Download pdf - pine oil MSDS

Pine Oil, White

Oil of Pine; Oils, Pine; Unipine; Yarmor pine oil

Not available.

Not available.

Not available.

TK5100000

8002-09-3

P1644, PI113

Not available.

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

CALL (310) 516-8000

SPECTRUM LABORATORY PRODUCTS INC.14422 S. SAN PEDRO STREETGARDENA, CA 90248

22 0

Material Safety Data SheetNFPA HMIS Personal Protective Equipment

Section 1. Chemical Product and Company Identification

Common Name/Trade Name

CatalogNumber(s).

CAS#

RTECS

CI#

Manufacturer

Synonym

Chemical Name

Chemical Family

IN CASE OF EMERGENCYCHEMTREC (24hr) 800-424-9300

Chemical Formula

Supplier

See Section 15.

Commercial Name(s) Not available.

TSCA TSCA 8(b) inventory: Pine Oil

220

Health Hazard

Fire Hazard

Reactivity

Page Number: 1

Pine Oil: ORAL (LD50): Acute: 3200 mg/kg [Rat]. DERMAL (LD50): Acute: 5000 mg/kg [Rabbit].

1) Pine Oil, White 8002-09-3 100

Toxicological Dataon Ingredients

Name

Section 2.Composition and Information on IngredientsExposure Limits

TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by WeightCAS #

Hazardous in case of skin contact (irritant), of eye contact (irritant). Slightly hazardous in case of skin contact(permeator), of ingestion, of inhalation.CARCINOGENIC EFFECTS: Not available.MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available.Repeated or prolonged exposure is not known to aggravate medical condition.

Section 3. Hazards IdentificationPotential Acute HealthEffects

Potential Chronic HealthEffects

Continued on Next Page

Pine Oil, White Page Number: 2

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptomsappear.

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Removecontaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Getmedical attention.

Not available.

Not available.

Section 4. First Aid MeasuresEye Contact

Skin Contact

Serious Skin Contact

Inhalation

Serious Inhalation

Ingestion

Serious Ingestion

Not available.

Combustible.

Not available.

CLOSED CUP: 78C (172.4F).

Not available.

SMALL FIRE: Use DRY chemical powder.LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Flammable in presence of open flames and sparks, of heat.

Not available.

Risks of explosion of the product in presence of mechanical impact: Not available.Risks of explosion of the product in presence of static discharge: Not available.

Not available.

Section 5. Fire and Explosion DataFlammability of the Product

Auto-Ignition Temperature

Flash Points

Flammable Limits

Products of Combustion

Fire Hazards in Presence ofVarious Substances

Explosion Hazards inPresence of VariousSubstances

Fire Fighting Mediaand Instructions

Special Remarks onFire Hazards

Special Remarks onExplosion Hazards

Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Combustible material.Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Finish cleaning by spreadingwater on the contaminated surface and allow to evacuate through the sanitary system.

Section 6. Accidental Release MeasuresSmall Spill

Large Spill



Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoidall possible sources of ignition (spark or flame).

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do notingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical adviceimmediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatiblessuch as oxidizing agents.

Section 7. Handling and StoragePrecautions

Storage

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below theirrespective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-stationlocation.

Splash goggles. Lab coat. Gloves.Appropriate respiratory protection is required when exposure to airborn comtaminants exceed acceptable limits and/ifwhen used in an area with inadequate general ventilation or no local exhaust (fume hood). Respirators should beselected and used in accordance with OSHA, Subpart 1(29CFR 1910.134). Be sure to use an approved/certifiedrespirator or equivalent.

Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialistBEFORE handling this product.

TWA: 20 (ppm)Consult local authorities for acceptable exposure limits.

Section 8. Exposure Controls/Personal ProtectionEngineering Controls

Personal Protection

Personal Protection in Caseof a Large Spill

Exposure Limits

212.22C (414F)

Liquid.

Not available.

Not available.

-10C (14F)

0.938 - 0.946 @ 15.6 C.(Water = 1)

>1 (Air = 1)0.1 kPa (@ 20C)

Not available.

Not available.

Not available.

Very slightly soluble in cold water.

Not available.

Not available.

Not available.

Pine

Not available.

Colorless to light yellow.

Section 9. Physical and Chemical PropertiesPhysical state andappearance

Odor

Taste

ColorMolecular Weight

pH (1% soln/water)

Boiling Point

Melting Point

Critical Temperature

Specific Gravity

Vapor Pressure

Vapor Density

Volatility

Odor Threshold

Water/Oil Dist. Coeff.

Ionicity (in Water)

Dispersion Properties

Solubility



The product is stable.

Not available.

Reactive with oxidizing agents.

Not available.

Not available.

Not available.

Heat, ignition sources, incompatible materials

Section 10. Stability and Reactivity DataStability

Instability Temperature

Conditions of Instability

Incompatibility with varioussubstances

Corrosivity

Special Remarks onReactivity

Special Remarks onCorrosivity

Polymerization Will not occur.

Absorbed through skin. Eye contact. Inhalation.

Acute oral toxicity (LD50): 3200 mg/kg [Rat].Acute dermal toxicity (LD50): 5000 mg/kg [Rabbit].

Hazardous in case of skin contact (irritant).Slightly hazardous in case of skin contact (permeator), of ingestion, of inhalation.

Not available.

Not available.

Acute Potential Health Effects:Skin: Causes skin irritation. It can be absorbed through the skin.Eyes: Causes eye irritation. May cause slow healing eye injury and blindness.Inhalation: Inhalation of mist or vapor may cause respiratory tract irritation with coughing, respiratory depression.Ingestion: Can cause gastroenteritis with nausea, vomiting. May affect behavior/central nervous system (ataxia,excitement, headache), cardiovascular system (hypotension, bradycardia). Possible aspiration into the lungs. Maycause chemical pneumonitis if aspirated into the lungs.Chronic Potential Health Effects:Inhalation: Prolonged or repeated inhalation may affect behavior/central nervous system. May cause asthmaticallergic reaction.Skin: Prolonged or repeated skin contact may cause contact allergic dermatitis.

Not available.

Section 11. Toxicological InformationRoutes of Entry

Toxicity to Animals

Chronic Effects on Humans

Other Toxic Effects onHumans

Special Remarks onToxicity to Animals

Special Remarks onChronic Effects on Humans

Special Remarks on otherToxic Effects on Humans

Not available.

Not available.

Possibly hazardous short term degradation products are not likely. However, long term degradation products mayarise.

Not available.

Not available.

Section 12. Ecological InformationEcotoxicity

BOD5 and COD

Products of Biodegradation

Toxicity of the Productsof Biodegradation

Special Remarks on theProducts of Biodegradation



Section 13. Disposal ConsiderationsWaste Disposal Waste must be disposed of in accordance with federal, state and local environmental control

regulations.

DOT Classification CLASS 3: Flammable liquid.

Not available.

UNNA: 1272 : Pine Oil PG: III

Section 14. Transport Information

Identification

DOT (Pictograms)

Special Provisions forTransport

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).EINECS: This product is not on the European Inventory of Existing Commercial Chemical Substances.Canada: Listed on Canadian Domestic Substance List (DSL).China: Listed on National Inventory.Japan: Not listed on National Inventory (ENCS).Korea: Listed on National Inventory (KECI).Philippines: Listed on National Inventory (PICCS).Australia: Listed on AICS.

02

2220 j

CLASS B-3: Combustible liquid with a flash point between 37.8C (100F) and 93.3C(200F).

R36/38- Irritating to eyes and skin.

Section 15. Other Regulatory Information and Pictograms

Other Regulations

Other Classifications WHMIS (Canada)

DSCL (EEC)

HMIS (U.S.A.) Health HazardFire Hazard

Reactivity

National Fire ProtectionAssociation (U.S.A.)

Personal Protection

Health

Flammability

Reactivity

Specific hazard

WHMIS (Canada)(Pictograms)

Federal and StateRegulations

Connecticut hazardous material survey.: Pine OilNew Jersey: Pine OilTSCA 8(b) inventory: Pine Oil

CaliforniaProposition 65Warnings

California prop. 65: This product contains the following ingredients for which the State of California has found tocause cancer which would require a warning under the statute: No products were found.California prop. 65: This product contains the following ingredients for which the State of California has found tocause birth defects which would require a warning under the statute: No products were found.

S26- In case of contact with eyes, rinseimmediately with plenty of water and seekmedical advice.S37- Wear suitable gloves.



DSCL (Europe)(Pictograms)

TDG (Canada)(Pictograms)

ADR (Europe)(Pictograms)

Protective Equipment

Wear appropriate respirator when ventilationis inadequate.

Lab coat.

Splash goggles.

Gloves.

Not available.

Not available.

CALL (310) 516-8000

All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials,deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actualconditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.

Notice to Reader

Verified by Sonia Owen.Printed 10/7/2008.

Validated by Sonia Owen on 10/6/2008.

Other SpecialConsiderations

References

Section 16. Other InformationMSDS Code P3890