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Wilson, Tabatha
From: Reiber, LorettaSent: Tuesday, May 13, 2014 8:29 AMTo: Wilson, TabathaSubject: FW: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016Attachments: 0537_001.pdf; RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN
70-00016; 644597.pdf
Can you please put the attachments and this e‐mail on the web and Zylab? Thanks.
From: Tom Hammons [mailto:[email protected]] Sent: Friday, May 02, 2014 1:15 PM To: Reiber, Loretta; Suel, Kevin Cc: Chuck Hammock; Mitch Colvin Subject: FW: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Loretta, Attached are the dioxin results, I had previously sent them on 3/25. I spoke witht eh lab and the pesticide RL was a typo. Attached is the corrected report from the lab. Thanks, Tom Hammons
From: Tom Hammons Sent: Tuesday, March 25, 2014 5:47 PM To: Reiber, Loretta; Suel, Kevin Cc: Chuck Hammock; Mitch Colvin Subject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Loretta, Thank you for the congratulations. After receiving your email I reviewed what was submitted and realized that I inadvertently left out the dioxin results. These results were from the Summit lab and were in the attachments of the complete report. These results are included in the attachment that accompanies this email. If I need to resubmit the complete report, let me know. I attempted to contact you this afternoon concerning the MQL’s of some of the pesticides. After speaking with Mr. Suel, I reviewed some of our previous PPS data and I see that some of the MQL’s appear to be incorrect. I will contact the lab and attempt to clear this up. Thanks Tom Hammons Lion Oil Company
From: Reiber, Loretta [mailto:[email protected]] Sent: Monday, March 24, 2014 3:14 PM
2
To: Tom Hammons; Suel, Kevin Cc: Chuck Hammock; Mitch Colvin Subject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Tom, I have looked at the PPS information that you e‐mailed to me. I didn’t receive any information regarding dioxins. Also, several of the pesticides on page 2 of the lab report were listed as having an MQL of 1,000 µg/l. Since that is much higher than what is required, I’m questioning if the units are incorrect. Can you please look into the matter? Congratulations on your new baby! Thanks. Loretta
From: Tom Hammons [mailto:[email protected]] Sent: Friday, March 21, 2014 5:26 PM To: Suel, Kevin; Reiber, Loretta Cc: Chuck Hammock; Mitch Colvin Subject: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Pleased see the attached PPS for the Lion Oil Refinery 010 Outfall. A hard copy is also en route via Fed Ex. If you have any questions, feel free to give me a call at 870‐864‐1449. Thanks Tom Hammons Lion Oil Company
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Wilson, Tabatha
From: Reiber, LorettaSent: Monday, April 28, 2014 1:36 PMTo: Tom Hammons; Suel, KevinCc: Chuck Hammock; Mitch ColvinSubject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016
I have not received the dioxin results or the information regarding the pesticides. Was it submitted and I just haven’t seen it? If it has not been submitted, please let me know ASAP when I can expect to see it. Loretta Reiber, P.E. Engineer, NPDES Permits
From: Reiber, Loretta Sent: Wednesday, March 26, 2014 7:46 AM To: 'Tom Hammons'; Suel, Kevin Cc: Chuck Hammock; Mitch Colvin Subject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Just submit the dioxin results. We don’t need the whole report again. I just figured you were sleep deprived when they weren’t included After you contact the lab regarding the pesticides, please let me know what they have to say. Thanks.
From: Tom Hammons [mailto:[email protected]] Sent: Tuesday, March 25, 2014 5:47 PM To: Reiber, Loretta; Suel, Kevin Cc: Chuck Hammock; Mitch Colvin Subject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Loretta, Thank you for the congratulations. After receiving your email I reviewed what was submitted and realized that I inadvertently left out the dioxin results. These results were from the Summit lab and were in the attachments of the complete report. These results are included in the attachment that accompanies this email. If I need to resubmit the complete report, let me know. I attempted to contact you this afternoon concerning the MQL’s of some of the pesticides. After speaking with Mr. Suel, I reviewed some of our previous PPS data and I see that some of the MQL’s appear to be incorrect. I will contact the lab and attempt to clear this up. Thanks Tom Hammons Lion Oil Company
From: Reiber, Loretta [mailto:[email protected]] Sent: Monday, March 24, 2014 3:14 PM To: Tom Hammons; Suel, Kevin
2
Cc: Chuck Hammock; Mitch Colvin Subject: RE: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Tom, I have looked at the PPS information that you e‐mailed to me. I didn’t receive any information regarding dioxins. Also, several of the pesticides on page 2 of the lab report were listed as having an MQL of 1,000 µg/l. Since that is much higher than what is required, I’m questioning if the units are incorrect. Can you please look into the matter? Congratulations on your new baby! Thanks. Loretta
From: Tom Hammons [mailto:[email protected]] Sent: Friday, March 21, 2014 5:26 PM To: Suel, Kevin; Reiber, Loretta Cc: Chuck Hammock; Mitch Colvin Subject: Lion Oil Company, NPDES Permit Number AR0000647, AFIN 70-00016 Pleased see the attached PPS for the Lion Oil Refinery 010 Outfall. A hard copy is also en route via Fed Ex. If you have any questions, feel free to give me a call at 870‐864‐1449. Thanks Tom Hammons Lion Oil Company
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 1 of 7
Report To
Mitch Colvin Tom Hammons
Lion Oil
P. O. Box 7005
1000 McHenry
El Dorado, AR 71731-7005
644597LIN5-LAccount Project
Results
BottleCASFlagsRLUnitsResultsParameter
1280758 Priority Pollutant Scan
02/26/2014 09:00:00T HammonsCollected by:
02/26/2014Received:
Liquid Aqueous Affiliation: Lion Oil
Prepared: 03/07/2014 10:00:00
EPA 1613 -- Subcontr 03/07/2014 10:00:00SKL QCgroupAnalyzed
See Attached SEMO2378-tetrachlorodibenzo-p-dioxin
Prepared: 557089 02/27/2014 09:45:00
EPA 200.8 5.4 02/27/2014 15:19:00WOB QCgroup 557158Analyzed
0.000873 mg/L J0.001 7440-36-0Antimony 23N
0.00464 mg/L 0.0005 7440-38-2Arsenic 23N
<0.0005 mg/L 0.0005 7440-41-7Beryllium 23N
<0.0005 mg/L 0.0005 7440-43-9Cadmium 23N
0.00203 mg/L 0.0005 7440-47-3Chromium 23N
0.00515 mg/L 0.001 7440-50-8Copper 23N
0.00371 mg/L 0.0005 7439-92-1Lead 23N
0.00453 mg/L 0.001 7440-02-0Nickel 23N
0.00733 mg/L 0.001 7782-49-2Selenium 23N
<0.0005 mg/L 0.0005 7440-22-4Silver 23N
0.00032 mg/L J0.0005 7440-28-0Thallium 23N
EPA 200.8 5.4 02/28/2014 13:05:00WOB QCgroup 557309Analyzed
0.0527 mg/L 0.005 7440-66-6Zinc 23N
Prepared: 557069 02/27/2014 10:15:00
EPA 245.1 3 02/28/2014 10:15:00WOB QCgroup 557243Analyzed
0.240 ug/L 0.200 7439-97-6Mercury 20N
Prepared: 557067 02/27/2014 12:00:00
EPA 420.4 1 02/28/2014 11:12:43MDD QCgroup 557249Analyzed
0.0044 mg/L J0.005Phenolics, Total Recoverable 25N
Prepared: 557175 02/27/2014 09:00:00
EPA 608 02/28/2014 13:06:00KJS QCgroup 557283Analyzed
<0.200 ug/L 0.200 12674-11-2PCB-1016 26N
<0.200 ug/L 0.200 11104-28-2PCB-1221 26N
<0.200 ug/L 0.200 11141-16-5PCB-1232 26N
<0.200 ug/L 0.200 53469-21-9PCB-1242 26N
<0.200 ug/L 0.200 12672-29-6PCB-1248 26N
<0.200 ug/L 0.200 11097-69-1PCB-1254 26N
<0.200 ug/L 0.200 11096-82-5PCB-1260 26N
<0.010 ug/L 0.010 309-00-2Aldrin 26N
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 1 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 2 of 7
Results
BottleCASFlagsRLUnitsResultsParameter
1280758 Priority Pollutant Scan
02/26/2014 09:00:00T HammonsCollected by:
02/26/2014Received:
Liquid Aqueous Affiliation: Lion Oil
EPA 608 02/28/2014 13:06:00KJS QCgroup 557285Analyzed
<0.0253 ug/L 0.0253 319-84-6Alpha-BHC(hexachlorocyclohexane) 26N
<0.0101 ug/L 0.0101 319-85-7Beta-BHC(hexachlorocyclohexane) 26N
<0.0101 ug/L 0.0101 319-86-8Delta-BHC(hexachlorocyclohexane) 26N
0.0640 ug/L 0.0101 58-89-9Gamma-BHC(Lindane) 26N
<0.0101 ug/L 0.0101 12789-0306Chlordane 26N
<0.0253 ug/L 0.0253 72-54-84,4-DDD 26N
<0.0253 ug/L 0.0253 72-55-94,4-DDE 26N
<0.0101 ug/L 0.0101 50-29-34,4-DDT 26N
<0.0101 ug/L 0.0101 60-57-1Dieldrin 26N
<0.010 ug/L 0.010 959-98-8Endosulfan I (alpha) 26N
<0.0101 ug/L 0.0101 33213-65-9Endosulfan II (beta) 26N
<0.0101 ug/L 0.0101 1031-07-8Endosulfan sulfate 26N
<0.0101 ug/L 0.0101 72-20-8Endrin 26N
<0.0253 ug/L 0.0253 7421-93-4Endrin aldehyde 26N
<0.010 ug/L 0.010 76-44-8Heptachlor 26
<0.010 ug/L 0.010 1024-57-3Heptachlor epoxide 26N
<0.0101 ug/L 0.0101 8001-35-2Toxaphene 26N
Prepared: 557195 02/27/2014 09:00:00
EPA 614 02/28/2014 13:37:00KJS QCgroup 557295Analyzed
<0.0404 ug/L 0.0404 2921-88-2Chlorpyrifos 27N
Prepared: 557275 02/28/2014 12:50:00
EPA 624 02/28/2014 12:50:00AAC QCgroup 557275Analyzed
<1.00 ug/L 1.00 71-43-2Benzene 09N
<1.00 ug/L 1.00 75-27-4Bromodichloromethane 09N
<1.00 ug/L 1.00 75-25-2Bromoform 09N
<1.00 ug/L 1.00 74-83-9Bromomethane (Methyl Bromi 09N
<1.00 ug/L 1.00 56-23-5Carbon Tetrachloride 09N
<1.00 ug/L 1.00 108-90-7Chlorobenzene 09N
<1.00 ug/L 1.00 75-00-3Chloroethane 09N
0.790 ug/L J1.00 67-66-3Chloroform 09N
<1.00 ug/L 1.00 74-87-3Chloromethane 09N
<1.00 ug/L 1.00 124-48- 1Dibromochloromethane 09N
<1.00 ug/L 1.00 75-34-31,1-Dichloroethane 09N
<1.00 ug/L 1.00 107-06-21,2-Dichloroethane 09N
<1.00 ug/L 1.00 156-60-5trans-1,2-Dichloroethene 09N
<1.00 ug/L 1.00 75-35-41,1-Dichloroethylene 09N
<1.00 ug/L 1.00 78-87-51,2-Dichloropropane 09N
<1.00 ug/L 1.00 10061-01-5cis-1,3-Dichloropropene 09N
<1.00 ug/L 1.00 10061-02-6trans-1,3-Dichloropropene 09N
<1.00 ug/L 1.00 100-41-4Ethylbenzene 09N
<1.00 ug/L 1.00 75-09-2Methylene chloride 09N
<1.00 ug/L 1.00 79-34-51,1,2,2-Tetrachloroethane 09N
<1.00 ug/L 1.00 127-18-4Tetrachloroethylene 09N
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 2 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 3 of 7
Results
BottleCASFlagsRLUnitsResultsParameter
1280758 Priority Pollutant Scan
02/26/2014 09:00:00T HammonsCollected by:
02/26/2014Received:
Liquid Aqueous Affiliation: Lion Oil
EPA 624 02/28/2014 12:50:00AAC QCgroup 557275Analyzed
<1.00 ug/L 1.00 108-88-3Toluene 09N
<1.00 ug/L 1.00 71-55-61,1,1-Trichloroethane 09N
<1.00 ug/L 1.00 79-00-51,1,2-Trichloroethane 09N
<1.00 ug/L 1.00 79-01-6Trichloroethylene 09N
<1.00 ug/L 1.00 75-01-4Vinyl chloride 09N
Prepared: 557311 02/28/2014 13:15:00
EPA 624 02/28/2014 13:15:00AAC QCgroup 557311Analyzed
<1.00 ug/L P1.00 107-02-8Acrolein 13N
<1.00 ug/L 1.00 107-13-1Acrylonitrile 13N
Prepared: 557312 02/28/2014 13:15:00
EPA 624 02/28/2014 13:15:00AAC QCgroup 557312Analyzed
<1.00 ug/L 1.00 110-75-82-Chloroethylvinyl ether 13N
Prepared: 557103 02/27/2014 07:50:00
EPA 625 02/28/2014 12:25:00KJS QCgroup 557270Analyzed
<1.01 ug/L 1.01 83-32-9Acenaphthene 24N
<1.01 ug/L 1.01 208-96-8Acenaphthylene 24N
<1.01 ug/L 1.01 120-12-7Anthracene 24N
<1.52 ug/L 1.52 92-87-5Benzidine 24N
<1.01 ug/L 1.01 56-55-3Benzo(a)anthracene 24N
<1.01 ug/L 1.01 50-32-8Benzo(a)pyrene 24N
<1.01 ug/L 1.01 205-99-2Benzo(b)fluoranthene 24N
<1.01 ug/L 1.01 191-24-2Benzo(ghi)perylene 24N
<1.01 ug/L 1.01 207-08-9Benzo(k)fluoranthene 24N
<1.01 ug/L 1.01 85-68-7Benzyl Butyl phthalate 24N
<1.01 ug/L 1.01 101-55-34-Bromophenyl phenyl ether 24N
12.6 ug/L 1.01 84-74-2Di-n-butylphthalate 24N
<1.01 ug/L 1.01 193-39-5Indeno(1,2,3-cd)pyrene 24N
<1.01 ug/L 1.01 111-91-1Bis(2-chloroethoxy)methane 24N
<1.01 ug/L 1.01 111-44-4Bis(2-chloroethyl)ether 24N
<1.01 ug/L 1.01 39638-32-9Bis(2-chloroisopropyl)ether 24N
<1.01 ug/L 1.01 91-58-72-Chloronaphthalene 24N
<1.01 ug/L 1.01 95-57-82-Chlorophenol 24N
<1.01 ug/L 1.01 7005-72-34-Chlorophenyl phenyl ethe 24N
<1.01 ug/L 1.01 218-01-9Chrysene (Benzo(a)phenanthrene) 24N
<1.01 ug/L 1.01 53-70-3Dibenz(a,h)anthracene 24N
<5.07 ug/L 5.07 541-73-11,3-Dichlorobenzene 24N
<5.07 ug/L 5.07 95-50-11,2-Dichlorobenzene 24N
<5.07 ug/L 5.07 106-46-71,4-Dichlorobenzene 24N
<2.03 ug/L 2.03 91-94-13,3'-Dichlorobenzidine 24N
<1.01 ug/L 1.01 120-83-22,4-Dichlorophenol 24N
<1.01 ug/L 1.01 84-66-2Diethyl phthalate 24N
<1.01 ug/L 1.01 131-11-3Dimethyl phthalate 24N
<1.01 ug/L 1.01 105-67-92,4-Dimethylphenol 24N
<2.03 ug/L 2.03 51-28-52,4-Dinitrophenol 24N
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 3 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 4 of 7
Results
BottleCASFlagsRLUnitsResultsParameter
1280758 Priority Pollutant Scan
02/26/2014 09:00:00T HammonsCollected by:
02/26/2014Received:
Liquid Aqueous Affiliation: Lion Oil
EPA 625 02/28/2014 12:25:00KJS QCgroup 557270Analyzed
<2.03 ug/L 2.03 121-14-22,4-Dinitrotoluene 24N
<2.03 ug/L 2.03 606-20-22,6-Dinitrotoluene 24N
<1.01 ug/L 1.01 122-66-71,2-DPH (as azobenzene) 24N
<1.14 ug/L 1.14 117-81-7Bis(2-ethylhexyl)phthalate 24N
<1.01 ug/L 1.01 206-44-0Fluoranthene(Benzo(j,k)fluorene) 24N
<1.01 ug/L 1.01 86-73-7Fluorene 24N
<1.01 ug/L 1.01 118-74-1Hexachlorobenzene 24N
<1.04 ug/L 1.04 87-68-3Hexachlorobutadiene 24N
<1.01 ug/L 1.01 77-47-4Hexachlorocyclopentadiene 24N
<2.03 ug/L 2.03 67-72-1Hexachloroethane 24N
<1.01 ug/L 1.01 78-59-1Isophorone 24N
<1.01 ug/L 1.01 59-50-7p-Chloro-m-Cresol (4-Chloro-3-me 24N
<2.03 ug/L 2.03 534-52-14,6-Dinitro-2-methylphenol 24N
<1.01 ug/L 1.01 91-20-3Naphthalene 24N
<1.01 ug/L 1.01 98-95-3Nitrobenzene 24N
<1.01 ug/L 1.01 88-75-52-Nitrophenol 24N
<1.01 ug/L 1.01 100-02-74-Nitrophenol 24N
<1.01 ug/L 1.01 62-75-9N-Nitrosodimethylamine 24N
<1.01 ug/L 1.01 86-30-6N-Nitrosodiphenylamine (as DPA 24N
<2.03 ug/L 2.03 117-84-0Di-n-octylphthalate 24N
<5.00 ug/L 5.00 87-86-5Pentachlorophenol 24N
<1.01 ug/L 1.01 85-01-8Phenanthrene 24N
<1.01 ug/L 1.01 108-95-2Phenol 24N
<1.01 ug/L 1.01 621-64-7N-Nitrosodi-n-propylamine 24N
<1.01 ug/L 1.01 129-00-0Pyrene 24N
<1.01 ug/L 1.01 120-82-11,2,4-Trichlorobenzene 24N
<2.03 ug/L 2.03 88-06-22,4,6-Trichlorophenol 24N
Prepared: 557137 02/27/2014 08:45:00
SM 3500-Cr B-2009 02/27/2014 08:45:00PJD QCgroup 557137Analyzed
<3.00 ug/L 3.00 7440-47-3Hexavalent Chromium 01N
Prepared: 557048 02/27/2014 10:50:00
SM 4500-CN¯ E-1999 02/27/2014 17:26:44RSV QCgroup 557212Analyzed
0.00202 mg/L J0.005Cyanide 19N
The above methods that we used are approved for NPDES reporting as listed in 40 CFR 136 Table 1B or Ana-Lab has specific approval from EPA to use
these methods for NPDES reporting.
Sample Preparation
1280758 Priority Pollutant Scan 02/26/2014Received:
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 4 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 5 of 7
Sample Preparation
1280758 Priority Pollutant Scan 02/26/2014Received:
Prepared: 02/26/2014 00:00:00
02/26/2014 00:00:00AAJ QCgroupAnalyzed
7 SUBottle pH 01z
7 SUBottle pH 02z
7 SUBottle pH 03z
7 SUBottle pH 04z
7 SUBottle pH 05z
<2 SUBottle pH 06z
<2 SUBottle pH 07z
>12 SUBottle pH 08z
<1 degreesBottle Temperature on Receipt 01
<1 degreesBottle Temperature on Receipt 02
<1 degreesBottle Temperature on Receipt 03
<1 degreesBottle Temperature on Receipt 04
<1 degreesBottle Temperature on Receipt 05
<1 degreesBottle Temperature on Receipt 06
<1 degreesBottle Temperature on Receipt 07
<1 degreesBottle Temperature on Receipt 08
<1 degreesBottle Temperature on Receipt 09
<1 degreesBottle Temperature on Receipt 10
<1 degreesBottle Temperature on Receipt 11
<1 degreesBottle Temperature on Receipt 12
<1 degreesBottle Temperature on Receipt 13
<1 degreesBottle Temperature on Receipt 14
<1 degreesBottle Temperature on Receipt 15
<1 degreesBottle Temperature on Receipt 16
<1 degreesBottle Temperature on Receipt 17
<1 degreesBottle Temperature on Receipt 18
Prepared: 557089 02/27/2014 09:45:00
EPA 200.2 2.8 02/27/2014 09:45:00TES QCgroup 557089Analyzed
50/50 mlLiquid Metals Digestion 06N
Prepared: 557069 02/27/2014 10:15:00
EPA 245.1 3 02/27/2014 10:15:00PJD QCgroup 557069Analyzed
50/25 mlMercury Liquid Metals Digestion 06N
Prepared: 557067 02/27/2014 12:00:00
EPA 420.4 1 02/27/2014 12:00:00CDB QCgroup 557067Analyzed
50/50 mlPhenol Distillation 07N
Prepared: 557175 02/27/2014 09:00:00
EPA 608 02/28/2014 13:06:00KJS QCgroup 557283Analyzed
Entered 1.00Polychlorinated Biphenyls 26N
Prepared: 557175 02/27/2014 09:00:00
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 5 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 6 of 7
Sample Preparation
1280758 Priority Pollutant Scan 02/26/2014Received:
EPA 614/608/617/1657 02/27/2014 09:00:00DWL QCgroup 557175Analyzed
1/989 mlLiquid-Liquid Extr. W/Hex Ex 04
Prepared: 557195 02/27/2014 09:00:00
EPA 614/608/617/1657 02/27/2014 09:00:00DWL QCgroup 557195Analyzed
1/989 mlSolvent Extraction 04
Prepared: 557175 02/27/2014 09:00:00
EPA Method 608 02/28/2014 13:06:00KJS QCgroup 557285Analyzed
EnteredADEQ ArkansasPesticide Exp. 26z
Prepared: 557195 02/27/2014 09:00:00
EPA Method 614 02/28/2014 13:37:00KJS QCgroup 557295Analyzed
EnteredChlorpyrifos Expansion 27z
Prepared: 557311 02/28/2014 13:15:00
EPA Method 624 02/28/2014 13:15:00AAC QCgroup 557311Analyzed
EnteredAcrolein/Acrylonitrile Exp. 13N
Prepared: 557312 02/28/2014 13:15:00
EPA Method 624 02/28/2014 13:15:00AAC QCgroup 557312Analyzed
EnteredADEQ Arkansas VOA 13z
Prepared: 557103 02/27/2014 07:50:00
EPA Method 625 02/27/2014 07:50:00TRP QCgroup 557103Analyzed
1/986 mlLiquid-Liquid Extraction, BNA 05N
EPA Method 625 02/28/2014 12:25:00KJS QCgroup 557270Analyzed
EnteredADEQ ARKANSAS ABN 24z
Prepared: 557048 02/27/2014 10:50:00
SM 4500-CN¯ E-1999 02/27/2014 10:50:00CRG QCgroup 557048Analyzed
25/50 mlCyanide Distillation 08N
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 6 of 46
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Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected] Owned Integrity Caring Continual Improvement
Results05/01/2014Printed: Page 7 of 7
Qualifiers:
J - Analyte detected below quantitation limit P - Spike recovery outside control limits due to possible matrix
We report results on an 'As Received' or wet basis unless marked 'Dry Weight'. Unless otherwise noted, testing was performed at Ana-lab's
corporate laboratory that holds the following Federal and State certificates: Texas Department of Health Lead Firm Certificate 2110076, US
Department of Agriculture Soil Import Permit S-37592, Texas Commisson on Environmental Quality Drinking Water Laboratory Certificate
TX219, Texas Commission on Environmental Quality NELAP T104704201, Oklahoma Department of Environmental Quality Drinking
Water Certification Lab ID# D9913, EPA Lab Number TX00063, USEPA Approved Perchlorate Testing Lab, Oklahoma Department of
Environmental Quality Laboratory Certificate 8125, Arkansas Department of Environmental Quality Certification #03-070-0, Louisiana
Department of Environmental Quality Laboratory Certification (NELAP, LELAP) #02008, Louisiana Department of Health and Hospitals
Drinking Water (NELAP) # LA030020, US Department of Energy Approved, State of Kansas Department of Health and Environment
Waste Water and Solid/Hazardous Waste Cert. E-10365. The Accredited column designates accreditation by N -- NELAC, or z -- not
covered under NELAC scope of accreditation.
These analytical results relate to the sample tested. This report may NOT be reproduced EXCEPT in FULL without written approval of
Ana-Lab Corp. Unless otherwise specified, these test results meet the requirements of NELAC.
RL is the Reporting Limit (sample specific quantitation limit) and is at or above the Method Detection Limit (MDL). CAS is Chemical
Abstract Service number.
C. H. Whiteside, Ph.D., President
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJRES Created 10/13/2004 v1.2LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 7 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 1 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LIN5 -LAccount Project
Mitch Colvin Tom Hammons
Lion Oil
P. O. Box 7005
1000 McHenry
El Dorado, AR 71731-7005
Report ToWW
644597
SM 4500-CN¯ E-1999Liquid Aqueous 557212
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Cyanide 557048 ND 0.00665 0.020 mg/L 114223662
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Cyanide 0.533 0.500 mg/L 107 90.0 - 110 114223661
Cyanide 0.525 0.500 mg/L 105 90.0 - 110 114223672
Cyanide 0.506 0.500 mg/L 101 90.0 - 110 114223683
Duplicate
Limit%RPDUnitUnknownResultTypeSampleParameter
Cyanide 1279990 Duplicate 0.00974 0.00954 mg/L 2.07 20.0
Cyanide 1280475 Duplicate 0.00582 ND mg/L 4.37 20.0
ICV
FileOutLimits%Recover%UnitsKnownReadingParameter
Cyanide 0.210 0.200 mg/L 105 90.0 - 110 114223660
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Cyanide 557048 0.198 0.200 mg/L 98.8 90.0 - 110 114223663
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Cyanide 557048 0.198 0.199 0.200 90.0 - 110 98.8 99.4 mg/L 0.504 20.0
Mat. Spike
FileLimits %Recovery %UnitsKnownUnknownSpikeSampleParameter
Cyanide 1279990 0.114 0.00954 0.100 mg/L 104 90.0 - 110 114223667
Cyanide 1280475 0.109 ND 0.100 mg/L 103 90.0 - 110 114223670
EPA 420.4 1Liquid Aqueous 557249
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Phenolics, Total Recoverable 557067 ND 0.00377 0.005 mg/L 114224445
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Phenolics, Total Recoverable 0.197 0.200 mg/L 98.5 90.0 - 110 114224444
Phenolics, Total Recoverable 0.192 0.200 mg/L 96.0 90.0 - 110 114224453
Duplicate
Limit%RPDUnitUnknownResultTypeSampleParameter
Phenolics, Total Recoverable 1280241 Duplicate 0.0095 0.0113 mg/L 17.3 20.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 8 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 2 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
ICV
FileOutLimits%Recover%UnitsKnownReadingParameter
Phenolics, Total Recoverable 0.200 0.200 mg/L 100 90.0 - 110 114224443
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Phenolics, Total Recoverable 557067 0.204 0.200 mg/L 102 90.0 - 110 114224446
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Phenolics, Total Recoverable 557067 0.204 0.198 0.200 90.0 - 110 102 99.0 mg/L 2.99 20.0
Mat. Spike
FileLimits %Recovery %UnitsKnownUnknownSpikeSampleParameter
Phenolics, Total Recoverable 1280241 0.216 0.0113 0.200 mg/L 102 90.0 - 110 114224450
SM 3500-Cr B-2009Liquid Aqueous 557137
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Hexavalent Chromium 557137 ND 1.74 3.00 ug/L 114221752
Hexavalent Chromium 557137 ND 1.74 3.00 ug/L 114221760
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Hexavalent Chromium 85.0 80.0 ug/L 106 90.0 - 110 114221753
Hexavalent Chromium 85.0 80.0 ug/L 106 90.0 - 110 114221759
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Hexavalent Chromium 557137 84.8 80.0 ug/L 106 85.0 - 115 114221754
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Hexavalent Chromium 557137 84.8 84.0 80.0 85.0 - 115 106 105 ug/L 0.948 15.0
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Hexavalent Chromium 1280758 83.2 0 ND 80.0 70.0 - 130 104 ug/L 20.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Hexavalent Chromium 1280758 83.2 83.0 ND 80.0 70.0 - 130 104 104 ug/L 0 20.0
EPA 200.8 5.4Liquid Aqueous 557158
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Antimony 557089 ND 0.000399 0.001 mg/L 114222236
Arsenic 557089 ND 0.000193 0.0005 mg/L 114222236
Beryllium 557089 ND 0.00006050.0005 mg/L 114222236
Cadmium 557089 ND 0.000209 0.0005 mg/L 114222236
Chromium 557089 ND 0.000282 0.0005 mg/L 114222236
Copper 557089 ND 0.000425 0.001 mg/L 114222236
Lead 557089 ND 0.000227 0.0005 mg/L 114222236
Nickel 557089 0.000343 0.000264 0.001 mg/L 114222236
Selenium 557089 ND 0.000728 0.001 mg/L 114222236
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 9 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 3 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Silver 557089 ND 0.00006280.0005 mg/L 114222236
Thallium 557089 ND 0.000174 0.0005 mg/L 114222236
Zinc 557089 0.0126 0.00123 0.005 mg/L * 114222236
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Antimony 0.0503 0.05 mg/L 101 90.0 - 110 114222213
Antimony 0.0511 0.05 mg/L 102 90.0 - 110 114222226
Antimony 0.0503 0.05 mg/L 101 90.0 - 110 114222234
Antimony 0.0496 0.05 mg/L 99.2 90.0 - 110 114222242
Antimony 0.0498 0.05 mg/L 99.6 90.0 - 110 114222253
Antimony 0.0504 0.05 mg/L 101 90.0 - 110 114222262
Arsenic 0.0497 0.05 mg/L 99.4 90.0 - 110 114222213
Arsenic 0.0505 0.05 mg/L 101 90.0 - 110 114222226
Arsenic 0.0494 0.05 mg/L 98.8 90.0 - 110 114222234
Arsenic 0.0487 0.05 mg/L 97.4 90.0 - 110 114222242
Arsenic 0.0487 0.05 mg/L 97.4 90.0 - 110 114222253
Arsenic 0.0508 0.05 mg/L 102 90.0 - 110 114222262
Beryllium 0.0491 0.05 mg/L 98.2 90.0 - 110 114222213
Beryllium 0.047 0.05 mg/L 94.0 90.0 - 110 114222226
Beryllium 0.048 0.05 mg/L 96.0 90.0 - 110 114222234
Beryllium 0.0466 0.05 mg/L 93.2 90.0 - 110 114222242
Beryllium 0.0476 0.05 mg/L 95.2 90.0 - 110 114222253
Beryllium 0.046 0.05 mg/L 92.0 90.0 - 110 114222262
Cadmium 0.0501 0.05 mg/L 100 90.0 - 110 114222213
Cadmium 0.0503 0.05 mg/L 101 90.0 - 110 114222226
Cadmium 0.050 0.05 mg/L 100 90.0 - 110 114222234
Cadmium 0.0496 0.05 mg/L 99.2 90.0 - 110 114222242
Cadmium 0.0497 0.05 mg/L 99.4 90.0 - 110 114222253
Cadmium 0.0494 0.05 mg/L 98.8 90.0 - 110 114222262
Chromium 0.0498 0.05 mg/L 99.6 90.0 - 110 114222213
Chromium 0.0494 0.05 mg/L 98.8 90.0 - 110 114222226
Chromium 0.0486 0.05 mg/L 97.2 90.0 - 110 114222234
Chromium 0.0491 0.05 mg/L 98.2 90.0 - 110 114222242
Chromium 0.0491 0.05 mg/L 98.2 90.0 - 110 114222253
Chromium 0.0506 0.05 mg/L 101 90.0 - 110 114222262
Copper 0.0501 0.05 mg/L 100 90.0 - 110 114222213
Copper 0.0486 0.05 mg/L 97.2 90.0 - 110 114222226
Copper 0.0476 0.05 mg/L 95.2 90.0 - 110 114222234
Copper 0.0481 0.05 mg/L 96.2 90.0 - 110 114222242
Copper 0.0481 0.05 mg/L 96.2 90.0 - 110 114222253
Copper 0.0493 0.05 mg/L 98.6 90.0 - 110 114222262
Lead 0.0507 0.05 mg/L 101 90.0 - 110 114222213
Lead 0.0506 0.05 mg/L 101 90.0 - 110 114222226
Lead 0.0523 0.05 mg/L 105 90.0 - 110 114222234
Lead 0.0514 0.05 mg/L 103 90.0 - 110 114222242
Lead 0.0521 0.05 mg/L 104 90.0 - 110 114222253
Lead 0.0504 0.05 mg/L 101 90.0 - 110 114222262
Nickel 0.0495 0.05 mg/L 99.0 90.0 - 110 114222213
Nickel 0.0489 0.05 mg/L 97.8 90.0 - 110 114222226
Nickel 0.0475 0.05 mg/L 95.0 90.0 - 110 114222234
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 10 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 4 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Nickel 0.0482 0.05 mg/L 96.4 90.0 - 110 114222242
Nickel 0.0478 0.05 mg/L 95.6 90.0 - 110 114222253
Nickel 0.0496 0.05 mg/L 99.2 90.0 - 110 114222262
Selenium 0.0503 0.05 mg/L 101 90.0 - 110 114222213
Selenium 0.0511 0.05 mg/L 102 90.0 - 110 114222226
Selenium 0.0513 0.05 mg/L 103 90.0 - 110 114222234
Selenium 0.0499 0.05 mg/L 99.8 90.0 - 110 114222242
Selenium 0.0493 0.05 mg/L 98.6 90.0 - 110 114222253
Selenium 0.0519 0.05 mg/L 104 90.0 - 110 114222262
Silver 0.0496 0.05 mg/L 99.2 90.0 - 110 114222213
Silver 0.0498 0.05 mg/L 99.6 90.0 - 110 114222226
Silver 0.0494 0.05 mg/L 98.8 90.0 - 110 114222234
Silver 0.049 0.05 mg/L 98.0 90.0 - 110 114222242
Silver 0.0492 0.05 mg/L 98.4 90.0 - 110 114222253
Silver 0.0489 0.05 mg/L 97.8 90.0 - 110 114222262
Thallium 0.0504 0.05 mg/L 101 90.0 - 110 114222213
Thallium 0.0501 0.05 mg/L 100 90.0 - 110 114222226
Thallium 0.0518 0.05 mg/L 104 90.0 - 110 114222234
Thallium 0.0504 0.05 mg/L 101 90.0 - 110 114222242
Thallium 0.051 0.05 mg/L 102 90.0 - 110 114222253
Thallium 0.0495 0.05 mg/L 99.0 90.0 - 110 114222262
ICV
FileOutLimits%Recover%UnitsKnownReadingParameter
Antimony 0.0513 0.05 mg/L 103 90.0 - 110 114222212
Arsenic 0.0502 0.05 mg/L 100 90.0 - 110 114222212
Beryllium 0.0505 0.05 mg/L 101 90.0 - 110 114222212
Cadmium 0.0515 0.05 mg/L 103 90.0 - 110 114222212
Chromium 0.0508 0.05 mg/L 102 90.0 - 110 114222212
Copper 0.0513 0.05 mg/L 103 90.0 - 110 114222212
Lead 0.0517 0.05 mg/L 103 90.0 - 110 114222212
Nickel 0.0507 0.05 mg/L 101 90.0 - 110 114222212
Selenium 0.0505 0.05 mg/L 101 90.0 - 110 114222212
Silver 0.0492 0.05 mg/L 98.4 90.0 - 110 114222212
Thallium 0.0524 0.05 mg/L 105 90.0 - 110 114222212
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Antimony 557089 0.511 0.500 mg/L 102 85.0 - 115 114222237
Arsenic 557089 0.518 0.500 mg/L 104 85.0 - 115 114222237
Beryllium 557089 0.199 0.200 mg/L 99.3 85.0 - 115 114222237
Cadmium 557089 0.260 0.250 mg/L 104 85.0 - 115 114222237
Chromium 557089 0.513 0.500 mg/L 103 85.0 - 115 114222237
Copper 557089 0.494 0.500 mg/L 98.9 85.0 - 115 114222237
Lead 557089 0.536 0.500 mg/L 107 85.0 - 115 114222237
Nickel 557089 0.487 0.500 mg/L 97.3 85.0 - 115 114222237
Selenium 557089 0.532 0.500 mg/L 106 85.0 - 115 114222237
Silver 557089 0.102 0.100 mg/L 102 85.0 - 115 114222237
Thallium 557089 0.515 0.500 mg/L 103 85.0 - 115 114222237
Zinc 557089 0.501 0.500 mg/L 100 85.0 - 115 114222237
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 11 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 5 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Antimony 557089 0.511 0.508 0.500 85.0 - 115 102 102 mg/L 0.589 20.0
Arsenic 557089 0.518 0.514 0.500 85.0 - 115 104 103 mg/L 0.775 20.0
Beryllium 557089 0.199 0.200 0.200 85.0 - 115 99.3 99.8 mg/L 0.501 20.0
Cadmium 557089 0.260 0.264 0.250 85.0 - 115 104 105 mg/L 1.53 20.0
Chromium 557089 0.513 0.504 0.500 85.0 - 115 103 101 mg/L 1.77 20.0
Copper 557089 0.494 0.497 0.500 85.0 - 115 98.9 99.3 mg/L 0.605 20.0
Lead 557089 0.536 0.546 0.500 85.0 - 115 107 109 mg/L 1.85 20.0
Nickel 557089 0.487 0.489 0.500 85.0 - 115 97.3 97.7 mg/L 0.410 20.0
Selenium 557089 0.532 0.531 0.500 85.0 - 115 106 106 mg/L 0.188 20.0
Silver 557089 0.102 0.103 0.100 85.0 - 115 102 103 mg/L 0.976 20.0
Thallium 557089 0.515 0.526 0.500 85.0 - 115 103 105 mg/L 2.11 20.0
Zinc 557089 0.501 0.506 0.500 85.0 - 115 100 101 mg/L 0.993 20.0
LDR
FileOutLimits%Recover%UnitsKnownReadingParameter
Antimony 0.198 0.2 mg/L 99.0 90.0 - 110 114222214
Arsenic 9.52 10 mg/L 95.2 90.0 - 110 114222217
Beryllium 9.90 10 mg/L 99.0 90.0 - 110 114222217
Cadmium 9.59 10 mg/L 95.9 90.0 - 110 114222217
Chromium 9.26 10 mg/L 92.6 90.0 - 110 114222217
Copper 4.59 5 mg/L 91.8 90.0 - 110 114222216
Lead 9.68 10 mg/L 96.8 90.0 - 110 114222217
Nickel 4.52 5 mg/L 90.4 90.0 - 110 114222216
Selenium 10.2 10 mg/L 102 90.0 - 110 114222217
Silver 9.49 10 mg/L 94.9 90.0 - 110 114222217
Thallium 9.63 10 mg/L 96.3 90.0 - 110 114222217
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Antimony 1280443 0.516 0 0.00286 0.500 70.0 - 130 103 mg/L 20.0
Arsenic 1280443 0.522 0 0.00366 0.500 70.0 - 130 104 mg/L 20.0
Beryllium 1280443 0.196 0 0.000111 0.200 70.0 - 130 97.9 mg/L 20.0
Cadmium 1280443 0.258 0 ND 0.250 70.0 - 130 103 mg/L 20.0
Chromium 1280443 0.508 0 0.000479 0.500 70.0 - 130 102 mg/L 20.0
Copper 1280443 0.490 0 0.00307 0.500 70.0 - 130 97.4 mg/L 20.0
Lead 1280443 0.522 0 0.000493 0.500 70.0 - 130 104 mg/L 20.0
Nickel 1280443 0.482 0 0.00191 0.500 70.0 - 130 96.0 mg/L 20.0
Selenium 1280443 0.528 0 0.00244 0.500 70.0 - 130 105 mg/L 20.0
Silver 1280443 0.101 0 0.0000979 0.100 70.0 - 130 101 mg/L 20.0
Thallium 1280443 0.505 0 0.000804 0.500 70.0 - 130 101 mg/L 20.0
Zinc 1280443 0.499 0 0.00914 0.500 70.0 - 130 98.0 mg/L 20.0
Antimony 1280492 0.514 0 0.00164 0.500 70.0 - 130 102 mg/L 20.0
Arsenic 1280492 0.522 0 0.0013 0.500 70.0 - 130 104 mg/L 20.0
Beryllium 1280492 0.192 0 ND 0.200 70.0 - 130 96.0 mg/L 20.0
Cadmium 1280492 0.256 0 ND 0.250 70.0 - 130 102 mg/L 20.0
Chromium 1280492 0.505 0 0.000339 0.500 70.0 - 130 101 mg/L 20.0
Copper 1280492 0.532 0 0.0482 0.500 70.0 - 130 96.8 mg/L 20.0
Lead 1280492 0.516 0 0.000707 0.500 70.0 - 130 103 mg/L 20.0
Nickel 1280492 0.481 0 0.00226 0.500 70.0 - 130 95.7 mg/L 20.0
Selenium 1280492 0.526 0 ND 0.500 70.0 - 130 105 mg/L 20.0
Silver 1280492 0.0988 0 0.000122 0.100 70.0 - 130 98.7 mg/L 20.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 12 of 46
1
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 6 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Thallium 1280492 0.487 0 ND 0.500 70.0 - 130 97.4 mg/L 20.0
Zinc 1280492 0.497 0 0.0117 0.500 70.0 - 130 97.1 mg/L 20.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Antimony 1280443 0.516 0.521 0.00286 0.500 70.0 - 130 103 104 mg/L 0.966 20.0
Arsenic 1280443 0.522 0.518 0.00366 0.500 70.0 - 130 104 103 mg/L 0.966 20.0
Beryllium 1280443 0.196 0.197 0.000111 0.200 70.0 - 130 97.9 98.4 mg/L 0.509 20.0
Cadmium 1280443 0.258 0.256 ND 0.250 70.0 - 130 103 102 mg/L 0.976 20.0
Chromium 1280443 0.508 0.499 0.000479 0.500 70.0 - 130 102 99.7 mg/L 2.28 20.0
Copper 1280443 0.490 0.483 0.00307 0.500 70.0 - 130 97.4 96.0 mg/L 1.45 20.0
Lead 1280443 0.522 0.525 0.000493 0.500 70.0 - 130 104 105 mg/L 0.957 20.0
Nickel 1280443 0.482 0.475 0.00191 0.500 70.0 - 130 96.0 94.6 mg/L 1.47 20.0
Selenium 1280443 0.528 0.524 0.00244 0.500 70.0 - 130 105 104 mg/L 0.957 20.0
Silver 1280443 0.101 0.100 0.0000979 0.100 70.0 - 130 101 99.9 mg/L 1.10 20.0
Thallium 1280443 0.505 0.508 0.000804 0.500 70.0 - 130 101 101 mg/L 0 20.0
Zinc 1280443 0.499 0.492 0.00914 0.500 70.0 - 130 98.0 96.6 mg/L 1.44 20.0
Antimony 1280492 0.514 0.515 0.00164 0.500 70.0 - 130 102 103 mg/L 0.976 20.0
Arsenic 1280492 0.522 0.528 0.0013 0.500 70.0 - 130 104 105 mg/L 0.957 20.0
Beryllium 1280492 0.192 0.193 ND 0.200 70.0 - 130 96.0 96.5 mg/L 0.519 20.0
Cadmium 1280492 0.256 0.255 ND 0.250 70.0 - 130 102 102 mg/L 0 20.0
Chromium 1280492 0.505 0.511 0.000339 0.500 70.0 - 130 101 102 mg/L 0.985 20.0
Copper 1280492 0.532 0.533 0.0482 0.500 70.0 - 130 96.8 97.0 mg/L 0.206 20.0
Lead 1280492 0.516 0.519 0.000707 0.500 70.0 - 130 103 104 mg/L 0.966 20.0
Nickel 1280492 0.481 0.482 0.00226 0.500 70.0 - 130 95.7 95.9 mg/L 0.209 20.0
Selenium 1280492 0.526 0.532 ND 0.500 70.0 - 130 105 106 mg/L 0.948 20.0
Silver 1280492 0.0988 0.0988 0.000122 0.100 70.0 - 130 98.7 98.7 mg/L 0 20.0
Thallium 1280492 0.487 0.487 ND 0.500 70.0 - 130 97.4 97.4 mg/L 0 20.0
Zinc 1280492 0.497 0.497 0.0117 0.500 70.0 - 130 97.1 97.1 mg/L 0 20.0
EPA 245.1 3Liquid Aqueous 557243
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Mercury 557069 ND 0.0684 0.100 ug/L 114224329
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Mercury 5.12 5.000 ug/L 102 90.0 - 110 114224325
Mercury 5.10 5.000 ug/L 102 90.0 - 110 114224333
Mercury 5.12 5.000 ug/L 102 90.0 - 110 114224340
ICL
FileOutLimits%Recover%UnitsKnownReadingParameter
Mercury 19.4 20.00 ug/L 97.0 90.0 - 110 114224320
ICV
FileOutLimits%Recover%UnitsKnownReadingParameter
Mercury 5.10 5.000 ug/L 102 90.0 - 110 114224319
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Mercury 557069 4.86 5.00 ug/L 97.2 85.0 - 115 114224330
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 13 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 7 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Mercury 557069 4.86 4.85 5.00 85.0 - 115 97.2 97.0 ug/L 0.206 20.0
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Mercury 1280758 9.90 0 0.240 10.0 70.0 - 130 96.6 ug/L 14.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Mercury 1280758 9.90 9.76 0.240 10.0 70.0 - 130 96.6 95.2 ug/L 1.46 14.0
EPA 200.8 5.4Liquid Aqueous 557309
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Zinc 557089 0.00166 0.00123 0.005 mg/L 114225505
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Zinc 0.0498 0.05 mg/L 99.6 90.0 - 110 114225502
Zinc 0.0496 0.05 mg/L 99.2 90.0 - 110 114225513
ICV
FileOutLimits%Recover%UnitsKnownReadingParameter
Zinc 0.0506 0.05 mg/L 101 90.0 - 110 114225501
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Zinc 557089 0.507 0.500 mg/L 101 85.0 - 115 114225506
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Zinc 557089 0.507 0.509 0.500 85.0 - 115 101 102 mg/L 0.394 20.0
LDR
FileOutLimits%Recover%UnitsKnownReadingParameter
Zinc 9.35 10 mg/L 93.5 90.0 - 110 114225504
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Zinc 1280492 0.501 0 0.0114 0.500 70.0 - 130 97.9 mg/L 20.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Zinc 1280492 0.501 0.502 0.0114 0.500 70.0 - 130 97.9 98.1 mg/L 0.204 20.0
EPA Method 625Liquid Aqueous 557270
Blank
FileUnitsMQLMDLReadingPrepSetParameter
1,2,4-Trichlorobenzene 555103 ND 0.941 1.00 ug/L 114234323
1,2-Dichlorobenzene 555103 ND 1.04 5.00 ug/L 114234323
1,2-DPH (as azobenzene) 555103 ND 0.238 1.00 ug/L 114234323
1,3-Dichlorobenzene 555103 ND 0.954 5.00 ug/L 114234323
1,4-Dichlorobenzene 555103 ND 1.01 5.00 ug/L 114234323
2,4,6-Trichlorophenol 555103 ND 1.24 2.00 ug/L 114234323
2,4-Dichlorophenol 555103 ND 0.222 1.00 ug/L 114234323
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 14 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 8 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Blank
FileUnitsMQLMDLReadingPrepSetParameter
2,4-Dimethylphenol 555103 ND 0.536 1.00 ug/L 114234323
2,4-Dinitrophenol 555103 ND 1.34 2.00 ug/L 114234323
2,4-Dinitrotoluene 555103 ND 1.53 2.00 ug/L 114234323
2,6-Dinitrotoluene 555103 ND 1.29 2.00 ug/L 114234323
2-Chloronaphthalene 555103 ND 0.150 1.00 ug/L 114234323
2-Chlorophenol 555103 ND 0.275 1.00 ug/L 114234323
2-Nitrophenol 555103 ND 0.554 1.00 ug/L 114234323
3,3'-Dichlorobenzidine 555103 ND 1.39 2.00 ug/L 114234323
4,6-Dinitro-2-methylphenol 555103 ND 1.15 2.00 ug/L 114234323
4-Bromophenyl phenyl ether 555103 ND 0.772 1.00 ug/L 114234323
4-Chlorophenyl phenyl ethe 555103 ND 0.202 1.00 ug/L 114234323
4-Nitrophenol 555103 ND 0.789 1.00 ug/L 114234323
Acenaphthene 555103 ND 0.177 1.00 ug/L 114234323
Acenaphthylene 555103 ND 0.240 1.00 ug/L 114234323
Anthracene 555103 ND 0.241 1.00 ug/L 114234323
Benzidine 555103 ND 1.40 1.50 ug/L 114234323
Benzo(a)anthracene 555103 ND 0.225 1.00 ug/L 114234323
Benzo(a)pyrene 555103 ND 0.900 1.00 ug/L 114234323
Benzo(b)fluoranthene 555103 ND 0.547 1.00 ug/L 114234323
Benzo(ghi)perylene 555103 ND 0.881 1.00 ug/L 114234323
Benzo(k)fluoranthene 555103 ND 0.252 1.00 ug/L 114234323
Benzyl Butyl phthalate 555103 ND 0.204 1.00 ug/L 114234323
Bis(2-chloroethoxy)methane 555103 ND 0.277 1.00 ug/L 114234323
Bis(2-chloroethyl)ether 555103 ND 0.348 1.00 ug/L 114234323
Bis(2-chloroisopropyl)ether 555103 ND 0.738 1.00 ug/L 114234323
Bis(2-ethylhexyl)phthalate 555103 ND 1.12 1.12 ug/L 114234323
Chrysene
(Benzo(a)phenanthrene)
555103 ND 0.289 1.00 ug/L 114234323
Dibenz(a,h)anthracene 555103 ND 0.689 1.00 ug/L 114234323
Diethyl phthalate 555103 ND 0.253 1.00 ug/L 114234323
Dimethyl phthalate 555103 ND 0.540 1.00 ug/L 114234323
Di-n-butylphthalate 555103 ND 0.978 1.00 ug/L 114234323
Di-n-octylphthalate 555103 ND 1.92 2.00 ug/L 114234323
Fluoranthene(Benzo(j,k)fluor
ene)
555103 ND 0.318 1.00 ug/L 114234323
Fluorene 555103 ND 0.275 1.00 ug/L 114234323
Hexachlorobenzene 555103 ND 0.871 1.00 ug/L 114234323
Hexachlorobutadiene 555103 ND 1.03 1.03 ug/L 114234323
Hexachlorocyclopentadiene 555103 ND 0.536 1.00 ug/L 114234323
Hexachloroethane 555103 ND 1.05 2.00 ug/L 114234323
Indeno(1,2,3-cd)pyrene 555103 ND 0.596 1.00 ug/L 114234323
Isophorone 555103 ND 0.429 1.00 ug/L 114234323
Naphthalene 555103 ND 0.225 1.00 ug/L 114234323
Nitrobenzene 555103 ND 0.271 1.00 ug/L 114234323
N-Nitrosodimethylamine 555103 ND 0.542 1.00 ug/L 114234323
N-Nitrosodi-n-propylamine 555103 ND 0.425 1.00 ug/L 114234323
N-Nitrosodiphenylamine (as
DPA
555103 ND 0.404 1.00 ug/L 114234323
p-Chloro-m-Cresol
(4-Chloro-3-me
555103 ND 0.588 1.00 ug/L 114234323
Pentachlorophenol 555103 ND 0.960 10.0 ug/L 114234323
Phenanthrene 555103 ND 0.269 1.00 ug/L 114234323
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 15 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 9 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Phenol 555103 ND 0.332 1.00 ug/L 114234323
Pyrene 555103 ND 0.291 1.00 ug/L 114234323
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
1,2,4-Trichlorobenzene 51600 50000 ug/L 103 80.0 - 120 114224822
1,2-Dichlorobenzene 60200 50000 ug/L 120 80.0 - 120 114224822
1,2-DPH (as azobenzene) 49800 50000 ug/L 99.6 80.0 - 120 114224822
1,3-Dichlorobenzene 46100 50000 ug/L 92.2 80.0 - 120 114224822
1,4-Dichlorobenzene 48300 50000 ug/L 96.6 80.0 - 120 114224822
2,4,6-Trichlorophenol 50500 50000 ug/L 101 80.0 - 120 114224822
2,4-Dichlorophenol 48700 50000 ug/L 97.4 80.0 - 120 114224822
2,4-Dimethylphenol 43800 50000 ug/L 87.6 80.0 - 120 114224822
2,4-Dinitrophenol 53300 50000 ug/L 107 80.0 - 120 114224822
2,4-Dinitrotoluene 51600 50000 ug/L 103 80.0 - 120 114224822
2,6-Dinitrotoluene 44700 50000 ug/L 89.4 80.0 - 120 114224822
2-Chloronaphthalene 45200 50000 ug/L 90.4 80.0 - 120 114224822
2-Chlorophenol 46000 50000 ug/L 92.0 80.0 - 120 114224822
2-Nitrophenol 48700 50000 ug/L 97.4 80.0 - 120 114224822
3,3'-Dichlorobenzidine 53700 50000 ug/L 107 80.0 - 120 114224822
4,6-Dinitro-2-methylphenol 60200 50000 ug/L 120 80.0 - 120 114224822
4-Bromophenyl phenyl ether 51600 50000 ug/L 103 80.0 - 120 114224822
4-Chlorophenyl phenyl ethe 66000 50000 ug/L 132 80.0 - 120 * 114224822
4-Nitrophenol 62800 50000 ug/L 126 80.0 - 120 * 114224822
Acenaphthene 47100 50000 ug/L 94.2 80.0 - 120 114224822
Acenaphthylene 43800 50000 ug/L 87.6 80.0 - 120 114224822
Anthracene 56100 50000 ug/L 112 80.0 - 120 114224822
Benzidine 41300 50000 ug/L 82.6 80.0 - 120 114224822
Benzo(a)anthracene 48400 50000 ug/L 96.8 80.0 - 120 114224822
Benzo(a)pyrene 51300 50000 ug/L 103 80.0 - 120 114224822
Benzo(b)fluoranthene 56800 50000 ug/L 114 80.0 - 120 114224822
Benzo(ghi)perylene 48400 50000 ug/L 96.8 80.0 - 120 114224822
Benzo(k)fluoranthene 46300 50000 ug/L 92.6 80.0 - 120 114224822
Benzyl Butyl phthalate 45200 50000 ug/L 90.4 80.0 - 120 114224822
Bis(2-chloroethoxy)methane 46900 50000 ug/L 93.8 80.0 - 120 114224822
Bis(2-chloroethyl)ether 45300 50000 ug/L 90.6 80.0 - 120 114224822
Bis(2-chloroisopropyl)ether 48400 50000 ug/L 96.8 80.0 - 120 114224822
Bis(2-ethylhexyl)phthalate 44500 50000 ug/L 89.0 80.0 - 120 114224822
Chrysene
(Benzo(a)phenanthrene)
45100 50000 ug/L 90.2 80.0 - 120 114224822
Dibenz(a,h)anthracene 53100 50000 ug/L 106 80.0 - 120 114224822
Diethyl phthalate 50500 50000 ug/L 101 80.0 - 120 114224822
Dimethyl phthalate 47100 50000 ug/L 94.2 80.0 - 120 114224822
Di-n-butylphthalate 52700 50000 ug/L 105 80.0 - 120 114224822
Di-n-octylphthalate 43000 50000 ug/L 86.0 80.0 - 120 114224822
Fluoranthene(Benzo(j,k)fluor
ene)
45500 50000 ug/L 91.0 80.0 - 120 114224822
Fluorene 60900 50000 ug/L 122 80.0 - 120 * 114224822
Hexachlorobenzene 52800 50000 ug/L 106 80.0 - 120 114224822
Hexachlorobutadiene 57600 50000 ug/L 115 80.0 - 120 114224822
Hexachlorocyclopentadiene 59600 50000 ug/L 119 80.0 - 120 114224822
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 16 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 10 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Hexachloroethane 56500 50000 ug/L 113 80.0 - 120 114224822
Indeno(1,2,3-cd)pyrene 48500 50000 ug/L 97.0 80.0 - 120 114224822
Isophorone 48800 50000 ug/L 97.6 80.0 - 120 114224822
Naphthalene 55700 50000 ug/L 111 80.0 - 120 114224822
Nitrobenzene 48000 50000 ug/L 96.0 80.0 - 120 114224822
N-Nitrosodimethylamine 56900 50000 ug/L 114 80.0 - 120 114224822
N-Nitrosodi-n-propylamine 63600 50000 ug/L 127 80.0 - 120 * 114224822
N-Nitrosodiphenylamine (as
DPA
57600 50000 ug/L 115 80.0 - 120 114224822
p-Chloro-m-Cresol
(4-Chloro-3-me
53500 50000 ug/L 107 80.0 - 120 114224822
Pentachlorophenol 59600 50000 ug/L 119 80.0 - 120 114224822
Phenanthrene 49800 50000 ug/L 99.6 80.0 - 120 114224822
Phenol 58800 50000 ug/L 118 80.0 - 120 114224822
Pyrene 49700 50000 ug/L 99.4 80.0 - 120 114224822
DFTPP
FileOutLimits%%ReadingRefMassParameter
DFTPP Mass 127 131163 198 21102 54.9 40.0 - 60.0 114224821
DFTPP Mass 197 131163 198 0 0.0 0 - 1.00 114224821
DFTPP Mass 198 131163 198 38444 100.0 100 - 100 114224821
DFTPP Mass 199 131163 198 2662 6.9 5.00 - 9.00 114224821
DFTPP Mass 275 131163 198 8485 22.1 10.0 - 30.0 114224821
DFTPP Mass 365 131163 198 1012 2.6 1.00 - 100 114224821
DFTPP Mass 441 131163 443 4456 80.9 0 - 100 114224821
DFTPP Mass 442 131163 198 28113 73.1 40.0 - 100 114224821
DFTPP Mass 443 131163 442 5511 19.6 17.0 - 23.0 114224821
DFTPP Mass 51 131163 198 12860 33.5 30.0 - 60.0 114224821
DFTPP Mass 68 131163 69.0 0 0.0 0 - 2.00 114224821
DFTPP Mass 69 131163 198 17434 45.3 0 - 100 114224821
DFTPP Mass 70 131163 69.0 0 0.0 0 - 2.00 114224821
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
1,2,4-Trichlorobenzene 555103 18.5 25.0 ug/L 74.1 22.0 - 147 114234324
1,2-Dichlorobenzene 555103 18.9 25.0 ug/L 75.7 32.0 - 129 114234324
1,2-DPH (as azobenzene) 555103 22.0 25.0 ug/L 88.1 0.100 - 130 114234324
1,3-Dichlorobenzene 555103 16.1 25.0 ug/L 64.3 0.100 - 172 114234324
1,4-Dichlorobenzene 555103 17.3 25.0 ug/L 69.2 20.0 - 124 114234324
2,4,6-Trichlorophenol 555103 20.5 25.0 ug/L 82.0 37.0 - 144 114234324
2,4-Dichlorophenol 555103 17.6 25.0 ug/L 70.2 39.0 - 135 114234324
2,4-Dimethylphenol 555103 7.61 25.0 ug/L 30.4 32.0 - 119 114234324 *
2,4-Dinitrophenol 555103 14.6 25.0 ug/L 58.3 0.100 - 191 114234324
2,4-Dinitrotoluene 555103 19.2 25.0 ug/L 76.6 39.0 - 139 114234324
2,6-Dinitrotoluene 555103 18.8 25.0 ug/L 75.4 50.0 - 158 114234324
2-Chloronaphthalene 555103 18.0 25.0 ug/L 72.0 60.0 - 118 114234324
2-Chlorophenol 555103 17.4 25.0 ug/L 69.6 23.0 - 134 114234324
2-Nitrophenol 555103 17.7 25.0 ug/L 70.9 29.0 - 182 114234324
3,3'-Dichlorobenzidine 555103 17.2 25.0 ug/L 68.8 0.100 - 262 114234324
4,6-Dinitro-2-methylphenol 555103 23.6 25.0 ug/L 94.6 0.100 - 191 114234324
4-Bromophenyl phenyl ether 555103 22.7 25.0 ug/L 90.8 53.0 - 127 114234324
4-Chlorophenyl phenyl ethe 555103 24.5 25.0 ug/L 98.1 25.0 - 158 114234324
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 17 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 11 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
4-Nitrophenol 555103 11.9 25.0 ug/L 47.8 0.100 - 132 114234324
Acenaphthene 555103 19.3 25.0 ug/L 77.3 47.0 - 145 114234324
Acenaphthylene 555103 16.5 25.0 ug/L 66.0 33.0 - 145 114234324
Anthracene 555103 21.6 25.0 ug/L 86.2 27.0 - 133 114234324
Benzidine 555103 4.71 25.0 ug/L 18.8 0.100 - 130 114234324
Benzo(a)anthracene 555103 20.7 25.0 ug/L 82.8 33.0 - 143 114234324
Benzo(a)pyrene 555103 21.3 25.0 ug/L 85.2 17.0 - 163 114234324
Benzo(b)fluoranthene 555103 20.6 25.0 ug/L 82.4 24.0 - 159 114234324
Benzo(ghi)perylene 555103 30.4 25.0 ug/L 122 0.100 - 219 114234324
Benzo(k)fluoranthene 555103 20.4 25.0 ug/L 81.8 11.0 - 162 114234324
Benzyl Butyl phthalate 555103 21.6 25.0 ug/L 86.3 0.100 - 152 114234324
Bis(2-chloroethoxy)methane 555103 21.0 25.0 ug/L 84.0 33.0 - 184 114234324
Bis(2-chloroethyl)ether 555103 23.5 25.0 ug/L 94.0 33.0 - 184 114234324
Bis(2-chloroisopropyl)ether 555103 16.8 25.0 ug/L 67.2 36.0 - 166 114234324
Bis(2-ethylhexyl)phthalate 555103 23.6 25.0 ug/L 94.2 8.00 - 158 114234324
Chrysene
(Benzo(a)phenanthrene)
555103 20.7 25.0 ug/L 82.6 17.0 - 168 114234324
Dibenz(a,h)anthracene 555103 27.6 25.0 ug/L 110 0.100 - 227 114234324
Diethyl phthalate 555103 20.1 25.0 ug/L 80.4 0.100 - 114 114234324
Dimethyl phthalate 555103 18.1 25.0 ug/L 72.4 0.100 - 112 114234324
Di-n-butylphthalate 555103 22.0 25.0 ug/L 88.2 1.00 - 118 114234324
Di-n-octylphthalate 555103 18.2 25.0 ug/L 72.8 4.00 - 146 114234324
Fluoranthene(Benzo(j,k)fluor
ene)
555103 18.5 25.0 ug/L 74.1 26.0 - 137 114234324
Fluorene 555103 21.6 25.0 ug/L 86.5 59.0 - 121 114234324
Hexachlorobenzene 555103 23.5 25.0 ug/L 94.1 0.100 - 152 114234324
Hexachlorobutadiene 555103 19.3 25.0 ug/L 77.2 24.0 - 116 114234324
Hexachlorocyclopentadiene 555103 12.9 25.0 ug/L 51.5 0.100 - 130 114234324
Hexachloroethane 555103 18.2 25.0 ug/L 72.9 40.0 - 113 114234324
Indeno(1,2,3-cd)pyrene 555103 27.6 25.0 ug/L 110 0.100 - 171 114234324
Isophorone 555103 20.7 25.0 ug/L 82.7 21.0 - 196 114234324
Naphthalene 555103 21.2 25.0 ug/L 84.6 21.0 - 133 114234324
Nitrobenzene 555103 21.9 25.0 ug/L 87.6 35.0 - 180 114234324
N-Nitrosodimethylamine 555103 19.6 25.0 ug/L 78.4 0.100 - 130 114234324
N-Nitrosodi-n-propylamine 555103 21.4 25.0 ug/L 85.5 0.100 - 230 114234324
N-Nitrosodiphenylamine (as
DPA
555103 23.4 25.0 ug/L 93.6 0.100 - 130 114234324
p-Chloro-m-Cresol
(4-Chloro-3-me
555103 19.3 25.0 ug/L 77.3 22.0 - 147 114234324
Pentachlorophenol 555103 22.6 25.0 ug/L 90.4 5.00 - 112 114234324
Phenanthrene 555103 21.0 25.0 ug/L 84.1 54.0 - 120 114234324
Phenol 555103 10.6 25.0 ug/L 42.2 5.00 - 112 114234324
Pyrene 555103 21.3 25.0 ug/L 85.3 52.0 - 115 114234324
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
2,4,6-Tribromophenol 132690 CCV 66300 100000 ug/L 66.3 10.0 - 150 114224822
2-Fluorobiphenyl-SURR 132690 CCV 54900 50000 ug/L 110 30.0 - 150 114224822
2-Fluorophenol-SURR 132690 CCV 44800 100000 ug/L 44.8 10.0 - 150 114224822
4-Terphenyl-d14-SURR 132690 CCV 51300 50000 ug/L 103 30.0 - 150 114224822
Nitrobenzene-d5-SURR 132690 CCV 44200 50000 ug/L 88.4 30.0 - 150 114224822
Phenol-d6-SURR 132690 CCV 62000 100000 ug/L 62.0 10.0 - 150 114224822
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 18 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 12 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
2,4,6-Tribromophenol 555103 Blank 50.8 100 ug/L 50.8 10.0 - 150 114234323
2,4,6-Tribromophenol 555103 LCS 76.2 100 ug/L 76.2 10.0 - 150 114234324
2,4,6-Tribromophenol 555103 LCS Dup 84.8 100 ug/L 84.8 10.0 - 150 114234325
2-Fluorobiphenyl-SURR 555103 Blank 22500 50000 ug/L 45.0 30.0 - 150 114234323
2-Fluorobiphenyl-SURR 555103 LCS 41300 50000 ug/L 82.6 30.0 - 150 114234324
2-Fluorobiphenyl-SURR 555103 LCS Dup 42300 50000 ug/L 84.6 30.0 - 150 114234325
2-Fluorophenol-SURR 555103 Blank 28300 100000 ug/L 28.3 10.0 - 150 114234323
2-Fluorophenol-SURR 555103 LCS 46900 100000 ug/L 46.9 10.0 - 150 114234324
2-Fluorophenol-SURR 555103 LCS Dup 42800 100000 ug/L 42.8 10.0 - 150 114234325
4-Terphenyl-d14-SURR 555103 Blank 24500 50000 ug/L 49.0 30.0 - 150 114234323
4-Terphenyl-d14-SURR 555103 LCS 40700 50000 ug/L 81.4 30.0 - 150 114234324
4-Terphenyl-d14-SURR 555103 LCS Dup 39400 50000 ug/L 78.8 30.0 - 150 114234325
Nitrobenzene-d5-SURR 555103 Blank 27200 50000 ug/L 54.4 30.0 - 150 114234323
Nitrobenzene-d5-SURR 555103 LCS 34900 50000 ug/L 69.8 30.0 - 150 114234324
Nitrobenzene-d5-SURR 555103 LCS Dup 33600 50000 ug/L 67.2 30.0 - 150 114234325
Phenol-d6-SURR 555103 Blank 21800 100000 ug/L 21.8 10.0 - 150 114234323
Phenol-d6-SURR 555103 LCS 41200 100000 ug/L 41.2 10.0 - 150 114234324
Phenol-d6-SURR 555103 LCS Dup 36800 100000 ug/L 36.8 10.0 - 150 114234325
2,4,6-Tribromophenol 1280758 UNKNOWN77.2 101 ug/L 76.4 10.0 - 150 114224823
2-Fluorobiphenyl-SURR 1280758 UNKNOWN37.3 50.7 ug/L 73.6 30.0 - 150 114224823
2-Fluorophenol-SURR 1280758 UNKNOWN33.5 101 ug/L 33.2 10.0 - 150 114224823
4-Terphenyl-d14-SURR 1280758 UNKNOWN44.9 50.7 ug/L 88.6 30.0 - 150 114224823
Nitrobenzene-d5-SURR 1280758 UNKNOWN31.5 50.7 ug/L 62.1 30.0 - 150 114224823
Phenol-d6-SURR 1280758 UNKNOWN29.3 101 ug/L 29.0 10.0 - 150 114224823
EPA Method 624Liquid Aqueous 557275
BFB
FileOutLimits%%ReadingRefMassSampleParameter
BFB Mass 173 557275 174 48 0.5 0 - 2.00 114224858
BFB Mass 174 557275 95.0 10326 90.8 50.0 - 100 114224858
BFB Mass 175 557275 174 726 7.0 5.00 - 9.00 114224858
BFB Mass 176 557275 174 10058 97.4 95.0 - 101 114224858
BFB Mass 177 557275 176 669 6.7 5.00 - 9.00 114224858
BFB Mass 50 557275 95.0 2047 18.0 15.0 - 40.0 114224858
BFB Mass 75 557275 95.0 5336 46.9 30.0 - 60.0 114224858
BFB Mass 95 557275 95.0 11367 100.0 100 - 100 114224858
BFB Mass 96 557275 95.0 807 7.1 5.00 - 9.00 114224858
Blank
FileUnitsMQLMDLReadingPrepSetParameter
1,1,1-Trichloroethane 557275 ND 0.265 1.00 ug/L 114224861
1,1,2,2-Tetrachloroethane 557275 ND 0.270 1.00 ug/L 114224861
1,1,2-Trichloroethane 557275 ND 0.425 1.00 ug/L 114224861
1,1-Dichloroethane 557275 ND 0.496 1.00 ug/L 114224861
1,1-Dichloroethylene 557275 ND 0.404 1.00 ug/L 114224861
1,2-Dichloroethane 557275 ND 0.456 1.00 ug/L 114224861
1,2-Dichloropropane 557275 ND 0.415 1.00 ug/L 114224861
2-Chloroethylvinyl ether 557275 ND 0.423 1.00 ug/L 114224861
Benzene 557275 ND 0.187 1.00 ug/L 114224861
Bromodichloromethane 557275 ND 0.307 1.00 ug/L 114224861
Bromoform 557275 ND 0.288 1.00 ug/L 114224861
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 19 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 13 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Bromomethane (Methyl
Bromi
557275 ND 0.554 1.00 ug/L 114224861
Carbon Tetrachloride 557275 ND 0.459 1.00 ug/L 114224861
Chlorobenzene 557275 ND 0.226 1.00 ug/L 114224861
Chloroethane 557275 ND 0.396 1.00 ug/L 114224861
Chloroform 557275 ND 0.211 1.00 ug/L 114224861
Chloromethane 557275 ND 0.391 1.00 ug/L 114224861
cis-1,3-Dichloropropene 557275 ND 0.488 1.00 ug/L 114224861
Dibromochloromethane 557275 ND 0.185 1.00 ug/L 114224861
Ethylbenzene 557275 ND 0.180 1.00 ug/L 114224861
Methylene chloride 557275 ND 0.570 1.00 ug/L 114224861
Tetrachloroethylene 557275 ND 0.391 1.00 ug/L 114224861
Toluene 557275 ND 0.314 1.00 ug/L 114224861
trans-1,2-Dichloroethene 557275 ND 0.518 1.00 ug/L 114224861
trans-1,3-Dichloropropene 557275 ND 0.223 1.00 ug/L 114224861
Trichloroethylene 557275 ND 0.562 1.00 ug/L 114224861
Vinyl chloride 557275 ND 0.228 1.00 ug/L 114224861
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
1,1,1-Trichloroethane 19.4 20.0 ug/L 97.0 70.0 - 130 114224857
1,1,2,2-Tetrachloroethane 22.1 20.0 ug/L 110 70.0 - 130 114224857
1,1,2-Trichloroethane 20.3 20.0 ug/L 102 70.0 - 130 114224857
1,1-Dichloroethane 21.0 20.0 ug/L 105 70.0 - 130 114224857
1,1-Dichloroethylene 20.2 20.0 ug/L 101 70.0 - 130 114224857
1,2-Dichloroethane 18.7 20.0 ug/L 93.5 70.0 - 130 114224857
1,2-Dichloropropane 20.3 20.0 ug/L 102 70.0 - 130 114224857
Benzene 20.7 20.0 ug/L 104 70.0 - 130 114224857
Bromodichloromethane 18.3 20.0 ug/L 91.5 70.0 - 130 114224857
Bromoform 15.1 20.0 ug/L 75.5 70.0 - 130 114224857
Bromomethane (Methyl
Bromi
18.3 20.0 ug/L 91.5 70.0 - 130 114224857
Carbon Tetrachloride 18.3 20.0 ug/L 91.5 70.0 - 130 114224857
Chlorobenzene 18.8 20.0 ug/L 94.0 70.0 - 130 114224857
Chloroethane 21.0 20.0 ug/L 105 70.0 - 130 114224857
Chloroform 20.5 20.0 ug/L 102 70.0 - 130 114224857
Chloromethane 22.3 20.0 ug/L 112 70.0 - 130 114224857
cis-1,3-Dichloropropene 17.5 20.0 ug/L 87.5 70.0 - 130 114224857
Dibromochloromethane 15.6 20.0 ug/L 78.0 70.0 - 130 114224857
Ethylbenzene 19.2 20.0 ug/L 96.0 70.0 - 130 114224857
Methylene chloride 21.1 20.0 ug/L 106 70.0 - 130 114224857
Tetrachloroethylene 20.3 20.0 ug/L 102 70.0 - 130 114224857
Toluene 19.9 20.0 ug/L 99.5 70.0 - 130 114224857
trans-1,2-Dichloroethene 20.8 20.0 ug/L 104 70.0 - 130 114224857
trans-1,3-Dichloropropene 17.5 20.0 ug/L 87.5 70.0 - 130 114224857
Trichloroethylene 19.8 20.0 ug/L 99.0 70.0 - 130 114224857
Vinyl chloride 22.7 20.0 ug/L 114 70.0 - 130 114224857
IS Areas
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557275 LCS 140400 142600 71300 213900 114224859 557275
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 20 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 14 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
IS Areas
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557275 LCS Dup 139900 142600 71300 213900 114224860 557275
1,4-DichlorobenzeneD4
(ISTD)
557275 Blank 129700 142600 71300 213900 114224861 557275
ChlorobenzeneD5 (ISTD) 557275 LCS 234200 244100 122100 366200 114224859 557275
ChlorobenzeneD5 (ISTD) 557275 LCS Dup 236700 244100 122100 366200 114224860 557275
ChlorobenzeneD5 (ISTD) 557275 Blank 235300 244100 122100 366200 114224861 557275
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN123100 142600 71300 213900 114224862 1280758
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN220800 244100 122100 366200 114224862 1280758
IS RetTime
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557275 LCS 12.01 12.01 11.95 12.07 114224859 557275
1,4-DichlorobenzeneD4
(ISTD)
557275 LCS Dup 12.01 12.01 11.95 12.07 114224860 557275
1,4-DichlorobenzeneD4
(ISTD)
557275 Blank 12.01 12.01 11.95 12.07 114224861 557275
ChlorobenzeneD5 (ISTD) 557275 LCS 9.623 9.623 9.563 9.683 114224859 557275
ChlorobenzeneD5 (ISTD) 557275 LCS Dup 9.623 9.623 9.563 9.683 114224860 557275
ChlorobenzeneD5 (ISTD) 557275 Blank 9.623 9.623 9.563 9.683 114224861 557275
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN12.01 12.01 11.95 12.07 114224862 1280758
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN9.623 9.623 9.563 9.683 114224862 1280758
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
1,1,1-Trichloroethane 557275 19.5 20.0 ug/L 97.4 75.0 - 125 114224859
1,1,2,2-Tetrachloroethane 557275 21.9 20.0 ug/L 110 60.0 - 140 114224859
1,1,2-Trichloroethane 557275 21.8 20.0 ug/L 109 71.0 - 129 114224859
1,1-Dichloroethane 557275 22.1 20.0 ug/L 110 72.0 - 128 114224859
1,1-Dichloroethylene 557275 19.2 20.0 ug/L 95.9 50.0 - 150 114224859
1,2-Dichloroethane 557275 19.8 20.0 ug/L 99.2 68.0 - 132 114224859
1,2-Dichloropropane 557275 20.5 20.0 ug/L 102 34.0 - 166 114224859
2-Chloroethylvinyl ether 557275 13.3 20.0 ug/L 66.3 10.0 - 224 114224859
Benzene 557275 21.4 20.0 ug/L 107 64.0 - 136 114224859
Bromodichloromethane 557275 19.1 20.0 ug/L 95.4 65.0 - 135 114224859
Bromoform 557275 15.5 20.0 ug/L 77.4 71.0 - 129 114224859
Bromomethane (Methyl
Bromi
557275 18.8 20.0 ug/L 94.0 14.0 - 186 114224859
Carbon Tetrachloride 557275 18.1 20.0 ug/L 90.3 73.0 - 127 114224859
Chlorobenzene 557275 21.0 20.0 ug/L 105 66.0 - 134 114224859
Chloroethane 557275 21.6 20.0 ug/L 108 38.0 - 162 114224859
Chloroform 557275 21.6 20.0 ug/L 108 67.0 - 133 114224859
Chloromethane 557275 19.1 20.0 ug/L 95.3 10.0 - 204 114224859
cis-1,3-Dichloropropene 557275 17.4 20.0 ug/L 87.0 24.0 - 176 114224859
Dibromochloromethane 557275 16.6 20.0 ug/L 82.8 67.0 - 133 114224859
Ethylbenzene 557275 19.2 20.0 ug/L 96.2 59.0 - 141 114224859
Methylene chloride 557275 21.1 20.0 ug/L 106 60.0 - 140 114224859
Tetrachloroethylene 557275 20.8 20.0 ug/L 104 73.0 - 126 114224859
Toluene 557275 20.7 20.0 ug/L 104 74.0 - 126 114224859
trans-1,2-Dichloroethene 557275 20.3 20.0 ug/L 101 69.0 - 131 114224859
trans-1,3-Dichloropropene 557275 17.7 20.0 ug/L 88.6 50.0 - 150 114224859
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 21 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 15 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Trichloroethylene 557275 19.8 20.0 ug/L 99.0 66.0 - 133 114224859
Vinyl chloride 557275 17.9 20.0 ug/L 89.6 10.0 - 196 114224859
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
1,1,1-Trichloroethane 557275 19.5 18.5 20.0 75.0 - 125 97.4 92.6 ug/L 5.05 30.0
1,1,2,2-Tetrachloroethane 557275 21.9 21.8 20.0 60.0 - 140 110 109 ug/L 0.913 30.0
1,1,2-Trichloroethane 557275 21.8 20.8 20.0 71.0 - 129 109 104 ug/L 4.69 30.0
1,1-Dichloroethane 557275 22.1 21.0 20.0 72.0 - 128 110 105 ug/L 4.65 30.0
1,1-Dichloroethylene 557275 19.2 17.2 20.0 50.0 - 150 95.9 86.1 ug/L 10.8 30.0
1,2-Dichloroethane 557275 19.8 19.4 20.0 68.0 - 132 99.2 97.2 ug/L 2.04 30.0
1,2-Dichloropropane 557275 20.5 19.9 20.0 34.0 - 166 102 99.7 ug/L 2.28 30.0
2-Chloroethylvinyl ether 557275 13.3 12.3 20.0 10.0 - 224 66.3 61.4 ug/L 7.67 30.0
Benzene 557275 21.4 20.6 20.0 64.0 - 136 107 103 ug/L 3.81 30.0
Bromodichloromethane 557275 19.1 18.6 20.0 65.0 - 135 95.4 92.8 ug/L 2.76 30.0
Bromoform 557275 15.5 15.3 20.0 71.0 - 129 77.4 76.6 ug/L 1.04 30.0
Bromomethane (Methyl
Bromi
557275 18.8 18.6 20.0 14.0 - 186 94.0 93.1 ug/L 0.962 30.0
Carbon Tetrachloride 557275 18.1 17.1 20.0 73.0 - 127 90.3 85.5 ug/L 5.46 30.0
Chlorobenzene 557275 21.0 20.1 20.0 66.0 - 134 105 100 ug/L 4.88 30.0
Chloroethane 557275 21.6 19.8 20.0 38.0 - 162 108 99.0 ug/L 8.70 30.0
Chloroform 557275 21.6 20.8 20.0 67.0 - 133 108 104 ug/L 3.77 30.0
Chloromethane 557275 19.1 18.4 20.0 10.0 - 204 95.3 91.8 ug/L 3.74 30.0
cis-1,3-Dichloropropene 557275 17.4 16.9 20.0 24.0 - 176 87.0 84.6 ug/L 2.80 30.0
Dibromochloromethane 557275 16.6 15.8 20.0 67.0 - 133 82.8 78.8 ug/L 4.95 30.0
Ethylbenzene 557275 19.2 18.8 20.0 59.0 - 141 96.2 93.8 ug/L 2.53 30.0
Methylene chloride 557275 21.1 20.6 20.0 60.0 - 140 106 103 ug/L 2.87 30.0
Tetrachloroethylene 557275 20.8 19.4 20.0 73.0 - 126 104 97.0 ug/L 6.97 30.0
Toluene 557275 20.7 19.6 20.0 74.0 - 126 104 98.0 ug/L 5.94 30.0
trans-1,2-Dichloroethene 557275 20.3 19.7 20.0 69.0 - 131 101 98.7 ug/L 2.30 30.0
trans-1,3-Dichloropropene 557275 17.7 17.3 20.0 50.0 - 150 88.6 86.4 ug/L 2.51 30.0
Trichloroethylene 557275 19.8 19.3 20.0 66.0 - 133 99.0 96.4 ug/L 2.66 30.0
Vinyl chloride 557275 17.9 16.1 20.0 10.0 - 196 89.6 80.4 ug/L 10.8 30.0
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
1,1,1-Trichloroethane 1280758 19.6 0 ND 20.0 52.0 - 162 98.0 ug/L 30.0
1,1,2,2-Tetrachloroethane 1280758 22.4 0 ND 20.0 46.0 - 157 112 ug/L 30.0
1,1,2-Trichloroethane 1280758 20.6 0 ND 20.0 52.0 - 150 103 ug/L 30.0
1,1-Dichloroethane 1280758 20.8 0 ND 20.0 59.0 - 155 104 ug/L 30.0
1,1-Dichloroethylene 1280758 20.3 0 ND 20.0 0.100 - 234 102 ug/L 30.0
1,2-Dichloroethane 1280758 19.5 0 ND 20.0 49.0 - 155 97.5 ug/L 30.0
1,2-Dichloropropane 1280758 20.7 0 ND 20.0 0.100 - 210 104 ug/L 30.0
2-Chloroethylvinyl ether 1280758 16.2 0 ND 20.0 0.100 - 305 81.0 ug/L 30.0
Benzene 1280758 21.1 0 ND 20.0 37.0 - 151 106 ug/L 30.0
Bromodichloromethane 1280758 19.2 0 ND 20.0 35.0 - 155 96.0 ug/L 30.0
Bromoform 1280758 14.5 0 ND 20.0 45.0 - 169 72.5 ug/L 30.0
Bromomethane (Methyl
Bromi
1280758 19.4 0 ND 20.0 0.100 - 242 97.0 ug/L 30.0
Carbon Tetrachloride 1280758 18.6 0 ND 20.0 70.0 - 140 93.0 ug/L 30.0
Chlorobenzene 1280758 19.1 0 ND 20.0 37.0 - 160 95.5 ug/L 30.0
Chloroethane 1280758 21.4 0 ND 20.0 14.0 - 230 107 ug/L 30.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 22 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 16 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Chloroform 1280758 22.3 0 0.790 20.0 51.0 - 138 108 ug/L 30.0
Chloromethane 1280758 22.9 0 ND 20.0 0.100 - 273 114 ug/L 30.0
cis-1,3-Dichloropropene 1280758 17.2 0 ND 20.0 0.100 - 227 86.0 ug/L 30.0
Dibromochloromethane 1280758 16.4 0 ND 20.0 53.0 - 149 82.0 ug/L 30.0
Ethylbenzene 1280758 19.5 0 ND 20.0 37.0 - 162 97.5 ug/L 30.0
Methylene chloride 1280758 21.3 0 ND 20.0 0.100 - 221 106 ug/L 30.0
Tetrachloroethylene 1280758 20.6 0 ND 20.0 64.0 - 148 103 ug/L 30.0
Toluene 1280758 20.3 0 ND 20.0 47.0 - 150 102 ug/L 30.0
trans-1,2-Dichloroethene 1280758 21.3 0 ND 20.0 54.0 - 156 106 ug/L 30.0
trans-1,3-Dichloropropene 1280758 17.1 0 ND 20.0 17.0 - 183 85.5 ug/L 30.0
Trichloroethylene 1280758 20.7 0 ND 20.0 71.0 - 157 104 ug/L 30.0
Vinyl chloride 1280758 27.8 0 ND 20.0 0.100 - 251 139 ug/L 30.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
1,1,1-Trichloroethane 1280758 19.6 19.3 ND 20.0 52.0 - 162 98.0 96.5 ug/L 1.54 30.0
1,1,2,2-Tetrachloroethane 1280758 22.4 22.4 ND 20.0 46.0 - 157 112 112 ug/L 0 30.0
1,1,2-Trichloroethane 1280758 20.6 20.9 ND 20.0 52.0 - 150 103 104 ug/L 0.966 30.0
1,1-Dichloroethane 1280758 20.8 20.5 ND 20.0 59.0 - 155 104 103 ug/L 0.966 30.0
1,1-Dichloroethylene 1280758 20.3 20.7 ND 20.0 0.100 - 234 102 104 ug/L 1.94 30.0
1,2-Dichloroethane 1280758 19.5 19.0 ND 20.0 49.0 - 155 97.5 94.8 ug/L 2.81 30.0
1,2-Dichloropropane 1280758 20.7 20.6 ND 20.0 0.100 - 210 104 103 ug/L 0.966 30.0
2-Chloroethylvinyl ether 1280758 16.2 20.6 ND 20.0 0.100 - 305 81.0 103 ug/L 23.9 30.0
Benzene 1280758 21.1 20.7 ND 20.0 37.0 - 151 106 104 ug/L 1.90 30.0
Bromodichloromethane 1280758 19.2 18.2 ND 20.0 35.0 - 155 96.0 90.9 ug/L 5.46 30.0
Bromoform 1280758 14.5 14.4 ND 20.0 45.0 - 169 72.5 72.0 ug/L 0.692 30.0
Bromomethane (Methyl
Bromi
1280758 19.4 18.8 ND 20.0 0.100 - 242 97.0 94.1 ug/L 3.04 30.0
Carbon Tetrachloride 1280758 18.6 17.8 ND 20.0 70.0 - 140 93.0 89.1 ug/L 4.28 30.0
Chlorobenzene 1280758 19.1 19.0 ND 20.0 37.0 - 160 95.5 94.8 ug/L 0.736 30.0
Chloroethane 1280758 21.4 21.2 ND 20.0 14.0 - 230 107 106 ug/L 0.939 30.0
Chloroform 1280758 22.3 21.2 0.790 20.0 51.0 - 138 108 102 ug/L 5.71 30.0
Chloromethane 1280758 22.9 22.1 ND 20.0 0.100 - 273 114 110 ug/L 3.57 30.0
cis-1,3-Dichloropropene 1280758 17.2 17.0 ND 20.0 0.100 - 227 86.0 85.2 ug/L 0.935 30.0
Dibromochloromethane 1280758 16.4 15.4 ND 20.0 53.0 - 149 82.0 76.8 ug/L 6.55 30.0
Ethylbenzene 1280758 19.5 19.4 ND 20.0 37.0 - 162 97.5 97.0 ug/L 0.514 30.0
Methylene chloride 1280758 21.3 21.5 ND 20.0 0.100 - 221 106 108 ug/L 1.87 30.0
Tetrachloroethylene 1280758 20.6 20.3 ND 20.0 64.0 - 148 103 101 ug/L 1.96 30.0
Toluene 1280758 20.3 20.3 ND 20.0 47.0 - 150 102 101 ug/L 0.985 30.0
trans-1,2-Dichloroethene 1280758 21.3 20.8 ND 20.0 54.0 - 156 106 104 ug/L 1.90 30.0
trans-1,3-Dichloropropene 1280758 17.1 17.1 ND 20.0 17.0 - 183 85.5 85.4 ug/L 0.117 30.0
Trichloroethylene 1280758 20.7 20.4 ND 20.0 71.0 - 157 104 102 ug/L 1.94 30.0
Vinyl chloride 1280758 27.8 25.5 ND 20.0 0.100 - 251 139 127 ug/L 9.02 30.0
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
1,2-DCA-d4 (SURR) 557275 CCV 22.5 20.0 ug/L 112 70.0 - 130 114224857
1,2-DCA-d4 (SURR) 557275 LCS 22.0 20.0 ug/L 110 70.0 - 130 114224859
1,2-DCA-d4 (SURR) 557275 LCS Dup 21.9 20.0 ug/L 110 70.0 - 130 114224860
1,2-DCA-d4 (SURR) 557275 Blank 22.0 20.0 ug/L 110 70.0 - 130 114224861
Bromofluorobenzene
(SURR)
557275 CCV 19.8 20.0 ug/L 99.0 70.0 - 142 114224857
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 23 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 17 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Bromofluorobenzene
(SURR)
557275 LCS 19.5 20.0 ug/L 97.5 70.0 - 142 114224859
Bromofluorobenzene
(SURR)
557275 LCS Dup 19.9 20.0 ug/L 99.5 70.0 - 142 114224860
Bromofluorobenzene
(SURR)
557275 Blank 20.6 20.0 ug/L 103 70.0 - 142 114224861
Dibromofluoromethane
(SURR)
557275 CCV 20.8 20.0 ug/L 104 70.0 - 140 114224857
Dibromofluoromethane
(SURR)
557275 LCS 21.1 20.0 ug/L 106 70.0 - 140 114224859
Dibromofluoromethane
(SURR)
557275 LCS Dup 20.8 20.0 ug/L 104 70.0 - 140 114224860
Dibromofluoromethane
(SURR)
557275 Blank 20.2 20.0 ug/L 101 70.0 - 140 114224861
TolueneD8 (SURR) 557275 CCV 20.7 20.0 ug/L 104 70.0 - 140 114224857
TolueneD8 (SURR) 557275 LCS 20.9 20.0 ug/L 104 70.0 - 140 114224859
TolueneD8 (SURR) 557275 LCS Dup 21.2 20.0 ug/L 106 70.0 - 140 114224860
TolueneD8 (SURR) 557275 Blank 20.5 20.0 ug/L 102 70.0 - 140 114224861
1,2-DCA-d4 (SURR) 1280758 UNKNOWN22.3 20.0 ug/L 112 70.0 - 130 114224862
1,2-DCA-d4 (SURR) 1280758 MS 22.0 20.0 ug/L 110 70.0 - 130 114230125
1,2-DCA-d4 (SURR) 1280758 MSD 22.0 20.0 ug/L 110 70.0 - 130 114230126
Bromofluorobenzene
(SURR)
1280758 UNKNOWN20.2 20.0 ug/L 101 70.0 - 142 114224862
Bromofluorobenzene
(SURR)
1280758 MS 19.5 20.0 ug/L 97.5 70.0 - 142 114230125
Bromofluorobenzene
(SURR)
1280758 MSD 19.8 20.0 ug/L 99.0 70.0 - 142 114230126
Dibromofluoromethane
(SURR)
1280758 UNKNOWN19.7 20.0 ug/L 98.5 70.0 - 140 114224862
Dibromofluoromethane
(SURR)
1280758 MS 20.4 20.0 ug/L 102 70.0 - 140 114230125
Dibromofluoromethane
(SURR)
1280758 MSD 20.0 20.0 ug/L 100 70.0 - 140 114230126
TolueneD8 (SURR) 1280758 UNKNOWN20.9 20.0 ug/L 104 70.0 - 140 114224862
TolueneD8 (SURR) 1280758 MS 20.9 20.0 ug/L 104 70.0 - 140 114230125
TolueneD8 (SURR) 1280758 MSD 20.8 20.0 ug/L 104 70.0 - 140 114230126
EPA 608Liquid Aqueous 557283
Blank
FileUnitsMQLMDLReadingPrepSetParameter
PCB-1016 557175 ND 0.155 0.500 ug/L 114232801
PCB-1221 557175 ND 0.143 0.500 ug/L 114232801
PCB-1232 557175 ND 0.143 0.500 ug/L 114232801
PCB-1242 557175 ND 0.143 0.500 ug/L 114232801
PCB-1248 557175 ND 0.143 0.500 ug/L 114232801
PCB-1254 557175 ND 0.143 0.500 ug/L 114232801
PCB-1260 557175 ND 0.143 0.500 ug/L 114232801
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
PCB-1016 1170 1000 ug/L 117 70.0 - 130 114224967
PCB-1016 1000 1000 ug/L 100 70.0 - 130 114232807
PCB-1260 980 1000 ug/L 98.0 70.0 - 130 114224967
PCB-1260 866 1000 ug/L 86.6 70.0 - 130 114232807
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 24 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 18 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
PCB-1016 557196 9.60 10.0 ug/L 96.0 24.3 - 151 114232803
PCB-1260 557196 7.13 10.0 ug/L 71.3 23.2 - 147 114232803
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Decachlorobiphenyl 557175 Blank 104 100 ug/L 104 10.0 - 200 114232801
Tetrachloro-m-Xylene (Surr) 557175 Blank 73.1 100 ug/L 73.1 10.0 - 200 114232801
Decachlorobiphenyl 1280758 UNKNOWN0.0403 0.101 ug/L 39.9 10.0 - 200 114224969
Tetrachloro-m-Xylene (Surr) 1280758 UNKNOWN0.0632 0.101 ug/L 62.6 10.0 - 200 114224969
EPA Method 608Liquid Aqueous 557285
Blank
FileUnitsMQLMDLReadingPrepSetParameter
4,4-DDD 557175 ND 0.0194 0.025 ug/L 114231283
4,4-DDE 557175 ND 0.0161 0.025 ug/L 114231283
4,4-DDT 557175 ND 0.00591 0.010 ug/L 114231283
Aldrin 557175 ND 0.00253 0.010 ug/L 114231283
Alpha-BHC(hexachlorocyclo
hexane)
557175 ND 0.015 0.025 ug/L 114231283
Beta-BHC(hexachlorocycloh
exane)
557175 ND 0.00871 0.010 ug/L 114231283
Chlordane 557175 ND 0.00188 0.010 ug/L 114231283
Delta-BHC(hexachlorocycloh
exane)
557175 ND 0.00523 0.010 ug/L 114231283
Dieldrin 557175 ND 0.00653 0.010 ug/L 114231283
Endosulfan I (alpha) 557175 ND 0.00719 0.010 ug/L 114231283
Endosulfan II (beta) 557175 ND 0.00767 0.010 ug/L 114231283
Endosulfan sulfate 557175 ND 0.00333 0.010 ug/L 114231283
Endrin 557175 ND 0.00857 0.010 ug/L 114231283
Endrin aldehyde 557175 ND 0.0144 0.025 ug/L 114231283
Gamma-BHC(Lindane) 557175 ND 0.00897 0.010 ug/L 114231283
Heptachlor 557175 ND 0.00147 0.010 ug/L 114231283
Heptachlor epoxide 557175 ND 0.00128 0.010 ug/L 114231283
Toxaphene 557175 ND 0.00373 0.010 ug/L 114231283
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
4,4-DDD 98.9 100 ug/L 98.9 85.0 - 115 114224986
4,4-DDD 120 100 ug/L 120 85.0 - 115 * 114231289
4,4-DDE 103 100 ug/L 103 85.0 - 115 114224986
4,4-DDE 108 100 ug/L 108 85.0 - 115 114231289
4,4-DDT 94.0 100 ug/L 94.0 85.0 - 115 114224986
4,4-DDT 117 100 ug/L 117 85.0 - 115 * 114231289
Aldrin 105 100 ug/L 105 85.0 - 115 114224986
Aldrin 103 100 ug/L 103 85.0 - 115 114231289
Alpha-BHC(hexachlorocyclo
hexane)
103 100 ug/L 103 85.0 - 115 114224986
Alpha-BHC(hexachlorocyclo
hexane)
112 100 ug/L 112 85.0 - 115 114231289
Beta-BHC(hexachlorocycloh
exane)
97.3 100 ug/L 97.3 85.0 - 115 114224986
Beta-BHC(hexachlorocycloh
exane)
110 100 ug/L 110 85.0 - 115 114231289
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 25 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 19 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Delta-BHC(hexachlorocycloh
exane)
94.5 100 ug/L 94.5 85.0 - 115 114224986
Delta-BHC(hexachlorocycloh
exane)
106 100 ug/L 106 85.0 - 115 114231289
Dieldrin 94.6 100 ug/L 94.6 85.0 - 115 114224986
Dieldrin 121 100 ug/L 121 85.0 - 115 * 114231289
Endosulfan I (alpha) 98.0 100 ug/L 98.0 85.0 - 115 114224986
Endosulfan I (alpha) 117 100 ug/L 117 85.0 - 115 * 114231289
Endosulfan II (beta) 94.8 100 ug/L 94.8 85.0 - 115 114224986
Endosulfan II (beta) 117 100 ug/L 117 85.0 - 115 * 114231289
Endosulfan sulfate 89.1 100 ug/L 89.1 85.0 - 115 114224986
Endosulfan sulfate 107 100 ug/L 107 85.0 - 115 114231289
Endrin 94.1 100 ug/L 94.1 85.0 - 115 114224986
Endrin 121 100 ug/L 121 85.0 - 115 * 114231289
Endrin aldehyde 93.5 100 ug/L 93.5 85.0 - 115 114224986
Endrin aldehyde 111 100 ug/L 111 85.0 - 115 114231289
Gamma-BHC(Lindane) 92.3 100 ug/L 92.3 85.0 - 115 114224986
Gamma-BHC(Lindane) 108 100 ug/L 108 85.0 - 115 114231289
Heptachlor 88.9 100 ug/L 88.9 85.0 - 115 114224986
Heptachlor 107 100 ug/L 107 85.0 - 115 114231289
Heptachlor epoxide 97.9 100 ug/L 97.9 85.0 - 115 114224986
Heptachlor epoxide 116 100 ug/L 116 85.0 - 115 * 114231289
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
4,4-DDD 557175 0.861 1.00 ug/L 86.1 34.3 - 136 114231284
4,4-DDE 557175 0.919 1.00 ug/L 91.9 44.1 - 130 114231284
4,4-DDT 557175 1.00 1.00 ug/L 100 24.4 - 154 114231284
Aldrin 557175 0.732 1.00 ug/L 73.2 25.5 - 119 114231284
Alpha-BHC(hexachlorocyclo
hexane)
557175 0.813 1.00 ug/L 81.3 30.2 - 126 114231284
Beta-BHC(hexachlorocycloh
exane)
557175 0.916 1.00 ug/L 91.6 39.3 - 147 114231284
Delta-BHC(hexachlorocycloh
exane)
557175 0.873 1.00 ug/L 87.3 42.5 - 135 114231284
Dieldrin 557175 1.02 1.00 ug/L 102 41.6 - 140 114231284
Endosulfan I (alpha) 557175 0.927 1.00 ug/L 92.7 34.1 - 126 114231284
Endosulfan II (beta) 557175 0.925 1.00 ug/L 92.5 41.3 - 129 114231284
Endosulfan sulfate 557175 0.938 1.00 ug/L 93.8 43.6 - 142 114231284
Endrin 557175 1.01 1.00 ug/L 101 39.4 - 148 114231284
Endrin aldehyde 557175 0.928 1.00 ug/L 92.8 40.8 - 137 114231284
Gamma-BHC(Lindane) 557175 0.811 1.00 ug/L 81.1 29.9 - 130 114231284
Heptachlor 557175 0.779 1.00 ug/L 77.9 18.9 - 128 114231284
Heptachlor epoxide 557175 0.935 1.00 ug/L 93.5 42.1 - 132 114231284
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
4,4-DDD 557175 0.861 0.832 1.00 34.3 - 136 86.1 83.2 ug/L 3.43 40.0
4,4-DDE 557175 0.919 0.873 1.00 44.1 - 130 91.9 87.3 ug/L 5.13 40.0
4,4-DDT 557175 1.00 0.984 1.00 24.4 - 154 100 98.4 ug/L 1.61 40.0
Aldrin 557175 0.732 0.752 1.00 25.5 - 119 73.2 75.2 ug/L 2.70 40.0
Alpha-BHC(hexachlorocyclo
hexane)
557175 0.813 0.816 1.00 30.2 - 126 81.3 81.6 ug/L 0.368 40.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 26 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 20 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Beta-BHC(hexachlorocycloh
exane)
557175 0.916 0.869 1.00 39.3 - 147 91.6 86.9 ug/L 5.27 40.0
Delta-BHC(hexachlorocycloh
exane)
557175 0.873 0.828 1.00 42.5 - 135 87.3 82.8 ug/L 5.29 40.0
Dieldrin 557175 1.02 0.967 1.00 41.6 - 140 102 96.7 ug/L 5.33 40.0
Endosulfan I (alpha) 557175 0.927 0.885 1.00 34.1 - 126 92.7 88.5 ug/L 4.64 40.0
Endosulfan II (beta) 557175 0.925 0.883 1.00 41.3 - 129 92.5 88.3 ug/L 4.65 40.0
Endosulfan sulfate 557175 0.938 0.923 1.00 43.6 - 142 93.8 92.3 ug/L 1.61 40.0
Endrin 557175 1.01 0.951 1.00 39.4 - 148 101 95.1 ug/L 6.02 40.0
Endrin aldehyde 557175 0.928 0.895 1.00 40.8 - 137 92.8 89.5 ug/L 3.62 40.0
Gamma-BHC(Lindane) 557175 0.811 0.802 1.00 29.9 - 130 81.1 80.2 ug/L 1.12 40.0
Heptachlor 557175 0.779 0.812 1.00 18.9 - 128 77.9 81.2 ug/L 4.15 40.0
Heptachlor epoxide 557175 0.935 0.893 1.00 42.1 - 132 93.5 89.3 ug/L 4.60 40.0
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Decachlorobiphenyl 132147 CCV 96.1 100 ug/L 96.1 0.100 - 180 114224986
Decachlorobiphenyl 132147 CCV 119 100 ug/L 119 0.100 - 180 114231289
Tetrachloro-m-Xylene (Surr) 132147 CCV 100 100 ug/L 100 9.90 - 130 114224986
Tetrachloro-m-Xylene (Surr) 132147 CCV 99.4 100 ug/L 99.4 9.90 - 130 114231289
Decachlorobiphenyl 557175 Blank 104 100 ug/L 104 0.100 - 180 114231283
Decachlorobiphenyl 557175 LCS 99.8 100 ug/L 99.8 0.100 - 180 114231284
Decachlorobiphenyl 557175 LCS Dup 104 100 ug/L 104 0.100 - 180 114231285
Tetrachloro-m-Xylene (Surr) 557175 Blank 73.1 100 ug/L 73.1 9.90 - 130 114231283
Tetrachloro-m-Xylene (Surr) 557175 LCS 61.6 100 ug/L 61.6 9.90 - 130 114231284
Tetrachloro-m-Xylene (Surr) 557175 LCS Dup 65.2 100 ug/L 65.2 9.90 - 130 114231285
Decachlorobiphenyl 1280758 UNKNOWN0.0403 0.101 ug/L 39.9 0.100 - 180 114224987
Tetrachloro-m-Xylene (Surr) 1280758 UNKNOWN0.0632 0.101 ug/L 62.6 9.90 - 130 114224987
EPA Method 614Liquid Aqueous 557295
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Chlorpyrifos 557195 ND 0.0394 0.040 ug/L 114225107
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Chlorpyrifos 958 1000 ug/L 95.8 80.0 - 120 114225106
Chlorpyrifos 1180 1000 ug/L 118 80.0 - 120 114226875
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Chlorpyrifos 557195 0.727 1.00 ug/L 72.7 6.22 - 164 114225108
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Chlorpyrifos 557195 0.727 0.812 1.00 6.22 - 164 72.7 81.2 ug/L 11.0 30.0
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Tributylphosphate 132891 CCV 1180 1000 ug/L 118 0.100 - 495 114225106
Tributylphosphate 132891 CCV 1940 1000 ug/L 194 0.100 - 495 114226875
Triphenylphosphate 132891 CCV 1010 1000 ug/L 101 0.100 - 1070 114225106
Triphenylphosphate 132891 CCV 1200 1000 ug/L 120 0.100 - 1070 114226875
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 27 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 21 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Tributylphosphate 557195 Blank 1130 1000 ug/L 113 0.100 - 495 114225107
Tributylphosphate 557195 LCS 1250 1000 ug/L 125 0.100 - 495 114225108
Tributylphosphate 557195 LCS Dup 1380 1000 ug/L 138 0.100 - 495 114225109
Triphenylphosphate 557195 Blank 934 1000 ug/L 93.4 0.100 - 1070 114225107
Triphenylphosphate 557195 LCS 832 1000 ug/L 83.2 0.100 - 1070 114225108
Triphenylphosphate 557195 LCS Dup 889 1000 ug/L 88.9 0.100 - 1070 114225109
Tributylphosphate 1280758 UNKNOWN1.40 1.01 ug/L 139 0.100 - 495 114225110
Triphenylphosphate 1280758 UNKNOWN0.790 1.01 ug/L 78.2 0.100 - 1070 114225110
EPA Method 624Liquid Aqueous 557311
BFB
FileOutLimits%%ReadingRefMassSampleParameter
BFB Mass 173 557311 174 4 0.2 0 - 2.00 114225541
BFB Mass 174 557311 95.0 2066 83.5 50.0 - 100 114225541
BFB Mass 175 557311 174 142 6.9 5.00 - 9.00 114225541
BFB Mass 176 557311 174 2065 100.0 95.0 - 101 114225541
BFB Mass 177 557311 176 127 6.2 5.00 - 9.00 114225541
BFB Mass 50 557311 95.0 429 17.3 15.0 - 40.0 114225541
BFB Mass 75 557311 95.0 1068 43.2 30.0 - 60.0 114225541
BFB Mass 95 557311 95.0 2473 100.0 100 - 100 114225541
BFB Mass 96 557311 95.0 187 7.6 5.00 - 9.00 114225541
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Acrolein 557311 ND 0.883 1.00 ug/L 114225545
Acrylonitrile 557311 ND 0.697 1.00 ug/L 114225545
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
Acrolein 42.1 40.0 ug/L 105 70.0 - 130 114225542
Acrylonitrile 42.3 40.0 ug/L 106 70.0 - 130 114225542
IS Areas
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557311 LCS 31610 32430 16220 48650 114225543 557311
1,4-DichlorobenzeneD4
(ISTD)
557311 LCS Dup 31750 32430 16220 48650 114225544 557311
1,4-DichlorobenzeneD4
(ISTD)
557311 Blank 29570 32430 16220 48650 114225545 557311
ChlorobenzeneD5 (ISTD) 557311 LCS 77730 80580 40290 120900 114225543 557311
ChlorobenzeneD5 (ISTD) 557311 LCS Dup 79780 80580 40290 120900 114225544 557311
ChlorobenzeneD5 (ISTD) 557311 Blank 76420 80580 40290 120900 114225545 557311
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN30730 32430 16220 48650 114225546 1280758
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN79340 80580 40290 120900 114225546 1280758
IS RetTime
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557311 LCS 14.66 14.66 14.60 14.72 114225543 557311
1,4-DichlorobenzeneD4
(ISTD)
557311 LCS Dup 14.67 14.66 14.60 14.72 114225544 557311
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 28 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 22 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
IS RetTime
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557311 Blank 14.67 14.66 14.60 14.72 114225545 557311
ChlorobenzeneD5 (ISTD) 557311 LCS 10.96 10.96 10.90 11.02 114225543 557311
ChlorobenzeneD5 (ISTD) 557311 LCS Dup 10.96 10.96 10.90 11.02 114225544 557311
ChlorobenzeneD5 (ISTD) 557311 Blank 10.97 10.96 10.90 11.02 114225545 557311
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN14.67 14.66 14.60 14.72 114225546 1280758
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN10.97 10.96 10.90 11.02 114225546 1280758
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
Acrolein 557311 56.6 40.0 ug/L 142 0.100 - 425 114225543
Acrylonitrile 557311 42.3 40.0 ug/L 106 71.0 - 117 114225543
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
Acrolein 557311 56.6 58.4 40.0 0.100 - 425 142 146 ug/L 2.78 30.0
Acrylonitrile 557311 42.3 44.3 40.0 71.0 - 117 106 111 ug/L 4.61 30.0
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Acrolein 1280758 52.9 0 ND 40.0 70.0 - 130 132 * ug/L 30.0
Acrylonitrile 1280758 41.8 0 ND 40.0 70.0 - 130 104 ug/L 30.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Acrolein 1280758 52.9 38.8 ND 40.0 70.0 - 130 132 * 97.0 ug/L 30.6 * 30.0
Acrylonitrile 1280758 41.8 41.5 ND 40.0 70.0 - 130 104 104 ug/L 0 30.0
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
1,2-DCA-d4 (SURR) 557311 CCV 19.6 20.0 ug/L 98.0 70.0 - 130 114225542
1,2-DCA-d4 (SURR) 557311 LCS 20.5 20.0 ug/L 102 70.0 - 130 114225543
1,2-DCA-d4 (SURR) 557311 LCS Dup 20.1 20.0 ug/L 100 70.0 - 130 114225544
1,2-DCA-d4 (SURR) 557311 Blank 20.8 20.0 ug/L 104 70.0 - 130 114225545
Bromofluorobenzene
(SURR)
557311 CCV 18.2 20.0 ug/L 91.0 70.0 - 142 114225542
Bromofluorobenzene
(SURR)
557311 LCS 18.8 20.0 ug/L 94.0 70.0 - 142 114225543
Bromofluorobenzene
(SURR)
557311 LCS Dup 19.0 20.0 ug/L 95.0 70.0 - 142 114225544
Bromofluorobenzene
(SURR)
557311 Blank 19.7 20.0 ug/L 98.5 70.0 - 142 114225545
Dibromofluoromethane
(SURR)
557311 CCV 20.6 20.0 ug/L 103 70.0 - 140 114225542
Dibromofluoromethane
(SURR)
557311 LCS 20.2 20.0 ug/L 101 70.0 - 140 114225543
Dibromofluoromethane
(SURR)
557311 LCS Dup 20.3 20.0 ug/L 102 70.0 - 140 114225544
Dibromofluoromethane
(SURR)
557311 Blank 20.5 20.0 ug/L 102 70.0 - 140 114225545
TolueneD8 (SURR) 557311 CCV 18.8 20.0 ug/L 94.0 70.0 - 140 114225542
TolueneD8 (SURR) 557311 LCS 19.3 20.0 ug/L 96.5 70.0 - 140 114225543
TolueneD8 (SURR) 557311 LCS Dup 18.8 20.0 ug/L 94.0 70.0 - 140 114225544
TolueneD8 (SURR) 557311 Blank 18.9 20.0 ug/L 94.5 70.0 - 140 114225545
1,2-DCA-d4 (SURR) 1280758 UNKNOWN20.4 20.0 ug/L 102 70.0 - 130 114225546
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 29 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 23 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
1,2-DCA-d4 (SURR) 1280758 MS 20.4 20.0 ug/L 102 70.0 - 130 114229683
1,2-DCA-d4 (SURR) 1280758 MSD 20.4 20.0 ug/L 102 70.0 - 130 114229684
Bromofluorobenzene
(SURR)
1280758 UNKNOWN18.8 20.0 ug/L 94.0 70.0 - 142 114225546
Bromofluorobenzene
(SURR)
1280758 MS 19.3 20.0 ug/L 96.5 70.0 - 142 114229683
Bromofluorobenzene
(SURR)
1280758 MSD 18.5 20.0 ug/L 92.5 70.0 - 142 114229684
Dibromofluoromethane
(SURR)
1280758 UNKNOWN20.7 20.0 ug/L 104 70.0 - 140 114225546
Dibromofluoromethane
(SURR)
1280758 MS 21.1 20.0 ug/L 106 70.0 - 140 114229683
Dibromofluoromethane
(SURR)
1280758 MSD 21.1 20.0 ug/L 106 70.0 - 140 114229684
TolueneD8 (SURR) 1280758 UNKNOWN18.5 20.0 ug/L 92.5 70.0 - 140 114225546
TolueneD8 (SURR) 1280758 MS 19.2 20.0 ug/L 96.0 70.0 - 140 114229683
TolueneD8 (SURR) 1280758 MSD 18.9 20.0 ug/L 94.5 70.0 - 140 114229684
EPA Method 624Liquid Aqueous 557312
BFB
FileOutLimits%%ReadingRefMassSampleParameter
BFB Mass 173 557312 174 4 0.2 0 - 2.00 114225547
BFB Mass 174 557312 95.0 2066 83.5 50.0 - 100 114225547
BFB Mass 175 557312 174 142 6.9 5.00 - 9.00 114225547
BFB Mass 176 557312 174 2065 100.0 95.0 - 101 114225547
BFB Mass 177 557312 176 127 6.2 5.00 - 9.00 114225547
BFB Mass 50 557312 95.0 429 17.3 15.0 - 40.0 114225547
BFB Mass 75 557312 95.0 1068 43.2 30.0 - 60.0 114225547
BFB Mass 95 557312 95.0 2473 100.0 100 - 100 114225547
BFB Mass 96 557312 95.0 187 7.6 5.00 - 9.00 114225547
Blank
FileUnitsMQLMDLReadingPrepSetParameter
1,1,1-Trichloroethane 557312 ND 0.232 1.00 ug/L 114225551
1,1,2,2-Tetrachloroethane 557312 ND 0.217 1.00 ug/L 114225551
1,1,2-Trichloroethane 557312 ND 0.389 1.00 ug/L 114225551
1,1-Dichloroethane 557312 ND 0.259 1.00 ug/L 114225551
1,1-Dichloroethylene 557312 ND 0.388 1.00 ug/L 114225551
1,2-Dichloroethane 557312 ND 0.156 1.00 ug/L 114225551
1,2-Dichloropropane 557312 ND 0.267 1.00 ug/L 114225551
2-Chloroethylvinyl ether 557312 ND 0.107 1.00 ug/L 114225551
Benzene 557312 ND 0.186 1.00 ug/L 114225551
Bromodichloromethane 557312 ND 0.186 1.00 ug/L 114225551
Bromoform 557312 ND 0.549 1.00 ug/L 114225551
Bromomethane (Methyl
Bromi
557312 ND 0.338 1.00 ug/L 114225551
Carbon Tetrachloride 557312 ND 0.285 1.00 ug/L 114225551
Chlorobenzene 557312 ND 0.120 1.00 ug/L 114225551
Chloroethane 557312 ND 0.370 1.00 ug/L 114225551
Chloroform 557312 ND 0.294 1.00 ug/L 114225551
Chloromethane 557312 ND 0.304 1.00 ug/L 114225551
cis-1,3-Dichloropropene 557312 ND 0.0689 1.00 ug/L 114225551
Dibromochloromethane 557312 ND 0.119 1.00 ug/L 114225551
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 30 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 24 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Blank
FileUnitsMQLMDLReadingPrepSetParameter
Ethylbenzene 557312 ND 0.243 1.00 ug/L 114225551
Methylene chloride 557312 ND 0.231 1.00 ug/L 114225551
Tetrachloroethylene 557312 ND 0.324 1.00 ug/L 114225551
Toluene 557312 ND 0.182 1.00 ug/L 114225551
trans-1,2-Dichloroethene 557312 ND 0.256 1.00 ug/L 114225551
trans-1,3-Dichloropropene 557312 ND 0.0877 1.00 ug/L 114225551
Trichloroethylene 557312 ND 0.241 1.00 ug/L 114225551
Vinyl chloride 557312 ND 0.926 1.00 ug/L 114225551
CCV
FileOutLimits%Recover%UnitsKnownReadingParameter
1,1,1-Trichloroethane 17.2 20.0 ug/L 86.0 70.0 - 130 114225548
1,1,2,2-Tetrachloroethane 18.6 20.0 ug/L 93.0 70.0 - 130 114225548
1,1,2-Trichloroethane 17.9 20.0 ug/L 89.5 70.0 - 130 114225548
1,1-Dichloroethane 21.1 20.0 ug/L 106 70.0 - 130 114225548
1,1-Dichloroethylene 21.1 20.0 ug/L 106 70.0 - 130 114225548
1,2-Dichloroethane 18.7 20.0 ug/L 93.5 70.0 - 130 114225548
1,2-Dichloropropane 18.8 20.0 ug/L 94.0 70.0 - 130 114225548
2-Chloroethylvinyl ether 17.9 20.0 ug/L 89.5 70.0 - 130 114225548
Benzene 18.7 20.0 ug/L 93.5 70.0 - 130 114225548
Bromodichloromethane 16.5 20.0 ug/L 82.5 70.0 - 130 114225548
Bromoform 13.9 20.0 ug/L 69.5 70.0 - 130 * 114225548
Bromomethane (Methyl
Bromi
21.0 20.0 ug/L 105 70.0 - 130 114225548
Carbon Tetrachloride 16.3 20.0 ug/L 81.5 70.0 - 130 114225548
Chlorobenzene 17.8 20.0 ug/L 89.0 70.0 - 130 114225548
Chloroethane 21.5 20.0 ug/L 108 70.0 - 130 114225548
Chloroform 20.6 20.0 ug/L 103 70.0 - 130 114225548
Chloromethane 23.0 20.0 ug/L 115 70.0 - 130 114225548
cis-1,3-Dichloropropene 17.0 20.0 ug/L 85.0 70.0 - 130 114225548
Dibromochloromethane 15.7 20.0 ug/L 78.5 70.0 - 130 114225548
Ethylbenzene 17.3 20.0 ug/L 86.5 70.0 - 130 114225548
Methylene chloride 22.8 20.0 ug/L 114 70.0 - 130 114225548
Tetrachloroethylene 18.2 20.0 ug/L 91.0 70.0 - 130 114225548
Toluene 18.0 20.0 ug/L 90.0 70.0 - 130 114225548
trans-1,2-Dichloroethene 22.1 20.0 ug/L 110 70.0 - 130 114225548
trans-1,3-Dichloropropene 16.5 20.0 ug/L 82.5 70.0 - 130 114225548
Trichloroethylene 17.6 20.0 ug/L 88.0 70.0 - 130 114225548
Vinyl chloride 22.4 20.0 ug/L 112 70.0 - 130 114225548
IS Areas
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557312 LCS 31610 32430 16220 48650 114225549 557312
1,4-DichlorobenzeneD4
(ISTD)
557312 LCS Dup 31750 32430 16220 48650 114225550 557312
1,4-DichlorobenzeneD4
(ISTD)
557312 Blank 29570 32430 16220 48650 114225551 557312
ChlorobenzeneD5 (ISTD) 557312 LCS 77730 80580 40290 120900 114225549 557312
ChlorobenzeneD5 (ISTD) 557312 LCS Dup 79780 80580 40290 120900 114225550 557312
ChlorobenzeneD5 (ISTD) 557312 Blank 76420 80580 40290 120900 114225551 557312
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN30730 32430 16220 48650 114225552 1280758
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 31 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 25 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
IS Areas
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN79340 80580 40290 120900 114225552 1280758
IS RetTime
PrepSetFileOutHighLowCCVISMReadingTypeSampleParameter
1,4-DichlorobenzeneD4
(ISTD)
557312 LCS 14.66 14.66 14.60 14.72 114225549 557312
1,4-DichlorobenzeneD4
(ISTD)
557312 LCS Dup 14.67 14.66 14.60 14.72 114225550 557312
1,4-DichlorobenzeneD4
(ISTD)
557312 Blank 14.67 14.66 14.60 14.72 114225551 557312
ChlorobenzeneD5 (ISTD) 557312 LCS 10.96 10.96 10.90 11.02 114225549 557312
ChlorobenzeneD5 (ISTD) 557312 LCS Dup 10.96 10.96 10.90 11.02 114225550 557312
ChlorobenzeneD5 (ISTD) 557312 Blank 10.97 10.96 10.90 11.02 114225551 557312
1,4-DichlorobenzeneD4
(ISTD)
1280758 UNKNOWN14.67 14.66 14.60 14.72 114225552 1280758
ChlorobenzeneD5 (ISTD) 1280758 UNKNOWN10.97 10.96 10.90 11.02 114225552 1280758
LCS
OutFileLimitsRecover%UnitsKnownReadingPrepSetParameter
1,1,1-Trichloroethane 557312 17.6 20.0 ug/L 88.2 75.0 - 125 114225549
1,1,2,2-Tetrachloroethane 557312 17.6 20.0 ug/L 88.0 60.0 - 140 114225549
1,1,2-Trichloroethane 557312 18.0 20.0 ug/L 90.2 71.0 - 129 114225549
1,1-Dichloroethane 557312 23.2 20.0 ug/L 116 72.0 - 128 114225549
1,1-Dichloroethylene 557312 19.4 20.0 ug/L 97.2 50.0 - 150 114225549
1,2-Dichloroethane 557312 18.8 20.0 ug/L 93.8 68.0 - 132 114225549
1,2-Dichloropropane 557312 19.4 20.0 ug/L 97.1 34.0 - 166 114225549
2-Chloroethylvinyl ether 557312 17.4 20.0 ug/L 87.2 10.0 - 224 114225549
Benzene 557312 19.0 20.0 ug/L 94.9 64.0 - 136 114225549
Bromodichloromethane 557312 17.7 20.0 ug/L 88.4 65.0 - 135 114225549
Bromoform 557312 13.2 20.0 ug/L 66.0 71.0 - 129 114225549 *
Bromomethane (Methyl
Bromi
557312 22.1 20.0 ug/L 111 14.0 - 186 114225549
Carbon Tetrachloride 557312 17.2 20.0 ug/L 85.8 73.0 - 127 114225549
Chlorobenzene 557312 18.7 20.0 ug/L 93.6 66.0 - 134 114225549
Chloroethane 557312 22.4 20.0 ug/L 112 38.0 - 162 114225549
Chloroform 557312 21.5 20.0 ug/L 107 67.0 - 133 114225549
Chloromethane 557312 20.8 20.0 ug/L 104 10.0 - 204 114225549
cis-1,3-Dichloropropene 557312 16.8 20.0 ug/L 83.8 24.0 - 176 114225549
Dibromochloromethane 557312 15.9 20.0 ug/L 79.4 67.0 - 133 114225549
Ethylbenzene 557312 17.6 20.0 ug/L 88.0 59.0 - 141 114225549
Methylene chloride 557312 22.7 20.0 ug/L 113 60.0 - 140 114225549
Tetrachloroethylene 557312 18.7 20.0 ug/L 93.4 73.0 - 126 114225549
Toluene 557312 18.2 20.0 ug/L 91.0 74.0 - 126 114225549
trans-1,2-Dichloroethene 557312 21.0 20.0 ug/L 105 69.0 - 131 114225549
trans-1,3-Dichloropropene 557312 15.6 20.0 ug/L 78.2 50.0 - 150 114225549
Trichloroethylene 557312 17.9 20.0 ug/L 89.3 66.0 - 133 114225549
Vinyl chloride 557312 17.7 20.0 ug/L 88.4 10.0 - 196 114225549
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
1,1,1-Trichloroethane 557312 17.6 16.2 20.0 75.0 - 125 88.2 81.2 ug/L 8.26 30.0
1,1,2,2-Tetrachloroethane 557312 17.6 18.1 20.0 60.0 - 140 88.0 90.6 ug/L 2.91 30.0
1,1,2-Trichloroethane 557312 18.0 18.0 20.0 71.0 - 129 90.2 89.8 ug/L 0.444 30.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 32 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 26 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
LCS Dup
Limit%RPDUnitsLCSD%LCS%Limits%KnownLCSDLCSPrepSetParameter
1,1-Dichloroethane 557312 23.2 22.2 20.0 72.0 - 128 116 111 ug/L 4.41 30.0
1,1-Dichloroethylene 557312 19.4 18.6 20.0 50.0 - 150 97.2 93.1 ug/L 4.31 30.0
1,2-Dichloroethane 557312 18.8 18.1 20.0 68.0 - 132 93.8 90.6 ug/L 3.47 30.0
1,2-Dichloropropane 557312 19.4 18.5 20.0 34.0 - 166 97.1 92.6 ug/L 4.74 30.0
2-Chloroethylvinyl ether 557312 17.4 17.1 20.0 10.0 - 224 87.2 85.7 ug/L 1.74 30.0
Benzene 557312 19.0 17.8 20.0 64.0 - 136 94.9 89.2 ug/L 6.19 30.0
Bromodichloromethane 557312 17.7 16.6 20.0 65.0 - 135 88.4 83.0 ug/L 6.30 30.0
Bromoform 557312 13.2 13.7 20.0 71.0 - 129 66.0 68.4 * ug/L 3.57 30.0
Bromomethane (Methyl
Bromi
557312 22.1 21.3 20.0 14.0 - 186 111 106 ug/L 4.61 30.0
Carbon Tetrachloride 557312 17.2 15.7 20.0 73.0 - 127 85.8 78.4 ug/L 9.01 30.0
Chlorobenzene 557312 18.7 18.3 20.0 66.0 - 134 93.6 91.3 ug/L 2.49 30.0
Chloroethane 557312 22.4 21.2 20.0 38.0 - 162 112 106 ug/L 5.50 30.0
Chloroform 557312 21.5 20.5 20.0 67.0 - 133 107 102 ug/L 4.78 30.0
Chloromethane 557312 20.8 19.2 20.0 10.0 - 204 104 96.0 ug/L 8.00 30.0
cis-1,3-Dichloropropene 557312 16.8 15.8 20.0 24.0 - 176 83.8 79.2 ug/L 5.64 30.0
Dibromochloromethane 557312 15.9 14.8 20.0 67.0 - 133 79.4 74.2 ug/L 6.77 30.0
Ethylbenzene 557312 17.6 16.9 20.0 59.0 - 141 88.0 84.6 ug/L 3.94 30.0
Methylene chloride 557312 22.7 22.4 20.0 60.0 - 140 113 112 ug/L 0.889 30.0
Tetrachloroethylene 557312 18.7 18.0 20.0 73.0 - 126 93.4 90.2 ug/L 3.49 30.0
Toluene 557312 18.2 17.4 20.0 74.0 - 126 91.0 87.0 ug/L 4.49 30.0
trans-1,2-Dichloroethene 557312 21.0 19.8 20.0 69.0 - 131 105 99.0 ug/L 5.88 30.0
trans-1,3-Dichloropropene 557312 15.6 15.3 20.0 50.0 - 150 78.2 76.3 ug/L 2.46 30.0
Trichloroethylene 557312 17.9 17.1 20.0 66.0 - 133 89.3 85.3 ug/L 4.58 30.0
Vinyl chloride 557312 17.7 16.3 20.0 10.0 - 196 88.4 81.6 ug/L 8.00 30.0
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
1,1,1-Trichloroethane 1280758 18.2 0 ND 20.0 52.0 - 162 91.0 ug/L 30.0
1,1,2,2-Tetrachloroethane 1280758 19.0 0 ND 20.0 46.0 - 157 95.0 ug/L 30.0
1,1,2-Trichloroethane 1280758 19.6 0 ND 20.0 52.0 - 150 98.0 ug/L 30.0
1,1-Dichloroethane 1280758 24.1 0 ND 20.0 59.0 - 155 120 ug/L 30.0
1,1-Dichloroethylene 1280758 21.2 0 ND 20.0 0.100 - 234 106 ug/L 30.0
1,2-Dichloroethane 1280758 19.3 0 ND 20.0 49.0 - 155 96.5 ug/L 30.0
1,2-Dichloropropane 1280758 20.0 0 ND 20.0 0.100 - 210 100 ug/L 30.0
2-Chloroethylvinyl ether 1280758 17.4 0 ND 20.0 0.100 - 305 87.0 ug/L 30.0
Benzene 1280758 19.7 0 ND 20.0 37.0 - 151 98.5 ug/L 30.0
Bromodichloromethane 1280758 18.0 0 ND 20.0 35.0 - 155 90.0 ug/L 30.0
Bromoform 1280758 13.8 0 ND 20.0 45.0 - 169 69.0 ug/L 30.0
Bromomethane (Methyl
Bromi
1280758 23.2 0 ND 20.0 0.100 - 242 116 ug/L 30.0
Carbon Tetrachloride 1280758 17.2 0 ND 20.0 70.0 - 140 86.0 ug/L 30.0
Chlorobenzene 1280758 19.5 0 ND 20.0 37.0 - 160 97.5 ug/L 30.0
Chloroethane 1280758 23.5 0 ND 20.0 14.0 - 230 118 ug/L 30.0
Chloroform 1280758 23.1 0 0.810 20.0 51.0 - 138 111 ug/L 30.0
Chloromethane 1280758 21.2 0 ND 20.0 0.100 - 273 106 ug/L 30.0
cis-1,3-Dichloropropene 1280758 16.9 0 ND 20.0 0.100 - 227 84.5 ug/L 30.0
Dibromochloromethane 1280758 16.0 0 ND 20.0 53.0 - 149 80.0 ug/L 30.0
Ethylbenzene 1280758 18.2 0 ND 20.0 37.0 - 162 91.0 ug/L 30.0
Methylene chloride 1280758 24.0 0 0.660 20.0 0.100 - 221 117 ug/L 30.0
Tetrachloroethylene 1280758 19.8 0 ND 20.0 64.0 - 148 99.0 ug/L 30.0
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 33 of 46
1
2
3
4
Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 27 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
MS
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
Toluene 1280758 18.7 0 ND 20.0 47.0 - 150 93.5 ug/L 30.0
trans-1,2-Dichloroethene 1280758 22.3 0 ND 20.0 54.0 - 156 112 ug/L 30.0
trans-1,3-Dichloropropene 1280758 17.0 0 ND 20.0 17.0 - 183 85.0 ug/L 30.0
Trichloroethylene 1280758 18.4 0 ND 20.0 71.0 - 157 92.0 ug/L 30.0
Vinyl chloride 1280758 19.6 0 ND 20.0 0.100 - 251 98.0 ug/L 30.0
MSD
Limit%RPDUnitsMSD%MS%LimitsKnownUNKMSDMSSampleParameter
1,1,1-Trichloroethane 1280758 18.2 17.7 ND 20.0 52.0 - 162 91.0 88.6 ug/L 2.67 30.0
1,1,2,2-Tetrachloroethane 1280758 19.0 18.5 ND 20.0 46.0 - 157 95.0 92.3 ug/L 2.88 30.0
1,1,2-Trichloroethane 1280758 19.6 19.2 ND 20.0 52.0 - 150 98.0 95.8 ug/L 2.27 30.0
1,1-Dichloroethane 1280758 24.1 24.0 ND 20.0 59.0 - 155 120 120 ug/L 0 30.0
1,1-Dichloroethylene 1280758 21.2 20.0 ND 20.0 0.100 - 234 106 100 ug/L 5.83 30.0
1,2-Dichloroethane 1280758 19.3 19.7 ND 20.0 49.0 - 155 96.5 98.7 ug/L 2.25 30.0
1,2-Dichloropropane 1280758 20.0 19.8 ND 20.0 0.100 - 210 100 98.9 ug/L 1.11 30.0
2-Chloroethylvinyl ether 1280758 17.4 17.7 ND 20.0 0.100 - 305 87.0 88.6 ug/L 1.82 30.0
Benzene 1280758 19.7 19.2 ND 20.0 37.0 - 151 98.5 96.0 ug/L 2.57 30.0
Bromodichloromethane 1280758 18.0 17.6 ND 20.0 35.0 - 155 90.0 88.0 ug/L 2.25 30.0
Bromoform 1280758 13.8 13.1 ND 20.0 45.0 - 169 69.0 65.7 ug/L 4.90 30.0
Bromomethane (Methyl
Bromi
1280758 23.2 22.8 ND 20.0 0.100 - 242 116 114 ug/L 1.74 30.0
Carbon Tetrachloride 1280758 17.2 16.8 ND 20.0 70.0 - 140 86.0 84.0 ug/L 2.35 30.0
Chlorobenzene 1280758 19.5 19.3 ND 20.0 37.0 - 160 97.5 96.6 ug/L 0.927 30.0
Chloroethane 1280758 23.5 22.6 ND 20.0 14.0 - 230 118 113 ug/L 4.33 30.0
Chloroform 1280758 23.1 22.9 0.810 20.0 51.0 - 138 111 110 ug/L 0.905 30.0
Chloromethane 1280758 21.2 20.8 ND 20.0 0.100 - 273 106 104 ug/L 1.90 30.0
cis-1,3-Dichloropropene 1280758 16.9 16.1 ND 20.0 0.100 - 227 84.5 80.6 ug/L 4.72 30.0
Dibromochloromethane 1280758 16.0 15.3 ND 20.0 53.0 - 149 80.0 76.6 ug/L 4.34 30.0
Ethylbenzene 1280758 18.2 18.0 ND 20.0 37.0 - 162 91.0 90.2 ug/L 0.883 30.0
Methylene chloride 1280758 24.0 23.8 0.660 20.0 0.100 - 221 117 116 ug/L 0.858 30.0
Tetrachloroethylene 1280758 19.8 19.8 ND 20.0 64.0 - 148 99.0 99.2 ug/L 0.202 30.0
Toluene 1280758 18.7 18.9 ND 20.0 47.0 - 150 93.5 94.6 ug/L 1.17 30.0
trans-1,2-Dichloroethene 1280758 22.3 21.9 ND 20.0 54.0 - 156 112 109 ug/L 2.71 30.0
trans-1,3-Dichloropropene 1280758 17.0 16.1 ND 20.0 17.0 - 183 85.0 80.5 ug/L 5.44 30.0
Trichloroethylene 1280758 18.4 17.9 ND 20.0 71.0 - 157 92.0 89.6 ug/L 2.64 30.0
Vinyl chloride 1280758 19.6 17.7 ND 20.0 0.100 - 251 98.0 88.5 ug/L 10.2 30.0
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
1,2-DCA-d4 (SURR) 557312 CCV 19.6 20.0 ug/L 98.0 70.0 - 130 114225548
1,2-DCA-d4 (SURR) 557312 LCS 20.5 20.0 ug/L 102 70.0 - 130 114225549
1,2-DCA-d4 (SURR) 557312 LCS Dup 20.1 20.0 ug/L 100 70.0 - 130 114225550
1,2-DCA-d4 (SURR) 557312 Blank 20.8 20.0 ug/L 104 70.0 - 130 114225551
Bromofluorobenzene
(SURR)
557312 CCV 18.2 20.0 ug/L 91.0 70.0 - 142 114225548
Bromofluorobenzene
(SURR)
557312 LCS 18.8 20.0 ug/L 94.0 70.0 - 142 114225549
Bromofluorobenzene
(SURR)
557312 LCS Dup 19.0 20.0 ug/L 95.0 70.0 - 142 114225550
Bromofluorobenzene
(SURR)
557312 Blank 19.7 20.0 ug/L 98.5 70.0 - 142 114225551
Dibromofluoromethane
(SURR)
557312 CCV 20.6 20.0 ug/L 103 70.0 - 140 114225548
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 34 of 46
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Phone 903/984-0551 FAX 903/984-5914 e-Mail [email protected]
Quality Control Page 28 of 2805/01/2014Printed
Ana-Lab Corp. P.O. Box 9000 Kilgore, TX 75663
LELAP-accredited #02008
Employee Owned Integrity Caring Continual Improvement
Surrogate
FileLimits%Recover%UnitsKnownReadingTypeSampleParameter
Dibromofluoromethane
(SURR)
557312 LCS 20.2 20.0 ug/L 101 70.0 - 140 114225549
Dibromofluoromethane
(SURR)
557312 LCS Dup 20.3 20.0 ug/L 102 70.0 - 140 114225550
Dibromofluoromethane
(SURR)
557312 Blank 20.5 20.0 ug/L 102 70.0 - 140 114225551
TolueneD8 (SURR) 557312 CCV 18.8 20.0 ug/L 94.0 70.0 - 140 114225548
TolueneD8 (SURR) 557312 LCS 19.3 20.0 ug/L 96.5 70.0 - 140 114225549
TolueneD8 (SURR) 557312 LCS Dup 18.8 20.0 ug/L 94.0 70.0 - 140 114225550
TolueneD8 (SURR) 557312 Blank 18.9 20.0 ug/L 94.5 70.0 - 140 114225551
1,2-DCA-d4 (SURR) 1280758 UNKNOWN20.4 20.0 ug/L 102 70.0 - 130 114225552
1,2-DCA-d4 (SURR) 1280758 MS 20.4 20.0 ug/L 102 70.0 - 130 114230030
1,2-DCA-d4 (SURR) 1280758 MSD 20.4 20.0 ug/L 102 70.0 - 130 114230031
Bromofluorobenzene
(SURR)
1280758 UNKNOWN18.8 20.0 ug/L 94.0 70.0 - 142 114225552
Bromofluorobenzene
(SURR)
1280758 MS 19.3 20.0 ug/L 96.5 70.0 - 142 114230030
Bromofluorobenzene
(SURR)
1280758 MSD 18.5 20.0 ug/L 92.5 70.0 - 142 114230031
Dibromofluoromethane
(SURR)
1280758 UNKNOWN20.7 20.0 ug/L 104 70.0 - 140 114225552
Dibromofluoromethane
(SURR)
1280758 MS 21.1 20.0 ug/L 106 70.0 - 140 114230030
Dibromofluoromethane
(SURR)
1280758 MSD 21.1 20.0 ug/L 106 70.0 - 140 114230031
TolueneD8 (SURR) 1280758 UNKNOWN18.5 20.0 ug/L 92.5 70.0 - 140 114225552
TolueneD8 (SURR) 1280758 MS 19.2 20.0 ug/L 96.0 70.0 - 140 114230030
TolueneD8 (SURR) 1280758 MSD 18.9 20.0 ug/L 94.5 70.0 - 140 114230031
RPD is Relative Percent Difference: abs(r1-r2) / mean(r1,r2) * 100% Recover% is Recovery Percent: result / known * 100%
Blank - Method Blank; LCS - Laboratory Control Sample; CCV - Continuing Calibration Verification; MS - Matrix Spike; ICV - Initial Calibration
Verification; LDR - Linear Dynamic Range Standard; DFTPP - GC/MS Tuning Compound; BFB - GC/MS Tuning Compound
Corporate Shipping: 2600 Dudley Rd. Kilgore, TX 75662
Form rptPROJQCGrpt Created 01/27/2005 v1.0LDSClient v1.5.17.799 www.ana-lab.com
Ark-La-Miss Region: 4720 Viking Dr. Suite A Bossier City LA 71111
NELAP-accredited #T104704201
Report Page 35 of 46
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