COLUMBIA ANALYTICAL SERVICES - ANALYTICAL TEST

Columbia Analytical Services inc. A FULL SERVICE ENVIRONMENTAL LABORATORY

December 4, 2007

Ms . Nandra Weeks Geosyntec 2258 Riverside Ave. Jacksonville, Florida 32204

PROJECT:CARUS CHEMICAL FR1347 Submission #:R2740633

Dear Ms. Weeks

Enclosed are the analytical results of the analyses data has been reviewed prior to report submission. any questions please contact me at (585) 288-5380.

Thank you for letting us provide this service.

Sincerely,

COLUMBIA ANALYTICAL SERVICES

Deb Patton Project Chemist

Enc.

requested. All Should you have

1 Mustard St.• Suite 250 • Rochester, NY 14609 • Tele:(585)288·5380 • Fax:(585)288·8475

Columbia Analytical Services inc.

1 Mustard ST. suite 250 Rochester, NY 14609 (585) 288-5380

THIS IS AN ANALYTICAL TEST REPORT FOR:

Client Geosyntec

Project Reference: CARUS CHEMICAL FR1347

Lab Submission #

Project Manager

Reported

R2740633

Deborah Patton

12/04/07

Report Contains a total of ~ pages

The results reported herein relate only to the samples received by

the laboratory. This report may not be reproduced except in full,

without the approval of Columbia Analytical Services.

This package has been reviewed by Columbia Analytical Services• QA

Department/Lab~ratory Dir~?"r -Jf..~omply with NELAC standards prior

to report submittal. /li,/d,,,,,!_f':~

SDG NARRATIVE

CASE NARRATIVE COMPANY: Geosyntec-11 Carus Chemicals FR1347 Submission #: R27 40633

Geosyntec samples were collected on 10/29/07 and 10/30/07 and received at CAS on 10/31/07 and 11/01/07 with cooler temperatures of 2° and 3°C.

INORGANICS

Five soil samples were analyzed for a client specified list of AVS/SEM metals and Wet Chemistry parameters. Please see attached data pages for method numbers.

Site specific QC was not requested but was run on sample OU1-SS-LVR205-071030. The Spike Sample Recoveries for Cadmium, Lead and Zinc could not be accurately determined since the amount of spike added was less then four times the amount present in the samples and was therefore diluted out. All RPD's were within limits.

All results between the CRDL and IDL have been "B" flagged as estimated.

All CRDL recoveries were within QC limits.

The Blanks associated with these samples were free of contamination.

No other analytical or QC problems were encountered.

1 certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the details conditioned above. Release of the data contained in this .hard copy data. package has M:'.Lth~boratory Manager or his designee, as verified by the following signature. I? ~

CJA<:> A'=>t"'/vLt"' t:SA I GHING f-OKM I LOGIN SHEET

SDG#: 1050477 BATCH COMPLETE: _yes DA TE REVISED: SUBMISSIOfl R2740633 DISKETTE REQUESTED: Y _X_ N DATE DUE: 11/26/07 --CLIENT: Geosyntec-IL DA TE: 11 /02/07 PROTOCOL: SW846 CLIENT REP: Deb Patton CUSTODY SEAL: PRESENT/ABSENT: SHIPPING No.: PROJECT: CARUS CHEMICAL FR1347 CHAIN OF CUSTODY: PRESENT/ABSENT: CASJOB# CLIENT/EPA ID MATRIX REQUESTED PARAMETERS DATE DATE pH % REMARKS

SAMPLED RECEIVE[ (SOLIDS) SOLIDS AMPLE CONDITIO~ 1050477 OU1-SS-LVR203-071030-AVS SOIL AVS/SEM Metals 10/30/2007 10/31/07 1050478 OU1-SS-LVR206-071030-AVS SOIL AVS/SEM Metals 10/30/2007 10/31/07 1050479 OU1-SS-LVR201-071029-AVS SOIL AVS/SEM Metals 10/29/2007 10/31/07 1050480 OU1-SS-L VR406-071029-AVS SOIL AVS/SEM Metals 10/29/2007 10/31/07 1050816 OU1-SS-l VR205-071030-AVS SOIL AVS/SEM Metals 10/30/2007 11/1/07

BATCHIN1 11 /2/2007

+ ~·

INORGANIC QUALIFIERS

C (Concentration) qualifier -B - if the reported value was obtained from a reading that was less than the Contract Required

Detection Limit (CRDL) but was greater than or equal to the Instrument Detection Limit (IDL). This qualifier may also be used to indicate that there was contamination above the reporting limit in the associated blank. See Narrative for details.

U - if the analyte was analyzed for, but not detected

Q qualifier - Specified entries and their meanings are as follows: D - Spike was diluted out E - The reported value is estimated because the serial dilution did not meet criteria. J - Estimated Value M - Duplicate injection precision not met. N - Spiked sample recovery not within control limits. S - The reported value was determined by the Method of Standard Additions (MSA). W - Post-digestion spike for Furnace AA Analysis is out of control limits (85-115), while sample

absorbance is less than 50% of spike absorbance. * - Duplicate analysis not within control limits. + - Correlation coefficient for the MSA is less than 0.995.

M (Method) qualifier: - "P" for ICP - "A" for Flame AA - "F" for Furnace AA - "PM" for ICP when Microwave Digestion is used - "AM" for Flame AA when Microwave Digestion is used - "FM" for Furnace M when Microwave Digestion is used - "CV" for Manual Cold Vapor AA - "AV" for Automated Cold Vapor AA - "AF" for Automated Cold Vapor Atomic Fluorescence Spectrometry - "CA" for Midi-Distillation Spectrophotometric - "AS" for Semi-Automated Spectrophotometric - "C" for Manual Spectrophotometric - "T" for Titrimetric - " " where no data has been entered - "NR" if the analyte is not required to be analyzed.

CAS/Rochester Lab ID # for State Certifications

NELAP Accredited Delaware Accredited Connecticut ID # PH0556 Florida ID# E87674 Illinois ID #20004 7 Maine ID #NY0032 Massachusetts ID# M-NY032 Navy Facilities Engineering Service Center Approved

H:IFORMS\QUALIF _I.DOC

Nebraska Accredited New Jersey ID # NY004 New York ID# 10145 New Hampshire ID# 294100 AIB Pennsylvania ID # 68-786 Rhode Island ID# 158 West Virginia ID# 292

CHAINS OF CUSTODY

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Cooler received on 10131I01 by:~/ COURIER: CAS UPS

.~U~ @ VELOCITY CLIENT

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PC Secondary Review: ·

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YES NO Sample J.D. Reagent Vol. Added Final pH '

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Chain of Custody

Submission: R2740633 Client: Geosvntec-IL

Lab ID: 1050477 Matrix SOIL

Received into GAS-Rochester 10/31/07

Container: 10504771

[)ate of Custody User Dept Storage Location Purpose Empty

10131107 16:35 rjones Sample Management Cooler 2 Storage 0 11106107 9:29 tchrist wet Chemistry Cooler 2 Analysis 0 1110610715:18 tchrist Wet Chemistry Cooler 2 Storage 0


Received into GAS-Rochester Custody: 10/31/07

Container: 10504781

£)ate of Custody User Dept Storage Location Purpose Empty ·---------

1013110716:35 rjones Sample Management Cooler 2 Storage 0 11106107 9:29 tchrist Wet Chemistry Cooler 2 Analysis 0 1110610715:18 tchrist Wet Chemistry Cooler 2 Storage 0



Container: 10504791

f)ate of Custody User Dept Storage Location Purpose Empty ---·

1013110716:35 rjones Sample Management Cooler 2 Storage 0 11106107 9:29 tchrist Wet Chemistry Cooler 2 Analysis 0

---------------------------- ..... ------------------------------------.---------------------~-------.------------------------------------------------------~----1110610715:18 tchrist Wet Chemistry Cooler 2 Storage 0



Container: 10504801

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1013110716:35 rjones Sample Management ------------c:;;;;1.;r2--------------------Siora9e ______________ Ef-

11106107 9:29 tchrist Wet Chemistry Cooler 2 Analysis 0 1110610715:18 tchrist Wet Chemistry Cooler 2 Storage 0

Tuesday, December 04_, 2007 Page 1 of2

Chain of Custody

Submission: R2740633 Client: Geosvntec-IL


Received into CAS-Rochester Custody: 11/1/07

Container: 10508161

[)ate of Custody User Dept Storage Location Purpose Empty

11101107 14:38 rjones Sample Management Cooler 2 Storage 0 11106107 9:29 tchrist Wet Chemistry Cooler 2 Analysis 0 1110610715:18 tchrist Wet Chemistry

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Tuesday. Deceniber 04, 2007 Page 2 of2

METALS DATA

Columbia Analytical Services

METALS COVER PAGE- INORGANIC ANALYSES DATA PACKAGE

Contract: R2740633 SDG No.: 1050477

Lab Code: Case No.: SAS No.:

SOW No.: SW84.6 CLP-M Client: Geosyntec

Sample No.

OU1-SS-LVR203-071030-A' 0Ul-SS-LVR207-071030-A' OU1-SS-LVR201-071029-A' ou1-ss-LVR406-071029-A' OU1-SS-LVR205-071030-A' OU1-SS-LVR205-071030-A' ou1-ss-LVR205-071030-A' MBLK 11/6

Were ICP interelement corrections applied?

Were ICP background corrections applied? If yes-were raw data generated before application of background corrections?

Comments: See Attached Case Narrative

Lab Sample ID.

1050477 1050478 1050479 1050480 1050816 10508160 1050816S 1058797

Yes/No YES

Yes/No YES

Yes/No NO

I certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hardcopy data package and in the computer-readable data submitted on diskette has been authorized by the Laboratory Manager or the Manager's designee, as verified by the following signature.

ignature:.____,_,/'-"=a/'-=\-/ --t-! C:~· c~~-· - Name:

ate: 1 ~1.r/o7 Title:

COVER PAGE - IN

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Geosyntec Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : OUI-SS-LVR203-071030-AVS

Date Sampled : 10/30/07 10:00 Order #: 1050477 Date Received: 10/31/07 Submission #: R2740633

ANALYTE METHOD PQL RESULT

CADMIUM 60108 0.00517 0.0178

COPPER 60108 0.0366 1.16

LEAD 60108 0.0281 0.233

NICKEL 60108 0.0792 0.143

ZINC 60108 0.711 40.8

Reported: 12/04/07

Sample Matrix: SOIL/SEDIMENT

DRY WEIGHT DATE UNITS ANALYZED DILUTION

umoles/g 11/28/07 10.0 umoles/g 11/28/07 10.0 umoles/g 11/28/07 10.0 umoles/g 11/28/07 10.0 umoles/g 11/28/07 200.0

< Acid Volatile Sulfide I Simultaneously Extracted Metals >


Geo syn tee Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : OU1-SS-LVR207-071030-AVS

Date Sampled : 10/30/07 15:00 Order#: 1050478 Date Received: 10/31/07 Submission #: R2740633


CADMIUM 6010B 0.000543 0.00382 COPPER 6010B 0.00381 0.0283 LEAD 6010B 0.00292 0.0150 NICKEL 6010B 0.00826 0.0341 ZINC 6010B 0.00370 0.355

Reported: 12/04/07






Geosyntec Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : OU1-SS-LVR201-071029-AVS



CADMIUM 6010B 0.00637 0.0703

COPPER 6010B 0.0451 5.95

LEAD 6010B 0.0346 0.178 NICKEL 6010B 0.0976 0.930

ZINC 6010B 0.438 35.6

Reported: 12/04/07






Geosyntec Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : 0Ul-SS-LVR406-071029-AVS



CADMIUM 60108 0.00782 0.0445

COPPER 60108 0.0553 1.68

LEAD 60108 0.0424 0.241

NICKEL 60108 0.120 0.387

ZINC 60108 0.538 19.1

Reported: 12/04/07






Geosyntec Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : OU1-SS-LVR205-071030-AVS



CADMIUM 6010B 0.00672 0.118

COPPER 6010B 0.0476 0.134

LEAD 6010B 0.0365 0.482

NICKEL 6010B 0.103 0.201

ZINC 6010B 0.462 36.2

Reported: 12/04/07






Geosyntec Project Reference: CARUS CHEMICAL FR1347 Client Sample ID : METHOD BLANK

Date Sampled : 11/06/07 Date Received:

Order #: 1058797 Submission #: R2740633


CADMIUM 6010B 0.000445 0. 000445 u

COPPER 6010B 0.00315 0.00315 u

LEAD 6010B 0.00241 0. 00241 u

NICKEL 6010B 0.00681 0.00681 u

ZINC 6010B 0.00306 0. 00306 u

Reported: 12/04/07


DATE UNITS ANALYZED DILUTION



7olumbia Analytical Services

METALS -2A-

INITIAL AND CONTINUING CALIBRATION VERIFICATION

,,ab Code: Case No.: SAS No.: SDG NO.: 1050477

:nitial Calibration Source: PE PURE ~~~~~~~~~~~~

~ontinuing Calibration Source: PE PURE

Concentration Units: ug/L

Initial Calibration Continuing Calibration

Analyte True Found %R(l) True Found %R(l) Found %R(l) M

!cadmium 500. ol 509. 30 llOl. 9 I 500.0 I 506. 511 101. 3 I 507.421101.5 Ip I )copper 1250.ol 1261. n 1100. 9 I 1250.0 I 1247.131 99.8 I 1255.051100. 4 IP I !Lead 500.ol 500. 32 I 100. l I 500.0 I 494. 491 98. 9 I 479.53f 95.9 f PI !Nickel 2000.ol 2019.291104.o I 2000.0 I 2063 .171 103. 2 I 2092.161104.6 IP I I zinc 1000. ol 1021. 54 1102. 2 I looo.o I 1006. 911100. 1 I 962. 041 96. 3 I P I

(l) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

Form II (Part l) - IN

':olumbia Analytical Services

METALS -2A-


:,ab Code: Case No.: SAS No.: SDG NO.: 1050477

Cnitial Calibration Source:

:ontinuing Calibration Source: PE PURE

Concentration Units: uq/L



!cadmium 500.0 I 510. 211 102. 1 I 508.95l 1oi.0 IP I I copper 1250.0 I 1261. 341 loo. 9 I 1212.16l1oi.0 IP I !Lead 500.0 I 490. 631 98 .1 I 492. 01 I 98. 4 I P I !Nickel 2000.ol 2094.201104. 7 I 2091.011104.91 PI I zinc 1000.0 I 977. 211 91. 1 I 971. 371 97 .1 I P I

(1) Control Limits: Mercury 80-120; Other Metals 90-110; .Cyanide 85rll5

Form II (Part 1) - IN

':olumbia Analytical Services

METALS -2A-


Contract: ~R2:=_:7~4~0~6~3~3~~~~~~~~~~~~~~~~~

C.ah Code: Case No.: SAS No.: SDG NO.: 1050477

Initial Calibration Source:

Continuing Calibration Source: PE PURE

Concentration Units: ug/L



/cadmium 500.0 I 500. 56/ loo. l I 500.54/101.1 /PI /copper 1250.0 I 1241. 26/ 99. 3 I 1259.11/ 100.1 /PI /Lead 500.0 I 472.05/ 94.4 / 475.25/ 95.1 /PI /Nickel 2000.0 I 2064.09/ 103.2 / 2090.21/ 104.9 /PI

(1) Control Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115

Form II (Part 1) - IN

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