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UNIVERSITY OF NAIROBI A STUDY OF PIPED WATER QUALITY COMPLIANCE AROUND THE UNIVERSITY OF NAIROBI. By WANJIRU WILFRED GATIMU F16/40376/2011 A project submitted as a partial fulfilment for the requirement for the award of the degree of BACHELOR OF SCIENCE IN CIVIL ENGINEERING Year of submission (2016)

UNIVERSITY OF NAIROBI PROJECT

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  • UNIVERSITY OF NAIROBI

    A STUDY OF PIPED WATER QUALITY COMPLIANCE

    AROUND THE UNIVERSITY OF NAIROBI.

    By

    WANJIRU WILFRED GATIMU

    F16/40376/2011

    A project submitted as a partial fulfilment for the requirement for the

    award of the degree of

    BACHELOR OF SCIENCE IN CIVIL ENGINEERING

    Year of submission

    (2016)

  • i

    Abstract

    The objective of the surveillance was to collect and collate information that helps in promoting

    improvement of water supply vis--vis quality. The water quality was in compliance with the

    Kenya standards which are based on health criteria given by WHO water quality guidelines. The

    study was accomplished by establishing sampling points around the University of Nairobi that are

    strategically defined by the NCWSC.

    Water quality was assessed by conducting experiments and analysing the data. The water samples

    were tested for typical parameters namely; chemical substances, physical properties and

    bacteriological quality. Laboratory testing was carried out at the UON Public Health Laboratory

    and the Kabete Water Treatment laboratory. Thereafter, the parameters were compared with water

    quality guidelines given by WHO, KEBS and WASREB. All the parameters were within the

    recommended except the free residual chlorine in Central Park which was 0.1mg/l, a value below

    the recommended minimum of 0.2mg/l.

    The water supplied quality parameters were found to be in compliance, therefore clean and safe

    for consumers. This report is based on data collected for the month of February 2016.Evidently,

    water quality management is a complex activity and requires the accomplishment of compliance

    to water quality standards (Chapman 1996). Therefore, clear and appropriate measures for water

    quality management should be put in place.

  • ii

    Dedication

    I would like to dedicate this report to my dearest sister, to my best friend and my guardians for

    their unwavering support and motivation throughout my study.

  • iii

    Acknowledgement

    First and foremost, I would like to thank the Almighty God for this far He has brought me and the

    gift of able parents who are always there to guide and show moral support through my education.

    Special gratitude and appreciation to all those gave me the possibility to successfully complete this

    project. I thank my final year project supervisor, Eng. D.M. Wanjau, whose help, stimulating

    suggestions, encouragement and the help to coordinate my project especially in writing this report.

    For all the staff, both from UON and NCWCS, I acknowledge with much appreciation their crucial

    role especially in the laboratories and the permission to use the required equipment and necessary

    chemicals to complete the report.

  • iv

    Table of Contents

    Abstract ............................................................................................................................................ i

    Dedication ....................................................................................................................................... ii

    Acknowledgement ......................................................................................................................... iii

    Illustrations .................................................................................................................................... vi

    Abbreviations ............................................................................................................................... viii

    Chapter One .................................................................................................................................... 1

    Introduction ..................................................................................................................................... 1

    1.1 General ............................................................................................................................. 1

    1.2 Problem statement ............................................................................................................ 2

    1.3 Objectives ......................................................................................................................... 2

    Chapter Two.................................................................................................................................... 3

    Literature Review............................................................................................................................ 3

    2.1 Overview of existing water supply in Nairobi ................................................................... 3

    2.2 Introduction ....................................................................................................................... 6

    2.3 Aesthetic Parameters of Water ......................................................................................... 9

    2.4 Microbiology and Bacteriological Aspects..................................................................... 12

    2.5 Chemical Parameters ...................................................................................................... 13

    2.6 Surveillance and Monitoring .......................................................................................... 18

    2.7 Sampling ......................................................................................................................... 21

    2.8 Health implications ......................................................................................................... 23

    2.9 Treatment and disinfection ............................................................................................. 30

    2.9.1 Water treatment process ............................................................................................. 30

    2.9.2 Chlorination ................................................................................................................ 32

    Chapter Three................................................................................................................................ 33

    Methodology ................................................................................................................................. 33

    3.1 Introduction ........................................................................................................................ 33

    3.2 Study area........................................................................................................................... 33

    3.3 Limitations of the study ..................................................................................................... 35

    3.4 Sampling ............................................................................................................................ 35

    3.5 Laboratory tests .................................................................................................................. 36

    3.6 Questionnaire ..................................................................................................................... 37

  • v

    Chapter Four ................................................................................................................................. 38

    Results and Analysis ..................................................................................................................... 38

    Chapter Five .................................................................................................................................. 49

    Discussions ................................................................................................................................... 49

    5.1 Physiochemical aspects ...................................................................................................... 49

    5.2 Acceptability aspects ......................................................................................................... 50

    5.3 Bacteriological quality ....................................................................................................... 51

    5.4 Other parameters considered.............................................................................................. 51

    Chapter Six.................................................................................................................................... 52

    Conclusions ................................................................................................................................... 52

    Chapter Seven ............................................................................................................................... 54

    Recommendations ......................................................................................................................... 54

    References ..................................................................................................................................... 55

    Appendices .................................................................................................................................... 57

    Appendix I: Schedules .................................................................................................................. 57

    Appendix II: Tables ...................................................................................................................... 60

    Appendix III: Pictorials................................................................................................................. 61

  • vi

    Illustrations

    List of Charts

    Chart 1:Turbidity analysis of results. ............................................................................................ 40

    Chart 2: pH analysis of results. ..................................................................................................... 41

    Chart 3: Colour result analysis. ..................................................................................................... 42

    Chart 4: Residual chlorine results analysis. .................................................................................. 43

    Chart 5: Conductivity result analysis. ........................................................................................... 44

    Chart 6: Analysis of fluorides results............................................................................................ 45

    Chart 7: Analysis of hardness results. ........................................................................................... 46

    Chart 8: Analysis of results for total alkalinity. ............................................................................ 47

    Chart 9: Analysis of results for TDS............................................................................................. 48

    List of Figures

    Figure 1:Schematic layout of water sources, treatment and transmission system (BRL and

    Suereca, 2010)................................................................................................................................. 4

    Figure 2:General layout of Distribution Network (Saureca, 2007) ................................................ 5

    Figure 3:Sampling points around the University environs. .......................................................... 34

    Figure 4:Sampling points in Nairobi County ................................................................................ 34

    List of Tables

    Table 1: Hardness ......................................................................................................................... 15

    Table 2: Minimum sample numbers for piped drinking-water in the distribution system. .......... 22

    Table 3: WHO drinking water guidelines ..................................................................................... 25

    Table 4: Microbiological limits for drinking water and containerized water. .............................. 26

    Table 5: Aesthetic Quality for Requirements of Drinking water and Containerized water (KS 150

    and WHO Guidelines)................................................................................................................... 27

    Table 6: Aesthetic quality requirements for drinking water and bottled drinking water (adopted

    from KS 05-459: Part 1:1996). ..................................................................................................... 28

    Table 7: Microbiological limits for drinking water and containerized drinking water (Adopted

    from KS 05-459: Part 1:1996). ..................................................................................................... 29

    Table 8: Ranking of technical complexity and cost of water treatment processes. ...................... 31

    Table 9: Recommended treatment in relation to number of coliform organism per 100ml. ........ 31

  • vii

    List of Pictorials

    Photograph 1: Mixing of the sample with DPD tablet (Serena Hotel) ......................................... 61

    Photograph 2:Reading the concentration of Residual Chlorine .................................................... 61

    Photograph 3:Testing of pH .......................................................................................................... 62

    Photograph 4: Testing conductivity of the samples ...................................................................... 62

    Photograph 5:Alkalinity test through titration .............................................................................. 63

    Photograph 6:Turbidimeter at Kabete Treatment Works.............................................................. 63

    Schedule 1: WSP Sample Schedules for Water Quality Monitoring ............................................ 20

  • viii

    Abbreviations

    Acronym Meaning

    CaCO3 Calcium Carbonate

    F.T.U. Formazin Turbidity Units

    KEBS Kenya Bureau of Standards

    Mg/l Milligrams per litre

    M.P.N. Most Probable Number

    NCWSC Nairobi City Water and Sewerage Company

    NaCl Sodium Chloride

    N.T.U. Nephelometric Turbidity Units

    pH Concentration of hydrogen ion

    P.H.E. Public Health Education

    Ppm parts per million

    T.C.U. True Colour Units

    TDS Total Dissolved Solids

    U.O.N. University of Nairobi

    S Micro Siemens

    W.H.O. World Health Organization

    WASREB Water Services Regulatory Board

    WSB Water Service Board

    WSP Water Service Provider

  • 1

    Chapter One

    Introduction

    1.1 General

    Over the years, especially in developing countries, consumers have encountered substandard water

    supply. This has been a significant danger to the health and well-being of the consumer. The water

    supply agencies have a responsibility to serve the community with quality water as specified in

    the World Health Organization (WHO) standards. Here in Kenya, WASREB has stipulated local

    standards mostly from the WHO water quality guidelines.

    However, due to the vulnerability of water to contamination there is need for continuous and

    frequent assessment of its quality before supply to the community. Hence, the surveillance of the

    water quality standards can be done either on site at various supply points or the parameters tested

    in a laboratory. The latter is then checked if it complies with the requirements stipulated in the

    standards.

    Water suppliers need to carry out a wider range of analyses relevant to the operation and

    maintenance of water-treatment and distribution systems, in addition to the health-related

    parameters laid down in national water-quality standards.

    Evidently, all people whatever the stage of development, social and economic backgrounds have

    the right to access adequate supply of safe drinking water. Cost effective improvement of drinking

    water quality at tap involves source water quality improvement, better water management and

    advances in water treatment technology.

  • 2

    1.2 Problem statement

    The Nairobi water utility NCWSC has the stringent water quality monitoring programs to ensure

    the water they supply the city is safe for drinking and domestic purposes. However, due to high

    leakage and pipe bursts in the network and intermittent supply, water is sometimes contaminated

    before it reaches the tap. These kind of leakages sometimes occur along areas with sewage

    overflows. Therefore, for those who cannot afford bottled water or boil the water, they have to

    take chances with tap water.

    Most people residing within and around the University of Nairobi rely on piped water for

    consumption. Although its the most reliable means; if not monitored the health of the consumers

    is at risk. This poses danger, of the water supplied to communities not being well monitored, to

    curb the hazards caused by substandard water. Often, the source of water dictates the treatment

    requirements before supply. However, even after treatment there is need to monitor the quality of

    the water at various supply points. This continuous assessments ensure that the consumer gets safe

    water.

    Water obtained from boreholes as underground water should be monitored to ensure it meets the

    standards cut. More often than not, borehole water is not treated.

    As part of the quality assurance program and process control, WSPs are required to undertake their

    own monitoring of water quality. Drinking-water suppliers are responsible at all times for the

    quality and safety of the water that they produce (WHO, 2011).

    1.3 Objectives

    1. To determine if the quality of the water supplied to the university environs meets the minimum

    requirement of WHO, KEBS, and WASREB guidelines.

    2. It seeks to ensure a minimum required number of samples and tests on water supply and

    collected data is compliant to the standards.

    3. To evaluate the safety of the water consumed by the public residing around the water supply

    region.

    4. To bring out the challenges faced in water quality monitoring.

  • 3

    Chapter Two

    Literature Review

    2.1 Overview of existing water supply in Nairobi

    The water supply of Nairobi city is made up of the sources, treatment and storage, and distribution

    systems. Among the sources Sasumua, Ruiru and Thika (Ndakaini) dams and Kikuyu springs. The

    existence of private boreholes and other local water sources such as streams or rivers and spring

    well also contribute considerably to supply.

    Sasumua dam is located about 90km north of Nairobi city. It was constructed on the Sasumua

    stream, a tributary of the Chania River on the south end of Aberdare Ranges. It has a water

    treatment plant with a daily capacity of 63,700m3 (BRL and Seureca, 2010).

    Thika dam also located about 80km north of Nairobi city. Its water is transported to Ngethu

    Treatment Works through a series of tunnels and pipelines. Ngethu treatment plant has a daily

    capacity of 457,900m3 (BRL and Seureca, 2010).

    Ruiru dam is located about 40km north of Nairobi city. Its raw water is transported to Kabete

    Water Treatment Works through pipelines. The design capacity of the transmission lines is

    30,000m3 every day (BRL and Seureca, 2010).

    Kikuyu springs is a small source compared to the rest. It is located about 19km west of Nairobi

    city. Supply from kikuyu spring is estimated about 4,800m3 every day (BRL and Seureca, 2010).

  • 4

    Figure 1:Schematic layout of water sources, treatment and transmission system (BRL and

    Suereca, 2010)

  • 5

    Water distribution system.

    The water distribution network is about 480km2. The city is conveniently divided into 11

    distribution pressure zones (BRL and Seureca, 2010). The distribution system integrates both

    storage tanks and booster station strategically sited in terms of demand and the hydraulic operation

    requirements.

    Figure 2:General layout of Distribution Network (Saureca, 2007)

  • 6

    2.2 Introduction

    To sustain life, water is essential and should be adequate, safe and accessible. For human health,

    the quality of drinking water provides significant benefits to avoid diseases related contamination.

    As stated by WHO (2008), safe drinking water does not represent any significant risk to health

    over a lifetime of consumption, including different sensitivities that may occur between life stages.

    A guideline value represents the concentration of a constituent that does not result in any

    significant risk to the health of the consumer over a lifetime of consumption. Whenever a guideline

    value is exceeded, this should be a signal to investigate the cause with a view to taking remedial

    action or to consult with the authority responsible for public health. Although the guideline values

    describe a quality of water that is acceptable for life long consumption, the establishment of these

    guideline value should not be regarded as implying that the quality of drinking water maybe

    degraded to the recommended level. Indeed, a continuous effort should be made to maintain

    drinking water quality at the highest possible level (WHO, 1997).

    In case of short-term deviations to the guideline value, it is does not necessarily mean that the

    water is unsuitable for consumption. The amount by which, and the period for which, any guideline

    value may be exceeded without affecting public health depends upon the specific substance

    involved. It is recommended that in such a case, the surveillance agency should be consulted for

    suitable action, taking into account the intake of the substances from sources other than drinking

    water, the toxicity of the substance, the likelihood and nature of any adverse effects and the

    practicability of the remedial measures.

    Guidelines that were considered for the report are:

    i. WHO guidelines which are international standards for drinking water (Table 3).

    ii. KEBS guidelines which are Kenyan national standards for drinking and containerized

    water borrowed from WHO (Table 4&5 ).

    iii. WASREB guidelines that are borrowed from the Kenya Standards by the Water Service

    Requlatory Board to ensure Water Service Providers meet the cut (Table 6&7).

  • 7

    2.2.1 Quality standards

    Standards provide a common reference point for the assessment of the quality of goods and

    services (KEBS). They ensure that products and services are safe, reliable and of preferred quality.

    2.2.2 Water quality

    Water quality is one of the main indicators of the quality of service provided to the consumer,

    therefore has an impact on both the public health and aesthetic value of the water. It can be thought

    of as a measure of the sustainability of water for a particular use based on selected physical,

    chemical and biological characteristics. A drinking-water quality guideline value represents the

    concentration of a constituent that does not result in any significant health risk to the consumer

    over a lifetime of consumption. Drinking-water should be suitable for human consumption and for

    all usual domestic purposes. Regulatory government agencies must always maintain surveillance

    on water supplied to the public. When a guideline value is exceeded, the cause should be

    investigated and corrective action taken.

    Although guidelines for drinking-water quality are based on the best available public health advice,

    there is no guarantee that consumers will be satisfied or dissatisfied by water supplies that meet or

    fail to meet those guidelines (WHO, 1997). It is therefore wise to be aware of consumer perceptions

    and to take into account both health-related guidelines and aesthetic criteria when assessing

    drinking-water supplies. In drawing up national standards for drinking-water quality, it will be

    necessary to take into account various local, geographical, socioeconomic and cultural factors. As

    a result, national standards may differ appreciably from the guideline values.

    Water quality Assessment: is the overall process of evaluation of the physical, chemical and

    biological nature of water in relation to natural quality, human effects and intended uses,

    particularly uses which may affect human health and the health of the aquatic system itself

    (Chapman, 1996).

  • 8

    Water quality Monitoring: is the actual collection of information at set locations and at regular

    intervals in order to provide the data which may be used to define current conditions, establish

    trends, etc. It is long-term, standardized measurement and observation of the aquatic environment

    in order to be used for interpretation and assessment (WHO, 1997).

    I. Surface water quality (WASREB)

    The natural and human activities that cause change of quality of surface water include;

    Weathering rocks and erosion.

    Decay of organic matter such as leaves, branches of trees which result in humid substances.

    Flooding river banks resulting in high turbidity.

    Industrial and domestic wastes such as oil and grease, detergents, inorganic salts etc.

    Agricultural runoff including fertilizers, herbicides and pesticides.

    II. Ground water quality (WASREB)

    Ground water obtained from boreholes contains no or low levels of harmful pathogens but it can

    be polluted with naturally occurring chemicals. More often than not, contamination can be caused

    by poor sanitary protection at the top of the borehole. Composition of ground water highly depends

    on;

    Composition of the soil (humic substances, organic matter and minerals).

    Retention time of ground water.

    Quality of water to be infiltrated for example rain or surface water.

  • 9

    2.3 Aesthetic Parameters of Water

    2.3.1 Turbidity

    Turbidity is a measure of the amount of light dispersed by the particles suspended in a sample of

    water. It is a function of the concentration and the nature of the particles. It is caused by presence

    of suspended matter such as clay, silt and fine particles of organic and inorganic matter, plankton

    and other microscopic organisms. Turbidity is usually measured using a turbidimeter which works

    on the principle of light scattering. The amount of light scattered is proportional to the turbidity of

    the liquid and can be measured. The WHO guideline value for turbidity is 5NTU or FTU and above

    this value, water can be objected to aesthetic reasons while a value of less than 1NTU or FTU is

    preferred for disinfection efficiency. Presence of clay and other inner suspended particles in

    drinking water may not adversely affect the health but may cause need for additional treatment.

    Soon after rainfall, variation in ground water turbidity may be an indication of surface

    contamination. A turbidity indicating surface runoff suggest possible pollution therefore requires

    satisfactory treatment before supply to the public (PHE lecture notes 481, 2014).

    Turbidity affects the acceptability of water to the consumers and the selection as well as the

    efficiency of the treatment process to be conducted. Whenever the treatment involves disinfection

    with chlorine, turbidity exerts a chlorine demand and protects microorganisms and may also

    stimulate the growth of bacteria (WHO, 2008).

    2.3.2 Colour

    Colour in drinking water may be due to the presence of organic matter such as humic substances,

    metals such as iron and manganese, or highly coloured industrial wastes (WHO, 2008). It is an

    indication of large amount of organic chemicals in adequate treatment and high disinfection

    demand. The colour in unpolluted surface waters is caused by the presence of humic and fulvic

    acids which are derived from peat and soil humus. In some waters the brown colour is enhanced

    by the presence of iron and manganese. Waters subject to industrial pollution may also contain a

    wide variety of coloured materials.

  • 10

    The colouring materials may be procured by surface water when flowing through swamps or by

    groundwater when dissolving minerals. Red water results from the presence of iron compounds in

    water. Swampy water appears black due to ink formed by the combination of organic acids with

    tannates and gallates. Blue water may result from copper compounds in suspension or in solution

    or from landing bluing (Leonard, 1973)

    2.3.3 Odour

    Odour is an unpleasant distinctive smell that is caused by the presence of organic substances in

    water (WHO, 2008). Some odours are indicative of increased biological activity, while others may

    originate from industrial or municipal discharges in to natural sources therefore causing algae

    growth.

    The odour of water changes with temperature and sometimes not being noticeable when water is

    cold. Water for domestic use should have no odour. The intensity of odour is expressed as threshold

    odour, based on diluting a portion of sample of water with odour free water. While in the fields of

    stream pollution and air pollution, the threshold odour test expresses odour in parts per million

    (ppm).Sanitary surveys should include investigations of sources of odour when problems are

    identified.

    2.3.4 Taste

    Taste is the combined perception of substances detected by the senses of taste and smell. Taste

    problems in drinking water supplies are often the largest single cause of consumer complaints.

    Changes in the normal taste of a public water supply may signal changes in the quality of the raw

    water sources or deficiencies in the treatment process (WHO, 2008).

    It may originate from the treatment process as a result of chlorination or through water reacting

    with substances in the water distribution pipes such as asphaltic or bituminous coating on pipes or

    reservoirs.

    Some substances such as certain organic salt produce a taste without an odour and can be evaluated

    by a taste test. Furthermore, other sensations ascribed to the sense of taste are odour, even though

    the sensation is not noticed until the substance is consumed.

    Water should be free of tastes that would be objectionable to the majority of consumers.

  • 11

    2.3.5 Temperature

    Cool water is generally more palatable than warm water, and temperature will have an impact on

    the acceptability of a number of other inorganic constituents and chemical contaminants that may

    affect taste. High water temperature enhances the growth of microorganisms and may increase

    problems related to taste, odour, colour and corrosion (WHO, 2011).

    2.3.6 Total dissolved solids

    Total dissolved solids are a measure of all inorganic and organic substances contained in a liquid

    in molecular, ionized or micro-granular suspended form. Total dissolved solids are normally

    discussed in fresh water systems as salinity comprises of some of the ion constituting the definition

    of TDS. The principal application of TDS is in the study of water quality for streams, rivers and

    lakes and although TDS is not considered a primary pollutant, it is used as an indicator of aesthetic

    characteristics of drinking water and as an aggregate indicator of the presence of a broad array of

    chemical contaminants. (Total dissolved solids-Wikipedia the free encyclopaedia). The amount of

    TDS contained in water vary considerably with the different geologic conditions due to the

    differences in the solubility of minerals.

    2.3.7 Conductivity

    Electrical conductivity is the ability of a substance to conduct an electrical current, measured in

    Micro Siemens per centimetre. The higher the conductivity the greater the number of ion in the

    water. Ions such as sodium, potassium, and chloride give water higher conductivity. Conductivity

    can be an indicator of the amount of dissolved salts in a sample. Conductivity often is used to

    estimate the amount of total dissolved solids (TDS) rather than measuring each dissolved

    constituent separately (Farrell-Poe, 2005)

  • 12

    2.4 Microbiology and Bacteriological Aspects

    Microbial parameters have an immediate and significant impact on human health and have to be

    analysed frequently (WHO, 2008). Microorganisms are usually very small living organisms which

    can only be seen with the help of a microscope. Many species of the organisms have been identified

    and studied extensively. Engineers are interested in microorganisms that are involved in causing

    water-borne diseases, decomposition and stabilization of organic matter and useful reactions that

    are gainful e.g.: industrial production of alcoholic beverages, fermented dairy products, vitamins,

    enzymes etc.

    Particularly, public health engineers have interest on how pathogens find their way into water,

    their movement from one point to another and their behaviour in relation to change of environment

    in a water supply system.

    2.4.1 Escherichia coli (E. coli)

    Is abundant in human and animal faeces; in fresh faeces it may attain concentrations of 109 per

    gram. It is found in sewage, treated effluents, and all natural waters and soils subject to recent

    faecal contamination, whether from humans, wild animals, or agricultural activity. Recently, it has

    been suggested that E. coli may be present or even multiply in tropical waters not subject to human

    faecal pollution. However, even in the remotest regions, faecal contamination by wild animals,

    including birds, can never be excluded. Because animals can transmit pathogens that are infective

    in humans, the presence of E. coli or thermotolerant coliform bacteria must not be ignored, because

    the presumption remains that the water has been faecally contaminated and that treatment has been

    ineffective (WHO, 2008).

    2.4.2 Coliform organisms (total coliforms)

    Coliform organisms have long been recognized as a suitable microbial indicator of drinking-water

    quality, largely because they are easy to detect and enumerate in water. The term coliform

    organisms refers to Gram-negative, rod-shaped bacteria capable of growth in the presence of bile

    salts or other surface-active agents with similar growth-inhibiting properties and able to ferment

    lactose at 3537C with the production of acid, gas, and aldehyde within 2448 hours (WHO,

    2008).

  • 13

    They are also oxidase-negative and non-spore-forming and display b-galactosidase activity.

    Bacteria are responsible for most of the most devastating water-borne diseases. Of concern is the

    E.coli which is a faecal bacteria usually secreted in large numbers through human faeces.

    Under the WHO standards, drinkable water should not have any trace of indicator organisms

    (coliform or E.coli bacteria).

    2.4.3 Bacteriological standards

    Bacteriological classification of treated water supplies is as follows (Kabete treatment procedures);

    Class I Excellent- contains no coliforms and no E.coli.

    Class II Satisfactory- contains 1 to 3 coliforms and no E.coli.

    Class III Suspicious- contains 4 to 10 coliforms and no E.coli.

    Class IV Unsatisfactory- contains more than 10 coliforms and no E.coli.

    Class V Unsatisfactory- contains one or more coliforms and 1 E.coli or more.

    It should be noted that treated water should be restricted to class 1 only.

    2.5 Chemical Parameters

    Many chemicals in drinking water are of concern only after an extended period of exposure. Where

    water sources are likely to be used for long periods, chemical contaminants should be given greater

    attention. This entails adding treatment processes or seeking alternative sources. The later has been

    significantly preferred.

  • 14

    2.5.1 Hydrogen ion concentration (pH)

    It is the measure of acidity or alkalinity of water. It is a measure of hydrogen ions [H+] expressed

    by the function pH given by:

    PH= -log10 = log10 (1/ [H+]

    A value of 7 is the neutral value .Any value below 7 indicates acidity and any above 7 indicates

    alkalinity. The range of natural pH in fresh waters extends from around 4.5 for upland water to

    over 10.0 in waters where there is intense photosynthetic activity by algae. However, the most

    frequently encountered range is 6.0 8.0.

    In treatment and distribution systems, it is necessary to know the pH of water, because

    a) Effectiveness of coagulants are highly dependent on pH (Ratnayaka, et al., 2009).

    b) pH determines effectiveness of disinfection. More alkaline water requires a longer contact time

    or a higher free residual chlorine level at the end of the contact time for adequate disinfection (0.4

    0.5 mg/L at pH 68, rising to 0.60 mg/L at pH 89; chlorination may be ineffective above pH 9)

    (WHO, 2004: Ratnayaka, et al., 2009).

    c) pH is influential for control of solubility and rate of reaction of most of the metal species

    involved in corrosion reactions. It is particularly important in relation to the formation of a

    protective film at the metal surface. For some metals, alkalinity and calcium hardness also affect

    corrosion rates (WHO, 2004). The optimum pH will vary in different water supplies according to

    the composition of the water and the nature of the construction materials used in the distribution

    system. It is usually in the range of 6.5 to 8 (WHO, 2004).

    2.5.2 Hardness

    Water that is considered hard is high in dissolved minerals, specifically calcium and magnesium.

    As the concentration of these minerals increase, the water becomes harder. Other ions which occur

    in relative low concentrations but are still responsible for water hardness are iron, manganese,

    aluminium and zinc (Water hardness, 2013)

    There is no health risks associated with hard water. On the contrary, people who take hard water

    throughout their lifetime have a lower rate of cardiovascular disease.

  • 15

    However, there are problems associated with hard water, these include

    Grey straining of washed clothes.

    Scum on wash and bath water following use of soap or detergent.

    Reduced lathering of soaps.

    Build-up of scale on electric heating elements and boilers.

    Reduced water flow in hot water distribution pipes due to scale build-up.

    Accumulation of whitish- grey scale in tea kettles and other containers used to

    boil water.

    Table 1: Hardness

    Concentration of CaCO3, mg/l Degree of hardness

    0 50 Soft

    50 100 Moderately soft

    100 150 Slightly hard

    150- Moderately hard

    200-300 Hard

    >300 Very Hard

    Source: ( Ratnayaka, et al., 2009).

    Low level of hardness can be easily removed by boiling. High degree of hardness is removed by

    the addition of lime. This method has also the benefit that iron and manganese contents are

    removed and suspended particles including micro- organism are also reduced.

    2.5.3 Fluorides

    Fluoride comes from minerals such as fluorspar but in some countries fluoride is artificially added

    to water. When present in optimum concentration of 0.8 to 1.2mg/l (depending on water intake per

    day), fluoride minimizes dental caries. However, when present in excess concentrations, it is

    responsible for adverse effects starting from mild mottling of teeth (yellowish discoloration) (FCE

    481lecture notes, 2013).

  • 16

    Over many years, fluoride can build up in peoples bones, leading to skeletal fluorosis

    characterized by stiffness and joint pain. In severe cases, it can cause changes to the bone structure

    and cause crippling effects. Infants and young children are most at risk from high amounts of

    fluoride as their bodies are still growing.

    2.5.4 Alkalinity

    Alkalinity is the concentration of hydrogen ions that can be neutralized or the acid neutralizing

    capacity of water. Alkalinity is a measurement of acid neutralizing capacity. It is the total

    concentration of strong acid required to reduce the pH to an end point of say 4.5 (AWWA, 2011).

    In natural water, pH is determined largely by the concentration of hydrogen ions and alkalinity by

    the concentrations of hydroxyl, bicarbonate and carbonate ions in water. Other species often

    present in small concentrations such as silicates, borates, ammonia, phosphates and organic bases

    contributes for alkalinity (Dallas and Day, 2004).

    Information concerning alkalinity is used in the following ways in practice.

    a) Chemical Coagulation

    Chemicals used for coagulations in conventional treatment system are usually metallic salts that

    have acidic character. When dosed into water, the formation of hydroxide floc is the result of the

    reaction between the acidic coagulant and the natural alkalinity of the water, which usually consists

    of calcium bicarbonate. The hydrogen ions released react with the alkalinity of the water. If the

    raw water has insufficient alkalinity or buffering capacity, additional alkali such as hydrated

    lime, sodium hydroxide, or sodium carbonate must be added. Thus, the alkalinity acts to buffer the

    water in a pH range where the coagulant can be effective. For effective and complete coagulation

    to occur, alkalinity must be present in excess of that destroyed by the acid from the coagulant

    (Ratnayaka, et al., 2009).

    b) Water Softening

    Water softening is a removal of calcium, magnesium, and other polyvalent cations, including

    Ba2+, Sr2+, Fe2+, and Mn2+, achieved through cation exchange with addition of lime and soda

    ash. Alkalinity is a major item that must be considered in calculating the lime and soda ash

    requirements in softening of water by precipitation methods. The alkalinity of softened water is a

    consideration in terms of whether such waters meet drinking water standards ( Ratnayaka, et al.,

    2009).

  • 17

    c) Corrosion Control

    Many factors determine whether water will be corrosive but three specific characteristics are

    important (Ratnayaka, et al., 2009):

    i. Low pH value, i.e. acidity;

    ii. High free carbon dioxide (CO2) content; and

    iii. Absence or low amount of alkalinity.

    To control corrosion in water distribution networks, the methods most commonly applied are

    adjusting pH, increasing the alkalinity and/or hardness or adding corrosion inhibitors, such as

    polyphosphates, silicates and orthophosphates (WHO, 2004). Alkalinity must be known in order

    to calculate the Langelier saturation index that measures the corrosiveness of water.

    d) Buffering

    Alkalinity is important for fish and aquatic life because it protects or buffers against rapid pH

    changes. Aquatic organisms are sensitive to pH change of water. Few aquatic organisms tolerate

    waters with pH less than 4 or greater than 10 (Dallas and Day, 2004).

    Higher alkalinity levels in surface waters will buffer acid rain and other acid wastes and prevent

    pH changes that are harmful to aquatic life.

    There are three kinds of alkalinity referred to in environmental literature. Phenolphthalein

    alkalinity, methyl orange alkalinity, and total alkalinity (Sawyer, et al., 2003).

    1. Phenolphthalein alkalinity: A measure of concentrated acid required to reduce a base as strong

    as or stronger than the carbonate ion. If the sample water has a pH level higher than approximately

    8.3, you will see two equivalence points in the titration curve instead of just the one around 4.5.The

    first drop in pH at around 8.3 is the phenolphthalein equivalence point, and the amount of acid

    used to titrate to this point is used to calculate the phenolphthalein alkalinity. If the sample water

    is initially below pH 8.3, the phenolphthalein alkalinity is zero.

    2. Methyl orange alkalinity: A measure concentrated acid required to reduce a base as strong as,

    or stronger than the bicarbonate ion. This is calculated using the volume of acid needed to titrate

    to the lower pH equivalence point of 4.5.

    3. Total alkalinity: The sum of the phenolphthalein alkalinity and the methyl orange alkalinity.

  • 18

    2.6 Surveillance and Monitoring

    Surveillance is an investigative activity undertaken to identify and evaluate factors associated with

    drinking water which could pose a risk to health. Therefore, there is protection of public health by

    promoting improvement of the quality of water supplies. A surveillance agency is responsible for

    independent (external) surveillance through periodic audit of all aspects of safety and verification

    testing. Water quality monitoring is the foundation on which water quality management is based

    (Bartram and Balance, 1996).

    International standards (WHO)

    National standards (KEBS)

    WASREB

    WASREB ensures that surveillance and monitoring is done by the Water Service Providers. WSP

    are liable to the health and dissatisfaction of consumers. Reports should also be made to Water

    Service Boards.

  • 19

    Currently, water quality sampling and testing is conducted at sources, treatment plants, storages

    and distributions by the Water Quality Assurance Department of the Nairobi City Water and

    Sewerage Company (NCWSC). The objective of sampling and testing is for compliance with

    established standards. Sampling and testing is also conducted at the request of customers or when

    there is complaint from customers with respect to water quality.

    Under the WHO guidelines on, water quality standards, there should be separate roles in

    monitoring by the WSP and an independent regulating body.

    Monitoring of the water control measures includes;

    Temperature of remote areas that is done frequently e.g. weekly.

    Disinfectants and pH usually employed weekly or monthly.

    Microbial quality of water especially following system maintenance or repairs.

    However, daily monitoring is necessary in the presence of suspected water related cases of human

    illness. For recently commissioned or following maintenance of the system, monitoring of drinking

    water quality is required to be more frequent. This should be done until the water quality has

    stabilized.

    2.6.1 Monitoring programs

    According to WASREB quality guidelines, monitoring program involves some surveillance

    mechanisms that include;

    a) Self-monitoring

    Self-monitoring is undertaken by WSP in accordance with sampling schedule. The monitoring in

    the sampling schedule are the minimum self-monitoring frequencies that must be performed;

    however the provider may choose to perform monitoring at a greater frequency than specified if

    so desired.

  • 20

    Schedule 1: WSP Sample Schedules for Water Quality Monitoring

    Name of Water Service Provider:

    Category:

    System description:

    Water production to town (m3/yr.)

    Number of separate networks

    Include layout showing sampling points in

    the system.

    Network 1

    description

    Number of tests

    planned according to

    guideline

    Number of tests

    conducted

    Number of tests

    within standard

    Residual chlorine

    Bacteriological

    Turbidity, pH,

    colour

    Other

    physiochemical

    Source: (WASREB)

  • 21

    b) Scheduled monitoring

    Scheduled monitoring involves the systematic sampling and inspection by the WSB in accordance

    with a predetermined schedule. Scheduled monitoring will serve to check for compliance with the

    requirements.

    c) Unscheduled monitoring

    Unscheduled monitoring is instituted by the WSB to provide a less formal type of surveillance on

    the provider. Similarly, WASREB can undertake unscheduled monitoring to check water

    compliance by the WSPs and WSBs.

    d) Demand monitoring

    The WSP conducts demand monitoring when an upset or other disruption of system operation

    occur. In addition, the WSB and WASREB depending on the severity of the occurrence can

    undertake demand monitoring as and when required.

    2.7 Sampling

    2.7.1 Sample collection

    When water samples are collected for analysis, care should be taken to ensure that there is no

    external contamination of the samples. In order to minimize inconsistencies and ensure the

    accuracy of the process, it is recommended that the sampling should be done by qualified persons

    (WASREB).

    Glass bottles are considered the best for sampling with a capacity of at least 200ml. They should

    have securely fitting stoppers or caps with nontoxic liners and both bottles and liners should be

    sterilized. Avoid cotton wool plugs or paper caps as they tend to fall off during sampling and

    increase the risk of contamination. Bottles can be reused to minimize costs but after they have been

    desterilized.

  • 22

    Whenever chlorine is used for disinfection, a chlorine residual may be present in the water after

    sampling and will continue to act on any bacteria in the sample; the results of the microbiological

    analysis may therefore not be indicative of the true bacteriological content of the water. To

    overcome this difficulty, it is common procedure to add sodium thiosulfate to the sample, which

    immediately inactivates any residual chlorine but does not affect the microorganisms that may be

    present. The sodium thiosulfate should be added to the sample bottles before they are sterilized.

    For 200-ml samples, four or five drops of aqueous sodium thiosulfate solution (100 g/litre) should

    be added to each clean sample bottle (WHO, 1997).

    2.7.2 Sampling from a tap

    1.0 Clean the tap. Remove from the tap any attachments that could cause splashing. Use a clean

    cloth and wipe the outlet to remove any dirt.

    2.0 Open the tap. Turn on the tap and let the water run for at least one minute. The tap should

    be left to run at maximum flow.

    3.0 Sterilize the tap. Sterilize the tap for a minute with the flame from a gas burner, cigarette

    lighter, or an ignited alcohol-soaked cotton wool swab.

    4.0 Open the tap before sampling. Turn on the tap and allow flow for at least a minute at

    medium flow. Care should be taken not to adjust flow after it has been set.

    5.0 Filling sterilized bottle. Carefully unscrew the cap or pull out the stopper of the bottle.

    While holding the cap and protective cover face downwards, immediately hold the bottle

    under the water jet and fill. A small air space should be left to make shaking before analysis

    easier. After placing a stopper or screwing on the cap, fix a brown paper protective cover

    in place with a string.

    Table 2: Minimum sample numbers for piped drinking-water in the distribution system.

    Population served No. of monthly samples

    100000 1 per 10 000 population, plus 10 additional

    samples

    Source: (WHO, 1997).

  • 23

    2.7.3 Sampling points

    The Drinking Water Quality and Effluent Monitoring Guideline established by Water Services

    Regulatory Board has set clear that strategic sampling points should be identified within a

    distribution system to ensure that they are representatives of the entire system and at the same time

    ensuring that particular problem areas are identified.

    Sampling points should include the most unfavourable sources or places in the supply system

    particularly points of possible contamination such as unprotected sources, loops, reservoirs, low-

    pressure zones and ends of the system.

    For a given network, sampling points should be uniformly distributed throughout a piped

    distribution system, taking population distribution into account; the number of sampling points

    should be proportional to the number of links or branches. The samples should be representatives

    of the different sources from which water is obtained by the consumers or enters the system.

    In systems with more than one water source, the locations of the sampling points should take into

    account of the number of inhabitants served by each source (WHO, 1997).

    2.8 Health implications

    According to WHO, 2008, the principal risks to human health associated with the consumption of

    polluted water are microbiological in nature. However the importance of chemical contamination

    should never be underestimated. Widespread health risk associated with drinking-water is

    contamination, either directly or indirectly, by human or animal excreta, particularly faeces. If

    such contamination is recent, and if those responsible for it include carriers of communicable

    enteric diseases, some of the pathogenic microorganisms that cause these diseases may be present

    in the water. Drinking the water, or using it in food preparation, may then result in new cases of

    infection. An estimated 80% of all diseases and over one-third of deaths in developing countries

    are caused by the consumption of contaminated water and on average as much as one-tenth of each

    persons productive time is sacrificed to water-related diseases.

    Through epidemiological investigations, it is evident that all aspects of the water supply services

    influence health, so do hygiene behaviours and sanitation. The provision of safe drinking-water is

    the most important step which can be taken to improve the health of a community by preventing

    the spread of waterborne disease.

  • 24

    Microbiological monitoring provides a sensitive indication of the extent to which source

    protection, treatment, and distribution are effective barriers to the transmission of infectious agents

    of waterborne disease at the time that the samples were taken. It is important to realize at the outset

    that microbiological integrity is provided by source protection and treatment, and that sudden loss

    of this integrity or steady deterioration may be missed if monitoring is not frequent enough.

    It is difficult with the epidemiological knowledge currently available to assess the risk to health

    presented by any particular level of pathogens in water, since this will depend equally on the

    infectivity and invasiveness of the pathogen and on the innate and acquired immunity of the

    individuals consuming the water. It is only prudent to assume, therefore, that no water in which

    pathogenic microorganisms can be detected can be regarded as safe, however low the

    concentration. Furthermore, only certain waterborne pathogens can be detected reliably and easily

    in water, and some cannot be detected at all.

    Over many years, a universal agreement was adopted on the concept of faecal indicator species as

    the most specific and suitable bacteriological indicator of faecal pollution is the Escherichia coli.

    Any water that contains E. coli must be regarded as faecally contaminated and unsafe, and

    requiring immediate remedial action.

    Only strict attention to source protection and to the design and operation of efficient treatment and

    distribution will guarantee the exclusion of pathogens from drinking-water delivered to the

    consumer. For each water supply, the quality of the source water must guide the selection of the

    treatment processes, and due attention must be given to the ability of these processes to eliminate

    different pathogens.

  • 25

    WHO drinking water guidelines

    Table 3: WHO drinking water guidelines

    Parameter Unit WHO guideline

    pH pH scale 6.5 to 8.5

    Odour and Taste Not objectionable

    Colour TCU

  • 26

    Kenya Bureau of Standards (KEBS) Guidelines

    i. Bacteriological quality

    Kenya Drinking Water Quality Standards, KS 150-1996 that conforms to WHO guideline limits.

    Table 4: Microbiological limits for drinking water and containerized water.

    Type of microorganisms Drinking water Containerized water

    Total viable counts at 370C

    per ml (max)

    100 20

    Coliforms in 250ml Shall be absent Shall be absent

    E.coli in 250ml Shall be absent Shall be absent

    Staphylococcus aureus in

    250ml

    Shall be absent Shall be absent

    Sulphite reducing anaerobes

    in 50ml

    Shall be absent Shall be absent

    Pseudomonas aeruginosa

    fluoresence in 250ml

    Shall be absent Shall be absent

    Streptococcus faecallis Shall be absent Shall be absent

    Shigella in 250ml Shall be absent Shall be absent

    Salmonela in 250ml Shall be absent Shall be absent

  • 27

    ii. Desirable Aesthetic Quality

    Table 5: Aesthetic Quality for Requirements of Drinking water and Containerized water (KS 150

    and WHO Guidelines).

    Substance or characteristic Drinking water Containerized water

    Colour in TCU (max) 15 15

    Taste and colour Shall not be offensive to

    consumers

    Shall not be offensive to

    consumers

    Suspended matter nil nil

    Turbidity in NTU (max) 5 1

    Total dissolved solids (mg/l)

    max

    1500 1500

    Hardness as CaCO3(mg/l)

    max

    500 500

    Aluminium as Al, mg/l 0.1 0.1

    Chloride as Cl, mg/l (max) 250 250

    Copper as Cu, mg/l (max) 0.1 0.1

    Iron as Fe, mg/l (max) 0.3 0.3

    Sodium as Na, mg/l (max) 200 200

    Sulphate as SO-42, mg/l (max) 400 400

    Zinc as Zn, mg/l (max) 5 5

    pH 6.5 to 8.5 6.5 to 8.5

    Magnesium as Mg, mg/l

    (max)

    100 100

    Chlorine concentration as Cl,

    mg/l

    0.2-0.5 nil

    Calcium as Ca, mg/l 250 250

    Ammonia mg/l (max) 0.5 0.5

    Fluorides mg/l, (max) 1.5 1.5

  • 28

    Water Service Regulatory Board (WASREB) Guidelines

    Table 6: Aesthetic quality requirements for drinking water and bottled drinking water (adopted

    from KS 05-459: Part 1:1996).

    Substance or

    characteristic

    unit Drinking water Bottled

    drinking water

    Method of test

    colour TCU 15 15 KS 05-459

    Taste and colour Shall not be

    offensive to

    consumers

    Shall not be

    offensive to

    consumers

    KS 05-459

    Suspended

    matter

    nil Nil KS 05-459

    turbidity NTU, max 5 1 KS 05-459

    Total dissolved

    solids

    mg/l max 1500 1500 KS 05-459

    Hardness as

    CaCO3

    mg/l max 500 500 KS 05-459

    Aluinium as Al mg/l max 0.1 0.1 KS 05-459 Chloride as Cl- mg/l max 250 250 KS 05-459

    Copper as Cu mg/l max 0.1 0.1 KS 05-459

    Iron as Fe mg/l max 0.3 0.3 KS 05-459

    Manganese as

    Mn

    mg/l max 0.1 0.1 KS 05-459

    Sodium as Na mg/l max 200 200 KS 05-459

    Sulphate as SO4 mg/l max 400 400 KS 05-459

    Zinc as Zn mg/l max 5 5 KS 05-459

    PH 6.5 to 8.5 6.5 to 8.5 KS 05-459

    Magnesium as

    Mg

    mg/l max 100 100 KS 05-459

    Chlorine

    concentration

    Mg/l 0.2-0.5 Nil KS 05-459

    Calcium as Ca mg/l max 250 250 KS 05-459

    Ammonia (N) mg/l max 0.5 0.5 KS 05-459

    Fluoride as F* mg/l max 1.5 1.5 KS 05-459

    Arsenic as As mg/l max 0.05 0.05 KS 05-459

    Cadmium as Cd mg/l max 0.005 0.005 KS 05-459

    Lead as Pb mg/l max 0.05 0.05 KS 05-459

    Mercury (Total

    Hg)

    mg/l max 0.001 0.001 KS 05-459

    Selenium as Se mg/l max 0.01 0.01 KS 05-459

    Chromium as Cr mg/l max 0.05 0.05 KS 05-459

    Cyanide as CN mg/l max 0.01 0.01 KS 05-459

  • 29

    Phenolic

    substances

    mg/l max 0.002 0.002 KS 05-459

    Barium as Ba mg/l max 1.0 1.0 KS 05-459

    Nitrate as NO3 mg/l max 10 10 KS 05-459

    Table 7: Microbiological limits for drinking water and containerized drinking water (Adopted

    from KS 05-459: Part 1:1996).

    Type of micro-

    organism

    Drinking water Containerized

    drinking water

    Method of test

    Total viable counts at

    370C, per ml, max

    100 20 KS 05-200+

    Coliforms in 250ml Shall be absent Shall be absent KS 05-200

    E. Coli in 250ml Shall be absent Shall be absent KS 05-200

    Staphylococcus

    aureus in 250ml

    Shall be absent Shall be absent KS 05-200

    Sulphite reducing

    anaerobes in 50ml

    Shall be absent Shall be absent KS 05-200

    Pseudomonas

    aeruginosa fl

    uorescence

    in 250ml

    Shall be absent Shall be absent KS 05-200

    Streptococuus

    faecalis

    Shall be absent Shall be absent KS 05-200

    Shigella in 250ml Shall be absent Shall be absent KS 05-200

    Salmonella in 250ml Shall be absent Shall be absent KS 05-200

  • 30

    2.9 Treatment and disinfection

    According to the WHO guidelines for drinking water quality, this involves the ability to achieve a

    guideline value within a drinking water supply. Collection, treatment, storage and distribution of

    drinking-water involve deliberate additions of numerous chemicals to improve the safety and

    quality of the finished drinking-water for consumers. In addition, water is in constant contact with

    pipes, valves, taps and tank surfaces, all of which have the potential to impart additional chemicals

    to the water. A qualitative ranking of treatment processes based on their degree of technical

    complexity is as shown. The higher the ranking the more complex treatment.

    2.9.1 Water treatment process

    Water treatment involves physical, chemical and biological changes that are meant to transform

    raw water into potable and wholesome waters. The specific treatment process used in any specific

    case depends on the nature and quality of the raw water and the desired treatment water quality.

    Thus, in many cases it is sufficient to only aerate and disinfect borehole water for domestic use.

    Surface water on the other hand, due to pollution from various sources (sewage, industrial, bacteria

    etc.) will usually nee full treatment which consists of coagulation / flocculation, sedimentation,

    filtration and disinfection. In some cases especially where water of very high quality is required it

    may be necessary to carry out more advanced treatment like adsorption with activated carbon. Yet

    at other times methods for reducing the concentration of specific substances like fluorides may be

    necessary.

    Water treatment processes may be simple in nature, like sedimentation or may involve very

    complex physiochemical changes, as in coagulation. The analysis carried out during water analysis

    do not usually show how complex some of the physiochemical relationships in the water may be

    and such analysis on its own may not reveal how much chemicals need to be added into the water

    in order to achieve the desired results. The use of the jar test clearly illustrates this point. The actual

    test procedures may also vary but the procedures given in the Standard Methods for the

    Examination of Water and Waste Water (APHA) are well suited for most conditions (PHE lecture

    notes 481).

  • 31

    Table 8: Ranking of technical complexity and cost of water treatment processes.

    Ranking Examples of treatment processes

    1 Simple chlorination

    Plain filtration (rapid sand, slow sand)

    2 Pre-chlorination plus filtration

    Aeration

    3 Chemical coagulation

    Process optimization for control of DBPs

    4 Granular activated carbon (GAC) treatment

    Ion exchange

    5 Ozonation

    6 Advanced oxidation processes

    Source: (WHO, 2008).

    In order to transform raw water, that contains coliform organisms, to potable water the

    recommended treatment is as shown;

    Table 9: Recommended treatment in relation to number of coliform organism per 100ml.

    Coliform organism (Number/100ml). Recommended treatment.

    0-50 Bacterial quality requiring disinfection only.

    50-5000 Bacterial quality requiring full treatment

    (coagulation, sedimentation, filtration and

    disinfection only)

    5000-50000 Heavy pollution requiring extensive treatment.

    Greater than 50000 Very heavy pollution unacceptable as a source

    unless no alternative exists. Special treatment

    needed.

    Source: (WHO, 1997).

  • 32

    2.9.2 Chlorination

    This method of disinfection is achieved through the use of pressurized liquefied chlorine gas,

    sodium hypochlorite solution or calcium hypochlorite granules and on site chlorine generators.

    They all dissolve in water to form hypochlorous acid (HOCL) and hypochlorite ion (OCL).

    Different techniques of chlorination can be used including breakpoint chlorination, marginal

    chlorination and super chlorination. Breakpoint chlorination is a method in which the chlorine dose

    is sufficient to rapidly oxidize all the ammonia nitrogen in the water and to leave a suitable free

    residual chlorine available to protect the water against reinfection from the point of chlorination to

    the point of use. Super chlorination/dechlorinating is the addition of a large dose of chlorine to

    effect rapid disinfection and chemical reaction, followed by reduction of excess free chlorine

    residual. Removing excess chlorine is important to prevent taste problems. It is used mainly when

    the bacterial load is variable or the detention time in a tank is not enough. Marginal chlorination is

    used where water supplies are of high quality and is the simple dosing of chlorine to produce a

    desired level of free residual chlorine. The chlorine demand in these supplies is very low, and a

    breakpoint might not even occur.

    Chlorination is employed primarily for microbial disinfection. However, chlorine is an oxidant

    that can remove or assist in the removal of some chemicals for example decomposition of easily

    oxidized pesticides such as aldicarb or oxidation of dissolved species to more easily removable

    forms (e.g., arsenite to arsenate).

    A disadvantage of chlorine is its ability to react with natural organic matter to produce THMs and

    other halogenic DBPs. However the by-product formation may be controlled by optimization of

    the treatment system (WHO, 1997).

    Other disinfection methods include Ozonation, the use of chlorine dioxide, UV radiation and

    advanced oxidation processes

  • 33

    Chapter Three

    Methodology

    3.1 Introduction

    This entails the experimental data through description of methods and techniques used in collection

    of data, analysis and experimentation which helps in accomplishing the projects objectives being

    assessed of the water quality. The approach of the study was to sample points and establish whether

    the various water parameters conform to the WHO, KEBS and WASREB standards.

    3.2 Study area

    The objective of the surveillance is to assess the quality of the Water Service Providers (WSP).

    The sampling points are random, fixed and recognized by the Water Service Provider as genuine.

    For this reason they are more likely to identify any and detect any local problems such as cross

    connections and contaminations from leaking distribution system. Data was collected in the month

    of February 2016.

    Criteria for selecting sampling locations was based on the functional and recognized points used

    by WSP. These points can be used to establish the quality of water in the University since the

    selected points are representations of water quality monitoring in the area. Points selected are areas

    around the University of Nairobi and are as listed below:

    Central park.

    Serena hotel.

    Nairobi primary school.

    Metropolitan estate.

    Boulevard hotel.

  • 34

    Figure 3:Sampling points around the University environs.

    Figure 4:Sampling points in Nairobi County

  • 35

    3.3 Limitations of the study

    1. Water quality monitoring was conducted for the month of February due to time limit and

    delayed permits from the Water Service Providers. However, it is required that water

    quality monitoring be done at least on monthly basis.

    2. All the laboratory water quality parameters were conducted under the constraint of the

    available equipment at the University of Nairobi Public Health Laboratories (Hyslop

    building). One of the highlight parameters left out was the bacteriological test. None of the

    coliform counts or the E.coli test was conducted.

    3. Comparison of data obtained from both the NCWSC Kabete treatment works and the UON

    laboratories may have been different due to the different technologies of the equipment

    used.

    4. There was missing water quality data, as well as inconsistent sampling frequency. The

    report is based on available data obtained from Water Quality Department of NCWSC.

    3.4 Sampling

    The minimum number of samples that were collected were in accordance to WASREB

    requirements. For each sampling point, one sample was collected to represent a population of

    5,000.

    Field tests of residual chlorine were done to reduce the effect of light on the sample hence

    increasing the accuracy of the final result. The chlorine in water sample is affected by illumination

    from sunlight during transport to the lab.

    All the sampling bottles were provided by the University of Nairobi and were fully disinfected and

    cleaned with distilled water. To obtain the samples, care was observed to give true representation

    of the existing conditions and handled in such a way to prevent deterioration and contamination

    before arriving at the laboratories. Each sample was correctly and clearly marked with a permanent

    marker and the point of collection noted.

  • 36

    3.5 Laboratory tests

    After sampling, the laboratory tests were categorised as follows:

    Physical tests.

    Chemical tests.

    Bacteriological examination.

    The tests carried are in accordance to those proposed by WASREB to the WSP on monthly basis

    (Schedule, appendix).

    3.5.1 Physical tests conducted

    They included;

    Turbidity (Turbidimeter).

    Colour (Lovibond comparator).

    Temperature.

    Total dissoved solids.

    3.5.2 Chemical tests conducted

    The chemical tests conducted include;

    pH (pH meter).

    Residual chlorine (N N-diethyl-p-phenylenediamine, DPD tablet).

    Conductivity

    Hardness

    Fluorides.

    Total coliforms and E.coli bacterial contamination tests were done at Kabete Treatments

    Works Laboratory since the UON . Two methods were incorporated namely the presence

    absence test and the M.P.N. test. However, WHO (1997), recommends presence-absence tests

    for monitoring good quality drinking water where positive results are known to be rare.

    Further, treated water containing residual chlorine kills present bacteria in the water. MPN test

    was also done to determine the exact total coliform and E.coli numbers.

  • 37

    3.6 Questionnaire

    Coordinator Nairobi water treatment labs (Kabete).

    How is the treatment process carried out?

    How often is sampling of piped water carried out?

    In case of vehicle or machine breakdowns, what are the contingency plans?

    How do you deal with pipe bursts in areas prone to contamination (sewer lines and dump sites)?

    How can clients/customers contact you in case they are not satisfied with the quality of water

    supplied to them?

    ...

  • 38

    Chapter Four

    Results and Analysis

    Results were summarized in two categories as follows:

    Category A which represents experiments that I, (Gatimu, project student), conducted

    (P.H.E. labs).

    Category B which represents experiments conducted by WSP (Kabete treatment labs).

    Physical Parameters

    Parameters

    1 2 3 4 5

    WHO

    KEBS

    Serena

    Hotel

    Central

    Park

    Boulevard

    Hotel

    Metropolitan

    Estate

    Nairobi

    Primary

    School

    W

    A

    S

    R

    E

    B

    A B A B A B A B A B

    Colour(TCU) 5 0 5 0 5 0 5 0 5 0 < 15 < 15 <

    1

    5

    Turbidity(NTU) 1 1.4 0.9 1.23 1.1 1.39 0.9 0.5 0.6 0.5 < 5 < 5