Eugene Demler (Harvard)Kwon Park
Anatoli PolkovnikovSubir Sachdev
Matthias Vojta (Augsburg)Ying Zhang
Competing orders in the cuprate superconductors
Talk online at http://pantheon.yale.edu/~subir
(Search for “Sachdev” on )
( )† †0 cos cos
0
Hole-doped cuprates are BCS superconductors w
-wa
ith
ve pairing
spin-single t
x y dc c k k
S
↑ ↓ ≡ ∆ = ∆ −
=��
kk -k
yk
xk
0 0
2 2
Low enerSuperflow
1/ 2 fermion
gy excitat
ic quasiparticles
:
:
ons:
ii
S
e
E
θ
ε
∆ →
==
∆
+ ∆k k k
0
0
BCS theory also predicts that the Fermi surface, with gapless quasiparticles, will reveal itself when 0, eitherlocally or globally at low temperatures. can be suppressedby a strong magnetic fiel
∆ →∆
d, and near vortices, impurities and interfaces.
Superconductivity in a doped Mott insulator
Hypothesis: cuprate superconductors have low energy excitations associated with additional order parameters
Theory and experiments indicate that the most likely candidates are spin density waves and associated
“charge” order
Competing orders are also revealed when superconductivity is suppressed locally, near impurities or around vortices.
S. Sachdev, Phys. Rev. B 45, 389 (1992); N. Nagaosa and P.A. Lee, Phys. Rev. B 45, 966 (1992);
D.P. Arovas, A. J. Berlinsky, C. Kallin, and S.-C. Zhang Phys. Rev. Lett. 79, 2871 (1997); K. Park and S. Sachdev Phys. Rev. B 64, 184510 (2001).
Superconductivity can be suppressed globally by a strong magnetic field or large current flow.
OutlineI. Experimental introduction
II. Spin density waves (SDW) in LSCO Tuning order and transitions by a magnetic field.
III. Connection with “charge” order – phenomenological theorySTM experiments on Bi2Sr2CaCu2O8+δ
IV. Connection with “charge” order – microscopic theoryTheories of magnetic transitions predict bond-centered modulation of exchange and pairing energies with even periods---a bond order wave
V. Conclusions
The doped cuprates
2-D CuO2 planeNéel ordered ground state at zero doping
2-D CuO2 planewith finite hole doping
I. Experimental introduction
Phase diagram of the doped cuprates
T
δ
d-waveSC
3DAFM
0
ky
•
kx
π/a
π/a0
Insulator• •• ••••
Superconductor with Tc,min =20 K•
T = 0 phases of LSCO
δ~0.12-0.140.055SC+SDW SCNéel SDW
0.020
S. Wakimoto, G. Shirane et al., Phys. Rev. B 60, R769 (1999).
G. Aeppli, T.E. Mason, S.M. Hayden, H.A. Mook, J. Kulda, Science 278, 1432 (1997).
Y. S. Lee, R. J. Birgeneau, M. A. Kastner et al., Phys. Rev. B 60, 3643 (1999).
SDW order parameter for general ordering wavevector
( ) ( ) c.c.iS eα α⋅= Φ +K rr r
( ) is a field and =(3 / 4, )Spin density wave is (and not spiral):
α π πΦ complexlongitudi nal
r Kie nθ
α αΦ =
Bond-centered
Site-centered
H
δ~0.120.055SC+SDW SCNéel SDW
0.020
ky
•
kx
π/a
π/a0
InsulatorSuperconductor with Tc,min =20 K
••• •
II. Effect of a magnetic field on SDW order with co-existing superconductivity
H
δ
Spin singlet state
SDW
Effect of the Zeeman term: precession of SDWorder about the magnetic field
Characteristic field gµBH = ∆, the spin gap1 Tesla = 0.116 meV
Effect is negligible over experimental field scales
δc
( )~ zcH νδ δ−
2
Elastic scattering intensity
( ) (0) HI H I aJ
� �= + � �� �
Dominant effect: uniformuniform softening of spin excitations by superflow kinetic energy
2 2
2
Spatially averaged superflow kinetic energy3 ln c
sc
HHvH H
� �
1sv
r�
r
( ) 2
2
The presence of the field replaces by3 ln c
effc
HHH CH H
δ
δ δ � �= − � �� �
E. Demler, S. Sachdev, and Y. Zhang, Phys. Rev. Lett. 87, 067202 (2001).
Competing order is enhanced in a
“halo” around each vortex
• Theory should account for dynamic quantum spin fluctuations
• All effects are ~ H2 except those associated with H induced superflow.
• Can treat SC order in a static Ginzburg-Landau theory
( )1/ 2 22 2 2 22 2 21 2
0 2 2
T
b rg gd r d c sα τ α α α ατ ��= ∇ Φ + ∂ Φ + Φ + Φ + Φ �� �
� �S
2 22
2c d rd ατ ψ� �= Φ� �� ��S v
( )4
222
2GL rF d r iAψ
ψ ψ� �
= − + + ∇ −� �� �� �
�
( ) ( )( )
( )
,
ln 0
GL b cFZ r D r e
Z rr
ψ τ
δ ψδψ
− − −= Φ� �� �
� �� � =
�S S
(extreme Type II superconductivity)Effect of magnetic field on SDW+SC to SC transition
Infinite diamagnetic susceptibility of non-criticalsuperconductivity leads to a strong effect.
Main results
E. Demler, S. Sachdev, and Y. Zhang, Phys. Rev. Lett. 87, 067202 (2001).
( )( )( )~
ln 1/c
c
H δ δδ δ−
−
2
2
Elastic scattering intensity3( ) (0) ln c
c
HHI H I aH H
� �= + � �� �
( ) ( ) 2
2
1 exciton energy30 ln c
c
SHHH b
H Hε ε
=
� �= − � �� �
T=0
δδc
2 4
B. Khaykovich, Y. S. Lee, S. Wakimoto, K. J. Thomas, M. A. Kastner,
Elas
and
tic neutron scatterin
R.J. Birgeneau, cond-
g off La C
mat/01
uO
12505.
y+
( )( )
2
2
2
Solid line --- fit to :
is the only fitting parameterBest fit value - = 2.4 with
3.01 l
= 6
n
0 T
0
c
c
c
I H HHH
a
aI H
a H
� �= + � �� �
Neutron scattering measurements of static spin correlations of the superconductor+spin-density-wave (SC+SDW) in a magnetic field
2- 4Neutron scattering of La Sr CuO at =0.1x x x
B. Lake, H. M. Rønnow, N. B. Christensen, G. Aeppli, K. Lefmann, D. F. McMorrow, P. Vorderwisch, P. Smeibidl, N. Mangkorntong, T. Sasagawa, M. Nohara, H. Takagi, T. E. Mason,Nature, 415, 299 (2002).
2
2
Solid line - fit ( ) nto : l c
c
HHI H aH H
� �= � �� �
Spin density wave order parameter for general ordering wavevector( ) ( ) c.c.iS eα α
⋅= Φ +K rr r
( ) is a field and =(3 / 4, )Spin density wave is (and not spiral):
α π πΦ complexlongitudi nal
r K
III. Connections with “charge” order – phenomenological theory
ie nθα αΦ =
Bond-centered
Site-centered
( ) ( ) ( )2 2 2 c.c.iS eα αα
δρ ⋅∝ = Φ +�K rr r r
J. Zaanen and O. Gunnarsson, Phys. Rev. B 40, 7391 (1989). H. Schulz, J. de Physique 50, 2833 (1989). K. Machida, Physica 158C, 192 (1989). O. Zachar, S. A. Kivelson, and V. J. Emery, Phys. Rev. B 57, 1422 (1998).
A longitudinal spin density wave necessarily has an accompanyingmodulation in the site charge densities, exchange and pairing
energy per link etc. at half the wavelength of the SDW
“Charge” order: periodic modulation in local observables invariant under spin rotations and time-reversal.
Order parmeter ( )2~ αα
Φ� r
Prediction: Charge order should be pinned in halo around vortex core
K. Park and S. Sachdev Phys. Rev. B 64, 184510 (2001).E. Demler, S. Sachdev, and Ying Zhang, Phys. Rev. Lett. 87, 067202 (2001).
STM around vortices induced by a magnetic field in the superconducting stateJ. E. Hoffman, E. W. Hudson, K. M. Lang, V. Madhavan, S. H. Pan,
H. Eisaki, S. Uchida, and J. C. Davis, Science 295, 466 (2002).
-120 -80 -40 0 40 80 1200.0
0.5
1.0
1.5
2.0
2.5
3.0
Regular QPSR Vortex
Diffe
renti
al Co
nduc
tance
(nS)
Sample Bias (mV)
Local density of states
1Å spatial resolution image of integrated
LDOS of Bi2Sr2CaCu2O8+δ
( 1meV to 12 meV) at B=5 Tesla.
S.H. Pan et al. Phys. Rev. Lett. 85, 1536 (2000).
100Å
b7 pA
0 pA
Vortex-induced LDOS of Bi2Sr2CaCu2O8+δ integrated from 1meV to 12meV
J. Hoffman E. W. Hudson, K. M. Lang, V. Madhavan, S. H. Pan, H. Eisaki, S. Uchida, and J. C. Davis, Science 295, 466 (2002).
Fourier Transform of Vortex-Induced LDOS map
J. Hoffman et al. Science, 295, 466 (2002).
K-space locations of vortex induced LDOS
Distances in k –space have units of 2π/a0a0=3.83 Å is Cu-Cu distance
K-space locations of Bi and Cu atoms
(extreme Type II superconductivity)
T=0Summary of theory and experiments
STM observation of CDW fluctuations enhanced by superflow
and pinned by vortex cores.
Neutron scattering observation of SDW order enhanced by
superflow.
E. Demler, S. Sachdev, and Y. Zhang, Phys. Rev. Lett. 87, 067202 (2001).
Quantitative connection between the two experiments ?
( )( )( )~
ln 1/c
c
H δ δδ δ−
−
δδc
Pinning of CDW order by vortex cores in SC phase
( ) ( ) ( ) 22 *1 1, , ,vdα α ατ ζ τ τ τΦ ∝ Φ Φ�r r r
( )2 ,α τΦ r
low magnetic fieldhigh magnetic field
near the boundary to the SC+SDW phase
→→
�
�
Y. Zhang, E. Demler, and S. Sachdev, cond-mat/0112343.
( )( )
1/2
pinAll where 0 0
c.c.v v
Ti
vd e θα
ψζ τ
=
� �= Φ +� �� �Sr r
r
100Å
b7 pA
0 pA
Vortex-induced LDOS of Bi2Sr2CaCu2O8+δ integrated from 1meV to 12meV
J. Hoffman E. W. Hudson, K. M. Lang, V. Madhavan, S. H. Pan, H. Eisaki, S. Uchida, and J. C. Davis, Science 295, 466 (2002).
Magnetic transitions in the coupled ladder antiferromagnet:
S. Chakravarty, B.I. Halperin, and D.R. Nelson, Phys. Rev. B 39, 2344 (1989).
ij i ji j
H J S S<
= ⋅�� �
Action for quantum spin fluctuations in spacetimeDiscretize spacetime into a cubic lattice with Néel order orientation an
( ),
1 1 exp 2a a a a
aaZ d
g µµ
δ +
� �= − ⋅� �
� ��∏ � n n n n
Quantum path integral for two-dimensional quantum antiferromagnet Partition function of a classical three-dimensional ferromagnet at a “temperature” g
⇔
cubic lattice sites; , , ; a x yµ τ→ →
IV. Microscopic theory of the charge order: magnetic transitions in Mott insulators and superconductors
Missing: Spin Berry PhasesMissing: Spin Berry Phases
AiSAe
Berry phases profoundly modify paramagnetic states with 0a S= =
��
n
(Can be neglected on the coupled ladder, but not on the square lattice)
( ),
a 1 on two square sublattices
1 1 exp
; Neel order parameter; oriented area of spherical triangle
formed
by
2
~
,
2a a a a a a
a aa
a a a
a
a
iZ d Ag
SA
µ τµ
µ
δ η
η η
+
→ ±
� �= − � �
�
→
−
→
⋅�
� �∏ ��
n n n n
n
n 0and an arbitrary reference poin , ta µ+n n 0n
an a µ+n
aA µ
aγ a µγ +
Field theory of paramagnetic (“quantum disordered”) phase on the square lattice Discretize spacetime into a cubic lattice:
Change in choice of n0 is like a “gauge transformation”
a a a aA Aµ µ µγ γ+→ − +
(γa is the oriented area of the spherical triangle formed by na and the two choices for n0 ).
The area of the triangle is uncertain modulo 4π, and the action is invariant under4a aA Aµ µ π→ +
0′n
aA µ
an a µ+n
0n
These principles strongly constrain the effective action for Aaµ
2 2
2,
withThis is compact QED in 2+1 dime
nsions with Berry
1 1exp cos2 22
pha
ses. ~
a a a aaa
e
iZ dA A Ae
g
µ µνλ ν λ τµ
ε η� �� �= − ∆ −� �� �� �� �
� �∏ ��
Simplest large g effective action for the Aaµ
This theory can be reliably analyzed by a duality mapping.
The gauge theory is always in a confiningconfining phase:
There is an energy gap and the ground state has a bond order wave.
N. Read and S. Sachdev, Phys. Rev. Lett. 62, 1694 (1989).S. Sachdev and R. Jalabert, Mod. Phys. Lett. B 4, 1043 (1990).
K. Park and S. Sachdev, Phys. Rev. B 65, 220405 (2002).
A. W. Sandvik, S. Daul, R. R. P. Singh, and D. J. Scalapino, cond-mat/0205270
Bond order wave in a frustrated S=1/2 XY magnet
( ) ( )2 x x y yi j i j i j k l i j k l
ij ijklH J S S S S K S S S S S S S S+ − + − − + − +
⊂
= + − +� ��
g=
First large scale numerical study of the destruction of Neel order in S=1/2antiferromagnet with full square lattice symmetry
N. Read and S. Sachdev, Phys. Rev. Lett. 62, 1694 (1989); S. Sachdev and K. Park, Annals of Physics 298, 58 (2002).
IV. Microscopic theory of the charge order: magnetic transitions in Mott insulators and superconductors
“Large N” theory in region with preserved spin rotation symmetry S. Sachdev and N. Read, Int. J. Mod. Phys. B 5, 219 (1991). M. Vojta and S. Sachdev, Phys. Rev.Lett. 83, 3916 (1999).M. Vojta, Y. Zhang, and S. Sachdev, Phys. Rev. B 62, 6721 (2000).
See also J. Zaanen, Physica C 217, 317 (1999),S. Kivelson, E. Fradkin and V. Emery, Nature 393, 550 (1998),
S. White and D. Scalapino, Phys. Rev. Lett. 80, 1272 (1998).C. Castellani, C. Di Castro, and M. Grilli, Phys.Rev. Lett. 75, 4650 (1995).
S. Mazumdar, R.T. Clay, and D.K. Campbell, Phys. Rev. B 62, 13400 (2000).
Hatched region --- spin orderShaded region ---- charge order
Long-range charge order without spin
order
IV. Bond order waves in the superconductor.
g
Charge order is bond-centered and has an even period.
C. Howald, H. Eisaki, N. Kaneko, and A. Kapitulnik, cond-mat/0201546
IV. STM image of pinned charge order in Bi2Sr2CaCu2O8+δ in zero magnetic field
Charge order period = 4 lattice spacings
Charge order period = 4 lattice spacings
C. Howald, H. Eisaki, N. Kaneko, and A. Kapitulnik, cond-mat/0201546
Spectral properties of the STM signal are sensitive to the microstructure of the charge order
Measured energy dependence of the Fourier component of the density of states which modulates with a period of 4 lattice spacings M. Vojta, cond-mat/0204284.
D. Podolsky, E. Demler, K. Damle, and B.I. Halperin, cond-mat/0204011
Theoretical modeling shows that this spectrum is best obtained by a modulation of bond variables, such as the exchange, kinetic or pairing energies.
H. A. Mook, Pengcheng Dai, and F. DoganPhys. Rev. Lett. 88, 097004 (2002).
IV. Neutron scattering observation of static charge order in YBa2Cu3O6.35(spin correlations are dynamic)
Charge order period = 8 lattice spacings
Charge order period = 8 lattice spacings
“Large N” theory in region with preserved spin rotation symmetry S. Sachdev and N. Read, Int. J. Mod. Phys. B 5, 219 (1991). M. Vojta and S. Sachdev, Phys. Rev.Lett. 83, 3916 (1999).M. Vojta, Y. Zhang, and S. Sachdev, Phys. Rev. B 62, 6721 (2000).
See also J. Zaanen, Physica C 217, 317 (1999),S. Kivelson, E. Fradkin and V. Emery, Nature 393, 550 (1998),
S. White and D. Scalapino, Phys. Rev. Lett. 80, 1272 (1998).C. Castellani, C. Di Castro, and M. Grilli, Phys.Rev. Lett. 75, 4650 (1995).
S. Mazumdar, R.T. Clay, and D.K. Campbell, Phys. Rev. B 62, 13400 (2000).
Hatched region --- spin orderShaded region ---- charge order
IV. Bond order waves in the superconductor.
g
ConclusionsI. Cuprate superconductivity is associated with doping
Mott insulators with charge carriers
II. The correct paramagnetic Mott insulator has bond-order and confinement of spinons
III. Mott insulator reveals itself vortices and near impurities. Predicted effects seen recently in STM and NMR experiments.
IV. Semi-quantitative predictions for neutron scattering measurements of spin-density-wave order in superconductors; theory also establishes connection to STM experiments.
V. Future experiments should search for SC+SDW to SC quantum transition driven by a magnetic field.
VI. Major open question: how does understanding of low temperature order parameters help explain anomalous behavior at high temperatures ?
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