UNIOLEO FA C0810H Issuance Date: 1-Dec-14 Revision Date: - Version: 1604/1511

Material Safety Data Sheet SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION

1.1 PRODUCT IDENTIFIER

Product Name: Product Description: CAS Number: Formula:

UNIOLEO FA C0810H CAPRYLIC/CAPRIC ACID 124- 07-2 (Caprylic Acid), 334-48-5 (Capric Acid) C8H16O2-C10H20O2

1.2 INTENDED USE OF THE PRODUCT

Use of the Product: : Intermediate for production MCT. Intermediate for industry.

1.3 SUPPLIER DETAIL

Manufacturer: Address:

PT Unilever Oleochemical Indonesia Industrial Estate of Sei Mangkei Huta VI Sei Mangkei Bosar Maligas, Simalungun North Sumatra 21183-Indonesia

1.4 EMERGENCY CONTACT

Emergency Telephone: Quality Department: Tel. +62-6226979000

SECTION 2 : HAZARD IDENTIFICATION

2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE

Classification according to Regulation (EC) No 1272/2008

Skin Irritation/Corrosion: Acute aquatic toxicity: Chronic aquatic toxicity:

Category 1B, H314 Category 3, H402 Category 4, H413

SECTION 2 : HAZARD IDENTIFICATION contd.

2.2 LABEL ELEMENT

Pictogram:

Signal word: Danger

Hazard statement(s): H314: H402: H413:

Causes severe skin burns and eye damage/ Harmful to aquatic life. May cause long lasting harmful effect to aquatic life.

Precautionary statement(s) P264 P280 P301 + P330 + P331 P303 + P361 + P353

P305 + P351 + P338

P273 P310 P405 P501

Wash skin thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED : rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair) : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES :Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue Rinsing. Avoid release to the environment. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container to an approved waste disposal plant.

2.3 OTHER HAZARDS

None.

SECTION 3 : COMPOSITION/INFORMATION OF INGREDIENTS

3.1 COMPONENT

Synonyms: CAS No: EC No:

CAPRYLIC/CAPRIC ACID 124- 07-2 (Caprylic Acid), 334-48-5 (Capric Acid) C8H16O2-C10H20O2

Component Formula Identification

Concentration (%) CAS No. EC No.

Contains: Hexanoic Acid Octanoic Acid Decanoic Caid Dodecanoic Acid

C6H12O2 C8H16O2

C10H20O2 C12H24O2

142-62-1 124-07-2 334-48-5 143-07-7

2055507 2046775 2063764 2055821

0-0.5 55-61 38-44 0-0.5

SECTION 4 : FIRST AID MEASURES

4.1 DESCRIPTION OF FIRST AID MEASURES

General Advice: Inhalation:

Skin contact: Eye contact: Ingestion:

Consult a physician. Show this safety data sheet to doctor in attendance. If breath in, move person into fresh air. If no breathing, give artificial respiration. Consult a physician. Wash off with soap and plenty of water. Consult a physician. Rinse opened eye for several minutes under running water. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED

The most important known symptoms and effects are described in the labelling and or section 11.

4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED

No data available.

SECTION 5 : FIREFIGHTING MEASURES

5.1 EXTINGUISHING MEDIA

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or CC

5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Fire Hazard: Carbon oxides

5.3 ADVICE FOR FIREFIGHTERS

Wear self-contained breathing apparatus for fire-fighting if necessary.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8.

6.2 ENVIRONMENTAL PRECAUTIONS

Avoid discharge into drains, water course or onto the ground.

6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP

Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

SECTION 7 : HANDLING AND STORAGE

7.1 PRECAUTIONS FOR SAFE HANDLING

Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2

7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

Store in cool place. Keep container tightly closed in a dry well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage Storage temperature: Store at maximum 30oC Exposure to ultraviolet light and sunlight must be minimized to prevent quality loss.

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 CONTROL PARAMETERS

No occupational Exposure Limits (OELs) have been establish for this product or its chemical components.

8.2 EXPOSURE CONTROLS

Appropriate engineering controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Provide exhaust ventilation or other engineering control to control the airborne level.

Personal Protective Equipment: Safety glasses

Hand gloves

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION contd.

Eye/Face protection: Skin protection: Respiratory protection

Other Information:

Safety glasses or chemical goggles. Chemically resistant protective gloves. None required for ambient temperature, although an appropriate NIOSH approved air-purifying respirator should be used if a mist or vapor is generated. When using, do not eat, drink or smoke.

SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

Physical state at 20oC: Appearance: Odour: Odour Threshold: pH: Melting/freezing point: Boiling point: Flash point: Evaporation rate: Flammability (solid, gas): Upper/lower flammability or explosive limits: Vapour pressure: Relative Vapour density: Relative density: Water solubility: Partition coefficient : n-octanol/water: Auto-ignition temperature: Decomposition temperature:

Liquid Light yellow Musty rancid No data available No data available ca.7°C 250°C - 300°C ca. 135°C -open cup No data available. No data available. No data available. No data available. No data available. ca. 0,88 g/cm3 at 30°C Slightly soluble in water. Log pow 3.1 > 250 °C No data available.

SECTION 10 : STABILITY AND REACTIVITY

10.1 REACTIVITY 10.2 CHEMICAL STABILITY 10.3 POSSIBILITY OF HAZARDOUS REACTIONS 10.4 CONDITION TO AVOID 10.5 INCOMPATIBLE MATERIAL 10.6 HAZARDOUS DECOMPOSITION PRODUCTS

No data available. Stable under recommended storage conditions. No data available. No data available. Bases, Oxidizing agents. No data available. In event of fire : see section 5.

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1 INFORMATION ON TOXICOLOGICAL EFFECTS

Acute toxicity LD50 Oral-rat: LD50 Dermal-rat: LC50 Inhalation-rat:

Skin corrosion/irritation: Serious eye damage/eye irritation: Respiratory or skin sensitization: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: Specific target organ toxicity= single exposure: Specific target organ toxicity= repeat exposure: Aspiration hazard:

Additional Information:

> 2000 mg/kg (OECD Guideline 434) > 2000 mg/kg (OECD Guideline 434) > 0.1621 mg/L air (nominal), 4 Hours. Corrosive. Irritating. No effect (2.5% dose, 24 h, Guinea pig) Negative, S. typhimurium, OECD Guideline 471 (Bacterial Reverse Mutation Assay) No data available. 1000 mg/kg bw/day (nominal) , rat, OECD Guideline 422 No data available.

1000 mg/kg bw/day (nominal) OECD Guideline 422

(Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test) No data available.

SECTION 12 : ECOLOGICAL INFORMATION

12.1 TOXICITY

Caprylic Acid/Octanoic Acid: LC50 Fish: EC50 Invertebrate: EC50 algae:

Chronic toxicity to fish NOEC (28D):

22 mg/L (exposure time : 96 h, Species : Pimephales promelas, semi-static or flow-through) 128 mg/l (exposure time : 48 h, Species : Hyale plumulosa) 31 mg/l (exposure time : 72 h, Species : Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) 2 mg/l (juvenile fish, OECD Guideline 305 E (Bioaccumulation: Flow-through Fish Test))

12.2 PERSISTANCE AND DEGRADABILITY

Biodegradability: Rapidly bio degradable ( > 72 % in 30 days)

12.3 BIOACCUMULATIVE POTENTIAL

No data available.

12.4 MOBILITY IN SOIL

No data available.

12.5 OTHER ADVERSE EFFECTS

Harmful to aquatic life. May cause long lasting harmful effect to aquatic life. Avoid release to the environmental.

SECTION 13 : DISPOSAL CONSIDERATIONS

13.1 WASTE TREATMENT METHODS

Waste disposal recommendation: Disposal must be made according to official regulation. Do not dump into any sewers, on the ground, or into any body of water.

SECTION 14 : TRANSPORTATION INFORMATION

14.1 UN NUMBER

Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:

3265 3265 3265

14.2 UN PROPER SHIPPING NAME

Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Octanoic) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Octanoic) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Octanoic)

14.3 TRANSPORT HAZARD CLASS(ES)

Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:

8 8 8

14.4 PACKAGING GROUP)

Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:

III III III

14.5 ENVIRONMENTAL HAZARDS

Land transport ADR/RID: Maritime transport IMDG: Air transport IATA:

No No No

14.6 SPECIAL PRECAUTIONS FOR USE

No data available. No Data Available.

SECTION 15 : REGULATORY INFORMATION

INVENTORY LIST

Listed on TSCA (US), DSL (Canada), EINECS (EU), IECSC (China), KECI (Korea), PICCS (Philippines).

SECTION 16 : OTHER INFORMATION

MSDS updated on: 1-Apr-16

MSDS creation date: 1-Jan-15:

MSDS No: UOI-MSDS-QA-006