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LECTURE 1
Ionic Bonding
IB Chemistry Power Points
Topic 4
Bonding
www.pedagogics.ca
STRUCTURE AND BONDING
Key Concept:The physical properties of a substance (such as hardness, density, melting point and conductivity) depend on the structure of the substance. Bonding determines arrangement of particles and therefore, the type of structure. Basic theory – things you should know
1. The noble gases (He, Ne, Ar, Kr, Xe and Rn) are in Group VIII, they are all relatively inert meaning they do not react and bond like other elements.
2. We can conclude that noble gas electron configuration appears to confer stability. All noble gases have just filled their ‘outer shell’ of electrons
3. Other elements have a tendency to obtain the same electron arrangement (a full outer shell of valence electrons). Obtaining this electron arrangement is accomplished by different methods of chemical bonding.
4. The type of bonding depends on an element’s position in the periodic table
TYPES OF BONDING
CHEMICAL BONDS....are strong intramolecular bonds that hold atoms together in molecules, ionic solids and metals. These bonds are broken and made in chemical reactions. ionic
covalent dative covalent (or co-
ordinate) metallic
PHYSICAL BONDS....are intermolecular forces that exist between two or more separate molecules. These are the attractions involved in physical changes.
van der Waals‘ forces - weakest dipole-dipole interactions
hydrogen bonds - strongest
PART 1: CHEMICAL BONDS
THE IONIC BOND
Ionic bonds are formed between elements whose atoms tend to “lose” electrons to gain the nearest noble gas electronic configuration and those which tend to “gain” electrons. The electrons are transferred from one atom to the other.
Sodium Chloride
Na ——> Na+ + e¯ and Cl + e¯ ——> Cl¯
THE IONIC BOND
Ionic bonds are formed between elements whose atoms tend to “lose” electrons to gain the nearest noble gas electronic configuration and those which tend to “gain” electrons. The electrons are transferred from one atom to the other.
Sodium Chloride
Na ——> Na+ + e¯ and Cl + e¯ ——> Cl¯
2,8,1 2,8 2,8,7 2,8,8
THE IONIC BOND
Ionic bonds are formed between elements whose atoms tend to “lose” electrons to gain the nearest noble gas electronic configuration and those which tend to “gain” electrons. The electrons are transferred from one atom to the other.
Sodium Chloride
Na ——> Na+ + e¯ and Cl + e¯ ——> Cl¯
2,8,1 2,8 2,8,7 2,8,8
or 1s2 2s2 2p6 3s1 1s2 2s2 2p6 1s2 2s2 2p6 3s2 3p5 1s2 2s2 2p6 3s2 3p6
HL only responsible for s,p,d,f electron configurations
THE IONIC BOND
Ionic bonds are formed between elements whose atoms tend to “lose” electrons to gain the nearest noble gas electronic configuration and those which tend to “gain” electrons. The electrons are transferred from one atom to the other.
Sodium Chloride
Na ——> Na+ + e¯ and Cl + e¯ ——> Cl¯
2,8,1 2,8 2,8,7 2,8,8
or 1s2 2s2 2p6 3s1 1s2 2s2 2p6 1s2 2s2 2p6 3s2 3p5 1s2 2s2 2p6 3s2 3p6both species end up with the electronic configuration of the nearest
noble gas
the resulting ions are held together in a crystal lattice by electrostatic attraction.
SODIUM CHLORIDE
Cl
SODIUM ATOM2,8,1
Na
CHLORINE ATOM2,8,7
SODIUM CHLORIDE
SODIUM ION2,8
CHLORIDE ION2,8,8
both species now have ‘full’ outer shells; ie they have the electronic configuration of a noble gas
Na+
Cl
ELECTRON
TRANSFER
Mg ——> Mg2+ + 2e¯ and 2Cl + 2e¯ ——> 2 Cl¯
Mg
Cl
Cl
e¯
e¯
THE IONIC BOND
FORMATION OF MAGNESIUM CHLORIDE
MAGNESIUM CHLORIDE
Cl
MAGNESIUM ATOM2,8,2
MgCHLORINE ATOMS
2,8,7
Cl
MAGNESIUM CHLORIDE
Cl
MAGNESIUM ION2,8
MgCHLORIDE IONS
2,8,8
Cl
2+
• also known as cations; they are smaller than the original atom.
• formed when electrons are removed from atoms.• the energy associated with the process is known as the
ionisation energy
Recall: 1st IONISATION ENERGY (1st I.E.)The energy required to remove one mole of electrons (to infinity) from the one mole of gaseous atoms to form one mole of gaseous positive ions.
e.g. Na(g) ——> Na+(g) + e¯ or Mg(g) ——> Mg+(g) + e¯
Other points (HL topic 12)
Successive IE’s (2nd , 3rd , etc) get larger as the proton:electron ratio increases.
Large jumps in value occur when electrons are removed from shells nearer the nucleus because there is less shielding and more energy is required to overcome the attraction.
If the I.E. values are very high, covalent bonding will be favoured (e.g. beryllium).
THE FORMATION OF POSITIVE IONS
• known as anions• are slightly larger than the neutral atom - electron repulsion
in outer shell• formed when electrons are added to atoms• energy is released as the nucleus pulls in an electron• this energy is the electron affinity.
ELECTRON AFFINITYThe energy change when one mole of gaseous atoms acquires one mole of electrons (from infinity) to form one mole of gaseous negative ion
e.g. Cl(g) + e¯ ——> Cl¯(g) and O(g) + e¯ ——> O¯(g)
The greater the effective nuclear charge (E.N.C.)of a species, the easier an electron is attracted.
THE FORMATION OF NEGATIVE IONS
Ions form from a tendency toward a lower energy, stable, noble gas electron configuration
Transition metals have more complex electron arrangements (d – subshell HL material) thus can form more than one ion.
IONIC COMPOUNDS - CRYSTAL LATTICE STRUCTURE
Cl-
Chloride ion
Na+
Sodium ion
Oppositely charged ions held in a regular3-dimensional lattice by electrostatic attraction
The arrangement of ions in a crystal lattice depends on the relative sizes of the ions
The Na+ ion is small enough relative to a Cl¯ ion to fit in the spaces so that both ions occur in every plane.
Each Na+ is surrounded by 6 Cl¯and each Cl¯ is surrounded by 6 Na+
Oppositely charged ions held in a regular 3-dimensional lattice by electrostatic attraction:
The arrangement of ions in a crystal lattice depends on the relative sizes of the ions
Physical properties of ionic compounds
Melting pointvery high A large amount of energy must be put in to overcome the
strong electrostatic attractions and separate the ions.
StrengthVery brittle Any dislocation leads to the layers moving and similar
ions being adjacent. The repulsion splits the crystal.
Electrical don’t conduct when solid - ions held strongly in the lattice
conduct when molten or in aqueous solution - the ions
become mobile and conduction takes place.
Solubility Insoluble in non-polar solvents but soluble in water
Water is a polar solvent and stabilises the separated ions.
IONIC COMPOUNDS - ELECTRICAL PROPERTIES
SOLID IONIC COMPOUNDS DO NOT CONDUCT ELECTRICITY
Na+
Cl- Na+
Cl-
Na+
Cl-Na+
Cl-
Na+
Cl- Na+
Cl-
IONS ARE HELD STRONGLY TOGETHER
+ IONS CAN’T MOVE
- IONS CAN’T MOVE
MOLTEN IONIC COMPOUNDS DO
CONDUCT ELECTRICITY
Na+
Cl-
Na+
Cl-
Na+
Cl-
Na+Cl-
IONS HAVE MORE FREEDOM IN A LIQUID SO CAN MOVE TO THE ELECTRODES
SOLUTIONS OF IONIC COMPOUNDS
IN WATER DO CONDUCT
ELECTRICITY
DISSOLVING AN IONIC COMPOUND IN WATER BREAKS UP THE STRUCTURE SO IONS ARE FREE TO MOVE TO THE ELECTRODES
Many ionic compounds are soluble in water - dissolving