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Breakthrough TechnologiesBreakthrough TechnologiesFor Downstream Oil IndustryFor Downstream Oil Industry
Co
nte
nts
Co
nte
nts 1. IndianOil R&D
2. Breakthrough Technologies
Alternative Energy- Biofuels- Hydrogen-CNG- CTL / Gasification- Shale Oil
Biotechnology
Polymers & Petrochemicals
TechnicalServices
Refinery Technology- FCC/HD - Catalyst- Pipelines (iPIG)
Lubricant
Technology
Nanotechnology
Fuel Additives
IndianOil-R&D
• 52 Pilot Plants
• 61 Research and Technology Partners
• 332 Patents filed till date
• 200 Effective Patents
• 231 Scientists
IndianOil-R&D At a Glance
IISc
BARC
DCE
NCCRIITM
IndianOil-R&DIndianOil-R&D COLLABORATIVE RESEARCHCOLLABORATIVE RESEARCH
IITD
Co
nte
nts
Co
nte
nts 1. IndianOil R&D
2. Breakthrough Technologies
Indmax
• Indadept•Kero HDT
Food Grade Hexane
IndianOilR&D
TECHNOLOGY BASKETTECHNOLOGY BASKET
Catalyst
Sweetening Process CFC
• Delayed Coking• Indalin
• DHDT• Isom
Needle Coke
Indmax Technology- Resid to LPG, Light Olefins & High Octane Gasoline
Technology demonstrated in 2003Can process wide variety of feedstocks including Atmospheric Residue and Vacuum Residue with CCR upto 11 wt%
High flexibility to produce LPG, Gasoline and diesel.
Employs proprietary catalyst formulationTypical product yields
LPG 35-50 wt% (Propylene 45-50wt% in LPG) Gasoline 20-40 wt% (High octane 98+) Diesel 15-25 wt%
INDMAX unit at GR (100,000 TPA)
BRPL (0.74)
Paradip (4.0)
INDMAX
Guwahati
(0.1)
Worldwide licensing through Lummus Technology Inc., USA
Proposals submitted to various refineries globally– Takreer, Ras Tanura, Idemitsu, Japan, OMV, Austria (Aug’08), PTTAR, Thailand (Sep’08)
Digboi (0.1)
Polymer Grade Hexane (PGH) /Food Grade Hexane (FGH)
Joint Technology Licensing with EIL
28,000 TPA Unit operational at Gujarat Refinery
1 Unit (20,000 TPA) licensed to Bhatinda Refinery
PGH and FGH from PGH and FGH from paraffinic Naphtha and paraffinic Naphtha and raffinate from Aromatic raffinate from Aromatic Extraction UnitExtraction Unit
Benzene Reduction Benzene Reduction
Feed : 1.3-4 %Feed : 1.3-4 %
Product : < 100 ppmProduct : < 100 ppm
11
DHDT Technology
• Can upgrade straight run as well as cracked diesel
streams • Sulphur reduction from ~1.8% to less than 50/ 10 ppm
• Cetane improvement by 7-10 units
• Proprietary catalyst
• Joint licensing with Engineers India Ltd.
• 1.2 MMTPA unit under construction at Bongaigaon
Refinery. Commissioning in Mar, 2010
• 5.0 MMTPA unit under implementation at Paradip
Refinery based on process data input from IOC R&D
12
INDAdept ProcessAdsorptive Deep desulphurisation
• Only novel adsorptive, low
cost, efficient deep desulphurisation technology for both Gasoline and Diesel
• Proprietary adsorbent in hydrogen environment
• Two reactors operated in
swing mode of adsorption and regeneration
Adsorption Regeneration
H2
AirN2
Diesel
1 2
13
INDAdept Process
INDAdeptD
• S reduction from 500 to < 10 ppm• No change in cetane & other properties• H2 consumption 0.1 wt% only
INDAdeptG
• S reduction from 1000 to < 10 ppm• RON reduction of ~ 2 units• H2 consumption 0.2 wt% • Suitable for treating Coker/ FCC gasoline• Employs single reaction step
Category – Technical Development “Hydro-Processing Technology for Green Fuels
World Petroleum Congress Award
Chairman, IOCL Receiving the Award from King of Spain: WPC 2008
INDALIN+ Value addition from Naphtha/Condensate
– 50-55% LPG with <3% olefins meeting Auto Grade spec.
– 17-34% High Octane Gasoline (95+) with 95% Sulphur reduction
– 25-30% BTX in gasoline– Can also handle gas oil range feed stocks– No external hydrogen supply and feed
desulfurization– Proprietary catalyst– Process developed for upgrading
condensate to Propylene/ Ethylene / LPG for Saudi Aramco. Propylene yield ~18% on feed.
Delayed Coker
• Joint Licensing with EIL
Needle Coke Commercialized at GR in 2003
Licensed to BGR in 2003 & NRL in 2007
Value addition ~ $700-800 per MT of Needle Coke
Light Naphtha Isomerisation•Joint licensing with EIL•Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010
Other TechnologiesOther Technologies
Light Naphtha Isomerisation•Joint licensing with EIL•Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010
Other TechnologiesOther Technologies
FCC catalyst and additive technology (i-Max series) for
LPG & Propylene enhancement
• ZSM-5 additives (i-MAX, i-MAX Super, i-MAX Supreme
and i-MAX Ultra)- Used in IOC and non-IOC refineries in
India
• Propylene selective ZSM-5 additive
• Metal Passivator additive for RFCC units
FCC & RFCC Catalysts & Additives
DHDT Catalyst
Commercial demonstration of INDICAT-DH-IV
• Demonstrated at CPCL in Jun, 09
• Consistent performance with Diesel meeting Euro-IV/V
quality
• 88- 90% Desulphurisation in VGO mode
• Delta Diesel Cetane (Product- Feed) of 7 units under 55
Kg/cm2g
• FCC & RFCC (FCC MOD)• Hydrocracker (HC MOD)• CRU (REF MOD)• Diesel-hydrodesulphurisation (DHDS-MOD)• Delayed Coker • Hydrogen Generation Unit
Used for Troubleshooting, Optimization, Process design, catalyst evaluation and Technology development
PROCESS SIMULATORSPROCESS SIMULATORS
TECHNICAL SOLUTIONSTECHNICAL SOLUTIONS
• Right Fit Technology Selection & Licensing
• Revamp of Process Units• Catalyst Management
– FCC/Hydroprocessing– Catalyst Selection– Catalyst Health Monitoring– Remaining Life Prediction
• Process Optimisation• Troubleshooting• Static Equipment Inspection Services• Unit Turnaround Management
• SERVO-LI Lubricity improver for diesel – Excellent Lubricity Performance– Biodegradable source– Good Storage Stability
• SERVO-AO : for gasoline – Excellent Oxidation Stability– High Storage Life– Minimum Treat Cost
• MFA for diesel – High Performance– Component in Premium Diesel
FUEL ADDITIVESFUEL ADDITIVES
BioremediationOiliVorous-S
Oily sludge site before treatment
Oily sludge site after treatment
•Bio-Process for bioremediation of oily sludge using OiliVorous-S bacteria.
•In use at refineries, marketing & pipeline installations at both IOC & Non-IOC locations since 1994.
•Bioremediation carried out both on sea and on-shore.
•Good results obtained on sea using bacteria, especially designed to weather high salt concentration.
Before treatment After treatment
Bioremediation of oil contaminated water at Duliajan
(Assam)
BioremediationOiliVorous-S
Automobile Industry
Textile
Chemical
Railways
CementAviation
Defence
Steel
LubricantTechnology
LUBRICANTS LUBRICANTS The TECHNOLOGY BASKETThe TECHNOLOGY BASKET
SERVO Lubricants Covering:•Automotive oils
• Rail Road Oil • Marine Oil• Industrial lubricants • Metal Working oils • Jute Batching Oils• Rubber Process oils • Agro spray oils • High Performance Greases• Synthetic Lubricants
More than 4000 formulations accounting for
~ 800 commercial grades
With strong R&D backup, SERVO holds 38% National Lube Business
About 200 New and Revised formulations
every year
• High performance engine oils meeting latest
API, ACEA, JIS and OEM customized
specifications
• Gas Engine Oils
• Energy efficient, long life industrial lubricants
& greases
• Synthetic compressor, gear, specialty
lubricants
• NSF listed food grade lubricants & greases
• Biodegradable lubricants
LUBRICANTS LUBRICANTS TECHNOLOGY BASKETTECHNOLOGY BASKET
Marine Oils
Servo RR 606MGFirst ever Multi-grade RR Oil in India
Indian Railways saved
over $ 200 million since 2000
LUBRICANTS LUBRICANTS RAILROAD OILRAILROAD OIL
AFRICA 2008• Total Energy Consumption: 453 Mmtoe (4% of world
consumption)
• Total Proven Oil Reserves: 125.6 Billion barrels (10% of world reserves)
• Crude Oil Production: 10.3 million bopd (12.5% of world oil production)
• Total Oil Consumption: 2.9 million bopd (3.4% of world consumption)
• Total Refining Capacity: 3.2 million bopd ( 3.65% of world refining capacity)
AFRICA 2008
Th bpd
0
200
400
600
800
1000
1200
1400
LT Dist MD Dist FO Others
‘000
bpd 666
1232
429554
0
10
20
30
40
50
60
70
80
0
5
10
15
20
25
30
35
AFRICA 2030
Product Deficit Product Surplus
LP
G
MS
Je
tKe
ro
H
SD
Oth
ers
T
ota
l
5
24
3
38
1
71
Na
ph
tha
F
O
To
tal
11
25
36
Figs in MMTPA
Net Product Deficit:35 MMTPA
33
Diesel Quality worldwideDiesel Quality worldwide
Our Offering
Novel Technologies, Technological Solutions & Technical Services for :– Refinery Revamp/ Modernization– Setting up Green Field Refineries, and Installations,– Efficiency , Productivity & Profitability Improvement,
Energy Conservation etc
– Value Addition – Product Quality Improvement– Reliability Enhancement– Product, Crude Oil & Gas Pipleines – Environment Protection– Collaborative R&D
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