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Bridging Dimensions in Organic Electronics: Assembly of Electroactive Polymer Nanodevices from Fluids. Huai-Yuan (Michael) Tseng EE C235. Introduction. Organic / flexible electronics Low cost solution process Spin / drop cast Printing Large area Plastic substrate. - PowerPoint PPT Presentation
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Huai-Yuan (Michael) TsengEE C235
Organic / flexible electronics◦ Low cost solution process
Spin / drop cast Printing
◦ Large area Plastic substrate
Difficult to scale down to sub-micron feature sizes
Top-down technique – Self align printing
Noh, Y. Y.; Zhao, N.; Caironi, M.; Sirringhaus, H. Nat. Nanotechnol.2007, 2 (12), 784–789. Sele, C. W.; Von Werne, T.; Friend, R. H.; Sirringhaus, H. AdV. Mater.2005, 17 (8), 997–1001
However, low device densities, limited by printing feature size
Large area organics/flexible nanoelectronics◦ High density of nanodevices◦ Addressing
Nanoarrays and crossbars
Beckman, R.; Johnston-Halperin, E.; Luo, Y.; Green, J. E.; Heath, J. R. Science 2005 (310 )p465
Only a single wire conduct
PEDOT:PSS =Poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate)
PDMS Molding
On/off is controlled by switching the conductivity of a transistor channel consisting of PEDOT/PSS in contact with a common electrolyte. Doping and de-doping of PEDOT can result in conductivity changes of up to five orders of magnitude
This work has successfully demonstrate◦ Large area patterning of connected micro/nanolines from the
conducting polymer PEDOT, assembled from fluids◦ Nanotransistors
Large area nanoregistration
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