72
LAMPIRAN
73
LAMPIRAN IV-1 DATA PIROLISIS ROCK-EVAL DAN TOC SUMUR LUK-2
Sample Formation Lithology Sample TOC S1 S2 S3 HI OI OPI Tmax PY S2/S3
Depth (m) Type Wt% mg/g mg/g mg/g mg/gC mg/gC (°C)
160 Muara Enim Carb clyst CUTT 7,35 0,10 3,53 4,33 48 59 0,03 431 3,63 0,82
180 Muara Enim Carb clyst CUTT 1,99 0,06 1,68 1,68 84 84 0,03 428 1,74 1,00
440 Muara Enim Coal CUTT 43,52 1,21 77,56 19,75 178 45 0,02 428 78,77 3,93
520 Air Benakat Coal CUTT 44,74 1,18 78,98 13,89 177 31 0,01 426 80,16 5,69
540 Air Benakat Carb clyst CUTT 13,26 0,41 14,65 5,67 110 43 0,03 427 15,06 2,58
710 Air Benakat Clyst CUTT 0,70 0,02 0,62 0,86 89 123 0,03 429 0,64 0,72
840 Air Benakat Clyst CUTT 0,84 0,03 0,67 0,58 80 69 0,04 426 0,70 1,16
950 Air Benakat Clyst CUTT 0,62 0,01 0,41 0,51 66 82 0,02 431 0,42 0,80
1130 Air Benakat Sst CUTT 0,10
110
1200 Air Benakat Clyst CUTT 0,56 0,02 0,42 0,26 75 46 0,05 423 0,44 1,62
1300 Air Benakat Clyst CUTT 0,72 0,06 0,67 0,65 93 90 0,08 421 0,73 1,03
1400 Air Benakat Clyst CUTT 0,83 0,04 0,69 0,41 83 49 0,05 423 0,73 1,68
1500 Air Benakat Clyst CUTT 0,74 0,07 0,60 0,58 81 78 0,10 423 0,67 1,03
1600 Air Benakat Clyst CUTT 0,66 0,05 0,50 0,43 76 65 0,09 423 0,55 1,16
1700 Air Benakat Clyst CUTT 0,97 0,11 1,09 0,56 112 58 0,09 425 1,20 1,95
1840 Air Benakat Clyst CUTT 0,78 0,09 0,86 0,33 110 42 0,09 428 0,95 2,61
1900 Air Benakat Clyst CUTT 1,13 0,06 1,23 0,56 109 50 0,05 425 1,29 2,20
2080 Air Benakat Clyst CUTT 1,05 0,09 1,17 0,67 111 64 0,07 426 1,26 1,75
2150 Air Benakat Clyst CUTT 1,36 0,14 1,71 0,77 126 57 0,08 427 1,85 2,22
2210 Air Benakat Clyst CUTT 0,70 0,07 0,75 0,44 107 63 0,09 429 0,82 1,70
TOC = Total Organic Carbon
HI = Hydrogen Index =
100*(S2/TOC)
Tmax = Temperature of
Maximum S2
S1 = Free Hydrocarbons
OI = Oxygen Index =
100*(S3/TOC)
*TOC by Leco
Analyser
S2 = Pyrolysable Hydrocarbons
Oil Production Index =
S1/(S1+S2)
74
LAMPIRAN IV-2 DATA REFLEKTANSI VITRINIT
Sample Age Population 1 (Indigenous) Population 2 (Caved/Suppressed) Population 3 (Oxidised/Reworked) Depth
(m) Mean No. of Min Max Mean No. of Min Max Mean No. of Min Max
Ro. (%) Readings Ro. (%) Ro. (%) Ro. (%) Readings Ro. (%) Ro. (%) Ro. (%) Readings Ro. (%) Ro. (%)
160 Muara Enim 0,26 20 0,21 0,33
0,38 2 0,37 0,38
180 Muara Enim 0,26 2 0,25 0,27 0,22 6 0,21 0,23
440 Muara Enim 0,28 26 0,27 0,30
520 Air Benakat 0,30 27 0,28 0,33
540 Air Benakat 0,31 17 0,28 0,34 0,24 3 0,22 0,25
710 Air Benakat 0,36 8 0,33 0,39 0,27 5 0,24 0,30
840 Air Benakat 0,37 7 0,34 0,39 0,27 10 0,25 0,30 0,60 6 0,55 0,66
950 Air Benakat 0,40 19 0,34 0,49
1130 Air Benakat
1200 Air Benakat 0,43 10 0,36 0,52 0,30 4 0,29 0,31
1300 Air Benakat 0,45 10 0,38 0,53 0,31 3 0,30 0,33
1400 Air Benakat 0,46 13 0,38 0,53 0,35 1 0,35 0,35
1500 Air Benakat 0,48 12 0,40 0,55
1600 Air Benakat 0,51 14 0,44 0,56 0,40 1 0,40 0,40
1700 Air Benakat 0,53 16 0,48 0,58
1800 Air Benakat 0,55 11 0,49 0,60 0,46 2 0,45 0,46
1900 Air Benakat 0,57 8 0,52 0,62
2080 Air Benakat 0,59 10 0,56 0,63
2150 Air Benakat 0,60 8 0,56 0,63 0,52 1 0,52 0,52 0,69 4 0,67 0,72
2210 Air Benakat 0,61 13 0,58 0,65
75
LAMPIRAN IV-3 HISTOGRAM REFLEKTANSI VITRINIT
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 160 m Indigenous Ro (%) Average : 0,26 Range : 0,21-0,33 Std. Deviation : 0,04 No.of Readings : 20 Readings : 0,21 0,21 0,22 0,22 0,22 0,22 0,23 0,24 0,24 0,24 0,25 0,25 0,27 0,28 0,28 0,28 0,29 0,31 0,33 0,33
Reworked
Ro (%) Average : 0,38 Range : 0,37-0,38 No.of Readings : 2 Readings : 0,37 0,38
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 180 m Indigenous Ro (%) Average : 0,26 Range : 0,25-0,27 Std. Deviation : 0,01 No.of Readings : 2 Readings : 0,25 0,27
Cavings
Ro (%) Average : 0,22 Range : 0,21-0,23 No.of Readings : 6 Readings : 0,21 0,21 0,21 0,22 0,23 0,23
: indigenous
: reworked
: cavings
76
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 440 m Indigenous Ro (%) Average : 0,28 Range : 0,27-0,30 Std. Deviation : 0,01 No.of Readings : 26 Readings : 0,27 0,27 0,27 0,27 0,27 0,27 0,27 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,28 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,30 0,30 0,30
Sample depth : 520 m Indigenous Ro (%) Average : 0,29 Range : 0,28-0,31 Std. Deviation : 0,01 No.of Readings : 11 Readings : 0,28 0,28 0,28 0,28 0,29 0,29 0,29 0,29 0,31 0,31 0,31
Cavings
Ro (%) Average : 0,25 Range : 0,24-0,25 No.of Readings : 4 Readings : 0,24 0,24 0,25 0,25
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
77
Sample depth : 520 m Indigenous Ro (%) Average : 0,30 Range : 0,28-0,33 Std. Deviation : 0,01 No.of Readings : 27 Readings : 0,28 0,28 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,29 0,30 0,30 0,30 0,30 0,30 0,30 0,30 0,30 0,31 0,31 0,31 0,32 0,32 0,32 0,32 0,33 0,33
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 540 m Indigenous Ro (%) Average : 0,31 Range : 0,28-0,34 Std. Deviation : 0,02 No.of Readings : 17 Readings : 0,28 0,29 0,29 0,29 0,29 0,30 0,30 0,30 0,30 0,30 0,30 0,31 0,32 0,34 0,34 0,34
Cavings
Ro (%) Average : 0,24 Range : 0,22-0,25 No.of Readings : 3 Readings : 0,22 0,25 0,25
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
78
Sample depth : 710 m Indigenous Ro (%) Average : 0,36 Range : 0,33-0,39 Std. Deviation : 0,02 No.of Readings : 8 Readings : 0,33 0,33 0,35 0,36 0,37 0,37 0,38 0,38 0,39
Cavings
Ro (%) Average : 0,27 Range : 0,24-0,30 No.of Readings : 5 Readings : 0,24 0,26 0,27 0,29 0,30
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 840 m Indigenous Ro (%) Average : 0,37 Range : 0,34-0,39 Std. Deviation : 0,02 No.of Readings : 7 Readings : 0,34 0,36 0,37 0,38 0,39 0,39 0,39
Cavings
Ro (%) Average : 0,27 Range : 0,25-0,30 No.of Readings : 10 Readings : 0,25 0,26 0,26 0,26 0,26 0,27 0,28 0,28 0,29 0,30
Reworked
Ro (%) Average : 0,6 Range : 0,55-0,66 No.of Readings : 6 Readings : 0,55 0,56 0,59 0,61 0,62 0,66
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
79
Sample depth : 950 m Indigenous Ro (%) Average : 0,40 Range : 0,34-0,49 Std. Deviation : 0,05 No.of Readings : 19 Readings : 0,34 0,34 0,34 0,35 0,35 0,36 0,37 0,37 0,39 0,39 0,41 0,41 0,46 0,47 0,48 0,48 0,49
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 1200 m Indigenous Ro (%) Average : 0,43 Range : 0,36-0,52 Std. Deviation : 0,06 No.of Readings : 10 Readings : 0,36 0,36 0,38 0,40 0,42 0,43 0,45 0,48 0,49 0,52
Cavings
Ro (%) Average : 0,30 Range : 0,29-0,30 No.of Readings : 4 Readings : 0,29 0,30 0,30 0,31
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
80
Sample depth : 1300 m Indigenous Ro (%) Average : 0,45 Range : 0,38-0,53 Std. Deviation : 0,05 No.of Readings : 10 Readings : 0,38 0,39 0,40 0,43 0,45 0,46 0,46 0,49 0,52 0,53
Cavings
Ro (%) Average : 0,31 Range : 0,30-0,33 No.of Readings : 3 Readings : 0,29 0,30 0,30 0,31
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 1400 m Indigenous Ro (%) Average : 0,46 Range : 0,38-0,53 Std. Deviation : 0,05 No.of Readings : 13 Readings : 0,38 0,39 0,40 0,42 0,43 0,46 0,48 0,50 0,50 0,51 0,52 0,52 0,53
Cavings
Ro (%) Average : 0,35 Range : 0,35-0,35 No.of Readings : 1 Readings : 0,35
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
81
Sample depth : 1500 m Indigenous Ro (%) Average : 0,48 Range : 0,40-0,55 Std. Deviation : 0,05 No.of Readings : 12 Readings : 0,40 0,41 0,43 0,43 0,45 0,47 0,49 0,52 0,53 0,53 0,54 0,55
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 1600 m Indigenous Ro (%) Average : 0,51 Range : 0,44-0,56 Std. Deviation : 0,04 No.of Readings : 14 Readings : 0,44 0,46 0,47 0,48 0,49 0,49 0,51 0,53 0,53 0,53 0,54 0,54 0,55 0,56
Cavings
Ro (%) Average : 0,40 Range : 0,40-0,40 No.of Readings : 1 Readings : 0,40
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
82
Sample depth : 1700 m Indigenous Ro (%) Average : 0,53 Range : 0,48-0,58 Std. Deviation : 0,03 No.of Readings : 16 Readings : 0,48 0,49 0,49 0,51 0,51 0,52 0,53 0,54 0,54 0,55 0,55 0,56 0,56 0,56 0,57 0,58
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 1800 m Indigenous Ro (%) Average : 0,55 Range : 0,49-0,60 Std. Deviation : 0,04 No.of Readings : 11 Readings : 0,49 0,49 0,49 0,53 0,55 0,56 0,56 0,58 0,59 0,59 0,60
Cavings
Ro (%) Average : 0,46 Range : 0,45-0,46 No.of Readings : 2 Readings : 0,45 0,46
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
83
Sample depth : 1900 m Indigenous Ro (%) Average : 0,57 Range : 0,52-0,62 Std. Deviation : 0,03 No.of Readings : 8 Readings : 0,52 0,54 0,54 0,56 0,57 0,59 0,60 0,62
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 2080 m Indigenous Ro (%) Average : 0,59 Range : 0,56-0,63 Std. Deviation : 0,02 No.of Readings : 10 Readings : 0,56 0,56 0,57 0,58 0,58 0,59 0,59 0,59 0,60 0,63
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
84
Sample depth : 2150 m Indigenous Ro (%) Average : 0,60 Range : 0,56-0,63 Std. Deviation : 0,03 No.of Readings : 8 Readings : 0,56 0,57 0,58 0,60 0,60 0,62 0,63 0,63
Cavings
Ro (%) Average : 0,52 Range : 0,52-0,52 No.of Readings : 1 Readings : 0,52
Reworked
Ro (%) Average : 0,69 Range : 0,67-0,72 No.of Readings : 4 Readings : 0,67 0,67 0,69 0,72
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
Sample depth : 2210 m Indigenous Ro (%) Average : 0,61 Range : 0,58-0,65 Std. Deviation : 0,02 No.of Readings : 13 Readings : 0,58 0,59 0,59 0,60 0,60 0,61 0,61 0,61 0,62 0,63 0,64 0,65 0,65
28
21
14
7
0 1.0 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0
Vitrinite Reflectance
Read
ings
85
LAMPIRAN IV-4 DATA REFLEKTANSI VITRINIT, KOMPOSISI KEROGEN, DAN TAI
Fluo. Non Fluo.
1 160 DC 20 0,21 - 0,33 0,26 2 0,37 - 0,38 0,38 NDP - lt.yell 0 95 tr 5 0 Good
2 180 DC 6 0,21 - 0,23 0,22 2 0,25 - 0,27 0,26 NDP - lt.yell 0 90 tr 10 0 Good
3 440 DC Coal 26 0,27 - 0,30 0,28 Whole Rock NDP yell lt .yell/yell tr 20 2 78 tr Good
4 520 DC Coal 27 0,28 - 0,33 0,30 2- lt .yell lt .yell/yell tr 20 5 75 tr Good
5 540 DC 3 0,22 - 0,25 0,24 17 0,28 - 0,34 0,31 2- - lt .yell/yell 0 25 4 71 tr Good
6 710 DC 5 0,24 - 0,30 0,27 8 0,33 - 0,39 0,36 Whole Rock 2- to 2-/2 - lt .yell/yell tr 65 3 32 tr Good
7 840 DC 10 0,25 - 0,30 0,27 7 0,34 - 0,39 0,37 6 0,55 - 0,66 0,60 2- to 2-/2 yell lt .yell/yell 0 20 4 74 2 Good
8 950 DC 19 0,34 - 0,49 0,40 2-/2 to 2 - yell 0 30 3 67 0 Good
9 1130 DC 2-/2 to 2 - yell tr 15 3 82 tr Very Poor Poor
10 1200 DC 4 0,29 - 0,31 0,30 10 0,36 - 0,52 0,432-(*); 2-/2
to 2lt .yell/yell yell tr 25 4 71 0 Good
11 1300 DC 3 0,30 - 0,33 0,31 10 0,38 - 0,53 0,45 Barren 2-/2 to 2 lt .yell yell 0 30 3 67 0 Good
12 1400 DC 1 0,35 - 0,35 0,35 13 0,38 - 0,53 0,46 2 - yell 0 10 2 85 3 Good
13 1500 DC 12 0,40 - 0,55 0,48 2 to 2/2+ - yell 0 5 2 90 3 poor Poor
14 1600 DC 1 0,40 - 0,40 0,40 14 0,44 - 0,56 0,51 2 to 2/2+ - yell 0 40 2 56 2 Mod
15 1700 DC 16 0,48 - 0,58 0,53 2 to 2/2+ yell yell 0 45 3 50 2 Mod
16 1800 DC 2 0,45 - 0,46 0,46 11 0,49 - 0,60 0,55 2/2+ to 2+ - yell 0 65 2 30 3 Mod
17 1900 DC 8 0,52 - 0,62 0,57 2/2+ to 2+ - yell 0 60 2 34 4 Good
18 2080 DC 10 0,56 - 0,63 0,59 2/2+ to 2+ - yell 0 70 2 25 3 Good
19 2150 DC 1 0,52 - 0,52 0,52 8 0,56 - 0,63 0,60 4 0,67 - 0,72 0,69 2+ - - 0 65 3 28 4 Good
20 2210 DC 13 0,58 - 0,65 0,61 2+ - - 0 20 3 71 6 Good
Notes :
DC : Ditch Cuttings NDP : No Determination Possible Fluo. : Fluorescene lt.yell : light yellow/yellowish tr : trace (< 1%) Kerogen Residue : Barren (0); Very Poor (VP); Poor (P)
TAI : Thermal Alteration Index Barren : No or Poor Vitrinite and/or Lipt : Liptinite wht : white/whitish * : cavings
# R : Number of Readings No Measurable Vitrinite Vit. : Vitrinite gn : green/greenish ** : reworked/oxidized Additive Contaminant : + (trace < 1%); +++ (minor 1-5%);
Preparation : KC (Kerogen Concentrates); WR (Whole Rock) Inert. : Inertinite o : orange/orangish NA : Not Analysed ++++ (moderate 5-10%); +++++ (major >10%)
Scale :
1 - 5
Fluo.
Amorph.
Liptinite
(Herb.)
Mu
ara
En
im F
m.
Air
Ben
akat
Fm
.
# R Range Mean
Cavings/Suppressed Insitu Rework/Oxidized
# R Range Mean #R Range Mean
AmorphousLipt. Vit. Inert.
Remarks
(%)
No. F
orm
atio
nDepth (m)
Sam
ple
T
yp
e
An
alis
ed
Lith
olo
gy
Vitrinite Reflectance Kerogen Composition and TAI
Ker
ogen
Lev
el
Ro% Values
Remarks
TAIFluorescene Colors
(in Blue-Light Excitation)
86
LAMPIRAN IV-5A KEROGEN APPRAISAL SUMMARY : LUK-2
87
LAMPIRAN IV-5B GEOCHEMISTRY LOG/PETROLEUM SOURCE ROCK SUMMARY : LUK-2
88
LAMPIRAN IV-6A DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 1840
Peak Label Compound Name Peak Ht Norm %
nC5 Normal Alkane C5 ` #VALUE!
n C6 Normal Alkane C6 0 0,00
n C7 Normal Alkane C7 0 0,00
n C8 Normal Alkane C8 0 0,00
n C9 Normal Alkane C9 0 0,00
n C10 Normal Alkane C10 0 0,00
n C11 Normal Alkane C11 0 0,00
n C12 Normal Alkane C12 0 0,00
n C13 Normal Alkane C13 34 0,70
n C14 Normal Alkane C14 65 1,35
n C15 Normal Alkane C15 194 4,02
n C16 Normal Alkane C16 324 6,71 Pristane: 673
n C17 Normal Alkane C17 662 13,70 Phytane: 244
n C18 Normal Alkane C18 464 9,60 Pristane/Phytane: 2,76
n C19 Normal Alkane C19 290 6,00 Pristane/nC17: 1,02
n C20 Normal Alkane C20 255 5,28 Phytane/nC18: 0,53
n C21 Normal Alkane C21 179 3,71
n C22 Normal Alkane C22 166 3,44 n-Alkanes:
n C23 Normal Alkane C23 144 2,98 A. Total C25-C33 Odd: 1041,00
n C24 Normal Alkane C24 142 2,94 B. Total C24-C32 Even: 893,00
n C25 Normal Alkane C25 155 3,21 C. Total C26-C34 Even: 871,00
n C26 Normal Alkane C26 195 4,04 CPI* : 1,18
n C27 Normal Alkane C27 227 4,70
n C28 Normal Alkane C28 163 3,37 D. Total C23-C27 Odd: 526,00
n C29 Normal Alkane C29 189 3,91 E. Total C25-C29 Odd: 571,00
n C30 Normal Alkane C30 176 3,64 F. Total C24-C28 Even: 500,00
n C31 Normal Alkane C31 339 7,02 CPI2* : 1,10
n C32 Normal Alkane C32 217 4,49
n C33 Normal Alkane C33 131 2,71
n C34 Normal Alkane C34 120 2,48
n C35 Normal Alkane C35 0
n C36 Normal Alkane C36 0
n C37 Normal Alkane C37 0
4831 100,00
4831* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961
CPI2= (D+E)/;(2*F), after Marzi et al, 1993
WHOLE OIL GC DATA SHEET
n-AlkaneIsoprenoids
2 .0 0 4 .0 0 6 .0 0 8 .0 0 1 0 .0 0 1 2 .0 0 1 4 .0 0 1 6 .0 0 1 8 .0 0 2 0 .0 0
6 5 0 0
7 0 0 0
7 5 0 0
8 0 0 0
8 5 0 0
9 0 0 0
9 5 0 0
1 0 0 0 0
T i m e
R e s p o n s e _
S i g n a l : W B - 1 8 4 0 .D \F ID 1 A .C H
nC
14
nC
15 nC
21
nC
16 n
C17
nC
18
pr
ph nC
20
nC
19
nC
22
nC
23 nC
24nC
25
nC
26
nC
27
nC
13
nC
28 nC
29
nC
30
nC
31
nC
32
nC
33
nC
34
nC
35
89
LAMPIRAN IV-6B DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 1900 m
90
LAMPIRAN IV-6C DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2080 m
Peak Label Compound Name Peak Ht Norm %
nC5 Normal Alkane C5 0
n C6 Normal Alkane C6 0 0,00
n C7 Normal Alkane C7 0 0,00
n C8 Normal Alkane C8 0 0,00
n C9 Normal Alkane C9 0 0,00
n C10 Normal Alkane C10 0 0,00
n C11 Normal Alkane C11 0 0,00
n C12 Normal Alkane C12 0 0,00
n C13 Normal Alkane C13 28 0,66
n C14 Normal Alkane C14 53 1,25
n C15 Normal Alkane C15 136 3,21
n C16 Normal Alkane C16 260 6,14 Pristane: 479
n C17 Normal Alkane C17 524 12,38 Phytane: 173
n C18 Normal Alkane C18 454 10,73 Pristane/Phytane: 2,77
n C19 Normal Alkane C19 268 6,33 Pristane/nC17: 0,91
n C20 Normal Alkane C20 209 4,94 Phytane/nC18: 0,38
n C21 Normal Alkane C21 162 3,83
n C22 Normal Alkane C22 161 3,80 n-Alkanes:
n C23 Normal Alkane C23 154 3,64 A. Total C25-C33 Odd: 965,00
n C24 Normal Alkane C24 133 3,14 B. Total C24-C32 Even: 776,00
n C25 Normal Alkane C25 150 3,54 C. Total C26-C34 Even: 725,00
n C26 Normal Alkane C26 173 4,09 CPI* : 1,29
n C27 Normal Alkane C27 213 5,03
n C28 Normal Alkane C28 159 D. Total C23-C27 Odd: 517,00
n C29 Normal Alkane C29 187 E. Total C25-C29 Odd: 550,00
n C30 Normal Alkane C30 141 F. Total C24-C28 Even: 465,00
n C31 Normal Alkane C31 272 CPI2* : 1,15
n C32 Normal Alkane C32 170
n C33 Normal Alkane C33 143
n C34 Normal Alkane C34 82
n C35 Normal Alkane C35 0
n C36 Normal Alkane C36 0
n C37 Normal Alkane C37 0
4232 100
4232* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961
CPI2= (D+E)/;(2*F), after Marzi et al, 1993
WHOLE OIL GC DATA SHEET
n-AlkaneIsoprenoids
2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0
6 0 0 0
6 5 0 0
7 0 0 0
7 5 0 0
8 0 0 0
8 5 0 0
9 0 0 0
9 5 0 0
T im e
R e s p o n s e _
S ig n a l: W B -2 0 8 0 . D \ F I D 1 A . C H
nC
14
nC
15
nC
21
nC
16
nC
17
nC
18
pr
ph
nC
20
nC
19
nC
22
nC
23
nC
24 n
C2
5nC
26
nC
27
nC
13
nC
28
nC
29
nC
30
nC
31
nC
32
nC
33
nC
34
91
LAMPIRAN IV-6D DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2150 m
Peak Label Compound Name Peak Ht Norm %
nC5 Normal Alkane C5 0
n C6 Normal Alkane C6 0 0,00
n C7 Normal Alkane C7 0 0,00
n C8 Normal Alkane C8 0 0,00
n C9 Normal Alkane C9 0 0,00
n C10 Normal Alkane C10 0 0,00
n C11 Normal Alkane C11 0 0,00
n C12 Normal Alkane C12 0 0,00
n C13 Normal Alkane C13 21 0,52
n C14 Normal Alkane C14 40 0,99
n C15 Normal Alkane C15 96 2,37
n C16 Normal Alkane C16 234 5,77 Pristane: 432
n C17 Normal Alkane C17 771 19,00 Phytane: 156
n C18 Normal Alkane C18 497 12,25 Pristane/Phytane: 2,77
n C19 Normal Alkane C19 248 6,11 Pristane/nC17: 0,56
n C20 Normal Alkane C20 201 4,95 Phytane/nC18: 0,31
n C21 Normal Alkane C21 132 3,25
n C22 Normal Alkane C22 151 3,72 n-Alkanes:
n C23 Normal Alkane C23 125 3,08 A. Total C25-C33 Odd: 842,00
n C24 Normal Alkane C24 124 3,06 B. Total C24-C32 Even: 699,00
n C25 Normal Alkane C25 128 3,16 C. Total C26-C34 Even: 575,00
n C26 Normal Alkane C26 159 3,92 CPI* : 1,33
n C27 Normal Alkane C27 161 3,97
n C28 Normal Alkane C28 132 3,25 D. Total C23-C27 Odd: 414,00
n C29 Normal Alkane C29 203 5,00 E. Total C25-C29 Odd: 492,00
n C30 Normal Alkane C30 156 3,85 F. Total C24-C28 Even: 415,00
n C31 Normal Alkane C31 216 5,32 CPI2* : 1,09
n C32 Normal Alkane C32 128 3,16
n C33 Normal Alkane C33 134 3,30
n C34 Normal Alkane C34 0
n C35 Normal Alkane C35 0
n C36 Normal Alkane C36 0
n C37 Normal Alkane C37 0
4057
4057* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961
CPI2= (D+E)/;(2*F), after Marzi et al, 1993
WHOLE OIL GC DATA SHEET
n-AlkaneIsoprenoids
2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0
6 0 0 0
6 2 0 0
6 4 0 0
6 6 0 0
6 8 0 0
7 0 0 0
7 2 0 0
7 4 0 0
7 6 0 0
7 8 0 0
8 0 0 0
8 2 0 0
8 4 0 0
8 6 0 0
8 8 0 0
9 0 0 0
T i m e
R e s p o n s e _
S i g n a l : W B - 2 1 5 0 . D \ F I D 1 A . C H
nC
14
nC
15 nC
21
nC
16
nC
17
nC
18
pr
ph n
C2
0
nC
19
nC
22
nC
23 nC
24 n
C25
nC
26
nC
27
nC
13
nC
28
nC
29
nC
30
nC
31
nC
32
nC
33
92
LAMPIRAN IV-6E DATA GC SUMUR LUK-2 SAMPEL CUTTINGS 2210 m
Peak Label Compound Name Peak Ht Norm %
nC5 Normal Alkane C5 0
n C6 Normal Alkane C6 0 0,00
n C7 Normal Alkane C7 0 0,00
n C8 Normal Alkane C8 0 0,00
n C9 Normal Alkane C9 0 0,00
n C10 Normal Alkane C10 0 0,00
n C11 Normal Alkane C11 0 0,00
n C12 Normal Alkane C12 0 0,00
n C13 Normal Alkane C13 23 0,80
n C14 Normal Alkane C14 39 1,36
n C15 Normal Alkane C15 83 2,89
n C16 Normal Alkane C16 215 7,48 Pristane: 140
n C17 Normal Alkane C17 176 6,12 Phytane: 76
n C18 Normal Alkane C18 173 6,02 Pristane/Phytane: 1,84
n C19 Normal Alkane C19 145 5,04 Pristane/nC17: 0,80
n C20 Normal Alkane C20 134 4,66 Phytane/nC18: 0,44
n C21 Normal Alkane C21 129 4,49
n C22 Normal Alkane C22 122 4,24 n-Alkanes:
n C23 Normal Alkane C23 145 5,04 A. Total C25-C33 Odd: 28,83
n C24 Normal Alkane C24 118 4,10 B. Total C24-C32 Even: 23,03
n C25 Normal Alkane C25 138 4,80 C. Total C26-C34 Even: 18,92
n C26 Normal Alkane C26 152 5,29 CPI* : 1,39
n C27 Normal Alkane C27 184 6,40
n C28 Normal Alkane C28 146 5,08 D. Total C23-C27 Odd: 16,24
n C29 Normal Alkane C29 188 6,54 E. Total C25-C29 Odd: 17,74
n C30 Normal Alkane C30 136 4,73 F. Total C24-C28 Even: 14,47
n C31 Normal Alkane C31 201 6,99 CPI2* : 1,17
n C32 Normal Alkane C32 110 3,83
n C33 Normal Alkane C33 118 4,10
n C34 Normal Alkane C34 0
n C35 Normal Alkane C35 0
n C36 Normal Alkane C36 0
n C37 Normal Alkane C37 0
2995 100
2875* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961
CPI2= (D+E)/;(2*F), after Marzi et al, 1993
Isoprenoids
WHOLE EXTRACT GC DATA SHEET
n-Alkane
2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0
6 0 0 0
6 2 0 0
6 4 0 0
6 6 0 0
6 8 0 0
7 0 0 0
7 2 0 0
7 4 0 0
7 6 0 0
7 8 0 0
8 0 0 0
8 2 0 0
8 4 0 0
8 6 0 0
8 8 0 0
T i m e
R e s p o n s e _
S i g n a l : W B - 2 2 1 0 . D \ F I D 1 A . C H
nC
14
nC
15
nC
21
nC
16
nC
17
nC
18
pr
ph
nC
20
nC
19 nC
22
nC
23 nC
24nC
25
nC
26
nC
27
nC
13
nC
28
nC
29
nC
30
nC
31
nC
32
nC
33
93
LAMPIRAN IV-7 DATA GC SUMUR LUK-2 SAMPEL OIL 1130 m
Peak Label Compound Name Peak Ht Norm %
nC5 Normal Alkane C5
n C6 Normal Alkane C6
n C7 Normal Alkane C7
n C8 Normal Alkane C8
n C9 Normal Alkane C9
n C10 Normal Alkane C10
n C11 Normal Alkane C11
n C12 Normal Alkane C12
n C13 Normal Alkane C13 3971 0,39
n C14 Normal Alkane C14 16367 1,60
n C15 Normal Alkane C15 36691 3,59
n C16 Normal Alkane C16 47374 4,63 Pristane: 95323
n C17 Normal Alkane C17 57798 5,65 Phytane: 15752
n C18 Normal Alkane C18 61410 6,00 Pristane/Phytane: 6,05
n C19 Normal Alkane C19 68496 6,70 Pristane/nC17: 1,65
n C20 Normal Alkane C20 69324 6,78 Phytane/nC18: 0,26
n C21 Normal Alkane C21 67183 6,57
n C22 Normal Alkane C22 67258 6,57 n-Alkanes:
n C23 Normal Alkane C23 66656 6,52 A. Total C25-C33 Odd: 21,21
n C24 Normal Alkane C24 67308 6,58 B. Total C24-C32 Even: 23,23
n C25 Normal Alkane C25 68265 6,67 C. Total C26-C34 Even: 16,96
n C26 Normal Alkane C26 68580 6,70 CPI* : 1,08
n C27 Normal Alkane C27 70538 6,89
n C28 Normal Alkane C28 59114 5,78 D. Total C23-C27 Odd: 20,08
n C29 Normal Alkane C29 44689 4,37 E. Total C25-C29 Odd: 17,94
n C30 Normal Alkane C30 29875 2,92 F. Total C24-C28 Even: 19,06
n C31 Normal Alkane C31 23728 2,32 CPI2* : 1,00
n C32 Normal Alkane C32 12748 1,25
n C33 Normal Alkane C33 9732 0,95
n C34 Normal Alkane C34 3154 0,31
n C35 Normal Alkane C35 1771 0,17
n C36 Normal Alkane C36 700 0,07
n C37 Normal Alkane C37 349 0,03
n C38 Normal Alkane C38
1023079,00* CPI= 0.5*((A/B) + (A/C)), after Bray and Evans, 1961
CPI2= (D+E)/;(2*F), after Marzi et al, 1993
WHOLE OIL GC DATA SHEET
n-AlkaneIsoprenoids
2 . 0 0 4 . 0 0 6 . 0 0 8 . 0 0 1 0 . 0 0 1 2 . 0 0 1 4 . 0 0 1 6 . 0 0 1 8 . 0 0 2 0 . 0 0
5 0 0 0
1 0 0 0 0
1 5 0 0 0
2 0 0 0 0
2 5 0 0 0
3 0 0 0 0
3 5 0 0 0
4 0 0 0 0
4 5 0 0 0
5 0 0 0 0
5 5 0 0 0
6 0 0 0 0
6 5 0 0 0
7 0 0 0 0
7 5 0 0 0
8 0 0 0 0
8 5 0 0 0
9 0 0 0 0
9 5 0 0 0
1 0 0 0 0 0
T i m e
R e s p o n s e _
S i g n a l : B T 4 7 4 9 8 W . D \ F I D 1 A . C H
nC
14
nC
15
nC
16
nC
17
nC
18
pr
ph
nC
19
nC
20
nC
22
nC
24
nC
26
nC
27
nC
28
nC
29
nC
30
nC
31
nC
32
nC
33
nC
34
nC
35
nC
36
nC
37
nC
13
nC
21
nC
23
nC
25
94
LAMPIRAN IV-8 DATA GC-MS SATURATES SUMUR LUK-2
GC-MS PEAK ABUNDANCE* DATA - TERPANES (m/z 191)
Peak ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil
1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m
Tricyclics
A 82 20 49 10 12 6049 B 106 30 82 15 26 4238
C 76 24 70 14 23 2214
D 107 35 129 20 56 1672
E 64 20 62 7 24 2042 F 119 42 231 24 78 1739
G 68 27 195 13 48 1678
H 20 24 45 8 19 3117
I 32 12 98 5 15 1091
K 0 0 0 0 0 4324 L 0 0 0 0 0 6329
Total 674 234 961 116 301 34493
Tetracyclics
X1 192 33 256 21 84 7356
X2 207 172 480 58 146 435 X3 243 60 291 23 94 505
X4 18 12 0 0 0 2858
X5
X6 118 34 264 17 68 578
X7 0 0 0 0 0 1223 X8
Total 778 311 1291 119 392 12955
**Bicadinanes
R1 5 0 21 0 0 730
R2 10 0 21 0 0 466
R3 23 0 110 0 16 3056
R4 27 0 37 0 0 803 R5 42 0 182 0 30 7213
R6 18 0 37 0 10 1364
R' 34 0 67 0 21 1329
Total 159 0 475
77 14961
Tricyclics: A,B = C19
C = C20
D,E = C21
F = C23
G = C24
H = C25
I = C26
K = C28 pair
L = C29 pair
X1 = 10ß(H)-des-A-Oleanane Bicadinanes:
X2 = 10ß(H)-des-A-Lupane R1 - R6 = C30 Resin Derived Alkanes X3 = C24 Tetracyclic (Unidentified) R' = C31 Resin Derived Alkane X4 = 10ß(H)-des-A-Ursane
X5 = C24 Tetracyclic (Coals)
X6 = C24 17,21-Secohopane
X7 = C25 17,21-Secohopane
X8 = C26 17,21-Secohopane
95
* Peak
Abundance in units
See Terpane Peak Identification Table for Normal Peak ID's
C30 = Unidentified Higher Plant Related (Non-Bicadinane) Terpanes
C27ß = 17ß(H)-22,29,30-Trisnorhopane (Immature)
C30/C31 ßß = ßß Hopanes (Immature)
GC-MS PEAK ABUNDANCE* DATA - TERPANES (m/z 191)
Peak
ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil
1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m
C30 Terpanes
C30 699 226 1889 66 342 3570
C30
C30
Total 699 226 1889 66 342 3570
Hopanes and Moretanes 1 117 24 562 16 62 6701
2 318 166 818 44 181 2443
3'
3 0 0 0 0 0 0
4 503 329 1600 79 352 4114
5 195 23 199 12 68 16137 6 699 226 1889 66 342 3570
7 239 115 505 28 112 2830
8 97 63 369 20 59 3294
9 254 281 661 46 156 253
10 100 74 145 11 38 2109 11 21 10 151 0 18 1392
12 43 34 157 0 29 742
13 0 0 65 0 0 492
14 0 0 80 0 0 417
15 0 0 39 0 0 272 16 0 0 35 0 0 97
17 0 0 0 0 0 0
18 0 0 0 0 0 0
Total 2586 1345 7275 322 1417 44863
Other Terpanes Cy 226 131 718 33 146 1395
Cz 366 242 663 58 211 3528
Cx 50 17 165 10 24 1923
C30 ßß
C31 ßß Total 642 390 1546 101 381 6846
Ol 296 48 560 26 171 24802
Tx 124 0 119 12 74 4570
Gm 0 0 0 0 0 0
96
GC-MS PEAK ABUNDANCE* DATA - STERANES
Peak
ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil
1840 m 1900 m 2080 m 2150 m 2210 m
DST-2 1130
m
Steranes (m/z 217)
1 25 8 119 6 22 498
2,3 13 4 101 2 8 415
4 22 6 129 4 10 423 5 76 26 187 13 50 563
6 46 8 53 3 14 425
7,8 35 12 130 3 18 544
9 19 18 94 4 13 1287
10 55 19 103 5 30 223 11 27 17 92 6 15 793
12,13 76 28 194 9 38 932
14 41 40 106 9 27 463
15 253 69 363 24 109 1120
Total 688 255 1671 88 354 7686
Steranes (m/z 218)
1 19 9 49 4 12 247 2,3 20 7 179 5 11 525
4 16 10 154 4 11 455
5 45 21 93 9 27 318
6 37 24 84 5 20 204
7,8 96 49 175 13 42 570 9 143 124 297 26 84 467
10 70 66 256 72 245 364
11 218 192 479 43 122 667
12,13 153 175 566 53 117 1268
14 592 201 944 73 246 2080 15 1361 1151 2333 192 816 1055
Total 2770 2029 5609 499 1753 8220
See Sterane Peak Identification Table for
Peak ID's
* Peak Abundance in units
GC-MS PEAK ABUNDANCE* DATA - DIASTERANES
Peak ID Cuttings Cuttings Cuttings Cuttings Cuttings Oil
1840 m 1900 m 2080 m 2150 m 2210 m DST-2 1130 m
Diasteranes (m/z 217)
A 15 8 193 3 13 551 B 14 7 138 3 9 503
C 6 5 91 2 6 282
D 7 4 88 2 7 285
E 25 7 138 4 13 554
F 24 9 108 5 15 498 a
b
c 6 4 54 2 4 314
d 8 4 84 2 8 529
e f
Total 105 48 894 23 75 3516
See Sterane Peak Identification Table for
Peak ID's
* Peak Abundance in units
97
LAMPIRAN IV-9 DATA GC-MS AROMATICS SUMUR LUK-2
GC-MS PEAK ABUNDANCE* DATA - AROMATICS
Peak ID
Cuttings Cuttings Cuttings Cuttings Cuttings LUK- 2
1840 m 1900 m 2080 m 2150 m 2210 m DST-2 [oil , 1130 m]
Dimethylnaphthalenes (m/z 156)
1,2 (2,6 + 2,7-DMN) 39 11 22
162736
3 (1,3 + 1,7-DMN) 41 12 17
93334
4 1,6-DMN 105 27 40
196185 5 (2,3 + 1,4-DMN) 20 8 10
44216
6 1,5-DMN 9 4 6
16893 7 1,2-DMN 12 4 7
38761
Total
226 66 102 0 0 552125 Max Abundance
1 1 1 1 1 1
Trimethylnapthalenes
(m/z 170) 8 1,3,7-TMN 63 20 28
4 74474 9 1,3,6-TMN 91 32 42
7 81039
10 (1,3,5+1,4,6-TMN) 65 23 31
5 84907
11 2,3,6-TMN 73 21 31
5 53182 12 1,2,7-TMN 65 23 34
6 59540
13 1,6,7-TMN 61 20 30
4 47098 14 1,2,6-TMN 46 15 22
2 37297
15 1,2,4-TMN 10 4 8
7 19967 16 1,2,5-TMN 66 23 33
2 73126
Total
540 181 259 0 42 530630 Max Abundance
1 1 1 1 1 1
Phenanthrenes (m/z 178, 192)
17 P 639 93 173 43 45 10027
18 3-MP 44 7 25 7 8 1930 19 2-MP 43 9 25 9 9 1664 20 9-MP 60 12 33 12 12 2001 21 1-MP 46 8 25 8 8 1166
Total
832 129 281 79 82 16788 Max Abundance
1 1 1 1 1 1
Triaromatic Steranes (m/z 231)
C20 C21 C2620S C2620R+C2720S
C2820S C2720R C2820R
Total
0 0 0
0 Max Abundance
1 1 1
1
Monoaromatic Steranes (m/z 253)
C28a20R + C29b20R
C29a20R Max Abundance
1 1 1
1
Intermediate Stages in Calc. of Ro1 and Ro2
F1
0,45 0,44 0,46 0,44 0,46 0,53 F2
0,22 0,25 0,23 0,25 0,24 0,25
98
LAMPIRAN IV-10 HASIL PERHITUNGAN DATA GC-MS SATURATES SUMUR LUK-2
GC-MS BIOMARKER DATA: TERPANES (m/z 191)
Sample ID C19 Tri (B) % C28-C29 Tri Des-A-Lup % C24-C26 Sec Cy C29 Hop Tot Bicad Ol Gm x 100
C23 Tri (F) Tot Tri Des-A-Ol Tot Tetr C29 Hop C30 Hop C30 Hop C30 Hop C30 Hop
a,b,c
a
a,b
a
a,b
a,b
a,c
a,c
a,c
Cuttings 1840 m
0,89
0,00
1,08
15,17
0,45
0,72
0,23
0,42
0,00
Cuttings 1900 m
0,71
0,00
5,21
10,93
0,40
1,46
0,00
0,21
0,42
Cuttings 2080 m
0,35
0,00
1,88
20,45
0,45
0,85
0,25
0,30
0,00
Cuttings 2150 m
0,625
0,00
2,76
14,29
0,42
1,20
0,00
0,39
0,00
Cuttings 2210 m
0,33
0,00
1,74
17,35
0,41
1,03
0,23
0,50
0,00
DST-2 Oil 1130 m
2,44
30,88
0,06
4,46
0,34
1,15
4,19
6,95
0,00
Type of Parameter: a = Source
b = Maturity
c = Biodegradation
GC-MS BIOMARKER DATA: STERANES (m/z 217)
Sample ID Tot Hop Tot Pregn C27 Dia % Total Steranes* 15B Drim
Tot Ster Tot Ster Tot Dia C27 C28 C29 Homodrim Homodrim
a,b,c
a,b,c
a,b,c
a,b,c
a
a,b
Cuttings 1840 m
3,76
0,00
0,28
19,7674
22,53
57,70
0,04
0,11
Cuttings 1900 m
5,27
0,00
0,31
17,25
22,35
60,39
0,07
0,14
Cuttings 2080 m
4,35
0,00
0,37
32,08
22,74
45,18
0,06
0,15
Cuttings 2150 m
3,66
0,00
0,26
28,41
17,05
54,55
0,01
0,19
Cuttings 2210 m
4,00
0,00
0,29
25,42
21,19
53,39
0,50
0,31
LUK- 2 DST-2 [oil, 1130 m]
5,84
1,95
0,30
24,71
32,25
43,04
1,93
0,87
99
GC-MS BIOMARKER DATA: DISTRIBUTION OF TERPANE CLASSES ON m/z 191
Sample ID % % % % % % % % %
C19-C22 C23+ C24 Des-A C24-C26 C30-C31 C30* Ol Hopanes & Gm
Tricyc Tricyc Tetracyc 17,21-Secohop Bicad Terpanes Moretanes
a,b,c a,b c b a,c a,c c b b,d
Cuttings 1840 m 7,30 4,01 11,08 1,98 2,67 11,73 4,97 54,18 0,00
Cuttings 1900 m 5,05 4,11 10,85 1,33 0,00 8,85 1,88 67,93 0,00
Cuttings 2080 m 2,78 4,03 7,28 1,87 3,36 13,38 3,97 62,49 0,00
Cuttings 2150 m 8,66 6,56 13,39 2,23 0 8,66 3,41 55,51 0,00
Cuttings 2210 m 4,47 5,07 10,27 2,16 2,44 10,84 5,42 56,99 0,00
LUK- 2 DST-2 [oil, 1130 m] 11,03 12,43 7,58 1,22 10,17 2,43 16,87 35,16 0,00
Predominant Source: a = Maturity dependent
b = Bacterial/algal
c = Higher plant
d = Salinity indicator
100
LAMPIRAN IV-11 HASIL PERHITUNGAN DATA GC-MS AROMATICSS SUMUR LUK-2
GC-MS AROMATICS MATURITY PARAMETERS*
Sample ID DNR-
1 DNR-
6 TNR-
1 TNR-
3 TNR-
4 MPR-
1 MPR-
2 MPI-
1 MPI-
2
Calculated Ro.
Vit. (%)**
# Ro. Vit.
Rc1 Rc2 Ro1 Ro2 (%)
Cuttings 1840 m
4,33
1,95
1,12
6,60
1,41
1,89
0,72
0,18
0,17
0,51
0,80 0,84
0,72
0,55
Cuttings 1900 m
2,75
1,38
0,91
5,75
1,53
2,00
0,75
0,21
0,24
0,53
0,82 0,83
0,82
0,57 Cuttings 2080 m
3,67
2,20
1,00
4,13
1,55
2,00
0,76
0,32
0,32
0,59
0,82 0,87
0,75
0,59
Cuttings 2150 m
0,00
0,00
0,00
0,00
0,00
2,00
0,75
0,38
0,43
0,63
0,82 0,83
0,82
0,60 Cuttings 2210 m
0,00
0,00
1,00
0,29
3,00
2,13
0,75
0,39
0,42
0,64
0,82 0,86
0,80
0,61
DST-2 Oil 1130 m
9,63
3,68
0,63
3,66
1,60
3,08
0,83
0,41
0,38
0,65
0,86 1,03
0,81
-
DNR = Dimethylnaphthalene Ratio
MPR = Methylphenanthrene Ratio
* See Appendices for calculations and references
TNR = Trimethylnaphthalene Ratio
MPI = Methylphenanthrene Index
** From published formulae: see Appendices for derivation
TA = Triaromatic Sterane
and references
# Measured (sediments)
101
LAMPIRAN IV-12 KETERANGAN PUNCAK KROMATOGRAM
TERPANE PEAK IDENTIFICATIONS (m/z 191)
Peak No. Carbon No. Identification
A,B 19 Tricyclic terpane C 20 Tricyclic terpane D,E 21 Tricyclic terpane F 23 Tricyclic terpane G 24 Tricyclic terpane H 25 Tricyclic terpane I 26 Tricyclic terpane
X1 24 10(H)-de-A-Oleanane
X2 24 10(H)-de-A-Lupane
X3 24 Tetracyclic Terpane
X4 24 10(H)-de-A-Ursane
X5 24 Tetracyclic Terpane (coals)
X6,X7,X8 24-26 17,21-Secohopane
J 27 Tricyclic terpane K 28 Tricyclic terpanes L 29 Tricyclic terpanes R 30 Bicadinane
1 27 18(H),21(H)-22,29,30-trisnorneohopane (Ts)
2 27 17(H),21(H)-22,29,30-trisnorhopane (Tm) R' 31 Homobicadinane
3’ 28 17(H),21(H)-29,30-bisnorhopane C27 27 17(H),21(H)-22,29,30-trisnorhopane
3 28 17(H),21(H)-28,30-bishorhopane
4 29 17(H),21(H)-30-norhopane Cy 29 18(H),21(H)-30-norhopane (C29 Ts)
Cz 30 15-methyl-17(H)-27-norhopane (diahopane)
Cx 30 Pentacyclic Terpane
5 29 17(H),21(H)-30-normoretane Ol 30 18(H)-Oleanane
6 30 17(H),21(H)-hopane
7 30 17(H),21(H)-moretane Gm 30 Gammacerane
8 31 17(H),21(H)-30-homohopane (22S)
9 31 17(H),21(H)-30-homohopane (22R)
10 31 17(H),21(H)-30-homomoretane 11 32 17(H),21(H)-30,31-bishomohopane (22S)
12 32 17(H),21(H)-30,31-bishomohopane (22R)
13 33 17(H),21(H)-30,31,32-trishomohopane (22S) 14 33 17(H),21(H)-30,31,32-trishomohopane (22R)
102
15 34 17(H),21(H)-30,31,32,33-tetrahomohopane (22S)
16 34 17(H),21(H)-30,31,32,33-tetrahomohopane (22R)
17 35 17(H),21(H)-30,31,32,33,34-pentahomohopane (22S) 18 35 17(H),21(H)-30,31,32,33,34-pentahomohopane (22R) MH 28-36 Methylated Hopane (m/z 205)
103
STERANE PEAK IDENTIFICATIONS (m/z 217, 218, 259)
Peak No. Carbon No. Identification
A 27 13(H),17(H)-Diacholestane (20S) B 27 13(H),17(H)-Diacholestane (20R)
C 28 24-Methyl-13(H),17(H)-Diacholestane (20S)
D 28 24-Methyl-13(H),17(H)-Diacholestane (20R)
E 29 24-Ethyl-13(H),17(H)-Diacholestane (20S)** ¹F 29 24-Ethyl-13(H),17(H)-Diacholestane (20R)
a 27 13(H),17(H)-Diacholestane (20S)
b 27 13(H),17(H)-Diacholestane (20R) c 28 24-Methyl-13(H),17(H)-Diacholestane (20S)
d 28 24-Methyl-13(H),17(H)-Diacholestane (20R)
e 29 24-Ethyl-13(H),17(H)-Diacholestane (20S) f 29 24-Ethyl-13(H),17(H)-Diacholestane (20R)
1 27 5(H),14(H),17(H)-Cholestane (20S)
¹2 27 5(H),14(H),17(H)-Cholestane (20R) ¹3 27 5(H),14(H),17(H)-Cholestane (20R)
4 27 5(H),14(H),17(H)-Cholestane (20S)
5 27 5(H),14(H),17(H)-Cholestane (20R)** 6 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20S)**
²7 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)**
²8 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)** 9 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20S)
10 28 24-Methyl-5(H),14(H),17(H)-Cholestane (20R)
11 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20S)
12 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R) 13 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R)
14 29 24-Ethyl-5(H),15(H),17(H)-Cholestane (20S)
15 29 24-Ethyl-5(H),14(H),17(H)-Cholestane (20R) R 30 Bicadinane R' 31 Homobicadinane
DI- AND TRINUCLEAR AROMATIC HYDROCARBON
PEAK IDENTIFICATIONS
Peak No. Dimethylnaphthalenes (m/z 156) 1 2,6-DMN 2 2,7-DMN
104
3 (1,3 + 1,7)-DMN 4 1,6-DMN 5 (2,3 + 1,4)-DMN 6 1,5-DMN 7 1,2-DMN Trimethylnaphthalenes (m/z 170) 8 1,3,7-TMN 9 1,3,6-TMN 10 (1,3,5 + 1,4,6)-TMN 11 2,3,6-TMN 12 1,2,7-TMN 13 1,6,7-TMN 14 1,2,6-TMN 15 1,2,4-TMN 16 1,2,5-TMN
Tetramethylnaphthalenes (m/z 184) 17 1,3,5,7-TeMN 18 1,3,6,7-TeMN 19 1,2,4,6-TeMN 20 1,2,5,7-TeMN 21 2,3,6,7-TeMN 22 1,2,6,7-TeMN 23 1,2,3,7-TeMN 24 1,2,3,6-TeMN 25 1,2,5,6-TeMN 26 DBT
Cadalenes (m/z 198) C Cadalene iC iso-Cadalene
105
Phenanthrenes (m/z 178, 192) 17 P 18 3-MP 19 2-MP 20 9-MP 21 1-MP
Dimethylphenanthrenes (m/z 206) 32 (3,5 + 2,6)-DMP 33 2,7-DMP 34 (1,3 + 3,9 + 3,10+2,10)-DMP 35 (1,6 + 2,9 + 2,5)-DMP 36 1,7-DMP 37 (2,3 + 1,9)-DMP 38 (4,9 + 4,10)-DMP
Triaromatic Steranes (m/z 231) 39 C20 TAS 40 C21 TAS 41 C26 20S TAS 42 C26 20R + C27 20S TAS 43 C28 20S TAS 44 C27 20R TAS 45 C28 20R TAS
Monoaromatic Steranes (m/z 253) 46 5b-Stigmastane 20R+Diastigmastane 20R MAS 47 28a20R+C29b20R MAS
106
GC-MS AROMATICS MATURITY PARAMETER CALCULATION
Parameter Compounds Peak No's DNR-1 = 2,6-DMN+2,7-DMN 1+2 1,5-DMN 6 DNR-6 = 2,6-DMN+2,7-DMN 1+2 1,4-DMN+2,3-DMN 5 TNR-1 = 2,3,6-TMN 11 1,3,5-TMN+1,4,6-TMN 10 TNR-2 = 1,3,7-TMN+2,3,6-TMN 8+11 1,3,6-TMN+1,3,5-TMN+1,4,6-TMN 9+10 TNR-3 = 1,2,5-TMN 16 1,2,4-TMN 15 TNR-4 = 1,2,7-TMN 12 1,2,6-TMN 14 *MPR-1 = 2-MP+3-MP 19+18 1-MP 21 *MPR-2 = 2-MP 19 9-MP 20 MPI-1 = 1.5 * (2-MP+3-MP) 1.5 * (19+18) P+1-MP+9-MP 17+21+20 MPI-2 = 3 * (2-MP) 3 * (19) P+1-MP+9-MP 17+21+20 DNR and TNR after Alexander et al, 1985, 1986, Radke et al, 1986 MPR and MPI after after Radke et al, 1982, 1983 *Radke, 1987: MPR-1 = 1-MP/P; MPR-2 = 2-MP/P; MPR-3 = 3-MP/P; MPR-9 = 9-MP/P.
107
CALCULATION OF EQUIVALENT VITRINITE REFLECTANCE
Parameter : MPI-1 = 1.5 * (2-MP + 3-MP) P + 1-MP + 9-MP MPR-2 = 2-MP 9-MP F1 = 2-MP + 3-MP 2-MP + 3-MP + 1-MP + 9-MP
F2 = 2-MP 2-MP + 3-MP + 1-MP + 9-MP
Equivalent Reflectance (%) :
Rc1 = 0.6 MPI-1 + 0.4 (for Ro. <
1.35%) = -0.6 MPI-1 + 2.3 (for Ro. > 1.35%)
Rc2 = 0.99 (Log10 MPR-2) + 0.94
Ro1 = -0.166 + 2.242F1
Ro2 = -0.112 + 3.739F2
Rc1 and Rc
2 after Radke et al, 1983, 1984
Ro1and Ro
2 after Kvalheim et al, 1987
108
109
110
111
112
113