005-72-

98-95-3 78-59-1 88-75-5 105-67-9


umber 765616 ed: 12/8/87 d: 12/9/87 laneous A Hr: 1415 ndfill

500 Cone. : Low /11/87 Date Anal: 12/16/87

9 Acenaphthene 5 2,4-Dinitrophenol 7 4-Nitrophenol 2 2,4-Dinitrotoluene 2 2,6-Dinitrotoluene 2 Diethylphthalate 3 4-Chlorophenyl-phenylether

lOU 86-73-7 Fluorene lOU 534-52-1 4,6-Dinitro-2-nethylphenol lOU 86-30-6 N-Nitrososdiphenylamine(1)

lOU lOU 101-55-3 4-Broinophenyl-phenylether lOU 118-74-1 Hexachlorobenzene lOU 87-86-5 Pentachlorophenol

85-01-8 Phenanthrene lOU 120-12-7 Anthracene

lOU 84-74-2 Di-n-Butylphthalate lOU 206-44-0 Fluoranthene

lOU 129-00-0 Pyrene

ug/1 Scan lOU SOU SOU lOU lOU lOU lOU lOU sou lOU

lOU lOU 50U lOU lOU lOU lOU lOU

87-68-3 Hexachlorobutadiene lOU 85-68-7

(1)

59-50-7 4-Chloro-3-Mftthylphenol lOU 91-94-1 56-55-3 117-81-7 218-01-9 117-84-0 205-99-2 207-08-9

50-32-8 193-39-5

53-70-3 191-24-2 92-87-5


77-47-4 Hexachlorocyclopentadiene 88-06-2 2,4,6-Trichlorophenol


131-11-3 Dimethyl Phthalate

208-96-8 Acenaphthylene

lOU lOU

lOU

lOU

lOU

Butylbenzylphthalate lOU 3,3'-Dichlorobenzidine 20U BenzoCa)Anthracene lOU bis(2-Ethylhexyl)Phthalate 31B Chrysene lOU Di-n-Octyl Phthalate lOU Benzo(b)Fluoranthene lOU Benzo(k)Fluoranthene lOU

Benzo(a)Pyrene lOU Indeno(l,2,3-cd}Pyrene lOU Dibenzo(a,h)Anthracene lOU

Benzo(g,h,i)Perylene lOU Benzidine SOU


(Ohn J. Molloy, P.E. ''Laboratory Director

1515

CO tn

o o to

o » - . o

m l J u ^ \ LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE, NY 11747 • 516-694-3040




765616


] J * 1 1 E s t i m a t e d 1 C . A . S , 1 1 P r o b a b i l i t y 1 Scan ! C o n c e n t r a t i o n ! Number 1 Compound Name 1 F i t ! « 1 u g / 1 1

[Unknown 1 ! 186 ! 54. J , B ! 21964498 1 1 , 1 3 - T e t r a d e c a d i e n e 1 86 I 1248 I 7 6 J , B 1

! I l l 1 1 I I I I 1 I I I 1

1 I I I 1 1 X \ \ V 1 I I I 1

1 l i t 1 1 I I I 1 1 \ \ I t 1 I I I 1

1 I I I 1 t t I ) 1

t I I I 1

1 I I I 1

1 ! ! ! 1 1 I I I 1 1 I I I 1

1 I I I 1

1 I ' l l 1 1 I I I 1

1 I I I 1

1 I I I > 1 I I I 1

! . „ 1 . .1. ..._ J I 1 ! ! 1 ! : ! ! ! 1 1 1 1 1 1 I I I 1

**************

Date Reported: 01/05/88 .u IJL-

; V'* ******** Kohn J. Molloy, P.E. Laboratory Director

cn tn >

o o to




Sample Lab No. 765616 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «4A Hr: 1415 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBE

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


R

alpha-BHC beta-BHC delta-BHC gamma-BHC i Heptachlor Aldrin Heptachlor Endosulfan Dieldrin 4,4'-DDE Endrin Endosulfan 4,4'-DDD Endosulfan 4,4'-DDT

[Lindane)

Epoxide I

II

Sulfate

Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

of extract injected (uL) of water ext racted (mL) of total extract (mL) of sample ex tracted (g)

us

0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0, 0, 0 1 1

l/l

05U 05U 05U 05U 05U 05U 05U 05U lOU lOU lOU IOLT

lOU , lOU , lOU SOU , lOU , SOU

.0 u

.SOU

. SOU

. sou

. sou

. sou

.0 u

.0 u

Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

**************

if) tn

o o

. 3ohn J. Molloy, P.E. Laboratory Director

O I — t — to

l i2Ai LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW *»4A

7 6 5 6 1 6


C.A.S. 1 Number

• — —

Compound Name ! No Unknowns Found I

- - - -

\ 1

1 1

1

I _ ... _

1 RT ! 1 ** !

Fraction 1 min 1 Pest 1

- -- --| — -


ug/1 1 0.. 20U !

1

1 1

* * * * * * * * * * * * * *

Date Reported: 01/07/88 ly* * * * * * * * * * * *

f'bhn J. Molloy, P.E. Laboratory Director

in tn >

o O

o 1— i—

CJ

WflH >AG- OF



Water/Waste Water Laboratory • Hazardoui Waste Laboratory • Air Testing Laboratory Pilot Plant Studies and Other Analytical Services

LABORATORY REPORT

PROJECT NO, LAB NO. 7«SA17

JUMfi a4A5 L A ^ CLIENT'S NAME AND ADDRESS

TOMN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTON* NY 11948


MW »1A (1415 HRS.) NORTH SEA LANDFILL FULL CLP f. COC


PARAM-ETER RESULT

PARAM-ETER RESULT

PARAM-ETER RESULT

PARAM-ETER RESULT

ANTI- SELFN- DISS. DISS. MONY <A0.0 • lUH < ^0 .0 *H£ CADMIUM KTi.OO* ZINC 20.0 •

ARSENIC <10.0 • SILVER <10.0 • DISSt

CHROM> 20.0 • DISS. IRON 90.0 •

BERYLLIUM <5.00»

THALLIUM <t0.Q •

DISS. COPPER 30.0 t

DISS. MANO. 320.•

rADMIIIM <S.OOt ZINC 70*0 • DISS* LEAD <S«QO» CYANIDE <10«0 »

CHROM-lUM 220 •# -IRQJt. 29700 •

DISS. MERCURY. <Q.20» PHENOLS <1.00»

COPPER BQ>Q t MANOA-

ttES£_ 1010 • DISS*

<40>0 • N02-N +

N03-N 1.00

LEAD 44.Q • DISS*

nNTIH. <ftO.Q *

DISS. SELEN t. <3tOQt

AMMONIA (HH3-N^ 2.60

MERCURY <0.20# DISS*

ftRSEMin , <lOtO • DISS*

SILVER < 1 0 . 0 # T . DISS SOLIDS A0*0

NICKEL <40.0 • DIS BERYLLIUM <r).00t

DISS. THALL, <10.0 t

T. ORG. CARBON 1.80

L

REMARKS - BILLS t REPORTSICLV

ALL RESULTS IN (MR/L) EXCEPT AS NOTED BY t (UQ/L) OR X (PERCENT) AND T.COLI PACT. r. FECAL COLI (MPN/IOOML) COl OP. """- ÎDITY % PH (UNITS)

V3S (COUNTS/ML) -wS) SFTT.SOLJD.q(ML/L) tTTO 200

DATE RLPORTED 2/ 5/86

LABORATORV DIRECTOR

THE L.«mLi IY OF H2M LABS, INC. SHALL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

l i2M LABS, INC. 575 BROAO HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765618 Date Collected: 12/08/87 Date Received: 12/09/87 Point: MW «4B Hr: 1515 North Sea Landfill



Scan # Number ug/1

74-87-3 74-83-9 75-01-4 75-00-3

123 75-09-2 75-35-4 75-34-3

156-60-5 224 67-66-3

107-02-2 75-69-4 71-55-6 56-23-5 75-27-4 70-87-5

10061-02-6 79-01-6

124-48-1 79-00-5 71-43-2

10061-01-5 110-75-6 75-25-2

127-18-4 79-34-5

108-88-3 108-90-7 100-41-4 541-72-1 95-50-1

106-46-7

Chloromethane lOU Bromomethane lOU Vinyl Chloride lOU Chloroethane lOU Methylene Chloride 2BJ 1,1-Dichloroethene 5U 1,1-Dichloroethane 5U cis/trans-1,2-Dichloroethene 5U Chloroform 3J 1,2-Dichloroethane 5U Trichlorofluoromethane 5U 1,1,1-Trichloroethane 5U Carbon tetrachloride 5U Bromodichloromethane 5U 1,2-Dichloropropane 5U trans-l,3-Dichloropropene 5U Trichloroethene 5U Dibromochloromethane 5U 1,1,2-Trichloroethane 5U Benzene 5U cis-1,3-Dichloropropene 5Ll 2-Chloroethylvinylether lOU Bromoform 5U Tetrachloroethene 5U 1,1,2,2-Tetrachloroethane 5U Toluene 5U Chlorobenzene 5U Ethylbenzene 5U 1,3-Dichlorobenzene 5U 1,2-Dichlorobenzene 5U 1,4-Dichlorobenzene 5U

Date Reported: 12/31/87 ***************:

******** /Oohn J. Molloy, P.E. Laboratory Director

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rnlMJ^m LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE, NY 11747 • 516-694-3040



Sample Lab No. 765618 MW «4B


C.A.S. ! Number ! Compound Name 124-38-9!Carbon dioxide

" 1 -

! % ! 1 Probability! 1 Fit IRFit 1 ! 100 ! 80 !

--| -

1 1

- • ' • • - —

Scan 1 « ! 11 !

- 1 •


ug/1 1 .__i.QJ...B !..,

1

1 1

1

1 1 1 t

-l-1

1 ..... _ _.-..„ ^ - ' .

t 1 1 1

1 1 1 1

1 1

1 1

1 1

1 r t . . _..' , 1 1

! L 1

1 1

1 1

1

1 1 1

1 1 '

1 t ' 1 ' . . ._ _ -... ... - . . ^ J 1 1 > 1 1 ', 1 1 1 1 1

( J '

**************

Date Reported: 12/31/87 ************


tn tn

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Wi2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY. 11747 • 516-694-3040



Sample Lab Number 765618 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: nu »4B Hr: 1515 North Sea Landfill Cone. Factor: 500 Cone.:

Scan C.A.S. Number 65-75-9 108-95-2 111-44-4 95-57-8

541-73-1 106-46-7 95-50-1

39638329 bi 621-64-7 N-

67-72-1 98-95-3 78-59-1 88-75-5 105-67-9

N-Nitrosodimethylamine Phenol bis(2-Chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Oichiorobenzene

s(2-ehloroisopropyl)ether Nitroso-Di-n-Propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2, 4-Dimethylphenol


Low Date Ext: 12/11/87

C.A.S. ug/1 Number lOU 83-32-9 lOU 51-28-5

lOU 100-02-7 lOU 121-14-2 lOU 606-20-2 lOU 84-66-2

Date Anal: 12/17/87

lOU 7005-72-3 lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

86-73-7 534-52-1

86-30-6

101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2

206-44-0 129-00-0

ug/1 Scan Acenaphthene lOU 2,4-Dinitrophenol SOU 4-Nitrophenol SOU 2,4-Dinitrotoluene lOU 2,6-Dinitrotoluene lOU Diethylphthalate lOU 4-Chlorophenyl-phenylether lOU

Fluorene lOU 4,6-Dinitro-2-Methylphenol SOU

N-Nitrososdiphenylamine(l) lOU

4-Bromophenyl-phenylether lOU Hexachlorobenzene lOU Pentachlorophenol SOU Phenanthrene lOU Anthracene lOU Di-n-Butylphthalate lOU Fluoranthene lOU

Pyrene lOU



88-06-2 2,4,6-Triehiorophenol lOU





85-68-7 Butylbenzylphthalate lOU 91-94-1 3,3'-Dichlorobenzidine 20U

56-55-3 Benzo(a)Anthracene IDU 117-81-7 bis(2-Ethylhexyl)Phthalate 94B 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Benzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU 193-39-5 Indeno(l,2,3-cd)Pyrene lOU 53-70-3 Oibenzo(a,h)Anthracene lOU

191-24-2 Benzols,h,i)Perylene lOU 92-87-5 Benzidine SOU

1512



r x x x X X

lohn J. nolloy, P.E. Laboratory Director

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m \ j l j ^ \ LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY. 11747 • 516-694-3040



Sample Lab No. 765618 MW « 4 B


C..r.A..,S_. Number

21964498

Compound Name Unknown 1 ;i 13-Tetradecadiene

% Probability

Fit

-

...

Scan

182 1245

—

Estimated 1 Concentrat ion 1

ug/1 1 58J,B ! 8J,B 1

1 t

t 1

1 1

1 1

1

1

t

1 1 1

1 1

1 1

1 1

1

I 1

1 1

1

J 1

1

1

* * * * * * * * * * * * * *

Date Reported: 01/05/88 ************ .Xohn J. Molloy, P.E. Laboratory Director

in PI

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03

H2M LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765618 Date Collected: 12/8/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «4B Hr: 1515 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/11/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-55-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


O. 0. o. 0. 0. 0. 0.

0.05U 0.05U 0.05U 0.05U 0.05U 0.05U

05U OSU-^ lOU . lOU . lOU , lOU-^ ,10U

0. lOU 0. lOU o. sou O. lOU 0.50U

0 u SOU sou sou sou sou ,0 u , o u

1. o. o. 0. 0. 0. 1. 1,

vi = Volume of extract injected (uL) Vs = Volume of water extracted (mL) Vt = Volume of total extract (mL) Ws = Weight of sample extracted (g)

Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

**************

9

* * * * * * * * * * *^


in

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t i2Ai LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040

HOLZMACHER, McLENDON and MURRELL, P.C • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765618 MW « 4 B


1 I 1 RT ! E s t i m a t e d ! C . A . S . ! 1 ! # 1 C o n c e n t r a t i o n ! Number 1 Compound Name 1 F r a c t i o n ! m in I u g / 1 1

I Unknown 1 P e s t 1 1 6 . 1 0 8 ! 0 . 2 1 J I

I I I I 1

1 I I I 1 . . . . . 1 1 I I 1

1 1 1 1 t ! 1 ! ! 1

. . . 1 ! ! ! !

* * * * * * * * * * * * * *

Date Reported: 01/07/88 A; - M ^ fc * * * * * * * * * *

t 6hn 3. Molloy, P.E. aboratory Director

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WHM, f i l M . LABS, INC. Environmental Testing Laboratories


PAG OF

LABORATORY REPORT

/ CLIENT'S NAME AND ADDRESS


TOWN OF SOUTHAMPTON

HAMPTON ROAD


PARAMETER RESULT

PARAMETER RESULT


MU #1B (1515 HRS.) NORTH SEA LANDFILL FULL CLP f. COC

PARAMETER RESULT

PARAMETER

LAB NO. 7A5At9 PRfllFCT NO. SHMP RAOf! 1 A


RESULT

ANTIMONY

ARRFMTr BERYL

LIUM

nADMIUM CHROM

IUM

COPPER

LEAD

MERCURY

NICKEL

<A0.0 •

<:i0.0 *

<5.00»

<^.nf\*

110.*

80,0 »

8.00*

<0.20#

<)0»0 •

SELENIUM

STI UPP THALLIUM

77Nr

IRON HANOA-

HE8E DISS.

ANTIM. DISS.


REMARKS - BILLS 8 REPOR

ALL RESULTS IN (MO/L) EXCEPT AS T.COL! BACT. r crnA|_ ^ Q L I

IDITY X PH TZTO 300 V3S <C.OUNTS/l

^,t,f. uin«i)S) SETT

<5.00flJe

< \ C i . t i *

<10.0 *

40.0 •

30A0 *

1340 • .

<60.0 f

<10.0 »

<5.00*

rstci .v

NOTED BY t (MPN/IOOML) (UNITS)

ID ,SOLIDS(Ml./

DISS. CADMIUM

DISS. rHRHH. DISS.

COPPER DISS. 1 FAD

DISS. HFRnilRY

DISS. NICKEL DISS.

SELEN. DISS.

SILVER DISS.

THALL.

(UO/L) UR

L)

<5.00#

50.0 *

70.0 *

10.0 *

<:0.20«

<40,0 *

<S.00*

10.0 t

<10.0 t

X (PERCENT

DISS. 7. INC

PISS. TRDN

DISS. MANG.

CYANIDE

PHENOLS N02-N +

N03-N AMMONIA (NH3-N) T. Dtsts SOLIDS

T. ORG. CARBON

) AND '—^

40.0 »

1330 •

1870 *

<10.0 *

<1.00*

0.40

4.40

170.

S.IO

DATE REPORTED 2/ 5/B8

y LABORATORY DIRECTOR

THE LIABILITY OF H2M LABS, INC. SHALL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

H2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765620 Date Collected: 12/08/87 Date Received: 12/09/87 Point: Trip Blank North Sea Landfill Date Ext: 12/16/87 Date Anal: 12/16/87 Conc./Dil. factor: 1.1 Cone: Low



74-74-75-75-

123 75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

450 108-108-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--OO--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichioropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/1

lOU lOU lOU lOU 2BJ 5U 5U 5U 5U 5U 5U 5U 5U 5U SU 5U 5U SU 5U 5U SU lOU 5U 5U 5U 3J 5U 5U 5U 5U 5U

Date Reported: 12/31/87 *************:

UlMuO^r—' *************

.John J, Molloy, P.E. Laboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765620 T r i p B l a n k


Number Compound Name 124-38-9 I Carbon_d_ipxide

iProbability! Scan.

iRFit 1 n fJ-JL 100 84 11

Est im Concent

Ljg/

9 3 ,

a.t..ed ._ rat_^pn

'iZ.._....-.Z.. B


* * * * * * * * * * * * * * * , *

^ * * * * * * * * * * *

/ j o h n J . M o l l o y , P . E . • - L a b o r a t o r y D i r e c t o r

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CJ

li2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040

HOLZMACHEa McLENDON and MURRELL. P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765680 Date Collected: 12/09/87 Date Received: 12/09/87 Point: MW *t3A Hr: 0930 North Sea Landfill Date Ext: 12/16/87 Date Anal Conc./Dil. factor: 1.1 Cone:

12/16/87 Low


Scan « C.A.S. Number ug/1

74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 75-35-4 75-34-3

156-60-5 67-66-3

107-02-2 75-69-4 71-55-6 56-23-5 75-27-4 70-87-5

10061-02-6 79-01-6

124-48-1 79-00-5 71-43-2

10061-01-5 110-75-6 75-25-2

127-18-4 79-34-5

108-88-3 108-90-7 100-41-4 541-72-1 95-50-1 106-46-7

Chloromethane lOU Bromomethane lOU Vinyl Chloride lOU Chloroethane lOU Methylene Chloride SU 1,1-Dichloroethene 5U 1,1-Dichloroethane SU cis/trans-1,2-Dichloroethene 5U Chloroform 5U 1,2-Dichloroethane 5U Trichlorofluoromethane 5U 1,1,1-Trichloroethane 5U Carbon tetrachloride SU Bromodichloromethane 5U 1,2-Dichloropropane 5U trans-l,3-Dichloropropene 5U Trichloroethene 5U Dibromochloromethane SU 1, 1,2-Trichloroethane 5U Benzene 5U cis-1,3-Dichloropropene 5U 2-Chloroethylvinylether lOU Bromoform 5U Tetrachloroethene 5U 1,1,2,2-Tetrachloroethane 5U Toluene 5U Chlorobenzene 5U Ethylbenzene 5U 1,3-Dichlorobenzene 5U 1,2-Dichlorobenzene 5U 1,4-Dichlorobenzene 5U

Date Reported: 12/31/87 ****************

' ' •n /QA^^JA'-John J. Molloy, P.E. .Laboratory Director

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H2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY. 11747 • 516-694-3040


T o w n o f S o u t h a m p t o n Hampton Road S o u t h a m p t o n , NY 11968

Sample Lab No. 765680 MW «3A


C . A . S . Number Compound Name 1.24_-3a:;;;9 !j;.arbqn _dipxi^^^

Probability!. _Scan_ Fit IRFit ! i . .

Estima Cpricentr

ug7i at

.y. J...

ion I

99 85 11 ..8J.j,.B.

**************

Date Reported: 12/31/87 /Oohn J. Molloy, P.E. Laboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE, NY. 11747 • 516-694-3040




1 0 8 - 9 5 - 2 1 1 1 - 4 4 - 6

9 5 - 5 7 - 8 5 4 1 - 7 3 - 1 1 0 6 - 4 6 - 7

9 5 - 5 0 - 1 39638329 b 621-64-7 N

6 7 - 7 2 - 1 98-95-3 7 8 - 5 9 - 1 8 8 - 7 5 - 5

1 0 5 - 6 7 - 9

S a m p l e La D a t e C o l l D a t e Rece T y p e : Mis P o i n t : MW N o r t h Sea C o n e . Fac D a t e E x t :

C. A

N - N i t r o s o d i m e t h y l a m i n e P h e n o l b i s ( 2 - C h l o r o e t h y l A e t h e r 2 - C h l o r o p h e n o l 1 , 3 - D i c h l o r o b e n z e n e 1 , 4 - D i c h l o r o b e n z e n e 1 , 2 - D i c h l o r o b e n z e n e


H e x a c h l o r o e t h a n e N i t r o b e n z e n e I s o p h o r o n e 2 - N i t r o p h e n o l 2 , 4 - D i m e t h y l p h e n o l

u g / 1 lOU lOU lOU lOU lOU lOU

1 1 1 - 9 1 - 1 b i s ( 2 - C h l o r o e t h o x y ) M e t h a n e 1 2 0 - 8 3 - 2 2 , 4 - D i c h l o r o p h e n o l 1 2 0 - 8 2 - 1 1 , 2 , 4 - T r i c h l o r o b e n z e n e

9 1 - 2 0 - 3 N a p h t h a l e n e

Num

8 3 -5 1 -

1 0 0 -1 2 1 -6 0 6 -

8 4 -lOU 7 0 0 5 -lOU 8 6 -lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

534-86-

101-118-87-85-

120-84-

206-129-

b N ect ive eel «3 La

tor 12

.S. ber 32-28-02-14-20-66-72-73-52-30-

umber 765680 ed: 12/9/87 d: 12/9/87 laneous A Hr: 0930 ndfill : 500 Cone. : Low /14/87 Date Anal: 12/17/87

9 Acenaphthene 5 2,4-Dinitrophenol 7 4-Nitrophenol 2 2,4-Dinitrotoluene 2 2,6-Dinitrotoluene 2 Diethylphthalate 3 4-Chlorophenyl-phenylether 7 Fluorene 1 4,6-Dinitro-2-Methylphenol 6 N-Nitrososdiphenylamine{1)

55-3 4-Broroophenyl-phenylether 74-1 Hexachlorobenzene 86-5 Pentachlorophenol 01-8 Phenanthrene 12-7 Anthracene 74-2 Oi-n-Butylphthalate 44-0 Fluoranthene 00-0 Pyrene

ug/1 Scan lOU SOU SOU lOU lOU lOU lOU lOU sou lOU

lOU lOU

sou lOU lOU lOU lOU IQU

87-68-3 Hexachlorobutadiene lOU 59-50-7 4-Chloro-3-Mcthylphenol lOU


88-06-2 2,4,6-Trichlorophenol IQU




85-68-7 Butylbenzylphthalate lOU 91-94-1 5,3'-Dichiorobenzidine 20U 56-55-3 Benzo(a)Anthracene. lOU

117-81-7 bis(2-Ethylhexyl)Phthalate 59B 218-01-9 Chrysene lOU 117-84-0 Di-n-Octyl Phthalate lOU 205-99-2 Senzo(b)Fluoranthene lOU 207-08-9 Benzo(k)Fluoranthene lOU 50-32-8 Benzo(a)Pyrene lOU

193-39-5 Indeno(l,2.3-cd)Pyrene lOU 53-70-3 Dibenzo(a,h)Anthraeene lOU

191-24-2 Benzo(g,h,i)Perylene lOU 92-87-5 Benzidine SOU

1511

(1 ) Cannot be s e p a r a t e d from d i p h e n y l a m i n e

D a t e R e p o r t e d : 0 1 / 0 5 / 8 8

rohn J . M o l l o y , P . E . L a b o r a t o r y D i r e c t o r

CO

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IO cri

l i2M LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. MW #3A

765680


1 I % ! 1 E s t i m a t e d 1 C . A . S . ! I P r o b a b i l i t y I Scan ! C o n c e n t r a t i o n ! Number 1 Compound Name 1 F i t ! « 1 u g / 1 1

!Unknown 1 ! 183 ! 5 4 J , B 2 1 9 6 4 4 9 8 ! 1 , 1 3 - T e t r a d e c a d i e n e ! 89 ! 1246 ! 5 6 J !

1 Unknown 1 i 1350 1 2 2 J 1 I I I 1

1 I I I 1

1 I I I 1

1 \ I \ t

1 I I I 1

1 I I I 1

I I I I 1

1 t 1 1 . . . 1

t 1 t 1 1

1 I I I I

1 1 1 1 1

1 I I I 1

I I I I 1

1 l i t 1 1 1 1 1 1 1 1 1 1 1 1 I I I 1

1 1 . . I I . .1

1 1 1 1 1 1 I I I 1

1 \ \ * 1 J _ „ ! __ - „ 1 ^ „ !. _._ „ ._. . . ; . - „ . . l .


************** * • *

;***********

/ôhn 3. Molloy, P.E. •Laboratory Director

o o to

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Wi2H. LABS, INC. 575 BROAO HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765680 Date Collected: 12/9/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «3A Hr: 0930 North Sea Landfill Collected By: VH 03 Concentration: Low Cone, Factor: 333 Date Ext. 12/14/87 Date Anal. 12/18/87

C.A.S. NUMBER

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 55469-21-9 12672-29-6 11097-69-1 11096-82-5


o o o o

Vs = 500 mL

Date Reported


f extract injected ( f water extracted (m f total extract (mL) f sample extracted (

Vt = 1.5 ml Vi =

uL) L)

g)

5 UL

ug/1

0.05U 0.05U 0. 05U 0.05U 0. 05U 0.05U 0.05U o.osu-^ 0. lOU 0. lOU 0.lOU y 0 . l O U ^ O.IOU 0. lOU O.IOU 0. SOU 0. lOU 0.5OU 1. 0 U

0. sou 0. sou 0. sou o.sou 0. sou 1.0 u 1. 0 u

Ws =

^ / n y / Q R **************

*/7 ^

b t<f-^^<—^ 'yir* * * * * * * * * * *

hn J. Molloy, P.E

Laboratory Director

CO tn >

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(O CD

l i2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHER. McLENDON and MURRELL P.C. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES



765680


C.A.S. Number

——«

• • —

Compound Name No Unknowns Found

- -

! Fraction ! 1 Pest

1

_ -\

RT 1 n 1

min 1 — '

- - - •

Estimated 1 Concentration!

ug/1 ! 0.2U 1

_ ._ ... . . .1.

_ .. .- -...!...

**************

Date Reported: 01/07/88 3hn J. Molloy, P.E.

Laboratory Director

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t i2A i H I M . LABS, INC. Environmental Testing Laboratories


>A0 OF

LABORATORY REPORT

r

Water/Waste Water Laboratorv • Hazardous Waste Laboratory • Air Testing Laboratory Pilot Plant Studies and Other Analytical Services


TOMN OF SOUTHAMPTON

HAMPTON ROAD


PARAM-FTFR R P R l l l T

PARAM-FTFR P F s m T

TYPE OF SAMPLE - MISCELLANEOUS DATE COlLECTED - 1 2 / 9 / 8 7

MU t3A (0930 HRS.) NORTH SEA LANDFILL FULL CLP 8 COC

PARAM-FTFR RFf i l l l T

PARAM-FTFP

LAB NO. 7Af)ABl p e n IFPT w n . B M M P H A O K I A

COLLECTED BY VH 03 DATE RECEIVED - 1 2 / 9 / 8 7

RFRIU T

/

A N T I MONY

ARSENIC BERYl -

LIUM

CADMIUM CHROM

IUM

COPPER

LEAD

MERCURY

NICKEL

< A 0 . 0 •

1 2 . 0 •

< 5 . 0 0 #

<S.OO*

AO.O t

8 0 . 0 t

50>0 * +

< 0 , 2 0 t

< 4 0 . 0 t

SELENIUM

SILVER THAL

LIUM

ZINC

IRON MANGA

NESE D I S S .

ANTIM. D I S S .


REMARKS - B ILLS f, REPORT

ALL RESULTS IN (MG/L) EXCEPT AS T .COLI BACT. f. FECAL COLI COLOR; OnoD ID ITY X PH "" " " p, V3S (COUNTS/I Q^TO ^ ° ° *S) SETT

K^.oo^tje

< 1 0 . 0 f

< 1 0 . 0 •

1 0 0 . #

.^SflOO t

3 8 0 . »

< A0 .0 t

< 1 0 . 0 #

< S . 0 0 t

rsjcLv

NOTED BY * (MPN/IOOML)

(UNITS) I D , S O L i n S ( M L / l

D I S S . CADMIUM

D I S S . CHROM.

D I S S . COPPER

D I S S . LEAD

D I S S . MERCURY

D I S S . NICKEL

D I S S . SELEN.

D I S S . SILVER

D I S S . THALL.

( U G / L ) OR

. )

< S . 0 0 #

< 1 0 . 0 *

< 2 0 . 0 *

< 5 . 0 0 *

< 0 . 2 0 t

< 4 0 . 0 •

< S . 0 0 f

< 1 0 . 0 t

< 1 0 . 0 •

X (PERCENT

D I S S . ZINC

D I S S . IRON

D I S S . MANO.

CYANIDE

PHENOLS N02-N -f

N03-N AMMONIA (NH3-N) T . ORG.

CARBON T . DISS

SOLIDS

) AND

^ ^

4 0 . 0 •

AOO. t

1 7 0 . *

< 1 0 . 0 #

< 1 . 0 0 »

0 . 1 0

0 . 3 7

1 .80

1 0 0 .

DATE REPORTED 2 / 5 /8P

7_a__irtL , - trT . LABORATORY DIRECTOR

THE . ....v, LABS, INC. SHALL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

H I H LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765683 Date Collected: 12/09/87 Date Received: 12/09/87 Point: MW #3B Hr: llOO North Sea Landfill Date Ext: 12/16/87 Date Anal: 12/16/87 Conc./Dil. factor: 1.1 Cone: Low


Scan

122

197 210

« C.A.S. Number

74-87-3 74-83-9 75-01-4 75-00-3 75-09-2 75-35-4 75-34-3

156-60-5 67-66-3

107-02-2 75-69-4 71-55-6 56-23-5 75-27-4 70-87-5

10061-02-6 315

324

79-01-6 124-48-1 79-00-5 71-43-2

10061-01-5

424

448

110-75-6 75-25-2

127-18-4 79-34-5

108-88-3 108-90-7 100-41-4 541-72-1 95-50-1

106-46-7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-ChioroethyIvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Dichlorobenzene 1,2-Dichlorobenzene 1,4-Dichlorobenzene

ug/1

lOU lOU lOU lOU 2BJ 5U 3J 2J 5U 5U 5U 5U 5U SU 5U 5U 3J 5U 5U IJ SU lOU SU 4J 5U 2J SU 5U SU 5U SU

Date Reported: 12/31/87 * * * * * * * * * * * * * * * *

•y / I ;

* 3eTrV*~««*'*-<t^* * * * * * *

J o h n J . M o l l o y , P . E . L a b o r a t o r y D i r e r c t o r

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HIM LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040




765683


C.,A^S._. Number Compound Name 1 2 4 - 3 8 - 9 I Ca rbon d i p x ajde.

% P r o b a b i l i t y

F i t I R F i t Scan

1 0 0 9 9 11

Es t ima t_ed ' C o j n c e n t r a t i o n

'ug/l Z... 56 J, B

• A : * : * * * * * * * * * * * ! *

Date Reported: 12/31/87 * * ; • * * * * * * * * * * * *

J;Chn J. Molloy, P.E. Laboratory Director

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fi2M LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE. NY. 11747 • 516-694-3040



Scan tt

C . A . S .

Number 6 5 - 7 5 - 9

108-95-2 111-44-4

9 5 - 5 7 - 8

541-73-1 106-46-7

95-50-1 39638329 b 621-64-7 N

67-72-1 9 8 - 9 5 - 3

78-59-1 8 8 - 7 5 - 5

105-67-9

N - N i t r o s o d i n e t h y l a m i n e Phenol b i s ( 2 - C h l o r o e t h y l ) e t h e r 2 -Chlorophenol 1 ,3 -Oich lo robenzene 1 ,4 -Dich lo robenzene l , 2 - D i c h l o r o b e n 2 e n e


Hexach lo roe thane N i t robenzene I sophorone 2 - N i t r o p h e n o l 2 ,4 -Dime thy lpheno l

111-91-1 b i s ( 2 - C h l o r o e t h o x y ) M e t h a n e 120-83-2 2 , 4 - D i c h l o r o p h e n o l 120-82-1 1 , 2 , 4 - T r i c h l o r o b e n 2 e n e

91-20-3 Naphtha lene

87-68-3 H e x a c h l o r o b u t a d i e n e 59-50-7 4 - C h l o r o - 3 - n e t h y l p h e n o l

77-47-4 H e x a c h l o r o c y c l o p e n t a d i e n e 88-06-2 2 , 4 , 6 - T r i c h l o r o p h e n o l

91-58-7 2 - C h l o r o n a p h t h a l e n e

131-11-3 Dimethyl P h t h a l a t e 208-96-8 Acenaphthylene

(1) - Cannot be s e p a r a t e d from d ipheny lamine

Date Repor ted : 0 1 / 0 5 / 8 8

Sampl

Date

Date Type: Point Nortt-Cone.

Date

ug/1 IQU lOU IQU lOU lOU lOU

.e Lab Num Collected Received:

ber 765683 : 12/9/87 12/9/87

Miscellaneous ;: MU lt3B Hr: 1100 ) Sea Landfill Factor: 500 Cone.: Low

Ext: 12/14/87 Date Anal: 12/17/87 C.A.S. Number 83-32-9

51-28-5 100-02-7 121-14-2 606-20-2 84-66-2

lOU 7005-72-3

lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

lOU lOU

lOU lOU

lOU

lOU lOU

amine

86-73-7

534-52-1 86-30-6

101-55-3 118-74-1 87-86-5 85-01-8

120-12-7 84-74-2

206-44-0 129-00-0

85-68-7

91-94-1 56-55-3

117-81-7 218-01-9 117-84-0 205-99-2 207-08-9

50-32-8 193-39-5 53-70-5

191-24-2 92-87-5

Acenaphthene 2,4-Oinitrophenol 4-Nitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene

Diethylphthalate 4-Chlorophenyl-phenylether

Fluorene 4,6-Dinitro-2-Methyiphenol

N-Ni trososdi phenyl am i n e d )

4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate

Fluoranthene Pyrene

Butylbenzylphthalate 3,3*-Dichlorobenzidine Benzo(a)Anthracene bis(2-Ethylhexyl)Phthalate

Chrysene Di-n-Octyl Phthalate Benzo(b)Fluoranthene Benzo(k)Fluoranthene

Benzo(a)Pyrene Indeno(1,2,3-cd)Pyrene Dibenzo(a,h)Anthracene

Benzo(g,h,i)Perylene Benzidine

i c i c * * * t * t x K n t l t *

*

X / t * X X X X 1

/yohn J.

X

/l J *

t x x x x x x

Molloy, P.E. •Laboratory Director

ug/1 lOU 50U SOU lOU lOU lOU lOU lOU SOU lOU


lOU 20U IDU

3508 lOU lOU lOU lOU lOU lOU lOU lOU

sou

Scan

1514

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I l i C y ^ m LABS, INC. 575 BROAO HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. MW « 3 B

7 6 5 6 8 3


t t % I 1 Estimated ' C.A.S. 1 IProbability! Scan I Concentration Number ! Compound Name i Fit 1 *t 1 ug/1

1 Unknown ! ! 182 1 34J,B 1 Unknown 1 ! 220 ! lOJ !Unknown I I 357 ! 30J I Unknown I I 656 I 8J

112050 iNonanoic acid ! 70 ! 678 ! 86J !Decanoic acid I ! 911 ! lOJ I Unknown ! I 984 ! 6J

3774525 IThiocyanic acid- 1 1 1 1 4-hydroxyphenyl ester 70 1 998 ! 14J

21964498 11,13-Tetradecadiene 1 89 1 1246 1 lOJ

! ! ! I I

* * * * * * * * * * * * * *

Date Reported: 01/05/88 rohn J. Molloy, P.E, Laboratory Director

in tn >

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Sample Lab No. 765683 Date Collected: 12/9/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «3B Hr: 1100 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/14/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 5V-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5

alpha-BHC beta-BHC delta-BHC gamms-BHC (Lindane) Heptachlor Aldrin Heptachlor Epoxide Endosulfan I Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-DDD Endosulfan Sulfate 4,4'-DDT Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

05U 05U 05U 05U 05U 05U 05U

0.05U/ O. lOU O. lOU O.lOU.

o.lou/ 0. lOU 0, lOU 0. lOU 0. SOU O. lOU

SOU 0 u SOU

0. sou 0. sou 0. sou 0. sou 1.0 u 1. o u

0, 1. o.


Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

> l ! : * * * * X * * > > c * A 3 c » : 3 i K

A rf * * «*3l:*3>c3*;***:3ie

y hn J. Molloy, P.E. Laboratory Director

tn rn >

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CJ Ul

H2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY, 11747 • 516-694-3040




765683


C. A. ! 1 ! RT ! Estimated !

S. ! ! \ u \ Concentration! Number 1 Compound Name ! Fraction I min ' ug/1 I

.......

—

..._.

1 No Unknowns Found 1 Pest I — 1 0.2U I

;- - -- \ - \ ' - — \ |-

1 I ! I I

1 I I ) 1 1 1 1 1 1

1 I I I 1 1 I I I 1

— -

1 I I I 1

* * x * * * * x x * * * * *

Date Reported: O1/07/88 A X X X :*: A >c

) h n J . M o l l o y , P . E . ( l a b o r a t o r y D i r e c t o r

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l i2M PAG OF


575 Broad Hollow Road, Melville, New York 11747-5076 • (516)694-3040

Water/Waste Water Laboratory » Hazardous Waste Laboratory • Air Testing Laboratory Pilot Plant Studies and Ottter Analytical Services

LABORATORY REPORT

LAB NO. 765A82 PRn.lFCT HO. SHHP aM5 L i U


TOWN OF SOUTHAMPTON

HAMPTON ROAD


TYPE OF SAMPLE - MISCELLANEOUS DATF COLLECTED - 12/ 9/87

MW #38 (1100 HRS.) NORTH SEA LANDFILL FULL CLP f, COC

COLLECTED BY VH OJ DATE RECEIVED - 12/ 9/87

PARAM-RFSULT

PARAM-ETER RESULT

PARAM-ETER RESULT

PARAM-ETER RESULT

ANTI-MQNY <rt0.0 #

SELEN- DISS. nJM <5.Q0«»Jt-' CADMIUM <5tOQ»

DISS. ZIHC so»o *

ARSFNTC- 1^.0 • SILVER 0 • DISS. TRON .10000 •

BERYl.-LIUM <5.Q0*

THAL-LTUM <llQtQ t

DISS. COPPER <?.0,Q f

DISS. MAN61 30>Q f

CAHMTUM <S.QO» ZINC _yo.o » DISS. LEAD <g«QOt CYANIDE <10.0 *

CHROM-lUM <10>0 • IRON 36400 f

DISS. MERCURY 0.30t PHENOLS <1.00»

COPPER 100.• MANOA-

NESE 30<>0 • DISS*

NICKEL <'40»0 * N02-N 4

N03-N <0.10

.EAD DISS.

17.0 * ^ milJL <.M,<> f DISS.

SELENI <5.00» AMMONIA (NH3-N) A!b5

MERCURY Q.3Q» DISS.

ARSENIC ^ • Q f PISS.

SILVER <IQ>0 • T. ORO. CARBON 13.1

NICKEL <40.0 * DIS BE-RYLLIUM <S.00t

DISS. THALL. <10.0 •

T. DISS SOLIDS >JAO.

REMARKS - BILLS X REPORTSICLV

ALL RESULTS IN (MR/L) E.XCEPT AS NOTED BY t (UG/L) OR X (PERCENT) T.COLI BACT. R FECAL COLI (MPN/IOOML) COLOR7 ODORf TURBIDITY f, PH (UNITS) APC t FECAL STREP (COUNTS/ML)

105) SETT.SOLIDS(ML/L) /.GTO 300 V3S

AND DATE REPORTED 2/S/R8

L BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID

H2H LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765684 Date Collected: 12/09/87 Date Received: 12/09/87 Point: MW «3C Hr: 1230 North Sea Landfill Date Ext: 12/16/87 Date Anal: 12/16/87 Conc./Dil. factor: 1.1 Cone: Low


Scan *» C A . S. Number

74-74-75-75-

123 75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

449 108-108-100-541-95-

106-

-87--83--01--00--09--35--34--60--66--02--69--55--23--27--87--02--01--48--00--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7


ug/1

lOU lOU lOU lOU 2BJ 5U 5U 5U 5U 5U 5U 5U SU SU 5U SU 5U SU 5U SU 5U lOU SU 5U SU 3J 5U 5U SU 5U 5U

Date Reported: 12/31/87 ****************

'yi ' i i . \Li7<.M > —• * * * ' * * * * * * * * * * * * * J o h n J . M o l l o y , P . E . L a b o r a t o r y D i r e ; c t o r

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CO OD

l i2Ai LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040




765684


1 I 1 I

C.A.S. ! 1 Number ! Compound Name I 124-38-9 1 Carbon dioxide

1

' 1

1

\ 1

1 1

1 1 „ _,. 1 1 1

1

1 1

1

1 t _ _ 1

1

1

1 1

» 1 1

1

% 1 1 Estimated 1 Probability 1 Scan ! Concentration I Fit IRFit ! « 1 ug/1 1 99 1 83 1 11 ! 9J,B 1

I I I >

1 1 1

1 1 1 1 I * 1 1 1 1 j„ „_ ._ ^ .. . _ J-

1 t 1 V 1 1 I I . 1

1 1 1 1 1 1

t 1 1 1 1 1

1 1 t 1 1 1

1 ' ,,,, •

_ 1... 1 : 1 1 1 t ' — *—

1 . L 1 1 t 1 1 _ ^ 1 _

1 t 1 ]

1 I t '

1 I I 1 1 1 1 ......I


************** * *

* * * * * * * * * * * * *

I,''John J. Molloy, P.E. Laboratory Director

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t U M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Scan i

C.A.S. Number 65-75-9 108-95-2 111-44-4 95-57-8

541-73-1 106-46-7 95-50-1

39638329 bi 621-64-7 N-

67-72-1 98-95-3 78-59-1 88-75-5

105-67-9

N-Nitrosodimethylamine Phenol

bis(2-Chloroethyl)ether 2-Chlorophenol 1.3-Dichloroben2ene l,4-Dichloroben2ene 1,2-Oichloroben2ene

s(2-chloroisopropyl)ether Nitroso-Di-n-Propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Oiniethylphenol

111-91-1 bis (2-Chloroethoxy)Methane 120-83-2 2,4-Dichloroohenol 120-82-1 1, 2, 4-Trichlorobenrene 91-20-3 Naphthalene

87-68-3 Hexachlorobutadiene 59-50-7 4-Chloro-3-Methylphenol

77-47-4 Hexachlorocyclopentadiene 88-06-2 2,4, 6-Trichlorophenol


131-11-3 Dimethyl Phthalate 208-96-8 Acenaphthylene

Sample Lab N Date Collect Date Receive Type: Miscel Point: nu «3 North Sea La Cone. Factor Date Ext: 12

C.A.S. ug/1 Number lOU 83-32-lOU 51-28-lOU 100-02-lOU 121-14-lOU 606-20-lOU 84-66-lOU 7005-72-lOU 86-73-

534-52-

86-30-

umber 765684 ed: 12/9/87 d: 12/9/87 laneous C Hr: 1230 ndfill : 500 Cone.: Low /14/87 Date Anal: 12/17/87

lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

lOU

lOU

lOU lOU

lOU

lOU lOU

101-55-118-74-87-86-

85-01-120-12-84-74-

206-44-129-00-

85-68-7 91-94-1

56-55-3 117-81-7 218-01-9

117-84-0 205-99-2 207-08-9

50-32-8 193-39-5 53-70-3

191-24-2 92-87-5

Acenaphthene 2,4-Dinitrophenol 4-Nitrophcnol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Diethylphthalate

4-Chlorophenyl-phenylether Fluorene 4,6-Dinitro-2-Methylphenol

N-Nitrososdiphenylamine(l)

4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene


Butylbenzylphthalate 5,3'-Dichlorobenzidine Benzo(a)Anthracene bis(2-Ethylhexyl)Phtha Chrysene Di-n-Octyl Phthalate Benzo(b)Fluoranthene Benzo(k)Fluoranthene Benzo(a)Pyrene

Indenod, 2,3-cd)Pyrene Dibenzo(a,h)Anthracene Benzo(g,h,i)Perylene Benzidine

ug/1 lOU SOU 50U lOU lOU 100 lOU lOU

sou lOU


lOU 20U lOU

late 250B lOU lOU lOU lOU lOU lOU lOU lOU

sou

Scan

1515



X j h n t *-« T Y T x i » « X

/i'ot\T\ J . Mol loy, P.E. ' l abora to ry D i rec tor

in cn >

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t i2M LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY. 11747 • 516-694-3040




765684


C. A... S_^ Number Compound Name

!Unknown 2196 4 4 981.1,13 - T_e t r.ade c adi ei e

% Probability

Fit

87

Scan

._-18.5... 1246

Estimated Congent_rajt,io.n I

ug/L__..l.._.Jj 5QJ.j,.B_ 3DJ

Date Reported: 01/05/88 '******

Molloy., P.E Laboratory Director

CO tn >

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l i2Ai LABS, INC. 575 BROAD HOLLOW ROAO. MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765684 Date Collected: 12/9/87 Date Received: 12/9/87 Type: Miscellaneous Point: MW «3C Hr: 1230 North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext. 12/14/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5

alpha-BHC beta-BHC delte-BHC gamma-BHC (Lindane) Heptachlor Aldrin Heptachlor Epoxide Endosulfan I Dieldrin 4,4'-DDE Endrin Endosulfan II 4,4'-DDD Endosulfan Sulfate 4,4'-DDT Methoxychlor Endrin Ketone Chlordane Toxaphene Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260

O. 0. 0. 0. 0. 0.

o.

05U 05U 05U D5U 05U 05U 05U

0.05U-O. lOU 0. lOU O. lOU 0. lOU O. lOU O. lOU O. lOU

sou lOU

o. o. o. sou 0 u 50U sou sou sou

o. sou 1.0 u 1.0 u

Vi = Volume of extract injected CuL) Vs = Volume of water extracted (mL) Vt = Volume of total extract (mL) Ws = Weight of sample extracted (g)

Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

**************

*»* *********** ^-ohn J. Molloy, P.E. Laboratory Director

CQ m >

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l i2A i LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE. NY 11747 • 516-694-3040



Samp le Lab No. MW «3C

765684


Number

• - — -

—

! Compound Name 1 Unknown i Unknown f

1

1

1

1

1

1

1

t

1

1

J Fraction I ! Pest ! 1 Pest !

'"T ' ~ _L. -.. - -

•-

- - • • — ••

„..! .

- • ' — — — " " • " "

1

1

RT n 1

min ! 15-934! 34-410!

• '

- .

r

1

• _.- - ~-1

I 1

1 1

1 ... —

]

1 ._ .-


uo/1 1. 0.23J 1. 0-23J „ L

1

1

' 1

1

1

1

1

1 .. _- " j 1

J ( j 1

! ... ' 1 _..!.

Date R e p o r t e d : 0 1 / 0 7 / 8 8

; * * * * * * * * * * « « *

Lb^^4iii lr**** rohn J . M o l l o y , P . E .

l a b o r a t o r y D i r e c t o r

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l i2M t U M LABS, INC. Environmental Testing Laboratories

575 Broad Hollow Road, Melville, New York 11747-5076 •(516) 694-3040


PA( . 0

LABORATORY REPORT

LAB NO. 765A85 PRn-IFCT » n . SHMP RAO?i I ft


TOWN OF SOUTHAMPTON

HAMPTON ROAD

SOUTHAMPTONf NY U948

TYPE OF SAMPLE DATE COLLECTED

MISCELLANEOUS 12/ 9/87

COLLECTED BY VH 03 DATE RECE.TVEn - 12/ 9/P7

MW t3C (1230 HRS.) NORTH SEA LANDFILL FULL CLP t COC

PARAM-ETER RESULT

PARAM-ETER RESULT

PARAM-ETER RESULT

PARAM-ETER RESULT

ANTI-MQNY <60«0 •

SELFN- DISS, lUM <5.00»Mg CADMIUM <5.00»

DISS. ZINC 20.0 •

ARSENIC <tQtQ • SILVER <310,0 • DISS*

CHROMt 310>Q t DISS. IRON HBQtt

BERYL-LIUM <5.00«

THAL-LIUH <tQ>0 •

DISS. COPPER 2QtQ •

DISS. -MftNOt 3 Q t Q »

CADMIUM <S.00» ZINC 80.0 • DISS. LEAD <5.00t CYANIDE <10.0 •

CHROM-lUM 30.0 • IRON 2700 •

DISS. MERCURY <0.20» PHENOLS <1.00»

COPPER 110.t MANUA-NESE 90.0 t

DISS. NICKEL <40.0 •

N02-N + N03-N <0.10

LEAD A2,(i fS DISS. ANTIHt <6Q.O •

DISS. SELEN, <3.00»

AMMONIA (NH3-N) <0.02

MERCURY 0.40* DISS.

ARSENIC <IQtQ f DISS.

SRVER <10tQ f T. ORO. CARBON 3.30

NICKEL DIS BE- DISS. T. DISS

<<>0.0 f RYLLIUM <S.00f THALL. <1Q.0 • SOLIDS 180.

REMARKS - BIILS T. REPORTS tCLV

ALL RESULTS IN (MO/L) EXCEPT AS NOTED BY t (UG/L) OR X (PERCENT) AND T.COLI BACT. ?. FECAL COLI (MPN/IOOML) COLORi ODOR» TURBIDITY S PH (UNITS) APC 8 FECAL RTRF.P (COUNTS/ML)

HOS) SFTT.SOLUiS(ML/L) ^^TO ^ 0 ^ ^ ^ LL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

DATE REPORTED 2/ 5/88

H2H LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765686 Date Collected: 12/09/87 Date Received: 12/09/87 Point: Field Eauip. Blank North Sea Landfill Date Ext: 12/16/87 Date Anal: 12/16/87 Conc./Dil. factor: 1.1 Cone: Low


Scan ** C.A.S. Number ug/1

123

448

74-74-75-75-75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

108-108-100-541-95-

106-

87-3 83-9 01-4 00-3 09-2 35-4 34-3 60-5 66-3 02-2 69-4 55-6 23-5 27-4 87-5 02-6 •01-6 •48-1 •00-5 •43-2 •01-5 -75-6 -25-2 -18-4 -34-5 -88-3 -90-7 -41-4 -72-1 -50-1 -46-7

Chloromethane lOU Bromomethane lOU Vinyl Chloride lOU Chloroethane lOU Methylene Chloride 6B 1,1-Dichioroethene 5U 1,1-Dichioroethane SU cis/trans-1,2-Dichloroethene 5U Chloroform 5U 1,2-Dichloroethane 5U Trichlorofluoromethane SU 1,1,1-Trichloroethane 5U Carbon tetrachloride 5U Bromodichloromethane 5U 1,2-Dichloropropane 5U trans-l,3-Dichloropropene 5U Trichloroethene 5U Dibromochloromethane 5U 1,1,2-Trichloroethane SU Benzene 5U cis-1,3-Dichloropropene 5U 2-Chloroethylvinylether lOU Bromoform 5U Tetrachloroethene 5U 1,1,2,2-Tetrachloroethane 5U Toluene 2J Chlorobenzene 5U Ethylbenzene 5U 1,3-Dichlorobenzene 5U 1,2-Dichlorobenzene 5U 1,4-Dichlorobenzene 5U

Date Reported: 12/31/87 ****************


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H2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY 11747 • 516-694-3040



Sample Lab No. 765686 Field Blank


C.A.S. Number Compound _i |ame_ 124-38-9!Carbon dioxide

% Probability

F i t 1 0 0

R F i t 8 5

_Scan_ E:5t_im

u g /

a t e d _! r a t _ i o n I 1 """ 1

1 1 ..6J^. B

_ I J ! ! ., „ L ""l" t t t <

1 7""" I T " 1 ! L I ! L. I I I I I I I ! ! i..

' 1 " ' 1 1 1 I I I 1 1 . _ J...

* * * * * * * * * * * * * *

Date Reported: 12/31/87 V-]. ] - ,^_.^ ^ ^ * ys fVs«>* * * *««* * Cf'ohn J . M o l l o y , P .E . L a b o r a t o r y D i r e c t o r

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H^M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040


Town of Soutfiampton Hampton Road Southampton, NY 11968

Scan C.A.S. Number 65 -75 -9

108-95-2 111-44-4

9 5 - 5 7 - 8

541-73-1 106-46-7

9 5 - 5 0 - 1 39638329 b 621-64 -7 N

67-72-1 98-95-3 7 8 - 5 9 - 1 88 -75 -5

105-67-9

N - N i t r o s o d i m e t h y l a m i n e Phenol b i s ( 2 - C h l o r o e t h y l ) e t h e r 2 - C h l o r o p h e n o l l , 3 - D i c h l o r o b e n 2 e n e 1 , 4 - D i c h l o r o b e n z e n e 1 , 2 - D i c h l o r o b e n z e n e


Hexach lo roe thane N i t r o b e n z e n e I sopho rone 2 - N i t r o p h e n o l 2, 4 - D i i n e t h y l p h e n o l

111 -91 -1 b i s { 2 - C h l o r o e t h o x y ) M e t h a n e 120-83-2 2 , 4 - D i c h l o r o p h e n o l 120 -82 -1 1 . 2 , 4 - T r i c h l o r o b e n z e n e

91-20-3 Naph tha lene

87 -68 -3 H e x a c h l o r o b u t a d i e n e 59-50-7 4 - C h l o r o - 3 - M e t h y l p h e n o l

77 -47 -4 H e x a c h l o r o c y c l o p e n t a d i e n e 88 -06 -2 2 , 4 . 6 - T r i c h l o r o p h e n o l

91 -58-7 2 - C h i o r o n a p h t h a l e n e

131-11-3 D i m e t h y l P h t h a l a t e 208-96-8 Acenaph thy lene

(1) Cannot be separated from diphenylamine


Saapl

Date Date Type:

Point

.e Lab Number 765686 Collected Received:

: 12/9/87 12/9/87

Miscellaneous :: Field Eouipaent Blank

North Sea Landfill Cone. Date

Ufl/l lOU lOU lOU lOU lOU lOU

Factor: ! 500 Cone.: Low Ext: 12/14/87 Date Anal: 12/17/87 C.A.S. Number

83-32-9 51-28-5

100-02-7

121-14-2 606-20-2

84-66-2 lOU 7005-72-3 lOU lOU lOU lOU lOU lOU lOU

lOU lOU lOU lOU

lOU lOU

lOU lOU

IQU

lOU lOU

Sffline

86-73-7 534-52-1 86-30-6

101-55-3 118-74-1 87-86-5 85-01-8 120-12-7 84-74-2 206-44-0 129-00-0

85-68-7 91-94-1 56-55-3 117-81-7 218-01-9 117-84-0 205-99-2 207-08-9 50-32-8 193-39-5 53-70-3 191-24-2 92-87-5

Acenaphthene 2,4-Dinitrophenol 4-Nitrophenol

2,4-Dinitrotoluene 2,6-Dinitrotoluene

Diethylphthalate 4-Chlorophenyl-phenylether

Fluorene 4,6-Dinitro-2-MethyIphenol N-Nitrososdiphenylamine(l)

4-Broniophenyl-pheny lether

Hexachlorobenzene

Pentachlorophenol Phenanthrene Anthracene Di-n-Butylphthalate Fluoranthene Pyrene

Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)Anthracene bis(2-Ethylhexyl)Phthalate

Chrysene Di-n-Octyl Phthalate Benzo(b)Fluoranthene Benzo(k)Fluoranthene Benzo(a)Pyrene Indeno(1,2,3-cd)Pyrene Dibenzo(a,h)Anthracene

Benzo(g,h,i)Perylene

Benzidine

X X X X X X X X X X X X X X

X ^ X

X y x X. X x x x x x x x x x

/'ohn J. Molloy, P.E. Laboratory Director

ug/1 lOU SOU SOU lOU IDU lOU lOU lOU

sou lOU

lOU lOU SOU lOU lOU lOU lOU IQU

lOU 20U lOU 72B lOU lOU IQU lOU lOU lOU lOU lOU SOU

Scan

1514

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HIM LABS, INC. 575 BROAD HOLLOW ROAD. MELVILLE, NY. 11747 • 516-694-3040



Sample Lab No. Field Blank

765686


C.A.S. Number

I % , IProbability

Compound Name 1 Fit Unknown !

- \

- — — — • ; •

Scan _

184

-~

Estimated I Concentration!

_"' ug/1 ._. J 60J,B !

1 1

I 1

t

1 1 1

I 1

1

1

I 1

1 1

1 t

1 1

1

1 t

r 1

1

1

] I t

**************

Date Reported: 01/05/88 * * ^ ** * jr*Tk * * * * * *

Jfohn J. Molloy, P.E. Laboratory Director

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l i2M LABS, INC. 575 BROAD HOLLOW ROAO, MELVILLE, NY 11747 • 516-694-3040



Sample Lab No. 765686 Date Collected: 12/9/87 Date Received: 12/9/87 Type: Miscellaneous Point: Field Equipment Blank North Sea Landfill Collected By: VH 03 Concentration: Low Cone. Factor: 333 Date Ext, 12/14/87 Date Anal. 12/18/87

C.A.S. NUMBER ug/1

319-84-6 319-87-7 319-86-8 58-89-8 76-44-8 309-00-2 1024-57-3 959-98-8 60-57-1 72-55-9 72-20-8 33213-65-9 72-54-8 1031-07-8 50-29-3 72-43-5 53494-70-5 57-74-9 8001-35-2 12674-11-2 11104-28-2 11141-16-5 53469-21-9 12672-29-6 11097-69-1 11096-82-5


0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 0. 0. 0. 0. 0. 1. 1,

05U 05U 05U 05U 05U 05U 05U 05U lOU lOU lOU lOU lOU lOU lOU SOU . lOU

sou .0 u .sou , sou . sou . sou .sou .0 u .0 u


Vs = 500 mL Vt = 1.5 ml


Vi = 5 uL Ws =

**************

Molloy, P.E. Laboratory Director

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HIM LABS, INC. 575 BROAD HOUOW ROAD. MELVILLE. NY 11747 • 516-694-3040





CÂ- s..-_. Number Compound Name_ Fraction

i N.? ..yn!iQ9wn§__Foy!i>cL i. Pest

RT

m m

Estimated Con c «Mltr a t i o n

ug7l , 0. 2U

**************

Date Reported: 01/07/88 /ohn J. Moiioy, P.E. Laboratory Director

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Water/Waste Water Laboratory • Hazardous Waste Laboratory • Air Testing Laboratory Pilot Plant Studies and Ottier Analytical Services

LABORATORY REPORT

LAB NO. 7 4 S A 8 7 PRO.IFCT MO. SHMP BAOS L A ^


TOWN OF SOUTHAMPfON

HAMPTON ROAD

SOUTHAMPTONI NY 11948


FIELD EQUIPMENT BLANK NORTH SEA LANDFILL FULL CLP R COC

COLLECTED BY VH 03 DATE RECFIVED - 12/ 9/B7

PARAMETER RESULT

PARAMETER RESULT

PARAM-ETER RESULT

ANTI-MONY <:<SQ>0 f

SELEN- AMMONIA lUM <5.00 <vfer (NH3-N) <0.02

ARSENIC T. ORO.

<1Q.0 t SJLyEfi <t0.Q » CMBffiN <0.05 BERYL

LIUM <5.00» THALLIUM <10.0 •

T. DISS SOLIDS <5.00

CADMIUM <5.00# ZINC ?0.0 * CHROM-

lUM <10.0 t IRON 110.*

COPPER <20.0 t MANOA-

NESE <20.0 *

LEAD <5.00* CYANIDE j ^ * t \ yv A

•s 1 M . M #

MERCURY <0.20t PHENOLS <l.00#

NICKFL < A 0 , 0 • N02-N +

N03-N <0.10

REMARKS - BILLS % REPORTSICIV

ALL RESULTS IN (MO/L) EXCEPT AS NOTED BY t (UG/L) OR X (PERCENT) AND T.COLI BACT. I FECAL COLI (MPN/IOOML) C0LOR» O00R» TURBIDITY X PH (UNITS) APC I FFPAi "'REP (COUNTS/ML)

„„c 'HOS) SFTT.SOLIOS(ML/L) 300 ^3S TSTO •ALL BE LIMITED TO THE PRICE OF THE SERVICE RENDERED AND PAID.

PATE REPORTED 2 / S / P 8

H2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040



Sample Lab No. 765688 Date Collected: 12/09/87 Date Received: 12/09/87 Point: Trip Blank North Sea Landfill Date Ext: 12/16/87 Date Anal: 12/16/87 Conc./Dil. factor: 1.1 Cone: Low


Scan

122

450

n « C A . S. Number

74-74-75-75-75-75-75-

156-67-

107-75-71-56-75-70-

10061-79-

124-79-71-

10061-110-75-

127-79-

108-108-100-541-95-

106-

-87--83--01--nn--09--35--34--60--66--02--69--55--23--27--87--02--01--48--OO--43--01--75--25--18--34--88--90--41--72--50--46-

-3 -9 -4 -3 -2 -4 -3 -5 -3 -2 -4 -6 -5 -4 -5 -6 -6 -1 -5 -2 -5 -6 -2 -4 -5 -3 -7 -4 -1 -1 -7

Chloromethane Bromomethane Vinyl Chloride Chloroethane Methylene Chloride 1,1-Dichloroethene 1,1-Dichloroethane cis/trans-1,2-Dichloroethene Chloroform 1,2-Dichloroethane Trichlorofluoromethane 1,1,1-Trichloroethane Carbon tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-1,3-Dichloropropene 2-Chloroethylvinylether Bromoform Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene 1,3-Diehlorobenzene 1,2-Dichlorobenzene 1,4-Diehlorobenzene

ug/1

lOU lOU lOU lOU U B 5U 5U 5U 5U SU 5U 5U SU SU 5U SU 5U 5U SU 5U SU lOU SU 5U SU 2J 5U 5U SU 5U 5U

Date Reported: 12/31/87 3ic4:*L*A:^3fe::#cX«:3K3tc**:ii:A

^J£K1JJ-

.ilohn J. Molloy, P.E. Laboratory Director

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ti2M LABS, INC. 575 BROAD HOLLOW ROAD, MELVILLE. NY. 11747 • 516-694-3040

HOLZMACHEa McLENDON and MURRELL, PC. • ENVIRONMENTAL and INDUSTRIAL ANALYTICAL SERVICES


Sample Lab No. 765688 Trip Blank


C.A.S. Number

....__.

! % !.. _ ! _ _ E s t i mated _. 1_ !Probability! Scan ! Concentration!

Compound Name ! Fit IRFit ! « ! ug/1 ! No Unknowns Found ! — ! — ! — ! 5U !

t i l l 1 1 1 1 1 t

1 I I 1

___ _._ _ ! ! 1 ! _, _ _ _ . . \ . . _ . 1 1 1

I I I ! ! ! I 1 ! ! ! 1

... ,_ _ 1 I I 1 !

: * : > i t * * » : * * * * * : * * * *

D a t e R e p o r t e d : 1 2 / 3 1 / 8 7

/,,;. t Sk * * t V ^ * * * * *

/ / J o h n J . M o l l o y , P . E , L a b o r a t o r y D i r e c t o r

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H2M LAES, INC.

III. 2. Reporting Package for ID n MW «1A

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1 \T"rij2^ ttm^xmm t» fmt»u C # r ** C«»if . . X . f M V " W

gSTO 200 VaS

L J L / ^ IL Ltjtoi^rom

Ocntiaiino Chain cf Qatody Page 1

Sanples JteOBivad t y T»>vv MÛ«\

Signature AA M - ^

datt i»-\^vn .\rlt tdae ^*^«' «H^/

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RIC DATA: PU7e43 #1 SCANS 12/14/87 2 0 : 3 2 J 0 0 C A L I : PU7843 *2 SAMPLE:-êHeBW ^^^-^ r ^ s r s ^ O A I W » / / }

COHDS.: RANGE: G h i e e O LABELi N e^ 4 . 6 (ÛAN: A 6 ; 1.0 J 0 BAÊ: U 20..

1 TO 1000

100.0-1

RIC

n

O

(U

ii^ O V , U.H

N

OJ »H

O . UJk-

$ * H O ZUJ

U.S H

< • O l-l

49

\ /

0 (*.

\ 239 4"

r 131

0

r

" 1 — 200

10:uu

381

o o

T i A n> s

454

t

•100 ' •( I • I l i t

»<»

1 A.

1 ^

)c::i» 0 0

4

'v/ •-'.'V.'f^ / *

617

(P

r

v.,

filV-• ; : ( i .

883712 .

791 .q-iR

'I V

800 .ir*. rift

— 1

1000 SCAH

QuANTXT.-Txoiv REPORT Fxi_E. FU7843

DAT/^. PU78A3 T I 1 2 / 1 4 / 5 7 20: 32.- 00 S A M P L E 5MLS «W-#1A 7 6 5 5 6 9 CONOS. •

S U B M I T T E D BV: NO. SEA A N A U V S T : S S

AMOUNT=AREA * REF AMNT/(REF AREA « RESP FACT) R e S P . F A C . F^ROM L i B R A R V E N T R V No 1 2 3 4 5 6 7 8 9

10 11 12 13 14 15 16 - ~J

T '

BROMOCHRLOROMETHANE (INT. STD. ) 1.2-DICHLOROETHANE 04 (SURR. STO) CHLOPOI«THANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE MET.-.VLENE CHLORIDE (C) ACETONE CARBON DISULPHIDE 1.1-DICHLOROETHENE (B) 1,1-DICHLOROETHANE(£) TRA-J5 -1/2-DICHLOROETHENE (D) CHLOROFORM 1,Z-DICHLOROETHANE(H) TRICHLOROFLUOROMETHANE L'l.rHl OROFLUOPOMETHANE r.,--r- r v < ^ _

... L'.CF :L':!•::::!.NL (INT. S T O >

:iCl-..OfVOr:iHAUE (I) •E:-i.Ac:-'. 0R1CE( J)

26 27 28 29 30 31 32 33 34 35 36

38 39 40 41 42 43 44 45 46 47 4B 49

N Q 1 2 3 4 5 6 7 e-a. 10 11 12 13 14 15 4M~

• Z J ' HLCROF-f-.uP -:Ar-.'E < L >

•ANE(X) T-/V .: X. 3-C'ICf-!L0R0PR0PENE

"(•-1 •:-!(. CÔETHENE -: K ) D I . & F O M O ' J H L O R O M E T H A N E ( 0 ) 1 . 1 , 2 - T K I C H R 0 E T H A N E ( M ) BENZENE(BEN) C I 5 - 1 . 3 - D I C H L 0 R 0 P R 0 P E N E ( Z )

(AA)

Br-00 r ' . y •

a - •

.OrÔETHYLVINYLETHER (NN) •'r::RM < F' ) : L E N Z E N E - D 5 ( INT . STD)

' - ••lOfjE; I. MBK ) • '-.f--' E N T A N O N E ( M I B K )

' . ro - , - ^ . r : . _OF :OETHENE(N) E'^v.-,,., , I , Z, C - T E T R A C H L O R O -T C L ' - L ' H L V "i OL: C K L 0 F 0 B £ N Z E N E ( Q ) ETHYLBENZENE(EB) BTVPENE META-XYLENE OFTi-0,^PARA-XYLENE M E T A - D I C H L O R O B E N Z E N E (MDCB) O r r ^:-CICHLOKOBENZENE (ODCB) F f f . - D I C H L O R O B E N Z E N E ( P D C B ) D>.---OLUENE(SURR. STD) E. '- •FLUORBENZENEfSURR. STD)

ise 65 50 94

NOT 64 84

S C A N 187 239 27 60

FOLWD 96

131 *e6-

TlME 9

11 1 3

21 37 21 00

R E F 1 1. 1 1. 1 0. 1 0.

4: 48 6:33 5' 10

1 1

RRT 000 278 144 321

513 701

0. 0. «:• 66-7 A«OV'

M E T H A B6 A BB A BV A BV

A BB A BV

-d^ 6' Dl 96 63 96 r - : 6Z

lei — 86

180 198 211 228 23? 151 -70

9: 00 9:54

10: 33 11: 24 11: 57 7: 33

1 1 1 1 1 1 -i-

0. 1. 1. 1. i. 0. -9r

»7^ A PB

A R E A < H G H T ) 356004. 480795.

1983. 4140.

1183. 16033S. lOOBQ.

A M O U N -50. 00e 40. 68e 0. 211 0. 54€'

0. 147 11. 50*

UG/L UG/L UG/L UC/L

UC/L UG/L

963 059 128 219 278 807

A*BV A 68

BB BB BB BB

IftLi^. Sl ass iiiCifL

A>OD

8425. 786.

1319. 14016. 1633. 908. aaao.

a». 101 UC/L

%TOT 9. 43 7. 67 0. 04 0. 10

0. 03 2. 17 la. 9P.

0. 83Z 0. 03E 0. 124 0. 495 0. 066 0. 051

OC/L UG/L UC/L UC/L UG/L UG/L

a. 00 0. 1 6 0. 0 1 0. 0 S 0. 0 9 O. 0 1 0. 0 1 ar ara ^

cn 3"

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• 4 ^ •%i rocaitr

- i « « - 7. ao Ol BQa A«BM aîgiji. mfti a i9 McrL aBi aa 03 19 114 381 19.03 19 1.000 A B B 1424190. 50. 000 UC/L 9. .

21 22

24 25 26 27 28 29 30 31 32 33 34

' i i ^

1 1 V

6. S l ^ l^ GO an/\%/\. uc/u - < e — » * * -

83 63 75

130 129

97 78 75 63

1 7 3 117 —*e-

45 46 47 48 49

146 146 146 100

r^«=;

x C

2ZC 261 272 321 330 339 331 337 352 381 482 361

19 0.

13 13 16 16 16 16 16 1 T

03 36 e3 30 57 33 51 36 c. . • (-•

19 19 19 19 19 19 19 19 19 19 o4

0. 0. 0. 0. 0. 0. 0. 0. 0. 1. 1.

554 4)30. 598 685 714 843 866 890 869 885 924 000 000

A 6B A*'iiB

_^765. 3US3G3I

A BB A«-BB A BV A BB A»BB A*BV A VB A BB A BB A BB A EV

0 749 A OP

14016. 4257. 8356. 7761. 3339. 2521.

35336. 48080.

742. 722.

1165390. IDîa.

0. 125 Bl 777

UG/L

0. 903 0. 293 0. SIB 0, 450 0. 273 0. 186 1. 069 5. 152 0. 173 0. 072

50. 000 0. SD'P

UG/L UC/L UG/L UC/L UG/L UC/L UG/L UG/L UG/L UG/L UC/L

•.•?4 '_ JJ

.J . « '

1. 1. J-

C ;;

471 521 521 ^542 i: 1 o

A BB A*eB A«BB A BB A SB

5842 4633 4633

62660? TOlfc'?:-

0. 390 0. 355 0 314 50 ses 44. 978

UG/L UG/L UG/L UG/L UG/L

0. 02 0. 71 O. 17 0 06 0. 10 0. 08 O. 05 0. 04 0. 20 0. 97 0. 03 O. 01 9. 43 &. I O >

37 38 39 40 41

JUU.

164 83 92

112 106 1 rt /I

104

421 419 450 475 509 . ,. ,-.

- • -

21 : C, c C :-• E c ' '-• "7 ' " • ] ' jC '

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• - .

— - . .;

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34

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0. 873 0 869 0. 934 e 985 1. 056 , M ^ ^

l 382

ft gg A BB A BB A BB A*BV A BB

A*sy

957. 3947. 1521. 5238. 679.

3S63

0. 084 UG/L 0. 187 UC/L 0. 078 UC/L 0. 233 UG/L 0. 070 UG/L

— a a 77B i\r.n

0. 02 0. 04 0 01 0. 04 0. 01

M ^ /-X 0. 07 0. 07 0. 06 9 Z3 e. 48

r Y^l/^7

^ ' / I /^9Y^/0 2(r ^ /S

in cn >

o o ts)

o 01 o

DUAL MASS SPECTRUM 12/14/87 20:32:00 + 6:33 SAMPLE: 5MLS MW-#1A 765569 CONDS.: ENHANCED (S 15B 2N 0T)

DATA: PU7843 «131 CALI: FIJ7S43 «I2

BASE M/Z: 49/ 49 RIC: 119235./ 147193.

100.9-1

5 0 . 8 -

r 37184.

1

/ ^ / / t ^ U n ( 7? /c/y/ c6c.

I " ' I ' ' r I ' I I ' l • | ' " i ' - ' - | - i " | - - i • { • I [• I I — I ' V I ' I ' 1 I I I I V I v ' "I—I' ' r I' I "I—I i I

M/Z 5 0 100 150

i ] t l i j | | ' ' l i i ' h ' ' ^ l ^ ' 'Ml t i l '^ ' ''• '• ^ ' ^ " ' ''' '• ^ I T T ' T I T I I I I I, 1 , 1 ^

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I "[' r

250

50 .0 -

j — L H I t-fJ-^L_J—V 1—\2^

T9T0 300 V3S >- 071P IS4.

1006 ir

SAMPLE

C.H2.CL2

?IT 398

LIBRARY SEARCH 12/14/87 20:32:00 + 6:33 SAMPLE: 5MLS MW-«1A 765569 CONDS.: ENHANCED <S 158 2N 0T)

' > • ' ' . " • >

METHYLENE CHLORIDE <C>

DATA: PIJ7843 » 131 CALI: PU7S'i3 » 2

BASE M/Z: 49 RIC: 116095.

T**-< r 'i • • • ] • • • ' — H - — • ' " •••. -I ;«

- 1 — • — r - — I — ' ' I I • I ' • I • I

1006 SAMPLE MINUS LIBRARY

I i-. i, •

29T0 3 0 0 V3S UJ9 -I ' r -

150 zm

19^.0-1

DUAL MASS SPECTRUM 12/14/87 20:32:00 + 16:33 SAMPLE: 5MLS MW-»1A 765569 CONDS.: ENHANCED <S 15B 2N 0T)

DATA: PLI7843 tt.?31 CALI: PU7843 «2

BASE M/Z: 73/ 44 RIC: 23303./ 68863.

5 0 . 0 -

P^ t^z^r?^^

l l

M/Z 50

-f4 1.11 I r - r "l' !• i M 'I 'l ' i ' v ' - i ' ' l ''" I '•' Juuj I I, . 1 1,1 ,, n i l , I

50.0

10P

ITT

100

'itiîjli iÎiitpi'l i i l i l

1—\ ' [ - i ' r - l—[• •!• I ' l ' "r I ' l I "I I V ' 150 200

I - I • • L u I . • . 1 . .1 - I t - l . - i I . 1

1, I ll 1 l l l . l I ta—I l l l . l I }l .1. r ' I '

2\

r 10304.

J u }i>'ii)1iitmi(i\ n ' ' i ' l i ' l j l ' ' M ' f i i i i ' I j i ' m ' I ' l h I n ' H t l' 'i

10304, C9T0 SOO V3S

1000

SAMPLE

LIBRARY SEARCH 12/14/87 20:32:00 + 16:33 SAMPLE: 5MLS MW-#1A 765569 CONDS.: ENHANCED <S 15B 2N 0T>

DATA: PU7843 1» 331 CALI: PU7343 tt 2

BASE M/Z: 78 RIC: 23327.

1.I1I1. .11 l j I . I l l I 1 , 1 i l j l . i l , l i I 1 , l l I 1, I , • .1 , 111. 1 1 i I, , I 1,1 1 1 , i i | l . t , I l l , I ., I . I | i I l i . i I l l . 1 , I 06. H6

RANK „

FIT 837

?8 2

BENZENE<BEH>

SAMPLE MINUS LIBRARY 1800

i.l, I,,.I I l,.lll i l l! Hill I.l I.l I ll . I I I III I I I I 111 It III I I . I I II I l l l l l l . l I.

-1000

1^9T0 ZOO

I ' ' •' " I ' I " 1 —

15<? L'M-.I

V3S ^5G

DUAL MASS SPECTRUM 12/14/87 20:32:00 + 0:45 SAMPLE: 5MLS MW-«1A 765569 CONDS.: ENHANCED (S 15B 2N OT)

DATA: PIJ7843 «15 CALI: PU7843 »2

BASE M/Z: 44/ 44 RIC: 230143./ 343039.

108.01

58.8 —

m

r 297984.

C^c\-i?v y \ ^ C c i y c . e X j ' — '

i-Y r ' I I I I i ' I ' I ' I ' I ' I ' I ' I ' T 1 I I I I 1 I I I I — r — 1 — I I I

M/2 150

50.0-

50 100 151 I..*-L g - g — i 1-,.. J...,...!. 1.1.-4 .1 .I-J--I-J t J I t—I- I- I-

200 250 ^ l-l \ - Y - \ F -I -I I l-l- \ I- I-

5910 300 V3S 297384.

LIBRARY SEARCH 12/14/87 20:32:00 + 0:45 SAMPLE: 5MLS MW-»1A 765569 CONDS.: ENHANCED <S 15B 2N 0T>

DATA: PU7843 » 15 CALI: PU7S43 » 2

BASE M/Z: 44 RIC: 229631.

1006

SAMPLE

I • I n I l.i I I l | l I I , I " > t

CARBON DIOXIDE (ACN) I ; I >• ( « I I I » • > « ;> I . I ) •• .' ( ' • • «| • ' — I ' ' I ' > I ' I i | • • • • I » ' , « ' I ««, i« ) . I • [ I »i» ' .

C.02

»K 44 1

• 31 FIT 1000

U NITROGEN OXIDE (N20)

I • ' " t ' > I • t • I ' I ' • • » ' f

Q.N2

Is -IT H

1

'n* •" t " ' ^ V I " I ' I ' r-—'• t ' * • • • t " " " I 1 t ' I > I I • I I

CYCLOPROPANE.. 1.- l-DIBR0M0-2-CHLnR0-2-FLLI0R0-- J — I — — I — • ' I

;3.H2.CL.BR2.F

• H T "

'^ 1 •• 23714 , IT 982 1

ggXO 300 V3S -1 ' r -

50 100 sn - > — , — . — | -

2m ?50

DUAL MASS SPECTRUM 12/14/87 20:32:00 + 2:27 SAMPLE: 5MLS MU-»1A 765569 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7843 »49 CALI: PU7S4:; ft2

BASE M/Z: 44/ 44 RIC: 87423./ 182815.

08.0 —

58 .8-

r 62976.

ii/) /M{n^yi

1 | i l i i | • ,11 lj •• I . y i i i , i i i 1.1,1 . i p I .|. i | . . ^ 1 . . , . y ,| • . , , • ^ • I n • y . n I • ] ' I ' T I T I '1 " I ' t ' I I ' I ' r ' I ' I '

N/Z 50

3 0 . 0 —

4 i T i i l ^ ' P ' ^ ^

100 T»T|l " | | l | l '^^ l j |TTTri l T i lP1 'P ' ' ' ^ i ^ ' ' ' * ' ^ ' I 'T^

00 150 I'fiO \ ^ . \ - T^SJVTT J77rf777l777J 7 ^ 7 ^ 7 I 77T<- 7 j 7 ^77 j . 7 I 7 ;< T h J " V JT j 7 = t7 j 7l77;t 7I.77I 7t. 7 h ' i

250 3

)0, Z.9T0 3 0 0 V3S 62976.

LIBRARY SEARCH 12/14/87 20:32:00 + 2:77 SAMPLE: 5MLS MW-#1A 765569 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7843 # 49 CALI: PU7843 tt 2

BASE M/Z: 44 RIC: 783^ 5.

1000

SAMPLE

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C7.H14.03

I 6925 FIT 936

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XI .,iJ-4. 2-PENTANOL, 4-METHYL-

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Cr.HlE.D

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TOTAL ION CHROnflTOCRRH F i l e >P39!0 3 S . e - 5 8 e . 0 M U . 2iJL MMlfl 76556.<» BNO 19UL BH392">i r iL HP-2

T I C 408 880 1288 1688 2888 1288

. I ... -1_

Data File: >P3810::B2 Name: 2UL MUIA 765569 BNA hisc: lOUL BN392->lhL HP*2

Quant Out pu t File -P7'810: :QT

BTL^K

Id Flle: !IDXPP::nE Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Operator ID: GLENN Quant Time: 871218 00:34 Injected at: 871217 23:47

01 cn >

o o ts)

to

QUANT REPORT

Operator ID: GLENN Output File: '^P3810::QT Data File: >P3810::B2 Name: 2UL MUIIA 765569 BNA flisc: lOUL BN392->inL HP#2

Quant Rev: 6 Quant Tlme: In jected at:

Dl lut ion Factor:

871218 00:34 871217 23:47

1.00000

BTL*28

ID File: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19: 15

Compound R.T. Scan# Area Cone Un 1 11

1) •l,4-DICHL0R0BENZENE-d4 3) 2-Fluorophenol (SS) 6) Phenol-d6 (SS) 14) *NAPHTHALENE-d8 15) N i t r o b e r f t e n e - d 5 (SS) 26 ) *ACENAPHTHENE-dlO 30) 2-Fluorobiphenyl (SS) 41) 2,4,6-Tribromopheno1 (SS) 42) »PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 59) bis(2-Ethvlhexvl)Phthalate 61) *PERYLENE-dl2

11 8,

11, 15. 13 21, 19, 23. 25. 33. 30. 34. 38.

.81

.78

.51

.56

.52

. 02

.06 ,56 .60 93 ,79 56 ,09

395 246 33 0 579 479 847 751 972 1072 1481 1327 1512 1685

12453 22274 21527 -i33a0 24621 25729 33101 11580 49484 54499 48<'51 16260 47686

40 67.

40. 40

40. 48, 41. 40. 40. 43. 9.

40.

.00

.92

. 0 0

.00

.82

. 0 0 , 17 ,62 ,00 00 68 74 00

ug/mL ug/mL ug/mL ug -mL ijg/rnL

ug/mL ug'-mL ug/mL ug/mL ug/mL ug/mL ug/mL ug-TTiL

9c 62 9'-57 ]9 39 98 98 68 59 44

-7C

Compound is ISTD

in m >

o o Isl

(J

MS data file header from : >P3810

Sample: 2UL MUIA 765569 BNA Operator: GLENN MS 12/17/87 23:47 Misc : lOUL BN392->1ML HP*2 BTL#28 Sys. #: 2 MS model: 70 SLJ/HU rev.: IA ALS * : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records: 2 Source temp.: 0 Analyzer temp.: 280 Transfer line temp. : 0

Chromatographic temperatures Chromatographic times, min. Chromatographic rate, deg/min

30. 4.0 8.0

300. 7.3 0.0

0. 0. 0 0.0

0. 0.0

0. 0. 0 0. 0

>P3810 2UL MUIA 765569 BNA lOUL BN392->1ML HPi^2 35.0 I 500.0 CLP ADC TIC

Upslope: .20 Area Reject: 7993. Max Peaks: 2 Bunching: 1 Dnslope: 0.00 Results File IP3310 Sorted by Time/Area INT

Peak R.T. i\ m m .

1 2

7.49 29. 14

f 1 rst -^can

180 1243

max scan

183 1246

last peak scan height

139 1263

21316 7936

raw area

98217 75635

CO r r area

53172 72504

cor r H max,

73.34 100.00

% of t O t 5 1

42 . 7UV 57.691

Sum of corrected areas: 125676. Summary of Unknowns PBM Library Search and Quantitation

Standard Concentration

1 2 3 4 5 6

Area

40. 0 40.0 40.0 40.0 40.0 40.0

7"5933. 99644.

125932. 137158. 161209. 153654.

Re tent ion T ime

11 15, 21, 25. 33, 38.

81 56 02 60 93 09

Unk nown Window

13 18 23 29 36

, 79 69 ,29 31 77 01

13.69 18.29 23.31 29.77 36. 01 45.03

Dilution Factor (OF) -Amount Method (AM) -

1.00 Fractional Solids (FS) 0.00 Amount Used (AU)

1. 00 0. 00

Correction Factor • •••••*•• (AM / AU) / (DF • FS)

Cone Int Std Unknown Concentration - * Area Unk • Correction Factor

Area Int Std

in cn >

12:42 AM FRI., 18 D E C , 1987

O O to

i(^

RCrCRENCr STRNPffltB SPCCTRUfl Fjl» >P3 Bpk flb 3

48888-

-

e-1

589 9968

57

1 ' 1 ' 48

bi«i2-Ethylh»xyl)Phth*l«t» 871627 26:51 SUB 149 /

7 " ••=•?' T 7 ...JI.J.J 1 1. ... ..'. ! ... < 8« 128 168 208 248

Sc an 34.65

2?9

\ 'r

1516 • in.

-188

-n 1 I 1 ' ' 1 -

286

SAMPLE SPECTRUM (BfiCKCROUND SUBTRACTED)

File >P38J0 Bpk Ab 6862

2UL n u i f l 7 iSS6? i t t a 10UL BN392=>I.1l. HP»i SUE

149

Scan 1S12 34 .S6 a i n .

4888- 57

f\ vM| H t *

71 83

i . > ,»^ 132 /

- lee

48 ' ' I • ^ " i r ' -

99 120

167 /

I ' ' I •*' M ' ' ' I I 168 288 ;48

279 \

• • I 1 ?88

:flnPLE SPECTRUM I O H A L T E R F D I F i l e >P3e i0 ^ 2UL HUIH 765Es9 ENH leUL EHSS'S*) IML HP<t2 Bpk Ab 6062

.Icari IE 12 34.56 min .

4e80-

149 /

57 71 83

„ , / / 18^ 132 167 /

I 279

48 88 128 ' I ' • • I 160

• I • • ' I ' ' • I • 280 248

160

1 1 1 ^ ^

288

Data File: >P3810::B2 Name: 2UL MUIA 765569 BNH Misc: lOUL BN392=MML HP#2 Quant Time: 871218 00:34 Injected at: 871217 23:47

Quant Output File: '"P3810::QT

BTL t2 3 Quant ID File: !IDXPP::ME

Last Calibration: 871216 19:15

Compound No: 59 Compound Name: bis(2-Ethylhexyl)Phthalate Scan Number: 1512 Retention Tine: 34.56 m m . Quant Ion: 149.0 Area: 16260 Concentration: 9.74 ug/mL q-va1ue: 85

in cn y-

o o

o

12 I t 24 28 36 40 44

Fil« >P38ie Bpk Ab 11254

41

43

2UL nUlA 765569 BNA leUL BN392«>inL HP>2 SUB ADO DVC

61 56 59

83

Sc*n 183 7 .49 n i n .

181 : I I I ' I I I I I I I I I ' I T I ' T t I I I I I I I I I I T I I I I I I 1 I I I f I I I i I I I I I I I I I I I I I I I I I I 0 ^ rt ^ n . ' i\ ^f. AA f /\ #*./*

rtrea

Unknown # , 1 53172.0 0 Tentative Concentration i; 0 0

Sample file: >P3810 Spectrum #: 183

No data base entries were retrieved.

Ul

o o 10

o -J

F i l * > P 3 8 i e Bpk Ab 7 9 4

41

2UL MUIA 7 6 E 5 6 9 BNA leUL BH392->1ML HP»2 SUB ADD DVC

5 5 /

Sc*n 1246 2 9 . 1 4 s i n .

6 7

5 3 69

L 81

95 96

6C ^ • 1 ' I ' ' ' I ' l I

189 110 123 124

4* 98 180 i : o

I ' I 130

F i l * >BICDB Bpk Ab 9 9 9 9

-I " 1

1 , 1 3 - T « t r « d * c « d i * n « ( 8 C I 9 C I )

5 5

S c » n 6 1 2 6 8 . 0 8 B i n .

5 3

8-V+^

^L ^^ ^L J-^ 95 96 ^ Y ^ 1 - -> , - ' ' 1 ^ Ll® 123 124

I • I

4 8 5 8 6 8 -44i+- Jli

; 8 98 168 I I S 120 138

F l !«• >EIGDB Bok fib 9 9 9 9

41 I

B i c y c l o C 4 . 1 . e : h » p t a n » , 2 - » e t h v l - ( 9 C I ) S c a n 8 2 8 8 . 8 0 B i n .

f 4 67 ^ f i 81

82 95

5 3

8 ') 48 50

rl+U- l-Ui,

96

AU 10? 'J** \ \ \ \

60 70 80 ' I

90 100 110 130

F i l e :-BI&M< Bp.k fib 9-<99

41 /

53

t , l 2 - T . - t d e < : a C i e n e ( 8 C I 9 C I )

Sl 82

Sc ».n 53?' Ci.L-O fcir.

67 69 /

l | i i i , i , J k , i , . , i i ' ^1^2^ l«'^ l ie 123 134

48 ' I I I I ' I • !• I I I I I ' I •! •! I I I I ' I ' !• I I I i I ' I ' I 'I—I I I I I ' I I I

50 6 8 7 8 88 98 186 l i e 120 136

Mr ea

Unknown 4 ,2 72504.00 Tentatis-e Concentration 1 s 21.00

1. 1,13-Tetradecadiene (8C19CI) 2. Bicyclo[4.1.Olheptane, 2-methyl- (9CI) 3. 1,12-Tridecadiene (eCI9CI) 4. 1,14-Tetradecanediol (8CI9CI) 5. Bicyclo[2.2.llheptane, 2-methyl- (9CI) 6. SpIropentane , butyl- (8CI9CI) 7. BicycloC4.1.0]heptane, 3-methyl- (9CI)

194 C1'*H26 110 C8H14 180 C13H24 23 0 Cl4H3riG2 110 C8HI4 124 C9H16 lie C6H14

Sample file: >P3810 Spectrum #: 1246 ^ Search speed: 1 Tilting option: N No. of ion ranges searched: 46 >

Prob, CAS # CON • ROOT K DK *FLG TILT \ CON C_I R_I M

67 21964498 6126 "BIGDB 94 34 94 15 34 2 O I--Nl Nj

k r_. 0.:^_.\.0:, ,

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T izue 14 52 13

T i rae 1 1 3 2 IS Mfe - . h c d P E S T C I P

D e t e VED : 3 DEC 8 7

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Author Inst:umen t Col 'jmn No t es

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3.23 5 6 6 6 6 7.88 7.17 7.35 7.48 7.59 8.18 8.54 9.96

11.62 11.89 14.88 15.54 15.72 16.68 17.27 17.73 18.64 19.86 22.81 25.36 25.97 27.78 28.34 28.99 29.51 29.76 38.3afW 31.59 31.99 32.18 32.94

AREA 48941 32566 81388 142346 164496 68891 516618 274588 76549 51323 114638 34362

8564E+e7 26394 78589 33521 42725 33181 163296 185768 44711 32893 783348 26571 73725 31458 87676 15627 56616 178566

2246166 185476

i'477388 68426 46729 34589 355686

TYPE 68 PB BV W W W W W W W VB PV SHB BB PB BB BV PV VB BB PB BB PB PB PB PB PV PB BB BB PV VB P8 PB PV VB PB

upyjaoujiJ ' 23.51 > P I ^ P

31.38

TOTAL AREA= 1.7454E-»67 HUL FACTOR^ 1.6666E-»66

RAH DATA TRAMSMITTB) CARIH»TS TRAMSNITTH)

AR/HT 6.658 6.838 8.644 6.639 8.651 8 857 8.648 8.842 8 872 8.883 8 112 e.8y9 8.651 8 878 8.865 9.859 8.889 8.886 8.884 8.666 6.874 6.118 8.8% 8.126 8.869 8.172 8.197 8.864 8.859 8.119 8.887 8.666 6.656 8.686 8.684 8.878 6.676

AREA:C 8.288 8.186 8.466 8.816 8.942 8.344 2.956 1.573 8.464 8.294 8.657 8.197

68 524 8.151 8.458 e. l92 8.245 8.198 8.936 1.664 6.256 8.189 4.488 8.152 8.422 8.188 8.499 8.886 8.321 8.977

12.869 1.663 2.735 6.392 8.268 6.198 2.838

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RIC DATA: PU7844 #1 SCANS 12/14/87 21t48:00 , . CALI: PLI7844 «2

COHDS.: RANGE: G 1.1006 LABEL: H 6. 4.0 QUAN: A 6. 1.8 J 9 BASE: U 20.

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AMOUNT=APEA * REF AMrMT/(REF AREA • RESP FACT) R E S P FAC. P R O M LIBRAHV ENTRV

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I ' - 1 , 1-DICHLOROETHENE (B) i : 1 l-DICHLOROETHANE(E) l o InA'viE - 1 , 2-DICHLOROETHENE (D) 13 CHLOROFORM 14 1 , £-CICHLOROETHANE<H) 15 Ti-.:.T C! iLOROPLUOROnETHANE 1 -•.: '•:.:-;:. :RO-LUOROMETHANE

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f t . ' i 128 65

NOT 94 62

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187 239

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DUAL MASS SPECTRUM 12/14/87 21:48:00 + 6:33 SAMPLE: 5MLS MW-IB 765571 COHDS.: ENHA^^CED <S 15B 2H 61)

DATA: PIJ7844 #131 CALI: pn7;?.44 H2

BASE M/Z: 49/ 49 RIC: 95359./ 128895.

100.0-1 r 29088.

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LIBRARY SEARCH 12/14/87 21:48:00 + 6:33 SAMPLE: 5MLS MW-IB 765571 CONDS.: ENHANCED (S 158 2N OT)

DATA: PU78<H » 131 CALI; PLI7S<V1 « 2

BASE M/Z: 49 RIC: 33823.

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DUAL MASS SPECTRUM 12/14/87 21:48:00 + 11:21 SAMPLE: 5MLS MW-IB 765571 CONDS.; ENHANCED <S 158 2N OT)

DATA: PU7844 #227 CALI: PU7S44 «2

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LIBRARY SEARCH 12/14/87 21148100 • 11:21 SAMPLE: 5MLS MW-IB 765571 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7844 « 227 CALIt PU7844 « 2

BASE M/Z; 83 RIC: 26431.

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DATA: PU7844 «16 CALI: Pn7S44 #2

BASE M/Z; 44/ 44 RIC: 110079./ 145919.

190.0-1 r 126208.

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LIBRARY SEARCH 12/14/87 21:48:00 + 0:48 SAMPLE: 5MLS MW-IB 765571 CONDS.! ENHANCED <S 15B 2N OT)

DATA: PU7844 » 16 CALI: PU73'14 « 2

BASE M/Z: 44 RIC: 110207.

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DUAL MASS SPECTRUM 12/14/87 21:48:00 + 2:27 SAMPLE: 5MLS MW-IB 765571 CONDS.: ENHANCED (S 15B 2H OT)

DATA: pn7844 «49 CALI: PU7X44 i»2

BASE M/Z: 44/ 44 RIC: 71679./ 156159.

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LIBRARY SEARCH 12/14/87 21:48:00 + 2:27 SAMPLE: 5MLS MW-IB 765571 CONDS.: ENHANCED (S 15B 2N OT)

DATA: PU7344 » 49 CALI: P1J7844 « 2

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SAMPLE

•J , l l l l l , . .,.. l l , ,J,l, | I 1,1 | . U | H—f. - r ' 1 — ' ! ' * ' ' I ' ' <• 1*—•* • | - ' — ^ " - " T - -1—* C12.H24

1 11032 FIT 849

^ o . k •:••

r

.1.1

1-NONEHE, 4,6,8-TRIMETHYL-

r 1 ' T » ' r I 1 " I ' 1 •• • J • •. ) • — 1 — 1 '•• '1 • 1 ' '< 1 — . - . — T — 1 — 1 — I ' l l — 1 » 1 • • I ' l 1 1

C6.H13.0.CL

B PK 45 RANK 2 I ,* 5H9 FIT 843

J11.H24.0

I 11777 , 'IT 827

M/J

2-PENTANOL, 3-CHL0R0-4-METHYL-, < R * , R * ) - ( . + - .

^ I ' l l f I ' *) I * — I — ^ — 1 ~ — » - _, I I I « I

1-HEXAfJML, 2- ETHVL-2-PF.0FYL

. X J . ^

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. 6 - 5 8 9 . 0 amu. 2UL hWlB 765571 BHP leUL BN392->lf1L Hf>»2

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Data File: >P3311::B2 Name: 2UL nu.lB ."65 571 BNA Misc: lOUL eN392 = >ll1L HPr2

Quant Output File: '^P?811::GT

BTLit:

led Fl le: ! IDXPP: : ME Title': PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Operator ID: GLENN Quant Time: 871218 01:30 Injected at: 871218 00: *4

cn cn >

o o

Operator ID: GLENN Output File: ^P3811::QT Data File: >P3811::82 Name: 2UL hUlB 765571 BNA flisc: lOUL 8N?92->1ML HP*2

QUANT REPORT

Quant Rev: 6 6 Quant T ime In jected at

Dilut ion Factor:

871218 01:30 87121B 00:44

1.00000

BTL1t29

ID Flle: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Compound R.T. Scan* Area Cone Uni t s

1) *l,4-DICHL0R0BEN2ENE-d4 7) 2-FluorQpheno1 (SS) 6) Phenol-de (SS) 14) *NAPHTHALENE-d8 1^) Nl t rob';(Tzene-d5 (SS) 26) *ACENAPHTHENE-dlO 30) 2-Fluorobiphenyl (SS) 41) 2,4,6-Tribromophenol (SS) 42) *PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 59) b i 5 ( 2 - E t h y l h e x y l ) P h t h a l a t e c l ) •PERYLENE-d l2

* Compound i s ISTD

1 1 , 8,

11, 15, 17, 21. 19, 23. 25. 33. 30, 34. 38.

.80

.77

. 52 ,55 . 52 ,03 .06 ,56 .59 95 ,79 56 ,12

393 2-+4 3 79 577 47 846 749 970 1070 1480 1325 1510 1684

8235 15276 15594 30752 17959

19851 24826 9139

39182 54638 40453 31253 55248

40 70, 45 40. 42 40. 46, 42, 40, 40. 36. IS. 40.

. 00

.02

.73

.00

.52 , 0 0

.83 ,57 ,00 00 ,00 68 , 0 0

ug.'mL u g mL ug -ml. ug -'mL ug. mL ug. mL ug/mL ug-'mL ug/mL ug/mL ug -'rnL ug--'mL

ug/mL

95 t? 98 5o

e- 9-. 96 91 66 64 42 87 78

in cn >

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MS data file header from >P3811

Operator: GLENN Sample: 2UL MUJIB 765571 BNA Misc : lOUL BN392->1ML HP#2 Sys. *: 2 MS model: 70 SUI/HU rev.: IA

Method file: EXTBNA Tuning file: MT8002 Source temp.: 0 Analyzer temp.: 280

MS 12/18'--87 BTL#29

ALS # : 0 No. of extra records: Transfer line temp. :

0: «4

Chroma tograph Chromatograph Chroma

>P3811 35

Upsl Dn.5 1

Peak #

1 2 3 4 9

6 7

8 9

10

11 12 13 14 15

16 17 18

.0 1 500. ope : ope: 0

R.T. min.

7.49 29. 14 30.52 31.18 32.07

32.28 33.20 34.36 34. 99 35.34

35.58 36.30 37.22 38.51 40.12

40.86 41.35 44.49

tograph

ic temp eratures : 30. ic t imes , m m . ic rate , deg/PT

2UL MUIIB 765571 BNh 0 CLP ADC TIC .20 A . 00 P

first "scan

179 1242 1310 1341 1386

1396 1440 1498 1529 1546

1557 1592 1638 1702 1780

1815 1840 1992

rea Re ject : 2SU I ts

max scan

181 1244 W 4 5 t5^4 r58S

1393 1443 1500 1531 1548

1560 1595 1640 1703 1782

1818 1342 1996

: 4. 0 in: 8.0

300. 7.3 0.0

0. 0 0.0 0. 0.0

lOUL BN392->1ML HP#2

5599. M File IP3eil S

last scan

183 1250 1317 1348 1390

1402 1448 1502 1533 1555

1566 1596 1643 1710 1788

1822 1846 1999

Sum o f Summary of Unknowns

Standi

1 4..

3 4 5 6

PBM Ll

srd Concentration

40 40 40 40 40 40

.0

.0 0 0 0 0

peak height

21226 7800 1788 2784 2275

1896 1899 2376 1849 3157

4135 2670 2908 3339 2618

2842 1956 1260

corrected

ax Peaks: 0r t ed by T

rat^ area

60750 60774 27341 39905 26735

38980 49335 35979 40198 95608

99638 51499 76569 118408 98947

84818 66975 41995

areas:

18 Bunc imeÂrea

c 0 r r . a r e a

46834 48793 61*^0

i*4J^ 6672

10441 773 0 82 75 o595 12764

22113 8948

12518 17415 102 04

11314 7717 6413

263583.

0. 0 0.0 5 0.0

h 1 ng : 1 INT

cor r . S max .

95.99 100.00 13.98 24.63 13.67

21.40 15.34 16.96 13.52 26. 16

45.32 18.34 25.66 35.69 2 0.91

23. 19 15.82 13. 14

3rary Search and Quantitation

Area

55990. 68127. 93893.

111945. 175723. 201877.

Retent ion Time

11.80 15.55 21.03 25.59 33.95 58.12

Unknown U 1 n(

3.82 13.68 18.29 23.31 29.77 36.03

dow

13.68 18.29 23.31 29.77 36.03 45.04

H to

17 18 2 4 2

J 2 7

2 4

8 •7,

4. 6. 3.

4 . 2 .

Df ra 1

.^63

.511

.587

.559

.531

.'='61 973 i?9 ^02 342

78'' 395 749 6 07 371

292 928 473

in cn >

o o

O O 1—

RCrCRCNCe STBNBWKP SPECTRUfI

FiU >P3589 bi«(2-Ethylhexyl)PhthaUt» Bpk fib 39968

46660-• 57

0-J

SUB 149 /

871827 2d:51 Scan 1S16 34.65 Ain.

Ii 71 83

113 132

7 — 1 — I I I I I 'I 'I

40 68 ' ' I I

-166

167 / 160

I. y 279 \

M i l i I I I I I I I I I I I I I I I I I I I I I I I I I I

126 160 260 246 ee SOMPLE SPECTRUM (BPCKCROUND SUBTRRCTEI')

Fil; >P?ejl SUL Mail; 76557: BUfl IBUL BM392=> l.rL HPs2 Bpk fit 12633 SUB

149

S c M !5ie 34.56 Bin.

I f i i ? ^ ^ ^ 1-1 0«

57

jjuM 71 63 / / 164

/ 132

f l''l I '!• I ' 1 '

i2e

167 /

. I. 27?

l-f.'? ' ' I I I ' I I I I I I I

••• iC>l

SOMPLE SPECTPUM fUNKLTERED)

File >P2311 ^2UL MUIE 765571 hHd lOUL BN3J2=>lf1L HP«: Epl. (3b 12635

149

Scan 151 e ; 34 .5ii II,in . \

•106 10060-^

6-

=.1^ 71 33 104 132

/ • • • ' " I ' •

'

167 279

\ • • • 1 ' • • 1 • • • 1

40 86 126 160 '266

Data Flle: >P3811::B2 Name: 2UL MUllB 765571 BNi-i Misc: lOUL BN392->1ML HP*2 Quant Time: 871218 01:30 Injected at: 871218 00:44

Quant Output File: '^F7611::ijT

BTL^4' Quant ID File: !IDXPP::ME

Last Calibration: 871216.19:15

Compound No: 59 Compound Name: b1s(2-EthyIhexy1)Phthalate Scan Number: 1510 Retention Time: 34.56 m m . Quant Ion: 149.0 Area: 31253 Concentration: 18.68 ug/mL q-value: 87

Ul cn

o o N)

o N) o ts)

12 16 2f 28 40 4a

File >P3811 Bpk fib 11644

i 41 3 \

2UL nUlB 765571 BNfi 16UL BN392>>tML HP«2 SUB «0E DVC

43

59 56 56 ./ 83 / \ .1 ^

y . 1 T 1 [ T T , , • , , , 1 , 1 1 , , , , i 1 , ,1 1 1 1 1 , , , , , , , , 1 1 , 1 1 , 1 I T 1 1 1 1 1 I J 1 , T

48 58 68 78 8C 98

Scan 7.49

161 •v.

181 •lin.

:8C

ri r e a =

Unknown ^f, 1 4 6 3 3 4 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 33.00

Sample file: >P3811 Spectrum *: 181

No d a t a b a s e e n t r i e s were r e t r i e v e d .

Ul cn >

o o

o N) o OJ

File >P38il Bpk Rb 671

4» J /

+V

2UL n U l B 7 6 5 5 7 1 BNfi 10UL BH392->1ML HP»2 SUB fiDD DVC

55 /

Scan 1244 D9.14 (iiin.

65

67 /

82 /

58 68 J iV , " „ ,H i

78 88

96 85 / 98 110 111 123

•' ' I '•

90 ' / • l l l . l " '

188 118 128

File >BICD9 Bpk fib 999?

H ' - /

1 ,13-Tetradecadiene (8C19CI)

55

Scan 8126 6.66 min.

52

• I I

56

65

67 82 /

• ' ' ' I ' l

35 96 ./ 98 l^^ll 123 t

56 • I '

96 166 lie • I '

126 - 6

ril» >SICBB Bpk fib 999?

41

1 ,12-Tridecadjene (eCI9CI) S..-An S39£ 0 . 0 0 m m .

If. : l . l l ' .

51

1 - ^ 46

^ i ^.'•i

55 /

i i j l l l .

6 5

6 7

/ 111

91

t « fe 86 90

95

I I _ -. 111 ,'• r - -

106

»°*111 123 f 1 1 1 •'." ••• I n

110 I •

120

F i l e >BIGDB Bpl fib ? 9 9 9

_J)ii: VC l o C 2 . 2 . 1 ^ h e p t a n e , 2 - a e r n y l - t 9 L l ;

67 0 . 0 0 mjr,

6 ' I ' f t I I I ' l

54 51 /

Uil-

81 / I

40 50 6 6 t I ' ' ' ' ' I

91

9 5 /

70 86 ' I ' 96

104 ' ^ 4 . I j l 112 F

I I I . I I I "TT~rT~i I r 0 106 116 126

A r e a U n k n o w n # , 2 4 3 7 9 7 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 17. 00

1. 1,13-Tetradecadiene (8CI9CI) 2. 1,12-Tridecadiene t8CI9Cl) 3. Bicyclo[2.2.llheptane, 2-methyl- (9CI) 4. Bicyclo[4.1.OJheptane, 2-methyl- (9C1) 5. 1 ,14-Tetradecanediol (8CI9CI) 6. 8-AzabicycloC5.1.Oloctane (8CI9CI) 7. 9-Decen-l-ol (8CI9Cn

194 C14H26 180 C13H24 110 C8H14 110 C8H14 230 C14H7002 111 C7H13N 156 C10H20O

Sample file: >P3811 Spectrum •: 1244 Search speed: 1 Tilting option: N No. of ion ranges searched 48 ^

^ • ' cn

>

Prob. CAS # CON # ROOT K DK •FLG TILT % CON C_I R_r g

1 . 86 21964498 8126 "BIGDB 103 25 60 w

o M O 1^.

File >P3 Bpk flb 6

811 44

43 /

1 e 1 • 48

File >BI Bpk Ab 9

CDB 999

43

/

1.1 46

rile >BICDB Bok fib 9999

d-5

..>

/

in 0 1 •

40

File .-BlC-IiB Bpi. fib •>999

43

.ii.l 46

2UL MUIB 765571 BNft leuL BN392->1I1L HP«2 SUB ADD DVC

57 71

/ 9/ 113127 141 153 165 ll. ,..i 1 1. . , ' > - > \ / l"l 68

1 ' I ' 1 ' 1 ' • 1 ' 1 ' ! ' 1 ' 1 ' 1 • '

O V i < f O 1 £ . V I t V i C V A O V

Scan 35.68

1566 • in.

I ' l ' " 1 288

Hexadecane, 2 ,6 ,16 ,14-tetraaethyl- (8CI9Cn Scan 11255 6.00 min.

' 85 , f" / 99 tl3i27 141 !=:£ i^g i ^ t , ,93 197 ;

II, n. ..1 .1 .1 . "^ ^ . -^-.r^ ! ^ .-- -o,

60

57

1.

/

60

57 /

' 1 •

66

1 ' 1 ' r • 1 ' I • 1 • I • I • 1 ' 1 • 1 • I '

86 166 126 146 168 186

Dodecane, 2 ,6,10-frlaethy 1 - (eC19CI)

266

Scan 4636 6.66 «in.

/ "^J 113127 j4, 155 g ,93 j,;.^ 1 , / ^ -^ — .^ .-. ..-- ..• I.

, 111. . 1. i , 1 . . ,1 J ^ -, — . ^ f " 1 ..» 1 ! • 1 ' 1 ' 1 • 1 • 1 • 1 • i 1 ' 1 • 1 . I .

66 166 129 140 160 186 1 • 1 • >••

200

Heptaccsane I8CI9CI) Sc»n 6220 0 . 0 0 B. 1 r..

V 85 t 99 :pi27 14J 15^ 168 169 183 197 :

' V 1 1 1' ( 1 1 1 r 1 1 • 1 • 1' 1 1 ' 1 > 1 ' T '

86 166 120 146 166 186 I ' l '

266

H r e a =

U n k n o w n i ^ , 1 1 2 2 1 1 3 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 5. 00

1. Hexadecane, 2,6 ,10,14-tetramethy1- (8CI9CI) 2. Dodecane, 2,6,10-trimethy 1- (8CI9CI) 3. Heptacosane (8C19CI) 4. Nonane, 3-methy1-5-propy1- (8CI) 5. Nonane, 3 , 7-d ime thy 1- (8CI9CI.' 6. Tr1tetracontane (8CI9CI) 7. Nonane, 2-methy1-5-propyl- (SCI)

23 2 C2nH42 212 C15H32 730 C2:"H56 134 C13H28 15o C11H24 604 C43H38 184 C13H28

Sample file: >P3811 Spectrum *: 1560 Search speed: 1 Tilting option: N No. of ion ranges searched

U) 5: cn

>

1.

Prob. CAS * CON • ROOT

44 638368 11255 "BIGDB 68 74

K DK #FLG TILT % CON C_I R_I o

72 17 O K) O Ul

?

s

nr:cN5T.RUCT S C R E E N P U M P Diti hcauisiticr.

<^-rp ••me 14:55.49

Time 12 10 03 Method:PESTCLP

Date VED 2 3 CEC 8 7

Date VEC :3 DEC 8 7

F I L E : i :rESTC122 RrtKSE (MIN.): 8.633 TO 35.888

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3.22 £.88 6.92 7.18

11.63 14.88 15.73 19.83 22.82 25.58 25.98

AREA TYPE 68435 24811 24488

149580 58445 42852 88456

155868 27822 46534

124968 ^'^1^26.33 <,70 18883 r V ^ 26 - 58pf i>Û)39463 ^ 26.68 24829

27.28 17645 27.32 26546 27.53 17328

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27.76 28.81 28.28 28.33 28.45 28.66 28.88 28.99 29.85 29.27 29.58 29.76

15391 82534 73686

287128 137758 34642 45111

116896 193186 456476

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P8<- 38!38«^»'!<'i438388

39.38

38.92 31.14 31.35 31.65 32.86 33.28

473158 367578 549838 998628 39124 128468

B8 PV VP VB PB BB PB PB PB PP PP PV VV VB PV VP PV VV VV VP PV

w VV VP PV w w w w w w Be w w w w PV

w

TOTM. M £ A = HUL FACTORS 1

9213886

E-êp

AR/HT 8.861 8 853 8.842 8.841 8.647 8.075 8 689 0.178 0 872 8.288 0.172 0.139 0.154 6.867 8.081 8.076 e 048 b.040 8.085 0.044 0.081 0.885 0.116 0.114 0.076 0.069 0.078 0.102 0.133 0.118 0.133 0.656 0.266 0.150 0.166 0.331 8.166 0.192

AREA3: 8.656 8.269 0.265 1.623 0.634 8.456 8.873 1.692 8.293 6.585 1.356 8.285 0 428 0.270 0.192 8.288 0.195 0.277 0.643 0.167 0.896 8.799 3.116 1.495 0.376 0.498 1.269 2.897 4.889

19.783 10.241 15.610 5.135 3.989 5.959

18.838 8.425 1.387

RAU DATA TRAHSMITTED \ FILE: RU4eSl::-27 CARIhPTS TRAHSWTTED > FILE: CP4892: -27

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RIC DATA: PLI7845 #1 SCANS 12/14/87 23je6:8e CALI: PU7845 «2 SAMPLE:'SeHeefR 5>H/« ^ M / - / 6 7^^jr3 CONDS.: RANGE: G 1,1060 LABEL: H 8.. 4.9 QUAH: A 6, 1.9 J Q BASE: U 20-

1 TO 1000

100.0-1

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H

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187

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3

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QuANTXTATXc^.! R E P O R T Fn_e: FU7845

DATV-.: PU7645. TI 12/14/87 23 06: 00 SAMPLE: SflLS MW-IC 765573 CONOS. : SUBMXTTEC BV: NO. SEA ANALVST; SS

AMOUNT=AREA * REF AMNT/(REF AREA • RESP FACT) ReSP. FAC. FROM L i B R A R V ElMTRV

No 1 2 3 4 5 6 7 6 9

le il 12 13 14 15 16

Z6 27 28 29 30 31 32 33 34

36 39 4G 41 42 43 44 45 46 47 48 49

No 1 2 3 4 5 6. 7 O--4-10 11 L2 L3 J.4 15

N A M E BROMOCHRLOROMETHANE (INT. STD. ) 1, 2-DlCHLOROETHANE D4 (SURR. STD) CHLOROMETHANE BROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE (C) ACETONE CARBON DISULPHIDE 1, 1-DICHLOROETHENE (B) 1, l-DICHLCROETHANE(E) TRANS -1,2-DtCHLOROETHENE (D) CHLOROFORM 1, 2-DICHLGR0ETHANE(H) TRICHLOROFLUOROMETHANE DICHLOP OFL'JOROMETHANE ACROLEIN ACRVLC''.:lTri;_£ 1 . J -DI ' -LC* -•ODENZENECINT. STD) Z-EUTAMONr. ( M£K i 1 , 1 , l-TPICHLOROETHANE ( I ) f- ^ . r r r - • T r - r A C H L O R J "E ( J ) 0'I'-0\l_ <'.'.'-. >^T'l^ eRorioo: CHLOROMETHANE ( L ) 1, 2-DICHL0R0PR0PANE(X) TRANS 1- 3-DICHLOROPROPENE (AA) TRICHLOROETHENE(K) DIBROMOC HLOROMETHANE(0) 1, 1, 2-TRICHR0ETHANE(M) BENZENE(BEN) C I S - 1 . 3-DICHL0ROPROPENE(Z) 2-CHLOROETHYLVINYLETHER(NN) BROMOFORM(P) CHL0R0EENZENE-C5 (INT. STD) 2-HEXAN0NE(MBK) 4-METHYL-S:-PENTANONE ( MIBK ) TETRAC HLGROETHENE(N) ETHANE, 1, 1, 2. 2-TETRACHLORO-TOLUENE(TOL) C HLOROEENZENE(Q) ETHYLBENZENE(EB) STYRENE META-XYLENE ORTHO/PARA-X YLENE META-DICHLOROBENZENE(MDCB) 0RTH0-DICHL0ROBEN2ENE (ODCB) PARA-DICHLOROeENZENE < PDCB > D8-T0LUENE(SURR. STD) EROMOFLUORBENZENECSURR. STD)

M/r 128 65 50 94 62

NOT 84 -4S-

S C A N 187 240 31 61 72

FOUND 131 -Mnb-

TiME 9:21

12:00 1:33 3: 03 3:36

6:33 s- aa

REF- RRT 1 JL eee 1 1. 283 1 e. 166 1 0. 326 1 0. 385

1 0. 701 01 %9n

M E T H A BB A BB A BB A»BV A BB

A VB A*BP

A R E A ( H G H T ) 310496. 438382,

900. 3272. 2137.

182612. sq/IO.

AMOUMT X T O T 30. 000 UC/L 9. 64 42. 328 UG/L 8. 20 0. 110 UC/L 0. 02 0. 489 UC/L 0. 09 0. 326 UG/L 0. 06

15. 023 UG/L 2. 90 i., age UC/L 0. at

in cn >

o o K)

O

,8-19

MOT rOUMD 96 63 96 83 62 NOT •SS-i-Siu

179 200 220 228 239

FOUND

8 : 5 7 1 0 : 0 0 1 1 : 00 1 1 : 24 1 1 : 37

a ao

1 1 1 1 1

0. 957 1. 070 1. 176 1. 219 1. 278

A*BB A BB A»BB A 68 A BB

-SS-JJL2- 7 a i

1 01 a t f l AOBP

•4M9- 7 i a q a. ,0.;7afc A v>a

6575 . 0. 744 UG/L 0. 14 1026 . 0. 037 UG/L 0. 0 1 2462 . 0. 266 UG/L 0. 05

29495 . 1 . 194 UG/L 0. 23 725. 0. 034 UG/L 0. 0 1

ai iBf l 19, 0fca w c / L a. t 7

•4i—9i.Mk9 A»DD aggg A<h9<ti

B. 90B UC/U A. 7a

114 3 8 1 1 9 : 0 3 .19 1 . OOO-, •#I^B8 1474660. 78. BfcO ygi^L.—14. OB 30. 000 UC/L 9. 64

. ».

- » ^ -iJS. -f-aSii •J.3ftQd. -3 J,g7 U C / U Cll f \S

NOT FOUND FOUND

o- a a Jkq Q, 5 0 ^ Af tBc 7 0 q f l . • l l q s i IJC/U 01 a a 2a 25 2c. 27 26 29 30 31 32 33 34

E3 63 75

MOT

97 78 75 63

NOT I.J 7

••') 3

263 292 296

FOUND 319 315 319 329 344

FOUND 482

13:09 14: 36 14:48

19 O. 690 19 0. 766 19 0. 777

15 15 15 16 17

57 45 37 27 12

24: 06

19 19 19 19 19

34 -34-

0. 837 0. 827 0. 837 0. 864 0. 903

1. -0^

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A*VB A«6e A BB

A*BB A«BB A BV A VB A*BB

A BE

4539. 2507. 2014.

1738. 4655. 4114. 7322. 2371.

1137420.

O. 282 0. 167 0. 121

O. 137 0. 332 0. 120 0. 758 0. 535

50. 000 O, 784

UG/L UG/L UG/L

UG/L UG/L UG/L UG/L UG/L

UG/L UC/U

O. 05 0. 03 0. 02

O. 03 0. 06 0. 02 O. 15 O. 10

9. 64

nfcs aa-04 34—o, gso Aftue liOaBBfli ^ B . g g g U C / U a, Bfc 3 7 3 8 3 9 4 0 4 1

1 6 4 8 3 9 2

1 1 2 1 0 6

434 442 458 474 501

21:42 22:06 22: 54 23: 42 25: 03

34 34 34 34 34

0. 0. 0. 0. 1.

900 917 950 983 039

A»VB A»BB A BB A VV A»BB

O O i G l 3 4 1. BOO iM»DD

2327. 6281.

35768. 2293. 3208. aoniD.

0. 209 0. 304 1. 875 0. 104 0. 338

UG/L UG/L UG/L UG/L UC/L

0. 04 0. 06 0. 36 0. 02 0. 07

69. H E UC/L—13. aa

45

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3 5 : 1 5 3 4 1 . 4 6 3 A BB

2 2 : 4 2 3 0 : 4 2

34 e. 9 4 2 1. 37fl

A BV A BB

6 7 1 .

864678. 735184.

O. 046 UG/L O. 01

54. 000 UC/L 10. 41 48. 283 UG/L 9. 31

/

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100.0-1

DUAL MASS SPECTRUM 12/14/87 23:06:00 + 6:33 SAMPLE: 5MLS MW-IC 765573 COHDS.: ENHANCED <S 15B 2N 0T)

DATA: PU7845 HI31 CALI: PU7345 »2

BASE IVZ: 49/ 49 RIC: 131583./ 162047.

r 42368.

5 0 . 0 -

hiCUcA^C^n^ ^ . / ^ / ^ ^ / ^ ^

T—I 'I 'I ULLU

1 1 " I " ' I ' ' I ' " ' I ' -T-T r ' r ' l - "I •' I •' 'I ' I I T I T

M/Z 50 100

5 0 . 8 -

J U-L 150 200 250

1 - I TI I TI l 7 i tr b f 7I7 I7 } -

100.0-' 9^^0

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^ 42368.

1004 ^r

SAMPLE

LIBRARY SEARCH 12/14/87 23:06100 + 6:33 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED (S 15B 2N 0T)

DATA: PU7845 #131 CALI: PU7S45 ^ 2

BASE M/Z: 49 RIC: 129791.

I ' I • I '• 'i ' " l l 1 1 » « » . » , •• I —1- •) I «i 'I I * I ' I I'i I I* ••

C.H2.a2

RANK 1 t 7 FIT 999

Ji

METHYLENE CHLORIDE (C)

T 1 , , r-

SAMPLE MINUS LIBRARN -I • r -

1004

M -1004

• t I

ZTZO 3 0 0 V3S

— j —

i nn ~ i — ~T

>50

DUAL MASS SPECTRUM 12/14/87 23:06:00 + 11:24 SAMPLE: 5MLS Ml-l-lC 765573 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7.S45 1*228 CALI: PU7S45 «2

BASE M/Z: 83/ 44 RIC: 26879./ 51711.

100.0-1 r 8480.

a / i UYT^y^^^-^

50.0-

I .1 , 1 . i . l h . . I 1 1 I 1 . . 1 I . 1 . 1 1 . , l . l l 11 1 . 1.1

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f f t ti'^ln'i

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t - l • I - ' I'ljl'i'ii' 'pl| i ' i | j i ' ' ' i t i ' i ' 'i t i ' l ' i f -V- ' ' ' j ' i ' ' ' i ' ' i ' ' V i

100.'' 9T20 300 V3S

S480.

LIBRARY SEARCH 12/14/87 23:06:00 + 11:24 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED <S 15B 2H 0T>

DATA: PU7845 # 228 CALI: FU7S45 U 2

BASE M/Z: 83 RIC: 26637.

1000

SAMPLE

iM UJIL. l l i i . l l , .U.<| I , . ^...J-f. < i ^ i I - i ^ — ^ ^ a ^ l * ^ H ^ i » » J * ^ ^

c.H.aa .» I . I 1 1 1 " I •! f • • ! • • ' t " I • I

CHLOROFORM

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83 1

+ I • I * i " ' I ' t . » - I — ^

1000 SAMPLE MINUS LIBRARY

I . , i ' ' ' • I I I I , , i , i , I l l I I I > I i i . i , I 1 . 1 1 I l l 11 .1 I I I K I I < I I I . l I .1 • . I ,

-1000 M/?

- T • • ^ I •' ^ — - r -

irm 150 6TZ0 300 V3S

200 — r 25v:

DUAL MASS SPECTRUM 12/14/87 23:06:00 + 22:54 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7845 #458 CALI: PU7845 «2

BASE M/Z: 91/ 98 RIC: 40063./ 206591.

100.01 r 31808.

-hi. cC/a^L^

50.0

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100 150 ZnO 250 B^ t nhn f i 7*7|b,tT 17 >;• I.Tht h i t »'T 'V '-- '-TiH4 r i ' t iTi^ ' ' ' I I I It I. IT ' - t

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LIBRARY SEARCH 12/14/87 23:06:00 + 22:54 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED <S 15B 2N OT)

DATA: PU7845 # 458 CALI: PU7S45 » 2

BASE M/Z: 91 RIC: 39939.

1061

SAMPLE

. I , •. 1 , 1 1 • ., Ii.i ,1 ll 1,111 • — , — - J — i — I ••• •.

C7.H8 TOLUENE aOL>

91

I 3^ FIT 919

M ' • ' 1^ ' » >•' '« ' i ' ••• ' . ' l I ' M ' > ••[ • r I 1 * • « ' I • • • ' I 1 t • ' . ; • » . •!

• I > I ' ' I . ' l ' " . ' I < 1 I I ' ' t ' I 1 < • " f " •"> ' ' I -, r—~r

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I I I I I ll I I ll t.,,i I < I I I , I . . I .. I . 1 1 . . , I I I , ,

M/Z T330 3 0 0 V3S —,—^ 100

150 - I — — I — I — t -

250

DUAL MASS SPECTRUM 12/14/87 23:06:00 + 0:48 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED <S 15B 2H OT)

DATA: PU7y45 #16 CALI: PU7843 «2

BASE M/Z: 44/ 44 RIC: 110207./ 1338S7.

100.0-1

50.0-

r 110080.

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LIBRARY SEARCH 12/14/87 23:06:00 + 0:48 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED (S 15B 2N OT)

DATH: PU7845 # lb CALI: PU7S45 (( 2

BASE M/2: 44 RIC: 103351.

1004

SMfLE

r I t ' I " * ' I ' ' I I I • I I " » • I •t • ' ' t t • •• ' I - > — ^ 1 ' i ' ) • ' • ' 1 * I •' 1 I ' I 1 M 1 I • Y

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M HT*§§J B PK 44 RANK 3 I 23714 ' IT 975

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DUAL MASS SPECTRUM 12/14/87 23:06:00 + 2:27 SAMPLE: 5MLS MW-IC 765573 CONDS.: ENHANCED (S 158 2H 0T)

DATA: PU7S45 #4LH CALI: FU7S'15 #2

BASE M/Z: 44/ 44 RIC: 80835./ 169471.

100.0-j

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150 77 I 77^77! 77I I I t I i i | i i . . j | .

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LIBRARY SEARCH 12/14/87 23:06:00 + 2:27 SAMPLE: 5MLS MW-IC 765573 CONDS.; ENHANCED <S 15B 2N OT)

DATA: PU7845 # 49 CALI: PU7845 # 2

BASE M/Z: 44 RIC; 71551.

1000

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D a t a F l l e : > P 3 8 1 2 : : B 2 Name: 2UL MWIC 7 6 5 5 7 3 BNA M i s c : lOUL B N 3 9 2 - > l r i L HP4f2

Q u a n t O u t p u t F i l e : ' " P 3 3 1 2 : : Q T

BTL4t3 0

Id F l l e : ! I D X P P : : M E T i t l e : PRIORITY POLLUTANTS L a s t C a l i b r a t i o n : 8 7 1 2 1 6 1 9 : 1 5

O p e r a t o r I D : GLENN Q u a n t T i m e : 8 7 1 2 1 8 0 2 : 2 7 I n j e c t e d a t : 8 7 1 2 1 8 0 1 : 4 0

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Operator ID: GLENN Output File: '^P3812::QT Data Flle: >P3812::B2 Name: 2UL liUlC 765573 BNA Misc: lOUL BN392->1ML HP#2

QUANT REPORT

Quant Rev: 6 Quant Time: Injected at:

Di lution Factor:

871218 02:27 871218 01:40

1.00000

BTL4f30

ID File: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Compound R.T. Scan# Area Cone Un 1 ts

1) •l,A-DICHL0R0BENZENE-d4 3) 2-Fluoropheno I (SS.' 6) Phenol-do (SS ' 14) *NAPHTHALENE-d8 15) h'li t r o b e n * e n e - d 5 ( SS .i 2 6 ) •ACENAPHTHENE-dlO 3 0 ) 2 - F l u o r o b i p 1 - i e n y l (S£) 41) 2,4,6-Tribromophenol (SS) 42) *PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl^ (SS) 59) bis(2-Ethylhexyl)Phthalate 61) •PERYLENE-dl2

11 8 11 15 13 21 19 23 25 33. 30 34. 39,

81 77 .52 58 . 52 03 06 56 60 93 79 58 09

395 246 381 580 479 343 751 972

1072 1481 1327 1513 1685

11714 21870 2 0813 40530 2 0779 23341 24975 9636

42677 41841 28190 52245 39522

40 70 43 40 36 4 0 40 33 40 40. 32 40. 40.

.00 9 0 . 17 00 .84 00 07 18 00 00 76 77 00

ug/mL ug-'mL ug/rnL ug.'mL ug-''mL ug--'nriL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL

93 63 9.5 60 8 3 8'^ 9S 90 6 7 57 47 32

Compound is ISTD

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Sample: 2UL MLJIC 765573 BNA Operator: GLENN MS 12/18/87 Misc : lOUL BN392->1ML HP#2 BTL*30 Sys. *: 2 MS model: 70 SU/HU rev.: IA ALS # : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records: 2 Source temp.: 0 Analyzer temp.: 280 Transfer line temp, : 0

Chromatographic temperatures Chromatographic times, m m . Chromatographic rate, deg/min

1:40

30. 4. 0 8.0

300. 7.3 0. 0

0. 0.0 0.0

0. 0. 0 .5

0. 0. 0 0. 0

= 3812 2UL MWIC 765573 35.Cl 500.0 CLP ADC TIC

BNA lOUL BN392->1ML HP#2

Upsl Dnsl

Peak #

1 2 3 4

ope : ope: 0

R.T. min.

7.49 16.98 17.45 29.16

.20 Area Re 00 R

f irst •^can

180 641 667

1244

esu 1 t s

max scan

183 649 672 1247

je F :t : 7268. Max lie IP38i2 Sor

last scan

186 656 674 1252

peak he 1 gh t

21992 7534 2598 1492

Peaks: ted by

raw area

74748 95934 32459 18039

4 Bunc TimC'-'Area

corr . a r e a

55354 49230 8758 9843

h ing : 1 INT

C O r r .

S ma.v .

10 0.00 88.9 4 15.82 17.78

H of total

44.v36 39. •964 7.110 7.990


St andard

1 2 3 4 5 6

Loncent ration Area

40 40 40 40 40 40

0 0 0 8 0 0

72680. 95408. 114247. 124732. 132980. 131338.

Re t ention T ime

11 15 21 25 33 38,

81 58 03 60 93 09

Unknoi-jn IJ 1 n d o w

3 13, 18, 23, 29 36,

78 69 31 32 76 01

or 13 18.31 23.32 29. 76 36. 01 45 . 04

Dilution Factor (DF) • 1 Amount Method (AM) • 0,

00 Fractional Solids (FS) 00 Amount Used (AU)

1. 00 0.00

Correction Factor » ••••••*• « (AM / A U ) / (DF • FS)

Cone Int Std Unknown Concentration " • Area Unk * Correction Factor

Area Int Std

2:35 AM FRI., 18 D E C , 1987

in cn >

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RCrERCNCe STBNPBRP SPECTRUW rii» >F'35»5 bisi2-Erhylh*xvljphth«l4r» S71627 iwsSl Bpk Rb 39968 SUB

1 4 9

S c a n I S l b 3 4 . 6 5 ( l i n .

46666-57

7 1 8 3

,^|,|L/./,.";';'.., IX 46 80 128 U 6 266

-lee 167 / 186 279

2 4 0 I ' ' ' i ^ °

see SRMPLC SPECTRUM (EPCKCROUND SUBTRRCTED)

r i l e > P 3 8 ! 2 2U1. r j U l C 7 6 5 5 7 3 BMP ICUL B M 2 9 2 s M . 1 L HPs2 Bpk Ab 1 8 8 2 4 SUB

149 2 0 0 6 0 - 1 /

1 8 3 32

Sca.n I S i : -3 4 . 5 8 m n .

I / / ^^^ 1'

4A An 1 2 H '-r-^

- 1 0 0

169

167 /

' • I I I I I I I ?fi«

279

-T-r-r-r-t 1-0 >f lR

Sfl t lPUE SPECTRUM (UNCiLTEREDl

F i l e > P 3 e i 2 2UL MWIC r 6 £ : £ 7 3 E M H l O U L EN592«> IML H P « ; Epk Ob 1 6 3 2 4 "

14?< 20006-1 /

1 5 7 1 8 3

104 , 3 2 1 II ll u / • I I / / ' ^

M p >r)l, ••^^•/"|-^ , . ' T | i T i f . . " i , . H I ["A. I I . I , , . , I , I I I I . I 46 86 120 166 266 246

167

: c * n 1 5 1 3 54 . 5 3 n i i n .

•106

2 7 9

I ' l l i ^ ' T 2 8 0

Data File: >P3&12::B2 Name: 2UL MWIC 765573 BNA Misc: lOUL BN392»>1ML HP#2 Quant Time: 871218 02:27 Injected at: 371218 01:40

Quant Output File: '^P3312:--QT

BTLSf3Li Quant ID File: !IDXPP::ME


Compound No: 59 Compound Name: bis(2-Ethylhexyl)Phtha1 ate Scan Number: 1513 Retention Time: 34.58 min. Quant Ion: 149.0 Area: 52245 Concentration: 40.77 ug/mL q-«âlue: 82

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File >P3812 Bpk flb 11308

• 4 1

43

2UL MWIC 765573 BNR 10UL BN392»>1HL HP«2 SUB flDB DVC

I I I M . 1 1 .

51 59

I I I I I I I I I M r' t% I I I I

69 83

Scan 183 7 . 4 9 w i n .

161

I I I I I I I I I I I I I I I i I [ I I I I [ I I f i j T n r.f. rt*» t Sf OU 7 0

H r e a

U n k n o w n i ^ , 1

55354.00 Tentativ.'e Concentration is • 0 . 0 0

S a m p l e f i l e : > P 3 8 1 2 S p e c t r u m * : 183

Nc data base entries were retrieved.

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F i l e > P 3 8 1 2 Bpk Rb 1 3 1 7

42 / a 44

2UL n u i C 7 6 5 5 7 3 BNfi leUL BN392->1HL HP«2 SUB POO OVC

56 - - ^ 5 6

"^ 84 65 67

+444

S c a n 6 4 9 1 6 . 9 8 s i n .

113 r

I I I I I I f I I I I I I I I •! I I I I I ; T H I I I I I r I I I I I I I I I f I I I 1 1 I I I I I I I I I I p I I I I I I I I I I I I 0 ^ * . ^ n ^ n n n O M I f%n • • / * OV OU flu OV 9V > W i ^ V

^

File >BIGIiB Bpk Bb 9999

41

04+t

1 - H e x e n e ( 8 C I 9 C n S c a n 9 9 6 6 . 0 0 m i n .

55 5 6

44

i' I . . . 1111 n ( 1 1 1 '^1 " •• I

69 6 5 / / I H i l l

84 ?? I

es 89 | . H H I 11 I I I I l l I

r 'O 58 I P 11 i 11 ' • • ji^ ^ '

?S 188 • • I ' l '

118

F i l e >BICCB Bpk. Ob 9 9 9 9

41 -I /

e II|i 11;

1-Pentene, 2-methyl- i8CI9Cn

56

55 f 69 44

A.M^ 40 50 60

• • I ' ' ^ ' l 70

•T-

84 '7 •^. 85

' • [ • • • ' I

60 90 ! • ' • • ! ' ' • • I ' • ' • : • •

100 110

Scan 995 6.06 nin.

4-0

File . BlC-rf Bpl: Ob 9999

_ Cvc lobu tanone , 2-it,«thyl- (8C19CI) S c s n ? 7 ' i 6 O.Ot' t l . in .

42 /

44

4 6 1 1 1 1 1 1 I 1 1 1 1

56

69 /

84

- " T I 1 1 1 1 I 1 1 1 1 1 1 1 1 I I I 1 1

60 70 80

85

I I I I I i t I I I I I I I H I I I T I H I I I ! I I I I I I I I

96 100 110

A r e . U n k n o w n # , 2 49230.00 Tentati v'e Concentration is 21.00

1. 1-Hexene (8CI9CI) 2. 1-Pentene, 2-methyl- (8CI9CI) 3. Cyclobutanone, 2-methyl- (8CI9CI) 4. 1-Propene, 2-methyl- (9CI) 5. 2,5-Pyrrolidinedione , 1-methyl- (9CI) 6. 1-Pentene, 4-methyl- (8CI9CI) 7. Cyanic acid, propyl ester (8CI9CI)

84 C6H12 84 C6H12 84 C5H80 56 C4H8 113 C5H7N0? 84 C6H12 85 C4H7N0

Sample file: >P3812 Spectrum #: Search speed: 1 Tilting option: N

649 No. of ion ranges searched 47

cn cn >

Prob.

1. 28»

CAS # CON « ROOT K DK #FLG TILT S CON C_I R_It

592416 990 "BIGDB 48 52 3 0 79 36 10 14

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: ; r 2 4 8 C 3 00 7 7 ? 5 7 72 \-V -. : . ^ e 9 2 0 2 M 5 5 s r 1 7 ' 3 V E 13 " 2 1 4 2 2 S-^P 2 9 EV

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RUH f / < UtmCFILE yORKFILE SAMPLE t $

10= Bl \ DEC/29/87 88:48-53

MVEAX RT 3.24 3.36 5.47 6.68 6.73 6.81 6.92 7.88 7.17 7.27 7.35 7.68 8.55 11.62 15.72 16.68 19.88 21.22 22.82

W-24-34. ErJ-^27.69^

AREA 93565 58678 46738 119498 192118 287168 77656 691598 162898 79437 127878 167806

4573E+87 61312 187618 19449 562198 58658 53477 19227

Oi<-

28.33 28.98 29.58 29.76 38.38 (J*"

486926 229486 1343166 48581

iMk67526

TYPE BV V8 BB PV W W W W W W W W SHB PB PB BB PB PB P8 PB BV 88 VB PB B8 PB

AR/HT 6.875 8.847 8.837 8.845 8.838 8.848 8.868 8.848 8.848 8 869 8.868 9 156 8 858 8.954 8 882 8.682 8 132 8.175 8 877 8 886 8.394 8.855 8.867 8.875 8.845 8.855

AREAS: 8.476 8.252 8.235 8.681 8.966 1.841 8.396 3.476 8.815 8 399 8.643 8.848

73.254 8.388 8.541 e 898 2.826 8.255 8.269 8.897 8.284 2.448 1.154 6.751 8.244 1.345

TOTAL AREA= 1.9894E+87 MUL FACTOR^ 1.6666E-»66

RAy DATA TRAHSNITTtO CARD-PTS TRAKSMITTD)

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RIC 12/15/87 2:53:00 SAMPLE: 5MLS 765575 F'Û Bla^^;^ CONDS.: RANGE:'G 1.1008 LABEL: H Q, 4.8 QUAH: A e. 1.0 J 9 Bf tk : U 29. 3

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No 1 3

8 9 IG 11 12 13 14 15 it 1""

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43 44 A5 46 47 46 49

NAME BROMOCHRLOROMETHANE (INT. STD. ) 1, 2-DICHLOROETHANE D4 (SURR. STD) CHLOROMETHANE EROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE (C) ACETONE CARBON DISULPHIDE 1, 1-DICHLOROETHENE (B) 1, l-OICHLOROETHANE(E) TRANS -1. 2-DICHLOROETHENE (D) CHLOROFORM 1, 2-0ICHL0R0ETHANE(H) IFIC HLOROFLUOROMETHANE L : : .HLOROFLUOROMETHANE •-.:.•'OLEOLH -.''•r-.'--LONITRILE : ."-LIFLUOROBENZENEdNT. SICO ;-' •: ;'A\!QMF f MEK ) 1.. 1. 1-TRICHLGROETHANE (I) ' Af- CON TETRACHLORIDE ( J ) VTrcVL ACETATE r<' •-••iOOXCHUSROnETHANECL! 1. "-OICHLOROPROPANE(X) TRANS 1, 3-OICHLOROPROPENE (AA) TFIC HLOROETHENE(K) DIBROMOCHLOROMETHANE(O) 1, 1/ 2-TRICHR0ETHANE(M) BENZENE(BEN) CIS-1, 3-0ICHL0R0PR0PENE<Z) 2-CHLOROETHYLVINYLETHER(NN) bROI10FORM(P> CHL0R0EENZENE-D5 (INT. STD) 2-HEXAN0NE(MEK) 4-m£THYL-2-PENTAN0NE(MIEK) T ETRAC HLOROETHENE(N) ETHANE, 1, 1- 2, 2-TETRACHLORO-TOLUENE(TOL) CHLOROBENZENE (O.) ETHYLBENZENE(EB) STYRENE META-XYLENE ORTHO/PARA-XYLENE META-DICHLOROBENZENE(MDCB) GRTHO-DICHLOROBENZENE (ODCB) FARA-DICHLOROBENZENE(PDCB) D6-T0LUENE(SURR. STD) BROMOFLUORBENZEh^ (SURR. STD)

No 1 2 3 4 5 6 7

A . JB-10 11 12 L3 .4 15

M/Z S C A N TIMK R E F RRT M E T H A R E ACHOHT) 128 191 9:33 1 1. 00© A BB 138372. 65 245 12- 15 1 1- 283 A BB 212339. 50 29 l- 27 1 0. 152 A BB 3463. 94 47 2- 21 1 0. 246 A»B6 5726. 62 60 3: 00 1 0. 314 A*BB 3795.

NOT FOUND 84 131 6: 33 1 O. 686 A BB 23637. .43 AAQ &i-»9 ^ 01 sat? A BP S79X,

A M O U N T 50. 600 46. 267 0. 948 1. 922 1. 299

4. 363

UC/L UG/L UG/L UG/L UC/L

UC/L UC/U

7.TOT 7. 82 7. 24 0. 15 0. 38 e. 20

0. 68 >• a a

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J ^ -USA. A 9 . Ol t a a — A OD - '44< 07. OOO UCi^L 96

NOT 96 83 62

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182 FOUND

223 232 250 159

11 11 12 7

06

09 36 30 57

1 0. 953 A 66

1 1 1 1

1. 1. 1. 0.

168 213 309 832

A*66 A»BB A BB A BB

7904.

3593. 2080. 679. 606.

2. 007 UG/L

0. 869 0. 189 0. 071 0. 089

UC/L UC/L UC/L UC/L

0. 31

0. 14 0. 03 0. 01 0. 01

h i ^ 1 T O O O 1 tr_ / I •S -T/»

^9 114 389 19:27 19 1. 000 A BB .738049. 50. eoe UG/L 7. 82

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2* * c6 27 28 29 30 31 32-33 34

K O J NCT 75

IvOT 127 97

NOT 7«\

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FOUND FOUND

302 FOUND

355 360

FOUND

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494 3©*-

15.

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A BB

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3317.

640. 2351.

655.

545811. 7044.

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50. &-

400 UG/L

102 UG/L 337 UG/L

298 UG/L

000 UG/L 6S4 UQ/'L

0. 06

0.02 0. 05

0. 05

7. 82 e. 10

37 38 39 40 41 f '--\

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9 >-164 83

NOT 112 MOT k e tJ i ^

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484-457 448

FOUND 510

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51 24

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DUAL MASS SPECTRUM 12/15/87 2:53:00 + 6:33 SAMPLE: 5MLS FIELD BLANK 765575 CONDS.: ENHANCED <S 15B 2N 0T)

DATA: PU7848 #131 CALI: PU7848 *2

BASE M/Z: 49/ 44 RIC: 26047./ 42343.

100.0-1 r 7488.

50.8'

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Sf'ZO 3 0 0 V3S

100.0

LIBRARY SEARCH 12/15/87 2:53:00 + 6:33 SAMPLE: 5MLS FIELD BLANK 765575 CONDS.: ENHANCED <S 15B 2N 0T)

DATA: PU7848 « 131 CALI: PU784S « 2

BASE M/Z: 49 RIC: 24255.

1000 ^r

SAMPLE

U-I IP I I n . I t • .l,», I l j I , I.l l.,l-..| r—i fii - i j — , I I I I • .—,—U—»ti i . i i« .—I u , 1,111 ,,4. ti'« I I ] I I I .

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METHYLENE CHLORIDE (C)

- l U 1 • I ' I • |.

SAMPLE MINUS LIBRARY 1000

U«;;'" V

I i , , i l , I II I I I I I I I,,, I M l . . .

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Data File: >P3815::B2 Name: 2UL FIELD BLHNK E'NA

flisc: iOUL BN?92=>inL HP*2 765575

Ouant Output File: '^P~3i5::Q^

BTL;^?3

Id Fl le: ! IDXPP: : tl£" Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Operator ID: GLENN Quant Time: 871218 05:16 In;ected at: 871218 04:29

cn tn >

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QUANT REPORT

Operator ID: GLENN Output File: '^P3815::QT Data File: >P3815::B2 Name: 2UL FIELD BLANK BNA Misc: IOUL 8N392->lhL HP#2 765575

Ouant Re',.': 6 Qu a n t Time: Injected at:

Di lut ion Fac tor:

871218 05:l6 871218 04:29

1.00000

BTL#33

ID Fi le: ! IDXPP: : flE Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Compound R.T. Scan* fitrea Cone Un 1 t

1) *1,A-DICHLGRDBEN2ENE-d4 3.1 2-F luoropheno 1 fSS) 6) Phenol-d6 (SS) 14) •NAPHTHALENE-d8 15) N 1 t r obe r r2ene -d5 (SS) 26 ) *ACENAPHTHENE-dlO 30) 2-Fluorobiphenyl (SS) 41) 2,4,6-Tribromopheno1 (SS) 42) •PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 5 9 ) b i s ( 2 - E t h y l h e x y n P h t h a l a t e 61 ) *PERYLENE-d l2

11 8.

11, 15. 13, 21, 19, 23, 25. 33. 30, 34. 38.

.81 / /

.52 , 55

.52 ,03 .06 ,56 .60 93 ,79 65 .11

395 2 4 c.

781 579 47'^ 848 751 972 1072 1481 1327 1516 1685

8293 12855 13801 31907 i79«l 2301« 28427 10028 53270 69217 57926

332918 62204

40, 58, 40, 40. 40, 40, 46, 40, 40, 40. 40.

180. 40.

.00 ,87 .43 , 00 .41 , 00 .25 ,29 ,00 00 70 64 ,00

ug mL ug 'mL ug.'mL ug mL

•J9 'mL

ug •' mL

ug-mL ug''mL ug/mL ug/mL ug/mL ug/'mL 'jg/mL

Qc;

^& 9t C^ "^

—• 9 2 9:i 9 0

6:' 57 4 0

38 7-

* Compound i s ISTD

in tn 3>

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Sample: 2UL FIELD BLANK BrJA Operator: GLENN Misc : IOUL BN392->1ML HP*2 765575 Sys. #: 2 MS model: 70 SU/HU rev.: IA

Method file: EXTBNA Tuning file: MT8002 Source temp,: 0 Analyzer temp.: 280

MS 12/18/87 BTL#33

ALS « : 0 No. of extra records: i Transfer line temp. :


30. 4.0 8.0

300. 7.3 0.0

0. 0. 0 0.0

0. 0,0 .5

0. 0.0 0. 0

>P3815 2UL FIELD BLANK BNA IOUL BN392»>1ML HP4^2 76^575 35.0 I 500.0 CLP ADC TIC

Upslope: .20 Area Reject: 8847. Max Peaks: 4 Bunching: Dnslope: 0.00 Results File IP3815 Sorted bv Time.Area INT

Peak *

1 2 3 4

R.T. m m .

7.49 29.14 29.49 35.08

first "scan

180 1243 1260 1535

max scan

183 1246 1263 1537

last scar.

185 126 0 1272 1540

peak height

12823 83202 3151 3643

raw area

48484 456904 92785

107488

cor r . area

32947 361761 21685 20920

cor r . H may .

9. 11

10 0.00 5.99 5.78

\ o f total

7.534 82.724 4.959 4.784


Standard Concentration Area

1 2 3 4 5 6

40 40, 40, 40, 40 40,

88469. 88469. 110015, 151725. 208378. 192567,

Retention T 1 me

11 15, 21 25 33 38,

81 55 03 60 93 11

Unkr.ouin Window

3 13 18 23 29 36

78 68 29 31 76 02

13 18, 23, 29, 36 45,

68 29 31 76 02 06

Dilution Factor (DF) » Amount Method (AM) -


1. 00 0. 00

Correction Factor - •** • » ••« (AM / AU) / (DF • FS)

Cone Int Std Unknown Concentration " • Area Unk * Correction Factor

Area Int Std cn tn >

5:23 AM FRI., 18 D E C , 1987 O O to

O to CJl to

RErCRENCE STBNDORD SPCCTRUM File >P35e9 bis(i:-Ethylh#xvnPhth»l»te S71B27 Bpk Ob 39968 SUB

149 40000-] '

• 57 ,,, \ ^ / 83 U 3 132 / ^ a

1 . 1 . 1 1 . 1 1 . I 1 I 1 1 1 1 1 1 1 1 1 1 1 1 I . . 1 . . 1 1 1 1 1 1

40 60 ize ue 230

2WJ51

1 1 T - | I 1

240

ScAn 34.65

279

\

1516 Bin.

-100

-fl • ' • • ; i .

2oo SRMPLE SPECTRUM (BCiCKCROUHI) SUBTRACTED) File >P3ei5 2UL FIELD BLRNK BNP I0UL BN392=>1P!1- HPB2 765E Bpk fib 64087 SUE

149

\ . ,

\ II J ' / T '--' 1 -' i?j,U| i„,j.|.,.,|,^,|,i;,,.,., . ,L,,p,.,r,, ,.1^., ,.,L,, . ' , , , , ,

46 80 120 16i?i 201?

2* l

- r - p r -

Sc4n IS!6 34.65 • i n .

-100

279

i;4ei JSk?

SAMPLE SPECTRUM (UNALTERED) F i l e >F381E 2J,'L F IELB BLANK ENv< 10UL EN i? ;«MML HP«i 76£S Bpk Pb 64 1t.e

149

4G063-

0-40 80 120 160 200 240

ican ;51fc C;4 .65 «. 1 r, .

)-ie0

279

\L ,. , 1 . 1 ••'-6 280

Data File: >P3315::B2 Name: 2UL FIELD BLAf4K BNA Misc: IOUL BN'392=>1ML HPi^2 Quant Time: 871218 05:16 Injected at: 371213 04:29

Quant Output File: '•P?815::QT

765?7? ETL^-7: Quant ID Fl le: ! IC'XPF: : ME


Compound No: 59 Compound Name: bis(2-Ethylhexyl )Phtha1 ate Scan Number: 1516 Retention Time: 34.65 m m . Quant Ion: 149,0 Area: 382918 Concentration: 180.64 ug/mL q - v a 1 u e : 88

Ul tn >

O o to

o to c/i CJ

Id. It. 20 24 2 b 36 4 8

F i l e >P3 Bpk Ab 6

815 2V 851

41

JL FIELD BLANK BNA IBUL BN392«>1ML HP»2 76SE7S SUB ADD DVC

43

59 51 66 / 83

• - - - ^ l l / .4 y* r * A ^ n ^ r t rtA /%/« *tW DC! O V r V OlCt 7 V

F i l e >BI Bpk fib 9

CBB 999

41

C u * n i d i n * ( 8C I9C I )

J,

60

40 50 60 78 80 90

Sc«n 7 ,49

101

183 • i n .

r- j I I I 1"! i V

Scan 0 , 0 0

1581 • l i n .

100

Unknown i^, 1 32947.00 Tentative Concentration is Area =

1. Guanidme (8CI9C1)

15.00

5 9 CH'>N3


183 No. of ion ranges searched: 46

1.

Prob. CAS * CON # ROOT K

11* 113008 1581 "BIGDB 20

DK *FLG TILT S

34 1 0 27

CON

65

c_i

2

R _ I U

cn tn >

o o to

o to CJl

F i U >F381S 2UL FIELD BLANK BNfi 10UL BN392->1ML HP«2 765S75 Scan 1246 Bpk Ab 8782 SUB ADD DVC 29.14 •in.

41 3^ --- b2

96 - \ \ ^ ^*^ 123

11.1, Jri, , 1 , 1 , , |i.. , » , .r. •-• 137 166

1 • 1 '

.....

ise 219 222 250

Fil* >BIGDB Bpk Ab 9999

41

1 ,13-Tttrad*cadi*r>* (8CI9CI)

55

Scan 8126 8.00 min.

82 /

||"'. > " t " I

46 -xili*-

96 / 109 123 13? 166 179 194 195

£0 160 - . — I — • -

280 240

n 1 * >EICDB Bpk Ab 9999

64

7-H»x«d*cyn» f9CI) Scan 54rS 0.00 a m .

H4tO-

67 /

ft I

95 ' 109 123 137 \ t S \7'-^ 1'53 218 222 t

40 80 i2e 16>J • I •

200 • I ' 240

F i l e /BlCPB t o k Pb 99•?•:

C y c l o d o d e c e n e , l E ) - i e t l 9 C l J Scar. 5 4 H 6 0 . 0 8 mjr..

Of O O

H 1» { 7

0-ik-J vJ u L 96

i. 109 / 123

1 ' i 1 1

136

T-T-I-

166

1 1 ih

168 ^

40 80 120 160 2 0 0 240

P r i

U n k n o w n \- , 2 7 ' 6 1 7 6 1 . Q T e n t a t i v e C o n c e n t r a t i o n 1 s 95. 00

1. 1 , 1 3 - T e t r a d e c a d i e n e ( 8 C I 9 C I )

2. 7-Heyade.:yne (9CI ) 3. Cyclododecene, ( E ) - (8CI9CIJ 4. 9-Octadecyne (9CI) 5. 1 , 1 4 - T e t r a d e c a n e d i o l ( 8 C I 9 C I ) 6. 5-Hexadecyne (9C1) 7. 1-Hexadecyne (8CI9CI)

194 222

166 25 0 27 0 222 222

C14H2 6 C16H30

C12H22 C18H34

C14H70O2 C16H30 C16H3 0

Sample file: Search speed:

>P3815 Spectrum #: 1 Ti1t ing opt ion: N

1246 No. of ion r a n g e s s e a r c h e d : 47

in tn >

1.

2. 3. 4. 5. 6.

Prob.

89 79 • 74 72* 71

CAS * CON #

21964498 8126 74685282 5425 1486755 5488

35365594 5435 19812647 5381

70* 71899371 884

ROOT

"BIGDB "BIGDB "BIGDB "BIGDB "BIGDB "BIGDB

K

117 68 65 79 102 62

DK #FLG TILT H CON C_l R_IL

11 69 44 77 41 55

1 0 1 1 1 0

0 0 0 0 0 0

94 50 56 52 87 48

3 38 13 38 26 39

66 37 39 28 29 28

83 4 0 76 61 74

O O to

O IO Ul cn

File >P3815 2UL FIELD BLANK BNA 10UL BN392«>IML HP»2 766E7E Bpk Ab 205 SUB ADD DVC

55 57 - ^ 83 97

I 1 / i n ill L I ^ * ' 219

"I", .'Hy.H-i''* . .^ . ' I . , • /. : I I I , •> SO 120 160 280

Scan 29.49

25J

1263 • in.

I r I I I 240

File >BICD6 Bpk fib 9999

55 69

3 - O c t a d e c e n e , ( C l - ( 8C I9CI ) Scan 0 . 0 0

0462 • i n .

_

0-

"- ^

Un

O J

L-iJ L,

97 / 111 125

/ r-4-—

139 154 182 /

196 209 224

/ 2SC

.

'-& 48 6 0 I t i U 2 8 0 2 4 8

r i l e >BICDE Phosphon i c a c i d , d i o c t a d e c y l e s t e r ( eC I9C I ) Eok Ab 9999

55

Scan 0 , 0 0

8329 • i n .

69 97

0 p.. . •»

l i t

,1,1 III. I iiiii , M „,.iii„

^?5^ 129 153

4M 80 120 160 2 0 0 ' I '

F i l e >B IGr iF BC'k fib 9 9 9 9

4 3

1-Oc t . a d e c e n e I S C I 9 C I ) Sc i n 0.OC1

.946t n, 1 r. ,

83 9? /

j i l , , 1 , , 4 , ,Jii, , 1 , , .I,, f, ,.r^,.v 40 80 120

' 7 125 139 154 182 196 210 / / ,'

I " I I I I I I p

2 2 4

160 200 ' I ' 240

H r e a

U n k n o w n # , 3 2 1 6 8 5 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 0 0

1. 3-Octadecene, (E)- (8CI9CI) 2. Phosphonic acid, dioctadecyl ester (8CI9C!) 3. 1-Octadecene (8C19CI) 4. 1-Octadecanol (8CI9CI) 5. 9-Eicosene, (E)- (9C1) 6. Cyclohexadecane (8CI9CI) 7. Hexadecanol (UAN8CI9CI)

252 C1SH?6 586 C36H^5G3P 252 C18H36 270 C18H7aO 28 0 C2 0HaO 224 C16H32 2 42 C1';'H340

Sample file: >P3815 Spectrum *: Search speed: 1 Tilting option: N

1. 2.

Prob.

71* 71

CAS # CON * ROOT

7206191 19047859

8462 8329

1263 No. of ion ranges searched:

k DK tFLG TILT CON C I R_K

Ul cn >

o o to

"BIGDB 95 "BIGDB 111

70 89

0 0

70 29 14

2 9 38

o 6 0 > 30 S

^ ' ^ MBl 4 n i

. ' • ..V '-i^ .* . i " . . ; ;

ViilfeWî:, ' . ' ' •

>?ii i r c O M S T R U C T SCREEN r.tJM? ,• J t 2 A. c o 'J i s i t i 0 r.

T i m e 14 00 Oi D a t e FRI 18 DEC 8 7

T i m e : 2 < 7 : 5 i D a r t F R I 18 CTC 6 7 M e t h o d P E S T C L P

F I L E : i.-PESTCeSS P.ftKCS (MIH.): e.833 TO 35.688

5

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REirrr Time:l3:59 14 DaterFRI 18 DEC 87

1:PESTC095 PESTCLF

A 'J t h c r : n s t r u m e n t C c I u m n U :• t e s

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F i l e : > P 3 7 9 ? : : e 3 2UL MUI6 7 6 f ' 6 08 IOUL B N 3 9 2 - > 1 M L

BNA HP4^2

Quan t Output File: • •P379?: :QT

BTL^,i29

I d F l 1 e : ! 1 D X P P : : M E Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15


CO tn

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Operator ID: GLENN Output File: '^P3793::QT Data Flle: >P3793::B? Name: 2UL MIJ6 765608 BNA Misc: IOUL BN392-MML HP#2

QUANT REPORT

Quant Rev: 6 Quant Time: Injected at

Dl lut ion Factor:

871216 21:00 871216 20:13

1.OOOOO

BTL^t28

1D F11e: ! IDXPP: :ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19 15

Compound R.T. Scan* An Lone Units

1) •l,4-DICHL0R08EN2ENE-d4 ? ) 2-F1uoropheno1 CSS) t-) Phenol-do ( SS J

14) *HAPHTHALENE-d8 15) f.l 1 t r o b e r r : e n e - d 5 (SS) 2 6 ) *ACENAPHTHENE-dlO 30 ) 2 - F l u o r o b I p h e n y l (SS) 4 i ) 2 , 4 , 6 - T r i b ro rnopheno 1 (SS) 42 ) •PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 59 ) b I S ( 2 - E t h y i h e x y l ) P h t h a l a t e 6 1 ) *PERYLENE-d l2

11, 3. 11 15. 13 21. 19. 23, 25, 34. 30. 34. 38.

.86

.82

.55

.60

.57 ,03 .11 ,61 ,67 .00 86 65 , 1?

397 248 382 581 481 850 75 3 974 1075 1484 1330 1516 1689

14116 21365 23505 51037 31081 3^221 54952 27741 78366 98254

101215 123194 98789

40. 57, 40, 40. 45 40. 60. 74. 4Cl.

40. 50. 40. 40.

. 00

.43

.45 , 0 0

. 0 3 0 0

, 13 .96 . 00 00 09 94 00

uq^'mL ug -"'mL u g .'rriL ug mL

uq - rnL ug mL ug/mL u g -••' m L

ug/mL ug/mL uq^'mL ug mL uq--mL

9 ''-c -z

9 c. 5t. ;51 jc;

9 9 76 6S 52 37 :-.9 73

* Compound i s ISTD

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MS data file header from : >P3793

Sample: 2UL MUJ6 7fr560S BNA Operator: GLENN MS Misc : IOUL BN392»>1ML HP*2 Sys. #: 2 MS model: 70 SU/HU rev.: IA ALS * : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records: Source temp.: 0 Analyrer temp.: 280 Transfer line temp, :

12/-l6'-87 20: 13 BTL*28

Chromatographic temperatures Chromatographic times, min. Chromatographic rate, deg-'min

30. 300. 0. 4.0 7.3 0.0 8.0 0.0 0.0

0. 0. 0.0 0.0 .5 0.0

>P3 79 3 2UL ML.ir, 35.0 I 5 0 0.0 CLP ADC TIC

U p s l o p e : .20 Area R e j e c t : 8375. D n s l o p e : 0.0 0 R e s u l t s File IP3793

765608 BNA IOUL B.').'.92= > IML HF#2

tia X Fe at. 5 : 7 So f t e d b',' T 1 rrie

Bunch 1ng y'i-ir e a 1 f. T

Peak

3 4 5

P. T. nr. 1 n .

t 1 r s t "scan

17 22 29 29

5^ , 44 35 , 19 27

182 666 907 1245 1251

max scan

185 671 912

1248 1252

last scan

188 674 917 1251 1260

peak he ight

29576 4063 4437

34710 9436

r ,a i*i

a r ^ a

73467 16255 12218

122516 50052

corr area

63522 15365 11252

116949 40753

corr % m a ,v

53.59 13. 14 9.62

10 0.00 34.85

°i of t C t 5 1

14

u V y 6 2 e 121 837 927

6 7

29.50 37.29

126 0 1641

1 2 D 3

1645 1268 16 47

2853 2112

19544 10587 9530

9 . 05 ? .873 3 . '-' 0 9


St andard

1 9

5 6

Concen t ra t i on Area

40 40 40 40 40. 40,

Di lut ion Factor (DF) Amount Method (AM)

83752. 117224. 157325. 202260. 271087. 282204.

Re tent ion T 1 me

11, 15 21, 25 34, 38

86 60 08 67 00 18

Unk no ..on UJ 1 n d o w

3.79 13.73 18. 34 23.38 29.83 36. 09


13.73 13.3^ 23.33 29.83 36. 0' 45. 03

1.00 0. 00

Correction Factor » •••••••• - (Afl / AU) '' (DF * FS)

Cone Int Std U n k n o w n C o n c e n t r a t i o n » * A r e a Unk • C o r r e c t i o n F a c t o r

A r e a I n t S t d

9 : 0 8 PM UED. , l 6 D E C , 1 9 8 7

RCrERCNCC STflNDflRP SPCCTRUH

Fi i» >P3 Bpk Pb 3

4eee8-

6-

569 9968

57

te

bis ii-tthyihexyi jPhthai*t* 671*2? SUE M 9 /

.,L,r..,.,, ,< ; 1. .1 . / 80 120 160 280

26i51

240

Scan 34,65

279

\

ISii;.

-100

-a r-| 1 I T 1 -

280

SOMPLE SPECTRUM (BfiCKCROUND SUBTPOCTED)

r i l e > P 3 ? 9 3 2'J',. nU£ 7 £ 5 £ e S ESS leU'.. 8M392 = > JP!',. HP«2 Bpk Rb 404 16 SUB

149

4 0000-1

S c i n 1516 34 . 6 5 m i n .

71 / ll

S3 / /

113 /

13? /

n >"" I f "''-^ i " i I F37'?3 ^ 2UL MW6 7 6 5 6 0 6 BMP IC'UL EN3?2 = >1ML HF»2 Epi. Pb 4 0 4 1 6

4 6 0 0 0 -• 57

149 /

'1 83

I ' ' ' I ' ' ' I ' ' ' I ' •' V • ' ' I ' ' ' I •' • I • • ' I • ' • I ' • • I ' ' ' 40 38 120 160 200 240

167 /

Scan 15 I'i 34 .65 m m .

-100

27?

\ . r • • • ' i ' ^ 1

280

Data F i l e : > P 3 7 9 3 : : B 3 Name: 2UL MW6 7b56 08 BNA M i s c : IOUL BN392 = >1ML HPiVl Quant T i m e : 871216 2 1 : 0 0 I n j e c t e d a t : 871216 2 0 : 1 3

Quant O u t p u t F i l e : ''-P3 7'^3: •• QT

Quant ID File BTLii2 8

!IDXPP::ME Last Calibration: 871216- 19:15

Compound No: 59 Compound Name: bis(2-Ethy1hexyl)Phtha 1 ate Scan Number: 1516 Retention Time: 34.65 m m . Quant Ion: 149.0 Area: 123194 Concentration: 40.94 ug/mL q-value: 89

CO CTJ

O o to

o to OD

12. 16 20 24 ' 26 32 36 40 44

Filt >P3793 Bpk Rb 15319

41

43

2UL MU6 765688 BNft leUL BH392»>inL HP»2 SUB ROD OVC

56 59

I ' l ' •' I I ' ' ' I f- r.

69 /

83

Scan 185 7 .54 a i n .

101

I ^ I I I I I I I I I ; I I I I I I ' I ! j I I I I I I I I I ^ I I I I I I I I I j I 6 .^ T f . ^f^ r , A I /%n

A r e a Unk ncum # , 1 6 8 5 2 2 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 33. 00

Sample file: >P3793 Spectrum #: 185

No data base e n t r i e s were retrieved.

cn C ^

O O to

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r n . >P3793 Bpk Pb 788

41

2UL MU6 765688 BNfl leUL BN392->1ML HP»2 SUB ROD DVC

60 73

r I ''•' I I I

57 r ?4 87 98 115

Scan 671 17.44 •in.

129

I I'l I ' l l I I I '

t o O O

1 I I I ' I I ; I

1 A tl i £ . V

Fil* >BICOB Bpk fib 9999

• 4 1 / 1,1

51 SS

H « x a n o i c a o d ( D 0 T ) i e C I 9 C I )

6 0

73

S c a n 1867 0 . 8 0 m i n .

40 50

74 87 88 J0J J 0 2 j j g j , g

6 0 68 I •

90 ' ' I '

100 110 i :

Unkni:jt,in i i , 2 Area = 15365.0 0 Tentative Concentration i:

1. Hexanoic acid (DOT)(8CI9C I )

5.00

iio C O H I 2 G :

Sample file: >P3793 Spectrum h' Search speed: 1 Tilting option: N

6-' No. of ion ranges searched: 48

Prob. CAS # CON • ROOT K

60 142621 1867 "BIGDB 47

DK #FLG TILT \

48 1 0 91

CON

14

c_i

30

R_IU

t^

O O to

o to CP CJl

File >P3793 Bpk Rb 3539

55

2UL I1U6 765686 BNR 18UL BN392->1ML HP«2 SUB ROD OVC

67 82

iiL i''"H I '|'"'i

96 / 189

/ 123 137

1 -4- - I — I I I I I I I — I — I I I — r

160 200

Scan 1246 29.19 Bin.

250 :

?48

Fil* >Biei)B Bpk fib 9999

55

1 ,13-T«tra<l*cadi*n* (8CI9CI1

67 /

82 /

40 68 L J L

96 / 189

/ •25 137 166 179 194 195

-«-129 160

T-l—. ^ r —r

Scan 8.ee

8126 ain .

•'• I I

2-»a

Til* >T;ICDB Epk Rb 9999

1 , 1 4 - T « r r a d r c a n * d i o l (8CI9Cn

69 82 -~^ { 95

1,111, • III! i l l ..

109 Ui II

12" 124

40 80 120 160 ^00

Scan 0 .08

5361 K i n .

240 -H9

F i l e >F!GPB Bpk Rb •99'^9

1 , 12-Tri<3«cadiene tSCI9Cn

67 81 / / 9 5 109 123 152 162 180 197

Sc * n 0.00

5395. D. j r , .

I I'"I I'T 88

I ' I I I ' l l I " I — I I ' I — I — I I I I I I I I I I I I I

128 168 200 2 4 8

A r e a =

U n k n o w n i , 4 1 1 6 9 4 9 . 0 T e n t a t i v e C o n c e n t r a t i o n i s . Uij

1. 1/i3-Tetradecadiene f8CI9CI) 2. 1,14-Tetradecaned lol C8CI9CI) 3. 1,12-Tridecadiene (8CI9CI) 4. 1,12-Dodecanediol (8C19CI) 5. Cyclododecano 1 (8C19C1) 6. Cyclododecene, (2)- t8CI9Cl) 7. Cyclododecene, (E)- (8CI9CI)

194 230 180 2 02 184 166 166

C14H26 C14H3r:0 C13H24 C12H2oO C12H2 40 C12H22 C12H22

tn m >

Samp 1e f i l e : S e a r c h s p e e d :

> P 3 7 9 3 S p e c t r u m « : 1 T i l t i n g o p t i o n : N

1248 No of ion ranges searched:

O o to

1. 2. 3.

Prob

93 75 71

CAS # CON •

21964498 19812647 21964487

8126 5381 5398

ROOT

'BIGDB 'BIGDB 'BIGDB

117 102 94

DK #FLG TILT

11 41 27

0 0 0

86 83 93

CON C I R

3 20 15

68 35 38

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31

fc

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Time !3 2 7 3 8 Date FRI 18 DEC 8 7

Time C7 12 0 3 Date TRI IS Dr:C 8 7 Method FESTCLP

o. 5^86

x i \ : i -. 1:!: •" ii

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1 : F E S T C 0 8 6

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MLR TRACOR 5 5 0 1 5M s r - : 2 5 C SUPELCOPOF.T

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MEA% RT

3.23 5.47 6.6» 6.73 £.81 6.91 7.88 7.17 7.27 7 35 7.49 7.59 8.18 8.54 1 9.17

11.62 15.72 16.68 18.65 21.44 22.82 28.33 28.99 29.58 29.76,

16

AREA 39557

299398 138758 258586 268838

62889 788658

s. N" '»

TYPE BP PB BV W W W VV

79934 0 W 98316 98480 68879

152698 25645

.5542E+07 21288

185588 43238 87891

213848 24876 42941 37227 85891

1231988 51326

38.38fi»" »êi9898 31.59 32.94

42543 127538

VV W VV VB PV

SHB Be PB VB PB PB 86 PB PB PB PB BB BS BV P8

TOTAL AREA= 2.8248E487 NUL FACTOR= 1.9M»E-*98

EC/29/87

AR/HT 8.855 8.833 8.839 8.836 8.843 8.858 8.841 8.858 8 869 8.868 8.181 9.127 8.184 8.858 8.869 8.856 8.899 8.869 8.118 8.897 8.871 8.862 8.886 8.873 8.849 8.856 8.128 8.875

86-25 = 87

AREA;: 8.195 1.479 8.686 1.277 1.285 8.387 3.896 8.395 8.486 8.447 8.340 8.754 8.127

76.789 0.185 0.521 8.214 8.438 1.857 8.123 8.212 8.184 8.424 6.886 8.254 1.886 8.218 8.638

RMI DATA TRAHSNIHED CAia>-PTS TRANSMITTED \i FILE: Ry4898: -27 FILE= CP4836:=-27

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DATA: PU7855 «1 CALI: FU7855 »2

r.CAKS 1 TO 900

SAMPLE: 5MLS MM-»2 765610 CONDS.: RANGE: G 1 , 900 LABEL: H 0.. 4 .0

100.0-

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NO. SEA ANAL.VST-- SS

AMO!JNT-AREA • REF AMNT/(REF AREA * RESP FACT) ReSP F .a.C F-ROM LX8RARV E N T R V

No 1

t 7 R 9

10 11 12 13 14 15 1 '_,

28 29 30

33

36

38 39 40 41 42 43 44 45 46 47 ^8 49

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r.'CriOCHRLOROMETHANE ( INT . STD. ) .1 3-OICHLOROETHANE 04 (SURR. STD) CHLOF.O, -'ETHANE f.:ROr'iO!l£1HANE VINYL ."HLORIDE CHLOrOETHANE r-lETHVLCNE CHLORIDE (C ) ACETONE CAPEC'N DISULPHIDE 1,1-DICHLOROETHENE (E) 1, l-DICHLOROETHANE(E) TRANS -1,2-DICHLOROETHENE (D) CHLOROFORM 1. Z-DICHLOROETHANE(H) T i TC HL0ROFLU0ROMETHAt-4E D I. •': HLOROFLUOROMETHANE

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M/ 1 128 65 50

NOT NOT NOT 34

• 45

SCAN 171 226 24

FOUND FOUND FOUND

112 e » ^

T I M E 8

11 1

33 18 12

R E F RRT

1 1. eoo 1 1. 322 1 C. 140

I'i.jT rour»>o

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1 0. 635 0. 600

M E T H A«-BB A»eB A 86

A VB A MB

AREA(HGHT) 124166. 293810.

2167.

20S7. n067D.

A M O U N T X T O T 30. 000 UC/L 1. 31 53. 173 UC/L 1. 61 0. 703 UG/L 0. 02

0. 416 UG/L 0. 01 11. 017 UCi L Q. 06

NOT FOUND -^»3-NOT 83

NOT 101 -86-

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210 FOUND

146 MOT FQWM&

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1242. (!iC09.

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0. 430 UG/L

0. 4 0 2 UG/L 76. fPÔ UGifL

0. 07 / »

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4i C O 26 27 2B 29 30 31 32 33

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NOT NOT NOT 129 NOT NOT NOT !'40T NOT

^^7 rOUND FOUND FOUND

314 FOUND FOUND fÔUND rcuND FOUND

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179690. 164966.

il 237 UC/L 1. 55 :5. 077 UG/L 1. 67

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DUAL MASS SPECTRUM 12/16/87 7:39:00 + 12:36 SAMPLE: 5MLS MW-«2 765610 CONDS.: ENHANCED (S 15B 2H 0T)

DATA: PU7855 It252 CALI: PU7S55 #2

BASE M/Z: 97/ 57 RIC: 24223./ 98047.

100.0n

50.eH

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Data Flle: >P3794::B3 Name: 2UL MUI2 76^610 SNH rii5c: IOUL BN392--inL HP*2

Ouant Output File: '•P3794; :QT

BTL5:2 9

Id File: !IDXPP::ME Tjtle: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Operator ID: GLENN Ouant Time: 871216 21:54 Injected at: 871216 21:08

TIC page 1 of 2

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TOTOL ION CHROMPTOCROM

f i l e >P3794 3S

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26

. e - 5 S e . e a a u . S'-'L tiw2 765610 BNfl TIC

1200 1400 1600 . . . 1 . . . . 1 . . . . 1 . . . . 1 . . . . 1 . . . . 1

«

• l a £

1 1 n ?

» ' , l o

Li . . . . . . . 1 , i ' l ' " M * ^ " l • ! ' 1 • 1 ' 1 • 1 • r ' T - ^ T - ' - l '

2 8 3 0 32 34 36 38

10IJL BN392«'>

1600 . . . . r . . . . 1

r ' t ' I • 1 ' 40 42

i nL HP»2

2000

44

Data F i l e : > P 3 7 9 4 : : B 3 Name: 2UL riU)2 7656 10 BNH N i s c : IOUL B N 3 9 2 - > l n L Hf iVl

Quant O u t p u t F i l e : '^P3 79 4; QT

BTL-, -29

Id Flle: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15


TIC page 2 of 2

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Operator ID: GLENN Output File: '^P3794::QT Data File: >P3794::B3 Name: 2UL MU)2 765610 BNA M I S C : IOUL BN392=>1ML HP#2

QUANT REPORT

Quant Rev: 6 Quant Time: In jected at :

Dilut ion Factor:

871216 21:54 871216 21:08

1.00000

BTLî29


Compound R.T. Scan* Area Cone Un 1 t 5 q

1) *1.4-DICHL0R0BENZENE-d4 3 ,1

1 4 ) 1 5 ) 2 6 ; 3 0 ) 4 1 ) 4 2 ) 5 2 ) 5 3 ) 5 9 ) 6 1 )

2 - F l u o r o p h e n o l (SS i • tJ r tPHTHALENE-dS

N i t r o b e n z e n e - d ? ( S S ) * H r E N A P H r H E f . ' E - d iO

2 - F 1 u o r o b 1 p h e n y 1 ( S S ) 2,4,6-Tribromophenol (SS)

•PHENANTHRENE-d 1 0 •CHRYSENE-dl2 Terphenyl-dl4 (SS) bis(2-Ethylhexyl)Phthalate

•PERYLENE-dl2

11.85 8 15 13 21 19

86 .62 ,56 , 08 10

23.60 25.66 33.99 30.86 34.63 38. 17

396 249 5B1 48 0 8-1* 752 973

1074 1483 1329 1514 1688

14593 12 76

53750 23276 336''r--0536 16342 72262 83122 69394 379 73 ^5213

40 . 0 0 uq /'mL J,

-.0 31, .4 0

44 . 44, 40. 40, 40, 14, 40,

Ou 12 • j 0

"'8

00 00 60 92 0 0

u 5 mL ug mL u q -'rr.L ug -• TiL

u9' mL ug/mL ug 'mL ug/mL ug/mL ug .''mL uq 'mL

3 1

38 9 ^

Compound i s I S T D

in tn >

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MS data file header fro m >P3794

Sample: 2UL MU)2 765610 BNA Operator: GLENN MS Misc : IOUL BN392-MML HP#2 Sys. #: 2 MS model: 70 SU -'HU) rev.: IA ALS * : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records Source temp.: 0 Analyzer temp.: 280 Transfer line temp.


12^^6/87 21 : 08 BTL#29

3 0 . 4 . 0 8 . 0

3 0 0 . 7 . 3 0 . 0

0 . 0 . 0 0 . 0

0 . 0 . 0

, 5

0 , 0 . 0 0 . 0

>P379 4 2UL MUI2 7o5610 BNA IOUL BN39 2=>1ML HP*2 35.0 1 5 0 0.0 CLP ADC TIC

Upslope: .20 Area Reject: 9333. Mo< Peaks: 7 Bunch 1 nq: 1 Dns 1 ope 0.0 0 Resul ts File IP37''4 Sorted by Time'^'Area NT

Peak

1

3 4 5

R. T, min.

<• I r s t ' . •: a n

5.23 7.53 8.57

11.08 29. 19

63 181 231 356

1244

ma x >can

71 184 235 358

1247

last scan

73 187 237 363

125 0

p >:•• a V.

he i gh t

44369 26758 54991 11328 68172

r ato area

101897 65402

147588 30867

196565

corr a r e a

101652 65306

146795 29926

192855

5-2.71 3 3.86 76. 12 15.52

100.00

% of total

16.6 19 10.677 24.000 4.893

31.^30

6 /

29.27 29.49

1250 126 0

1251 1262

1260 1267

16740 3 045

71779 14466

65265 9857

3 7 .84 5. 11

10.670 1.6 12

Sum of corrected areas: 611656 Summary of Unknowns PBM Library Search and Quantitation

Standard

1 2 3 4 5 6

Concentration Area

40.0 40.0 40.0 40.0 40.0 40.0

93331, 123829, 157451. 190612, 222422. 216144,

Re ten tion T ime

11.35 15.62 21. 08 25.66 33.99 38.17

Unk nown U) 1 ndow

3.81 -13.74 -18.35 -23.37 -29.83 -36.08 -

13.74 18.35 23.37 29.83 36.08 45 . 03

Dilution Factor (DF) Amount Method (AM)


Correction Factor « •••••••• > (AM / AU) / (OF • FSJ

Cone Int Std

Area Int Std

1. 0 0

0. 00

Unknown Concentration Area Unk • Correction Factor

10:02 PM UED., 16 D E C , 1987

Ul tn >

o o to

o o

12 16 2e 24 26 3t 4tl 44

Fjl» >P3794 Bpk Rb 29086

4 3

2UL MUZ 7 6 S 6 1 0 BNfl 10UL BH392->1ML HP«2 SUB nOO DVC

S c a n 71 S . 2 3 n i n .

44 53

I T T T f 40

' 1 1 ' > ' 1 ' ' I 63

79 /

93 / 107 121 123 13J

80 I • ' • ' • ' I '

100 I > I I I I > I I '

120

H r e a =

U n k n o w n 4^, 1 1 0 1 6 5 2 . 0 T e n t a t i v e C o n c e n t r a t i o n i s uA . 0 0

Sample file: >P3794 Spectrum #:

No data base entries were retrieved.

in tn >

o o to

o CJ o

File >P3794 2UL MU2 765610 BNfi 10UL BN392->JHL HP»2 Bpk fib 13526 SUB flDB DVC

43

Scan 184 7.53 Bin.

1

J-t-r-rr-

E9 Sl 66 69 93 101 :

V I f I f T I I I f I I I I I I I I I I I I I I f I • I I I I I I I I T I I < » I I > I r I I I I I I I I I I I

OV 7C 1(1 «

r i l * >BICDB Bpk fib 9999

Hydroperox id* , 1 , 1 - d i • • t h y l e t h y l (9CI) Scan 1591 0 . 0 0 min .

^ 0 J

41

, u^

4 3

/

• 1 • •

50

/ 5 6

, ,>-4.l-

/

• ( • • • ' 1 •

7 3

• • ' 1 • • ' • 1 ' ' ' ' 1 •

8 9 /

" M ' ' ' ' 1 ' ' • • 1 ' ' • • 1 ' '

• ^

46 50 60 88 se 108

H r e a

U n k n o w n * , 2 6 5 3 0 6 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s

1 . H y d r o p e r o x i d e , 1 , 1 - d i me t h y I e t h y 1 ( 9 C r )

2 6.00

9 0 C4H10O2


18^ No. of ion ranges searched: 46

Prob. CAS i\ CON * ROOT K DK *FLG TILT S

15 75912 1591 "BIGDB 34 31 1 0 36

CON C_l R_IU

57 3

Ul tn

o o to

o Q O CP

Fi1* >P3794 Bpk fib 20983

43 /

2UL MU2 765610 BNfl 10UL BN392->1ML HP»2 SUB fiDD DVC

59

53

I ' l ' i ' t ' i I I I '

71 80 87 /

107 I I I I I' I'l I I t j I I I I I I I I I I

Scan 235 8.57 n m .

15 : / •

1 1 ' ' ' ' I . ''' I ' ' ' ' I ' ' ' ' I '''' I 1 V O 1 Ccl I TV

Fil* >BIQDB Bpk fib 9999

43 -i /

Cuanidin* (8CI9Cn

59

Scan 1581 0 .00 i i i n .

0 -W

60

' ' I ' 68

• I ' ' ' '

180 * I I I I I I I

128 148

U n k n o w n ^^, 3 A r e a = 1 4 6 7 9 5 . 0 T e n t a t i v e C o n c e n t r a t i o n i s

1. Guanidme (8CI9CI)

63.0 0

5 9 CHt N3

Sample file: >P3794 Spectrum »: Search speed: 1 Tilting option: N

235 No. of ion ranq es searched: 46

Prob. CAS W CON * ROOT K

42» 113008 1581 "BIGDB 23

DK #FLG TILT \

44 2 0 74

CON

22

C_I R

17 Ul tn >

o o to

o o

F i l e >P3794 Bpk fib 2032

43

2UL NU2

59 87

765618 BNft leut BN392«>1ML HP«2 SUB ADD DVC

ill .1 69

11 i ' ( i 1 1 1 1 1 1 1

88 12T 156 I

Scan 358 11.08 Bin.

199

I r 111 1111 11 I I n I 11 I'l I IT111 I I I n I I I I 11 11 ! 11 1 1 1 1 1 1 1111

\vZ 12v \TZ :66 1S8 TT'-e

File >BICDB Bpk flb 9999

45 /

t-r4V,

48

59 /

K

Ethane, isothiocyanato- (9CI1

87

Scan 6620 0.00 min.

72 /

>e f I'l 11 f i l l

89

88 188 ' » i T T l ' I H | T " > H [ r ' l t l y i | t l f y f T ' f > i | » » l > T T ^ - » ^ T^^'f

128 146 160 168

File >B!:SB Bpk fib 4280

Thiocyanic acid, etSyl ester (8CI9Cn

87

Sc*n 6S7i 0.00 Bin.

45

59 /

04

72 /

89

40 60 ' ' r " ^ I' " • I I ., I . I ,i .•! • ...I • . . . 1 . •• . ) , •• •;• i . ,, y ,

80 100 120 140 160 160

F i l e ^Bl&IiB Bp>: fib " 2 0 0

43

59 72 /

ficetanide, N - e t h y l - (eC19Cl)

87

88

Scai^ 6614 O.CiO Riir,.

1 1 ^ I 1 1 1 1 1 I'l 1111 1 1 1 1 1 n I i'l 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 11111 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1111

40 60 88 100 120 140 160 180

Area = Unk nown ^ , 4 29926.00 Tentative Concentration is

1. Ethane, isothiocyanato- C9CI) 2. Thiocyanic acid, ethyl ester (.8CI9CI) 3. Acetamide, N-ethyl- (8C19C1> 4. Propana1 , 2-hydroxy-2-methy1 - (9CI) 5. Morpholine (ACN)(601901) 6. Dodecanamide C9C1)

13.0 0

87 C3H5NS 87 C3H5NS 87 C4H9N0 88 C4HSu2 e^ C4H^r40 199 C12H25NO

Sample file: >P3794 Spectrum tt: Search speed: 1 Tilting option: N

1.

358

Prob. CAS # CON * ROOT K

37» 542858 6628 "BIGDB 34 72

No. of ion ranges searched:

DK #FLG TILT X COtJ C_I R.

83 29 14

Ul cn 3>

o o to

o CJ o

F i l e > F 3 Bpk fib 6

7 9 4 6 8 6

5 5

J 4 0

F i l e > B I Bpk fib 9

CDB

5 5

,1 1 4 8

F i l e > E I G D B Bpk flb 9 9 9 9

4 1 . — • '

i , ! 4 0

F i l e ;> B ! ( Bpk flb 9 '

-

a '

-IiB ^?5i

5 5

fl 0-1 r - i - 1

4 0

2UL I1UI2 7 6 5 6 1 0 BNfl l e U L B N 3 9 2 - > 1 M L H P » 2 SUB fiDD DVC

/ / 9 6

III i , r ^ r ^ P 1 3 7 1 6 6 1 8 0 1 9 4 ll . 1 .11. II, i ^^ .—• -^ y /

6 7

B i c y c

6 7

1

, 1 , , , 1 , 1 , 1 , 1 I 1 , 1 1 1 1 1 T ' T I

8 0 1 2 0 16C

1 , 1 3 - T e t r a d e c a d i e n e ( 8 C I 9 C I )

f 9 6 j / 1 8 9 1 2 3 , 3 , , ^ ^ , j ^ .

SO 1 2 0 1 6 6

l o C e . 2 . O J d o d e c a n e , 11 , 1 1 - d i m e t h y l

®2 9 6 , ./ 1 1 0 1 3 8

i. Ii / i ^ ^ r ^ ^ ^ 7 ' . ,111 jii B. - •. ' / 1 1 . 1 , 1 1 . 1 . . . , . . . , . . . , .

8 0 1 2 0 it jO

6 8 ' • V ,

ll . 1 . .!

I , U ' - r . o d e c a n e d i o l t S C l ^ C I )

52

^ 9 6 / 1 0 9 1 2 3 1 3 8 1 S 4 1 7 2

1.. it,. ;:. ^ . ^ ^ ^ I 1 I I 1 1 1 I I 1 1 • T 1 I 1 1 1 1 1 1 1 I 1

8 0 1 2 0 1 6 0

2 0 0

1 9 4 1 9 5

' '• 1 ' ' ' 1 2 8 8

- ( 9 C n

1 9 4 1 9 5

' 1 ' " ' 1 2 0 0

2 0 3

- t 1 1 I 1 I

2 0 0

S c a n 2 9 . 1 9

2 5 0

2 4 0

S c a n 0 . 0 0

2 4 8

S c a n 1 0 . 0 0

. • 1 .

24 i )

1 2 4 7 a i n .

8 1 2 6 a i n .

5 4 2 0 • i n .

o c a n S 4 3 0 j C i .Ce . i i n . 1

2 4 8

A r e a = Unknown i/^, 5 1 9 2 8 5 5 . 0 T e n t a t i v e C o n c e n t r a t i o n 1 s 40. 0 0

1.

3. 4. 5. 6 . 7.

1,13-Tetradecad lene (8CI9CI) Bicyc!o[8.2.0 ]dodecane, 11,11-dimethyl. 1,12-Dodecanediol 18C19CI) 9-Octadecyne (9C1) 1,14-Tetradecanedio 1 (8CI9CI) Cyclododecanol (8CI9CI) Cyclododecene, lE)- (8CI9CI)

t9CI ) 194 C14H26 1-54 C14H26 2 02 C12H2602 25 0 C18H34 23U C14H3 0O2 184 C12H2'*0 166 C12H22

Sample file: >P3794 Spectrum *: Search speed: 1 Tilting option N

Prob, CAS # CON • ROOT


DK *FLG TILT CON C I R

Ul tn >

o o to

1 . 2 . 3 .

9 9 * 8 4 » 73

21964498 62338298

5675514

8126 15420

5430

"BIGDB "BIGDB "BIGDB

123 85

108

5 58 29

1 2 1

0 0 0

90 6 4 8 4

6 8

25

68 55 32

o u

http://Ci.Ce

REFERCNCE STRNDflRD SPCCTRUW F i l e >P5SS9 b i s (S-Ete iy l t iexy l lPh t t ia la te 871027 20»51 Bpk fib 39968 SUB

149 40000-

1 57

L 71 83

. j f l . J . . .1

48

113 ,32 _ • > . . < . . - . /

I I 1 1 I i n I I I I I I I i I I I 1 I I I I I I I I I

167 / 180

• I. y S8 128 L60 268

' I I • I I I I I 248

Scan 1516 34.65 a i n .

-100

279

r | - | • • ' l ^ 268

SAMPLE SPECTRUM tBflCKCROUND SUBTRACTED) Fil« >P3?94 2UL t1U2 765618 EHfl IOUL EH392=>in5. HP«2 Bpk flb 18560 SUB

149 20O00T /

4 ^Z^ 71 83 J2, \ ll I / / -^ ^

9 - 1 A f.^. (.1(1 ^ Y ' ' I'I'I i'< ri I'l I I '*

Scan 1514 34.63 a m .

80

-100

167 / 279

120 160 I ' ' I M ' I I ' ' • 1 '•

200 240 I I I I

•>f.9t

SAMPLE SPECTPUM (UHOLTERED) Flle >P3794 ^ 2UL MU; Bpk O D 18560

20000-3

3 C7

765iie BHfl leUL EH392»>inL HP»j

149

Scan lEl* 34.63 m m .

J \ / / t l * y

40 80 120 160 8^^!

H00 * £ 1 iOI

/ 207 /

279

200 240 f ' ' '

280 ¥-

Data File: >P3794::B3 Name: 2UL MU2 765610 BNA Misc: IOUL BN392->1ML HP*2 Quant Time: 871216 21:54 Injected at: 871216 21:08

Quant Output File: '••P3'?94: : QT

BTLit2 9 Quant ID Flle: !IDXPP::HE


Compound No: 59 Compound Name: bis(2-Ethyihexyl )Phtha 1 ate Scan Number: 1514 Retention Time: 34.63 m m . Ouant Ion: 149.0 Area: 37973 Concentration: 14.92 ug'mL q-value: 89

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TOTAL ION CHROMATOCROn File >P3ei6

200000-

igeoeen

160000-

1 140000-1

_ 120000-

100000^

seeee-

60000-

-40000-

238oS-

0J T r 4

3s.e-s«e.e 200

. 1 . . . . 1 . . .

[/>

o c if a.

£

1

->-T-T-,, • 1 ,

6 8

:_ T

aau. 2UL TIC 400

•r n 1

1

• 1 •'T— 10

o 1 •

1

12

MWJ ?^?4ld

600 . . . 1 . . . . 1 .

1

a. <

J

1 • 1 ' 1 •

14 16

fiCIDPlOLiL BN392-

800

Z

1 • 1 • 1 • 1 • 1

16 20 •• T ' 22

>1ML HP-i.

1000

to

1 2 a. E 1 <<•

-r-' .. *--T •^

24

Data File: >P3316::B2 Name: 2UL MUI2 765610 AC IDR Misc: IOUL BN392->iML HP#2 765575

Quant Output Fil' -P3816::QT

BTL1I 34

Id F11e: IIDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15


TIC page 1 of 2

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TOTAL lOH CHPOMflTOGRAM File >P381635.6-500.0 aau. 2UL MW2 766610 flCIDR10UL BN39J«>1ML t iP ' t

Tic 1000

200000-

180000

160000^

140000^

120000^

100000^

8 '"? *3 0"

60000-

40000

28008-

0-

n I

c f

X a.

1200 . . I . .

•I ^

1400 • , I I .,

1600 ' . . - • ' • - . . '

1800 . . 1 .

S -II

yy-u^ W"

2000

j i ^ 2 I i

" % 7 " ^ '

i .

'A.. ^ ^

•J\ ^

I • I • I ' I • I • I ' 1 ' I • I • I ' I ' I ' I • 1 ' 1 ' I ' I ' > • I • I ' I

26 28 30 32 34 36 38 4e 42 44

Data Flle: >P3816::B2 Name: 2UL MU2 765610 AC 1DR Misc: IOUL BN392->1ML HP*2 765575

Quant Output File: ^P3816::QT

BTL^f3^

Id Flle: IIDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15


TIC page 2 of 2

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QUANT REPORT

Operator ID: GLENN Quant Rev: 6 Quant Time: 871218 06:12 Output File: '^P3816::QT Injected at: 871218 05:25 Data File: >P3816::B2 Dilution Factor: 1.00000 Name: 2UL MU2 765610 ACIDR Misc: IOUL 8N392->1ML HP#2 765575 BTL:t34

ID File: I IDXPP: :ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Compound R.T. Scan^t Area Cone Units

1) •I,4-DICHL0R0BENZENE-d4 3) 2-Fluoropheno1 (SS) 6) Phenol-d6 (SS) 14) *NAPHTHALENE-d8 26) *HCENAPHrHENE-dlO 41) 2,4,6-Tr1bromopheno 1 (SS) 42) •PHENANTHRENE-dlO 52) *CHRYSENE-dl2 59) bis(2-Ethylhexyl)Phthalate 61) •PERYLENE-dl2

• Compound is ISTD

11 8, 11 15, 21 23. 25, 33. 34, 38.

.80

.76

.51 ,57 .02 ,57 .59 ,94 ,57 14

391 242 377 576 84^ 969 1068 1477 1508 1682

7755 32243 41262 32699 24086 28968 58909 78945 15445 62601

40, 157, 12' , 40, 40,

111. 40, 40, 6.

40.

,00 ,39 .26 ,00 ,00 ,22 .00 ,00 ,39 00

ug. ug-ug ug-ug ug. ug/ ug-ug/ ug/-

-mL mL mL 'mL mL mL ••mL 'mL mL mL

95 53 9g

o4

•9 b

35 6o 53 87 79

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Ul


S a m p l e : 2UL MLJ2 765610 ACIDR O p e r a t o r : GLENN M isc : IOUL BN392->1ML HP#2 765575 S y s . # : 2 MS m o d e l : 70 SU/'HU r e v . : lA

Method f i l e : EXTBNA T u n i n g f i l e : MT8002 S o u r c e t e m p . : 0 A n a l y z e r t e m p . : 280

MS 12/'18/-'87 BTL*34

ALS « : 0 No. of extra records: 1 Transfer line temp. :

5:25

Chromatograph Chromatograph Chroma

>P3ei6 35 .01 500.

Upslope: Dns1 ope: 0

Peak

it

1 2 3 4 5

6 y 8 9 10

11 12 13 14 15

16 17

18 19 20

R.T. min .

27.05 28.34 29.13 29.24 29.30

29.58 30.75 31.18 32.10 32.28

33.2 0 33.34 34.37 35.00 35.35

35.62 36.01 36.31 37.26 40. 17

tograph

ic temperatures : 30. 1c t imes, min ic rate

2UL MLJ2 7656 0 CLP ADC TIC .20 Area Rej .00 R

first -ican

1138 1200 1240 1245 1248

1261 1319 1339 1334 1394

1439 1446 1496 1527 1544

1556 1576 1591 1636 1779

e s u 1 t s

max scan

1140 1203 1242 1247 1250

1264 1321 1342 1337 1396

1441 1448 14'98 1529 1546

1559 1578 1593 1639 1781

Summary of Unknowns

Stand

1 2 3 4

: 4.0 , deg/min: 8.0

10 ACIDRIOUL BN3

ect : 5416. M File 1P3816 S

last scan

1143 1206 1245 1248 1254

1267 1324 1346 1389 1398

1445 1450 1501 1531 1551

1564 1582 1595 1642 1787

Sum of PBM Ll

ard Concentration

40 40 40 40

.0

.0

.0

.0

peak height

15665 20101 28431 12971 14752

13905 11438 17252 11526 10685

9547 10152 16397 10473 13452

19910 9762 17938 26095 14342

corrected

300. 7.3 0.0

0. 0. 0.0 0.0 0.0 .5

92=>1ML HP4f2 765575

av Peaks: 20 Bunch orted by Time/Area

raw area

60321 101219 154885 79088

134932

132202 133384 236209 188792 156308

260170 188657 295912 254239 510572

602371 441826 363887 633153 696736

areas:

cor r . area

27956 41775-91875-36449 41262,

37080 28854 76204-35444 36811

422 09* 31165 5748-7-

29512 66965-

107573-32232 57929-

101758-59579-

1040119. b r a r y Search and Quantitation

Area

54156. 74425. 119951. 156999.

Re tent ion T I m e

11.80 15.57 21.02 25.59

0. 0.0 0.0

inq: 1 INT

corr. *» ma.-. .

25.99 38.83 85.41 33.88 38.36

34. 47 26.32 70.84 32.95 34.22

39.24 28.97 53.44 27.43 62.25

100.00 29.96 53.85 94.59 55.38

Unknown Ui ndow

3.85 -13.68 -18.29 -93.31 -

13.68 18.29 23.31 29.76

S to

4 8 3 3

3 •7

/ 7

-7

4 2

2 6

10 3 5 g

5

of tol

.633

.016

.833

.504

.967

.565 ^ 7 ^

.3 2c. -i08 539

0 58 996 527 837 433

342 099 569 783 7-

in tn >

0 0 to

0

<T<

F i l e >P3 Bpk fib 4

8 1 6 0 1 2

4 3 /

0-1 ' •TO

Bpk Rb 9 Cl 9 '

[)B ?9 3

/

4 8

Fl l e >BIGDB Epk fib 9 9 9 9

4 3 , /

40

F i l e >BI Iipk Ob 9 5.99

4 3 /

1 0"^ 1 1

40

2U

!

il

L

57

/

r " 1

I

|i

17 /

6 0

c

1 11

57 /

1 60

c

H

.7 /

f 1

60

nU2 7 6 5 6 1 0 fiCIDRieUL BH392->1I1L HP*2 7 6 5 S 7 S SUB ADD DVC

7 95 / 99 1 ,3 127 141 169

' r ' 1 ' 1 OV

1 .l 8 8

•1 - 1 80

' a d ^ c a n e

'1 / 8 5

/

I ' l 1 I I 1

80

' 1 ' I ' 1 1 1 ' 1 ' 1 ' T ' n — ' ^ ^ ' 7

: 8 S : 2 8 148 !&6 ! S 8

P e n t a c o « a n e ( e C I 9 C n

99 113 127 141 155 169 1 8 3 J ' 1 ' 1 ' ' 100 120 140 160 ISO

O c t a c o s a n e ( 8 C I 9 C I )

•^^ J13 127 141 lEE 169 183 . , ' ' ' •• . ' '

. 1 . 1 . , . 1 : - , 1 I . 1 < 1 • 1

100 i t 0 140 i t e l e o

, 2 , f c , 1 0 . 1 5 - t e t r a i i i e t h y l - ( 9 C I )

99 113 1 2 - 141 15S 169 183 ,' ,-' / / / / /

1 ' 'I 1 | - ' i 1 I 7 1 1 1 1 I f 1 7—r T~»" I 100 120 140 160 180

S c a n 2 8 . 3 4

2 1 9

• I ' l *

S c « n

e.ee

197 211

2 0 0

Sc».r\ 0 . 0 0

197 211 • '

. 1 - 1 •

200

1203 • i n .

'-B

6 8 9 2 • i n •

6093 • i n .

X

S c a n 6 1 t l 0 . 0 0 * » - . .

197 2 1 i r

' 1 ' 1 •

2 0 0

Area Unknown #,2 41775.00 Tentative Concentration is 11.00

1. Pentacosane <8CI9C1) 2. Octacosane (8CI9CI) 3. Heptadecane, 2 ,6 ,10 ,15-1etramethy 1 4. Nonacosane (8CI9CI) 5. Eicosane, 10-methyl- (901) 6. Pentatriacontane (8CI9CI) 7. Tetratetracontane (8CI9CI)

(9C1 )

352 394 296 408 296 492 618

C25H52 C28H5e C21H44 C29H60 C21H44 C35H72 C44H9 0 tn

>

Samp 1e file' Search speed

>P3816 Spectrum »: 1 Tilting option: N


O O IO

O CJ

Prob CAS # CON * ROOT K DK #FLG TILT CON C I

1 . 2 . 3 . 4 . 5 . 6 .

86 83 83 83 83 78

629992 630024

54833486 630035

54833237 630079

6092 6093 6161 8905 6226 6147

"BIGDB "BIGDB "BIGDB "BIGDB "BIGDB "RIGOR

103 92 83 88 82 7 0

37 45 50 57 51 RI

2 2 2 2 2 •?

0 0 0 0 0 n

79 82 81 80 78 ->Q

5 5 1 4 5 /,

6 0 57 57 57 57 Kc;

3 7 27 23 25 22 1 A.

File >P3816 2UL MW2 765610 ACIDRieUL BN392->1ML HPa2 765575 Scan 1242 Bpk fib 2228 SUB ADD DVC 29.13 ain.

55

^ " • • ^ , - ' " 9 6 .„„

55 219 250 t i r |j / - *'' 123 138 i< pilil, ,J|II,,JI,I,.,I1LI, IL, , ; , , < - , .^TTI .-r •tv O V t c B I O

I ' ' I I I > I I I ' ' I I I C V V £-VV

File >BICDB Bpk fib 9999

55

9 - O c t a d e c e n - l - o l , ( 2 1 - ( e C I 9 C n S c a n 5 5 4 6 0 . 0 0 a i n .

Li 48

69 ez 9 6

III.I M • nillii.

r ^7 124 1 111, , H I . , » ^ , • • • f

38 166 lee 194 208 222 250 I I / I ^ ^

80 128 160 208 ;40

F i l e > E I I : B B Epk fib 9 9 9 9

C y c l o d o d e c e n e , ( E l - f 8 C I 9 C n Scan 54s8 0 .00 mir,.

67 / 8 3

/ 9 6 109

I 123 138 166 !•;.•?

4 0 80 12tf I t o £0'iJ 24H

F i l e >FK-riB Bpl; fib '?9?'?'

ilL

1 , 1 2 - D o d 9 c a n e d i D l t S C I 9 C l )

' 96 / 109 123 138 154 172

O.Ot n i i n .

2 0 3

4 0 I i " l ' I ! • - ' I l - l

80 120 ' I ' I ' I ' ' • ! " • I I I I • I I I I

160 2 0 0 2 4 0

Are< U n k n o w n ^^, 3 9 1 8 . 7 5 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 23.0 0

1. ^ •

3. 4. 5. 6. 7.

9-Octadecen-l-ol , (Z)- (8C19CI) Cyclododecene, (E)- (8C19CI) 1,12-Oodecanedio I (8CI9CI) 16-Octadecena1 (9CI) 17-OctadecenaI C9CI) Cyclododecanol (8C19CI) Cyclododecene, (Z>- (8C19CI)

268 C18H360 166 C12H22 202 C12H2602 266 C18H340 266 C1HH340 184 C12H240 166 C12H22

Sample file: >P3816 Spectrum #: 1242 Search speed: 1 Tilting option: N No. of ion ranges searched 48

Prob. CAS * CON # ROOT K DK tFLG TILT S CON C_rR_IU

73 143282 5546 "BIGDB 76 92 55 14 H-CD

F i l e > P 3 8 1 6 2UL nW2 7 6 5 6 1 8 fiCIDRieUL B N 3 9 2 ' > i n L HPa2 7 6 5 5 7 5 Bpk fib 3 0 3 6

J 4 3 57 /

SUB fiDD DVC Scan 1342

31 .18 a i n .

) ' I ' l ' l I I I I I T I I I I 48 60

71 / 85

i f i i . i I l i l t I

9 9 111 113 1 27 141 155 1 6 9 1 8 3 196 t

^ ' / / -^ -^F., I III II I'l i i i | I I I 1 1 1 ! iri n i l III i i | i ii' 0

11 I I'l'l I I I I I I II I'l III II I'l I i i | I I I i | n I I'l n i l III II

180 128 148 160 188

File >BI(;DB Bpk flb 9999

43

Docosane (eCI9CI)

57 /

Scan 0.00

6221 • in .

71 85

' ^ 111 113 127 141 155 169183 197

40 60 80 180 120 14d 160 180

File >BIGDB Iron, tricarbony1CN-I pheny1-2-pyridiny1 me thy1ene) Scar. Bok flb 9999 0.00

6168 • in .

43 /

71 / 85

'9 112 113 127 141 155 16?ie3 19 A 0- -W-40

' I I " 60

'•I"'' ' I I .••.,.'. . . I I""! ' 80 100 120 140

. • • • 1 . • I • • • • I '

160 l.:iO

File >BIC-D? Bpk Ob 9999

Undecane, 3 ,S-dimerhy1 - (SCI S c an 0.00

6154 oiir..

Il 0-Vf

/ 85

Tl III ' , f y \

99 111 113 12" 141 155 156

'I'l'l 1111 111 1111 n'l III' 111 111 ITI'I 111 ni'i 111111111111 I'l 11111 I'l 11II m 111111111111

40 60 80 100 120 140 160 180

Area Unknown #,8 76204.00 Tentative Concentration is 14.00

Docosane (8CI9CI) Iron , tricarbonyl[N-(phenyl-2-pyridinylmethylene)ben zenamine-N,N']- (9C1) Undecane, 3 ,8-dimethy 1- (3CI) Hexatriacontane (8CI9CI) Undecane, 5-ethy 1-5-propy1 - (8CI9CI) Tritetracontane (8C19C1)

310 C22H46 398 C21H14FeN203

184 C13H28 506 C36H74 226 C16H34 604 C43H88 226 C16H34

Samp 1 earch

1. 2. 3. 4. 5.

e file speed

Prob.

79 76 71 70 70

>P3816 1 TI

CAS #

629970 74764117 17301303 630068

2755079

Spect 1 t ing

CON *

6221 6168 6154 6193

23921

rum #: opt ion: N

ROOT

"BIGDB "BIGDB "BIGDB "BIGDB "BIGDB

1342

K

100 92 80 78 62

No.

DK

47 45 28 84 70

of ion ranc

#FLG TILT

2 0 2 0 1 0 2 0 2 0

es search

\

64 100 76 75 77

CON

10 6 12 8 8

ed:

C_I R

48 45 38 42 42

CO tn

o o to

o CJ t -UD

i . '

36 19 13

File >P3816 2UL nU2 766610 ACIDRIOUL BH392'>1ML HPe2 765575 Scan 1441 Bpk flb 1041

4 3

4{

SUB ADD DVC 3 3 . 2 0 » i n . 57

lUUM 85

i n 125141 147 169 181 203 211 221 :

• I '"' I I r ' 1 ' I •' I I I ' I I r' I ' I' ' I 1?f> e^n *^f* * ^*\ ^^ft "^Cf^

I" in J Dv CV 188 i^v inv lev i6«) ^vv c.t.'o


,43

Nonane, 3,7-di»ethyl- (eCI9CI) Scan 0.00

57

IS 71

85

'l*^! •'•I'-

113 127 141 156 /

—I "f I—>—I—"—r-"—I—""-I—'—r"'—r—'—i • i—' i • i—'—i—' i •—r-^ 50 108 128 14f3 160 iSG 208 228

6100 • in .

4-0

File >BICDE Epk fib 9999

Pentatriacontane (8C19CI) Sc an

o.ee

71 85

113 127 141 155 169 183 197 211

^'i- ' I I'l - , — I — I '"'I • I"' 1 •' I ' — I ' ' 1 '• I • I • I ' I — ' — T — ' — r ^ ~ T — ' - T

60 80 100 Ii*;' 140 lt)0 IS'.' 200 'ilK

6147 mi n .

r

-Hj

Bpk Ob 9'J?9

7?

T*tratetricontane ieC:9CI) C1.C10

99'.;v ni i r

8 5 —•' 113 12 ; 141 155 169 183 197 211 225

/ / / / / / /

40 60 ' ~ I •• I i " l ' T ' I ' ' I I I ' I I I I ' i I I ' ' I ' I I I I I I I 80 100 120 140 160 180 200 220

A r e a Unknown ^^,11 4 2 2 0 9 . 0 0 T e n t a t i v e C o n c e n t r a t i o n 1 s 8. 00

1 2. 3. 4. 5, 6 . 7,

Nonane, 3,7-dimethy1- (8CI9CI) Pentatriacontane (8C19CI) Tetratetracontane (8C19C1) Hexane, 3,3-dimethy 1- (8CI9CI) Decane, 2,3,8-trimethy1- (9CI) Octane, 6-ethy1-2-methy1- (9CI) 1-Nonene, 4,6,8-1rimethy 1- (9C1)

156 C11H24 492 C35H72 618 C44H90 114 C3H1S 184 C13H28 156 C11H24 168 C12H24

Ul cn

Sample file: >P3816 Spectrum •: 1441 " Search speed: 1 Tilting option: N No. of ion ranges searched: 48 Q

O to

1 .

Prob. CAS * CON # ROOT K

41 17302328 6100 "BIGDB 57 29

DK #FLG TILT % CON C_I R_I' ^ CJ

0 0 87 43 14 3f o

File >P3816 2UL nU2 765610 ACIDRIOUL BN392->1HL HPa2 765575 Scan 1498 j Bpk flb 2541

43 57

SUB fiDD DVC 34.37 ain.

"i I P

es

r-r-

97 / 111 125 141 154 182 196 211 225 252 :

J- L C r" -^ i. L - - ^ - - 0 I I I ' I I I' I I I I I '1 I I ' I I i' I I I 1 I 1 I I I I 1 • ^'» ,.-*» .«A/« .%.«/* I C V 1 O V ^ W £.*tv

File >BICDB Bpk fib 9999

43

Pentatriacontane (8CI9CI)

57

Scan 6147 0.00 ain.

113 127 /

141 155 183 197 211 225 239

40 80 120 160 • I • ' • I

200 240

File >B!GDB Epk flb 9999

,43 J /

57

85

Tetratetracontane 18CI9CI)

97 113 127 141 155 183

Scan 8906 0 .00 a m .

>7 211 225 23? f

0^^ 40

—T— 80 120 160 2 ye 240

File >BIGDB Bpk fib 9999

43 /

Hi?;, a t r l a c o n r a n e (SCI9CI) J c a n * ! 9 : 0 . 0 0 B , i n .

57

;U4L 3 r i ' p'l 40

• L J I "I I I r i I I ' I I I 80 120

113 127 141 155 133 197 211 225 2 3 9 t -' / ' " ^ -^ / / / ^ I-..

• I I l i t ' ' I •

160 ' I ' ' ' I I ' ' I

200 240

H r e a

Unknown 4^, 13 5 7 4 3 7 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 1 0 . 00

1. Pentatriacontane (8CI9CI) 2. Tetratetracontane (8C19CI) 3. Hexatriacontane (8C19CI) 4. Octacosane (8CI9CI) 5. Nonacosane (8CI9CI) 6. Pentacosane (8CI9C1) 7. Undecane, 3,8-dimethy1- (8C1)

49 2 C7'FH72 618 C44H9 0 506 C36H74 394 C2eH5e 408 C2^H60 352 C25H52 184 C13H28


1498 No. of ion ranges searched 48 tn

>

P r o b .

58

CAS #

630079

CON *

6147

ROOT

"BIGDB

K

83

DK •FLG TILT \

68 2 0 83

O CON C_I R_I ^

17 25 O io to

File >P3816 2UL MU2 765618 ACIDRIOUL BN392->inL HPa2 765575 Scan 1546 Bpk Ab 2237

43 /

57 SUB ADD DVC 35.35 Bin,

J 11 97 / J. I i-^l 1 ll

113 127 141 168 182 196 210 224 239 ' I I I I I ^ I I i I • |i 1 I I I I I 1 I V I I I I I I I I ' I I i' I I t I I I I I I I I

k C v lOO cvv cnv

File >SICDB Bpk fib 9999

43

Hexatriacontane (8CI9CI) Scan 6193 0.00 min.

9>l. • ll, ,.lJ 40

97 113 127 141 155 163 197 211 225 / / / /

239

60 120 160 lOO I • T • •

240

File >BICDB Eok fib 9999

43 5-

Pentacosane iSCI9CIi Scar, 6892 0 .00 M i n .

8 5 99 113 127 141 155 18? 197 211 225 239

40 00 120 I • • ' I '

160 - T — -

200 • 1 • 240

4-0

F i l e ..-Blulili Bpl flb 9999

1*/

T e t r a t e t r a c o r . t a n e t8C I9C lJ ; can 590': 0 .00 a i r , .

8 5 113 127 141 155 163 197 211 225 239 \

48 8 0 •' I r-120 160 -'-r I ' I I

200 - ^ r. ' I '

240

A r e a = U n k n o w n t , 15 6 6 9 6 5 . 0 0 T e n t a t i v e C o n c e n t r a t i o n 1 s

1. Hexatriacontane (8C19CI) 2. Pentacosane (8CI9C1) 3. Tetratetracontanc (801901) 4. Pentatriacontane (8C19CI) 5. Tridecane, 7-hexyl- (8C19C1) 6. Pentadecane, 2-methyl- (8CI9CI) 7. Tetradecane, 4-ethyl- (9CI)

0 0

506 352 618 492 268 226 226

C36H74 C25H52 C44H9 0 C35H72 C19H40 C16H34 C16H34

Sample file: >P3816 Spectrum *: 1546 Search speed: 1 Tilting option: N No. of ion ranges searched

Ul m

4 >

o o

Prob. CAS # CON # ROOT K DK #FLG TILT \ CON C_I R_ M

67 630068 6193 "BIGDB 81 81 2 0 83 14 34 O CJ to to

r i l e >P3 Bpk Ab 3<

316 507

43 /

1,

r i i * >B i ( Bpk Pb 9<

2UL nU2 765610

57 ^ ' 71

97 1. ., .| ,' 1 1 1 1 1 1 1

OV

:oB ?99 43 /

ll 48

F i l e >BICDB Epk flb 9999

•7?

r. ILL . . O-T"'" •

40

F i l e :> BIC ppk fib :*« t99

43

4 0

57 . - - ' •

85

i 1 ' 1 ' ' ' 1 '

se

j i

57

^ 85

I.l :.i • 1 " 1 T , . , .

80

Ir

.u

Pen t

97

Te-tr

97

' • " ' i

on , . ^ r 1 c a r s o n

57

35 99

- ..1 i 8 0

' • I

fiCIORlSUL BN392->1ML HP«2 765575 SUB ADD DVC

113 127 141 , 5 5 i e 3 , 9 , 2 , 1 / / / / - . ^ ^ - - ^ I

128 268

a t r i a c o n t a n e ( 8 C I 9 C n

113 127 141 155 169 1 1 / / . . ^

128 168

a t e t r a c o n t a n e (8C I9CI )

113 127 141 155 169

' " ' 1 " • ' T ' ' " ! ' " • 1 120 160

2C0

197 211

20t'

197 211

300

. ' l C M - i p h e r i y l - i : - p y r i d i n y l n i e t h y l e n i r

113 127 141 155 169 197 211 1 / / / ^ \ /

120 160 I T I 1 1 1 1

200

Scan 3 5 . 6 2

225 239 / /

15E9 • i n .

248

Scan 0 . 0 0

225 239

6147 • i n .

2 4 8

Scan 8906 0 .00 B i n .

225 239t - 1 A

1 — ' ' • r • ' • •0 240

) Sc an C.OiO

225 239 / /

61t% Hi 1 n .

r : .

' ' 2-io' "

Area Unk nown i\ , \ t i 107573.0 Tentative Concentration 1 s 2 0.00

4. 5 . 6. 7.

Pentatriacontane (8CI9CI) Tetratetracontane (8CI9CI) Iron, t r icarbonyl [N-(phenyl-2-pyridinylmethylene)ben 2enamine-N,N']-'(9CI) Heptadecane, 2 ,6 ,10 ,15-tetramethy1- (9CI) Heptacosane (8C19C1) Hexadecane, 1-iodo- (8C19C1) Hexadecane, 2-methyl- (8C19CI)

4 9 2 6 1 8 3 9 8

2 9 6 3 8 0 3 5 2 2 4 0

C35H72 C44H9 0 C21H14FeN203

C21H4a C27H56 C16H33I C17H36

Samp 1e file: Search speed:

Prob,

>P3816 Spectrum «: 1 Tl11ing opt ion:

CAS i\ CON t ROOT

N 1559

No. of ion ranges searct.ed:

DK #FLG TILT \

57

CON C I R lU

1 . 2 . 3 . 4 . 5 .

86 83 83 7 4 7 1

630079 7098228

74764117 54833486

5 9 3 4 9 7

6147 8906 6168 6161 6220

"BIGDB "BIGDB "BIGDB "BIGDB "BIGDB

9 7 113

8 7 8 7

102

5 4 43 5 0 4 6 5 1

2 2 2 1 2

0 0 0 0 0

66 7 4 90 8 1 79

5 7 5

13 13

60 5 4 5 7 39 3f i

3 1 52 25 4 4

36

Ul m >

o o to

o CJ to CJ

File >P3816 2UL MU2 765610 ACIDRIOUL BN392->1HL HP-2 76ES7S Sean 1593 Bpk Ab 2654 SUB ADD DVC 36.31 ain.

57 43 - ^

85 „„ , I / 9^ 113 127 154 168 196 210 225 238 267 :

i W i i | i i M i i ' i i i i i i i i i , i i ' ^ ' ^ j -I I ' l I I ' l 1

!28 I I I I I I I I I I I I I I I I I I I I I I

168 200 243

File >BICDB Bpk Ab 9999

43

Hexatriacontane (8CI9Cn

0-V

57

iUi

Scan 6193 0.00 nin.

97 H 3 127 155 169 183 211 225 239 253

48 60 128 168 288 248

File >BICSS Bpk flb 9999

43

O c t a d e c a n e , 2 - i i . e t h y l - ( 8 C I 9 C n

65

I :!3 127 155 169 183 211

Scan 27420 0.00 min.

- ^ 40 80 120 160 200 240

File PIC-DB Epk fib 9999

Heptacosane (8CI9Cn Sc an 6220 0 .0 0 II. 1 r..

4 3 j:-

'•l 40

85 t j / 99 113 127 155 1 9 183 211 22^' 2 39 253 F

T I I H I I' l I i"i I I'I I I I I 1 1 I '1 I I I I'r I I I I 1 I I I I I I ' O

80 120 160 200 240

A r e a Unknown # , 18 5 7 9 2 9 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i : 1 0 . 0 0

1. Hexatriacontane (8CI9CI) 2. Octadecane, 2-methyl- (8CI9CI) 3. Heptacosane (8C19C1) 4. Pentacosane C8CI9CI) 5. Heptadecane (8CI9CI) 6. Undecane, 3,8-dimethy 1- (8CI) 7. Hexadecane (8CI9CI)

506 C3oH74 268 C19H40 380 C27H56 352 C25H52 24 0 C17H36 184 C13H2S 226 C16H34


Prob. CAS • CON # ROOT

78 630068 6193 "BIGDB 68 94

1593 No.

K DK

8 94

of ion ranges searched:

•FLG TILT \ CON C_I

2 0 61 2 55

Ul m >

5; 0 0 to

R I 0 u

1 to

F i l e > P 3 8 1 6 2UL rlU2 7 6 5 6 1 0 A C I D R I O U L BN392«>1ML HP»2 7 6 5 5 7 5 S c a n 1639 Bpk Rb 2 8 3 9 SUB ADD DVC 3 7 . 2 6 B i n .

5 7 69

• '^

., 1 !• I '

81 / 1 . 95

("1 ("1

121 /

136 ^ r-1 I -1

168 ~->.,

175 /

1 I I 1

189 ..---•1 1 1 1

216 J

1 1 1 1

232 /

'•^ I

259 \

1 1 1 (

b 273. /

1 1 T 1 *•„

F i l e > B i e D B D o d e c a n e 2 - c y e l o h e x y l - , 2 - c y c l o h e x y l - t S C l ) Bpk flb 9 9 9 9

S c a n 5 4 9 9 0 . 0 0 n i n .

55 69

ill 0-¥^ JuJ

111 125 140 168 170

l|i • | i ' ' l

68

252 I

126 168 L 8 8 2 4 8 H6 I • • • I '

2 6 6

F t l f r > £ I C D B Bpk flb 9 9 9 9

41 69

8 2

: , 6 - O c t a d i e n e , 4 - i i » * t h y l - ( 9 C I )

124 125

S c a n 3 4 2 5 0 . 0 0 B i n .

0+-40 8 0 120 160 2 0 0

• ' ' I ' ' J

2 4 0 2 8 0

F i l e >B lGI iE Epk flb 9 9 9 9

-I 4 1

1 , ^ - H e p t a d i e n e , 3 , 3 - d i m e t h y l - , l E J - ( 9 C I ) S c a n 3411; 0 . 0 0 I I . i r . .

69 /

8 1 109 124

40 I 1 "H I p I I I I I ' I I I I

80 120 I I I I I ' ' ' I ' ' '

160 2 0 0 I I I I I I I I

2 4 0 I ' I'

280

^ .r ea

U n k n o w n # , 1 9 1 0 1 7 5 8 . 0 Ten t a t i 'ê C o n c e n t r a t i o n i s 13.00

4. p. _

6 . 1

Dodecane 2-cyc lohexyl-, 2-c'yc lohexyl - (3C.I) 2 ,6-Uc tadiene , 4-methyl- CCI) 1 ,5-Heptadiene, 3,3-dimethy1-, (E)- (9CI) 1 ,5-Heptadiene, 2,3,6-trime thy 1 - (SCI9CI) 2 ,6-Octadiene , 4 ,5-dimethy1- (8CI9CI) 2,6-Octadien-l-ol , 3,7-dimethy 1-, (E)- (8C19CI) 2,6-Octadiene , 2,7-dime thy 1- (8CI9CI)

252 CieH36 124 C-5H16 124 C9H16 138 C10Hi3 133 C10H13 154 C10H;3Q 138 C10H18

Sample file: >P3816 Spectrum *: 1639 Search speed: 1 Tilting option: N No. of ion ranges searched: 64

Ul tn >

o O to

Prob.

1. 70* 13151821 5499

CAS # CON # ROOT K DK #FLG TILT \ CON C_I R_IU O

"BIGDB 32 103 3 0 210 9 42 13 to Ul

F i l e >P3J Bpk flb 2S

316 ; 9 8

57

L

T i l * >B1C Bpk Pb 9<

; D B >99

57

Ii

46

F i l e > B I G Bpk flb 9«

, D B ' ^ 9 57

J l i

0-V • ' ' 40

F i l e >EI(: Bpk flb 9?

DE 99 57

L 40

2UL MU2 7 6 5 6 1 8 ACIDRIOUL BN392->1HL HPa2 SUB ADD DVC

( 9 9 127 1 4 , J 5 5 , g 2 197 2 1 0 1,1 . . r ^ . / / ^ / / ^

1 1 * ' 1 ' ' S8

/

60

71 / 8 5

J 1

80

\ A. •\ I • ¥ - r - i ' ^ T

80

1 1 1 • I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 • I 1 1 1 , 1

t t -v l e v £ « o

E i c o s a n e , 7 - h e x y I - (9C1)

9 9 127 141 155 182 197 211

120 168 2 8 8

U n d e c a n e , 3 , S - d i B e t h y 1 - ( 8 C I )

1 1_3 127 14 1 155 156

. 1 . . . 1 . . . f . . . 1 1 . . . . . . . 1

120 160 200

H e x a t r i a c o n t a n e f :?CI9ClJ

9 ' ' 127 141 165 183 197 211 .. / .'• . ^ / t ^

- | * V T " ' -r J r i I I I 1 '1 I f t T I • ! 1 I ' l ! I' T 1

120 160 2 0 0

7 6 5 5 7 5

2 3 1 1

1 ! t - T I

2 4 8

25

/

S c a n 1781 4 0 . 1 7 B i n .

2 266 :

1 ' ' ' I 0 C O V

S c a n 6 2 8 5 0 . 0 0 B i n .

2 3 9 2 5 2 281 :

2 4 0

• • • 1 •

2 4 0

2 3 9

l l l l l

2 4 0

2 5

1 • ' • 1 V

2 6 8

Sc an 0 . 0 0

6 1 5 4 B i n .

L J ^ 1 1 • • • 1 • '

2S0

Sc an 0 . 0 0

3 2 6 7

/

6 1 9 :< 1 Hi i r , .

1 A 1 ' ' ' r «••

2 8 0

Hrea

Unknown t, 2 0 59579.00 Tentative Concentration is 11.00

1. Eicosane, 7-hexyl- (9C1) 2. Undecane, 3,8-dimethy 1- (8CI) 3. Hexatriacontane (8CI9CI) 4. Dotrlacontane (8C19CI) 5. Tr1tetracontane (8CI9CI) 6. Docosane (8CI9CI) 7. Heptadecane, 9-octyl- (8CI9CI)

3 6 6 1 8 4 5 06 4 5 0 6 0 4 3 1 0 3 5 2

C 2 o H ^ 4 C13H2S C36H74 C32H6 6 C«3H83 C22H46 C 2 ^ H 5 2

Sample file: >P3816 Spectrum #: 1781 Search speed: 1 Tilting option: N No. of ion ranges searched 4(

1. 2. 3. 4. 5. 6.

Prob

79 76 70 70 70 70

CAS # CON * ROOT K DK #FLG TILT \ CON C_I R_l

55333998 17301303

630068 544854

7098217 629970

6285 6154 6193 6261 6150 6221

"BIGDB "BIGDB "BIGDB "BIGDB "BIGDB "BIGDB

101 91 74 65 61 77

44 17 88 100 107 70

2 1 2 2 2 2

0 0 0 0 0 0

76 81 81 77 92 75

10 13 6 8 10 10

48 40 42 42 42 42

Ul tn >

o o to

o 3 (J 5 cr» 1 I K

12 19

nrcorJSTRUCT S Z : { I Z H DUM." D i * ^ A c o ' j i s i t i o n

T i me 1? 5 6 D a t e FRI 18 DEC 8 '

T i m e : : 06 IS D a t e F K ; 16 DCC C M e t h o d P E S T C I P

:U.V. i:PESTCG94 IT

EAKGE ( « ! K . ) : 6.633 TO 25.866

C9c 1 mr I 1.1 ff

I :|«l-' v,h I I I ! * I 11 r'l

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3 8 0 5 0 0 8 8 1 6 8 5 : ^ ' ZE - : : 0 7 3 1 4 S : : i i : : - " r 4 "» 6 : 0 . 0 6 1 1 3 0 6 1 I " i r 5 3 2 6 C 1 4 4 3 0 7 8 ZcP. 2E 5 6 7 ? 0 0 2 5 5 3 6 T ' E E

6 2 5 0 0 0 6 ! 1 7 3 0 1 I 3 E F ! 7 7 2 0 6 0 0 2 0 6 4 8 4 ' E Ul

b e tn • C 8 1 7 9 0 5 8 5 . 2 5 1 9 2 2 7 E V > . ? i : 5 8 9 0 3 9 0 8 25 5 1 8 5 VV

O o to

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2 1 15 8 5 7 0 . 2 1 5 4 5 9 6 B S E B 22 1 6 3 7 6 0 . 0 9 0 1 9 2 9 2 l D v g 2 3 2 0 7 3 7 0 . 3 4 6 7 4 0 5 M C V V t O 24 2 1 C 9 4 0 . 5 5 7 1 1 9 3 2 1 8 > V B °° 25 2 5 5 0 0 0 . 4 » 6 1 0 6 1 0 1 7 2 BV

•^;: ,!-• -:• - f m . ' ' - . i< '-<0-- • •'

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22.82

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^^= '29.52

^ 3«.3«

RUM i ^ ? / 5 ^ UOKKFILE ID: Bl X yORKFILE H M E : N SAMPLE i 19

AREAS: RT

3.23 6.68 6.74 6.81 6.92 7.88 7.17 7.69 8.11 8.55 ; 9.96 11.35 11.63 11.89 14.88 15.68 15.54 16.68 17.27 17.73 18.64 28.58 22.82 23.68 25.36 25.97 27.78 29.98 29.52 29.76

AREA ' 42229 57833 63289 76587 31418 178328 82428 65792 53863

J4268ee 49778 33968 62348 55168 55888 24958 53561

238518 63844 33124

994568 64635 87155 26354 76449 84981 15631

172638 2283188 124668

38 38^W»:Wb97788 31.59 31.99 32.18 32.94

TOTAL AR£A= NUL FACTOR=

72339 61673 54516

452138

OEC/29/87

\

FYPE BB BV W W VP PV VB VB BV SH8 PB PP PV VB PV VB PV PB PB PB BB BB PB BP PV BV PB VB BV VB 68 PB PV VB PB

9660588 1. uOo^c'ôo

AR/HT 8.851 8.853 6.846 8.853 8.845 8.838 8.845 8.189 8.116 8.854 8 085 8 898 8 848 ft. 864 8 889 8.867 8.889 8.666 6.673 8.168 8.689 8.168 8.668 8.896 8.246 8.187 8.853 8.119 6.689 8.667 6.655 8 879 6.885 8.685 6.876

68=49=28

AREA:: 8.448 8.594 8.659 8.798 6.327 1.774 8.859 8.685 8.561

35.694 8.519 0.354 0.649 0.575 0.582 8.268 8.558 2.461 8.657 8.345 18.359 8.673 8.968 8.275 8.796 8.884 8.163 1.798

23.781 1.299 3.181 8.754 8.642 8.568 4.718

RAM DATA TRAMSNITTED FIL£: Ry4637==-27 CARD-PTS TRAHSMITTED ^ FILE= CP4877- -27

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LIBRARY SEARCH 12/16/87 7:39t0Q + 12:36 SAMPLE: 5MLS MM-#2 765616 CONDS.: ENHANCED <S 15B 2H GT)

DATA: PU7855 » 252 CALI: PU7S55 « 2

BASE M/Z: 97 RIC: J4223.

1164

SAMPLE

I . I . I u +J- • J y i - l I i iy — i|i f l H I—|p ->. i . • | ^ 1 " ' ' " I l - l • »• I • • • i r - t "

60 76 8y 2CC0 200 V3S

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RIC 12/16/87 8:28:00 SAMPLE: 5MLS MW4-C 765612 CONDS.: RANGE: G 1, 900 LABEL: N 6, 4.6 QUAH: A 0.. 1.0 J 0 B(«E: U 26.' 3

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AMOUNT=AREA • REF AMNT/(REF AREA * RESP FACT) RESP. r^c. P R O M LXBRARV ENTRV

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N.«.Me EROnOCHRLOROMETHANE (INT STD ) 1, 2-DICHLOROETHANE 04 (SURR. STD) CHLOROMETHANE PROMOMETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE (C) ACETONE CARBON DISULPHIDE 1,1-DICHLOROETHENE (B) 1, l-DICHLOROETHANE(E) TRANS -1, 2-OICHLOROETHENE (D) CHLOROFORM 1. 2-DICHLOROETHANE(H) TrlCHLOROFLUOROMETHAtvJE rncHLOROFLUOROMETHANE A,, ROLE I N •'=••-••>•; O N I T P I L E ', - - ;.IFLUCROEENZI;NL ; : -.'T STD ) /^-• : 'TAr, ;oNE fMEK) I , . . . .:.- iK ICHLOROETHAlvL 0 - F.C'N T E T R A C H L 0 F : I D = ? ' . - • • ) •. -.^v,. AC£"Â-E i .Sv i - iGDICHUt iRQr iETKANt f i . J 1, 2-DICHLGR0PR0PANE<> ) rPAr.lS 1, 3-DICHLOROPROFENE (AA) 1 r.IC HLOROETHENE ( K ) DIBROMOCHLOROMETHANE < O) 1 1, 2-TRICHR0ETHANE(Mi E.ENZENE(BEN) C L S - l / 3 -D ICHLOROPROFENE(2 ) 2 - C HLOROETHYLVINYLETHER(NN) EF-Or-lOFORM(P) Cf^ 'L0R0BENZENE-D5 ( I N T . STD) c -KEVANONE(NBK) -; - ' - r tTTHYL-S-PENTANONECMIBK) T£ iÂCHLOROETHENE(N) n -' OUE, 1, 1. 2, 2-TETRACHLORO-TOLUENE(TOL) C HLOROBENZENE(Q) ETHYLBENZENE(EB) ETYRENE META-XYLENE ORTHO/PARA-XYLENE META-DICHLOROBENZENE < MDCB) ORTHO-DICHLOROeENZENE (ODCB) PARA-DICHLOROBENZENE(PDCB) D8-T0LUENE(SURR. STD) BROMOFLUORBENZENE(SURR. STD)

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DUAL MASS SPECTRUM 12/16/87 8:28:00 + 22:36 SAMPLE: 5MLS MM4-C 765612 CONDS.: ENHANCED (S 15B 2N 0T)

DATA: PU7y5b #450 CALI: PU7856 «2

50

nt

7^/ct C/^-C^

ll . l l l . l - f — 1 1 r

1 ..tTT,

I.l i T — r

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LIBRARY SEARCH 12/16/87 8:28:00 + 22:30 SAMPLE: 5MLS MW4-C 765612 CONDS.: ENHANCED <S 15B 2H OT)

DATA: PU7856 11 450 CALI: PU735b » 2

II ff I T • • • I •

TOLUENE<TOL)

BASE M/Z: 91 RIC: 13663.

I ' « • • » I • - r • • • '^1 •• ' •

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I 91

1 39

IT 833

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F i l f >P3?95 3 5 . e

?8e08»H

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550088-

seeeeo-.

450088-

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Data File: >P3 795::B3 Name: 2UL nUAC 765612 BNA flisc: IOUL BN392«>1ML HP 2

Quan t Out put File "P379'?: :QT

ETLitJ'O

Id File: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15

Operator ID: Quant Time; Injected at :

GLENN 871216 2 2 : 5 1 871216 2 2 : 0 4

tn

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QUANT REPORT

Operator ID: GLENN Quant Rev: 6 Quant Time: 871216 22:51 Output File: '^P3795::QT Injected at: 871216 22:04 Data File: >P3795::B3 Dilution Factor: 1.00000 Name: 2UL nU)4C 765612 BNA Misc: IOUL BN392->inL HP*2 BTL4t30


Compound R.T. Scan* Area Cone Units

1) •l,4-DICHL0R0BEN2ENE-d4 3) 2-Fluoropheno1 (SS) 6) Pr,enol-d6 (SSJ 14) *NAPHTHALENE-d8 15,' N 11 robe*izene-d5 (SS) 26) *ACENAPHTHENE-dlO 30) 2-Fluorobiphenyl (SS) 41) 2,4,6-Tribromopheno1 (SS) 42) •PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 59) bis(2-Ethylhexyl)Phthalate 61) *PERYLENE-dl2

* Compound is ISTD

11 8,

11, 15, 13, 21. 19, 23. 25, 34. 30. 34. 38.

.85

.82

.57 ,62 .56 , 03 .10 ,62 .66 01 ,85 71 19

395 246 381 580 479 848 751 973 1073 1483 1328 1517 1688

12144 21587 22865 44954 23643 32017 43234 26964 71433 98520 90761

566683 103283

40 67, -45. AO. 37, 40. 50, 77. 40, 40. 44.

187. 40.

.00

.50 ,74 ,00 ,80 , GO .56 ,88 ,00 00 ,80 82 00

ug-^mL ug/mL ug/mL ug/mL ug^'mL ug -'mL ug/mL ug-'mL ug/mL ug/mL ug/mL ug/mL ug/mL

95 71 8« 61 6 0 9A

97 78 6A 53 37 87 77

in cn

o o to

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tIS d a t a f i l e h e a d e r f r o m >P3795

Sample: 2UL MUI4C 765612 SNA Operator: GLENN MS 12/16/87 22:04 Misc : IOUL BN392->inL HP#2 BTL#30 Sys. »: 2 MS model: 70 SU/HU rev.: lA ALS # : 0

Method file: EXTBNA Tuning file: MTe002 No. of extra records: 2 Source temp.: 0 Analyzer temp.: 280 Transfer line temp. : 0

Ch Ch Ch

iromatographic temperatures iroma t ogr aph ic times, m m . iromatoqraphic rate, deg/min

30. 4. 0 8.0

300. 7.3 0. 0

0. 0.0 0.0

0. 0. 0

0. 0. 0 0.0

>P7795 2UL MUI4C 765612 BNA IOUL BN392='1ML HPii2 35.01 500.0 CLP ADC TIC

Upslope: .20 Area Reject: 13009. M.3x Pe.sks: A Bunching Dnslope: 0.00 Results File IP3795 Sorted b;,,' Time/Area INT

Peak iff

1 2 3 4

R.T. m m .

7.53 29.18 29.27 29.49

first "scan

180 1243 1249 1259

max scan

183 1246 1250 1261

last

5 c a n

136 1249 1259 1266

peak he 1gh t

25775 80763 19440 5393

r a M area

619A0 231586 84532 23748

c o r r .

area

olA63 226117 762 05 18834

C o r '» ma-

100 33 8

^ .

13 .00 70 33

\ Of r ,:• r =. 1

1 6 . i:o<4

5«. 0-: 19.917 4.922


Standard

1 2 3

Concen trat ion Area

40 40 40 40 40 40.

0 0 0 0 0 0

130093. 130093, 144820, 186063. 264680. 295177.

Re tention T 1 me

11 15, 21 25. 3^. 38,

85 62 08 66 01 19

U n k n o w n UJ 1 n d o t :

3 13. 18, 23, 29. 36.

83 74 35 37 84 10

13.7A 18.75 23.37 29.84 36.10 45 . 05

Dilution Factor (DF) Amount Method (AM)


1.00 0. 00

Correction Factor (AM / AU) / (DF • FS)

Cone Int Std Unknown Concentration " * Area Unk • Correction Factor

Area Int Std

10:58 PM WED., 16 D E C , 1987

cn tn >

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RCrCRENCC STPNPflKD SPECTRUM File >F3585 bis(2-Efrhylh«xyDPhthal»t# Epk flb 39968 SUB

149

871627 28:51 Scam 1516 34 .65 min .

40088-

e-i

57 71 83

113 ,32

I I ' I ' l

40 •.ilX..,r.., .X:.. ..

-100

167 / 188

I .1. - 279 \

T -r r r r i » | i T i | t t r j ? T r- f T T T

80 126 160 I I I I I I ' I I I I I I I

206 240 280

SPMPLE SPECTRUM (BflCKCROUND SUBTRACTED)

file >P3??5 2'JL RU4C 7£5612 Et<Pi tCUl. BW3'52=> irtL Hpe2 Scsn 1517 Bp*.- fib 60438 SUB 34.71 m m

149

' 1-100

4t'O00-

e- -f4-f 4U 71 83

{ / 113'2'

•^-r«- > " r , . , , , .L, , ,..,1 167 / 180

I I I V ;", I ' . I I' 'f I f l " . I I I I I I I I I , I I I I I I I | - I I I y * ^ - *

Ic? 166 i0?i 2-4? 26"?

SAMPLE SPECTPUM (UNOLTERED)

Tile .SF3755 ^ 2UL MU4C 76Cil2 BNM 10UL BH:?i = >lML H9*2 tpk Pb 60504

14 9

4e'53e- 57 71 83

! ! •

1 ,..|[,.-,.lf,,^ , \ i7 . t< , . T 40

-T 88

Scan 1517 54 .71 m m .

-100

/ 180

1 L y 120 160 288

279

\

248 280

Data F i l e : > P 3 7 9 5 : : 8 3 Name: 2UL MUAC 765612 BNA M i s c : IOUL BN392->1ML HP4f2 Quant T i m e : 871216 2 2 : 5 1 I n j e c t e d a t : 871216 2 2 : 0 4

Quant O u t p u t F i l e : '^P3 7 9 5 : : Q T

BTL^t3 0 Quant ID F i l e : ! IDXPP: :ME

Las t C a l i b r a t i o n : 871216- 19 :15

Compound No: 59 Compound Name: bis(2-Ethy1hexy1)Phtha1 ate Scan Number: 1517 Retention Time: 3A.71 m m . Quant Ion: 149.0 Area: 566683 Concentration: 187.82 ug/mL q-va1ue: 87

in tn >

o o to

o CO

12 I r Z-* 28 3 i

F i l e >P3795 2UL MW4C 765612 BNR 10UL BN392->1ML HP»2 Bpk flb 13879 SUB ADD DVC

43

^ 41

8 I I I I I ' 40

61 56 S9 / 69

/ 83

Scan 183 7 . 5 3 B i n .

101

I I I I I I I I ' ' I I ' ' * M ' ' ' ' I ' ' I ' I ' ' ' ' I ' ' ' ' I ' ' I ' 1 ' ' ' ' I ' ' ' ' I ' ' ' ' I se 6Q 78 SC 90 IGC

F i l » >BICDB Bpk fib 9999

H y d r o p e r o x i d * , 1 , l ' d i i i * t h y l « t r ^y l ( 9C I )

50

Scan 1591 0 .88 m i n .

-J H

1 41 4 ,

e 1 • 11 < 11

43 ^ '

50

59 )

56 ,..:;:;a^,t^,^ ^

73 , ' • "

89 /

• ' • 1 1 • • • 1 • • • • t '

. ^

1S0

U n k n o w n ^f , 1

A r e a = 6 l ' 4 6 3 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 1 9 . 0 0

1 . H y d r o p e r o x i d e , 1 , 1 - d i m e t h y l e t h y l ( 9 C I ) 90 CAHIOO:


183 No. of ion ranqes searched: A 6

Prob. CAS • CON # ROOT K

15 75912 1591 "BIGDB 3A

DK #FLG TILT

31 1 0

S CON C_I P.

37 59 3 in cn >

o o to

o

F i l « > P 3 7 9 5 Bpk fib 7 9 3 1

55

2UL tHI4C 7 6 5 6 1 2 BNfl l eUL BN392->IML HP»2 SUB nOO DVC

67 /

82 / 9 6

Ji, .III,.. .,t. . |li S8

109 /

1 2 3 137 166

I I " I I

120

188 194 /

S c a n 1246 2 9 . 1 8 B i n .

2 5 0 t

I I I I I I I I I — I I I I I I I I I I I '

163 280 2 4 0


55

1,13-T»trad«cadi»n* (8CI9Cn Scan 8126 0.08 Mtn.

H 40

67 / III

S3 L 109 123 137 166 179 194 195

120 160 - 1 1 • •! I • • • I • • • 1 r-

206 240

F i l e >BICDB B i c y c l o C 9 . 2 , 8 } d o d e c a n e , 11 , 1 1 - d i m e t h v l - l 9 C n Bpk Ob 9 9 9 9

67 * / 96 ' ' 1 1 0 1-^8

lc»r \ 1 5 4 2 3 0 . 0 0 K i n .

I, !., I 1 i 0 ^

40

12? I t i 179 194 195 L^^JH^,,

K O 120 \ b V 2 0 0 , ; 4 i >

F i l e >HC-DB Bel. flb ?i^-?9

•J-Oc t a d e c y n e (9CI ) 0 . 0 0 c m .

ei 95 /

8-Y^ 48

I " I " I r'"i

10?

i 137 16fc 1-53 i0T

88 I I ' I I I " I I I • I

128 ' I I ' ' I 168

' I ' • ' I 1 ' I I I I'

200 2 4 0

Hrea =

Unknown # , 2

226117.0 Tentati 'v 'e C o n c e n t r a t i o n i: A9 . QO

1. 1,13-Tetradecadiene (8CI9CI) 2. Bicyclo[8.2.0]dodecane, 11,11-dimethy1 3. 9-Octadecyne (9CI) A. 1,12-Dodecanediol (8CI9CI) 5. 1 ,14-Tetradecanedio1 (8CI9CI) 6. 9-Octadecen-l-ol, (Z)- (8CI9CI) 7. Cyclododecanol (8CI9C1)

C9CI ) 19A C1AH26 194 C1AH26 250 CieH34 202 C12H2602 23 0 C1AH3 0O2 268 C18H360 l&A C12H240

Sample file: >P3795 Spectrum #: 1246 tn Search speed: 1 Tilting option: N No. of ion ranges searched: 48 *"

Prob.

O

CAS « CON ^ ROOT K DK »FLG T I L T 54 CON C_I R_II to

1. 86 21964498 8126 2. 79* 62338298 15420 3. 76» 35365594 5435 4. 73 5675514 5430

"BIGDB "BIGDB "BIGDB "BIGDB

117 90 85 108

11 53 71 29

1 2 1 1

0 0 0 0

88 64

52 88

6

13 47 22

59 43 33 32

7.

6'.

e: 66

o to CP

r

.nrccNSTRUCT scr.i^K TUMP Data Acauisi*-:cn

Time -.4 OP. d d Date;WED 2 3 DEC 6 7

Time :C :; "JZ Date UtD 2 3 Z t z g-

FILE: i:PESTC12e SAKCE <KIK.): 8.623 TO 3^.266 ene'TJIf

* - . M i l •

I.' •.! I

Q

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AREA;: RT

3.23 6.86 6.92 7.68 7.17 7.66 8.55

11.62 11.89 14.86 15.73 16.68 17.27 18.64 22.82 25.85 28.34 28.97 29.54 29.76 38.38^^*'' 31.59 31.99 32.94

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'25.54

AREA TYPE 72881 88 22995 16640 32339 182116 78689

2941466 see 47241 BV 31136 21778 56634 164598 27835

487258 55482 115196 188856 397188

4955388 329448

*''i65898 66473 26468 199488

PV VP PV VB PB

V8 P8 VB P8 BB PB PB PV BB VB PV VB BB PB BV PB

8 6.

AR/HT 6.678 8.674 6 645 6.656 .643 154

8.655 6.856 8.682 8.869 8.118 8.866 8.875 6.181 8.871 8.586 6.856 6.188 8.186 8.128 8.856 8.116 8.888 6.876

AREA:: 6.677 e.2ie 8.151 0 364 6.966 6.746

27.642 6.444 6.293 8.285 6.532 8.983 6.262 4.579 6.521 1.683 1.767 3.732

46.569 3.696 2.499 6.625 8.249 1.874

TOTAL AREA= l.e641E+87 mJL FACTOR 1.8888E-f86

RAU DATA TRAMSHITTED \ FILE= RI I4845 : : -27 CARD-PTS TRAHSmnED J FILE: CP4881 :=-27

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RIC DATA: PIJ7857 #1 SCANS 12/16/87 9:19:06 . CALI: PU7857 »2 SAMPLE: 5MLS EQUIP.FIELD BLANK 765614 CONDS.: RANGE: G 1, 909 LABEL: N 8, 4.8 QUAH: A 8. 1.8 J 8 BASE: U 28..

1 TO 988

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D^-^ : FU7857. TI 1H/16./S7 9:19.-e0 S.- MPi_E 5MLS EQUIP. FIELD BLANK 76S614

SuRMXTTED Bv: NO. SEA AiMAi_vsr: SS

Ar';OiJNT=AREA • REF AMNT/(REF AREA • RESP FACT) R E S P P-AC. FROH L I B R A R V ENTRV

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NAME BROMOCHRLOROMETHANE (INT. STD. ) 1, 2-DICHLOROETHANE D4 (SURR. STO> CHLOROMETHANE BFvOMOnETHANE VINYL CHLORIDE CHLOROETHANE METHYLENE CHLORIDE ACETONE CARBON DISULPHIDE 1,1-DICHLOROETHENE 1,i-DICHLOROETHANE(E) TRANS -1, 2-DICHLOROETHENE CHLGROFORM 1,2-DICHLOROETHANE(H) TRICHLOROFLUOROMETHANE c: CHLOROFLUOROMETHANF: ACROLEIN .'-C-'-V/LOMITRILE A -:- riF!_U0R0BErv'7L';L. • I'JT STD) :-2-' I ^'O'-'Ot-JE (MEK •• X. ..... :.-TniCHL0ROt:TH^:i-,f. ^ D CARBOr.' TETRACHLGPTDE ' -J ) vioo\_ A'.:ETATE BnC;MO!:'ICHL.GROMETHANE ' L ) 1, 2-DlCHLOROPROPANE '. X ) TRANS 1,3-DICHLOROPROFENE (AA) TRICHLOROETHENE(K) DIBROMOCHLOROMETHANE(0) 1, -TRICHROETHANE(M) BENZENE(BEN) CIS-1,3-DICHL0R0FR0PENE(Z) 2-CHLOROETHYLVINYLETHER(NN) BROMOFORMCP) CHL0R0BENZENE-D5 (INT STD) 2-HEXAN0NE(MBK) 4-METHYL-2-PENTAN0NE(MIBK) TETRAC HLOROETHENE < N) ETHAUE, 1, 1. 2, 2-TETRACHLORO-TCLOENE(TOL) C HLOROBENZENE(Q) ETHYLBENZENE(EE) ETYRENE META-XYLENE ORTHO/PARA-XYLENE META-DICHLOROBENZENE(MDCB) ORTHO-DICHLOROBENZENE (ODCB) PARA-DICHLOROBENZENE(PDCB) D8-TOLUENE(SURR. STD) BROMOFLUORBENZENE(SURR. STD)

M/r 128 65

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SCAN 182 235


123 -±ee-

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11. 45

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R E F RRT M C T H 1 1. 000 A*6B 1 1. 291 A*BB

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2330. 0760.

A M O U N T %TOT 50. 000 UC/L 0. 71 56. 056 UC/L 0. 80

0. 572 UC/L 0 01 C. 6 H UOifL 0 04

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22: 27 30: 15

34 34

0. 943 1 271

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154786 148903

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0. 187 UC/L 0. 00 0. 287 UC/L 0 00

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DUAL MASS SPECTRUM 12/16/87 9:19:88 * 13:80 SAMPLE: 5MLS EQUIP.FIELD BLANK 7G5614 CONOS.: ENHANCED <S 15B 2N 8T)

DATA: PU7857 11260 CALI: PU7S57 112

BASE M/Z: 97/ 57 RIC: 13071./ 79183.

ll 58

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DATA: PN7S57 t* 266 CALI: FIJ7357 tt 2

BASE M/Z: 97 RIC: 13071.

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DATA: PU7857 #23 CALI; P!j7:557 «2

BASE M/Z: 43/ 43 RIC: 830?.7./ 154111.

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DATA: PU7857 » 23 CALI: PU7857 tt 2

BASE M/Z: 43 RIC: 87679.

1000 1

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C13.H24.0

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CYCLOBUTANONE, 2- < 2.. 6-DIMETHYLHEPTYL) -

C12.H24 1-DECENE.. 2..4-DIMETHYL-

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Quant Output File: '^P3796::QT

BTL t Jl

Id File: !IDXPP::ME Title: PRIORITY POLLUTANTS Last Calibration: 871216 19:15


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Operator ID: GLENN Output File: '^P3796::QT Data File: >P3796::B3 Name: 2UL FIELD BLANK BNA Misc: IOUL BN392»>1ML HP#2 765614

QUANT REPORT

Quant Rev: 6 Quant Time Injected at

OilutI on Factor :

871216 23:47 871216 23:00

1.00000

BTL*31


Compound R.T. Scan* Area Cone Units

1) 3) 6)

14) 15) 26) 30) 41) 42) 52) 53) 59) 61)

•1,4-DICHL0R0BENZENE-d4 2-Fluorophenol (SS) Fhenol-d6 (.SS)

*NAPHTHALENE-d8 N 1 t roberTzene-d5 (SS)

*ACENAPHTHENE-dlO 2-Fluorobiphenyl (SS) 2,4,6-Tribromopheno1 (SS)

•PHENANTHRENE-dlO •CHRYSENE-dl2 Terphenyl-dl4 (SS) bis(2-Ethylhexyl)Phthalate •PERYLENE-dl2

Compound is ISTD

11 8. 11 15. 1.', 21, 19. 23. 25, 33. 30. 34. 38,

.85

.81

.56 ,61 .56 ,07 .10 ,62 .66 ,99 ,85 62 , 16

397 248 383 582 481 850 753 975 1075 1484 1330 1515 1689

14263 2b287 27230 50091 27162 31595 46128 27370 65578 70253 70641 54071 68632

40 o9. 4o , 40. 38, 40, 54, 80, 40, 40. 48. 25. 40.

.00

.99

.38 ,00 .97 .00 ,67 ,11 ,00 00 ,90 13 00

ug/mL ug/mL ug/mL ug/mL ug/mL ugz-mL ug/'mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL

92 67 88 59 31 96 98 82 65 53 37 38 77

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Sample: 2UL FIELD BLANK BNA Operator: GLENN MS Misc : IOUL BN392->1ML HPt2 765614 Sys. *: 2 MS model: 70 SW/HU rev.: IA ALS * : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records: 2 Source temp,: 0 Analyzer temp.: 280 Transfer line temp. : 0


30. 4.0 8.0

300. 7.3 0.0

0. 0.0 0.0

0. 0. 0 .5

0. 0.0 0. 0

>P3796 2UL FIELD BLANK BNA IOUL BN392->1ML HP^12 765614 35.01 500.0 CLP ADC TIC

Upslope: .20 Area Reject: 9035. Max Peaks: 3 Bunching: Dnslope: 0.00 Results File IP3796 Sorted by Time/Area INT

Peak if

1 2 3

R.T. min .

7.55 29.18 29.26

f irst ^can

183 1245 1251

max scan

186 1248 1252

last scan

188 1251 1261

peak he 1ght

22416 38977 9307

r ai*)

area

58847 119647 44586

cor r . area

53511 118113 39328

corr. S mas: .

49.54 10 0.00 33.30

54 of total

27.094 54.69-4 18.211


S t a n d a r d

1 2 3 4 5 6

L o n c e n t r a t i o n Area Re t en t ion

T i me

40, 40, 40. 40. 40. 40.

90348. 113529. 148416. 170076. 189446. 195225.

11, 15 21, 25, 33. 38.

35 61 07 65 99 16

Unk nouin Ul 1 ndow

3 . 7 8 1 3 . 7 3 1 8 . 3 4 2 3 . 3 6 2 9 . 8 2 3 6 . 0 8

13.7? 13.34 23. 36 29.82 36. 08 45. 04

Di lut ion Factor (DF) Amount Method (AM)

1.00 Fractional Solids <FS) 0.00 Amount Used (AU)

1.00 0.00

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Cone Int Std Unknown Concentration Area Unk • Correction Factor

Area Int Std in tn >

11:54 PM MED., 16 D E C , 1987 O O to

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RCrCRENCE STPNDPRD SPECTRUM ril» >P3589 Disii-EthylhtfxylJPhth*l*te Bpk flb 39968 SU£

149

671627 2 6 t S l Scan iSlb 34.6S ain.

40008-57

71 83

I ..L.f t r... L .1. ..[ y I ? I I I 1 1 I T ' ' '

167 180 279

\

-100

40 80 I ' ' I I

120 I I I I I I I I I I I I I I I I I I I I I I r I I I I I I °

lD0 200 240 280

SOMPLE SPECTPUM (BOCKGROUND SUBTRPCTEP.l riJe ,SP37?6 2UL FIELD BLRNK BNS 10UL SM392=>inL HP»2 76S6 Scan 1515 Bpk flb 25040 SUB 34.62 sin.

149

hi 00 20Ciee-

57

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Att 1 I ' I I

Re i"r'' -'l-l ^ • • * i I '' ." T'

ise

167 / Li . 207

/ I '*' I 1 ' • M ' ' M ' ' I I ' I ' I I

16? 2^0 24«

279

X Hr JS0

SAMPLE SPECTRUM (UNfiLTEREDl r JI e :• P3

Epk Ob 2

20086-

796 2jaL FIELD ELHNK BNO 10 5040

1

% ^ 71 83 ^ / / 1 3 132

JI. ...» ..A ( ... . .< , / .

UL EN392

49 /

167 /

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40 80 120 160 .... —

= >lt1L HP«2

219

200

7656

- - 1 - -240

Scan 34.62 1

279

\ 1.

• 1 ' • ' r 28

1515 B i n .

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0

Data File: >P3796::B3 Quant Output File: ^P3796::QT Name: 2UL FIELD BLANK BNA Misc: IOUL BN392-MML HP*2 765614 BTLii31 Quant Time: 871216 23:47 Quant ID File: !IDXPP::ME Injected at: 871216 23:00 Last Calibration: 871216 19:15

Compound No: 59 Compound Name: bis(2-Ethylhexyl)Phtha1 ate Scan Number: 1515 Retention Time: 34.62 min. Quant Ion: 149.0 Area: 54071 Concentration: 25.13 ug/mL q-value: 88

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FJ1» >P3796 2UL FIELD BLANK BNO leUL BH392»>irtL HP«2 765614 Sc*n 186 Bpk Rb 11812 SOB ADD BVC 7.55 Min.

43

41 50 56 /

59 83 101

^ I I I I I I I I » I ' I I I I I I I I I M I I I I t I I I I I I I I I I I I I > , I I I I I I I I I I I I I I I r I I I I «A rf% £ r t T f . f yn r*f\ • ^ A T V 9 0 OV I V OV 7V 1 VV

A r e a = Unknown 4^, 1 5 8 5 1 1 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s 2 6 . 0 0

Sample f i l e : >P3796 Spec t r um #: 186

No data base entries were retrieved,

Ul tn

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F i l e > P 3 7 9 6 2UL FIELD BLANK BNO 10UL BN392->1ML HP»2 7 6 5 6 1 4 Sc»n 1248 Bpk Ob 3 8 5 0 SUB ODD DVC 2 9 . 1 8 a i n .

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5 5

1 , 1 3 - T « t r * d e c * d i e n « ( 8 C 1 9 C I )

j -Y - i . 4iD

67 /

82 / 96

/ ' ? ' 123 137 166 179 194 195

*> - ,—I " ' I I • ' • • - I I I — I »• I I I

80 120 160 200

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8126 • i n .

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Fl l e >BIGDB Epk Ob 9 9 9 9

5 5

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69 .32

/ 109 123 124

80 I < 1 ' I ~ ' ' I '

120

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160 I ' » ' I I

2 6 0 240

l - \rea

3 . 4 , 5 , 6 , 7 ,

U n k n o w n # , 2 113113.0 Tentatis'e Concentration 1 s

1,13-Tetradecadiene (8CI9CI) 1,12-Dodecanediol <.8CI9CI) 1,14-Tetradecanediol (8CI9CI) 5-Octadecyne (9CI) 9-Octadecen-l-ol, (Z)- (8CI9CI) BicycI0C8.2.01 dodecane, 11,11-d1 methyl 1,12-Tridecadiene (8C19CI)

23.0 0

- (9C1)

194 C14H26 2 02 C12H2'',02 230 C14H30O2 250 C18H34 2o8 C1BH360 194 C14H26 180 C13H24

Sample file: >P3796 Spectrum «: 1248 ^ Search speed: 1 Tilting option: N No. of ion ranges searched: 48 >

Prob CAS * CON • ROOT K DK *FLG TILT S CON C_I R_IU i

1 2 3

89 83 76

21964498 5675514 19812647

8126 5430 5381

"BIGDB "BIGDB "BIGDB

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11 23 40

0 0 0

87 88 80

6 14 28

62 51 37

80 71 74

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mh */S S A 7/, t9> Me^J Sl lCUoBnA

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M^S-A 5 'A 7/;B0iS

M^lf^ BNA 7/fÛ'

tîti >c Sf A li>n',H

7i^l^ /t iirx K SÂ 70bZ{C-

S / ^ / ^ 2^1 Brt

i iLiL

7/;^ l e t gii

T b T M ^ / ^ It

^

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7(}'^(JOH- fin A ft 5? l4

'W M ^ H ^ SI

Vici 7B ^ A / -r SH • ^ 10 ^, H Sf

g^' ftMoJ Slc<l<: lU 5Z

m_ My^lA

m ^w//^ '76f^'i 76^^71

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m Mt^lC r ^ ^ r ^ J

HJHU MS 7( '5^7i / h s

«'*/ fifh/IC I^Ô 1 0 5 ^ 7 1 mS/>

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igis

V m f7tf/7 / ^ / ^ k 7(;5^7$

n?hft /k7J 7^^^ô

i f ^^^ "^

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7LS7B^ 7/77110

TOTQL ION CHROMOTOCRPH FJl* >P3?97 aS.e-See.e amu, SIH. HV4ft ?^§6li JNA idUL *N3?2->inL H^«J

seeeee-

D a t a F l l e : >P379 .7 : : B3 Name: 2UL f1Ul4hi 7 6 5 6 1 6 BNH M i s c : IOUL B N 7 9 2 » ^ i n L H P f 2

Q u a n t O u t p u t F i l e : ' •P?? ' ^? ; ::JT

BTL:r

I d F 1 1 e : ! I D X P P : :ME T i t l e : P R I O R I T Y POLLUTAtJTS L a s t C a l i b r a t i o n : 8 7 1 2 1 o 1 9 : 1 5

O p e r a t o r I D : GLENN O u a n t T i m e : 8 7 1 2 1 7 0 0 : 4 ? I n j e c t e d a t : 8 7 1 2 1 6 2 3 : 5 7

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QUANT REPORT

Operator ID: GLENN Output File: '*'P3797::QT Data File: >P3797::B3 Name: 2UL MU)4A 765616 BNA Misc: IOUL BN392->1ML HP#2

Quant Rev: 6 Quant Tlme Injected at

Dilut ion Factor;

S71217 00:A3

6: 1216 23:57 1.00000

BTLif32


Compound R.T. Scan* f*rea Cone Un 1 ts

1) •l,4-DICHL0R0BEN2ENE-d4 3) 2-Fluoropheno1 (SS) 6) Phenol-d6 (SS) 14) •NAPHTHALENE-d8 15) Nltroben2ene-d5 (SS) 26) •ACENAPHTHENE-dlO 30) 2-Fluorobiphenyl (SS) 41) 2,4,6-Tribromophenol (SS) 42) •PHENANTHRENE-dlO 52) •CHRYSENE-dl2 53) Terphenyl-dl4 (SS) 59) bis(2-Ethylhexyl)Phthalate 61) •PERYLENE-dl2

11 9, 11, 15. 13, 21. 19, 23. 25, 33. 30. 34, 38.

.84

.81

.56 ,61 .57 ,07 .11 ,62 .65 ,98 .85 ,62 .16

397 248 383 582 4S2 850 754 975 1075 1484 1330 1515 1689

15368 28473 30457 55953 36576 36286 60423 31559 73968 83485 95016 39613 80269

40, 70. 48, 40. Ar. ,

40. 62, 80. 40, 40. 55. 15. 40.

.00

.36

. 15 ,00 ,98 ,00 ,35 ,43 ,00 00 ,34 49 ,00

ug.-'mL ug'-mL ug 'mL ug^'mL ug^'mL ug'-'mL ug/-mL ug/mL ug/mL ug/mL ug/mL ug.''mL ug/mL

92 69 90 56 /• 4.

95 98 81 64 52 37 S4 79

Compound is ISTD

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Sample: 2UL MLJ4A 765616 BNA Operator: GLENN MS 12/16/87 23:5: Misc : IOUL BN392->1ML HP#2 BTL#32 Sys. *: 2 MS model: 70 SU/HLJ rev.: IA ALS • : 0

Method file: EXTBNA Tuning file: MT8002 No. of extra records: 2 Source temp.: 0 Analyzer temp.: 280 Transfer line temp. : 0

Chromatographic temperatures Chromatographic times, m m . Chromatographic rate, deg/min

30. 4.0 8.0

300. 7.3 0.0

0. 0.0 0.0

0. 0.0 .5

0. 0.0 0.0

>P3797 2UL MUI4A 765616 BNA IOUL BN392=>1ML HP4t2 35.01 500.0 CLP ADC TIC

Upslope: .20 Area Reject: 9948. Max Peaks: 3 Bunching: Dnslope: 0.00 Results File IP3797 Sorted by Time/Area INT

Peak tt

1 2 3

R.T. m m .

7.55 29.18 29.48

first " scan

18? 1245 1261

max scan

186 1248 1263

last scan

188 1251 1273

peak height

27727 64082 2952

raw a r e a

67963 187247 15249

corr. area

67773 184992 12301

cor r . % ma.\ .

36.64 100.00 6.65

% of t o r a 1

25.568 6^.791 4.641


Standard

1 o

5 6

Concent rat ion Area

40.0 40.0 40.0 40.0 40.0 40.0

99483. 126304. 169637. 193988. 226595. 225970.

Retention T 1 me

11, 15 21, 25, 33, 38,

34 61 07 65 98 16

Unk noum Ul 1 ndow

3, 13 18, 23, 29, 36,

78 -

36 82 07

13.- 3 18.34 23.36 29.82 36. 07 45. 03

Dl lution Factor (DF) Amount Method (AM)

1.00 Fractional Solids iFS) 0.0 0 Amount Used (AU)

i . 00 U . 00

Correction Factor - ••••••«• . ( ^ / AU) / (DF • FS)

Cone Int Std Unknown Concentration « * Area Unk • Correction Factor

Area Int Std

12:51 AM THU., 17 D E C , 1987

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REFERENCE STftNPWRD SPECTRUW F i i « >P3589 b i s ( i - £ t h y l h » x y r ) f h t h a l » t » Bpk Pb 39968 SUB

149

87ia27 26851 3c*n iSib 34.65 min.

4eeee-1 57

71 83

T 48

li. .. H. ... J.J.. •» I . I . I I t I [ I I T I I r r I T I 1

8 88 1

1»3 132

128

167 / 188

i A _ . y >79

\

lee

168 288 248 I r ' I > 1 ^ *

288

SOMPLE SPECTRUM tBOCKCROUNB SUBTRACTED) File >P3797 2UL MU40 765616 BNP leUL BN392=>1HL HP«2 Bpk Rb 17928

i . .

SUB 149 /

Sc*n 1515 34.62 kin.

loeoe- 71 83

•11.. ,..il i.../ 11-3 132

167 279

\

40 80 126 166 I 1 ' I 1 ' ' ' I

28e

188

246 =•$8

SAMPLE SPECTRUM (UNOLTERED) File >P3797 2UL l1U4fi 76Ss,16 BNft 10L'L EN3'?2«>1ML HF»: Bpk Ab 17921?

149

Ccan ISIE 34 .62 m m .

18888-:

8-:

71 83 Jjj 1 / / ^7 ^7 [ 287 48 88 128 169 288 248

167 / 279

188

288

Data File: >P3797::B3 Name: 2UL MU4A 765616 BNA Misc: IOUL BN392=>1ML HP^2 Quant Time: 871217 00:43 Injected at: 871216 23:57

Quant Output File:

BTL#32 Quant ID File: !IDXPP::ME


Compound No: 59 Compound Name: bis(2-EthyIhexy1)Phthalate Scan Number: 1515 Retention Time: 34.62 min. Quant Ion: 149.0 Area: 59613 Concentration: 15.49 ug/mL q-value: 84

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12 16 24 2K 32 4 0

File >P3797 2UL MU4fi 765616 BNP IflUL BN392->1ML HP«2 Bpk Rb 14584 SUB RDD DVC

43

41 56 59 / 83

Scan 186 7 .55 nin.

101 :

l l | l i l l | l l i l | l l l l | l l l l | . l l l | l l l l l l l l I [ l l l l [ I I I T | l l l l | J I ' l | l l l l | l

48 58 68 78 88 98 188 •e

F i l e >BICDB Bpk Pb 9999

H y d r o p e r o x i d e , 1 , 1 - d i » e t h y l e t h y l ( 9C I )

59

Scan 1591 8 .88 m i n .

8-

41

^^rJ^

43 .^

> ' • ! • •

58

• ' i ' •

56

^,.^01

/

73 1 , 1 1 r'T , •

89 /

, . te

40 58 78 88 58 160

U n k n o w n ^^, 1 A r e a = 6 7 7 7 3 . 0 0 T e n t a t i v e C o n c e n t r a t i o n i s

1 . H y d r o p e r o x i d e , 1 , 1 - d i m e t h y l e t h y I (9CI )

27. 0 0

9 0 C4H10O2



P r o b .

15

CAS •

75912

CON #

1591

ROOT

"BIGDB

K

34

DK

31

•FLG T ILT

1 0

\

32

CON

57

C_I

3

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File >P3797 Bpk Pb 6581

55

2UL MU4fl 765616 BNP IBUL BH392->1ML HP»2 SUB ROD DVC

Scan 1248 29.18 nin.

0-

"•

,u 67

^-JlU

82 /

\ -T-r-^

96

1 fl 1

189 /

T + T -

124

" • ' • • ' '

137 166

1 ' ' ' 1 1 1

lee 194

. • ^ • < 1 I

222 258

-

K5

File >BIi:DB Bpk Pb 9999

55

I ,13-Tetr»dec»diene (801901) Scan 8126 8.88 nin.

1 J '' ' aijj. . 1 . A . ,1 48 S0

96 / 189 ll /

123 13? 166

128 ' I ' 168

179 194 195

288 • ' I •

248

File >BICDB BicydoC8.2.B^dodecane, 11 ,1 l-diaethyl - (9CI) Bok Pb 9999

41 67 S2 5^

e-V4-48

i li ll li T , .-"'I- .-•i"'. I"

/ l i e 138

123 f - 165 179 194 195

88 120 168 • y

280

Scan 15420 8.88 nin.

4-0 248

F i l e >B1SDB Bpk Pb 9 9 9 9

1 , l 2 - D o d e . : a n e d i o l ( 8 C I 9 C I )

gift . p, A 48

82 96

J l ' . , I'llii , ^1. 88

189 / 123 138 154 172 283

128 • I I I I i I I

168 ' I ' I I I I 288

S c a n 543«i 0 . 0 8 n i i n .

248

Area = Unk nown ^ , 2 1 8 4 9 9 2 . 0 T e n t a t i v e C o n c e n t r a t i o n i s 3 8 . 0 0

1. 1,13-Tetradecadiene (8CI9CI) 2. BicycloC8.2.Oldodecane, 11,11-dimethy1- (9CI) 3. 1,12-Dodecanediol (8CI9CI) 4. 1,14-Tetradecanediol (8CI9CI) 5. 1-Hexadecyne (8C19CI) 6. 9-Octadecyne (9CI) 7. Cyclododecanol (eCI9CI)

194 C14H26 194 C14H26 202 C12H26U2 230 Cl4H3;"iQ2 222 C16H3 0 250 C18H34 184 C12H240

Sample file: >P3797 Spectrum #: 1248 Search speed: 1 Tilting option: N No, of ion ranges searched

cn tn >

1 2 3

Prob

86 83» 74 71

CAS # CON •

21964498 62338298 5675514 19812647

8126 15420 5430 5381

ROOT

"BIGDB "BIGDB "BIGDB "BIGDB

K

117 97 108 103

DK *FLG TILT S CON C_I R_

11 46 29 40

1 2 2 1

0 0 0 0

86 62 89 79

6 14 14 28

59 51 39 29

O O IO

o u CD O

."..TCC.'.'STnUC"' SCHET'-.' r v ] ^ ? n » t .i A c a u i 5 i t i o r.

T : n i e : 3 : 4 9 02 D c t e : F R ! 18 DEC 6

T i m e 1 0 . 5 3 S6 D . i t e . F R ! 18 DEC 8 ' M e t h o d ; PESTCL.P

F I L E : l:PESTC992 RMGl ( f l lK. ) : 8.833 TO 35.658

3.eire"i M

* 11 r

~^' J : 7 • - ^ • ^

- - ^•:''t« I

i.e 2R niHUTES

3R

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O U 03

- • i ^ .

Channel, •.*.: REINT Tiae-13:48:09 Date FKI 18 DEC 87

Ssrap1• naa* D a t a f i l e . Method name

3 PESTC092 FE3TCLP

.t. c t h 0 r : ns t rument C •? I 'J!t.n No t es

TRACOH 5 50 ! •'t 3F-22rC/l 95'4 £F-24Qi CN :-0 C ' 110

5L'-ri.CC-.='0?iT

Rvn t i me A c r t : m e

T'cwr- =eni

.: _• V V !t 1 Tl

T- '. t a. A f

De1 a y t i me Acq. d^ t e . Er.d FV Actual FV

0 0 C min Fnl :f DEC 87 :5 C C C sec i <; 0 0

AF.E.i. PEF. CE.'JT .=IEF.

ra : n ' R z 3 ? e s i. n a me Are* *h C/ Area Peak Ht

; •" n

0 : 7C

c C;.; 0 .-1 f

3:267 i 2 C C 6 t 2??8 : :32

9Se

.•> C <- r

r r

2 2 9? 2 ?76 Z 0 7 9 4 C 6 : <; <£9i

r. ; c

2 6 1

1040 4<C4 2892 2020 562 49

VE

EE

f : Si / ;.; 9 7 100

13 <; 1 7 1

082

^fl7 0

0 . 0o3

14 2 9

6163

< ^ \ i::4 c-y:p

19 ces 2 1 553 26 179

2 7 zi^nc/p;of lUtr. SU.)

0.571 0 077 2 24 1

25 483

10079 13.5 0

3933 1 2731!5

TOTAL 100 000 176392?

4 i 6?

1 1 311

: 9 2 2 1

5 7 9 2 6C4

VC E3 EC BB

EE EB VV

vs

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• i . - v : - i b i i . : ^ ' I... - fi-. '7-77-^7^

->

Pg^^r \u<r .S t< t .> 23.43

38.37

,-Z?/Op!

5 7 0 V RUH t ^ V 7 *^ BORKFILE ID- 81 tlORtCFILE NMC: SW«.E f

AREA:IC RT

3.21 4.66 5.46 6.59 6.73 6.81 6.91 7.68 7.17 7.27 7.35 7.49 7.59 8.54

11.68 16.68 22.82 28.34 28.98 29.49 29.76

. 38.37(1

16

. DEC/29/87 ^

AREA TYPE 293256

19756 46756 97237

186796 262486

56927 587538 385986

65846 78749 435P6 85983

1.18«3F*«7 38888 31163 22582 21183 29729

383376 166136

"."#49966

BP B6 88 BV W W VV W W VV W W VB

SHB PB PB PB PB B8 PB BB PB

TOTAL AREA* 1.5824E4«7 NUL FACTORS l.MeSE^M

AR/HT 6.673 9.667 8.637 6.646 8 037 e.048 e.854 8 642 8 848 9.865 8.858 9.695 6 696 6.651 6.865 6.698 9.678 8.665 9.879 9.664 9.654 8.856

01 37 92

AREA: : 1.952 6.132 9.311 8.647 1.293 1.348 0.339 3.911 £.037 0.438 0.524 0.298 9.572

79.693 8.254 8.267 8.156 8.141 8.198 2.552 9.796 2.995

RMI DATA TRAHSNITTEO FILE Ry4619: -27 CARD-PTS TRAHSMITTED ' ^

i

7/r'<^/^

•ILE= CP4619 - 2 7

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