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1 Temperature Effects on the Unsaturated Permeability of the Densely 1 Compacted GMZ01 Bentonite under Confined Conditions 2 3 W. M. Y E a,b,* , M. WAN a , B. CHEN a Y. G. CHEN a Y. J. CUI a,c , J. WANG d 4 a. Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education, Tongji 5 University, Shanghai 200092China 6 b. United Research Center for Urban Environment and Sustainable Development, the Ministry of 7 Education, Shanghai 200092China 8 c. UR Navier, Ecole des Ponts ParisTech, France 9 d. Beijing Research Institute of Uranium Geology, Beijing 100029China 10 11 *To whom correspondence and reprint requests should be addressed; Tel.: +86 21 6598 3729; Fax: 12 +86 21 6598 2384, E-mail: [email protected] 13 14 hal-00693404, version 1 - 2 May 2012 Author manuscript, published in "Engineering Geology 126 (2012) 1-7" DOI : 10.1016/j.enggeo.2011.10.011

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Temperature Effects on the Unsaturated Permeability of the Densely 1

Compacted GMZ01 Bentonite under Confined Conditions 2

3

W. M. Y E a,b,*, M. WAN a, B. CHEN a,Y. G. CHEN a,Y. J. CUI a,c, J. WANGd 4

a. Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education, Tongji 5

University, Shanghai 200092,China 6

b. United Research Center for Urban Environment and Sustainable Development, the Ministry of 7

Education, Shanghai 200092,China 8

c. UR Navier, Ecole des Ponts ParisTech, France 9

d. Beijing Research Institute of Uranium Geology, Beijing 100029,China 10

11

*To whom correspondence and reprint requests should be addressed; Tel.: +86 21 6598 3729; Fax: 12

+86 21 6598 2384, E-mail: [email protected] 13

14

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Author manuscript, published in "Engineering Geology 126 (2012) 1-7" DOI : 10.1016/j.enggeo.2011.10.011

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Abstract 15

In this study, temperature controlled soil-water retention tests and unsaturated hydraulic conductivity 16

tests for densely compacted Gaomiaozi bentonite - GMZ01 (dry density of 1.70 Mg/m3) were 17

performed under confined conditions. Relevant soil-water retention curves (SWRCs) and unsaturated 18

hydraulic conductivities of GMZ01 at temperatures of 40°C and 60°C were obtained. Based on these 19

results as well as the previously obtained results at 20°C, the influence of temperature on 20

water-retention properties and unsaturated hydraulic conductivity of the densely compacted 21

Gaomiaozi bentonite were investigated. It was observed that: (i) water retention capacity decreases as 22

temperature increases, and the influence of temperature depends on suction; (ii) for all the 23

temperatures tested, the unsaturated hydraulic conductivity decreases slightly in the initial stage of 24

hydration; the value of the hydraulic conductivity becomes constant as hydration progresses and 25

finally, the permeability increases rapidly with suction decreases as saturation is approached; (iii) 26

under confined conditions, the hydraulic conductivity increases as temperature increases, at a 27

decreasing rate with temperature rise. It was also observed that the influence of temperature on the 28

hydraulic conductivity is quite suction-dependent. At high suctions (s > 60 MPa), the temperature 29

effect is mainly due to its influence on water viscosity; by contrast, in the range of low suctions (s < 30

60 MPa), the temperature effect is related to both the water viscosity and the macro-pores closing 31

phenomenon that is supposed to be temperature dependent. 32

33

Key words:GMZ bentonite; nuclear waste repository; temperature; water-retention property; 34

unsaturated permeability 35

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1 Introduction 36

In a conceptual multi-barrier disposal radioactive waste repository (Figure 1), significant 37

Temperature- Hydraulic-Mechanical (THM) phenomena take place in the engineered barrier and in 38

the near field due to the combined actions of heating and hydration (Sanchez et al, 2004). The 39

hydraulic property of the compacted bentonite used as engineered barrier material is one of the key 40

properties for the design of such a disposal system. This explains the large number of studies that 41

have been performed in this area: Dixon et al (1987), Nachabe (1995) and Liu and Wen (2003) tested 42

the permeability of saturated compacted bentonites and analyzed the related influencing factors; Villar 43

(2000, 2002) and Komine (2004) reported different empirical relations between dry density and 44

saturated permeability of compacted benonite; Komine (2004) and He and Shi (2007) predicted the 45

saturated permeability of bentonite based on the changes in porosity. For the unsaturated bentonite, 46

after an investigation to the unsaturated permeability of the mixture of the Kunigel V1 bentonite and 47

Hostun sand under confined conditions, Loiseau (2001) found that for suction lower than 23MPa, the 48

unsaturated permeability increases with suction decrease, while for suction higher than 23MPa, the 49

unsaturated permeability decreases as suction decreases. Under both confined conditions and 50

unconfined conditions, Cui et al. (2008) tested the unsaturated permeability of the mixture of 51

Kunigel-V1 bentonite/Hostun sand based on the instantaneous profile method, and found that as 52

suction decreases, the unsaturated permeability decreases to a certain value and then turns to increase. 53

Cho et al. (1999) reported that the influence of temperature on the permeability of bentonite is 54

mainly because the intrinsic permeability, viscosity and density of water are influenced by 55

temperature. Changes in viscosity of water with temperature have been found to be the most 56

important mechanism (Towhata et al, 1993; Cho et al, 2000; and Villar and Lloret, 2004). 57

GMZ bentonite has been selected as the potential buffer/backfill material for the construction of 58

the engineered barrier in the Chinese deep geological disposal program for high level radioactive 59

nuclear waste, thanks to its high montmorillonite content, high cation exchange capacity (CEC), large 60

specific surface and other desirable properties (Liu and Wen, 2003). Studies on the mineralogy and 61

chemical composition, mechanical properties, hydraulic behavior, swelling behavior, thermal 62

conductivity, microstructure and volume change behavior of the GMZ bentonite have been conducted 63

over years (Ye et al., 2010b). The investigation of the hydraulic properties of the GMZ bentonite has 64

been the gravity center of the recent studies. Liu and Wen (2003) tested the saturated permeability and 65

analyzed the related influencing factors of the compacted GMZ bentonite. Using the instantaneous 66

profile method, Ye et al. (2010a) tested the unsaturated permeability of the densely compacted 67

specimen, with a dry density of 1.7Mg/m3, under confined (constant-volume) conditions. Results 68

show that the unsaturated hydraulic conductivity of the compacted bentonite changes from 1.13×10-13 69

m/s to 8.41×10-15 m/s (gravimetric water content from 12% to 28%) and it is not solely function of 70

suction. While under unconfined (free-swelling) conditions, the unsaturated hydraulic conductivity of 71

the Gaomiaozi bentonite is in a larger range of 1.0×10-12 - 1.0×10-15 m/s. Based on the 72

Kozeny–Carmen semi-empirical function, Niu et al (2009) proposed a semi-empirical equation for the 73

calculation of the unsaturated permeability of the GMZ bentonite with the consideration of 74

micro-structural changes. 75

As far as the influence of temperature effect is concerned, Ye et al. (2009b) reported that the 76

water retention capacity of the highly-compacted GMZ bentonite and bentonite-based mixtures 77

decreases as the temperature increases, regardless of the confining conditions. 78

In this paper, the soil-water retention curves (SWRCs) of the densely compacted Gaomiaozi 79

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bentonite (GMZ01) under confined conditions and at various temperatures (20°C, 40°C and 60°C) are 80

presented. Based on the results obtained, the unsaturated permeability of the GMZ01 is investigated 81

by performing infiltration tests under controlled temperature. 82

2. Materials 83

The Gaomiaozi deposit is located in the northern Chinese Inner Mongolia autonomous region, 84

300 km northwest from Beijing (Ye et al., 2009a, 2010b). Some basic properties of the GMZ01 85

bentonite tested in this paper are listed in Table 1, which indicates that the GMZ01 bentonite has high 86

cation exchange capacity and high adsorption ability. 87

3 Experimental Methods 88

The instantaneous profile method has been adopted in this study. This method was successfully 89

used by many researchers to determine the unsaturated hydraulic conductivity of geomaterials (Daniel, 90

1982;Richards and Weeks, 1953; Hamilton et al., 1981; Watson, K.K., 1966; Meerdink et al., 1996; 91

Fujimaki and Inoue, 2003; Cui et al., 2008; Ye et al., 2010a). As an unsteady-state method, it can be 92

used either in the laboratory or in situ (Benson and Gribb 1997). 93

In order to apply this method to determine the unsaturated permeability of the GMZ01 bentonite 94

at different temperatures, on the one hand, the SWRCs of this soil should be determined at relevant 95

temperatures, and on the other hand, the corresponding suction profiles should be determined by 96

performing infiltration test at different temperatures with suction monitoring. For a given temperature, 97

the hydraulic gradient was determined using the suction profile; the water flux was determined using 98

the water content profile; the hydraulic conductivity was then calculated based on the generalized 99

Darcy’s law. The detailed calculation procedure can be found in Ye et al. (2009a). 100

101

3.1 Determination of SWRCs 102

3.1.1 Suction control 103

The vapour equilibrium technique (for high suctions) and osmotic technique (for low suctions) 104

were employed for suction control in this study. At high suctions, the experimental setup used was 105

described by Ye et al (2005), as shown in Fig.2. Note that the vapor equilibrium technique was 106

employed by number of researchers for controlling total suction in unsaturated soil tests (Bernier et al, 107

1997; Blatz and Graham, 2000; Lloret et al, 2003; Chen et al, 2006). 108

In this study, the confined GMZ01 specimen was placed in a desiccator and the water vapour 109

above a saturated salt solution was circulated to provide the desired suction to the specimen. Saturated 110

salt solutions and their corresponding suctions imposed at 20, 40 and 60°C are shown in Table 3 111

(Tang and Cui, 2005). 112

For low suctions, the osmotic technique was used and the corresponding setup is shown in Fig 3 113

(Delage et al., 1992; 1998). Note that Tang et al. (2010) studied the temperature effect on the 114

calibration curve of PEG solutions and found that this effect is insignificant. Thus, in this study, the 115

osmotic technique was employed without temperature correction. 116

117

3.1.2 Apparatus 118

Custom-designed stainless steel cells with small holes in two ends (Fig.2, Ye, 2009a) were 119

employed for water retention test under confined conditions. The holes were designed as channels for 120

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moisture exchange between the specimen in the cell and the circulating air (or PEG solution) around it. 121

For the temperature control, the setups were placed in ovens (Fig 3 and Fig 4), which have 122

temperature controlled to an accuracy of ±0.1°C. Note that temperatures of 20, 40 and 60°C were 123

selected as the testing temperatures in this study. 124

3.1.3 Specimen preparation 125

The GMZ01 bentonite powder was compacted into a thin cylindrical specimen, which has a final 126

dimension of 20 mm in diameter and 6 mm in height. For the compaction, a press was used and the 127

compaction was carried out at a velocity of 0.1 mm/min. The final dry density and water content of 128

the compacted specimen were 1.70g/cm3 and 10.65%, respectively. 129

3.2 Infiltration test 130

The schematic layout of the temperature controlled infiltration test is shown in Fig.5. A 131

custom-designed cylinder (Ye et al., 2009a, 2010a) is put in an oven with temperature controlled to an 132

accuracy of ±0.1°C. The resistive relative humidity (RH) sensors (Cui et al, 2008) were used to 133

monitor the RH changes. Note that the same type of sensor was used by Ye et al. (2009a, 2010a). It 134

can be seen from Fig.5 that the sensors were installed every 30 mm along the length of the cell (4 135

sensors) with a fifth sensor in the upper base plate of the cell. As the sensors measure the air relative 136

humidity, no direct contact with soil specimen was allowed. For this reason, a small cavity was bored 137

in the soil for each transducer. This cavity had a dimension allowing introducing the transducer cap: a 138

porous stone of 2 mm thick and 5 mm in diameter. This porous stone separated the transducer from 139

the soil sample and allowed the air humidity transfer from the specimen to the transducer (Ye et al., 140

2009a). 141

The distilled water was used in the infiltration test. The water absorbed by the specimen can be 142

quantified by calculating the water volume change in the left marked glass pipe, which can be 143

compensated by water from the right tube, in the U-shaped system outside the oven. Two drops of 144

silicone oil were added into the left pipe to prevent water evaporation. A soft tube was used for 145

connecting the U-shaped system to the inlet of the specimen in order to warm up the water to current 146

testing temperature before absorption. The humidity and temperature changes were recorded by the 147

data logging system. 148

A double-piston mould was used for the compaction of the specimen (Cui and Delage, 1996). 149

The powder of the GMZ01 bentonite was compacted in 5 layers. After the first layer (30 mm) was 150

compacted and the surface of specimen was carefully scarified for the integrity of the specimen, the 151

equal parts of the GMZ01 powder were added from two ends of the mould and then compacted to two 152

15 mm sub-layers. This procedure was repeated for the other 3 layers. The compaction was conducted 153

at a speed of 0.1 mm/min. The specimen has a final height of 150 mm, a dry density of 1.70 Mg/m3, a 154

suction about 90 MPa for 40°C temperature and 100MPa for 60°C temperature, and a degree of 155

saturation around 0.49 for 40°C temperature and 0.41 for 60°C temperature. 156

The unsaturated permeability test on the GMZ01 bentonite at 20°C was previously measured and 157

reported by Ye et al. (2010) and thus only the infiltration tests at temperatures of 40°C and 60°C were 158

performed in this study. 159

160

4. Results and discussion 161

4.1 SWRCs 162

The SWRCs of the highly-compacted GMZ01 specimen following wetting path at different 163

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temperatures (20°C, 40°C and 60°C) under confined conditions are shown in Fig.5. Based on these 164

results, an equation can be proposed to describe the water retention curves of the densely compacted 165

GMZ01 bentonite (1.7 Mg/m3): 166

{ }cb

sat

a

ww

])(72.2ln[ ψη

+= (1) 167

with 168

r

r

ψ

ψψ

η1000

1

)1ln(

1+

+−= , (2) 169

Where ψ (MPa) is the suction; rψ (MPa) is a reference suction (309 MPa in this study); wsat is the 170

water content in the saturated state: ( )4.2732000018.025.0 −−+= Twsat ; T (K) is the absolute 171

temperature; a (MPa), b and c are soil parameters: 395.20)273(1474.4 +−−= TLna ; b = 0.8086 ; 172

c = 0.5864. 173

Fig.6 indicates that, the water retention capacity decreases as temperature increases and the 174

degree of the temperature influence depends on suction. This phenomenon can be analyzed separately 175

at low and high suctions. At high suctions (> 4 MPa), changes of clay fabric and fluid in 176

intra-aggregate spaces play a significant role in water retention capacity of GMZ bentonite. 177

Intra-aggregate water moves into macro-pores (inter-aggregates pores) with temperature increase (Ye 178

et al, 2009a). This process decreases the suction in the macro-pore level. As the suction is controlled, 179

water flows out from the macro-pores, leading to a decrease of water retention capacity. At low 180

suctions, capillary effect plays a decisive role in the water retention capacity. Increase of temperature 181

causes changes in surface tension, which results in decrease of water content under constant suction 182

conditions. 183

In order to quantitatively assess the influence of temperature on the water retention capacity of 184

the bentonite under different suctions, a ratio kT is defined as follows: 185

%1001

21 ×−=T

TTT w

wwk (3) 186

where wT1 and wT2 are water content at temperature T1 and T2 respectively for the same suction. 187

The relationship between the ratio kT and suction for the GMZ01 bentonite at 40°C and 60°C are 188

given in Fig.7. It can be observed that the effect of temperature on the water retention capacity is 189

closely related to suction, particularly in the range from 30 to 60 MPa. This effect reaches a maximum 190

at a suction around 40 MPa. 191

4.2 Unsaturated permeability 192

4.2.1 Test at 40°C 193

The relative humidity changes with hydration time in the infiltration test at 40°C are shown in 194

Fig.8. Based on the SWRCs measured at 40°C (see Fig.6), the development of suction with hydration 195

time can be obtained. Note that the conversion from relative humidity to suction was done using the 196

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Kelvin’s law. Fig 8 indicates that, for the relative humidity sensor located 3 cm from the hydration 197

water inlet at the bottom of the specimen, suction decreases rapidly in the first 200 h of hydration and 198

then decreases much more slowly. For suction measured at 6 cm, it begins to decrease rapidly after 199

100 h hydration and gradually decreases after 800 h hydration. As it is relatively far from the water 200

inlet, suctions measured at 12 cm and 15 cm from the bottom of the specimen start to decrease rapidly 201

after 200 and 300 h of hydration, respectively. The slope of the curve of suction versus time decreases 202

as the distance from the inlet increases. The test was stopped after about 1670 h hydration, when the 203

sensor at 3 cm distance from the inlet indicated that zero suction (100% relative humidity) was 204

achieved at this height. 205

The relationship between the unsaturated hydraulic conductivity and suction is shown in Fig.9. It 206

can be observed that at 40°C temperature, the unsaturated hydraulic conductivity of the GMZ01 with 207

a dry density of 1.7 Mg/m3 is on the whole between 1.64×10-13m/s and 1.34×10-14m/s. During the 208

initial stages of hydration, the hydraulic conductivity gradually decreases with suction decrease, and 209

the hydraulic conductivity reaches the minimum value of 1.34×10-14m/s when the suction drops to 210

45 MPa; the hydraulic hydraulic conductivity keeps steady in the range of suction from 20 MPa to 211

60MPa; but when suction drops to a level lower than 20 MPa, the unsaturated hydraulic conductivity 212

increases rapidly and reaches 1×10-13m/s. 213

4.2.2 Test at 60°C 214

The unsaturated hydraulic conductivity of the confined GMZ01 determined at 60°C is shown in 215

Fig.10. It can be seen that the values are generally between 1.79×10-14m/s and 1.19×10-13m/s. As the 216

infiltration of water progresses, suction drops from 80 MPa to 55 MPa, while the unsaturated 217

hydraulic conductivity decreases slightly. With suction reduction from 55 MPa to 20 MPa, the 218

hydraulic conductivity remains almost constant despite of the suction changes. For suction lower than 219

20 MPa, the hydraulic conductivity rapidly increases with decreasing suction and reaches a final value 220

of 1×10-13m/s. 221

When the soil suction is decreased from the initial value (about 80 MPa) to zero, the hydraulic 222

conductivity first decreases from 2×10–14m/s to 7×10–15m/s and then increases to 1×10–13m/s, which is 223

close to the saturated hydraulic conductivity. As in the first stage, water transfer is primarily governed 224

by the network of large pores and these large pores are progressively decreasing in quantity and in 225

size, resulting in hydraulic conductivity decreases. After completion of this large-pore clogging by gel 226

creation, a normal conductivity increase with suction decrease is observed (Ye et al., 2009a). 227

4.3 Influence of temperature on the unsaturated hydraulic conductivity 228

To further assess the influence of temperature on the unsaturated permeability of the highly 229

compacted GMZ01 bentonite, the unsaturated hydraulic conductivity of the confined specimen at 230

20°C (Ye et al, 2009a) are compared to those measured at 40°C and 60°C (Fig.11). It can be seen that 231

under confined conditions, the unsaturated hydraulic conductivity of the highly compacted GMZ01 232

bentonite increases with temperature rise. Moreover, the rate of change also decreases as temperature 233

increases. The temperature effect becomes more significant at higher suctions (above 20 MPa). In the 234

range of lower suctions (less than 20 MPa), it is observed that the lower the suction the less the 235

temperature effect. The possible explanation is that for lower suctions the moisture absorbed by the 236

bentonite is mainly associated with microstructure changes and the temperature effect on the 237

microstructure is not significant. 238

The influence of temperature on the hydraulic conductivity is mainly related to the influence of 239

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temperature on the water viscosity and the pore structure of the bentonite. To remove the influence of 240

temperature on water viscosity, the relative hydraulic conductivity is introduced to allow for a better 241

analysis of the influence of temperature on hydraulic conductivity. Relationships between the relative 242

permeability and degree of saturation (Sr) of the confined GMZ01 at 40°C and 60°C are given in 243

Fig.12. It can be observed that when Sr is higher than 0.57, the hydraulic conductivity at 60°C is 244

similar to that observed at 40°C. This means that in this range of degree of saturation the influence of 245

temperature on permeability is mainly due to the influence on water viscosity. On the contrary, when 246

Sr is lower than 0.57, the relative permeability at 40°C is found higher than that at 60°C. Interestingly, 247

this threshold corresponds to a suction of 60 MPa, and from Figs 9, 10 and 11 it can be observed that 248

when s > 60 MPa the hydraulic conductivity decreases with suction decrease. As mentioned above, in 249

this suction range hydration leads to progressive macro-pores closing thus to a decrease in hydraulic 250

conductivity. This macro-pore closing process can be assumed to be more significant at higher 251

temperature because of softer clay aggregates and lower water viscosity, explaining a lower hydraulic 252

conductivity at 60°C than at 40°C. As the relative hydraulic conductivity has been found independent 253

of temperature when Sr > 0.57 (Fig. 12), it can be supposed that the macro-closing process ended 254

when Sr > 0.57; in other words, the influence of temperature on pore structure became insignificant in 255

this range. 256

It is also important to note that the obtained results could be affected by the possible density 257

gradient along the specimen as identified by Dixon et al. (2002) and Villar et al. (2008). This density 258

gradient can be formed owing to the expansion of the hydrated bentonite that intrudes into the drier 259

area under the effect of swelling pressure. If it occurs, the computation of degree of saturation without 260

considering this gradient is not correct and the water retention curve considered is also inappropriate. 261

In other words, the simultaneous profile method meets its limitation. Because in this study, no specific 262

analyses were conducted after the infiltration tests, this phenomenon can not be verified. Further 263

studies will be performed to investigate this aspect. 264

265

5 Conclusions 266

The SWRCs of the highly compacted GMZ01 confined specimens on wetting path and at 267

different temperatures (20°C, 40°C and 60°C) show that the water retention capacity decreases as 268

temperature increases; and the influence of temperature depends on suction. The ratio kT can be used 269

to quantitatively describe the influence of temperature on water retention capacity of bentonite at 270

different suctions. 271

Under confined conditions and at 40°C temperature, the unsaturated hydraulic conductivity of 272

the GMZ01 bentonite at a dry density of 1.7Mg/m3 is between 1.64×10-13m/s and 1.34×10-14m/s. At 273

60°C temperature, the value is slightly lower, between 1.19×10-13m/s and 1.79×10-14m/s. 274

For all the temperatures considered, the unsaturated hydraulic conductivity decreases slightly in 275

the first stage of hydration. The value of the hydraulic conductivity becomes constant as hydration 276

progresses. Finally, the hydraulic conductivity increases rapidly with suction decreases when 277

saturation is approached. This phenomenon may be explained by the changes in the soil 278

microstructure. 279

Under confined conditions, the hydraulic conductivity increases as temperature increases, at a 280

rate that decreases with temperature rise. Also, the influence of temperature on the hydraulic 281

conductivity is quite suction-dependant. At high suctions (s > 60 MPa) or low degrees of saturation 282

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(Sr < 0.57), the temperature effect is mainly due to its influence on water viscosity; on the contrary, in 283

the range of low suctions (s < 60 MPa) or high degrees of saturation (Sr > 0.57), the temperature 284

effect is related to both the water viscosity and the macro-pores closing phenomenon that is supposed 285

to be temperature dependent. Note that further studies are needed to investigate the possible dry 286

density gradient effect on the hydraulic conductivity determined based on the simultaneous profile 287

method. 288

289

ACKNOWLEDGEMENTS 290

The authors are grateful to the National Natural Science Foundation of China (Projects No. 291

41030748, No.40772180 and No.40728003), Kwang-Hua Fund for College of Civil Engineering at 292

Tongji University, China Atomic Energy Authority (Project [2007]831), and Shanghai municipality 293

(Leading Academic Discipline Project - B308). 294

295

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390

Table 1 Basic Properties of GMZ01 bentonite 391

Property Description

Specific gravity of soil 2.66 pH 8.68−9.86

Liquid limit (%) 276 Plastic limit (%) 37

Total specific surface area/

(m2·g−1)

570

Cation exchange capacity/

(mmol·g−1) 0.773 0

Main exchanged cation/

(mmol·g−1)

Na+(0.433 6), Ca2+(0.291 4), Mg2+(0.123 3),

K+(0.025 1)

Main minerals

Montmorillonite(75.4%), quartz (11.7%), feldspar (4.3%),

cristobalite (7.3%) 392

393

Table 2 Salt solution and corresponding suction at different temperatures (MPa)(Tang 2005) 394

Salt solution 20°C 40°C 60°C

LiCl 2 309.0 − 340

MgCl2 150.0 162.4 187.7

K2CO3 113.0 122.0 144.8

Mg(NO3)2 82.0 103.1 139

NaNO2 57.0 −

NaNO3 39.0 49.5 61.6

NaCl 38.0 40.6 44.2

(NH4)2SO4 24.9 32.2

KCl 21.0 27.8 33.4

ZnSO4 12.6 −

KNO3 9.0 −

K2SO4 4.2 5.1 5.5

395

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Compacted bentonite

HLW

Host rock

Canister

396 Fig. 1. Schematic view of a high level nuclear waste repository (Sanchez, 2004) 397

398

399

400

Fig. 2. Constant-volume hydration cell 401

402

403 Fig. 3. Setup for the water retention curve determination using the vapor equilibrium technique 404

405

PolyethyleneMembrane

Semi-permeableMembrane

Specimen

PEG20000 Solution

Magnetic Stirrer

Oven(temperature Control ¡ À0.1℃)

Porous Stone

Rubber RingSteel Bracket

406

Fig. 4. Setup for the water retention curve determination using the osmotic technique 407

408

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Data Logger

Humidity Sensor

Oven(Temperature Control± 0.1℃)

Compacted Bentonite

Porous Stone Valve

Water Level

409

Fig. 5. Schematic layout of the temperature controlled infiltration test 410

0

4

8

12

16

20

24

28

0.01 0.1 1 10 100 1000Suction /MPa

w /% Measured (60℃℃℃℃)

Measured (40℃℃℃℃)

Measured (20℃℃℃℃)

Caculated (20℃℃℃℃)

Caculated (40℃℃℃℃)

Caculated (60℃℃℃℃)

411 Fig. 6. Water retention curves of the confined specimen at different temperatures 412

413

0000

5555

10101010

15151515

1111 10101010 100100100100 1000100010001000Suction /MPa

k T

/%

40-60℃℃℃℃20-60℃℃℃℃20-40℃℃℃℃

414

Fig. 7. Change of KT with suction 415

416

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15

40

50

60

70

80

90

100

0 200 400 600 800 1000 1200 1400 1600 1800

Time(h)

Hu

mid

ity(%

)

15cm

12cm

9cm

6cm

3cm

417 Fig. 8. Evolution of the relative humidity of confined GMZ01 with time at 40°C 418

1.E-15

1.E-14

1.E-13

1.E-12

0 10 20 30 40 50 60 70 80Suction(MPa)

K(m

/s)

3cm

6cm

9cm

Fitted Curve

419 Fig. 9. Change of unsaturated hydraulic conductivity with suction for the confined GMZ01 at 40°C 420

1.E-15

1.E-14

1.E-13

1.E-12

0 10 20 30 40 50 60 70 80

Suction(MPa)

K(m

/s)

3cm

6cm

9cm

Fitted Curve

421

Fig. 10. Change of unsaturated hydraulic conductivity with suction for the confined GMZ01 at 60°C 422

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1.0E-15

1.0E-14

1.0E-13

1.0E-12

0 10 20 30 40 50 60 70 80Suction(MPa)

K(m

/s)

20℃40℃60℃

423 Fig. 11. Evolution of unsaturated hydraulic conductivity with suction for the confined GMZ01 at 424

different temperatures 425

426

0.0

0.1

1.0

0.4 0.5 0.6 0.7 0.8 0.9 1Sr

Kr

(m/s

)

3cm 40℃℃℃℃3cm 60℃℃℃℃

427

Fig. 12. Relationship between Kr and Sr of the confined GMZ01 at 40°C and 60°C 428

429

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