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i
Dust PalliativeSelection and
ApplicationGuide
United StatesDepartment ofAgriculture
Forest Service
Technology &DevelopmentProgram
7700—Transportation System2500—Watershed and Air ManagementNovember 19999977 1207—SDTDC
iii
DUST PALLIATIVESELECTION ANDAPPLICATION GUIDE
Peter BolanderPavement Engineer, Pacific Northwest Region
Alan YamadaProject Leader
San Dimas Technology and Development CenterSan Dimas, California
November 1999
Information contained in this document has been developed for theguidance of employees of the Forest Service, USDA, its contractors,and cooperating Federal and State agencies. The Department ofAgriculture assumes no responsibility for the interpretation or use of thisinformation by other than its own employees. The use of trade, firm, orcorporation names is for the information and convenience of the reader.Such use does not constitute an official evaluation, conclusion,recommendation, endorsement, or approval of any product or service tothe exclusion of others that may be suitable.
The US Department of Agriculture (USDA) prohibits discrimination in itsprograms and activities on the basis of race, color, national origin, sex,religion, age, disability, political beliefs, and marital or familial status.(Not all prohibited bases apply to all programs.) Persons with disabilitieswho require alternative means for communication of program information(Braille, large print, audiotape, etc.) should contact USDA Office ofCommunications at 202-720-22791 (voice), or 800-855-1234 (TDD).
To file a complaint, write the Secretary of Agriculture, U.S. Departmentof Agriculture, Washington, DC 20250, or call 1-800-245-6340 (voice),or 800-855-1234 (TDD). USDA is an equal employment opportunityemployer.
v
Contents
ACKNOWLEDGEMENTS ................................................................................................................. 1
INTRODUCTION............................................................................................................................... 1
DUST ABATEMENT BASICS ............................................................................................................ 1
DUST PALLIATIVE BASICS.............................................................................................................. 2
SUPPRESSANT SELECTION TIPS ................................................................................................. 2
SUPPRESSANT APPLICATION TIPS .............................................................................................. 15
General Application Tips ............................................................................................................ 15
Water Application Tips ............................................................................................................... 15
Chloride Application Tips ........................................................................................................... 15
Petroleum Application Tips ........................................................................................................ 16
Organic Nonpetroleum Application Tips ..................................................................................... 16
Electrochemical Application Tips ............................................................................................... 16
Polymer Application Tips ............................................................................................................ 16
Clay Additive Application Tips .................................................................................................... 16
ENVIRONMENTAL IMPACTS ........................................................................................................... 16
PAST FIELD OR LABORATORY STUDY REFERENCES................................................................ 18
ONGOING FIELD OR LABORATORY STUDIES ............................................................................. 18
LITERATURE CITED ........................................................................................................................ 19
1
ACKNOWLEDGEMENTS
The author would like to first acknowledge all theForest Service personnel and suppressantmanufacturers/suppliers that have shared theirwisdom and knowledge on the use of dustsuppressants. Acknowledgements should also goto UMA Engineering, George Giummarra, andDavid Jones, for without their studies and writings,this report would have been much more difficult topull together.
INTRODUCTIONThe purpose of this publication is to helppractitioners understand and correctly choose andapply the dust palliative that is appropriate for theirparticular site, traffic conditions, and climate. Inaddition, this publication describes the expectedperformance, limitations, and potentialenvironmental impacts of various palliatives.
This guide examines most of the commonlyavailable dust palliatives currently available anddoes not endorse any particular product. Sincenew products will become available and existingproducts will most likely change followingpublication of this report, it is recommended thatthis guide be used as a starting point fordetermining which palliative would be mostappropriate for a given situation.
DUST ABATEMENT BASICS
Dust from unpaved roads is not only a nuisancebut creates a safety hazard by reducing the driver’svisibility. Dust also affects the health of road usersand increases wear-and-tear on vehicles. Dust isalways considered an intruder at campsites andpicnic areas. In some areas there are regulationsthat limit the amount of particulate allowed in theatmosphere.
Fine particles, including dust, act to help hold thesurface of unpaved roads together. With a loss offine particles from the roadway, there is an increasein roadway surface raveling and maintenancecosts. These fines are smaller than what the eyecan see and pass through the 75 µm (No. 200)sieve.
How can dust emissions from the roadway bereduced or eliminated? Since the fines act as abinder that holds the surface of the unpaved road
together, removing them is not a good option.Sealing the surface with an asphalt or concretepavement or Bituminous Surface Treatmenteliminates the dust problem; however, the lowtraffic on most Forest Service roads does not justifythe cost of sealing the road with asphalt, concrete,or a surface treatment. Another alternative is toapply a dust suppressant product. These productsare not a permanent solution and will requirefurther applications as the effectiveness of theproduct decreases with time. Dust suppressantsare one of many possible methods to control dust(Foley 1996; UMA 1987; Washington Dept. ofEcology 1996).
Dust suppressants work by either agglomeratingthe fine particles, adhering/binding the surfaceparticles together, or increasing the density of theroad surface material. They reduce the ability ofthe surface particles to be lifted and suspended byeither vehicle tires or wind.
To properly select the appropriate palliative onemust understand the primary factors that generatedust. They include the following:
• Vehicle speed
• Number of wheels per vehicle
• Number of vehicles
• Vehicle weight
• Particle size distribution (gradation) of thesurface material
• Restraint of the surface fines (compaction,cohesiveness/bonding, durability)
• Surface moisture (humidity, amount ofprecipitation, amount of evaporation).
An excellent description of these factors thatgenerate dust and how to analyze total long-termcosts can be found in Foley et al. (1996) and UMAEngineering (1987).
Selection of the proper dust abatement programmust include an understanding of not only theabove factors, but the total long-term cost andenvironmental impacts of that program. Long-termcosts include road improvement, road preparation,application of the suppressant in conjunction withthe number of times the palliative needs to beapplied, and expected change in maintenancepractices. Environmental considerations typically
2
include impacts to the water quality, aquatic habitat,and plant community.
Besides controlling dust, a good dust abatementprogram may include reduced maintenancebladings and decreased aggregate loss (UMA1987; Addo and Sanders 1995; Lund 1973).
DUST PALLIATIVE BASICS
There are a wide variety of dust suppressantsavailable on the market today and there willcontinue to be more in the future. They can bedivided into seven basic categories: water, waterabsorbing products, petroleum based products,organic nonpetroleum based products,electrochemical products, polymer products, andclay additive products. The categories are listedin order based on an estimate of past usage/popularity.
Typical suppressants in each category are:
• Water
• Water Absorbing Products (deliquescent/hydroscopic)
- calcium chloride brine and flakes- magnesium chloride brine- sodium chloride (salt)
• Organic Petroleum Products
- asphalt emulsions- cutback asphalt (liquid asphalt)- dust oils- modified asphalt emulsions
• Organic Nonpetroleum Products
- animal fats- lignosulfonate- molasses/sugar beet- tall oil emulsions- vegetable oils
• Electrochemical Products
- enzymes- ionic products- sulfonated oils
• Synthetic Polymer Products
- polyvinyl acetate- vinyl acrylic
• Clay Additives
- bentonite- montmorillonite
Table 1 gives an overview of these sevencategories, listing their attributes, limitations, typicalapplication rates, and common names based onFoley et al. (1996), UMA Engineering (1987), TTAO(1986), Bolander (1997), and Scholen (1992).Table 2 lists manufacturers and some distributorsof the various dust palliatives.
SUPPRESSANT SELECTION TIPSTo determine the most cost-effective dust palliative,it is recommended that the flow diagram by UMAEngineering (1987) and Washington StateDepartment of Ecology (1996) in figure 1 befollowed. Important benefiting factors (Langdon1980) of dust palliatives that should be consideredwhen evaluating and selecting the proper dustpalliative include:
• Cohering the dust particles to themselves orto larger particles
• Resisting wear by traffic
• Remaining on the road
• Resisting aging.
Based on the above characteristics, the productselection chart shown in table 3 should aid inselecting the most suitable dust palliative (Foley etal. 1996; UMA 1987; Bolander 1997; Bolander1999; Scholen 1992; Langdon et al. 1980; Han1992). When using the information in table 3, firstperform a soils analysis to classify the surfacematerial. Some palliatives require a claycomponent (plasticity index) or specific amount offines to properly bind and/or agglomorate. Table 1provides additional information about dustsuppressant limitations, application methods, andenvironmental impact, which helps further inselecting the best dust palliative. The flow diagramin figure 1 leads the practitioner to figure 2, whichis a guide for determining the overall cost of thedust abatement program including the yearly andpossibly the multi-year cost of a dust abatementapplication. Figure 3 is a guide for summarizingthe expected benefits of the selected dust controlplan.
If a petroleum dust palliative is being considered,further suppressant selection information can befound in Langdon (1980) and Langdon, Hicks, andWilliamson (1980).
3
Dust SuppressantCategory
Water
Attributes
• agglomerates thesurface particles
• normally, readilyavailable
Limitations
• evaporates readily• controls dust
generally for lessthan a day
• generally the mostexpensive and laborintensive of theinorganicsuppressants
Application
• frequency dependson temperature andhumidity; typicallyonly effective from1/2 to 12 hours
Origin
• any potable watersource
Environmental Impact
• none
Water Absorbing:Calcium Chloride(deliquescent)
• ability to absorbwater from the air isa function oftemperature andrelative humidity; forexample, at 25°C(77°F) it starts toabsorb water at 29%relative humidity, andat 38°C (100°F) itstarts to absorbwater at 20% relativehumidity
• significantlyincreases surfacetension of water filmbetween particles,helping to slowevaporation andfurther tightencompacted soil asdrying progresses
• treated road can beregraded andrecompacted withless concern forlosing moisture anddensity
• requires minimumhumidity level toabsorb moisture fromthe air
• doesn’t perform aswell as MgCl in longdry spells
• performs better thanMgCl when highhumidity is present
• slightly corrosive tometal, highly toaluminum and itsalloys, attractsmoisture, therebyprolonging activeperiod for corrosion
• rainwater tends toleach out highlysoluble chlorides
• if high fines contentin treated material,the surface maybecome slipperywhen wet
• effectiveness whenless than 20%solution hasperformance similarto water
• generally 1 to 2treatments perseason
• initial application:flake: @ 0.5 to 1.1kg/m2 (1.0 to 2.0
lb/y2), typicalapplication 0.9 kg/m2
(1.7 lb/y2) @ 77%purityliquid: 35 to 38%residual @ 0.9 to 1.6L/m2 (0.2 to0.35 g/y2), typicalapplication is 38%residual concentrateapplied undiluted @1.6 L/m2 (0.35 g/y2)
• follow-up: apply@ 1/2 to 1/3 initialdosage
• by-product in theform of brine frommanufacture ofsodium carbonate byammonia-sodaprocess and ofbromine from naturalbrines
• three forms:flake, or Type I, @ 77to 80% puritypellet, or Type II, @94 to 97% purityclear liquid @ 35 to38% solids
• water quality impact:generally negligible ifthe proper bufferzone exists betweentreated area andwater
• fresh water aquaticimpact: may developat chlorideconcentrations aslow as 400 ppm fortrout, up to 10,000ppm for other fishspecies
• plant impact: somespecies susceptible,such as pine,hemlock, poplar,ash, spruce, andmaple
• potential concernswith spills of liquidconcentrate
Table 1—Road dust suppressants.
4
Dust SuppressantCategory
Attributes Limitations Application Origin Environmental Impact
Water Absorbing:Magnesium Chloride(deliquescent)
• starts to absorbwater from the air at32% relative humidityindependent oftemperature
• more effective thancalcium chloridesolutions forincreasing surfacetension, resulting in avery hard roadsurface when dry
• treated road can beregraded andrecompacted withless concern forlosing moisture anddensity
• requires minimumhumidity level toabsorb moisture fromthe air
• more suitable in drierclimates
• in concentratedsolutions, verycorrosive to steel(note: some productsmay contain acorrosive-inhibitingadditive); attractsmoisture, therebyprolonging activeperiod for corrosion
• rainwater tends toleach out highlysoluble chlorides
• if high fines contentin treated material,the surface maybecome slipperywhen wet
• effectiveness whenless than 20%solution hasperformance similarto water
• generally 1 - 2treatments perseason
• initial application:28 to 35% residual@ 1.4 to 2.3 L/m2
(0.30 to 0.5 g/y2),typical application is30% residualconcentrate appliedundiluted @ 2.3 L/m2
(0.50 g/y2)• follow-up:
apply @ 1/2 initialdosage
• occurs naturally asbrine (evaporated)
• water quality impact:generally negligible ifthe proper bufferzone exists betweentreated area andwater
• fresh water aquaticimpact: may developat chlorideconcentrations aslow as 400 ppm fortrout, up to 10,000ppm for other fishspecies
• plant impact: somespecies susceptiblesuch as pine,hemlock, poplar, ash,spruce, and maple
• potential concernswith spills
Water Absorbing:Sodium Chloride(hygroscopic)
• starts to absorbwater from the air at79% relative humidityindependent oftemperature
• increases surfacetension slightly lessthan calcium chloride
• requires minimumhumidity level toabsorb moisture fromthe air
• moderately corrosiveto steel in dilutesolutions
• tends not to hold upwell as a surfaceapplication
• generally 1 - 2treatments perseason
• higher dosages thancalcium treatment
• occurs naturally asrock salt and brines
• same as calciumchloride
Table 1—Road dust suppressants (continued).
5
Dust SuppressantCategory
Attributes Limitations Application Origin Environmental Impact
Organic PetroleumProducts
• binds and/oragglomeratessurface particlesbecause of asphaltadhesive properties
• serves to waterproofthe road
• under dry conditionssome products maynot maintainresilience
• if too many fines insurface and high inasphaltenes, it canform a crust andfragment under trafficand in wet weather
• some products aredifficult to maintain
• generally 1 to 2treatments per season
• 0.5 to 4.5 L/m2 (0.1 to 1g/y2) depending onroad surface condition,dilution, and product
• the higher viscosityemulsions are used forthe more open-gradedsurface materials
• follow-up: apply atreduced initial dosages
• cutback asphalt: SC-70
• Asphalt emulsion:SS-1, SS-1h, CSS-1,or CSS-1h mixedwith 5+ parts waterby volume
• modified asphaltemulsions
• emulsified oils• mineral oils
• wide variety ofingredients in theseproducts
• “used” products aretoxic
• oil in products mightbe toxic
• need product specificanalysis
• potential concernswith spills andleaching prior to theproduct “curing”
Organic Nonpetroleum:Lignin Derivatives
• binds surfaceparticles together
• greatly increases drystrength of materialunder dry conditions
• retains effectivenessduring long dryperiods with lowhumidity
• with high amounts ofclay, it tends toremain slightly plasticpermitting reshapingand additional trafficcompaction
• may cause corrosionof aluminum and itsalloys
• surface bindingaction may bereduced orcompletely destroyedby heavy rain, due tosolubility of solids inwater
• becomes slipperywhen wet, brittlewhen dry
• difficult to maintainas a hard surface,but can be doneunder adequatemoisture conditions
• generally 1 to 2treatments perseason
• 10 to 25% residual@ 2.3 to 4.5 L/m2
(0.5 to 1.0 g/y2),typical application is50% residualconcentrate appliedundiluted @ 2.3 L/m2
(0.50 g/y2) or50% residualconcentrate applieddiluted 1:1 w/water@ 4.5 L/m2 (1.0 g/y2)
• may beadvantageous toapply in twoapplications
• also comes inpowdered form thatis mixed 1 kg to 840liters (1 lb to 100gallons) of water andthen sprayed
• water liquor productof sulfite papermaking process,contains lignin insolution
• composition dependson raw materials(mainly wood pulp)and chemicals usedto extract cellulose;active constituent isneutralized ligninsulfuric acidcontaining sugar
• water qualityimpacts: none
• fresh water aquaticimpacts: BOD maybe high uponleaching into a smallstream
• plant impacts: none• potential concern
with spills
Table 1—Road dust suppressants (continued).
6
Dust SuppressantCategory
Attributes Limitations Application Origin Environmental Impact
Organic Nonpetroleum:Molasses/Sugar BeetExtract
• provides temporarybinding of thesurface particles
• limited availability • not researched • by-product of thesugar beetprocessing industry
• water quality impact:unknown
• fresh water aquaticimpact: unknown
• plant impact:unknown, noneexpected
Organic Nonpetroleum:Tall-Oil Derivatives
• adheres surfaceparticles together
• greatly increases drystrength of materialunder dry conditions
• surface bindingaction may bereduced orcompletely destroyedby long-termexposure to heavyrain, due to solubilityof solids in water
• difficult to maintainas a hard surface
• generally 1 treatmentevery few years
• 10 to 20% residualsolution @ 1.4 to 4.5L/m2 (0.3 to 1.0 g/y2);typical application is40 to 50% residualconcentrate applieddiluted 1:4 w/water@ 2.3 L/m2 (0.5gal/y2)
• distilled product ofthe kraft (sulfate)paper makingprocess
• water quality impact:unknown
• fresh water aquaticimpact: unknown
• plant impact:unknown
Organic Nonpetroleum:Vegetable oils
• agglomerates thesurface particles
• limited availability• oxidizes rapidly, then
becomes brittle
• generally 1 treatmentper season
• application rate variesby product, typically1.1 to 2.3 L/m2
(0.25 to 0.50 g/y2)• the warmer the
product, the faster thepenetration
• follow-up: apply atreduced initialdosages
• some products:canola oil, soybeanoil, cotton seed oil,and linseed oil
• water quality impact:unknown
• fresh water aquaticimpact: someproducts have beentested and have alow impact
• plant impact:unknown, noneexpected
Table 1—Road dust suppressants (continued).
7
Dust SuppressantCategory
Attributes Limitations Application Origin Environmental Impact
ElectrochemicalDerivatives
• changescharacteristics ofclay-sized particles
• generally effectiveregardless of climaticconditions
• performancedependent on fine-clay mineralogy
• needs time to “set-up,” i.e. react withthe clay fraction
• difficult to maintain iffull strengtheningreaction occurs
• limited life span
• generally diluted 1part product toanywhere from 100to 600 parts water
• diluted product alsoused to compact thescarified surface
• typical products:sulfonated oils,ammonium chlorideenzymes, ionicproducts
• need product specificanalysis
• some products arehighly acidic in theirundiluted form
Synthetic PolymerDerivatives
• binds surfaceparticles because ofpolymer’s adhesiveproperties
• difficult to maintainas a hard surface
• generally 1 treatmentevery few years
• 5 to 15% residualsolution @ 1.4 to 4.5L/m2 (0.3 to 1.0 g/y2);typical application is40 to 50% residualconcentrate applied,diluted 1:9 w/water@ 2.3 L/m2 (0.50gal/y2)
• by-product of theadhesivemanufacturingprocess
• typically 40 to 60%solids
• water quality impact:none
• fresh water aquaticimpact: generally low
• plant impact: none• need product specific
analysis
Clay Additives • agglomerates withfine dust particles
• generally increasesdry strength ofmaterial under dryconditions
• if high fines contentin treated material,the surface maybecome slipperywhen wet
• generally 1 treatmentevery 5 years
• typical applicationrate is at 1 to 3% bydry weight
• mined natural claydeposits
• water quality impact:unknown
• fresh water aquaticimpact: none
• plant impact: none
Table 1—Road dust suppressants (continued).
8
Water Absorbing
Organic
Petroleum
Organic
Nonpetroleum
Calcium Chloride
Magnesium Chloride
Blend of Calcium and
Magnesium Chloride
Sodium Chloride
Asphalt Emulsion
Cutback
Dust Oil/Dust Fluids
Modified Asphalt
Emulsion
Lignosulfonate
Calcium Chloride Liquid
Calcium Chloride Flakes
Dowflake
Liquidow
DustGard
Dust-Off
Chlor-tex
Dust Fyghter
Morton Salt
IMC Salt
CSS-1
MC-70
Fuel Oil
Duo Prime Oil
EnviroKleen
Asphotac
Coherex
DOPE-30
PennzSuppress-D
Penetrating Emulsion
Primer (PEP)
Petro Tac
Road Pro
Sandstill
DC-22
Dustac
Dustac-100
CalBinder
Polybinder
RB Ultra Plus
General Chemical
General Chemical
Dow Chemical
Dow Chemical
IMC Salt
Cargill Salt Division
Soil-Tech
Midwestern Industrial Supply, Inc.
Morton International
IMC Salt
Any major asphalt supplier
Any major asphalt supplier
Pacific Northern Industrial Fuels
Lyondell Petrochemical Co.
Midwestern Industrial Supply, Inc.
Actin
Witco Corp.
Morgan Emultech, Inc.
Pennzoil-Quaker State Co.
Koch Asphalt Co.
Syntech Products, Inc.
Midwestern Industrial Supply, Inc.
Energy Systems Associates, Inc.
Dallas Roadway Products, Inc.
Georgia Pacific West, Inc.
Georgia Pacific West, Inc.
California-Fresno Oil Co.
Jim Good Marketing
Roadbind America Inc.
800-668-0433
800-668-0433
800-447-4369
800-447-4369
913-344-9334
800-553-7879
702-873-2023
800-321-0699
312-807-2000
800-323-1641
206-282-4421
800-423-8434
800-321-0699
219-397-5020
800-494-8287
530-241-1364
713-546-4000
909-829-0505
800-537-0288
800-321-0699
703-503-7873
800-317-1968
360-733-4410
360-733-4410
209-486-0220
805-746-3783
888-488-4273
www.genchem.com
www.genchem.com
www.dowcalciumchloride.com
www.dowcalciumchloride.com
www.soil-tech.com
www.midwestind.com
(white mineral oil)
www.midwestind.com
(synthetic iso-alkane)
www.witco.com
www.pennzsuppress.com
www.kochmaterials.com
www.syntechproducts.com
www.midwestind.com
www.dallasroadway.com
(was Lignosite)
www.gp.com/chemical/
lignosulfonate
www.calfresno.com
www.roadbind.com
Suppressant Category Product NameManufacturer or PrimaryDistributor Phone Number Web Site
Table 2—Suppressant manufacturers.
9
Suppressant Category Product NameManufacturer or PrimaryDistributor Phone Number Web Site
Electro-
chemical
Synthetic
Polymer
Emulsions
Dust Down
Dust Control E
Dustrol EX
Road Oyl
Soapstock
Dust Control Agent SS
Bio Cat 300-1
EMCSQUARED
Perma-Zyme 11X
UBIX No. 0010
Road Bond EN-1
Terrastone
CBR Plus
Condor SS
SA-44 System
Settler
TerraBond Clay
Stabilizer
Aerospray 70A
Soil Master WR
Earthbound L
ECO-110
PolyPavement
Liquid Dust Control
Marloc
Soiloc-D
Soil Seal
Soil Sement
TerraBond PolySeal
Top Shield
Amalgamated Sugar Co.
Pacific Chemicals, Inc./
Lyman Dust Control
Pacific Chemicals, Inc /
Lyman Dust Control
Soil Stabilization Products Co., Inc.
Kansas Soybean Association
Indiana Soybean Association
Greenland Corp.
Soil Stabilization Products Co., Inc.
Soil Stabilization Products Co., Inc.
The Charbon Group, Inc.
Enzymes Plus, Div of Anderson
Affiliates
C.S.S. Technology, Inc.
Moorhead Group
CBR Plus, Inc. (Canada)
Earth Sciences Products Corp.
Dallas Roadway Products, Inc.
Mantex
Fluid Sciences, LLC
Cytec Industries
Enviromental Soil Systems, Inc.
Earth Chem Inc.
Chem-crete
PolyPavement Company
Enviroseal Corp.
Reclamare Co.
Hercules Soiloc
Soil Stabilization Products Co., Inc.
Midwestern Industrial Supply, Inc.
Fluid Sciences, LLC
Base Seal International, Inc.
208-733-4104
604-828-0218 or
800-952-6457
604-828-0218 or
800-952-6457
800-523-9992
800-328-7390
800-735-0195
888-682-6040
800-523-9992
800-523-9992
714-593-1034
800-444-7741
800-541-3348
831-685-1148
604-684-8072
503-678-1216
800-317-1968
800-527-9919
888-356-7847 or
318-264-9448
800-835-9844
800-368-4115
970-223-4998
972-234-8565
323-954-2240
561-969-0400
206-824-2385
800-815-7668
800-523-9992
800-321-0699
888-356-7847
800-729-6985
Table 2—Suppressant manufacturers (continued).
www.sspco.org
www.sspco.org
www.sspco.org
www.natural-industrial.com
www.csstech.com
www.terrastone.com
www.cbrplus.com
www.earthscienceproducts.com
www.dallasroadway.com
www.fluidsciences.com
www.cytec.com
www.earthchem.com
www.chem-crete.com/
soilstabilizer.htm
www.polypavement.com
www.enviroseal.com
www.sspco.org
www.midwestind.com
www.fluidsciences.com
www.baseseal.com
Molassas/Sugar Beet
Tall Oil Emulsion
Vegetable Oils
Enzymes
Ionic
Sulfonated Oils
Polyvinyl Acetate
Vinyl Acrylic
Combination of Polymers
10
Suppressant Category Product NameManufacturer or PrimaryDistributor Phone Number Web Site
Clay
Additives
Bentonite
Montmorillonite
Central Oregon Bentonite
Pelbon
Volclay
Stabilite
Central Oregon Bentonite
American Colloid Co.
American Colloid Co.
Soil Stabilization Products Co.,
Inc.
541-477-3351
800-426-5564 or
847-392-4600
708-392-4600
800-523-9992
www.colloid.com
www.colloid.com
www.sspco.org
Table 2—Suppressant manufacturers (continued).
11
Identify Emission Source Requiring Control
Trafficked Is Source Trafficked or Untrafficked? Untrafficked
Paved Unpaved Evaluate Prevention Options
Evaluate Prevention Options Evaluate Prevention Options Develop a Dust Control Plan.(Contact Your Local Air Pollution Control
Authority Office for Assistance)
If Considering Surface Modifications: Determine Traffic Volume and Type
(Passenger Vehicle, Truck, Heavy Equip.)
Develop a Dust Control Plan.(Contact Your Local Air Pollution Control
Authority Office for Assistance)
Proceed with Plan Implementation
Monitor Plan Success; Revise, if Necessary.
Proceed with Plan Implementation
Monitor Plan Success; Revise, if Necessary.
<500 ADT >500 ADT
Evaluate Road Condition
Consider Higher Standard of Surface Treatment:
Chip Seal Coating or Asphalt Paving.Good Poor Upgrade Road
Evaluate Surfacing Materials
Satisfactory Unsatisfactory
No Solution
Still No Solution
Determine Subgrade Type, Climate and Environmental Constraints
Modify or Add Surfacing Materials
Evaluate Chemical Suppressants.Communicate With Vendors and Select Most
Suitable Product(s) for Your Site; See Table 3 for Guidance.
Determine Application Rates and Frequency; See Table 1 for Guidance
Obtain Suppliers Information (Quotes, Instructions, etc.)
Determine Application Procedure and Personnel & Equipment Requirements
Develop a Dust Control Plan. (Contact your Local Air Pollution Control Authority Office for Assistance)
Determine Costs and Benefits and Evaluate Overall Cost Effectiveness of Plan; See Tables 2 & 3 for Guidance
Cost Effective
Proceed with Plan Implementation
Monitor Plan Success and Revise, if Neccesary
Unsatisfactory
Not Cost Effective
Figure 1—Guidelines for cost-effective selection and use of dust palliatives.
12
CalciumChloride
Traffic Volumes, AverageDaily Traffic Surface Material Climate During Traffic
Plasticity Index Fines (Passing 75 m, No. 200, Sieve)
Light<100
Medium100 to250
Heavy>250(1) <3 3–8 >8 <5 5–10 10–20 20–30 >30
(3)
(3)
(3,4)
(3,4)
(3)(6)
(6) (6)
(3,4)
(3)
(6)
(5)
(4)(3,6)(6)
Wet&/or
RainyDampto Dry
Dry(2)Dust Palliative
Petroleum
Lignin
Tall Oil
Vegetable Oils
Electro-chemical
Synthetic Polymers
Clay Additives(6)
MagnesiumChloride
Legend
Notes:
= Good = Fair = Poor
(1) May require higher or more frequent application rates, especially with high truck volumes(2) Greater than 20 days with less than 40% relative humidity(3) May become slippery in wet weather(4) SS-1 or CSS-1 with only clean, open-graded aggregate(6) Road mix for best results
Table 3—Product selection chart.
13
Forest Date
Road Name Estimated ADT
Road Number Average Road Width
Project Location From To Length
Dust Palliative Product First Application Rate
Second Application Rate
A. Road Improvement Costs• Drainage improvements• Geometric improvements• Repair of failed areas• Addition of gravel surfacing
B. Surface Preparation Costs• Addition of select material (fines, etc.)• Break up and loosen, watering, shaping, compacting
C. Product Supply and Application Cost• Material supply• Diluting with water (if necessary)• Transportation & application
D. Miscellaneous Costs• Traffic control, detours• Inspection, supervision• Other costs
TOTAL COST OF PROGRAM
COST EXCLUDING ITEM "A" ABOVE
Item Total Cost Cost/km
Figure 2—Cost record for dust control programs.
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Forest Date
Road Name Estimated ADT
Road Number Average Road Width
Project Location From To Length
Dust Palliative Product First Application Rate
Second Application Rate
A. Reduced Maintenance costs• Estimate 25 to 75% savings over previous blading costs. Use local figures, if available.
B. Reduced Regravelling• Estimate based on traffic volume and climate. Use local figures, if available.
C. Other (intangible)• Reduced vehicle accidents• Reduced vehicle damage• Higher quality of life and property values• Reduced cleaning costs• Reduced dust induced respiratory problems• Reduced sedimentation in water bodies• Reduced impact on dust sensitive vegetation• Reduced complaints from public
TOTAL TANGIBLE BENEFITS OF PROGRAM
Benefits Estimated Savings per Year
Figure 3—Benefits of dust control programs.
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SUPPRESSANT APPLICATION TIPS
Once a suitable product is selected, the next stepis to determine the appropriate application rate andfrequency. Table 1 lists broad ranges of applicationrates for various products and can be used as aguideline. Manufacturer ’s literature, pastexperience, and field or laboratory test plots overa square meter (1 square yard) can also be usedto help determine the appropriate application rate.
Generally, higher application rates or increasedfrequency is required when the following conditionsare present:
• High traffic volumes with high speeds and alarger percentage of truck traffic
• Low humidity conditions, especially whenusing calcium chloride
• Low fines content in road surface, typicallywhen there is less than 10 percent passingthrough the 75 µm (No. 200) sieve
• Poorly bladed surface and/or loose wearingsurface.
General Application TipsThe performance of any dust suppressant isrelated to many application factors. Applicationmethod, rate, frequency, and product concentrationare a few of these factors. A stable, tight surfacethat readily sheds surface water is another. Ifproperly applied and constructed, a longer life andhigher level of service can be expected from thedust abatement efforts (Foley et al. 1996; UMA1987; Washington Dept. of Ecology 1996;Giummarra, Foley, and Cropley 1997). Since dustsuppression and road maintenance efforts areusually combined, it is prudent to include thefollowing practices in the maintenance andrehabilitation of road surfaces prior to applying adust palliative:
• Repair unstable surfacing and/or subgradeareas
• Adequately drain (crown and crossfall) theroad surface
• Remove boney (poorly graded) surfacematerial
• Grade sufficient depth of roadway to removeruts, potholes, and erosion gullies
• Compact the roadway (depending ontreatment and sequence of operations).
Maximum benefits can also be achieved byadequate penetration of the liquid dustsuppressant. This penetration should be on theorder of 10 to 20 millimeters (3/8 to 3/4 inches).Proper penetration mitigates loss of the palliativeresulting from surface wear. Adequate penetrationalso resists leaching, imparts cohesion, and resistsaging (Langdon 1980).
Application tips that apply to all liquid dustsuppressant products include:
• Apply suppressants, especially salts,immediately following the wet season.
• If possible, apply after rain so materials aremoister (aids mixing) and more workable. Ifapplied just before a rain, the material maywash away.
• Adhere to manufacturers’ recommendationson minimum application rate, compaction andcuring time prior to allowing traffic.
• If the surface material is dry, dampen, exceptwhen using cut-back asphalt products.
• If a hard crust is present, break up and loosenthe surface.
• Use a pressure distributor to uniformlydistribute the dust suppressant.
• Ensure that the necessary “residual” of theproduct is obtained. The residual is the amountof product that remains after the evaporationof water from the concentrate, as well as thatused to dilute the product prior to application.The residual (sometimes called solids orbinder) is the portion of the product that isresponsible for the binding and/oragglomeration of the particles.
Water Application TipsRegular, light watering is more effective than lessfrequent, heavy watering.
Chloride Application TipsLight compaction is recommended after a chloridebrine application.
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Petroleum Application Tips
Soil type and density greatly affect the rate andamount of penetration. In all instances, it isdesirable to attain a 12 to 25 millimeter (1/2 to 1inch) penetration. Most products (with theexception of SS- and CSS-1) will penetrate andcoat most soils if they have been loosened byscarification. For surfaces which have not beenscarified, only those products with low viscositieswill penetrate.
Organic Nonpetroleum Application TipsRemove loose material prior to application unlessthe road surface will be mixed and/or compactedafter the spray application. When applyingvegetable oils, the top 25 to 50 millimeter (1 to 2inches) of the surface should be loose to improvepenetration.
Electrochemical Application TipsTypically these products are mixed into the roadsurface.
Polymer Application TipsLight compaction is recommended after a polymerapplication, unless the polymer is mixed into theroad surface.
Clay Additive Application TipsEnsure that the clay and the associated water usedfor compaction is uniformly distributed throughoutthe surface material. This method requires aminimum of 8 passes with a motor-grader or useof a cross-shaft rotary mixer.
All dust suppressants have a limited lifespan andrequire regular applications to satisfactorily controldust on a long-term basis. Subsequentapplications should be made if and when dustlevels exceed acceptable levels. Thesesubsequent applications may be lighter than theinitial application.
ENVIRONMENTAL IMPACTSAny suppressant ingredient may migrate due tocarelessness in application, run-off, leaching, dustparticle migration, or adhesion to vehicles.Carefully review the product literature, MaterialSafety Data Sheet, and manufacturer’s instructionsbefore purchase and use. Observe all safety
precautions and follow manufacturer’s directionswhen handling, mixing, and applying dustsuppressants. Application of all dust suppressantsmust comply with federal, state, and local laws andregulations. These vary by locality and need to bechecked prior to implementing the dust abatementprogram.
The primary environmental concern with dustpalliatives is how they impact the groundwaterquality, freshwater aquatic environment, and plantcommunity. Take all necessary precautions tokeep dust palliative material out of water drainagesand roadway ditches leading to streams.
The impact of dust palliatives on groundwaterquality is based on how the suppressant migratesto the local groundwater table in conjunction withthe chemicals used in the suppressant. Chemicalanalysis of the suppressant will assist indetermining if harmful constituents are present.Knowing the depth to groundwater and thepermeability of the native soil will assist indetermining how and if the chemicals will leach tothe groundwater table. A direct way to evaluate thecontamination of harmful constituents to thegroundwater is to conduct water quality samplingof the surrounding area before and after dustpalliative application.
The impact of dust palliatives on the freshwateraquatic environment is measured by both thetoxicity to fish and the availability of oxygen. Eachstate sets its own standards and they may vary bywatershed and the type and age of the fishpopulation. The test to determine toxicity is theLC50 test and the test to determine availableoxygen is the BOD (Biochemical Oxygen Demand)test. The LC50 test measures the lethalconcentration (LC) of product, expressed in partsper million (ppm), that will produce a 50 percentmortality rate in the test group in 96 hours. Thelarger the concentration, the less toxic the material.Typically, less than 100 ppm is considered toxic,1,000 ppm is considered practically nontoxic, andgreater than 10,000 ppm is considered nontoxic.The BOD test measures the oxygen used bymicrobes as it digests (feeds on) the product inwater. Typically, the products that are derived fromorganic nonpetroleum suppressants are the mostlikely to have high BOD results.
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There are no standard tests for measuring howdust palliatives impact the plant community;however, some tests have been performed thatsimply observe the impact on plant life.
Addo and Sanders (1995) summarize a number ofenvironmental impact studies on the use of variouschlorides on water quality, plants, and animals.Heffner (1997) updates the work by Schwendeman(1981) concerning the environmental impacts ofsome of the most common dust palliatives used bythe Forest Service. Based on their efforts, thefollowing is recommended when using thesepalliatives once or twice a year at their typicalapplication rates:
Lignosulfonate - Determine prior to application ifsignificant migration (water drainage) might occurfrom the treated area into local streams, ponds,and lakes. Ensure that migration will not impactthe oxygen needs of the aquatic community.
Calcium and Magnesium Chlorides - Restrict theuse of chlorides within 8 meters (25 feet) of a bodyof water. In areas of shallow groundwater,determine if significant migration of the chloridewould reach the groundwater table. Restrict theuse of chlorides if low salt tolerant vegetation iswithin 8 meters (25 feet) of the treated area.Typical low-tolerant vegetation includes variousvarieties of alder, hemlock, larch, maple,ornamentals, and pine.
Evaluations of other dust palliatives have not beenmade. If there is concern regarding the impact ofa dust palliative on the environment, then, as aminimum, the LC50 and BOD tests should beperformed. Results can be used to estimate thepotential impact of the dust palliative in questionon the local aquatic and plant communities.
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PAST FIELD OR LABORATORY STUDY REFERENCES
Gifford Pinchot National Forest Study (1988)“Dust Abatement Review and Recommendation,” by Marjorie Apodaca and Don Huffmon (internal report).
Lolo National Forest Study (1992)“Dust Abatement Product Comparisons in the Northern Region,” by Steve Monlux, EngineeringField Notes, Volume 26, May–June, 1993.
Fremont National Forest Study (1991)“Asphotac, A Demonstration of a Dust Palliative,” by Joe Acosta, Jim Bassel, and John Crumrine(internal report).
Larimer County, Colorado Study (1995)“Effectiveness and Environmental Impact of Road Dust Suppressants,” by Jonathan Addo and ThomasSanders, Department of Civil Engineering, Colorado State University, Report No. 95-28A, March 1995.
Forest Service Region Six Laboratory Study (1999)“Laboratory Testing of Nontraditional Additives for Dust Abatement and Stabilization of Roads and Trails,”by Peter Bolander, Transportation Research Board, Proceedings of the 7th International Conferenceon Low Volume Roads, TRR No. 1652, Volume 2, May 1999.
US Army Corps of Engineers Waterways Experiment Station (WES-1993)“Evaluation of Methods for Controlling Dust,” by Richard Grau, Technical Report No. GL-93-25, September1993.
US Army Corps of Engineers Construction Engineering Research Laboratory (1997)“Effectiveness of Dust Control Agents Applied to Tank Trails and HelicopterLanding Zones,” by Dick Gebhart and Thomas Hale, Technical Report 97/69,April 1997.
ONGOING FIELD OR LABORATORY STUDIES
Council for Scientific and Industrial Research (CSIR), South Africa“Holistic Approach to Research into Dust and Dust Control on Unsealed Roads,” by David Jones,Transportation Research Board, Proceedings of the 7th International Conference on Low Volume Roads,TRR No. 1652, Volume 2, May 1999.
Environmental Technology Evaluation Center (EvTEC), Highway Innovative Technology Evaluation Center,Civil Engineering Research Foundation, Washington, D.C.“Dust Control/Road Stabilization Agents” (ongoing study).
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LITERATURE CITED
Addo, J., and T. Sanders. 1995. Effectiveness and Environmental Impact of Road Dust Suppressants,Mountain-Plains Consortium, Colorado State University, MPC Report No. 92-28A.
Bolander, P. 1999. “Laboratory Testing of Nontraditional Additives for Dust Abatement and Stabilization ofRoads and Trails,” Transportation Research Board, Proceedings from the Seventh InternationalConference on Low-Volume Roads, Transportation Research Record No. 1652, Volume 2,Washington D.C.
Bolander, P. 1997. “Chemical Additives for Dust Control-–What We Have Used and What We Have Learned.”In Variable tire pressure, flowable fill, dust control, and base and slope stabilization, TransportationResearch Board, Transportation Research Record No. 1589, Washington D.C.
Foley G., S. Cropley, and G. Giummarra. 1996. Road Dust Control Techniques—Evaluation of ChemicalDust Suppressants’ Performance, ARRB Transport Research Ltd., Special Report 54, Victoria, Australia.
Giummarra, G., G. Foley, and S. Cropley. 1997. “Dust Control—Australian Experiences with Various ChemicalAdditives,” In Variable tire pressure, flowable fill, dust control, and base and slope stabilization,Transportation Research Board, Transportation Research Record No. 1589, Washington D.C.
Han, C. 1992. Dust Control on Unpaved Roads, Minnesota Local Roads Research Board (LRRB), ReportNo. MN/RC-92/07.
Heffner, K. 1997. Water Quality Effects of Three Dust-Abatement Compounds, USDA Forest ServiceEngineering Field Notes, Volume 29.
Langdon, B. 1992. An Evaluation of Dust Abatement Materials Used in Region 6, Transportation ResearchInstitute, Civil Engineering Department, Oregon State University, Research Report 80-3.
Langdon, B., G. Hicks, and R. Williamson. 1980. A Guide for Selecting and Using Dust Palliatives,Transportation Research Institute, Civil Engineering Department, Oregon State University, ResearchReport 80-13.
Lund, J. 1973. Surfacing Loss Study, unpublished, USDA Forest Service, Portland, Oregon.
Scholen, D.E. 1992. Non-Standard Stabilizers, Federal Highway Administration, FHWA-FLP-92-011,Washington D.C.
Schwendeman, T. 1981. Dust Control Study—Part 2—Dust Palliative Evaluation, USDA Forest Service,Gallatin National Forest.
Transportation Technical Assistance Office of the University of Missouri-Rolla. 1986. Operating Tips - RoadDust Suppressants, Northwest Technology Transfer Center, Olympia, Washington.
UMA Engineering Ltd. 1987. Guidelines for Cost Effective Use and Application of Dust Palliatives, Roadsand Transportation Association of Canada, Ottawa, Canada.
Washington Department of Ecology. 1996. Techniques for Dust Prevention and Suppression, WashingtonDepartment of Ecology Fact Sheet, Publication No. 96-433.
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About the Authors…
Pete BolanderPete graduated from Michigan State University with a degree in civil engineering. He has a master’s degree in soilmechanics and foundation engineering from Oregon State University. Pete began his career with the Forest Serviceas a geotechnical engineer on the Willamette NF. After 10 years on the Willamette, Pete moved to the PacificNorthwest Regional Office (Region 6) in Portland, OR as the Regional Pavement Engineer.
Alan YamadaAlan graduated from the University of Hawaii with a Bachelor of Science in Civil Engineering and is a licensedProfessional Engineer in the State of Oregon. He served as a Zone Engineer in Region 2 and on the constructionteam for the Coldwater Visitor Center and the Johnston Ridge Observatory within the Mount St. Helens NationalVolcanic Monument in Region 6. Alan joined the Center in December 1996 and serves as a project leader supportingthe Engineering Program.
Library CardBolander, Peter, ed. 1999. Dust palliative selection and application guide. Project Report. 9977-1207-SDTDC. San Dimas, CA: U.S. Department of Agriculture, Forest Service, San DimasTechnology and Development Center. 20 p.
This publication helps practitioners understand and correctly choose and apply the dust palliativethat is appropriate for their particular site, traffic conditions, and climate. Describes the expectedperformance, limitations, and potential environmental impacts of various palliatives. It isrecommended that this guide be used as a starting point for determining which palliative wouldbe most appropriate for a given situation.
Keywords: dust abatement, palliatives, suppressants
Additional single copies of this document may be ordered from:USDA Forest ServiceSan Dimas Technology and Development CenterATTN: Richard Martinez444 E. Bonita AvenueSan Dimas, CA 91773Phone: (909) 599-1267 x201Fax: (909) 592-2309E-Mail: rmartinez/[email protected]: Richard Martinez/WO/USDAFS
For additional technical information, contact Peter Bolander at the following address:USDA Forest ServicePacific Northwest Region333 SW 1st AvenueP.O. Box 3623Portland, OR 97204Phone: (503) 808-2500Fax: (503) 808-2511
An electronic copy of this document is available on the Forest Service’s FSWeb Intranet at:http://fsweb.sdtdc.wo.fs.fed.us