Company address; Mietitura AS, Paal Bergs vei 42, 1348 ... · (GOST 12.1.007-76) and GSH According to GOST 12.1.007, the product is classified as moderately hazardous one in terms

side 1 Mietitura AS®

Company address; Mietitura AS, Paal Bergs vei 42, 1348 Rykkin, 0219 Bærum, Norway

Post address; Mietitura AS, 1334 Rykkin Postkontor, PoBox 29, Norway

Tel: +47 454 01 266 E-post: [email protected]

MATERIAL SAFETY DATA SHEET

Produkt: Paint additive

Foraflex

Valid Until: 22.07.2019 All-Union State Standard (GOST) 233299-95

Nasjonalprodukt klassifisering kode 02 57108 HS kode 3824909708

1. NAME AND COMPOSITION OF THE SUBSTANCE.

1.1 Name: Foraflex Paint additive, TU 2332-003-15259672-2016.

1.2 Product intended use: additive.

1.3 Chemical product identification

1.3.1 Product name Paint additive «Foraflex» [1]

1.3.2 Brief application

recommendations

(application

restrictions)

The product is used for addition to finished paints to provide them with

additional properties, i.e. to provide treated surface with water repellent,

corrosion resistant, and antiwear properties, to protect vessels from

biological fouling and icing [1]. Single-ingredient composition [1].

1.4 Composition

1.4.1 General product data

1.4.1.1 Chemical name (as

per IUPAC)

None. Mixture. [1]

mailto:[email protected]


1.4.1.2 Chemical formula None. Mixture. [1]

1.4.1.3 General composition

description (with refer to its

lineup; production method)

The product is produced by mixing solvent (xylene) and nano-

microdisperesed polytetrafluoroethylene «FORUM», with the

size of its nano-structured particles of 0.1 to 1.2 µm. [1]

1.4.2 Ingredients

(name, CAS and EC numbers, mass fraction (its total must be 100%), MPCw.a., hazard class, references to

data sources)

Ingredients Hygienic regulations regarding

work area air

CAS

number

EC number

MPCw.a.,

mg/m3

Hazard class

Xylene 50 p 3 1330-20-7 215-535-7

Polytetrafluor

oethylene

10 4 9002-84-0 -

Note: p – vapors and/or gases

1.6 Safety Data Sheet Complies with the Recommendations of UN ST/SG/AC.10/30 «GHS»

IUPAC – International Union of Pure and Applied Chemistry

GHS – Recommendations of UN ST/ SG/AC.10/30 «Globally

Harmonized System of Classification and Labelling of

Chemicals»

CAS number – Substance number as per Chemical Abstracts Service Register

EC number – Substance number as per European Chemical Agency Register

MPCw.a.

– Maximum permissible concentration of chemical substance in

the work area air, mg/m3

Signal word – a word used for emphasizing the degree of chemical product’s

hazard and selected in accordance with GOST 31340-2013

2. INFORMATION ABOUT MANUFACTURER.

VLADFORUM LLC. Adresse: 690 039 23б-701, Eniseiskaya St, City of Vladivostok, Russland;

Tel./Fax: (423) 222-16-99, 222-17-94.

e-post:[email protected],

Web: www.forumshop.ru,

3. HAZARDS (DANGERS) IDENTIFICATION..

3.1 Hazard Statement

Signal Word Caution (Warning)

Brief statement (wording): classified as moderately hazardous substance in terms of the degree

of its effect on human body. High concentrations of vapors of xylene found in this additive have

mailto:[email protected]

http://www.forumshop.ru/


a narcotic effect and adverse impact on nervous system and cause skin and conjunctiva irritation.

This paint additive is classified as a fire- and explosion-hazardous product: autoignition

temperature: over 450oC; closed-cup flash point: not below 23oC; xylene vapors’ flammability

limits in air (by volume): lower limit: 1%, higher limit: 6%. In case of release decontaminate by

covering with sand moving to designated location.

Detailed statement: 16 sections of the Safety Data Sheet

MAIN HAZARDOUS

INGREDIENTS

Maximum permissible

concentration in the

work area, mg/m3

Hazard

class

CAS

Number

EC

Number

Xylene 50 3 1330-20-7 215-

535-7

Polytetrafluoroethylene

Forum

10 4 9002-84-0

3.2. General degree of

chemical product’s

hazard (information

about hazard

classification in

accordance with the

legislation of the

Russian Federation

(GOST 12.1.007-76)

and GSH

According to GOST 12.1.007, the product is classified as moderately

hazardous one in terms of the degree of its effect on human body, 3rd

hazard class [2].

According to GHS, GOST 32419-2013 and GOST 32423-2013, the

product is inflammable liquid (class 3). In case of skin contact it causes

skin damage/necrosis (class 2) and has sensitizing effect. In case of

conjunctiva contact causes serious eye damage/irritation (class 2A). Has

acute chronic aquatic toxicity (class 1) [3].

3.3 Warning labels identification as per GOST 31340-2013

3.3.1 Signal word «Caution» [4]

3.3.2 Hazard symbols «Dry tree and dead fish», «Flame», «Exclamation sign» [4]

3.3.3 Hazard statement

(H phrases)

H226: Flammable liquid and vapor

H315: Causes skin irritation

H317: May cause an allergic skin reaction

H319: Causes serious eye irritation

H410: Very toxic to aquatic life with long-lasting effects [4]

4 EMERGENCY FIRST AID MEASURES.

4.1 Encounterable symptoms

4.1.1 Inhalation Inertia, weakening response to external stimuluses, dyspnea.

Excitement followed by depression, weakening response to

external stimuluses, headache, vertigo, cough, throat irritation,

nausea, vomiting, respiratory rhythm disturbance.

High concentrations cause dystocia, tonic-clinic muscle activity,

pain attenuation, body temperature reduction, respiration and heart

rate fall; severe cases: loss of consciousness [5,6,7].

4.1.2 Skin contact Redness, dryness [5,6,7]

4.1.3 Eye contact Irritation, conjunctiva redness, eye watering [5,6,7]


4.1.4 Ingestion Bellyache, nausea, vomiting. Dystocia, tremor, drowsiness,

headache, vertigo, respiratory rhythm disturbance, nausea,

vomiting, abdominal pain, diarrhea [5,6,7].

4.2 First aid measures

4.2.1 Inhalation Fresh air, rest, warmth; strong tea, coffee. In case of respiration

disturbance: oxygen inhalation; in case of respiration arrest: mouth-

to-mouth resuscitation [5,6,7].

4.2.2 Skin contact Flush with running water. Remove excessive substance with cotton

wool ball, flush with running water and soap [5,6,7].

4.2.3 Eye contact Flush with large amount of running water, keeping palpebral fissure

wide-open. Seek for medical attention [5,6,7].

4.2.4 Ingestion Flush mouth cavity with water, drink large amount of water, take

activated carbon and saline purge [5,6,7].

4.2.5 Counter-indications None [5,6,7]

5. FIRE-FIGHTING MEASURES AND MEANS.

5.1 General description

of fire and explosion

hazard (as per GOST

12.1.044-89)

According to GOST 12.1.044, this paint additive is combustible liquid

[8].

5.2 Fire and explosion

hazard indices (as per

GOST 12.1.044-89 and

GOST 30852.0-2002)

No general product data available [1].

Polytetrafluoroethylene: possible emission of toxic vapors at the

temperature exceeding 260 OC. Burns up in the atmosphere with the

oxygen content exceeding 95%, provided there is an ignition source.

5.3 Combustion and/or

thermal destruction

products and their

hazards

Fire smoke may contain original material as well as combustion

products of various content. Combustion and thermal destruction

product are carbon oxides (II) and (IV) and nitrogen oxides (II) and

(IV).

Hazards:

Light degree: no loss of consciousness, short-term syncope,

drowsiness, nausea, occasional vomiting; headache, excitement

followed by depression, vertigo, cough, smarting eyes, nasopharynx

irritation, eye watering, rhinitis, tightness, chest pain, fast shallow

breath and hart beat.

Moderate degree: loss of consciousness, after recovery: general

weakness, memory failures, locomotor impairment, spasms; sense of

fear, blue lips, leg numbness.

Severe degree: long-term loss of consciousness, clonic and tonic spasm

[5.6.9].

5.4 Recommended

firefighting media

Fire outbreaks: carbon dioxide, chemical foam, water mist, diammonium phosphate powder air-filled foam; sand, fire blanket.

Large-scale fire: extinguish fire from a large distance using air-filled

foam, powder or carbon dioxide [1,9].


5.5 Firefighting media to

avoid

None [1,9]

5.6 Personal protective

firefighting equipment

(Firefighters’ PPE)

Fireproof suit equipped with self-rescue device [10].

5.7. Extinguishing

features

None [10].

6. MEASURES TO PREVENT EMERGENCIES .

6.1 Prevention measures against adverse effect on humans, environment, building, structures etc.

during accidents and emergencies

6.1.1 General necessary

actions

Isolate dangerous area within 200-m radius. Adjust this distance in

accordance with chemical survey results. Remove unauthorized

personnel. Enter dangerous area wearing protective equipment. Keep

windward size. Avoid low places. Observe fire safety measures. Do not

smoke. Eliminate fire and spark sources. Provide affected persons with

medical assistance. Send people from affected area to medical

examination [10].

6.1.2 Personal

protective equipment

(Emergency crews’

PPE)

Chemical survey and work superintendent: Portable respiratory device

Emergency crews: self-contained protective suit equipped with self-

contained gas mask or breathing apparatus. Fire outbreaks: fireproof suit

equipped with self-rescue device. In case of the lack of the above-

mentioned items: field protective suit equipped with industrial gas mask

with filter cartridge. Low aiborne concentrations (with maximum

permissible concentration exceeded up to 100 times) – protective wear,

small-sized industrial gas mask equipped with universal protective filter

cartridge, self-containing personal protective set with forced supply of

purified air to breathing area. Oil-and-gasoline resistant gloves, gloves

made of butyl rubber dispersion, protective shoes [10].

6.2 Procedure for eliminating accidents and emergencies

6.2.2 Actions in case of

fire

Do not approach burning containers. Cool down containers with

water from maximum distance. Extinguish fire with water mist, air-

filled and chemical foams from maximum distance [10].

Stop train traffic and maneuvers in the dangerous area. Do not touch

spilled substance. Eliminate leak while observing precautionary

measures. Pump the substance into proper container or discharge

container while observing liquid mixing conditions. Block spillages

with an earth mound. Prevent the substance from entering water

bodies, basements and sewage [10].

7. HANDLING AND STORAGE.

7.1 Safety measures during chemical product handling

7.1.1 Engineering

safety measures

systems

Fire safety and industrial sanitation rules must be strictly observed during

manufacturing, testing and application of the paint additive, pursuant to

GOST 12.3.002 and GOST 12.3.005 [11].


All works relevant to manufacturing, application and testing of the paint

additive must be carried out in premises equipped with general suction

and-exhaust ventilation and local exhaust ventilation [12], which provide

the air purity in the work area, where hazardous substance concentration

must not exceed permissible values. For the purpose of ensuring the

process of manufacturing and applying modified epoxy primer, it is

necessary to provide adequate equipment and system sealing and integrity

of electric trigger hardware and instrumentation. When handling the paint

additive, possible combustible vapors’ ignition sources must be removed,

and the possibility of occurring static electricity and sparking eliminated.

Primary firefighting equipment must always be available [1,13].

7.1.2 Environmental

protection measures

Sealing of containers and equipment during the additive’s manufacturing

and transportation. Monitoring of hazardous substance content in

environmental mediums. Analysis of industrial emissions and effluents in

terms of whether their hazardous substance content is within permissible

concentrations. Waste treatment in accordance with the requirements

SanPiN 2.1.7.1322 [14].

For the purpose of preventing atmospheric air pollution, continuous

monitoring of maximum permissible emissions observance (MPE) must

be established, pursuant to GOST 17.2.3.02 [1,15].

7.1.3

Recommendations on

safe movement and

transportation

This paint additive is transported by all modes of transportation, using

covered vehicles, pursuant to hazardous goods transportation rules

applying to a particular mode of transportation. When transporting,

loading, unloading and storing modified epoxy primer, container must

be protected from damage, pollution and moisturizing. When carrying

out loading and unloading operations, safety rules established by GOST

12.3.00.9 must be observed [1].

7.2 Rules of Chemical product storage

This paint additive must be stored in dry, properly ventilated premises,

with recommended temperature range of minus 40 OC to plus 40 OC,

away from ignition and heat sources.

Container must not be exposed to the effects of atmospheric

precipitation and direct sunlight, pursuant to GOST 9980.5.

Warranty shelf life: 18 months from the date of manufacture.

Incompatible substances and materials for storage:

- Class 7 and 1 substances and subclass 8.2. substances;

- Inflammable gases without additional hazard type;

- Pungent and (or) corrosive inflammable gases;

- Poisonous and inflammable gases without additional hazard type.

7.2.2 Container and

package (including

their materials)

This additive is delivered to consumers using consumer package.

Package means shall comply with the requirements of TR TS 005/2011.

The product shall be put into 0.2-l, 0.5-l, 1-l, 3.5-l and 10-l consumer

polymer containers, pursuant to GOST R 51760. Each consignment

must be provided with packing list, operation and transportation

documents put into polyethylene film bag.


When shipping the product to the Extreme North or its equivalent

regions, packaging must be carried out with refer to GOST 15846 [1].

7.3 Domestic safety

measures and storage

rules

No domestic use [1].

8. EXPOSURE CONTROL AND PERSONAL PROTECTION.

8.1 Work area

parameters subjected

to mandatory

monitoring

Work area air is monitored in accordance with GOST 12.1.005 and

regulations established by GN 2.2.5.1313-03 [2,8].

Work area air must be monitored by ingredients of the solvent found

in the paint additive:

Xylene – MPCw.a. = 50, vapors, 3rd hazard class

8.2 Measures for

keeping hazardous

substance content

within acceptable

concentration

Systematic monitoring of MPCw.a.. Use of personal protective

equipment. Availability of effective suction-and-exhaust ventilation,

which ensures the compliance with legally established hygienic

regulations on chemical ingredients, sealing of equipment and

containers, availability of protective and treatment facilities, which

enables to undertake environmental safety measures [16].

8.3 Personnel’s personal protective measures

8.3.1 General

recommendations

When handling the paint additive, avoid inhaling its vapors, as well as its

ingestion and skin and eye contact. Handle in accordance with safety and

industrial hygiene rules. Use in properly ventilated premises only. Keep

away from open flame or sparks. Wash hands before breaks and at the

end of work. Do not eat, drink and smoke when using this product. Keep

your work clothes separately. Production premises must be equipped with

suction-and-exhaust ventilation and local ventilation proving required

condition of the work area air [1,11,12]. Those who handle the paint

additive must be provided with protective wear and personal protective

equipment. Those who handle the paint additive must undertake

preliminary (when being hired) and periodic medical examinations,

pursuant to the Order of the Ministry of Health Care and Medical Industry

of the Russian Federation # 90-96 [1].

8.3.2 Respiratory

protection (types of

personal respiratory

protective equipment)

Respirators «Lepestok» (GOST 12.4.028) are used for respiratory

protection at the stage of raw material preparation, while universal

respirators (GOST 17269) are used at the stage of manufacturing

modified epoxy primer [17].

8.3.3 Protective

equipment (material,

type) (protective

wear, protective

shoes, hand

protection, eye

protection)

Rubber gloves (type 1, A GOST 20010) and skin-care products (GOST

12.4.068) must be used for hand skin protection.

Goggles ZP GOST R 12.4.013 must be used for eyes protection. Workers

must have protective wear (cotton suit or overall) and rubber shoes

(GOST 5375) [18].

8.3.4 Personal

protective equipment

for domestic use


9 PHYSICAL AND CHEMICAL PROPERTIES.


9.1 Physical state

(aggregative state,

color, odor)

Grey homogeneous suspension with specific odor [1].

9.2 Parameters

describing basic

product properties

(temperature, pH,

solubility, n octanol

water coefficient and

other parameters

specific to a particular

type of product)

Density at plus 20 OC: 0.8-1 kg/m3;

- mass fraction of polytetrafluoroethylene, %: no less than 25;

- aqueous extract .pH: 7;

- distillation temperature, OC: 137 – 143.

10. STABILITY AND REACTIVITY DATA.

10.1 Chemical

stability (in case of

unstable product,

indicate

decomposition

products)

This paint additive is chemically stable, provided storage and

transportation conditions are met [1].

10.2 Reactivity This paint additive is inert to water and organic solvents. As a working

liquid, it is exposed to hydrolysis and oxidization, which are most intense

in an acidic environment [1,5,6].

10.3 Conditions to

avoid (including

dangerous

expressions during

contact with

incompatible

substances and

materials)

Prevent reactions between this paint additive and paints containing

oxidizing agents, strong alkaline and strong acid materials to avoid the

occurrence of an exothermic reaction [5,6].

11.TOXICOLOGICAL INFORMATION..

11.1 General

description of the

effect (assumption of

the degree of hazard

(toxicity) effect on

human body)

According to GOST 12.1.007, the product is classified as moderately

hazardous one in terms of the degree of its effect on human body, 3rd

hazard class [2].

Due to the presence of xylene solvent, this paint additive has an

expressed irritating effect on skin and moderate irritating effect on

conjunctiva, and also affects nervous system.

The paint additive’s vapors may cause inertia, drowsiness and

headache, During continuous or repeatable exposure, the product

causes mild irritation and skin dryness. Continuous inhalation of the

product’s vapors can cause severe damage to health [5,6].

11.2 Routes of

exposure (inhalation,

oral, skin and eye

contact)

Inhalation: when inhaling aerosol (in case of spray application); oral:

when reaching digestion organs (e.g., in case of violating occupational

hygiene rules). Skin and conjunctiva contact (e.g., in case of using

modified epoxy primer without personal protective equipment) [4].


11.3 Target human

organs, tissues and

systems

Central and peripheral nervous system, cardio-vascular systems, morphological composition of peripheral blood, blood-making organs,

liver, respiratory tracts [5,6].

11.4 Information

about hazardous

effects during direct

exposure to the

substance and their

consequences

(irritating effect on

upper respiratory

tracts, eyes, skin

(including skin-

resorptive effect) and

sensitization)

The product has an irritating effect on hand skin, conjunctiva and

respiratory tracts, and also sensitizing and skin-resorptive effects [6-7].

Xylene: the product has expressed irritating effect on skin and moderate

irritating effect on conjunctiva. It penetrates through intact skin

(saturated aqueous solution, «tail» method, 4 hours a day during 10

days: changes in genital toxicity indices). The product shows no

sensitizing effect during animal experiments (skin tests, Guinea pigs)

[7].

11.5 Information

about long-term

hazardous effects on

human body (effect

on reproduction

function,

carcinogenicity,

cumulativity and the

like)

Xylene:

- The product has embryotoxic effect (150 mg/m3, inh., 24 hours a day

during 7-14 days of pregnancy, rats: affects embryo and fetus; 1500

mg/m3, inh., 24 hours a day during 7-14 days of pregnancy, rats: fetal

toxicity);

- The product has gonadotoxic effect (500 mg/kg, intraperitoneally, 2

days before connubium, rats: spermatogenesis disorder (including

genetic material, sperm morphology, amount and mobility of sperm

cells));

- The product has teratogenic effect (500 mg/m3, inh., 12 hours a day

at the 6th and 16th day of pregnancy, rats: musculoskeletal system

disorder) during animal experiments [4,12].

According to the International Agency for Research on Cancer’s

classification [25], xylene (dimethylbenzene) is not classified as human

carcinogen, group 3 (unable to classify as human carcinogen).

Xylene is enlisted in the list of potentially hazardous chemical

substances in terms of the effect on reproduction function (hazardous

effects on gonads and/or embryo, according to the data of clinical and

experimental studies).

11.6 Acute toxicity

indices (DL50, route of

exposure (delivered

into stomach, applied

to skin), type of

animal; CL50,

exposure time (h),

type of animal)

Xylene:

LD50 = 5627 mg/kg; mouse, delivered into stomach;

LD50 > 5000 mg/kg; rabbit, applied to skin;

LC50 > 25.7 mg/l; rat, 4 hours;

[5,6]

12. ECOLOGICAL INFORMATION.

12.1 General

description of

environmental impact

Main hazardous environmental impacts are atmospheric air pollution in

the inhabited areas, turbidity of sewage and natural waters (water

bodies).


(atmospheric air, soil,

water bodies)

The product has a hazardous effect on sanitary regimen of water bodies.

Its threshold concentration in terms of its effect on biological oxygen

demand of diluted sewage waters is 0.5 mg/l; the concentration of 1

mg/l has an adverse impact on the oxygen regimen of water bodies (by

xylene). The product inhibits the intensity of biomass growth. It can

pollute environment, change organoleptic water properties, has an

adverse impact on the oxygen regimen of water bodies, change self-

purification processes of water bodies and cause their biodegradation,

reduce in-water oxygen content, slow mineralization processes of in-

water organic substances [19].

12.2 Routes of

environmental impact

In case of violation of storage and transportation riles; uncontrolled

waste dumping and burial; discharge into open water bodies or «relief»;

misuse; container cleaning; accidents and emergencies.

12.3 Most important characteristics of environmental impact

12.3.1 Hygienic standards

(Permissible concentrations in atmospheric air, water (including fishery water bodies) and soils)

Table 2 [20-23]

Ingredients MPCatm.a or

RSELatm.a,

mg/m3 (LHI1,

hazard class)

MPCwater or

RPLwater, mg/l,

(LHI, hazard

class)

MPCfish. or

RSELfish., mg/l

(LHI, hazard

class)

MPC or RPCsoils,

mg/kg (LHI)

Xylene 0.2 refl. (3rd

hazard class)

0 0.05 org.

odor. (3rd

hazard class)

0.05 org. (3rd

hazard class)

0.3

(translocation)

Polytetrafluoroethylene Not available Not available Not available Not available

1 LHI – limiting harmful index (tox. – toxicological, s.-t.(san.-tox.) – sanitary and toxicological; org.

– organoleptic, including description of the nature of changes in organoleptic water properties (odor.

– changes water odor; turb. – increases water turbidity; paint. – paints water; foam – causes foaming;

film. – forms a film on water surface; off-fl. – provides water with off-flavour; op. – causes

opalescence), refl. – reflectory; res. – resorptive; refl.-res. – reflectory and resorptive; fish. – fishery

(change in commodity properties of commercial aquatic organisms); gen. – general sanitary).

2 Water of utility and drinking/cultural and domestic water bodies

3 Water of fishery water bodies (including sea ones)

12.3.2 Ecotoxicity

indices (CL, EC, NOEC

for fishes, Daphnia

magna, seaweeds and

the like)

Process xylene:

LC50 = 2.6 mg/l; Salmo mykiss, 96 hours;

EC50 > 1 mg/l, Daphnia magna, 24 hours;

NOEC = 0.44 mg/l, Pseudokirchneriella subcapitata, 73 hours [5,6,19]

12.3.3 Migration and

transformation in the

environment due to

the biodegradation or

other processes

(oxidization,

The product does not transform and does not produce secondary

hazardous products when reacting with outer environmental mediums

[1,19].


hydrolysis and the

like)

13. WASTE (REMAINS) DISPOSAL CONSIDERATIONS

13.1 Safety measures

for handling wastes

generated during

application, storage and

transportation

Avoid direct contact. Use personal protective equipment. Safety

measures are similar to those recommended for handling primary product

(see Sections 7 and 8).

13.2 Information about

places and methods of

product (material;

including containers)

decontamination,

disposal or elimination

Liquid wastes of this paint additives (including solvents and remains)

must be collected into sealed labelled acid-resistant containers, which,

once accumulated, are sent to special enterprises, which have permission

and license issued by local sanitary or environmental protection

authorities, to be eliminated, and disposed by the contractor in pursuant

to SanPiN 2.1.7.1322003 [1,8].

13.3 Recommendations

on removal of wastes

generated during

domestic use of the

product


14. TRANSPORT INFORMATION.

14.1 UN number (in

accordance with the

UN recommendations

on transport of

dangerous goods)

Serial number UN 1307 [24]

14.2 Shipping and/or

transportation name

«Paint additive»

Paint additive «Foraflex» [1]

14.3 Types of

transport

To be transported in packages by all modes of transportation, under

conditions preventing the package from pollution, mechanical damage

and effects of atmospheric precipitation, pursuant to cargo

transportation rules applying to each mode of transportation [1].

14.4 Classification of

dangerous goods as

per GOST 19433-88:

- class;

-subclass;

3 [24]

3.3 [24]

- classification code

(as per GOST 19433-

88 for railway

transportation)

- hazard sign(s)

drawing(s) number

(s)

3313 [24]

Railway transportation: 3013 [25]

14.5 Hazard

classification of

3 [24]

None [24]


goods as per UN

recommendations on

transport of

dangerous goods

- class or subclass;

- additional hazard;

- UN packing group;

III [24]

14.6 Transport

labelling (handling

signs as per GOST

14192-96)

Transport labelling is carried out in accordance with GOST 14192,

accompanied by labelling handling sign # 1 «Fragile. Caution»,

handling sign # 2«Protect from sunlight», handling sign # 4 «Protect

from moisture», handling sign # 7 «Sealed package», handling sign #

11 «Upper side» and handling sign # 22 «Limited number of stack

layers» [26]

14.7 Air

Transportation

Information about the hazard during air transportation is applied in

accordance with cargo transportation rules applying to a particular

mode of transportation.

Enterprise emergency cards (unnumbered) regarding motorway and

river transportation.

Emergency card F-A, S-F regarding sea transportation [27].

15. REGULATORY INFORMATION.

15.1 National legislation

15.1.1 Laws of the

Russian Federation

«On engineering regulation»

«On environmental protection»

«On public sanitary and epidemiological welfare»

15.1.2 Regulatory

documents on human

and environmental

protection

requirements

«Unified sanitary, epidemiological and hygienic requirements for

commodities subjected to sanitary and epidemiological supervision

(monitoring)» (approved on May 28, 2010, # 299)

16 OTHER INFORMATION

16.1 Information about

revision (reissuance) of the

safety data sheet

This safety data sheet was initially developed in

accordance with the requirements of GOST 30333-2007

[30,31].

16.2 List of data sources used for preparing this safety data sheet

1. TU 2332-003-15259672-2016 Paint additive «Foraflex»

2. GN 2.2.5 1313-03 Maximum permissible concentrations (MPC/RSEL) of hazardous substances in

the work area air.

3. Globally Harmonized System of Classification and Labelling of Chemicals (GHS)

4. GOST 31340-2013 Labelling of chemicals. General requirements

5. Data of the ECHA (European Chemicals Agency) information system. [Electronic source]: Access

mode: http://echa.europa.eu/

6. On-line hazardous substances database “Automated Distributed Information Retrieval System”.

[Electronic source]: Access mode: http://www.rpohv.ru/arips.

http://echa.europa.eu/

http://www.rpohv.ru/arips


7. Information card of potentially hazardous chemical and biological substance

8. Register of Potentially Hazardous Chemical and Biological Substances, rev. 1 and 2.

Dimethylbenzene (isomer mixture). Stare Registration Certificate, series ВТ # 000525 dated March

26, 2015.

9. GOST 12.1.044-89 (ISO 4589-84) with rev. 1 Оccupational safety standards system. Fire and

explosion hazard of substances and materials. Nomenclature of indices and methods of their

determination

10. A.Ya. Korolchenko Fire and explosion hazard of substances and materials and their firefighting

media. Handbook published in 2 parts. – Moscow: Association «Pozhnauka», 2000, 2004;

11. Safety rules and procedure for recovering from accidents related to dangerous goods during their

railway transportation (Novosibirsk: Novosibirsk Institute of Railway Transport Engineers, 1997).

Emergency cards regarding dangerous goods transported by railways of the CIS, Latvian

Republic, Lithuanian Republic and Estonian Republic (Moscow: Transport, 2000, revised with

amendments and additions dated November 21, 2008 and May 22, 2009; revised protocols dated

May 14, 2010; October 21, 2010; October 29, 2011; May 18, 2012; and October 17, 2012);

Emergency card # 305.

12. GOST 12.1.005-88 «General sanitary requirements for working zone air»

13. GOST 12.4.021-75 «Ventilation systems. General requirements»

14. Occupational safety procedures for analytical laboratories. Rules of handling highly inflammable

liquids.

15. Sanitary Rules and Regulations «SanPiN 2.1.7.132203 Hygienic requirements for disposal and

decontamination of production and consumption wastes»

16. SanPiN 2.1.6.1032-01 “Hygienic requirements for assuring atmospheric air quality in the

inhabited areas” (approved by the Chief State Medical Officer of the Russian Federation on May

17, 2001)

17. Sanitary Rules and Regulations «SanPiN 2.1.7.132203 Hygienic requirements for disposal and

decontamination of production and consumption wastes»

18. GOST 17269 Combination chemical cartridge and mechanical filter respirators РУ-60м and РУ-

60му

19. GOST 5375-79 Rubber moulded boots.

20. Data of the eChemPortal. [Electronic source]: Access mode: http://echemportal.org/

21. MPC/RSEL of polluting substances in an atmospheric air of inhabited areas. GN 2.1.6.1338-

03/2.1.6.2309-07. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation,

2003, 2008;

22. MPC/RPL of in-water chemical substances in the utility and drinking/cultural and domestic water

bodies. GN 2.1.5.1315-03/GN 2.1.5.2307-07.

23. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation, 2003, 2008;

24. MPC/RPL of in-soil chemical substances. GN 2.1.7.2041-06/GN 2.1.7.2511-09.

25. Hygienic standards. – Moscow: Ministry of Healthcare of the Russian Federation, 2006, 2009;

26. Water quality standards for fishery water facilities, including standards on maximum permissible

concentrations of in-water hazardous substances in the fishery water facilities. Approved by the

Order # 20 of the Federal Fishery Agency dated January 18, 2010;

27. Recommendations on transport of dangerous good. Model regulations. 17th revised edition. The

United Nations Organization, New-York and Geneva, 2011;

28. GOST 19433-88 with rev. 1 Dangerous goods. Classification and marking – Moscow: standard

publishing office, 1988;

http://echemportal.org/


29. GOST 14192-96 with rev. 1-3 Marking of cargoes – Moscow: standard publishing office

30. International Maritime Dangerous Goods Code. IMDG Code. 2006 edition. – C – published by the

Closed Joint Stock Company “Central Scientific Research Design Institute of Marine Fleet”, 2007

31. Montreal Protocol on Substances that Deplete the Ozone Layer dated September 16, 1987.

32. Stockholm Convention on Persistent Organic Pollutants dated May 22, 2001

33. GOST 30333-2007 «Chemical production safety passport. General requirements»

34. Methodological recommendations for preparing and issuing substance (material) safety data sheet.

– Moscow: All-Russian Scientific Research Center for Standardization, Notification and

Certification of Raw Materials, Materials and Substances of the Committee for Standardization,

Metrology and Certification of the Russian Federation, 1995.

Documents

Company address; Mietitura AS, Paal Bergs vei 42, 1348 ... · (GOST 12.1.007-76) and GSH According to GOST 12.1.007, the product is classified as moderately hazardous one in terms