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    September 2004 NREL/SR-510-36391

    Y.Y. Lee, R.B. Chen, Z. Wu, and J. HayesAuburn UniversityAuburn, Alabama

    Kinetic and ModelingInvestigation on Dilute SulfuricAcid and Hot WaterFractionation of Selected

    Biomass Plan

    May 1997

    National Renewable Energy Laboratory1617 Cole Boulevard, Golden, Colorado 80401-3393

    303-275-3000 www.nrel.gov

    Operated for the U.S. Department of EnergyOffice of Energy Efficiency and Renewable Energy

    by Midwest Research Institute Battelle

    Contract No. DE-AC36-99-GO10337

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    September 2004 NREL/SR-510-36391

    Kinetic and ModelingInvestigation on Dilute SulfuricAcid and Hot WaterFractionation of Selected

    Biomass Plan

    May 1997

    Y.Y. Lee, R.B. Chen, Z. Wu, and J. HayesAuburn UniversityAuburn, Alabama

    NREL Technical Monitor: R. Torget

    Prepared under Subcontract No. XAW-3-13441-01

    National Renewable Energy Laboratory1617 Cole Boulevard, Golden, Colorado 80401-3393

    303-275-3000 www.nrel.gov

    Operated for the U.S. Department of EnergyOffice of Energy Efficiency and Renewable Energy

    by Midwest Research Institute Battelle

    Contract No. DE-AC36-99-GO10337

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    This publication was reproduced from the best available copy

    Submitted by the subcontractor and received no editorial review at NREL

    NOTICE

    This report was prepared as an account of work sponsored by an agency of the United States government.Neither the United States government nor any agency thereof, nor any of their employees, makes anywarranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, orusefulness of any information, apparatus, product, or process disclosed, or represents that its use would notinfringe privately owned rights. Reference herein to any specific commercial product, process, or service bytrade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement,recommendation, or favoring by the United States government or any agency thereof. The views and opinionsof authors expressed herein do not necessarily state or reflect those of the United States government or anyagency thereof.

    Available electronically at http://www.osti.gov/bridge

    Available for a processing fee to U.S. Department of Energyand its contractors, in paper, from:

    U.S. Department of EnergyOffice of Scientific and Technical InformationP.O. Box 62Oak Ridge, TN 37831-0062phone: 865.576.8401fax: 865.576.5728email: mailto:[email protected]

    Available for sale to the public, in paper, from:U.S. Department of CommerceNational Technical Information Service5285 Port Royal RoadSpringfield, VA 22161phone: 800.553.6847fax: 703.605.6900email: [email protected] ordering: http://www.ntis.gov/ordering.htm

    Printed on paper containing at least 50% wastepaper, including 20% postconsumer waste

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    REPORT DOCUMENTATION PAGEForm Approved

    OMB No. 0704-0188

    The public reporting burden for this collection of information is estimated to average 1 hour per response, including the time for reviewing instructions, searching existing data sources,gathering and maintaining the data needed, and completing and reviewing the collection of information. Send comments regarding this burden estimate or any other aspect of thiscollection of information, including suggestions for reducing the burden, to Department of Defense, Executive Services and Communications Directorate (0704-0188). Respondentsshould be aware that notwithstanding any other provision of law, no person shall be subject to any penalty for failing to comply with a collection of information if it does not display acurrently valid OMB control number.

    PLEASE DO NOT RETURN YOUR FORM TO THE ABOVE ORGANIZATION.1. REPORT DATE (DD-MM-YYYY)

    September 2004

    2. REPORT TYPE

    Subcontract Report

    3. DATES COVERED (From - To)

    May 1997

    5a. CONTRACT NUMBERDE-AC36-99-GO10337

    5b. GRANT NUMBER

    4. TITLE AND SUBTITLE

    Kinetic and Modeling Investigation on Dilute Sulfuric Acid and HotWater Fractionation of Selected Biomass: May 1997

    5c. PROGRAM ELEMENT NUMBER

    5d. PROJECT NUMBER

    NREL/SR-510-36391

    5e. TASK NUMBER

    BB04.7610

    6. AUTHOR(S)

    Y.Y. Lee, R.B. Chen, Z. Wu, and J. Hayes

    5f. WORK UNIT NUMBER

    7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES)

    Auburn University

    Auburn, Alabama

    8. PERFORMING ORGANIZATIONREPORT NUMBER

    XAW-3-13441-01

    10. SPONSOR/MONITOR'S ACRONYM(S)

    NREL

    9. SPONSORING/MONITORING AGENCY NAME(S) AND ADDRESS(ES)National Renewable Energy Laboratory1617 Cole Blvd.Golden, CO 80401-3393 11. SPONSORING/MONITORING

    AGENCY REPORT NUMBER

    NREL/SR-510-36391

    12. DISTRIBUTION AVAILABILITY STATEMENT

    National Technical Information ServiceU.S. Department of Commerce5285 Port Royal RoadSpringfield, VA 22161

    13. SUPPLEMENTARY NOTES

    NREL Technical Monitor: R. Torget

    14. ABSTRACT (Maximum 200 Words)

    Subcontractor developed a processing model to evaluate and optimize an NREL-developed biomass pretreatmenttechnology. The technology, taking advantage of the biphasic nature of hemicellulose in pretreatment, is a two-stage,reverse-flow, shrinking-bed system. The contract simulation found that this system could increase sugar yield byabout 5%, with bed shrinkage of 27% and sugar yield of 95% at optimum conditions.