Prospect of High Gradient Cavity

H. Hayano, 10222013

Tohoku Forum for Creativity 2013

Remarks of Rongli Geng at IWLC2010

>60MV/m by Thin-Film coated Cavity

Look review lecture by T. Tajima(LANL)for

“Thin Film coated Cavity”

Nb3Sn : tri-niobium tin

MgB2 : magnesium di-boride

Multi-layer thin film concept

T. Tajima

How to make thin-film on Nb?

Look presentation by Chaoyue Cao (IIT)for

“Point Contact Tunneling as a Surface Superconductivity Probe of bulk Nb and (Nb1-xTix )N Thin Films”

@ 5th Thin Film workshop 2012(Jlab)

• A thin film synthesis process based on sequential, self-limiting surface reactions between vapors of chemical precursors and a solid surface to deposit films in an atomic layer-by-layer manner.

Atomic layer deposition (ALD)C. Cao

ALD thin film materialsC. Cao

Advantages:

Atomic-level control of thickness and composition Smooth, continuous, pinhole-free coatings on large area substrates No line-of-sight limits → excellent conformality over complex

shaped surfacesCoat inside Nb SRF cavity with precise, layered structure → ALD

200 nmZnOSi

ALD is very good at coating non-planar surfaces

C. Cao

Multilayer thin films for SRF• Superconductor-Insulator multilayer [Gurevich, Appl. Phys. Lett. 88, 012511 (2006)]

Potential path to high Eacc and high Q0

Bi=B0exp(-Nd/lL)

C. Cao

Nb1-xTixN Thin Films made by ALD

Chemistry: (NbCl5:TiCl4) + Zn + NH3 at 450°C, 500°C

Can vary Ti content with NbCl5:TiCl4 ratio (1:2 ~ 20% TiN)

Impurity content: 0.05 atom % Cl

21 sec/cycle 2-7-1-5-1-5 ("NH3 dose"-"purge"-"MClx dose"-"purge"-"Zn dose"-"purge ")

C. Cao

Nb1-xTixN-based superconductor-insulator structuresAluminum nitride: AlN Oxygen-free insulator, stable interface with Nb(Ti)N Good thermal conductivity (285 W/m-K) Similar structure to Nb(Ti)N

– 0.27% mismatch between in-plane spacing of (001)-oriented AlN and (111)-oriented NbN Can be grown with AlCl3 and NH3 at same temperature as Nb(Ti)N

C. Cao

49nm Nb0.8Ti0.2N on AlN Tc= 12.8Kby SQUID

2Δ/kTc = 3.4 - 3.6(BCS limit)

Δ(meV)

Γ(meV)

C. Cao

28nm Nb0.8Ti0.2N (without AlN layer)Tc= 8.3Kby SQUID

Δ(meV)

Γ(meV)

C. Cao

• Point contact tunneling (PCT) technique is ideal for measuring the local surface superconducting energy gap and density of states (DOS) of samples with a natural barrier.

• Nb1-xTixN on AlN gives Tc = 12.8K, Δ = 1.8-2.2 meV, 2Δ/kTc = 3.4-3.6(BCS limit).

• Nb1-xTixN (without AlN) Tc = 8.3K. High quality gap region DOS, low zero bias conductance. Δ = 1.8-2.2 meV.

Conclusion

Substrate

Strained layer, low Tc

12.8 K

C. Cao

Application of “thin-film on Nb” to ILC?

Technology of;(1) nm-level Smooth Nb cavity surface,

(2) Well controlled thin-film formation on Nb cavity, will be required.

Then, we can reach >100MV/m with TESLA cavity shape.

Tumbling, electro-polish, etc.

Hydroforming without welding.

Atomic Layer Deposition (ALD)

End of slide

Prospect of High Gradient Cavity

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