Fastness as self shade
Dyeingdepth
(1/6 SD)
LightOxidative
bleach damageWashing Water
ISO 105-B02AATCC 16E
20AFUM&S C10A
ISO 105-C06 C2S
AATCC61-2A
ISO 105-E01
Ch Ch Ch Ch/CO Ch/CO Ch/CO
Exhaust dyeing
Yellow K-HL 0.67% 5 4-5 4-5 4-5/ 5 4-5 / 5 4-5 / 4-5
Red K-HL 1.00% 4 4 4-5 4-5 / 4 4-5 / 4-5 4-5 / 4-5
Blue K-HL 0.58% 4-5 4-5 4-5 4-5 / 4-5 4-5 / 4-5 4-5 / 4-5
Violet K-HL 0.67% 4 4 4 4-5/5 4-5/5 4-5/4-5
Grey K-HL 1.00% 4-5 4-5 3-4 4-5/4-5 4-5/4-5 4-5/4-5
Continuous dyeing
Yellow K-HL 6.67g/ 5 5 4-5 4-5/5 4-5/5 4-5/5
Red K-HL 6.67g/ 4 4-5 4-5 4-5/5 4-5/5 4-5/5
Blue K-HL 6.67g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5
Violet K-HL 7.50g/ 5 4-5 4-5 4-5/5 4-5/5 4-5/5
Grey K-HL 10.00g/ 5 4-5 4 4/5 4-5/5 4/5
HEAD OFFICE 112-31 Yeomchang-Dong Kangseo-Gu, Seoul, 157-040, Korea Tel: 82-2-3665-4001 Fax: 82-2-3660-8635E-mail: [email protected]: http://www.kyungin.co.kr
Edition 2012Copyrightⓒ2012 Kyung-In Synthetic Corporation. All rights reserved.
Kyung-In Synthetic Corporation
Synozol K-HL dyesReactive dyes
Kyung-In Synthetic Corporation
For Exhaust & Continuous dyeing
Synozol K-HL dyes*Material : Exhaust dyeing - Unmercerized cotton
Continuous dyeing - Mercerized cotton
NEW TO THE INDUSTRY
One trichromatic combination for multiple processes
Pale / Light shades with high light fastness
Extremely cost efficient
Unique range of dyes - market exclusive
Tailing / Listing in Pad Application eliminated
Perfect leveling in difficult shade area’s
Homogeneous Violet and Grey as supplementary products
Synozol K-HL dyes
Superior technical advantages with low cost
Can be used as an alternative to Vat dyes for pale shades
Proven dyestuff chemistry using just 3 core elements
Excellent Compatibility
Unique alternative for pale shades with good light fastness
In Exhaust and Continuous dyeing
Excellent
Compatibility
Excellent Reproducibilty !!Right First Time !!
LEVELING & REPRODUCIBILITY!
Easy to formulate
Earth shades
Low Sensitivity
to various dyeing
parameters
Synozol K-HL dyes
+++ : suitable++ : suitable with limits
+ : unsuitable
Exhaust +++
Padding Cold Pad Batch +++
Continuous PDPS +++
PDT ++
E-control ++
Cotton +++
Viscose rayon +++
PES/CO +++
PA/CO ++
Suitability
BrownYellow K-HL 0.33%Red K-HL 0.33%Blue K-HL 0.33%
YEL K-HLRED K-HLBLU K-HL
80.0%
100.0%
60.0%
40.0%
20.0%
0.0%0 10 20 30 40 50 60
min.
YEL K-HLRED K-HLBLU K-HL
80.0%
100.0%
60.0%
40.0%
20.0%
0.0%0 10 20 30 40 50 60
min.
2min 5min 10min 20min 45min 60minFixation time
Cotton
Rayon
Exha
ust d
yein
g
Synozol K-HL dyes are specially designed for pale shade dyeing,
giving improved benefits in terms of reproducibility and good light
fastness for both exhaust and continuous dyeing.
In the past, difficult shades (earth tones, greys, olives) gave problems of leveling and
light fastness in exhaust dyeing and tailing /listing issues when dyed continuously.
Vat dyes were invariantly the only alternative UNTIL NOW!
Shade (1/6 Standard Depth) in Exhaust dyeing
Synozol K-HL dyes
Yellow K-HL0.67%
Red K-HL1.00%
Blue K-HL0.58%
EXHAUST DYEING
For Cotton For Rayon
Flexible Application methods(Exhaust & Continuous dyeing)
PERFECT CONSISTENCY & REPRODUCIBILITY!
Yellow K-HL 0.33%Red K-HL 0.33%Blue K-HL 0.33%
Recipe Yellow K-HL 0.50%Red K-HL 0.25%Blue K-HL 0.25%
Yellow K-HL 0.25%Red K-HL 0.25%Blue K-HL 0.50%
Combination
Brown Olive Grey
Fastness
Low Sensitivity For Right First Time
Soda ash & Glauber’s salt
-1Da
Db
1
0.5
-0.5
-1
0
1
4
5926 8
3
-0.5 0.5 1
Soda ash(g/ ) 10 15 20
Glauber’s Salt (g/ )
20 1 2 3
30 4 5(Std) 6
40 7 8 9
Time & Temperature
-1Da
Db
1
0.5
-0.5
-1
0
17
15
141318
12
16
1011
-0.5 0.5 1
Time(min) 30 40 50
Temperature(C˚)
55 10 11 12
60 13 14(Std) 15
65 16 17 18
Exha
ust d
yein
g
Low Sensitivity to Dyeing Factors in PDPS
CONTINUOUS DYEING
3
4
5
6
7
2
1 standard condition Salt 200g/ Soda ash 20g/ NaOH 10ml/ Time 60sec
Soda(g/ ) / NaOH(ml/ )
+5/5
+60Time(sec)
Salt(g/ )
+50-5/5
-50
-30
5
3
6
7
4
2 1
duller brighterDC
gree
ner
redd
erDH
-1.5 -1
1.5
1
0.5
-0.5
-1
-1.5
-0.5 1 1.5
0.5
2 34
5
6 17
Continuous and cold pad batch dyers major problems come from tailing and side/center
shade difference when pale shades are produced. Even when light fastness is achieved the
shade continuity remained an issue UNTIL NOW!
Shade (1/6 Standard Depth) in Continuous dyeing
Synozol K-HL dyes
Yellow K-HL6.67g/
Red K-HL6.67g/
Blue K-HL6.67g/
Cont
inuo
us d
yein
g
Light Oxidativebleach damage Washing Water
ISO 105-B02 AATCC 16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
Ch Ch Ch Ch CO Ch CO Ch CO
Brown 4 4 4 4-5 5 4-5 5 4-5 5
Olive 4 4 4 4-5 5 4-5 5 4-5 5
Grey 4 4 4 4-5 5 4-5 5 4-5 5
Synozol Violet K-HL and Synozol Grey K-HL were developed to achieve easily, critical Violet and Grey pale shades with
excellent light fastness properties, good reproducibility which are difficult to dye level with trichromatic combinations.
Homogeneous dyes
Combination
Shade (1/6 Standard Depth)
Light Oxidative bleach damage Washing Water
ISO 105-B02
AATCC16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
Ch Ch Ch Ch CO Ch CO Ch CO
Recipe1 4 4 4 4-5 5 4-5 5 4-5 5
Recipe2 4 4 4 4-5 5 4-5 5 4-5 5
Recipe3 4-5 4-5 4 4-5 5 4-5 5 4-5 5
Recipe4 4 4-5 4 4-5 5 4-5 5 4-5 5
Recipe1 4 3-4 4 4-5 5 4-5 5 4-5 5
Recipe2 4 4 4-5 4-5 5 4-5 5 4-5 5
Recipe3 4-5 4-5 3-4 4 5 4-5 5 4-5 5
Recipe4 4 4-5 3-4 4 5 4-5 5 4-5 5
Cont
inuo
us d
yein
g
No Tailing & Listing
Yellow K-HL 1.10g/Red K-HL 0.90g/Blue K-HL 0.78g/
Recipe Yellow K-HL 4.05g/Red K-HL 3.12g/Blue K-HL 2.40g/
Yellow K-HL 3.20g/Red K-HL 2.50g/Blue K-HL 4.00g/
Combination
LT. Stone
Exhaust dyeing
Exha
ust d
yein
g
Continuous dyeing
Cont
inuo
us d
yein
g
Violet K-HL 0.10%Yellow K-HL 0.02%
Violet K-HL 1.0g/Yellow K-HL 0.2g/
Recipe1
Violet K-HL 0.10%Blue K-HL 0.02%
Violet K-HL 1.0g/Blue K-HL 0.2g/
Recipe2
Grey K-HL 0.10%Yellow K-HL 0.02%
Grey K-HL 1.0g/Yellow K-HL 0.2g/
Recipe3
Grey K-HL 0.10%Violet K-HL 0.02%
Grey K-HL 1.0g/Violet K-HL 0.2g/
Recipe4
LT. Brown Steel Grey
Fastness
Light OliveSynozol Yellow K-HL 2.62g/Synozol Red K-HL 2.89g/Synozol Blue K-HL 3.19g/
Left102%CMC DE= 0.2
Center100% (STD)CMC DE= 0.0
Right98%CMC DE= 0.2
Listing PropertyTailing Property
Start100% (STD)CMC DE= 0.0
End97%CMC DE= 0.3
Violet K-HL0.67%
Violet K-HL7.5g/
Grey K-HL1.00%
Grey K-HL10.0g/
Exha
ust
dyei
ngCo
ntin
uous
dy
eing
Light Oxidativebleach damage Washing Water
ISO 105-B02 AATCC 16E 20AFU M&S C10A ISO 105-C06 C2S AATCC 61-2A ISO 105-E01
Ch Ch Ch Ch CO Ch CO Ch CO
LT. Stone 4 4-5 4-5 4-5 5 4-5 5 4-5 5
LT. Brown 4 4 4-5 4-5 5 4-5 5 4-5 5
Steel Grey 4 4 4 4-5 5 4-5 5 4-5 5
60˚C10
,30
,30
,40
,30,
Auxiliary Dye Glauber's salt addition Soda ash addition Washing off
* Applicable in : - Cold Pad Batch (minimum 24hours batching time for Grey K-HL) - Pad-dry-thermofix - E-control
Exha
ust d
yein
g
Cont
inuo
us d
yein
g
Trichromatic Combination
Recommended dyeing process Recommended dyeing process
Trichromatic CombinationEXHAUST DYEING
Dye(%o.w.f) <0.1% 0.1-0.5% 0.5-1.0%
Glauber’s salt g/ 20 30 40
Soda ash g/ 10 15 15
Unmercerized Cotton
Washing offPad Dry SteamPad
Chemical Amount
Padding
Synozol Dyes Xg/
Migration Inhibitor 10g/
Wetting Agent 1g/
Reduction Inhibitor 1g/
Liquor Temperature 25˚C
Liquor Pick up 60%
DryingTemperature 120˚C
Time 1min
Alkali Padding
Soda ash 20g/
Caustic soda(38˚Be) 10m /
Glauber’s salt 200g/
Liquor Temperature 25˚C
Liquor Pick up 80%
Steaming (Fixation)
Temperature 102˚C
Time 1min
CONTINUOUS DYEING
Yellow K-HL 1.0%o.w.f
Y + R + B 0.67+0.17+0.17%o.w.f
Y + R0.67+0.33%o.w.f
Y + B0.67+0.33%o.w.f
Y + R + B 0.33+0.33+0.33%o.w.f
Y + R + B 0.33+0.50+0.17%o.w.f
Y + R0.33+0.67%o.w.f
Y + R + B 0.33+0.17+0.50%o.w.f
Y + B0.33+0.67%o.w.f
R + B0.50+0.50%o.w.f
R + B0.67+0.33%o.w.f
R + B0.83+0.17%o.w.f
Red K-HL1.0%o.w.f
R + B0.33+0.67%o.w.f
R + B0.17+0.83%o.w.f
Blue K-HL1.0%o.w.f
Yellow K-HL10.0g/
Y + R + B 6.7+1.7+1.7g/
Y + R6.7+3.3g/
Y + B6.7+3.3g/
Y + R + B 3.3+3.3+3.3g/
Y + R + B 3.3+5.0+1.7g/
Y + R3.3+6.7g/
Y + R + B 3.3+1.7+5.0g/
Y + B3.3+6.7g/
R + B5.0+5.0g/
R + B6.7+3.3g/
R + B8.3+1.7g/
Red K-HL10.0g/
R + B3.3+6.7g/
R + B1.7+8.3g/
Blue K-HL10.0g/
30,