MATERIAL SAFETY DATA SHEET
NOVEMBER 2014
MOLIROX
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1. PRODUCT IDENTIFICATION
Supplier Company: Solchem Ltda. Address: Don Carlos 2939 Of.608. Las Condes- Santiago Telephone Number: +56-22 3349 442 Fax Number: +56-22 3349 397 Emergency Number: RITA – CHILE
In case of Emergency, Call: +56 22 7771 994 Manufacturer Sipcam S.p.A. Address: Via Giam Galeazzo 3. Milano - Italy Telephone Number: 0039-(0) 371-5961 Fax Number: 0039-(0) 371-71408 Emergency Number: + 39 0371 5961 Information about MSDS [email protected] 2. COMPOSITION/INFORMATION ON INGREDIENTS Product Name: MOLIROX Hazard Identification: Hazards Class or Division 6.1 Pesticide, liquid, toxic. Secondary Risk: Class 3 - Flammable liquid. Chemical Formula: C9H17NOS Chemical Name (IUPAC): S-ethyl hexahydro-1-H-azepine-1-carbothioate Concentration: Molinate 74,7 % w/v (747 g/L); Equivalent to 72.6% w/w CAS Number: 2212-67-1
UN/ID Number: 2903 - Pesticide, liquid, toxic.
3. HAZARDS IDENTIFICATION
CLASIFICATION a)Risks to People´s Health:
Slightly dangeours substance. Class II (Yellow label).
Inhalation, Long Term Exposition:
Symptoms of acute exposure.
Symptoms may include salivation, sweating, headache, blurred vision, tears and nausea .
In case of skin contact: Causes mild skin irritation In case of eyes contact: Causes eye and redness irritation. In case of ingestion: Harmful if swallowed. b) Environmental Hazards : Very toxic to acuatic organismos. May causes adverse effects
to acuatic environmental.
c) Unusual Fire, Explosion and Reactivity Hazards:
Flammability.
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MATERIAL SAFETY DATA SHEET
NOVEMBER 2014
MOLIROX
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4. FIRST AID MEASURES
Ingestion:
If swallowed call a doctor immediately for treatment advice. DO NOT INDUCE VOMITING. Do not give anything by mouth to an unconscious person.
Inhalation: If inhaled, move person to fresh air. If person is not breathing, call a doctor immediately, and then give artificial respiration, preferably mouth to mouth if possible.
Eye Contact: Hold eye open and rinse slowly and gently with water for 15 – 20 minutes. Call a doctor for treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a doctor for treatment advice.
5. FIRE FIGHTING MEASURES
In case of Fire: Use dry chemical, foam or CO2 extinguishing media.
Specific Risks:
During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion.
Firefighter Equipment: Hazards Decomposition Products:
Phosphorus oxides Sulfide dioxide Nitrogen Oxides and Monoxide and Carbon dioxide
Wear full protective clothing and self-contained breathing apparatus. Can decompose at high temperatures forming toxic gases.
6. ACCIDENTAL RELEASE MEASURES
Personal safety Precautions:
Wear chemical resistant gloves and glasses.
Environmental Precautions: Clean up Methods:
Contain the spill to prevent it from spreading, contaminating soil, or entering sewage and drainage systems or any body of water. Water runoff can cause environmental damage. If water is used to fight fire, dike and collect runoff. Clean up spills immediately. If a liquid, cover entire spill with absorbing material and place into compatible disposal container, then arrange for disposition.
MATERIAL SAFETY DATA SHEET
NOVEMBER 2014
MOLIROX
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7. HANDLING AND STORAGE
Precautions for Safe Handiling: Keep in well-sealed containers. Prevent eating, drinking, tobacco use, and cosmetic application in areas where there is a potential for exposure to the material. Wash thoroughly with soap and water after handling. Before opening the container, read very well the label. Wear chemical –resistant gloves, coveralls, socks and chemical- resistant footwear. For overead exposure, wear chemical- resistant headgear. Prevent eating, drinking, tobacco usage and cosmetic application in areas where there is a potential for exposure to the material. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airbone levels below exposure limits.
Conditions for Safe Storage: Store the material in a well-ventilated, secure area, out of reach of
children and domestic animals. Do not store food, beverages or tobacco products in the storage area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Breathing Protection: Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels blow exposure levels.
Eye Protection: Wear chemical splash goggles. Facilities utilizing this material should be equipped with an eyewash facility and safety shower.
Skin and body Protection:
Wear chemical resistant glasses, gloves, coveralls, socks and chemical resistant footwear.
Hygiene Aids: Remove and discard contaminated clothing and wash the area with soap an water. Keep away from children and domestic animals.
9. PHYSICAL AND CHEMICAL PROPERTIES Formulation: Liquid formulation Color: Soft Yellow Odor: Slight aromatic pH: 7-9 Boiling Point: Information Not available Ignition Point: 27º C Auto- ignition temperature: 248 °C Solubility in H2O: Soluble in water Density 1,025 – 1,035 g/mL (a 20ºC)
MATERIAL SAFETY DATA SHEET
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MOLIROX
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10. STABILITY AND REACTIVITY
Stability: Stable under normal use and storage conditions, like well- ventilated
area. Do not storage or transport next to food for human consumption.
Conditions for Storage: :
The containers must be kept hermetically sealed and stored in a dry, fresh and well ventilated place. They must be carefully opened and manipulated.
Material to Avoid:
Incompatible with alkaline substances as lime, lime sulfur, strong acids and strongly oxidizing compounds.
Toxic fumes from thermal Decomposition:
Monoxide and carbon dioxide, nitrogen oxides (NOx), phosphorus compounds, sulfide dioxide and mercaptans.
Dangerous products from Ignition:
Nitrogen oxides (NOx), carbon monoxide, phosphorus oxides (P2O5) and sulfide dioxide.
Proper Handling: It is forbidden to eat, drink or smoke while its handling. Any open container should be carefully sealed. The hands must be washed before breaks and at the end of the work.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity/Irritation Studies: Oral (LD50) : 483 mg/kg Species: Rat Dermal (LD50) : 4.350 mg/kg Species: Rat Ingestion(LC50) : 1,39 mg/kg
Species: Rat
Systemic and local Effects:
Symptoms may include salivation, sweating, headache, blurred vision, tears and nausea.
Skin Contact: Irritating Eye Contact : Skin Sensitization:
Irritating Slightly Sensitizer
Specific effects: Principal routes of exposure are skin contact and inhalation. The product could be absorbed through the skin, and generate some liver damage.
12. ECOLOGICAL INFORMATION Toxicity to aquatic Organisms:
Algae: EC50 (96 h) 0.22 mg/L (Selenastrum capricornutum) Microcrustaceans: EC50 (48 h) 14.9 mg/L (Daphnia magna) Fishes: LC50 (96 h) 16 mg/L (O. mykiss) Persistence and degradation: Do not exist available relevant data
Environmental Toxicity:
Bioaccumulation Potential. Kow logP 2.88 (--) (n-octanol/water) Soil Mobility: Do not exist available relevant data.
Ecotoxicological Effects:
-Observation: Extremely toxic for fishes -Aerobic degradation: DT50 8 – 25 days in soil.
MATERIAL SAFETY DATA SHEET
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MOLIROX
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13. DISPOSAL CONSIDERATIONS
DISPOSAL: Do not reuse product containers. Dispose of products containers, and
residues according to local, state, and federal health and environmental regulations.
INTERNATIONAL REGULATIONS: Rail Transport (RID / ADR): Hazards Class or Division 6.1
Secondary Risk: Class 3 – Flammable liquid. Packing Group: III UN/ID Number: 2903 Pesticide, liquid, toxic.
Maritime Transport (IMO/IMDG): Hazards Class or Division 6.1 Secondary Risk: Class 3 - Flammable liquid. Packing Group: III UN/ID Number: 2903 Pesticide, liquid, toxic.
Air Transport (ICAO / IATA): Hazards Class or Division 6.1 Secondary Risk: Class 3 - Flammable liquid. Packing Group: III UN/ID Number: 2903 Pesticide, liquid, toxic.
15. REGULATORY INFORMATION
International Regulations: Information Not Available. Chilean Regulations: NCh 382.
NCh 2120/3 NCh 2120/6 NCh 2190
Labeling Logo: Safety Logo 8 Anexo K. Safety Logo 14 Anexo Q. NCh 2190. 2003
16. OTHER INFORMATION
Reasonable care has been taken in the preparation of this information, but it doesn´t waranty the merchantability or any other warranty, expressed or implied, with respect to this information. Because we can´t control all the conditions under the products is going to be apply, every user must check all the recommendation indicated in this material safety data sheet, and be sure if they are in the specific context to his purpose.
14. TRANSPORT INFORMATION
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