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UNIVERSITAT AUTÒNOMADE BARCELONA
CSICCONSEJO SUPERIOR DE
INVESTIGACIONES CIENTÍFICAS
CRISTAL LOQUÍMIC A DE PEROVSKITES
COMPLEXES DE COURE I TITANI.
RELACIÓ ENTRE SÍNTESI, ESTRUCTURA I
PROPIETATS SUPERCONDUCTORES
Memoria presentada per Maria Rosa Palacín i Peiró
per a optar al grau de Doctora en Ciències Químiques.
Bellaterra, novembre de 1995.
BIBLIOGRAFIA
BIBLIOGRAFIA
BIBLIOGRAFIA
1. B.T. Mattias, M. Marezio, E. Corenzivit, A.S. Cooper, H.E. Barz. Science 175 (1972)
1465.
2. J.F. Schooley, W.R. Hosler, M.L. Cohen. Phys. Rev. Lett. 12 (1964) 474.
3. A. Magnéli, B. Blomberg. Acta Chemica Scandinavica 5 (1951) 372.
4. F. Nydahl. Acta Chemica Scandinavica 5 (1951) 670.
5. A. Magnéli. Acta Chemica Scandinavica 1 (1953) 315.
6. A. Magnéli. Arkiv für Kemi l (1949) 269.
7. D.C. Johnston, H. Parkash, W.H. Zachariasen, R. Viswanathan. Mat. Res. Bull 8 (1973)
777.
8. D.C. Johnston. /. Low Temp. Phys. 25 (1976) 145.
9. A.W. Sleight, J.L. Gillson, P.E. Bierstedt. Solid State Commun. 17 (1975) 27.
10. J.G. Bednorz, K.A. Müller. Z. Phys. B Condens. Matter. 64 (1986) 189.
11. M.K. Wu, J.R. Ashburn, C.J. Torng, P.H. Hör, R.L. Meng, L. Gao, Z.J. Huang, Y.Q.
Wang, C.W. Chu. Phys. Rev. Lett. 58 (1987) 908.
12. C.N.R. Rao, P. Ganguly, A.K. Raychaudhuri, R.A. Mohan Ram, K. Sreedhar. Nature 326
(1987) 856.
13. M.A. Alario-Franco, C. Chaillout, J.J. Capponi, J.L. Tholence, B. Souletie. Physica C 222
(1994) 52.
14. X.J. Wu, S. Adachi, C.Q. Jin, H. Yamauchi, S. Tanaka. Physica C 223 (1994) 243.
15. H. Ihara, K. Tokiwa, H. ozawa, M. Hirabayashi, A. Negishi, H. Matuhata, Y.S. Song.
Jpn. J. Appl. Phys. 33 (1994) L503.
16. T. Kawashima, Y. Matsui, E. Takayama-Muromachi. Physica C 224 (1994) 69.
17. M.A. Alario-Franco, P. Bordet, J.J. Capponi, C. Chaillout, J. Chenavas, T. Fournier, M.
Marezio, B. Souletie, A. Sulpice, J.L. Tholence, C. Colliex, R. Argoud, J.L. Baldonedo,
M.F. Gorius, M. Perroux. Physica C 231 (1994) 103.
18. M.A. Alario-Franco. Adv. Mater. 7(2) (1995) 229.
19. M.A. Subramanian, C.C. Torardi, J.C. Calabrese, J. Gopalakrishan, K. Morrissey, T.R.
Askew, R.B. Flippen, U. Chowdry, A.W. Sleight. Science 239 (1988) 1015.
20. A.K. Ganguly, K.S.N. Swamy, C.N.R. Rao. Physica C 156 (1988) 788.
•279
BIBLIOGRAFIA
21. M.A. Subramanian, C.C. Torardi, J. Gopalakrishnan, P.L. Gai, J.C. Calabrese, T.R.
Askew, R.B. Flippen, A.W. Sleight. Science 242 (1988) 249.
22. A. Schilling, M. Cantoni, J.D. Guo, H.R. Ott. Nature 363 (1993) 56.
23. C.W. Chu, L. Gao, F.Chen, Z.J. Huang, R.L. meng, Y.Y. Xue. Nature 365 (1993) 323.
24. A.W. Sleight. Science 242 (1988) 1519.
25. H.K. Müller-Buschbaum. Angew. Chem. Int. Ed. Engl. 28 (1989) 1472.
26. P.M. Grant. Adv. Mater. 2(5) (1990) 232.
27. Physics Today Special Issue 44(6) (June 1991).
28. Y.K. Tao, Y.Y. Sun, P.H. Hor, C.W. Chu. J. Solid State Chem. 105 (1993) 171.
29. C.N.R. Rao en "Chemistry of Advanced Materials" (Ed. C.N.R. Rao) Blacwell Scientific
Pub. Oxford, (1993) Cap. 7.
30. "Chemistry of Superconductor Materials" (Ed. T.A. Vanderah) Noyes Publications. New
Jersey (1992).
31. Chemistry in Britain Special Issue (September 1994).
32. M.A. García Aranda. Adv. Mater. 6(12) (1994) 905.
33. RJ. Cava, B. Battlog. MRS Bulletin (January 1989) 49.
34. M.G. Smith, A. Manthiram, J. Zhou, J.B. Goodenough, J.T. MarkerL Nature 351 (1991)
549.
35. H.F. Kay, P.C. Bailey. Acta Cryst. 10 (1957) 219.
36. W. Jackson, W. Reddish. Nature 156 (1945) 717.
37. V. Ginzburg. /. Phys. USSR 10 (1946) 107.
38. R.W.G. Wyckoff. "Crystal Structures" Interscience Publishers (John Wiley & Sons). New
York (1964). Vol. 2. Cap. VHA.
39. J.B. Goodenough, J.M. Longo en "Landolt Börnstein numerical data and functional
relationships in science and technology" (Ed. K.H. Hellwege, A.M. Hellwege) Springer
Verlag. Berlin Heidelberg (1970) Group HI Vol. 4a. Cap. 3.
40. P.S. Galasso. "Perovskites and High Tc Superconductors" Gordon and Breach Science
Pub. New York (1990).
41. V.M. Goldschmidt. Skrifter Norske Videnskaps-Akad. Oslo I. Mat.-Naturv. Kl. NS8
(1926).
42. J.M.D. Tascón, S. Mendioroz, L. González-Tejuca. Z. Phys. Chem. Neue Folge 124
(1981) 109.
280-
BIBLIOGRAFIA
43. A. Hammon en "Advances in Electrochemical Science and Engineering" (Ed. H.Gerischer, W. Tobias) VCH Verlagsgesellschaft Weinheim (1992). Vol. 2,2nd. Chapter.
44. K. Chahara, T. Ohno, M. Kasai, Y. Kozono. Appl. Phys. Lett. 63(14) (1993) 1990.45. R. von Helmolt, J. Wecker, B. Holzapfel, L. Schultz, K. Samwer. Phys. Rev. Lett. 71(14)
(1993) 2331.46. S. Jin, T.H. Tiefel, M. McCormack, R.A. Fastnacht, R. Ramesh, L.H. Chen. Science 264
(1994) 413.
47. G. Blasse. J. Inorg. Nucí. Chem. 27 (1965) 993.48. N. Setter. L.E. Cross. /. Mater. Sei. 15 (1980) 2478.49. C.N.R. Rao, J. Gopalakrishnan. "New Directions in Solid State Chemistry" Cambridge
University Press. New York (1989). Cap. 5.50. M.T. Anderson, J.T. Vaughey, K.R. Poeppelmeier. Chem. Mater. 5 (1993) 151.51. P.D. Battle, T.C. Gibb, P. Lightfoot. /. Solid State Chem. 84 (1990) 237.
52. P. Bordet, C. Chaillout, J.J. Capponi, J. Chenavas, M. Marezio. Nature 327 (1987) 687.
53. C.L. Teske, H. Müller-Buschbaum. Z. Anorg. Allg. Chem. 379 (1970) 234.54. M.T. Weller, D.R. Lines. /. Solid State Chem. 82 (1989) 21.55. A.M. Guloy, B.A. Scott, R.A. Figat. J. Solid State Chem. 113
(1994) 54.56. S.N. Ruddlesden, P. Popper. Acta Cryst. 10 (1957) 538.57. B. Aurivillius. Artiv For Kemi 1(54) (1949) 47.58. B. Aurivillius. Arkiv For Kemi 1(58) (1949) 499.
59. M.R. Palacín. "Estudi de perovskites mixtes de coure i titani. Inducció de
bidimensionaliíat per al desenvolupament de nous òxids superconductors" Treball derecerca del pla de doctorat de Ciència de Materials; Universitat Autònoma de Barcelona(Octubre 1993).
60. M.T. Anderson, K.R. Poeppelmeier. Chem. Mater. 3 (1991) 476.
61. X.Z. Zhou, M. Raudsepp, Q.A. Pankhurst, A.H. Morrish, Y.L. Luo, I. Maartense. Phys.Rev. B 36 (1987) 7230.
62. T. Siegrist, L.F. Schneemeyer, J.V. Waszczak, N.P. Singh, R.L. Opila, B. Batlogg, L.W.Rupp, D.W. Murphy. Phys. Rev. B 36(16) (1987) 8365.
63. Y. Maeno, T. Nojima, Y. Aoki, M. Kato, K. Hoshino, A. Minami, T. Fujita. Jpn. J. Appl.
Phys. 26 (1987) L774.64. D. Shindo, K. Hiraga, M. Hirabayashi, A. Tokiwa, M. Kikuchi, Y. Syono, O. Nakatsu,
N. Kobayashi, Y. Muto, E. Aoyagi. Jpn. J. Appl. Phys. 26 (1987) L1667.
65. X. Zhang, S. Labroo, P. Hill, N. Ali, E. Funk, J.R. Grains. Phys. Lett. A 130 (1988) 311.
•281
BIBLIOGRAFIA
66. H. Adrian, S. Neilsen. Europhys. Lett. 5 (1988) 265.
67. Y. Zhao, H. Zhang, S. Shu, Z. Su, Z. Chen, Q. Zhang. Solid St. Commun. 67 (1988) 31.
68. R. Aoki, S. Takahashi, H. Murakami, T. Nakamura, Y. Tagaki, R. Liang. Physica C 156
(1988) 405.
69. P.P. Miceli, J.M. Tarascón, L.H. Greene, P. Barboux, F.J. Rotella, J.D. Jorgensen. Phys.
Rev. B 37(10) (1988) 5932.
70. J.M. Tarascón, P. Barboux, P.F. Miceli, L.H. Greene, G.W. Hull, M. Eibschutz, S.A.
Sunshine. Phys. Rev. B 37(13) (1988) 7458.
71. B. Jayaram, S.K. Agarwal, C.V.N Rao, A.V. Narlikar. Phys Rev. B 38 (1988) 2904.
72. R.F. Jardim, S. Gama, O.P. de Lima, I. Torriani. Phys. Rev. B 38 (1988) 4580.
73. M.G. Smith, J. Zhang, H. Oesterreicher. Mater. Res. Bull. 23 (1988) 4580.
74. S.X. Dou, A.J. Bourdillon, X.Y. Sun, J.P. Zhou, H.K. Liu, N. Savvides, D. Haneman,
C.C. Sorrell, K.E. Easterling. /. Phys. C: Solid St. Phys. 21 (1988) L127.
75. R. Jones, P.P. Edwards, M.R. Harrison, T. Thanyasiri, E. Sinn. /. Am. Chem. Soc. 110
(20) (1988) 6719.
76. R. Xu, Y. Ping. /. Mater. Sei. Lett. 8 (1989) 1461.
77. N. Murayama, E. Sudo, K. Kani, A. Tsuzuki, S. Kawakami, M. Awano, Y. Torii. Jpn.
J. Appl. Phys. 27(9) (1988) L1623.
78. M.J. Rey, P. Dehaudt, J. Joubert, A.W. Hewat. Physica C 167 (1990) 162.
79. C. Greaves, P.R. Slater. Physica C 161 (1989) 245.
80. A. Ichinoise, T. Wada, H. Yamauchi, S. Tanaka. /. Ceram. Soc. Jpn. Inter. Ed. 97 (1989)
1053.
81. C. Greaves, P.R. Slater. IEEE Transactions on Magnetics 27(2) (1991) 1174.
82. C.E. Hamrin Jr., W.D. Arnett, R.J. De Angelis, X.X. Ding, W.D. Ehmann. Sol. State
Cow. 69(11) (1989) 1063-6.
83. J.M. Longo, P.M. Raccah. /. Solid State Chem. 6 (1973) 526.
84. A. Kareiva, M. Karppinen, L. Niinistö. J. Mater. Chem. 4(8) (1994) 1267.
85. N.N Greenwood, A. Eamshaw. "Chemistry of the Elements" Pergamon Press, oxford
1989 cap. 14
86. I.M. Kolthoff, H. Menzel. "Volumetric Analysis" Ed. John Wiley and Sons, London
(1929) vol II, cap. XII.
87. A.I. Nazzal, V.Y. Lee, E.M. Engler, R.D. Jacowitz, Y. Tokura, J.B. Torrance. Physica
C 152-155 (1988) 1367.
282-
BIBLIOGRAFIA
88. J. Rodríguez-Carvajal. PROGRAM FULLPROF (Version 2.4.2-Dec 93-
ILLJRQ(unpublished).
89. J. Laugier, A. Filhol. CELREF (Affinement des paramètres de maille a partir des angles
de Bragg observés)(Version Octobre 1978).
90. V. Primo. DRXWIN (Versió Lib, Febrer 1995, Departament de Química Inorgànica,
Universitat de València).
91. P. Stadelmann. Ultramicroscopy 21 (1987) 131.
92. A.K. Cheetham, AJ. Skarnulis. Anal. Chem. 53 (1981) 1060.
93. A.K. Cheetham, D.M. Thomas. /. Solid State Chem. 71 (1987) 61.
94. S.J. Hibble, A.K. Cheetham, D.E. Cox. Inorg. Chem. 26 (1987) 2389.
95. A.K. Cheetham, A.M. Chippindale en "Chemistry of superconductor materials" Ed. T.A.
Vanderah. Noyes Publications. New Jersey 1992. cap 14.
96. S.J. Hibble, A.K. Cheetham, A.M. Chippindale, P. Day, J.A. Hriljac. Physica C 156
(1988) 604.
97.L.N. Mulay. en "Theory and Applications of Molecular Paramagnetism" (E.A Boudreaux,
L.N. Mulay éd.) John Wiley & Sons, New York (1976). Cap. 9.
98. L.J. Van der Pauw. Philips Res. Repts. 13 (1958) 1.
99. 22. N. Ramadass, J. Gopalakrishnan and M.V.C. Sastri. /. Inorg. Nucí. Chem. 40 (1977)
1453.
100. O.M. Parkash, D. Kumar, D.K. Gangopadhayay, D. Bahadur. Phys. Stat. Sol. A 96
(1986) K79.
101. R. Jones, W.R. McKinnon. SoLState Corn. 76(3) (1990) 397.
102. M.L. Rojas, L.G. Fierro. /. Solid State Chem. 89 (1990) 299.
103. M.R. Palacûi, J. Bassas, J. Rodríguez-Carvajal, P. Gómez-Romero. /. Mater. Chem.
3(11) (1993) 1171.
104. M.P. Attfield, P.D. Battle, S.K. Bollen, S.H. Kim, A.V. Powell, M. Workman. /. Solid
State Chem. 96 (1992) 344.
105. M.T. Anderson, V.E. Balbarin, D.A. Groenke, G.A. Bain, K.R. Poeppelmeier. J. Solid
State Chem. 103 (1993) 216.
106. S. Lamarti-Sefïan, P. Gravereau, F. Weill, B. Darriet, G. le Flem. CJl. Acad. Sei. Paris.
315 (H) (1992) 1661.
107. S. Sefian-Lamarti, F. Weill, B. Darriet, P.Gravereau, G. le Flem. /. Solid State Chem.
113(1994)398.
108. M. Arjomand, D.J. Machin. J. Chem. Soc. Dalton Trans. 11 (1975) 1061.
109. M. Machida, K. Yasuoka, K. Eguchi, H. Arai. J. Solid State Chem. 91 (1991) 176.
•283
BIBLIOGRAFIA
110. W. Wingmei, S. Qiang, H. Gang, R. Yufang, W. Hongyiang. /. Sòlid State Ghent. 110
(1994) 389.
111. S. Geller. /. Chemical Physics 24(6) (1956) 1236.
112. M.R. Palacín, J. Bassas, J. Rodríguez-Carvajal, A. Fuertes, P. Gómez-Romero. Mat. Res.
Bull. 29 (9) (1994) 973.
113. P. Gómez-Romero, M.R. Palacín, N. Casañ-Pastor, A. Fuertes, B. Martínez. Sòlid State
Iònics 63-65 (1993) 603.
114. N. Casan-Pastor, P. Gómez-Romero, A. Fuertes, M.R. Palacín, J.M. Navarro, M. Brossa
en "Superconductivity in Spain" Programa MIDAS, Madrid; (1993) 87.
115. K. Sreedhar, P. Ganguly. Inorg. Chem. 27 (1988) 2261-9.
116. M.R. Palacín, A. Fuertes, N. Casan-Pastor, P. Gómez-Romero. "Materials Science
Forum" Trans Tech Publications, Switzerland; 152-153 (1994) 293.
117. M. Bennahmias, J.C. O'Brien, H.B. Radousky, TJ. Goodwin, P. Klavins, J.M. Link,
C.A. Smith, R.N. Shelton. Phys. Rev. B 46(18) (1992) 11986.
118. H.W. Zandbergen, RJ. Cava, J.J. Krajewski, W.F. Peck Jr. /. Solid State Chem. 101
(1992) 322.
119. N. Rosov, J.W. Lynn, H.B. Radousky, M. Bennahmias, TJ. Goodwin, P. Klavins, R.N.
Shelton. Phys. Rev. B 47(22) (1993) 15256.
120.1. Feiner, U. Asaf, D. Hechel, U. Yaron, T. Kröner. Physica C 214 (1993) 169.
121. H. Jhans, S.K. Malik, R. Vijayaraghavan. Physica C 215 (1993) 181.
122. H.D. Yang, H.L. Say. Physica C 219 (1994) 241.
123. H. Michor, M. Vybornov, T. Holubar, W. Perthold, G. Schaudy, G. Hilscher, P. Rogl.
Physica C 226 (1994) 1.
124. G. Hilscher, T. Holubar, H. Michor, W. Perthold, G. Schaudy, M. Vybornov, P. Rogl.
Physica C 235-240 (1994) 873.
125. B. Hellebrand, X.Z. Wang, P.L. Steger. /. Solid State Chem. 110 (1994) 32.
126. T.A. Mary, U.V. Varadaraju. Physica C 215 (1993) 269.
127. L.F. Mattheiss. Phys. Rev. B 45(5) (1992) 2442.
128. M.T. Anderson, K.R. Poeppelmeier, J.P. Zhang, HJ. Fan, L.D. Marks. Chem. Mater.
4 (1992) 1305.
129. WJ. Zhu, Y.Z. Huang, T.S. Ning, Z.X. Zhao. Mat. Res. Bull. 30(2) 1995 243.
130. J.B. Goodenough, J.A. Kafalas, J.M. Longo en "Preparative Methods in Solid State
Chemistry" Ed. P. Hagenmiiller. Academic Press, New York (1972). Cap 1.
284-
BIBLIOGRAFIA
131. J.B. Goodenough, N.F. Mott, M. Pouchard, G. Demazeau, P. Hagenmuller. Mat, Res.
Bull. 8(1973)647.
132. G. Demazeau. "High Pressure Chemical Synthesis" Ed. J. Jurczak, B. Baranowski.
Elsevier Science Publishers, New York (1989). Cap. 5.
133. Z. Hiroi, M. Takano. Physica C 235-240 (1994) 29.
134. M.R. Palacín, A. Fuertes, N. Casañ-Pastor, P. Gómez-Romero. /. Solid State Chem. in
press.
135. A. Maeda, T. Noda, H. Matsumoto, T. Wada, M. Izumi, T. Yabe, K. Uchinokura, S.
Tanaka. /. Appl. Phys. 64(8) (1988) 4095.
136. T. Wada, N. Suzuki, A. Maeda, T. Yabei, K. Uchinokura, S. Uchida, S. Tanaka. Phys.
Rev. B 39(13) (1989) 9126.
137. W.I.F. David, W.T.A. Harrison, R.M. Ibberson, M.T. Weller, J.R. Grasmeder, P.
Lanchester. Nature 328 (1987) 328.
138. L. Ganapathi, A.K. Ganguly, R.A. Mohan Ram, C.N.R. Rao. /. Solid State Chem. 73
(1988) 593.
139. H. Snaked, B.W. Veal, J. Faber Jr., R.L. Hitterman, U. Balachandran, G. Tomlins, H.
Shi, L. Morss, A.P. Paulikas. Phys. Rev. B 41(7) (1990) 4173.
140. S. Jin, J.E. Graebner. Mat. Sei. and Eng. B l (1991) 243.
141. T. Den, T. Kobayashi. Physica C 196 (1992) 141-52.
142. S.J. Wuu, D.H. Chen, T.W. Liu, C.H. Cheng, C.T. Chang, S.R. Sheen, M.K. Wu.
Physica C 226 (1994) 37-42.
143. B. Okai. Jpn. J. Appl. Phys. 29 (1990) L2180.
144. J.M. Tarascón, B.G. Bagley en "Chemistry of Superconductor Materials" Ed. by T.A.
Vanderah, Noyes Publications, New Jersey (1992), cap 8.
145. S.A. Sunshine, L.F. Schneemeyer, T. Siegrist, D.C. Douglas, J.V. Waszczak, R.J. Cava,
E.M. Gyorgy, D.W. Murphy. Chem. Mater. 1 (1989) 331.
146. P.R. Slater, C. Greaves. Physica C 180 (1991) 299.
147. Q. Xiong, Y.Q. Wang, J.W. Chu, Y.Y. Sun, K. Matsuishi, H.H. Feng, P.H. Hör, C.W.
Chu. Physica C 198 (1992) 70.
148. M. Pissas, G. Kallias, E. Moraitakis, D. Niarchos, A. Simopoulos. Physica C 234 (1994)
127.
149. M. Pissas, G. Kallias, A. Simopoulos, D. Niarchos, A. Kostikas. Phys. Rev. B 46(21)
(1992) 14119.
150. S.F. Hu, R.S. Liu, S.C. Su, D.S. Shy, D.A. Jefferson. J. Solid State Chem. 112 (1994)
203.
•285
BIBLIOGRAFIA
151. J.Q. Li, W J. Zhu, Z.X. Zhao, D.L. Yin. Solid State Commun, 85(9) (1993) 739.
152. P.R. Slater, C. Greaves, M. Slaski, E.Z. Kurmaev, S. Uhlenbrock, M. Neumann. Physica
C 231 (1994) 109.
153. S. Adachi, S. Takano, H. Yamauchi. Physica C 196 (1992) 125.
154. Q. Huang, S.A. Sunshine, R.J. Cava, A. Santoro. /. Sòlid State Chem. 102 (1993) 534.
155. G. Roth, P. Adelmann, G. Heger, R. Knitter, Th. Wolf. /. Phys I France l (1991) 721.
156. T.A. Mary, N.R.S. Kumar, U.V. Varadaraju. /. Solid State Chem. 107 (1993) 524.
157. T. Krekels, O. Milat, G. Van Tendeloo, S. Amelinckx, T.G.N. Babu, AJ. Wright, C.
Greaves. /. Solid State Chem. 105 (1993) 313.
158. J.T. Vaughey, J.P. Thiel, E.F. Hasty, D.A. Groenke, C.L. Stern, K.R. Poeppelmeier, B.
Dabrowski, D.G. Hinks, A.W. Mitchell. Chem. Mater. 3 (1991) 935.
159. Q. Huang, R.J. Cava, A. Santoro, JJ. Krajewski, W.F. Peck. Physica C 193 (1992) 196.
160. T.G.N. Babu, J.D. Kilgour, P.R. Slater, C. Greaves. /. Solid State Chem. 103 (1993)
472.
161. AJ. Wright, C. Greaves. Physica C 235-240 (1994) 885.
162. M.T. Anderson, K.R. Poeppelmeier. Chem. Mater. 3 (1991) 476.
163. M.T. Anderson, K.R. Poeppelmeier, S.A. Gramsch, J.K. Burdett. /. Solid State Chem.
102 (1993) 164.
164. M.R. Palacín, A. Fuertes, N. Casañ-Pastor, P. Gomez-Romero. Adv. Mater. 6(1) 54
(1994).
165. M.R. Palacín, F. Krumeich, M.T. Caldes, P.Gómez-Romero. /. Solid State Chem. 117
(1995) 213.
166. P. Gómez-Romero, M.R. Palacín, J. Rodríguez-Carvajal. Chem. Mater. 6 (1994)
2618A. Gormezano, M.T. Weller. J. Mater. Chem. 3(7) (1993) 771.
168. A. Gormezano, M.T. Weller. /. Mater. Chem. 3(9) (1993) 979.
169. K.B. Greenwood, G.M. Sarjeant, K.R. Poeppelmeier, P.A. Salvador, T.O. Mason, B.
Dabrowski, K. Rogacki, Z. Chen. Chem. Mater, l (1995) 1355.
170. A. Fukuoka, S. Adachi, T. Sugano, XJ. Wu, H. Yamauchi. Physica C 231 (1994) 372.
171. L. Rukang. /. Mater. Chem. 4(5) (1994) 773.
172. L. Rukang. J. Solid State Chem. 114 (1995) 57.
173. T. Itoh, H. Uchikawa en "Studies of High Temperature Superconductors" (Ed. Anant
Narlikar) Nova Science Publishers. New York (1990). Vol 5, cap. 8.
174. Y.D. Tretyakov, A.R. Kaul, N.V. Makukhin. /. Solid State Chem. 17 (1976) 183.
175. W. Wong-ng, B. Paretzkin, E.R. Fuller Jr. /. Solid State Chem. 85 (1990) 117.
286-
BIBLIOGRAFIA
176. W. Wong-Ng. Pow. Diff. 7(3) (1992) 125.
177. P. Karen, O. Braaten, A. Kjekshus. Acta. Chem. Scand. (1992) 805.
178. E. Takayama-Muromachi, A. Navrotsky. /. Sòlid State Chem. 106 (1993) 349.
179. RJ. Cava, T. Siegrist, B. Hessen, JJ. Krajewski, W.F. Peck Jr., B. Batlogg, H. Takagi,
J. V. Waszczak, L.F. Schneemeyer, H.W. Zandbergen. /. Sòlid State Chem. 94 (1991)
170.
180. SJ. La Placa, J.F. Bringley, B.A. Scott, D.E. Cox. Acta Cryst. C 49 (1993) 1415.
181. J.M.S. Skakle, A.R. West. /. Am. Ceram, Soc. 77(8) (1994) 2199.
182. J.M.S. Skakle, A.R. West /. Mat. Chem. 5(5) (1995) 765.
183. T. Mathews, K.T. Jacob. /. Mater. Res. 8(12) (1993) 3015.
184. M.R. Palacín et al. (manuscrit en preparació).
185. J. Livage, M. Henry, C. Sanchez. Prog. Solid State Chem. 18 (1988) 259.
186. G.R. Lee, J.A. Crayston. Adv. Mater. 5(6) (1993) 434.
187. J. Livage en "Soft Chemistry Routes to New Materials" (Ed. J. Rouxel, M. Tournoux,
R. Bree) Trans Tech Publications. Switzerland (1994) p. 43.
188. S. Barboux-Doeuff, C. Sanchez. Mat. Res. Bull. 29 (1994) 1.
189. G. Pfaff. Chem. Mater. 6 (1994) 58.
190. F. Celani. // Nuovo Saggiatore 4 (1988) 7.
191. Y. Zhang, G.G. Stangle. J. Mater. Res. 9(8) (1994) 1997.
192. Y. Wu, Z. Yu, S. Liu. J. Solid State Chem. 112 (1994) 157.
193. W.Mingmei, S. Qiang, H. Gang, R. Yufang, W. Hongyiang. /. Solid State Chem. 110
(1994) 389.
194. H.S. Horowitz, SJ. McLain, A.W. Sleight, J.D. Druliner, P.L. Gai, M.J. Van Kavelaar,
J.L. Wagner, B.D. Biggs, SJ. Poon. Science 243 (1989) 66.
195. S.H. Sieh, WJ. Thomson. Physica C 204 (1992) 135.
196. P. Barboux en "Chemistry of Superconductor Materials" (Ed. T.A. Vanderah) Noyes
Publications. New Jersey (1992). Cap 7.
197. T. Moeller en "Comprehensive Inorganic Chemistry". Pergamon Press, Oxford (1973)
Vol. 4 Cap 44.
198. L.F. Schneemeyer, J.V. Waszczak, S.M. Zahorak, R.B. van Dover, T. Siegrist. Mat. Res.
Bull. 22 (1987) 1467.
199. C.R. Fincher Jr, G.B. Blanchet. Phys. Rev. Lett. 67(20) (1991) 2902.
200. M. Rajendran, M. Subba Rao. /. Solid State Chem. 113 (1994) 239.
201. J.H. Choy, Y.S. Han, J.T. Kim, Y.H. Kim. /. Mater. Chem. 5(1) (1995) 57.
202. J.L. Tallón, B.E. Mellander. Science 258 (1992) 781.
•287
BIBLIOGRAFIA
203. M.A. Alano-Franco, MJ.R. Henche, M. Vailet, J.M.G. Calbet, J.C. Grenier, A.
Wattiaux, P. Hagenmuller. /. Solid State Chem. 46 (1983) 23.
204. E. Garcia-Gonzalez, M. Parras, J.M. González-Calbet, M. Vallet-Regi. /. Solid State
Chem. 104 232 (1993).
205. E. Garcia-Gonzalez, M. Parras, J.M. González-Calbet, M. Vallet-Regí. J. Solid State
Chem. 105 363 (1993).
206. C.P. Poole Jr., T. Datta, H.A. Farach. "Copper Oxide Superconductors" Wiley-
Interscience Pub., New York (1988). Cap VI.
207. J.E. Sunstrom IV, S.M. Kauzlarich, P. Klavins. Chem. Mater. 4(2) 346 (1992).
208. C. Eylem, G. Sàghi-Szabó, B.H. Chen, B. Eichhorn, J.L. Peng, R. Greene, L.
Salamanca-Riba, S. Nahm. Chem. Mater. 4(5) 1038 (1992).
209. J.E. Sunstrom IV, S.M. Kauzlarich. Chem. Mater. 5(10) 1539 (1993).
210. R.D. Shannon. Âcta Cryst. A 32 751 (1976).
211. M.A. Alano-Franco, J.M. Gonzalez-Calbet, M. Vallet-Regi, J.C. Grenier. /. Solid State
Chem. 49 (1983) 219.
212. M. Vallet-Regi, J.M. Gonzalez-Calbet, J. Verde, M.A. Alario-Franco. /. Solid State
Chem. 57 (1985) 197.
213. J.M. Gonzalez-Calbet, M. Vallet-Regi, M.A. Alario-Franco. /. Solid State Chem. 60
(1985) 320.
214. M. Hervieu, B. Domenges, C. Michel, G. Heger, J. Provost, B. Raveau. Phys. Rev. B
36(7) (1987) 3920.
215. J.M. Gonzalez-Calbet, M. Parras, M. Vallet-Regi, J.C. Grenier. J. Solid State Chem. 86
(1990) 149.
216. E. Garcia-Gonzalez "Orden-Desorden en el sistema TR-Ba-Cu-Fe-O (TR=Y, Ln)" Tesi
doctoral, Universidad Complutense de Madrid (1992).
217. O. Milat, T. Krekels, S. Amelinckx, C. Greaves, A.J. Wright. Physica C 217 (1993)
444.
218. M. Hervieu, C. Michel, B. Raveau. Chem. Mater. 5 (1993) 1126.
219. L. Barbey, B. Domengès, N. Nguyen, B. Raveau. /. Solid State Chem. 111 (1994) 238.
220. M.R. Palacín et al. (manuscrit en preparació).
221. CU. Segre, B. Dabrowski, D.G. Hinks, K. Zhang, J.D. Jorgensen, M.A. Beño, I.K.
Schuller. Nature 329 (1987) 227.
222. M. Izumi, T. Yate, T. Wada, A. Maeda, K. Uchinokura, S. Tanaka, H. Asano. Phys.
Rev. 540(10) (1989)6771.
288-
BIBLIOGRAFIA
223. M. Guillaume, P. Allenspach, J. Mesot, B. Roessli, U. Staub, P. Fischer, A. Furrer. Z.
Phys. B 90 (1993) 13.
224. M. Guillaume, P. Allenspach, W. Henggeler, J. Mesot, B. Roessli, U. Staub, P. Fischer,
A. Furrer, V. Trounov. /. Phys. Condens. Matter 6 (1994) 7963.
225. R.A. Jennings, C. Greaves. Physica C 235-240 (1994) 989.
226. A.M. Glazer. Acta Cryst. B 28 (1972) 3384.
227. A.M. Glazer. Acta Cryst. A 31 (1975) 756.
228. M. O'Keefe, B.C. Hyde. Acta Cryst. B 33 (1977) 3802.
229. K.S. Aleksandrov. Ferroelectrics 14 (1976) 801.
230. H.D. Megaw. /. Phys. Radium. 33 (1972) C2-1.
231. R. Deblieck, G. Van Tendeloo, J. Van Landuyt, S. Amelinckx. Acta Cryst. B 41 (1985)
319.
232. G. Burns, A.M. Glazer. "Space Groups for Solid State Scientists" 2nd. ed. Academic
Press Inc. San Diego (1990). App. 9.
233. K.S. Aleksandrov, J. Bartolomé. /. Phys.: Condens. Matter 6 (1994) 8219.
234. H. Unoki, T. Sakudo. /. Phys. Soc. Japan 23(3) (1967) 546.
235. V.J. Minkiewicz, Y. Fujii, Y. Yamada. /. Phys. Soc. Japan 28(2) (1970) 443.
236. A. Bulou, J. Nouet. /. Phys. C: Solid State Phys. 15 (1982) 183.
237. T.J. Kistenmacher. Solid State Comm. 65(9) (1988) 981.
238. A.V. Narlikar, C.V. Narashima Rao, S.K. Agarwal en "Studies of High Temperature
Superconductors" Ed. by A. Narlikar, Nova Science Publishers, New York (1989). Vol
1, cap. 15.
239. M.H. Whangbo, C.C. Torardi. Ace. Chem. Res. 24(6) (1991) 127.
240. M.R. Palacín et al. (manuscrit en preparació).
241. B. Domenges, M. Hervieu, C. Michel, B.Raveau. Europhys. Lett. 4(2) (1987) 211.
242. M. Hervieu, C. Michel, B. Raveau en "Studies of High Temperature Superconductors"
Ed. by A. Narlikar, Nova Science Publishers, New York (1989). Vol 3, cap. 2.
243. H.W. Zandbergen, R.J. Cava, J.J. Krajewski, W.F. Peck Jr. Physica C 192 (1992) 223.
244. M.R. Palacín et al. (manuscrit en preparació).
245. A.T. Casey, S. Mitra en "Theory and Applications of Molecular Paramagnetism" (E.A
Boudreaux, L.N. Mulay ed.) John Wiley & Sons, New York (1976). Cap. 5.
246. R.P. Gupta, M. Gupta. Physica C 162-164 (1989) 1437.
247. C.N.R. Raó, J. Gopalakrishnan, A.K. Santra, V. Manivannan. Physica C 174 (1991) 11.
248. J.G. Bednorz, M. Takashige, K.A. Muller. Europhys. Lett. 3 (1987) 379.
249. R.J. Cava, R.J. Van Dover, B. Batlogg, E.A. Rietman. Phys. Rev. Lett. 58 (1987) 408.
•289
BIBLIOGRAFIA
250. J.M. Tarascón, L.H. Green, W.R. McKinnon, G.W. Hull, T.H. Geballe. Science 235
(1987) 1373.
251. C.N.R. Rao, P. Ganguly. Curr. Sei. 56 (1987) 47.
252. Beille, R. Cabanel, B. Chevalier, C. Chaillout, G. Demazeau, F. Deslandes, J.
Etourneau, P. Lejay, C. Michel, J. Provost, A. Sulpice, J.L. Tholence, R. Tournier. C./?.
Acad. Sei. 304(11) (1987) 1097.
253. Y. Tokura, H. Tagatí, S. Uchida. Nature 337 (1989) 345.
254. R.J. Cava, B. Batlogg, J.J. Krajewski, R. Farrow, L.W. Rupp Jr., A.E. White, K. Short,
W.F. Peck, T. Kometani. Nature 332 (1988) 814.
255. M. Dion, M. Ganne, M. Tournoux. Mat. Res. Bull. 16 (1981) 1429.
256. J. Gopalakrishnan, V. BhaL Mat. Res. Bull. 22 (1987) 413.
257. R.A. Mohan-Ram, A. Clearfield. /. Sòlid State Chem. 94 (1991) 45.
258. J. Gopalakrishnan, S. Uma, V. Bhat Chem. Mater. 5 (1993) 132.
259. D. Nicholls en "Comprehensive Inorganic Chemistry". Pergamon Press, Oxford (1973)
Vol. 3 Cap 41.
260. A. Gormezano, M.T. Weller. Physica C 235-240 (1994) 999.
261. S. Ondoño. "Recubrimientos de YBa2Cu3O7.s sobre substratos metálicos en forma de
hilo mediante electrodeposición y electroforesis" Treball de recerca del pla de doctorat
de Ciència de Materials; Universitat Autònoma de Barcelona (Octubre 1994).
262. AJ. Jacobson, B.C. Tofield, B.E.P. Fender. Acta Cryst. B 28 (1972) 956.
263. J.M. Tarascón, W.R. McKinnon, L.H. Greene, G.W. Hull, E.M. Vogel. Phys. Rev. B
36(1) (1987) 226.
264. Y.K. Tao, J.S. Swinnea, A. Manthiram, J.S. Kim, J.B. Goodenough, H. Steinfink. J.
Mater. Res. 3(2) (1988) 248.
265. M.S. Hedge, K.M. Satyalakshmi, S. Ramesh, N.Y. Vasanthacharya, J. Gopalakrishnan.
Mat. Res. Bull. 27 (1992) 1099.
266. A. Santoro en "Chemistry of Superconductor Materials" Ed. by T.A. Vanderah, Noyes
Publications, New Jersey (1992), cap 3.
267. J.B. Goodenough en "Electron Transfer in Biology and the Solid State" Ed. By M.K.
Johnson, R. Bruceking, D.M. Kurtz Jr., C. Kitel, M.L. Norton, R.A. Scott. Adv.
Chemistry Series 226 ACS WDC (1990) cap 16.
268. D.V. Formichev, O.G. D'yachenko, A.V. Mironov, E.V. Antipov. Physica C 225 (1994)
25.
290-
BIBLIOGRAFIA
269. A.T. Casey, S. Mitra en "Theory and Applications of Molecular Paramagnetism" (E.A
Boudreaux, L.N. Mulay ed.) John Wiley & Sons, New York (1976). Cap3.
270. J.L. Routbort, S.J. Rothman. /. Appl. Phys. 76(10) (1994) 5615.
271. L.F. Schneemeyer, J.V. Waszczak, T. Siegrist, R.B. van Dover, L.W. Rupp, B. Battlog,
R.J. Cava, D.W. Murphy. Nature 328 (1987) 601.
272. R.J. Cava, B. Batíogg, C.H. Chen, E.A. Rietman, S.M. Zahurak, D. Werder. Nature 329
(1987) 423.
273. A.T. Fiory, S. Martin, L.F. Schneemeyer, R.M. Fleming, A.B. White, J.V. Waszczak.
Phys. Rev. B 38 (1988) 7129.
274. T. Penney, S. von Molnar, D. Kaiser, F. Holtzberg, A.W. Kleinsasser. Phys. Rev. B 38
(1988) 2918.
275. G. Ottaviani, C. Nobili, F. Nava, M. Affronte, T. Manfredini, F.C. Matacotta, E. Galli.
Phys. Rev. B 39(13) (1989) 9069.
276. M. Tetenbaum, B. Tani, C. Czech, M. Blander. Physica C 158 (1989) 377.
277. Z. Zhou, A. Navrotsky. /. Mater. Res. 8(12) (1993) 3023.
278. J.M.S. Skakle, A.R. West. /. Mater. Chem. 4(11) (1994) 1745.
279. K. Kishio, T. Hasegawa, K. Suzuki, K. Kitazawa i K. Fueki. Mat. Res. Soc. Symp. Proc.
156 (1989) 91.
280. R.J. Cava, B. Batlogg, R.B. van Dover, J.J. Krajewski, J.V. Waszczak, R.M. Fleming,
W.F. Peck Jr., L.W. Rupp Jr., P. Marsh, A.C.W.P. James, L.F. Schneemeyer. Nature
345 (1990) 602.
281. R.J. Cava, J.J. Krajewski, H. Tagaki, H.W. Zandbergen, R.B. Van Dover, W.F. Peck Jr.,
B. Hessen. Physica C 191 (1992) 237.
282. J.C. Grenier, A. Wattiaux, J.P. Doumerc, P. Dordor, L. Fournes, J.P. Chaminade, M.
Pouchard. /. Solid State Chem. 96 (1992) 20.
283. F.C. Chou, J.H. Cho, D.C. Johnston. Physica C 197 (1992) 303.
284. A. Demourgues, A. Wattiaux, J.C. Grenier, M. Pouchard, J.L. Soubeyroux, J.M. Dance,
P. Hagenmuller. /. Solid State Chem. 105 (1993) 458.
285. J.P. Locquet, C. Gerber, A. Cretton, Y. Jaccard, E. Williams, E. Mächler. Appl. Phys.
A 57 (1993)211.
286. F.C. Chou, D.C. Johnston, S.W. Cheong, P.C. Canfield. Physica C 216 (1993) 66.
287. N. Casañ-Pastor, P. Gómez-Romero, A. Fuertes, J.M. Navarro. Solid State Ionics 63-65
(1993) 938.
288. N. Casañ-Pastor, P. Gómez-Romero, A. Fuertes, J.M. Navarro, M.J. Sanchis, S. Ondoño.
Physica C 216 (1993) 478.
•291
BIBLIOGRAFIA
289. S. Ondoño-Castillo, C.R. Michel, A. Seffar, J. Fontcuberta, N. Casañ-Pastor. Physica
C 235-240 (1994) 563.
290. C.R. Michel. "Dopaje y preparación de nuevos óxidos cerámicos mediante métodos
electroquímicos" Trabajo de investigación del plan de doctorado en Ciencia de
Materiales; Universitat Autònoma de Barcelona (Septiembre 1995).
291. L. Katz, R. Ward. Inorg. Chem. 3(2) (1964) 205.
292. R.D. Rosenstein, R. Schor. /. Chem. Phys. l (1963) 1789.
293. X.W. Zhang, Q. Wong. /. Am. Ceram. Soc. 74(11) (1991) 2846.
294. D. Reinen, H. Weitzel. Z. anorg. allg. Chem. 424 (1976) 31.
295. M.D. Marcos, J.P. Attfíeld. J. Mater. Chem. 4(3) (1994) 475.
296. W.A. Groen, F.P.F. van Berkel, DJ.W. Ijdo. Acta Cryst. C 42 (1986) 1472.
297. T.C. Gibb, P.D. Battle, S.K. Bollen, RJ. Whitehead. J. Mater. Chem. 2(1) (1992) 111.
298. A.V. Powell, J.G. Gore, P.D. Battle. /. Alloys and Compounds 201 (1993) 73.
299. R.C. Currie, J.F. Vente, E. Frikkee, D.J.W. Ijdo. /. Solid State Chem. 116 (1995) 199.
300. M.P. Attfíeld, P.d. Battle, S.K. Bollen, T.C. Gibb, RJ. Whitehead. J. Solid State Chem.
100 (1992) 37.
301. J.H. Choy, J.H. Park, S.T. Hong, O.K. Kim. /. Solid State Chem. Ill (1994) 370.
302. I. Alvarez, M.L. López, C. Gonzalez, A. Jerez, M.L. Veiga, C. Pico. Solid State Ionics
63-65 (1993) 609.
303. M.L. López, M.L. Veiga, J. Rodríguez-Carvajal, F. Fernández, A. Jerez, C. Pico. Mat.
Res. Bull. 27 (1992) 647.
304. R. Rodríguez, A. Fernández, A. Isalgué, J. Rodríguez, A. Labarta, J. Tejada, X.
Obradors. J. Phys. C: Sòlid State Phys. 18 (1985) L401.
305. T. Sekiya, T. Yamamoto, Y. Torii. Bull. Chem. Soc. Jpn. 57 (1984) 1859.
306. R.A. Beyerlein, A.J. Jacobson, K.R. Poeppelmeier. J. Chem. Soc. Chem. Commun.
(1988) 225.
307. P. Woodward, R.D. Hoffmann, A.W. Sleight. /. Mater. Res. 9(8) (1994) 2118.
308. M.A. Alario-Franco, I.E. Grey, J.C. Joubert, H. Vincent, M. Labeau. Acta Cryst. A 38
(1982) 177.
309. E. Garcia-Gonzalez, M. Parras, J.M. González-Calbet, M. Vallet-Regí. /. Solid State
Chem. 110 142 (1994).
310. K. Vidyasagar, A. Relier, J. Gopalakrishnan, C.N.R. Rao. /. Chem. Soc. Chem.
Commun. (1985) 7.
311. A.A. Colville. Acta Cryst. B 26 (1970) 1469.
292-
BIBLIOGRAFIA
312. A.A. Colville, S. Geller. Acta Cryst. B 27 (1971) 2311.
313. J. González-Calbet, M. Vallet-Regí. /. Sòlid State Chem. 68 (1987) 266.
314. K.R. Poeppelmeier, M.E. Leonowicz, J.M. Longo. /. Solid State Chem. 44 (1982) 89.
315. C. Michel, L. Er-Rakho, B. Raveau. Mat. Res. Bull. 20 (1985) 667.
316. C. Michel, L. Er-Rakho, M. Hervieu, J. Pannetier, B. Raveau. /. Solid State Chem. 68
(1987) 143.
317. L. Er-Rakho, C. Michel, B.Raveau. /. Solid State Chem. 73 (1988) 514.
318. H. Fujishita, M. Sera, M. Sato. Physica C 175 (1991) 165.
319. W.T. Fu, DJ.W. Ijdo, R.B. HelmholdL Mat. Res. Bull. 27 (1992) 287.
320. K. Otzschi, Y. Ueda. /. Solid State Chem. 107 (1993) 149.
321. RJ. Cava, H.W. Zandbergen, R.B. Van Dover, JJ. Krajewski, T. Siegrist, W.F. Peck
Jr., R.S. Roth, RJ. Felder. J. Solid State Chem. 109 (1994) 345.
322. N. Rangavital, G.N. Subbanna, T.N. Guru Row, C.N.R. Rao. /. Solid State Chem. 114
(1995) 95.
323. K. Otzschi, K. Koga, Y. Ueda. /. Solid State Chem. 115 (1995) 490.
324. SJ. La Placa, J.F. Bringley, B.A. Scott, D.E. Cox. /. Solid State Chem. 118 (1995) 170.
325. J.H. Clark en "Comprehensive Inorganic Chemistry". Pergamon Press, Oxford (1973)
Vol. 3 Cap 34.
326. A.R. Armstrong, W.I.F. David. Chem. in Britain Sept. (1994) 727.
327. RE. Bonesteel. Phys. Rev. B 47(14) (1993) 9144.
328. B.Büchner, M. Breuer, A. Freimuth, A.P. Kampf. Phys. Rev. Lett. 73(13) (1994) 1841.
329. J.S. Choi, M. Sarikaya, I.A. Aksay, R. Kikuchi. Phys. Rev. B 42(7) (1990) 4244.
330. X. Zhang, C.R.A. Catlow. Phys. Rev. B 46(1) (1992) 457.
331. SJ. Rothman, J.L. Routbort, U. Welp, I.E. Baker. Phys. Rev. B 44(5) (1991) 2326.
332. M.S. Islam, R.C. Baetzold. /. Mater. Chem. 4(2) (1994) 299.
-293
APÈNDIX 1
APÈNDK l
DEFINICIÓ DELS FACTORS D'ACORD D'UN AFINAMENT(PROGRAMA FULLPROF)
En el programa FULLPROF (88) els factors d'acord d'un afinament a partir de dadesexperimentals es defineixen de la següent manera:
*,= 100 - (E IR^-K^O / E toJ
= 100- ^(E w to^-Hj1) / E w I»J2
on Yi representa el nombre de comptes per segon (c.p.s) de cada punt experimental mentre
que %2 i Re,,,«*«! són els paràmetres de bondat de l'ajust:
X2 =
i z w m j«
(N-P+C) és el nombre de graus de llibertat en realitzar l'afinament, on N és el nombre depunts experimentals, P el nombre de paràmetres afinats i C el nombre de restriccionsimposades en dur a terme l'afinament
-297
APÈNDIX 2
APÈNDK2
DADES ADDICIONALS SOBRE ELS AFINAMENTS RIETVELD REALITZATS
Hom presenta en aquest apèndix la sortida d'ordinador dels afinaments Rietveld
descrits en aquesta memòria. Aquests afinaments han estat realitzats amb el programa
FULLPROF (88), i les taules següents mostren les dades per a cada reflexió permesa. HW
representa l'amplada del pic, ETA/M és un paràmetre que ajusta la forma dels pics a una
combinació linial entre una corba Lorentziana i una Gaussiana, POSN indica la posició (26)
i ICALC i IOBS són les intensitats calculada i observada respectivament. Després de cada
taula de valors es mostra el difractograma observat com punts discrets i el calculat com una
línia que s'hi superposa; la línia base representa IOBS-ICALC (Yi^-Yi^) i les barres
verticals indiquen la posició de les reflexions de Bragg permeses pel grup espacial.
•301
APÈNDIX 2
La2CuTiO6 sint. 1400°C (AFINAMENT PER DIFRACCIÓ DE NEUTRONS)
Grup espacial: Pnma (lambda=1.3428A 20^=5°, step=0.1°, 29fm=75°)
H K L Mult ETA/M Iteth« lute lob« H K L Mult Hw ETA/M 2letha Icalc Iot»
010121022121020121202220132113
1
32102322132003113242042
10
2102010011322322041331302041124243004411353352204015
110
101201212102112202013
2123
1
1
310
3
22231223311312302400
442
•2«244488
444888428
48
4
8
48
4
8
8
8
8
48
4844888
•448
888828244
0.2810.2710.2710.2(40.2530.2530.2530.2520.2510.2510.2520.2520.2520.2540.2540.25«0.2590.2590.2««0.2«70.2700.2710.2810.2810.2820.2850.3860.2870.2880.2910.2930.3100.3130.3130.3140.3190.3240.3260.3270.3280.3320.3330.3350.33«0.3470.3500.3510.3550.35«0.36»0.3740.3740.3770.383
0.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.219
17.00619.53119.72521.90727.Í1S27.89827.89929.37831.01731.20832. «1132.79432.97434.16834.40235.8«!37.02837.19239.66040.06740.95941.05743.53243. «2943. «7544.38944. «70
44.7S544.94745.57845.94«49.01049.35549.35849.52950.37051.13951.35051.51551. «4152.21052.41*52.«««52.82854.3C754. «9154.84955.33«55.53«57.02357. «4757. «5058.02058.712
«.23.17.«4.70.
230.34.9.
94.135.17«.292.390.
14641255
130.187.117.
1305«79.99.
107.98.90.
101.15.1.
22.7.
241.«2.94.
164.421.119.
0.17.57.13.29.57.1«.5.
111.
95.
25.0.
49.8.
220.779.142.«2.7.
20.1C.25.58.75.
231.34.10.91.
135.18«.293.404.
145«.12 «5.167.233.138.
1296.712.104.108.105.93.
102.10.1.
21.5.
228.57.78.
162.417.122.
0.1«.57.14.29.«0.21.«.
131.10«.29.0.
«1.13.
223.801.14«.
SC.11.
414321214330103414321442
23241042203312140424431433502
0013315520424S122020«13154433S22í«355C«44330404115015
141234120314303142341204
22314324023131204243144342153
4488888844848288e4848848888
8a4884488888448
8484888844e
0.3850.3900.3940.3970.3990.3990.4000.4010.4030.4050.40«0.4080.4090.4110.4140.4200.4260.4380.4410.4430.4470.4480.4480.4520.4540.4610.4630.4670.4730.4750.4770.4810.4840.4860.4900.4910.4940.5040.5050.5180.5240.5270.5320.5370.5380.5390.5440.5470.5500.5530.5540.5540.555
0.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.2190.219
58.98759.56259.962«0.30360.49260.53260.64060.75460.94761.17461.321«1.54961.62161.84262.12962.83463.389C4.65564.94665.09265.52065.58165.65266.01566.22766.87567.055
67.467
68.001
68.176
68.32268.747«9.02469.16569.50569.64269.92370.79670.90171.96572.51972.78073.19473.57473.70873.81474.22374.44874.68774.88874.99574.99575.059
140.98.1.
133.199.103.299.105.
5.79.«.3.
38.«9.42.94.
136.17.19.3.
54.24.3.
23.116.
4.30.73.
140.
133.197.124.11«.90.
160.142.140.
2.0.
190.114.205.
62.10.«3.40.35.43.9«.4.1.0.
12.
154.108.
1.125.198.103.301.107.
«.78.£.3.
40.73.42.82.
103.8.
16.3.
55.25.4.
26.135.
5.31.67.
137.132.194.124.119.93.
166.147.154.
5.0.
205.121.192.58.10.64.41.35.39.83.4.0.0.
11.
302
APÊNDDC2
«oveene«uSo
_ - v»
. _ «o
JLV1ISN31NI
-303
APÊNDK2
LajCuTiO, sinL 675°C (AFINAMENT PER DIFRACCIÓ DE NEUTRONS)
Grup espacial: Pnma aambda=1.9845A 26^=1°, step=0.05°, 29^=160°)
H K L M«
0 1 11 0 10 21 10 02 01 22 11 02 01 12 10 30 22 21 3 11 2 22 2 12 0 20 4 02 1 22 3 00 1 31 3 22 3 11 0 33 0 12 2 21 4 11 1 33 1 11 2 33 2 10 4 22 4 02 3 22 0 3
itt Hw
0.«3CO.C3S0.«35O.C35O.C3»0.«3>O.C3»O.C42O.C45O.C4SO.C4»O.C4*0.««9O.CS3O.C53O.S5»O.CS30.««3O.C74O.C75O.S81O.C810.«950.«9SO.C9«0.7030.7030.7030.7040.7110.7120.7400.7400.7410.7410.7510.7Í1
ET A/M
0.7(00.7«00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(00.7(0
2t*«fca
25.18929.14«2». 22«32. «9541. «7441.70341.74744.37S4«.i754«.S»S4». 3254». 34449.43451.71051.73454.0515«. 200SC. 217C0.42C(O.(0((2.502«2. (01(C. 491««.599««.«14«•.454«*.494«8. 51«(•.(4170.40170.4417«. 11S7«. 1557«. 24«7«. 26571.04«79.793
leak
; ..,..
30.1.
12.4.
22.22.44.
188.22«.
5.12.
C.197.90.3.4.
15.9.
10.3.0.2.1.3.7.
33.11.1C.21.0.1.
Iot»
0.2.2.1.C.>.
30.1.
1C.C.
24.25.49.
li».22«.15.14.7.
191.•7.3.«.
12.7.8.2.0.1.0.3.8.
37.12.1*.23.0.1.
H K
3 01 42 42 13 10 30 51 33 31 52 23 20 04 02 44 12 51 04 01 14 12 33 31 S2 53 0
2244C1
1 24 22 04 03 2
L Mu
22132313113240200
221340310341423
It Hw
0.7C20.7620.7630.7730.7730.7740.7750.8000.800o.aoi0.8130.8130.8430.8440.8450.8SO0.8620.8770.8780.89«0.89«0.8970.8970.8990.8990.91«0.91«0.9170.9170.9180.9200.9370.9590.9601.0081.0091.009
ETA/M 2t*tlu
0.7SO 79.8170.760 79.95«0.760 79.9700.760 81.6400.760 81.6640.760 81.7100.760 81.88C0.760 85.3630.760 85.4010.7(0 85.5390.760 87.1390.760 87.1630.760 90.7030.760 90.7780.7SO 90.8960.760 92.6020.760 92.8080.760 94.3360.760 94.4070.760 96.1670.760 9«. 2380.760 9«. 2700.760 9«. 2930.7SO 9«. 4310.760 9«. 4450.760 98.0210.760 98.0220.760 98.098
0.760 98.159
0.760 99.1970.760 98.3760.760 99.8670.760 101.7070.760 101.7790.760 105.40«0.760 105.4640.760 105.47«
leak
2.3.1.4.C.0.9.3.1.0.1.4.
23.45.
121.3.0.7.4.
11.0.
30.8.7.
33.C.0.2.
5.
0.
8.1.
11.4.
1.
4.8.
lolM
3.3.1.S.7.0.
12.2.1.0.1.«.
25.48.
128.4.0.
11.«.
12.0.
33.9.7.
35.5.0.2.4.0.
7.1.
12.
5.1.3.«.
304
APÈNDIX 2
H K L Mult Hw ETA/M 2tettw leak lob* H K L Mult Hw ETA/M 2leth* leak lob«
1 S2 14 14 32 S2 43 41 34 30 52 24 20 f2 <3 31 53 51 62 «0 44 42 34 33 04 0
14202324134a2033121404243
1.0141.03«1.0371.03«1.0401.0681.0681.0981.09»1.1011.1321.1331.13«1.1391.1711.1741.1741.2171.2181.3061.3081.3581.3601.41«1.417
0.760 105.8000.760 107.30«0.760 107. 3C50.760 107.4570.760 107.5810.760 109.3890.760 109.4140.760 111.2250.760 111.3000.760 111.4070.760 113.1380.760 113.2000.7SO 113.4990.760 113.5190.760 115.2110.7SO 115.3630.760 115.4040.760 117.5210.760 117.5370.760 121.4290.760 121.5170.760 123.5090.7ÍO 123.5770.760 125. «190.760 125. «CO
S.1.1.0.4.1.1.11.13.18.34.67.19.24.9.8.5.0.0.22.45.2.8.5.1.
S.1.1.0.4.0.1.11.13.19.35.«8.19.25.11.10.7.0.0.17.3«.1.4.2.1.
1 44 40 13 14 12 53 S0 71 0S 03 42 S1 1S 11 73 24 21 25 22 44 41 S3 «4 52 7
415433215132S1143S1423100
1.4211.4231.4821.4831.4851.4931.4941.5031.5571.5631.5671.57«1.6451.S511.6721.7501.7522.0102.0202.0232.0282.0412.0442.2202.243
0.760 125.7880.760 12S.87S0.760 127.8420.760 127.8950.760 127.9370.7SO 128.1990.760 128.2280.760 128.5090.760 130.1660.760 130.3140.760 130.4450.760 130.7020.760 132.5970.760 132.7500.760 133.3130.760 135.2100.760 135.2570.760 140.5610.760 140.7390.760 140.7900.760 140.8800.760 141.1150.760 141.1750.760 144.0150.760 144.367
3.2.2.10.10.0.2.14.12.0.7.19.0.6.2.6.4.32.1.9.20.15.4.5.1.
2.1.1.8.7.0.2.11.13.0.7.19.0.1.0.3.2.35.1.10.22.17.5.7.2.
-305
APÈNDIX 2
en
Í
10oo
ot>
_ . o
_ _ V)
1VIISN3XNI
306
APÈNDIX 2
La2Ba2Cu2Ti2Olw (AFINAMENT PER DIFRACCIÓ DE NEUTRONS)
Grup espacial: P4/mmm (lambda=2.4497A 26^=1°, step=0.1°, 26^=160°)
H K L Mult Hw ETA/M 2tetlu Icalc lobt H K L Mult Hw ETA/M Ztctha Icalc IOÍM
0 0 10 0 20 0 30 0 41 0 01 0 11 0 20 0 51 0 31 0 41 1 01 1 10 0 C1 1 21 0 51 1 31 1 40 0 71 0 C1 1 50 0 82 0 01 0 72 0 11 1 62 0 22 0 31 0 82 0 42 1 00 0 » 11 1 7 «2 1 1 1 «
2 0.8512 0.7882 0.7242 O.CCO
O.S590.6520.«290.5960.5950.5540.5530.5480.5330.5320.5080.5080.4790.4760.4650.4500.4370.4370.43«0.43«0.4340.4330.4340.4450.44«0.44«0.4470.4480.449
0.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.4570.457
8.89017.8332«. 8883«. 1183«. 25337.40140. «7945.59745.70852.10452.20553.07155.41955. «1259.59459. «87«5.125«5.70«««.03871.7887«. «307«. 95877.41877. «S379. «0779.76983.24887.84288.08188.1S188.45188. «1088.850
7.1.0.2.0.1.4.3.1.
23.2.0.3.3.S.3.
257.0.5.2.
48.IS«.
0.0.4.0.0.1.1.1.0.2.0.
10.4.0.2.0.0.2.4.2.
17.2.0.2.2.7.3.
255.0.3.2.
48.169.
0.0.5.1.0.1.0.0.0.2.0.
2 1 22 0 52 1 31 1 82 1 41 0 90 0 102 0 C2 1 51 1 92 0 71 0 102 1 «0 0 112 0 82 2 02 1 72 2 11 1 102 2 21 0 112 2 30 0 12
2 1 82 2 43 0 0
2 0 93 0 13 0 21 1 112 2 53 0 31 0 12
1C8
1C8
1C828
1«888
1C284
1«888882
1«84888e888
0.4590.4810.4820.5250.5280.5320.5570.5610.6140.7150.7180.7610.7680.8501.0231.0351.0531.0631.1321.1541.3041.3371.6371.6721.6941.7011.7281.7S71.9962.43«2.5302.54«3.938
0.457 90.9140.457 94.2800.457 94.3600.457 98.9710.457 99.2130.457 99.5870.457 101. «070.4S7 101.9320.457 105.5580.457 111.1080.457 111.2790.457 113.2520.457 113.5990.457 116.9650.457 122.8940.457 123.2750.457 123.8140.457 124.1020.457 12«. 0400.457 12«. «340.457 130.3180.457 131.0530.457 136.8630.457 137.4490.457 137.8040.457 137.9220.457 138.35«0.457 138. 9600.457 142.2120.457 147.2040.457 148.0980.457 148.2490.457 157.413
2.4.1.4.
23.0.7.5.5.0.1.0.£.1.
138.120.
1.0.0.0.0.0.0.6.0.1.1.0.1.3.4.0.
16.
2.3.1.4.
27.0.7.7.4.0.1.0.5.0.
139.117.
0.0.0.0.0.0.0.5.0.1.0.0.2.6.8.1.
10.
•307
APÈNDIX 2
O«sH?U
CQ
í
VI
iÜCD
. oOO
_ . o
S;B)¡UQ) JLVJLISN31NI
308
APÈNDK2
Nd2Ba2Cii2Ti2O11_5 (AFINAMENT PER DIFRACCIÓ DE NEUTRONS)
Grup espacial: P4/mmm (lambda=2.5795A 26^=1°, step=0.1°, 28^=160°)
H K L Mult Hw ETA/M 2UUu leak lob« H K L Mult Hw ETA/M 2teth» Icalc lob.
0 00 00 01 01 01 00 01 01 01 11 10 01 11 01 11 i0 01 01 10 02 01 02 01 12 02 01 02 0
234012S3401C25347CS8071«238
4
2224e82884828888288248888888
O.CC20.634O.COC0.6050.6010.5910.57«0.5750.555O.S540.5510.5440.5430.5300.5300.5120.5100.5030.4900.4750.4730.4720.4710.4650.464
0.4540.4420.441
0.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2S90.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.259
18.83728.41938.20938.49239.70843.18«48.29848.53355.35755.570SC. 49558.80459.21463.388C3.584«9.44269.88672.50376.66581.77682.48482.72783.25785.21885.57089.41094.25894.786
127.39.5.0.
50.30.61.65.90.7.
20.89.15.
204.124.959.21.93.37.
169.703.
8.37.54.27.15.1.e.
112.37.5.0.
44.33.56.62.74.6.
15.69.13.
194.122.958.18.75.34.
179.772.
9.37.55.29.20.1.7.
021222212102212120222212120
0 91 01 71 11 20 51 31 81 40 90 100 £1 51 90 70 101 60 110 82 01 72 11 102 20 112 30 12
288
16168
168
16828
1688e
162
1
2
0.4410.4410.4400.4390.4340.4290.4280.4240.4240.4240.4250.4250.4320.4570.4600.4740.4800.5150.6400.6610.6690.6870.7350.7820.9381.0401.657
0.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.2590.259
94.85294.96295.20495.73398.051
101.768101.947106.951107.502107.571109.815110.563114.914121.277121.689123.799124.648128.329136.565137.59«137.954138.746140.677142.369146.875149.195158.147
8.0.
24.19.18.76.29.66.
1101.
78.145.17442.45.
0.11711.
507.552.10.43.31.26.16.14.41.
7.0.
26.21.20.85.34.61.
114.1.
75.159.190.
46.45.0.
124.5.
478.537.
9.35.21.18.9.
24.40.
-309
APÈNDIX 2
O»sHÍS
U«M«8
•OZ
enc«
O Oes s-'i-l 05
oo
o00
_ _ o
_ _ o-*-
Ots
JLVXISN31NI
310
APÈNDK2
Eu2Ba2Cu2Ti2OlW (AFINAMENT PER DIFRACCIÓ DE RAIGS X)
Grup espacial: P4/mmm (lambda=1.5418A 29^=2°, step=0.025°, 2efm=60°)
H K L Mi
0 0 10 0 20 0 30 0 41 0 01 0 11 0 20 0 51 0 31 0 41 1 01 1 10 0 «1 1 21 0 51 1 31 1 40 0 71 0 fi1 1 5o o e :
lit Hw
1 0.233i 0.2211 0.212i 0.207
0.2070.2070.20«0.20«0.2070.2090.2090.2100.2110.2110.2140.2150.2200.2200.2230.2290.23C
ET A/M
0.54«0.54C0.54C0.54C0.5460.54«0.54S0.5460.5460.5460.5460.5460.5460.5460.54«0.5460.5460.5460.54«0.5460.54«
2teth*
5. «2011.253K. 91422.61722. «6723.56525.5532«. 3772«. 57932.3(032.56033.06934.21134.55336.75036.91140.01140.13841.54943.7254«. 180
leak
18.15.5.
59.145.
2.1.0.
13.840.394.
1.5.1.
54.8.
206.12.9.1.
8«.
lob«
5.13.
C.C«.
141.2.1.1.
25.839.378.
3.7.2.
65.10.
206.12.17.3.
88.
H K L
1 0 72 0 02 0 11 1 62 0 22 0 31 0 80 0 92 0 41 1 72 1 02 1 12 1 22 0 52 1 31 1 81 0 92 1 40 0 102 0 6
Mult
84888882888
1616
81«88
1«28
Hw
0.2370.2370.2380.2410.2420.2480.25«0.25«0.2570.2570.2570.2590.2630.2«90.2700.2780.2790.2800.2830.285
ETA/M
0.5460.5460.54«0.54«0.5460.54«0.54«0.54«0.54«0.54«0.54«0.5460.54«0.5460.54«0.54«0.54«0.54«0.54«0.546
2tetha
4«. 69346.71347.09047.94948.20850.03052.13552.36152.50152.60452.62352.96853.99655.56455.68157.64157.85357.98458.71059.161
Icalc lote
8. 8.252. 252.
1. 1.4. 1.1. 0.1. 0.
30. 24.4. 4.
29. 29.10. 10.35. 35.0. 0.0. 0.1. 0.3. 1.
119. 125.9. 9.
272. 275.6. 2.2. 0.
-311
APÈNDIX 2
O«S
H«s
U<ses
IT)V)
« 8o_ _ V) CD
oro
«ri«s
oes
312
APÈNDIX 2
Tb2Ba2Cu2Ti2Olw (AFINAMENT PER DIFRACCIÓ DE RAIGS X)
Grup espacial: P4/mmm (lambda=1.5418A 20^=2°, step=0.025°, 26fm=600)
H K L Mult Hw ETA/M Zteth« Ic*k lob« H K L Mull Hw ETA/M 2teth* leak lobs
0 00 00 00 0i 01 01 00 01 01 01 11 10 01 11 01 11 10 01 01 10 0
13340125340163S347658
222248828848288882882
0.2370.2190.30«0.19»0.1980.1980.1980.1990.1990.2030.2040.2050.2060.2070.3120.2130.2220.2220.2370.2360.246
0.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.358
5.C1711.2481C. 90722. «0722.93923. «3525. «1C28.3C428. «3432.42«32.66433.17134.19«34. «503«. 78737.00140.09240.12141.57943.7984«. 159
28.22.10.73.172.3.0.1.18.
1021.489.3.7.1.79.8.
2C3.17.1C.3.
108.
10.31.7.85.190.2.2.3.44.
1062.4C3.4.4.0.83.8.
262.17.27.8.
108.
12212210212222211203
00010000011110110100
701e2389470125389410C
8488888388816168
1«88
1C28
0.2490.2490.2510.2550.25C0.2650.27«0.2770.2790.2790.2800.2820.2880.3970.3980.3090.3100.3130.31«0.330
0.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.3580.358
4«.4«.47.48.48.50.53.53.52.52.53.53.54.55.55.57.57.58.58.59.
71««67343013357173151337«37«Cl7991431S8«93848«90863144«83383
8.333.2.5.2.2.3«.8.39.20.4«.1.0.3.4.
163.17.
373.9.4.
8.337.2.0.1.1.29.7.37.19.42.1.0.4.7.
1C«.18.389.«.3.
•313
APÈNDK2
Hc*U
cdOoes
1V1ISN31NI
314
APÈNDK2
Tb2Ba2Cu2Ti2Olw (AFINAMENT PER DIFRACCIÓ DE NEUTRONS)
Grup espacial: I4/mcm (lambda=1.2272À 20^=1°, step=0.05°, 26fm=126°)
H
0
0
0
1110112202
21222201222012222221022332323221302333322
K L
0 40 Co e1 01 21 40 10i e1 80 00 20 120 41 11 10
0 61 31 5o e0 141 121 70 101 90 1C1 142 02 20 122 41 112 C1 160 182 80 141 01 21 131 42 101 S0 1C1 151 181 80 202 122 11 102 32 S1 170 18
Mult
2224882884828
1C8
8
1C
1C
828
1C8
1C284ee8
1C8
82888
1C1C1C8
1C8
1C8
1C
28
1C1C1C1C1C
8
Hw
0.2710.2C50.2CO0.2SO0.25»0.2580.25C0.25C0.2550.2550.2540.2540.2540.2540.2540.2540.2540.2540.2540.2540.2540.2540.2540.2540.2550.2550.2550.2550.2550.25C0.25C0.2SC0.2580.2580.2580.2580.2580.2580.2580.25»0.2600.2600.2620.2620.2620.2620.2630.2640.2650.2650.2660.2680.2660.268
ETA/M
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
2tetha
8.93413.41817.92218.19218.74120.30132.45522.C7325.C4625.8382C.23427.02427.39029.04129.05029.22229.74931.12131.62531.63732.77233.08334.49235.54936.3033C.73C3«. 86537.15337.73538.00838.43739.39840.89541.03241.27741.28741.40441. CCC41.67842.44443.59543.71C45.09C45.21C45.22345.44945.83C46.30147.59847.60448.06748.99449.01149.128
leak
23.4.0.0.
10.3.9.9.7.1.3.
1C.4.2.
41.19.3.S.
124.5.
14.2.C.0.
15.2.
79.11.
C.3.1.2.0.0.0.4.0.3.3.2.
12.3.
10.1.0.
11.10.22.
0.24.0.1.0.8.
loi»
21.3.0.0.
10.3.
10.9.7.1.3.
15.4.2.
43.19.4.3.
124.5.
13.2.5.1.
1C.2.
83.9.C.3.2.1.1.1.0.
5.0.2.2.2.
10.2.
10.1.0.
12.9.
21.0.
23.1.1.0.7.
H
213303232442431444043243332342434133344244043242344433
K L
2 141 201 122 70 222 92 1C1 141 190 00 20 200 42 111 221 10 C1 30 241 51 1C2 180 83 03 22 131 213 41 70 220 103 C1 91 242 151 183 82 02 22 200 122 40 261 113 101 232 C0 242 172 80 141 131 203 12
Mult
88
1C1C
21C
81C1C
4888
1C8
1C8
1C2
1C1C
884e
1C1C8
1688
81C
81C1C88
1C88
1C2
1C8
1C1C8
1C1C
81C1C
8
Hw
0.2680.2690.2700.2700.2710.2730.2740.2750.2750.2750.27C0.27C0.2770.2780.2780.2790.2790.2800.2810.2820.2820.2820.2830.2830.2830.2830.2840.2850.2850.28C0.2870.2870.2890.2890.2910.2910.2910.2910.2920.2920.2930.2940.2940.2950.29C0.29C0.2970.2980.3000.3010.3010.3020.3020.303
ETA/M
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
2tetha
49.34949.70550.14250.36250.72C52.14452.70353.02C53.03C53.12253.33953.3C353.96«54.31454.33C54.94555.05355.3C955.718SC. 209SC. 223SC. 331SC. 52456.624SC. 832SC. 84257.27157.45357.45557.78858.38058.47859.08959.11759.70259.70859.89459.991ÇO. 191ÇO. 214ÇO. 598ÇO. 790ÇO. 827Cl. 09461.686Cl. 710Cl. 78162.400C2.B7363.15363.160C3.45063.463C3.83C
leak
5.0.
1C.0.1.0.
21.2.0.
32.9.1.1.0.1.1.2.1.5.3.0.4.0.1.3.1.1.1.1.7.8.1.0.0.0.0.1.2.1.
18.
13.3.0.0.
11.0.3.C.0.
37.2.3.0.4.
lob»
5.0.
1C.1.1.0.
22.2.0.
30.10.1.0.0.2.3.3.1.5.2.0.3.0.1.5.1.1.1.1.C.7.1.0.0.0.0.1.1.1.
18.12.3.0.0.
12.0.3.5.0.
37.2.3.0.4.
•315
H K L·
1 1 2 «2 2 224 2 104 0 1C0 0 264 1 153 3 143 2 192 1 254 2 122 0 2 «3 1 224 3 14 3 32 2 244 3 53 3 1C4 1 171 1 284 0 184 2 145 1 05 1 23 2 215 1 44 3 7S I C2 1 270 0 304 3 93 1 244 2 1C2 0 283 3 185 1 84 1 194 0 202 2 264 3 115 2 15 1 103 2 235 2 31 1 305 2 54 2 184 3 133 3 205 1 124 1 215 2 73 1 262 1 294 0 220 0 322 0 305 2 92 2 284 3 155 1 14
2 254 04 22 204 4
S 2 113 3 22
Mult
68
1C82
1C8
1C1C1C8
1C1C1C8
1C8
1C88
1C8
1C1C1C1C1C1C
21C1C1C88
1C1C
88
1C1C1C1C1C
81C1C1C
81C1C1C1C1C
828
1«8
1C1C1C
48
1C8
1C8
Hw
0.3040.3040.30«0.3100.3100.3100.3110.3110.3110.3130.3140.3150.3170.3180.3200.3210.3210.3210.3210.3220.3220.3230.3230.3250.32C0.32C0.3290.3290.3310.3310.3320.3330.3340.3340.3340.3350.3360.3380.3390.3410.3420.3420.3430.3430.34C0.3470.3490.3490.3500.3510.3510.3510.3510.3530.3550.3570.3580.3600.3610.3620.3620.3620.3630.3630.3660.3670.367
ETA/M
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
ZteUia
«4.058C4.337C4.893CC.04C««.074««.13»««.327««.33«««.350CC.98C«7.203C7.475«8.012C8.36CC6.C9C«».1326». 144C9.14C«9.171C9.24069.419«9.502C9.C6770.07»70.24270.24471.16371.19871.48271.71471.74072.18072.20772.27472.44372.45672.73373.29273.53574.07174.07C74.09674.43274.47775.15375.25775. «9875.7107«. 0557«. 0707C.2297C.2CO76.26876.51877.08077.43077. CSC78.13578.19578.37178.39378.45078. «2778. «4779.15979.42979.447
Ici 1C
12.3.0.
10.1.1.2.0.0.1.7.2.1.0.
14.1.1.0.7.5.4.0.3.0.1.1.2.0.1.0.0.
10.0.0.4.0.
11.0.0.0.
14.0.0.0.0.e.i.0.7.2.0.
14.0.2.0.0.0.2.0.2.0.
12.8.
0.
0.
0.1.
lob*
12.2.0.
10.1.1.2.0.0.1.8.3.2.1.
18.1.2.0.8.5.4.0.4.1.2.1.3.0.2.0.0.9.0.0.4.0.
11.0.0.0.
17.0.0.0.0.7.1.0.C.1.0.
14.0.2.0.0.0.2.0.2.0.
13.».0.0.0.1.
H K L·
4 1 231 1 324 4 C4 0 245 1 1C4 3 173 1 284 4 85 3 05 3 25 2 132 1 315 3 44 2 224 4 102 0 320 0 345 3 C3 2 272 2 303 3 245 2 155 1 185 3 84 3 194 1 25C O OC 0 24 4 12C 0 44 0 26C i l5 3 101 1 34C O CC 1 33 1 304 2 24C I S5 2 17C 0 84 4 142 1 335 1 205 3 124 3 21C 1 73 3 2 «3 2 29C 0 102 2 322 0 344 1 270 0 3 «C 1 94 4 1C4 0 285 3 145 2 19C 2 0« 2 2« 0 12« 2 44 2 2 «« 1 115 1 22
Mull
1C888
1C1C1C88
1C1C1C1C1C882
1C1C86
1C1C1C1C1C
488e8
1C1Cee
1C1C1C1C1C
88
1C1C1C1C1C
81C
888
1C2
1C88
1«
1C8
1«8
1«1«1«1«
MW
0.3700.3700.3700.3730.3750.3750.3750.3770.3770.3780.3780.3780.3810.3620.3850.3850.38«0.38C0.38C0.3870.3890.3920.3920.3930.3930.3930.3930.3940.39«0.3970.3970.4020.4020.4020.4020.4040.4040.40«0.4080.4080.4100.4100.4110.4120.4140.4140.4150.4150.4150.4200.4200.4200.4210.4230.4240.4270.4270.4290.4290.4290.4300.4330.4340.4340.43«0.436
El A/M
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
0.194
0.194
¿lema
79.97880.00380.04280.59781.02181.02281.04781.27581.35981.53581.54381.56282.06262.34882.85482.89982.90«82.93882.97283.24383.48»83.»»«84.00184.16284.17784.19084.24C84.42184.77784.94584. »7785.72885.73285.78485.81686.0768«. 12086.36586.77286.78587.03587.04287.17287.31287.C4787.66287.81687.84787.85588.60088. «4588. «5288.7188». 00«8». 2078». «4»89. «7589.90789.91589.98490.158»0.51290.67990.71190.94590.962
icaic
0.1.1.
11.1.0.
14.0.
0.1.0.0.1.5.4.3.1.0.0.3.0.0.0.6.0.0.1.0.8.1.0.1.s.2.0.0.0.3.1.0.8.0.0.0.».1.1.7.0.0.0.«.0.1.0.3.2.1.0.
18.14.0.0.3.0.2.
1OOS
0.1.0.
10.2.0.
15.0.0.2.0.0.0.3.4.3.1.0.0.4.0.0.0.».0.0.1.0.».1.0.1.s.2.0.0.0.3.1.0.e.0.0.0.».i.i.8.0.0.0.4.0.1.0.4.2.1.0.
1«.14.0.0.4.0.
2.
H K L
5 « 14 3 333 1 32C 2 C5 4 31 1 3 «5 4 55 3 1C3 3 294 4 liC 2 •C 0 14C 1 133 2 312 1 355 2 215 4 74 1 29C 2 102 2 344 0 302 0 3 «5 4 95 1 24C 0 1C4 2 2 «0 0 38C 1 155 3 184 3 254 4 20C 2 125 4 11C 3 15 2 233 1 34C 3 33 3 30C 3 5C 1 171 1 38C 0 18C 2 143 2 33S 4 135 3 204 1 31C 3 75 1 2C2 1 374 4 224 0 324 3 274 2 302 2 3«C 3 9C 2 1C2 0 385 4 15C 1 195 2 25C 0 200 0 40C 3 115 3 22
Mult
1C1C1C1C1C8
1C1C
88
1C8
1C1C1C1C1C1C1C888
1C1C8
1C2
1C1C1C8
1C1C1C1C1C1C
81C1C88
1C1C1C1C1C1C1C1C
88
1C1C8
1C1C
81C1C1C
82
1C1C
Hw
0.4390.4390.4400.4400.4420.4420.4470.4470.4470.4470.4490.4490.4510.4510.4510.4530.4540.4550.4CO0.4C10.4C30.4C30.4650.4850.4C80.4C80.4690.4690.4690.4700.4720.4750.4790.4830.4830.4830.48C0.48C0.4910.4920.4920.4920.4940.4950.49C0.49C0.49C0.5000.5010.5010.5030.5080.5080.5110.5110.5130.5170.5170.5180.5190.5190.5220.5270.5290.529
ETA/M 2tcUu
0.194 91.4600.194 91.4850.194 91.5100.194 91.5480.194 91.8070.194 91.8700.194 92.5030.194 92.5140.194 92.5400.194 92.6040.194 92.7CC0.194 92.7720.194 93.0310.194 93.0700.194 93.0830.194 93.3920.194 93.5470.194 93.58C0.194 94.3330.194 94.3840.194 94.7200.194 94.7390.194 94.9410.194 94.9C50.194 95.3850.194 95.4110.194 95.4430.194 95.4710.194 95.47C0.194 95. CCS0.194 95.91C0.194 9C.2520.194 9C.C880.194 97.2070.194 97.2320.194 97.2C30.194 97.5570.194 97. COI0.194 98.2590.194 98.2720.194 98.3290.194 98.3C10.194 98.5300.194 98.6620.194 98.7920.194 98.8040.194 98.8310.194 99.3140.194 99.3450.194 99.3790.194 99.5990.194 100.1540.194 100.2280.194 100.5010.194 100.5210.194 100.7250.194 101. 17C0.194 101.2350.194 101. 2C30.194 101.4470.194 101. 4CO0.194 101.7150.194 102.3070.194 102.5000.194 102.518
leak
0.0.2.1.0.0.0.1.5.C.1.1.1.0.0.0.0.0.8.1.3.C.0.0.4.0.0.0.0.0.5.
12.0.0.0.3.0.0.0.0.1.2.1.0.0.0.0.0.
11.0.2.1.0.0.2.0.C.0.0.0.0.0.2.0.2.
lob»
0.0.2.1.0.0.0.0.4.5.1.1.1.0.0.0.0.1.C.1.3.C.0.0.3.0.0.0.0.0.c.
12.0.0.0.3.0.0.0.0.1.2.1.0.0.0.0.0.
12.0.2.1.0.0.2.0.4.0.0.0.0.0.2.0.2.
H
33455C75475C3C7541C44755252C755
2775C3C75C07C36447557553CC447
K L
3 321 364 244 171 282 181 05 01 331 25 23 132 351 211 45 43 291 400 222 320 341 C5 C2 271 393 242 383 151 8s e4 194 04 22 204 44 260 402 11 105 101 233 344 C2 31 300 240 422 53 171 384 83 311 351 125 124 212 73 262 292 372 224 102 340 362 9
Mult
81C
81C1C1C84
1C1C
81C1C1C1C8
1C88
1C8
1C8
1C1C1C8
1C1C8
1C8
1C1C1C88
1C1C8
1C8
1C1C16
82
161C1C1C1C1C168
1C1C1C1C161C1C16
816
Hw
0.5340.5380.5400.5440.5450.5450.5480.5480.5480.5500.5500.5500.5500.5530.5550.5550.5550.55C0.5580.5640.5640.5640.5640.5650.5650.5700.5750.57C0.5780.5780.5780.5780.5800.5810.5860.5870.5870.59C0.59C0.59C0.59C0.5960.597O.COOO.COO0.6030.6040.6080.6080.6090.6110.6150.615O.C19O.C190.6190.6210.6220.6220.6220.6250.6310.6320.6370.640
ETA/M
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
2tetlu
103.079103.449103. C81104 . 113104.138104.205104.457104.457104.512104. C37104. C37104.645104. C98105.018105. 17C105. 17C105.218105. 25C105.470106.038106.045106.078106.078106.113106.154106.648107. 14 C107.175107.348107.348107. 3C3107. 43C107.618107.638108. ICC108.200108.247108.989108.994108.994109. 01C109.049109.083109.357109.403109. 663109.724110. 09C110.109110.169110.375110.700110.714111.029111.029111.044111.210111.243111.251111.279111.512112.053112.108112.491112.709
Icalc
2.0.7.0.
10.12.0.1.0.1.2.1.0.1.0.1.0.3.1.3.0.1.0.0.0.0.0.0.4.2.0.1.1.8.2.0.3.0.8.4.0.1.0.0.0.1.1.0.0.3.8.0.0.
5.3.0.0.c.0.0.3.1.
11.2.0.
lobs
1.0.7.0.9.
12.0.1.0.1.2.1.0.1.0.1.0.3.1.5.0.1.0.0.0.0.0.0.4.1.0.1.1.8.2.0.4.0.9.5.0.1.0.0.0.1.1.0.0.4.
10.0.0.
5.3.0.0.7.0.0.4.1.
10.1.0.
•317
APÈNDK2
H K L Mult Hw ETA/M Itetlu leak lob* H K L Mult Hw ETA/M 2tetha Icalc lob«
1 1 424 4 287 1 145 S 146 3 196 1 252 1 41í 4 12« 0 262 2 407 2 115 4 23S 1 323 3 3 «S 2 242 0 427 1 165 1C5 286 147 04 337 3 27 2 135 2 31« 3 217 3 44 1 37
1«
1CS
1C1C1C1C•8
1C1C1C8
1C8
1C8
1C1C
81C1C1C1C1C1C1C
O.C41O.C4CQ.C49O.C49O.C49O.CSOO.CSOO.CS8O.CC1O.CC1O.CC4O.C72O.C72O.C78O.C81O.C82O.C88O.C88O.C88O.C92O.C93O.C94O.C9CO.C9CO.C9C0.7020.7040.705
0.194 112.7980.194 113.2170.194 113.4700.194 113.4700.194 113.4780.194 113.4920.194 113.5490.194 114.1310.194 114.3500.194 114.3990.194 114. COC0.194 115.2020.194 115.2290.194 115. «2 80.194 115.8780.194 115.9420.194 11C. 3440.194 IIC. 3440.194 IIC. 3730.194 116. C310.194 IIC. 7180.194 IIC. 7770.194 IIC. 9130.194 IIC. 9220.194 11C.9CS0.194 117.3270.194 117.4990.194 117.573
2.2.1.1.0.0.0.0.1.7.0.0.3.0.
14.1.1.2.
14.3.1.0.3.0.0.1.0.0.
1.1.1.1.0.0.0.0.1.9.0.0.3.0.
13.1.1.2.
13.3.1.0.2.0.0.1.1.0.
3076347e52e52673e57S47e62454
1 400 443 C1 272 394 303 103 231 341 435 33 302 425 52 173 384 182 331 205 203 353 125 71 290 444 324 271 39
1C2
1C1C1C
a1C1C1616161C8
1C1C8
1C1C168
1C16161688
1C16
0.7050.7100.7190.7190.7200.7240.7« 90.7700.7700.7710.77C0.7770.7830.7900.7900.7920.7920.7980.8010.8010.8020.8090.8120.8130.8200.8310.8330.833
0.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.1940.194
117.586117.898118.483118.521118.565118.827121.697121.721121.757121.797122.100122.151122.509122.924122.940123.007123.045123.401123.569123.569123.517123.972124.176124.222124.602125.183125.272125.319
4.1.1.0.0.2.9.0.1.0.0.0.2.0.0.2.C.0.0.0.0.4.0.0.
0.1.0.0.
5.1.1.0.0.2.
11.0.2.0.0.0.2.0.0.2.5.0.0.0.0.3.0.0.0.2.0.0.
318
APÈNDIX 2
Ori
H01s«s
03
.QH
== -a .
I/) SO «8»H t-
OCDes
o00
«o
1V1ISN31NI
-319
Universal Auiwomi lie uawloiu
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