ZEITSCHRIFT FأœR NATURFORSCHUNG Transition Metal Sulfur Ylide Complexes, XL Structure and Reactivity

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  • Z E I T S C H R I F T FÜR N A T U R F O R S C H U N G

    T E I L Β

    Anorganische Chemie, Organische Chemie

    Beratende Herausgeber

    E . 0 . F I S C H E R , München G . G L I E M A N N , Regensburg H . N Ö T H , München D . S C H U L T E - F R O H L I N D E , Mülheim/R. F . F . S E E L I G , Tübingen W . S T E G L I C H , B o n n W . V O E L T E R . Tübingen A . W E I S S , München

    H E R A U S G E G E B E N U N T E R M I T W I R K U N G

    D E R I N S T I T U T E D E R M A X - P L A N C K - G E S E L L S C H A F T

    K u r a t o r i u m

    E . B Ü N N I N G , Tübingen A . B T J T E N A N D T , München M . E I G E N , Göttingen W . G E N T N E R , Heide lberg

    Schriftführende Herausgeber

    H . P . F R I T Z , München R . G O M P P E R , München H . S C H M I D B A U R , München

    1981 B A N D 36 b

    V E R L A G D E R Z E I T S C H R I F T F Ü R N A T U R F O R S C H U N G T Ü B I N G E N

  • Teil a enthält Arbeiten aus Physik, physikalischer Chemie, Kosmophysik

    Teil e enthält Arbeiten aus Biochemie, Biophysik, Biologie, Virologie

  • B a n d 3 6 b Z e i t s c h r i f t für N a t u r f o r s c h u n g 1981

    Contents

    C o n t e n t s o f N u m b e r 1

    Original Communications

    Electrochemical Syntheses, I V . M e t a l Carbony l Compounds of the I ron Group Elements (In German) J . G R O B E a n d B . H . S C H N E I D E R 1

    Electrochemical Syntheses, V . Phosphane Subst i ­ tuted M e t a l Carbonyls of the I ron Group Elements (In German) J . G R O B E a n d B . H . S C H N E I D E R 8

    The C r y s t a l Structures of BaSe2 and B a S e 3 F . H U L L I G E R and T . SIEGRIST 14

    A c y l - and Alkylidenephosphines, X V . 2 ,2 -Dimethyl - propylidynephosphine, a Stable Compound w i t h a Phosphorus A t o m of Coordinat ion N u m b e r 1 (In German) G . B E C K E R , G . G R E S S E R , and W . U H L 16

    I R , 3 1 P , 5 5 M n and 1 8 5 . 1 8 7 R e N M R Spectroscopic Investigations of Some Carbonylmanganese and -rhenium Complexes (In German) A . K E Ç E C I and D . R E H D E R 20

    O n Oxidpnict ides : Preparat ion and Crys ta l Struc­ ture of B a 2 M n 2 S b 2 0 and B a 2 M n 2 B i 2 0 (In German) E . B R E C H T E L , G . CORDIER , and H . S C H Ä F E R 27

    Solutions of L i t h i u m Tetrahydrido Aluminates i n E t h e r s : a 7 L i and 2 7 A 1 N M R Study H . N o r a , R . R U R L Ä N D E R , and P . W O L F G A R D T 31

    Penta-Coordinated Complexes of Bis(2,4-pentane- dionato) Copper(II) w i t h Some Oxygen Donor Organic Solvents B . P . B A R A N W A L , G . K . P A R A S H A R , and R . C. M E H R O T R A 42

    The React ion between Borontrinuoride and Sodium Diethylphosphite Synthesis and Reactions of Tris(diethylphosphitoborane) (In German) H . B I N D E R and J . P A L M T A G 45

    Perf luoromethyl Element Ligands , X X I V ; Organo t i n Compounds as Reagents, I I I . Cleavage Reactions of the E l e m e n t - E l e m e n t - B o n d i n Compounds of the Type R n E - E R m (R = C H 3 C F 3 ; E = Ρ, A s , S, Se, T e ; n,m = 1, 2) (In German) P . D E H N E R T , J . G R O B E , and D u c L E V A N 48

    Preparat ion and Crysta l Structure of S b C l 3 I 2 - 1 , 4 - Di th iane (In German) G . K I E L 55

    Mössbauer Spectroscopic Studies of Monosubst i - tuted Pentacyano Ferrate(II ) Complexes, N a 3 [ F e ( C N ) 5 R N H 2 ] · n H 2 0 A . N . G A R G and P . N . S H U K L A 59

    Preparat ion and Spectroscopical Character isat ion of Tetrakis(chloro-iodo)oxalato-osmates(IV) (In German) W . P R E E T Z and H . S C H U L Z 62

    Preparat ion and Character izat ion of Monoorgano- bismuth(III ) and B i s m u t h ( I I I ) Der ivat ives o f Mercaptocarbonic Ac ids (In German) U . P R A E C K E L and F . H U B E R 70

    Coll is ional A c t i v a t i o n Mass Spectra of C e H e M * and C7H7M4- Fragment Ions f rom T r a n s i t i o n M e t a l π-Complexes (In German) J . M Ü L L E R and F . L Ü D E M A N N 74

    Crysta l and Molecular Structure o f (Tetramethyl - cyclobutadiene)cis-1,2-dicyano-ethene-l ,2- dithiolato-nickel(II) (In German) R . H E M M E R , H . A . B R U N E , a n d U . T H E W A L T 78

    Some N e w 1-D Compounds w i t h M e t a l - H a l i d e C h a i n D . L A Y E K and G . C. P A P A V A S S I L I O U 83

    N o n Deprotonated M e t a l Complexes of the B i s - amide Tetradentate L i g a n d N , N ' - ( D i p i c o l y l ) - l , 8 - naphthylenediamine T u . F . ZAFLROPOULOS , S. P . P E R L E P E S , P . V . I O A N N O U , J . M . T S A N G A R I S , a n d A . G . G A L I N O S

    87 Metal-π Complexes of Benzene Der ivat ives , X I I I ,

    Bis(methylthio-77-benzene)chromium(0). P r e p a r a ­ t i o n and F u n c t i o n as a B identa te Che la t ina L i g a n d (In German) H . B U R D O R F and C H R . E L S C H E N B R O I C H 94

    The C r y s t a l and Molecular Structure of 2-{8-(2- Aminophenoxy)-3 ,6-dioxaoctyloxy}benzoic A c i d · NaC104, a L inear Po lye ther w i t h T e r m i n a l A m i n o and Carboxy l Funct i ons Κ. K . C H A C K O and W . S A E N G E R 102

    Synthesis of 6 - N - A r y l and H e t e r o a r y l Benzthiazoles as Po tent ia l Anthe lmint i cs S. A B U Z A R and S. S H A R M A 108

    N e w F u r a n o i d Diterpenes f rom Teucrium scor- dium L . G . Y . P A P A N O V and P . Y . M A L A K O V 112

    O n the Diastereoisomerism of N a t u r a l a n d Synthet i c α-Bisabolols (In German) E . F L A S K A M P , G . N O N N E N M A C H E R , a n d Γ. ISAAC 114

  • I V C o n t e n t s

    Studies on Ferrocene Derivatives (VII) . Synthesis of Some New Ferrocenyl Dibromides, Benzofuranes and Indoles A . M . E L - K H A W A G A , K . M . H A S S A N , and A . A . K H A L A F 119

    Notes

    Rhombohedral ly Crysta l l iz ing Zinc Hexacyano- metalates(III) Z n 3 [ M ( C N ) 6 ] 2 (In German) H . S I E B E R T and W . J E N T S C H 123

    A n Unexpected Intramolecular Photoreaction of a Hexachlorooctal^drocumethanonaphthaline (In German) H . P A R L A R and Y . I N ANICI 125

    C o n t e n t s o f N u m b e r 2

    Original Communications

    Synthesis of Sodium-Chelates of Methylen-bis- iminodiphenylphosphorane] (In German) R . A P P E L and K . W A I D 127

    Synthesis of Symmetr i ca l Diaminocarbodiphos- phoranes R 2 N P h 2 P = C = P P h 2 N R 2 (In German) R . A P P E L and K . W A I D 131

    The Crysta l Structure of Methyltr iphenylphos- phonium Hexachlorot i tanate (In German) E . H E Y and U . M Ü L L E R 135

    Preparat ion and Characterization of Te t rabuty l - ammonium Tetraiodooxotechnetate(V), ( T B A ) [ T c O I 4 ] (In German) G . P E T E R S and W . P R E E T Z 138

    Reactions of T h a l l i u m (III) Carboxylates w i t h Ketones (In German) M . V O L L M E R H A U S and F . H U B E R 141

    Cycl ic Diazastannylenes, X . The Crysta l and Mole ­ cular Structure of a Molecule w i t h a Distorted Cube-Shaped SruNaO-Cage (In German) M . V E I T H and 0 . R E C K T E N W A L D 144

    O n the React ion of Aromat i c Phosphane D e r i v a ­ tives w i t h Electrons, I . (In German) W . K A I M 150

    Diazaboro l idy l - a Stable Substituent at Sul fur Nitrogen Compounds (In German) W . H A U B O L D , H . G . F E H L I N G E R , and G . F R E Y 157

    Structures and V ibra t i ona l Spectra of Tetramethy l ­ ammonium α-Dodecatungstosilicate and Te t ra - buty lammonium ^-Dodecatungstosilicate (In German) J . F U C H S , Α. T H I E L E , and R . P A L M 161

    Synthesis and Structure of 1,2,3 -Thiadiazol- and I , 2,3 -Selenadiazol-Pentacarbonyl Complexes of the Elements Chromium and Tungsten ( In German) V . B Ä T Z E L and R . B O E S E 172

    O n Cyanohalogenomercurates of A l k a l i Metals (In German) G. T H I E L E , Κ . B R O D E R S E N , and H . F R O H R I N G 180

    Metallomethanes, I V . Molecular and Crysta l Struc­ ture of Bis(chloromercuri)methane CH2(HgCl)2 (In German) K . - P . J E N S E N , D . K . B R E I T I N G E R , and W . K R E S S

    188 Pt ( I I ) , Pd(I I ) and Cu(II) Complexes w i t h the L i g a n d

    4,4 ,5 ,5-Tetramethyl imidazoUne-l -oxyl -2-m- pyridyl -3 -oxide (In German) K . E . SCHWARZHANS and A . S T U E F E R 195

    Trans i t ion M e t a l Sulfur Y l i d e Complexes, X L Structure and R e a c t i v i t y of ?y 5-Thiacyclohexa- dienyl-1-oxide Complexes of Chromium (In German) L . W E B E R , D . V E H R E S C H I L D - Y Z E R M A N N , C. I£RÜ- G E R , and G . W O L M E R S H Ä U S E R 198

    Trans i t ion M e t a l Complexes of Diazenes, X V I . Structure and Mossbauer D a t a of (2,3-Diaza- norbornene)Fe3(CO)9 (In German) H . K I S C H , C. K R Ü G E R , and A . T R A U T W E I N 205

    Electret Mode l for the Collective Behaviour of Bio logical Systems H . B I L Z , H . B Ü T T N E R , and H . F R Ö H L I C H 208

    The M e t a l Complexes of Heterocycl ic /?-Diketones and their Derivat ives , P a r t V I I I . Synthesis, Structure, P r o t o n N M R and Infrared Spectral Studies of the Complexes of A l ( I I I ) , Fe ( I I I ) , Co(III) , R h ( I I I ) , In(III ) , and Zr ( IV) w i t h l -Phenyl-3-methyl-4-tr i f luoroacetyl -pyrazolone-5 ( H P M T F P ) E . C H . O K A F O R 213

    (Aminoethynyl)metal lat ions, I X . Reactions of Y n - amines w i t h Cyanoketenes (In German) G. H I M B E R T and L . H E N N 218

    Preparat ion of l , 3 -D imethy l -6 -hyd iOxy -d ihydro - thymine by Photochemical A d d i t i o n of Water to I , 3 -Dimethy l - thymine (I