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Unit 2: Study of Matter You may already know why ice floats. Ironically, if the ice was “dry,” it would sink. What explains that?

Unit 2: Study of Matter You may already know why ice floats. Ironically, if the ice was “dry,” it would sink. What explains that?

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Unit 2: Study of Matter You may already know why ice floats. Ironically, if the ice was dry, it would sink. What explains that? Slide 2 Unit 2 Objectives Definitions: matter, element, compound, mixture, (chemical) symbol, heterogeneous, homogeneous, metal, nonmetal, metalloid, physical change, chemical change, nuclear change, Laws of conservation, exothermic, endothermic, Kinetic Molecular Theory, real gas, ideal gas, change of state, phase diagram, triple point, critical point. Differentiate between elements, compounds, and mixtures. Arrange a matter hierarchy. Identify chemical symbols for elements. Separate mixtures physically. Differentiate between hetero- and homogeneous mixtures. Sepearate metallic, nonmetallic, and metalloid elements. Determine the physical and chemical properties of a substance. Distinguish chemical and physical properties from chemical and physical changes. Perform calculations using the Law of Definite Composition. Slide 3 Unit 2 Objectives Pt.2 The Kinetic Molecular Theory (KMT) is based on the idea that particles in matter are always in motion. The KMT can be applied to describe properties of solids, liquids, and gases. Boiling, melting, freezing are among the physical processes that can alter a substances state. How to interpret a phase diagram. Identify the triple point and critical point. (EFS D4) To use systems thinking and systems tools to identify patterns, impacts, and relationships between a products life cycle and the health of the system as a whole. Embed their understanding of the Materials cycle principle in their work. (EFS D5) Articulate how human choices regarding consumption, production, distribution, and disposal of material goods affect our ability to thrive over time. Slide 4 Essential Questions How do the types of substances elements and compounds differ? How do the states of matter differ according to the Kinetic Molecular Theory? GUIDING QUESTIONS: What are the characteristics of elements and compounds? Why cant a compound be separated by physical means? What are the different categories of elements? How do the properties of the general types of elements compare? What are the characteristics of mixtures? What physical means are used to separate mixtures? What are the distinctions between matter and energy? Why are chemical and physical properties important? What is the importance of the Laws of Conservation of Matter and Energy and Definite Composition? How are physical, chemical, and nuclear changes distinguished? What is the Kinetic Molecular Theory of Matter? How can the theory be used to describe matter? How does a real gas differ from an ideal gas? What is a change of state? What occurs when a substance undergoes a change of state? What is a phase diagram and how is it interpreted? Slide 5 Your Take How many atoms are in the body?(P3) What is plasma? What is dark matter? How do we measure how much matter is present? How are they able to organize the elements onto a table? (P5) How is aluminum made? Are there more than the four common states of matter? Can you turn lead into gold by firing other atoms at it? (P7) How do they find new elements? Why could lead be in our water? Cornstarch + Water = ??? Where did the names of elements come from? Slide 6 Castagno Chemistry Challenge II Rules: 1) Do NOT help anyone else. 2) You have a maximum of 10 minutes to complete the challenge. 3) Credit only goes to COMPLETELY correct answers 1 st 2pts, 2 nd 1pt, 3 rd 0pts, 4 th 0pts Questions? Slide 7 The Challenge Organize the matter hierarchy.matter hierarchy Slide 8 What Is Matter? As defined in Unit 1, matter is anything that has mass and occupies space (volume) There are 3 visible in this picture, sort of. Slide 9 Classification of Matter Can it be separated? Pure substances Mixtures Can it be decomposed by ordinary chemical means? Is the composition uniform? CompoundsElements Heterogeneous mixtures Homogeneous Mixtures Forward Slide 10 Mixtures A mixture is a combination of two or more substances. Substances can be elements or compounds. Mixture can be easy to identify or not. Slide 11 Solid - Solid Jewelry alloys Rocks Slide 12 Solid - Liquid Iced Tea Chocolate Milk Aka Powdered-drink mixes Slide 13 Liquid-Liquid Liquid mixture Vinegar and other household liquids Slide 14 Liquid - Solid Mercury in Silver dental amalgam (filling) Slide 15 Liquid - Gas Fog Slide 16 Gas Liquid Carbonated- beverages Slide 17 Gas Gas Atmosphere Slide 18 Mixtures II Separation Anxiety Mixtures can be separated physically Filters based on particle size Distillation based on boiling point Centrifuge based on density Back Slide 19 Homogeneous Mixtures Uniformity throughout the entire mixture. Back Slide 20 Heterogeneous Mixtures Easy to identify different materials within the sample. Different colors stand out Different densities settle into layers Back Slide 21 Pure Substances FIXED composition Each sample (like salt) has the same Composition (make-up) Characteristics (color, density, etc.) Back Slide 22 Compounds Composed of chemically bonded atoms of different elements Individual Molecules (water) Ionic crystals (salt) Back Slide 23 Elements (I) A pure substance composed of atoms that can not be broken down into simpler, stable substances. Slide 24 Elements (II) Symbols Every element is abbreviated with a symbol Saves space on a periodic table Makes writing formulas much easier Some are common or make sense C carbon Al aluminum But some seem very out of place Slide 25 Elements (III) Symbols (II) Challenge #2 Thou fhouldeth puteth thyne notebookf away. Medieval Matching Game Slide 26 Elements (IV) - Identification Challenge #3 Notebooks away! The rare back-to-back challenge! Can you identify the elements as metallic, nonmetallic, metalloid, or the single, very special, undecided one?identify the elements Slide 27 Elements Examples 1) Worlds largest gold bar, 250kg Estimated worth (9/30/13): $10,663,679 ($42.53/g) 2) The Hope Diamond (carbon) Estimated worth: $350,000,000 ($38,461,538/g) 3) Chunks of Boron Estimated worth: $11.14/g (pure) Slide 28 Elements (V) - Metals As challenge #3 revealed, the majority of elements are metallic. Typical properties associated with them Conductors of heat and electricity Malleable (sheets, foils) Ductile (wires) Slide 29 Elements (VI) Nonmetals The second largest category of elements are nonmetallic Opposite properties of the metals Poor conductors of heat and electricity Brittle Typically break instead of flatten into sheets or wires Of course, most nonmetals are gases so how can you flatten a gas anyway? Slide 30 Elements (VIII) Metalloids Just a few elements, located on the staircase, have intermediate properties. Less malleable than metals Less brittle than nonmetals Semiconductors Not as conductive as a metal, more conductive than a nonmetal Slide 31 Elements (IX) Specialty Hydrogen! Typically non- metallic with all associated properties However, it is believed to behave as a metal inside the gas giants Jupiter and Saturn. This metallic form helps explain the massive magnetic fields those planets have. Back Slide 32 Check Yourself Challenge #4 - Notebooks away! Class Quiz Slide 33 The Grand Unified States of Matter The extremely rare double back- to-back Challenge #5 Notebooks out! Describe as much as possible of the 4 examples of matter located on the desks in the classroom. Slide 34 States of Matter So we know there are 4 states of matter but do any others exist? Fundamental (4) Solid, liquid, gas, plasma Non-classical (8*) Glass, plastic crystal, liquid crystal, magnetically ordered (ferro-, antiferro, ferri- magnet), Copolymers, Quantum spin liquids Low-Temperature States (7*) Superfluid, Bose-Einstein Condensate, Fermionic condensate, Rydberg molecule, Quantum Hall State, Strange matter (quark), Photonic matter (formed September 2013) High Energy States (3*) Quark-gluon plasma, color-glass condensate, gravitational singularity (VERY high energy) Other proposed states (6*) Degenerate matter, supersolid, string-net liquid, superglass, dark matter, equilibrium gel Total: 4 + 8 + 7 + 3 + 6 = 28 (source: wikipedia) Slide 35 Kinetic Molecular Theory Every state of matter, from the normal to the strange, have one thing in common: Manner of definition Each state of matter is defined by the movement of the particles within. Slide 36 Kinetic Molecular Theory II The KMT is what describes the movement It can be applied specifically to each state of matter Slide 37 Gas The Kinetic Molecular Theory has 5 distinct points for gases 1) Individual particles are far apart relative to their size 2) Collisions between particles and containers are elastic (no energy loss) 3) Particles are in constant motion 4) No forces of attraction between particles 5) Temperature of the gas depends on the average kinetic energy of the particles Slide 38 Gas II Steam and smoke are good examples. The KMT describes 1) Indefinite shape (only containers define the shape) 2) Indefinite volume (any amount fills a container) Slide 39 Gas III 3) Low density & 4) High compressibility Gas particles are very far apart 5) Fluidity Gas particles always moving Slide 40 Gas IV 6) Expansion (Gas tanks) Volume can grow 7) Diffusion (Scented candle) Spreading through an area 8) Effusion (flat tire) Escape tiny opening Slide 41 Solid What explains solids always keeping their shape? 1) Specific, repeating pattern of atom arrangement 2) Particles vibrate in position Slide 42 Solid II Lack of movement explains 1) Definite volume 2) Definite shape 3) Incompressibility Close arrangement results in 4) Typically high density (solid v liquid v gas of the same substance) Slide 43 Liquid Unlike solids, liquids particles are not in fixed positions They do remain fairly close together This allows a liquid to take any shape Slide 44 Liquid II Shifting positions explains Fluidity, Indefinite shape Closeness of particles means Definite volume Still fairly dense (usually less so than the solid, water is an exception) Relatively incompressible Slide 45 Plasma Typical properties of a gas except most/all particles are ionized (charged) Extremely common, albeit temporarily seen on Earth Slide 46 St. Elmos Fire* A weather phenomenon typically produced during thunderstorms. There needs to be a sustained imbalance Of electric energy often found in places we would consider a lightning rod. When a limit is, reached, the energy is discharged into the glow of fire. Slide 47 STOP! In the name of conservation! Challenge #6 Notebooks closed! There are two major laws (among many) that we encounter in this class. What are they? Slide 48 Conservation of Matter In chemical reactions, matter cannot be created nor destroyed. 20g of reactants will form a minimum and maximum of 20g product. Slide 49 Conservation of Energy The amount of energy present in a system will remain constant. The energy present could cause a change, such as melting of an ice cube, but overall energy is conserved. Slide 50 Ch-ch-changes! Challenge #7 Notebooks away! There are 6 changes of state between solid, liquid, and gas. Name the transition AND the associated change (ie: L -> G) Slide 51 Properties The characteristics of substances are known as properties Physical Chemical Forward Slide 52 Physical Properties Can be described by sight or feel Color Texture or measured without changing the substances identity Melting/Freezing Point, Boiling Point Density Slide 53 Physical Changes When a substance changes form but not identity Crush Tear Rip Boil Freeze Condense Melt Sublimate Deposit Back Slide 54 Chemical Properties Ability of a substance to undergo change to form a new substance Aka identity changes Cannot be determined by simply looking at the substance Slide 55 Chemical Changes The substance undergoing a transformation into a new substance(s) Adding sodium to water causes this Back Slide 56 Physical and Chemical Change Physical Change The substance changes form Melt, Boil, Freeze, Condense, Sublimate, Deposit, Crushed, Torn, Smashed Chemical Change The substance changes identity React, Burn, Oxidize, Reduce Slide 57 Phase Diagrams Challenge #8.1 Notebooks away! Describe what is happening from A to B B to C C to D D to E E to F Slide 58 Phase Diagrams Challenge 8.1 Slide 59 Phase Diagrams Challenge #8.2 Notebooks away! Describe what is happening from A to B B to C C to D D to E E to F Slide 60 Phase Diagrams Challenge 8.2 Slide 61 Phase Diagrams Challenge Answers 8.1 A to B = solid heating B to C = melting C to D = liquid heating D to E = boiling E to F = vapor heating 8.2 A to B = vapor cooling B to C = condensing C to D = liquid cooling D to E = freezing E to F = solid cooling Slide 62 Phase Diagram - Cooling A cool curve is a graph which shows the temperature of a substance decreasing over time. Phase changes that occur during this process are Condensing Freezing Slide 63 Phase Diagram Cooling II Phase changes occur during segments of no temperature change FREEZING CONDENSING Solid Liquid Gas Slide 64 Phase Diagram Cooling III Condensing (Gas to Liquid) The process of a gas becoming a liquid Requires a LOSS of energy (cooling) Freezing (Liquid to Solid) The process of a liquid becoming a solid Requires a LOSS of energy (cooling) Slide 65 Phase Diagram - Heating A heating curve is a graph which shows the temperature of a substance increasing over time. Phase changes that occur during this process are Melting Boiling Slide 66 Phase Diagram Heating II Phase changes occur during segments of no temperature change MELTING BOILING Solid Liquid Gas Slide 67 Phase Diagram Heating III Melting (Solid to Liquid) The process of a solid becoming a liquid Requires a GAIN of energy (heating) Boiling (Liquid to Gas) The process of a liquid becoming a gas Requires a GAIN of energy (heating) Slide 68 Phase Diagram - Review Whether heating (L) or cooling (R), CHANGES IN STATE occur on the FLAT LINES Boiling/Condensing higher Melting/Freezing lower BC MF Slide 69 Phase Diagram - Y Challenge #9 Notebooks away! Slide 70 Phase Diagram - Y Label X, Y, Z, D, and E X Z? Z X? X Y? Y X? Y Z? Z Y? Slide 71 Phase Diagram - Y Label X = Solid Y = Liquid Z = Gas D = Triple Point E = Critical Point X Z = sublimation Z X = deposition X Y = melting Y X = freezing Y Z = boiling Z Y = condensation Slide 72 Phase Diagram Y II Area X is always a solid Area Y is always a liquid Area Z is always a gas On the line = both (equilibrium) Critical Point = liquid state cannot exist beyond this temperature Triple Point = all 3 states of matter in equilibrium Slide 73 Phase Diagram Y III Sublimation (Solid to gas) The process of a solid becoming a gas by SKIPPING the liquid state Requires a GAIN of energy (heating) Deposition (Gas to Solid) The process of a gas becoming a solid by SKIPPING the liquid state Requires a LOSS of energy (cooling) Note: Since the Y-diagram is a pressure/temperature comparison, ANY change can occur by simply altering the pressure.