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Unit 4: Bonding Class Packet
Name:_________________________ Period:__________
DATE TOPIC/ACTIVITY HOMEWORK
Monday 11/4 1. Ionic, Covalent and Metallic Bonds Inquiry Lab
Tuesday 11/5 1. Finish Lab2. Ionic versus Covalent Bonding
Wednesday 11/6 1. Work on Venn Diagram2. Octet Rule
Thursday 11/7 1. Ionic, Covalent and Metallic Properties Quiz
2. Electron Dot Diagrams and Transfer of Electrons
Video Notes: Ionic Bonding & Lewis Structures
Friday 11/8 1. Lewis Structure Practice
Monday 11/11LATE START
1. Lewis Structure Stations
Tuesday 11/12 1. Lewis Structure Quiz2. Start Video Notes
Wednesday 11/13 1. Working with Ions Worksheet2. Introduction to Polyatomic Ions
Thursday 11/14 1. Writing Binary Ionic Formulas 2. Writing Polyatomic Formulas
Friday 11/15 1. Bond with a Classmate Video Notes: Ionic Naming
Monday 11/18 1. Naming Ionic Compounds
Tuesday 11/19 1. Naming Ionic Compounds White Boards
Wednesday 11/20 1. Big Ionic Quiz Video Notes: Covalent Bonding
Thursday 11/21 1. Review Quiz2. Covalent WebQuest
Friday 11/22 1. Covalent WebQuest Finish WebQuest
Monday 11/25 1. Mixed Naming Practice
Tuesday 11/26 1. Mixed Naming Quiz
11/27-11/29 THANKSGIVING BREAK!
12/2 Monday 1. Ionic, Covalent Naming and Formula Review Video Notes: Polarity and IMF
12/3 Tuesday 1. Polarity and Intermolecular Forces
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Unit 4: Bonding Class Packet
12/4 Wednesday 1. Molecular Geometry Lab
12/5 ThursdayBEIERMAN ABSENT
1. Review2. Work on Study Guide
12/6 Friday UNIT 4 EXAM
Bonding Notes
I. Introduction to Chemical BondingA. Ionic Bonding
1. Transfer of electrons2. Attraction between large numbers of + ions and - ions
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Unit 4: Bonding Class Packet
3. Results when there is large electronegativity difference4. Generally, involves a metal and a nonmetal
B. Covalent Bonding 1. Sharing of electron pairs between two atoms2. Results when there is small electronegativity difference3. Generally, involves two or more nonmetal atoms
II. Ionic Bonding – transfer of electronsA. Attraction between cations and anionsB. Generally, between a metal and a nonmetal
1. Most metals are cations (positive ions)2. Most nonmetals are anions (negative ions)
C. Octet Rule1. Atoms lose, gain, or share electrons to have 8 in the outer level
a. (except H, He, they are fine with 2)2. Most compounds follow the octet rule
a. There are exceptions but we will discuss those next unit.
D. Electron Dot Symbol (Dot Diagrams)1. use dots to represent the valence electrons
2. K Mg Al Si
N S Br Ar
III. Ionic Bonding and Ionic CompoundsA. Ionic Compounds
1. Again, generally contain a metal and a nonmetal2. Cations and anions combined so that charges are equal3. Most form crystalline solids4. Represented by a formula unit; simplest ratio of the ions
B. Electron Dot Symbols and Ionic Bonding1. sodium and fluorine
Na + F
atom atom2. magnesium and chlorine
ClMg +
Cl
atom atoms3
Unit 4: Bonding Class Packet
IV. Ions - ReviewA. atoms are neutral because they have equal numbers of protons and electrons, so when they lose or
gain electrons the become charged. B. ions – positive or negative charges atoms that formed when atoms lose or gain electrons
Group Valence Electrons Lose/Gain Charge1 1 lose 1 1+2 2 lose 2 2+
13 3 lose 3 3+14 4 shares None15 5 gains 3 3 -16 6 gains 2 2 -17 7 gains 1 1 -18 8 unreactive none
1. Cations are positive ionsa. metals lose electrons to form + ionsb. Na+ sodium ion lost one electron ( e- )c. Mg 2+ magnesium ion lost two electrons
2. Anions are negative ionsa. nonmetals gain electrons to form - ionsb. monatomic anions have –ide endingc. Cl- chloride ion gained one electrond. O2- oxide ion gained two electrons
3. Transition Metals & Post Transition Metalsa. All metals not in groups 1, 2, & 13b. most have more than one possible chargec. use Roman Numeral to show the charge of transition metals
Fe2+ iron (II) Cu+ copper (I)Fe3+ iron (III) Cu2+ copper (II)
d. Ag+, Zn2+, and Cd2+ have only one possible charge and do not get a Roman Numeral
V. Writing Formulas for Binary Ionic Compounds A. Chemical formulas are chemical symbols that tell what elements are involved in the compound and
the relative proportions1. The subscript (small number) tells you how many atoms of the element involved.
a. H2O – contains 2 hydrogens and 1 oxygenB. Binary contains only two elements (metal + nonmetal)
1. + and – charges must balance2. the positive ion (metal) is written first3. –ide ending usually indicates a binary compound
C. Charge Flip to get formula1. The positive charge on cation becomes the subscript on the anion, and the negative charge on
anion becomes the positive subscript on the cation. a. I.e. Aluminum sulfide
i. Al is +3, sulfide is sulfur, which is -24
Unit 4: Bonding Class Packet
ii. So formula is Al2S3
VI. Writing formulas for other ionic compounds A. When more than two elements are present, then the compound contains a polyatomic ion
1. polyatomic ion – group of atoms that bind covalently but act as one ion2. –ite ending indicates one less oxygen than –ate; the charge will be the same
SO42- SO3
2-
sulfate ion sulfite ion
B. Writing formulas for ionic compounds with polyatomic ions1. The charge flip is still used, you will use parenthesis if subscript is added for the polyatomic ion
(meaning you need more than one of that polyatomic ion)2. Examples
a. sodium carbonate - Na2CO3
b. calcium nitrate – Ca(NO3)2
VII. Naming Ionic Compounds
1. Name of Metal + Name of Nonmetal (-ide ending)a. If a polyatomic ion is present then you name same as before but add polyatomic ion name
for anionName of metal + polyatomic ionPolyatomic ion + name of anion (-ide ending)
2. When a transition metal is present, Roman Numerals are used to show the charge of transition metals (except Ag, Zn, Cd because we know these have a set charge)
a. There is three ways to find charge of transition metali. Do it in your head ii. Reverse charge flip
i. The subscript on nonmetal becomes positive charge on metal. ii. The subscript on metal becomes negative charge on nonmetal.
1. Check nonmetals actual charge. If it does not match, multiply each charge by that factor.
2. Use charge to write Roman numeral.iii. Use the following formula
0 = (x)(subscript of metal) + (charge of anion)(subscript of anion)Where x is the charge on the metal and should be your roman numeral
Introduction to BondingSUBSTANCE GROUP #1:
For each of the following substances, place the symbol of the first element in its spot on the periodic table using red ink. Then, place the symbol of the second element in the substance in its spot on the periodic table using black ink. Then label charges up top!
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Unit 4: Bonding Class Packet
NaCl LiBr KF ZnCl2 Fe2O3 CuI2 Al2S3
QUESTIONS FOR SUBSTANCE GROUP #1:1. Where are all the first elements located on the periodic table (red symbols)?
2. Based on your knowledge about the periodic table, what “classification” would you give these elements? Metal or Non-Metal?
3. Where are all the second elements located on the periodic table (black symbols)?
4. Based on your knowledge about the periodic table, what “classification” would you give these elements? Metal or Non-Metal
SUBSTANCE GROUP #2
For each of the following substances, place the symbol of the first element in its spot on the periodic table using a red ink. Then, place the symbol of the second element in the substance in its spot on the periodic table using black ink. Then label charges up top!
CCl4 P2O5 N2O4 NI3 PBr3 F2Se
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Unit 4: Bonding Class Packet
QUESTIONS FOR SUBSTANCE GROUP #2:1. Where are all the first elements located on the periodic table (red symbols)?
2. Based on your knowledge about the periodic table, what “classification” would you give these elements? Metal or Non-Metal?
3. Where are all the second elements located on the periodic table (black symbols)?
4. Based on your knowledge about the periodic table, what “classification” would you give these elements? Metal or Non-Metal?
TYING IT TOGETHER:1. Group 1 substances are called ionic compounds and Group 2 substances are called covalent
molecules. Write a simple rule that will allow you to classify compounds as ionic or covalent on the basis of what you have learned from the model.
2. Did the subscripts (the little numbers shown in the compound formulas) provide any insight into determining whether a substance is ionic or covalent? Why or why not?
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Unit 4: Bonding Class Packet
ELEMENT EVALUATION:Fill in the following tables identifying the type of element present in the substance. Use “M” for metal, and “NM” for non-metal.
FORMULA 1ST ELEMENT (M or NM) 2ND ELEMENT (M or NM) CLASSIFICATION(Ionic or Covalent?)
NaBr
SF6
CoBr2
BaS
NO2
C6H6
CrCl3
CO2
MnO2
PbCl2
OF2
CsF
Fill in the Venn diagram concerning ionic, covalent, and metallic using the following properties as well as any others you can think of- use PENCIL so that we can make CHANGES!
Burns easily, hard to burn, High melting points, Low melting points, High boiling points, Low boiling points, make crystal structures, electrons are shared, electrons are transferred, delocalized electrons, made of metals, made of non-metals, made of anions, made of cations, named with prefixes, named with roman numerals, large differences in electronegativity, small differences in electronegativity, make alloys, lots of energy to form bonds, has electrostatic attractions, makes molecules, makes polymers, minerals, plastic, conduct electricity when dissolved, conducts electricity as a solid, does not conduct electricity, brittle, electrolyte, non-electrolyte
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Unit 4: Bonding Class Packet
Types of Bonds
Complete the Venn diagram below with properties of ionic and Covalent Bonds:
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Metallic
CovalentIonic
Unit 4: Bonding Class Packet
Bonds formed between two nonmetals are _______________ and involve the ____________ of electrons.
Bonds formed between two metals are _______________ and involve the ____________ of electrons.
Bonds formed between metals and nonmetals are ____________ and involve the ___________ of electrons.
Describe the following as ionic, metallic, or covalent:NaCl _____ Al _____ Lithium _____CO2 _____ C6H12O6 _____ Strontium bromide _____Au _____ Ti _____ Tin (II) chloride _____MgBr2 _____ K2O _____ Nitrogen (IV) oxide _____Fe _____ CH4 _____ Hydrogen selenide _____H2O _____ H2S _____ Copper (II) phosphate _____Ca3(PO4)2 _____ PI3 _____ Lead (IV) nitrate _____
Lewis Structures Introduction
A Lewis structure is a way to represent the valence electrons of an atom using dots. These valence electrons are important because they are involved in
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Ionic Bonds
Covalent Bonds
Unit 4: Bonding Class Packet
bonding. The Lewis structure for an atom is formed by writing the element symbol and placing one dot next to the symbol for each valence electron. For example, the Lewis structure for carbon would have four dots surrounding it, while the Lewis structure of chlorine would have seven.
In a molecule, atoms are held together with covalent bonds. These bonds are formed when pairs of electrons are shared. For example, carbon will bond with four chlorine atoms to form the molecule carbon tetrachloride, CCl4. Each bond in the molecule represents a pair of shared electrons and is represented as a dash. The guiding principle behind bonding in atoms is the octet rule which states that each element is trying to get a full set of valence electrons. When carbon shares electron pairs with four chlorine atoms it has an octet. Each chlorine atom has three nonbonding pairs of electrons and one bonding pair. This arrangement is favorable because both carbon and the chlorine atoms have an octet of electrons
ElementMetal or
Nonmetal?
Lewis Dot Structure
as an ATOM
Gain or lose
electrons?
How many
e-?
Lewis Dot Structure
of Stable ION
Becomes like
which noble gas?
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Unit 4: Bonding Class Packet
Fluorine
Lithium
Aluminum
Sulfur
Radium
Phosphorous
Using your chart, draw Lewis structures for the following compounds:
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LiF Li3P
AlF3 Aluminum Sulfide
Radium Fluoride Radium Sulfide
Li2S
Aluminum Phosphide
Radium Phosphide
Summarize:-Why do metals bond with nonmetals?
-What determines how many atoms of the metal and nonmetal will combine to form the compound?
Unit 4: Bonding Class Packet
Lewis Dot Structures Practice
How many valence electrons do cations show in the Lewis dot diagrams? ____ anions? ____
Draw the following ionic compound.Lewis Diagram Lewis Diagram
NaF CsCl
K2O MgO
Rb3N SrI2
CaBr2 BaS
SrO Fe2O3
Mg3P2 Ag2S
AlI3 CuO
CuS NiCl3
CrN TiO2
MnO2 PtCl2
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Unit 4: Bonding Class Packet
Working with Ions
1. What is an ion?
2. What is a cation?
3. What is an anion?
For each element below, tell how many electrons it would prefer to gain/lose in order to
fulfill the Octet Rule The first one is done for you as an example.
Element Gain or Lose Electrons? Ion Formed Type of Ion
Mg lose 2 electrons Mg2+ cation
Na
F
O
K
Al
Li
Cl
Br
Any Noble Gas
5. What is the “octet rule”?
6. Which elements are “exceptions” to the octet rule?
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Unit 4: Bonding Class Packet
Lewis Structures Part 2Molecules that don’t follow octet rule
There are some cases in which all of the elements in a Lewis structure will not follow the octet rule. Recall that the octet rule states atoms will share valence electrons in a way that gives them a complete set (8). In a few examples the elements have less than octet. Boron trihydride is an example of a compound where an element has less than an octet. Other molecules may contain elements with more than an octet of electrons. In the phosphorus pentafluoride molecule the bonded phosphorus atom has 10 electrons around it. Elements in period 3, 4, 5, and 6 can take extra electrons because they have an empty d orbital available.
Resonance Resonance occurs when more than one valid Lewis structure can be written for a compound. The
nitrate ion, NO3– has a double bond between nitrogen and one of the oxygen atoms. The double bond could form with any of the three oxygen atoms to give a working model of the molecule. Experimentation shows that there are not three distinct models for this ion. Instead there is one structure that is a hybrid of all three – a sort of average. Resonance structures only differ by the placement of their electrons. These Lewis structures are drawn by creating models for each and putting double-headed arrows between each structure.
Draw Lewis Structures for the following. 1. BF3 6. ICl4–
2. AsF6– 7. BeH2
3. ClF3 8. TeF4
4. SF6 9. SnCl3–
5. RnCl2 10. PO43-
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Unit 4: Bonding Class Packet
Bond with a Classmate
You will be given either a positive or negative ion. Your job is to find other people to “bond” with. When you have finished filling in the information for 4 compounds, go to Mrs. Beierman to get a new ion. Then, bond 5 more times. Keep going until you’ve filled in all the blanks below.
Cation Anion Lewis Dot Diagram (Show the transfer of electrons) Final Formula
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Unit 4: Bonding Class Packet
Cation Anion Lewis Dot Diagram Final Formula
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Unit 4: Bonding Class Packet
Writing and Naming Binary Ionic Formulas
1. Na2S
2. Li2O
3. BeO
4. AlCl3
5. AlN
6. MgS
7. Ag2S
8. CaF2
9. MgCl2
10. Al2O3
11. Li3P
12. BeF2
13. K3P
14. Mg3P2
15. CaO
16. NaCl
17. Sr3P2
18. BaO
19. Calcium bromide
20. Potassium phosphide
21. Beryllium fluoride
22. Aluminum oxide
23. Magnesium oxide
24. Strontium phosphide
25. Potassium sulfide
26. Aluminum nitride
27. Beryllium oxide
28. Sodium fluoride
29. Lithium selenide
30. Barium oxide
31. Aluminum sulfide
32. Sodium chloride
33. Aluminum iodide
34. Sodium iodide
35. Rubidium nitride
36. Magnesium carbide
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Unit 4: Bonding Class Packet
Writing and Naming Binary Ionic Compounds (transition metals with single element anions)
1. CuS
2. SnF2
3. PtO2
4. PbO2
5. SbP
6. CuCl2
7. SnCl4
8. Au3P
9. AuAs
10. Cu2O
11. SnS2
12. CrP2
13. FeCl3
14. SnBr2
15. SnI
16. PbS2
17. CuCl
18. BiBr3
19. AuF3
20. Hg3P2
21. Iron (III) chloride
22. Copper (II) oxide
23. Antimony (III) sulfide
24. Mercury (II) oxide
25. Tin (IV) iodide
26. Iron (III) phosphide
27. Cobalt (II) sulfide
28. Platinum (IV) sulfide
29. Nickel (II) oxide
30. Copper (II) bromide
31. Tin (IV) fluoride
32. Manganese (II) chloride
33. Nickel (II) phosphide
34. Cobalt (III) oxide
35. Vanadium (V) sulfide
36. Gold (III) arsenide
37. Mercury (II) phosphide
38. Titanium (III) carbide
39. Tin (II) fluoride
40. Lead (IV) nitride
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Unit 4: Bonding Class Packet
Writing and Naming Polyatomic Compounds (All metals bound to a polyatomic ion)
1. Li2SO4
2. Na2SO4
3. Al(ClO3)3
4. AgNO3
5. MgSO4
6. K3PO4
7. K2CO3
8. LiClO3
9. Sn(SO3)4
10. PbSO4
11. Sn(OH)4
12. AuOH
13. Sb2(SO4)3
14. Cu(NO3)
15. Sr(ClO3)2
16. Pb(ClO3)4
17. Mg(ClO3)2
18. Mg(NO3)2
19. Tin (II) phosphate
20. Uranium (IV) nitrate
21. Magnesium nitrate
22. Magnesium hydroxide
23. Barium sulfate
24. Calcium sulfate
25. Lithium hydroxide
26. Sodium hydroxide
27. Magnesium chlorate
28. Chromium (III) phosphate
29. Copper (II) sulfate
30. Nickel (II) sulfate
31. Mercury (I) chlorate
32. Vanadium (V) carbonate
33. Ammonium sulfate
34. Nickel (II) carbonate
35. Cobalt (II) hydroxide
36. Lead (II) chlorate
Covalent WebQuest
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Unit 4: Bonding Class Packet
Open the following PBS Covalent Bonding tutorial link and answer the following questions as you read through each page: https://pbslm-contrib.s3.amazonaws.com/WGBH/arct15/SimBucket/Simulations/chemthink-covalentbonding/content/index.html
● Page 2-3:How is the movement of electrons different when the atoms are close?
What happens if you try to move the atoms very close to each other?
● Pages 6-9Describe what is happening in a covalent bond.
How is this different from an ionic bond?
● Page 11-13What kind of atoms have the strongest attraction for another atom’s electrons? What is this property called?
*Skip pages 14-20*● Pages 21-24
Fill in the following table:
Type of Bond Number of e- Shared Relative Strength
● Pages 25-35Looking at the examples on pages 32-33, how can you tell that these chemical formulas are covalent and not ionic just by looking at them? In other words:An ionic bond is between a _______________ and a _________________.A covalent bond is between a _________________ and a ________________.
After completing the practice in the tutorial, fill in the missing names or formulas for the following. The prefixes can also be found on the back of your periodic table.
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Unit 4: Bonding Class Packet
Chemical Name Chemical Formula
Antimony tribromide
Hexaboron monosilicide
Chlorine dioxide
Dinitrogen trioxide
SeF6
CH4
NF3
P4S5
Open the following website:https://phet.colorado.edu/sims/html/molecule-shapes/latest/molecule-shapes_en.htmlClick on the “Model” page. Check the “Show Bond Angles” box. Take about 5 minutes and play around with this molecule builder. Get to know some of things you can do with it, then answer the following questions.
1. Build a molecule with two atoms and a single bond. Draw this below:
This shape is called LINEAR. Why do you think this name was chosen?
2. Build a molecule with three atoms and two double bonds. Draw this below including bond angles:
This shape is also called LINEAR. Why do you think this name was chosen?
3. Build a molecule with 4 atoms, 3 single bonds. Draw this below including bond angles:
This shape is called TRIGONAL PLANAR. Why do you think this name was chosen?
4. Build a molecule with 3 atoms, 2 single bonds, and 1 lone pair of electrons. Draw this molecule below including bond angles:
This shape is called BENT. Why do you think this name was chosen?
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Unit 4: Bonding Class Packet
How is this shape similar and different from the trigonal planar shape?
5. Build a molecule with 5 atoms and 4 single bonds. Draw this below including bond angles:
This shape is called TETRAHEDRAL. Why do you think this name was chosen?
6. Build a molecule with 4 atoms, 3 single bonds, and 1 lone pair of electrons. Draw this below including bond angles:
This shape is called PYRAMIDAL. Why do you think this name was chosen?
How is this shape similar and different from the tetrahedral shape?
7. **What happens to the bond angle as more atoms or lone pairs of electrons are added in? Why do you think the atoms do this? (Hint: What else is around the outside atoms that we aren’t being shown?)**
Use the information from number 1-7 above to fill in the chart below:
Number of Atoms
Number of Bonding Areas (single or double bond) Around Central Atom
Number of Lone Pairs Around Central Atom
Sketch of Molecule Shape Name
2 NA NA
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Unit 4: Bonding Class Packet
3 2 0
3
1 or 2 lone pairs
4
4
5
You will be responsible for knowing the shapes above (MEMORIZE THEM) . . . there are also molecules that have 5 or 6 atoms which are shown below.
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Unit 4: Bonding Class Packet
On the bottom of the screen, switch the type to “Real Molecules”. On the top right, there is a drop down box for you to change the molecules. Look through them and decide on the name of the shape for each molecule.
Formula Shape Formula Shape
H2O CH4
CO2 SF4
SO2 XeF4
XeF2 BrF5
BF3 PCl5
ClF3 SF6
NH3
Covalent Bond Practice
1. Fill in the missing information on the chart.
Element # of Protons # of Electrons # of Valence Electrons
Carbon
Hydrogen
Chlorine
Helium
Phosphorus
Oxygen
Sulfur
Nitrogen
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Unit 4: Bonding Class Packet
2. For each of the following covalent bonds: Write the number of valence electrons. Draw the Lewis Structure
a) SiCl3 b) SCl2
c) NOCl d) NCl3
e) COCl2 f) SiF4
g.) O2 h.) CO
i.) I2 j.) AsH3
3. How does the octet rule relate to the electron configuration of a noble gas?
4. Explain the difference between an ionic and covalent bonds.
5. Why do some molecules show resonance structures?
6. Explain the sharing of electrons with respect to polar and nonpolar covalent bonds.
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Unit 4: Bonding Class Packet
7. Rank the intermolecular forces from strongest to weakest.
8. Explain VSEPR theory.
9. Indicate the number of valence electrons and draw Lewis structures for the following. You must show unshared electron pairs.
a. I2 b. OF2 c. CS2
d. OH- e. PO43- f. H3O+
10.Indicate whether the bonds in these compounds are ionic, polar covalent, or nonpolar covalent.
a. KClb. MgF2 c. HCl d. H2O
11. Indicate the number of valence electrons and draw the resonance structures for, carbonate ion CO3
2-.
Write the formula for the covalent compound 12. nitrogen tribromide
13. hexaboron monosilicide27
Unit 4: Bonding Class Packet
14. chlorine dioxide
15. hydrogen moniodide
16. iodine pentafluoride
17. dinitrogen trioxide
18. ammonia (nitrogen trihydride)
19. phosphorus triiodide
20. dihydrogen monoxide
21. diphosphorous pentoxide
Write the names for the following compounds:
22. P4S5
23. O2
24. SF6
25. Si2Br6
26. CCl4
27. CH4
28. B2Si
29. NF3
30. H2O
31. N2O5
Lewis Structure Practice for Covalent CompoundsDraw the Lewis structure for the following ions:
32. ClO4-
33. NH4+
34.SO32-
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Unit 4: Bonding Class Packet
35.N3-
36.OH-
37.BrO3-
38.Draw resonance Lewis structures for NO3-
39.Draw resonance Lewis structures for CO3-2
Mixed Practice Naming
Write the names of the following compounds:
1. PbCl22. SBr2
3. P4H10
4. NaC2H3O2
5. AgNO3
6. Ba(OH)2
7. NH4NO3
8. Na2SO4
9. CuSO4
10. Cu2SO4
11. Fe2(SO4)3
12. C2H6
13. Cr(OH)3
14. Ba(NO3)
15. KMnO4
16. K2CrO4
17. P2O5
18. N2O3
19. CoF3
20. SnI4
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Unit 4: Bonding Class Packet
21. CaO
22. PbCl4
23. Ba(C2H3O2)2
24. PBr5
25. (NH4)3PO4
26. CaCO3
27. NH4C2H3O2
28. AlPO3
Write the formulas of the following compounds:1. iron (II) sulfide
2. copper (I) oxide
3. dinitrogen pentoxide
4. potassium permanganate
5. cesium chloride
6. lead (II) nitrate
7. xenon hexafluoride
8. lithium phosphide
9. lithium phosphate
10. ammonium oxide
11. dinitrogen monoxide
12. tetraphosphorus decoxide
13. magnesium chloride
14. magnesium hydroxide
15. mercury (II) bromide
16. cobalt (II) bicarbonate
17. tin (IV) fluoride
18. ammonium sulfate
19. diarsenic trisulfide
20. barium phosphate
21. aluminum permanganate
22. strontium oxide
23. strontium chloride
24. calcium carbonate
25. calcium sulfide
26. calcium sulfate
27. calcium sulfite
28. potassium nitrate
Bond Polarity Introduction
1 2 13 14 15 16 17 18
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Unit 4: Bonding Class Packet
In the empty spaces of the chart above, fill in the element symbols and electronegativity values. Notice the transition metals are absent.
1. Electronegativity values generally _______________ down a
group and ____________ across a period.
2. Metals tend to have ____________ electronegativity values
and nonmetals are _____________ values.
3. When lithium bonds with fluorine they form an
________________ bond.
a. What is the electronegativity difference of lithium and fluorine that might help characterize the
properties they have? _____
b. List some of the properties:
4. When fluorine bonds with another fluorine atom they form a ________________ bond.
a. What is the electronegativity difference of the two fluorine atoms that might help characterize the
properties they have? _____
b. List some of the properties:
5. When hydrogen bonds with fluorine atom they form a ________________ bond.
a. What is the electronegativity difference of the hydrogen and fluorine atoms that might help
characterize the properties they have? _____
b. List some of the properties:
6. HF and F2 are both ________ compounds, but they actually have some slightly different properties. F2 is
not attracted to an electromagnetic field, where HF is. HF has a high boiling point, but F2 is very low.
Based on the information you obtained so far, what characteristic might cause these differences?
7. Fill in the chart below:
Electronegativity Difference Type of Bond
0.0-0.4
0.5-1.4
1.5-4.0
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Unit 4: Bonding Class Packet
Using your table above find the electronegativity difference for each substance. If more than one bond is formed, find all differences. Then, check which bonds are present.
Substance Electronegativity difference(s) Ionic Covalent Polar NonpolarI2
PCl3SiO2
Br2
CO2
NaClCH4
N2O5
NH3
KClNaNO3
KClO3
Ca(ClO3)2
Molecular Polarity
Fill in the chart below.
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Unit 4: Bonding Class Packet
1. In terms of lone pair electrons, how can you determine if a molecule is polar?
2. What molecular shapes are always polar?
3. What molecular shapes are always nonpolar?
4. How can a molecule be nonpolar if it contains polar bonds?
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