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side 1 Mietitura AS®
Company address; Mietitura AS, Paal Bergs vei 42, 1348 Rykkin, 0219 Bærum, Norway
Post address; Mietitura AS, 1334 Rykkin Postkontor, PoBox 29, Norway
Tel: +47 454 01 266 E-post: post@mietitura.no
MATERIAL SAFETY DATA SHEET
Produkt: Paint additive
Foraflex
Valid Until: 22.07.2019 All-Union State Standard (GOST) 233299-95
Nasjonalprodukt klassifisering kode 02 57108 HS kode 3824909708
1. NAME AND COMPOSITION OF THE SUBSTANCE.
1.1 Name: Foraflex Paint additive, TU 2332-003-15259672-2016.
1.2 Product intended use: additive.
1.3 Chemical product identification
1.3.1 Product name Paint additive «Foraflex» [1]
1.3.2 Brief application
recommendations
(application
restrictions)
The product is used for addition to finished paints to provide them with
additional properties, i.e. to provide treated surface with water repellent,
corrosion resistant, and antiwear properties, to protect vessels from
biological fouling and icing [1]. Single-ingredient composition [1].
1.4 Composition
1.4.1 General product data
1.4.1.1 Chemical name (as
per IUPAC)
None. Mixture. [1]
side 2 Mietitura AS®
1.4.1.2 Chemical formula None. Mixture. [1]
1.4.1.3 General composition
description (with refer to its
lineup; production method)
The product is produced by mixing solvent (xylene) and nano-
microdisperesed polytetrafluoroethylene «FORUM», with the
size of its nano-structured particles of 0.1 to 1.2 µm. [1]
1.4.2 Ingredients
(name, CAS and EC numbers, mass fraction (its total must be 100%), MPCw.a., hazard class, references to
data sources)
Ingredients Hygienic regulations regarding
work area air
CAS
number
EC number
MPCw.a.,
mg/m3
Hazard class
Xylene 50 p 3 1330-20-7 215-535-7
Polytetrafluor
oethylene
10 4 9002-84-0 -
Note: p – vapors and/or gases
1.6 Safety Data Sheet Complies with the Recommendations of UN ST/SG/AC.10/30 «GHS»
IUPAC – International Union of Pure and Applied Chemistry
GHS – Recommendations of UN ST/ SG/AC.10/30 «Globally
Harmonized System of Classification and Labelling of
Chemicals»
CAS number – Substance number as per Chemical Abstracts Service Register
EC number – Substance number as per European Chemical Agency Register
MPCw.a.
– Maximum permissible concentration of chemical substance in
the work area air, mg/m3
Signal word – a word used for emphasizing the degree of chemical product’s
hazard and selected in accordance with GOST 31340-2013
2. INFORMATION ABOUT MANUFACTURER.
VLADFORUM LLC. Adresse: 690 039 23б-701, Eniseiskaya St, City of Vladivostok, Russland;
Tel./Fax: (423) 222-16-99, 222-17-94.
e-post:forum@forumshop.ru,
Web: www.forumshop.ru,
3. HAZARDS (DANGERS) IDENTIFICATION..
3.1 Hazard Statement
Signal Word Caution (Warning)
Brief statement (wording): classified as moderately hazardous substance in terms of the degree
of its effect on human body. High concentrations of vapors of xylene found in this additive have
side 3 Mietitura AS®
a narcotic effect and adverse impact on nervous system and cause skin and conjunctiva irritation.
This paint additive is classified as a fire- and explosion-hazardous product: autoignition
temperature: over 450oC; closed-cup flash point: not below 23oC; xylene vapors’ flammability
limits in air (by volume): lower limit: 1%, higher limit: 6%. In case of release decontaminate by
covering with sand moving to designated location.
Detailed statement: 16 sections of the Safety Data Sheet
MAIN HAZARDOUS
INGREDIENTS
Maximum permissible
concentration in the
work area, mg/m3
Hazard
class
CAS
Number
EC
Number
Xylene 50 3 1330-20-7 215-
535-7
Polytetrafluoroethylene
Forum
10 4 9002-84-0
3.2. General degree of
chemical product’s
hazard (information
about hazard
classification in
accordance with the
legislation of the
Russian Federation
(GOST 12.1.007-76)
and GSH
According to GOST 12.1.007, the product is classified as moderately
hazardous one in terms of the degree of its effect on human body, 3rd
hazard class [2].
According to GHS, GOST 32419-2013 and GOST 32423-2013, the
product is inflammable liquid (class 3). In case of skin contact it causes
skin damage/necrosis (class 2) and has sensitizing effect. In case of
conjunctiva contact causes serious eye damage/irritation (class 2A). Has
acute chronic aquatic toxicity (class 1) [3].
3.3 Warning labels identification as per GOST 31340-2013
3.3.1 Signal word «Caution» [4]
3.3.2 Hazard symbols «Dry tree and dead fish», «Flame», «Exclamation sign» [4]
3.3.3 Hazard statement
(H phrases)
H226: Flammable liquid and vapor
H315: Causes skin irritation
H317: May cause an allergic skin reaction
H319: Causes serious eye irritation
H410: Very toxic to aquatic life with long-lasting effects [4]
4 EMERGENCY FIRST AID MEASURES.
4.1 Encounterable symptoms
4.1.1 Inhalation Inertia, weakening response to external stimuluses, dyspnea.
Excitement followed by depression, weakening response to
external stimuluses, headache, vertigo, cough, throat irritation,
nausea, vomiting, respiratory rhythm disturbance.
High concentrations cause dystocia, tonic-clinic muscle activity,
pain attenuation, body temperature reduction, respiration and heart
rate fall; severe cases: loss of consciousness [5,6,7].
4.1.2 Skin contact Redness, dryness [5,6,7]
4.1.3 Eye contact Irritation, conjunctiva redness, eye watering [5,6,7]
side 4 Mietitura AS®
4.1.4 Ingestion Bellyache, nausea, vomiting. Dystocia, tremor, drowsiness,
headache, vertigo, respiratory rhythm disturbance, nausea,
vomiting, abdominal pain, diarrhea [5,6,7].
4.2 First aid measures
4.2.1 Inhalation Fresh air, rest, warmth; strong tea, coffee. In case of respiration
disturbance: oxygen inhalation; in case of respiration arrest: mouth-
to-mouth resuscitation [5,6,7].
4.2.2 Skin contact Flush with running water. Remove excessive substance with cotton
wool ball, flush with running water and soap [5,6,7].
4.2.3 Eye contact Flush with large amount of running water, keeping palpebral fissure
wide-open. Seek for medical attention [5,6,7].
4.2.4 Ingestion Flush mouth cavity with water, drink large amount of water, take
activated carbon and saline purge [5,6,7].
4.2.5 Counter-indications None [5,6,7]
5. FIRE-FIGHTING MEASURES AND MEANS.
5.1 General description
of fire and explosion
hazard (as per GOST
12.1.044-89)
According to GOST 12.1.044, this paint additive is combustible liquid
[8].
5.2 Fire and explosion
hazard indices (as per
GOST 12.1.044-89 and
GOST 30852.0-2002)
No general product data available [1].
Polytetrafluoroethylene: possible emission of toxic vapors at the
temperature exceeding 260 OC. Burns up in the atmosphere with the
oxygen content exceeding 95%, provided there is an ignition source.
5.3 Combustion and/or
thermal destruction
products and their
hazards
Fire smoke may contain original material as well as combustion
products of various content. Combustion and thermal destruction
product are carbon oxides (II) and (IV) and nitrogen oxides (II) and
(IV).
Hazards:
Light degree: no loss of consciousness, short-term syncope,
drowsiness, nausea, occasional vomiting; headache, excitement
followed by depression, vertigo, cough, smarting eyes, nasopharynx
irritation, eye watering, rhinitis, tightness, chest pain, fast shallow
breath and hart beat.
Moderate degree: loss of consciousness, after recovery: general
weakness, memory failures, locomotor impairment, spasms; sense of
fear, blue lips, leg numbness.
Severe degree: long-term loss of consciousness, clonic and tonic spasm
[5.6.9].
5.4 Recommended
firefighting media
Fire outbreaks: carbon dioxide, chemical foam, water mist, diammonium phosphate powder air-filled foam; sand, fire blanket.
Large-scale fire: extinguish fire from a large distance using air-filled
foam, powder or carbon dioxide [1,9].
side 5 Mietitura AS®
5.5 Firefighting media to
avoid
None [1,9]
5.6 Personal protective
firefighting equipment
(Firefighters’ PPE)
Fireproof suit equipped with self-rescue device [10].
5.7. Extinguishing
features
None [10].
6. MEASURES TO PREVENT EMERGENCIES .
6.1 Prevention measures against adverse effect on humans, environment, building, structures etc.
during accidents and emergencies
6.1.1 General necessary
actions
Isolate dangerous area within 200-m radius. Adjust this distance in
accordance with chemical survey results. Remove unauthorized
personnel. Enter dangerous area wearing protective equipment. Keep
windward size. Avoid low places. Observe fire safety measures. Do not
smoke. Eliminate fire and spark sources. Provide affected persons with
medical assistance. Send people from affected area to medical
examination [10].
6.1.2 Personal
protective equipment
(Emergency crews’
PPE)
Chemical survey and work superintendent: Portable respiratory device
Emergency crews: self-contained protective suit equipped with self-
contained gas mask or breathing apparatus. Fire outbreaks: fireproof suit
equipped with self-rescue device. In case of the lack of the above-
mentioned items: field protective suit equipped with industrial gas mask
with filter cartridge. Low aiborne concentrations (with maximum
permissible concentration exceeded up to 100 times) – protective wear,
small-sized industrial gas mask equipped with universal protective filter
cartridge, self-containing personal protective set with forced supply of
purified air to breathing area. Oil-and-gasoline resistant gloves, gloves
made of butyl rubber dispersion, protective shoes [10].
6.2 Procedure for eliminating accidents and emergencies
6.2.2 Actions in case of
fire
Do not approach burning containers. Cool down containers with
water from maximum distance. Extinguish fire with water mist, air-
filled and chemical foams from maximum distance [10].
Stop train traffic and maneuvers in the dangerous area. Do not touch
spilled substance. Eliminate leak while observing precautionary
measures. Pump the substance into proper container or discharge
container while observing liquid mixing conditions. Block spillages
with an earth mound. Prevent the substance from entering water
bodies, basements and sewage [10].
7. HANDLING AND STORAGE.
7.1 Safety measures during chemical product handling
7.1.1 Engineering
safety measures
systems
Fire safety and industrial sanitation rules must be strictly observed during
manufacturing, testing and application of the paint additive, pursuant to
GOST 12.3.002 and GOST 12.3.005 [11].
side 6 Mietitura AS®
All works relevant to manufacturing, application and testing of the paint
additive must be carried out in premises equipped with general suction
and-exhaust ventilation and local exhaust ventilation [12], which provide
the air purity in the work area, where hazardous substance concentration
must not exceed permissible values. For the purpose of ensuring the
process of manufacturing and applying modified epoxy primer, it is
necessary to provide adequate equipment and system sealing and integrity
of electric trigger hardware and instrumentation. When handling the paint
additive, possible combustible vapors’ ignition sources must be removed,
and the possibility of occurring static electricity and sparking eliminated.
Primary firefighting equipment must always be available [1,13].
7.1.2 Environmental
protection measures
Sealing of containers and equipment during the additive’s manufacturing
and transportation. Monitoring of hazardous substance content in
environmental mediums. Analysis of industrial emissions and effluents in
terms of whether their hazardous substance content is within permissible
concentrations. Waste treatment in accordance with the requirements
SanPiN 2.1.7.1322 [14].
For the purpose of preventing atmospheric air pollution, continuous
monitoring of maximum permissible emissions observance (MPE) must
be established, pursuant to GOST 17.2.3.02 [1,15].
7.1.3
Recommendations on
safe movement and
transportation
This paint additive is transported by all modes of transportation, using
covered vehicles, pursuant to hazardous goods transportation rules
applying to a particular mode of transportation. When transporting,
loading, unloading and storing modified epoxy primer, container must
be protected from damage, pollution and moisturizing. When carrying
out loading and unloading operations, safety rules established by GOST
12.3.00.9 must be observed [1].
7.2 Rules of Chemical product storage
This paint additive must be stored in dry, properly ventilated premises,
with recommended temperature range of minus 40 OC to plus 40 OC,
away from ignition and heat sources.
Container must not be exposed to the effects of atmospheric
precipitation and direct sunlight, pursuant to GOST 9980.5.
Warranty shelf life: 18 months from the date of manufacture.
Incompatible substances and materials for storage:
- Class 7 and 1 substances and subclass 8.2. substances;
- Inflammable gases without additional hazard type;
- Pungent and (or) corrosive inflammable gases;
- Poisonous and inflammable gases without additional hazard type.
7.2.2 Container and
package (including
their materials)
This additive is delivered to consumers using consumer package.
Package means shall comply with the requirements of TR TS 005/2011.
The product shall be put into 0.2-l, 0.5-l, 1-l, 3.5-l and 10-l consumer
polymer containers, pursuant to GOST R 51760. Each consignment
must be provided with packing list, operation and transportation
documents put into polyethylene film bag.
side 7 Mietitura AS®
When shipping the product to the Extreme North or its equivalent
regions, packaging must be carried out with refer to GOST 15846 [1].
7.3 Domestic safety
measures and storage
rules
No domestic use [1].
8. EXPOSURE CONTROL AND PERSONAL PROTECTION.
8.1 Work area
parameters subjected
to mandatory
monitoring
Work area air is monitored in accordance with GOST 12.1.005 and
regulations established by GN 2.2.5.1313-03 [2,8].
Work area air must be monitored by ingredients of the solvent found
in the paint additive:
Xylene – MPCw.a. = 50, vapors, 3rd hazard class
8.2 Measures for
keeping hazardous
substance content
within acceptable
concentration
Systematic monitoring of MPCw.a.. Use of personal protective
equipment. Availability of effective suction-and-exhaust ventilation,
which ensures the compliance with legally established hygienic
regulations on chemical ingredients, sealing of equipment and
containers, availability of protective and treatment facilities, which
enables to undertake environmental safety measures [16].
8.3 Personnel’s personal protective measures
8.3.1 General
recommendations
When handling the paint additive, avoid inhaling its vapors, as well as its
ingestion and skin and eye contact. Handle in accordance with safety and
industrial hygiene rules. Use in properly ventilated premises only. Keep
away from open flame or sparks. Wash hands before breaks and at the
end of work. Do not eat, drink and smoke when using this product. Keep
your work clothes separately. Production premises must be equipped with
suction-and-exhaust ventilation and local ventilation proving required
condition of the work area air [1,11,12]. Those who handle the paint
additive must be provided with protective wear and personal protective
equipment. Those who handle the paint additive must undertake
preliminary (when being hired) and periodic medical examinations,
pursuant to the Order of the Ministry of Health Care and Medical Industry
of the Russian Federation # 90-96 [1].
8.3.2 Respiratory
protection (types of
personal respiratory
protective equipment)
Respirators «Lepestok» (GOST 12.4.028) are used for respiratory
protection at the stage of raw material preparation, while universal
respirators (GOST 17269) are used at the stage of manufacturing
modified epoxy primer [17].
8.3.3 Protective
equipment (material,
type) (protective
wear, protective
shoes, hand
protection, eye
protection)
Rubber gloves (type 1, A GOST 20010) and skin-care products (GOST
12.4.068) must be used for hand skin protection.
Goggles ZP GOST R 12.4.013 must be used for eyes protection. Workers
must have protective wear (cotton suit or overall) and rubber shoes
(GOST 5375) [18].
8.3.4 Personal
protective equipment
for domestic use
No domestic use [1].
9 PHYSICAL AND CHEMICAL PROPERTIES.
side 8 Mietitura AS®
9.1 Physical state
(aggregative state,
color, odor)
Grey homogeneous suspension with specific odor [1].
9.2 Parameters
describing basic
product properties
(temperature, pH,
solubility, n octanol
water coefficient and
other parameters
specific to a particular
type of product)
Density at plus 20 OC: 0.8-1 kg/m3;
- mass fraction of polytetrafluoroethylene, %: no less than 25;
- aqueous extract .pH: 7;
- distillation temperature, OC: 137 – 143.
10. STABILITY AND REACTIVITY DATA.
10.1 Chemical
stability (in case of
unstable product,
indicate
decomposition
products)
This paint additive is chemically stable, provided storage and
transportation conditions are met [1].
10.2 Reactivity This paint additive is inert to water and organic solvents. As a working
liquid, it is exposed to hydrolysis and oxidization, which are most intense
in an acidic environment [1,5,6].
10.3 Conditions to
avoid (including
dangerous
expressions during
contact with
incompatible
substances and
materials)
Prevent reactions between this paint additive and paints containing
oxidizing agents, strong alkaline and strong acid materials to avoid the
occurrence of an exothermic reaction [5,6].
11.TOXICOLOGICAL INFORMATION..
11.1 General
description of the
effect (assumption of
the degree of hazard
(toxicity) effect on
human body)
According to GOST 12.1.007, the product is classified as moderately
hazardous one in terms of the degree of its effect on human body, 3rd
hazard class [2].
Due to the presence of xylene solvent, this paint additive has an
expressed irritating effect on skin and moderate irritating effect on
conjunctiva, and also affects nervous system.
The paint additive’s vapors may cause inertia, drowsiness and
headache, During continuous or repeatable exposure, the product
causes mild irritation and skin dryness. Continuous inhalation of the
product’s vapors can cause severe damage to health [5,6].
11.2 Routes of
exposure (inhalation,
oral, skin and eye
contact)
Inhalation: when inhaling aerosol (in case of spray application); oral:
when reaching digestion organs (e.g., in case of violating occupational
hygiene rules). Skin and conjunctiva contact (e.g., in case of using
modified epoxy primer without personal protective equipment) [4].
side 9 Mietitura AS®
11.3 Target human
organs, tissues and
systems
Central and peripheral nervous system, cardio-vascular systems, morphological composition of peripheral blood, blood-making organs,
liver, respiratory tracts [5,6].
11.4 Information
about hazardous
effects during direct
exposure to the
substance and their
consequences
(irritating effect on
upper respiratory
tracts, eyes, skin
(including skin-
resorptive effect) and
sensitization)
The product has an irritating effect on hand skin, conjunctiva and
respiratory tracts, and also sensitizing and skin-resorptive effects [6-7].
Xylene: the product has expressed irritating effect on skin and moderate
irritating effect on conjunctiva. It penetrates through intact skin
(saturated aqueous solution, «tail» method, 4 hours a day during 10
days: changes in genital toxicity indices). The product shows no
sensitizing effect during animal experiments (skin tests, Guinea pigs)
[7].
11.5 Information
about long-term
hazardous effects on
human body (effect
on reproduction
function,
carcinogenicity,
cumulativity and the
like)
Xylene:
- The product has embryotoxic effect (150 mg/m3, inh., 24 hours a day
during 7-14 days of pregnancy, rats: affects embryo and fetus; 1500
mg/m3, inh., 24 hours a day during 7-14 days of pregnancy, rats: fetal
toxicity);
- The product has gonadotoxic effect (500 mg/kg, intraperitoneally, 2
days before connubium, rats: spermatogenesis disorder (including
genetic material, sperm morphology, amount and mobility of sperm
cells));
- The product has teratogenic effect (500 mg/m3, inh., 12 hours a day
at the 6th and 16th day of pregnancy, rats: musculoskeletal system
disorder) during animal experiments [4,12].
According to the International Agency for Research on Cancer’s
classification [25], xylene (dimethylbenzene) is not classified as human
carcinogen, group 3 (unable to classify as human carcinogen).
Xylene is enlisted in the list of potentially hazardous chemical
substances in terms of the effect on reproduction function (hazardous
effects on gonads and/or embryo, according to the data of clinical and
experimental studies).
11.6 Acute toxicity
indices (DL50, route of
exposure (delivered
into stomach, applied
to skin), type of
animal; CL50,
exposure time (h),
type of animal)
Xylene:
LD50 = 5627 mg/kg; mouse, delivered into stomach;
LD50 > 5000 mg/kg; rabbit, applied to skin;
LC50 > 25.7 mg/l; rat, 4 hours;
[5,6]
12. ECOLOGICAL INFORMATION.
12.1 General
description of
environmental impact
Main hazardous environmental impacts are atmospheric air pollution in
the inhabited areas, turbidity of sewage and natural waters (water
bodies).
side 10 Mietitura AS®
(atmospheric air, soil,
water bodies)
The product has a hazardous effect on sanitary regimen of water bodies.
Its threshold concentration in terms of its effect on biological oxygen
demand of diluted sewage waters is 0.5 mg/l; the concentration of 1
mg/l has an adverse impact on the oxygen regimen of water bodies (by
xylene). The product inhibits the intensity of biomass growth. It can
pollute environment, change organoleptic water properties, has an
adverse impact on the oxygen regimen of water bodies, change self-
purification processes of water bodies and cause their biodegradation,
reduce in-water oxygen content, slow mineralization processes of in-
water organic substances [19].
12.2 Routes of
environmental impact
In case of violation of storage and transportation riles; uncontrolled
waste dumping and burial; discharge into open water bodies or «relief»;
misuse; container cleaning; accidents and emergencies.
12.3 Most important characteristics of environmental impact
12.3.1 Hygienic standards
(Permissible concentrations in atmospheric air, water (including fishery water bodies) and soils)
Table 2 [20-23]
Ingredients MPCatm.a or
RSELatm.a,
mg/m3 (LHI1,
hazard class)
MPCwater or
RPLwater, mg/l,
(LHI, hazard
class)
MPCfish. or
RSELfish., mg/l
(LHI, hazard
class)
MPC or RPCsoils,
mg/kg (LHI)
Xylene 0.2 refl. (3rd
hazard class)
0 0.05 org.
odor. (3rd
hazard class)
0.05 org. (3rd
hazard class)
0.3
(translocation)
Polytetrafluoroethylene Not available Not available Not available Not available
1 LHI – limiting harmful index (tox. – toxicological, s.-t.(san.-tox.) – sanitary and toxicological; org.
– organoleptic, including description of the nature of changes in organoleptic water properties (odor.
– changes water odor; turb. – increases water turbidity; paint. – paints water; foam – causes foaming;
film. – forms a film on water surface; off-fl. – provides water with off-flavour; op. – causes
opalescence), refl. – reflectory; res. – resorptive; refl.-res. – reflectory and resorptive; fish. – fishery
(change in commodity properties of commercial aquatic organisms); gen. – general sanitary).
2 Water of utility and drinking/cultural and domestic water bodies
3 Water of fishery water bodies (including sea ones)
12.3.2 Ecotoxicity
indices (CL, EC, NOEC
for fishes, Daphnia
magna, seaweeds and
the like)
Process xylene:
LC50 = 2.6 mg/l; Salmo mykiss, 96 hours;
EC50 > 1 mg/l, Daphnia magna, 24 hours;
NOEC = 0.44 mg/l, Pseudokirchneriella subcapitata, 73 hours [5,6,19]
12.3.3 Migration and
transformation in the
environment due to
the biodegradation or
other processes
(oxidization,
The product does not transform and does not produce secondary
hazardous products when reacting with outer environmental mediums
[1,19].
side 11 Mietitura AS®
hydrolysis and the
like)
13. WASTE (REMAINS) DISPOSAL CONSIDERATIONS
13.1 Safety measures
for handling wastes
generated during
application, storage and
transportation
Avoid direct contact. Use personal protective equipment. Safety
measures are similar to those recommended for handling primary product
(see Sections 7 and 8).
13.2 Information about
places and methods of
product (material;
including containers)
decontamination,
disposal or elimination
Liquid wastes of this paint additives (including solvents and remains)
must be collected into sealed labelled acid-resistant containers, which,
once accumulated, are sent to special enterprises, which have permission
and license issued by local sanitary or environmental protection
authorities, to be eliminated, and disposed by the contractor in pursuant
to SanPiN 2.1.7.1322003 [1,8].
13.3 Recommendations
on removal of wastes
generated during
domestic use of the
product
No domestic use [20].
14. TRANSPORT INFORMATION.
14.1 UN number (in
accordance with the
UN recommendations
on transport of
dangerous goods)
Serial number UN 1307 [24]
14.2 Shipping and/or
transportation name
«Paint additive»
Paint additive «Foraflex» [1]
14.3 Types of
transport
To be transported in packages by all modes of transportation, under
conditions preventing the package from pollution, mechanical damage
and effects of atmospheric precipitation, pursuant to cargo
transportation rules applying to each mode of transportation [1].
14.4 Classification of
dangerous goods as
per GOST 19433-88:
- class;
-subclass;
3 [24]
3.3 [24]
- classification code
(as per GOST 19433-
88 for railway
transportation)
- hazard sign(s)
drawing(s) number
(s)
3313 [24]
Railway transportation: 3013 [25]
14.5 Hazard
classification of
3 [24]
None [24]
side 12 Mietitura AS®
goods as per UN
recommendations on
transport of
dangerous goods
- class or subclass;
- additional hazard;
- UN packing group;
III [24]
14.6 Transport
labelling (handling
signs as per GOST
14192-96)
Transport labelling is carried out in accordance with GOST 14192,
accompanied by labelling handling sign # 1 «Fragile. Caution»,
handling sign # 2«Protect from sunlight», handling sign # 4 «Protect
from moisture», handling sign # 7 «Sealed package», handling sign #
11 «Upper side» and handling sign # 22 «Limited number of stack
layers» [26]
14.7 Air
Transportation
Information about the hazard during air transportation is applied in
accordance with cargo transportation rules applying to a particular
mode of transportation.
Enterprise emergency cards (unnumbered) regarding motorway and
river transportation.
Emergency card F-A, S-F regarding sea transportation [27].
15. REGULATORY INFORMATION.
15.1 National legislation
15.1.1 Laws of the
Russian Federation
«On engineering regulation»
«On environmental protection»
«On public sanitary and epidemiological welfare»
15.1.2 Regulatory
documents on human
and environmental
protection
requirements
«Unified sanitary, epidemiological and hygienic requirements for
commodities subjected to sanitary and epidemiological supervision
(monitoring)» (approved on May 28, 2010, # 299)
16 OTHER INFORMATION
16.1 Information about
revision (reissuance) of the
safety data sheet
This safety data sheet was initially developed in
accordance with the requirements of GOST 30333-2007
[30,31].
16.2 List of data sources used for preparing this safety data sheet
1. TU 2332-003-15259672-2016 Paint additive «Foraflex»
2. GN 2.2.5 1313-03 Maximum permissible concentrations (MPC/RSEL) of hazardous substances in
the work area air.
3. Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
4. GOST 31340-2013 Labelling of chemicals. General requirements
5. Data of the ECHA (European Chemicals Agency) information system. [Electronic source]: Access
mode: http://echa.europa.eu/
6. On-line hazardous substances database “Automated Distributed Information Retrieval System”.
[Electronic source]: Access mode: http://www.rpohv.ru/arips.
side 13 Mietitura AS®
7. Information card of potentially hazardous chemical and biological substance
8. Register of Potentially Hazardous Chemical and Biological Substances, rev. 1 and 2.
Dimethylbenzene (isomer mixture). Stare Registration Certificate, series ВТ # 000525 dated March
26, 2015.
9. GOST 12.1.044-89 (ISO 4589-84) with rev. 1 Оccupational safety standards system. Fire and
explosion hazard of substances and materials. Nomenclature of indices and methods of their
determination
10. A.Ya. Korolchenko Fire and explosion hazard of substances and materials and their firefighting
media. Handbook published in 2 parts. – Moscow: Association «Pozhnauka», 2000, 2004;
11. Safety rules and procedure for recovering from accidents related to dangerous goods during their
railway transportation (Novosibirsk: Novosibirsk Institute of Railway Transport Engineers, 1997).
Emergency cards regarding dangerous goods transported by railways of the CIS, Latvian
Republic, Lithuanian Republic and Estonian Republic (Moscow: Transport, 2000, revised with
amendments and additions dated November 21, 2008 and May 22, 2009; revised protocols dated
May 14, 2010; October 21, 2010; October 29, 2011; May 18, 2012; and October 17, 2012);
Emergency card # 305.
12. GOST 12.1.005-88 «General sanitary requirements for working zone air»
13. GOST 12.4.021-75 «Ventilation systems. General requirements»
14. Occupational safety procedures for analytical laboratories. Rules of handling highly inflammable
liquids.
15. Sanitary Rules and Regulations «SanPiN 2.1.7.132203 Hygienic requirements for disposal and
decontamination of production and consumption wastes»
16. SanPiN 2.1.6.1032-01 “Hygienic requirements for assuring atmospheric air quality in the
inhabited areas” (approved by the Chief State Medical Officer of the Russian Federation on May
17, 2001)
17. Sanitary Rules and Regulations «SanPiN 2.1.7.132203 Hygienic requirements for disposal and
decontamination of production and consumption wastes»
18. GOST 17269 Combination chemical cartridge and mechanical filter respirators РУ-60м and РУ-
60му
19. GOST 5375-79 Rubber moulded boots.
20. Data of the eChemPortal. [Electronic source]: Access mode: http://echemportal.org/
21. MPC/RSEL of polluting substances in an atmospheric air of inhabited areas. GN 2.1.6.1338-
03/2.1.6.2309-07. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation,
2003, 2008;
22. MPC/RPL of in-water chemical substances in the utility and drinking/cultural and domestic water
bodies. GN 2.1.5.1315-03/GN 2.1.5.2307-07.
23. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation, 2003, 2008;
24. MPC/RPL of in-soil chemical substances. GN 2.1.7.2041-06/GN 2.1.7.2511-09.
25. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation, 2006, 2009;
26. Water quality standards for fishery water facilities, including standards on maximum permissible
concentrations of in-water hazardous substances in the fishery water facilities. Approved by the
Order # 20 of the Federal Fishery Agency dated January 18, 2010;
27. Recommendations on transport of dangerous good. Model regulations. 17th revised edition. The
United Nations Organization, New-York and Geneva, 2011;
28. GOST 19433-88 with rev. 1 Dangerous goods. Classification and marking – Moscow: standard
publishing office, 1988;
side 14 Mietitura AS®
29. GOST 14192-96 with rev. 1-3 Marking of cargoes – Moscow: standard publishing office
30. International Maritime Dangerous Goods Code. IMDG Code. 2006 edition. – C – published by the
Closed Joint Stock Company “Central Scientific Research Design Institute of Marine Fleet”, 2007
31. Montreal Protocol on Substances that Deplete the Ozone Layer dated September 16, 1987.
32. Stockholm Convention on Persistent Organic Pollutants dated May 22, 2001
33. GOST 30333-2007 «Chemical production safety passport. General requirements»
34. Methodological recommendations for preparing and issuing substance (material) safety data sheet.
– Moscow: All-Russian Scientific Research Center for Standardization, Notification and
Certification of Raw Materials, Materials and Substances of the Committee for Standardization,
Metrology and Certification of the Russian Federation, 1995.
Recommended