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IMCD Brazil + Ingevity A new partnership
Ingevity High Performance Additives
Who We Are Bold, Energetic, Ingenious and Genuine
Why We’re Here Purify, Protect and Enhance
What’s Important to Us § Safety and Sustainability § Customers § People
§ Integrity and Ethical Behavior § Creativity and Innovation § Commitment to Excellence
What We Want to Be § Recognized leader in our markets § Proud of where we work § Positive influence in our communities
Our History
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1846 1888 1900s 1934 1954 1964 1977
1984 2003 1997 2002 2011 2012
Jan-2015 Jun-2015 Jul-2015 Sep-2015 May-2016 Our Future
Ingevity announced as
name of specialty
chemicals business
MWV merges with RockTenn
to become WestRock
Ingevity Zhuhai, China carbon facility
opened
Ingevity spinoff from
WestRock
A thriving specialty
chemicals and materials company
Ellis, Chaflin & Co. founded,
later Mead Paper Company
Piedmont Pulp & Paper Co.
founded, later Westvaco
Carbon production begins at
Tyrone, Pa. (1914) and Luke,
Md. (1931)
Tall oil distillation and lignin
Development began in
Covington, Va.
Pine chemicals production moved to
Charleston, S.C.
Formal incorporation
of SCD businesses
DeRidder, La. plant added
to operations base
Commercial Applications
Center established
in Shanghai, China
Wickliffe, Ky. Carbon Plant
added to operations base
Mead and Westvaco
merged to form MeadWestvaco,
rebranded to MWV in 2008
Purification Materials
Wujiang (PMW) China carbon plant added to
operations base
MWV adds Brazil locations
& DRT Alliance formed
MWV announces plans to separate
specialty chemicals business
St. Johns Chemical added to
operations base
116 202 0
80 25 107
255 133 31
77 87 95
115 182 50
6 91 186
196 184 170
Ingevity High Performance Additives
Meet Ingevity § Headquarters: Charleston, South Carolina § Formerly known as: MWV Specialty Chemicals, spun off May 2016
§ Named #1 U.S. spinoff by Forbes
§ Sales: $900+ Million (2016) § Employees: 1,500+
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The meaning behind Ingevity
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Purify Protect Enhance
Purifying air and water. Protecting crops and roads.
Enhance metalworking cuts and oilfield drilling performance.
Ingevity’s Lubricants Group
$10M+ !in growth
11 globally located team
members
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Launch AltaLUB 5300
in 2016
DeRidder, La.
Waynesboro, Ga.
Covington, Va.
Wickliffe, Ky.
Zhuhai, China
Wujiang, China
Shanghai, China
Charleston, S.C. Lille, France
Charleston, S.C.
Manufacturing Technical Administration and Sales
116 202 0
80 25 107
255 133 31
77 87 95
115 182 50
6 91 186
196 184 170
Performance Chemicals Performance Materials
Our Global Presence
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The Value of our Products
• Adhesives • Publication Inks • Paper Chemicals • Rubber
• Oilfield • Asphalt • Metalworking • Chemical Intermediates
• Coatings • Lubricants • Soaps & Detergents • Mining
• Nutraceuticals • Bio-fuels • Binders
Ingevity Value Added Processing End Markets
Fatty Acids & Distilled Tall Oil Rosin Bio-fractions
Pulp Mill
Crude Tall Oil
Bio-Refinery
IMCD Brazil + Ingevity"
• Helps broaden Ingevity’s territory and allows for better service tocustomers in Brazil
• Increases IMCD Brazil’s product portfolio
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High Performance Lubricant Additives
Have you heard? We’re not just TOFA & DTO anymore.
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Key Functionalities of our Product Strategy
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Lubrication
Emulsification Corrosion Inhibition
Lubrication Lubrication
Corrosion Corrosion Inhibition Emulsification Emulsification Emulsification
Ingevity High Performance Additives
Ingevity’s Metalworking Fluid Additives
Category DTO TOFA Diacid 1550 AltaLUB 5300
Co-emulsifiers " " " "
Surfactants (wetting agents) " " "
Corrosion Inhibitors "
Lubricity Additives " " " "
Couplers "
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TOFA is primarily used by customers to create derivatives. Benefits: § Lubricity agent
§ Low viscosity allows easy handling
§ Rosin content lends less bioactivity relative to vegetable alternatives
§ Multiple reactive sites for derivatization
Metalworking TOFA
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Tall Oil Fatty Acids (TOFA)
Palmitic acid (C16:0) CH3 O
OH
O
OH
CH3Stearic acid (C18:0)
Oleic acid (C18:1)
Linoleic acid (C18:2) C H 3 O H
O C H
3 O H
O
Isomer ratios determined by the CTO – pine trees change regionally so TOFA varies
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Tall Oil Based Derivatives
§ TOFA is an ideal base material for derivatization
§ Many tall oil derivatives are used in lubricants
C H 3
O H
O
C H 3 O H
O
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Tall Oil Based Derivatives
Esters § Fuel lubricity additives § Metalworking fluid lubricants § Can be ethoxylated to make non-ionic surfactants
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Tall Oil Based Derivatives
Amides § Emulsifiers and lubricants for Metalworking § Corrosion inhibitors § Detergents in fuel systems
H2O
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Tall Oil Based Derivatives
Diacids and Dimer Acids § Corrosion inhibitors in water based-systems § Dimers and dimer esters for fuel additive lubricants § Emulsifiers/couplers in MWF
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Tall Oil Based Derivatives
Estolides § Bio-based base oil § Engine oil § Metalworking fluid base oil § Demonstrate exceptional results in the areas of
oxidative stability, hydrolytic stability, volatility, biodegradability and renewable carbon content
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TOFA Product list
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Product Acid value,
min (mg KOH/g)
Color, max (Gardner)
Rosin content, max (%)
Country of origin
Altapyne™ L-1 192 4.0 1.0 United States
Altapyne L-5 190 7.0 5.0 United States
DTO is primarily used by customers as co-emulsifiers. Benefits: § Excellent co-emulsification additive § Fatty acid component provides good lubricity § Higher rosin content contributes to:
§ Reduced foam § Reduced bioactivity relative to fatty acids
Metalworking DTO
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Crude Tall Oil—Valuable Bio Mass Based Raw Material for the Chemical Industry
Biorefinery
Renewable Forests
Tall Oil Fatty Acid Soap, detergents, cleaners, asphalt emulsifiers, rubber emulsifiers, adhesives, paints, coatings, Lubricant Additives, Oilfield Chemicals
Rubber emulsifiers, lubricants Ink resins, paper size, adhesives and rubber emulsifiers
Mining
Distilled Tall Oil
Tall Oil Rosin
Tall Oil Pitch
Energy Use !!Destroys Natural
Functionality !!Does not capture
nature’s chemical value !!Poor use of renewable
resource
Tall Oil Heads
Mining, fuels
Nutraceuticals, Pitch fuel for energy
Extraction
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Distilled Tall Oil (DTO) TOFA: and TOR:
C H 3 O H
O
C H 3 O H
O
CH3
CH3CH3
O
OHCH3
CH3
CH3CH3
O
OHCH3
DTO has the properties of both TOFA and Rosin: the best of both worlds.
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Metalworking DTO Usage
§ Useful as co-emulsifier in soluble oil and in synthetic formulations § DTO is oil soluble § Must be neutralized to make it water soluble § The acid number of the DTO is used to determine how much base
needed to neutralize § Best to add DTO to oil phase first and then add neutralizing base
before adding water
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What makes DTO perform so well?
Acid Number Softening Point
Color, Gardner
Tall Oil Rosin 170-175 >72 4-7
dehydrobetic acid neoabietic acid abietic acid palustric acid
Isomers Comprising Tall Oil Rosin
neoabietic acid abietic acid palustric acid
55% of rosin acid content
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Mixed Tall Oil Fatty Acid and Rosin (DTO)
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Product Acid value,
min (mg KOH/g)
Color, max (Gardner)
Rosin content, max (%)
Country of origin
Altapyne 226 170 7 30 United States
Diacid 1550
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Why use Diacid 1550?
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Unique technology
Branched structure is less vulnerable to microbial contamination
Commonly used amine salts are already TSCA registered
Diacid 1550 is a specialty additive
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Diacid 1550 features
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§ Multifaceted additive with key benefits
§ Corrosion Inhibition—It’s a great alternative to Corfree M1
§ Emulsification—It’s the best additive on the market for tightening emulsions
§ Lubrication—It’s a great lubricity additive, especially in aluminum forming applications
Diacid 1550 is the best additive for tightening emulsions. See for yourself…
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Emulsion Video
Ingevity High Performance Additives
Diacid 1550 is a great alternative to Corfree M1 because ________.
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Corrosion testing in formulation These results were obtained from a single metalworking fluid formulation. Each formulation is different, and other formulations may demonstrate different performance.
% Surface Rust as Function of Total Corrosion Inhibitor
100.0050.0025.0012.506.253.131.560.780.390.200.100.050.020.010.01
0.023 0.043 0.063 0.083 0.103 0.123
% Corrosion Inhibitor (Acid + Amine)
% S
urf
ace
Ru
st
Corfree M1Diacid 1550, 7%OCD 2010OCD 536
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Corrosion test picture in formulation
How to formulate with Diacid 1550:
1. Diacid 1550 is easiest to formulate with when added into the oil phase of a semi-synthetic or soluble oil.
2. From there, the water soluble components and bases can be added later, effectively neutralizing Diacid 1550 and allowing it to function.
3. Once the effects of Diacid 1550 in a particular system are realized, the formulator can adjust the percentage to optimize the benefits.
Diacid 1550 is oil-soluble or lipophilic. However when neutralized with an appropriate base (sodium or potassium hydroxide or an alkanolamine such as TEA), the resulting salt becomes water soluble.
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Key Trend: • Non-ionic emulsifiers with mid-level
HLB values (around 12 HLB) will lead to higher foam or “more stabilized” foam • EXAMPLE: TEA salts of Diacid 1550
~ 12 HLB • These will create a synergistic
effect on building foam. • If your customer already has
foaming issues, using a TEA salt of Diacid 1550 may not be the right path forward to decrease foam.
Diacid 1550 Foaming Trend Study
Reducing the non-ionic emulsifier dose Increasing Diacid 1550
Generally results in lower foam
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Foam
Yes
∆ NI HLB
∆ to low HLB(≤10 HLB)
∆ to high HLB (≥13)
Do not ∆ to mid HLB
(10–13)
Foam
�Diacid 1550 conc.
(≥2%)
Foam
�NI conc.
(≤3%)
No foam
No foam
∆ NI Conc.
∆ Diacid Conc.
No
Foam No foam
Foam No foam
�Diacid 1550 conc.
(≥2)
�NI conc.
(≤3%)
∆ to low Diacid 1550 conc. (1%)
∆ to mid Diacid 1550 conc. (1.5%)
∆ to high Diacid 1550 conc. ( 2%)
Foam
�NI HLB
(≤10)
No foam
�NI HLB
(≤10)�NI HLB
(≥13)
�NI dosage (4–5%)
∆ to low conc. (≤3%)
∆ to mid conc. (3.1–4.9%)
Do not ∆ to high conc. (≥5%)
∆ Diacid 1550 conc. (1–1.5%)
�NI HLB
(≤10)
�Diacid 1550
conc. (≥2%)
�NI HLB
(≤10)
Diacid 1550Decision Guide
ingevity.com
Foam No foam Foam No foam
Foam No foam
Foam No foam Foam No foam
Foam No foam Foam No foam
The above are only recommendations to reduce foam and may not solve your particular challenge. Please contact the Ingevity technical team for more assistance at [email protected].
KeyHLB Hydrophilic-lipophilic balanceNI Non-ionicconc. Concentration∆ Change� Increase� Decrease
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Diacid 1550 LubricationAluminum Can Drawing Trial
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Diacid 1550 provides superior lubrication, requiring less force than isostearic acid to extrude cans. Cans made with Diacid 1550 were also smoother and rounder, and Diacid 1550 foamed less than isostearic acid. Finally, Diacid 1550 also acted as a cleaner, leaving less residue on the cans and dies after application.
Ingevity High Performance Additives
AltaLUB 5300
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Introducing AltaLUB 5300
AltaLUB 5300 is a performance lubricity additive that:
§ offers ease of formulation
§ demonstrates low foam profiles
§ is hydrolytically stable
Robust performance for:
§ semi-synthetics
§ synthetics
§ soluble oils
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Description AltaLUB 5300 is a lubricant performance additive for metalworking fluids. Its unique chemical properties lend themselves to applications where low foam and high lubricity are valued. It also demonstrates ease of formulation versus other complex self-emulsifying esters currently available in the market. Applications include soluble oils, semi-synthetic and synthetic metalworking fluid formulations. Features § High boundary lubrication § Low foam § Ease of formulation
Property Result
Appearance at 25°C amber liquid
Color, Gardner 6 - 7 Odor mild
Acid number, mg KOH/g 100-110 Viscosity at 25°C, cP 460
Weight average molecular weight, g/mol 500
Flash point, closed cup °C 227
Density at 25°C, g/mL 0.8
AltaLUB 5300 Typical Properties
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Four-Ball Test Data
20 minute ramp to 200 kg, 600rpm
AltaLUB 5300
LA-8330
Methyl Ester
Standard
Scar diameter (mm) 0.89 0.95 1.05
Torque (kgf·∙m) 0.0756 0.0976 0.0921
Coefficient of Friction 0.08 0.11 0.1
Fluid Temperature (°F)
127 157 150
AltaLUB 5300 is an excellent lubricant as it had the: § lowest torque § lowest scar
diameter
§ lowest coefficient of friction
§ lowest fluid temperature
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Falex Four-Ball Wear Testing
Ingevity High Performance Additives
Hydrolytic Stability
Samples were mixed with 2000ppm DI water and placed in an oven for 14 days. Acid number was tested periodically. An increase in acid number indicates hydrolysis. AltaLUB 5300 showed no significant hydrolysis after 14 days
Esters often have low hydrolytic stability. AltaLUB 5300 was tested at 80°C versus a competitive self emulsifying ester, and a methyl ester standard for benchmarking.
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Product Starting AN Final AN Change
AltaLUB 5300 110.8 110.6 -0.2
Competitive SEE 31.1 31.0 -0.1
TOFA Methyl Ester 4.3 14.2 +9.9
Ingevity High Performance Additives
Microtap Torque Test Test Results
Superior performance on aluminum Equivalent performance on steel
AltaLUB 5300 was tested in a semi-synthetic formulation versus a self-emulsifying ester control. The concentrates were diluted to 5% with DI water, and four samples were tested per fluid, per metal.
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AltaLUB 5300 Complex self-emulsifying ester
Objective: Quantitatively determine performance differences between self emulsifying ester lubrication additives and AltaLUB 5300 .
How: Measure drill wear using a semi-synthetic metal working fluid at low concentration and low flow rate to stress the drilling conditions.
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Drill Wear Machine Shop Testing
Ingevity High Performance Additives
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21 rows x 59 holes per row = lots of holes!
Ingevity High Performance Additives
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Wear Face
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Drill Face Area of measured wear
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! Resolution is 200x! Outside edge is a high speed area, subject to
wear! Drill tends to “flatten” here! Area is integrated to measure drill wear
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Drill Face Area of measured wear
Ingevity High Performance Additives
AltaLUB 5300 Value-In-Use in a semi-synthetic formulation
More consistency & precision, lower variability
0,050
0,060
0,070
0,080
0,090
0,100
0,110
4000 5000 6000 7000 8000 9000 10000
Dril
l Wea
r
Altalub 5300
Competitive SEE
Number of Holes Drilled
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Machine Shop Trial !Ra Values
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For each fluid, 29,412 holes were drilled. The Ra was measured on the cutting surface inside the hole after every 9,804 holes.
16,4%
28,5%
# Ra
41,429
45,322
Average Ra
Lower surface roughness on average Less change over course of trial
Higher precision cutting for longer
Va ues
AltaLUB 5300 Performance in Twist Compression Testing
Good mixed-film boundary lubricant
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TCT @ 10,000 PSI vs. 42% chlorinated paraffin
AltaLUB 5300 42% Cl Paraffin
AltaLUB 5300 TBD = 26.52s
CP TBD = 32.62s
*Testing on cold rolled steel
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AltaLUB 5300: Bridging the Gap
AltaLUB 5300
0 100 200 300 400 500 600 700 800 900 1000 1100
Temperature (°C)
Temperature profiles of EP lubricantsC
oeff
icie
nt o
f fri
ctio
n0.5
0.4
0.3
0.2
0.1
0.0
Mineral oil Chlorinated paraffins
Phosphorous compounds
Sulfur compounds
Fatty products
Ingevity High Performance Additives
AltaLUB 5300 High Pressure Forming Performance
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0
2
4
6
8
10
12
14
16
18
AltaLUB 5300 & Active Sulfur
Polymeric Ester & Active Sulfur
TCT Friction
0
0,5
1
1,5
2
2,5
3
3,5
4
4,5
5
ALtaLUB 5300 & Active Sulfur
Ploymeric Ester & Active Sulfur
Time to Breakdown
Twist Compression Testing on SS304 Ester lubricant & sulfur compounds
AltaLUB 5300 High Pressure Forming Performance
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Twist Compression Testing on SS304 Ester lubricant & sulfur compounds
10
10,5
11
11,5
12
12,5
13
13,5
AltaLUB 5300 & Inactive Sulfur
Polyol Ester & Inactive Sulfur
Polymeric Ester & Inactive Sulfur
TCT Friction
0 0,5
1 1,5
2 2,5
3 3,5
4 4,5
5
AltaLUB 5300 & Inactive Sulfur
Polyol Ester & Inactive Sulfur
Polymeric Ester & Inactive
Sulfur
Time to Breakdown
Customer Feedback: Highlights Favorable § Easy to formulate in synthetic and semis § Helps stabilize emulsions § Extends the life of existing formulas § Very good mixed boundary lubricant § Important part of some effective CP replacement systems Challenges § Foam in some synthetic systems § Doesn’t drop-in for more water soluble lubes § Not a drop-in for high MW synthetic esters § Regulatory status is a challenge
IMCD Brazil’s new distribution line from Ingevity Refinery Products § Altapyne™ L-1
§ Good lubricity § Easy to handle § Great for derivatization
§ Altapyne L-5 § Good lubricity § Easy to handle § Great for derivatization
§ Altapyne 226 § Good co-emulsifier § Rosin content enhances
performance (lower foam, added biostability)
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Specialty Products § Diacid 1550
§ Multi-faceted product § Great coupler, corrosion
inhibitor, lubricant (particularly aluminum forming)
§ AltaLUB™ 5300 § Excellent mixed-boundary
lubricant § Useful for removing and forming
applications
? Questions